p$f m$m&m'$wt t $M LIBRARY OF THE UNIVERSITY OF CALIFORNIA. Class PRODUCER GAS. THE SCIENTIFIC PUBLISHING CO PRODUCER GAS. A SKETCH OF THE PROPERTIES. MANUFACTURE, 5EOUS FUEL. Net BooK. CL This book is supplied to the trade on terms which do not allow them to a discount to the public. F.LC., F.C.S., .'and Technical College; Past-President West of Scot' and Iron and Steel Institute; Author of "Fuel," "The Metallurgy of Iron and Steel," &c., &c. PRICE, 1Os. NET. MANCHESTER : THE SCIENTIFIC PUBLISHING COMPANY. {ALL RIGHTS RESERVED.} SCIENTIFIC PUBLISHING CO PRODUCER GAS. A SKETCH OF THE PROPERTIES, MANUFACTURE, AND USES OF GASEOUS FUEL. BY A. HUMBOLDT SEXTON, F.I.C., F.C.S., Professor of Metallurgy in the Glasgow and West of Scotland Technical College . Past-President West of Scotland Iron and Steel Institute; Author of " Fuel" " The Metallurgy of Iron and Steel," <&c., 20 ' 65 5 \ Nitrogen, 77-68 Variation in the Volumes of Gases. It must be borne in mind that the volume of a gas changes very considerably with changes of temperature and pressure, and therefore that when weights of gases are compared it must always be under the same conditions of temperature and pressure. As, however, all gases are affected in the same proportion, the percentage composition by weight or volume is not altered, however much the actual weight of a given volume may vary. When weights of gases are given it is always the weight of a standard volume under normal temperature and pressure, i.e., C. (32 F.), and 760 mm. of mercury (30") barometric pressure. Volumes of gases at any other temperature or pressure must always be reduced by calculation to these conditions. The pressure to which a gas is subjected is measured either by the height of a column of mercury which it will support, measured in inches or millimetres, or, what is the same thing, if it be at the atmospheric pressure, the 8 PRODUCER GAS. height at which the barometer stands, or by the pressure in pounds or other units per square inch to which it is subjected above the atmospheric pressure*. Boyle's Law. The law according to which the volume of a gas varies with the pressure to which it is subjected is called Boyle's law, and may be simply stated " The volume occupied by a given mass of any gas is inversely proportional to the pressure to which it is sub- jected." Or if it is put into the form of an equation : If V be the volume of gas at pressure P, and V be the volume at pressure P f . Then F : F ; : P' : P. Whence F = V'P'jP and V = VP/P'. From these equations the required volumes are easily calculated. Example 1. A mass of gas occupies a volume of 10 cub. ft. when the barometer stands at 30in., what volume will it occupy if the pressure falls to 29in. ? Obviously with decreased pressure the volume will be larger. OA Example 2. A mass of gas occupies a volume of 10 cub. ft. when the pressure is 29in.. what volume will it occupy at 30in. ? Obviously the volume will be less. 9Q F=10 x ^ = 9-67 cub. ft. oU Example 3. A volume of gas occupies 100 cub. ft. at atmospheric pressure, what volume will it occupy at a * Atmospheric pressure is always measured by the height of the column of mercury which it will sustain, this being called the barometric pressure. It may be measured either in inches or millimetres, and the one is very easily converted into the other. (1) To convert inches into millimetres, multiply by 25'4. (2) To convert millimetres into inches, multiply by 0'03937 = about A. The barometric pressure measured in inches, multiplied by - 4908, will give the pressure in pounds per square inch. The barometric pressure in millimetres, multiplied by 0'01932, will give the pressure in pounds per square inch. In some cases the pressure is measured in inches of water. The specific gravity of mercury (water = 1) is 13'58, so that To convert pressure measured in inches of merciiry into pressure measured in inches of water, multiply by 13 '58. To convert pressure in inches of water into pressure in inches of mercury, multiply by 0'07364. PRODUCER GAS. 9 pressure of 51bs. per square inch above atmospheric pressure ? Here again the volume will obviously be less. T7 , 100 x 15 1500 -T5T5- -20- !=75cub ' ft - As the volume varies inversely as the pressure it is quite evident that the density, that is, the weight of a given volume, must vary directly as the pressure, so that if D be the density at a pressure P and D f P' D : D' :: P : P and D=D' x PjP and D'=D x P '/P Example 4. A cubic foot of air weighs -08071b. when the pressure is 760mm., what will be the weight of a cubic foot under a pressure of 900mm. Obviously the weight will be greater. Charles' Law. The law which connects the change of volume of a gas with change of temperature is known as Charles' law. It may be stated in several ways, the simplest probably being as follows : Gases expand ^1^ of their volume at C. for each 1 C. rise of temperature, and I T of their volume at 32Fah. for each 1 Fah. rise of temperature, so that 273 volumes at C. 491 volumes at 32 Fah. 273 + 1 at 1 C. 491 + 1 at 33 Fah. 273 + 2 at 2 C. 491 + 2 at 34 Fah. 273 - 2 at - 2 C. 491 -- 2 at 30 Fah. and in general 273 t 491 t at t Fah. at t C. A proportion, therefore, will give the volumes at any temperature. If V be the volume at C., and V be the volume at t C., then V : V : : 273 : 273 + t (273 V = ' 273 x 273 273 + t Example 5. A mass of gas occupies a volume of 100 cub. ft. at 20 C., what volume will it occupy at C. ? 10 PRODUCER GAS. v 100 x 273 27300 273 + 20 : -293-= =93-17 cub. ft. A temperature 273 below C. or 491-32=459 below Fah. is called the absolute zero, and temperatures measured from this point are called absolute temperatures. So that the absolute temperature in C. degrees will be the temperature measured on the ordinary scale + 273, and similarly the absolute temperature in Fah. degrees will be the ordinary temperature + 459. From the equations given above it follows that the volume of gas is propor- tional to its absolute temperature. As the volume is directly, the density or weight of a given volume will obviously be inversely as the absolute temperature. When corrections have to be made for both tempera- ture and pressure, one correction may be made first, and then the other, using the corrected volumes as the starting point, or both corrections may be made together. Example 6. A mass of gas occupies 100 cub. ft. at 10 C. and 750mm. bar., what will its volume be at Q C. and 760 mm. bar. ? (1) Taking the pressure first. As the pressure is greater the volume will be less. 760 : 750 : : 100 : x = 98-68 ' (2) As the temperature is less the volume will also be less. 273 + 10 : 273 : : 98'68 : x 273 x 98-68 273 + 10 : 95 ' 19 or the two equations may be combined and worked as a compound proportion. 760 : 750 \ 283 : 273 J : : J _ 750 x 273 x 100 760 x 283 The student should make himself quite familiar with these methods of calculation.* *See the author's "Home Work on Chemistry." Hall, Is. PRODUCER GAS. 11 Calculation of the Composition of Gases by Weight. Analyses of gases are almost invariably stated in percentage by volume, since gases are usually measured and not weighed. For many purposes this is quite convenient, but it is often necessary to calculate the percentage composition by weight, and this can be readily done from an analysis by volume using the data already given. An example will make the method quite clear. The following figures represent the composition of a sample of producer gas by volume : Hydrogen Marsh gas Ethylene ... Carbon monoxide . Oxygen Carbon dioxide ... Nitrogen ... 100-00 If we assume the total 100 to stand for 100 cub. ft. then the percentage of each constituent will stand for cubic feet in the hundred, and by multiplying these figures by the weight of 1 cub. ft. (see above) the weight of each constituent in 100 cub. ft. will be obtained. 9-601 3-60 1 101 21-60 J 1-50] 5-00 58-60 J 1 Combustible, 34-90. Diluent 65-10 Hydrogen Marsh gas Ethylene Carbon monoxide Oxygen Carbon dioxide Nitrogen 9-60 3-60 10 21-60 1-50 5-00 58-60 X x X X x x x 0056 0447 0784 0781 0893 1227 0784 05371b. 16091b. 00781b. l-68691bs. 13391b. 61351b. 4-59421bs. 100 cub. ft. = 7-25091bs. One cubic foot therefore weighs -0725091b. From these figures the percentage composition by weight can be easily calculated. Thus : Of hydrogen 7'25091bs. of the gas contains 05371b., so that the amount in lOOlbs. will be 0537 x 100 *. 12 PRODUCER GAS. Working out the other items in the same way Per cent, by weight. Hydrogen ... ... ... ... -74 Marsh gas ............ 2-22 Ethylene .......... \. -11 Carbon monoxide ... ... ... 23*27 Oxygen ... ... ... ... 1*85 Carbon dioxide ... ... ... 8*47 Nitrogen ............ 63*34 100-00 If it be not desired to obtain the weight of 100 cub. ft., but only the percentage composition by weight, the result can be obtained more simply by multiplying the per- centage, of each gas, by volume by its specific gravity, and then working out the percentage as before. As the specific gravity of a gas is always half its molecular weight, these numbers using the approximate molecular weights, which are always round numbers can be used. It must be noted that for various reasons the densities of gases, as deduced from their chemical composition, do not always agree exactly with the figures determined by direct experiment. The former are taken in most of the calcula- tions given here. Per cent. Hydrogen ... 9*60 x 1 = 9*60 = -74 Marsh gas ... 3-60 x 8 = 28'80 = 2-22 Ethylene ...... -10 x 14 = 140 = -11 Carbon monoxide... 21-60 x 14 = 302-40 === 23-32 Oxygen ...... 1-50 x 16 = 24-00 - 1-85 Carbon dioxide ... 5'00 x 22 = 110*00 == 8'48 Nitrogen ...... 58-60 x 14 = 820-40 = 63-27 The small percentage of hydrogen by weight compared with its large percentage by volume is noteworthy. Amount of Air required for Combustion. Since the air is usually measured, not weighed, this can be obtained from the volume composition of the gases. The volume of oxygen required for the combustion of each of the constituent gases has already been given, and by multiplying the percentage of each gas by the volume of oxygen required for the complete combustion of one volume, taking the gas, the analysis of which has already been given, and adding the results, the amount of oxygen required for 100 cub. ft. will be obtained. PRODUCER GAS. 13 Gas by vol. ... 9-60 x ... 3-60 x 10 x ... 21-60 x ... 5-00 ... 58-60 1-50 2 3 Cubic feet. Hydrogen 9'60 x -5 = 4'80 Marsh gas 3'60 x 2 --= 7-20 Ethylene -10 x 3 = '30 Carbon monoxide 21-60 x -5= 10-80 Carbon dioxide Nitrogen Oxygen io~(M)0~ 23-10 Amount of oxygen required for combustion of 100 cub. ft. ... ... 23-10 Less oxygen in gas ... ... ... ... 1*50 21-60 As air contains 21 per cent, by volume of oxygen, the volume of air which will contain 2 1*60 parts of oxygen will be 21-60/21 x 100 == 102-85 cub. ft. at C. and 760mm. bar., and this amount will therefore be required for each 100 cub. ft. of gas at the same temperature and pressure. In practice, an excess of 5 to 50 per cent, over this amount must be allowed. The same results could have been obtained from the percentage by weight, but in that case the weight of air would have been obtained. The Volume and Weight of Products of Combustion. The volume of the products of combustion can be easily obtained, it being of course assumed that they leave the furnace at a temperature above 100 C., so that the water is in the form of steam. Vol. of water for one part by vol. of gas. Vol. of CO 2 for one part by vol. of gas. Vol. H 2 O. Vol. C0 3 . Hydrogen Marsh gas 9-60 3-60 3-60 X 1 x2 X 1 9-60 7-20 3-60 Ethylene 10 10 x2 x2 20 20 Carbon monoxide 21-60 X 1 21-60 Carbon dioxide 5-00 5-00 Nitrogen Oxygen 58-60 1-50 - 17-00 30-40 14 PRODUCER GAS. So that 100 cub. ft. of the gas will yield Water (steam) 17-00 cub. ft. Carbon dioxide ... ... 30*4 Nitrogen (from gas) ... ... 58*6 ,, (from air) 81-25 Excess of air, say, 25^ N. ... 20-31 O. 5-40 Total products of combustion for 100 cub. ft. of gas at the same temperature and pressure ... 212-96 The weight of the products of combustion can be calculated from the volume thus obtained, or from the percentage composition of the gas by weight, the latter being in general the most convenient. If the weight of the oxygen used be known, the weight of the products of combustion can be easily calculated. It will be the sum of the weights of the gas consumed, the oxygen required for combustion, the nitrogen mixed with this oxygen in the air, and the excess of air mixed with the actual products of combustion. In the case of the gas already considered the oxygen required by weight for each lOOlbs. of gas will be 28*451bs. -l*851bs. present in the gas=26*601bs., and the products of combustion for each lOOlbs. will be Water ............ 11-77 Carbon dioxide ... ... 51-46 Nitrogen from gas ... ... 63*34 Nitrogen from air ... ... 89*04 o^o/ fN ... 22-26 25^ j Q 6>65 IT c Excess of air CHAPTER II. THERMAL UNITS. HEAT OF COMBUSTION. CALORIFIC POWER. CALCULATION OF THE CALORIFIC POWER OF FUELS. CALORIFIC INTENSITY. TEMPERATURE OF COMBUSTION. HEAT CARRIED AWAY BY PRODUCTS OF COMBUSTION. HEATING BY CONTACT AND BY RADIATION. EVERY chemical change is attended with either the evolution or the absorption of heat, and when in any chemical change the amount of heat evolved is sufficient to cause the production of light, combustion is said to take place. In some cases, however, the action is complex, and whilst the ultimate result is heat evolu- tion, there may be intermediate changes in which heat is absorbed, and the final result will be the algebraic sum of all the thermal changes that have taken place. The heat is always measured in units, the unit being the amount of heat required to produce some definite change, usually to heat a given mass of material through a definite range of temperature. There are thus three things to be selected in order to determine the unit, viz., the substance to be heated, the weight to be taken, and the temperature through which it is to be raised. The material used is always water ; the weight is lib., 1 gramme, or 1 kilogramme, according to the system of weights being used, and the temperature is one degree on either the Centigrade or the Fahrenheit scale. As it does not follow that the amount of heat required to raise lib. of water 1 will be the same at all parts of the scale, it is necessary to define at what temperature the experiment is to be made. The difference in the amount of heat required for any ordinary range of temperature, say between to 20 C., is so small that for all practical purposes the temperature may be disregarded. Three units are in use : (1) The amount of heat required to raise lib. of water 1C. This is called the centigrade unit (C.U.), and will usually be used in this book. 16 PKODUCER GAS. (2) The amount of heat required to raise lib. of water 1F. This is called the British thermal unit (B.Th.U.), and is commonly used by engineers and other practical men in this country. It will be seen that in these two systems the weight of water is the same, the degree being the only variable, and therefore the value of the units must be directly proportional to the degree used. As the centigrade degree is larger than the Fahrenheit degree in the proportion of 9 : 5, the centigrade unit will bear the same ratio to the Fahrenheit unit. As an amount of heat expressed in any given set of units will vary inversely as the size of the units, an amount of heat expressed by x C.U. units will be 9/5 x B.Th.U., and any amount of heat expressed by y B.Th.U. will be expressed by 5/9 y C.U. (3) The amount of heat required to raise one kilo- gramme of water 1C. is called a calorie, and that required to raise one gramme of water 1C. is called a gramme- calorie. As in most cases the fuel used will be weighed in the same units as the water, the same number will express either the C. U. or the calories. Evaporative Power. Engineers very frequently express amounts of heat by the quantity of water at 100C. (212F.) which would be evaporated into steam at the same temperature, thus eliminating the difference due to the use of different thermometric scales. This is called the evaporative power. In general an evaporative power of lib. = 537 C.U. or 966 B.Th.U., but, as will be seen below, the relationship is not always quite so simple. Heat of Combustion. The amount of heat evolved by any chemical change, and therefore by the complete com- bustion of a given weight of a combustible, is fixed and definite, and is quite independent of the rate of combustion, or any other circumstance, so that it is possible to assign fixed heat values to the combustion of any fuel of definite composition. The amount of heat evolved by the combustion of one unit weight (pound, kilogramme, or gramme) of any fuel is called its absolute heating power, or calorific power, and is indicated by the letters C.P. PRODUCER GAS. 17 Carbon. When carbon is burnt with a sufficient excess of oxygen for the combustion to be complete, carbon dioxide is formed, and each lib. of carbon in burning will form 3flbs. of carbon dioxide, and will evolve 8,080 units of heat or the C.P. of C (to C0 2 ) = 8,080 C.U. 14,544 B.Th.U. Carbon, however, can be burnt in two stages. When the temperature is very high and the oxygen is limited in quantity, or, what comes to the same thing, when the carbon is in large excess, carbon monoxide is formed C + = CO. The combustion of carbon to carbon monoxide only yields about one-third the heat which would be evolved if it were burnt to carbon dioxide. C.P. of C (to CO) = 2,416 say, for all practical pur- poses 2,400 C.U. = 4,320 B.Th.U. The difference between the two amounts, i.e., the 8,080 and the 2,400 units, is evolved when the carbon monoxide is burnt to carbon dioxide. Thus lib. of carbon forms 2 Jibs, of carbon monoxide, and evolves 2,400 C.U. ; 2^1bs. of carbon monoxide forms 3f Ibs. of carbon dioxide, and evolves 5,680 C.U. ; lib. of carbon burning to carbon dioxide yields 3lbs. of the gas, and evolves 8,080 C.U. As 2 Jibs, of carbon monoxide burning to carbon dioxide gives 5,680 units of heat, lib. will give 5,680 -f- 2J = 2,434 = say, 2,400 C.U. ; so C.P. of carbon monoxide (GO) burning to carbon dioxide C0 2 = 2,400 C.U. = 4,320 B.Th.U. Carbon can be made to combine with many other elements, and although the union cannot be brought about directly it is possible to determine indirectly the amount of heat evolved. For instance, lib. of carbon combining with Jib. of hydrogen to form IJlbs. of Marsh gas (CH A ) evolves 1,543 C.U., lib. of carbon combining with lib. of hydrogen to form IJlbs. of ethylene (C^) evolves 664 units, whilst lib. of carbon combining with j^jyth its weight of hydrogen to form l^lbs. of acetylene not only evolves no heat but absorbs 1,852 units. These figures may be expressed. Heating power of lib. C (to CH^) = 1543 + C.U.