D ILLINOIS UNIVERSITY OF ILLINOIS AT URBANA-CHAMPAIGN PRODUCTION NOTE University of Illinois at Urbana-Champaign Library Brittle Books Project, 2015.COPYRIGHT NOTIFICATION In Public Domain. Published prior to 1923. This digital copy was made from the printed version held by the University of Illinois at Urbana-Champaign. It was made in compliance with copyright law. Prepared for the Brittle Books Project, Main Library, University of Illinois at Urbana-Champaign by Northern Micrographics Brookhaven Bindery La Crosse, Wisconsin 2015THE BOOK op the BALANCE OF WISDOM. AN ESSAY ON DETERMINATIONS OF SPECIFIC GRAVITY BY THE ARABIANS OF THE XIITH CENTURY. Read before the N. Y. Academy of Science May 29th, 1876, by H. CABBINGTON BOLTON, Ph.D. Reprinted from the American Chemist, May1 1876. NEW YORK: JOHN F. TROW & SON, PRINTERS AND BOOKBINDERS, 205-213 East Twelfth Stkeet. 1876.NOTES ON THE EARLY LITERATURE OF CHEMISTRY. BY H. CAKRINGTON BOLTON, PH.D. vn. THE BOOK OF THE BALANCE OF WISDOM. ^ Head before the New Yorh Academy of Sciences May Z 29, 1876. 3 . . ■ . * So rapid are the strides made by science in this £ progressive age, and so boundless is its range, that those who view its career from without find great dif- v . iiculty in following its diverse and intricate pathways, jf1 while those who have secured a footing within the ^ mysterious domain and are free to journey on the ^ same road are often quite unable to keep pace with its fleet movements and would fain retire from the unequal contest. It is not surprising, then, that those actually contributing to the advancement of science, H. pressing eagerly upward and onward, should neglect to look back upon the labors of those who precede 4 them, and should sometimes lose sight of the obliga- ^ tions which science owes to forgotten generations. 2*7 Could the wisdom of the world concealed in the | silent unwritten history of past ages be divulged *5 by a miracle of revelation, how startling and inter- esting would be the wonderful disclosure! Imagina- - tion fails to conceive of the possible social and scien- tific status of the present era, had the named and the unnamed " lost arts " been preserved through all time, . and had the experience of the human race been unin- ^ teiTuptedly handed down to the existing generation, csi The legitimate feeling of exultation and satisfaction . ' enjoyed by oriental scholars when years of painstaking b 3,751 4 research amid the musty records of the past are at length rewarded by a literary and historical discovery of importance, seems to ns comparable to the pleasur- able excitement experienced by the scientists whose investigations of nature are crowned by the determi- nation of a new species, or the establishment of a new law. In this respect, the Egyptologist and the Natu- ralist, the student of ancient history and the student of modern chemistry, have a common purpose, each in his own sphere seeking the truth. Original investigations in the field of history are, however, vouchsafed only to those profound linguists whose erudition and skill in deciphering semi-oblit- erated cryptographs have been the fruit of a lifetime's laborious study ; and these absorbed in their study of the ancient, too often neglect to compare the wisdom of early times with the progress of modern scientific truths, and fail to appreciate the points most valuable to the student of science. Hence the history of science yet remains to be written. This suggestion may be met with references to the works of the savans who, especially in the preceding century, devoted much to the elaboration of historical treatises in their several departments of science ; but these are few in number, and as we believe merely sketch the outlines, the details of which will yet be supplied by some mighty genius at once a linguist, an archaeologist and a scientist. Meanwhile, in default of the erudition which alone allows of critical examination of monumental inscrip- tions, papyri, and original manuscripts, the humble searcher after knowledge must be content to study available translations, notes, and criticisms provided by oriental scholars, and to bring into prominence such materials as his imperfect powers can command. Bearing in mind the great obligations whicfr the exact sciences owe to the Arabian philosophers of the middle ages, it Is not 'surprising that such of their5 works as are made available by the translations of linguists, afford abundant and rich sources of infor- mation to the student of the History of Science. The work named at the beginning of this article forms a remarkable contribution to the early history of the determination of specific gravities^ This "Book of the Balance of Wisdom " is an Arabic treatise on the water-balance, written in the twelfth century, for an account of which the historian of science is indebted to the chevalier N. Khanikoff, sometime Russian Con- sul General at Tabriz, an important city of northern Persia. Mr. Khanikoff having obtained access, in some manner not explained, to a manuscript copy of the Arabic work, translated into the French language copious extracts, and prepared an analysis of its con- tents; these data, together with a transcript of the original Arabic version, he communicated to the American Oriental Society. The Society's Committee of Publication, in preparing the Russian Consul's work for their Journal, translated his notes into English, re- translated the Arabic extracts, and added their own valuable comments. The completed article is found in the sixth volume of the Journal of the American Oriental Society, pp. 1 to 128, published in 1859. The Book of the Balance of Wisdom treats exclu- sively of the balance and of the results attainable by this instrument which has given to modern science so many beautiful discoveries. Its exposition of the principles of the centres of gravity, of researches into the specific gravity of metals, precious stones and liquids, shows these Orientals to have attained to ex* peri mentation, a step in the progressive knowledge of physical truths entirely unknown to the ancients. Be- fore offering such citations from this work as may seem necessary to establish this proposition, we will endeavor to answer two questions which naturally suggest themselves to our readers. What is the date -of the original manuscript, and who was its Author?6 most