'HE UNIVERSITY OF CALIFORNIA LIBRDRY OF THE UNIVERSITY OF CUIFORNK LIBRII HE UNIVERSITY OF CALIFORNIA LIBRARY OF THE UNIVERSITY OF CALIFORNIA LIBRAI 9i IHE UNIVERSITY OF CALIFORNIA LIBRARY OF THE UNIVERSITY OF CALIFORNIA LIBRA IIVERSITY OF CUIFORNU LIBRARY OF THE UNIVERSITY OF CALIFORNIA LIBRARY OF >ibte? J IIVERSITY OF CALIFORNIA LIBRARY OF THE UNIVERSITY OF CALIFORNIA LIBRARY OF \^/Tb UVERSITV OF CHIFORNIA LIBRARY OF THE UNIVERSITY OF CHIFBRNU U8RRt OF ' 1 OTthofhombic, 2 Monoclmic -Tncluxed Dispersion. 3 jVlono clinic - .Horizontal Dispersion. r s - r -iic 'Cro'ssed Dispersion.. 1 SPtcruUi-son, Wewtta vtn, Cl. A TEXT-BOOK OF MINERALOGY WITH AN EXTENDED TREATISE ON CRYSTALLOGRAPHY AND PHYSICAL MINERALOGY. b\ EDWARD SALISBURY DANA, CURATOR OP MINERALOGY, YALE COLLEGE. ON THE PLAN AND WITH THE CO-OPERATION OP PROFESSOR JAMES D. DANA WITH UPWARDS OF EIGHT HUNDRED WOODCUTS ANO "oNE COLORED* 'fr-ATE. NEWLY REVISED AND ENLARGED. (HTH EDITION.) ' NEW YORK: JOHN WILEY & SONS, 15 ASTOR PLACE. 1885, PMYSIC8 PHYSICS DfiPT COPTRIGHT BT EDWARD S. DATTA, 1877. PREFACE. THE preparation of a "Text-Book of Mineralogy" was undertaken in 1868, by Prof. J. D. Dana, immediately after the publication of the fifth edition of the System of Mineralogy. The state of his health, however, early compelled him to relinquish the work, and he was not able subsequently to resume it. Finally, after the lapse of seven years, the editorship of the volume was placed in the hands of the writer, who has endeavored to carry out the original plan. The work is intended to meet the requirements of class instruction. With this end in view the Descriptive part has been made subordinate to the more important subjects embraced under Physical Mineralogy. The Crystallography is presented after the methods of Naumann ; his system being most easily understood by the beginner, and most convenient for giving a general knowledge of the principles of the Science. For use in calculations, however, it is much less satisfactory than the method of Miller, and a concise exposition of Miller's System has accordingly been added in the Appendix. The chapter on the Physical Characters of Min- erals has been expanded to a considerable length, but not more than was absolutely necessary in order to make clearly intelligible the methods of using the principles in the practical study of crystals. For a still fuller discussion of these subjects reference may be made to the works of Schrauf and of Groth, and for details in regard to the optical characters of mineral species to the Mineralogy of M. DesCloizeaux. The Descriptive part of the volume is an abridgment of the System of Mineralogy, and to that work the student is referred for the history of each upecies and a complete list of its synonyms ; for an enumeration of ob- served crystalline planes, and their angles ; for all published analyses ; 665366 IV PREFACE. for a fuller description of localities and methods of occurrence, and also foi an account of many species of uncertain character, not mentioned in the following pages. 'A considerable number of changes and additions, how- over, have been made in the preparation of the present work, made neces- sary by the progress in the Science, and among these are included many new species. The chemical formulas are those of modern Chemistry. The new edition of Rammelsberg's Handbuch der Mineralchemie has been often used in the preparation of the volume, and frequent references to him will be found in the text. The work has throughout been under the supervision of Prof. Dana, and all the proofs have passed under his eye. Acknowledgments are also due to Prof. G. J. Brush and Prof. J. P. Cooke for friendly advice on manj points. PREFACE TO THE REVISED EDITION. IN this Revised Edition, the chief additions are contained in four sup- plementary chapters, covering about fifty pages. Of these, two are devoted to descriptions of new instruments and methods of research in Crystallog- raphy and Physical Mineralogy; and the others to brief descriptions of the minerals recently announced, and a concise statement of important new facts in regard to the characters or occurrence of old species. A number of new figures are introduced in illustration of these subjects. The work has been repaged ; and a new index, much more complete than the former one, has been added. >!EW HAVEN, January, 1883. TABLE OF CONTENTS. INTRODUCTION. F A. R, r r i. PHYSICAL MINERALOGY. Section I. CRYSTALLOGRAPHY. FAOB DESCRIPTIVE CRYSTALLOGRAPHY 1-83 General Characters of Crystals 1 Descriptions of some of the Simpler Forms of Crystals 3 Systems of Crystallization 8 Laws with reference to the Planes of Crystals 10 I. Isometric System 14 II. Tetragonal System 25 III. Hexagonal System 31 IV. Orthorhombic System 41 V. Monoclinic System 47 VI. Triclinic System 50 MATHEMATICAL CRYSTALLOGRAPHY 51 Methods of Calculation in General . 53 Special Methods of Calculation in the different Systems 62 Measurement of the Angles of Crystals 83 COMPOUND OR TWIN CRYSTALS 88 IRREGULARITIES OF CRYSTALS 102 CRYSTALLINE AGGREGATES. Ill PSEUDOMORPHOUS CRYSTALS 113 Section I. SUPPLEMENTARY CHAPTER. Improved Instruments for the Measurement of the Angles of Crystals 115 Section II. PHYSICAL CHARACTERS OF MINERALS. I. COHESION AND ELASTICITY i!9 Cleavage and Fracture 119 Hardness 1-0 Tenacity 121 II. SPECIFIC GRAVITY 123 III. LIGHT 125 Fundamental Principles of Optics 125 Distinguishing Optical Characters of Crystals of the different Systems 135 Isometric Crystals 135 Uniaxial Crystals 136 Biaxial Crystals 144 Diaphaneity ; Color 161 Lustre. . . 167 Vi TABLE OF CONTENTS. PAGE IV. HEAT .................................................................... 168 V. ELECTRICITY MAGNETISM ................................................... 169 VI. TASTE AND ODOR ............................................ .............. 171 Section II. SUPPLEMENTARY CHAPTER. I. COHESION AND ELASTICITY ................................................... 173 II. SPECIFIC GRAVITY .......................................................... 173 III. LIGHT ......................................... ........................ 177 Determination of Indices of Refraction .................................... 177 Polarization Instruments .................................... ........... 178 Discussion of the Various Explanations offered for Observed " Optical Anoma- lies " of Crystals .................................................... 185 II. CHEMICAL MINERALOGY. Chemical Constitution of Minerals ____ . ........................................... 191 Dimorphism ; Isomorphism ...................................................... 199 Chemical Examination of Minerals : In the Wet Way ........................................................ 202 In the Dry Way ; Blowpipe Analysis ..................................... 203 III. DESCRIPTIVE MINERALOGY. Classification of Mineral Species .................................................. 215 Description of Mineral Species .......................... * ........... . .......... 221-419 Supplementary Chapter ...................................................... 420-440 APPENDIX A. Miller's System of Crystallography .................................. 441 APPENDIX B. On the Drawing of Figures of Crystals .............................. 463 APPENDIX C. Catalogue of American Localities of Minerals ........................ 473 APPENDIX C. Supplementary Chapter ............................................ 503 GENERAL INDEX. . , INTRODUCTION. THE Third Kingdom of Nature, the Inorganic, embraces all species nut organized by living growth. Unlike a plant or animal, an inorganic spe- cies is a simple chemical compound, possessing unity of chemical and physi- cal nature throughout, and alike in essential characters through all diversity of age or size. The Science of Mineralogy treats of those inorganic species which occur ready formed in or about the earth. It is therefore but a fragment of the Science of Inorganic nature, and it owes its separate consideration simply to convenience. The Inorganic Compounds are formed by the same forces, and on the same principles, whether produced in the laboratory of the chemist or in outdoor nature, and are strictly no more artificial in one case than in the other. Calcium carbonate of the chemical laboratory is in every character the same identical substance with calcium carbonate, or calcite, found in the rocks, and in each case is evolved by nature's operations. There is hence nothing whatever in the character of mineral species that entitles them to constitute a separate division in the natural classification of Inorganic species. The objects of Mineralogy proper are three-fold : 1, to present the true idea of each species ; 2, to exhibit the means and methods of distinguishing species, which object is however partly accomplished in the former ; 3, to make known the modes of occurrence and associations of species, and their geographical distribution. In presenting the science in this Text Book, the following order is adopted : I. PHYSICAL MINERALOGY, comprising that elementary discussion with regard to the structure and form, and the physical qualities essential to a right understanding of mineral species, and their distinctions. II. CHEMICAL AND DETERMINATIVE MINERALOGY, presenting briefly the general characters of species considered as chemical compounds, also giving the special methods of distinguishing species, and tables constructed for this purpose. The latter subject is preceded by a few words on the use of the blow-pipe. III. DESCRIPTIVE MINERALOGY, comprising the classification and descrip- tions of species and their varieties. The descriptions include the physical and chemical properties of the most common and important of the minerals, Vlll INTRODUCTION. with some account also of their association and geographical distribution. The rarer species, and those of uncertain composition, are only very briefly noticed. Besides the above, there is also the department of Economic Mine] alogy, which is not hero included. It treats of the uses of minerals, (1) as ores; (2) in jewelry ; and (3) in the coarser arts. The following subjects connected with minerals properly pertain to Geology : 1, Lithdo- gical geology, or Lithohgy, which treats of minerals as constituents of rocks. 2, Chemical geology, which considers in one of its subdivisions the origin of minerals, as determined, in the light of chemistry, by the associations of species, the alterations which species are liable to, or which they are known to have undergone, and the general nature, origin, and changes of the earth's rock formations. Under chemical geology, the department which considers especially the associations of species, and the order of succession in such associations, has received the special name of the par agenesis of minerals ; while the origin of minerals or rocks through alteration, is called metamorphism or pseudomorphism, the latter term being restricted to those cases in which the crystalline form, and sometimes also the cleavage, of a mineral is retained after the change. LITEKATUKE. For a catalogue of mineralogical works, and of periodicals, and transactions of Scientific Societies in which mineralogical memoirs have been and are published, reference is made to the System of Mineralogy (1868), pp. xxxv-xlv., Appendix II. (18 T4), and Appendix III. ^1882). The following works, however, deserve to be mentioned, as they will be found use- ful as books of reference. In CRYSTALLOGRAPHY Naumann. Lehrbuch der reinen und angewandten Krystallographie. 2 vols., 8vo. Leipzig, 1829. Naumann. Anfangsgrtinde der Krystallographie. 2d ed., 292 pp., 8vo. Leipzig, 1854. Naumann. Elemente dertheoretischen Krystallographie. ii83 pp., 8vo. Leipzig, 1856. Miller. A Treatise on Crystallography. Cambridge, 1889. Grailich. Lehrbuch der Krystallographie von W. H. Miller. 328 pp., 8vo. Vienna, 1856. Kopp. Einleitung in die Krystallographie. 348 pp., 8vo. Braunschweig, 1862. Von Lang. Lehrbuch der Krystallographie. 358pp., 8vo. Vienna, 18(>i5. Quenstedt. Grundriss der bestimmenden und rechnenden Krystallographie. Tubingen, 1873. Rose-Sadebeck. Elemente der Krystallographie. Cd ed., vol. i., 181 pp., 8vo. Berlin, 1873. Vol. ii., Angewandte Krystallographie. 284 pp., 8vo. Berlin, 1876. Schrauf. Lehrbuch der Physikalischen Mineralogie. Vol. i., Krystallographie. 251 pp., 8vo., 1866 ; vol. ii., Die angewandte Physik der Krystalle. 426 pp. Vienna, 1868. Grroth. Physikalische Krystallographie. 527pp., 8vo. Leipzig, 1876. Klein. Einleitung in die Krystallbercchnung. 39o pp., 8vo. Stuttgart, 1876. Mallard. Traite de Cristallographie geometrique et physique, vol. i. Paris, 1876. Bauerman. Text-Book of Systematic Mineralogy. Vol. i., 367 pp , 12mo. London. 1881. LieUsch. Geometrische Krystallographie. 464 pp., 8vo. Leipzig, 1881. Tschcrmak. Lehrbuch der Mineralogie. Lief. I., II., pp. 1-308. Vienna, 1881-82. _ In PHYSICAL MINERALOGY the works of Schrauf (1868), and Grotli (1870), and TschermaJc, titles as in the above list. Reference is also made to the works on Physics, mentioned on p. 160. In addition to these, on pp. Ill, 122, 160, 167, 171, 190, a few memoirs of especial importance on the different subjects are enumerated. In CHEMICAL MINERALOGY : ftammelsbera^Haridbuch der Mineral chemie, 2d ed., Leipzig, 1875. In Determinative Mineralogy, Brush, New York, 1878. In DESCRIPTIVE MINERALOGY : among recent works those of Brooke and Miller (2d ed. of Phillips' Min.), London, 1852; Quenstedt, 3d ed., Tubingen, 1877; Schrctuf, Atlas der Krystallformen, Lief. I.-V., 1871-1878 ; Grotli (Tabellarische Uebersicht der Mineralien, etc.), 2d ed., 1882; v. Kokscharof, Materialien zur Mineralogie Russ lands, vol. i., 1865, vol. viii., 1881 ; Des Cloizeaux, vol. i., 1862, vol. ii., Paris, 1874; Dana, System of Miner- alogy, 1888, App. I., 1872, App. II., 1874, App. III., 1882; Blum, 4th ed., 1874; Nau- mann-Zirkel, llth ed., 1881. The following publications are devoted particularly to Mineralogy : Jahrbuch fiir Mineralogie ; G. Leonhard and H. B. Geinitz, Editors ; after 1879, E. W. Benecke, C. Klein, and H. Rosenbusch. Mineralogische Mittheilungen ; commenced 1872, G. Tschermak, Editor ; since 1878, published as the Mineralogische und Petrographische Mittheilungen. Mineralogical Magazine and Journal of the Mineralogical Society ; London, and Truro, Cornwall. Commenced 1875. Zcitschri-ft fiir Krystallographie ; P. Groth. Editor ; Leipzig. Commenced 1876. Bulletin de la Societe Mineralogique de France. Commenced 1878. ABBKEYIATIONS. For abbreviations of the names of Mineralogical works, of Journals, publications of Scientific Societies, etc., see System Min., 5th ed., pp. xxxv.-xlv., App. III., p. viii. The following abbreviations are used in the Description of Species. B.B. Before the Blowpipe (p. 210). Obs. Observations on occurrence, etc. Comp. Composition. O.F. Oxidizing Flame (p. 204). Diff. Differences, or distinctive characters. Pyr. Pyrognostics. G. Specific Gravity. Q. Ratio. Quantivalent Ratio (p. 198). Germ. German. R.F. Reducing Flame (p. 204). H. . Hardness. Var. Varieties. An asterisk (*), appended to the name of a mineral species in the Descriptive part of this work, indicates that additional facts in regard to it are mentioned in the Supplementary Chapter, pp. 420 to 440. ix I. PHYSICAL MINERALOGY. THE grand departments of the science here considered are the following 1. STRUCTURE. Structure in Inorganic nature is a result of mathemati- cal symmetry in the action of cohesive attraction. The forms produced are regular solids called crystals ; whence morphology is, in the Inorganic kingdom, called CRYSTALLOLOGY. It is the science of structure in this king - dom of nature. 2. PHYSICAL PROPERTIES OF MINERALS, or those depending on relations to light, heat, electricity, magnetism ; on differences as to density or specific gravity, hardness, taste, odor, etc. Crystallology is naturally divided into, I. CRYSTALLOGRAPHY, which treats of the forms resulting from crystallization ; II. CRYSTALLOGENY, which de- scribes the methods of making crystals, and discusses the theories of their origin. Only the former of these two subjects is treated of in this work. SECTION L v. ,_;FGS^; * CRYSTALLOGRAPHY. Crystallography embraces the consideration of (1) normally formed or regular crystals ; (2) twin or compound crystals ; (3) the irregularities of crystals ; (4) crystalline aggregates ; and (5) pseudomorphous crystals. 1. GENERAL CHARACTERS OF CRYSTALS. (1) External form. Crystals are bounded by plane surfaces, called simply planes or faces, symmetrically arranged in refer- ence to one or more diametral lines called axes. In the an- nexed figure the planes 1 and the planes i are symmetrically arranged with reference to the vertical axis c c ; and also the planes of each kind with reference to the three transverse axes. (2) Constancy of angle in, the same species. The crystals of any species are essentially constant in the angle of inclination w between like planes. The angle between 1 and i, in a given species, is always essentially the same, wherever the crystal is found, and whether a product of natfcre or of the laboratory. CRYSTALLOGRAPHY. (3) Difference of angle of different species. The crystals of different species commonly differ in angles between corresponding planes. The angles of crystals are consequently a means of distinguishing species. (4) Diversity of planes. While in the crystals of a given species there is constancy of angle between like planes, the forms of the crystals may be exceedingly diverse. The accompanying figures are examples of a few of the forms of the species zircon. There is hardly any limit to the number of forms which may occur ; yet for each the angles between like planes are essentially constant. Crystals occur of all sizes, r frpm the merest microscopic point to a yard or more in diame- ter. , A single crystal pir qnart$, now at Milan, is three and a quarter feet long, and five and a half in /circumference 5 ^Tnji'VtS weight is estimated at eight hundred and seventy pounds. A single davity in a vein of quartz near the Tiefen Glacier, in Switzerland, discovered in 1867, h?,s r affoide(?. fifni(ky Tjivartz crystals weighing in the aggregate about 20,000 pounds ; a co^.d^r^Vjle.iiuVnber'.cC? r ttfe- P slRgle r crystals having a weight of 200 to 850 pounds, or even more/ One of the gigantic beryls from Acworth, New Hampshire, measures four feet in length, and two and a half in circumference; and another, at Graf ton, is over four feet long, and thirty-two inches in one of its diameters, and does not weigh less than two and a half tons. But the highest perfection of form and transparency are found only in crystals of small size. In its original signification the term crystal was applied only to crystals of quartz (f. 1), which the ancient philosophers believed to be water congealed by intense cold. Hence the term, from Kpvo9, large), and a shorter lateral, the brachydiagonal axis (named from /3pa^u9, short). 3. Eight Rectangular Prism (f. 24). Base a rectangle, and in conse- quence of its unequal sides, two opposite lateral planes of the prism are broader than the other two. Edges all rectangular, but of three kinds : (a) four longer basal ; (b) four shorter basal ; (a) four lateral. Axes con- necting the" centres of opposite faces, rectangular, unequal ; a vertical, a macrodiagonal, and a brachy diagonal, being like those of the right rhom- bic prism. In the rectangular prism, either of the faces may be made the basal, and either axis, consequently, the vertical. 4. Oblique Prisms. Figs. 25 and 26 represent prisms oblique in the direction of one axis. As seen in them, the vertical axis c is oblique to the lateral axis , called the dinodiagonal axis ; but b, the orthodiagonal axis, is at right angles to both c and d. Similarly, the axial sections cb, # are mutually oblique in their inclinations, while ca, cb and ca, ba are at right angles. The dinodiagonal section ca is called the section or plane of sym- metry. The form in f. 25 is sometimes called an oblique rhombic prism. The edges are of two kinds as to length, but of four kinds as to interfacial angles over them : (a) four basal obtuse ; (b) four basal acute ; (c) two lateral ob- tuse : (d) two lateral acute. The prism is in position when placed with the dinodiagunal section vertical. Figs. 27 and 28 show the doubly oblique, or oblique rhomboidal prism, in which all the axes, and hence all the axial sections, are oblique to each CRYSTALLOGRAPHY. other. All these cases will receive further attention in the description of actual crystalline forms. 25 26 27 28 The prisms (in f. 21, 24, 26, 28) in which the planes are parallel to tho three diametral sections, are sometimes called (Jiainetral prisms. This term also evidently includes the cube. The planes which form these diametral prisms are often called pinacoids. The terminal plane is the basal pinacoid, or simply base ; also, in f. 24 the plane (lettered ^-1) parallel to the macrodiagonal section is called the macropinacoid, and the plane (i-i) parallel to the brachy diagonal the Irachypinacoid. In f. 26 the plane (i-i) parallel the\tb ortho-diagonal section is called the orthopinacoid, and the plane (i-i) parallel to the clinodiagonal section the chnopinacoid. The word pinacoid is from the Greek TrtWf, a board. (c). SIX-SIDED PRISM. The Hexagonal prism. Base an equilateral hexagon. Edges of two kinds : (a) twelve basal, equal and similar, (b) six lateral, equal and similar ; interfacial angle over the former 90, ove.r the latter 120. Solid angles, twelve, similar. Axes: a vertical, of different length in different species ; three late- ral equal, intersecting at angles of 60, as in the rhombohedron, and the dihexagonal pyramid or quartzoid, connecting the centres either of the lateral edges (f . 29), or lateral faces (f. 30). 3. SYSTEMS OF CRYSTALLIZATION. The systems of crystallization are based on the mathematical relations of the forms ; the axes are lines assumed in order to exhibit these relations, they mark the degree of symmetry which belongs to each group of forms, and which is in fact the fundamental distinction between them. The num- ber of axes, as has been stated, is either three or four the number being four when there are three lateral axes, as occurs only in hexagonal forms. Among the forms with three axes, all possible conditions of the axes exist both as to relative lengths and inclinations ; that is, there are (as has been exemplified in the forms which have been described), (A) among ortho- metric kinds, or those with rectangular axial intersections ; (a) the three axes equal ; (b) two equal, and the other longer or shorter than the two ; (c) the three unequal ; and (B) among clinometrio kinds, one or more of the intersections may be oblique (in all of these the three axes are unequal). The systems are then as follows : A. Axes three ; orthometric. 1. ISOMETRIC SYSTEM. Axes equa". Examples,, cube, regular octahe- dron, rhombic dodecahedron CRYSTALLOGRAPHY. 9 ^ 2. TETRAGONAL SYSTEM. Lateral axes equal ; the vertical a varying axis Ex., square prism, square octahedron. 3. OBTHORUOMBIO SYSTEM. Axes unequal. Ex., right rhombic prism< rectangular prism, rhombic octahedron. B. Axes three; clinometric. 1. MONOCLINIC SYSTEM. Axes unequal ; one of the axial intersection oblique, the other two rectangular. Ex., the oblique prisms (f. 25, 26). 2. TRICLINIG SYSTEM. Axes unequal ; three of the axial intersections ob- lique. Ex., oblique rhomboidal prism (f. 27, 28). C. Axes four. HEXAGONAL SYSTEM. Three lateral axes eqnal, intersect- ing at angles of 60. The vertical axis of variable length. Example, hexagonal prisms (f. 29, 30). The so-called Diclinic system (two oblique axes) is not known to occur, for the single sub- stance, an artificial salt, supposed to crystallize in this system has been shown by von Zepha- rovich to be triclinic. Moreover, von Lang, Quenstedt, and others have shown mathemati- cally that there can be only six distinct systems. The six systems may also be arranged in the following groups: 1. Isometric (from ttro?, equal, and /uerpoi/, measure), the axes being all equal; including: I. ISOMETRIC SYSTEM. 2. Isodiametric, the lateral axes or diameters being equal; including: II. TETRAGONAL SYSTP:M ; III. HEXAGONAL SYSTEM. 3. Anisometric (from aVt1 / / ~^""i y 1 / / to/' ^_2 r , _-.-- V V an infinite distance, its position is expressed by c : oo b : oo a, as is illus- trated by f. 36 ; again, its position is expressed by oo c : I : oo 0, if parallel to G and a ; and by oo c : oo b : a, if parallel to c, b. These may also be written Oc : fl : 1, n = m. 1 [m] when m > 1, n = 1. 1 [1] when m and n = 1. 1 \i-ri\ when m = oo , n > 1. 1 [i] when m = oo , n = 1. 1 [ZT] when m and n = In lettering the planes of the several forms only the essential part of the symbol is used: tha cube is // (hexahedron) ; the octahedron 1(=1 1 : 1) the dodecahedron i (oo : 1 : 1), ( i stands for infinity) ; m is used for the planes m : 1 : ] ; m-m for m : m : 1 ; i-n for f symmetry. ~lL\\e'se\Q\\ kinds of solids described on pp. 15 to 19, include all the holohedral forms possible in this system, as is evident from their geometrical development. In them exists the/highest degree of sym metry possible in any geometrical solids. In' the cube, as lias already been stated, all planes, solid angles, and edges are equal and similar. The three diametral planes, passing each through two of the axes, arp the chief planes of symmetry, every part of the crystal TETRAGONAL SYSTEM. on one side of the plane having its equal and symmetrical part on the oppo- site side. Further than this, each of the six planes passing through the diagonal edges of the cube, and consequently parallel to the dodecahedral planes, are also planes of symmetry. There are hence in this system nin* planes of symmetry. II. TETRAGON AL S YSTEM. In the TETRAGONAL SYSTEM, there are three rectangular axes ; but while the two lateral axes are equal, the remaining vertical axis is either longer or shorter than they are ; there are consequently to be considered the lateral axes (a) and the vertical axis (o). The general geometrical expression for the planes of crystals becomes for this system mo : na : a, and, if this be developed in the same way as the cor- responding expression in the Isometric system, all the forms* geometrically possible are derived. 1. me : na : a \in-ri\ when m >1, n >1. o j G : a : a [1] when wt=l ' \ mo : a : a 3 \ \ mo : oo a : a [tn-i] when m^l, n= [m] when [i- G : oo a : a [!-*] when m=l, n= oo . 4. oo c : na : a \i-n\ when m= , n >1. 5. QO o : a i a [/] when w&=oo, %=1. 6. oc i-i ; ooP=/; oo Pn-i-n ; mP^m-i\ mP=m ; P-l; and iP/i=m-/i. A. Holohedral Forms. Basal plane. There are two similar planes corresponding to the sym- bol G : QO a : oo a (or Oc : a : a), parallel to both the lateral axes ; each is called the basal plane. They do not inclose a space, and consequently they can occur onlv in combination with other planes. Prisms. The planes having the symbol oo o : oo a : a are parallel to the vertical and one of the lateral axes. There are four such planes, one at each extremity of the two lateral axes, and, in combination with the plane O, they form the square prism, which has been called the diametral prism, seen in f. 106. For the symbol oo G : a : a, the planes are parallel to the vertical axis, * The word form has been freely used in the preceding pages ; from this point on. how- ever, it needs to be more exactly denned. In a crystallographic sense it includes all th planes geometrically possible, nerer less than two, which have the same general symbol. 26 CRYSTALLOGRAPHY. and meet the others at equal distances. There are. as in the t case, four such planes. They form, in combination with the plane 6>, that square prism which is seen in f. 107, and may be called the unit prism. Both the prisms i-i and / are alike in their degree of symmetry. Each has four similar vertical edges, and eight similar basal edges unlike the vertical. There are also in each case eight similar solid angles. 108 109 i-2 -^ -* \i l i . \ 12 ^ --J 110 '212 The form i-n (oo c : na : a) is another prism, but in this each plane meets one of the lateral axes at the unit distance, and the other at some multiple of its unit distance. As is evident in the accompanying horizontal section (f. 113), this general symbol requires eight similar planes, two in each quadrant, and the complete form is shown in f. 109. The sixteen basal edges are all similar; the vertical edges are of two kinds, four axial X, and four diagonal T (f. 109). The regular octagonal prism with eight similar vertical edges, each angle being 135, is crystallographically impossible. Ill 112 \\ i /i I i :-J< The planes / truncate the edges of the diametral prism i-i, as in f. 108. Similarly the planes i-i truncate the vertical edges of /. The prism i-n be- vels the edges of i-i, as in f. 110, where i-n=i-%. The relation of the two square prisms, i-i and /, may be further illus- trated by the figs. Ill and 112. In f. 112 the sections of the two prisms are shown with the dotted lines for the axes, and in f. Ill there are the two forms complete, the one (/) within the other (i-i). The unit prism /is sometimes called the prism of the first series, and the prism i-i that of the second series. Octahedrons or Pyramids. The forms m-i and m both give rise to square octahedrons, corresponding to the two kinds of square prisms. In m-i the planes are parallel to one lateral axis and meet the vertical axie at variable distances, multiples (denoted by m) of the unit length. The total number of such planes, for a given value of m, is obviously eight, and TETRAGONAL SYSTEM. the form is shown in f. 114 and 115. These planes replace the basal edges of the form shown in f. 106, and m varies in value from to oo. When m=0 the four planes above and below coincide with the two basal 114 116 planes; as m increases, there arises a series, or zone, of planes, with mu- tually parallel intersections (f. 116) ; and when m=ao , the octahedral planes m-i coincide with the planes i-i. The value of m in a particular species depends upon the unit value assumed for the vertical axis c. The same form replaces the vertical angles of the prism 7, as in f. 117. The octahedrons of the m series meet both of the lateral axes at equal distances and the vertical axis at variable distances. It is clear that the whole number of planes for this form, when the value of mis given, is also eight, one in each octant. When m=l the solid in f. HS^is obtained, which is sometimes called the unit octahedron. As m decreases, the octahe- drons become more and more obtuse, till m 0, when the eight planes coin- cide with the two basal planes. As m increases from unity, on the other hand, the octahedrons or pyramids become more and more acute, and when #2,= oo they coincide with the prism I\ this series forms another zone of planes. These octahedrons replace the basal edges in the form f. 107, as seen in f. 119, and as the octahedron is more and more developed it passes to f . 120, and finally to f . 118. 124 The same form replaces the solid angles of the form f. 106. as seen in f, 121, and this too gradually passes into f. 122 and f. 114. 28 CRYSTALLOGRAPHY. The relation of the octahedrons 1 and I-i (m andm-i) is the same as that of the prisms /and i-i (compare f. 112). Similarly, too, they are often called octahedrons (or pyramids) of the first (m) and second (m-i) series. As will be seen in f. 123, ~L-i truncates the pyramidal edges' of the octahe- dron 1, and, conversely, the edges of the octahedron 2-i are truncated by the octahedron 1 (f. 124). Octagonal pyramids. The form m-n (me : na : a) in this system has, as in the preceding sys- tem, the highest number of similar planes which are geometrically possible ; in this case the num- ber is obviously sixteen, two in each of the eight sectants, as in f. 125, where ra=l, ra=2. These sixteen similar planes together form the octagonal pyramid (strictly double pyramid) or zirconoid, f. 126. It has tw r o kinds of terminal edges, the axial X and the diagonal Y ; the basal edges are all similar. It is seen (}n-n=~L- < 2) in f. 127 in combination with the diametral prism, and in f. 128 with 1, where it bevel* the vertical edges. 126 Other tetragonal forms are illustrated in figures 2 to 8, of zircon crystals, on p. 2 ; f. 8 is the most complex, and besides 3-3 shows also the related zirconoids 4-4 and 5-5. Several series of forms occur in f . 129, of vesuvianite. In the unit series of planes there are the octahedrons (or pyramids) 1, 2, 3, and the prism /; in the diametral series 1-*, i-i ; of octagonal prisms, 2-2, i-3 ; of zir- conoids 2-2, 3-3, 5-5, 4-2, f -3, the whole num- ber of planes being 154. B. Ilemihedral Forms. Among hemihedral forms there are two divisions, as in the isometric system : 1. Hemiholohedral, having the full number of planes in half the sectants (a) Vertically-alternate, or sphenoidal forms. The planes occur in two sectants situated in a diagonal line at one extremity, and two in the trans- verse diagonal at the other. TETRAGONAL SYSTEM. 29 With octahedral planes \(mc : a : a) the solid is a tetrahedron (f. 130, 131) called a sphenoid, having the same relation to the square prism of 130 132 f. 106 that the regular tetrahedron has to the cube. Fig. 130 is the positive sphenoid or +1, and 131 the negative, or 1. The form \(mc : oo a : a) is similar. Fig. 132 represents the sphenoid in combination with the prism If the planes of each sectant are the two of the octagonal pyramid \(mc : na : a) (f. 126), the form is a dipioid (f. 133). It is in combination with the octahedron 1-i in f . 134. (b) Vertically -direct, or the planes occuring in two opposite sectanta above, and in two on the same diagonal below. The result is a horizontal prism, or forms resembling those of the orthorhombic system. Character- izes crystals of edingtonite. (c) Vertically-oblique. Planes occurring in two adjacent octants above, and in two diagonally opposite below, producing monoclinic forms, as in a hydrous ammonium sulphate. 2. Holohemihedral, all the sectants having half the full number of planes. As the largest number of planes of a kind is two, half the full number is in all cases one. Hemihedrism may occur in the forms m-n (f. 126, 127), or zirconoids, and in the forms i-n (f. 109), or the octagonal prism. The following are the kinds : (a) Vertically-direct. The occurring plane of the sectants, the right one in the upper series, and that in the same vertical zone below, as indi- cated by the shading in f. 135 ; or else the left one above, and that in the same vertical zone below, f. 136. 135 () Vertically-alternate. The occurring plane the right above, and that in the alternate zone below, as indicated in f. 137 ; or else the l?ft above, and that in the alternate zone below, f. 138. As the right of the two planes above is in the same vertical zone with the left of the two below (supposing the lower end made the upper), the two kinds of the first division will be the rl m-n ; and the Ir m-n (in f. 136 on the angles of the prism i-i) ; and the two of the second division the rr and the U m-n (in f . 138, on the angles of the prism i-i). CRYSTALLOGRAPHY. 140 Wernerite. Wulfenite. The completed form for the first methods has parallel faces, and is like' the ordinary square octahedron in shape, because the upper and lower planes belong to the same vertical zone. But in the second it is gyroidal ; the upper pyramid has its faces in the same vertical line with an edge of the lower, as represented in f. 139, the form II m-n. The first of these methods occurs in octagonal prisms, producing a square prism, either r i-n, or I i-n. Fig. 140 represents a com- bination of the octahedron 1-?* with the unit-octahedron 1, and two hemihedral forms, one of them Ir 1-2, the other rl 3-3. The plane 1 shows the posi- tion of the octant ; 3-3 is to the right of 1, and 1-2 to the left. In f. 141, which is a top view of a crystal of wernerite, there occurs I 3-3 large, along with r 3-3 small, indicating hemihedrism, and, judging from that of the allied species sarcolite, it is of the square oc- Scheelite. tahedral kind, rl 33 and Ir 3-3. Fig. 142 contains the hemihedral prism I i-^ , com- bined with the unit-octahedron 1, and the basal plane O. Variable elements in this system. In the tetragonal system two ele- ments are variable, and in any given case must be decided before the rela- tions of the forms can be definitely expressed. (a) The position of the lateral axes. These axes are equal, but there are two possible positions for them, for in a given square octahedron they may be either diagonal or diametral; in other words, given an octahedron, as in f. 115, 116, the prismatic planes may be made diametral (i-i), and the octahe- dron so belong to the m-i series, or the prismatic planes may be made diag- onal, that is / (QO c : a : a\ when the corresponding octahedrons belong to the_m series. The ratio of the lateral axes for the two cases is obviously 1:1/2, or 1:1.4142 + . (1) The length of the vertical axis. Among the several occurring octa- hedrons, one must be assumed as the unit, and the others referred to it. In f. 143, of zircon, the octahedron 1 is made the unit, and by measur- ing the basal angle it is found mathematically, as explained later, that the length of the vertical axis is 0.85 times that of the lateral axes. The octahedron 3 has then the symbol 3c : a : a as referred to this unit. If the latter octahedron had been taken as the fun- damental form, the length of the vertical axis would have been 3 x 0.85 times that of the lateral axes, and the symbol of the first plane would have been \c : a : a. Which form is to be taken as the unit or fundamental, that is, what length of the vertical axis c is to be adopted, depends upon various considerations. in general that form is HEXAGONAL SYSTEM. 31 assumed as fundamental which is of most common occurrence or to whieb the cleavage is parallel ; or which best shows the morphological relations of the given species to others related to it in chemical composition, or which gives the simplest symbols for the occurring forms of a species. Prominent characteristics of ordinary tetragonal forms. The promi- nent distinguishing characteristics of tetragonal forms are : (1) A symme- trical arrangement of the planes in fours or eights. (2) The frequent oc- currence of a square prism diagonal to a square prism, the one making with the other an angle of 135. (3) The occurrence of bevelling planes on the lateral edges of the square prism. (4) A resemblance of the octahedrons to the regular octahedron, in having a square base, but a dissimilarity in that the angles over the basal edges do not equal those over the terminal. (5) Cleavage may be either basal, square-prismatic, or octahedral; prismatic cleavage, when existing, is alike in two directions, parallel to the lateral faces of one of the square prisms, and is always dissimilar to the basal cleav- age; the basal, or the lateral, is sometimes indistinct or wanting: the pris- matic may occur parallel to the lateral planes of both square prisms, but when so, that of one will be always unlike in facility that of the other. Planes of symmetry. There are five planes of symmetry in the tetra- gonal system : one principal plane of symmetry normal to the vertical axis, and four others, intersecting in this axis ; these four are in two pairs, the planes of each pair normal (90) to each other, and diagonal (45) to those of the other. III. HEXAGONAL SYSTEM. The HEXAGONAL SYSTEM includes two grand divisions : 1. The HEXA- GONAL proper, in which (1) symmetry is by sixes, and multiples of six ; (2) hemihedral forms are of the kind called vertically-direct ; and (3) cleavage and all physical characters have direct relations to the holohedral hexagonal form. 2. The RHOMBOHEDRAL, in which (1) symmetry is by threes and multi- ples of three, rhombohedral forms being hemihedral in mathematical rela- tion to the hexagonal system, and of the kind called vertically-alternate ; (2) cleavage, and many other physical characters, usually partake of the hemihedrism. While the rhombohedron is mathematically a hemihedral form under the hexagonal system, and is properly so treated in a system of mathema- tical crystallography, it is not so genetically, or in its fundamental relations. Moreover, it has its own hemihedral forms, which, under the broad hexago- nal system, are tetartohedral. The holohedral forms, all of which belong to the Hexagonal division, are here first described ; and then the hemihedral forms, which include, be- sides a few under the hexagonal division, the whole of the Rliombohedral division. A. Holohedral Forms : HEXAGONAL DIVISION. The general expression for planes of this system is me : na : a : pa, where there are to be considered the vertical axis, c, and three equal lateral axes, a. 32 CRYSTALLOGKAPHY. It is evident, however, that the position of any plane is determined by its intersections with two of the lateral axes, as its direction with the third follows directly from them. (Compare f. 146.) Consequently, in writn.g the symbol of any plane it is necessary to take into consideration only the vertical axis, and two of the lateral axes adjacent to each other. The various holohedral forms possible in this system are derived after the analogy of those of the tetragonal system. The parameters for all the lateral axes are given below for sake of comparison. It is to be noted here that m may be either < 1, or > 1 ; n is always > 1 and < 2, while p > 2 and< oo ; further than this it is always true that $=-;' me \na\a\ (pa) \m-n\ when m ^ 1, n > 1 and < 2. me: a: a: (oo 0) e : : : (oo 0) oo c: na : a: (pa) ooc:20:0: (20) oo c : a : a : (oo 0) 00 : : : (0) The abridged symbols need no explanation beyond that which has been given on p. 25 ; mPnm-n ; &Pn=i-n, etc. Basal planes. The form 0=0c : a : a includes the two basal planes bove and below, parallel to the plane of the lateral axes. [m-ri] M [1J [**] [t-2] ta when when when when when when when when m in 'HI tu- rn m m m >. 1, 1, 1, 1, GO, 00, > o, n> n = n = n> n = n = n = 1 2. 1. 1. 1 2. 1. 1. and and < 2. 144 147 Prisms. ^The form jT=oo G : a : a comprises the six planes parallel to the vertical axis, and meeting the two adjoining lateral axes at equal dis- tances. These six planes with the basal plane form the hexagonal unit prism, f. 144. The form t'-2=oo0 : 20 : a includes the six planes which are parallel to the vertical axis but meet one of the lateral axes at the unit distance, and the other two at double that distance. These plai.os with the basal plane form the diametral prism, f. 145. The relations ol the two prisms / and i-2 are shown in f. 146. In f. 14T, it will be seen that the one prism truncates the vertical edges of the other. The faces of the ^-2 inake an angle of 150 with the faces of /. These two prisms have an inti- mate connection with each other, and together form a regular twelve-sided prism, a prism which is crystallographically impossible except as the result of the combination of these two different forms. HEXAGONAL SYSTEM. 33 The form i-2 is a special case of the general form i-n or oo c : na : a. When n is some number less than 2, and greater than 1, there must be tw etc. Hexagonal pyramids, or Qaartzoids. The symbol l=c : a : a belongs to the twelve planes of the unit pyramid, f. 148, while the general form m mc : a : a includes all the pyramids in this series where the length of the vertical axis is some multiple of the assumed unit length. As in the tetragonal system, when m diminishes, the pyramids become more and more obtuse, and the form passes into the basal plane when m is zero; while as m increases, the pyramids become more and more acute, and finally coincide with the prism /. These pyramids consequently replace the basal edges between O and 7, f. 149, and with them form a vertical zone of planes. The pyramids of the m-2 series have the same relation to those of them series, just described, that the prism ?'-2 has to the prism /. They replace the basal edges between i-"2 and O (f. 145), and as the value of m varies, give rise to a series or zone of planes between these limits. The pyramids of both the first (m) and the second (m-2) series are well shown in f. 150, of apatite. In the first series there are the pyramids ^, 1, and 2 ; and in the second series the pyramids 1-2, 2-2, and 4-2. The cor 149 responding prisms /and -2 are also shown, and the zones between each of them and the basal plane O are to be noticed. Attention may also be called to the fact, exemplified here, that the pyramid 2-2 truncates the ver- tical edges of the pyramid 2 ; also 1-2 truncates the vertical edges of 1 ; while the latter form (1) also truncates the vertical edges of f-2, as is seen in f. 147. Di hexagonal pyramids, or BeryUoids. The general form mo : na : a gives the largest number of similar planes possible in this system, which ia here obviously twenty-four, that is, two in each of the twelve sextants. These pyramids correspond to the prisms of the i-n series, and form the dihexagonal pyramids, or beryl loids, as in f. 151. The berylloid has three kinds of edges : the axial edges X (L 151, 152), connecting' the apex with the extremity of one of the axes ; the diagonal edges Y, and the basal edges Z 3 34 CRYSTALLOGRAPHY. in the upper pyramid, one of these two planes for each sectant may be distinguished as the right, and the other the left, as lettered in f. 152 ; ^and the sa7ne, after inverting the crystal, for those of the other pyramid. It is to be observed that in a given position of the form, as that of f. 151, the right 153 154 of the upper pyramid will be over the left of the lower pyramid, and the reverse. Fig. 153 represents the planes of such a form m-n combined with the unit prism 7, and the planes are lettered , r, in accordance with the above. In f. 154, of a crystal of beryl, the prism I is combined with tho pyramids 1, 2, 2-2, and the berylloid 3-f . B. Ilemihedral Forms. I. VERTICALLY DIRECT. The planes of the upper range of sectants being in the same vertical zone severally with those below. (A). Ilemiholohedral. Ilalf the sectants having the full number of planes : 1. Trigonal pyramids. The diametral pyramid ra-2 is some- 155 times thus hemihedral, as in the annexed figure (f. 155) of a crys- tal of quartz, in which there are only three planes, 2-2 7 at each o.xtremity, and each of those above is in the same zone with one below. The completed form would be an equilateral and symme- trical double three-sided pyramid. 2. Trigonal prisms. The occurrence of three out of the six planes of the prism /, or fc-2, produces a three-sided prism. The is thus hemihedral in tourmaline (f. 156, a top view of a crystal), and the prism -2 in quartz. Both these forms properly belong to the Rhombo- hedral division. 3. Ditrigonal prisms. An hexagonal prism hemihedral to the dihexago- nal prism occurs in quartz and tourmaline, the hexagonal prism sometimes having only the alternate vertical edges bevelled, as in f. 185, and f. 186, p. 40. (B\ Ilolohemihedral. All the sectants having half the full number of planes : 1. Uemi-dihexagonal pyramids. Each sectant has one out of the twi planes of the dihexagonal pyramid (f. 151, 153) ; this is indicated by prism HEXAGONAL SYSTEM. 35 the shading in f. 157. The occurring plane may be the right above and left below, or left above and right below, and the form accordingly 156 157 158 Tourmaline. Apatite. either rl m-n, or IT m-n. Examples of the first of these occur in f. 158, representing a crystal of apatite, the planes 0(3-f), and o'(k-Q being of this kind. This method of hemihedrism occurs only in forms that are true hexagonal ; it is often called pyramidal hemihedrism, II. VERTICALLY ALTERNATE, the planes of the upper range of sectants being in zones alternate with those below. (A) Ilemiholohedral forms, or those in which half the sectants have the full number of planes as in the RHOMBOHEDRAL DIVISION. 1. Rhombohedro'ns,and their relation to Hexagonal forms. The rhom- bohedron is derivable from the hexagonal p} r ramid by a suppression of the alternate planes and the extension of the others. In f. 159, if the shaded planes in front and the opposite ones behind are suppressed, while the others are extended, a rhombohedron will be derived. This is further shown in f. 160, where the hexagonal pyramid is represented within the rhom- bohedron. Another similar rhombohedron, complementary to this, would result from the suppression of the other alternate half of the planes. One of these rhombohedrons is called minus, and the other plus (f. 161, 162). The form in f. 148 is made up, under the rhombohedral system, of +R and R (or +1 and 1) combined, as in the annexed figure (f. 163), of a crystal of quartz. 159 160 Fig. 164 shows the combination of the rhombohedron with the prism /; in f. 165 the former is more developed, and it finally passes into the com 36 CKYSTALLOG RAPHY. plete rhombohedron, f. 161. In f. 166 the rhombohedral planes occur on the alternate angles of the diagonal prism i-2. The symbol of the unit rhombohedron as referred to the hexagonal sys- tem is (0 : a : a), a second rhombohedron may be |(20 : a : a) and so on ; it is, however, more simple to write only +7? or 7?, and +27? or 27-?, and so on ; or, where there is no confusion with the symbols of hexagonal forms, as -f 1. 1, and +m, m. 163 164 Quartz. 166 This hemihedrism resulting in the rhombohedron is analogous, in the alternate 'positions of the planes above and below, to that producing the tetrahedron in the isometric system. But owing to the fact that there are three lateral axes instead of two, the rhombohedron has its opposite faces parallel, nnlike the tetrahedron. In f. 167 the planes 7? belong to the rhombohedron -fl ; -f to the rhombohedron H-f , having the verti- tical axis ; O is the basal plane, or mathematically the rhombohe- dron 0, the vertical axis being 00. / is the hexagonal prism oo : 1 : 1, or more properly a rhom- bohedron with an infinite axis, 000. Cinnabar. ^ -I tne are rhombohedral, but belong to the minus series ; J has the vertical Calcite. axis|0; 4.40; 2, 20; f, |0, this last being complementary to +f, and the same identical form, except that all the parts are reversed. Fig. 168, A-E represent different rhombo- hedrons of the species calcite : A., the rhombohedron 1 ; 7?, 4; C, 2 ; 7?, f; E, 4 ; having respectively for the vertical axis, 10, -J^ 20, |0, 40, with 0=0.8543, the lat- eral axes being made equal to unity. In f. 169 the rhombohedron 2 (or 27?) is combined with 1 (or R\ the latter truncating the terminal edges of the former. In relation to the series of + and rhombohedrons it is important to note that, since the position of \lt is that of the vertical edge of -f 7?, in combination with it, it truncates these edges. Similarly +J7? truncates the same edges of %R, and so on. HEXAGONAL SYSTEM. 37 Also + R truncates the edges of -27?, and - R the edges of + 2R (f. 169) 2/ truncates the edges of +47?, and so on. 2. Scalenohedrons ; forms hemihedral to the dihexagonal pyramid. As the rhombohedron is a hemihedral hexagonal pyramid or -quartzoid, so a seal enohed ron is a hemihedral dihexagonal pyramid or berylloid. The method of hemihedrism is similar by tlie suppression of the planes of the alternate sectauts, as indicated by the shading in f . 170 (analogous to f. 159) and the extension of those of the other sectants. A scalenohedron is 173 174 represented in f. 171, a hexagonal double pyramid with a zig-zag basal out- line, and three kinds of edges ; the shorter terminal edge X, the longer terminal edge Y, and the basal edge Z; the lateral axes terminate in the middle of the edges Z. There are plus and minus scalenohedrons, as there are plus and minus rhombohedrons, and they bear the same rela- tion to each other. The relations of the form to replacements of the rhom- 175 bohedron are illustrated in the other figures. Fig. 172 repre- sents a rhombohedron (+1 or R) with its basal edges bevel- led ; and this bevelment, continued to the obliteration of the planes 7?, produces the scalenohedron shown by the dotted lines. The scalenohedron in f. 171, 172 has the vertical axis equal to 3c', or three times as long as that of 7?, the lateral axes of both being equal ; and hence it is that the planes are lettered I 3 , the 1 referring to the rhombohedron and the index 3 being the multiple that gives the value of the vertical axis of the scalenohedron, In f. 173 there are two scalenohedrons of the same series, viz., I 6 , I 8 , combined with the rhombohedrons R (or +1) and + 4. Fig. 174 shows the scalenohedron I 3 combined with the rhom bohedron 4 (or 47); and 175, the same with the rhombohe- dron 5 ( + 5R). Other scalenohedrons replace the basal angles of a rhombohedron by two similar planes (f. 176); or bevel the terminal edges; or replace the terminal solid angles by six planes, two to each terminal edge, or to each 38 CRYSTALLOGRAPHY. \hombohedral face ; a? id they will be relatively + or -, according to theii position in one or the other set of sectants, as has been explained. Fig. 177 represents the top view of a crystal of tourmaline. It contains the rhombo 176 Tourmaline. hedral planes, 72, f, ^, , , , 2, along with the scalenohedrons *, 3 5 i B ,l|, 1% and also two others bevelling the terminal edges of the rhombohedron R. The scalenohedrons i 2 , -J 3 , i 5 , bevel the basal edges of the rhombohedron -J; and consequently the lengths of the axes are respectively 2, 3, 5 times that of the rhombohedron , and hence, equal Ic, fc, 7*5. Every scalenohedron corresponds to a bevelment of the basal edges of some rhombohedron and that particular one whose lateral edges are parallel to those of the scalenohedron. The symbols for them accordingly are made up of the symbol of the rhombohedron and an index which expresses the relation of its vertical axis as to length to that of the rhombohedronj according to a method proposed by Naumann. (See p. 72.) Hexagonal pyramids of the m-2 or diagonal series occur in many rhombohedral species ; as f. 178 of corundum, which contains 4-2(^,4-2,^-2 (for 9-2 on the figure read f-2, Klein), along with the rhombohedron 1, and the basal plane ; also f. 167, in which is the pyramid 2-2. Ilemihedral forms of the same pyramids (of the kind described on p. 34) are met with in rhombohedral species, but only such as have also tetartohedral modifications. Ilemihedral forms of the hexagonal and dihex- Corundum. a g Ona ] p r i sms (p. 34.) are a l so characteristic of some rhombohedral species, and of those that have either tetartohedral or hemimorphic modifi- cations. Fig. 179 illustrates the relative positions of the zones of the + and rhombohedrons, and diagonal pyramids m-2 alternating with regions of -r- and scalenohedrons in the scheme of the rhombohedral system. The figure is supposed to be a top view. It is similar to f. 152, p. 34, and like that contains the upper planes of the dihexagonal pyramid ; but these are divided between a plus and a minus scalenohedron, those planes marked + being the former, and the others ( ) the latter. The three lateral axes are lettered each bb. The posi- tion of the + mR zone of planes (or plus rhombohedrons) relative to the scalenohedrons is shown by the lettering + It ; of tho mR zones (or minus rhombohedrons) by R. The position of the vertical zone of m-2, or diametral pyramidal planes, is indicated by the letter d. The order of succession, beginning with one of the plus interaxial sectants (the one in the medial line below) and numbering it I. is as follows : HEXAGONAL SYSTEM. !(1) Plus scalenohedrons, or planes of the general form +m n . (2) Zone of plus rhombohedrons, +mR. (3) Plus scalenohedrons, or planes of the general form +m n . (4) Zone of diagonal pyramids, m-2. 5(5) \Iinus scalenohedrons, or planes of the general form m n . (6) Zone of minus rhombohedrons, mil. (7). Minus scaleiiohedrons, m". (8) Zone of diagonal pyramids, m-2. 5(9) Plus scalenohedrons, +m n . (10) Zone of plus rhombohedrons, +mR. (11) Plus scalenohedrons, +m n . (12) Zone of diagonal pyramids. And so on around, as the figure illustrates. In the lower pyramid the order of succession If the same ; but the plm planes are directly below the minus of the above view of the uppet pyramid. The plw scalenohedrons have the pyramidal edge over the +mR section, the more obtuse of the two (or edge Y) ; and the minus scalenohedrons have that edge the less obtuse (or edge Jf), and that over the mR section the more obtuse (or edge Y). B. Holokemikedral forms, or those in which all the sectants have half the full number of planes (as shown by the shading in f. 180). Gyroidal, or trapezohedral forms. Of the planes, in f. 181 there would occur only those lettered r, r, above and below ; or those lettered I, I, and, unlike f. 157, the planes above and below are not in the same zone. The 180 181 form is consequently gyroidal, the planes being inclined around the prism, both above and below, and in the same direction at the two extremities. It is also called plagihedraL The symbol for the planes is rr m-n, or U m-n, according as the occurring planes of the two in the same sector are the right or the left. Fig. 182 is an example of U 6-f in the species quartz. C. Tetartohedral Forms. These forms are hemihedral to the Rhombohedron. (A) Holomorphic forms, like the preceding hemihedral, the planes occur- ring equally in the upper and lower range of sectants. 