* (to (7 2 # 4 ) = 664 + (to C 2 ff 2 ) = 1852 - The importance of these facts will be seen later * The sign + in this connection indicates evolution of heat, and the sign - absorption of heat. The sign ie placed after the figures 18 PRODUCER GAS. Hydrogen. One pound of hydrogen burning evolves 34,180 C.U., so that C.P. of H = 34,180 C.U. = 61,524 B.Th.U. This is on the assumption that the water formed is condensed, the temperature of the gases produced being reduced below 100C., which is the condition under which all thermo-chemical experiments are made. If the products of combustion be kept above 100C., the steam will be kept in the gaseous condition, and the heat evolved will therefore be less by the amount of heat which the steam would give up on condensation, i.e., the latent heat of the steam. The latent heat of steam is 537 C.U., or 966 B.Th.U., and, as each pound of hydrogen forms 91bs. of water, the heat thus not given out will be 537 x 9 = 4,833 C.U., or 8694 B.Th.U., so that C.P. of H (above 100C.) = 34,180 - 4,833 - 29,347 C.U., or 61,524 - 8,694 = 52,830 B.Th.U., or,. in round numbers, near enough for all practical purposes, 29,300 C.U. = 53,000 B.Th.U. Calorific Power of Solid Fuels. The calorific power of a solid fuel can be calculated from these data if it be assumed that the elements in the fuel evolve the same amount of heat which they would do if they were in the free condition. This assumption is certainly not correct, but is near enough to allow of comparative results being obtained for ordinary fuels, as these are made up of more or less unstable compounds which have been formed without a very large absorption or evolution of heat. Such fuels consist mainly of carbon and hydrogen, with sometimes other combustible elements, such as sulphur, &c. (1) The fuel contains carbon and hydrogen only. Let C = the percentage of carbon and H the percen- tage of hydrogen in the fuel, then if the products of combustion be above 100C. 8080 C + 29300 H . f .. C.P. = - r-r or if the steam be condensed 8080 C + 34180 H "loo- (2) If the fuel contains oxygen the case is a little more complex. The oxygen is not present as free gas, but is already in combination, so that it is evident that the elements with which it is combined will be able to PRODUCER GAS. 19 take up so much less oxygen, and therefore evolve so much less heat. The oxygen is assumed to be combined with hydrogen in the proportions required to form water, so that the oxygen, being combined with one-eighth its own weight of hydrogen, that amount will be unavailable for combustion. If C H and be the percentage of these elements, then cp= 8080 C+ 29300 (g-iO). nCU| C.P. = 1*544 C + 53000 (ff - j 0) in RTh-U . assuming the products of combustion not to be condensed. If they are, the higher values for H must be used. The term (H % 0) is called the available hydrogen, as it expresses the amount of hydrogen in the fuel which is available for combustion. Calorific Power of Gaseous Fuel. The calorific power of a compound gas cannot be calculated from that of the elements, because the formation of a compound is always attended with the evolution of absorption of heat, and the heat of combustion of the compound will be less or greater than that of the elements just by this amount. For example, Marsh gas CH 4 contains 75 per cent. C and 25 per cent. H. Its heat of combustion calculated from the elements and the water being condensed would be C = -75 x 8080 = 6060 H = -25 x 34180 = 8545 14605 The calorific power of Marsh gas as determined by experiment is 13,062, so that the difference is 14,605 13,062 = 1,543. In this case the heat evolved by the combustion of the gas is less than that which would be evolved by the combustion of the elements by 1,543 units, which is the amount of heat which would be evolved by lib. of C combining with hydrogen to form Marsh gas. In the case of acetylene, which contains 92*3 per cent. of and 7*7 per cent. H, the figures would be C 8080 x -923 = 7457-8 H 34180 x -077 = 2631-8 10089-6 C.U. or 20 PRODUCER GAS. The heat evolved by the combustion of lib. of the gas is 11,941 C.U., so that the gas in this case evolves more heat on combustion than the free elements would do, and the difference, 10,089 -- 11,941 - - 1,852, is the heat absorbed by the union of lib. of carbon with hydrogen to form acetylene. It is obvious, therefore, that the calorific power of a mixed gas must be calculated from the compound or elementary gases of which it is a mixture, and not from the elements which they contain considered as being free. As the products of combustion will in practice be always at temperatures above 100C., the amount of latent heat held by the steam must be deducted from the experimental figures in all cases where the gases contain hydrogen. The following calorific powers will be needed : Marsh gas, methane CH^. C.P.= 13062 C.U.= 23512 B.Th.U. Here for each pound of the gas burnt 2'251bs. of water will be formed, so that the effective calorific power C.P.= 13062 - (537 x 2-25) - 11854 C.U. = 23512 - (966 x 2-25) = 21339 B.Th.U. ; or, in round numbers for practical purposes, we may say 12,000 C.U. or 21,000 B.Th.U. Ethylcnc (0 2 # 4 ). C.P.= 11143 C.U. or 20057 B.Th.U. As each pound of the gas produces l'281bs. of water, the effective calorific power will be C.P. = 11143 - (537 X 1-28) = 10456 C.U. C.P.= 20057 - (966 x 1-28) = 18821 B.Th.U.; say, in round numbers, 10400 C.U. or 18800 B.Th.U. Acetylene. C.P.= 11941 C.U. - 21493 B.Th.U. As each pound of gas produces -691b. of water, the effective C.P. will be C.P = 11941 - (537 x 69) = 11571 C.U. - 21493 - (966 x -69)=i20827 B.Th.U. ; say, in round numbers, 11500 C.U. and 20800 B.Th.U. From these figures it is easy to calculate the calorific power of any gas. Take, for example, the gas already considered : PRODUCER GAS. 21 Hydrogen -74 x 29,300 = 21,682 C.U. Marsh gas 2-22x12,000 = 26,640 Ethylene -11 X 1 0,400 = 1,144 Carbon monoxide ... 23'27 x 2,400 55,848 Nitrogen ... ... 63*34 Carbon dioxide & oxygen 10*32 ForlOOlbs 105,314 C.P., i.e., heating power for lib. == 1,053'1 C.U. As 100 cub. ft. of the gas weighs 7'24821bs., 1,000 cub. ft. will weigh 72'4821bs., and the calorific power per 1,000 cub. ft. will be 76,333 C.U. = 137,399 B.Th.U. The calorific power of any other gas known composi- tion can, of course, be calculated in the same way. Calorific Intensity. The actual amount of heat evolved by the combustion of any fuel is, as already explained, fixed and definite, but the temperature that can be obtained varies very much with varying conditions, such, for instance, as rate of combustion. The calorific intensity or pyrometric heating power is the increment temperature that would be produced by the combustion of lib. of the fuel. The temperature that can be attained in practice can never be calculated, as the conditions vary so much, but it is possible to calculate what it would be under certain well-defined conditions, and though the results obtained are not attainable in o practice, they are very valuable for comparison. The assumption which lies at the base of all such calculations is that all the heat is transferred to the products of combustion, and that ^fcheref ore there is no loss of heat. In order to show how the calorific intensity of fuels may vary, and that the calorific intensity is not by any means proportional to the calorific power, the cases of carbon, hydrogen, and Marsh gas will be considered. Carbon. One pound of carbon on burning forms 3f Ibs. of carbon dioxide and evolves 8,080 units of heat, so that if there were no loss of heat, and if the heat were all im- parted to the products of combustion, the resulting temperature would be 8080 3-67 x -2163 10178 C. 22 PRODUCER GAS. - 18321 F ' 2163 being the specific heat of carbon dioxide. If, instead of being burnt in oxygen, the carbon were burnt in air, the amount of heat would be the same, but the oxygen used would be mixed with nitrogen, which would remain with the carbon dioxide, and would have to be heated to the same temperature. The 2f Ibs. of oxygen required for the combustion of lib. carbon would be mixed 77 with 2-67 x ^ == 8'9 parts of nitrogen in the air. So that Zo the C.I. would be PT 8080 _ (3-67 X -2163) + (8-9 x -2438) and if there be an excess of air, then the excess of air x its specific heat must also be added to the denominator, and would thus further reduce the temperature. Hydrogen. In the case of hydrogen the heat evolution is, assuming the temperature of the gases to be above 100C. 29,300 units, and it yields nine parts of water which as steam has a specific heat of -4805 ; so that _ 29300 " 9 x -4805 and if the combustion be in air, as eight parts of oxygen will be mixed with 8 x -^- = = 26*8 parts of nitrogen, 29300 (9 x -4805) + (26-8 x -2438) Therefore, whilst the actual amount of heat evolved by the combustion of carbon and hydrogen is in the ratio of 1 : 3 -62, the temperature attainable by the combustion of hydrogen and carbon in oxygfcn is in the ratio of 1 : -68. The calculation of the calorific intensity of some other gases, though not of much practical importance, is instructive. Carbon Monoxide. . 1 1-57 x -2163 or if burnt in air 2400 (1-57 x -2163) + (1-91 x -2438) j.5 - 7067, = 2980 PRODUCER GAS. 23 Marsh Gas. The calorific power is 12,000. In oxygen rT = 12000 (2-75 x -2163) + (2-25 x -4805) And in air r = 12000 ' ~(2-75 x -2163)-i-(2-25 x -4s05) + (13-4 x -2438) -2427. In order to calculate the calorific power of any mixed gas it is necessary to know the nature and weight of the products of combustion, the specific heat, and the amount of oxygen consumed. To take again the gas dealt with in the previous examples, which contained Hydrogen ... ... ... ... '74 Marsh gas 2*22 Ethylene '11 Carbon monoxide ... ... ... 23*27 Oxygen ... ... ... ... 1*85 Carbon dioxide ... ... ... 8*47 Nitrogen 63*34 The calorific intensity in oxygen will be p -r _ ( -0074 x 29300) + ( -Q222 x 12000) + ( -001 x 10400) + ( "2327 x 2400) ~ (-5146x -2163) + (-1177 x -4805) + ( -6334 x '2488) - 3264 Or in air p T ( -0074 x 29300) + ( -0222 x 12000) + ( "001 x 10400) + ( '2327 x 2400) (5146 x -2163) + (-1177x -4805) + (1 -5238 x -2438) = 1950. Temperature of Combustion. In order that combustion may take place a certain temperature is necessary, and if the gas be very much diluted, or if a very large excess of air be used, it may happen that the temperature produced by combustion is insufficient to keep the gas alight. This is not uncommon with poor gas, such as blast-furnace gas, and in such cases it is necessary to keep a fire of solid fuel burning on the grate, or to keep up the tempera- ture in some other way. Heat Carried Away by the Products of Combustion. It is always essential, except in certain cases where a forced draught is used, to allow the products of combustion to leave the furnace at a high temperature, in order that a good draught may be produced, and thus a large amount of heat may be carried away. If the temperature of the 24 PRODUCER GAS. gas be known, it is easy to calculate the amount of heat carried. Thus in the gas which has already been considered, for each pound of gas the products of combustion are : Carbon dioxide... -51461bs. x "2163 = -1113 C.U. Water -11771bs. x '4805 = -0565 Nitrogen -63341bs.| v . 94 oo _. .07-, * 89041bs.j X 24< "__ " 5393 If the weight of each gas be multiplied by its specific heat, the sum will be the amount of heat carried away by each pound of fuel consumed in this case '5393 units of heat for each 1C. of temperature of the gas above the temperature of the air ; or if the gases were at 200C. (the air being at 0), a very moderate temperature, the loss would be 107*8 units, or 10*8 per cent, of the heating power of the fuel. In practice the amount of heat carried away will be much larger, as there will always be considerable excess of air Heating by Contact and by Radiation. The way in which the heat is to be applied to a certain extent modifies the value of the gas. A non-luminous flame, such as that of hydrogen or carbon monoxide, may have a very high temperature and be very efficient for heating where the flame can come in contact with the surface being heated, but it radiates heat very feebly, and therefore is not efficient where heating by radiation is required. On the other hand, a luminous flame loaded with hot carbon is not very efficient where contact heating is required, and deposits soot very readily, but it is excellent for heating by radiation. As heating by radia- tion is far more extensively used than heating by contact, a gas which burns with a luminous flame is in general better than one the flame of which is non-luminous. CHAPTEK III. NATURAL GAS. COAL GAS. OIL GAS. ACETYLENE. Natural Gas. This gas is of little importance in this country. A brief mention of it may, however, be of interest, in order that it may be compared with other gases used for fuel. The following may be taken as an average analysis by volume : Carbon dioxide ......... '6 Carbon monoxide ...... '6 Oxygen .................. -8 - Ethylene .................. 1-0 Pecentage of Ethane (C 2 H.) ......... 5-0 Methane (C H 4 ) ......... 67-0 Hydrogen ............... 22'0 Nitrogen .................. 3-0 100-0 It will be seen, therefore, that the gas is composed almost entirely of combustible gases, there being only 4'4 per cent, of diluents, and its calorific power will there- fore be very high. Owing to the large quantity of ethylene, it burns with a very luminous flame. The percentage composition by weight will be : Carbon dioxide... -6 x '1227 = -0736 ... 1-82 Carbon monoxide '6 X '0781 - -0469 ... 1-16 Oxygen -8 x -0893 = -0714 ... 177 Ethylene 1-0 X -0784 = -0784 ... 1-94 Ethane 5'0 X '0837 = -4185 ... 10-35 Methane 67'0 x "0447 = 2-9949 ... 74-09 Hydrogen 22-0 x -0056 = -1232 ... 3'05 Nitrogen .. 3-0 x -0784 = -2352 ... 5-82 4-0421 100-00 Coal Gas. Coal gas, as is well known, is prepared by the destructive distillation of coal. The gases are not present in the coal, but are produced by destructive action of the heat, whence the name destructive distillation. 26 COAL GAS. The gas consists almost entirely of combustible gases r and burns with a highly luminous, often smoky, flame. The composition of the gas varies considerably according to the coal used and conditions of distillation, but the lighting power varies much more than the heating power r probably because the dense hydrocarbons, which are the principal illuminating constituents, are somewhat unstable, and tend to break up at high temperatures. The principal illuminating constituent is ethylene, but this is .always associated with larger or smaller quantities of its higher homologues of the olefine, or C n H 2n series, and hydrocarbons of lower series, such as the acetylene C n H 2n _ 2 series. The distillation also produces large quantities of liquid hydrocarbons which are removed by condensation and washing, and which are known collectively as coal tar, and also gaseous and liquid compounds containing sulphur, viz., hydrogen sulphide H 2 S and carbon disulphide CS 2 , which are removed when the gas is to be used for illuminating purposes. Some of the nitrogen present in the coal is given off as ammonia which is dissolved in the water used for washing the gas, and is afterwards recovered and converted into ammonium sulphate. There are two varieties of coal gas, that made from ordinary bituminous gas coal and that made from cannel coal, the latter containing a much larger percentage of the olefines, and therefore having much greater illuminating power. The following analyses may be taken as illustrating the composition of coal gas by volume. (i) (2) (3) Hydrogen 51-80 48*32 36-10 Carbon monoxide Marsh gas 9-10 31-80 4-63 39-55 6-80 37-80 Olefines .... 5-20 5-18 16-40 Nitrogen 2-10 2-32 2-90 100-00 100-00 100-00 (1) and (2) London gas, (3) cannel gas. It will be seen that the gas consists almost entirely of combustibles, there being only about 2 or 3 per cent, of COAL GAS. 27 diluents, and that the great bulk of it is gases that burn with a non-luminous flame, though by the high temperature they produce they assist in making luminous the carbon separated from the ethylene. Taking an average analysis as : * By Weight, Hydrogen ... 48 x '0050 = -2688 = 8'59 % Carbon monoxide 8 x '0781 = -6248 = 19*96 Methane ... 36 x -0447 = = 1-6092 == 51-41,, Ethylene ... 3-8 x -0784 = -2979 = 9-52,, Nitrogen ... .4-2 x -0784 -3293 = 10-52 3-1300 100-00 1,000 cub. ft. of the gas would weigh 31'311bs. The calorific power can be easily calculated : Hydrogen -0859 x 29300 = 2516-9 Carbon monoxide -1996 x 2400== 479'0 Methane -5141 x 12000 = 6169'2 Ethylene -0952 x 10400 = 990-1 Nitrogen -1052 10155-2 and as 1,000 cub. ft. weigh 31'31bs., theheat evolved by the combustion of 1,000 cub. ft. will be 317858 C.U., 572144 B.Th.U. Such a gas will require a very large amount of oxygen for its combustion. Hydrogen 48 X -5 = 24 Carbon monoxide 8 x -5 = 4 Methane 36 x 2-72 Ethylene 3-8 x 3 = 11-4 Nitrogen 4-2 111-4 100 volumes of the gas will thus require 111-4 volumes of oxygen or 530-5 volumes of air. The weight of the products of combustion will also be very large. The advantages of coal gas as a fuel are : (1) Owing to its high calorific power, a large amount of heat can be obtained from a small quantity of gas, and therefore for many small operations where cost of the fuel is of small importance it is of great value, and is very largely used. * J. S. C. I., 1888, p. 20. 28 COAL GAS. (2) It burns with a very luminous flame, and thus is well suited for heating by radiation where the flame is not brought in contact with any cold surface. Against these advantages are to be set two dis- (1) The cost is very great. Assuming gas to be supplied at 2s. 6d. per 1,000 cub. ft., the cost per 1,000 ., . 