happily both queries admit of satisfactory replies, based on internal evidence. The dedication of the work proves it to have been composed at the court of the Saljuke Sultan Sanjar who reigned oyer a large part of the ancient Caliphate of Bagdad from a.d. 1117 to 1157. In this introduc- tion, the author appeals to this potentate in the follow- ing fulsome expressions of homage characteristic of the Orientals: 44 Most magnificent Sultan, the exalted Shah of Shahs, the king of subject nations, the chief of the Sultans of the world, the Sultan of God's earth .... the shelter of Islamism and of Muslims, the arm of victorious power . . . . Prince of Believers—may ' God perpetuate his reign and double his power! For his felicity is the illuminating sun of the world, and his justice its vivifying breath." And immediately following this passage, occurs mention of the date: " I sought assistance from his beams of light irra- diating all quarters of the world, and was thereby guided to the extent of my power of accomplishment in this work, and composed a Book on the Balance of Wisdom for his high treasury, during the months of the year 515 of the Hegira of our Elect Prophet Mo- hammed—may the benedictions of God rest upon him and his family, and may he have peace!" This proves the treatise to have been written in the years 1121-1122 a.d. At this period of the world's history we find Arab philosophers cultivating litera- ture and science, while the rest of Europe was just emerging from intellectual darkness. The religious world had scarce recovered from the intense excite- ment aroused by Peter the Hermit and his followers, who led the tumultuous rabble 600,000 strong towards the Holy City; and priests, knights and peasants were preparing with frantic zeal for a Second Crusade. Aboard and H6loise were names which afforded end- less discussions in the cloister and on the hearth. Science was at a low ebb, a century elapsed before7 Albert lis Magnus and Roger Bacon exerted their in- fluence ; and scholastic philosophy, attaining its lof- tiest height, swayed the intellects of the age. The authorship of the Book of the Balance of Wis- dom is easily determined by the fortunate circumstance that the author names himself several times, ''but in so modest a manner as scarcely to attract attention; instead of heralding himself at once, in his first words, after the usual expressions of religious faith, as Arab authors are wont to do, he begins his treatise by dis- coursing on the general idea of the balance " and then simply remarks: " Says al-Khazini, after speaTcing of the balance in general," and proceeds to enumerate the advantages of the balance which he is about to des- cribe. Two other passages in the extracts furnished by Mr. Khanikoff satisfy the Oriental scholars who have examined them that the author is this self- named al-Khazini. Attempts to identify al-Khazini with individuals of historical fame have given rise to differences of opinion, but the weight of evidence is in favor of re- garding him as the same with Alhazen the Arab opti- cian and physiologist. Alhazen seems to have been a native of Persia and to have resided in Spain and Egypt, but of his biog- raphy little is known. He is especially distinguished for his demonstration of the theory of vision, showing that the rays of light are reflected from external ob- jects to the eye and do not issue forth from, the eye to impinge on external things, as up to his time had been taught. This explanation, moreover, was not based on mere hypothesis, but was the result of anatomical investiga- tions as well as of mathematical discussions. Alhazen also explained the astronomical refraction of light, its dependence on the variation of the density of the media traversed, and its influence in producing the phenomenon of twilight. In the discussion of all8 these problems he evinced true scientific greatness. He favored the theory of the progressive development of animal forms, anticipating a doctrine but newly obtain- ing acceptance. Dr. J. W. Draper,* who has been our guide in this connection, says of Alhazen: Though more than seven centuries part him from our times, the physiologists of this age may accept him as their com- peer." The name al-Khazini signifies "related to the treas- urer," which accords with his statement that the work was composed for the royal treasury. The Book of the Balance of Wisdom begins with a dedication to God " the compassionate, the merciful," and a pious statement of the author's religious faith. An introduction, divided into eight sections, then fol- lows ; in the first section, the advantages and uses of the Balance are enumerated in this language: " These advantages are: 1, exactness in weighing; this balance shows variations to the extent of a mithkal, j- or of a grain, although the entire weight is a thousand mithkals, provided the maker has a delicate hand, attends to the minute details of the mechanism, and understands it; 2, that it distinguishes pure metal from its counterfeit, each being recognized by itself without any refining; 3, that it leads to a knowledge of the constituents of a metallic body without separ- ation one from another............; 4, that it shows the superiority in weight of one of two metals over the other in water, when their weight in air is the same, and reversely............; 5, that it makes the sub- stance of the thing weighed to be known by its weight ............; 6............; 7, the gain above ail others-that it enables one to know what is a gen- uine precious stone, such as a hyacinth, or ruby, or emerald, or fine pearl; for it truly discriminates * Hist. Int. Devel. Europe, page 360. t We cannot here undertake to discuss the ancient Arabic system of weights, but merely state that while authorities differ, Mr. Khanikoff, after a careful examination and comparison of modern and ancient standards of weight in Georgia,'Daghistan and elsewhere, ^where Arabic customs have suffered little change, assigns to the mithkal the value of 4.5 grammes. The mithkal, according to Abu-r-Raihan (quoted below) equals 6 daniks; 1 danik=4 tassujs; 1 tassuj=4 grains; and 1 grain =4 barley-corns.9 between these and tlieir imitations or similitudes in color, made to deceive." Then follows the theory of the water balance; and in the fourth section some account of its early history and the