1. Rhombohedral tetartohedrism. Occurring planes the alternate of those mentioned on page 35, that is, the alternate planes r of one base, and I of the other. They are the r of three alternate sectants above, and 40 CRYSTALLOGRAPHY. the I of three sectants below alternate with these. A form of ^ this kina consists of six equal planes, equally spaced, and hence, equal in inclina- tions, and is therefore, in the completed state, a rhombohedron. It occurs in menaccanite or titanic iron, and in quartz (f. 183, planes 13 --if). 2. Gyroidal or tmpezohedral tetartohedrism. Occurring planes the alternate of those lettered r or I in f. 153, p. 34, that is, the alternate planes r, or alternate Z, of both bases. 183 184 185 Quartz. Quartz. In f. 185, the planes o\ o n , c : b : na \mc:b:a \_m] oo c : b : a [/] ( c : b : a [1] oo c : b : oo a [i-i] ( me : oo b : a [//v4] oo c : oo b : a [i-i] ( me : b : oo a [m>$] Qc : b : a [O] The abridged y mbols need very little explanation additional to that given on p. 25. As before, only the essential part of the symbol is given ; m is written first, and refers in a]l oases to the vertical axis (c), and n refers to one of the lateral axes, whether the longer (b) or the shorter (d) is indicated by the sign p'aced over it, as tl or n. When n~ oo, this is indicated by the hitherto used, and the sign is placed over it, I, or $, with the same signi- Tneso correspond to the symbols used by Naumann, as follows: 0=0 P', i-l= m-i mP=m m-tl=mP/l, etc. * For the relation of the axes thus lettered to those of Dana's System of Mineralogy and 1 , of other auth :>rs, seep. 53. CRYSTALLOGRAPHY. A. Holohedral forms. Pinacoids. The final case mentioned in the above enumeration em braces, as before, the two basal planes, or basal pinacoids ; the one pre- ceding it includes the two planes parallel to the vertical and macrodiagonal axes (<; and &), called the macropinacoids, and the next above includes the planes parallel to the vertical and brachydiagonal axes (c and cc), called the brachypiiiacoids. These three sets of planes together form the solid in f. 188, which is called the diametral prism. In consequence of the ine- quality of the different pairs of planes there are only four similar edges in any set; thus four similar vertical edges; four macrodiagonal basal edges, two above and two below, between and i-i ; and similarly four brachy- diagonal basal edges between and i-i / the eight solid angles are all similar. 187 188 Prisms. The form oo c : b : 0, or /, includes the four planes of the unit prism which, in combination with O, is seen in f. 187. In this case the eight basal edges are similar, being made in each case by a similar pair of planes O and /. Of the vertical edges there are two pairs, those at the_extremity of the axis #, which are obtuse, and those at the extremity of $, which are acute. Similarly, there are two sets of basal solid angles, four in each; for though each solid angle is formed by the meeting of the same three planes, the angles are different in the two cases. The form / replaces the four similar vertical edges of f. 188 ; the macro- pinacoids i-l truncate the obtuse vertical edges of the prism 7J and the brachypinacoids i-l truncate the acute vertical edges of /, as shown in f. 189. There are two other series of prisms with symbols oo c : nb : a and oo c : b : na. In the latter series the axis b is made the unit ; the reason for this will be obvious when the relations of the two forms are explained. The prism / meets both axes a and 190 191 at their unit lengths, as in f. 187. If, now, the prismatic planes meet the longer lateral axis (b) at a greater distance, a prism is formed such as that in f. 190, whose symbol is i5,or QO c : %b : a. This is a macrodiago- nal prism ; and others might have the symbols i-$ (oo c : 35 : a), i-4 ( for /; also, ra=l, m=$, ra=-J. m |, and finally m=Q, for the basal plane O. 204 206 207 The general form in this system, consisting of eight similar planes, may le written either me : nb : a (m-n) or mo :b:na (m-n). The relation be- tween the two is the same as that between the prisms i-i; and i-h. Thus, in f. 204, one plane of the octahedron 2c : 2b : a (2-2) is Driven, and also one plane of another octahedron or pyramid, whose symbol is 2c : b : a ('2). If n becomes less ^than unity, as -, the plane has the symbol 2c : %b : a (2-J). In order to avoid this use of fractions the symbols written ^4c : b : 2a, that is, 4-5. The plane is shown in f. 205, in its two positions correspond- ing to 20 \\l\a, and c : b : 2a, the two being crystallographically iden- ORTHORHOMBIC SYSTEM. Thus there are two series of pyramidal planes : a macrodiagonal (m-n\ where the shorter axis is taken as the unit, and a br achy diagonal (m-7i), where the unit is the longer lateral axis; and between the two lie the unit octahedron (1) and those of the m series, just as the prism / lies between the prisms i-n and i-n. The macrodiagonal planes 1-2 and 2-2 are shown in f. 206 and f. 2_07. It is also seen in f. 207 that the planes 2-2, 24, 2-2 all make parallel intersec- tions with each other and with i-t, being an example of a zone where the ratios of the ver- tical axes are the same. Further orthorhombic forms are displayed in f. 208, of sulphur, already referred to. The full symbol of the plane 1-5 is c : b : 3a. B. Hemihedral Forms. Sulphur. The hemihedral forms that have been ohserved are of two kinds : 1, The vertically -oblique (p. 14), producing monoolinic forms; and 2, the hemimorphic, in which the planes of the octahedrons or domes of one base have no corresponding planes at the opposite extremity. The former kind 211 Humite. Humite. Calaminc. is illustrated in f. 209, of the species chondrodite (var. hnmite, type 111). Fig. 210 represents the.holohedral form of the same; the planes f-i, 14, 24, are of macrodomes ; %-%, |--, f-, 4-, of brachy domes ; and the others of various octahedrons, mostly in two vertical zones, the unit zone (me : b : a\ and the 1 : 2 zone (ma : %b : a). In f. 209 the alternate of the macro- domes and of the octahedral planes of the 1 : 2 zone are absent in the upper half of the form, and are present without those with which they alternate in the lower half. The crystal consequently resembles one under the monoclinic system. Datolite was formerly cited as a hemihedral orthorhombic species, but it has been found to be really monoclinic. Furthermore, it has been recently shown by the author, by reference to the optical properties, that the ehon 46 CRYSTALLOGRAPHY. drodite of the second and third types (see p. 327) is not orthoihombic but monodinic, and this must be true also of humite.* Hernimorphic forms characterize the species topaz and ealamine. The latter (in f. 211) has only the planes of a hernioctahedron at one extremity, and planes of hemidomes at the other. For the pyro-electric properties of such forms, see p. 169. Variable elements. In the orthorhombic system the lengths of the three axes are variable, though their position is fixed, and after these are fixed the choice of one for the vertical axis must be arbitrarily made. In other words, given an orthorhombic crystal, the three rectangular directions are fixed, but two assumptions must be made which will mathematically deter- mine the length of two of the axes in terms of the third. For instance, in a crystal, if certain occurring domes are adopted as the unit planes \-l and l-, this will determine "the relative lengths of the three axes, for which two measurements will be necessary ; or, if an occurring octahe- dron is assumed as the unit octahedron (1,) this alone will obviously fix the axes ; but here, also, two independent measurements are necessary in order to enable us to calculate their length, as is explained later, p. 74. Hav- ing determined upon the relative lengths of the axes, one of these must be made the vertical axis (c\ and then, of the two remaining, the shorter will be the brachydiagonal (a), and the longer the macrodiagonal axis (). In deciding these arbitrary points, the following serve as guides : The habit of the crystals; the relations of the given species to those allied in composition; the cleavage, which is regarded as pointing to tluit form which is properly fundamental ; and other considerations. How arbitrary the choice generally is is well shown by the fact that, in a considerable number of species belonging to this system, different lengths of axes, as also cliff- -rent positions for them, have been adopted by different authors. "Where an optical examination can be made of an orthorhombic crystal, the results show what the true position of the axes is, in accordance with the principles proposed by Schrauf. This subject is alluded to again in its proper place (p. 151). The general characteristics of the crystals of this system, are not so marked as those of the preceding systems. The kind of symmetry should be well understood, though, as remarked on p. 50, crystals which are in appearance orthorhombic maybe really monoclinic; the true test of the system is to be found in the three rectangular axial directions. A pris- matic habit is very common, the prisms (except the diametral prism) not being square, also the prominence of some of the most commonly occur- ring macrodomes and brachy domes ; a prismatic cleavage is common, and often a cleavage exists parallel to one of the pinacoids (e.g., i-l) and not to the other, which could not be true in the tetragonal system ; similarly the planes i-l, i-l are sometimes physically different, e.g., in regard to lustre. As has already been remarked, forms apparently hexagonal are common among certain species belonging to this system ; this is true in those cases * Since the above paragraph was put into type, Des Cloizeaux has announced that an opti- cal investigation by him has proved that humite crystals, of types II. and III., are really monoclinic^ as suggested above. The figures are allowed to remain, however, since they illus- trate the form which this method of hemihediism would produce. MONOCLINIC SYSTEM. 47 where the prism has an angle approximating to 120. It is immediately evident, as is explained more thoroughly in the chapter on compound crystals, that if three individual crystals are united each by a prismatic face, when the prismatic angle is near 120, they will form together a six-sided prism, approximating more or less closely to a regular hexa gonal prism. Similarly, under the same circumstances, the correspond ing pyramids will thus together form a more or less symmetrical hexagonal pyramid. This is illustrated by the accompanying figures of witherite, where the prismatic angle is 118, 30'. It need hardly be added that this is true in general, not only of the vertical prism, but also of a macrodome or brachydome, having an angle near 120. The optical relations connected with this subject are alluded to elsewhere, p. 151. Planes of Symmetry. The three diametral planes are planes of symmetry in this system, and they are the only ones. X 212 V. MOKOCLINIC SYSTEM. In the MONOCLTNIC SYSTEM the three axes are un- equal in length, and while two of them have rectan- ' gular intersections, the third is oblique. The position usually adopted for these axes is as shown in f. 214, where the vertical axis, c, and lateral axis, J, make retangular intersections, The same is true of b and #, while c and d are oblique to one another. The following is an enumeration of the several distinct forms possible in this system, deduced, as be- fore, from the general expression : 214 m-n -\-m-n m-n -f m-n m,c : oo b : a + me : oo b : a j QO c : n b : a \ oo c : b : na x> c : b : a oo c I oo b i a oo c : b : QO a Oc :b : a [ m [ + 7H [i-n -*] i* ( me : nb : a \ +mc : nb : a j me : b : na ( +mc : b : na j mo : b : a ( c : b : a )+mc : b : a \_-\-in\ + c:b:a [+1] mo '. b '. oo a \m-i\ The abridged symbols correspond to those in the orthorhombic system, explained on p. 42. The only point to be noted is that where n or i relates to the clinodiagonal axis, d, this i3 indicated by an accent placed over it, as m-l, m-n ; but in m-i, and m-n, etc. , i and n refer to the orthodiagonal axis. Naumann wrote these mPcc , and mPri, or else with the accent across the initial letter P. The minus signs are used in the same way as by Naumann (see p. 76). Pinacoids. As in the orthorhombic system, there are three pairs of pinacoidal planes : the base O=Qc : b : a\ the ortbopinacoid, parallel to the CRYSTALLOGRAPHY. 216 / 1 / ii 1 1 / -, )- 7 217 ortho-axis (5) oo c : "b : a, or i-i ; and the clinopinacoid, parallel to the in olined axis (#), QO c : b : oo a, or i-l. In the solid (f. 216) or diametral prism formed of these three pairs of planeo, the four vertical edges are similar, and this is also true of the four edges between O and i-l. On the other hand, the four remaining edges are of two sets ; that is, the edge in front above is similar to the edge be- hind and below, for the angles are equal and inclosed by similar planes ; but these edges are not similar to the remaining two. since, though the planes are the same, the inclosed angles are unequal to the former. Further, there are two sets of solid angles, two in front and two dia- gonally opposite behind, being alike ob- tuse angles, and the other four alike and acute. Prisms. In consequence of the similarity of the vertical edges of the diametral prism, they must all be replaced if one is ; this is done by the unit prism /(oo c : b : a), in f. 215, 217. Of the other prisms, each obviously consist-- ing of four planes, there are two series, the orthodiagonal, i-n, and clinodiagonal, i-n, bearing the same relation to each other as the macro- and brachy-diagonal prisms in the orthorhombic system, in fact, tbe same explanation may be made use of here. Fig. 217, of a crystal of datolite from Toggiana. shows the pinacoid planes, as also the unit prism, /, and the clinodiagonal prism, i-b. Clinodomes. The form m-l (me : l> : GO a] includes the four planes parallel to the clino- diagonal axis, and meeting the others at variable distances. They are analo- gous to the brachydomes of the orthorhombic system. There are four of these planes, because the two axes, c and &, make rectangular intersections. This is also seen in f. 218, since, as has been remarked, the four clino- diagonal edges in f. 21g are similar, and hence are simultaneously replaced by these clinodomes. 220 7 Orthodomes. Of the general form, me : oo b : a, there are two sets oi planes, two in each (hemi-orthodo'mes), both of which are alike in that they are parallel to the orthodiagonal (b} axis (see f. 219). They are unlike, how- ever, in that two are opposite an obtuse angle, and two opposite the acute angle. Consequently these two pairs of planes are distinct, and must occur MONOCLINIC SYSTEM. ra 22o thepl r - tiated by f. 220, where, as has been remarked, the obtuse edges, above i S21 233 front, and below behind are similar, and are hence replaced by planes of ^"-)> io simi^an^ di8 ' inc tf of plus and minus belongs to }, f , and the signs are used in the same way. & For each form there are only four similar planes. The m series is that of the unit octahedrons,- properly hemi-octahe- kZ; in f e 99? Jra , ra Vo m > ai | d ' The f de ' P of +T and -1 Three pinatoS ' U * Sam6 plaileS "* in coinb lati with the 0n ?> +m ~ n > ~ m ~ n > and +m -> ~^-^ ^ ive each fo r simi- ft - V u ear 6Xact1 ^ the 8ame relation to ea h otli er as the m-n fhoinbic system, so that no additional explanation is needed here in regard to them. (f * ^i ? dat lite maj be referred to for illustrations of the 1 " ^ 11Ch > V ? been 1Jamed - Tllere are here tliree different omes f ., 2-^ and 4-^ each comprising four planes; a minus hemi- + 2i^ l t PP , Slte the btUSe ^4-Afid also a 'plus orthodomo, tese two planes are quite distinct, though numerically the symbols ;.re e sanie) ; moreover, of hemi-octahedrons of the unit series, there are -4 -4, +2, +t, + l, + f, +|; also of orthodiagonalpyramids, -4-2, 6-3, also +2-2, and of clinodiagonal planes, -8-S, and +12-| A 1 study of a few such figures, especially with the help of models, will give the student a clear idea of the symmetry of this system. It will be that all the planes above in front are repeated below behind, and e below in front appear again above behind. More important than tnis, it will be seen that the clinodiagonal diametral plane divides the crys- tal into two symmetrical halves, right and left; in other words, as remarked later, it is a plane of symmetry. Ilemihedral forms occur of a hemimorphic character, in which the planes the opposite extremities of the vertical axis are unlike ; thus, the * one or more hemi-pyrarnidsmay occur at one extremity, without 4iose corresponding at the other, as in tartaric acid, ammonium tartrate, etc. With many monocliriic crystals the obliquity is obvious at sight ; but with many others it is slight, and can be determined only by exact measurements 50 CRYSTALLOGRAPHY. In datolite it is only six minutes. The character of the symmetry exhibits f urthe the obliquity. But, as seen above, both + and - planes of he same value do occurtogether, and though they are real y distinct yet : they may give a monoclinic crystal the aspect of w orthorhomfoc crystal other hand, true orthorhombic crystals may be hemihedral, and thus may be monoclinic in the character of the symmetry (p. 45). Variable elements. In the monoclinic system, the only element which is fixed is the position of the orthodiagonal axis (b) at right angles to the plane in which the other axes must lie. The lengths of these axes must obviously be assumed in the same way as in the preceding system; but, further than this, their position in the given plane, and the angle they make with each other, are both arbitrary; in other words, any plane m the zone at righl ano-les to the clinopinacoid may be taken as the base (O) and any othei as "the orthopinacoid (i-i). The existence of a prismatic cleavage, or one parallel to a plane in the orthodiagonal zone often points to the^planes which are really to be considered fundamental. In many cases it is considered desirable to assume an angle near 90 as the angle of obliquity, so as to show the degree of divergence from the rectangular type. It need hardly be added that authorities differ widely both as to the position and lengths given to the axes of the same species. ' Plane of symmetry. Monoclinic crystals have but one plane o sym- metry the diametral plane in which the vertical and clinodiagonai axes lie, that is, the plane parallel to the clinopinacoids. The maximum num- ber of similar planes for any form is four, and it will be noticed that there is no single form which alone can enclose a space, or form a geo *,rical solid. YL TRICLINIC SYSTEM. In the TRICLINIC SYSTEM the three axes are unequal, and their intersections are mutually oblique. In consequence of this fact, there is no plane symmetry. " Only diagonally opposite octants are similar; there can conse- quently be onlv two planes of anyone kind. There are no truncations or bevelments, and no Intel-facial angles of 90, 135, or 120. The prisms are all hemiprisms, and the octahedrons tetarto-octakedrons. The lateral axes are called the macrodiagonal (b), and the Irachydiago- nal (a). In f . 225 the diametral prism (made up of three pairs of < 224 planes) is represented, and in f . 224 the unit pram. To the latter u added Fin f 226) one plane -1 on two diagonally oppose edges, which are two out of the eight of the unit octahedron (f. 227). Tins octahedron, as will MATHEMATICAL CKTSTALLOGKAPHY. 51 he seen, is made up of four sets of different planes. The different kinds of planes are distinguished by the long or short mark over the n (n or n} and also by giving those which occur in the right-hand octants, in front, an accent ; those above (in the obtuse octants) are minus, and the others plus. The form m-n consequently may be -m-n', or m-n, -{-m-n, 01 +m-n; and similarly with m-n. In f. 228 the unit prism is combined with a hernidorne and a vertical plane parallel to the brachydiagonal section. ^ The forms, although oblique in every direction, may still be closely similar to monoclinic forms of related species. Anorthite. Axinite. The annexed figures are of triclinic species. In f. 229, of anorthite, of the feldspar group, the form is very similar to those of the monoclinid feldspar, orthoclase ; in orthoclase, on the brachydiagonal (clinodiagonal) section is 90, whence it is monoclinic, while in anorthite this angle is 85 50', or 4 10' from 90, and this is the principal source of the diversity of angle and form. Fig. 230 represents one of the crystalline forms of axinite, nearly all of which fail of any special monoclinic habit. MATHEMATICAL CRYSTALLOGRAPHY. Introductory remarks on the proper symbol of each plane of a general crystalline form. Hitherto the symbol me : nb : a has been employed to express the general position of all the planes comprising any crystalline form, and it has been shown that there are in some cases forty-eight similar planes answering to the general symbol, and in other cases only two. In order, however, to express the exact position of each individual plane be- longing to such a form, it becomes necessary to resort to the methods of analytical geometry. As shown in f. 231, the portions of the axes, when the centre is the starting point, which lie above, to the right, and in front of the centre, are called plus (-H); the corresponding portions of the axes measured from the centre below, to the left, and behind, are called, for the 52 CRYSTALLOGRAPHY. sake of distinction, minus (-). The planes of the firs quadrant (see also f. 232) are all positive (+); the planes of the second positive (+) wi th reference to the axes o and a, but negative (-) with reference to b ; in the 231 232 third both lateral axes are negative (-) ; in the fourth quadrant the planes are positive in regard to c and ft, but negative w \ th respect to a. Ihe lower quadrants are respectively similar, except that the vertical axis is always q negative. The symbols for each plane of the orthorhombic octahedron (f. 231), taken in the same order, will be as follows . Above. +c: + & : Below, -c: + b: c : -I : * V * V * i , i A i A i / and for the several values of the coefficients This reduces the zone equation torn = r (after dividing by $ = oo 2 ), and to this all the planes of the zone conform. So also for the zone of 1-2, /, 3-}, 14,^etc., in f. 23i. The parameters of the plane / and 14 arranged as above give 1 i 1 1 and the values of Jf, ty R are ^ 2 , -a 2 and -H" 2 respectively. Hence the zone equation becomes 1 3 1 I . Q . m n r ' MATHEMATICAL CRYSTALLOGRAPHY. 55 797 and if r = 1, the general formula n = y is derived. Between i : 1 : 1 (/) and 1 : i : 1 (1-1} the values of n are positive, as with the series of planes i:l-i:l-; 6c:^:a; 5:*:l;4:f:l; 3:f:l; 2:2:1; f : 3 : 1, etc., 1:^:1. Between 1 : * : 1 234 and % the values of n are negative, that is, are measured on the back half of the axis b ; as, for example, |- : 4 : 1 ; J : 3:1; : 2:1; -|: 1:1. As the zone continues on from : 1:1 to 1 : - 1 : i (l-), and i : 1 : 1 (7), the unit axis is changed, making n = 1. The zone equa- tion then becomes r = r, the values of r being ?/2/"^~ -L positive between -| : 1 : 1 and 1 : 1 : i, and negative between 1 : 1: i and i : 1 : 1. The successive planes are f: 1:2; f- : 1:3; 4 | ) 1 4. 1 1 L. a 4 1 1 3 1 O. t). "I . Ockf . l.rr, -L. A it * j .^ -- "t j y J- . o , .j . . .4, 6t i. oth figures 233 and 234 are illustrations of this zone. If the student will select a variety of examples of zones from the figures in the descriptive part of this work, and will apply the zone equation as given above to them, paying special attention to the signs of the parameters of each plane, he will soon find that the apparent difficulties of the subject disappear. EXHIBITION OP THE ZONE-RELATIONS OP DIFFERENT PLANES BY MEANS OP METHODS OP PROJECTION. The relations of the different planes of a crystal are to some extent exhi- bited graphically in such figures as have been already given. Other meth- ods, however, are used which have special advantages. The two most important are briefly mentioned here. 1. Queiistedtfs method of projection. In this method the planes of a crystal are projected upon a horizontal plane, usually that of the base (O). Every plane is regarded as pass- ing through the unit-length of the axis which is taken as the vertical ; these planes consequently appear as straight lines intersecting each other on the plane of projection. The following are examples. In f. 235, of galenite, there are present the planes of the cube, octahedron, dodecahedron, and tetragonal trisoctahedron |-|. In the projection (f. 236) the plane of the paper is taken as that of the cubic plane, the two equal lateral axes (a) are shown in the dotted lines, and the vertical axis is perpendicular to the plane of the paper at their point of intersection. Any arbitrary length of the lateral axes, as ca, is taken as the unit. One of the cubic planes coin- cides with the plane of the paper, and the others, since they are supposed to pass through the unit point of the vertical axis, coincide with the projec- tions of the lateral axes, and are marked Zf, //. The octahedral planes (1) appear as lines connecting the unit lengths of the equal lateral axes ; of the dodecahedral planes, four pass each through 56 CRTS TALLOGEAPH Y. the extremity of one lateral axis, and parallel to the other, and four others are diagonal lines passing through the centre ; they are marked * in the figure. The other planes, f-f, when passing through the unit point of the vertical axis, are represented by the symbols 1 : f : 1, and 1 : 1 : f, and 1 : f : }, in the first quadrant, and similarly in the other three. The projection of the first of these planes is the line joining the points x (ex = f of ca j )and a? : that of the second plane is the line joining the points a 1 and y (cy = f of # : ); that of the third plane is the line joining the points s 1 and 2* (c2 l = cz f of ca). The same method is followed in the other quadrants, the twelve lines, lightly drawn, in the figure are the projections of the twelve corresponding planes of the form f-J. Fig. 237. 238, give another example (topaz) from the orthorhombic system. The dotted lines, as before (f. 238), show the lateral axes on which the relative unit lengths of b and a belonging to this species have been marked off (b = 1.892, a = 1). The four lines passing through these unit points, a and Z>, are the pro- jections of the unit octahedron 1. The unit prism, /, is projected in lines parallel to these, and passing through the centre. The prism i-% also passes through the centre, but the direction is that of a line joining the unit length of the axis b with two times that of d. The symbol of the octahedron *( = %c : b : a), becomes, on supposing the plane to pass through the unit point of the vertical axis c : f b : \a* and it is consequently projected in the lines MATHEMATICAL CRYSTALLOGRAPHY. 57 joining the points t(ct = l of cb\ and s (cs = | of ca). The symbol of the plane f 2 (= f c : b : 2#) becomes, on the same condition, c : \b : f 0, and ita projection lines consequently connect the points t (ct = | of <#) and u (cu f of ca). The same method is followed in the other systems ; in the hexagonal there are on the plane of projection three equal lateral axes cutting each other at angles of 60. it will be seen from these examples that planes in a zone all pass through the same point of intersection; as in f. 234, O, f-f, 1, *(*), and, f. 237, /, a-2, i-i (c) ; this is also true mathematically of the planes O, 1, f , /, whose projections are parallel. This principle, which follows immediately from the fact stated above that planes in a zone have a common ratio for two of the axes, is very important. If a given plane lie in two zones its projection must necessarily pass through the two points of intersections which belong to each of these respectively, and consequently its position is determined. The plane on f. 237 which has no written symbol for instance, lying in the zone with f and f , and the zone with 1 and f-2, must, when projected, pass through the intersection point (f. 238) s of the former zone, and also through v that of the second zone. The plane itself, then, is one which meets the vertical axis at its unit length, the axis b obviously at an infinite distance, and the axis a at a distance J of its unit length ; hence, the sym- bol is G : oo b : \a, or f c : oo b : a (f -?,) in the form it is usually written. In many cases the ratios of the lateral axes are obvious at sight, as here ; in every case, however, the position of the zonal point, and of the two points of intersection on the axes, admits of exact determination by a series of simple equations. These equations it is unnecessary to add here ; reference for them may be made to Quenstedi's Crystallography, or that of Klein, mentioned on p. 59. This method is of so general use and of so easy application that every student should be familiar with it. Its advantages are that it leads tu a clearer comprehension of the relations of the different forms, showing immediately all the zones in which they lie, and in many cases without the 58 CRYSTALLOGRAPHY. 72 use of equations suffices to determine the symbols of an unknown plane, and that more simply than by the use of the zonal equation. The general principles contained in the method have been made by its proposer (Quen- stedt) the basis of an ingenious and philosophical system of Crystallograpny (Grundriss der bestimmenden und reclmenden Krystallographie von Fr. Aug. Qnenstedt, Tubingen, 1873). 2. Spherical projection of Neumann ami Miller. In this subject, as viewed by Miller, a crystal is situated within a sphere so that the centres of the two coincide. If now perpendiculars, or normals, be drawn from this centre to each pb.ne, and be produced, they will meet the surface of the sphere, and these normal points will determine the position of each plane. If, then, this sphere is regarded as projected upon a horizontal plane it will appear as a circle, and the various normal points will occupy each its pro- per position on or within this circle. This will be made more clear by an example. If the crystal (f. 237) be supposed to occupy the centre of a sphere, and if the terminal plane coincide with the plane of the paper, a normal to the plane O will meet the sphere of projection at the central point (f. 239) ; the planes i-i at the points indicated, and so of the other planes 1, f, i-2, etc. Two principles here are of fundamental importance: 1st, all planes of a zone have their nor- mals in the same great circle, as i-i, f , f 4, etc. ; and 2d, the an- gles between these normal points are the supplements of the an- gles between the actual planes. These having been stated, it will be clear at once that the calcula- tion of the angles between dif- ferent planes, i.e., their normals, becomes merely a matter of solv- ing a series of spherical triangles in which some parts are given and others obtained by calcula- tion. Upon this basis a system of crystallography was construct- ed by Miller in 1839, which, as further developed by Grail ich, Schrauf, von Lang and Maskelyne, has every advantage over that of Nauinaun in the matter of facility of calculation as in some other even more import- ant respects. The method of construction of the circle of projection, for a given crystal, is in most cases very simple. The position of the crystal is commonly so taken that the prismatic zone is represented by the circumference of the circle, and the position of the normal-points of all prismatic planes lie upon it. The normal-points of the pinacoid planes are at 90 from one another (the macropinacoid is not present on the crystal, f 2:J7). The two corresponding diameters, at right angles to each other, which are properly the projections of two great cir- cles, intersect at the centre the normal-point of the basal plane, ; these diameters repre- sent respectively the macrodome (m-l) and brachydome (*$) zones of planes. The several positions of the normal-points of the prismatic planes are determined by laying off the sup- plement angles of each with a protractor ; that of 2 is 43 25', and of /, 62 8i', from the MATHEMATICAL CRYSTALLOGRAPHY. 5Jj normal-point of i-i. The lines drawn between 2, 0, and -2 (behind), and 7, <9, /(behind) represent the zones of the m-2 and m pyramids respectively. The position of the normal- points of a dome or pyramid upon its respective zonal line (great circle) is formed by laying off from the centre a distance equal to the tangent of half the supplement angle of the given plane on 0, taking the radius as unity. For example, A $-1 120 27', hence the position of the required normal-point will be about (.5040) of the radius measured from 0. It is in general necessary to determine in this way the normal-points of but very few of the planes, since those of the others are given by the zonal connection between the planes. Thus in this case, having determined in the way explained the positions of the points i-i, i-%, /, and f-i, no further calculation is needed; the point of intersection of the great circle joining i-i. 4, and i-l, and that joining/, 0, /, is the normal-point of $; also the point of intersection of the great circle -2, f-i, -2 with /, 0, /, is the normal-point of 1, and with -2, 0, *-2 that of f-1 The method explained is the same for all the orthometrio systems ; for the clinometric sys- tems the same principle is made use of, though the application is not quite so simple, since the basal plane does not fall at the centre of the circle. In the system of Miller the general form of the symbol is hkl, in which k, &, and I are always whole numbers, and, the reciprocals of Naumann's symbols. To translate the latter into the former it is only necessary to take the reciprocals and reduce the result to three whole numbers and write them in the proper order. In general, for m-n (me : nb : ), h : k : I = mn : m : n. the latter expression being written in its simplest form, and, if neces- sary,- fractional forms must be reduced to whole numbers by multiplication. Conversely, from hkl is obtained m = -, n = , and hence, = m-n. This applies to all the sys- L/C IK terns except the hexagonal, where a special process is required. See Appendix (p. 441). METHODS OF CALCULATION. In mathematical crystallography there are three problems requiring solution: 1st, The determination of the elements of the crystallization of a species, that is, the lengths and mutual inclination of the axes ; 2d, The determination of the mutual interfacial angles of like or unlike known planes ; and 3d, The determination of the symbols, that is, values of the parameters m and n for unknown planes. This whole subject has been exhaustively discussed by Naumann in his several works on crystallography. (For titles, see p. iv.) The long series of formulas deduced by him cover almost every case which can arise. In the present place the matter is treated briefly, since for all ordinary problems in crystallography the amount of mathematics required is very small. This is especially true in view of the fact that a large part of unknown planes can be determined by the zonal equation already given. When complicated problems do arise, the me hods of spherical trigonometry (based on the spherical projection of Miller) offer, in the opinion of most crystallographers. the simplest and shortest mode of solution. It is be- lieved that the student who has mastered the elements of the subject, after the method of Naumann here followed, will, if he desire t<> go further, find it to his advantage to turn to the system of Miller, referred to on p. 58 (See also Appendix. ) The formulas given under the different systems in the following pages are mostly those of Naumann, and it has been deemed desirable to explain at length, in most cases, the methods by which these formulas are deduced. If the student will follow these explanations through, he will find himself in a position to solve more difficult problems involving similar methods. Spherical triangles are employed in most cases, as early used by Hausmann (1813), by Naumann (1829), and others ; and carefully explained by Von Kobelf in 1867 (Zur Berechnung der Krystallformen). The same methods have been elaborated by Klein (Einleitung in die Krystallberechnung, Stuttgart, 1875). THE RATIO OP THE TANGENTS IN RECTANGULAR ZONES. Tangent principle. In any rectangular zone of planes, that is, a zone lying between two planes at right angles to each other, one of them being a diametral plane, the tangents of the supplement angles made with thk CRYSTALLOGRAPHY. 240 diametral plane are proportional to the lengths of the axis corresponding to it. Examples of rectangular zones are afforded by the zones between i-i and i-i, also 1 and O, f. 130, and / and O, in f. 208 ; still again between / and O, in f. 167; / and O, also i-2 and O, in f. 150. In f. 217, the zone be- tween i-i and i-i, and O and i-i, as also the zones between i-i and any one of the orthodomes, are rectangular zones, but not the zones between the basal and vertical planes (except i-i), nor those between i-i and a clinodome. The truth of the above law is evident from the accompanying figures. If the angles between the planes e l , #, / (f. 240) and the basal plane are given, their supplements are the angles with the basal diametral section a 1 , a 2 , a 3 , respec- tively (f. 241). The tangents of these angles are the respective lengths of the vertical axis, corresponding to each plane, as seen in the successive triangles. In each case we have b tan a = c, and hence, tan a 1 : tan a 2 : tan a 3 = c l : & : c 3 . By the law stated on p. 10, the ratio of the axes must have some simple numerical value. In other words, if c l be taken as the unit, (? and ; tan = m + 1. 4. Form m-n, hexoctahedron. The edges of the hexoctahedron are of three kinds, A, B, C (f. 247), and two measurements are, in general, needed in order to deduce the values of m and n. (a) Given A and B. In the oblique-angled spherical triangle I (f. 247), the three angles are \A, %B, and 45. In this triangle, the side opposite %A (= angle v) is calculated, and from it are obtained the values of m and n, as follows : cosi> = 4- cos IB sin tan sin v = m ; tan v n. (5) Given A and C. In the oblique-angled triangle II (f. 247), the three angles are equal respectively to %A, \C, and 60 The side oppDsite \A (= angle p) is calculated. But the angle between the diagonals, that is, the octahedral and dodecahedral axes, is 35 16', and the third angle of the triangle is f, the inclination of the edge C on the dodecahedral axis ; MATHEMATICAL CRYSTALLOGRAPHY. 65 hence, J = 144 44' p. Again, in the right-angled triangle III (f. 247), one angle %C\ and the adjacent side = , whence the other side, 8 (the in- clination of the edge B on the dodecahedral axis), is obtained ; v =135 S, and from this, as above, and from the angle /o, are deduced the values oi n and n. The formulas are : = 135 b ; tan v = n ; tan = m. (c ) Given B and C. K the right-angled triangle, III (f. 247), the two les are given, equal respectively to \B and %G. From the triangle is deduced the side opposite $C (= angle 8 denned before), and from it is obtained i/, and from v and \B, the values of m and n, as in the first case The formulas are : cos = - * ; v = 135 8 ; tan v=n\ tan J.Z? sin v = m. If, instead of m-n, the form is m 248 -p only one measurement is needed, and the process is simplified. When the angles of any plane m-n on two cubic planes are given, their supplements will be the angles of the plane upon the corresponding diametral sections, and from them the values of m-n may be readily calcu- lated. Thus (in f . 248), the angles of a given plane on a cubic plan at a 9 will be the supplement of its angle upon the section a 1 a*, that is, the angle B in the spherical triangle ; similarly, the angle of a cubic plane at a* will be the supplement of its angle on the section #V, the angle A in the spherical triangle. In this same triangle C = 90. Hence, the sides opposite A. and B^ that is, the inclinations of the two edges on the adjacent axis, may be calculated, and this axis being equal to unity, their tangents will give the corresponding lengths of the other axes. These lengths may not be the values of m and n in the form in which the symbol is generally written, where the unit axis is always the shortest, but the latter are immediately deducible. For ex- ample, if the angles here mentioned for the plane numbered 4 (in f. 247) had been measured, the values of the axes obtained by calculation, when the front axis is the unit, would be -J and -J respectively, and the symbol, hence, 1 : i : 1, which is equivalent to 1 : f : 3, or m-n = 3-J for the general form. Hem ihedral forms. For each hemihedral form the formulas are iden- tical with those already given for the corresponding holohedral, so far as the edges of the two are the same. For example, in comparing f. 69 and f. 87 it is seen that the edges A and C are the same in both, while B of the holohedral form differs from B' of the hemihedral. The formulas re* 66 CRYSTALLOGRAPHY. quired to cover these additional cases are given belotv, they are obtained in a manner similar to those in the preceding pages. Form J(m), f. 85. Given E'. cos e = 2 cos \B'\/\ ; f = 35 16'+ e ; tan Form J(m-m), f. 81. Given j'. tan i^V2 = m. Form J(m-n), f. 87. (a) Given J/ and B f . cos cos \A' = - - = cos a = - f-p- : cos p = -. =-=57 ; m = x ; n = - - sm %A ' sm -J^ ' cot a cotp cot a + cot ,^. (J) Given ^?' and C'. sn tan (8 + 45) = rc; - - tan f = m. Form iO'-n], f. 92. Given ^1". tan \A!' n. Form [m-n], f. 100. (a) Given ^!" and B" . cos -i^.'' n cos \A" = <*os v ; tan p = n ; - , p,, = m. sin j cos (1) Given ^1" and 67" i xr/* ^ zi COB (H <508 44'' 2 cos (7 v- = sm O cos#=: sin \A" v 2 tan (45 + 0) = m ; sin (45 + ^) tan 4"= () Given B" and 67". 1 /T//4/T fi 2 cos J67"V-J = sin 6^ ; cos S = sn tan (45 -f S) = n; sin (45 -f 5) tan \B' = m. The various combinations of holohedral and hemihedral forms which may occur are unlimited, and it would be unwise to attempt here to show C 8 - C S MATHEMATICAL CRYSTALLOGRAPHY. 67 the methods of working them out. It is only necessary to remark that the solution can generally be readily obtained by the use of one or two spheri- cal triangles in the way shown in the preceding cases. The calculation of the intcrfacial angles between two known forms can often be performed by the formulas already given, or by similar methods For the more general cases, reference must be made to the cosine formula, p. 62. Interfacial Angles. I. Holohedral Forms. The following are some of the angles among the more common of Isometric holohedral forms; adjacent planes are to be understood, unless it is stated otherwise. The angles A, B, C\ above, are those over the edges so lettered in the figures referred to (see pp. 15-19), or over the corresponding edges in related forms : fff\H= 90, f. 38 1 A 2-2 = 160 32', f. 58 e-| A *-|, 4 = 133 49' H A 1 = 125 16', f. 40, 41 1 A 3-3 = 150 30, f. 57 f A *-, 6 r ,= 157 23 H A = 135, f. 43, 45. 1 A \ = 169 49 2 A *-2, A,= 143 8, f. 65 #A *-f = 146 19 1 A 2 = 164 12. f. 53 -2 A i-2, G,= 143 8 H A i-2 = 153 26, f . 64 1 A 3 = 158 e-2 A fr#, ov. top, = 126 52 H A *-3 = 161 34 1 A 34 = 157 45 i-2 A -3 = 171 52 H A H = 133 19 1 A 4-2 = 151 52 i-2 A 2-2 = 155 54 H A 14 = 136 45 1 A 5- = 151 25 i-3 A *-3, A,= 154 9, f. 66 //A 2-2 = 144 44, f. 55 i A = 120 f. 45 3 A *-3, C,= 126 52 .# A 3-3 = 154 46 i A &', ov. top,= 90 2 A 2, -4,= 152 44, f. 51 H A f, ov. 1,= 115 14 * A *'-f = 167 42 2 A 2, .,= 141 3 ^ A 2, u = 109 28, f. 52 i A *-2 = 161 34, f . 68 3 A 3, 4,= 142 8 H A 3, " = 103 16 t A '-3 = 153 26 3 A 3, B,= 153 28 tf A 3-| = 143 18, f. 70 i A 2-2 = 150 8-f, 4,= 158 13, f, 69 # A 4-2 = 150 48 A 3-| = 160 54 3-2, #, = 149 ff A 5-| = 147 41 t A 3-3 = 148 31 3-$, 6 Y ,= 158 13 1 A 1 = 109 28, f. 42 A 4-i = 166 6 4-2, A,= 162 15 1 A 1. top,= 70 32 t A 5- = 162 58* 4-2, B,~ 154 47 1 A = I* 4 44, f 47 2-2 A 2-2, B,= 131 49, f. 54 4-2, tf,= 144 3 1 A H = 143 11 2-2 A 2-2, <7,= 146 27 5-|, .4,= 152 20 1 A i-2 = 140 16, f. 67 2-2 A 2-2, ov. top. =109 28 5-f,, #,= 160 32 1 A -3 = 136 54 3-3 A 3-3, B,= 144 54, f. 61 5-|, C,= 152 20 1 A H = 168 41 3-3 A 3-3, (7,= 129 31 II. Hemihedral Forms. The following are the angles for the corresponding hemihedral forms : 1 A 1 = 70 32', f. 76, 76A 3-3 A 3-3, C,= 134 2' t-3 A *-3, #,= 107 27f f A i^, -4,= 162 39i 3-1- A 3-^, A,- 158 13, f. 87 4-2 A 4-2, A,= 128 15 I A f #,= 82 10 3-| A 3-^ -B,= HO 55^ 4-2 A 4-2, #,= 154 47| 9 A 8. .4.= 152 44, f. 85 8- A 3-f, C',= 158 13 4-2 A 4-2, C,= 131 49 2 A2 'R = 9o 4-2 A 4-2, A, = 162 15 3-| A 3-;S ^1,= 115 23, f. IOC 3 A 3, A, = 142 8 4-2 A 4-2, B, = 124 51 3-f A 3-|, JB, = 149 3 A 3, 1?,= 99 5 4-2 A 4-2, (7,= 144 3 3-f A 8-f, O,= 141 47 H A H. X= 93 22 i'-$ A *-f, -4,= H2 37 5-f A -fr, -4,= 119 8* M A l-i' ^= 160 15 *-| A M, (7,= 117 29 5-f A 6-fr, -B,= 160 33 2-2 A 2-2, 4= 109 28, f. 81 *-2 A , 4,= 126 52, f. 92, 93 5-f A 5-^, 6',= 131 5 2-2 A 2-2, C,= 146 26* J-2 A -2, 6',= 113 35 8-8 A 3-3, #,= 124 7 *-3 A -3, -4,= 143 8 In the forms -}, 2 (f. 92), 3, 4, A is the angle at the longer edge, and C that at either of the others. 68 CRYSTALLOGRAPHY. II. TETRAGONAL SYSTEM. In the Tetragonal system, as has been fully explained (p. 30), the \cngfh of the vertical axis is variable, and must be determined for each species. If the length of c is known, then it may be required to determine the symbols of certain planes by means of measured angles. These two problems are in a measure complementary to each other, and the same methods will give a solution to either case. (For figures of the forms see pages ^7 and 28.) The calculation of the interfacial angles can be performed by similar methods or by the cosine formula. 1. Form m. The edges are of two kinds, pyramidal X, and basal Z. If either angle is known, the angle a, which is the inclination of the edge X on the lateral axis, may be calculated by the spherical triangle, as in f. 242, 243. (Compare the explanation of this case, p. 62.) Obviously in the plane right-angled triangle formed by the two axes and the edge X, tan a = me (since a = 1). If c is known, then m is determined ; and, con- versely, a value being assumed for m, in the special case, c is given by tho calculation. The general formulas are : cot |X= sin a, or tan \Z V~% = tan a ; then tan a = me. 2. Form m-i. (a) Given the angle Z, me is found immediately ; the solution is obvious, for in the section indicated by the dotted line (f. 249), \Z = a, and the tangent of this angle is equal to the vertical axis, (b) Given the angle Y. A spherical triangle placed as in f. 249, has one angle = | Y, a second = 45, and the third =90, whence the side opposite | Y is calculated, which is the complement of a. The general formulas, which may serve to de- duce the value of ra, when c is given, or the con- verse, are : cos J J*"Vlf = sin a, or tan \Z tan a, and tan a = mo. If a series of square octahedrons m, or m-i, occur in a vertical zone, their symbols may be calculated in both cases alike by the law of the tangents, the angles of the planes on O, or on /, or i-i, respectively, being given. (See p. 60.) 3. Form i-n.For the angle of the edge X(f. 109, p. 26), at the extrem- ity of a lateral axis, tan -J JT = n. From tlie angle of the other edge Y, we have X = 135- \Y; and hence, tan (135- Y) = n. 4. Form m-n. The edges are of three kinds, X, Y, Z(L 250), and two angles ^must be given in the general case to determine m and n. (a) Given Xand Z. A spherical triangle having its vertices on the edgea Xand Z, and the lateral axis, as 1, f. 250, will have two of its angles equal to |X, |Z, respectively, and the third equal to 90. The solution of this triangle gives the sides, viz., a and v, the inclinations of the edges X and MATHEMATICAL CRYSTALLOGRAPHY. f>9 Z, respectively, on the lateral axis. The tangents of these angles give the values of in and n. The formulas are as follows : cos sin = cos a, tan a = m and cot f V3 = me. ny 3 tanjZ n i found from tLl = ; further, sin \Z = cos i X n-l c' (c) Given l^and Z. 2ft sinjZ tan \Z cos P : -^/T' and cot If m, that is the inscribed rhombohedron, is known, one measnrome?it will give the value of n. Z' = basal edge of the inscribed rhombohedrou (care must be taken to note whether < is'obtuse or acute). (d) Given X sin = 2 cos iX cos \ tan (0-J2P) cot 4Z r = (*) Given JT. sin = 2 cos ^F cos (/) Given Z. tan JZ, cot JZ X = n. If 7i is known. From X, we have sin %Z = - - cos -JX ; then, as n-\- 1 under (a). From Y, sin Z = cos %Y, and then as above. From Z, Yl/ J. cos f ' is obtained as under (a), and then inc. IY. OKTHORHOMBIO SYSTEM. Of the three rectangular axes in the Orthorhombic system, one is always taken equal to unity, in this work the shortest (&). This leaves two inknovvn quantities to be determined for each species, namely, the lengths 74 CRYSTALLOGRAPHY. of the axes c and #, expressed in terras of the unit axis d, and for this end two independent measurements are required. The simpler cases are considered here. Calculation of the Lengths of the Axes. Let a = the inclination of the edge Z to the axis d (f. 253). B = the inclination of the edge X to the axis d. 7 = the inclination of the edge Y to the axis b. From the plane triangle formed by each edge and the axes adjacent (f 253, 254) the following relations are deduced, when d = 1 : tan = c and _tan a = b. tan a = b, and b tan 7 = 4 tan /3 = 4 ail d c cot 7 = b. (1) Given a and /3, (2) Given a and 7, (3) Given and 7, 255 The angles a, 0, 7 are often given direct by measurement; for, obviously (f. 254, 255), a = the semi -prismatic angle I A /(over *-t). # = the semi-basal angle of 14 A 14. 7 = the semi-basal angle of 1-2 A 1-L Also /A t = a + 90 ; 14 A ^4 = /3 + 90 ; It A <9 = 180-/3, etc. From the octahedron (f. 253), the angles a, & 7 are calculated immedi- ately by the following formulas, and from them the length of the axes aa above. (a) Given X and Z (spherical triangle I, f. 253), sin sin () Given JTaiid Z (spherical triangle II, f. 253), (c) Given Xand ^(spherical triangle 111, f. 253), sin ft = cos sin MATHEMATICAL CRYSTALLOGRAPHY. 75 If any one of the angles a, ft, or 7 is given, as from the measurement of aprism or dome, and also any one of the angles of the octahedral edges X, Y, or Z, a second of the former angles may be calculated, and from the two the axes are obtained as before. The formulas, derived from the same spherical triangles, are as follows : (1) Given Xand a, sin ft = cot Xtan a. X and ft, tan a = tan X sin ft. X and 7, cos ft = cot %X cot 7. (2) Given J^and a, sin 7 = cot ^l^cot a. Y and ft, cos 7 = cot -J Z cot . Y and 7, cot a = tan -J I 7 sin 7. (3)* Given Z and a, tan 7 = tan Z cos a. Z and ft, cos a = cot -J Z tan 7. Z and 7, sin a = cot Z tan /. Calculation of the values of m and ft. The above formulas cover all the ordinary cases, the only change that is required in them is to write for , i (basal) = Z+Z. An}'- three of these angles will serve to give for the unit form ( 1) the length and obliquity of the axes, or, when these are known, two of these angles are sufficient to deduce the values of ra and n for any unknown form. In the first case, as one of the three measured angles must be either Y+ Y' or Z + Z ', the formulas given above do not immediately apply. For example, if X, X.' and Y-+- Y' are given. Placing a spherical triangle, abc, in f. 256, with its vertices on the edges X, X r , and Y, in this the three angles will equal X, X and Y+ Y respectively ; here the side, ac, opposite the angle ( Y+ Y) is calculated, which gives the value of fjb + //, also the side, fo," opposite A' '; then, again, in the right-angled spherical triangle, where bo and X are known, /A is obtained, thus p' is known and also /#. The lengths of the axes follow from the formulas given above. The following are some of the cases which may occur: (a) Given O, and i4. O/\i-i (front)= 180- /9, behind = ft. (b) Given 0, - 1-t, and -I- l-i. O^- l-i = 180 v'; 0/\+ l-i = 180 - 2 sin v sin v , ^ OAf v. By the formula given above, tan p = ^ , _^ , , also, p 180 __ (/3 + z/). Thus ft, p, and j/ are known, and from them the relation of the axes d and c is deduced. (c) Given i-i, 1-* and + l-i. i-i A \4 = 180 /,*-* A + 1-* = 180 - /i. As before, tan ft = 2 f in ^ sin ^ and v = i 80 - (^ + /*). Bill (U- tt 78 CRYSTALLOGRAPHY. (d) Given the prism I and (f. 257). In the spherical triangle ABC : C= 90 (inclination of base on cli lodiagonal section), BOl\I, A = J(/A Z). Hence, the sides CA and CB are calculated ; CA = ft (or, as in this case, 180 fi) CB , Z on d -= - 1 sin A sin B also, sin a : sin ft : sin 7 = sin A : sin B : sin C. The relations between the angles a, ft, 7, and the angles /x, v, etc., are as follows : 2 sin p sin p 2 sin TT sin TT' tan a = . f- - = . T ^r-. sin (p p) sm (TT TT ) ~ 2 sin A sin a' 2 sin v sin i/ tan 8 = . sin (/A /A) sin (v z^) 2 sin T sin r r 2 sin a sin 0-' tan 7 = ; -. - 7 = . -, jr . sm (T T ) sm ( = /3 + /4 + z/ = 7-}- - * COS V = " COS = : - =i^ : - 7> - * : ^FF : - i sin X sin C sin JT sin A cos JT + cos l^cos C cos Z -f- cos I 7 ' cos ./? 7T = T * sin ;r sin c sin ;r sin B cos JT + cos Z cos ^4 cos !F 4- cos Z cos ./? COS sin v sin o- = d : b, sin TT = b : c, sin JJL = c : d. For any form ra-tt A ?;4 = 180 F; i-nAi- = J80 X; m- A O = 180 Z. For a vertical heraiprism, X+ Y+C= 180, d : b = sin Y . sin a : sin X : sin 0. For a macrodiagonal hemidorae, Y+ Z + B = 180, d : c ==. sin Y . sin a : sin Z . sin 7. For a brachydiagonal hemidome, X+Z +A = 180, 2 : c sin 2T sin : sin Z sin 7. By writing me for c y nb for 0, etc., these formulas will answer also for the determination of m and n. It is supposed in the above that the measured edge is parallel to the axis of the given hemiprism, etc. ; when this is not the case the relations are a little less simple. MATHEMATICAL CRYSTALLOGRAPHY. 83 MEASUREMENT OF THE ANGLES OF CRYSTALS.* The angles of crystals are measured by means of instruments which aie called goniometers. The simplest form of these instruments is the hand -goniometer, repre- sented in f. 260. It consists of an arc, graduated to half degrees, or finer, and two movable arms. In the instrument figured, one of the arms, ao, has the motion, forward and backward by means of slits gJt, ik; the other arm, cd, has also a similar slit, and in addition it turns around the centre of the arc as an axis. The planes whose inclination is to be measured are applied between the arms ao, co 9 and the latter adjusted so that they and the surfaces of the planes are in close contact. This adjustment must be made with care, and when the instrument is held up to the light none must pass through between the arm and the plane. The number of degrees read off on the arc between k and the left edge of d (this edge being in the line of the centre, o, of the arc) is the angle required. The motion to and fro by means of the slits is for the sake of convenience in measuring small or imbedded crystals. In a much better form of the instrument the arms are wholly separated from the arc ; and the arc is a delicately graduated circle to which the arms are adjusted after the measurement. The hand-goniometer is useful in the case of large crystals, and those whose faces are not well polished ; the measurements with it, however, are seldom within a quarter of a degree of accuracy. In the finest specimens of crystals, where the planes are smooth and lustrous, results far more accurate may be obtained by means of a different instrument, called the reflecting goniometer. Reflecting Goniometer. This instrument was devised by Wollaston, in 1809, but it has been much improved in its various parts since his time, especially by Mitscherlich. The principle on which it is constructed may be understood by reference to the following figure (f. 261), which repre gr.nts a crystal, whose angle, abe. is required. The eye at P, looking at the face of the crystal, $, serve to centre it. The method of procedure is briefly as follows : The crystal is attached by means of suitable wax at &, and adjusted so that the direction of the combination-edge of the two planes to be measured coincides with the axis of the instrument ; the wheel, n, is turned until an object (e.g., a window- bar) reflected in one plane is seen to coincide with another object not reflected (e.g.