30000 units of heat will be in pence Q ^^ = '094. ol i oOo Supposing a coal with a heating power of 8,000 to be obtainable at 15s. a ton, the cost per 1,000 units of heat obtained from it would be 15 X 12 180 X 1000 2240 x 8000 : 17920000 In some cases the convenience of the gas is so great that even with this great difference in cost its use is advan- tageous, but it is quite obvious that such cases will not be very numerous. (2) The gas has a great tendency to smoke and to deposit soot, a defect common to all highly luminous gases, hence burners must be so arranged that there is a large surface exposed to the air. This prevents the use of large flames, and therefore renders the gas unsuitable for use on a large scale. When the burning gas comes in contact with a cold surface, combustion is always incom- plete, soot is deposited, and thus the efficient heating power is very much reduced. The soot is a very bad conductor, and is extremely troublesome. In order to avoid the difficulty, when coal gas is used as a fuel it is usually diluted with air, as in the Bunsen burner, till its richness is reduced and the flame becomes non -luminous. It will be seen, however, that this is to sacrifice the chief advantages of coal gas and to reduce it to the rank of the cheaper non-luminous producer gas. Coal gas is largely used for domestic heating in this way, not because it is the cheapest or best gas for the purpose, but because it is the only one which is available. The high cost of coal gas is due to several reasons : (1) When the coal is distilled only a small proportion of the fuel, rarely 30 per cent., is converted into gas, the greater part being left as a residue or coke. The coke is OIL GAS. 29 of course a by-product, and has a relatively small value because the coals which are best for gas making usually yield an inferior coke, which is often very high in ash. (2) The coals are selected because of the high illuminating power of the gas they yield, and are therefore relatively costly. (3) A considerable quantity of fuel is used in the distillation. (4) As the gas is to be used mainly for illuminating purposes, and therefore will be burnt in rooms often with little ventilation, and often containing articles that might be damaged by sulphur oxides, the gas must be thoroughly freed from sulphur, which is a somewhat costly process. Oil Gas. This gas is made by the destructive distillation of mineral oils by very rapid heating to a high tempera- ture. The composition of the gas varies considerably, the following analysis will serve as an illustration of its composition : By Volume. By Weight. Hydrogen 31 61 4-43 Carbon monoxide Luminous hydrocarbons^ . . Marsh gas 14 16-29 46-17 27 31-96 51-77 Nitrogen 5-06 9-93 Oxygen 73 1-64 It will be seen that the gas resembles coal gas in some respects. Owing to the high percentage of ethylene, it burns with a very luminous flame, and shows a very great tendency to produce smoke and deposit soot. It requires a very large quantity of air for its combustion, and is quite unsuited for use as a fuel gas under ordinary conditions, even if its cost were not prohibitive. Assuming the luminous hydrocarbons to be ethylene, the calorific power of the gas and the amount of oxygen required for combustion would be : J Chiefly Ethylene. 80 ACETYLENE. CP O per 100 cub. ft. Hydrogen 0443 1298- 15-80 Carbon monoxide . . Ethylene 0027 3196 6-5 3323-8 07 48-87 Marsh gas . ... 5177 6212-4 92-34 Nitrogen 0993 Oxygen . . 0164 Less oxygen present.. 10840-7 157-08 73 1-0000 156-35 cf or air 744-5 cf. According to Mills & Rowan, the amount of gas pro- duced by the process in which the oil is broken up by being allowed to fall into retorts filled with red-hot bricks or similar processes is about 150 cub. ft. per gallon of oil. Assuming the oil to have a specific gravity of -9200, one gallon of the oil would weigh about 9*21bs. and the yield would be 36,522 cub. ft. per ton. Acetylene. Closely allied to these highly luminous gases, though made by quite a different process, is acetylene. When a mixture of lime and carbon is heated to a very high temperature by the electric arc, decomposition takes place, carbon monoxide is evolved, and a carbide of calcium is left. Ca O + 3C = = Ca C a + C O. When this carbide is treated with water acetylene is evolved, Ca C 2 + 2 H 2 O = = Ca O, H 2 O + C 2 H 2 Acetylene burns with a more luminous flame than any other hydrocarbon. The gas is, however, quite unsuited for use as fuel. It is very unstable, its decomposition evolving a considerable amount of heat, and at high temperatures it may even decompose with explosion. There is a great tendency to the separation of carbon during combustion, and consequent production of smoke, and when used for lighting it requires the use of very small burners and a copious supply of air. The following series of analyses of acetylene made from calcium carbide are given by Prof. Lewes in his Cantor lectures on acetylene : Journal of the Society of Arts, vol. 47 (1899), p. 137. ACETYLENE. 31 American Carbide. German Carbide. Swiss Carbide. Phosphoretted hydrogen ... Sulphuretted hydrogen Ammonia 0-05 0-08 0-08 0-03 0-07 C-07 0-03 o-io 0-11 Hvdroffen 0-09 0-07 0-16 Nitrogen 0-42 0-20 0-34 Oxycren . 0-87 0-55 0-63 Acetylene 98-41 99-01 98-63 - 100-00 100-00 100-00 CHAPTER IV. SIMPLE PRODUCER GAS. STEAM ENRICHED PRODUCER GAS. COAL ENRICHED PRODUCER GAS. CARBON DIOXIDE IN PRODUCER GAS. EFFICIENCY OF A GAS PRODUCER. Loss OF HEAT IN GAS PRODUCER. IN all gases produced by destructive distillation a con- siderable portion of the fuel used is left as a solid non-volatile residue, and unless this can be economically used the gas must be very costly. In order to prepare a gas for use as fuel at cheap rate the whole of the fuel must be gasified, and this is done in the manufacture of producer gas. When carbon in any form, for example, coke or charcoal, is burnt in a limited supply of air at a high temperature the product of combustion is carbon monoxide, and this is combustible. If, therefore, the fuel be thus burnt all the carbon is converted into combustible carbon monoxide, and no residue is left except the non-combustible ash. In order that theory of the manufacture of producer gas may be clearly understood it will be best to describe some simple form of gas producer, and consider what changes take place in it, and then to consider the commercial forms of producer in use to-day. For this purpose the producer designed by Bischof and once used in the Hartz may be taken. It is shown in section in Fig. 1. It will be seen from the sketch that it is little more than a deep fireplace indeed, this is the character of all simple producers. The fuel is supplied at the top, the ashes are poked out through the bars at the bottom, and the gases are drawn off near the top. Simple Producer Gas. In a gas producer almost any fuel may be used, but at the outset it will be best to consider the case of a more or less pure carbon such as coke or charcoal, as the reactions which take place are simpler in this case than in any other Coke is now rarely used in practice except when the gas is to be used for gas PRODUCER GAS. 33 FIG. 1. BISCHOF PRODUCER. engines, and therefore the absence of tarry matter is essential. Suppose the producer figured above to be full of coke or charcoal which is burning. As the air passes in between the bars combustion will take place and carbon dioxide will be formed, which will, however, if the temperature be high enough and the quantity of coke large enough, be at once reduced to carbon monoxide, so that the net result will be the combustion of the carbon to carbon monoxide (C + O = CO), in which form it leaves the producer. Such a gas may be called simple producer gas, to distinguish it from the steam and hydrocarbon enriched gases which are usually used. The air , consists of oxygen and nitrogen mixed in approximately the following proportions : Oxygen Nitrogen O By Volume. 21 79 By Weight. 23 77 When carbon burns to form carbon monoxide, the carbon monoxide produced occupies twice the volume of the 34 PRODUCER GAS. oxygen which it contains, therefore 100 volumes of air will yield 79 volumes of nitrogen, passing through unchanged, and 42 volumes of carbon monoxide, so that the composition of the gas will be Carbon monoxide ... 42 = 34-7 per cent. Nitrogen 79 = 65 -3 121 100-0 provided that there be no carbon dioxide left unreduced. As in this case the two gases of which the gas is composed have almost the same specific gravity, the percentage composition by weight will be the same as that by volume, so that the composition by weight will be Carbon monoxide... ... ... ... 34*7 Nitrogen 65-3 HXH) 1,000 cub. ft. of the gas will weigh about 781bs., and one ton of carbon would give about 190,000 cub. ft. of gas. Assuming the coke used to contain 90 per cent, of carbon, one ton of coke would yield about 171,000 cub. ft. of gas. The heating power of the gas will necessarily be small, as 65 '3 per cent, of it is not combustible, and the remaining portion, which is combustible, has a low calorific power. The calorific power of the gas will be '347 X 2,400 = 832-8 CU = 1,499 B.Th.U., and 1,000 cub. ft. of the gas weighing about 781bs., evolve 64,958 C.U., or 116,925 B.Th.U. One pound of carbon will have combined with 1 - 331bs. of oxygen and produced 2 - 331bs. of carbon monoxide, which, mixed with the nitrogen, will give 6'7llbs. of simple producer gas. C.U. B.Th.U. lib. of carbon burning to carbon dioxide would give 8,080 14,500 6'711bs. of simple producer gas burning to carbon dioxide will give ... ... 5,588 10,058 Difference 2,492 4,442 This difference is just about 31 per cent, of the total heat which the 'solid fuel could evolve on combustion, and PRODUCER GAS. 35 therefore the conversion of the fuel into gas has been attended with a loss of 31 per cent, of the heating power of the fuel. This loss of heat is not, however, an absorption. It is not of the character of latent heat, or heat absorbed in doing work, as when water is boiled into steam, which heat can be recovered by reversing the change by condensing the steam back into water, but it is heat evolved, but evolved in the producer, where it is only to a small extent useful, instead of in the furnace, where it is wanted. What becomes of this heat will be fully considered later. Simple producer gas can be used in a few cases, but its low heating power and the large loss of heat in its production are great disadvantages. The gas can, however, be enriched by the use of coal instead of coke in cases where the products of distillation of the coal are not objectionable, and it can also be enriched and at the same time the expenditure of heat in its production can be reduced by using steam in conjunction with the air. Steam Enriched Gas. When steam is blown over red-hot coke it is decomposed thus : C + H 2 U = CO + 2H, so that the steam yields its own volume of carbon monoxide and its own volume of hydrogen. Each pound of carbon burnt by steam yields the same volume of carbon monoxide which it would do if burnt in air, but this, instead of being mixed with about twice its own volume of nitrogen, which is useless, is mixed with its own volume of hydrogen, which is combustible, and has a high calorific power. Thus the gas is enriched by the addition of hydrogen and at the same time by a reduction in the percentage of nitrogen. The decomposition of steam by carbon is made up of two parts, each of which will have its own thermal value ; first, the formation of a molecule of carbon monoxide, and second, the decomposition of a molecule of water. The first of these will evolve and the second will absorb heat. It will be seen that for each pound of hydrogen liberated Gibs, of carbon will be consumed, and will produce 141bs. of carbon monoxide. The thermal changes 36 PRODUCER GAS. can be thus expressed, taking the figures in round numbers : C.U. B.Th.U. Heat absorbed in separating lib. of hydrogen from the oxygen with which it was combined in the water 29,000 52,200 Heat evolved in the combustion of 61bs. of carbon to carbon monoxide 14,400+ 25,920 + Heat absorbed by the reaction for each 61bs. of carbon oxidised... 14,600- 26,280 Heat absorbed for each pound of carbon oxidised 2,433- 4,380 It is obvious that the amount of steam which can be used is limited, for if steam alone were used, unless heat were supplied from some external source, the fuel would soon be cooled below the temperature at which the decomposition could take place, and the reaction would cease. If air and steam be blown in together the combustion of the carbon by the air will supply the necessary heat to keep up the combustion, and as the combustion of carbon by air takes place at a much lower temperature than the decomposition of steam, if excess of steam be used it will not stop the combustion altogether, but by lowering the temperature will cause the production of a large quantity of carbon dioxide, and at the same time the excess of steam will pass through undecomposed, and thus will remain mixed with the gas. It is obvious that if air and steam be supplied together and the steam is to be decomposed the quantity of air must be sufficient to keep up the temperature of the fuel to the point at which decomposition of the steam can take place. Since each pound of carbon burnt by steam absorbs 2,433 C.U., and each pound burnt by air evolves 2,400 C.U., it is clear that if there were absolutely no loss of heat the quantity of carbon burnt by air must be about the same as that burnt by steam. In practice loss of heat cannot be avoided, and to com- pensate for this a much larger quantity of carbon must be burnt by air. PRODUCER GAS. 37 In order to see the effect of the use of steam a case may be assumed in which for every 51bs. of carbon consumed 41bs. is burnt by air and lib. by steam, proportions not very far removed from those in actual practice. For simplicity in expressing the results 12 grammes will be taken as the unit. Twelve grammes of carbon burnt by air gives 22 '4 litres of carbon monoxide, whch will be mixed with 42*1 litres of nitrogen, and 12 grammes of carbon burnt by steam will give 22-4 litres of carbon monoxide and 22*4 litres of hydrogen, so that 48 grammes of carbon burnt by air will give Nitrogen = 42-1 x 4 = 168-4 Carbon monoxide = 22-4 x 4 = 89-6J 12 grammes of carbon burnt by steam will give Carbon monoxide ... ... ... ... 22 -4 J Hydrogen ... ... ... ... ... 22 -4 And the composition of the resulting gas will be (by volume) Carbon monoxide... 37'Opercent.) 44-4 per cent. Hydrogen... ... 7-4 j combustible. Nitrogen ... ... 55 '6 ,, The gas is therefore much richer in combustibles than simple producer gas. The composition of the gas by weight will be Carbon monoxide ... ... ... 39*73 Hydrogen ... ... -57 Nitrogen 59*70 100-00 Owing to its extreme lightness the percentage of hydrogen by weight is very small. The calorific power of the gas will be 3973 x 2400 = 953-5 C.U. 0057x29300 ... = 167-0 C.U. 1120-5 C.U. as against 832, an increase of 287 C.U., or about 35 per cent. In B.Th.U the figures will be 3973 x 4320 = 1716-3 0057 x 53000 = 302-1 2018-4 B.Th.U. 38 PRODUCER GAS. One ton of carbon thus burnt will yield about 181,000 cub. ft. of gas, or, assuming the coke to contain as before 90 per cent, of carbon, one ton will yield about 163,000 cub. ft. One thousand cubic feet of the gas will weigh about 72-91bs., and will evolve on combustion about 81,684 C.U.,, or 147,141 B.Th.U. One pound of the gas will contain -17051b. of carbon. This if completely burnt to carbon dioxide would give 17 x 8080 =1374 C.U. - 2478 B.Th.U. One pound of the gas gives 1120-5 C.U. = 2018-4 B.Th.U. Loss 253-5 454-6 Or only about 20 per cent, of that which the solid fuel would give. Thus by the use of steam in the proportion assumed the gas has been enriched by about 35 per cent., and the loss of heat in its production has been reduced from 31 to 20 per cent., a saving of about 11 per cent. The action of the steam can be easily explained. Owing to the absorption of heat by the decomposition of the steam less heat is evolved in the producer, and an additional amount equal to that thus saved can be evolved in the furnace. The steam thus acts as a carrier of heat, and, whilst it cannot increase the total amount of heat evolved, it alters its distribution. The larger the proportion of steam that can be used the better, but for the reasons explained above excess must be carefully guarded against. Coal Enriched Gas. '1 he gas may be further enriched by the use of coal instead of coke. The coal is then distilled at the top of the producer by the heat of the ascending gas, the otherwise waste heat being thus utilised, and the producer gas is enriched by the addition of the coal gas produced by the distillation. Assume the producer to be charged with a coal yielding, say, 65 per -cent, of fixed carbon and 5 per cent, of ash, and giving, say, 10,000 cub. ft. of gas per ton, the gas containing by volume, say, 50 per cent, of hydrogen, 40 per cent of hydrocarbons, and 10 per cent, of carbon monoxide. It will not be difficult to see the nature of the gas which will be produced. It may be assumed that PRODUCER GAS. 39 steam is used as before. As there is only 65 per cent, of fixed carbon in the fuel, it will yield 181,000 x -65 = 117,650 cub. ft. of producer gas per ton of coal, which will have the same composition as that already given, and, in addition, there will be 10,000 cub. ft. of coal gas having the composition given above, so that the 128,000ft. of gas will contain r Hydrogen ... 5,000 From the coal gas . .. -j Hydrocarbons ... 4,000 { Carbon monoxide ... 1,000 r Hydrogen 8,706 From the producer gas -j Carbon monoxide... 43,530 [Nitrogen ... ... 65,414 This will give the composition by volume Hydrogen 10-8 Hydrocarbons ... ... ... 3'1 Carbon monoxide ... ... 34-9 Nitrogen ... ... ... 51 -2 100-0 Assuming the hydrocarbons to be all Marsh gas the percentage composition by weight will be Hydrogen -87 Hydrocarbons (Marsh gas) ... ... 1-98 Carbon monoxide ... ... ... 39 '38 Nitrogen ... 