well-known narrative of King Hiero's crown. " It is said that the [Greek] philosophers wTere first led to think of setting up this balance and moved thereto by the book of Menelaus * addressed to Domitian, in which he says: 4 O King, there wTas brought one day to Hiero, King of Sicily, a crown of great price, pre- sented to him on the part of several provinces, which was strongly made and of solid workmanship. Now it occurred to Hiero that this crown was not of pure gold, but alloyed with some silver ; so he inquired in- to the matter of the crown, and clearly made out that it was composed of gold and silver together. Pie therefore wished to ascertain the proportion of each metal contained in it, while at the same time, he was averse to breaking the crown on account of its solid workmanship. So he questioned the geometricians and mechanicians on the subject, but no one sufficient- ly skilled was found among them, except Archimedes the geometrician, one of the courtiers of Hiero. Ac- cordingly he devised a piece of mechanism which, by delicate contrivance, enabled him to inform King Hiero how much gold and how much silver was in the crown, while yet it retained its form. This was before the time of Alexander. Afterwards Menelaus [himself] thought about the water-balance and brought out certain universal arithmetical methods to be applied to it; and there exists a treatise by him on the subject. It wTas then four hundred years after Alexander." Al-Khazini takes pains in this sketch of the early history of specific gravity, to establish dates by ref- erence to cotemporaneous individuals, but his chro- nology is evidently at fault. The Hiero alluded to is Hiero II., who died 216 B.C., while Alexander the Great lived more than a century earlier (356 B.c.— 323 B.C.) This Arabic version of the anecdote of Hiero's * A celebrated mathematician who lived in the reign of Trojan, 98— 117 a.d., and author of a treatise on Spherical Geometry.10 crown lacks the piquancy ancl interest of the narrative as originally given by Vitruvius, and is moreover not an accurate transcription; the words " devised a piece of mechanism " convey the impression that Archime- des constructed some peculiar form of apparatus with which to solve the problem. Indeed this story, famil- iar as it is, is not unfrequently erroneously related, even as al-Khazini himself has done, and compilers of text books of natural philosophy, content to copy from each other instead of seeking the original sources, transmit the errors of detail. These reflections are in part suggested by a singular construction given to the narrative in a recent and really excellent text-book on the History of Natural Science, in which the authoress commits the remarka- ble anachronism of representing (in a woodcut) the crown and the metallic masses suspended - in water from spi'iiig-balances of modern appearance and con- struction. To dispel any lingering ideas of this character we here revive the passage in Vitruvius,* " De Architect tara," the original source of the narrative, and in which it appears that the " greatest geometer of an- tiquity " arrived at his results by a comparison of unequal volumes of water obtained by displacement, and not by direct weighings in that liquid. 44 Book IX. Chapter 3. Of the method of detedt- ing silver when mixed with gold." " Though Archimedes discovered many curious mat- ters which evince great intelligence, that which I am about to mention is the most extraordinary. Hiero, when he obtained the royal power in Syracuse, hav- ing, on the fortunate turn of his affairs, decreed a vo- tive crown of gold to be placed in a certain temple to the immortal gods, commanded it to be made of great * Marcus Vitruvius Pollio, a distinguished Roman architect and author, served as military engineer under Julius Caesar in Africa, B.C. 46. His work, "De Architectural1 (written in his old age), comprising ten books, is the only ancient treatise on the subject ex- tant. Of Vitruvius1 biography very little is known.11 value, and assigned an appropriate weight of gold to the manufacturer. He, in due time, presented the work to the King, beautifully wrought, and the weight appeared to correspond with that of the gold which had been assigned for it. But a report having been circulated that some of the gold had been abstracted, and that the deficiency thus caused had been supplied with silver, Hiero was indignant at the fraud, and unacquainted with the method by which the theft might be detected, requested Archimedes would un- dertake to give it his attention. " Charged with this commission, he, by chance, went to a bath, and being in the vessel, perceived that as his body became immersed, the water ran out of the vessel. Whence, catching at the method to be adopted for the solution of the proposition, he immediately followed it up, leaped out of the vessel in joy, and returning home naked, cried out with a loud voice that he had found that of. which he was in search, for, he continued exclaiming in Greek, dvprjua (I have found it out). "After this he is said to have taken two masses, each of a weight equal to that of the crown, one of them of gold and the other of silver. Having prepared them he filled a large vase with water up to the brim, wherein he placed the mass of silver, which caused as much water to run out as was equal to the bulk thereof. The mass being then taken out, he poured in by meas- ure as much water as was required to fill the vase once more to the brim. By these means he found what quantity of water was equal to a certain weight of silver. He then placed the mass of gold in the ves- sel, and on taking it out, found that the water which ran over was lessened, because the magnitude of the gold mass was smaller than that containing the same weight of silver. 