^ a chalk line on the floor), the position of the graduated circle is observed, and then both crystal and circle revolved together by means of the wheel, m, till the same reflected object now seen in the second plane again coincides with the fixed object (that is, the chalk line) ; the angle through which the circle has been moved, as read off by means of the vernier, is the supplement angle between the two planes. In order to secure accuracy, several conditions must be fulfilled, of which the following are the most important : 1. The position of the eye of the observer must remain perfectly stationary. 2. The object reflected and that with which it is brought in coincidence, should be at an equal distance from the instrument, and this distance should not be too small. 3. The crystal must be accurately adjusted j this is so when the line seen reflected in the case of each plane and that seen directly with which it is in coincidence are horizontal and parallel. It can be true only when the intersection edge of the two planes measured is exactly in the direction of the axis of the instrument, and perpendicular to the plane of the circle. 4. The crystal must be centered as nearly as possible, or, in other words, the same intersection -edge must coincide with a line drawn through the re- volving axis. This condition will be seen to be distinct from the preced- ing, which required only that the two directions should be the same. The error arising when this condition is not satisfied diminishes as the object reflected is removed farther from the instrument, and becomes zero if the object is at an infinite distance. The first and second conditions are both satisfactorily fulfilled by the use of a telescope, as , f. 262, with slight magnifying power. This is arranged for parallel light, and provided with spider lines in its focus. It admits also of some adjustments, as seen in the figure, but 86 CRYSTALLOGRAPHY. when used it must be directed exactly toward the axis of the goniometer. This telescope has also a little magnifying glass (g, f. 262) attached to it, which allows of the crystal itself being seen when mounted at k. This latter is used for the first adjustments of both planes, and then slipped aside, when some distant, object which has been selected must be seen in the field of the telescope as reflected, first by the one plane and then by the other as the wheel n is revolved. When the final adjustments have been made so that in each case the object coincides with the centre of the spider-cross of the telescope, and when further the edge to be measured has been centered, the crystal is ready for measurement. This telescope, obviously, can be used only when the plane is smooth and large enough to give distinct and brilliant reflections. In many cases sufficient accuracy is obtained without it by the use of a window-bar and a white chalk line on the floor below for the two objects ; the instrument in this case is placed at the opposite end of the room, with its axis parallel to the window ; the eye is brought very close to the crystal and held motionless during the measurement. The best instruments are provided with two telescopes. The second stands opposite the telescope, t (see figure), the centres of both telescopes being in the same plane perpendicular to the axis of the instrument. This second telescope has also a hair cross in the focus, and this, when illuminated by a brilliant gas burner (the rest of the instrument being protected from the light by a screen) will be reflected in the successive faces of the crystal. The reflected cross is brought in coincidence with the cross in the first telescope, first for one and then for the other plane. As the lines are delicate, and as exact coincidence can take place only after perfect adjustment, it is evident that a high degree of accuracy is possible. Still more than before, however, are well-polished crystals required, so that in the majority of cases the use of the ordinary double telescopes is impossible, very often, however, the second telescope may be advantage- ously replaced by another having an adjustable slit in its focus, as proposed by Websky, allowing of being made as narrow as is convenient ; or, as sug- gested by Schraufj^the spider-lines of the second telescope may be re- placed by a piece of tin-foil, in which two fine cross lines have been cut; these are illuminated by a gas-burner. By these methods the reflected object is a bright line or cross, instead of the dark spider-lines, and it is visible in the first telescope even when the planes are extremely minute, or, on the other hand, somewhat rough and uneven ; the image is naturally not perfectly distinct, but sufficiently so to admit of good measurements (0.<7., within two or three minutes). The third and fourth conditions are the most difficult to fulfil absolutely. In the cheaper instruments the contrivance to accomplish the end often consists of a jointed arm so placed as to have two independent motions at right angles to each other. In the best instruments the greatest care and attention is paid to this point, and a great variety of ingenious contrivances have been devised to overcome the various practical difficulties arising. The cut (f. 262) shows one of these in its simpler form. The crystal ia approximately adjusted by the hand, and then the operation completed by means of the screws c and d. These give two motions at right angles tc MATHEMATICAL CRYSTALLOGRAPHY. 87 each other, and the arrangement is such that the motions are made on the surface of a spherical segment of which the crystal itself occupies the centre, so that it is not thrown entirely out of the axis of the instrument by the motions of the screws. The adjustment having been accurately made, the edge is centered by means of two sliding carriages, a, &, moving at right angles to each other ; here they are moved by hand, but in better instruments by line screws. The edge must be first centered as carefully as practicable, then the complete adjustments made, and finally again centered, as before, to remove the excentricity caused by the movement of the ad- justment screws. The successful use of the most elaborate instruments is only to be attained after much patient practice. Theoretical discussions of the various errors arising in measurements and the weight to be attached to them have been given by Kuppfer (Preis- schrift iiber genaue Messung der Winkel an Krystallen, 1825), also by Naumann, Grailich, Schrauf, and others (see literature, p. iv). It has been stated that when the two planes have been adjusted in the goniometer so that their combination-edge is parallel to the axis of the instrument, the reflections given by them will be parallel. It is evident from this that any other planes on the crystal which are in the same zone with the two mentioned planes will also give, as the circle is revolved, reflections parallel to these. This means gives the test referred to on p. 53, leading on the one hand to the discovery of zones not indicated by parallel intersections, and on the other hand showing, in regard to supposed zones, whether they are so in fact or not. The degree of accuracy and constancy in the angles of crystals as they are given by nature is an important subject. Crystallography as a science is based upon the assumption that the forms made by nature are perfectly accurate, and whenever exact measurements are possible, supposing the crystals to have been free from disturbing influences, it has been found that this assumption is warranted by the facts ; in other words, the more accurate the measure- ments th>; more closely do the angles obtained agree with those required by theory. An example may illustrate this : On a crystal of sphalerite (zinc-blende), from the Binnenthal, exact measurements were made by Kokscbarow to test the point in question. He found for the angle of the tetrahedron 70 31' 48", required 70 3 31' 44" ; for the octahedral angle 109 3 27 42", required 109 28' 16'; and for the angle between the tetrahedron and cube 125 15' 52", required 125 15' 52". The crystallographic works of the same author, as well as those of many other workers in the same field, contain many illustrations on the same subject. At the same time variations in angle do occasionally occur, from a change in chemical composition, and from various disturbing causes, such as heat and pressure (see further, p. 107). Further than this, it is universally true that exact measurements are in comparatively few cases possible. Many crystals are large and rough, and admit of only approximate results with the hand goniometer; others have faces which are more or less polished, but which give uncertain reflections. This is due in some cases to striations, in others to the fact that the surfaces are curved or more or less covered with markings 01 etchings, like those common on the pyramidal planes of quartz. In all such cases there is a greater or less discrepancy between the measured and calculated angles. The important point to be noted always is the degree of accuracy attainably or, in other words, the probable error. The true result to be accepted is always to be obtained by the discussion of all the measurements in accordance with the methods of least squares. This method involves considerable labor, and in most cases it is sufficient to take the arithmetical mean, noting what degree of weight is to be attached to each measurement. It is to be noted that where measurements vary largely the probable error in the mean accepted will be con- siderable ; moreover an approximate measurement may not be the more accurate because it happens to agree closely with the theoretical angle. For the determination of the symbols of planes, measurement accurate within 30', or even 1, a>-e generally sufficient. When planes are rough and destitute of lustre the angles can best be obtained with the 88 C R YSTALLOGR APHT. reflecting goniometer, the reflections of the light from an object like a candle-flame, being ' taken in place of more distinct images. For" imbedded crystals, and often in other cases, measurements may be very advantage- ously made from impressions in some material, like sealing-wax. Angles thus obtained ought to be accurate within one degree, and suffice for many purposes. It is sometimes of advan- tage to attach to the planes to be measured, when quite rough, fragments of thin glass, from which reflections can be obtained; this must, however, be done with care, to avoid consider- able error. COMPOUND, OR TWIN CRYSTALS. TWIN CRYSTALS are those in which one or more parts regularly arrranged are in reverse position with reference to the other part or parts. They often appear externally to consist of two or more crystals symmetrically united, and sometimes have the form of a cross or star. They also exhibit the composition in the reversed arrangement of part of the planes, in the striae of the surface, and in re-entering angles ; in other cases the compound structure is detected only by polarized light. The following figures are examples of the simpler kinds. Fig. 263 is a twinned octahedron with 264 264A Spinel. Cassiterite. re-entering angles. Fig. 263A represents the regular octahedron divided into two halves by a plane parallel to an octahedral face ; the revolving of the upper half around 180 produces the twinned form. Fig. 264 consists of a square prism, with pyramidal terminations, twinned parallel to a diagonal plane between opposite solid angles, as illustrated in f. 264A, a representation of the simple form. A revolution of one of the two halves of f. 264A 180 about an axis at right angles to the diagonal plane outlined in the figure, would produce the form in fig. 264. Crystals which occupy parallel positions with reference to each other, that is, those whose similar axes and planes are parallel, are not properly called twins ; the term is applied only where the crystals are united in their reversed position in accordance with some deducibfe mathematical law. In conceiving of them we imagine first the two individuals or portions of the same individual to be in a parallel position, and then a revolution of 180 to take place about a certain line, as axis, which will bring them into the twinning position. An exception to the principle in regard to parallel axes is afforded in the case of hemihe- dral crystals, in some of which a revolution of 180 has the effect of producing an apparent!} holohedral form, the axes of the parts revolved remaining parallel. TWIN CRYSTALS. 89 In some cases (e.g.. hexagonal forms), a revolution of 60 would produce the twinned form, but in treating of the subject it is better to make the uniform assumption of a revolu- tion of iU J , which will answer in all cases. It is not to be supposed that twins have actually been formed by such a revolution of the parts of crystals, for the twin is the result of regular molecular growth or enlargement, like th.Hu 01 the simple crystal. This reference to a revolution, and an axis of revolution,, is only a convenient means of describing the forms. But while this is true, it is important to ob- serve that the Itiics deduced to explain the twinning of a crystal have, from a molecular standpoint, a real existence. The measurements of Schrauf on twins of cerussite (Tsch. Min. Mitth., 1873, 209) show the complete corresj iondence between the actual angles and those required in accordance with the law of twinning. Twinning axis. The line or axis about which the revolution of 180 is supposed to take place is called the t winning-axis (Zwillingsaxe, Germ.) t or axis of revolution. The following law has been deduced in regard to this axis, upon which the theory of the whole subject depends : The twinning axis is always a possible crystallographic line, usually either an axis or a normal to some possible crystalline plane. Twinning-plane. The plane normal to the axis of revolution is called the twinning-plane (Zwillingsflache, Germ.}. The axis and plane of twin- ning bear the same relation to both individuals in their reversed position ; consequently (except in some of hemihedral and triclinic forms) the twin- ned crystals are symmetrical with reference to the twinning-plane. Composition-ydane. The plane by which the reversed crystals are united is the composition-plane or -face (Zusammensetzungsflache, Germ.}. This and the twinning-plane very commonly coincide; this is true of the simple examples given above (f. 263, 264) where the plane about which the revolu- tion is conceived as having taken place (normal to the twinning axis), and the plane by which the semi-individuals are united, are identical. When not coinciding the two planes are generally at right angles to each other, that is, the composition face is parallel to the axis of revolution. Examples of this are given beyond (p. 99). Still again, where the crystals are not regularly developed, and where they interpenetrate, and, as it were, exer- cise a disturbing influence upon each other, the contact surface may be interrupted, or may be exceedingly irregular. In such cases the axis and Elane of twinning have, as always, a definite position, but the composition- ice has lost its significance. Thus in quartz the interpenetrating parts have often no rectilinear boundary, but mingle in the most irregular manner throughout the mass, and showing this composite irregularity by abrupt variations of the planes at the surface. Fig. 265 exhibits by its shaded part the parts of the plane 1 that appear over the surface of the plane R, owing to the interior composi- tion. This internal structure of quartz, found in almost all quartz crystals, even the common kinds, is well brought out 'by means of polarized light ; also, by etching with hydrofluoric acid, the plane 1 and R becoming etched unequally on the same amount of exposure to the acid. The twinning-plane is, with rare exceptions, a pos- sible occurring plane on the given species, and usually one of the more 90 CKYSTALLOGBAPHY. frequent or fundamental planes. The exceptions occur only in the triclinic and monoclinic systems, where the twinning axis is sometimes one of the oblique crystal lographic axes, and then the plane of twinning normal to it is obviously not necessarily a crystal lographic plane, this is conspicuous in albite. In these cases the composition-face is often of more significance than the twinning-plane, the former being distinct and parallel to the axis, in accordance with the principle stated above. With reference to the composition-face, the twinning may be described as taking place (1) by a revolution on an axis at right angles to the 'composition-face, (2) on an axis parallel to it and vertical, (3) by an axis parallel to it and horizontal; whether the revolution takes place with the right or left half of the crystal, the twin is right- or left-handed. One further principle is of theoretical importance in the mathematical explanation of the forms. The twinning axis may, in many cases, be ex- changed for another line at right angles with it, a revolution about which will also satisfy the conditions of producing the required form. An exam- ple of this is furnished by f. 318, of orthoclase ; the composition-face is parallel to i-i, the axis of revolution also parallel to this plane, and (a) nor- mal to i4, which is then consequently the twinning-plane, though the axis does not coincide with the crystallographic axis, or (b) it may coincide with the vertical axis, and then the twinning-plane normal to it is not a crys- tallographic plane. In other simpler cases also, the same principle holds good, generally in consequence of the possible mutual interchange of the planes of twinning and composition. In most cases the true twinning-plane is evident, since it is parallel to some plane on the crystal of simple mathe- matical ratio. An interesting example of the above principle is furnished by the species staurolite. Fig. 307, p. 98, shows a prismatic twin observed by the author among crystals from Fannin Co., Ga. The measured angle for i-i A *'-*' was 70 30' ; the twinning-axis deduced from this may be the normal to the plane 4-f, which would then be the twinning-plane. Instead of this axis, its complementary axis at right angles to it may be taken, which will equally well produce the observed form. Now in this species it happens that the planes -3 and i-'$ (over i-l) are almost exactly at right angles (90 8') with each other, and hence, according to this latter supposition,^'- 3 becomes the twinn ng-plane, and the axis of revolution is normal to it. Hence, either i- \ or i-3 may be the twinning-plane, either supposition agrees closely with the measured angle, which could not be obtained with great accuracy. The former method of twinning (f-f ) conforms to the other twins observed on the species, and hence it may be accepted. What is true hi this case, however, is not always true, for it will seldom happen that of the two complementary axes each is so nearly normal to a plane of the crystal. In most cases one of the two axes conforms to the law in being a normal to a possible plane, and the other does not, and hence there is no doubt as to which is the true twinning axis. Contact-twins and Penetration-twins. In contact-twins, when normally formed, the two halves are simply connate, being united to each other bj the composition-face ; this is illustrated by f. 263, 264. In actually occur- ring crystals the two parts are seldom symmetrical, as demanded by theory, but one may preponderate to a greater or less extent over the other; in some cases only a small portion of the second individual in the reversed position may exist. Yery great irregularities are observed in nature in this respect. Moreover, the re-entering angles are often obliterated by the ab- normal developments of one or other of the parts, and often only an indis- TWIN CRYSTALS. 91 tinct line on some of the faces marks the division between the twc individuals. Penetration-twins are those in which two or more complete crystals interpenetrate, as it were crossing through each other. Normally, the crystals have a common centre, which is the centre of the axial system fo f both ; practically, however, as in contact-twins, great irregularities occur. Examples of these twins are given in the annexed figures, 266 267 f. 266, of fluorite, and f. 267, of hematite. Other examples occur in the pages following, as, for instance, of the species staurolite, f . 309 to 312, the crystals of which sometimes occur in nature with almost the perfect symmetry de- manded by theory. It is obvi- ous that the distinction between contact and penetration-twins is not a very important one, and the line cannot always be clearly drawn between them. Paragenio and Metagenic twins. The distinction of paragenic and metagenic twins belongs rather to crystallogeny than crystallography. Yet the forms are often so obviously distinct that a brief notice of the dis- tinction is important. In ordinary twins, the compound structure had its beginning in a nucleal compound molecule, or was compound in its very origin ; and whatever inequalities in the result, these are only irregularities in the development from such a nucleus. But in others, the crystal was at first simple ; and afterwards, through some change in itself or in the condition of the mate- rial supplied for its increase, received new layers, or a continuation, in a reversed position. This mode of twinning is metagenic, or a result subse- quent to the origin of the crystal ; while the ordinary mode is paragenio. One form of it is illustrated in f. 268. The middle portion had attained a length of half an inch or more, and then became genicu- lated simultaneously at either extremity. These geniculations are often repeated in rutile, and the ends of the crystal are thus bent into one another, and occasionally produce nearly regular prismatic forms. This metagenic twinning is sometimes presented by the successive layers of deposition in a crystal, as in some quartz crystals, especially amethyst, the inseparable layers, exceedingly thin, being of oppo- site kinds. So calcite crystals are sometimes made up of twinned layers, which are due to an oscillatory process of twinning attending the progress of the crystal. In a similar manner, crystals of the triclinic feldspars, albite, etc., are often made up of thin plates parallel to i-%, by oscillatory compo- sition, and the face O, accordingly, is finely striated parallel to the edge Rutile. 92 CRYSTALLOGRAPHY. Repeated twinning. In the preceding paragraph one case of repeated twinning has been mentioned, that of the feldspars ; it is a case of parallel repetition or parallel grouping of the successive crystals. Another kind is that which is illustrated by f. 295, 297, 311, where the successively reversed individuals are not parallel. In this case the axes may, however, lie in a zone, as the prismatic twins of aragonite, or they may be inclined to each other, as in f. 311, of staurolite. In all such cases where the repeti- tion of the twinning tends to produce circular forms, as f. 281, of rutile, the number of individuals is equal to the number of times the angle between the two axial systems is contained in 360. For example, five-fold twins occur in the tetrahedrons of gold and sphalerite, since 5 x 70 32' (the tetra- hedral angle) = 360 (approx.). A compound crystal, when there are three individuals, is called a Trilling (Drilling, Germ.), where there are four individuals, a Fourling (Yierling, Germ.), etc. (See also on p. 186.) Compound crystals in which twinning exists in accordance with two laws at once are of rare occurrence; an excellent example is afforded by stauro- lite, f. 312. They have also been observed on albite (f. 333), orthoclase, chalcocite, and in other less distinct cases. JZxamples of different methods of Twinning* ISOMETRIC SYSTEM. With few exceptions the twins of this system are ol one kind, the twinning axis an octahedral axis, and the twinning plane consequently an octahedral plane inmost cases also the latter coincides Galenite. Sphalerite. Galenite. with the composition-face. Fig. 263 shows this kind as applied to tiie simple octahedron, it is especially common with the spinel group of min- erals ; similarly, f. 269, a more complex form, and also, f. 270, a dodeca- hedron twinned ; all these are contact twins. Fig. 271 is a penetration twin following the same law ; the twinning being* repeated, and the form flattened parallel to an octahedral face. Fig. 266, p. 91, shows a twin oi * A complete enumeration of the different methods of twinning observed under the differ- ent systems, with detailed descriptions and many figures, will be found in Vol. II. of Rose- Sadebeck's Crystallography (Angewandte KrystaUographie, 284 pp., 8vo, Berlin, 1876). TWIN CRYSTALS. 93 fluorite, two interpenetrating cubes ; f. 272 exhibits a dodecahedral twin of sodalite occurring in nature of almost ideal symmetry, and f. 273 is a tetrahedral twin of the species tetrahedrite ; the same law is true for all. Sodalite. Tetrahedrite. Haiiynite. Figs. 274, 275, 276, are twins whose axes are parallel ; these forms are possible only with hernihedral crystals. The twinning axis is here a dode- cahedral axis and the twinning plane a dodecahedral plane. The same 275 276 277 Pyrite. Magnetite. method of composition is often seen in dendritic crystallizations of native gold and copper, in which the an^le of divergence of the branches is 60 and 120, the interfacial angles of a dodecahedron. The brownish-black mineral in the mica from Pennsbury, Pa., is magnetite in this form (f. 277), as first observed by G. J. Brush. TETRAGONAL SYSTEM. The most common method is that where the t win- ning-plane is parallel to 1-i. It is especially characteristic of rntile and cassiterite. This is illustrated in f. 264 and similarly in f. 278. Fig. 268 shows a similar twin of rutile, and in f. 281 to 283 the twinning according to this law is repeated. In f. 281 the vertical axes of the successive six individuals lie in a plane, and an enclosed circle is the result ; in f. 282 the successive vertical axes form a zig-zag line ; there are here four individuals, CRYSTALLOGRAPHY. add four more behind, the last (VIII) uniting with the first (I), and let it be developed vertically, and the complex form produced results in the scalenohedron twin of f. 283. In chalcopyrite, the octahedron 1, which is 279 Cassiterite. Chalcopyrite. Scheelite. very near a regular octahedron in angle, may be the twinning-plane, and forms are thus produced very similar to f. 263. With hemihedral forms twinning may take place as shown in f. 280, where the axis of revolution Entile. Rutile. is a diagonal axis, and the plane of twinning the prism /. It is not always indicated by a re-entering angle, but is sometimes only shown by the oblique striations in two directions meeting in the line of contact. Rutile. Pyrrhotite. Another mode of twinning is that occurring in leucite, observed by vom Rath, who showed the species to be tetragonal. The twinning-plane is here 2-t. (Jahrb. Min., 1873, 113.) TWIN CRYSTALS. SYSTEM.- -In the holohedral division of this system twins are rare. plane nearl is tridymite t or. 885 gles to each other (O A 1 = 135 8'). Another example (see p. 288), where the twinning-plane is either the pyramid Galcite. Calcite. Chabazite. In the species of the rhombohedral division twins are numerous ; the ordinary methods are the following: the twinning-plane the rhombohe- dron R, f. 285 ; the rhombohedron -27?, f. 288 ; the rhombohedron \R, f. 286. The last mentioned method is common in masses of calcite, where by its frequent repetition it gives rise to thin lamellae ; these are observed often in crystalline limestones. (See p. 173.) 288 Pyrargyrite. The twinning-plane may also be the basal plane, the axis of revolution consequently the vertical axis. This is illustrated in f. 287, a complex penetration twin of chabazite, also f. 267 (hematite), and in f. 289, 290. It is also common with quartz, the two crystals sometimes distinct, and joined by a prismatic plane, sometimes interpenetrating each other very irregularly, as shown in f. 265. * G. vom Rath, Pogg. Ann., cxxxv. 437 ; clii 1. 96 CRYSTALLOGRAPHY. ORTHORHOMBIO SYSTEM. In the orthorhombic system twins are exceed ingly common, and the variety of methods is very great. These may, how ever, be brought into two groups, according as the twinning-plane is (1) a prismatic plane, vertical or horizontal, or (2) an octahedral plane. The twinning is very often repeated, and always in accordance with the law already stated, that the number of individuals is determined by the number of times that the angle of the two axial systems is contained in 360 (a) Twinning parallel to a prism whose angle is approximately 120. 1. Pris7ti vertical. The principal examples are aragonite, / A 1 = 116 10'; cerussite, 7 A 1= 117 13'; witherite, /A 7 118 30'; bromlite, / A 7 = 118 50' ; chalcocite, 7 A 7 = 119 35' ; stephanite, 7 A / = 115 39'; dyscrasite, 7A7= 119 59'. Figs. 291, 292, represent twins of ara- gonite in accordance with this law. Figs. 293, 294, show cross-sections of the two prisms of the preceding figures, in the latter the form is hexagonal, though not regularly so. Fig. 295 is a cruciform twin of the same species. 291 Aragonite. Aragonite. 295 Aragonite. 2. Prism horizontal ; that is, a macrodome. Examples: arsenopvrite, 14 A 14 = 120 46' ; leadhillite, 14 A 14 = 119 20' ; humite, type 1. 3. Prism horizontal ; that is, a brachydome. Examples : manganite, 1-2 A 1-2 = 122 5<) ! (f. 2l6) ; chrysoberyl, 3 I A 3-2 (f. 300) =120 13' ; columbite, 2-2 A 2-2 = 117 20'. In all these cases there is a strong tendency toward repetition of the twinning, by which forms often stel- late, sometimes apparently hexagonal, result. These forms are illustrated in the following figures : f. 297 is of witherite; f. 298 9 crystal of Leadh llite, in its twinned form of very rhombohedral spi*cr. Figs. 299 and 300 are both chrysoberyl, where 3-i is the twinning-plane ; six-rayed twins are very common in this species. The genesis of these forms is further illustrated by the following cross- Manganite. TWIN CRYSTALS. 97 sections. Fig. 301 shows a cross-section of a cerussite twin, and f. 302 one of the crystal of leadhillite figured above (f. 298). Witherite. Leadhillite. Chrysoberyl. Chrysoberyl. In f. 303, three rhombic prisms, /, of aragonite, are combined about their acute angles, the dotted lines showing the outlines of the prisms, and the f*-*+mr*n ~\ 1.1* J - . A.* C i1_ _ 1- _ 1 _1 1 1 /* f\r\ t f* cross lining the direction of the brachydiagonal ; and in f. 304, four are similarly united. In f. 305, three similar prisms, /, are combii are combined about the- 301 Cerussite. obtuse angle. This twin combination may take the form of a hexagonal prism, with or without re-entering angles ; of a three-rayed twin, like f. 301, and if a penetration-twin, of a composite prism, like-f. 306 (the num- bering of the parts showing the relation), or a six-rayed twin. In all these cases the stellate form depends on the extension of the individuals beyond the normal limits. (b) Prismatic angle approximately that of the regular octahedron, 109 28'. An example is furnished by the species staurolite (f. 307), where th 7 CRYSTALLOGKAPHY. \ tw inning-plane is H|, and the corresponding prismatic angle is 109 14' (over*-*, or 70 46' over i-l). 307 308 Another example is furnished by marcasite, whose prismatic angle is 106 5'. The twins are generally compound, the repetition with the t winning- plane sometimes parallel, sometimes oblique, see p. 247. In f. 308 the compound crys- tal consists of five individuals, Marcasite since five times 73 55' is ap- proximately equal to 360. Staurolite. nearly rectangular phillipsite, p. 345. 2. The twinning-plane may be also an octahedral plane. An excellent example is furnished by staurolite, where the twinning-plane isf-f (f. 310). The crystals cross at angles of nearly 120 and 60, hence the form in f. 311, consisting of three individuals (trilling) forming a six-rayed star. In f. 312 both this method of twinning: and that mentioned above are ( com- 312 Staurolite. Staurolite. Staurolite. Staurolite. bined. There are thus for the species staurolite three methods of twin- ning, parallel to *"-}, to f-, and to f-". If the occurring prism is made *-}, then the three twinning-planes become /, 1-i, 1, or fundamental planes, as is usually true. MONOCLINIC SYSTEM. The following examples comprise the more com- monly occurring methods of twinning in this system. (a) The twinniug-plane is the orthopinacoid (i-i). This is true in the se of the common twins of orthoclase (f. 318), called the CarUbad twins. case The axis of revolution is normal to i-i (see also p. 90), while the two crystals are united by the clinopinacoid, which is consequently the compo- sition-face. These twins may be either right- or left-handed (f. 318 or f. 319), according as the right or left half of the simple form (f. 317) has been revolved. TWIN CRYSTALS. Fig. 313, of pyroxene, is another familiar example ; so also f. 314, of which f. 315 is the simple form. Fig. 320 is a twin of scolecite, where the twin structure is shown by the striafions on the clinopinacoid. 313 315 Pyroxene. Ainpbibole. Scolecite. A form of penetration-twin, with i-i the twinning-plane, is shown in f. 321 (from von Lang). The mode of combi- nation and cross-penetration of the two crystals 321 1 , 2, is illustrated in f. 322 ; it is a medial section of f. 321 from front to back. Malachite. (b) The twinning-plane may also be the basal plane. This is common with orthoclase ff. 324); also with gypsum (f. 323). It has also been observed by the author in chondro- dite, type II and III, from Brewster, N. Y., see p. 305. (c) Figs. 325, 326. 327 show another method of twinning of orthoclase parallel to the clino- dome, 24. These twins are peculiar in that they form nearly rectangular prisms, since O A 24 = 135 3^'. They are common among the orthoclase crystals from Baveno, and hence are called Baveno twins. This method of twinning is also common with the amazon-stone of Pike's Peak. The union of four crystals of this kind produces the form represented in f. 325 ; and the same, by penetration, develops the penetration-twin of f. 327 (from v. Rath), which apparently consists of four pairs of twins, but may be regarded as made by the cross-penetration of the crystals of two pairs, or of the four of f. 325. Forms like f. 325 may have one of the four parts undeveloped and so consist of three united crystals, and also the other parts, as in such com- pound twins generally, may be very unequal. Twins corresponding to those of the orthorhombic system, where tho twinning-plane is a prism whose angle is nearly 120, have been observed by VODI Rath in hurnite, types II and III. TRIOIJNIC SYSTEM. In the twins of the triclinic system, the three axes 100 CEYSTALLOGEAPHY. may be axes of revolution, in which case the t winning-planes are not occur- ring crystallographic planes ; or, the pinacoid planes may be the planes of twinning and' the normals to them the axes of revolution. Some of the eases are illustrated in the following figures of albite. In f. 329 the brachr^pinacoid (i-Z) is the twinning-plane ; f . 328 is the same, but it is a penetration-twin ; this is the most common method of twinning with thia species. 323 324 Orthoclase. Orthoclase. In f. 332 the vertical axis is the twinn ing-axis. Fig. 333 (from G. Hose) is a double twin, the two halves of which are like f. 328, but they are twinned together like f. 332. It happens in albite that the plane angles on i-l, made by the edges /A O and /A 1 differ but 37' (the former being 116 26', the latter 115 55'), and hence it is that in the twin O and 1 fall nearly into one plane. CRYSTALS. 101 Composition parallel to <9, where the revolution is on a horizontal axis normal to the shorter diagonal of O, is ex- emplified in f. 334 (from G. Rose). Both right- and left-handed twins of this kind occur; also double twins in which this method is combined with twinning (like that in f . 329, 330), parallel to i-l. A thorough discussion of the method of twinning in the triclinic system lias been given by Schrauf in his monograph of the species brochantite (Ber. Ak., Wien, Ixvii., 275, 1873). Albite. REGULAR GROUPING OF CRYSTALS. Connected with the subject of twin crystals is that of the parallel posi- tion of associated crystals of the same species, or of different species. Crystals of the same species occurring together are very commonly in parallel position. In this way large crystals are sometimes built up of smaller individuals grouped together with corresponding planes parallel. This parallel grouping is often seen in crystals as they lie on the support- ing rock. On glancing the eye over a surface covered with crystals, a reflection from one face will often be accompanied with reflections from the corresponding face in each of the other crystals, showing that the crystals are throughout similar in their positions. Crystals of different species often show the same tendency to parallelism in mutual position. This is true most frequently of species which, from similarity of form and composition, are said to be isomorphous (see p. 199). Crystals of albite, implanted on a surface of orthoclase, are sometimes an example of this ; crystals of hornblende and pyroxene, and of various kinds of mica are also at times observed associated in parallel position. The same relation of position also occasionally occurs where there is no connection in composition, as the crystals of rutile on tabular crystals of hematite, the vertical axes of the former coinciding with the lateral axes of the latter. Breithaupt has figured crystals of calcite, whose rhombo- hedral faces ( \E] had a series of quartz crystals upon them, all in parallel position (f. 335) ; and Frenzel and vom Rath have described the same association where three such quartz crystals, one on each rhornbo- hedral face, entirely enveloped the calcite, and uniting with re-entering 102 CRYSTALLOGRAPHY. angles formed pseudo-twins (rather trillings) of quartz aftei calcite. The author has described a similar occurrence from u Specimen Mountain," in the Yellowstone Park ; the form is shown in f. 336. (Am. J. ScL, III., xii., 1876.) IRREGULARITIES OF CRYSTALS. The laws of crystallization, when unmodified by extrinsic causes, should produce forms of exact symmetry ; the angles being not only equal, but al^p the homologous faces of crystals and the dimensions in the directions r &xefe; r '' THis symmetry is, however, so uncommon, that it can l F fre^ considered" Bother than an ideal perfection. Crystals are very Sml often the fundamental forms are so completely dis- guised, that an intimate familiarity with the possible irregularities is re- quired in order to unravel their complexities. Even the angles may occasionally vary rather widely. The irregularities of crystals may be treated of under several heads: 1, Imperfection* of surface / 2, Variations of form and dimensions / 3, Variations of angles / 4, Internal imperfections and impurities. I. IMPERFECTIONS IN THE SURFACES OF CRYSTALS. 1. Striations or angular elevations arising from oscillatory combina- tions. The parallel lines or furrows on the surfaces of crystals are called stricBj and such surfaces are said to be striated. Each little ridge on a striated surface is enclosed by two narrow planes more or less regular. These planes often correspond in position to differ- ent planes of the crystal, and we may suppose these ridges to have been formed by a continued oscillation in the operation of the causes that give rise, when acting uninterruptedly, to enlarged planes. By this means, the surfaces of a crystal are marked in parallel lines, with a succession of nar- row planes meeting at an angle and constituting the ridges referred to. This combination of different planes in the fonna- 337 tion of a surface has been termed oscillatory com- bination. The horizontal striae on prismatic crystals of quartz are examples of this combination, in which the oscillation has taken place between the prismatic and pyramidal planes. As the crystals lengthened, there was apparently a continual effort to assume the terminal pyramidal planes, which effort was interruptedly overcome by a strong tendency to an increase in the length of the prism. In this manner, crystals of quartz are often tapered to a point, without the usual pyramidal terminations. Magnetite. Other examples are the striation on the cubic faces of pyrite parallel with the intersections of the cube with the planes of the pyritohedron ; also the striations on magnetite (f. 337) due to the oscillation between the octahedron and dodecahedron. IRREGULARITIES OF CRYSTALS. 103 Prisms of tourmaline are very commonly bounded vertically "by three convex surfaces, owing to an oscillatory combination of the planes /and i-%. Faces of crystals are often marked with angular elevations more or less distinct, due sometimes also to oscillatory combination. Octahedrons of fluorite are common which have for each face a surface of minute cubes, proceeding from an oscillation between the cube and octahedron. This is a common cause of drusy surfaces with the crystals of many minerals. 2. Striationsfrom oscillatory composition. The striations of the plane O of albite and other triclinic feldspars, and of the rhombohedral surfaces some calcite, have been attributed, on p. 91, to oscillatory twinning. 3. Markings from erosion and other causes. It is not uncommon that the faces of crystals are uneven, or have the crystalline structure developed as a consequence of etching by some chemical agent. Cubes of galenite are often thus uneven, and crystals of lead sulphate or lead carbonate are someiimes present as evidence with regard to the cause. Crystals of numer- ous other species, even of corundum, spinel, quartz, etc., sometimes show the same result of partial change over the surface often the incipient stage in a process tending to a final removal of the whole crystal. Interesting in- vestigations have been made by various authors on the action of solvents on different minerals, the actual structure of the crystals being developed in this way. These are referred to again in another place (p. 12^). The markings on the surfaces of crystals are not, however, always to be ascribed to etching. In most cases etchings, as well as the minute angular elevations upon the planes, are a part of the original molecular growth of the crystal, and often serve to show the successive stages in its history. They are the imperfections arising from an interrupted or disturbed de- velopment of the form, the perfectly smooth and even crystalline faces being the result of completed action free from disturbing causes. Ex- amples of the marking referred to occur on the crystals of most minerals, and conspicuously so on the pyramidal planes of quartz. The development of this subject belongs rather to crystallogeny refer- ence may, however, be made here to the memoirs of Scharff, bearing on this subject, especially one entitled " LJeber den Quarz, II., die Ueber- gangsflachen," Frankfort, 1874; also to the Crystallography of Sadebeck (for title free Introduction). It follows from the symmetry of crystallization that like planes should be physicaUy alike, that is in regard to their surface character ; it thus often happens that on all the crystals of a species from a given locality, or perhaps from all localities, the same planes are etched or roughened alike. For example, on crystals of datolite from Bergen Hill, the plane 2-i is almost uniformly destitute of lustre ; there is much uniformity on the crystals of quartz in this respect. 4. Curved surfaces may result from (a) oscillatory combination ; or (b) some independent molecular condition producing curvatures in the laminae of the crystal ; or (c) from a mechanical cause. Curved surfaces of the first kind have been already mentioned, p. 102. A singular curvature of this nature is seen in f. 339, of calcite ; and another in the same mineral in the lower part of f. 338, in which traces of a scaleno- hedral form are apparent which was in oscillatory combination with the prismatic form. 104 CRYSTALLOGRAPHY. Curvatures of the second kind sometimes have all the faces convex. This is the case in crystals of diamond (f. 340), some of which are almost spheres. The mode of curvature, in which all the faces are equally oon- vex, is less common than that in which a convex surface is opposite and parallel to a corresponding concave surface. Hhombohedrons of sideritc (see p. 403) are usually thus curved. The feathery curves of frost on win- dows and the flagging stones of pavements in winter are other examples of curves of the second kind. The alabaster rosettes from the Mammoth Cave, Ky., are similar. 339 340 Caleitc. Calcite. Diamond. V. A third kind of curvature is of mechanical origin. In many species crystals appear as if they had been broken transversely into many pieces, a slight dis- placement of which has given a curved form to the prism. This is common in tourmaline and beryl. The beryls of Monroe, Conn., often present these interrupted curvatures, as represented in f. 341. Crystals not unfrequently occur with a deep pyramidal depression occupying the Beryl, Monroe, Conn, place of each plane, as is often observed in common salt, alum, and sulphur. This is due in part to their rapid growth. II. VARIATIONS IN THE FORMS AND DIMENSIONS OF CRYSTALS. The simplest modification of form in crystals consists in a simple varia- tion in length or breadth, without a disparity in similar secondary planes The distortion, however, extends very generally to the secondary planes, especially when the elongation of a crystal takes place in the direction of a diagonal, instead of the crystallographic axes. In many instances, one or more planes are obliterated by the enlargement of others, proving a sor,rce of much perplexity to the student. The'interfacial angles remain constant, unaffected by these variations in form. These changes in form often give rise to what is called by Sadebeck pseudo-symmetry / the distorted forms of one system appearing similar to the normal forms of another. (Compare the descriptions of the following figures.) As most of the difficulties in the * See p. 188 for another use of this word. IRREGULARITIES OF CRYSTALS. 105 study of crystals arises from these distortions, this subject is one of great importance. Figs. 342 to 353 represent examples from the isometric system. A cube lengthened or shortened along one axis becomes a right square prism, and if varied in the direction of two axes is changed to a rectangu- lar prism Cubes of pyrite, galenite, iluorite, etc., are generally thus dis- torted, it is very unusual to find a cubic crystal that is a true symmetrical cube. In some species the cube or octahedron (or other isometric form) is lengthened into a capillary crj stal or needle, as happens in cuprite and pyrite. An octahedron flattened parallel to a face, or in the direction of a trigonal interaxis, is reduced to a tabular crystal (f. 342). If lengthened in the same direction, it takes the form in f. 343 ; or if still farther lengthened to the obliteration of A', it becomes an acute rhombohedron (same figure). 343 344 When an octahedron is extended in the direction of a line between two opposite edges, or that of a rhombic interaxis, it has the general form of a rectangular octahedron; and still farther extended, as in f. 344, it is changed to a rhombic prism with dihedral summits (spinel, fluorite, magne- tite). The figure represents this prism lying on its acute edge. The dodecahedron lengthened in the direction of a diagonal between the 345 346 obtuse solid angles, that is, that of a trigonal interaxis, becomes a six- sided prism with three-sided summits, as in f. 345 ; and shortened in the same direction is a short prism of the same kind (f. 346). Both resemble rhombohedral forms and are common in garnet and zinc blende. When lengthened in the direction of one of the cubic axes, it becomes a square prism with pyramidal summits (f. 347), and shortened along the same axis if is reduced to a square octahedron, with truncated basal angles (f. 348). 106 CRYSTALLOGRAPHY. The trapezohedron is still more disguised by its distortions. When elon- gated in the line of a trigonal interaxis, it assumes the form in f. 349 ; and still farther lengthened, to the obliteration of some of the planes, becomes a scalene dodecahedron (f. 350). This has been observed in flnor spar. Only twelve planes are here present out of the twenty -four. Threads oi native gold from Oregon, are strings of crystals presenting the form of this very acute rhombohedron, with the other planes of the trapezohedron 2-2 (the scalenohedral and the terminal obtuse rhombohedral) quite small at the extremities. If the elongation of the trapezohedron takes place along a cubic axis, it becomes a double eight-sided pyramid with four-sided summits (f. 351) ; or if these summit planes are obliterated by a farther extension, it becomes a complete eight-sided double pyramid (f. 352). 349 350 A scaleno-dodecahedron of calcite is shown distorted in f. 353, which ap- pears, however, to be an eight sided prism, bounded laterally by the planes R, 1 s , I 3 , and R, and their opposites, and terminated by the remaining planes. The following figures of quartz (f. 35-t, 355) represent distorted forms of this mineral, in which some of the pyramidal faces by enlargement dis- place the prismatic faces, and nearly obliterate some of the other pyramidal faces ; see also f. 336. 353 354 355 Calcite. Quartz. Quartz. Fig. 356 is a distorted crystal of apatite ; the same is shown in f. 357 with the normal symmetry. The planes between O and the right / are enlarged, while the corresponding planes below are in part obliterated. IRREGULARITIES OF CRYSTALS. 107 By observing that similar planes are lettered alike, the correspondence of the two figures will be understood. In deciphering the distorted crystalline forms it must be remembered that while the appearance of the crystals may be entirely altered, the angles remain the same ; moreover, like planes are physically alike, that is, alike in degree of lustre, in striations, and so on. 356 357 Apatite. Apatite. In addition to the variations in form which have just been described, still greater irregularities are due to the fact that, in almost all cases, crystals in nature are attached either to other crystals or to some rock surface, and in consequence of this are only partially developed. Thus quartz crystals are generally attached by an extremity of the prism, and hence have only one set of pyramidal planes ; perfectly formed crystals, as those from Ilerkiraer Co., N". Y., having the double pyramid complete, are rare. The same statement may be made for nearly all species. III. VARIATIONS IN THE ANGLES OF CRYSTALS. The greater part of the distortions described occasion no change in the mterfacial angles of crystals. But those imperfections that produce con- vex, curved, or striated faces, necessarily cause such variations. Further- more, circumstances of heat or pressure under which the crystals were formed may sometimes cause not only distortion in form, but also some variation in angle. The presence of impurities at the time of crystallization may also have a like effect. Still more important is the change in the angles of completed crystals which is caused by subsequent pressure on the matrix in which the} 7 were formed, as, for example, the change which may take place during the more or less complete metaiuorphism of the enclosing rock. The change of composition resulting in pseudomorphous crystals (see p. 113) is generally accompanied by an irregular change of angle, so that the pseudomorphs of a species vary much in angle. In general it is safe to affirm that, with the exception of the irregularities 108 CRYSTALLOGRAPHY. arising from imperfections in the process of crystallization, or from changes produced subsequently, variations in the angles are rare, and the constancy of angle alluded to on p. 87 is the universal law.* In cases where a greater or less variation in angle has heen observed in the crystals of the same species from different localities, the cause for this can usually be found in a difference of chemical composition. In the case of isomorphous compounds it is well known that an exchange of correspond- ing chemically equivalent elements may take place without a change of form, though usually accompanied with a slight variation in the funda- mental angles. The effect of heat upon the form of crystals is alluded to upon p. 168. IY. INTERNAL IMPERFECTIONS AND IMPURITIES. The transparency of crystals is often destroyed by disturbed crystalliza- tion, or by impurities taken up from the solution during the process of crystallization. These impurities may be simply coloring ingredients, or they may be inclosed particles, fluid or solid, visible to the eye or under the microscope. The coloring ingredients mav vary in the course of formation of the crystals, and thus layers of different colors result ; the tourmaline crystals of Chesterfield, Mass., have a red centre and blue exterior ; others from Elba are sometimes light-green below and black at the extremity ; many other examples might be given. The subject of the fluid and solid inclosures in crystals is one to which much attention has been directed of late years. Attention was early called to its importance by Brewster, who described the presence of fluids in quartz, topaz, beryl, chrysolite, and other minerals. In later years the mat- ter has been more' thoroughly studied by Sorby, Zirkel, Vogelsang, Fischer, Rosenbusch, and many others. (See Literature, p. 111.) Many crystals contain empty cavities ; in others the cavities are filled sometimes with water, or with the salt solution in which the crystal was formed, and not infrequently, especially in the case of quartz, with liquid carbonic acid, as first proved by Vogelsang, and recently followed out by Hartley. These liquid inclosures are marked as such, in many cases, by the presence in the cavity of a movable bubble. The solid inclosures are almost infinite in their variety. Sometimes they are large and distinct, and can be referred to known mineral species, as the scales of hematite to which the peculiar character of aventui ine feldspar is due. Magnetite is a very common impurity for many minerals, appearing, for example, in the Pennsbury mica; quartz is also often mechanicairy mixed, as in staurolite and gmelinite. On the other hand, quaitz crystals very commonly inclose foreign material, such as chlorite, tourmaline, rutile, hematite, asbestos, and many other minerals. * Referen e must be made here to the discussion by Scacchi of the principle of " Polysym- metry." (Atti Accad. Napoli, i., 1864.) See also Hirschwald, Zur Kritik des Leucitsystema, Tsch. Mia. Mitth., 1875, 227. See further the discussion on pp. 185 et seq. IRREGULARITIES OF CRYSTALS. 100 The inclosures may also consist of a heterogeneous mass of material ; as the granitic matter seen in orthoclase crystals in a porphyritic granite ; or the feldspar, quartz, etc., sometimes inclosed in large coarse crystals of beryl, occurring in granite veins. An interesting example of the inclosure of one mineral by another is afforded by the annexed figures of tourmaline, enveloping orthoclase (E. II. Williams, Am. J. Sci., III., xi., 273, 1876). Fig. 358 shows the crystal of tourmaline ; and cross-sec- tions of it at the pL-ints indicated (a, &, c) are given by f. 359, 360, 361. The latter show that the^f eld- spar increases in amount in the lower part of the crystal, the tourmaline being merely a thin shell. Similar specimens from the same locality (Port Henry, Essex Co., N". Y.) show that there is no ne- cessary connection between the position of the tour- maline and that of the feldspar. Similar occurrences are those of trapezohedrons of garnet, where the latter is a mere shell, enclosing calcite, or sometimes epidote. Analogous cases have been explained by some authors as being due to partial pseudomorph ism, the alteration progressing from the centre outward. The microscopic crystals observed as inclosures may sometimes be referred to known species, but more generally their true nature is doubtful. The term microlites, proposed by Yogelsang, is often used to designate the 362 366 minute inclosed crystals; they are generally of needle-like form, some times quite irregular, and often very remarkable in their arrangement and groupings ; some of them are exhibited in f. 367 and f. 368, as explained no CRYSTALLOGRAPHY. below. Trichite and belonite are names introduced by Zirkel ; the former name is derived from Opi& hair, the forms, like that in f. 362, are common in obsidian. Where me minute individuals belong to known species they are called, for example, feldspar microlites, etc. Crystallites is an analogous term which is intended by Vogelsang to cover those minute forms which have not the regular exterior form of crystals, but may be considered as intermediate between amorphous matter and true crystals. Some of the forms, figured by Yogelsang, are shown in f. 363 to 366 ; they are often observed in glassy volcanic rocks, and also in furnace slags. A series of names have been given to varieties of crystallites, such as globulites, margarites, etc.