5776 The calorific power will be, in Centigrade units Hydrogen -0087 X 29300 = 254-9 Marsh gas -0199 X 12000 = 238-9 Carbon monoxide . -3938 X 2400 = 945 -1 1438-8 In British thermal units Hydrogen -0087 x 53000 = 461-1 Marsh gas -0199x21000= 417*9 Carbon monoxide.., -3938 X 4320 = 1701-2 2580-2 1,000 cub. ft. of the gas will weigh about 69'51bs. and will evolve on combustion 99,996 C.U., or 179,323 B.Th.U. The following analyses of producer gas will serve to show how the composition of gas, in practice, agrees with 40 PRODUCER GAS. the examples worked above. When coal is used, calcula- tions as to the composition of the gas can only be rough approximations owing to variations in the quantity and composition of the coal gas, with the quality of the coal used. EXAMPLES OF PRODUCER GAS. (i) (2) (3) (4) (5) Hydrogen Hydrocarbons ... Carbon monoxide 8-60 2-40 2440 12-13 2-00 26-40 10-90 1-28 27-00 19-43 2-66 16-15 12-60 3-50 20-40 Carbon dioxide 5-20 9-16 4-50 11-53 5-50 Nitrogen Per cent, combustibles .. 59-40 35-40 50-31 40-53 5632 39-18 50-23 38-24 58-00 36-50 Carbon Dioxide in Producer Gas. It will be noticed that all the above analyses show in addition to the constituents already considered the presence of carbon dioxide. This gas is very objectionable, and if present in larger quantities than 4 or 5 per cent, shows either badly designed producers or careless working, very frequently by use of excess of steam, and therefore undue cooling. The effect of the carbon dioxide is threefold. (1) It represents its own volume of carbon monoxide burnt in the producer, and therefore so much the less combustibles and the more non-combustibles present in the (2) Since it contains twice as much oxygen as carbon monoxide it adds an additional amount of nitrogen, which is useless, to the gas. (3) It causes the useless evolution of a large additional amount of heat in the producer. The extent to which carbon dioxide deteriorates the value of the gas can be seen by considering the case of simple producer gas. Suppose that in such a gas instead of all the carbon being burnt to carbon monoxide one-fifth of it leaves the producer as carbon dioxide. Since carbon dioxide occupies the same volume as carbon monoxide containing the same amount of carbon, 60 grammes of carbon would give PRODUCER GAS. 41 4 x 12 grammes of C. burnt to carbon- monoxide 4x22-4== 89-61itres 1 x 12 grammes of C. burnt to carbon dioxide 1x22-4- 22-4 Nitrogen from air yielding 67 -2 litres of oxygen required for the combustion ...252 -8 ,, 364-8 The percentage composition by volume will be : Carbon monoxide ... ... ... 24-6 Carbon dioxide ... ... ... ... 6*1 Nitrogen 69-3 By weight the composition would be : Carbon monoxide ... 23*7 Carbon dioxide ... ... 9 '3 Nitrogen 67-0 100-0 The calorific power would be : In C. units -237x2400=568-8 In B.Th. units -237 X 4320 = 1024 The gas contains 12-69 per cent, of carbon, or in lib. 1269lb., and this burnt completely would yield 1269 x 8080 = 1025-3 C.U. 1269 X 14500= 1840-0 B.Th.U. The loss of heat in the producer, therefore, 1025 568 = 457 C.U. 1840 1024 = 816 B.Th.U. The presence of 6'1 per cent, of carbon dioxide by volume^-an amount well within that often found in practice in the gas represents a loss of one-fifth of the carbon consumed, a reduction of the calorific power of gas by about 264 C.U., or about 32 per cent., and increase of loss of heat in the producer from 31 to 46 per cent. This obviously means a very large waste of fuel. The presence of carbon dioxide in the gas is always due to one of three causes : (1) Too low a temperature in the producer, generally produced by the use of too large a quantity of steam. 42 EFFICIENCY OF GAS PRODUCERS. (2) The layer of hot fuel not being sufficiently thick to allow of the complete decomposition of the carbon dioxide produced. (3) The leakage of air into the producer above the zone of combustion. This is, however, of rare occurrence. EFFICIENCY OF GAS PRODUCERS. The object of the gas producer is to convert the solid fuel into gas, and this (as already described) always involves the expenditure of some heat, so that the heating power of the gas will always be less than that of the solid fuel from which it is derived. The smaller the difference that is, the nearer the heat obtained by the combustion of the gas approaches that which could be obtained by the direct combustion of the solid fuel from which the gas is made the greater will be the efficiency of the producer. If H be taken as the heating power of lib. of coal or other fuel from which gas is being made, H' the heating power of the gas derived from lib. of the fuel, and H" the heat evolved in the producer, then obviously, if all the fuel be consumed, H = H' + H". The efficiency of the producer will be the ratio TTf TT' of H': HOT , so that it may be written E=-fj-. If there were no heat evolved in the producer, then obviously H' would be equal to H, and the ratio would be 1. This can never be attained, but the nearer it is approached the more efficient is the producer. To take as an example the simple producer gas made from charcoal without steam, H = 8080 and H' -- 5588, so that E= = "691, or 69-1 per cent, ; whilst in the case of the example of steam-enriched gas considered above PI -- 8080 H' 6591, so that E = = -81, or 81 per cent. ; and in the case of a oUoU coal-fed producer, it may be higher still. In practice the efficiency will rarely be above 80 per cent., but with well-constructed producers and careful working it should reach that, or even 85 per cent. EFFICIENCY OF GAS PRODUCERS. 43 The efficiency will obviously be reduced by any action which tends to cause the evolution of heat in the producer, and therefore it is very much reduced by the presence of carbon dioxide in the gas. It is assumed in the above statement that the gas is burnt cold. If it is used hot in such a way that the sensible heat of the gas can be utilised the efficiency will be higher, as all the heat evolved in the producer will not be lost. It is quite obvious that the minimum amount of heat that must be evolved in the producer to keep the produc- tion of gas going on will be that required to balance the sources of loss of heat and keep the producer at the required temperature. Losses of Heat in Producer. There are several sources of loss of heat in the producer, none of which can be com- pletely prevented, but all of which should be reduced to a minimum. (1) Heat carried off by the escaping gas. The gas always leaves the producer at a high temperature, some- times as high as 600 C. (1,000 F.),and thus a large amount of heat may be carried away. One pound of carbon will give about 6' 7lbs. of producer gas with a specific heat of about -245, so that the heat carried away will be 6'7 x -245 = 1-64 units for each degree of temperature of the escaping gases per pound of fuel, or at 600 C. 985 units. As each pound of carbon can only evolve 8,080 units, this will be about 12 per cent, of the total available heat. Ten per cent, is a very usual amount to be thus carried away, but it may be much higher, especially if undecomposed steam bfe passing through the producer or if the gas contain a large quantity of hydrogen, as both of these have a Very high specific heat. For economical working, therefore, unless the gas is to be used hot and the sensible heat thus utilised, the temperature of the escaping gases must be kept as low as possible. With m#st forms of producer in use it is, however, impossible to keep the escaping gas at a low temperature without unduly cooling the mass of fuel, which is likely to produce greater evils. (2) Loss of heat by radiation. The mass of hot fuel is surrounded by walls which are exposed to the air, and from which radiation must be taking place. The 44 EFFICIENCY OF GAS PRODUCERS. thicker the walls the less heat will be lost through them. It is therefore not advisable that the producer should be a mere shell of iron lined with a thin layer of brick- work. Radiation may be much reduced by building the producers in banks of from six to twelve, instead of singly. (3) Heat carried out in the ashes. This is never large in amount, and in modern producers is so much reduced as to be of no importance. Assuming the fuel to contain 10 per cent, of ash having a specific heat of '2, and that it be drawn at a temperature of 600 C., the loss will only be 600 X *02 == 12 units for each pound of fuel consumed. (4) In some types of producer fuel may escape combustion and pass away in the ashes. The amount thus lost should not be large even with bar-bottom producers, but it will necessarily vary with the quality of the fuel and the care with which the producer is attended. Five per cent, is a common loss, but it may reach 10 per cent., or even more, and cases have been quoted in which it has reached 30 per cent. The proportion of fuel actually gasified to that supplied is called the grate efficiency of the producer. Assuming the loss of fuel in the ashes to be 10 per cent., the grate efficiency will be 9, or 90 per cent. The true efficiency of a producer will, of course, be the efficiency, as before defined, multiplied by the grate efficiency. Thus in the case of simple producer gas made in a producer having a grate efficiency of *9 the real efficiency would be -691 X '9 = '621 = 62-1 per cent. Use of Hot Gas. In describing the efficiency of a gas it has been assumed that the gas is burnt cold. If it be burnt hot so that the sensible heat of the gas can be utilised in furnace heating the efficiency will, of course, be somewhat higher, and the loss of heat in the producer will be less. The heat obtained by the combustion of lib. of the hot gas (E'\ i.e., the effectual calorific power of the hot gas, will be the heat evolved by the combustion of the cold gas added to heat carried over by the hot gas that is, it will be CP + (W X S X T) where W is the weight of the gas per Ib. of fuel consumed, S its specific heat, and T its temperature above that of the air, the last term giving the sensible heat of the gas in EFFICIENCY OF GAS PRODUCERS. 45 thermal units. The efficiency of the gas will, of course, be increased, and the hot gas efficiency will equal the cold gas efficiency Sensible heat of gas from lib. of fuel ~77~ , , H f + WST Calorific power of fuel E - There is another point which has to be taken into account in considering the efficiency of a gas producer which is usually neglected. If the gas is made from coal it will be laden with tarry matter, and if the gas mains be short this will be carried forward and will be burnt, whilst if the mains be long it will be wholly or partially condensed in the mains. In any case the tarry matter is condensed in taking the sample for analysis, and thus is not taken into account in the analysis. The amount of tar is considerable, and may sensibly increase the calorific power of the gas as burnt, and therefore the efficiency of the producer. The question of tar in producer gas will be considered more fully later. In a paper read before the Institute of Civil Engineers in 1896, Mr. C. T. Jenkins describes a method of calculating the efficiency of gaseous fuels, and gives a considerable number of examples. The formula he uses for the gas used cold is Efficiency = M x K x G ~~H~~ Where M is the heat of combustion of the gas for each kilogramme of carbon contained in it, which he calls the " figure of merit " of the gas, K is the proportion of carbon in the coal, G is the proportion of carbon which is gasified, and H is the heat of combustion of one kilo- gramme of the coal used for making the gas. If the whole of the carbon is gasified, G becomes 1, and the efficiency is , and M K is the calorific power of the gas per kilogramme of the coal. Pounds could, of course, be substituted for kilogrammes without altering the proportion, and " figure of merit " M could then be taken as the heat of combustion of the gas for each pound of carbon it contains. The hot gas efficiency he gives as cold gas efficiency x -. sensible heat per cubic metre of the gas *| ' calorific power of the gas / CHAPTEK V. CHIMNEY DRAUGHT PRODUCERS. THE OVERHEAD COOLING TUBE. FORCED DRAUGHT PRODUCERS. BLOWERS. AMOUNT OF STEAM KEQUIRED. The proper supply of air and steam to the producer is a matter of the utmost importance for successful working. CHIMNEY DRAUGHT PRODUCERS. In the early types of producer the ashpit was open and the draught was of the character of a chimney draught, no steam being used, or only so much as could be drawn in with the air, this being supplied either by blowing a steam jet or a water jet under the bars, or by keeping the ashpit full of water, which was evaporated by the heat radiated from the fire bars or by the hot ashes falling into it. In such a producer the amount of steam used was very small. It appears at first sight as if the only conditions under which a chimney draught could be used would be when the producer was at a much lower level than the furnace, so that the gas had to pass upwards a condition that could very rarely be arranged. Sir W. Siemens overcame this difficulty by the introduction of the overhead cooling tube connecting the gas producer with the furnaces. The gas from the producer passed into a vertical brick stack 8ft. to 12ft. high, thence by a horizontal tube to near to the furnaces, which were intentionally placed at some distance from the producers, and then down by another vertical tube to the ports, or to an underground flue. The set of tubes thus arranged acted as a syphon to draw the gas over. The gas in the up-comer tube being hotter was much lighter than the cooler gas in the down-comer tube, and thus a syphon was produced, the legs of which were of equal length, but the gas in the one was much heavier than the gas in the other, thus producing a draught, and at the same time cooling the gas, so that a large proportion of the tar was condensed in the cooling tube. Siemens says that the cooling tube should have a surface of not less than 60 sq. ft. per producer. CHIMNEY DRAUGHT PRODUCERS. 47 Siemens thus explains the action of the tube. "The gas rising from the producer at a temperature of 1,100 Fah. is cooled as it passes along the overhead tube, and the descending column is consequently denser and heavier than the ascending column of the same length, and continually overbalances it. The system forms, in fact, a syphon in which the two limbs are of equal length, but one is filled with a heavier liquid than the other. The height of cooling tube required to produce as great a pressure as would be obtained by placing the gas producer, say, ten feet deeper in the ground may be readily calculated. The temperature of the gas as it rises from the producer has been taken as 1,100 Fah., and we may assume that it is cooled in the overhead tube to 100 Fah. an extent of cooling easily attained. The calculated specific gravity, referred to hydrogen, of the gas of which I have quoted the analysis, being 13'4. We obtain the following data : Weight of gas per cubic foot at 1,100 Fah. = '0221b. 100 Fah. = -OGllb. Weight of atmosphere per cubic foot at ................. 60 Fah. = '0761b. and from these we have on the one hand the increase of pressure per foot of height in the flue rising directly from the gas producer '076 "022 '0541b. per square foot, and on the other hand the excess of pressure at the foot of the down-take from the cooling tube over that at the same level in the flue leading up from the gas producer (per each foot of height of the cooling tube) = 061 -- -022 = -0391b. per square foot. The height of the cooling tube above the level of the flue which will be sufficient to produce the required pressure equal to _lQftr-of heated gas column is therefore X 10ft. = 13ft. lOin., or say 14ft." The cooling tube cools the gas and condenses a large amount of the tar and water, and this Siemens contended was an advantage. It will be seen that with the cooling tube, the air current must be very sluggish, and therefore the com- bustion must be slow, for the pressure will be very small. The layer of fuel will be much thicker in a producer than in an ordinary fireplace, though in a " chimney draught " producer it can never be very thick, and this * Siemens' Collected Works, Vol. I., p. 222. 48 FORCED DRAUGHT PRODUCERS. will retard the passage of the air. Such a producer must also work with an open hearth, so that air can have free access, and therefore very little steam can be used. The open-grate chimney draught producer is now very little used. When the air is supplied under pressure by a fan, or otherwise, the conditions are considerably changed, a much greater pressure can be used, and therefore com- bustion can be made much more rapid, the hearth can be closed, and air and steam supplied in any required proportions. The overhead cooling tube becomes unnecessary, the producers can be put as near the furnaces as is convenient, and underground flues can be used. Air and steam can be supplied in any convenient way, the air by means of a fan or blower, and the steam by a jet from a boiler, but as the air and steam are always required together, a steam jet blower is almost always used. BLOWERS. Steam Jet Blower. The principle of this blower is very simple. A jet of steam is blown into a tube leading to the producer, and carries with it, by friction, the air required. Siemens designed a steam jet blower for the purpose, which he described in a paper read before the Institution of Mechanical Engineers in 1872, and though simpler forms are now generally used for gas producers, this one is of great interest. It is shown in section in Fig 2. Siemens thus describes it : - " A very thin annular jet of steam is employed in the form of a hollow cylindrical column discharged from the annular orifice between the two conical nozzles, the steam being supplied from the pipe C into the space between the two nozzles. The inner nozzle can be adjusted up or down by the hand screw D so as to diminish or increase the area of the annular orifice between the two nozzles for regulating the quantity of steam issuing. The air to be propelled by the steam jet is admitted from the pipe E through an exterior annular orifice surrounding the steam jet, and also through the centre of the hollow jet. The tube G, into which the steam jet issues, is made of a conical shape at the bottom, so as to form with the outer nozzle STEAM JET BLOWERS. 