4 4 After again filling the vase by measure, he put the crown itself in, and discovered that more water ran over than with the mass of gold, that was equal to it in weight; and thus from the superfluous quantity of water carried over the brim by the immersion of the crown, more than that displaced by the mass, he found by calculation, the quantity of silver mixed with the gold and made manifest the fraud of the manufacturer." * * The Architecture of Marcus Vitruvius Pollio, in ten books. Trans lated from the Latin by Joseph Grwilt, London, 1826, pp. 264, 265.12 Continuing the sketch of the history of the water- balance given by al-Khazini in the fourth section of the Introduction, we find references to several Arabian philosophers, among them the celebrated physician Avicenna (Ibn Bina) who " distinguished [the compo- nents of] a compound scientifically and exactly," and Abu-r-Raihan 44 who took observations on the relations of [different] metallic bodies and precious stones, one to another, as indicated by this balance." Al-Khazini also states that the instrument in ques- tion was called " the Physical Balance " by Moham- med Bin Zakariya of Rai, and it was named i ' the Balance of Wisdom," by the u eminent teacher Abu- Hatim al-Muzaifar Bin Ismail of Isfazar." Abu-r-Raihan alluded to above is often quoted by al-Khazini and deserves our attention. He was a distinguished Arabian astronomer born about 970, and died 1038 a.d. He was a member of the Society of Savans founded in the capital of Kharizm, and of which the eminent physician Avicenna was a shining light. He was the author of a number of works on astronomy, cosmography and physics, one of which entitled "The Book of the Best Things for the Know- ledge of Mineral Substances," and contained in the Ayin-Akbari, or Institutes of the Emperor Akbar, treats of the specific gravity of bodies and of hydro- static methods for determining them. It is this work to which al-Khazini refers. A review of Abu-r-Raihan's treatise has been published by M. J. J. Clement-Mul- let, under the title, " Recherches sur l'Histoire Nat- urelle et la Physique chez'les Arabes." * Since this Arabic manuscript is probably the most ancient work extant which systematically treats of specific gravities, we make another digression and give a brief synopsis of its contents. It contains theoretical explanations of the origin * Journal Asiatique. SerieV.,Vol. xi., p. 879.13 and formation of mineral bodies founded on the views of the Greeks, and particularly on those of Aristotle- According to these views, the variety of the weights of bodies depends upon the dry and the moist exhal- ation from them; air and water are the elements of these vapors, air giving the lightness and water the heaviness. The author then proceeds to describe methods for determining the specific gravity of bod- ies in the following words : '' Scientific men determine by means of water the measure of these differences in weights. They pre- pare a vessel filled with water in which they introduce 100 mithkals of each of the metals; the quantity of water thrown out by each gives the difference in vol- ume and weight, that one which displaces the largest bulk of water has consequently the largest volume but the least density, and that one which displaces the least water is the heaviest." * Abu-r-Raihan gives in tabular form the specific gravity of nineteen substances, nine of which are min- erals and nine are stones. In the following table we annex the values assigned by modern authorities, showing the remarkable accuracy, in most instances, of, the early determinations . TABLE OF SPECIFIC GKAVITIE8. Abu-r-Raihan. ....19.05 ....13.58 ....11.33 ..10.35 Modern Authorities. Gold..., Mercury, Lead... Silver... Bronze., Copper. Brass... Iron Tin..... 8.82 8.70 8.57 7.74 7.3t 19.30 13.568 11.346 10.52 7.79 7.29 3.99 8.90 3.52 2.73 2.75 2.90 2.61 8.05 to 8.95 8.78 8.58 Sapphire...... Oriental Ruby, Ruby......... Emerald...... Pearl......... Lapis Lazuli.. Cornelian..... Amber (?)..... Rock crystal.. 2.56 3.58 3.85 2.75 2.69 2.60 2.53 2.50 3.97 1.08 (?) 2.5814 In tlie third lecture of the Book of the Balance of Wisdom al-Khazini describes a form of specific gravity flask which he calls the "conical instrument of Abu-r-Raihan " and to whom he apparently ascribes the invention. A mere inspection of the accompany- ing cut, a fac-simile of that in the original manuscript, together with the explanations (also from the original), suffices to show its nature and the method of using it. The author remarks that "the instrument is very difficult to manage, since very often the water remains suspended in the lateral tube, dropping from it little by little into the scale of the balance*" This passage shows that Abu-r-Raihan had noticed capillary attrac- ■ tion; it is also certain that he understood that the size of the neck of the instrument alfected the delicacy of the determinations, for he says he would have it " made narrower than the little finger but for the difficulty of removing through a smaller tube the bodies immersed in the water." Al-Khazini's work is made up of eight lectures, each lecture includes several chapters and each chapter has several sections; to give the table of contents entire would undesirably lengthen this article, and we prefer to quote Al-Kliazini's own summary of his treatise as contained in the sixth section of the intro- duction. Place of the pan (of the balance) Tube in the form of a water pipe. Handle of the instrument. Mouth of the instrument. Neck of the Instrument. Perforation.15 " I have divided tlie book into three parts: 1. General and fundamental topics, such as heaviness and lightness; centres of gravity; the proportion of the submergence of ships in water; diversity of the causes of weight; mechanism of the balance and the steelyard; mode of weighing with it in air and in liquids; the instrument for measuring liquids, in order to ascertain which is the lighter and which is the heavier of two, without resort to counterpoises; know- ledge of the relations between different metals and precious stones in respect to [given] volume; sayings of ancient and modern philosophers with regard to the water balance and their intimations on the subject. This part includes four lectures of the book in their order. II. Mechanism of the balance of wisdom; trial of it; fixing upon it of [the points indicating] the specific gravities of metals and precious stones ; adop- tion of counterpoises suited to it; application of it to the verification of metals and distinguishing of one from another [in a compound], without melting or refining, in a manner applicable to all balances; recog- nition of precious stones and distinction of the gen- uine from their imitations or similitudes in color. There are here added chapters on exchange and the mint, in connection wTitli the mode of proceeding, in general, as to things saleable and legal tenders. This