* The microscopic inclosures may also be of an irregular glassy nature ; a kind that exists in crystals which have formed from a melted mass, as lavas or the slag of iron furnaces. In general, it may be said that while the solid inclosures occur sometimes quite irregularly in the crystals, they are more generally arranged with some evident reference to the symmetry of the form, or planes of the crystals. Examples of this are shown in the following figures: f. 367 ex 867 368 Augite. Leucite. Calcite. hibits a crystal of augite, inclosing magnetite, feldspar and nephelite microlites, etc., and f. 368 shows a crystal of leucite, a species whose crystals very commonly inclose foreign matter. Fig. 369 shows a section of a crystal of calcite, containing pyrite. Andalusite. ^ Another striking example is afforded by andalusite, in which the inclosed impurities are of considerable extent and remarkably arranged. Fig. 370 shows the successive parts of a single crystal, as dissected by B. Horsford * Die Krystalliten von Hermann Vogelsang. Bonn, 1875. CRYSTALLINE AGGREGATES. of Springfield, Mass. ; 371, one of tie four white portions; and 372 the central black portion. 372 LITERATURE. Some of the most important works on the subject are referred to here, but for a complete Ust of the literature up to 1873, reference may be made to Uosenbusch (see below). Blum, Leonhard, 8eyfert, and Sochting, die Einschliisse von Mineralien in krystallisirten Mineralien. (Preisschrift.) Haarlem, 1854. Brewster. Many papers published mostly in the Philosophical Magazine, and the Edinburgh Phil. Journal, from 1822-1856. Fischer. Kritische-microscopische mineralogische Studien. Freiburg in Br 64 pp 1869 Ite Fortsetzung, 64 pp., 1871 ; 2te Forts., 90 pp., 1873. Kosmnnn. Ueber das Schillem und den Dichroismus des Hypersthens Jahrb Min 1869 368 (ibid. p. 532, 1871, p. 501). Rosenbusch. Microscopische Physiographic der petrographisch wichtigen Mineralien 395 pp., Leipzig, 1873 Schrauf. Studien an der Mineralspecies Labradorit. Ber. Ak. Wien, lx., Dec., 1869. Sorby. ' On the microscopical structure of crystals, indicating the origin of minerals and rocks. Q. J. Geol. Soc., xiv., 453, 1858, (and many other papers). Sorby and Butler. On the structure of rubies, sapphires, diamonds, and some other minerals Proc. Roy. Soc., No. 109, 1869. Vogelsang. Die Krystalliten. 175 pp., Bonn, 1875. Vogelsang and Oeusler. Ueber die Natur der Fliissigkeitseinschlusse in gewissen Minera- lion. Pogg. Ann., cxxxvii., 56, 1869 (ibid. p. 257). Zirkel. Die microscopische Beschaff enheit der Mineralien und Gesteine. 502 pp. , Leipzig, 1873. CRYSTALLINE AGGREGATES. The greater part of the specimens or masses of minerals that occur, may be described as aggregations of imperfect crystals. Even those whose structure appears the most purely impalpable, and the most destitute in- ternally of anything like crystallization, are probably composed of crystal- line grains. Under the above head, consequently, are included all the remaining varieties of structure in the mineral kingdom. The individuals composing imperfectly crystallized individuals, may be: 1. Columns, or fibres, in which case the structure is columnar. 2. Thin lamina!, producing a lamellar structure. 3. Grains, constituting a granular structure. 1. Columnar Structure. A mineral possesses a columnar structure when it is made up of slender columns or fibres. There are the following varieties of the columnar struc ture : Fibrous ; when the columns or fibres are parallel. Ex. gypsum, asbeatua Fibrous minerals have often a silky lustre. 112 CRYSTALLOGRAPHY. Reticulated : when the fibres or columns cross in various directions, and produce an appearance having some resemblance to a net. Stellated or stellular: when they radiate from a centre in all directions, and produce star-like forms. Ex. stilbite, wavellite. Radiated, divergent : when the crystals radiate from a centre, without producing stellar forms. Ex. quartz, stibnite. 2. Lamellar Structure. The structure of a mineral is lamellar when it consists of plates or leaves. The laminae may be curved or straight, and thus give rise to the curved lamellar, and straight lamellar structure. Ex. wollastonite (tabular spar), some varieties of gypsum, talc, etc. When the laminae are thin and easily separable, the structure is said to be foliaceous. Mica is a striking example, and the term micaceous is often used to describe this kind of structure. 3. Granular Structure. The particles in a granular structure differ much in size. When coarse, the mineral is described as coarsely granular ; when fine, finely granular and if not distinguishable by the naked eye, the structure is termed im- palpable. Examples of the first may be observed in granular crystalline limestone, sometimes called saccharoidal ; of the second, in some varieties of hematite ; of the last, in chalcedony, opal, and other species. The above terms are indefinite, but from necessity, as there is every degree of fineness of structure in the mineral species, from perfectly im- palpable, through all possible shades, to the coarsest granular. The term phanero-crystdlline has been used for varieties in which the grains are dis- tinct, and crypto-crystalline, for those in which they are not discernible. Granular minerals, when easily crumbled in the fingers, are said to be friable. 4. Imitative /Shapes. Reniform : kidney shape. The structure may be radiating or concentric, Botryoidal: consisting of a group of rounded prominences. The name is derived from the Greek fiorpvs, a bunch of grapes. Ex. limonite, chal- cedony. Mammillary : resembling the botryoidal, but composed of larger prom- inences. Globular : spherical or nearly so ; the globules may consist of radiating fibres or concentric coats. When attached, as they usually are, to the sur- face of a rock, they are described as implanted globules. Nodular : in tuberose forms, or having irregular protuberances over the surface. Amygdaloidal ; almond-shaped, applied usually to a greenstone contain- ing almond-shaped or sub-globular nodules. PSEUDOMOKPHOUS CRYSTALS. 113 Coralloidal : like coral, or consisting of interlaced flexuous branchings of a white color, as in some aragonite. Dendritic : branching tree-like. Mossy : like moss in form or appearance. Filiform or Capillary : very slender and long, like a thread or hair ; consists ordinarily of a succession of mimite crystals. Acicular : slender and rigid like a needle. Reticulated : net-like. Drusy : closely covered with minute implanted crystals. Stalactitic : when the mineral occurs in pendant columns, cylinders, or elongated cones. Stalactites are produced by the percolation of water, holding mineral matter in solution, through the rocky roofs of caverns. The evaporation of the water produces a deposit of the mineral matter, and gradually forms a long pendant cylinder or cone. The internal structure may be imper- fectly crystalline and granular, or may consist of fibres radiating from the central column, or there may be a broad cross-cleavage. Common stalactites consist of calcium carbonate. Chalcedony, gibbsite, brown iron ore, and many other species, also present Stalactitic forms. The term amorphous is used when a mineral has not only no crystalline form or imitative shape, but also does not polarize the light even in its minute particles, and thus appears to be destitute wholly of a crystalline structure internally, as most opal. Such a structure is also called colloid or jelly- like, from the Greek for glue. Whether there is a total absence of crystal- line structure in the molecules is a debated point. The word is from a, privative, and popfj)?), shape. PSEUDOMORPHOUS CRYSTALS. Every true mineral species has, when crystallized, a form peculiar to itself ; occasionally, however, crystals are found that have the form, both as to angles and general habit, of a certain species, and yet differ from it entirely in chemical composition. Moreover it is often seen that, though in outward form complete crystals, in internal structure they are granular, or waxy, and have no regular cleavage. Such crystals are called pseudomorphs, and their existence is explained by the assumption, often admitting of direct proof, that the original min- eral has been changed into the new compound, or has disappeared through Borne agency, and its place been taken by another chemical compound to which the form does not belong. Pseudomorphs have been classed under several heads. 1. Pseudomorphs by substitution. 2. Pseudomorphs by simple deposition, (a) incrustation or (b) in/Ut^a* tion. 3. Pseudomorphs by alteration and these may be altered a) without a change of composition, by paramorphism ; b) by the loss of an ingredient ; v by the assumption of a foreign substance ; by a partial exchange of constituents. 8 114 CRYSTALLOGRAPHY. 1. The first class of pseudomorphs, by substitution, embrace those cases where there has been a gradual removal of the original material and a corresponding and simultaneous replacement of it by another, without, however, any chemical reaction between the two. A common example of this is a piece of fossilized wood, where the original fibre has been replaced entirely by silica. The first step in the process was the filling of all the pores and cavities by the silica in solution, and then as the woody fibre by gradual decomposition disappeared, the silica further took its place. Other examples are quartz after fluorite, calcite, and many other species, cassiterite after orthoclase, etc. 2. Pseudomorphs by incrustation, form a less important class. Such are the crusts of quartz formed over fluorite. In most cases the removal of the original mineral has gone on simultaneously with the deposit of the second, so that the resulting pseudomorph is properly one of substitution. In pseudomorphs by infiltration, a cavity made by the removal of a crystal has been filled by another mineral. 3. The third class of pseudomorphs, by alteration* include a considerable proportion of the observed cases, of which the number is very large. Con- clusive evidence of the change which has gone on is often furnished by a kernel of the original mineral in the centre of the altered crystal ; e.g., a kernel of cuprite in a pseudomorphous octahedron of malachite ; also of chrysolite in a pseudomorphous crystal of serpentine ; of corundum in fibrolite, or spinel (Genth). (a) An example of paramorphism is furnished by the change of aragonite to calcite at a certain temperature ; also the paramorphs of rutile after arkansite from Magnet Cove. (V) An example of the pseudomorphs in which alteration is accompanied by a loss of ingredients is furnished by crystals of limonite in the form of siderite, the carbonic acid having been removed ; so also calcite after gay-lussite ; native copper after cuprite. (c) In the change of cuprite to malachite, e.g., the familiar crystals from Chessy, France, an instance is afforded of the assumption of an ingredient, viz., carbonic acid. Pseudomorphs of gypsum after anhydrite occur, where there has been an assumption of water. (d) A partial exchange of constituents, in other words, a loss of one and gain of another, takes place in the change of feldspar to kaolin, in which the potash silicate disappears and water is taken up ; pseudomorphs of chlorite after garnet, pyromorphite after galenite, are other examples. The chemical processes involved in such changes open a wide field for investigation, in which Bischof, Delesse and others have done much. SECTION L SUPPLEMENTARY CHAPTER. IMPROVEMENTS IN THE INSTRUMENTS FOR THE MEASUREMENT OF THE ANGLES OF CRYSTALS (sec pp. 83-87). Reflecting Goniometer. A form of reflecting goniometer, well adapted for accurate measurements, and at the same time thoroughly practical, is shown in f. 372A. It is made on the Babinet type, with a horizontal graduated circle; the instruments of the Mitscherlich type, alluded to on p. 86, having a vertical circle. The horizontal circle has many advantages, especially when it is desired to measure the angles of large crystals or those which are 372A. attached to a large piece of rock. This particular form of instrument here figured is made^by K. Fuess,* in Berlin (Alte Jacobstrasse 108), and has * The author is indebted to R. Fuess for the electrotypes from which this and the fol- lowing figures (372A, B, c, D, also, f. 412c, D, E, F, H, K, L}have been primtcd. 115 116 IMPROVEMENTS IN GONIOMETERS. many improvements suggested by WEBSKY (Zeitschr. Kryst.. iv., 545. 1880. See also Liebisch, Bericht iiber die wissenschaftlichen Instruments auf der Berliner Gewerbeausstellung im Jab re 1879, pp. 330-332). The instrument stands on a tripod with leveling screws. The central axis, 0, has within it a hollow axis, h, with which turns the plate, d, carry- ing the verniers and also the observing telescope, the upright support of which is shown at B. Within b is a second hollow axis, e, which carries the graduated circle, /, above, and which is turned by the screw-head, g ; the tangent screw, a, serves as a fine adjustment for the observing telescope, B, the screw, c, being for this purpose raised so as to bind b and e together. The tangent screw, J3, is a fine adjustment for the graduated circle. Again, within e is the third axis, h, turned by the screw-head, i, and within It is the central rod, s, which carries the support for the crystal, with the adjusting and centering contrivances mentioned below. The rod, s, can be raised or lowered by the screw, h, so as to bring the crystal to the proper height, that is up to the axis of the telescope ; when this has been accomplished, the clamp at p, turned by a set-key, binds s to the axis, li. The movement of h can take place independently of g, but after the crystal is ready for measurement these two axes are bound together by the set-screw, I. The signal telescope is supported at C, firmly attached to one of the legs of the tripod. The crys- tal is mounted on the plate, u, with wax, the plate is clamped by the screw, v. The centering apparatus consists of two slides at right angles to each other (one of these is shown in the figure) and the screw, a, which works it ; the end of the other corresponding screw is seen at a'. The adjusting arrangement consists of two cylindrical sections, one of them, r, shown in the figure, the other is at r 1 '; the cylinders have a common centre. The circle is graduated to degrees and quarter degrees, and the vernier gives the readings to 30", but by estimate they can be obtained to 10". The signals provided are four in number, each in its own tube, to be inserted behind the collimator lens ; these are : (1) the ordinary telescope with the hair cross, to be used in the case of the most perfect planes ; (2) the commonly used signal,* proposed by Websky, consisting of two small opaque circles, whose distance apart can be adjusted by a screw between them ; the light passing between these circles enters the tube in a form resembling a double concave lens ; also (3) an adjustable slit ; and, finally, (4) a tube with a single round open- ing, very small. There are four observing telescopes of different angular breadth of field and magnifying power, and hence suitable for planes varying in size and in degree of polish. A Nicol prism is also added. The methods to be employed, both in making the preliminary adjust- ments required by every instrument before it can be used, and in the actual measurement of the angles of crystals, have been described by Websky (1. c.) with a fullness and clearness which leaves nothing to be desired, and refer- ence must be here made to this memoir. Microscope- Goniometer of Hirschwald. For the measurement of the angles of crystals whose planes are destitute of polish, HIRSCHWALD has devised a "microscope-goniometer" (Jahrb. Min., 1879, 301, 539; 1880, i., 156. See also Liebisch, 1. c., pp. 336, 377) ; the actual construction has been made by Fuess. The instrument consists of a Wollaston goniometer with a center- ing telescope and a vertical microscope. The principle upon which the use of the instrument is based is this : that a plane seen through a microscope * See Websky, Z. Kryst., iii., 241. CONTACT-LEVER GONIOMETER OF FUESS. ir will be in focus over its entire extent only when the plane is exactly at right angles to the axis of the microscope. The microscope stands vertically above the crystal, and is supported on a double slide, which allows of its being moved parallel and perpendicular to the axis of the goniometer, so that it is possible to see successively every portion of a crystal face fastened to the goniometer, and at the proper focal distance. The slide perpendicular to the axis of the goniometer carries a vernier, so that the position of the microscope can be measured on the fixed scale to a half millimeter. The micrometer screw of the microscope is arranged so that the raising or lowering of the microscope can be measured to 0-004 mm. The spider line in the eye-piece, parallel to the axis of rotation of the goniometer, is so adjusted that when the slide just mentioned stands at the zero of its scale, it lies exactly in the vertical plane through the axis. The horizontal centering telescope is placed opposite the crystal support, and moves on a slide parallel to the axis of the graduated circle. Its spider lines are so adjusted that their centre exactly coincides with this axis. The apparatus for centering and adjusting the crystal consists of a vertical disk allowing of motion in any direction perpen- dicular to the axis of rotation, and a spherical segment moved by four arms (Petzval support). In use the edge of the two planes to be measured is brought by means of the spider line of the microscope parallel to the axis of rotation of the goniometer, and there centered, by means of the telescope, so that as the crystal is turned this edge remains in the centre of the spider line of the centering telescope ; then the two planes which form this edge are, by successive adjustments by help of the microscope, brought each successively into an exactly horizontal position as the circle is revolved. The angle (normal angle) between the two planes is obtained in the usual manner. Hirschwald calculates that, with a sufficiently delicate arrangement of lenses, for planes whose width is 5 mm., the theoretical error of measurement is 2' 40"; for those with a width of 10 mm., the error is only 1'. The improved sup- port for the crystal is so arranged that when the edge is exactly adjusted and one of the two planes carefully placed with the microscope, the second plane must be for its whole extent in the proper position as soon as this is true for a single point of the plane. Contact-lever Goni- ometer of Fucss. An- other form of goniom- eter has been invented by FUESS (see Liebisch, 1. c., pp. 337-339) which aims to accom- plish the same end as that of Hirschwald the exact measurement of the angle between two unpolished surfaces but in this case the adjustment is accom- plished by mechanical means. The essential arrangement is shown in f. 372s, 372c. It consists of a Wollaston goniometer, G, supported upcn a perfectly even unpolished 118 IMPROVEMENTS IX GONIOMETERS. 372c. L.,.,. .^^ LJ glass plate, A. The contact-lever is carried by B, which rests on the glass plate by two pegs, o, and by the screw, n, with a graduated head turn- ing in connection with the index, y. Two arms, F F. go down from B, carrying the nut in which the screw, r, turns ; this screw moves B in a direction at right angles to the axis of the goniometer. The arm, D, contains the nut for the adjusting screw, m (similar to n), which belongs immediately to the lever system. On the arm C is attached the knife edge, I, which meets the edge, c, fastened to the arm, i ; this arm, /, turns about , and is supported by the screw, m. The adjustable ball, #. sup- ported on t, is to be placed so that the ivory index rests with the least pos- sible pressure on the crystal-face at K (see also f. 372c). The contact- lever, E, whose longer arm marks on the scale, 8, lies between I and c ; its head, d, is so to be adjusted that the lever resting on the lower edge, c, has a slight excess of weight on the side of the goniometer, so that it touches both edges. A perceptible play of the long arm corresponds to a raising or lower- ing of the ivory index of 0-0005 mm. If the plane has a width of 1 mm., the degree of accuracy attainable is theoretically 2'. In the preliminary centering and adjusting the work is facilitated by the arrangement shown in f. 372D. It consists of a plate, p, 372D which rests on A by the three set-screws, s. Two arms, with set-screws, t, resting on the side of the supporting plate, make possible, similar to r, a movement parallel to this side. An index finger, I, is supported above the plate, p. The screws, s and t, are now set so that the sharp edge of I is exactly in the prolongation of the axis of rotation of the goniometer, which is necessarily parallel to the upper and side surfaces of the supporting plate. By the help of this arrangement, the approximate centering and adjusting of the crystal-edge can be readily accomplished, and also the parallelism between the crystal-face and the supporting plate be proved. Measurement of the Angles of microscopic Crystals. BERTRAKD (C. E., Ixxxv., 1175, 1877 ; Bull. Soc. Min., i., 22, 96, 1878) has described a method for obtaining the interfacial angles of microscopic crystals, which may be briefly alluded to here. It is based on the geometrical principle that if the plane angles are known which the projections of a plane make with three perpendicular co-ordinate axes, the angular inclination of the plane to the three axes can be calculated. The crystal to be measured is fastened on a small cube of glass held in a pincer arrangement, on a secondary microscope stage ; this stage is, like the principal stage below it, movable about a ver- tical axis, and besides has by means of screws a motion in two perpendicular directions in a horizontal plane. The method of obtaining the desired angles is very ingenious, but too complex to allow of explanation here; reference must "be made to the original paper. With crystals of from 1-20 to 1-30 mm., Bertrand obtained results accurate within 6', and he states that the method can be extended to crystals which have a magnitude of only 1-100 mm. SECTION IL PHYSICAL OHAEAOTEES OF MLN"EEALS. THE physical characters of minerals are those which relate : L, tc Cohesion and Elasticity, that is : cleavage and fracture, hardness, and ten- acity ; IL, to the Mass and Volume, the specific gravity ; III., to Light, the optical properties of crystals ; also color, lustre, etc. ; IV., to Heat ; V., to Electricity and Magnetism ; VI., to the action on the Senses, aa taste, feel, etc. I. COHESION AND ELASTICITY.* By cohesion is understood the attraction existing between the molecules of a body, in consequence of which they offer resistance to a force tend- ing to separate them, as in breaking or scratching. This principle leads to some of the most universally important physical characters of minerals, cleavage, fracture, and hardness. Elasticity, on the other hand, is the force which tends to bring the molecules of a body back into their original position, from which they have been disturbed. Upon elasticity depends, for the most part, the decree of tenacity possessed by different minerals. A. CLEAVAGE AND FKACTURE. 1. Cleavage. Most crystallized minerals have certain directions in which their cohesive power is weakest, and in which they consequently, yield most readily to an exterior force. This tendency to break in the direction of certain planes is called cleavage, and being most intimately connected with the crystalline form it has already been necessary to define it, and to mention some of its most important features (p. 2). Cleavage differs (a) according to the ease with which it is obtained, and (b) accord- ing to its direction, crystallographically determined. (a) Cleavage is called perfect or eminent when it is obtained with great ease, affording smooth, lustrous surfaces, as in mica, topaz, calcite. Inferior degrees of cleavage are spoken of as distinct, indistinct or imperfect, inter- rupted, in traces, difficult. These terms are sufficiently intelligible without further explanation. It may be noticed that the cleavage of a species ia sometimes better developed in some of its varieties than in others. (b) Cleavage is also named according to the direction, crystallographically defined, which it takes in a species. When parallel to the basal section (O) it is called basal, as in topaz; parallel to the prism, as in amphibole, it is called prismatic ; also macrodiagonal, orthodiagonal, etc., when parallel to the several diametral sections ; parallel to the faces of the cube, octa- * SP.P. fnrthpr rvn n 172 120 PHYSICAL CHARACTERS OF MINERALS. hedron, dodecahedron, or rhombohedron, it is called cubic, as galenite; octahedral, as fluorite ; dodecahedral, as sphalerite ; rhombohedral, as calcite. Intimately connected with the cleavage of crystallized minerals are the divisional planes in- vestigated by Reusch (see Literature, p. 122). He has found that by pressure, or by a sudden blow, divisional planes are in many cases produced which are analogous to the cleavage planes. The first he calls Gleitflachen, or planes in which a sliding of the molecules upon each other takes place. Thus, for example, if two opposite dodecahedral edges of a cubic cleavage mass of rock-salt are regularly filed away, and the mass then subjected to pressure in this direction, a Gleitflache is obtained parallel to the dodecahedral face. The figures, on the other hand, obtained by a blow on a rounded steel point, placed perpen- dicular to the natural or cleavage face of a crystal, are called by him. fracture-figures (Schlag- fi'^uren). The divisional-planes in this case appear as cracks diverging from the point where the blow has been made. For instance, on a cubic face of rock-salt two planes, forming a rectangular cross, are obtained ; on biaxial mica, a six-rayed (sometimes three rayed) stai results from the blow, one ray of which is always parallel to the brachydiagoual axis of the prism. 2. Fracture. The term fracture is used to define the form or kind of surface obtained by breaking in a direction other than that of the cleavage in crystallized minerals, and in any direction in massive minerals. When the cleavage is highly perfect in several directions, as the cubic cleavage of galenite, fracture is often not readily obtainable. Fracture is defined as : (a) Conchoidal ; when a mineral breaks with curved concavities, more or less deep. It is so called from the resemblance of the concavity to the valve of a shell, from concha, a shell ; flint. (b) Even when the surface of fracture, though rough, with numerous small elevations and depressions, still approximates to a plane surface. (c) Uneven, / when the surface is rough and entirely irregular. (d) Hackley ; when the elevations are sharp or jagged ; broken iron. Other terms also employed are earthy, splintery, etc. B. HARDNESS. By the hardness of a mineral is understood the resistance which it offers to abrasion. The degree of hardness is determined by observing the ease or difficulty with which one mineral is scratched by another, or by a file or knife. In minerals there are all grades of hardness, from that of a substance impressible by the finger-nail to that of the diamond. To give precision to the use of this character, a scale of hardness was introduced by MOIIS. It is as follows : 1. Talc; common laminated light-green variety. 2. Gypsum ; a crystallized variety. 3. Calcite transparent variety. 4. Fluorite ; crystalline variety. 5. Apatite; transparent variety. (5.5. Scapolite; crystalline variety.) 6. Feldspar (orthoclase) ; white cleavable variety. 7. Quartz; transparent. HAKDNESS TENACITY. 121 8. Topaz / transparent. 9. SwppTwre: cleavable varieties. 10. jDiamond. If the mineral under trial is scratched by the file or knife as easily as apatite, its hardness is called 5 ; if a little more easily than apatite and not so readily as fluorite, its hardness is called 4.5, etc. For minerals as hard or harder than quartz, the file will not answer, and the relative hard- ness is determined by finding by experiment whether the given mineral will scratch, or can be scratched by, the successive minerals in the scale. It need hardly be added that great accuracy is not attainable by the above methods, though, indeed, for all mineralogical purposes exactness is quite unnecessary. The interval between 2 and 3, and 5 and 6, in the scale of Mohs, being a little greater than between the other numbers, Breithaupt proposed a Bcale of twelve minerals ; but the scale of Mohs is now universally accepted. Accurate determinations of the hardness of minerals have been made by FranJcenheim, Franz, Grailich and Pekarek, and others (see Literature, p. 122), with an instrument called a sderometer. The mineral is placed on a movable carriage with the surface to be experimented upon horizontal ; this is brought in contact with a steel point (or diamond-point), fixed on a support above; the weight is then determined which is just sufficient to move the carriage and produce a scratch on the surface of the mineral. By means of such an instrument the hardness of the different faces of a given crystal has been determined in a variety of cases. It has been found that different planes of a crystal differ in hardness, and the same plane dif- fers as it is scratched in different directions. In general, the hardest plane is that which is intersected by the plane of most complete cleavage. And of a single plane, which is intersected by cleavage planes, the direction perpendicular to the cleavage direction is the softer, those parallel to it the harder. This subject has been recently investigated by Exner (p. 122), who has given the form of the curves of hardness for the different planes of many crystals. These curves are obtained as follows : the least weight required to scratch a crystalline surface in different directions, for each 10 or 15, from to 180, is determined with the sclerometer ; these directions are laid off as radii from a centre, and the length of each is made proportional to the weight fixed by experiment, that is, to the hardness thus determined ; the line connecting the extremities of these radii is the curve of hardness for the given plane. C. TENACITY. Solid minerals may be either brittle, sectile, malleable, flexible, or elastic. (a) Brittle / when parts of a mineral separate in powder or -grains on attempting to cut it ; calcite. (b) Sectile ; when pieces may be cut off with a knife without falling to powder, but still the mineral pulverizes under a hammer. This character is intermediate between brittle and malleable ; gypsum. (c) Malleable ; when slices may be cut off, and these slices flattened out under a hammer ; native gold, native silver. (d) Flexible ; when the mineral will bend, and remain bent after the bending force is removed ; talc. 122 PHYSICAL CHARACTERS CF MINERALS. (e) Elastic / when after being bent, it will spring back to its original position ; mica. The elasticity of crystallized minerals is a subject of theoretical rather than practical importance. The subject has been acoustically investigated by Savart with very interesting results. Reference may also be made to the investigations of Neumann, and later those of Voigt and Groth. The most important principle established by these researches is, as stated by Groth, that in crystals the elasticity (coefficient of elasticity) differs in different directions, but is the same in all directions which are crystallo- graphically identical ; hence he gives as the definition of a crystal, a solid in which the elasticity is a function of the direction. Intimately connected with the general subjects here considered, of cohesion in relation to minerals, are the figures produced by etching on crystalline faces (Aetzfiguren, Germ.), investigated by Leydolt, and later by Baumhauer, Exner, and others. This method of investi- gation is of high importance as revealing the molecular structure of the crystal ; reference, however, must be made to the original memoirs, whose titles are given below, for the full discussion of the subject. The etching is performed mostly by solvents, as water in some cases, more generally the ordinary mineral acids, or caustic alkalies, also by steam and hydrofluoric acid; the latter is especially powerful in its action. The figures produced are in the majority of cases angular depressions, such as low triangular, or quadrilateral pyramids, whose outlines run parallel to some of the crystalline edges. In some cases the planes produced can be referred to occur- ring crystallographic planes. They appear alike on similar planes of crystals, and hence serve to distinguish different forms, perhaps in appearance identical, as the two sets of planes in the ordinary double pyramid of quartz ; so, too, they reveal the compound twinning struc- ture common on some crystals, as quartz (p. 89) and aragonite. Analogous to the etching-figures are the figures produced on the faces of some crystals by the loss of water (Verwitterungsfiguren, Germ,) This subject has been investigated by Pape (see below). LITERATURE. Cohesion / Hardness. FrankenJieim. De Crystallorum Cohaesione, 1829 ; also in Baumgarfcner's Zeitschrift fiii Physik, ix., 94, 194. 1831. Frankenheim. Ueber die Anordnung der Molecule in Krystallen ; Pogg. xcvii., 337. 1836. Sohncke. Ueber die Cohasion des Steinsalzes in krystallographisch verschiedenen Rich- tungen; Pogg. cxxxvii., 177. 1809. Pranz. Ueber die Hiirte der Mineralien und ein neues Verfahren dieselbe zu rnessen ; Pogg. Ixxx., 37. 1850. Grailwh und Pekdrek. Ber. Ak. Wien, xiii., 410. 1854. Exner. Ueber die Harte der Krystallflachen ; 166 pp. Wien, 1873. Elasticity. Savart. Pogg. Ann., xvi., 206. Neumann. Pogg. Ann., xxxi., 177. Voigt. Pogg. Ann. Erg. Bd., vii, i, 177, 1875. Groth. Pogg. Ann., clvii., 115, 787. 1876. Bauer. Untersuchung iiber den Glimmer und verwandte Minerale ; Pogg. cxxxviii., 337, Reusch. Ueber die Kornerprobe am Steinsalz u. Kalkspath. Pogg. cxxxii., 441, 1867; am zwei-axigen Glimmer, Pogg. Ann. cxxxvi, 430, 632 ; am krystallirten Gyps, ibid., p. 135. SPECIFIC GRAVITY 123 Baumhauer. Ueber Aetzfiguren und die Erscheinungen des Asteiismus an Krystallen ; Pogg. Ann. cxxxviii., 163 ; cxxxix., 349 ; cxL, 271 ; cxlv., 459 ; sliii., 621 ; Ber. Ak. Miinchen, Darnell. Quarterly Journal of Science, i., 24. 1816. Exner. An Losungsfiguren in Krystallen; Ber. Ak. Wien, Ixix., 6. 1874. Hirschwald. Aetzfiguren an Quarz-Krystallen ; Pogg. cxxxvii. , 548. 1869. Knop. Jahrb. Min., 1872, 785. Ley dolt. Ueber Aetzungen ; Ber. Ak. Wien, xv., 58; xix., 10. Pape. Ueber das Verwitterungs-Ellipsoid wasserhaltiger Krysteille; Pogg. cxxiv., 339: CKXV. , 513. 1865. II. SPECIFIC GKAVITY.* The specific gravity of a mineral is its weight compared with that of an- other substance of equal volume, whose gravity is taken at unity. In the case of solids or liquids, this comparison is usually made with water. If a cubic inch of any mineral weighs twice as much as a cubic inch of water (water being the unit), its specific gravity is 2, if three times as much, its specific gravity is 3, etc. The direct comparison by weight of a certain volume of water with an equal volume of a given solid is not often practicable. By making use, however, of a familiar principle in hydrostatics, viz., that the weight lost by a solid immersed in water is equal to the weight of an equal volume of water, that is of the volume of water it displaces, the determination of the specific gravity becomes a very simple process. The weight of the solid out of water (w) is determined by weighing in the usual manner ; then the weight in water is found (w'), when the loss by immersion or the difference of the two weights (w w') is the weight of a volume of water equal to that of the solid ; finally the quotient of the first weight (w) by that of the equal volume of water as determined (w w') is the specific gravity (G). Hence, For example, the weight of a fragment of quartz is found to be 4.534 grams. Its weight in water = 2.817 grains, and therefore the loss oi weight, or the weight of an equal volume of water = 1.717. Consequent!} 4 534 the specific gravity is equal to T-^T^J or 2.641. The ordinary method for obtaining the specific gravity of firm, solid minerals is first to weigh the specimen accurately on a good chemical bal- ance, then suspend it from one pan of the balance by a horse-hair, silk thread, or better still by a fine platinum wire, in a glass of water con- veniently placed beneath. The platinum wire may be wound around the specimen, or where the latter is small it may be made at one end into a little spiral support. While thus suspended, the weight is again taken with the same care as before. The water employed for this purpose should be distilled, to free it from all foreign substances. Since the density of water varies with its tempera- ture, a particular temperature has to be selected for these experiments, in * SPP fnrthpr nn r 1 73 124 PHYSICAL CHARACTERS OF MINERALS. order to obtain uniform results: 60 F. is the most convenient, and has been generally adopted. But the temperature of the maximum density of water, 39.2 F. (4 C.), has been recommended as preferable. For minerals soluble in water some other liquid, as alcohol, benzene, etc;., must be em- ployed, whose specific gravity (g) is accurately known ; from the com- parison with it, the specinc gravity (G) of the mineral as referred to water is determined, as by the formula : G= w w* A very convenient form of balance is the spiral balance of Jolly, where the weight is mea- Bured by the torsion of a spiral brass wire. The readings, which give the weight of the min- eral in and out of water, are obtained by observing the coincidence of the index with its image reflected in the mirror on which the graduation is made. A form of balance in which weights are also dispensed with, the specinc gravity being read off from a scale without calculation, has recently been described by Parish (Am. J. Sci., III., x., 352). "Where great accuracy is not required, it can be very conveniently used. If the mineral is not solid, but pulverulent or porous, it is best to reduce it to a powder and weigh it in a little glass bottle (f. 373) 373 called a pygnometer. This bottle has a stopper which fits tightly and ends in a tube with a very fine opening. The bottle is filled with distilled water, the stopper in- serted, and the overflowing water carefully removed with a soft cloth. It is now weighed, and also the mineral whose density is to be determined. The stopper is then removed and the mineral in powder or in small fragments inserted, with care, so as not to introduce air-bubbles. The water which overflows on replacing the stopper is the amount of water displaced by the mineral. The weight of the pygnometer with the enclosed mineral is determined, and the weight of the water lost is obviously the difference between this last weight and that of the bottle and mineral together, as first determined. The specific gravity of the mineral is equal to its weight alone divided by the weight of the equal volume of water thus determined. Where this method is followed with sufficient care, especially avoiding any change of temperature in the water, the results are quite accurate. Other methods of determining the specific gravity will be found described in the literature notices which follow. It has been shown by Rose that chemical precipitates have uniformly a higher density than belongs to the same substance in a less finely divided state. This increase of density also characterizes, though to a less extent, a mineral in a fine state of mechanical subdivision. This is explained by the condensation of the water on the surface of the powder. It may also be mentioned that the density of many substances is altered by fusion. The same mineral in different states of molecular aggregation may differ somewhat in density. Furthermore, minerals having the same chemical composition have sometimes different densities corresponding Co the different crystalline forms in which they appear (see p. 199). LIGHT. 125 For all minerals in a state of average purity the specific gravity is one of the most important and constant characteristics, as urged especially by Breithaupt. Every chemical analysis of a mineral should be accompanied by a careful determination of its density. Practical suggestions. The fragment taken should not be too large, say from two to five grams for ordinary cases, varying somewhat with the density of the mineral. The substance must be free from impurities, internal and external, and not porous. Care must be taken to exclude air-bubbles, and it will often be found well to moisten the surface of the specimen before inserting it in the water, and sometimes boiling is necessary to free it from air. If it absorbs water this latter process must be allowed to go on till the substance is fully satu- rated. No accurate determinations can be made unless the changes of temperature are rigorously excluded and the actual temperature noted. In a mechanical mixture of two constituents in known proportions, when the specific gravity of the whole and of one are known, that of the other can be readily obtained. This method is often important in the study of rocks. LITERATURE. SPECIFIC GRAVITY. Beudant. Pogg. Ann., xiv., 474. 1828. Jenzsch. Ueberdie Bestimmung der specifischen Gewichte ; Pogg. xcix., 151. 1856. Jotty. Ber. Ak. Miinchen, 1864, 162. Gadoliti. Eine einfache Methode zur Bestimmung des specifischen Gewichtes der Minera- lien; Pogg., cvi., 213. 1859. . G. Ilosc. Ueber die Fehler, welche in der Bestimmung des specifischen Gewichtes del Korper entstehen, wenn man dieselben im Zustande der feinsten Vertheilung wagt ; Pogg. Ixxiii., Ixxv , 403. 1848. Scheerer. Ueber die Bestimmung des specifischen Gewichtes von Mineralien ; Pogg. Ann. , Ixvii., 120, 1846. Journ. pr. Ch., xxiv., 139. kchiff. Ann. Ch. Pharm., cviii., 29. 1858. Schroder. Neue Beitrage zur Volumentheorie ; Pogg. cvi., 226. 1859. ; Die Volumconstitution einiger Mineralien ; Jahrb. Min , 1873, 561, 932 ; 1874, 399, etc. Tschermak. Ber. Ak. Wien, 292, 1863. Websky. Die Mineralien nach den fur das specifische Gewicht derselben angenommenen and gefundenen Werthen ; 170 pp. Breslau, 1868. III. LIGHT.* Before considering the distinguishing optical properties of crystals of the different systems, it is desirable to review briefly some of the more im- portant principles of optics upon which the phenomena in question depend. Nature of light. In accordance with the undulatory theory of Huy- ghens, as further developed by Young and Fresnel, light is conceived to consist in the vibrations, transverse to the direction of propagation, of the particles of imponderable, elastic ether, which it is assumed pervades all space as well as all material bodies. These vibrations are propagated with great velocity in straight lines and in all directions from the luminous point, and the sensation which they produce on the nerves of the eye is called light. The nature of the vibrations will be understood from f. 374. If AE represents the direction of propagation of the light-ray, each particle of ether vibrates at right angles to this as a line of equilibrium. The vibra- 126 PHYSICAL CHARACTERS OF MINERALS. tiou of the first particle induces a similar movement in the adjacent par- ticle ; this is communicated to the next, and so on. The particles vibrate successively from the line AB to a distance corresponding to bb' ', called the amplitude of the vibration, then return to b and pass on to ", and so on. Thus at a given instant there are particles occupying all positions, from that of the extreme distance ', or for the second case supposed. The velocity of this ray is then variable in a corresponding manner. The wave-suri'ace of the extraordinary ray is an ellipsoid of rotation. Moreover it ordinarily does not remain in the plane of incidence. Two cases are now possible : the index (&>) of the ordinary ray may be (1) greater than that of the extraordinary ray (e), in which case the velocity 01 the light in the direction of the vertical axis is less than that in any othei direction ; or (2) a> may be less than e, and in this case the velocity of pro- Eagation for the light has its maximum parallel to the vertical axis. The ormer are called negative, the latter positive crystals. The fact alluded to here should be noted that the value of the refractive index is inversely proportional to the velocity of the light, or elasticity of the ether, in the given direction. Negative crystals ; Wave-surface. Forcalcite o> =1/654:, e = 1-483, it is hence one of the class of negative crystals. The former value (o>) belongs to the ray vibrating at right angles to the vertical axis, and the latter value (e) to the ray with vibrations parallel to the axis. As has been stated, the refractive index for the extraordinary ray increases from 1.483 to 1.654, as the ray becomes more and more nearly parallel to the vertical axis. Fig. 387 illus- trates graphically the relation between the two indices of refraction, and the correspond- ing velocities of the rays ; ab represents the direction of the vertical axis, that is, the optic Also ma, mb represent the velocity 887 axis. of the light parallel to this axis, correspond- ing to the greater index of refraction (1'654). The circle described with this radius will represent the constant velocity of the ordi- nary ray in any direction whatever. Let further md, me represent the velocity of the extraordinary ray passing at right angles to the axis, hence corresponding to the smaller index :>f refraction (1-483). The ellipse, whose major and minor axes are cd and ab, will express the law in accordance with which the velocity of the extraordinary ray varies, viz., greatest in the direction md, least in the direction ab in which it coincides with the ordinary ray. For any inter- mediate direction, hgm, the velocity will be expressed by the length of the 'iue, km. Now let this figure be revolved about the axis ab ; there will be geneiated 138 PHYSICAL CHARACTERS OF MINERALS. a circle within an oblate ellipsoid of rotation (f. 388). The surface of the sphere is the wave-surface of the ordinary ray, 388 and that of the ellipsoid of the extraordinary ray ; the line of their intersection is the optic axis. In f. 377, p. 147, the ray of light is shown divided into two by the piece of calcite ; of these, bd, which is the more refracted, is the ordinary ray, and J = 1'548, e 1*558. The index of refraction for the ordinary ray (o>) is less than that of the extraordinary ray (e) ; quartz hence belongs to the class of positive crystals. The value of e (1*558) for the extraordinary ray corresponds to the direction of the ray at right angles to the vertical axis, when its vibrations are parallel to this axis. As the direction of the ray changes and becomes more and more nearly par- allel to the axis, the value of its index of re- fraction decreases, and when it is parallel to the latter, it has the value 1-548. The extraordin- ary ray then coincides with the ordinary, and there is no double refraction; this is, as be- fore, the line of the optic axis. The law for both rays can be represented graphically in the same way as for negative crystals. In f. 389, amb is the direction of the optic axis; let ina, tnb represent the velocity of the ordin- ary ray, which corresponds to the least re- fractive index (1-548), the circle afbe will express the law for this ray, viz., the velocity the same in every direction. Moreover, let md, mo represent the velocity of the extraor- dinary ray, at right angles to the axis, which corresponds to the maximum refractive index (1'558) ; the ellipse, adbc, will express the law for velocity of the extraordinary ray, viz., least in the direction md, and greatest in the direction ab, when it is equal to that of the ordinary ray, and varying uniformly between these limits. If the figure be revolved as before, thore will be generated a sphere, whose surface is the wave-surface of the ordin- ary ray, and within it a prolate ellipsoid w r hose surface represents the wave-surface of the extraordinary ray. The following list includes examples of both classes of uniaxial crystals : Negative crystals ( ), Calcite. Tourmaline, Corundum, Beryl, Apatite. Positive crystals (+), Quartz, Zircon, Hematite, Apophyllite, Cassiterite. It may be remarked that in some species both + and varieties have OPTICAL CHARACTERS OF UNIAXIAL CRYSTALS. 139 been observed. Certain crystals of apophyllite are positive for one end of the spectrum and negative for the other, and consequently for some color between the two extremes it has no double refraction. These principles make the explanation of the use of tourmaline plates and calcite prisxm as polarizing instruments (p. 150) more intelligible. The two rays into which the single ray is divided on passing through a uniaxial crystal are, as has been said, both polarized, the ordinary ray in a plane passing through the vertical axis and the extraordinary ray perpendicular to this. In a tourmaline plate of the proper thickness, cut parallel to the axis c, the ordinary ray is absorbed (for the most part) and the extraordinary ray alone passes through, having its vibrations in the direction of the vertical axis. In the calcite prism, of the two refracted and polarized rays, the ordinary ray is disposed of artificially in the manner mentioned (p. 151), and the extraordinary ray alone passes through, vibrating as already remarked, in the direction of the axis c, or, in other words, of the shorter diagonal of the Nicol prism . The relation of these phenomena to the molecular structure of the crystal is well shown by the effect of pressure upon a parallelepiped of glass Glass, normally, exhibits no colored phenomena in polarized light, since the elasticity of the ether is the same in ail directions, and there is hence no double refraction. But if the block be placed under pressure, exerted on two opposite faces, the conditions are obviously changed, the density is the same in the both lateral directions but differs from that in the direction of the axis of pressure. The sym- metry in molecular structure becomes that of a uniaxial crystal, and, as would be expected, on placing the block in the polari scope, a black cross with its colored rings is observed, exactly as with calcite. Similarly when glass has been suddenly and unevenly cooled its molecular structure is not homogeneous, and it will be found to polarize light, although the phenomena, for obvious reasons, will not have the regularity of the case described. It may be added here that recent investigations by Mr. John Kerr have shown that electri- city calls out birefringent phenomena in a block of glass. (Phil. Mag., 1., 337.) Optical Investigation of Uniaxial Crystals. Sections normal or parallel to the axis in polarized light. Suppose a section to be cut perpendicular to the vertical axis (axial section), it has already been shown that a ray of light passing through the crystal in this direction suffers no change, consequently, such a section examined in parallel polarized light, in the instrument (f. 385), appears as a section of an isometric crystal. If the same section be placed in the other instrument (f. 384, p. 152), arranged for viewing the object in converging light, or in the tourmaline tongs, a beautiful phenomenon is observed ; a symmetrical black cross when the Nicola or tourmaline plates are crossed with a series of concentric rings, dark and light, in monochromatic light, but in white light, showing the prismatic colors in succession in each ring. This is shown without the colors in f. 390, the arrangement of the colors in the elliptical rings of the colored plate (frontispiece) is similar. This cross becomes white when the Nicols or tourmalines are in a par- allel position, and each band of color in white light changes to its comple- mentary tint (f. 391). These interference figures are seen* in this form only in a plate cut perpendicular to the vertical axis, and marks the uni- zxial character of the crystal. The explanation of this phenomenon can be only hinted at in this place * Uniaxial crystals which produce circular polarization exhibit interference figures which differ somewhat from those described. Some anomalies are mentioned on p. 158. See also pp. 185 et seq. PHYSICAL CHARACTERS OF MINERALS. All the rays of light, whose vibrations coincide with the vibration-planes of either of the crossed Nicols, must necessarily be extinguished. This gives rise to the black cross in the centre, with its arms in the direction of The planes mentioned. All other rays passing through the given plate obliquely will be doubly refracted, and after passing through the second Nicol, thus being referred to the same plane of polarization, they will interfere^ and will give rise to a series of concentric rings, light and dark in homogeneous light, but in ordinary light showing the successive colors of the spectrum. In regard to the interference of polarized rays, the fact must be stated that that can take place only when they vibrate in the same plane ; two rays vibrating at right angles to each other cannot interfere. These interference phenomena are similar to the successive spectra obtained by diffraction gratings alluded to on p. 129. It is evident that, in order to observe the phenomena most advantageously, the plate must have a suitable thickness, which, however, varies with the refractive index of the substance The thicker the plate the smaller the rings and the more they are crowded together ; when the thickness is considerable, only the black brushes are seen. Section parallel (or sharply inclined) to the axis. If a section of a uni- axial crystal, cut parallel or inclined to the vertical axis, be examined in parallel polarized light, it will, when its axis coincides with the direction of vibration of one of the Nicol prisms, appear dark when the prisms are crossed. If, however, it be revolved horizontally on the stage of the polaii- scope (I, I, f. 384) it will appear alternately dark and light at intervals of 45, dark under the conditions mentioned above, otherwise more or less light, the maximum of light being obtained when the axis of the section makes an angle of 45 D with the plane of the Nicol. Between parallel Nicols the phenomena are the same except that the light and darkness are reversed. When the plate is not too thick the polarized ray, after passing the upper Nicol, will interfere, and in white light, the plate will show bright colors, which change as one of the Nicols or the plate is revolved. Examined in converging light, similar sections, when very thin, show in white light a series of parallel" colored bands. Determination of the indices of refraction o> and e. One prism will OPTICAL CHARACTERS OF UNIAXIAL CRYSTALS. 