49' a rapidly converging annular passage, regulated by adjust- ing the outer nozzle by means of the nut H at the bottom. The tube G continues to diverge very gradually for some distance above the jet orifice, the length of the convergent portion increasing with the outer annular air orifice, and also with the steam pressure employed." " A tapering spindle I is sometimes fixed in the centre of the inner nozzle and carried up through the mixing chamber G, for the purpose of preventing reflux through the centre of the combined current. UJJ 1 D FIG. 2. SIEMENS' STEAM JET. " The rationale of this arrangement is as follows r First, by gradually contracting the area of the air passages on approaching the jet the velocity of motion of the entering air is so much accelerated before it is brought into contact with the steam that the difference in the velocity of the two currents at the point where they come together is much reduced, and in consequence the eddies which previously impaired the efficiency of the steam jet are to a large extent obviated, and a higher useful effect is realised ; secondly, by the 50 STEAM JET BLOWERS. annular form of the steam jet the extent of surface between the air and the steam is greatly increased, and the quantity of air delivered is very much augmented in proportion to the quantity of steam employed."* By means of this jet used as an exhauster Siemens obtained a vacuum of 24in. of mercury, and with it he made many experiments to elucidate the laws according to which the jet blower acts. Principles of the Blower. As the jet of steam rushes from the orifice into the air it draws a considerable quantity of air with it, and if it be directed into a tube a stream of air and steam will be obtained. Apparatus on exactly the same principle is used for various purposes with fluids other than air and steam. In the trompe used in blowing the primitive Catalan forge for the manufacture of malleable iron, a current of water was the moving power, the air being carried along by it and discharged into the forge, and in the ordinary injectors used for feeding steam boilers a jet of steam is made to carry forward a stream of water. Sir W. Siemens says : " The result of a long series of experiments with this form of steam jet for exhausting and compressing air have led to the following con- clusions : " First, that the quantity of air delivered per minute by a steam jet depends 011 the extent of surface of contact between the air and steam irrespective of the steam pressure up to the limit of exhaustion or compression that the jet is capable of producing. " Second, that the maximum degree of vaccum or of pressure attainable increases in direct proportion to the steam pressure employed, other circumstances being similar. " Third, that the quantity of air delivered per minute within the limits of effective action of the apparatus is in inverse relation to the weight of air acted upon, and a better result is therefore obtained in exhausting air than in compressing it. " Fourth, the limits of air pressure attainable, with a given pressure of steam, are the same in compressing as in exhausting within the limit of a perfect vacuum in the latter case."t * Siemens' Collected Works, Vol. I., p. 142. t Siemens' Collected Works, Vol. I., p. 143. STEAM JET BLOWERS. 51 There are certainly other conditions besides steam pressure and the area of aperture of the steam jet which modify the action. If a jet of steam be blown from a nozzle so shaped that the jet is a cylinder, it will retain its form for a considerable distance, and therefore can only draw in the air by surface friction. On the other hand, if the jet be of such a form that the issuing jet of steam is conical, the area of section will increase rapidly, the steam will be mixed with the air, and the action will certainly not be merely due to friction of the air at the surface of the steam jet. The molecules of air being mixed with those of steam there will be impact, and the air will be swept forward by the steam, it has been said, " much in the same way as a piston would do, but, of course, with less solidity of action." In this case the propelling force would seem to be the momentum of the steam, which, in its turn, is due to the mass and the velocity. The best results seem, on the whole, to be obtained with solid diverging jets, and some engineers, after experimenting with hollow jets, have given them up, and returned to solid jets. The whole subject of the propelling force of the steam jet needs careful experimental examination. A blower therefore consists essentially of two parts, the steam jet and the tube into which it blows. Blower Tube. The receiving tube consists usually of two portions, a short upper portion expanding upwards, and a lower portion joining this at its narrowest point and expand- ing downwards. The best size has been arrived at by experience rather than from theory, and very few experi- ments have been made on the influence of varying size and form of the receiving tubes. As pointed out by Siemens, the upper part of the tube should be opened out into an inverted cone near the bottom of which the point blower should be put. The Simple Jet Blower. In this type of blower the steam jet is a simple tube, as shown in Fig. 3, the dimensions given being those commonly used. Annular Jets. A solid steam jet of small diameter, say jin., offers a very small surface of contact, so that the quantity of air carried forward is small in proportion to the amount of steam used, and as in a gas producer the quantity of steam that can be used with advantage is small, an excess of steam is likely to be supplied. 52 ANNULAR JETS. To overcome this difficulty annular jets have been devised. The jet is made much larger in diameter, but has a central air pipe, so that the steam escapes in the form of a ring, and air is admitted both inside and outside the jet. If the amount of air carried in depended entirely on the area of contact between the steam and air, a much larger quantity of air could thus be carried through by a given quantity of steam. The annular blowers have, however, not been altogether successful. The layer of steam is excessively thin, say /^in. or less, so that the continuity of the FIG. 3. STEAM JET. cylinder of steam is easily broken, and thus the efficiency is impaired, and therefore most users still prefer the solid jet. Adjustable Jets. It is often necessary, or at any rate advantageous, to be able to adjust the relative quantities of steam and air, and various blowers have been devised for the purpose. In the annular jet blowers adjustment is com- paratively simple. The best known of this type is the blower of Mr. Thwaite. (Fig. 4). In this two bronze nozzles are fitted, one inside the other, so as to leave an annular steam space, and they are so shaped that by ARGAND BLOWER. 53 raising or lowering the inner tube by means of a screw the width of the annular space can be increased or FIG. 4. THWAITE ADJUSTABLE ANNULAR STEAM JET BLOWER. diminished, thus increasing or diminishing the supply of steam, whilst the area of contact with the air remains unchanged. The Argand Blower. This type of blower (Fig. 5) has been used in the United States, and is said to be very sp AIR FIG. 5. ARGAND BLOWER. S.P., STEAM PIPE. efficient, but the author does not know if it has been used in this country. As will be seen from the illustration, 54 STEAM JET BLOWERS. the steam is delivered into a ring of circular or ellip- tical section, from which it passes by a large number of small holes, thus giving a very large number of small steam jets. By this means a very large surface of contact between the air and the steam is provided. The Korting Blower. In this blower a solid steam jet is used, which blows into an inverted cone like the top of the ordinary blower tube, the bottom of which opens into a second inverted cone into which the mixture of steam and air blows, this opens into a third, and, if required, a fourth, so that there are from three to five inverted cones through which the steam and air passes into the air tube, the volume of the gas being increased and its speed diminished in each. A pressure of from Sin. to 12in. of water can be obtained. The following details are given by Messrs. Korting : No. of blower ... 01234 5 6 7 Air delivered ) per minute in V 150 400 650 900 1500 2000 3000 4000 cubic feet ... ) Bore of steam IT -i ^ r pipeininches} t f ' 1 1* U If 2J Diameter ofl air conduit 4 8 9 10 12 13 16 18 in inches ... J The supply of steam can be regulated by~means of a spindle, which can be lowered into the top nozzle. Granger's Blower. This is a solid jet adjustable blower. It has three separate nozzles of different sizes, so arranged that by turning a handle any one of them can be brought into use, but never more than one at the same time, each jet as it comes into use coming at the same time into a position so as to be central with the tube. FIG. 6 A B C JETS. H, HANDLE FOR BRINGING ANY PARTICULAR JET INTO ACTION. BLOWER TUBE. 55 This blower seems to be one of the most efficient, and is very satisfactory in action. For ordinary purposes the smallest blower is used, but as any one of the others may be put into action varying proportions of steam and air may be obtained. If the amount of air depends only on the surface of contact, then as the surface of contact, i.e., FIG. 7. the circumference of section, varies as the radius, and the area varies as the square of the radius, the changing of the nozzle will increase both air and steam, but will increase the amount of steam in a larger ratio than the amount of air. The writer has no data by which he can determine to what extent this actually is the case. Other types of blowers have been suggested, but these are the principal ones in use. Blower Tube. The form of the blower tube is of great importance. (See Fig. 8.) The upper part has always the form of the frustum of an inverted cone, and at the Fio. 8. TUBE FOR STEAM JET BLOWER. bottom of this the current may be considered to be formed. It then widens out, so that, as the current of air and steam flows, its diameter is increased, and therefore its speed is reduced, till at the bottom of the tube it is delivered to the producer. Power of Blowers. The air is not required to be sent to the producer at a high pressure, from 5in. to lOin. of .56 AMOUNT OF STEAM REQUIRED. water being that usually used, though some blowers will give up to 12in. Mr. Thwaite gives the following table of the power of his annular blower : Diam. f S te amj et. ^.^ute'af Inches. atmospheric pressure. I 60 T 9 * 250 | 350 1 1,200 1J- 2,000 Steam at 601bs. pressure. Amount of Steam Required. The best proportions of steam and air cannot be rigidly fixed, the more steam that is used the better, until a limit is reached, this limit depending mainly upon the amount of heat that is available for decomposing the steam without unduly cooling the producer, and this will depend on the loss of heat in the producer itself. The average proportions when a producer is working well are about 10 parts steam and 90 parts air by volume, rising sometimes to 12' 5 parts of steam to 87'5 parts air, but rarely passing beyond this. Taking 10 per cent, of steam by volume as being a good working proportion, this will be about 6 per cent, of steam by weight, and about one-fifth of the carbon will be burnt by steam and four-fifths by air. Assuming 6 per cent, of steam by weight, it is very easy to calculate the amount of fuel that will be consumed. Since lib. of carbon will combine with l'331bs. oxygen to form carbon-monoxide, and air contains 23 per cent, by weight of oxygen, the amount of air required to burn lib. of carbon will be - - = 5'81bs., therefore lib. of O air will burn = '171 Ib. of carbon. o'o One pound of carbon in decomposing steam will also combine with l'331bs. of oxygen, and this will be contained in l'491bs. of steam, therefore lib. of steam will burn .. TQ = '671b. of carbon, so that for lOOlbs. of the gaseous JL 4y mixture '941bs. of air = '171 X 94 = 161bs. of carbon burnt by air. 61bs. of steam='67 X 6 = 4' ,, ,, ,, steam. 100 20- AMOUNT OF STEAM REQUIRED. 57 If loss of heat in the producer could be guarded against, a much larger proportion of steam could be used. One engineer of large experience has stated to the author that 7 per cent, by weight is the maximum amount of steam which should be used in an ordinary steam blown producer. Assuming the proportions above given to be correct, it is easy to ascertain what amount of steam will be required to work a gas producer. In all such calculations only the fixed carbon of the fuel must be taken into account, as all volatile matter will be expelled before the residue comes under the action of the air and steam. The amount of fixed carbon in and the amount of gas given off by the fuel should therefore always be determined. The amount of steam required will be Gibs, for each 201bs. of carbon burnt, or '31bs. of steam for each pound of carbon. Assuming the coal used to yield 60 per cent, of fixed carbon, '6 X *3 = "ISlbs. of steam will be required for each pound of coal consumed. To be on the safe side, the boilers should be capable of supplying two or three times this amount. Each pound of carbon will require 5'81bs. of air, or lib. ofcoal of the composition assumed will require 3'481bs. of air. As lib. of air under normal conditions of pressure and temperature occupies 12 "36 cub. ft., the volume of air required will be 58 '1 cub. ft. for each pound of carbon, or 34'9 cub. ft. for each pound ot coal consumed. The steam should be supplied at a high pressure, GOlbs. to 751bs. being usually used. CHAPTEK VI. CHIMNEY DRAUGHT PRODUCERS. CLOSED - HEARTH PRODUCERS. BAR-BOTTOM PRODUCERS. SOLID BOTTOM PRODUCERS. WATER - BOTTOM PRO- DUCERS. AUTOMATIC PRODUCERS. BLAST- FURNACE PRODUCERS. THE early forms of producer, such as those of Bischof and Ebelman, were little more than enlarged fireplaces, and for many reasons were not efficient. In 1861 Siemens introduced his gas producer, which did not differ in principle from those which had gone before, but which became a success, not so much on account of any improvement in the producer itself as because it was for the first time associated with the regenerative system of burning the gas, the regenerative gas furnace having just been invented by Siemens. The Siemens producer (Fig. 9) was a firebrick chamber about 8ft. square and 6ft. or 8ft. deep, narrowed at the bottom, by the front wall being sloped inwards, and provided with a series of firebars. The action of such a producer is very simple. Air enters through the firebars, and combustion takes place just as in an ordinary fireplace, the hot gases passing upwards are largely reduced to carbon monoxide by the action of the hot coke, and the volatile matters are distilled from the coal in the upper regions of the producer, aod the gas thus produced mixes with the carbon monoxide, carbon dioxide, and nitrogen from the combustion of the coke. The draught is produced entirely by the chimney, or rather by the overhead cooling tube, and is therefore a natural as distinguished from a forced draught. If the furnace could be placed at a considerable elevation above the producer the gas would tend to rise and produce sufficient pressure, but this is rarely possible, the furnaces and the producer being in most cases necessarily at about the same level. The draught obtained is only about '541bs. per square foot or '0031bs. per square inch, or, say, rt>m- of water. CHIMNEY DRAUGHT PRODUCERS. 59 Such a producer can never be very efficient. The draught is small, therefore the combustion is slow, rarely reaching lOlbs. of fuel per square foot of grate area per hour or less than that consumed in an ordinary boiler grate. There is always the possibility of the loss of fuel through the bars, so that the grate efficiency is low. The grates FIG. 9. SIEMENS GAS PRODUCER (OPEN TYPE). cannot be made of large size, as they must be of such form and size as to allow the ready removal of clinkers, 5ft. or 6ft. being the maximum satisfactory width. Assuming the hearth to be 5ft. X 8ft., this gives an area of 40ft., and with a combustion of lOlbs. per hour will give 4001bs. per hour per producer. The hearth .60 CHIMNEY DRAUGHT PRODUCERS. being open, very little steam can be used ; indeed, usually the only water vapour supplied is that evaporated from water in the ashpit or sprinkled on the bars, and there- fore the gasification is not likely to be economical. The layer of fuel must also be thin, so that usually a good deal of carbon-dioxide is present in the gas, and in order to produce a draught the gas must leave the producer at a high temperature, the sensible heat being completely lost in the cooling tube. On the other hand, the producer is cheap and easy to erect and to manage, and requires no steam supply ; but the disadvantages so far outweigh the advantages that open producers have almost ceased to be used. There are cases, however, such as when the producer can be practically made a fireplace, and the hot gas passed at once to the furnace, where this type of producer can be satisfactorily applied. The following is an analysis of gas made in a producer of this type, and will show its general character : By Volume. By Weight. Methane &c 4-40 2'5 Carbon monoxide Carbon dioxide Nitrogen 25-60 4-30 65-70 25-5 6-8 65'2 100-0.0 100-00 Calorific Power. C.U. B.Th.U. Methane -025 x 12000 = 300-0... -025 x 21000= 525 Carbon monoxide -255 x 2400-612- ...-255x 4320-1101-6 912-0 1626-6 lib. of gas will contain 'I462lb. carbon. If all the carbon were burnt to carbon dioxide it would evolve 1181-3 C.U., or 2126-3 B.Th.U., and the hydrogen burning to water would give213'6 C.U., or 379B.Th.U., so that the heat of combustion of the fuel used would be 1391'8 C.U., Q12 or 2495 B.Th.U., and the efficiency of the producer =T^QQ= 65 '5 per cent. CLOSED-HEARTH PRODUCERS. 61 CLOSED-HEARTH PRODUCERS. All modern producers are worked with closed hearths f the steam and air being supplied together. A much larger quantity of steam can thus be used, and it can be supplied much more rapidly and at a higher pressure. As the gas does not need to be hot to produce a draught, it can be cooled to a much greater extent before leaving the producer, if this be deemed desirable. A much richer gas can be obtained with, at the same time, much more rapid gasification, and the FIG. 10. SIEMENS CLOSED-HEARTH PRODUCER. process is much more completely under control. The overhead cooling tube, which gives a great deal of trouble from the accumulation of tar, also becomes unneces- sary, and is usually replaced by underground conduits. Siemens very early recognised the advantages of steam blowing, and suggested the use of his producer with a closed hearth, air and steam being blown beneath the- bars. Closed producers may be divided into five groups,, though it is impossible to arrange a classification that 62 CLOSED-HEARTH PRODUCERS. will be satisfactory from all points of view, and some producers might be put into more than one group : 1. Bar-bottom producers. 