part embraces three lectures. III. Novelties and elegant contiivances in the way of balances such as: the balance for weighing dirhams and dinars without resort to counterpoises; the balance for leveling the earth to the plane of the horizon; the balance known as the 1 even balance' which weighs from a grain to a thousand dirhams or dinars by means of three pomegranate counterpoises; and the hour-balance, which makes known the passing hours, whether of the night or of the day, and their fractions in minutes and seconds, and the exact correspondence therewith of the ascendant star and fractions of a degree. This part is in one lecture." In the seventh chapter, which treats of the "Mechan- ism of the Instrument for measuring Liquids____and Application of it according to the philosopher Pappus the Greek," we find a description of a hydrometer." The length of this instrument, which is cylindrical in shape, measures half a hand-cubit; and the breadth is equal to that of two fingers, or less. It is made of brass, is hollow, not solid, and the lighter particles of brass are carefully turned off by the lathe. It has two bases, at its two ends, resembling two light drum-skins, each fit- ted to the end, care- fully, with the most exact workmanship; and on the inner plane of one of the two bases is a piece of tin, carefully fitted to that plane by the lathe, shaped like a funnel, the base of which is the drum- skin itself. The in- strument being thus made, when put into liquid in a reservoir or vessel, it stands upon it in an erect position and does not incline anyway." The author then describes at length, the manner of gradu- ating the instrument, the 'decimal system being employed throughout. He re- marks that the weight of the funnel shaped piece of tin must be varied ac- cording to the den-17 sity of the water assumed as a standard." Tables of the specific gravities corresponding to the marks on the instrument accompany the detailed account of its application. The annexed figure of the hydrometer of Pappus (page 16) does not give a very clear idea of the iostium,ent, and is intended to show chiefly the manner of constructing and graduating it; the details given in the manuscript are so minute, however, that it is evident Pappus' instrument resembled closely that of Gay-Lussac. It was, however, provided with two scales, one with its numbers increasing upwards to indicate the volume submerged in liquids of different density; the other with its numbers increasing down- wards, to. show the specific gravities corresponding to those submerged volumes. The above-mentioned Pappus was an eminent Greek geometer of Alexandria, who flourished about 380 or 400 a.d. Consequently he was a cotemporary of Synesius of Cyrene (378-430 a.d.), in one of whose letters occurs what is ordinarily regarded as the first recorded mention of the hydrometer. It is certainly most interesting to find that al-Khazini's description of Pappus' instrument corresponds very closely with the statements of Synesius, a coincidence not observed by previous writers. Synesius, l< the good bishop of Ptolemais," writing to his instructress,* the fair pagan philosopher and mathematician, the ill-fated Hypatia, and being de- sirous of trying the winesf he is using, says: "My health is so delicate that I need a hydroscope, and I beg you to have one made for me of copper. It is a tube cylindrical in shape and of the form and size of a pipe: on its length it bears a straight line crossed by small lines, by means of which we determine the weight of waters. One end is terminated by a cone, * Not in a letter of Hypatia to Syne&ius, as Hoefer has it in his Hist. Physique, Paris 1872, 12mo. t Draper, Hist. Int. Bevel, Er,roy>e.18 arranged in such a manner that the tube and the cone have the same base. This instrument is called baryl- lion. If you place it in water, point downwards, it stands erect and the divisions that cross the vertical line can be easily counted, and by this means the den- sity of water is determined.* Hoefer, the French Historian of Chemistry, in relating this statement remarks that none of the commentators of the Letters of Synesius were able to explain the nature of this instrument until the mathematician Fermat, in answer to Castelli's request, communicated his view, correctly apprehending the principles and uses of the instrument described. This was in 1628, and now we learn that the Arabian philosophers five centuries earlier were perfectly familiar with the iden- tical instrument mentioned by Synesius. Al-Khazini describes several forms of balances at great length, giving details of construction and em- ployment. One of these balances he ascribes to Ar- chimedes ; and he professes to quote the particulars re- specting it from Menelaus, without however giving the title of the latter's work. Another balance described by our author is that of Muliammed Bin Zakariya of Rai; it-differs from that * Synesius Opera. Ep^t. XV. Lutetia, 1012, 4to, p. 174. BALANCE OF ARCHIMEDES. a. Bowl for gold . b. Bowl for silver. c. Movable weight.19 of Archimedes by tlie introduction of the needle, called by the Arabs the " tongue.1' and by the substi- tution of a movable suspended bowl for the movable weight. Finally, in the fifth lecture, he gives a minute descrip- tion of the Balance of Wisdom according to Abu- Hatim al-Muzaffar Bin Ismail of Isfazar. " He begins by remarking, that the balance being an instrument of precision, like astronomical instruments, such as the astrolabe and the zijassafaih, its whole workmanship should be carefully attended to, He next describes the beam, the front piece, the two 'cheeks' between which the 4 tongue' moves, and the tongue itself." He gives the length of the beam as four bazaar cubits (two meters) and remarks that 4'length of the beam influences the sensibility of the instrument; " it is con- structed of iron or bronze. The balance is provided with five bowls or pans, made of very thin plates of bronze, three of which have the form of hemispheres (see engraving, page 20), one of which is spherical and the remaining one, destined to be plunged into water, is finished with a conical bottom. Two of these bowls bore the name of the 44 aerial" and were perma- nently attached to the beam; another pan was mova- ble on the right arm of the beam ; and the bowl intend- ed to be immersed in water