141 Buffice for the determination of both indices of refraction, and its edge may be either parallel or perpendicular to the vertical axis. (a) If parallel to the vertical axis, the angle of minimum deviation for each ray in succession must be measured. The extraordinary ray vibrates parallel to, and the ordinary ray at right angles to, the direction of the edge of the prism. For convenience it is better to isolate each of the rays in succession, which is done with a single Nicol prism. If this is held before the observing telescope with its shorter diagonal parallel to the refracting edge of the prism, the ordinary ray will be extinguished and the image of the slit observed will be that due to the extraordinary ray. If held with its plane of vibration at right angles to the prismatic edge, the extraordinary ray will be extinguished and the other alone observed. From the single observed angle, for the given color, the index of refraction can be calculated, &> or e, by the formula given on p. 128, the angle of the prism being known. (b) If the refracting edge of the prism is perpendicular to the vertical axis of the crystal, the same procedure is necessary, only in this case the ordinary ray will vibrate parallel to the prismatic edge, and the extraordi- nary ray at right angles to it. The two rays are distinguished, as before, by a Nicol prism. Determination of the positive or negative character of the double refrac- tion. The most obvious way of determining the character of the double refraction (to > e or co > e) is to measure the indices of refraction in accord- ance with the principles explained in the preceding paragraphs. It is not always possible, however, to obtain a prism suitable for this purpose, and in an} 7 case it is convenient to have a more simple method of accomplishing the result. To do this, use may be made of a very simple principle : the + or character of a given crystal is determined by observing the effect produced when an axial section from it is combined in the polariscope with that of a crystal of known character. For instance, calcite is negative, and if it be placed in conjunction with the section of a positive crystal, the whole effect observed is the same as that which would be produced if the original plate were diminished in thickness, while, if combined with a negative crystal, it is as if the plate were made thicker. It has already been remarked that, as the axial plate of a crystal increases in thickness, the number of rings visible in the field of the polari- scope increases, and they become more crowded together ; but, if the section is made thinner, the successive rings widen out and become less numerous. One or the other of these effects is produced by the use of the intervening section. In the case of uniaxial crystals, however, the method which is practically most simple is that suggested by Dove the use of an axial plate of mica of a certain thickness. The section required is a cleavage piece of such a thickness that the two rays in passing through suffer a difference of phase which is equal to a quarter wave-length, or an odd multiple of this. Suppose that the section of the crystal to be examined, cut perpendicular to the axis, is brought between the crossed Nicols in the polariscope ; the black cross and the concentric colored rings are of course visible. Let now, while the given section occupies this position, the mica plate be placed upon it, with the plane of its optic axes (determined beforehand, and the direction 142 PHYSICAL CHARACTERS OF MINERALS. marked by a line for convenience) making an angle of 45 with the vibra- tion-planes of the ]^icols ; the black cross disappears and there remain only two diagonally situated dark spots in the place of it. Moreover, the colored curves in the two quadrants with these spots are pushed farther away from the centre than the others. The effect produced is represented in f. 392 and f. 393. If the line joining these two dark spots stands at right angles to the axial plane of the mica, the crystal is positive (f. 392), if this line coincides with the axial plane, the crystal is negative (f. 393). The explana- tion of this eff'v-t is not so simple as to allow of being introduced here ; the effect of the mica is to produce circular polarization of the light which it transmits. With both uniaxtal and biaxial crystals the student will find it of great assistance always to have at his side a good section of a positive and a negative crystal. By comparing the phenomena observed in the section under examination with those shown by crystals of known character, he will often be saved much perplexity. For the investigation of the absorption phenomena of uniaxial crystals see p. 165. CIRCULAR POLARIZATION. In what has been said of polarized light, in the preceding pages, it has been assumed that a polarized ray was one whose vibrations took place in a single plane, so that the plane of polarization at ri^ht angles to this was a fixed plane. Such a ray is said to be linearly polarized. There are some uniaxial crystals, however, which have the power to rotate the plane of polari- zation ; the ray is said to be circularly polarized. They manifest this in the phenomena observed when an axial section is examined in the polariscope. An axial section of a nniaxial crystal normally exhibits, in converging r)larized light, a black cross with a series of concentric colored circles, 390, p. 140. If, however, a section of quartz be cut perpendicular to the axis and viewed between the crossed Nicols, the phenomena observed are different from tl.ese: the central portion of the black cross has disap- peared, and instead, the space within the inner ring is brilliantly colored. Furthermore, when the analyzing Nicol is revolved, this color changes from blue to yellow to red, and it is found that in some cases this CIRCULAR POLARIZATION. 143 change is produced by revolving the Nicol to the right, and in other cases to the left. To distinguish between these the first are called right-handed rotating crystals, and the others left-handed. The relations here involved will be better understood if the quartz section is viewed in parallel mono- chromatic light. Under these circumstances a similar plate of calcite appears dark when the Nicols are crossed, but with quartz the maximum darkness is only obtained when the analyzer has been revolved beyond its first position a certain angle ; this angle increasing with the thickness of the section, and also varying with the color of the light employed. For a section 1 mm. thick in red light, a rotation of the analyzer of 19 is required to produce the maximum darkness. For yellow light the rotation is 24 with a plate of the same thickness ; with blue, 32, and so on. The rotation of the analyzer with some crystals is to the right, with others to the left. The explanation of these facts lies in the fact stated above, that the quartz rotates the plane of vibration of the polarized light, and the angle of rotation is different for rays of different wave-lengths. Furthermore, this rotation of the plane of vibration results from the fact that in quartz, even in the direction of its axis, double refraction takes place. The oscillations of the particles of ether take place not in straight lines but in circles, and they move in opposite directions for the two rays, ordinary and extraor- dinary. An axial section of a quartz crystal can never appear dark between crossed Nicols in ordinary light, since there is no point at which all the colors are extinguished ; on the contrary, it appears highly colored. The color depends upon the thickness of the section, and is the same as that observed in the centres of the rings in converging polarized light. If sec- tions of a right-handed and left-handed crystal are placed together in the polariscope, the centre of the interference figure is occupied with a four- rayed spiral curve, called from the discoverer Airy's spiral. Twins of quartz crystals are not uncommon, consisting of the combination of right- and left-handed individual, which sometimes show the spirals of Airy. It is a remarkable fact, discovered by Herschel, that the right- or left- handed optical character of quartz is often indicated by the position of the trapezohedral planes on the crystals. When a given trapezohedral plane appears as a modification of the prism, to the right above and left below, the crystal is optically right-handed ; if to the left above and right below, the crystal is left-handed. In f . 394 the plane is, as last remarked, left above and right below, and the crystal is hence left-handed. Cinnabar has been shown by Des Cloizeaux to possess the same property as quartz; and this is true also of some artificial salts, also solutions of sugar, etc. In twins of quartz, the component parts may be both right-handed or both left-handed (as in those of Dauphiny and the Swiss Alps) ; or one may be of one kind and the other of the other. Moreover, successive layers of deposition (made as the crystal, went on enlarging, and often exceedingly thin) are sometimes alternately right- and left-handed, showing a constant oscillation of polarity in the course of its formation ; and, when this is the case, and the layers are regular, cross-sections, examined by polarized light, exhibit a division, more or less perfect, into sectors of 120, parallel to the plane /?, or intc sectors of 6u. If the layers are of unequal thickness 144 PHYSICAL CHARACTERS OF MINERALS. there are broad areas of colors without sectors. In f. 395 (by Des Cloizeaux. from a crystal from the Dept. of the Aude), half of each sector of 60 is 395 -i right-handed, and the other half left (as shown by the arrows), and the dark radii are neutral bands produced by the overlapping of layers of the twc kinds. These overlapping portions often exhibit the phenomenon of Airy'e spiral. 0. BIAXIAL CRYSTALS. General Optical Character. As in the crystalline systems, thus far considered, so also in the anisome- tric systems, the orthorhombic, monoclinic, and triclinic, there is a strict corre- spondence between the molecular structure, as exhibited in the geometrical form of the crystals, and their optical properties. In the crystals of these systems there is no longer one axis around about which the elasticity of the light-ether, that is, the velocity of the light, is everywhere alike. On the contrary, the relations are much less simple, and less easy to comprehend. There are two directions in which the light passes through the crystal without double refraction these are called the optic axes, and hence the crystals are biaxial but in every other direction a ray of light is separated into two rays, polarized at right angles to each other. Neither of these conforms to the law of simple refraction. The subject was first developed theoretically by Fresnel, r and his conclusions have since been fully j^"* 8 verified by experiment. -A Axes of elasticity. In regard to the elasticity of the ether in a biaxial crystal there are %(1) a maximum value, (2) a minimum value, and (3) a mean value, and these values in the crystal are found in directions at right angles to each other. In f. 396, GO 1 represents the axis (c) of least elasticity, A A' of greatest elasticity (a), and BB' of mean elasticity (b). A ray passing in the direo- A'. c f OPTICAL CHARACTERS OF BIAXLAL CRYSTALS. 145 Hon CO' vibrates in a plane at right angles, that is, parallel to BB' and AA'. Similarly for the ray BB' the vibrations are parallel to AA' and CO', and for the ray AA' parallel to BB' and CO'. Between these extreme values of the axes of elasticity, the elasticity varies according to a regular law, as will be seen in the following discussion. The form of the wave-surface for a biaxial crystal may be determined by fixing its form for the planes of the axes a, b, and c. Wave-surface. First consider the case of rays in the plane of the axe* BB' and CC' (f. 397X A ray pass- ing in the direction BB' is separated 397 into two sets of vibrations, one paral- lel to A A', corresponding to the greatest elasticity, moving more rapidly than the other set, parallel to CC', which correspond to the least elasticity. The velocities of the two sets of vibrations are made pro- portional to the lengths of the lines mn, and mo respectively, in f. 397. Again, for a ray in the same plane, parallel to CC', the vibrations are (1) parallel to AA', and propagated faster (greatest elasticity) than the other set; (2) parallel to BB' (mean elasticity). Again, in f. 397, on the line CO', mn", and mq" are made proportional to these two velocities ; here mn = mn" ^ and for a ray in the same plane in any other direction, there will be one set of vibrations parallel to AA', with the same velocity as before, and another set at right angles with a velocity between mo and mq", determined by the ellipse whose semi-axes are proportional to the mean and least axes of elasticity. Fig. 397 then represents the section of the wave-surface through the axes CO' and BB'. The circle nn" shows the constant velocity for all vibrations par- allel to A A', and the ellipse the variable values of the velocity for the other set of vibrations at right angles to the first. Again, for a ray in the plane A A', BB', the method of the construction is similar. The vibrations will in every case take place in the plane at right angles to the direction of the ray, which plane must always pass through the axis CC' of least elasticity. Hence for every direction of the ray in the plane men- tioned, one set of vibrations will always be parallel to CC', and hence be propagated with a constant velocity 10 146 PHYSICAL CHARACTERS OF MINERALS. = mo', f . 398), and hence this is expressed by the circle oo'. The other set of vibrations will be at right angles to CC', and the velocity with which they are propagated will vary according as they are parallel to A A (= mn, f. 398), "or parallel to BB' (= mq'), or some intermediate value for an intermediate position. The section of the wave-surface is consequently a circle within an ellipse. Finally, let the ray pass in some direction in the plane CC', A A, of least and greatest elasticity, the section of the wave-surface is also a circle and ellipse. Suppose the ray passes in the direction Sarallel to AA, the vibrations will be L) parallel to CC', and (2) parallel to BB', those (1) parallel to CC' (least axis of elasticity) are propagated more slowly than those (2) parallel to BB (axis of mean elasticity). In f. 399, on the line AA' , lay off mo and mq' proportional to these two values. Again, for a ray parallel to CC' the vibrations will take place (1) parallel to AA, and (2) parallel to BB', the former will be propagated with greater velocity than those latter. These two values of the velocity in the direction CC' are represented by mn" and mq" (= mq'). For any intermediate position of the ray in the same plane there will always be one set of vibrations parallel to BB' (mq f = mq", f. 399, hence the circle). The other set at right angles to these will be propagated with a velocity va- rying according to the direction, from that corresponding to the least axis of elasticity (represented by mo' , f . 399), to that of the greatest axis of elasticity f Optic axes. It is seen that the cir- cle, representing the uniform velocity of vibrations parallel to b, and the ellipse representing the varying value of the velocity for the vibrations at right angles to these, intersect one an- other at P, P', f. 399. The obvious meaning of this fact is that, for the directions mP, and mP', making equal angles with the axis CC', the velocity is the same for both sets of vibrations ; these are not separated from each other, the ray is not doubly refracted, and not polarized. These two directions are called the OPTIC AXES. All anisometric crj stale have, as has been stated, two optic axes, and are hence called biaxial. OPTICAL CHARACTERS OF BIAXIAL CRYSTALS. 147 The complete wave-surface of a biaxial crystal is constructed from the three sections given in f. 397, 398, 399. It is shown graphically in f. 400, where the lines PP, and P' P' are the two optic axes. Bisectrices^ or Mean-lines. As shown in f . 399, the optic axes always lie in the plane of greatest (a) and least (c) elasticity, and the value of the optic axial angle is known when the axes of elasticity are given as stated below. The axis of elasticity which, as the line 6 y 6", f. 399, bisects the acute angle is called the acute bisectrix, or first nwan-line (erste Mittellinie, Germ.), and that bisecting the obtuse angle, the obtuse bisectrix, or second mean-line (zweite Mittellinie, Gen/i.). Positive and negative crystals. When the acute bisectrix is the axis of least elasticity (c), it is said to be positive, and when it is the axis of greatest (a) elasticity, it is said to be negative. Barite is positive, mica negative. Indices of refraction. It has been seen that in uniaxial crystals there are two extreme values for the velocity with which light is propagated, and corresponding to them, and inversely proportional to them, two indices of refraction. Similarly for biaxial crystals, where there are three axes of elasti- city, there are three indices of refraction a maximum index a, a minimum 7, and a mean value /3 ; a is the index for the rays propagated at right angles to a, but vibrating parallel to a ; is the index for rays propagated perpen- dicularly to b, by vibrations parallel to b ; 7 is the index for rays propagated perpendicularly to c, but vibrating parallel to c- a =,=, y = . u b If a, ft, and 7 are known, the value of the optic axial angle (2 V) can be calculated from them by the following formula : cos = dispersion of the optic axes. It is obvious that the three indices oi refraction may have different values for the different colors, and as the angle of the optic axes, as explained in the last paragraph, is determined by these three values, the axial angle will also vary in a corresponding manner. This variation in the value of the axial angle for rays of different wave lengths is called the dispersion of the axes, and the two possible cases are distinguished by writing p > v when the angle for the red rays (p) is greater than for the blue (violet, v), and p < v when the reverse is true. In the properties thus far mentioned, the three systems are alike ; in details, however, they differ widely. Practical Investigation of Biaxial Crystals. Interference figures. A section cut perpendicular to either axis will show, in converging polarized light, a system of concentric rays analogous to those of uniaxial crystals, f. 390, but more or less elliptical. There is, moreover, no black cross, but a single black line, which changes its position as the Nicols are revolved. 148 PHYSICAL CHARACTERS OF MINERALS. If a section of a biaxial crystal, cut, perpendicularly to the first, that ifc acute, bisectrix, is viewed in the polariscope, a different phenomenon is observed. There are seen in this case, supposing the plane of the axes to make an angle of 45 with the planes of polarization of the crossed Nicols, two black hyper- b^las, marking the position of the axes, a series of elliptical curves surround:- ing the two centres and finally uniting, forming a series of lemniscates. If monochromatic light is employed, the rings are alternately light and dark ; if white light, each ring shows the successive colors of the spectrum. If one of the Nicol prisms be revolved, the dark hyperbolic brushes gradu- ally become white, and the colors of the rings take the complementary tints after^ a revolution of 90. Since the black hyperbolic brushes mark the position of the optic axes, the smaller the axial angle the nearer together are the hyperbolas, and when the angle is very small, the axial figure observed closely resembles the simple cross of a uniaxial crystal. On the other hand, when the axial angle is large the hyperbolas are far apart, and may even be so far apart as to" be invisible in the field of the polariscope. When the plane of the axes coincides with the plane of vibration foi either Nicol, these being crossed, an unsymmetrical black cr>ss is observed, and also a series of elliptical curves. Both these figures are well exhibited on the frontispiece ; the one gradually changes into the other as the crystal-section is revolved in the horizontal plane, the Nicols remaining stationary. A section of a biaxial crystal cut perpendicular to the obtuse bisectrix will exhibit the same figures under the same conditions in polarized light, when the angle is not too large. This is, however, generally the case, and in consequence the axes suffer total reflection on the inner surface of the section, and no axial figures are visible. This is sometimes the case also OPTICAL CHARACTERS OF BIAXIAL CRYSTALS. 119 with a section cut normal to the acute bisectrix, when the angle is large. A micrometer scale in the polariscope, f. 384, allows of an approximate measurement of the axial angle ; the value of each division of the scale being known. Measurement of the axial angle* The determination of the angle made by the optic axes is of the highest importance, and the method of proce- dure offers no great difficulties. Fig. 401 shows the instrument recom- mended for this purpose by DesCloizeaux ; its general features will be understood without detailed description ; some improvements have been introduced by Groth, which make the instrument more accurate and con- venient of use. The section of the crystal, cut at right angles to the bisec- trix, is held in the pincers at c, with the plane of the axes horizontal, making an angle of 45 with the plane of vibration of the Nicols (NN). There is a cross- wire in the focus of the eye-piece, and as the pincers hold ing the section are turned by the screw F, one of the axes, that is one black hyperbola, is brought in coincidence with the vertical cross-wire, and then, by a further revolution of F, the second. The angle which the section has been turned from one axis to the second, as read oif at the vernier H on the graduated circle above, is the apparent angle for the axes of the given crystal as seen in the air (aca, f. 402). It is only the apparent angle, for, owing to the refraction suffered on passing from the section of the crystal to the air, the true axial angle is more 01 less increased, according to the refractive index of the given crystal. This being understood, the fact already stated is readily intelligible, that when the axial angle exceeds a certain limit, the axes will suffer total reflection (p. 128), and they will be no longer visible at all. When this is the case, oilf or some other medium with high refractive power is made use of, into which the axes pass when no longer visible in the air. In the instrument described a small receptacle holding the oil is brought between the tubes, as seen in the figure, and the pincers holding the section are immersed in this, and the angle measured as before. In the majority of cases it is only the acute axial angle that it is practi- cable to measure ; but sometimes, especially when oil is made use of, the obtuse angle can also be determined from a second section normal to the obtuse bisectrix. If E = the apparent semi-axial angle in air (f. 402). j H a = the apparent semi-acute angle in oil. ( H = " ' " obtuse " " " V a = the real (or interior) semi-acute angle (f. 402). V = u " " " semi-obtuse " (f. 402). n = index of refraction for the oil. ft = the mean refractive index for the given crystallized substance. * See further on p. 180. 4- Almond oil which has been decolorized by exposure to the light, is commonly employed. 150 PHYSICAL CHARACTERS OF MINERALS. sin E = n sin H a ; sin V a = sin H a ; sin V = -= sin H . These formulas give the true interior angle from the measured apparent angle when the mean refractive index (ft) is known. If, however, it is possible to measure both the acute and obtuse apparent angles, the true angle, and also the value of ft, can be determined from them. For sin V = cos V a , hence : sin H n sin E sin V n ' a In measuring this angle, if white light is employed, the colors being separated, the position of the hyperbolas is a little uncertain ; hence it is always important to measure the angle for monochromatic light, red and yellow and blue particularly. This is especially essential where the disper- sion of the axes is considerable. Determination of the indices of refraction* The values of the three indices of refraction, a, ft, 7, for biaxial crystals, may be determined from three prisms cut with their refracting edges parallel respectively to the three axes of elasticity o, b, and c. In each case, after the angle of the prism has been measured, the angle of minimum deviation must be meas- ured for that one of the two refracted rays whose vibrations are parallel to the edge of the prism ; the formula of p. 128 is then employed. It is possible, however, to obtain the values of a, ft, and 7 with (wo prisms ; in this case one of the prisms must be so made that its vertical edge is parallel to one axis of elasticity, while the line bisecting its refracting angle at this edge is parallel to a second. In the case of such a prism the minimum deviation of the ray is obtained for both rays, that having its vibrations parallel to the prism-edge, and that vibrating at right angles to this, that is parallel to the bisector of the prismatic angle. Of the three indices of refraction, ft is one which it is most important to determine, since by means of it, in accordance with the above formulas, the true value of the axial angle can be calculated from its apparent value in air. The prism to give the value of ft should obviously have its refract ing edge parallel to the mean axis of elasticity b, that is at right angles to the plane of the optic axes. Determination of the positive or negative character of biaxial crystals. The question of the positive or negative character of a biaxial crystal is determined from the values of the indices of refraction, where these can be obtained. If c, the axis of least elasticity, is the acute bisectrix, the crystal is optically positive ; if a, the axis of greatest elasticity, is the acute bisec- trix, the crystal is optically negative ; in the former case the value of b is nearer that of c than of a, in the second case the reverse of this is true. There is, however, a more simple method of solving the problem, as was remarked also in regard to uniaxial crystals. The methods are similar. The quarter-undulation mica plate may be employed just as with uniaxiaJ crystals, but its use is not very satisfactory excepting when the axial diver- gence is quite small. In this case it can be employed to advantage, the "- See further on pp. 177 et seq. DISTINGUISHING OPTICAL CHARACTERS OF OETHOKHOMBIC CRYSTALS. 151 plane of the axes of the crystal investigated being made to coincide with the vibration-plane of one of the Nicols. The more general' method is the employment of a wedge-shaped piece of quartz ; this is so cut that one sur- face coincides with the direction of the vertical axis, and the other makes an angle of 4 to 6 with it. By this means a section of varying thickness is obtained. The section to be examined normal to the acute bisectrix is brought between the crossed Nicols of the polariscope (f. 384), and with its axial plane making an angle of 45 with the polarization-plane of the JNicol prisms ; that is, so that' the black hyperbolas are visible. The quartz wedge is now introduced slowly between the section examined and the analyzer; in the instrument figured a slit above gives an opportunity to insert it. The quartz section is introduced first, in a direction at right angles to the axial plane, that is, to the line joining the hyperbolas, of the plate investigated ; and second, parallel to the axial plane, that is, in the direction of the line joining the hyperbolas. In one direction or the other it will be seen, when the proper thickness of the quartz wedge is reached, that the central rings appear to increase in diameter, at the same time advancing from the centre to the extremities. The effect, in other words, is that which would have been produced by the thinning of the given section. If the phenomenon is observed in the first case when the axis of the quartz is parallel to the axial plane, that is to the obtuse bisectrix, it shows that this bisectrix must have an opposite sign to the quartz, that is, the obtuse bisectrix is negative, and the acute bisectrix positive. If the mentioned change in the interference figures takes place when the axis of the quartz is at right angles to the axial plane, then obviously the opposite must be true and the acute bisectrix is negative. The same effect may be obtained by bringing an ordinary quartz section of greater or less thickness, cut normal to the axis, between the analyzer and the crystal examined, and then inclining it, first in the direction of the axial plane, and again at right angles to it. The method of investigation with the quartz wedge can be applied even in those cases where the axial angle is too large to appear in the air. For the investigation of the absorption phenomena of biaxial crystals, see p. 165. DISTINGUISHING OPTICAL CHARACTERS OP ORTHORHOMBIC CRYSTALS. In the Orthorhomlic System, in accordance with the symmetry of the crystallization, the three axes of elasticity coincide with the three crystallo- graphic axes. Further than this, there is no immediate relation between the two sets of axes in respect to magnitude, for the reason that, as has been stated, the choice of the crystallographic axes is arbitrary, and has been made, in most cases, without reference to the optical character. Schrauf has proposed that the crystallographic vertical axis (c) should be always made to coincide with the acute bisectrix, which would be very desirable, especially, as urged by him, in showing the true relations between the orthorLombic and hexagonal systems. Of course, this suggestion can be carried out only in those species in which the optical character is known. Schrauf (Phys. Min., p. 302, 303) has shown there is a close analogy between certain 152 PHYSICAL CHARACTERS OF MINERALS. orthorhombic crystals whose prismatic angle is near 120 (compare remarks on twins, p 96; and the crystals of the hexagonal system. With these the acute bisectrix is uniformly parallel to the prismatic edge, and normal to the six-sided basal plane, analogous to the one optic axis ot true hexagonal forms. Moreover, he shows that the nearer the prismatic angle approaches 120, the less the difference between the three axes of elasticity, and the nearer the approach to the uniaxial character. By the combination of thin plates of a biaxial mica optical phenomena may, under some conditions, be observed in polarized light which are similar to those shown by uniaxial crys- tals. Similarly twins of chrysoberyl (p. 97) have been described which in spots gave the axial image of uniaxial crystals. This subject has been investigated by Reusch (Pogg. cxxxvi., 626, 637, 1869), and later by Cooke (Am. Acad. Sci., Boston, p, 35, 1874). Practical Optical Investigation of OrtJwrhombic Crystals. Determination of the plane of the optic axes. The position of the three axes of elasticity in an orthorhombic crystal is always known, since they must coincide with the crystallographic axes ; but the plane of the optic axes, that is, of the axes of greatest (a) and least (c) elasticity, must in each case be determined. This plane will be parallel to one of the three diame- tral or pinacoid planes. In order to determine in which the axes lie, it is necessary to cut sections parallel to these three directions ; one of these three sections will in all ordinary cases show, in converging polarized light, the interference figures peculiar to biaxial crystals. It is evident, too, that two of the three sections named determine the character of the third, so that the plane of the optic axes and the position of the acute bisectrix can be in practice generally told from them. Measurement of the axial angle, p *. v. From the section showing the axial figures, that is, normal to the acute bisectrix, the axial angle can be measured in the manner which has been described (p. 149). If it is prac- ticable to determine also the obtuse axial angle, from a second section nor- mal to the obtuse bisectrix, it will be possible to calculate the true axial angle from these data, and also the mean index of refraction (0). There is further to be determined the dispersion of the axes. Whether the axial angle for red rays is greater or less than for blue (p > v, or p < v) can be seen immediately from the figure of the axes, as in f. 1, 15, in the colored plate, (frontispiece). It is obviously true in this case, from f. la, as also f. 15, that the angle for the blue rays is greater than that for the red (p < v), and so in general. This same point is also accurately determined, of course, by the measured angle for the two monochromatic colors. In all cases the same line will be the bisectrix of the axial angle for both blue and red rays, so that the position of the respective axes is symmetrical with refer- ence to the bisectrix. In f. 403, the dis- persion of the axes is illustrated, where p < v ; it is shown also that the lines, IP IP and .Z? 2 ^, bisect the angles of both red (pOp) and blue (vOv') rays. It also needs no further explanation that fora certain relatioD DISTINGUISHING OPTICAL CHARACTERS OF MONOCLINIC CRYSTALS. 153 >f the refractive indices of the different colors, the acute bisectrix of the axial angle for red rays may be the obtuse bisectrix for the angle for blue rays. Indices of refraction, etc. The determination of the indices of refrac- tion and the character (-1- or ) of the acute bisectrix is made for ortho- rhombic crystals in the same way as for all biaxial crystals (p. 150). It is merely to be mentioned that, since the axes of elasticity always coincide with the crystallographic axes, it will happen not infrequently that crystals without artificial preparation will furnish, in their prismatic or dome series, prisms whose edges are parallel to the axes of elasticity, and consequently at once suitable for the determination of the indices of refraction. DISTINGUISHING OPTICAL CHARACTERS OP MONOCLINIC CRYSTALS. Position of the axes of elasticity. In crystals belonging to the mono- clinic system one of the axes of elasticity always coincides with the ortho- diagonal axis &, and the other two lie in the plane of symmetry at right angles to this axis. Here obviously three cases are possible, according to which two of the axes, a, b, or c, lie in the plane of symmetry. Corresponding to these three positions of the axes of elasticity, there may occur three kinds of dispersion of these axes, or dispersion of the bisectrices. This dispersion arises from the fact that, while the position of one axis of elasticity is always fixed, the position of the other two is indeterminate and for the same crystal may be different for the different colors, so that the bisectrices of the different colors may not coincide. Uispersion of the bisectrices. 1. The bisectrices, that is, the axes of greatest and least elasticity, lie in the plane of sym- metry, while the orthodiagonal axis b coincides with b. The optic axes here suffer a dispersion in this plane of symmetry, and, as already stated, they do not lie symmetrically with reference to the acute bisectrix. "This is illustrated in f. 404, where MM is the bisec- trix for the angle, vOv', and BB for the angle pOp'. This kind of dispersion is called by DesCloizeaux inclined (dispersion inclinee). 2. The second case is that where the plane of the optic axes is perpendicular to the plane of symmetry, and the acute bisectrix stands at right angles to the orthodiagonal axis b. In other words, the acute bisectrix and the axis of mean elasticity both lie in the plane of syinmetry. In this case also dispersion of the axes may take place, and in this way the plane of the optic axes for all the colors lies parallel to the orthodiagonal, but these planes may have different inclinations to the ve *tical axis. This is called horizontal dispersion by DesCloizeaux. 3. Still again, in the third place, the plane of the optic axes lies perpen iicular to the plane of symmetry ; but in this Case the acute bisectrix is parallel to the crystallographic axis b, so that the obtuse bisectrix and axis of mean elasticity lie in the plane of symmetry. The dispersion which P' 154 PHYSICAL CHARACTERS OF MINERALS. results in this case is called by DesCloizeaux crossed (dispersion tournante or eroisee). Dispersion as shown in the interference figures. If an axial section of a monoclinic crystal be examined in converging polarized light, the kind of dispersion which characterizes it will be indicated by the nature of the interference figures observed ; the three cases are illustrated by the figures upon the frontispiece, taken from DesCloizeaux. (frontispiece). Figs. 1#, Ib represent the interference figures for an orthorhombic crystal (nitre), characterized by the symmetry in the size of the rings, and the distribution of the colors. Figs. 2a, 25 (diopside), 3rown and yellow; chrysolite. 12. Oil-green: the color of olive oil; >eryl, pitchstone. 13. Siskin-green : light green, much inclining to yellow; irani te. F. YELLOW. 1 . Sulphur-yellow : sulphur. 2. Straw-yellow : pale yel- ow ; topaz. 3. Wax-yellow : grayish yellow with some brown ; blende, >pal. 4. Honey-yellow : yellow with some red and brown ; calcite. 5. ^emon-yellow : sulphur, orpiment. 6. Ochre-yellow : yellow with brown ; ellow ochre. 7. Wine-yellow: topaz and fluorite. S. Cream-yellow: ome varieties of lithomarge. 9. Orange-yellow : orpiment. G. RED. 1. Aurora-red: red with much yellow; some realgar. 2. r lyacinth-red : red with yellow and some brown ; hyacinth garnet. 3. ^rick-red: poly halite, some jasper. 4. Scarlet-red: "bright red with a inge of yellow ; cinnabar. 5. Blood-red: dark red with some yellow ; yrope. 6. Flesh-red: feldspar. 7. Carmine-red: pure red; ruby sap- hire. 8. Rose-red : rose quartz. 9. Crimson-red : ruby. 10. Peach- lossom-red: red with white and gray; lepidolite. 11. Columbine-red: eep red with some blue ; garnet. 12. Cherry-red : dark red with some lue and brown : spinel, some jasper. 13. Brownish-red: jasper, limonite. H. BUOWN. 1. Reddish-brown : garnet, zircon. 2. Clove-brown : brown rith red and some blue ; axinite. 3. Hair-brown : wood opal. 4. JSroc- oli-brown : brown, with blue, red, and gray ; zircon. 5. Chestnut-brown : ure brown. 6. Yellowish-brown : jasper. 7. Pinchbeck-brown: yellow- ;h-brown, with a metallic or metallic-pearly lustre; several varieties of lie, bronzite. 8. Wood-brown : color of old wood nearly rotten ; some pecimens of asbestus. 9. Liver-brown : brown, with some gray and green ; isper. 10. Blackish-brown ; bituminous coal, brown coal. c. Peculiarities in the Arrangement of Colors. Play of Colors. An appearance of several prismatic colors in rapid Liccessioii on turning the mineral. This property belongs in perfection to lie diamond ; it is also observed in precious opal, and is most brilliant by an die-light. 164 PHYSICAL CHARACTERS OF MINERALS. Change of Colors. Each particular color appears to pervade a larger space than in the play of colors, and the succession produced by tinning the mineral is less rapid ; Ex. labradorite. Opalescence. A milky or pearly reflection from the interior of a speci- men. Observed in some opal, and in cat's eye. Iridescence. Presenting prismatic colors in the interior of a crystal. The phenomena of the play of colors, iridescence, etc., are sometimes to be explained by the presence of minute foreign crystals, in parallel positions ; more generally, however, they are caused by the presence of fine cleavage lamellse, in the light reflected from which interference takes place, analogous to the well-known Newton's rings. Tarnish. A metallic surface is tarnished, when its color differs from that obtained by fracture ; Ex. bornite. A surface possesses the steel tar- nish, when it presents the superficial blue color of tempered steel ; Ex. columbite. The tarnish is irised, when it exhibits fixed prismatic colors ; Ex. hematite of Elba. These tarnish and iris colors of minerals are owing to a thin surface film, proceeding from different sources, either from a change in the surface of the mineral, or foreign incrustation ; hydrated iron oxide, usually formed from pyrite, is one of the most common sources of it, and produces the colors on anthracite and hematite. Asterism. This name is given to the peculiar star-like rays of light observed in certain directions in some minerals by reflected or transmitted light. This is seen in the form of a six-rayed star in sapphire, and is also well shown in mica from South Burgess, Canada. In the former case it has been attributed by Yolger to a repeated lamellar twinning ; in the other case, by Rose, to the presence of minute inclosed crystals, which are a uniaxial mica, according to DesCloizeaux. Crystalline planes, which have been artificially etched, also sometimes exhibit asterism. In general the phenomenon is explained by Schrauf as caused by the interference of the light, due to fine striations or some other cause. (Upon the above subjects, see Literature, p. 167.) PHOSPHORESCENCE. Phosphorescence,* or the emission of light by minerals, may be produced in different ways : \>y friction, by heat, or by exposure to light. By friction* Light is readily evolved from quartz or white sugar by the friction of one piece against another, and merely the rapid motion of a feather will elicit it from some specimens of sphalerite. Friction, however, evolves light from a few only of the mineral species. By heat. Fluorite is highly phosphorescent at the temperature of 300 F. Different varieties give off light of different colors ; the chlorophane variety, an emerald-green light ; others purple, blue, and reddish tints. This phos- phorescence may be observed in a dark place, by subjecting the pulverized mineral to a heat below redness. Some varieties of white limestone or marble emit a yellow light. * This subject has been investigated by Becquerel, Ann. Ch. Phys., III., lv., 5-119, 1859 ; Faster, Mitth. nat. Ges. Bern, 1807, 62: and Hahn, Zeitsch. Ges. nab. Wiss. Berlin, II., Ix, 1,181, 1874. DIAPHANEITY COLOK LUSTRE. 165 By the application of heat, minerals lose their phosphorescent properties. But on passing electricity through the calcined mineral, a more or less vivid light is produced at the time of the discharge, and subsequently the specimen when heated will often emit light as before. The light is usually of the same color as previous to calcination, but occasionally is quite different. It is in general less intense than that of the unaltered mineral, but is much increased by a repetition of the electric discharges, and in some varieties of fluorite it may be nearly or quite restored to its former brilliancy. It has also been found that some varie- ties of fluorite and some specimens of diamond, calcite, and apatite, which are not naturally phosphorescent, may be rendered so by means of electricity. Electricity will also increase the natural intensity of the phosphorescent light. Light of the sun. The only substance in which an exposure to the light of the sun produces very apparent phosphorescence is the diamond, and some specimens seem to be destitute of this power. This property is most striking after exposure to the blue rays of the spectrum, while in the red rays it is rapidly lost. PLEOCHKOISM. Dichroism, Trichroism. In addition to the general phenomena of color, which belong to all minerals alike, some of those which are crystallized show different colors under certain circumstances. This is due to the fact that in them the absorption of parts of the spectrum takes place unequally in different directions, and hence their color by transmitted light depends upon the direction in which they are viewed. This phenomenon is called in sreneral pleochroism. lu uniaxial crystals it has been seen that, in consequence of their crystal- lographic symmetry, there are two distinct values for the velocity of light transmitted by them, according as the vibrations take place, parallel or at Tight angles to the vertical axis. Similarly the crystal may exert different degrees of absorption upon the rays vibrating in these two directions. For example, a transparent crystal of zircon looked through in the direction of the vertical axis appears of a pinkish-brown color, while in a lateral direc- tion the color is asparagus-green. This is because the rays (extraordinary) vibrating parallel to the axis are absorbed with the exception of those which together give the green color, and those vibrating laterally (ordinary) are absorbed except those which together appear pinkish-brown. Again, all crystals of tourmaline in the direction of the vertical axis are opaque, since the ordinary ray, vibrating normal to the axis c, is absorbed, while light-colored varieties, looked through laterally, are transparent, for the extraordinary ray, vibrating parallel to c, is not absorbed ; the color differs in different varieties. Thus, all uniaxial crystals may be dichroio^ or have two distinct axial colors. Similarly all biaxial crystals may be trichroic. For the rays vibrating in the directions of the three axes of elasticity may be differently absorbed. For diaspore the three axial colors are azure-blue, wine-yellow, and violet- blue. It will be understood that, while these three different colors are pos- sible, they may not exist ; or only two may be prominent, so that a biaxial mineral may be called dichroic. In order to investigate the absorption-properties of any uniaxial or biaxial crystal, it is evident that sections must be obtained which are parallel to the 166 PHYSICAL CHARACTERS OF MINERALS. several axes of elasticity. Suppose that f. 410 represents a rectangular solid with its sides parallel to the three axes of elasticity of a biaxial crystal. In an orthorhombic crystal the faces are those of the three diametral planes or pinacoids ; in a monoclinic crystal one side coincides with the clino pinacoid, the others are to be determined for each species. The light transmitted by this solid is examined by means of a single Nicol prism. Suppose, first, that the light transmitted by the parallelopiped (f. 410) in the direction of the vertical axis is to be examined. When the shorter diagonal of the Nicol coincides with the direction of the axis b, the color observed belongs to that ray vibrating parallel to this direction ; when it coincides with the axis a, the color for the ray with vibrations parallel to a is observed. In the same way the Nicol separates the different colored rays vibrating parallel to c and a respectively, when the light passes through in the direc- tion of b. So also finally when the section is looked through in the direction of the axis a, the colors for the rays vibrating parallel to b and c, respectively, are obtained. It is evident that the examination in two of the directions named will give the three possible colors. For epidote, according to Klein, the colors for the three axial directions are : Vibrations parallel to fe, brown (absorbed). " *' a, yellow. o Vibrations parallel to * *>> t. it Vibrations parallel to f, green. a, yellow. f , green, t, brown (absorbed). The colors observed by the eye alone are the resultants of the double set oi vibrations, in which the stronger color predominates ; thus, in the above example, the plane, normal to c is brown, to b, yellowish-green, to a, green. In any other direction in the crystal, the apparent color is the result of a mixture of those corresponding to the three directions of vibrations in differ- ent proportions. Dichroite is a striking example of the phenomenon of pleochroism. An instrument called a dichroscope has been contrived by Haidinger for examining this property of crystals. An oblong rhombohedron of Ice- land spar has a glass prism of 18 cemented to each extremity. It is placed 411 in a metallic cylindrical case, as in the figure, having a convex lens at one end, and a square hole at the other. On looking through it, the square hole appears double ; one image belongs to the ordinary and the other to the extraordinary ray. When a pleochroic crystal is examined with it, by trans- mitted light, on revolving it, the two squares, at intervals of 90 in the revo DIAPHANEITY COLOR LUSTRE. 167 lution, have different colors, corresponding to the direction of the vibrations of the ordinary and extraordinary ray in calcite. Since the two images are situated side by side, a very slight difference of color is perceptible. LITERATURE. PLEOCHROISM, ASTERISM, ETC. Haidinger. Ueber den Pleochroismus der Krystalle ; Pogg. Ixv., 1, 1845. TJeber das Schillern der Krystallflachen ; Pogg. Ixx., 574, 1847; Ixxi., 321; Ixxvi., 99, 1849. JReusch. Ueber das Schillern gewisser Krystalle : Pogg. cxvi., 392, 1862; cxviii., 256. 1863; cxx.,95, 1863. v. Kobell. Ueber Asterismus; Ber. Ak. Miinchen, 1863, 65. HamJwfer. Der Asterismus des Calcites ; Ber. Ak. Miinchen, 1869. Vogelsang. Sur le Labradorite colore ; Arch. Neerland., iii., 32, 1868. Schrauf. Labradorit; Ber. Ak., Wien, lx., 1869. Kosmann. Ueber das Schillern und den Dichroismus des Hypersthens ; Jahrb. Min., 1869, 368, 532 ; 1871, 501. Hose. Ueber den Asterismus der Krystallen ; Ber. Ak. Berlin, 1862, 614 ; 1869, 344 3. LUSTRE. The lustre of minerals varies with the nature of their surfaces. A varia- tion in the quantity of light reflected, produces different degrees of intensity of lustre ; a variation in the nature of the reflecting surface producer different kinds of lustre. A. The kinds of lustre recognized are as follows : 1. Metallic : the lustre of metals. Imperfect metallic lustre is expressed by the term sub-metallic. 2. Adamantine: the lustre of the diamond. When also sub-metallic, it is termed metallic-adamantine. Ex. cerussite, pyrargyrite. 3. Vitreous: the lustre of broken glass. An imperfectly vitreous lustre is termed sub-vitreous. The vitreous and sub-vitreous lustres are- the most common in the mineral kingdom. Quartz possesses the former in an emi- nent degree ; calcite, often the latter. 4. Itesinous : lustre of the yellow resins. Ex. opal, and some yellow varieties of sphalerite. 5. Pearly: like pearl. Ex. talc, brucite, stilbite, etc. When united with sub-metallic, as in hypersthenite, the term metallic-pearly is used. 6. Silky : like silk ; it is the result of a fibrous structure. Ex. fibrous calcite, fibrous gypsum. B. The degrees of intensity are denominated as follows: 1. Splendent : reflecting with brilliancy and giving well-defined images. Ex. hematite, cassiterite. 2. Shining : producing an image by reflection, but not one well defined. Ex. celestite. 3. Glistening : affording a general reflection from the surface, but no image. Ex. talc, chalcopyrite. 4. Glimmering: siffording imperfect reflection, and apparently from points over the surface. Ex. flint, chalcedony. A mineral is said to be dull when there is a total absence of lustre. Ex. chalk, the ochres, kaolin 168 PHYSICAL CHARACTERS OF MINERALS. The true difference between metallic and vitreous lustre is due to the effect which the different surfaces have upon the reflected light ; in general, the lustre is produced by the union of two simultaneous impressions made upon the eye. If the light reflected from a metallic surface be examined by a Nicol prism (or the dichroscope of Haidinger), it will be found that both rays, that vibrating in the plane of incidence and that whose vibra- tions are normal to it, are alike, each having the color of the material, only differing a little in brilliancy ; on. the contrary, of the light reflected by a vitreous substance, those rays whose vibrations are at right angles to the plane of incidence are more or less polarized, and are colorless, while those whose vibrations are in this plane, having penetrated somewhat into the medium and suffered some absorption, show the color of the substance itself. A plate of red glass thus examined will show a colorless and a red image. Adamantine lustre occupies a position between the others. The different degrees and kinds of lustre are often exhibited differently by unlike faces of the same crystal, but always similarly by like faces. The lateral faces of a right square prism may thus differ from a terminal, and in the right rectangular prism the lateral faces also may differ from one another. For example, the basal plane of apophyllite has a pearly lustre wanting in the prismatic planes. The surface of a cleavage plane in foliated minerals, very commonly differs in lustre from the sides, and in some cases the latter are vitreous, while the former is pearly. As shown by Haidinger, only the vitreous, adamantine, and metallic lustres belong to faces perfectly smooth and pure. In the first, the index of refrac- tion of the mineral is 1 '3 1 '8 ; in the second, 1-9 2 '5 ; in the third, about 2 '5. The pearly lustre is a result of reflection from numberless lamellae or lines within a translucent mineral, as long since observed by Breithaupt. IY. HEAT. The expansion of crystallized minerals by heat depends, as directly as their optical properties, on the symmetry of their molecular structure as shown in their crystalline form. The same three classes as before are dis- tinguished : A. Isometric crystals, where the expansion is in all directions alike. B. Isodiametric crystals, of the tetragonal and hexagonal systems. Ex- pansion vertically unlike that laterally, but in all lateral directions alike. C. Anisometric, of the orthorhombic, monoclinic, and triclinic systems. Expansion unlike in the three axial directions. The expansion by heat in the case of crystals may serve to alter the angles of the form, but it has been shown that the zone relations and the crystalline system remain con- stant. Mitscherlich found that in calcite there was a diminution of 8' 37" in the angle of the rhombohedron, on passing from 32 to 212 F. , the form thus approaching that of a cube, as the temperature increased. Dolomite, in the same range of temperature, diminishes 4' 4(5"; and in aragonite, between 63 and 212 F., the angle of the prism diminishes 2' 46", and 1-* : \-l increases 5' 30" ; in gypsum, / : i-l is increased 5' 24", /: 1, 4' 12", and \-i : i-i is diminished 7' 24". In some rhombohedrons, as of calcite, the vertical axis is lengthened (and the lateral shortened), while in others, like quartz, the reverse is true. The variation is such either way that the double refraction is diminished with the increase of heat ; for calcite possesses negative double refraction, and quartz, positive. The conductive power of a crystal depends, - as does expansion, on the symmetry of its crystalline form ; this is also true of its power of trans- ELECTRICITY MAGNETISM. 169 mitting or absorbing heat. It follows, moreover, from the analogous nature of heat and light, that heat rays are polarized by reflection, and by transmission in anisotrope media, in the same way as the rays of light. These subjects, considered solely in their relation to Mineralogy, are of minor importance ; they belong to works on Physics, and reference may be made to those whose titles are given in the Introduction, as also to the works of Schrauf and Groth. The change in the optical properties of crystals produced by heat has already been noticed (p. 151). Y. ELECTRICITY MAGNETISM. The electric and magnetic characters of crystals, as their relations to heat, bear but slightly upon the science of mineralogy, although of high interest to the student of physics. Frictional electricity. The development of electricity by friction is a familiar fact. All minerals become electric by friction, although the degree to which this is manifested depends upon their conducting or non- conducting power. There is no line of distinction among minerals, divid- ing them \\\^Q positively electric and negatively electric; for both kinds of electricity may be presented by different varieties of the same species, and by the same variety in different states. The gems are positively electric only when polished ; the diamond alone among them exhibits positive elec- tricity whether polished or not. The time of retaining electric excitement is widely different in different species, and topaz is remarkable for continu- ing excited many hours. Pressure also develops electricity in many minerals ; calcite and topaz are examples. Pyro-electricity. A decided change of temperature, through heat or cold, develops electricity in a large number of minerals, which are hence called pyro-electric. This property is most decided, and was first observed in a series of minerals which are hemimorphic or hemihedral in their development. The electricity in these minerals is of opposite character in the parts dissimilarly modified. Thus in tourmaline and calamine, the crystals of which are often differently modified at the two extremities, posi- tive and negative electricity are developed at these extremities or poles respectively. When the extremity becomes positive on heating it has been called the analogue pole, and when it becomes negative, it has been called the antilogue. The names were given by Rose and Riess, who investigated these phenomena. For a change of temperature in the opposite direction, that is, cooling, the reverse electrical effect is observed. Boracite, on whose crystals the -f- and tetrahedrons often occur, shows by heating the positive electricity for the faces of one tetrahedron and the negative for those of the other. Further investigations by Hankel and others (see Literature) have ex- tended the subject and shown that the phenomena of pyro-electricity belong to the crystals of a large number of species. Moreover, it is not, as once supposed, essentially connected with hemihedral development. The num- ber of poles, too, may be more than two, that is, the points at which posi 170 PHYSICAL CHARACTERS OF MINERALS. tive and negative electricity is developed. Thus for prelmite there Is a large series of such poles, distributed over the surface of a crystal. The investigations of Hankel have shown in general, that in crystals not hemi- hedrally developed, the same electricity is developed at both extremities of the same axis, and the distinction between positive and negative electricity is only shown by reference to the different crystallographic axes; on sym- metrically formed crystals of the isodiametric class the electricity is the same in all lateral directions, that is, on all prismatic planes, while different at the extremities of the vertical axis. Thermo-electricity. When two different metals are brought into con- tact, a stream of electricity passes from one to the other. If one is heated the effect is more decided and is sufficient to deflect more or less vigorously the needle of a galvanometer. According to the direction of the current produced by the different metallic substances, they are arranged in a thermo-electrical series; the extremes are occupied by antimony (+) and bismuth ( ), the electrical stream passing from bismuth to antimony. This subject is so far important for mineralogy, as it was shown by Bunsen that the natural metallic sulphides stand further off in the series than antimony and bismuth, and consequently by them a stronger stream is produced. The thermo-electrical relations of a large number of minerals was determined by Flight (Ann. Ch. Pharm., cxxxvi.). It was early observed that some minerals have varieties which are both 4- and . This fact was made use of by Rose to show a relation between the plus and minus hemihedral varieties of pyrite and cobaltite. The later investigations of Schrauf and Dana have shown, however, that the same peculiarity belongs also to glaucodot, tetradymite, skutterudite, danaite, and other minerals, and it is demonstrated by them that it cannot be dependent upon crystalline form, but, on the contrary, upon chemical composition. MAGNETISM. The magnetic properties of crystals are theoretically of interest, since they, too, like the optical and thermic, are directly dependent upon the form ; hence, with relation to magnetism they group themselves into the same three classes before referred to. All substances are divided into two classes, the paramagnetic and dia- magnetic, according as they are attracted or repelled by the poles of a mag- net. For purposes of experiment the substance in question, in the form of a rod, is suspended between the poles of the magnet, being movable on a horizontal axis. If of the first class, it will take a position parallel, and if of the second class, transverse, to the magnetic axis. By the use of a sphere it is possible to determine the relative amount of magnetic induction in different directions of the same substance. Experi- ment has shown that in isometric crystals the magnetism is alike in all directions ; in those optically uniaxial, that there is a direction of maximum and, normal to it, one of minimum magnetism ; in biaxial crystals, that there are three unequal axes of magnetism, the position of which may be determined. A few minerals have the power of exerting a sensible influence upon the magnetic needle, and are hence said to be magnetic. This is true of mag- netite and pyrrhotite (magnetic pyrites) in particular, also of franklinite, almandite, and other minerals, containing considerable iron protoxide (FeO). When such minerals in one part attract and in another repel the poles of TASTE AND ODOK. 171 the magnet, they are said to possess polarity . This is true of the variety of magnetite called in popular language loadstone. LITERATURE. ELECTBICITY.