2. Solid-bottom producers. 3. Water-bottom producers. 4. Automatic producers. 5. Blast-furnace producers. I. Bar-bottom Producers. In producers of this type the fuel rests on firebars, exactly as in the earlier Siemens producer ; but the hearth is closed, the air and steam being supplied beneath the bars. Siemens suggested a producer of this type (Fig. 10) by merely closing the front of the ashpit of his producer and blowing air and steam beneath the bars. Another well-known producer FIG. 11. THWAITE SIMPLEX GAS PRODUCER. of the type is the Simplex of Mr. Thwaite (Fig. 11), modified also in the Twin and Duplex producers, which will be subsequently described; but the best known is CLOSED-HEARTH PRODUCERS. 68 probably that of Mr. Dowson, largely used in the preparation of gas for small motors and similar purposes. It is not necessary to discuss these producers in detail, as they are now rarely used except under special circumstances. The disadvantages of this type of producer are easily seen. Clinker accumulates on the bars, and must be removed from time to time by poking. The hearth must therefore be small to allow of easy clinkering, and as unburnt coal may fall through with the ashes the grate efficiency will be low. It is impossible to FIG. 12. THE DOWSON GAS PRODUCER. obtain very rapid gasification, rarely above 201bs. of fuel per square foot of grate area per hour. The bars can, however, be clinkered without actually stopping gas production, though this must necessarily be checked. For small plants these producers are still used, as they are easy to erect and to manage, but for large installations they have been almost completely abandoned. The Dowson Producer. (Patent, 1878, No. 3,997 ; 1881, No. 2,895.) This producer, however, calls for remark, owing to its extensive use in the production of gas for small gas engines. 64 CLOSED-HEARTH PRODUCERS. The generator is cylindrical, and consists of an iron casing lined with firebrick, and is provided at the bottom with firebars, on which the fuel is consumed, and beneath which a jet of air and steam is supplied. No special boiler is needed, but the steam is produced and superheated in a coil of pipe contained in a separate superheating furnace, which, when once the producer is started, is heated by part of the gas. Coal, anthracite, FIG. 12A. DOWSON'S GAS GENEBATOR. or coke may be used ; but when the gas is to be used for gas engines, one of the two last named is preferable, or the gas is purified by washing, as described later. Mr. Dowson has recently patented a new form of producer, which is shown in Fig. 12A. It is a bar- bottom producer, and the chief peculiarity is that it is so CLOSED-HEARTH PRODUCERS. 65 arranged that air can be aspirated through or supplied by a blower, as may be required. It comprises a casing A partly lined with firebricks B, an outer casing C with air inlet D and space E containing loose pieces of iron. There is a water supply F to chamber G- with overflow H and outlet I. When air is drawn into the generator by the action of the engine connected therewith, the air pressure in the chamber J is reduced, and water is thereby caused to flow through the outlet I from the chamber G where the pressure is momentarily in excess. The water thus admitted into the chamber J flows to one or more channels K K where all or part of it is evaporated, and the steam mixes with the heated air in inclosed space E. If any excess of water falls from the channels K K it will fall on the loose pieces of iron in the inclosed space E, and will then be evaporated by coming in contact with heated surfaces. When air is forced into the generator by means of a blower or pump, the overflow H is raised so that the head of water in the chamber G is sufficient to overcome the pressure caused by the blower or pump in the chamber J. The heated air and the water vapour formed in the inclosed space E pass downwards through the passage L to the lower part of generator M and thence upwards through the fire. The gas formed leaves the fire at N, and after passing through the passage round the fuel container T it leaves the generator at P. When the generator is worked by the suction of an engine, the level of the water in G can be regulated by the height of the overflow H, so that none will enter the generator until the engine sucks, and then it will automatically draw in the quantity of water required to be vaporised. In this way the quantity of water admitted and the quantity of steam produced are governed by the engine, and are in proportion to the quantity of gas produced in the generator. In some cases an excess of water is purposely allowed to drain from the space E on to the floor Q of the generator so that some water may be vaporised by the heat of the fire on the grate R. An overflow for any excess of water is provided at S. Fig. 13 shows a bar bottom producer used in Sweden for gasifying wood. Solid-bottom Producers. In these producers the fuel rests on the solid bottom of the combustion chamber, or, 66 CLOSED-HEARTH PRODUCERS. rather, when the producer is at work there is a layer of ash or clinker on the bottom, upon which the fuel in process of gasification rests. The air is blown into the mass of ash and fuel either near the bottom or higher up, and the clinker is drawn off from time to time through doors placed near the bottom, so that the charge can descend, a certain thickness of clinker being always left. FIG. 13. SWEDISH GAS PRODUCER FOR USING WOOD. As there are no firebars, and the fuel is kept high in the producer, the combustion is almost if not quite perfect, and the grate efficiency approaches 1. The air and steam are supplied into the centre of the hot mass of fuel, and the combustion is rapid and complete. The air supply may be either by a central pipe or by a passage passing across the chamber. So there are no bars to be clinkered, and the ash only need be withdrawn periodically. This can be done from both sides or from several points in the circumference if necessary, and the hearth can be made larger than when bars are used. Essentially, therefore, such a producer consists of a firebrick chamber, round, square, or of any other form, cased with iron, and having a flat or slightly sloping bottom, and an arrangement for blowing in air and steam. The details may be modified to almost any extent, engineers frequently building producers for themselves CLOSED-HEARTH PRODUCERS. 67 to suit their own needs. If a producer of this sort is to be a success, great attention must be given to the arrangements for the supply of steam and air, so that it shall be evenly distributed through the mass, and no portion of the fuel shall escape combustion (this being far more important than in the case of bar-bottom producers, where the bars act as distributors), and to FIG. 14. WILSON GAS PRODUCER. arrangements for the withdrawal of ashes. If the producer, be too large, or be not properly provided with cleaning doors, it will be impossible to remove the ashes completely. As a rule, a distance of about 2ft. Gin. to 3ft. is as great as it is possible to reach to remove the ashes, unless the charge be held up, when a somewhat greater thickness is 68 CLOSED-HEARTH PRODUCERS. allowable. Either, therefore, there must be an efficient means of holding up the charge during cleaning, or the producer must be considerably narrowed at the bottom. Many solid-bottom producers have been designed, but only one or two need be mentioned. The Wilson Producer. This is the best known and most widely used of all the solid-bottom producers. It was patented by Messrs. Brook & Wilson in 1876. The original producer was square, but as now used it is always circular. It consists of a shell of firebrick cased with iron (Fig. 14), the internal diameter being usually about 8ft. The air and steam are supplied by a blower into a conical tube which opens into a brick passage running across the producer and com- municating with the interior by a series of rectangular openings. On each side of this air passage is a cleaning door for the removal of the ashes, and narrow doors are placed a little above the level of the air passage, so that a line joining them is at right angles to it. Clinker can be allowed to accumulate to any height that may be desired, and the air and steam passing through this on its way upward becomes hot. The air and steam, as will be seen, are delivered into the centre of the contents of the producer, and combustioi-i is very perfect. The maximum size which such a producer can be made depends on the power of the air to reach the circumference, as, should it fail to do so, fuel would escape combustion and would be lost in the ashes. These producers are made up to 12ft. in diameter, and a con- sumption of 401bs. of fuel per square foot of bottom can be obtained. The gas is also usually richer than that made in bar-bottom producers. The clinker has to be removed about once every 24 hours. For this purpose the blast is turned off, the narrow side doors are opened, and iron bars are put through, so as to rest on the top of the air passage, thus forming a sort of grate to support the contents of the upper part of the producer whilst the ashes are drawn out. The cleaning doors are then opened and the ashes raked out, the doors are closed, the bars withdrawn, the side doors closed, and the blast put on, the whole opera- tion of cleaning occupying about half an hour. Another important part of the Wilson producer is the arrangement for destroying tar. At the top of the pro- ducer a cone of brickwork is built, so as to descend about CLOSED-HEARTH PRODUCERS. 69 2ft. 6in. into the producer, and is supported by arches thrown from the lining, so as to form an annular space round the top, communicating with the interior of the producer by the above-mentioned arches, and also with the gas main. As the producer is kept full of coal, distillation can only take place at the top, and the products of distillation must pass downwards through the hot fuel before reaching the gas main. The tarry matters are thus decomposed by the hot coke into carbon, which is afterwards burnt, and permanent gases, which escape. The apparatus is efficient and compact. The ordinary size will gasify 4 cwt. of coal per hour. The space occupied is only about 9ft. by 14ft., allowing 126 square feet for coal storage. The table shown is an analysis of Wilson gas published by Mr. Wilson. By Volume. By Weight. Nitrogen 55-96 61'66 Carbon monoxide Hydrogen 22-32 12-11 24-59 95 Carbon dioxide Marsh gas 6-18 3-43 10-65 2*15 100-00 ] 00-00 It will be readily seen that solid-bottom producers may be modified to almost any extent. Fig. 15 shows a form used at one steel works. The brick air passage is replaced by an iron tube opening by a number of openings into the body of the producer, and com- municating below with an air chamber into which air and steam are supplied by the blowers. Across the producer is fixed an iron bar to carry the ends of the temporary bars used for holding up the charge during cleaning. The old type of Siemens open producer can readily be converted into a solid-bottom producer. Fig. 16 illustrates the method of doing this. A ridge or brick- work, carrying an air tube, is built up longitudinally along the bottom of the producer, and cleaning doors are arranged at each side of it. WATER-BOTTOM PRODUCERS. WATER-BOTTOM PRODUCERS 71 All solid-bottom producers are intermittent in their action ; that is, they must be periodically stopped for cleaning. If, however, the ashes be allowed to fall into a vessel of water, so arranged that there is a water seal to prevent the escape of gas, the ashes can be removed at intervals without stopping the gas production. Such j'jl|^jUi"^Vj.j'jjVtV\{-'f' *^,;j^ i*'!. '''I '-'!.'''.' ^V^'^V.^j jjAVil!A*i^f ^l^'l^.^U^-'?J^ ^ jm^ flRISPR^^t * *eT -"Ws' '"* ^A^T "^^"''''^'T^^'^^H-^j 1 !^^ "S^'?r v FIG. 16. SIEMENS OPEN PRODUCER CONVERTED INTO A SOLID-BOTTOM PRODUCER. a producer is usually called a water-bottom producer. In addition to allowing the ready removal of ashes, the ash is thoroughly cooled, any heat it may bring down being utilised in vaporising some water. It has been stated by at least one steel works chemist that, when steel is made in a furnace fired by gas from a water-bottom producer, there is much greater difficulty 72 WATER-BOTTOM PRODUCERS. in keeping down the sulphur in the steel than when dry- bottom producers are used. The author has made exten- sive inquiries among steel makers, and' whilst one or two think this to be the case, the majority have noticed no indication of such an action. Under these circum- stances it does not seem that there is any serious danger in this direction, except, perhaps, when an extremely low sulphur content is required, but he mentions the matter in order to induce those who have the opportunity to make experiments on it. The only FIG. 17. THE DAWSON PRODUCER. explanation of such a fact will be that certain sulphides, such as iron sulphide (iron pyrites) or calcium sulphide (from calcium sulphate), which might remain in the ash in the case of the dry-bottom producers, might be decomposed by water, the sulphur passing into the gas as hydrogen sulphide, in the case of the water-bottom producer. The first water-bottom producer was that of Mr. Dawson ; but as this type has been modified, it will be WATER-BOTTOM PRODUCERS. 73 sufficient to describe the later type of Dawson producer, patented in 1894, No. 15,150. The Dawson Producer. This producer (Fig. 17) consists of a circular shell of masonry cased with iron plates, supported on short columns, the casing plates being continued downwards into a water trough so as to give a water seal all round sufficient to prevent the escape of gas. The air and steam are supplied in the usual way, and are delivered by means of a vertical pipe covered with a hood, which passes well up into the mass of fuel. Poking holes are provided round the circumference and at the top. The ashes can be drawn all round the circumference, and as the blast need not be stopped, the producer can be worked continuously. The Duff Producer. Of the modern water-bottom producers the best known and most largely used is that of Mr. Duff (Fig. 18). This may be made circular or square, but is usually made circular externally, the internal brickwork being so arranged as to give a rectangular combustion chamber. It is cased with iron, and the casing -dips into a water trough on the two sides so as to form a water seal. Across the body of the producer from back to front, and occupying about half the width of the producer, is a ridge of brickwork. On this are fixed vertical iron plates, and above these two sloping grates. The producer is thus divided into two parts, about half the area being occupied by the grates, the other half by the water trough. The air is blown into the space beneath the grate, and passes between the bars into the fuel. The supernatant mass of fuel is thus partly supported on the grate and partly on the mass of ashes resting on the water trough, and as the charge sinks the ashes slip off the bars into the water trough. The producer is very easily cleaned, as the space from whicrj the ashes have to be raked is comparatively narrow. The essential peculiarity of the producer is the arrangement of its bars, and these, as will be seen, differ in function from the bars of an ordinary bar-bottom producer m so far that the ashes are not removed through them, but slide off. This principle can obviously be applied to other forms ot producer. The old type Siemens producer, for instance, can be comparatively easily converted into a producer of the Duff type. WATER-BOTTOM PRODUCERS. 75 The details of water-bottom producers can, of course, be varied indefinitely. In the Swindell producer inclined grates are used, sloping from the sides downwards, but not meeting, so as to leave a central mass of ash which passes down into the water trough, from which it can be drawn as usual. In the Thwaite small power producer (Fig. 19) a hanging grate is used, the ashes passing centrally into FIG. 19. THE THWAITE SMALL POWER PRODUCER. the water trough, the air being supplied into an annular space round the bars. The Wilson Water-bottom Producer. The Wilson producer may readily be converted into a water-bottom producer. This is done by Mr. Wilson, as shown in Fig. 20. ^ / Smith and Wincott Producer (Patent 1901, No. 12,895). This is the most recent and one of the best of the water- bottom producers. It is circular, cased with iron, the casing WATER-BOTTOM PRODUCERS WATER-BOTTOM PRODUCERS. 77 78 AUTOMATIC PRODUCERS. being carried down so as to form a water seal in the usual manner. The principal peculiarity is in the way in which the air and steam is supplied to the fuel. This is by a vertical central pipe which is widened out at the top so as to form an inverted cone, which at the top may have a diameter of about 3ft. A series of openings are provided FIG. 20. WILSON WATER-BOTTOM GAS PRODUCER. all round this by which the air and steam passes into the fuel, and the top is closed by a loosely fitting cap. Owing to the form of these openings there is a very large area for the passage of the air and steam, and these cannot possibly become choked with ash, a great advantage, especially with some classes of fuel. -AUTOMATIC PRODUCERS. In producers of this type the ashes are removed continuously by means of mechanism, so that hand labour is unnecessary. As the amount of labour required for water-bottom producers is very small, it is doubtful how far the application of mechanism will be economical. The first automatic producer, which, in a sense, was also the first of the water-bottom producers, was that of Mr. Alfred Wilson (see Fig. 22), which has now been in use for many years, and has proved itself to be efficient in practice. AUTOMATIC PRODUCERS. 