was fastened underneath the aerial bowl of the left arm; this bowl bore the name of the "aquatic" and the spherical bowl was named the " winged." We cannot here enter upon a more detailed exami- nation of this portion of al-Khazini's treatise; suffice it to say, he speaks of the mode of adjusting the bal- ance and of its application to the examination of metals and of precious stones. Al-Khazini distinctly states that in taking the specific gravity of bodies he employed " a determined sort of water similar in den- sity to the Vater ol the Jaihun of Khuwarazm," and further that "we made all our comparisons in oneBALANCE OF WISDOM. On^-third the ste of original drawing.) a. Means of Suspension. /. Air-bowl. i. Winged-bowl. I. Pomegranate counterpoise,, c. Tongue. g. Second air-bowl. Movable bowl. m. Rings of suspension. d. Two cheeks. h. Water-bowl. k. Basin.21 single comer of the earth, namely in Jurjaniyah [a city] of Khuwarazm......and early in the autumnal season of the year.1' The "Jaihun" is the modern river Oxus, and " Khuwarazm" corresponds to the modern province of Khiva. The editor, Mr. Khanikoff, calls special attention to the following passages, which he considers the most remarkable in the whole treatise: "When a heavy body of whatever substance is transferred from a rarer to a denser air it becomes lighter in weight, from a denser to a rarer air it be- comes heavier." (Lect. I. Chap. v. § 1.) " Air-weight cjpes not apparently vary, although there is actual variation, owing to difference of at- mospheres. As regards its water-weight, a body visibly changes, according to the difference between waters of [different] regions, wells and reservoirs, in respect to rarity and density, together with the inci- dental difference due to the variety of seasons and uses. So then the water of some determined region and known city is selected, and we observe upon the water weight of the body, noting exactly what it is, relatively to the weight of one hundred mithkals; and we refer [all] operations to that [result as a standard,] and keep it in mind against the time when we are called upon to perform them, if the Supreme God so wills. In winter one must operate with tepid, not very cold water, on account of the inspissation and opposi- tion tc gravity of the latter, in consequence of which the water-weight of the body [weighed in it] comes out less than it is found to be in summer. This is the reason why the water-bowl settles down when the water has just the right degree of coldness, and is in slow motion, while in case it is hot and moving quickly, or of a lower temperature, yet warmer than it should be, the bowl does not settle down as when the water is tepid. The temperature of water is plainly indicated, 'both in winter and summer ; let these particu- lars therefore be kept in mind." (Lect. Y. Chap. vi. § 5.) An examination of these extracts compels a belief that the Arabian philosophers of the twelfth century knew the air to have weight, though they never applied the means they had discovered of measuring22 it. The sentence in italics leads to the conjecture that they also had some means of determining the tem- perature of water; possibly a form of aerometer was the instrument employed, and they were thus enabled to recognize the fact that the density of water increases in proportion to its coldness. Al-KhazlnFs work contains several tables of the specific gravities of substances determined either by the Balance of Wisdom or by the hydrometer of Pap- pus. In these tables are enumerated fifty substances, nme of which are metals, ten precious stones, thirteen materials of which models were made, and eighteen liquids. The smallness of the list is not surprising, for most of the substances contained in modern lists of specific gravities were entirely unknown to the Ara- bians ; the exactness of the results obtained is marvel- lous, when we take into consideration the coarseness of their means of graduating instruments and the back- ward state of the mechanical arts at that period. The first table comprises the specific gravities of seven metals and two alloys; the results interpreted into our system, together with the values assigned by modern authorities * are found below. For sake of comparison, we also annex the figures obtained by Abu-r-Raihan, from whom it is believed al-Khazini quotes; the slight discrepancies are largely due to different methods of calculation adopted by Clement- Mullet and Khanikoff. Al-Khazini's First Table of Specific Gravities. Substances. Al-Khazini. Abu-r-Raihan. Modern Authorities. Gold [cast]... 19.05......19.05.......... 19.30 Mercury......13.56......13.58..........13.59 Lead........11.32......11.33..........11.34 Silver.......10.30......10.35..........10.52 Bronze ...... 8.82...... 8.82... .8.05 to 8.95 * Cf. Prof. F. W. Clarke's Tables of Specific Gravities, etc. in Constants of Nature, Part I. Smithsonian Miscellaneous Collections, 1873, 8vo.23 Copper...... 8.66.... .. 8.70...... .... 8.78 Brass....... 8.57.... ,8.57...... _____ 8.58 Iron (forged). 7.74.... ... 7.74. 7.79 Tin ......... 7.32..., . .. 7.31...... .... 7.29 It is.interesting to learn that the Arabian physicists fully appreciated the necessity of operating on pure materials and the advantages of averaging the results of many determinations. Thus, al-Khazini says he purified gold by melting it five times, after which it melted with difficulty, solidi- fied rapidly, and left hardly any trace upon the touch- stone : and, after ten trials to obtain the weight of the volume of water displaced by different weights of the gold, he found, for a hundred mithkals of gold, weights varying from 5 mithkals 1 danik and 1 tassuj to 5 mithkals 2 daniks; as mean weight he adopts 5 mithkals 1 danik 2 tassujs, which by calculation yields the figures in the preceding table. Likewise mercury was purified by passing it repeat- edly through many folds of linen cloth. In writing of mercury, he remarks that it is not, properly speaking a metal, but it is " the mother of the metals, as sulphur is their father." This view of the nature of mercury was prevalent among Arabian Chemists, and is found in the writings of Geber (or Djafar) who lived four centuries earlier. Geber writes of mercury: " it is also (as some say) the matter of metals with sulphur,1' * and he does not place it in the same class with metals