* Hankel. Ueber die Thermo-Electricitat der Krystalle; Pogg., xlix., 493; i, 237, 1840; Ixi. , 281. Rose u. Ries. Ueber die Pyro-Electricitat der Mineralien ; Ber. Ak. Berlin, 1843. Ueber den Zusammenhang zwischen der Form und der elektrisohen Polaritat del KrystaJUe ; Ber. Ak. Berlin, 1836. v. Kcbell Ueber Mineral-Eleetricitat ; Pogg., cxviii., 594, 1863. Bunsen. Thermo-Ketten von grosser Wirksamkeit ; Pogg., cxxiii., 505, 1864. FriedeL Sur les proprietes pyro-electrique desCristaux bons conducteurs de I'electricite : Aim. Ch. Phys., IV., xvii., 79, 1869.' Hose. Ueber den Zusammenhang zwischen hemiedrischer Krystallform und thermo-elek- trischem Verhalten beim Eisenkies und Kobaltglanz ; Pogg., cxh'i., 1, 1871. Schrauf u. E. S. Dana. Ueber die thermo-elektrischen Eigenschaften von Mineral varie- taten; Ber. Ak. Wien, Ixix., 1874 (Am. J. Sci., IIT., viii., 255). Hankel. Ueber die thermo-elektrischen Eigenschaften des Boracites ; Sachs. Ges. Wiss., vi., 151, 186o; ibid., viii., 323, 1866; Topaz, ix., 1870, 359; 10 Abhandlung, 1872, 21; cal- otte, beryl, etc., 1876. On MAGNETISM reference may be made to Faraday (Experimental Researches) ; Tyndall, Phil. Mag. ; Knoblauch and Tyndall, Pogg., Ixxxi., 481, 498 ; Ixxxiii., 384 ; Pflucker, Pogg., Ixxii., 315; IxxvL, 576; Ixxvii., 447; Ixxxvi., 1; Grailich u. von Lang, Ber. Ak., Wien, xxxii., 43 ; xxxiii., 439, etc., etc. VI. TASTE AKD ODOR. In their action upon the senses a few minerals possess taste, and others under some circumstances give off odor. TASTE belongs only to soluble minerals. The different kinds of taste adopted for reference are as follows : 1. Astringent / the taste of vitriol. 2. Sweetish astringent / taste of alum. 3. Saline ; taste of common salt. 4. Alkaline taste of soda. 5. Cooling / taste of saltpeter. 6. Bitter ; taste of epsom salts. 7. Sour : taste of sulphuric acid. ODOK. Excepting a lew gaseous and soluble species, minerals in the dry unchanged state do not give off odor. By friction, moistening with the breath, and the elimination of some volatile ingredient by heat or acids, odors are sometimes obtained which are thus designated : 1. Alliaceous j the odor of garlic. Friction of arsenical iron elicits this odor; it may also be obtained from arsenical compounds, by means of heat. 2. Horse-radish odor / the odor of decaying horse-radish. This odor is strongly perceived when the ores of selenium are heated. 3. Sulphureous j friction elicits this odor from pyrite and heat from many sulphides. 4. Bituminous ; the odor of bitumen. 5. Fetid / the odor of sulphuretted hydrogen or rotten eggs. It is eli- cited by friction from some varieties of quartz and limestone. 6. Argillaceous / the odor of moistened clay. It is obtained from sep- * Spft also on r>. 190. 172 PHYSICAL CHARACTERS OF MINERALS. pentine and some allied minerals, after moistening them with the breath ; others, as pyrargillite, afford it when heated. The FEEL is a character which is occasionally of some importance ; it is said to be smooth (sepiolite), greasy (talc), harsh, or meagre, etc. Some minerals, in consequence of their hygroscopic character, adhere to the to when brought in contact with it. SECTION IL SUPPLEMENTARY CHAPTER. I. COHESION AND ELASTICITY (pp. 119 to 122). THE etching-figures (Aetzfiguren) produced by the action of appropriate solvents upon the surfaces of crystals have been further investigated in the case of a considerable number of minerals, and the results have in some cases served to throw light upon the question as to which crystalline system a given species belongs. See the investigations of BAUMHAUEE of the etching-figures of lepidolite, tourmaline, topaz, calamine, Jahrb. Min., 1876, i. ; pyromorphite, mimetite, vanadinite, ib., 1876, 411 ; of ad nl aria, albite, fluorite, ib., 1876, 602 ; of leucite, Z. Kryst., i.,257, 1877; quartz, ib., ii., 117, 1878; mica (zinnwaldite), ib., iii., 113, 1878; bora-cite, ib., iii., 337, 1879; perofskite, ib., iv., 187, 1879; nephelite, ib., vi., 209, 1882. (For earlier papers giving results of etching experiments on muscovite, garnet, linnaeite, biotite, epidote, apatite, gypsum, in Ber. Ak. Miinchen, 1874, 245 ; 1876, 99.) On the etching-figures of alum, see FR. KLOCKE, Z. Kryst., ii., 126, 1878 ; of the different micas, F. J. WIIK, Oefv. Finsk. Vet. Soc., xxii., 1880. On the artificial twins (twinning-plane ^R) of calcite produced by simple pressure with a knife-blade on the obtuse edge of a cleavage frag- ment, see BAUMHAUER, Zeitschr. Kryst., iii., 588. 1879 ; BREZINA, ib., iv., 518, 1880. The fragment should have a prismatic form, say 6-8 mm. in length and 3-6 mm. in breadth, and be placed with the obtuse edge on a firm horizontal support. The blade of an ordinary table-knife is then applied to the other obtuse edge, as at a (f. 412A), and pressed gradually and firmly down. The result is that the portion of the crys- tal lying between a and b is reversed in position, as if twinned parallel to the horizontal plane %R. The twinning surface, gee, is perfectly smooth, and the re-entrant angle corresponds very exactly with that required by theory (Brezina). Earlier observations by Pfaff and Keusch have shown that twin lamellae ( %R) may be produced in a cleavage mass of calcite of prismatic form, by simple pressure exerted perpendicular to a straight ter- minal plane. Such twinning lamellae are often observed in thin sections of a crystalline limestone when examined in polarized light under the micro- scope. On the application of the fracture-figures (Schlagfiguren) in the optical examination of the mica species see Bauer, ZS. G. Ges.. xxvi., 137, 1874 (for earlier papers see p. 122) ; Tschermak, Z. Kryst., ii., 14, 1877. On the occurrence of Gleitflaclien on galena see Bauer, Jahrb. Min., 1882, i., 183. II. SPECIFIC GRAVITY (pp. 123, 124). Use of a Solution of high Specific Gravity. A solution of mercuric iodide in potassium iodide (Hg 2 I in KI) affords a means of readily ob- taining the specific gravity of any mineral not acted upon by it chemically, 173 174 SPECIFIC GRAVITY. and for which G. < 3-1 ; and also of separating from each other minerals of different densities, when intimately mixed in the form of small fragments. The solution is called the Sonstadt solution, having been first proposed by E. SOXSTADT in 1873 (Chem. News, xxix., 127) ; its application for the above objects was proposed by CHURCH in 1877 (Min. Mag., i., 237) ; and the method elaborated by THOULET in 1878 (0. R., Feb. 18, 1878 ; Bull. Soc. Min., ii., 17, 189, 1879), and later by GOLDSCHMIDT (J. Min., Beil.- Bd.,i., 179, 1881). The solution is prepared (Goldschmidt) as follows : The KI and HgJ are taken in the ratio of 1:1-239, and introduced into a volume of water slightly greater than is required to dissolve them (say 80 cc. to 500 gr. of the salts) ; the solution is then filtered in the usual way and afterward evap- orated down in a porcelain vessel, over a water-bath, until a crystalline scum begins to form, or when a fragment of tourmaline (G. =3-1) floats ; on cooling, the solution has its maximum density. If the mercuric iodide is not quite pure a small quantity in excess of that required by the above ratio must be taken. The highest specific gravity for the solution obtained by Gold- schmidt was 3-196, a solution in which fluorite floats. This maximum is not quite constant, varying with the moisture of the atmosphere and with the temperature. The method of using the solution for obtaining the specific gravity of small fragments of any mineral is, according to Goldschmidt, as follows : The fragments are introduced into a tall beaker, say 40 cc. capacity, with a por- tion of the concentrated solution ; then water is added drop by drop (or r, dilute solution of the same for high densities) from a burette, until the frag- ments, after being agitated, are just suspended, and remain so without either rising or falling. This process requires care and precision, since the princi- pal error to which the method is liable is involved here. The solution is now introduced into a little glass flask, graduated say to hold just 25 cc., and this amount having been exactly measured off, the weight is taken ; then the solution is poured back into the original beaker and the fact noted whether the fragments still remain suspended ; then introduced again into the flask and weighed, and so a third time. The average result of the three weigh- ings, diminished by the known weight of the flask and divided by 25, gives the specific gravity. The exact measurement of the 25 cc. is a matter of importance, and is most easily accomplished by adding at first a little more than enough and then removing the excess by a capillary tube or a piece of filter paper ; the reading is best taken from the lower edge of the meniscus. It is not necessary to clean and dry the flask each time. The weighing need not be very accurate, as an error of 25 mgr. only involves a change of a unit in the third decimal place (-001). The describer readily obtained results accurate to three decimals. The advantages of the method are that it is readily applicable in the case of small fragments (dust is to be avoided), it is easily used, and any want of homogeneity in the mineral makes itself at once apparent. This solution is also most useful in affording a means of separating me- chanically different minerals when intimately mixed together ; as, for example, in a fine-grained rock. For this purpose the rock must first be pulverized in a steel mortar, then put through a sieve, or better, through several, so as to obtain a series of sets of fragments of different size ; the dust is rejected. The fragments should be examined under the microscope, to see that they are homogeneous ; the largest fragments satisfying this condition will give the best results. SPECIFIC GRAVITY. 175 According to Thoulet the best method of procedure is to first determine the density of the fragments approximately by inserting typical ones in a series of samples of the solution of gradually Increasing density. This point deter- mined, some 60 cc. of the concentrated solution are introduced into the tube, A, and 1 or 2 grams of the weighed fragments (f added. Then the tightly-fitting rubber cork with the tube, F, is inserted ; the tube, F, is connected by a rubber tube with an air pump, and the air bubbles are in this way removed from the powder. The heavy parts of the mixture fall to the bottom, and are removed by opening the stop-cock at (7, and are washed out by use of the tube, B ; the other fragments float. Now a quantity of distilled water is added in order so to dilute the solu- tion as to cause the next heavier portions to sink, as determined by the equation tr, = - A) A 1 I where v = volume of the solution, D its specific gravity, Vi the volume of the water, and A the density desired. The cock at D is shut and that at C opened and air blown through the side tube, so as to mix the solution thoroughly ; then the original operation is repeated, and so on. GOLDSCHMIDT recommends the following method of procedure. The separation is conducted in a small slender beaker of about 40-50 cc. capacity. Instead of the series of standard solutions (the density of which is liable to alter) a series of minerals of y known specific gravity are used as indicators ; by means of them it is easy to determine the limits as to density which are required to make the separation desired, the constituent minerals having been determined by the microscope. For example, suppose it to be desired to separate augite, horn- blende, oligoclase, and orthoclase ; labradorite and albite are taken as indica- tors. Augite falls at once in the concentrated solution ; if diluted till the lab- radorite sinks, all the hornblende goes down ; before or with the albite the oligoclase sinks, and the orthoclase is left suspended. By the use of the 25 cc. flask, the exact specific gravity in each case can be obtained if desired. The operation of separation goes on as follows : The rock powder and the indicators are inserted with say 30 cc. of the concentrated solution into the beaker spoken of, then the whole is stirred vigorously and allowed to settle, and the lighter part decanted off. The heavier part which has settled is removed with a jet from a wash bottle, without disturbing the lighter fragments adhering to the upper part of the beaker. The latter are subsequently removed, washed, dried, again washed in the solution, and added to the rest for the further separation. If the separations accomplished in this way are not complete, they may be repeated most conveniently with the Thoulet apparatus. Under favorable conditions, and if the manipulation is skilful, the separation can be accom- plished with considerable exactness. For the best results the process must be repeated several times. THOULET recommends also (1. c.) this method of determining the specific gravity of small fragments of minerals. A float of wax (inclosing any suit- able solid body) is made with a specific gravity of from 1 to 2. The frag- 176 SPECIFIC GRAVITY. ments of the mineral are lightly pressed into the wax float, and this intro- duced into the Sonstadt solution, of such strength that the float remains in equilibrium at any level. If P, V, D are respectively the weight, volume, / p \ and density of the float alone I V = j and JP, v, d the same values for the fragments alone ( v = - J and finally A the density of the liquid in which the loaded float is in equilibrium ; then ni has proposed (Bull. Soc. Min., iii., 46, 1880) the following method for separating different minerals intimately mixed, which is applicable in cases where their density is greater than that of the Sonstadt solution. Lead chloride and zinc chloride, m appropriate proportions, are fused together (at 400 C.) and by this means a transparent or translucent solution is obtained of high specific gravity. Briefly, the method of procedure is as follows : A conical tube of glass is taken, of about 12 to 15 cc. capacity ; this will allow of the treatment of 4 or 5 grams of the mixed minerals. The chlorides of lead and zinc, in approximately the proper proportions, are placed in the glass tube and this, surrounded by sand, inserted in a platinum crucible. On the ap- plication of heat the zinc chloride fuses first, but finally a homogeneous mix- ture of the two liquids is obtained. Now, little by little, the mineral frag- ments are introduced and the liquid stirred ; then on allowing it to stand for a moment the heavier particles sink to the bottom and the lighter ones float. The tube is now removed from its sand bath and cooled rapidly. When solidified but still hot the glass may be plunged into cold water, in which case it will be broken and the fragments can be removed, so that the fused mass within can be obtained free. Subsequently the fragments in the upper and lower parts of the mass can be separated by solution in water to which a little acetic acid has been added. The author has operated on minerals vary- ing from wolframite (G. = 7-5) to beryl (G. = 2-7), and in some samples of sand has separated as many as 12 constituent minerals. D. KLEIN- (Bull. Soc. Min., iv., 149, 1881) has proposed to use one of the boro-tungstate salts in the place of the Sonstadt solution for the separation of minerals whose specific gravity is as high as 3-6. The most suitable salt for this purpose is the cadmium compound, JLCdaBaWQC^ + ie aq. It dis- solves at 22 C. in about -fa its weight of water, and crystallizes out both on evaporation and cooling. At 75 C. it melts (best over a water-bath) in its water of crystallization to a yellow liquid, on the surface of which a spinel crystal (G. =3 -55) floats. By the application of the Thoulet appara- tus (see above), so arranged as to allow of the application of heat, solutions of any specific gravity, hot or cold, from 1 to 3-6, can be obtained. A num- ber of common minerals (e. g. chrysolite, epidote, vesuvianite, some varie- ties of amphibole and mica) can be separated by the use of this liquid, while the Sonstadt solution is inapplicable. The fragments under examination must be free from the carbonates of calcium or magnesium, which decom- pose the boro-tungstate of cadmium. TOTAL KEFLECTROMETEE. 177 III. LIGHT (pp. 125-168). Measurement of Indices of Refraction. For the determination of the indices of refraction of crystallized minerals, various improvements have been made in former methods and some new methods devised. Use of the Horizontal Goniometer. The ordinary method for determining the index of refraction, requiring the observation of the angle of minimum deviation (d) of a light-ray on passing through a prism of the given mate- rial, having a known angle (<*), and with its edge cut in the proper Direc- tion, has already been mentioned (p. 128). The two measurements required in this case can be readily made with the horizontal goniometer of Fuess, described on p. 115. In this instrument the collimator is stationary, being fastened to a leg of tho tripod support, but the observing telescope with, the verniers moves freely. In the use for this object the graduated circle is to be clamped, and the screw attachments connected with the axis carrying the support, and the vernier circle and observing telescope are to be loosened. The method of observation requires no further explanation (see also pp. 141, 150). Total Reflectrometer.J?. KOHLRAUSCH has shown (Wied. Ann., iv., 1,1878) that the principle of total reflection (p. 128) may be made use of to deter- mine the index of refraction in cases where other methods are inapplicable. No prism is required, but only a small fragment having a single polished surface ; this may be cut in any direction for an isotrope medium ; it should be parallel to the vertical axis in a uniaxial crystal, and perpendicular to the acute bisectrix with a biaxial crystal. The arrangements required are, in their simplest form, a wide-mouthed bottle filled with carbon disulphide (refractive index 1-0) ; the top of this is formed by a fixed graduated circle, and a vertical rod, with a vernier attached, passes through the plate and car- ries the crystal section on its extremity, immersed in the liquid. The angle through which the crystal surface lying in the axis is turned is thus meas- ured in the same way as in f. 412H, by the vernier on the stationary gradu- ated circle. The front of the bottle is made of a piece of plate glass, and through this passes the horizontal observing telescope, arranged for parallel light. The rest of the surface of the bottle is covered with tissue-paper, through which the diffuse illumination from say a sodium flame has access ; the rear of the bottle is suitably darkened. When now the observer looks through the telescope, at the same time turning the axis carrying the crystal section, he will finally see, if the source of illumination is in a proper oblique direction, a sharp line marking the limit of the total reflection. The angle is then measured off on the graduated circle, when this line coincides with one of the spider lines of the telescopo. Now the crystal is turned in the opposite direction, and the angle again read off. Half the observed angle (2a) is the angle of total reflection ; if n is the refractive index of the car- bon disulphide, then the required refractive index is equal to n sin a. Under favorable conditions the results are accurate to four decimal places. This method is limited, of course, to substances whose refractive index is less than that of the liquid medium with which the bottle is filled. With a sec- 19 178 MEASUREMENT OF INDICES OF REFRACTION. tion of a uniaxial crystal, whose surface is most conveniently parallel to the vertical axis, the method is essentially the same. The section is so placed that in it the direction normal to the optic axis is horizontal. The light will be here separated into two rays, having separate limiting surfaces, and with a Nicol prism it is easy to determine which of them corresponds to the vibrations parallel and perpendicular, respectively, to the optic axis. For biaxial crystals the surface should be normal to the acute bisectrix. This will give by actual observation the values of a and y, and if %E, the appa- rent axial angle in air, is known, then /?, the mean index can be calculated (see p. 150). Instead of carbon disulphide the Sonstadt solution, with n = 1-73, can be employed. The total reflectrometer of Kohlrausch has been adapted in practical form to the horizontal goniometer (f. 372A) of Fuess (see Liebisch, Ber. Ges. Nat. Fr. Berlin, Dec. 16, 1879). Klein has sug- gested some improvements ( J. Min., 1879, 880), and Bauer (J. Min., 1882, i., 132) has shown how the method can be simply applied to the instrument for the measurement of the optic axial angle (f. 412n), and without its modification in any important respect. QUINCKE (abstract in Z. Kryst., iv., 540) has described another method for obtaining the refractive index of a substance on the principle of total reflection. In a word, it consists in observing on a spectrometer the limit- ing angle of total reflection for a plane section of the substance to be inves- tigated, brought with oil of cassia between two flint glass prisms. SORBY (Proc. Eoy. Soc., xxvi., 384; Min. Mag., i., 97, 194; ii., 1, 103) has developed the method of obtaining the refractive index of a transparent medium, first described by Duke de Chaulnes (1767), and has shown that under suitable conditions it allows of determinations being made with con- siderable accuracy. This method consists in observing the distance (d) which the focal distance of the objective is changed when a plane-plane plate of known thickness (t) is introduced perpendicular to the axis of the microscope between the objective and the focal point here Sorby makes use of a glass micrometer, upon which two systems of lines perpendicular to each other are ruled. The micrometer screw at g, in the Kosenbusch microscope (f. 412K, p. 181), makes it possible to measure the distance through which the tube is to be raised and lowered down to -001 mm. ; consequently both t and d can be obtained with a high degree of accuracy. BAUER has shown that the indices of refraction may be obtained with con- siderable accuracy from measurements, in the plane of the axes, of the distances between the black rings in the interference figures as seen in homogeneous light. The relation between these distances and the optical axes of elasticity was established by Neumann (Pogg. Ann., xxxiii., 257, 1834). Bauer has made use of this method in the case of muscovite (Ber. Ak. Berlin, 1877, 704). He has also developed the same method as applied to uniaxial crystals and employed it in the case of brucite (ib., 1881, 958). Polarization Instruments. Polariscope. The earlier forms of polari scope for converging and for par- POLARIZATIOX INSTRUMENTS POLABI8COPE. 179 412c. 412E. ol of?*' aS arran ed by Groth and constructed bv Fuess, are shown in fi 10'. Barytocalcite, 95 8'. BSO 4 Dreelite, 93-94. Anglesite, 103 38'. Glauberite, 83-83 30'. RS0 4 +nRCO 3 Susannite, 94. Leadhillite, 103 16'. Lanarkite, 84. 202 CHEMICAL MINERALOGT. Calcite, aragonite, and barytocalcite form an undoubted case of trimor phism, as has already been shown. Dreelite, anglesite, and glauberite constitute another like series, and moreover it is closely parallel in angle with the former. In the third line we have the snlphato-carbonate susan- nite near dreelite in angle, leadhillite (identical with susannite in composi- tion) near anglesite, and lanarkite, another sulphato-carbonate, near glau- berite, forming thus a third parallel line. The sulphuric acid in these sul- phato-carbonates dominates over the carbonic acid, and gives the form of the sulphates enumerated in the second line of the table. CHEMICAL EXAMINATION OF MINERALS. The chemical characters of minerals are ascertained (a) by the action of acids and other reagents ; (b) by means of the blowpipe assisted by a few chemical reagents ; (c) by chemical analysis. The last method is the only one by which the exact chemical composition of a mineral can be deter- mined. It belongs, however, wholly to chemistry, and it is unnecessary to touch upon it here except to call attention to the remarks already made (p. 160) upon the essential importance of the use of pure material for analysis. The various tests and reactions of the wet and dry methods are important, since they often make it possible to determine a mineral with very little labor, and this with the use of the minimum amount of material. a. Examination in the Wet Way. The most common chemical reagents are the three mineral acids, hydro- chloric, nitric, and sulphuric. In testing the powdered mineral with these acids, the important points to be noted are: (1) the degree of solubility, and (2) the phenomena attending entire or partial solution ; that is, whether a gas is evolved, producing effervescence, or a solution is obtained without effervescence, or ail insoluble constituent is separated out. Solubility. In testing the degree of solubility hydrochloric acid is most commonly used, though in the case of sulphides, and compounds of lead and silver, uitric acid is required. Less often sulphuric acid, and aqua regia (nitro-hydrochloric acid), are resorted to. Many minerals are completely soluble without effervescence : among these are some of the oxides, hematite, limonite, gothite, etc., some sulphates, many phosphates and arseniates, etc. Solubility with effervescence takes place when the mineral loses a gaseous ingredient, or when one is generated by the mutual decomposition of acid and mineral. Most conspicuous here are the carbonates, all of which dissolve with effervescence, giving off carbonic acid (properly carbon dioxide, CO 2 ), though some of them only when pulverized, or again, on the addition of heat. In applying this test dilute hydrochloric acid is employed. Sul- phuretted hydrogen (H 2 S) is evolved by some sulphides, when dissolved hi hydrochloric acid: this is true of sphalerite, stibnite, greenockite, etc. Chlorine is evolved by oxides of manganese and also chromic and vanadic acid salts, when dissolved in hydrochloric acid. Nitric peroxide is given off by many metallic minerals, and also some of the lower oxides (cuprite, etc.), when treated with nitric acid. CHEMICAL EXAMINATION OF MINKBALS, 203 The separation of an insoluble ingredient takes pla ce : With many sili- cates, the silica separating sometimes as a fine powder, and again as a jelly ; in the latter case the mineral is said to gelatinize (sodalite, analcite). In order to test this point the finely pulverized silicate is digested with strong hydrochloric acid, and the solution afterward slowly evaporated nearly to dryness. With a considerable number of silicates the gelatinization takes place only after ignition ; while others, which ordinarily gelatinize, are rendered insoluble'by ignition. With many sulphides a separation of sulphur takes place when they are treated with nitric acid. Compounds of titanic and tungstic acids are decomposed by hydrochloric acid with the separation of the oxides named. The same is true of salts of molybdic and vanadic acids, only that here the oxides are soluble in an excess of the acid. Compounds containing silver, lead, and mercury give with hydrochloric acid insoluble residues of the chlorides. These compounds are, however, soluble in nitric acid. When compounds containing tin are treated with nitric acid, the stannic oxide separates as a white powder. A corresponding reaction takes place under similar circumstances with minerals containing arsenic and antimony. Insoluble minerals. A large number of minerals are not sensibly attacked by any of the acids. Among these may be named the following oxides: corundum, spinel, chromite, diaspore, rutile, cassiterite, quartz; also cerargyrite ; many silicates, titanates, tantalates, and columbates ; also the sulphates (barite, celestite, anglesite); many phosphates (xenotime, lazulite, childrenite, ainblygonite), and the borate, boracite. b. ^Examination of Minerals by means of the Blowpipe. Blowpipe. The simplest form of the blowpipe is a tapering tube of brass (f. 413, 1), with a minute aperture at the extremity. A chamber is advantageously added (f. 413, 2) at o, to receive the condensed moisture, and an ivory mouth-piece is often very convenient. In the better forms of the instrument (see f. 413, 3), the tip is made of solid platinum (/"), which admits of being readily cleaned when necessary. Operations with the blowpipe often require an un inter- mitted heat for a considerable length of time, and always longer than a single breath of the operator. It is therefore requisite that breath- ing and blowing should go on together. This may be difficult at first, but the necessary skill or tact is soon acquired. Blowpipe-flame. The best and most con- venient source of heat for blowpipe purposes is ordinary illuminating gas. The burner is a simple tube, flattened at the top, and cut off a little obliquely ; it thus furnishes a flame of convenient shape. A similar 204 CHEMICAL MINKRALOGY. jet may also be used in conjunction with the ordinary Bunsen burner, it being so made as to slip down within the outer tube, and cut off the supply of air, thus giving a luminous flame. The gas flame required need not be more than an inch and a half in height. In place of the gas, a lamp fed with olive oil will answer, or even a good candle. The jet of the blowpipe is brought close to the gas flame on the higher Bide of the obliquely terminated burner. The arm of the blowpipe is inclined a little downward, and the blast of air produces an oblique conical flame of intense heat. This blowpipe flame consists of two cones : an inner of a blue color, and an outer cone which is yellow. The heat is most intense just beyond the extremity of the blue flame, and the mineral is held at this point when ite fusibility is to be tested. The inner flame is called the .REDUCING FLAME (R.F.) ; it is characterized by the excess of the carbon or hydrocarbons of the gas, which at the high temperature present tend to combine with the oxygen of the mineral brought into it, or in other words, to reduce it. The best reducing flame is produced when the blowpipe is held a little distance from the gas flame ; it should retain the yellow color of the latter. The outer cone is called the OXIDIZING FLAME (O.F.) ; it is characterized by the excess of the oxygen of the air over the carbon of the gas to be com- bined with it, and has hence an oxidizing effect upon the assay. This flame is best produced when the jet of the blowpipe is inserted a very little in the gas flame ; it should be entirely non-luminous. Supports. Of other apparatus required, the most essential articles are those which serve to support the mineral in the flame ; these supports are : (1) charcoal, (2) platinum forceps, (3) platinum wire, and (4) glass tubes. (1) Charcoal is especially useful as a support in the case of the examina- tion of metallic minerals, where a reduction is desired. It must not crack when heated, and should not yield any considerable amount of ash on com- bustion ; that made from soft wood (pine or willow) is the best. Pieces of convenient size for holding in the hand are employed ; they should have a smooth surface, and a small cavity should be in it made for the mineral. (2) A convenient kind of platinum forceps is represented in f. 414 ; it is made of steel with platinum points. These open by means of the pins 414 ; other forms open by the spring of the wire in the handle. Care must taken not to heat any substance (e.g., metallic) in the forceps, which when fused might injure the platinum. (3) Platinum wire is employed with the use of fluxes, as described in another place. (4) The glass tubes required are of two kinds : closed tubes, having only one open end, about four inches long ; and open tubes, having both ends open, four to six inches in length. Both kinds can be easily made by the student from ordinary tubing (best of rather hard glass), having a bore of 1 to J of an inch. CHEMICAL EXAMINATION OF MINERALS. 205 In the way of additional apparatus, the following articles are useful ; they need no special description : hammer, small anvil, three-cornered file, mag- net, pliers, pocket-lens, and a small mortar, as also a few of the test-tubel, etc., used in the laboratory. Chemical reagents. The commonest reagents employed are the fluxes^ TIZ., soda (sodium carbonate) ; salt of phosphorus (sodium-ammonium phosphate); and borax (sodium biborate). The method of using them is spoken of on p. 208. Nitrate of cobalt in solution is also employed. It is conveniently kept in a small bulb from which a drop or two may be obtained as it is needed. This is used principally as a test for aluminum or magnesium with infusible minerals, as remarked beyond. The fragment of the mineral held in the forceps is first ignited in the blowpipe name, a drop of the cobalt solution is placed on it, and then it is heated again ; the presence of either constitu- ent named is manifested by the color assumed by the ignited mineral. It is also used as a test for zinc. Potassium bisulphate and calcium fluoride (fluorite) in powder, metallic magnesium (foil or wire), and tin foil, are other reagents, the use of which is explained later. Test-papers are also needed, viz., blue litmus paper, and turmeric paper. The wet reagents required are : the ordinary acids, and most important of these hydrochloric acid, generally diluted one-half for use, and also barium chloride, silver nitrate, ammonium molybdate. The blowpipe investigation of minerals includes their examination, (1) in the platinum-pointed forceps, (2) in the closed tube, (3) in the open tube, (4) on charcoal, and (5) with the fluxes. (1) Examination in the forceps. The most important use of the plati- num-pointed forceps is to hold the fragment of the mineral while its fusi- bility is tested. The following practical points must be regarded : (1) Metallic minerals, which when fused may injure the platinum, should be examined on charcoal ; (2) the fragment taken should be thin, and as small as can conveniently be held ; (3) when decrepitation takes place, the heat must be applied slowly, or, if this does not prevent it, the mineral may be powdered and a paste made with water, thick enough to be held in the forceps or on the platinum wire ; or the paste may, with the same end in view, be heated on charcoal ; (4) the fragment whose fusibility is to be tested must be held in the hottest part of the flame, just beyond the extremity of the blue cone. In connection with the trial of fusibility, the following phenomena may be observed : (a) a coloration of the flame ; (b) a swelling up (stilbite), or an exfoliation of the mineral (vermiculite) ; or (c) a glowing without fusion (calcite) ; and (d) an intumescence, or a spirting out of the mass as it fuses (scapolite). The color of the mineral after ignition is to be noted ; and the nature of the fused mass is also to be observed, whether a clear or blebby glass is obtained, or a black slag, or whether magnetic or not, etc. The ignited fragment, if nearly or quite infusible, may be moistened with the 5 cobalt solution and again ignited (see above) ; also, if not too fusible, it may, after treatment in the forceps, be placed upon a strip of moistened turmeric paper, in which case an alkaline reaction shows the presence of the alkaline earths. . All grades of fusibility exist among minerals, from those 206 CHEMICAL MINERALOGY. which fuse in large fragments in the flame of the candle (stibnite, see below), to those which fuse only on the thinnest edges in the hottest blow- pipe flame (bronzite) ; and still again there are a considerable number which are entirely infusible (e.g., corundum). The following scale of fusibility, proposed by von Kobell, is made use of : 1, stibnite ; 2, natrolite ; 3, almandine garnet ; 4, actiiiolite ; 5, ortho- clase ; 6, bronzite. A little practice with these minerals will show the student what degree of fusibility is expressed by each number, and render him quite independent of the table; he will thus be able also to judge of his power to produce a hot flame by the blowpipe, which requires practice. Flame coloration. When coloration is produced it is seen on the exterior portion of the flame, and is best observed when shielded from the direct light. The presence of soda, even in small quantities, produces a yellow flame, which (except in the spectroscope) more or less completely masks the coloration of the flame due bo other sub- stances ; phosphates and borates give the green flame in general best when they have been pulverized and moistened with sulphuric acid ; moistening with hydrochloric acid makes the coloration in many cases (barium, strontium) more distinct. The colors which may be produced, and the substances to whose presence they are due, are as follows : (1) yellow, sodium / (2) violet, potassium ; (3) purple-red, lithium red, strontium / yellowish-red, calcium (lime) ; (4) yellowish-green, barium, molybdenum ; emerald-green, copper / bluish- green, phosphorus (phosphates) ; yellowish-green, boron (borates) ; (5) blue, azure-blue, copper chloride ; light-blue, arsenic ; greenish-blue, antimony. (2) Heating in the closed tube. The closed tube is employed to show the effect of heating the mineral out of contact with the air. A small frag- ment is taken, or sometimes the powdered mineral is inserted, though in this case with care not to soil the sides of the tube. The phenomena which may be observed are as follows : decrepitation, as shown by fluorite, calcite, etc. ; glowing, as exhibited by gadolinite ; phosphorescence, of which fluorite is an example ; change of color (limonite), and here the color of the mineral should be noted both when hot, and again after cooling; fusion ; giving off oxygen, as mercuric oxide ; yielding water at a low or high temperature, which is true of all hydrous minerals ; yielding acid or alkaline vapors, which should be tested by inserting a strip of moistened litmus or turmeric paper in the tube ; yielding a sublimate, which condenses in the cold part of the tube. Of the sublimates which form in the tube, the following are those with which it is most important to be familiar: Sublimate yellow, sulphur; dark brown-red when hot, and red or reddish-yellow when cold, arsenic sulphide; brilliant black, arsenic (also giving off a garlic odor); black when hot, brown-red when cold, formed near the mineral by strong heating, antimony oxy sulphide ; dark-red, selenium (also giving the odor of decay- ing horseradish) ; sublimate consisting of small drops with metallic lustre, teU-urium ; sublimate gray, made up of minute metallic globules, mercury ; sublimate black, lustreless, red when rubbed, mercury sulphide. (3) Heating in the open tube. The small fragment is placed in the tube about an inch from the lower end, the tube being inclined sufficiently to prevent the mineral from slipping out. The current of air, passing through CHEMICAL EXAMINATION OF MINEEALS. 207 the tube during the heating process, has an oxidizing effect. The special phenomena to be observed are the formation of a sublimate and the odor of the escaping gases. The acid or alkaline character of the vapors are tested in the same way as with the closed tube. Fluorides, when heated in the open tube with previously fused salt of phosphorus, yield hydrofluoric acid, which gives an acid reaction with test-paper, has a peculiar pungent odor, and corrodes the glass. The sublimates which may be formed, as far as they differ from those already mentioned, as obtained in the closed tube, are as follows : Subli- mate, white and crystalline, volatile, arsenous oxide ; white, near the min- eral crystalline, fusible to minute drops, yellowish when hot, nearly color less when cold, molybdic oxide / sublimate white, yielding dense white fumes, at first mostly volatile, forming on the upper side ot the tube, and afterward generally non-volatile on the under side of the tube, antimonous and antimonic oxides ; sublimate dark brown when hot, lemon-yellow when cold, fusible, bismuth oxide; sublimate gray, fusible to colorless drops, tellurous oxide / sublimate steel-gray, the upper edge appearing red, selenium / sublimate bright metallic, mercury. The odors which may be perceived are the same as those mentioned in the following article. (4) Heating alone on charcoal. The substance to be examined is placed in a shallow cavity ; it may simply be a small fragment, or, where the mineral decrepitates, it may be powdered, mixed with water, and thus the material employed as a paste. The points to be noticed are : (a) The odor given off after short heating. In this way the presence of eulphur, arsenic (garlic odor), and selenium (odor of decayed horseradish), may be recognized. (6) Fusion. In the case of the salts of the alkalies the fused mass is absorbed into the charcoal ; this is also true, after long heating, of the car- bonates and sulphates of barium and strontium. (c) The infusible residue. This may (1) glow brightly in the O.F., indi- cating the presence of calcium, strontium, magnesium, zirconium, zinc, or tin. " (2) It may give an alkaline reaction after ignition : alkaline earths. (3) It may be magnetic, showing the presence of iron. (d) The sublimate. By this means the presence of many of the metals may be determined. The color of the sublimate, both near the assay (N), and at a distance (D) ; as also when hot and when cold is to be noted. The most important of the sublimates, with the metals to which they are due, are contained in the following list : Sublimate, steel-gray (N)^ and dark gray (D), in R.F. volatile with a blue flame, selenium (also giving a peculiar odor) ; white (N) and red or deep yellow (D), in RF. volatile with green flame, tellurium ; white (N) and grayish (D), arsenic (giving also a peculiar alliaceous odor); white (N) and bluish (D), antimony (also giving off dense white fumes). Reddish-brown, silver ; dark orange-yellow when hot, and lemon- yellow when cold (N), also bluish-white (D), bismuth / dark lemon-yellow when hot, sulphur-yellow when cold, lead; red-brown (N) and orange-yellow (D), cadmium ; yellow when hot, white on cooling, sine (the sublimate becomes green if moistened with cobalt solution and again ignited); faint yellow when hot, white on cooling, tin (the sublimate 'Become? bluish-green when ignited after being moistened with the cobalt 208 CHEMICAL MINERALOGY. solution, in the RF. it is reduced to metallic tin) ; yellow, sometime? crys talline when hot, white when cold (N), bluish (D), molybdenum (i;j O.F the sublimate volatilizes, leaving a permanent stain of the oxide, in RF. gives an azure blue color when touched for a moment with the flame). (5) Treatment with, the fluxes. The three fluxes have been mentioned oil p. 205. They are used either on charcoal or with the platinum wire. If the latter is employed it must have a small loop at the end ; this is heated to redness and dipped into the powdered flux, and the adhering particles fused to a bead ; this operation is repeated until the loop is filled. Some- times in the use of soda the wire may at first be moistened a little to cause it to adhere. When the bead is ready it is, while hot, brought in contact with the powdered mineral, some of which will adhere to it, and then the heating process may be continued. Very little of the mineral is in general required, and the experiment should be commenced with a minute quantity and more added if necessary. The bead must be heated successively in the reducing and oxidizing flames, and in each case the color noted when hot and when cold. The phenomena connected with fusion, if it takes place, must also be observed. Minerals containing sulphur or arsenic, or both, must be first roasted, that is, heated on charcoal, first in the oxidizing and then in the reducing flame, till these substances have been volatilized. If too much of the mineral has been added and the bead is hence too opaque to show the color, it may, while hot, be flattened out with the hammer, or drawn out into a wire, or part of it may be removed and the remainder diluted with more of the flux. BORAX. The following list enumerates the different colored beads obtained with borax, and also the metals to the presence of whose oxides the colors are due : Colorless / silica, aluminum, the alkaline earths, etc. (both O.F. and RF.) ; also silver, zinc, cadmium, lead, bismuth, and nickel, O.F., and also RF., after long heating, but when first heated, gray or turbid ; K.F., man- ganese. Yellow / in O.F., titanium, tungsten, and molybdenum, also zinc and cadmium, when strongly saturated and hot / vanadium (greenish when hot) ; iron, uranium, and chromium, when feebly saturated. lied to brown ; in O.F., iron, hot (on cooling, yellow) ; O.F., chromium, hot (yellowish-green when cold) ; O.F., uranium, hot (yellow when cold) ; nickel, manganese, cold (violet when hot). Red ; RF., copper, if highly saturated, cold (colorless when hot). Violet / O.F., nickel, hot (red-brown to brown on cooling) ; O.F., man- ganese. Blue; O.F. arid E.F., cobalt, both hot and cold; O.F., copper, cold (when hot, green). Green O.F., copper, hot (blue or greenish-blue on cooling), R.F., bottle- green ; O.F., chromium, cold (yellow to red when hot), RF., emeral d -green ; O.F., vanadium, cold (yellow when hot), RF., chrome-green, cold (brown- ish when hot) ; RF., uranium, yellowish-green (when highly saturated). SALT OF rnospHORUS. This flux gives for the most part reactions similar to those obtained with borax. The only cases enumerated here are those which are distinct, and hence those where the flux is a good test. With silicates this flux forms a glass in which the bases of the silicate CHEMICAL EXAMINATION OF MINERALS. 209 are dissolved, but the silica itself is left insoluble. It appears as a skeleton readily seen floating about in the melted bead. The colors of the beads and the metals to whose oxides these are due, are : Blue ; K.F., tungsten, cold (brownish when hot) ; R.F., columbium, cold and when highly saturated (dirty-blue when hot). Both these give .colorless beads in the O.F. Green; R.F., uranium, cold (yellowish-green when hot); O.F., molyb- denum, pale on cooling, also R.F., dirty-green when hot, green when cold. Violet ; RF., columbium (see above) ; E.F., titanium cold (yellow when hot). SODA is especially valuable as a flux in the case of the reduction of the metallic oxides ; this is usually performed on charcoal. The finely pulver- ized mineral is intimately mixed with soda, arid a drop of water added to form a paste. This is placed in a cavity in the charcoal, and subjected to a strong reducing flame. More soda is added as that present sinks into the coal, and, after the process has been continued some time, the remainder of the flux, the assay, and the surrounding coal are cut out with a knife, and the whole ground up in a mortar, with the addition of a little water. The charcoal is carefully washed away and the metallic globules, flattened out by the process, remain behind. Some metallic oxides are very readily reduced, as lead, while others, as copper and tin, require considerable skill and care. The metals obtained may be: iron, nickel, or cobalt, recognized by their being attracted by the magnet ; or copper, marked by its red color ; bis- muth and antimony, which are brittle ; gold or silver ; antimony, tellurium, bismuth, lead, zinc, cadmium, which volatilize more or less completely and may be recognized by their sublimates (see p. 207) ; arsenic and mercury are also reduced, but must be heated with soda in the closed tube in order to collect the sublimates. The metals obtained may be also tested with borax on the platinum wire. By means of soda on charcoal the presence of sulphur in the sulphates may be shown, though they do not yield it upon simple heating. When soda is fused on charcoal with a compound of sulphur (sulphide or sulphate), sodium sulphide is formed, and if much sulphur is present the mass will have the hepar (liver-brown) color. In any case the presence of the sulphur is shown by placing the fused mass on a clean surface of silver, and adding a drop of water ; a black or yellow stain of silver sulphide will be formed. Illuminating gas often contains sulphur, and hence, when it is used, the soda should be first tried alone on charcoal, and if a sulphur reaction ia obtained (due to the gas), a candle or lamp must be employed in the place of the gas. It is also useful in the case of many minerals to test their fusibility or infusibility with soda, generally on the platinum wire. Silica forms if not in excess a clear glass with soda, so also titanic acid. Salts of barium and strontium are fusible with soda, but the mass is absorbed by the coal. Many silicates, though alone difficultly fusible, dissolve in a little soda to a clear glass, but with more soda they form an infusible mass. Manganese, when present even hi minute quantities, gives a bluish-green color to the soda bead. 210 CHEMICAL MINERALOGY. CHARACTERISTIC REACTIONS OP THE MOST IMPORTANT ELEMENTS AKD ov SOME o? THEIR COMPOUNDS. The following list contains the most characteristic reactions, both before the blowpipe (B.B.) and in some cases in the wet way, of the different ele- ments and their oxides. It is desirable for every student to be familiar with them. Many of them have already been briefly mentioned in the preceding pages. It is to be remembered that while the reaction of a single substance may be perfectly distinct if alone, the presence of other substances may more or less entirely obscure these reactions ; it is conse- quently obvious that in the actual examination of minerals precautions have to be taken, and special methods have to be devised, to overcome the diffi- culty arising from this cause. These will be gathered from the pyrognostic characters given (by Prof. Brush) in connection with the description of each species in the Third Part of this work. For many substances the most satisfactory and delicate tests are those which have been given by Bunsen in his important paper on Flame-reac- tions (Flammenreactionen, Ann. Ch. Pharm., cxxxviii., 257, or Phil. Mag., IY., xxxii., 81). The methods, however, require for the most part much detailed explanation, and in this place it is only possible to make this gen- eral reference to the subject. Alumina. B.B. ; the presence of alumina in most infusible minerals, containing a considerable amount, may be detected by the blue color which they assume when, after being heated, they are moistened with cobalt solu- tion and again ignited. Very hard minerals (e.g.) corundum) must be first finely pulverized. Antimony. B.B. ; antimonial minerals on charcoal give dense white inodorous fumes. Antimony sulphide gives in a strong heat in the closed tube a sublimate, black when hot, brown-red when cold. See also p. 207. In nitric acid compounds containing antimony deposit white antimonic oxide (Sb 2 O 5 ). Arsenic. B.B. ; arsenical minerals give off fumes, usually easily recog- nized by their peculiar garlic odor. In the open tube they give a white, volatile, crystalline sublimate of arsenious oxide. In the closed tube arsenic sulphide gives a sublimate dark brown-red when hot, and red or reddish- yellow when cold. The presence of arsenic in minerals is often proved by testing them in the closed tube with sodium carbonate and potassium cyan- ide. Strong heating produces a sublimate of metallic arsenic, proper pre- cautions being observed. Baryta. B.B. ; a yellowish-green coloration of the flame is given by all baryta salts, except the silicates. In solution the presence of barium is proved by the heavy white precipi tate formed upon the addition of dilute sulphuric acid. Bismuth. B.B. ; on charcoal alone, or with soda, bismuth gives a very characteristic orange-yellow sublimate (p. 207). Also when treated with equal parts of potassium iodide and sulphur, and fused on charcoal, a beauti- ful red sublimate of bismuth iodide is obtained. Boracic acid. Borates. B.B. ; many compounds tinge the flame intense yellowish-green, especially if moistened with sulphuric acid. For silicates CHARACTERISTIC REACTIONS OF THE DIFFERENT ELEMENTS. 211 the best method is to mix the powdered mineral with one part powdered tiuorite and two parts potassium bisnlphate. The mixture is moistened and placed on platinum wire. At the moment of fusion the green coloi appears, but lasts but a moment (ex. tourmaline). Heated in a dish with sulphuric acid, and alcohol being added and ignited, the flames of the latter will be distinctly tinged green. Cadmium. B.B. ; on charcoal cadmium gives a characteristic sublimate of the reddish-brown oxide (p. 207) Carbonates. Effervesce with dilute hydrochloric acid ; many require to be pulverized, and some need the addition of heat. Chlorides. B.B. ; if a small portion of a chloride is added to the bead of salt of phosphorus, saturated with copper oxide, the bead is instantly sur- rounded with an intense purplish flame. In solution they give with silver nitrate a white curdy precipitate, which darkens in color on exposure to the light ; it is insoluble in nitric acid, but entirely so in ammonia. Chromium. B.B. ; chromium gives with borax and salt of phosphorus an emerald-green bead (p. 208). Cobalt. B.B. ; a beautiful blue bead is obtained with borax in both flames from minerals containing cobalt. Where sulphur or arsenic is present it should first be roasted off on charcoal. Copper. B.B. ; on charcoal the metallic copper can be reduced from most of its compounds. With borax it gives a green bead in the oxidizing flame, and in the reducing an opaque red bead (p. 208). Most metallic compounds are soluble in nitric acid. Ammonia produces a green precipitate in the solution, which is dissolved when an excess is added, the solution taking an intense blue color. Fluorine. B.B. ; heated in the closed tube fluorides give off fumes of hydrofluoric acid, which react acid with test-paper and etch the glass. Sometimes potassium bisulphate must be added (see also p. 207). Heated gently in a platinum crucible with sulphuric -acid, most com- pounds give off hydrofluoric acid, which corrodes a glass plate placed over it. Iron. B.B. ; with borax iron gives a bead (O.F.) which is yellow while hot, but is colorless on cooling; K.F., becomes bottle-green (see p. 208). On charcoal with soda gives a magnetic powder. Minerals which contain even a small amount of iron yield a magnetic mass when heated in the reducing flame. Lvad. B.B. ; with soda on charcoal a malleable globule of metallic lead is obtained from lead compounds ; the coating has a yellow color near the assay and farther off a white color (carbonate) ; on being touched with the reducing flame both of these disappear, tinging the flame azure blue. In solutions dilute sulphuric acid gives a white precipitate of lead sul- phate ; when delicacy is required an excess of the acid is added, the solution evaporated to dryness, and water added, the lead sulphate, if present, will then be left as a residue. Lime. B.B. ; it imparts a yellowish-red color to the flame. In the pres- ence of other alkaline earths the spectroscope gi ves a sure means of detecting even when in small quantities. Many lime salts give an alkaline reaction with test-paper after ignition. 