79 The Wilson Automatic Producer. In some respects this resembles the ordinary Wilson producer, but the air and steam supply is placed at a much higher level, and the spaces each side, instead of being flat-bottomed, are circular in section, and inclined from back to front, so as to make two conical troughs, in each of FIG. 22. WILSON AUTOMATIC GAS PRODUCER. which works a screw by which the ashes are slowly pushed out. The troughs are kept filled with water, so as to keep the screws cool and protect them from oxidation. The wear and tear is said to be very slight, the screw lasting for years, and the power required to turn it is also small. The Taylor Producer. This is an American invention, and the author is not aware that it is in use in this country. The bottom of the producer (Fig. 23) is closed by an iron plate, beneath which is the ashpit, and through the centre of which passes the pipe for supplying the air and steam. The iron 80 DOWN-DRAUGHT PRODUCERS. bottom plate is a little larger than the bottom opening of the producer, and is so placed as to leave an annular space all round. As the ashes accumulate the bottom is rotated, a few turns being given occasionally. FIG. 23. TAYLOR PRODUCER. This breaks up the cinder and forces some of the ashes over the edge of the plate into the ashpit. A few turns of the bottom at frequent intervals will keep the fuel bed itlways in a solid condition and at the same level. DOWN-DRAUGHT PRODUCERS. Several attempts have been made to arrange pro- ducers in which the mixture of air and steam is supplied at the top of the gasifying chamber and the gas drawn off from the bottom, the idea apparently being that the tarry matters would be more completely destroyed. (See DOWN-DRAUGHT PRODUCERS. 81 Chapter IX.) Such producers have not come largely into use, and are subject to very serious defects, and especially to great difficulty in the removal of the ash. The first of these, that of Mr. Howson, was simply a solid-bottom producer, with apertures in the floor for the escape of the gas and doors for the withdrawal of the ash, the fuel being charged, as usual, at the top, and the air and steam being supplied from a series of ports near the top. Korting's Producer. This producer is a bar-bottom down- draught producer. It is made in several forms to deal with variations in the quality of the fuel available ; but that designed for use with bituminous coal, which is shown in Fig. 23A, will illustrate the principle on which FIG. 23A. KORTING'S GAS PRODUCES. it works. The producer is provided with a series of horizontal firebars on which the fuel rests, and with two vertical grates, C and C 1 , in this case on opposite sides of the producer, one near the bottom, the other near the top, each provided with its own air main F F 1 . The fuel is supplied, as usual, from the hopper B, and the air and steam passing in from the grates causes gasification. A passage N is provided so that the gas produced in the- upper part of the producer may find its way to the lower part without passing through the fuel. The gas is drawn off through the grate L to the main M. Ashes can be 82 DOWN-DRAUGHT PRODUCERS. removed through the door G. The vertical grates may be on the same or on opposite side of the producer. The producers described are, of course, but a few selected from the innumerable forms which have been described and patented. They are, however, typical, and the author does not think he has omitted any distinct types, though, obviously, details may be varied to almost any extent. THE BLAST FURNACE AS A GAS PRODUCER. An enormous amount of combustible gas is made in the blast furnaces used for smelting iron. As this gas is a by-product, the blast furnace should hardly be classed as a gas producer in the sense in which gas producers are considered here, but as the gas from it is very largely used for steam raising, furnace firing, and driving gas engines it deserves a brief consideration. At the tuyeres, in presence of a large excess of carbon and at a very high temperature, which necessarily exists in such a furnace, all the oxygen of the air is combined to carbon monoxide, and, as the only moisture carried in is that of the air, the amount of hydrogen in the gas is very small. As the gas reaches the upper part of the furnace, carbon monoxide is added to it from the reduction of the carbon dioxide of the limestone by the hot carbon, and at the same time carbon dioxide is formed by the action of the carbon monoxide on the oxide of iron ; thus the gas will be some what poorer in carbon monoxide and much poorer in hydrogen than producer gas made from coke with the aid of steam. When raw coal is used in the blast furnace the gas distilled from it will of course mix with the carbon monoxide, carbon dioxide, and nitrogen. The following analysis by volume will indicate the nature of the gas from a coke-fed blast furnace. (i) (2) (3) Carbon monoxide 28-80 29-50 28-10 Carbon dioxide Nitrogen 12-90 57-60 9-00 60-00 10-00 61-00 Hydrogen 0-70 1-50 0-90 From a coal-fed furnace the amount of hydrocarbons will be much larger. For example : BLAST-FURNACE PRODUCERS. 83 (l) (2) (3) (4) Carbon dioxide ... 8-57 8-61 5-40 6-79 Carbon monoxide. . . 27-15 28-06 30-10 26-40 Hydrogen 5-48 5-45 6-26 12-23 Marsh gas 4-27 4-37 3-20 71 Nitrogen 54-29 53-38 55-10 58-81 It will be seen, therefore, that the gas from a coal-fed furnace is little inferior to ordinary, and better than some varieties of producer gas. The blast furnace, taking into account the other work which it has to do, is probably the most perfect gas producing machine in existence. The column of material is so high that cooling is very perfect, and would be much more so if it were not for the reduction of the oxide of iron which takes place near the top of the furnace, and owing to the depth of the column of material and the high temperature the reduction of carbon dioxide to carbon monoxide is perfect, and as the slag is tapped in a liquid condition there can be no loss of unconsumed carbon. It has been suggested to model gas producers on the lines of the blast furnaces, adding a little limestone to flux away the ash of the coke, and where a sufficiently large quantity of gas is required such a type of producer would probably be very efficient. Steam could be used as in ordinary producers, but only in limited quantity. The high initial cost would be the chief drawback to a producer of this type. An ordinary Scotch blast furnace will gasify about 550 tons of coal a week, or something over three tons an hour, the diameter of the hearth being but little larger than an ordinary gas producer, whilst a modern Cleveland furnace will gasify about 1,500 tons of coke per week, or nearly nine tons an hour. The Thwaite Rapid Cupola Producer. Mr. B. H. Thwaite has recently designed a producer of the blast-furnace type, which is the first attempt to apply what many have long thought to be the correct principle to practice, and a large installation is at present in course of erection. The essential differences between this and the ordinary type of producer are (1) that air is supplied at a high pressure, (2) no steam is used, (3) the temperature is sufficiently high to fuse the slag, suitable fluxes being added when necessary. OF 84 BLAST-FURNACE PRODUCERS. The generator is very like a cupola furnace, about 30ft. high and about 6ft. internal diameter. The air is supplied a little above the bottom by a series of horizontal tuyeres at a pressure of about 21bs. or 31bs. on the square inch, though any convenient pressure can be used. The gas, which leaves the producer at a low tempera- ture, is forced through a "hydraulic head" to separate the tar, then through suitable washers if necessary to a gas holder. The bottom of the producer is so shaped that the liquid slag can be tapped off through a tap hole. 3.46 -' FIG. 23B. THWAITE'S GAS PBODUCEK FOB MOTIVE POWEB. A is the gas producer, which is supplied with fuel by the elevator B. C is a sciubber or rough filter, and D is a tubular recuperator in which the gas is cooled and the air for combustion is warmed. From this the gas passes to the purifier H, and thence to the gas holder I. The gas is good and of very uniform quality, and owing to the thorough absorption of heat by the mass of fuel in the upper part of the stack the loss of heat is small, and the producer has a very large gasifying capacity. Very little labour is needed, the combustion is complete, and the slag is very easily removed. Automatic charging is easily applied, the fuel being lifted by means of an endless BLAST-FURNACE PRODUCERS. 85 belt lifter and deposited in the charging hopper. The slag is easily converted into a perfectly white slag wool, for which there is a considerable demand. The following analyses are of gas made in a producer of this type : i. 2. 3. Carbon monoxide Marsh gas Hydrogen Total combustible Nitrogen Carbon dioxide . . Non- combustible 29-50 1-56 3-80 63-47 1-67 27-0 1-9 5-5 61-4 4-2 25-24 1-79 . 7-50 61-55 3-92 34-86 34-4 34-53 65-14 65-6 65-47 100-00 100-00 100-00 100-00 100-00 100-00 CHAPTEK VII. ; MOND GAS. THE PRODUCER. THE CONDENSING PLANT. THE PRODUCTS. COST OF WORKING. As has already been pointed out, if a very large excess of steam be blown into a gas producer, a great deal of it will pass through undecomposed. At the same time this will lead to a considerable modification in the reactions taking place. The amount of steam decomposed will be very large, so that the quantity of hydrogen in the gas will be much larger than in ordinary cases, sometimes rising above 25 per cent, by volume ; at the same time the temperature will be much reduced, and from one-half to two-thirds of the carbon will be oxidised to carbon-dioxide. Such a gas will therefore be very different in character from ordinary producer gas, and must be judged by different standards. It is largely a hydrogen and not a carbon monoxide gas. It is not likely such a gas would ever have been made commercially if the process had been considered only from the standpoint of gas production, but the alteration in the method of working brings with it another important change. In an ordinary producer fed with coal comparatively little of the nitrogen escapes in the form of ammonia, especially if the top of the producer be hot, but in presence of a large amount of steam and free hydrogen, and at the necessarily lower temperature of a producer blown with a large excess of steam up to 70 per cent, of the nitrogen in the fuel can be obtained in the form of ammonia, and thus, though the process is more costly, the extra cost may be more than paid for by the large amount of ammonia obtained. Mr. Beilby some years ago erected a plant at the Oak Bank Oil Works for the preparation of gas and recovery of ammonia, a large excess of steam being used. The method used was based on the principle adopted by Messrs. Young & Beilby in their retorts for the distilla- tion of shale and recovery of the ammonia. The plant is thus described in Mills & Kowans' fuel, p. 276 : " A number of vertical retorts are grouped together in a bench or double row, with passages surrounding them for the circulation of the heating gases." These are built of brick, and " have the exit pipe for the gases at about the MOND GAS. 87 middle of their height. The coal is fed in from hoppers at the top, and is distilled at a good heat in the upper part of the retorts. The tar vapours, together with the steam, pass down through the hot coke, and are decom- posed into permanent gases and ammonia, no tar being found in the pipes when the temperature is properly regulated. The coke passing into the lower half of the retorts is burnt in a mixture of steam and air, with excess of steam in order to secure the ammonia, and the gases from this portion ascend and pass away by the exit pipe. In starting these retorts it is necessary to obtain some gas for combustion in the chambers surrounding them in order to heat them up. This may be made from coke in a subsidiary producer placed alongside. The gases from the retorts are drawn away by the main, and are passed through condensers and scrubbers, when the ammonia is separated and recovered." About 75 per cent, of the nitrogen in the fuel is recovered as ammonia. Mond's Process. Dr. Ludwig Mond commenced experi- menting with gas plant about 1879, and in his presidential address to the Society of Chemical Industry in 1889 he pointed out what had been done in the direction of recovering ammonia from the products of the gasification of coal, and gave drawings of a gas producer and con- densing plant he had devised, and with which he had obtained good results. The plant now used is a modifica- tion and improvement of that there described, but the principle is exactly the same. The plant and method of working will be slightly modified according to whether the main object is the production of gas or the recovery of ammonia. It was principally with a view to the ammonia recovery that the process was devised. The Plant. The plant consists essentially of two parts, the gas producer and the condensing and recovery plant. The Producer. The producer now used is of the water-bottom type, and consists of a double-cylindrical wrought-iron shell, lined with firebrick up to near the top as usual. The bottom of the producer is narrowed, and terminates in an iron ring, on which hang the fire- bars which form a continuation of the producer, and being attached at the bottom to another iron ring form a hanging grate, through the centre of which the ashes pass out into the water trough. The outer shell of the producer is prolonged downwards into the trough of water so as to form a water seal, and the ashes are 88 MOND GAS. drawn from beneath this by means of spades and rakes in the usual way. In the centre of the top of the producer is the charging hopper, to which is attached a bell, which extends some distance into the producer, and which is always surrounded by hot gas when the producer FIG. 24. MOND PRODUCER. is at work. Steam and air are supplied into the space between the two casings of the producer, and passing downwards are delivered in a ring outside the grate, and thence pass into the mass of fuel, the gas being drawn off near the top of the producer as usual. MOND GAS. 89 The Condensing Plant. One characteristic of the Mond plant is its condensing plant. This is essential even if it be not desired to recover the by-products, on account of the large quantity of steam used, and the necessity for condensing the undecomposed excess. The ordinary plant consists of three portions, the regenerators, the washer, and the towers. The regenerators are a series of double wrought-iron tubes united alternately at bottom and top. The hot gas from the producer passes through the inner tubes, up and down, and the mixture of steam and air for supplying the producer passes in the opposite direction through the annular space between the inner and outer tubes, thus surrounding the hot gas, and as the gas is cooled the air and steam mixture is heated. The washer to which the gas next passes is a large wrought-iron chamber partly filled with water &nd provided with mechanical dashers fixed along the surface of the water in such a way that as they rotate the blades throw up a large quantity of spray which fills the chamber. The gas is thus cooled to about 90, and the water vapour formed is swept forward, so that there is no condensation of ammonia liquor. Three towers are used, called respectively the ammonia recovery or acid tower, the gas-cooling tower, and the air heating and saturating tower. The gas passes first to the acid tower, entering at the bottom and passing upwards. The tower is filled with a checker-work of firebrick, so as to give a large surface of contact, and a rain of sulphuric acid liquor is allowed to fall down it, which, meeting the free ammonia in the ascending gases, converts it into sulphate. The acid liquor contains only about 4 per cent, of free acid, and is circulated continuously by means of a pump, its strength being maintained uniform by drawing off the sulphate liquor and adding a corresponding amount of fresh acid. The liquor and acid is passed through a settling tank, so as to be thoroughly mixed before it reaches the pump. The gas from the acid tower, deprived of its ammonia, passes from the top of the tower into a large wrought- iron vessel, 12ft. diam., filled with wood packing so arranged as to give a large surface. The gas containing its burden of steam has here to meet a downward current of cold water, which considerably reduces its temperature. 90 MOND GAS. "When entering the gas-cooling tower it (the gas) is nearly saturated with steam, so that as its temperature begins to fall its capacity for carrying steam rapidly diminishes, and condensation takes place. The table (Appendix 1) shows how considerable the condensation must be, and the result is the utilisation of the latent heat of the steam, as well as the sensible heat of the steam and gas, in raising the temperature of the circu- lating water, which consequently escapes hot."* " From the gas-cooling tow r er the gas is conveyed by the gas mains to the furnaces for combustion for use in gas engines. In the works at North wich more than 24,000,000 cub. ft. of gas are used daily." The hot water which leaves this tower is pumped to the top of the heating and saturating tower, where its heat is given back to the cold air passing through on its way to feed the producer, and it is at the same time saturated with water vapour. The air is forced through the apparatus and to the producer by suitable blowers. The Steam. The amount of steam used is about 2J- tons per ton of fuel consumed. As a ton of carbon could only decompose 1| tons of water even if it were completely oxidised by steam, and as the fuel will probably not contain more than 60 per cent, of carbon, a considerable quantity of which will be burnt by air, by far the greater portion of the steam will pass through undecomposed ; probably, at least, two tons so passing. Hence the necessity for the elaborate condensing plant. The Products. Owing to the low temperature of the producer and the large excess of steam, the gas is very unlike ordinary producer gas. The percentage of carbon- dioxide and of hydrogen is high, and that of carbon- monoxide is low. The following analysis shows the composition of the gas : By Volume. By Weight. Carbon-monoxide iro 13'1 Carbon-dioxide 17-1 32-0 IVEarsh Sfas rs 1'2 Olefines 4 5 Hydrogen . . 