which he defines as " extensible under the hammer," a property not possessed by mercury under ordinary conditions. In this conception of al-Khazini we find moreover the germs of the doctrine of the transmutation of metals, the basis of that alchemical pseudo-science which subsequently acquired such a wonderful in- fluence over the human race. For if metals have * Geber, Sum of Perfection, Book I, Part III. Chap 6.24 mercury for a mother and sulphur for a father, they are not simple substances, and if compounds, they are capable of artificial preparation and mutual transfor- mation. This is, however, not the only passage con- taining allusions to a belief in transmutation, though no mention occurs of any practical attempts to effect it; the following extract clearly refers to the com- pound nature of metals. " When the common people hear from natural philos- ophers that gold is the most equal of bodies, and the one which has attained to perfection of maturity, at the goal of competition in respect to equilibrium, they firmly believe that it is something which lias gradu- ally come to that perfection by passing through the forms of all [other metallic] bodies, so that its gold nature was originally lead, afterwards became tin, then brass, then silver, and finally reached the perfec- tion of gold." Writing of the precious metals, al-Khazini dis- courses in a philosophical spirit on their universal ap- preciation, in the following language: " 4 Men prize these metals,' says Abu-r-Raihan, .'only because under the action of fire they admit of being made into conveniences for them, Such as vessels more durable than others, instruments of agriculture, weap- ons of war, and other things which no one can dispense with, who is set to possess himself of the good things of life and is desirous of the adornments of wealth.' But if besides the rarity of the occurrence of gold, its durability and the little appearance of moisture upon it, whether moisture of water or humidity of the earth, or of its being cracked or calcined by any fire, and consumed together; with its ready yielding to the stamp, which prevents counterfeiters from passing off something else for it, and lastly the beauty, of its aspect—if there is not [besides all these characteristics] some inexplicable peculiarity pertaining to gold, why is the little infant delighted with it, and why does he stretch himself out from his bed in order to seize upon it? And why is the young child lured thereby to cease from weeping, although he knows no value that it has, nor by it supplies any want? And why do all people in the world make it the ground of being at25 peace one with another, not drawing their swords to fight, though at the sacrifice of the powers of body and soul, of family connections, children, ground possessions, and everything, with even a superfluity of renunciation for the sake of acquiring that; and yet are ever longing for the third stream * to stuff their bellies with the dust ? " This passage is a sample of the simplicity of much of the Book of the Balance of Wisdom; and, occurring in the midst of the purely scientific demonstrations and data, is peculiarly refreshing; the author's testimony to that inexplicable peculiarity of gold which renders it the special object of avarice, leads us to conjecture that had he lived in modern times he would have proved a warm champion of " hard money " doctrines. The second table of specific gravities contains the determinations of various precious stones; it is not possible in every case to identify the stones, and hence some uncertainty obtains with regard to the values : Substances. Specific Gravities. Al-Khazini. Modern Authorities. Celestial Hyacinth_______ 8.96* 4.83 Red Hyacinth......... . .3.85f 3.99 [Ruby] of Badakhshan., 3.58 - Emerald.....,........ . 2.75 2.68 to 2.77 Lapis Lazuli......... 2.69 2.9 Fine Pearl............ 2.60 2.68 Cornelian............. 2.56 2.62 , , 2.56 2.69 Onyx and Crystal...... .2.50 2.63 % to 2.88 § Pharaoh's glass......... 2.49 2.45 | to 3.44** Substances. Specific Gravities. Al-Khazini gives detailed accounts of these pre- Al-Khazini gives detailed accounts of these pre- ♦Alluding, say the editors, to the traditional saying of the Arabians: " If the son of Adam were to possess two flowing rivers of gold and silver, doubtless he would desire a third." * Oriental sapphire. § Roek crystal 2.68 to 2.88. t Oriental ruby. |i English mirror glass. X Onyx 2.63 to 2.81. ** English flint glass. 226 eious stones, of \#iich we quote a few brief extracts. He says: "Emerald and chrysolite are interchangeable names, whether applied to one and the same thing, or to two things of which one has no real existence," a passage which shows that mineralogical terminology was afflicted with superfluous synonyms at an early day. Of the cornelian he says: " Men have long tired of the cornelian, so that it has ceased to be used as a stone for seal-rings; even for the hands of common people, to say nothing of the great." Of the " fine pearl," he writes: " The pearl is not a stone at all, but only the bone of an animal, and not homogeneous in its parts." "Coral," he writes, "is a plant, though petrified like the Jew's stone and the sea-crab." He is aware that " glass is not the product of a mine, but, on the contrary, kindred to stones, or sand, or alkali," and he states that he has included it in the above list, " because it resembles crystal." The third table comprises " the materials of models and patterns formed by goldsmiths, and woods of well known trees." Interpreting the Arabic weights as before, we have the following table: Substances. Specific Gravities. Al-Khazini. Modem Authorities. Clay of Siminjan____ .......1.99. clay 1.068 to 2.63 Pure salt........... .......2.19 2.068 to 2.17 Saline earth........ .......1.11 Sandarach.....______ .......0.71 1.05 to 1.09 Amber............. .......0.85 1.06 to 1.08 Enamel............ . .______8.93 Pitch ..... ......... .......1.04 1.07 Wax__________ _____ .......0.95 0.96 Ivory.............. .......1.64 1.82 Ebony ............. .......1.13 1.18 Pearl shell......... ....... 2.4& 2.64 Bakkam wood...... 1.03 Willow wood....... ... ...0.40 0.58 Substances. Specific Gravities.27 The last table embraces a number of liquids. Substances. Specific Gravities. Al-Khazini. Modern Authorities. Sweetwater.................1. 