212 CHEMICAL MINERALOGY. In solutions containing lime salts, even when dilute, ammonium oxalate throws down a white precipitate of calcium oxalate. Lithia. B.B. ; lithia gives an intense red to the outer flame; in very small quantities it is evident in the spectroscope. Magnesia. B.B. ; moistened, after heating, with cobalt nitrate and again ignited, a pink color is obtained from infusible minerals. "" Manganese. B.B. ; with borax manganese gives a bead violet-red (O.F.), and colorless (R.F.). 'With soda (O.F.) it gives a bluish-green bead ; this reaction is very delicate and may be relied upon, even in presence of almost any other metal. Mercury. B.B. ; in the closed tube a sublimate of metallic mercury is yielded when the mineral is heated with soda. Mercuric sulphide gives a black lustreless sublimate in the tube, red when rubbed (p. 207). Molybdenum. B.B. ; on charcoal molybdenum gives a copper- red stain (O.F.) which becomes azure-blue when for a moment touched with the R.F. (p. 208). Nickel. B.B. ; with borax nickel oxide gives a bead which (O.F.) is violet when hot and red-brown on cooling ; (R.F.) the glass becomes gray and turbid from the separation of metallic nickel, and on long blowing colorless. Nitrates. Detonate when heated on charcoal. Heated in a tube with sulphuric acid give off red fumes of nitric peroxide. Phosphates. B.B. ; most phosphates impart a green color to the flame, especially after having been moistened with sulphuric acid, though this test may be rendered unsatisfactory by the presence of other coloring agents. If they are used in the closed tube with a fragment of metallic magnesium or sodium, and afterward moistened with water, phosphuretted hydrogen ia given off, recognizable by its disagreeable odor. A few drops of a neutral or acid solution, containing phosphoric acid, produces in a solution of ammonium molybdate with nitric acid a pulveru- lent yellow precipitate. Potash. B.B. ; potash imparts a violet color to the flame when alone. It is best detected in small quantities, or when soda or lithia is present, by the aid f the spectroscope. Selenium. B.B. ; on charcoal selenium fuses easily, giving off brown fumes with a peculiar disagreeable organic odor (see also p. 207). Silica. B.B. ; a small fragment of a silicate in the salt of phosphorus bead leaves a skeleton of silica, the bases being dissolved. If a silicate in a fine powder is fused with sodium carbonate and the mass then dissolved in hydrochloric acid and evaporated to dryness, the silica is made insoluble, and when strong hydrochloric acid is added and then water, the bases are dissolved and the silica left behind. Many silicates, especially those which are hydrous, are decomposed by strong hydrochloric acid, the silica separating as a powder or as a jelly (see p. 203). Silver. B.B. ; on charcoal in O.F. silver gives a brown coating (p. 207). A globule of metallic silver may generally be obtained by heating on char- coal in O.F., especially if soda is added. Under some circumstances it ia desirable to have recourse to cupellation. From a solution containing any salt of silver, the insoluble chloride ia thrown down when hydrochloric acid is added. This precipitate is insoluble DETERMINATIVE MINERALOGY. 213 In acid or water, but entirely so in ammonia. It changes color on exposure to the light. Soda. B.J3. ; gives a strong yellow flame. ^ Sulphur, sulphides, sulphates. B.B. ; in the closed tube some sulphides give off sulphur, others sulphurous oxide which reddens a strip of moistened litmus paper. In small quantities, or in sulphates, it is best detected by fusion on charcoal with soda. The fused mass, when sodium sulphide has thus been formed, is placed on a clean silver coin and moistened ; a distinct black stain on the silver is thus obtained (the precaution mentioned on p. 209 must be exercised). A solution in hydrochloric acid gives with barium chloride a white in soluble precipitate of barium sulphate. Tellurium. B.B. ; tellurides heated in the open tube give a white or grayish sublimate, fusible to colorless drops (p. 207). On charcoal they give a white coating and color the R.F. green. Tin. B.B ; minerals containing tin, when heated on charcoal with soda or potassium cyanide, yield metallic tin in minute globules (see also p. 209). Titanium. B.B. ; titanium gives a violet color to the salt of phosphorus bead. Fused with sodium carbonate and dissolved with hydrochloric acid, and heated with a piece of metallic tin or zinc, the liquid takes a violet color, especially after partial evaporation. Tungsten. B.B. ; tungsten oxide gives a blue color to the salt of phos- phorus bead (R.F.). Fused and treated as titanic acid (see above) with the addition of zinc instead of tin, gives a fine blue color. Uranium. B.B. ; salt of phosphorus bead, in O.F., a greenish-yellow bead when cool. In E.F. a hue green on cooling (p. 209). Vanadium. B.B. ; the characteristic reactions of vanadium with the fluxes are given on p. 208. Zinc. B.B. ; on charcoal compounds of zinc give a coating which is yel- low while hot and white on cooling, and moistened by the cobalt solution and again heated becomes a line green (p. 207). Zirconia. A dilute hydrochloric acid solution, containing zirconia, im- parts an orange-yellow color to turmeric paper, moistened by the solution. Students who desire to become thoroughly acquainted with the use of the blowpipe should provide themselves with a thorough and systematic book devoted to the subject. The most complete American book is that by Prof. Brush (Manual of Determinative Mineralogy, with an introduction on blow- pipe analysis, New York, 1875). Other standard works are those of Ber zelius (The use of the Blowpipe in Chemistry and Mineralogy, translated into English by Prof. J. D. Whitney, 1845), and Plattner (Manual of Qualita- tive and Quantitative Analysis with the Blowpipe, translated by Prof. H. B. Cornwall, 1872). The work of Prof. Brush has been freely used in the preparation of the preceding notes upon blowpipe methods and reactions. DETERMINATIVE MINERALOGY Determinative Mineralogy may be properly considered under the general head of Chemical Mineralogy, since the determination of minerals dependi CHEMICAL MINERALOGY. moetly upon chemical tests. But crystallographic and all physical chaiactere have also to be used. There is but one satisfactory way in which the identity of an unknown mineral may in all cases be fixed beyond question, and that is by the use of a complete set of determinative tables. By means of such tables the mineral in hand is referred successively from a general group into a more special one, until at last all other species have been eliminated, and the identity of the one given is beyond doubt. A careful preliminary examination of the unknown mineral should, how- ever, always be made before final recourse is had to the tables. This examination will often suffice to show what the mineral in hand is, and in any case it, should not be omitted, since it is only in this way that a practi- cal familiarity with the appearance and characters of minerals can be gained. The student will naturally take note first of those characters which are at once obvious to the senses, that is : the color, lustre, feel, general struc ture, fracture ! , cleavage, and also crystalline form, if distinct ; also, if the specimen is not too small, the apparent weight will suggest something as to the specific gravity. The above characters are of very unequal importance. Structure, if crystals are not present, and fracture are generally unessential except in distinguishing varieties ; color and lustre are essential with metallic, but generally very unimportant with unmetallic minerals. Streak is of importance only with colored minerals and those of metallic lustre (p. 162). Crystalline form and cleavage are of the highest importance, but usually require careful study. The first trial should be the determination of the hardness (for which end the pocket-knife is often sufficient in experienced hands). The second trial should be the determination of the specific gravity. Treatment of the powdered mineral with acids may come next ; by this means (see p. 202) the presence of carbonic acid is detected, and also other results obtained (p. 203). Then should follow blowpipe trials, to ascertain the fusibility, the color given to the flame, if any, the character of the sublimate given off and the reactions with the fluxes and other points as explained in the pre ceding pages. How much the observer learns in the above way, in regard to the nature of his mineral, depends upon his knowledge of the characters of minerals in general, and upon his familiarity with the chemical behavior of the vari- ous elementary substances (pp. 210 to 4 213) with reagents, and before the blowpipe. If the results of such a preliminary examination are sufficiently definite to suggest thac the mineral in hand is one of a small number oJ species, reference may be made to their full description in Part 111. of this work for the final decision. A number of minor tables, embracing under appropriate heads minerals which have some striking physical characters, are added in the Appendix. They will in many cases aid the observer in reaching a conclusion. In addition to these tables, an extended table is also given for the systematic determination of the more important minerals, those described in full in the following pages. T III.* DESCRIPTIVE MINERALOGY, THE following is the system of classification employed in the arrangement of the species in this work. It is identical with that adopted in Dana's System of Mineralogy, 1868, to which treatise reference may be made for the discussion of the principles upon which it is based. In ^ general only the more prominent species are enumerated under the successive heads. The native elements are grouped as follows : SERIES I. The more basic, or electro-positive elements. 1. GOLD GROUP. Gold, silver (also hydrogen, potassium, sodium, etc.). 2. IKON GROUP. Platinum, palladium, mercury, copper, iron, zinc, lead (also cobalt, nickel, chromium, manganese, calcium, magnesium, etc.). 3. TIN GROUP. Tin (also titanium, zirconium, etc.). SERIES II. Elements generally electro-negative. 1. ARSENIC GROUP. Arsenic, antimony, bismuth, phosphorus, vanadium, etc. 2. SULPHUR GROUP. Sulphur, tellurium, selenium. 3. CARBON-SILICON GROUP. Carbon, silicon. SERIES III. -Elements always negative. 1. Chlorine, bromine, iodine. 2. Fluorine. 3. Oxygen. CLASSIFICATION OF MINERAL SPECIES. I. NATIVE ELEMENTS. Gold : silver. Platinum ; palladium ; iridosmine, IrOs, etc. ; itercuiy ; amalgam, AgHg, etc. ; copper ; iron. Arsenic ; antimony ; bismuth, Tellurium ; sulphur. Diamond ; graphite. 216 DESCRIPTIVE MINERALOGY. II. SULPHIDES, TELLURIDES, SELENIDES, ARSEN- IDES, ANTIMONIDES, BISMUTHIDES. 1. BINARY COMPOUNDS. SULPHIDES AND TELLURIDES of METALS OF THE SULPHUR AND ARSENIC GROUPS. (a) Realgar group. Composition US. Monoclinic. Realgar. (If) Orpiment group. Composition R^Sg. Ortliorhombic. Orpirnent; stibnite ; bismuthinite. (c) Tetradymite group. Tetradymite Bi 2 (Te,S) 3 . (d) Molybdenite group. Composition RS 2 . Molybdenite. 2. BINARY COMPOUNDS. SULPHIDES, TELLIJRIDES, ETC., OF METALS OF THE GOLD, IRON, AND TIN GROUPS. A. BASIC DIVISION. Dyscrasite; domeykite. B. PROTO DIVISION. Composition RS (or RgS), RSe, RTe. (a) Galenite group. Isometric ; holohedral. Argentite ; galenite ; clausthalite ; bornite ; alabandite. (o) Blende group. Isometric ; tetrahedral. Sphalerite. (c) Chalcocite group. Orthorhombie. Chalcoeite ; acanthite ; hes- site ; stromeyerite. (d) Pyrrhotite group. Hexagonal. Cinnabar ; millerite ; pyrrho- tite (Fe 7 S 8 ) ; greenockite ; niccolite. C. DEUTO OR PYRITE DIVISION. Composition RS 2 , et3. (a) Pyrite group. Isometric. Pyrite ; linnaeite ; smaltite ; cobal- tite ; gersdorftite. Chal copy rite. (b) Marcasite group. Ortliorhombic. Marcasite ; arsenopyrite ; sylvanite. (c) Nagyagite. (d) Covellite. 3. TERNARY COMPOUNDS. SULPHARSENITES, SULPHANTIMONITES, SULPHOBISMUTHITES. (a) GROUP I. Atomic ratio, R : As(Sb) : S = 1 : 2 : 4. Formula R(As,Sb) 2 S 4 = RS -h(As,Sb) 2 S 8 . Miargyrite ; sartorite ; zink- enite. (J) SUB GROUP. At. Ratio, R : As(Sb) : S = 3 : 4 : 9. Formula R3(As,Sb,Bi) 4 S 9 = 3RS + 2(As,Sb,Bi) 2 S 3 . Jordanite ; schir- merite etc (c) GROUP II. At. Ratio, R : (As, Sb) : S = 2 : 2 : 5. Formula R2(Sb,As) 2 S 5 = 2RS + (Sb,As) 2 S 3 . Jamesonite ; duf renoysite, (d) GROUP III. At. Ratio, R : (As,Sb) : S = 3 : 2 : 6. Formula R3(As,Sb) 2 S 6 = 3RS + (As,Sb^S 8 . Pyrargyrite, proustite ; bournonite ; boulangerite. CLASSIFICATION OP SPECIES. 217 (e) GROUP IV. At. Katio, K : (As,Sb,Bi) : S = 4 : 2 : 7. Formula E 4 (As,Sb,Bi) 2 S 7 = 4ES + (As,Sb,Bi) 2 S 8 . Tetrahedrite ; ten- nantite. (/) GROUP Y. At. Eatio, E : (As,Sb) : S = 5 : 2 : 8. Formula E 5 (As,Sb) 2 S 8 = 5ES + (As,Sb) 2 S 3 . Stephanite ; geocronite P ;>lybasite. Enargite. III. CHLORIDES, BROMIDES, IODIDES. 1. ANHYDEOUS CHLOEIDES. Composition mostly E(C1. Br, I) : also Kj(Cl,Br,I) (calomel), and EC1 6 (molysite). Halite ; svlvite ; cerargyrite ; embolite ; bromyrite. 2. HYDROUS CHLOEIDES. Carnallite. Tachhydrite. 3. OXYCHLOEIDES.Atacamite ; inatlockite. IV. FLUORIDES. 1. ANHYDROUS FLUOEIDES. Fluorite ; sellaite. Cryolite. 2. HYDEOUS FLUOEIDES. -Paclmolite ; ralstonite. V. OXYGEN COMPOUNDS. I. OXIDES. 1. OXIDES OF METALS OF THE GOLD, IRON, AND TIN GROUPS. A. ANHYDROUS OXIDES. (a) PROTOXIDES. Binary compounds of oxygen with a univalent or bivalent element. Formula EO or (E^O). Cuprite ; zincite ; tenorite. (&) SESQUIOXIDES. Binary compounds of oxygen with a sexivalent ele- ment. Formula RO 3 . Corundum; hematite. This group also includes menaccanite and perofskite. (c) COMPOUNDS OF PROTOXIDES AND SESQUIOXIDES. Ternary compounds of oxygen with a bivalent and a sexivalent element. Formula EEO 4 = EG Spinel Group. Isometric. Spinel ; gahnite \ magnetite ; franklinite ; chromite. Orthorhombic. Chrysoberyl. (d) DEUTOXIDES. Binary compounds of oxygen with a quadrivalent ele- ment. Formula EO 2 . TETRAGONAL. Rutile Group. Cassiterite ; rutile ; octatedrite ; haus- mannite ; braunnite. Orthorhombic. Brookite ; pyrolusite. B. HYDROUS OXIDES. Turgite. Diaspore ; gothite ; manganite. lamonite. Brncite ; gibbsite. -Psilomelane. 218 DESCRIPTIVE MINERALOGY. 2. OXIDES OF METALS OF THE ARSENIC AND SULPHUR GROUPS. Isometric. Arsenolite ; senarmontite. Orthorhombie. Claudetite ; valentinite ; bismite, etc. 3. OXIDES OF THE CARBON-SILICON GROUP. Quartz ; tridymite ; as- manite; opal. t II. TERNARY OXYGEN COMPOUNDS. 1. SILICATES. A. ANHYDROUS SILICATES. (a) BISILICATES. Salts of meta-silicic acid, H^SiOs. Quantivalent ratio for basic elements and silicon, 1 : 2. General formula RSiO 3 . This may be written : R \\ O 2 || SiO, to indicate that part only of the oxygen is regarded as linking oxygen, or, taking into account the quantivalence of the various basic elements that may be present, RS, aR, /3R [ O 2 j SiO. (a) Amphibole group. Pyroxene section (/A / = 86-88). Orthorhom- bic. Enstatite ; hypersthene. Monoclinic. Wollastonite ; pyroxene ; acmite ; segirite. Triclinic. Rhodonite ; babingtonite. Spodumene ; petal ite. (b) Amphibole section (I ^I 123-125). Orthorhombic. Anthophyl- lite, kupfl'erite. Monoclinic, amphibole ; arf vedsonite. Beryl. Eudialjte. Pollucite. (/8) UNISILICATES. Salts of the normal silicic acid, H 4 SiO 4 . Quantivalent ratio for basic elements and silicon, 1 : 1. General formula RgSiO,,. This may be written : Eg | O 4 j Si, to show that all the oxygen is regarded as linking oxygen, or, R$>,aR, /3R . || O 4 j| Si. The latter formula shows that, though elements of different quantivalence may be present, the same uni- silicate type still exists. The excess of silica sometimes present in both bisilicates and unisilicates, as well as other deviations from the ordinary types, are remarked upon in the pages which follow. (a) Chrysolite group. Orthorhoinbic, /A 1= 91-95 ; A 14 = 124- 129. Chrysolite, forsterite, tephroite, monticellite, etc. (b) Willemite group. Hexagonal, R A R = 116-117. Willemite, diop- tase, phenacite. (c) Isometric. Helvite. Danalite, R ? SiO 4 +RS. (a) Garnet group. Isometric. Q. ratio for R : R : Si = 1 : 1 : 2. Gen- eral formula RjffcSisO^. (e) Vesuvianite group. Tetragonal. Zircon, vesuvianite. (/ ) Epidote group. Anisometric. Epidote ; allanite ; zoisite ; gadoli- nite ; ilvaite. (a) Triclinic. Axinite. Danburite. (A) lolite. Qc) Mica group. /A 1 =120. Cleavage basal perfect; optic axis o? acute bisectrix normal to the cleavage-plane. Phlogopite ; biotite ; lepido melane ; muscovite ; lepidolite. (1) Scapolite group. Tetragonal. Sarcolite ; ineiomU ; wernerite ; ekebergite. (m) Hexagonal. Nephelife. Isometric. Sodalite ; hailynite ; nosite ; leucite. CLASSIFICATION OF SPECIES. 219 Feldspar group. Monoclinic or triclinic. /A /near 120 ; Q. ratio for E : S = 1 : 3. Anorthite ; labradorite ; andesite ; hyalophanc ; oligo- clase ; albite ; orthoclase (microcline). (7) SUBSILICATES. (a) Q. ratio for bases to silicon, 4: : 3. Chondrodite Tourmaline. (b) Q. ratio for bases to silicon, 3 : 2. Genlenite. Andalusite ; nbrolite ; cyanite (A18iO 6 ). Topaz ; euclase ; datolite. Guarinite ; titanite ; keil- hauite ; tscheffkinite. (e) Q. ratio for bases to silicon, 2 : 1. Staurolite. B. HYDROUS SILICATES GENERAL SECTION. BISILICATES. Fectolite ; laumontite ; okenite. Chrysocolla ; alipite, etc. UNISILICATES. Calamine ; prehnite. Thorite. Pyrosmalite. Apophyl- lite. SUBSILICATES. Allopliane. ZEOLITE SECTION. Thomsonite Chabazite heulandite. nite ; natrolite ; scolecite ; mesolite. Levynite. Analcite. ; gmelinite ; herschelite. Phillipsite. Harmotome. Stilbite ; MARGAROPHYLLITE SECTION. BISILICATES. Talc. Pyrophyllite. Sepiolite ; glaucoriite. UNISILIOATES. Serpentine group. Serpentine ; deweylite ; geiithite. Kaolinite group. Kaolinite ; pholerite ; halloysite. Pinite group. Tinite, etc. ; palagonite. Hydro-mica group. Fahluuite ; margarodite ; damounte ; paragonite ; cookeite. Hisingerite. Chlorite group. Yermiculites, Q. ratio of bases to silicon, 1:1. Fyro- Bclerite; jefferisite, etc. Penninite. Eipidolite ; prochlorite. Chloritoid ; margarite. Seybertite. 2. TANTALATES, COLUMBATES. Pyrochlore. Tantalite ; columbite; yttrotantalite ; samarskite; euxe- nite ; seschynite, etc. 3. PHOSPHATES, ARSENATES, VANABATES. ANHYDEOUS. Xenotime Y 3 P 2 O 8 ; pncherite. Descloizite. Zto^^.-Formnla B 3E,(P^8,V)|O 8 +E(01,FV Apatite; pyromor- pliite ; mimetite ; vanadinite. ../it, ^ \ ' Wagnerite; monazite. Triphylite ; triplite.-Arnblygcmte (hebromte) 220 DESCRIFflVE MINERALOGY. HYDROUS. Pharmacolite ; brushite. Yivianite ; erythrite. Libethinito ; olivenite. Liroconite ; pseudomalachite. Clinoclasite. Lazulite ; scoro dito ; wavellite ; pharraacosiderite. Childreiiite. Turquois ; cacoxenite. Torbernite ; autunite. Hydrous antimonate. Bindheimite. 4. EQUATES. Sassolite ; sussexite ; ludwigite. Boracite ; ulexite ; priceite. War- wickite. 5. TUNGSTATES, general formula KW 4 ; MtLYMATES, CHRtMATES, RCr* 4 . Wolframite ; scheelite ; st*lzite. Wulf enite. Crac^ite ; phenicechrite. 6. SULPHATES. ANHYDROUS. General formula KSO 4 . Orthorhombic I^I = 100-105. Barite ; celestite ; anhydrite ; anglesite ; zinkosite ; leadhillite. Caledonite. Dreelite ; susamrite ; connellite. Glanberite ; lanarkite. HYDROUS SULPHATES. Mirabilite. Gypsum. Polyhalite. Epsomite. Copperas group. Chalcanthite, CuSO 4 + 5aq, also the other vitriols, " Copiapite. Aluminite. Liuarite ; brochantite, etc. TELLURATES. Montanite, Bi 2 TeO 6 + 2aq. 7. CARBONATES. ANHYDROUS. Calcite group. Rhombohedral. General formula, KCO 3 . Calcite ; dolomite ; magnesite ; siderite ; rhodochrosite ; smithsonite. Aragonite group. Orthorhombic. Aragonitc ; witherite ; strontianite ; cerussite ; baryto-calcite. Phosgenite. HYDROUS CARBONATES. Gay lussite, Hydromagnesite. Hy drozincite ; malachite ; azurite. Bismutite, etc. VI. HYDROCARBON COMPOUNDS. I. NATIVE ELEMENTS. GOLD. Isometric. The octahedron and dodecahedron the most commcn forms. Crystals sometimes acicular through elongation of octa- 415 hedral or other forms ; also passing into filiform, reti- culated, and arborescent shapes ; and occasionally spongiform from an aggregation of filaments ; edges of crystals often salient (f. 415). Cleavage none. Twins : twinning-plane octahedral. Also massive and in thin laminae. Often in flattened grains or scales, and rolled masses in sand or gravel. H.=2-5-3. G.^15-6-19'5 ; 19-30-19-34, when quite pure, G-. Kose. Lustre metallic. Color and streak various shades of gold-yellow, sometimes inclining to silver-white. Very ductile and malleable. . Composition, Varieties Gold, but containing silver in different proportions, and some- times also traces of copper, iron, bismuth (maldonite), palladium, rhodium. Var. 1. Ordinary. Containing (HO to 16 p. c. of silver. Color varying, accordingly, from deep gold-yellow to pale yellow; G.=19-15'5. 2. Argentiferous ; Electrum. Color pale yellow to yellowish- white ; G. = 15 "5-12 '5. Ratio for the gold and silver of 1 : 1 corresponds to 35 "5 p. c. of silver, 2 : 1, to 21 -6 p. c. The average proportion of gold in the native gold of California, as derived from assays of several hundred millions of dollars' worth, is 880 thousandths ; while the range is mostly between 870 and 890 (Prof. J. C. Booth, of U. S. Mint). The range in the metal of Australia is mostly between 900 and 960, with an average of 1)25. The gold of the Chaudiere, Canada, contains usually 10 to 15 p c. of silver ; while that of Nova Scotia is very nearly pure. The Chilian gold afforded Domeyko 84 to 96 per cent, of gold and 15 to 3 per cent, of silver. (Ann. d. Mines, IV. vi.) Pyroguostic and other Chemical Characters. B.B. fuses easily. Not acted on by fluxes. Insoluble in any single acid ; soluble in nitro-hydrochlorio acid (aqua-regia). D-ff. Readily recognized by its malleability and specific gravity. Distinguished by it insolubility ra nitric acid from pyrite and chalcopyrite. Observations. Native gold is found, when in titu, with comparatively small exceptions, in the quartz veins that intersect metamorphic rocks, and to some extent in the wall rock of these veins. The metamorphic rocks thus intersected are mostly chloritic, talcose, and argillaceous schist of dull green, dark gray, and other colors ; also, much less commonly, mica and hornblendic schist, gneiss, dioryte, porphyry ; and still more rarely, granite. A " laminated quartzyte, called itacolumyte, is common in many gold regions, as those ot -brazil and North Carolina, and sometimes specular schists, or slaty rocks containing much foliated gpecular iron (hematite), or magnetite in grains. The gold occurs in the quartz in strings, scales, plates, and in masses which are sometim an agglomeration of crystals ; and the scales are often invisible to the naked eye, massive quartz that apparently contains no gold frequently yielding a considerable percentage 1 assayer It is always very irregularly distributed, and never in continuous pure bands metal, like many metallic ores. It occurs both disseminated through the mass of the quartz and in its cavities. The associated minerals are : pyrite, which far exceeds in quantity all others, and is generally auriferous; next, chalcopyrite, galenite, sphalente, arse nopyrite, each frequently auriferous ; often tetradymite and other tellurium ores, native bismuth, st nite, magnetite, hematite ; sometimes barite, apatite, fluorite, siderite, chrysocolla. ^ The gold of the world has been mostly gathered, not directly from the quartz veins, 01 222 DESCRIPTIVE MINERALOGY. from the gravel or sands of rivers or valleys in auriferous regions, or the slopes of mountain! or hills, whose rocks contain in some part, and generally not far distant, auriferous veins , such mines are often called aMuvial washings ; in California placer-digyings. Most of the gold of the Urals, Brazil, Australia, and all other gold regions, has come from such alluvial wash- ings. The alluvial gold is usually in flattened scales of different degrees of fineness, the size depending partly on the original condition in the quartz veins, and partly on the distance to which it has been transported. Transportation by running water is an assorting process ; tht coarser particles or largest pieces requiring rapid currents to transport them, and dropping first, and the finer being carried far away sometimes scores of miles. A cavity in the rocky slopes or bottom of a valley, or a place where the waters may have eddied, generally proves in such a region to be a pocket full of gold. In the auriferous sands, crystals of zircon are very common ; also garnet and cyanite in grains; often also mouazite, diamonds, topaz, magnetite, corundum, iridosmine, platinum. The zircons are sometimes mistaken for diamonds. Gold exists more or less abundantly over all the continents in most of the regions of crystal- line rocks, especially those of the semi-crystalline schists ; and also in some of the large islands of the world where such rocks exist. In Europe, it is most abundant in Hungary and in Transylvania ; it occurs also in the sands of the Rhine, the Reuss, the Aar, the Rhone, and the Danube ; on the southern slope of the Pennine Alps, from the Simplon and Monte Rosa to the valley of Aosta ; in Piedmont ; in Spain, formerly worked in Asturias ; in many of the streams of Cornwall ; near Dolgelly and other parts of North Wales ; in Scotland ; in the county of Wicklow, Ireland ; in Sweden, at Edelfors. In Asia, gold occurs along the eastern flanks of the Urals for 500 miles, and is especially abundant at the Beresov mines near Katharinenburg (lat. 56 40' N.) ; also obtained at Petro- pavlovski (60 N.) ; Nischne Tagilsk (50 N.) ; Miask, near Slatoust and Mt. IJmen (55 N., where the largest Russian nugget was found), etc. Asiatic mines occur also in the Cailas Mountains, in Little Thibet, Ceylon, and Malacca, China, Corea, Japan, Formosa, Sumatra, Java, Borneo, the Philippines, and other East India Islands. In Africa, gold occurs at Kordofan, between Darfour and Abyssinia ; also, south of the Sahara in Western Africa, from the Senegal to Cape Palmas ; in the interior, on the Somat, a day's journey from Cassen ; along the coast opposite Madagascar, between 22 D and 35 S., supposed by some to have been the Ophir of the time of Solomon. In South America, gold is found in Brazil; in New Granada ; Chili ; in Bolivia ; sparingly in Peru. Also in Central America, in Honduras, San Salvador, Guatemala, Costa Rica, and near Panama ; most abundant in Honduras. In North America, there are numberless mines along the mountains of Western America, and others along the eastern range of the Appalachians from Alabama and Georgia to Labra- dor, besides some indications of gold in portions of the intermediate Archean region about Lake Superior. They occur at many points along the higher regions of the Rocky Mountains, in Mexico, an$ in New Mexico, in Arizona, in the San Francisco, Wauba, Yuma, and other districts ; in Colorado, abundant, but the gold largely in auriferous pyrite ; in Utah, and Idaho, and Montana. Also along ranges between the summit and the Sierra Nevada, in the Humboldt region and elsewhere. Also in the Sierra Nevada, mostly on its western slope (the mines of the eastern being principally silver mines). The auriferous belt may be said to begin in the Californian peninsula. Near the Tejon pass it enters California, and beyond for 180 miles it is sparingly auriferous, the slate rocks being of small breadth ; but beyond this, northward, the slates increase in extent, and the mines in number and productiveness, and they continue thus for 200 miles or more. Gold occurs also in the Coast ranges in many localities, but mostly in too small quantities to be profitably worked. The regions to the north in Oregon and Washington Territory, and the British Possessions farther north, as also our possessions in Alaska, are at many points auriferous, and productively so, though to a less extent than California. In eastern North America, the mines of the Southern United States produced before the California discoveries, in 1849, about a million of dollars a year. They are mostly confined to the States of Virginia, North and South Carolina, and Georgia, or along a line from the Rappahannock to the Coosa in Alabama. But the region may be said to extend north to Canada ; for gold has been found at Albion and Madrid in Maine ; Canaan and Lisbon, N. H. ; Bridgewater, Vermont ; Dedham, Mass. Traces occur also in Franconia township, Mont- gomery Co. , Pennsylvania. In Canada, gold occurs to the south of the St. Lawrence, in the oil on the Chaud^re, and over a considerable region beyond. In Nova Scotia, mines are worked near Halifax and elsewhere. In Australia, which is fully equal to California in productiveness, and mach superior in the purity of the metal, the principal gold mines occur along the streams in the mountains of N. S. Wales (S. E. Australia), and along the continuation of the same range in Victoria (8. Australia). NATIVE ELEMENTS. 223 SILVER. Isometric. Cleavage none. Twins : twinning-plane octahedral. Com- monly coarse or fine filiform, reticulated, arborescent ; in the latter, the branches pass off either (1) at right angles, and are crystals (usually octa- hedrons) elongated in the direction of a cubic axis, or "else a succession of partly overlapping crystals ; or (2) at angles of 60, they being elongated in the direction of a dodecahedral axis. Crystals generally obliquely pro- longed or shortened, and thus greatly distorted. Also massive, and in plates or superficial coatings. H. 2-5-3. G.=lp-l-ll-l, when pure 10-5. Lustre metallic. Color and streak silver-white ; subject to tarnish, by which the color becomes grayish-black. Ductile. Comp., Var. Silver, with some copper, gold, and sometimes platinum, antimony, bismuth, mercury. Ordinary, (a} crystallized ; (b) filiform, arborescent ; (c) massive. Auriferous. Contains 10 to 30 p. c. of gold ; color white to pale brass-yellow. There is a gradual passage to argen- tiferous gold. Cupriferous. Contains sometimes 10 p. c. of copper. Fyr., etc. B.B. on charcoal fuses easily to a silver- white globule, which in O.F. gives a faint dark- red coating of the oxide ; crystallizes on cooling. Soluble in nitric acid, and deposited again by a plate of copper. Obs. Native silver occurs in masses, or in arborescent and filiform shapes, in veins travers- ing gneiss, schist, porphyry, and other rocks. Also occurs disseminated, but usually invisibly, in native copper, galenite, chalcocite, etc. The mines of Kongsberg, in Norway, have afforded magnificent specimens of native silver. The principal Saxon localities are at Freiberg, Schneeberg, and Johanngeorgenstadt ; the Bohemian, at Przibram, and Joachimsthal. It also occurs in small quantities with other ores, at Andreasberg, in the Harz ; in Suabia ; Hungary ; at Allemont in Dauphiny ; in the Ural near Beresof ; in the Altai, at Zmeoff ; and in some of the Cornish mines. Mexico and Peru have been the most productive countries in silver. In Mexico it hai been obtained mostly from its ores, while in Peru it occurs principally native. In Durango, Sinaloa, and Sonora, in Northern Mexico, are noted mines affording native silver. In the United States it is disseminated through much of the copper of Michigan, occasion- ally in spots of some size, and sometimes in cubes, skeleton octahedrons, etc. , at various mines. In Idaho, at the ' k Poor Man's lode," large masses of native silver have been ob- tained. In Nevada, in the Comstock lode, it is rare, and mostly in filaments ; at the Ophir mine rare, and disseminated or filamentous ; in California, sparingly, in Silver Mountain dis* trict, Alpine Co. ; in the Maris vein, in Los Angeles Co. ; in the township of Ascot, Canada. PLATINUM. Isometric. Rarely in cubes or octahedrons. Usually in grains ; occa- sionally in irregular lumps, rarely of large size. Cleavage none. H.=4-4-5. G.=16-19; 17-108, small grains, 17-608, a mass, Breith. Lustre metallic. Color and streak whitish steel-gray ; shining. Opaque. Ductile. Fracture hackly. Occasionally magneti-polar. Comp Platinum combined with iron, iridium, osmium, and other metals. The amount of iron varies from 4-20 p. c. Pyr., etc. Infusible. Not affected by borax or salt of phosphorus, except in the state of tine dust, when reactions for iron and copper may be obtained. Soluble only in heated nitro- hydrochloric aoid. 224 DESCRIPTIVE MINERALOGY". Diff. Distinguished by its malleability, high specific gravity, infusibility, and entire insol ability in the ordinary acids. Obs- Platinum was first found in pebbles and small grains in the alluvial deposits of thi river Pinto, in the district of Choco, near Popayan, in South America, where it received ita name platina,, from plata, silver. In the province of Antioquia, in Brazil, it has been found in auriferous regions in syenite (Boussingault). In Russia, it occurs at Nischne Tagilsk, and Goroblagodat, in the Ural, in alluvial material. Formerly used as coins by the Russians. Russia affords annually about 800 cwt. of platinum, which is neariy ten times the amount from Brazil, Columbia, St. Domingo, and Borneo. Platinum is also found on Borneo ; in the sands of the Rhine ; at St. Aray, val du Drac ; county of Wicklow, Ireland ; on the river Jocky, St. Domingo ; in California, but not abun- dant : in traces with gold in Rutherford Co., North Carolina ; at St. Francois Beauce, etc., Canada East. PLATINIRIDIUM. Platinum and iridium in different proportions. Urals ; Brazil. 4 PALLADIUM. Isometric. In minute octahedrons, Haid. Mostly in grains, sometimes composed of diverging fibres. H.=4-5-5. G.=ll-3-ll-8, Wollaston. Lustre metallic. Color whitish steel-gray. Opaque. Ductile and malleable. Comp. Palladium, alloyed with a little platinum and iridium, but not yet analyzed. Obs. Palladium occurs with platinum, in Brazil, where quite large masses of the metal are sometimes met with ; also reported from St. Domingo, and the Ural. Palladium has been employed for balances ;>al8o for the divided scales of delicate apparatus, for which it is adapted, because of its not blackening from sulphur gases, while at the same time it is nearly as white as silver. IRIDOSMINE. Osmiridium. Hexagonal. Rarely in hexagonal prisms with replaced basal edges. Commonly in irregular flattened grains. H.=6-T. G.=19-3-21-12. Lustre metallic. Color tin-white, and light steel-gray. Opaque. Malleable with difficulty. Comp., Var. Iridium and osmium in different proportions. Two varieties depending on these proportions have been named as species, but they are isomorphous, as are the metals (G. Rose). Some rhodium, platinum, ruthenium, and other metals are usually present. Var. 1. N&wjanskite, Haid. ; H.=7; G.=18'8-19'5. In flat scales ; color tin-white. Over 40 p. c. of Iridium. Probably IrOs. 2. tfls&er*kil$, Haid. In flat scales, often six-sided, color grayish-white, steel-gray. G. 20-21 2. Not over 30 p. c of iridium. One kind from Nischne Tagilsk afforded Berzelius TrOs 4 =Iridium 19-9, osmium 801=100 ; G. =21 '118. Another corresponded to the formula IrOs 8 . Pyr., etc. At a high temperature the sisserskite gives out osmium, but undergoes no further change. The newjanskite is not decomposed and does not give an osmium odor until fused with nitre. Diff. Distinguished from platinum by its superior hardness. Obs. Occurs with platinum in the province of Choco in South America ; in the Ural moun- tains ; in Australia. It is rather abundant in the auriferous beach-sands of northern Cali- fornia, occurring in small bright lead -colored scales, sometimes six-sided. Also traces in the g old-washings on the rivers du Loup and des Plantes, Canada. MERCURY. Quicksilver. Gediegeu Quecksilber, Germ. Isometric. Occurs in small fluid globules scattered through its ganglia G.= 13.568. Lustre metallic. Color tin- white. Opaque. NATIVE ELEMENTS. 225 Oomp. Pure mercury (Hg) ; with sometimes a little silver. Pyr., etc. B.B., entirely volatile. Dissolves readily in nitric acid. Obs. Mercury in the metallic state is a rare mineral ; the quicksilver of commerce is ob- tained mostly from cinnabar, one of its ores. The rooks affording the metal and its ores are mostly clay shales or schists of different geological ages. Its most important mines are those of Idria in Garniola, and Almaden in Spain. It ia found in small quantities in Carinthia, Hungary, Peru, and other countries ; in California, especially in the Pioneer mine, in the Napa Valley. AMALGAM. Isometric. The dodecahedron a common form, also the cube and octa hedron in combination (see f. 40, 41, etc., p. 15). Cleavage : dodecahedral in traces. Also massive. H. 3-3-5. G.= 13.75-1 4. Color and streak silver- white. Opaque. Fracture conchoidal, uneven. Brittle, and giving a grating noise when cut with a knife. Oomp. Both Ag Hg (= Silver 35'1, mercury, 64 '9), and Ag^Hgs (= Silver 26 '5, and mer- cury, 73 '5), are here included. Pyr., etc, B.B., on charcoal the mercury volatilizes and a globule of silver is left. In the closed tube the mercury sublimes and condenses on the cold part of the tube in minute glo- bules. Dissolves in nitric acid. Obs, From the Palatinate at Moschellandsberg. Also reported from Rosenau in Hungary, Sala in Sweden, Allemont in Dauphine, Almaden in Spain. ARQUERITE. Composition Ag, 2 Hg=silver 86'6, mercury, 13-4=100. Chili KONQS- BERQITE, AgisHg (?) Kongsberg, Norway. COPPER. Isometric. Cleavage none. Twins: twinning-plane octahedral, very common. Often filiform and arborescent ; the latter with the branches passing off usually at 60, the supplement of the dodecahedral angle. Also massive. H.= 2-5-3. G. =8-838, Whitney. Lustre metallic. Color copper-red. Streak metallic shining. Ductile and malleable. Fracture hackly. Oomp. Pure copper, but often containing some silver, bismuth, etc. Pyr., etc. B.B., fuses readily ; on cooling, becomes covered with a coating of black oxiae. Dissolves readily in nitric acid, giving off red nitrous fumes, and producing a deep azure- blue solution upon the addition of ammonia. Obs. Copper occurs in beds and veins accompanying its various ores, and is most abundant in the vicinity of dikes of igneous rocks. It is sometimes found in loose masses imbedded in the soil. Found at Turinsk, in the Urals, in fine crystals. Common in Cornwall. In Brazil, Chili, Bolivia, and Peru. At Walleroo, Australia. This metal has been found native throughout the red sandstone (Triassico-Jurassic) region of the eastern United States, in Massachusetts, Connecticut, and more abundantly in New Jersey, where it has been met with sometimes in fine crystalline masses. No known locality exceeds in the abundance of native copper the Lake Superior copper region, near Keweenaw Point, where it exists in veins that intersect the trap and sandstone, and where masses of immense size have been obtained. It is associated with prehnite, ditolite, analcite, laumon- tite, pectolite, epidote, chlorite, wollastonite, and sometimes coats amygdules of calcite, etc., in amygdaloid. Native copper occurs sparingly in California. Also on the Gila rivei in Arizona ; i large drift masses in Alaska. IK 226 DESCRIPTIVE MINERALOGY. IRON.* Isometric. Cleavage octahedral. /H.=4-5. G.=7-3-7'8. Lustre metallic. Color iron-gray. Stre'-ak shin- ing. Fracture hackly. Malleable. Acts strongly on the magnet. r Obs. The occurrence of masses of native iron of terrestrial origin has been several' ttime, reported, but it is not yet placed beyond doubt. The presence of metallic iron in grains iii basaltic rocks has been proved by several observers. It has also been noticed in other related rocks. The so-called meteoric iron of Ovifak, Greenland, found imbedded in basalt, is con- sidered by some authors to be terrestrial Meteoric iron usually contains 1 to 20 per cent of nickel, besides a small percentage of other metals, as cobalt, manganese, tin, copper, chromium ; also phosphorus common as a phosphuret (schreibersite), sulphur in sulphurets. carbon in some instances, chlorine. Among large iron meteorites, the Gibbs meteorite, in the Yale College cabinet, weighs 1,635 Ibs. ; it was brought from Eed River. The Tucson meteorite, now in the Smithsonian Institution, weighs 1,400 Ibs. ; it was originally from Sonora. It is ring-shaped, and is 49 inches in its greatest diameter. Still more remarkable masses exist in northern Mexico ; also in South America; one was discovered by Don Rubin de Celis in the district of Chaco-Gualamba, whose weight was estimated at 32.000 Ibs. The Siberian meteorite, discovered by Pallas, weighed originally 1,600 Ibs. and contained imbedded crystals of chrysolite. Smaller masses are quite common. Zmc.- -Native zinc has been reported to occur in Australia; and more recently Mr. W. D. Marks reports its discovery in Tennessee, under circumstances not altogether free from doubt LEAD. Native lead occurs very sparingly. It has been found in the Urals, in Spain, Ireland, etc. Dr. Genth speaks of its discovery in the bed rock of the gold placers at Camp Creek, Montana. TIN is probably only an artificial product. ARSENIC. Ehombohedral 72 A i2 = 85 41', O A R = 122 9', c = 1-3779, Miller. Cleavage: basal, imperfect Often grannlar massive; sometimes reticu- lated, renifonn, and stalactitic. Structure rarely columnar. H.==3*5. G.=5'93. Lustre nearly metallic. Color and streak tin-white, tarnishing soon to dark-gray. Fracture uneven and line granular. Comp. Arsenic, often with some antimony, and traces of iron, silver, gold, or bismuth. Pyr. B.B., on charcoal volatilizes without fusing, coats the coal with white arsenous oxide, and affords the odor of garlic ; the coating treated in R.F. volatilizes, tinging the flame blue. Obs. Native arsenic commonly occurs in veins in crystalline rocks and the older schists, and is often accompanied by ores of antimony, red silver ore. realgar, sphalerite, and other metallic minerals. The silver mines of Saxony afford this metal in considerable quantities ; also Bohemia, the Harz. Transylvania, Hungary. Norway, Siberia ; occurs at Chanarcillo, and elsewhere in Chili ; and at the mines of San Augustin, Mexico. In the United States it has been observed at Haverhiii and Jackson, N. H., at Greenwood, Me. ANTIMONY, Rhombohedral. J2 A J2 = 87 35', Hose ; A R = 123 32' ; c = 1-3068. 2 A 2 = 89 25'. Cleavage : basal, highly perfect ; J distinct. Generally massive, lamellar ; sometimes botryoidal or renif orm with a granular texture. * The asterisk in this and similar cases indicates that the species is mentioned again in the Supplementary Chapter, pp, 420 to 440. NATIVE ELEMENTS. 227 H.=3-3'5. G. 6-646-6-72. Lustre metallic. Color and streak tin- white. Very brittle. Comp, Antimony, containing sometimes silver, iron, or arsenic. py r ,_B.B., on charcoal fuses, gives a white coating in both O. and B.F. ; if the blowing be intermitted, the globule continues to glow, giving off white fumes, until it is finalty crusted over with prismatic crystals of aatimonous oxide. The white coating tinges the R.F. bluish- ereen Crystallizes readily from fusion. Occurs near Sahl in Sweden ; at Andreasberg in the Harz ; at Przibram ; at Allemont in Dauphiny; in Mexico; Chili; Borneo; at South Ham, Canada; at Warren, N. J., rare; at Prince William antimony mine, N. Brunswick, rare. ALLEMONTITE. Arsenical antimony, SbAs 3 . Color tin-white or reddish-gray. Occ Allemont ; in Bohemia ; the Harz. BISMUTH. Gediegen Wismuth, Germ. Hexagonal. R A R = 87 40', G. Rose ; A R = 123 36' ; 6 = 1-3035. Cleavage : basal, perfect ; 2, 2, less so. Also in reticulated and arbores- cent shapes ; foliated and granular. H.= 2-2-5. G.= 9-727. Lustre metallic. Streak and color silver-white, with* a reddish hue ; subject to tarnish. Opaque. Fracture not observable. Sectile. Brittle when cold, but when heated somewhat malleable. Oomo Var. Pure bismuth, with occasional traces of arsenic, sulphur, tellurium. Pvr etc. B B., on charcoal fuses and entirely volatilizes, giving a coating orange-yellow while hot, and lemon-yellow on cooling. Dissolves in nitric acid ; subsequent dilution caus< a white precipitate. Crystallizes readily from fusion. K^-H-I* Diff. Distinguished by its reddish color, and high specific gravity, from the other m Obs 8 ^-Bismuth occurs in veins in gneiss and other crystalline rocks and clay slate .accom- panying various ores of silver, cobalt, lead, and zinc. Abundant at the silver and cobalt mines of Saxony and Bohemia ; also fouud in Norway, and at Fahlun in Sweden. At Wheal Sparnon, and elsewhere in Cornwall, and at Carrack Fe in Cumberland ; at the Atlas maie Devonshire ; at Meymac, Correze ; at San Antonio, Chili ; Mt. Illampa (Sorata), in B la , At Lafce'a mine in Monroe, and near Seymour, Conn., in quartz ; occurs also at Brewer'i mine, Chesterfield district, South Carolina ; in Colorado. TELLURIUM.* Hexagonal, R A R = 86 57', G. Rose ; A * - 123 4', t = 1-8308. In six-sided prisms, with basal edges replaced. Cleavage : lateral perfect, basal imperfect. Commonly massive and granular. H.=2-2-5. G.=6-l-6'3. Lustre metallic. Color and streak tm-wmt< Brittle. Oomp According to Klaproth, Tellurium 92'55, iron 7-20, and gol ad thename ft***.) ; also at the Red Cloud mine, near Gold Hill, Boulder Co., Colorado 228 DESCRIPTIVE MINERALOGY. NATIVE SULPHUR. 1-23 : 1. A 1 Orthorhombic. /A 7 = 101 46', O/\1-l = 113 6': c : I : d = 2-34-4 41'; O A! = 108 19'. Cleavage: /, and 1, imperfect. Twins, composition -face, I, sometimes producing cruci- form crystals. Also massive, sometimes con sisting of concentric coats. ^ H.= 1:5-2-5. G. =2-072, of crystals from Spain. Lustre resinous. Streak sulphur-yel- low, sometimes reddish or greenish. Trans- parent subtranslucent. Fracture conchoidal, more or less perfect. Soctile. Comp. Pure sulphur; but often contaminated with clay or bitumen. Pyr., etc. Burns at a low temperature with a bluish flame, with the strong odor of sul- phurous oxide. Becomes resinously electrified by friction. Insoluble in water, and not acted on by the acids. Obs. Sulphur is dimorphous, the crystals being monoclinic when formed at a moderately high temperature (125 C., according to Frankenheim). The great repositories of sulphur are either beds of gypsum and the associate rocks, or the regions of active and extinct volcanoes. In the valley of Noto and Mazarro, in Sicily at Coml, near Cadiz, in Spain ; Bex, in Switzerland ; Cracow, in Poland, it occurs in the former situation ; also Bologna, Italy. Sicily and the neighboring volcanic isles ; the Solfatara, near Naples ; the volcanoes of the Pacific ocean, etc., are localities of the latter kind. Abundant in the Chilian Andes. Sulphur is found near the sulphur springs of New York, Virginia, etc., sparingly': in many coal deposits and elsewhere, where pyrite is undergoing decomposition ; at the hot springs and geysers of the Yellowstone park ; in California, at the geysers of Napa valley, Sonoma Co. ; in Santa Barbara in good crystals ; near Clear lake, Lake Co. ; in Nevada, in Humboldt Co., in large beds ; Nye and Esmeralda Cos., etc. ,^, h f.f ulp . bur mines of Sicily ' the crater of Vulcano, the Solfatara near Naples, and thebeda of California, afford large quantities of sulphur for commerce. DIAMOND.* Isometric. Often tetrahedral in planes, 1, 2, and 3-f. Usually with 418 419 420 curved faces, as in f. 419 (3-f) ; f. 420 is a distorted form. Cleavage : octahedral, highly perfect. Twins : twinning-plane, octahedral ; f . 418, is NATIVE ELEMENTS. 229 an elliptic twin of f. 419, the middle portion between two opposite sets oi six planes being wanting. Rarely massive. II.. 10. G. 3.5295, Thompson. Lustre brilliant adamantine. Color white or colorless : occasionally tinged yellow, red, orange, green, blue, brown, sometimes black. Transparent ; translucent when dark colored. Fracture conchoid al. Index of refraction 2-4. Exhibits vitreous electricity when rubbed. Oomp. Pure carbon, isometric in crystallization. Var. ] . Ordinary, or crystallized. The crystals often contain numerous microscopic cavi- ties, as detected by Brewster ; and around these cavities the diamond shows evidence, by polarized light, of compression, as if from pressure in the included gas when the diamond was crystallized. The coarse varieties, which are unfit, in consequence of imperfections, for use in jewelry, are called bort ; they are sold to the trade for cutting purposes. 2. Massive. In black pebbles or masses, called carbonado, occasionally 1,000 carats in weight. H =10 ; G. =3-012-3-416. Consists of pure carbon, excepting 0'27 to 2'07 p. c. (Brazil). 3. Anthracitic. Like anthracite, but hard enough to scratch even the diamond.^ In glo- bules or mammillary masses, consisting partly of concentric layers; fragile ; G =1'66; com- position, Carbon 97, hydrogen 0*5, oxygen 15. Cut in facets and polished, it refracts and disperses light, with the white lustre peculiar to the diamond. Locality unknown, but sup- posed to come from Brazil. Pyr., etc. Burns, and is wholly consumed at a high temperature, producing carbomo dioxide. It is not acted on by acids or alkalies. Diff. Distinguished by its extreme hardness, brilliancy of reflection, and adamantine lustre. Oba, The diamond often occurs in regions that afford a laminated granular quartz rock, called itacolumyte, which pertains to the talcose series, and which in thin slabs is more or less flexible. This rock is found at the mines of Brazil and the Urals ; and also in Georgia and North Carolina, where a few diamonds have boen found. It has also been detected in a species of conglomerate, composed of rounded siliceous pebbles, quartz, chalcedony, etc., cemented by a kind of ferruginous clay. Diamonds are usually, however, washed out from the soil. The Ural diamonds occur in the detritus along the Adolfskoi rivulet, where worked for sold, and also at other places. In India the diamond is met with at Purteal, between Hyderabad and Masulipata m, where the famous Kohinoor was found . The locality on Borneo is at Pontiana, on the west side of the Ratoos mountain. Also found in Australia. The diamond region of South Africa, discovered in 18(57, is the most productive at the present time. The diamonds occur in the gravel of the Vaal river, from Potchefstrom, cap- ital of the Transvaal Republic, down its whole course to its junction with the Orange river, and thence along th-3 latter stream for a distance of 60 miles. In addition to this the dia- monds are found also in the Orange River Republic, in isolated fields or Pans, of which Du Toit's Pan is the most famous. The number of diamonds which have been found at the Ciipo is very laro-e, and some of them are of considerable size. It has been estimated that the valuo of those obtained from Maroh, 1867, to November, 1875, exceeded sixty millions of dollars. As a consequence of this production the market value of the stones has been much dunin- In the United States a few crystals have been met with in Rutherford Co., N. C., and Hall Co., Ga. ; they occur also at Portis mine, Franklin Co., N. C. (Genth) ; one handsome one, over % in. in diameter, in the village of Manchester, opposite Richmond, Va. In California, at Cherokee ravine, in Butte Co. ; also in N. San Juan, Nevada Co., and elsewhere in the gold washings. Reported from Idaho, and with platinum of Oregon. The largest diamond of which we have any knowledge is mentioned by Tavermer as i possession of the Great Mogul. It weighed originally 900 carats, or 2769 3 grains, but was reduced by cutting to 861 grains. It has the form and size of half a hen's egg. It was found in 1550, in the mine of Colone. The Pitt or Regent diamond weighs but 136 2o carats, pi 41 9i o-rains but is of unblemished transparency and color. It is cut in the form ot a bril liant, and its value is estimated at 125,000. The Kohinoor measured, on its arrival m fing land about If inches in its greatest diameter, over f of an inch in thickness, and weighe ISiV, carats, and was cut with many facets. It has since been recut, and reduced to a dia meter of 1-V by 1* nearly, and thus diminished over one-third in weight. It is supposed by Mr. Tennant to have been originally a dodecahedron, and he suggests that the great Russian diamond and another large slab weighing 130 carats were actually cut from the original do< cahedron. Tavernier gives the original weight at 787| carats. The Rajah of Mattan has in his possession a diamond from Borneo, weighing 367 carats. The mines of Brazil were not known to afford diamonds till the commencement of the eighteenth century. 230 DESCRIPTIVE MINERALOGY. GRAPHITE. Plumbago. Hexagonal. In flat six-sided tables. The basal planes (0) are often striated "parallel to the alternate edges. Cleavage : basal, perfect. Com- monly in imbedded, foliated, or granular masses. Rarely in globular con- cretions, radiated in structure. H.=l-2. G.= 2-09-2-229. Lustre metallic. Streak black and shining. Color iron-black -dark steel-gray. Opaque. Sectile ; soils paper. Thin laminae flexible. Feel greasy. Var. (a) Foliated ; (b) columnar, and sometimes radiated ; (c) scaly, massive, and slaty ; (d) granular massive ; (e) earthy, amorphous, without metallic lustre except in the streak ; (/) in radiated concretions. Comp. Pure carbon, with often a little iron sesquioxide mechanically mixed. Pyr., etc. At a high temperature it burns without flame or smoke, leaving usually somo red oxide of iron. B.B. infusible; fused with nitre in a platinum spoon, deflagrates, con- verting the reagent into potassium carbonate, which effervesces with acids. Unaltered by acids. Dift See molybdenite, p. 233. Obs. Graphite occurs in beds and imbedded masses, laminae, or scales, in granite, gneiss, mica schists, crystalline limestone. It is in some places a result of the alteration by heat of the coal of the coal formation. Sometimes met with in greenstone. It is a common furnace product Occurs at Borrowdale in Cumberland ; in Glenstrathfarrar in Invernesshire ; at Arendal in Norway; in the Urals, Siberia, Finland ; in various parts of Austria; Prussia; France. Large quantities are brought from the East Indies. In the United States, the mines of Sturbridge, Mass., of Ticonderoga and Fishkill, N. Y., of Brandon, Vt., and of Wake, N. C., are worked; and that of Ashford, Conn., formerly afforded a large amount of graphite. It occurs sparingly at many other localities. The name black lead, applied to this species, is inappropriate, as it contains no l^ad. The name graphite, of Werner, is derived from ypdw, to write. Nordenskiuld makes the graphite of Ersby and Storgard monodinie. II. SULPHIDES, TELLURIDES, SELENIDES, ARSEN- IDES, BISMUTHIDES. 1. BINARY COMPOUNDS. SULPHIDES AND TELLUKIDES OF THE METALS OF THE SULPHUR AND AKSENIO GROUPS. REALGAR,* Monoclinic. 6" = 66 5', /A 7= 74 26', Marignac, Scacchi, A 14 138 21' ; c:b: d = 0-6755 : 0-6943 : 1. Habit pris- matic. Cleavage : i-l, O rather perfect ; I, i-i in traces. Also granular, coarse or fine ; compact. H.=l'5-2. G.=3'4-3-6. Lustre resinous. Color aurora-red or orange-yellow. Streak varying from orange-red to aurora-red. Transparent translu- cent. Fracture conchoidal, uneven. Comp, AsS= Sulphur 29.9, arsenic 70*1=100. Pyr,, etc. In the closed tube melts, volatilizes, and gives a transparent red sublimate ; in the open tube, sulphurous fumes, and a white crystalline sublimate of arsenous oxide. B.B. on jharcoal burns with a blue flame, emitting arsenical and sulphurous odors. Soluble in caustia alkalies. Obs. Occurs with ores of silver and lead, in Upper Hungary ; in Transylvania ; at Joachims- thal ; Schneeberg ; Andreasberg ; in the Binnenthal, Switzerland, in dolomite ; at Wiesloob in Baden ; near Julamerk in Koordistan ; in Vesuvian lavas, in minute crystals. ORPIMENT.* Orthorhombic. 