27 '2 2-2 Nitrogen 42-5 51-0 100-0 100-0 * Humphrey's, Proc. Inst. Civ. Eng. cxxix., pt. 3. MOND GAS. 91 The calorific power of such a gas will be Carbon monoxide... '131 X 2400=314 C 11= 565B.T.U. Marsh gas '012x12000=144 ,,= 259 Olefines (Qe C n H 2n ) '005x10000= 50 = 90 Hydrogen '022x29300=644 ,,=1159 1152 2073 and as 1000 cub. ft. weighs about 65'681bs., 1000 cub. ft. will give 75,663 CU of heat=136,193 B.T.U. The loss of heat in the producer is about 20 per cent., so that the heating power of the gas is about 80 per cent, of that of the fuel consumed. The gas is free from tar and excess of moisture, burns with a non-luminous flame, and has been successfully used for most purposes for which fuel gas is required, including steel melting. Ammonia. The ammonia recovered is equal to about 90 Ibs. of sulphate for each ton of coal consumed, or one ton of sulphate for each 23 tons of coal. As a rule, of course, Mond gas will be made chiefly for the purpose of recovering the by-products, in which case about 2J tons of steam will be used per ton of fuel, but a similar gas can be made without by-product recovery, in which case only about half this amount of steam need be used. In a paper read before the Institute of Civil Engineers, Mr. Humphreys gave a detailed account of experiments in connection with the working of a Mond gas plant. Those interested should refer to the paper. STATEMENT OF COST OF WQEKING A MOND PEODUCEE AND KECOVEEY PL ANT. t (At Winnington, Cheshire.) Price of coal per ton at works... ... ... 6 2 Selling price of sulphate. Price, August, 1896, net naked at works per ton 7 4 6 1 ton of sulphate is obtained from 23 tons of fuel gasified, but adding fuel for steam required the total is 28-56 tons. Cost per ton of sulphate of ammonia made Total cost of all fuel (28'56 tons at 6/2) ... 8 16 1 Wages at producers (23 tons at 6'4d.) 12 3 J Humphreys. 92 MOND GAS. Manufacturing, wages, administration 19 Manufacturing, wages, labour 19 8 Repair wages and materials, including renewals 18 3 Lubricants 1 8 Gas for lighting purposes 311 Sulphuric acid 0'95 tons at 145Tw 1 4 4 Total for above 12 17 11 Selling price of sulphate naked at works ... 7 4 6 Final cost of 23 tons of fuel gasified 5 13 5 or final cost of gas from 1 ton fuel gasified 4 11 or cost of 1,000 cubic feet of gas (at 15 C) 0'351d. or gas for 1 h.p. will cost '02685d. or gas for Ih. p. for 24 hours a day for a year 19 7'2 The Duff Plant. It will be evident that gas could be made with other types of producer, but the only one which seems to have been actually used in this way is the "Duff," an installation of which, put up by the United Alkali Company, at Fleetwood, has been running since the spring of 1899, gasifying 500 tons of slack per week without a stop or hitch of any kind, except a slight overhaul after twelve months' working. The producers used are rectangular, and the slack is distributed mechanically into large hoppers placed directly above the charging hoppers of the gas producers. The gas, as it leaves the producer, enters the recuperators or superheaters, which are narrow rectangular tanks or chambers with partitions to direct the passage of the air and steam on its way to the producers. These chambers contain zig-zag vertical pipes which convey the hot gases from the producer on their way to the washing plant. The gas then passes to the washing tower, where it meets a stream of descending sulphuric acid ; then to a cooling tower, in which the gas is cooled before passing to the engines ; and beyond this is a third tower where the incoming air meets the hot water from the cooling tower, and this becomes heated and charged with water vapour." It will be seen that the condensing plant closely resembles that used in the Mond process. Quite apart from the recovery of by-products, the gas made with excess of steam, which we may call Mond gas, seems to have advantages over ordinary producer gas MOND GAS. 93 for gas engines, and some other purposes. Such a gas may be made in any type of producer by using a large excess of steam, and if the ammonia is not to be recovered the excess of steam need not be so large as that used by Mr. Mond, probably one ton for each ton of coal burnt will be sufficient, and much less elaborate condensing plant will be necessary. CHAPTER VIII. WATER GAS. THE LEEDS PLANT. THE LOOMIS PLANT. THE DELLWIK-FLEISCHER PROCESS. PROPERTIES OF WATER GAS. As has been already pointed out, when steam is passed over red hot coke it is decomposed, and- a mixture of carbon monoxide and hydrogen is producd thus C + H 2 = CO+2H. This reaction, as will be seen, is made up of two parts, the decomposition of a molecule of water which will absorb heat, and the formation of a molecule of carbon monoxide which will evolve heat. The thermal result will be, starting from liquid water Heat of formation of one molecule of carbon monoxide 29000 + Heat of decomposition of one molecule of water 68360 Balance ... ... 39360- If, however, as will actually be the case in practice, steam be used, the latent heat of steam must be deducted from the figure given for the calorific power of hydrogen. The figures will then be Heat of decomposition of one mole- cule of water 68360 Latent heat of steam, 537 x 18 ... 9666 Heat of decomposition of steam ... ... 58694 Heat of formation of one molecule of carbon monoxide . 29000 + 29694 If the reaction is to go on, this 29694 units of heat must be supplied from outside. It will be seen, therefore, that such a process must either be worked intermittently, or else heat must be supplied by the combustion of fuel in some other way. The intermittent method of working has been almost 96 WATER GAS. universally used. Air is first blown over hot coke till the mass becomes very hot, the reaction being C + O = CO, by which 29,000 C units of heat are evolved for each 12 parts of carbon consumed. Steam is then blown over the hot coke, water gas being produced till the mass is so far cooled that the decomposition does not take place readily. The steam is then shut off, and air sent in till the coke is once more hot, and so on. Theoretically the gas should contain equal volumes of carbon monoxide and hydrogen, so that its composition would be : By Volume. By Weight. Carbon monoxide ... 50 93-33 Hydrogen . ... ... 50 6-67 100 100-00 Owing to the conditions of production, however, small quantities of nitrogen and carbon dioxide are always present. The idea of the manufacture of such gas must have occurred to makers of producer gas, and it is impossible to say by whom it was first put into practice, but a plant for the production of water gas is said to have existed at Phenixville, Pa., in 1874. A patent was granted to J. S. C. Lowe in 1875, and in 1886 the committee of the Franklin Institute awarded a medal of honour to Mr. Lowe for his pioneering work. Little was heard in this country of water gas as distinguished of course from the gas made in producers into which steam was blown at the same time as air, till the formation of the British Water Gas Syndicate and the erection of the plant of Mr. Samson Fox at the Leeds Forge in 1888. The Leeds Forge Plant. As this plant may be regarded as being the pioneer British plant, it will be taken as a type of the class of apparatus to which it belongs. " The generator consists of a cylindrical vessel of boiler-plate lined with firebrick. The bottom of the generator is somewhat narrowed, and the fuel WATER GAS. 97 falls on to the bottom in a cone, leaving an annulus round which alternately the air passes to the fuel, and the gas escapes from the fuel. Connected with this annulus through a port or passage formed in the brickwork is the valve chamber, which is kept cool by circulating water, and is provided with three passages, FIG. 26. WATER-GAS PLANT AT THE LEEDS FORGE. through one of which the air passes, and through another the gas escapes, the centre passage being in connection with the generator. The valve slides on the face of this box, and has a double U-shaped port which may be brought into alternate connection with either the air or gas passage and the centre passage." 98 WATER GAS. The air enters from the main under suitable pressure, being regulated by the valve, and the gas main conducts the water gas through a scrubber to the gas holder. From the upper part of the producer a producer gas main leads to the furnaces or other appliances where the producer gas is to be burned, and a pipe from a boiler leads a supply of steam to the upper part of the producer above the level of the fuel. The working is intermittent, coke or anthracite is charged by the hopper, the producer being kept full. Air is blown in from the air main, combustion takes place, and a gas, which is a simple producer gas, consisting almost entirely of carbon monoxide and nitrogen, passes away by the producer gas main. As the combustion of the coke evolves heat, the temperature rapidly rises. As soon as the charge is hot enough the air is shut off, and the producer gas valve is closed and the steam valve and the water gas valves are opened. The steam passing through tke coke is decomposed, and water gas is formed. This goes on till the coke is sufficiently cooled, when the current is again reversed. In the plant at the Leeds Forge, gas was made for 4 mins., and the heating up occupied 10 mins. Clinker was cleaned out every six hours through doors at the bottom of the generator, the process occupying about 8 mins. The average yield of water gas from common gas coke is about 34,000 cub. ft. to the ton, and the production of each generator in use at the Leeds Forge was 2,200 cub. ft. per hour, or 52,800 cub. ft. per day, the cost of gas being under 4d. per 1,000 cub. ft., including fuel, water, wages, superintendence, depreciation, and interest. Each cubic foot of water produces 2,250 cub. ft. of gas, or one ton of water (which in Leeds costs 1 Jd.) will produce 84,000 cub. ft. of gas. The amount of producer gas made is very large. Mr. Fox stated that three-quarters of the fuel was used in heat- ing up i.e., in the production of producer gas each ton of coke yielding 34,000 cub. ft. of water gas and 140,000 cub. ft. of producer gas, so that unless use can be made of the producer gas the process is not likely to be economical. WATER GAS. 99 If the producer gas formed in the heating-up stage is not to be used for fuel it can be used to heat the steam (so as to lengthen the time occupied in gas production), to raise the necessary steam, or in some other way. In Germany very similar plant was erected in 1885. The Lowe Producer. The producer described above is essentially that of Lowe, but the Lowe process as developed in America has been modified, and has been largely used for producing a lighting gas, for which purpose the water gas must be enriched with petroleum or some similar hydrocarbon, since water gas itself burns with a non-luminous flame. The apparatus consists of two parts a producer and a regenerator the latter being a circular chamber lined with firebrick and filled with a chequer-work of firebrick. The producer gas formed during the heating up is passed into the regenerator and there burnt, thus heating the brickwork to a very high temperature. When the heating up is finished, steam is put on in the usual way. At the top of the regenerator the water gas is made to meet a fine spray of petroleum, which is at once volatilised, and, passing over the hot brick work in the regenerator, is decomposed into permanent gases, which pass through the scrubber to the gasholder. The process is worked intermittently, as in the Leeds plant. The Loomis Plant. The producer used in this apparatus consists of a cylindrical casing lined with firebrick, about 12ft. by 9ft. At the top is a charging hopper, as usual, and at the bottom a firebrick grate over an ashpit. As originally described, the ashpit was divided by fireclay slabs. Air was drawn down through a series of ports, and the hot producer gas heated the fire- clay slabs under the grate to a very high temperature. When heating up was complete steam was blown into the ashpit, being there intensely heated by passing over the fireclay slabs, and passed up through the hot coke, producing water gas. Mr. Loomis gave the following estimate of gas produc- tion in his producer per 1,000,000 cub. ft., the coal costing about $3 a ton. 100 WATER GAS. Coal 25 tons 75 Coal for steam- 3 tons ... ... ... 9 Labour 22 Supplies and repairs ... ... ... 4 Purifying ... ... ... ... ... 5 115 Received for producer gas ... ... 44 75 Interest and depreciation... ... ... 25 S100 Or cost per 1,000 cub. ft., $0-10, or say 5d. ; or if the producer gas be lost, $0'14, say 7d. In the newer plants erected by the Loomis-Pettibone Company the arrangement is a little different. Two producers similar to that described above, except that there are no fireclay slabs in the ashpit, are worked together and are attached to a vertical boiler provided with suitable valves. " In starting fires, a layer of coal or coke about 5ft in depth is put on and ignited at the top, an exhauster creating a downward draught. When the body of the fuel is ignited coal is frequently charged, raising the fuel bed to about 8ft. above the grates, at which height it is maintained. Bituminous coal is generally used, and is charged at intervals as needed through, the feed door at the top of the generator." Air is also admitted by the same door, and by means of an exhauster is drawn down through the fresh charge of coal and through the hot bed of fuel beneath. The resultant producer or generator gas is drawn through the grates and ashpits of generators Nos. 1 and 2, the valves A and B, up through the vertical boiler to the scrubber and exhauster, through the valve C, and is delivered into a small gasholder for supply to the furnaces. When the exhauster has brought the fuel up to incandescence the charging doors E F are closed, valve B lowered, the valve C closed, and the valve D leading to the water gasholder opened. Steam is then turned on into the ashpit of generator 2, and in passing through the incandescent coal is decomposed, forming water gas. From generator 2 the To x/?aas fer a/xt To Producer Gas S/o/afes -Jo Lxfrousrer as>c/ Proc/vcer ~ Cos Ho/off r FIG. 27. LOOMIS-PETTIBONE WATEB-GAS PLANT. 102 WATER GAS. gas passes through the connecting pipe shown near the top of the generator and down through producer No. 1, through valve A into and up through the boiler, away by valve D, and then, after being washed in a scrubbier, is conducted into a holder. Water gas is made for 5 mins., when the temperature of the fuel beds having been considerably reduced the steam is shut off, and air is admitted. In starting the next run of water gas, the steam is sent into the bottom of generator 1. It will be seen that in this method of working, though coal is or may be used, the tarry matter will be com- pletely broken up by passing through the thick layer of hot fuel, and the steam is very completely decomposed ; also the sensible heat of the gases is to a large extent used in raising steam. The producer and water gas are sent to separate gas- holders, but may be mixed in one holder should it be thought to be desirable, or they may be used from the holders in any suitable proportion. The Dcllwik-Flcischcr Plant. It will be seen that all the forms of plant described indeed all in use until the introduction of the Dellwik-Fleischer plant labour under the disadvantage that during the heating-up stage a large quantity of producer gas is made, because under the conditions which hold in the producers it is impossible to oxidise the carbon more completely than to carbon monoxide. Thus but little heat is evolved in the producer, and a combustible gas escapes. " If the carbon could be burnt to carbon dioxide, the whole of the available heat of combustion would be evolved in the producer, thus the heating-up stage could be very much shortened, and no producer gas would be made. Messrs. Dellwik & Fleischer have succeeded in doing this, and their plant, therefore, marks an enormous forward step in the production of water gas indeed, makes it possible to make and use water gas economically where there is no demand for producer gas, which is hardly possible with any of the older types of plant. The essential difference between the plant of Messrs. Dellwik and Fleischer and the earlier types is that while in the latter the fuel bed was made so thick, and the quantity of air supplied was so small that the carbon dioxide WATER GAS. 103 formed at first was almost completely decomposed by the hot carbon, as in ordinary gas producers, in the former the bed of fuel is made so thin, and the air is supplied in such quantity that the carbon is completely burnt to carbon dioxide. The results which are obtained by this change are described in the following extract and accompanying table from Mr. Dellwik's paper, read before the Iron and Steel Institute in 1900.* The chemistry of the process is, of course, exactly the same as that of the other processes. It is described as follows by Mr. Dellwik : " If we look into the chemical reaction in the forma- tion of water gas, we find that 181bs. of steam, consisting of 21bs. of hydrogen and 161bs. of oxygen, require for their decomposition 2x28,780=57,560 thermal units. The 161bs. of oxygen combines with 121bs. of carbon to 281bs. of carbon monoxide, which in mixture with the 21bs. of hydrogen form 301bs. == 753-4 cub. ft. of water gas. The heat developed by the formation of the carbon monoxide is 12 x 2,400 = 28,800 thermal units, thus leaving a balance of 57,560-28,800=28,760 thermal units, which must be replaced by the combustion of carbon during the blows. Assuming, then, as is approxi- mately the case in practice, that the blow gas leaves the generator at a temperature of 700 C., we find lib. C requires for combustion .... The O is accom- panied by .... and the products of - combustion carry with them at 700 C The heat of com- bustion of lib. Cis . Old Method. to CO 1| Ibs. 4-321bs. N 1,136 Th.U. 2,400 Th.U. Dellwik Method. 32 12 to C0 2 ?? Ibs. O Balance available ) oinn 1 1 QA i, i- .LI. r 24:00 l.lob for heating the \- i O