1. Hot water......................958 .959 Ice.......................... .965 .916 to .926 Sea water............ .......1.041 1.028 to 1.04 Water of Indian melon........1.016 Salt water [saturated solution].. 1.144 1.205 Water of cucumber...........1.017 Water of common melon.......1.0B0 Wine vinegar................ 1.027 Wine....................... 1.022 1.013 Oil of sesame.................915 .992 to 1.038 Olive oil........... ..........920 .917 to .919 Cow's milk..................1.110 1.029 to 1.040 Hen's egg...................1.035 1.09 Honey....................... 1.406 1.450 Blood of men in good health. .1.033 1.053 Warm human urine...........1.018 ) 1 01t Cold human urine............ .1.025 \ ' The temperatures at which the determinations of the "hot water" and " sweet water n were made are not known; the difference of density observed, viz., 0.04166, approximates that between water at 3.9°C. and 100°C., which according to modern physicists is equal to 0.04044. The high specific gravity of cow's milk is note- worthy and may have led al-Khazini and others into lactometrical controversy. Besides these contributions to the knowledge of specific gravities, al-Khazini devotes some attention to certain subjects not closely connected with the main theme. In the third lecture he attempts to calculate the quantity of gold which would compose a sphere equal to the globe of the earth, and arrives at a number of mithkals which requires for expression twenty-nine digits.28 In the same lecture he takes up the problem of the chess-board, of which he supposes the squares to be filled with dirhams, each square containing twice the number in the preceeding; he finds the total number of dirhams to be 18,446,744,073,709,551,615. He then applies himself to ascertaining the dimensions of the treasury In which the treasure should be deposited, and finally quotes the lines of an Arabian poet which fix the time in which one might spend this sum at 200,000,000,000,000,000 years. In the last lecture he describes the methods of ap- plying the balance to leveling and to the measuring of time—of this portion Mr. Khanikoff gives the fol- lowing concise exposition: " The balance level consists of a long lever, to the two ends of which were attached two fine silken cords, turning on an axis fixed at a point a little above its centre of gravity, and suspended between two sight- pieces of wood, graduated. At the moment when the lever became horizontal, the cords were drawn in a horizontal direction, without deranging its equilibrium, and the divisions of the scales of the sight-pieces corres- ponding to the points where the cords touched them, were noted. For leveling plane surfaces, use was made of a pyramid with an equilateral triangular base, and hollow and open to the light, from the summit of which hung a thread ending with a heavy point. The base of the pvramitl thus arranged was applied to the plane which was to be leveled, and earned over this plane in all directions. Wherever the plane ceased to be horizontal the joint deviated from the centre of the base. " The balance-clock consisted of a long lever suspended similarly to the balance-level. To one of its arms was attached a reservoir of water, which, by means of a small hole perforated on the bottom of it, emptied itself in twenty-four hours. This reservoir, being filled with water, was poised by weights attached to the other arm of the lever, and in proportion as the water flowed from it, the arm bearing it was lifted, the weights on the other arm slid down, and by their distance from the centre of suspension indicated the time which had elapsed."29 Further analysis of the contents of this extraor- dinary work is incompatible with our reader's patience, and jet many points of interest demand at least a passing notice; these may, however, be embodied in a summary of the principal propositions contained in this treatise, and the recapitulation may serve to jus- tify in some measure this Contribution to the Early History of Chemical Physics. 1. The Book of the Balance of Wisdom shows the Arabian philosophers of the twelfth century to have entertained advanced views regarding attraction. They recognized gravity as a force, and attributed to it a direction towards the centre of the earth; they also knew that it diminishes with the distance, but they erroneously supposed this diminution to be in the direct ratio of the distance and not as its square. 2. They were acquainted with the connection be- tween the weight of the atmosphere and its increasing density, since mention is made of the loss of weight of a body weighed in a denser atmosphere. 8. They understood the theory of centre of gravity, and applied it to the investigation and construction of balance, and steelyards. 4. They made frequent use of the hydrometer, which they inherited from antiquity, and possibly they employed this instrument as a thermometer for dis- tinguishing by variations of density the different tem- peratures of liquids. 5. They observed the action of capillary attraction. 6. They compiled full and accurate tables of the specific gravities of most of the solids and liquids with which they were acquainted. 7. Their system of philosophy was founded on ex- periment and observation. In conclusion, we quote the following appropriate remarks from M. KhanikofTs introduction: " The history of the sciences presents to us an in- contestable fact of deep significance: the rediscov-30 ery in modern times of truths laboriously estab- lished of old; and this fact is of itself enough to indicate the necessity of searching carefully in the scientific heritage of the past after all that it may be able to furnish us for the increase of our actual know- ledge ; for a double discovery, necessarily requiring a double effort of human intellect, is an evident waste of that creative force which causes the advance of humanity in the glorious path of civilization." School of Mines, Columbia College, New Yobk, May, 1876.This book is a preservation facsimile produced for the University of Illinois, Urbana-Champaign. It is made in compliance with copyright law and produced on acid-free archival ! 60# book weight paper which meets the requirements of ANSI/NISO Z39.48-1992 (permanence of paper). Preservation facsimile printing and binding by Northern Micrographics Brookhaven Bindery La Crosse, Wisconsin 2015