7 A 1 = 100 40', O A 14 = 126 30', Mohs. c : I : d == 1-3511 : 1-2059 : 1. Cleavage : i-l highly perfect, i-l in traces, i-l longi- tudinally striated. Also, massive, foliated, or columnar; sometimes reui- form. H. = 1-5-2. G. = 3-48, Haidinger. Lustre pearly upon the faces ot per- fect cleavao-e ; elsewhere resinous. Color several shades of lemon-yellow. Streak yellow, commonly a little paler than the color. Subtransparent-- Biibtranshicent. Sub-sestUe. Thin laminae obtained by cleavage flexible but not elastic. Oomp. As 2 S 3 = Sulphur 39, arsenic 61=100. Pvr., etc. In the closed tube, fuses, volatilizes, and gives a dark yellow sublimate ; other reactions the same as under realgar. Dissolves in nitro-hydrochloric acid and caustic alkalies. Obs Orpiment in small crystals is imbedded in clay at Tajowa, in Upper Hungary, usually in foliated and fibrous masses, and in this form is found at Kapmk at Moldawa, and at Felsbbanya ; at Hall in the Tyrol it is found in gypsum ; at St. Gothard m dolomite ; at 232 DESCRIPTIVE MINERALOGY. the Solfatara near Naples. Near Julamerk in Koordistan. Occurs also at Acobambillo, Pent Small traces are met with in Edenville, Orange Co. , N. Y. The name orpiment is a corruption of its Latin name auripigmentum, " golden paint" which was given in allusion to the color, and also because the substance was supposed to con- tain gold. DIMORPHITE of Scaccbi may be, according to Kenngott, a variety of orpiment. STIBNITE, Antimonite. Gray Antimony. Antimony Glance. Antimonglanz, Germ. Orthorhombic. /A 1= 90 54/, O A 14 = 134 16', Krenner ; c\l:d = 1-0259 : 1-0158 : 1. O A 1 = 124 423 423 45'; A 1-2 = 134 Lateral planes deeply striated longitudinally. Cleavage : i-l highly perfect. Often columnar, coarse or tine ; also granular to impalpable. H.=2. G. =4-516, Haiiy. Lustre metallic. Color and streak lead- gray, inclining to steel-gray : sub- ject to blackish tarnish, sometimes iridescent. Fracture small sub-con- choidal. Sectile. Thin laminae a little flexible. Comp. Sb 2 S 3 = Sulphur 28 2, antimony 71 8=100. Pyr., etc, In the open tube sulphurous and antimonous fumes, the latter condensing as a white sublimate which B.B. is non-volatile. On charcoal fuses, spreads out, gives sulphurous and antimonous fumes, coats the coal white ; this coating treated in R.F. tinges the flame greenish -blue. Fus. =1. When pure perfectly soluble in hydrochloric acid. Diff Distinguished by its perfect cleavage ; also by its extreme fusibility and other blow- pipe characters. Ob-. Occurs with spathic iron in beds, but generally in veins. Often associated with blende, barite, and quartz. Met with in veins at Wolfsberg. in the Harz ; at Briiunsdorf, near Freiberg ; at Przibram ; in Hungary; at Pereta, in Tuscany; in the Urals; in Dumfriesshire; in Cornwall. Also found in different Mexican mines. Also abundant in Borneo. In the United States, it occurs sparingly at Carmel, Me. ; at Cornish and Lyme, N. H. ; at u Soldier's Delight," Md. ; in the Humboldt mining region in Nevada ; also in the mines of Aurora, Esmeralda Co., Nevada. Also found in New Brunswick, 20 m. from Fredericton, S. W. side of St. John R. This ore affords much of the antimony of commerce. The crude antimony of the shops is obtained by simple fusion, which separates the accompanying rock. From this product most of the pharmaceutical preparations of antimony are made, and the pure metal extracted. LIVING STONITE (Barcena). Resembles stibnite in physical characters, but has a red streak, and contains, besides sulphur and antimony, 14 p. c. mercury. Huitzuco, State of Guerrero, Mexico, gee p. 430. BISMUTHINITE. Bismuth Glance. Wismuthglanz, Germ. Cleavage : brachydiagonal In acicular crystals. Also Orthorhombic. /A / = 91 30', Haidinger. perfect ; macrodiagonal less so ; basal perfect, massive, with a foliated or fibrous structure. ^ H. = 2. G. = 6-4-6-459 ; 7'2 ; 7-16, Bolivia, Forbes. Lustre metallic. Streak and color lead-gray, inclining to tin-white, with a yellowish or irides- cent tarnish. Opaque. SULPHIDES, TELLUKIDES, SELENIDES, ETC. 233 Comp. Bi 2 S 3 = Sulphur 18'75, bismuth 81 '25=100 ; isomorphous with stibnite. Pyr,, etc. In the open tube sulphurous fumes, and a white sublimate which B.B. fuses into drops, brown while hot and opaque yellow on cooling. On charcoal at first gives sul- phurous fumes, then fuses with spirting, and coats the coal with yellow bismuth oxide. Fus. =1. Dissolves readily in hot nitric acid, and a white precipitate falls on diluting with water. Obs. Found at Brandy Gill, Carrook Fells, in Cumberland ; near Redruth; at Botallack near Land's End ; at Borland Mine, Gwennap ; with childrenite, near Callington ; in Saxony; at Riddarhyttan, Sweden; near Sorata, Bolivia. Occurs in Rowan Co., N. C., at the Barn- hardt vein ; at Haddam, Ct. ; Beaver Co., Utah. GUANAJUATITE ; F'renzelite. Fernandez, 1873 ; Castillo, 1873 ; Frenzel, 1874. A bismuth selenide, Bi 2 Se 3 ; sometimes with part of the selenium replaced by sulphur, that is, Bi 2 (Se,S) 3 , with Se : S 3 : 2, which requires Selenium 23 '8, sulphur 6 '5, bismuth 697=100. Isomor- phous with stibnite and bismuthinite (Schrauf). Guanajuato, Mexico. SILAONITB from Guanajuato is Bi 3 Se (Fernandez). See p. 428. TETRADYMITB, Tellurwismuth, G&rm. Hexagonal. Of\R = 118 38', .# A 72 = 81 2' ; c = 1-5865. Crystals often tabular. Cleavage : basal, very perfect. Also massive, foliated, or granular. H. = l'5-2. G.=7'2-7-9. Lustre metallic, splendent. Color pale steel- gray. Kot very sectile. Laminae flexible. Soils paper. Comp., Var. Consists of bismuth and tellurium, with sometimes sulphur and selenium. If sulphur, when present, replaces part of the tellurium, the analyses for the most part afford the general formula Bi 2 (Te, S) 3 . Var. I. Free from sulphur. Bi 2 Te 3 = Tellurium 48-1, bismuth 51 "9; G. =7-868, from Dahlonega, Jackson; 7-642, id., Balch. 2. Sulphurous. Containing 4 or 5 p. c. sulphur. G.=7-500, crystals from Schubkau, Wehrle. Pyr. In the open tube a whit/; sublimate of tellurous oxide, which B.B. fuses to colorless drops. On charcoal fuses, gives white fumes, and entirely volatilizes ; tinges the R. F. bluish- green ; coats the coal at first white (tellurous oxide), and finally orange-yellow (bismuth oxide) ; some varieties give sulphurous and selenous odors. Diflf. Distinguished by its easy fusibility ; tendency to foliation, and high specific gravity. Obs. Occurs at Schubkau, near Schemnitz ; at Retzbanya ; Orawicza; at Tellemark in Norway; at Bastnaes mine, near Riddarhyttan, Sweden. In the United States, associated with gold ores, in Virginia ; in North Carolina, Davidson Co. , etc. Also occurs in Georgia, 4 m. E. of Dahlonega, and elsewhere ; Highland, Montana T. ; Red Cloud mine, Colorado, rare ; Montgomery mine, Arizona. JOSEITE. _ A bismuth telluride, in which half the tellurium is replaced by sulphur and uelenium ; Brazil. WEHRLITE. Composition probably Bi(Te, S). G. =8-44. Deutsch Pilsen, Hungary. MOLYBDENITE.* Molybdanglanz, Germ. In short or tabular hexagonal prisms. Cleavage : eminent, parallel to base of hexagonal prisms. Commonly foliated, massive, or in scales: also tine granular. PL 1-1-5, being easily impressed by the nail. G.=4-44-4-8. Lustre metallic. Color pure lead-gray. Streak similar to color, slightly inclined to green. Opaque. Laminae very flexible, not elastic. SectiJe, and almost malleable. Bluish-gray trace on paper. 234 DESCRIPTIVE MINERALOGY. Comp. MoS a = Sulphur 41'0, molybdenum 59'0=100, Pyr., etc. In the open tube sulphurous fumes. B.B. in the forceps infusible, imparts a yellowish-green color to the tiame ; on charcoal the pulverized mineral gives in O. F. a strong odor of sulphur, and coats the coal with crystals of molybdic oxide, which appear yellow while hot, and white on cooling ; near the assay the coating is copper-red, and if the white coating be touched with an intermittent R. F., it assumes a beautiful azure-blue color. Decomposed by nitric acid, leaving a white or grayish residue (rnolybdic oxide). Diff. Distinguished from graphite by its color and streak, and also by its behavior (yield- ing sulphur, etc. ) before the blowpipe. Obs Molybdenite generally occurs imbedded in, or disseminated through, granite, gneiss, zircon-syenite, granular limestone, and other crystalline rocks. Found in Sweden ; Norway ; Russia. Also in Saxony ; in Bohemia ; Rathausberg in Austria ; near Miask, Urals ; Chessy in France ; Peru ; Brazil ; Calbeck Fells, and elsewhere in Cumberland ; several of the Cornish mines ; in Scotland at East Tulloch, etc. In Maine, at Blue Hill Bay and Camdage farm. In Conn,, at Haddam. In Vermont, at Newport. In N. Hampshire, at Westmoreland ; at Llandaff ; at Franconia. In Mass., at Shutesbury ; at Brimfield. In N. York, near Warwick. In Penn., in Chester, on Chester Creek ; near Concord, Cabarrus Co., N. C. In California, at Excelsior gold mine, in Excel- aior district. In Canada, at several places. 2. BINARY COMPOUNDS. SULPHIDES, TELLURIDES, ETC., OF METALS OF THE GOLD, IRON, AND TIN GROUPS. A. BASIC DIVISION. DYSCRASITE. Antimonial Silver. Antimon-Silber, Germ. Orthorhornbic. /A 1 = 119 59' ; A 14 130 41' ; c : I : d = 1-1633 : 1-7315:1; O A 1 = 126 40' ; A l- = 146 6'. Cleavage : basal distinct : \-l also distinct ; / imperfect. Twins : stellate forms and hexagonal prisms. Prismatic planes striated vertically. Also massive, granular ; par- ticles of various sizes, weakly coherent. H.= 3-5-4. G.= 9-44-9 -82. Lustre metallic. Color and streak silver- white, inclining to tin-white ; sometimes tarnished yellow or .blackish. Opaque. Fracture uneven. Comp. Ag 4 Sb= Antimony 22, silver 78=100. Also Ag 6 Sb= Antimony 15 '66, silver 84*34, and other proportions. Pyr., etc. B. B. on charcoal fuses to a globule, -coating the coal with white antimonous oxide, and finally giving a globule of almost pure silver. Soluble in nitric acid, leaving anti- monous oxide. Obs. Occurs near Wolfach in Baden, Wittichen in Suabia, and at Andreasberg ; also at AUemont in Daupbine, Casalla in Spain, and in Bolivia, S. A. DOMEYKITE, Arsenikkupfer, Germ. Reniform and botryoidal ; also massive and disseminated. H.:= 3-3-5. G.= T-7'50, Portage Lake, Genth. Lustre metallic but dull on exposure. Color tin-white to steel-gray, with a yellowish to pinchbeck- brown, and, afterward, an iridescent tarnish. Fracture uneven. TELLURIDES, SELENIDE8, ETC. 235 Comp. Cu 3 As=Arsenic 28 -3, copper 71 7=100. Pyr., etc. In the open tube fuses and gives a white crystalline sublimate of arsenoua oxide. B.B. on charcoal arsenical fumes and a malleable metallic globule, which, on treat- ment with soda, gives a globule of pure copper. Not dissolved in hydrochloric acid, but soluble in nitric acid. Obs From the mines of Chili. In N, America, found on the Sheldon location, Portage Lake ; and at Michipicoten Island, in L. Superior. ALGOPONITE. Composition, Cu 6 As = Arsenic 16 '5, copper 83*5. Chili ; also Lake Superior. WHITNEVITE. CuAs=Arsenic 11*6, copper 88 '4 =100. Houghton, Mich., also Calif ornia, Arizona. B. PROTO DIVISION. (a) Galenite Group. Isometric ; holohedral. ARGENTITE. Silver Glance. Vitreous Silver. Silberglanz, Germ. Isometric. Cleavage : dodecahedral in traces. Also reticulated, arbores- cent, and filiform ; also amorphous. H.=:2-2-5. G.= 7-196-7-365. Lustre metallic. Streak and color black- ish lead-gray ; streak shining. Opaque. Fracture small sub-conchoidal, ineven. Malleable. Comp Ag 2 S=Sulphur 12 '9, silver 87 '1=100. Pyr., etc. In the open tube gives off sulphurous oxide. B.B. on charcoal fuses with intu- mescence in O.F., emitting sulphurous fumes, and yielding a globule of silver. Diff. Distinguished from other silver ores by its malleability. Obs. Found in the Erzgebirge ; in Hungary ; in Norway, near Kongsberg ; in the Altai ; in the Urals at the Blagodat mine ; in Cornwall ; in Bolivia ; Peru ; Chili ; Mexico, etc. Occurs in Nevada, at the Comstock lode, and elsewhere. OLDIIAMITE from the Busti meteorite is essentially CaS. NAUMANNITE. A silver selenide, containing also some lead. Color iron-black. From the Harz. EUCAIRITE. A silver-copper selenide, (Cu, Ag) 2 Se. Color silver-white to gray. Sweden ; Chili. CROOKESITE. Massive, compact ; no trace of crystallization. H.=2-5-3. &.=6-90. Lustre metallic. Color lead-gray. Brittle. Comp (Cu 2 ,Tl,Ag) Se=Selenuim 33 -28, copper 45-76. thallium 17-25, silver 3'71.100. Pyr., etc. B.B. fuses very easily to a greenish-black shining enamel, coloring the flame strongly green. Insoluble in hydrochloric acid ; completely soluble in nitric acid. Obs. From the mine of Skrikerum in Norway. Formerly regarded as selenide of copper or berzelianite. GALENITE. Galena. Bleiglanz, Germ. Isometnc ; habit cubic (see f. 38, 39, etc., p. 15). Cleavage, cubic, per- fect ; octahedral in traces. Twins: twinning-plane, the octahedral plane, f. 425 (f. 263, p. 88); the same kind of composition repeated, f. 426, anJ 236 DESCRIPTIVE MINERALOGY. flattened parallel to 1. Also reticulated, tabular ; coarse or fine granular ; sometimes impalpable ; occasionally fibrous. 424 426 II.=2-5-2-75. G.=7'25-7'7. Lustre metallic. Color and streak pure lead-gray. Surface of crystals occasionally tarnished. Fracture flat sub- chonchoidal, or even. Frangible. Comp., Var PbS = Sulphur 13 "4, lead 86 -6 = 100. Contains silver, and occasionally selen- ium, zinc, cadmium, antimony, copper, as sulphides ; besides, also, sometimes native silver and gold ; all galenite is more or less argentiferous, and no external characters serve to dis- tinguish the relative amount of silver present. Pyr. In the open tube gives sulphurous fumes. B.B. on charcoal fuses, emits sulphurous fumes, coats the coal yellow, and yields a globule of metallic lead. Soluble in nitric acid. Diff. Distinguished in all but the finely granular varieties by its perfect cubic cleavage. Obs. Occurs in beds and veins, both in crystalline and uncrystalline rocks. It is often associated with pyrite, marcasite, blende, chalcopyrite, arsenopyrite, etc., in a gangue of quartz, calcite, barite, or fluorite, etc. ; also with cerussite, anglesite, and other salts of lead, which are frequent results of its alteration. It is also common with gold, and in veins of silver ores. Some prominent localities are : Freiberg in Saxony, the Harz, Przibram and Joachimsthal, Styria ; and also Bleiberg, and the neighboring localities of Carinthia, Sala in Sweden, Leadhills and the killas of Cornwall, in veins; Derbyshire, Cumberland, and the northern districts of England ; in Nertschinsk, East Siberia; in Algeria; near Cape of Good Hope ; in Australia ; Chili ; Bolivia, etc. Extensive deposits of this ore in the United States exist in Missouri, Illinois, Iowa, and Wisconsin. Other important localities are : in New York, Rossie, St. Lawrence Co. ; Wurtzboro, Sullivan Co. ; at Ancram. Columbia Co. ; in Ulster Co. In Maine, at Lubec. In New Hampshire, at Eaton and other places. In Vermont, at Thetford. In Connecticut, at Middletown. In Massachusetts, at Newburyport, at Southampton, etc. In Pennsylvania, at Phenixville and elsewhere. In Virginia, at Austin's mines in Wythe Co., Walton's gold mine in Louisa Co., etc. In Tennessee, at Brown's Creek, and at Haysboro, near Nashville. In Michigan, in the region of Chocolate river, and Lake Superior copper districts, on the N. shore of L. Superior, in Neebing on Thunder Bay, and around Black Bay. In Cali- fornia, at many of the gold mines. In Nevada, abundant on Walker's river, and at Steam- boat Springs, Galena district. In Arizona, in the Castle Dome, Eureka, and other districts. In Colorado, at Pike's Peak, etc. CLAUSTHALITB. Selenblei, Germ. Isometric. Occurs commonly in fine granular masses ; some specimens foliated. Cleavage cubic. H.=2'5-3. Gr.= 7-6-8-8. Lustre metallic. Color lead -gray, somewhat bluish. Streak darker. Opaque. Fracture granular and shining. Comp., Var. PbSe = Selenium 27'6, lead 72'4=100. Besides the pure selenide of lead, there are others, often arranged as distinct species, which contain cobalt, copper, or mercury in place of part of the lead, arid sometimes a little silver or iron. SULPHIDES, TKLLURIDES, SELENIDES, ETC. 237 Pyr. Decrepitates in the closed tube. In the open tube gives selenous fumes and a red sublimate. B. B. on charcoal a strong selenous odor ; partially fuses. Coats the coal near the assay at first gray, with a -reddish border (selenium), and later yellow (lead oxide) ; when pure entirely volatile ; with soda gives a globule of metallic lead. Obs Much resembles a granular galenite; but the faint tinge of blue and the B.B selenium fumes serve to distinguish it. Found at Glausthal, Tilkerode, Zorge, Lehrbach, etc., in the Harz ; at Rehjsberg in Sax ony ; at the Rio Tinto mines, Spain ; Cacheuta mine, Mendoza, S. A. ZORGITE and LEHKBACIIITE occur with clausthalite in the Harz. Zorgite is a lead-copper eelenide. Lehrbachite is a lead-mercury selenide. BEBZELIANITE. Cu 2 Se= Selenium 38 '4, copper 61 '6=100. Color silver -white. From Sweden, also the Harz. ALTAITE. Composition PbTe= Tellurium 38 '3, lead 61 '17. Isometric. Color tin-white. From Savodinski in the Altai ; Stanislaus mine, Cal. ; Red Cloud mine, Colorado ; Province of Coquimbo, Chili. TIEMANNITE (Selenquecksilber, Germ.). A. mercury selenide, probably HgSe. Massive. Found in the Harz ; also California. BORNITE. Erubescite. Purple Copper Ore. Buntkupfererz, Germ. Isometric. Cleavage : octahedral in traces. Massive, structure granular or compact. H. 3. G-.=4-4-5*5. Lustre metallic. Color between copper-red and pinchbeck-brown; speedily tarnishes. Streak pale grayish- black, slightly shining. Fracture small conchoidal, uneven. Brittle. Oomp. For crystallized varieties FeCu 3 S 3 , or sulphur 28 '06, iron 16'36, copper 55 '58=100. Other varieties are : Fe 2 Cu 3 S 4 , FeCu 5 S 3 , and so on. The ratio of R (Cu or Fe) to S has the values 5 : 4, 4 : 3, 3 : 2, 7 : 3 (Rammelsberg). Analysis, CoUier, from Bristol, Ct. Sulphur 25-83, copper 61 '79, iron 11 '77, silver tr. =99-39 (R : 8=3 : 2). Pyr., etc. In the closed tube gives a faint sublimate of sulphur. In the open tube yields sulphurous oxide, but gives no sublimate. B.B. on charcoal fuses in R.F. to a brittle mag- netic globule. The roasted mineral gives with the fluxes the reactions of iron and copper, and with soda a metallic globule. Soluble in nitric acid with separation of sulphur. Diff. Distinguished by its copper-red color on the fresh fracture. Obs. Found in the mines of Cornwall ; at Rose Island in Killarney, Ireland ; at Mount Catini, Tuscany; in the Mansfeld district, Germany; and in Norway, Siberia, Silesia, and Hungary. It is the principal copper ore at some Chilian mines; also common in Peru, Boli- via, and Mexico. At Bristol, Conn., it has been found abundantly in good crystals. Found massive at Mahoopeny, Penn., and in other parts of the same State; also at Chesterfield, Mass. ; also in New Jersey. A common ore in Canada, at the Acton and other mines. ALABANDITE (Manganglanz, Germ.). MnS= Sulphur 36*7, manganese 63.3=100. Isomet- ric. Cleavage cubic. Color black. Streak green. From Transylvania, etc. GKUNAUITE. A sulphide containing nickel, bismuth, iron, cobalt, copper. From Griinau, (5) Blende Group. Isometric ; tetrahedral. SPHALERITE or ZINC BLENDE. Black-Jack, Engl. Miners. Isometric: tetrahedral. Cleavage: dodecahedral, highly perfect. Twins: twinning-plane 1, as in f. 429. Also botryoidal, and other imitative shapes ; sometimes fibrous and radiated ; also massive, compact. H.= 3-5-4. G.= 3-9-4-2. 4-063, white, New Jersey. Lustre resinous to adamanite. Color brown, yellow, black, red, green ; white or yellow 238 DESCRIPTIVE MINERALOGY. when pure. Streak white reddish-brown. Transparent translucent, Fracture conchoidal. Brittle. 427 428 Comp., Var. ZnS Sulphur 33, zinc 67=100. But often having- part of the zinc replaced by iron, and sometimes by cadmium; also containing in minute quantities, thallium, indium, and gallium. Var. 1. Ordinary. Containing little or no iron ; colors white to yellowish- brown, sometimes black ; G. =3 9-4*1. 2. Ferriferous; Marmatite. Containing 10 p. c. 01 more of iron; dark-brown to black ; G.=8*9-4*2. The proportion of iron sulphide to zinc sulphide varies from 1 : 5 to 1 : 2. 3. Cudmiferous ; Przibramite. The amount of cadmium present in any blende thus far analyzed is less than 5 per cent. Each of the above varieties may occur (a) in crystals ; (b) firm, fibrous, or columnar, at times radiated or plumose ; (c) cleavable, massive, or foliated ; (d) granular, or compact massive. Pyr., etc. In the open tube sulphurous fumes, and generally changes color. B.B. on charcoal, in R.F., some varieties srive at first a reddish- brown coating of cadmium oxide, and later a coating of zinc oxide, which is yellow while hot and white after cooling. With cobalt solution the zinc coating gives a green color when heated in O.P. Most varieties, after roasting, give with borax a reaction for iron. With soda on charcoal in R.F. a strong green zinc flame. Difficultly fusible. Dissolves in hydrochloric acid, during which sulphuretted hydrogen is disengaged. Some specimens phosphoresce when struck with a steel or by friction. Diff. Generally to be distinguished by its perfect cleavage, giving angles of 60 and 120 ; by its resinous lustre, and also by its infusibility. Obs. Ocouis in both crystalline and sedimentary rocks, and is usually associated with galenite ; also with barite, chalcopyrite, fluorite, siderite, and frequently in silver mines. Derbyshire. Cumberland, and Cornwall, afford different varieties ; also Transylvania; Hun- gary ; the Harz; Sahla in Sweden; Ratieborzitz in Bohemia; many Saxon localities. Splendid crystals in dolomite are found in the Binnenthal. Abounds with the lead ore of Missouri, Wisconsin, Iowa, and Illinois. In JV. York, Sulli- van Co., near Wurtzboro' ; in St. Lawrence Co., at Cooper's falls, at Mineral Point; at the Ancram lead mine in Columbia Co. ; in limestone at Lockport and other places. In Mass., at Sterling ; at the Southampton lead mines ; at Hatfield. In N. Hamp., at the Eaton lead mine ; at Warren, a large vein of black blende. In Maine, at the Lubec lead mines, etc. In Conn., at Roxbury, and at Lane's mine, Monroe. In N. Jersey, a white variety at Frank- lin. In Penn., at the Wheatley and Perkiomen lead mines ; near Friedensville, Lehigh Co. In Virginia, at Austin's lead mines, Wythe Co. In Michigan, at Prince vein, Lake Superior. In Illinois, near Rosiclare ; near Galena, in stalactites, covered with pyrite, and galenite In Wisconsin, at Mineral Point. In Tennessee, at Haysboro', near Nashville. Named blende because, while often resembling galena, it yielded no lead, the word in Ger meaning blind or deceiving. Sphalerite is from (npoAepos, treacherous. (c) Chalcocite Group. Orthorhombic. HESSITE.* Tellursilber, Germ. Orthorhombic, and resembling chalcocite. Cleavage indistinct Mas fli ve ; compact or fine grained ; rarely coarse-granular. SULPHIDES, TELLURIDES, SELENIDES, ETC. 239 H.=2-3-5. G. 8-3-8*6. Lustre metallic. Color between lead-gray and steel-gray. Sectile. Fracture even. Comp Ag 2 Te= Tellurium 37 '2, silver 62 '8 =100. Silver sometimes replaced in part by gold. Pyr. In the open tube a faint white sublimate of tellurous oxide, which B.B. fuses to colorless globules. On charcoal fuses to a black globule ; this treated in R.F. presents on cooling white dendritic points of silver on its surface ; with soda gives a globule of silver. Obs. Occurs in the Altai, in Siberia, in a talcose rock ; at Nagyag in Transylvania, and at Retzbanya in Hungary ; Stanislaus mine, Calaveras Co. , Cal. ; Red Cloud mine, Colorado ; Province of Coquimbo, Chili. PETZITE. Differs from hessite in that gold replaces much of the silver. H. 2*5. G.= 8 '72-8 '83, Petz; 9-0*4, Kiistel. Color between steel-gray and iron-black, sometimes with pavonine tarnish. Streak iron-black. Brittle. Analysis by Genth, from Golden Rule mine, tellurium 32'68, silver 41-8H, gold 25 -60 = 10014. Occurs at Nagyag, Stanislaus mine, California, and several localities in Colorado. TAPALPITE (Tellurwismuthsilber). Composition (Ramm.), Ag 2 Bi. 2 Te.,S(Ag 2 S + 2BiTe). Granular. Color gray. Sierra de Tapalpa, Mexico. ACANTHITE. Orthorhombic. /A / = 110 54' ; O A l-l = 124 42', Dauber ; i : I : d = 1-4442 : 1-4523 : 1. A l- = 135 10' ; A 1 = 119 42'. Twins : parallel to l-l. Crystals usually slender-pointed prisms. Cleavage indis- tinct. H.=2-5 or under. G.=7'16-7'33. Lustre metallic. Color iron-black or like argentite. Fracture uneven, giving a shining surface. Sectile. Comp Ag 2 S, or like argentite. Sulphur 12 9, silver 87-1=100. Pyr. Same as for argentite, p. 235. Obs. Pound at Joachimsthal ; also near Freiberg in Saxony. CHALCOCITB. Chalcosine. Vitreous Copper. Copper Glance. Kupferglanz, Germ. Orthorhombic. /A /= 119 35', A I-l = 120 57'; r : I : a = 1*6676 : 1-7176 : 1 ; A 1 = 117 24' ; A \-l = 135 52'. Cleavage : /, indistinct. Twins : t winning-plane, /, producing hexagonal, or stellate forms (left half 430 431 432 433 Bristol, Ct. \ Bristol, Ct Bristol, Ct. of f. 432) ; also 4-, a cruciform twin (f. 432), crossing; at angles of 111 and 69 ; f. 433, a cruciform twin, having O and I of one crystal parallel respectively to i4 and O of the other. Also massive, structure granular, or compact and impalpable 240 DE8CEIPTTVE MINERALOGY. H.=2*5-3. G. 5-5-5*8. Lustre metallic. Color and streak blackish lead-gray : often tarnished blue or green ; streak sometimes shining. Frac- ture conchoidal. Comp. Cu 2 S= Sulphur 20 '2, copper 79-8=100. Pyr,, etc. Yields nothing volatile in the closed tube. In the open tube gives off sulphur- ous fumes. B.B. on charcoal melts to a globule, which boils with spirting; with soda ia reduced to metallic copper. Soluble in nitric acid. Obs. Cornwall affords splendid crystals. The compact and massive varieties occur in Siberia, Hesse, Saxony, the Bunat, etc. ; Mt. Catini mines in Tuscany ; Mexico, Peru. Bolivia, Chili. In the United States, it has been found at Bristol, Conn. , in large and brilliant crystals. In Virginia, in the United States copper mine district, Orange Co. Between Newmarket and Taneytown, Maryland. In Arizona, near La Paz ; in N. W. Sonora. In Nevada, in Washoe, Humboldt. Churchill, and Nye Cos. HARRISITE of Shepard, from Canton mine, Georgia, is chalcocite with the cleavage of galenite (pseudomorphous, Gentli). STROMEYERITE, Silberkupferglanz, Germ. Orthorhombic : isomorphous with chalcocite. massive, compact. H.=:2-5-3. G.=6-2-6-3. Lustre metallic. Streak shining. Fracture subconchoidal. /A 7= 119 35'. Also Color dark steel-gray. Comp, AgCuS=Ag 2 S+Cu a S=Sulphur 15'7, silver 53-1, copper 31 '2-100. Pyr., etc. Fuses, but gives no sublimate in the closed tube. In the open tube sulphurous fumes. B.B. on charcoal in O.F. fuses to a semi-malleable globule, which, treated with the fluxes, reacts strongly for copper, and cupelled with lead gives a silver globule. Soluble in nitric acid. Obs, Found at Schlangenberg, in Siberia ; at Rudelstadt, Silesia ; also in Chili ; at Com- bavalla in Peru ; at Heintzelman mine in Arizona. STERNBERGITE."5 An iron-silver sulphide, AgFe 2 S 3 . Johanngeorgenstadt and Joachimsthal. Ehombohedral. 434 (d) Pyrrhotite Group. Hexagonal. CINNABAR. Zinnober, Germ. E A E = 92 36', R/\O = 127 6' ; c = 1-1448. Ac- cording to DesCloizeaux, tetartohedral, like quartz. Also granular, massive ; sometimes forming super- ficial coatings. Cleavage: /, very perfect. Twins: twinning- plane O. H=2-2-5. G=8'998, a cleavable variety from Neumarktel. Lustre adamantine, inclining to metal- lic when dark-colored, and to dull in fjiable varieties. Color cochineal-red, often inclining to brownish-red and lead-gray. Streak scarlet, sub transparent, opaque. Fracture subconchHdal. un- even. Sectile. Polarization circular. Comp HgS (or Hg 3 S 3 )= Sulphur 13-8, mercury 86 '2=100. Sometimes impurt Prom clay uon sesquioxide, bitumen. SULPHIDES, TELLURIDES, 8ELENIDES, ETC. 241 Pyr. In the closed tube a black sublimate. Carefully heated in the open tube gives RU! phurous fumes and metallic mercury, condensing in minute globules on the cold walls of the Cube. B.B. on charcoal wholly volatile if pure. Obs. Cinnabar occurs in beds in slate rocks and shales, and rarely in granite or porphyry. It has been observed in veins, with ores of iron. The most important European beds of this ore are at Almaden in Spain, and at Idria in Carniola. It occurs at Reichenau and Windisch Kappel in Cariiithia ; in Transylvania ; at Ripa in Tuscany ; at Schemnitz in Hungary ; in the Urals and Altai ; in China abundantly, and in Japan ; San Onof re and elsewhere in Mexico ; in Southern Peru ; forming extensive mines in California, in the coast ranges the principal mines are at New Almaden and the vicinity, in Santa Clara Co. Also in Idaho, in limestone, abundant. This ore is the source of the mercury of commerce, from which it is obtained by sublima tion. When pure it is identical with the manufactured vermilion of commerce. METACINNABARITE (Moore). A black mercury sulphide (HgS). Rarely crystallized H.=3. G.=7-75. Lustre metallic. Redington mine, Lake Co., Cal. (TUADALCAZARITE. Essentially HgS, with part (ifs) of the sulphur replaced by selenium, and part of the mercury replaced by zinc (Hg : Zn=6 : 1, Peterben ; 12 : 1, Ramm.). Massive. Color -deep black. Guadalcazar, Mexico. LEVIGLIANITE is a ferruginous variety from Levigliani, Italy. MILLERITE.* Capillary Pyrites. Haarkies ; Nickelkies, Germ. Ehombohedral. E A R = 144 8 ', Miller. c = 0-32955. 6>A72 = 15910'. Cleavage : rhombohedral, perfect. Usual in capillary crystals. Also in columnar tufted coatings, partly serai-globular and radiated. H.= 3-3-5. G.=4r-6-5'65. Lustre metallic. Color brass-yellow, inclin- ing to bronze-yellow, with often a gray iridescent tarnish. Streak bright. Brittle. Comp. NiS= Sulphur 35 6, nickel 64 "4=100. Pyr., etc. In the open tube sulphurous fumes. B.B. on charcoal fuses to a globule. When roasted, gives with borax and salt of phosphorus a violet bead in 0. F. , becoming gray in R.F. from reduced metallic nickel. On charcoal in R.F. the roasted mineral gives a coherent metallic mass, attractable by the magnet. Soluble in nitric acid. Obs. Found at Joachimsthal ; Przibram ; Riechelsdorf ; Andreasberg ; several localities in Saxony ; Cornwall. Occurs at the Sterling mine, Antwerp, N. Y. ; in Lancaster Co., Pa., at the Gap mine ; with dolomite, and penetrating calcite crystals, in cavities in limestone, at St. Louis, Mo. BEYRICHITE (Lube). Formula Ni 5 S 7 Sulphur 43-6, nickel 56'4=100. Color lead-gray. Occurs in radiated groups with millerite in the Westerwald. PYRRHOTTTE. Magnetic Pyrites. Magnetkies, Germ. Hexagonal. O A 1 = 135 8' ; c = 0-862. Twins : twinning-plane 1 (f . 435). Cleavage : O, perfect ; I, less so. Commonly 435 massive and amorphous; structure granular. H.=3-5-4:-5. G.=4-4:-4-68. Lustre metallic. Color between bronze-yellow and copper-red, and subject to speedy tarnish. Streak dark grayish- black. Brittle. Magnetic, being attractable in fine powder by a magnet, even when not affecting an ordinary needle. Comp. (1) Mostly Pe,S 8 =Sulphur 39-5, iron 60-5=100 ; but varyingto Fe 8 S 9 ,Fe 9 S,o and Fei Sj i. Some varieties contain 3-6 p. c. nickel. Horbachite contains (Wagner) 12 p. c. Ni. Pyr., etc. Unchanged in the closed tube. In the open tulre gives sulphurous oxide. On Ifi 242 DESCRIPTIVE MINERALOGY. charcoal in R.F. fuses to a black magnetic mass ; in O.F. is converted into iron sesqui Dxide, which with fluxes gives only an iron reaction when pure, but many varieties yield small amounts of nickel and cobalt. Decomposed by muriatic acid, with evolution of sulphuretted hydrogen. Dift. Distinguished by its magnetic character, and by its bronze color on the fresh fracture. Obs. Occurs in Norway ; in Sweden ; at Andreasberg ; Bodenmais in Bavaria ; N. Tagilsk ; in Spain ; the lavas of Vesuvius ; Cornwall. In N. America, in Vermont, at Stafford, Corinth, and Shrewsbury ; in many parts of Massachusetts ; in Connecticut, in Trumbull, in Monroe ; in N. York, near Natural Bridge in Diana, Lewis Co. ; at O'Neil mine and elsewhere in Orange Co. In N. Jersey, Morris Co., at Hurdstown. In Pennsylvania, at the Gap mine, Lancaster Co. , niccolif erous. In Tennes- see, at Ducktown mines. In Canada, at St. Jerome ; Elizabeth town, Ontario (f. 435), etc. The niccoliferous pyrrhotite is the ore that affords the most of the nickel of commerce. TKOILITE. According to the latest investigations of J. Lawrence Smith, composition FeS, iron proto-sulphide ; that is, iron 63 '6, sulphur 36 '4= 100. Occurs only in iron meteor- ites. DAUBRiiELiTE (Smith). Composition Cr Q S 3 . Observed in the meteoric iron of Northern Mexico ; occurring on the borders of troilite nodules. Similar to shepardite, Haidingei (=schreiber8ite, Shepard), described by Shepard (1846) as occurring in the Bishopville, S. C., meteoric iron. SCUREIBERSITE also solely a meteoric mineral. Contains iron, nickel, and phosphorus. WURTZITE (Spiauterite). ZnS, like sphalerite, but hexagonal in crystallization. Bolivia. GREENOCKITE. Hexagonal ; hemimorphic. A 1 = 136 24' ; c = 0-8247. Cleavage : /, distinct ; 0, imperfect. H.=3-3'5. G.^4'8-4'999. Lustre adamantine. Color honey-yellow; citron-yellow ; orange-yellow veined parallel with the axis ; bronze- yellow. Streak-powder between orange-yellow and brick red. Nearly transparent. Strong double refraction. Not thermoelectric, Breithaupt. Oomp. CdS (or Cd 3 S 3 )=Sulphur 22-2, cadium 77'8. Pyr., etc. In the closed tube assumes a carmine -red color while hot, fading to the original yellow on cooling. In the open tube gives sulphurous oxide. B. B. on charcoal, either alone or with soda, gives in B.F. a reddish-brown coating. Soluble in hydrochloric acid, evolving sulphuretted hydrogen. Obs. Occurs at Bishoptown, in Renfrewshire, Scotland ; also at Przibram in Bohemia ; on sphalerite at the Ueberoth zinc mine, near Friedensville. Lehigh Co., Pa., and atGranby, Mo. NICCOLITE. Copper Nickel. Kupfernickel, Rothnickelkies, Germ. Hexagonal. O A 1 = 136 35' ; c : 0-81944. Usually massive, structure nearly impalpable ; also reniform with a columnar structure ; also reticu- lated and arborescent. H.=5-5'5. G.=7-33-7'671. Lustre metallic. Color pale copper-red, with a gray to blackish tarnish. Streak pale brownish-black. Opaque. Fracture" uneven. Brittle. Comp. NiAs (or Ni 3 As 3 )= Arsenic 56 "4, nickel 43-6=100; sometimes part of the arsenic replaced by antimony. Pyr., etc. In the closed tube a faint white crystalline sublimate of arsenous oxide. In the open tube arsenous oxide, with a trace of sulphurous oxide, the assay becoming yellowish- green. On charcoal gives arsenical fumes and fuses to a globule, which, treated with borax glass, affords, by successive oxidation, reactions for iron, cobalt, and nickel. Soluble in nitro-hydrochloric acid. Diff Distinguished by its color from other similar sulphides, as also by its pyrognostica 243 Obs. Occurs at several Saxon mines, also in Thuringia, Hesse, and Styria, and at Alle- mont in Dauphiny ; occasionally in Cornwall ; Chili ; abundant at Mina de la Rioja, in the Argentine Provinces. Found at Chatham, Conn., in gneiss, associated with smaltite. BHKITHAUPTITE. Composition NiSb= Antimony 07 '8, nickel 32 '2=: 100. Color light copper-red. Andreasberg. ARITE. AJC. antimoniferous niccolite, containing 28 p. c. Sb. Basses-Pyrenees ; Wolfach, Baden. 0. DEUTO OR PYBITE DIVISION. 4 (a) Pyrite Group. FYRITE.* Iron Pyrites. Schwefelkies, Eisenkies, Germ. Isometric ; pjritohedral. The cube the most common form ; the pyrito- hedron, f. 92, p. 23, and related forms, f. 94, 95, 96, also very common. See also f. 103, 104, 105, p. 24. Cubic faces often striated, with striationa of adjoining faces at right angles, and due to oscillatory combination of the cube and pyritohedron, the striae having the direction of the edges between and i-2. Crystals sometimes acicular through elongation of cubic and other forms. Cleavage : cubic and octahedral, more or less distinct. Twins: twining-plane /, f. 276, p. 93. Also reniform, globular, stalactitic, with a crystalline surf ace ; sometimes radiated subfibrous. Massive. 436 437 438 Kossie. H.=6-6-5. G.=4-83-5-2. Lustre metallic, splendent to glistening. Color a pale brass-yellow, nearly uniform. Streak greenish or brownish- black. Opaque. Fracture conchoidal, uneven. Brittle. Strikes fire with steel. Comp. Var. FeS 2 = Sulphur 53'3, iron 46-7=100. Nickel, cobalt, and thallium, and also copper, sometimes replace a little of the iron, or else occur as mixtures ; and gold is some- times present, distributed invisibly through it. Pyr etc. In the closed tube a sublimate of sulphur and a magnetic residue, charcoal gives off sulphur, burning with a blue flame, leaving ^ a residue which reacts Ills a pyrrhotite. Insoluble in hydrochloric acid, but decomposed by nitric acid. Diff. Distinguished from chaJcopyrite by its greater hardness, since it cannot be cut with a knife ; as also by its pale color ; from marcasite by its specific gravity and malleable like gold . , , Obs. Pyrite occurs abundantly in rocks of all ages, from the oldest crystalline rocks to the 244 DESCRIPTIVE MUSTERA^OGT. most recent alluvial deposits. It usually occurs in small cubes, also in irregular spheroidal nodules and in veins, in clay slate, argillaceous sandstones, the coal formation, etc. The Cornwall mines, Alston-Moor, Derbyshire, Fahlun in Sweden, Kongsberg in Norway, Elba, Traversella in Piedmont, Peru, are well-known localities. Occurs in New England at many places : as the Vernon slate quarries ; Roxbury, Conn. , etc. In N. York^ at Rossie, at Schoharie ; iu Orange Co. , at Warwick and Deerpark, and many otherplaces. In Pennsylvania, at Little Britain, Lancaster Co. ; at Chester, Delaware Co."; in Carbon, York, and Chester Cos. ; at Cornwall, Lebanon Co., etc. In Wisconsin, near Mineral Point. In N. Car., near Greensboro', Guilford Co. Auriferous pyrite is common at the mines of Colorado, and many of those of California, as well as in Virginia and the States south. This species affords a considerable part of the iron sulphate and sulphuric acid of commerce and also much of the sulphur and alum. The auriferous variety is worked for gold in many gold regions. The name #yn'te is derived from TrOp, fire, and alludes to the sparks from friction. HAUERITE. Composition MnS 2 = Sulphur 53-7, manganese 46 '3 =100. Isometric. Color reddish-brown. Kalinka, Hungary. CHALOOPYRITE,* Copper Pyrites. Kupferkies, Genn. Tetragonal ; tetrahedral. A I-i = 135 25'; c = 0-98556 ; O A 1 =' 125 40' ; 1 A 1, pyr., = 109 53' ; 1 A 1 (f. 440) = 71* 20' and 70 7'. Cleav- age : %-i sometimes distinct ; 0, indistinct. Twins : twinning-plane I-i ; the plane 1 (see p. 94). Often massive. 440 H.=3'5-4. G. 4*l-4'3. Lustre metallic. Color brass-yellow ; subject to tarnish, and often iridescent. Streak greenish-black a little shining. Opaque. Fracture conchoidal, uneven. Comp.CuFeS 2 = Sulphur 34-9, copper 34 '6, iron 30'5=100. Some analyses give other proportions ; bub probably from mixture with pyrite. There are indefinite mixtures of the two, and with the increase of the latter the color becomes paler. This species, although tetragonal, is very closely isomorphous with pyrite, the variation from the cubic form being slight, the vertical axis being '98556 instead of 1. Traces of selenium have been noticed by Kersten in an ore from Reinsberg near Freiberg. Thallium is also present in some kinds, and more frequently in this ore than in pyrite. Pyr., etc. In the closed tube decrepitates, and gives a sulphur sublimate ; in the open tube sulphurous oxide. B.B. on charcoal gives sulphur fumes and fuses to a magnetic glo bule. The roasted ore reacts for copper and iron with the fluxes ; with soda on charcoal gives a globule of metallic iron with copper. Dissolves in nitric acid, excepting the sulphur, and forms a green solution ; ammonia in excess changes the green color to a deep blue. Diff, Distinguished from pyrite by its inferior hardness, it can be easily scratched with the knife ; and by its deeper color. Not malleable like gold, from which it differs also in being decomposed by nitric acid. SULPHIDES, TELLUKIDES, SELENIDESj ETC. 245 Obs. Cbalcopyrite is the principal ore of copper at the Cornwall mines. Occurs at Frei- berg ; in the Bannat ; Hungary ; and Thuringia ; in Scotland ; in Tuscany ; in South Australia ; in fine crystals at Cerro Blanco, Chili. A common mineral in America, some localities are : Stafford, Vt. ; Rossie, Ellenville, N. Y. ; Pheuixville, etc., Penn. The mines in North Carolina and eastern Tennessee afford large quantities. Occurs in Gal. , in different mines along a belt between Mariposa Co. and Del NorU Co., on west side of, and parallel to, the chief gold belt ; occurring massive in Calaveras Co.; in Mariposa Co., etc. In Canada, in Perth and near Sherbrooke; extensively mined at Bruce mines, on Lake Huron. Named from %aA/cos, brass, and pyrites, by Henckel, who observes in his Pyritology (1725) that chalcopyrite is a good distinctive name for the ore. CUBANITE is CuFe a S 4 , or CuFe 2 S 3 (Scheidhauer). Occurs massive at Barracanao, Cuba; Tunaberg, Sweden. BARKHARDTITE, from North Carolina. Composition uncertain, perhaps Cu 4 Fe 2 S 6 . It may be partly altered from chalcopyrite. STANNITE (Zinnkies, Germ.}. A sulphide containing 26 p. c. tin; also copper, iron, and zinc. Massive. Color steel-gray. Chiefly from Cornwall, also Zmnwald. UNNJEITE. Kobaltnickelkies, Germ. Isometric. Cleavage : cubic, imperfect* Twins : twinning-plane octa- hedral. Also massive, granular to compact. U.=:5'5. G.=4*8-5. Lustre metallic. Color pale steel-gray, tarnishing copper-red. Streak blackish-gray. Fracture uneven or subconchoidal. Comp, Co 3 S 4 (or 2CoS+CoS 2 )= Sulphur 42'0, cobalt 58-0=100; but having the cobalt replaced partly by nickel or copper, the proportions varying very much. The Miisen ore (siegenite) contains 30-40 p. c. of nickel. Pyr., etc. The variety from Miisen gives, in the closed tube, a sulphur sublimate ; in the open tube, sulphurous fumes, with a faint sublimate of arsenous oxide. B.B. on charcoal gives arsenical and sulphurous odors, and fuses to a magnetic globule. The roasted mineral gives with the fluxes reactions for nickel, cobalt, and iron. Soluble in nitric acid, with separa- tion of sulphur. Diff. Distinguished by its color, and isometric crystallization. Obs, In gneiss, at Bastnaes, Sweden ; at Miisen, near Siegen, in Prussia ; at Siegen (siegenite), in octahedrons ; at Mine la Motte, in Missouri, mostly massive, also crystalline , and at Mineral Hill, in Maryland. SMALTITE.* Speiskobalt, Germ. Isometric. Cleavage : octahedral, distinct ; cubic, in traces. Also mas- sive and in reticulated and other imitative shapes. H. 5-5-6. G.=6'4: to 7*2. Lustre metallic. Color tin-white, inclining, when massive, to steel-gray, sometimes iridescent, or grayish from tarnish. Streak grayish-black. Fracture granular and uneven. Brittle. Comp., Var. For typical kind (Co,Fe,Ni)As 2 =: (if Co, Fe, and Ni be present in equal parts) Arsenic 72 '1, cobalt 94, nickel 9 '5, iron 9 -0=1 00. It is probable that nickel is never wholly absent, although not detected in some of the earlier analyses ; and in some kinds it is the principal metal. The proportions of cobalt, nickel, and iron vary much. The following analyses will serve as examples of the different varieties : As Co Ni Fe Cu 1. Schneeberg 70'37 13'95 1'79 11-71 1'39 S 0'66, BiO-01=99'8S Hofmana 2. Allemont (chloanthite) 7 I'll 18 '71 6-82 S 2 '29 =98 "93 Raminelsberg. 8. Kiechelsdorf 6042 10 "80 25'87 0'80 S 2-11 = 100. 4. Schneeberg 74 '80 879 12 '86 7 "33 S 0-85 =99 '63 Karstedt. 246 DESCRIPTIVE MINERALOGY. Pyr., etc. In the close tube gives a sublimate of metallic arsenic ; in the open tube a white sublimate of arsenous oxide, and sometimes traces of sulphurous oxide. B.B. on char- coal gives an arsenical odor, and fuses to a globule, which, treated with successive portions of borax-glass, affords reactions for iron, cobalt, and nickel. Obs. Usually occurs in veins, accompanying ores of cobalt or nickel, and ores of silvei and copper ; also, in some instances, with niccolite and arsenopyrite ; often having a coating of annabergite. Occurs at Schneeberg, etc., in Saxony ; at Joachimsthal ; also at Wheal Sparnon in Corn- wall ; at Riechelsdorf in Hesse ; at Tunaberg in Sweden ; Allemont in Dauphine. Als& in crystals at Mine La Motte, Missouri. At Chatham, Conn. , the chloanthite (chathamite) occura in mica slate, associated generally with arsenopyrite and sometimes with niccolite. SPATHIOPYRITJS is closely allied to smaltite, with which it occurs at Bieber in Hessen. SKUTTERUDITE (Tesseralkies, (?mw.). CoAs 3 =Arsenic79-2, cobalt 20'8=100. Isometric. Skutterud, Norway. COBALTITE. Glance Cobalt. Kobaltglanz, Germ. Isometric ; pyritohedral. Commonly in pyritohedrons (f. 92, 95, etc., p. 23). Cleavage : cubic, perfect. Planes striated. Also massive, granular or compact. Ii. = 5-5. G.= 6-6-3. Lustre metallic. Color silver- white, inclined to red ; also steel-gray, with a violet tinge, or grayish-black when containing much iron. Streak grayish-black. Fracture uneven and lamellar. Brittle. Comp., Var. CoAsS (or CoS a +CoAs-.)= Sulphur 19 '3, arsenic 45 '2, cobalt 35'5=100. The cobalt is sometimes largely replaced by iron, and sparingly by copper. Pyr., etc. Unaltered in the closed tube. In the open tube, gives sulphurous fumes and a crystalline sublimate of arsenous oxide. B.B. on charcoal gives off sulphur and arsenic, and fuses to a magnetic globule ;' with borax a cobalt-blue color. Soluble in warm nitric acid, separating arsenous oxide and sulphur. Diflf. Distinguished by its reddish-white color ; also by its pyritohedral form. Ob 1 ?. Occurs at Tunaberg. Hokansbo, in Sweden ; also at Skutterud in Norway. Other localities are at Querbach in Silesia, Siegen in Westphalia, and Botallack mine, in Cornwall. The most productive mines are those of Vena in Sweden. This species and smaltite afford the greater part of the smalt of commerce. It is also employed in porcelain painting. GERSDORFFITE. Nickelarsenikkies, Arseniknickelglanz, Germ. Isometric ; pyritohedral. Cleavage : cubic, rather perfect. Also lamel- lar and granular massive. H.=5-5. G. 5.6-6-9. Lustre metallic. Color silver-white steel- gray, often tarnished gray or grayish-black. Streak grayish-black. Frac- ture uneven. Comp., Var. Normal, NiAsS (or NiS 2 +NiAs 2 )- Arsenic 45 '5, sulphur 19 '4, nickel 35 -1 = 100. The composition varies in atomic proportions rather widely. Pyr., etc. In the closed tube decrepitates, and gives a yellowish-brown sublimate of arsenic sulphide. Jn the open tube yields sulphurous fumes, and a white sublimate of arsen- ous oxide. B.B. on charcoal gives sulphurous and garlic odors and fuses to a globule, which, with borax-glass, gives at first an iron reaction, and, by treatment with fresh portions of tho flux, cobalt and nickel are successively oxidized. Decomposed by nitric acid, forming a green solution, with separation of sulphur and arsen- ous oxide. Obs. Occurs at Loos in Sweden ; in the Harz ; at Schladming in Styria; Kamsdorf in Lower Thuringia ; Haueisen, Voigbland ; near Ems. Also found as an incrustation at Phenixville, Pa. SULPHIDES, TELLTTKIDE8, SELENIDES, ETC. 247 ULLMANNITE. NiSbS (NiS 2 +NiSb 2 )= Antimony 57'2, sulphur 15 '1, nickel 27 '7=100. Generally contains also some arsenic. Color steel-gray. Siegen, Harzgerode, etc. COKYNITE. M(As,Sb)S, but the arsenic (38 p. c. ) in excess of the antimony. Olsa, Corin- thia. WOLFACIIITE (Petersen), from Wolfach, Baden, is similar in composition, bub is orthorhombic in form. LAURITE. An osmium-ruthenium sulphide. Analysis (Wohler) Sulphur 31 '79 [Osmium 3-03], Ruthenium 05. 18=100. Occurs in minute octahedrons from the platinum - washfc iga of Borneo ; as also those in Oregon. Marcasite Group. Orthorhombic. MAROASITE. White Iron Pyrites. Strahlkies, etc., Germ. Orthorhombic. /A 1= 106 5', A 14 = 122 26', Miller ; I : I : & = 1-5737 : 1-3287 : 1. A 1 = 116 55' ; O A l-i = 130 10'. Cleavage: /rather perfect; \4 in traces. Twins : t winning-plane 7, sometimes consisting of five individuals (see f. 308, p. 98) ; also l-l. Also globular, reniform, and other imitative shapes structure straight columnar ; often massive, columnar, or granular. II. 6-65. G.= 4-678-4- 847. Lustre metallic. Color pale bronze-yel- low, sometimes inclined to green or gray. Streak grayish- or brownish- black. Fracture uneven. Brittle. Comp,, Var. FeS 2 , like py rite = Sulphur 53 "3, iron 46-7=100. The varieties that have been recognized depend mainly on state of crystallization ; as the Radiated (Strahlkies) : Radiated ; also the simple crystals. Cockscomb (Kammkiex} : Aggre- gations of flattened crystals into crest-like forms. Spear (Speerkies) : Twin crystals, with reentering angles a little like the head of a spear in form. Capillary (Ilaarkies) : In capil- lary crystallizations, etc. Fyr. Like pyribe. Very liable to decomposition ; more so than pyrite. Diff. Distinguished from pyrite by its paler color, especially marked on a fresh surface ; by its tendency to tarnish ; by its inferior specific gravity. ' Qbs. Occurs near Carlsbad in Bohemia ; at Joachimsthal, and in several parts of Saxony ; in Derbyshire ; near Alston Moor in Cumberland ; near Tavistock in Devonshire, and iu Cornwall. At Warwick, N. Y. Massive fibrous varieties abound throughout the mica slate of New England particularly at Cummington, Mass. Occurs at Lane's mire, in Monroe, Conn. ; in Trumbull ; at East Haddam ; at Haverhill, N. H. ; Galena, 111., in stalactites. In Canada in Marcasite is employed in the manufacture of sulphur, sulphuric acid, and iron sulphate, though less frequently than pyrite. ARSENOPYRITB, or MISPICKEL. Arsenical Pyrites. Arsenikkies, Germ. Orthorhombic. 1 A 1= 111 53', O A 14 = 119 37' ; c : I : & = 1'7588 : 1-4793:1. 6>Al = 115 12', O A l- = 130 4'. Cleavage: 7 rather distinct ; O, faint traces. Twins : twinning-plane /, and 1 4. Also colum- nar, straight and divergent ; granular, or compact. H.= 5-5-6. G. 6-6-6-4; 6'269, Franconia, Kenngott. Lustre metallic. 248 DESCRIPTIVE MINERALOGY. Color silver- white, inclining to steel-gray. Streak dark grayish-black. Frac ture uneven. Brittle. 443 444 445 Franconia, N. H. Franconia, N. H., and Kent, N. Y. Danaite. Comp., Var. FeAsS =FeS 3 +FeAs 2 = Arsenic 46 K), sulphur 19-6, iron 34 '4=100. Part o the iron sometimes replaced by cobalt ; a little nickel, bismuth, or silver are also occasionally present. The cobaltic variety, called danaite (after J. Freeman Dana), contains 4-10 p. c. of cobalt. Pyr., etc. In the closed tube at first gives a red sublimate of arsenic sulphide, then a black lustrous sublimate of metallic arsenic. In the open tube gives sulphurous fumes and a white sublimate of arsenous oxide. B.B. on charcoal gives the odor of arsenic. The varieties containing- cobalt give a blue color with borax-glass when fused in O.F. with successive por- tions of flux until all the iron is oxidized. Gives fire with steel, emitting an alliaceous odor. Decomposed by nitric acid with separation of arsenous oxide and sulphur. Diff. Distinguished by its form from smaltite. Leucopyrite (lollingite) do not give decided sulphur reactions. Obs. Found principally in crystalline rocks, and its usual mineral associates are ores of silver, lead, and tin ; pyrite, chalcopyrite, and spalerite. Occurs also in serpentine. Abundant at Freiberg ; at Reichenstein in Silesia ; at Schladming ; Andreasberg ; Joachims- thai ; at Tunaberg in Sweden ; at Skutterud in Norway ; in Cornwall ; in Devonshire at the Tarnar mines. In New Hampshire, in gneiss, at Franconia (danaite) ; also at Jackson and at Haverhill. In Maine, at Blue Hill, Corinna, etc. In Vermont, at Brookfield, Waterbury, and Stockbridge. In Mass., at Worcester and Sterling. In Conn., at Monroe, at Mine Hill, Roxbury. In New Jersey, at Franklin. In N.Tork, massive, in Lewis, Essex Co., near Edenville, and else- where in Orange Co. ; in Carmel ; in Kent, Putnam Co. In California, Nevada Co., Grass valley. In S. America, in Bolivia ; also, niccoliferous var., between La Pas and Yungas in Bolivia (anaL by Kroeber). LOLLINGITE is FeAs 2 (^Arsenic 72'8, iron 27 -2), and LEUCOPYBITE is Fe 2 As 3 (^Arsenic 66'S, iron 33 -2). They are both like arsenopyrite in form. Found, the former at Lolling ; Schladming ; Satersberg, near Fossum, Norway ; the latter at Reichenstein ; Geyer (geyerite) near Hiittenberg, Carinthia. GLAUCODOT (Co,Fe)S 2 -f-(Co,Fe)As 2 , with Co : Fe=2 : 1 = Sulphur 19 '4, arsenic 45 -5, cobalt 23 '8, iron 11-3=100. Form like arsenopyrite. Huasco, Chili; Hakansbo, Sweden. ALLOCLABITE R 4 (As,Bi) 7 S6, with R=Bi,Co,Ni,Fe,Zn. Orawicza, Hungary. SYLVANITB. Graphic Tellurium. Schrifterz, Schrift-Tellur, Germ. Moiioclinic. C = 55 21 J', /A 1= 94 26', O A 14 = 121 21' ; c : b : d = 1-7732 : 0-889 : 1, Kokscharof. Cleavage : *4 distinct. Also massive ; imperfectly columnar to granular. H.=l'5-2. Gr. 7-99-S-33. Lustre metallic. Streak and color pure steel- gray to silver-white, and sometimes nearty brass-yellow. Fracture uneven, Comp., Var. (Ag,Au)Te 2 = (if Ag : Au=l : 1) Tellurium 55 -8, gold 28-5, silver 15 ?= 100. Antimony sometimes replaces part of the tellurium, and lead part of the other metals. 8ULPHABSENITES, SULPHANT1MONITES, ETC. 249 Pyr., etc. In the open tube gives a white sublimate which near the assay is gray ; when treated with the blowpipe flame the sublimate fuses to clear transparent drops. B.B. on charcoal fuses to a dark gray globule, covering the coal with a white coating, which treated in R.F. disappears, giving a bluish-green color to the flame; after long blowing a yellow, malleable metallic globule is obtained. Most varieties give a faint coating of the oxides oi lead and antimony on charcoal. Obs. Occurs at Offenbanya and Nagyag in Transylvania. In California, Calaveras Co., at the Melones and Stanislaus mines ; Bed Cloud mine, Colorado. Named from Transylvania, the country in which it occurs, and in allusion to syhaiiium, one of the names at first proposed for the metal tellurium. Called graphic because of a resem- blance in the arrangement of the crystals to writing characters. Schrauf has stated that, according to his measurements, sylvanite is orthorhombic. CALAVERITE (Genth.) has the composition AuTe 4 = Tellurium 55'5, gold 44-5=100. M-aa- Bive. Color bronze-yellow. Stanislaus mine, Cal. ; Red Cloud mine, Colorado. NAGYAGITE.* Blattererz, Blattertellur, Germ. Tetragonal. A l-i = 127 37' ; o = 1-298. A 1 = 118 37'. Cleav- age: basal. Also granularly massive, particles of various sizes ; generally foliated. H.=1-1'5. G.= 6-85-7-2. Lustre metallic, splen- dent. Streak and color blackish lead-gray. Opaque. Sectile. Flexible in thin laminae. Comp. Uncertain, perhaps B(S,Te) 9 , withR=Pb,Au (Ramm.). Analysis, Schonlein, Te 30-52, S 8-07, Pb 50'78, Au 9'11, Ag 0'53, Cu 0-99=100. Pyr., etc. In the open tube gives, near the assay, a grayish sublimate of antimonate and tellurate, with perhaps some sulphate of lead ; farther up the tube the sublimate consists of antirnonous oxide, which volatilizes when treated with the flame, and tellurous oxide, which at a high temperature fuses into colorless drops. B.B. on charcoal forms two coatings : one white and volatile, consisting of a mixture of antimonite, tellurite, and sulphate of lead ; and the other yellow, less volatile, of oxide of lead quite near the assay. If the mineral is treated for some time in 0. F. a malleable globule of gold remains ; this cupelled with a little assay lead assumes a pure gold color. Decomposed by nitro-hydrochloric acid. Obs. At Nagyag and Offenbanya in Transylvania, in foliated masses and crystalline plates. COVELLITE (Kupferindig, Germ.). Composition CuS= Sulphur 33 -5, copper 66'5=100. Hexagonal Commonly massive. Color indigo-blue. Mansfeld, etc. ; Vesuvius, on lava ; MELONITE (Genth.). A nickel telluride, formula probably Ni 2 Te 3 tellurium 76 '5, nickel 23-5=100. Hexagonal. Cleavage basal eminent. Color reddish- white. Streak dark-gray. Occurs mixed with other tellurium minerals at the Stanislaus mine, Cal. 3. TERNAKY COMPOUNDS. SULPHAKSENITES, SULPHANTIMONITES, SULPHOBISMUTHITES.* (a) GROUP I. Formula R(As,Sb) 2 S 4 =ES + (As,Sb) 2 S 8 . MIARGYRITB. Monoclinic. O= 48 14'; /A 7= 106 31', O A 14 = 136 8' ; c : I : d = 1-2883 : 0-9991 : 1, iSTaumann. Crystals thick tabular, or stout, or short prismatic, pyramidal. Lateral planes deeply striated.. Cleavage : f-t-, 1-a imperfect. * The species of this group contain as bases chiefly copper, lead, and silver. They can bo most readily distinguished by their behavior before the blowpipe. Attention may be calle to the group of lead sulphantimonites, zinkentte, plagionite, (jamesonite) boulangente mene- 'lUnite, geocronite, for which the prognostics are nearly similar, and which are mosl ***tinguished by their specific gravity. 250 DESCRIPTIVE MINERALOGY. H.=: 2-2*5. G.=5*2-5*4r. Lustre submetallic-adamantine. Color iron black. Streak dark cherry-red. Opaque, except in thin splinters, which, by transmitted light, are deep blood-red. Fracture subconchoidal. Comp. AgSbS 2 (orAg 2 S + Sb 2 S 3 )=:Sulphur 21 '8, antimony 41 -5, silver 36 '7=100. Pyr., etc. In the closed tube decrepitates, fuses easily, and gives a sublimate of antimony sulphide ; in the open tube sulphurous and antimonoue fumes, the latter as a white sublimate*. B.B. on charcoal fuses quietly, with emission of sulphur and antimony fumes, to a gray bead, which after continued treatment in O.F. leaves a bright globule of silver. If the silver globule be treated with phosphorus salt in O.F., the green glass thus obtained shows traces of coppei when fused with tin in B. F. Decomposed by nitric acid, with separation of sulphur and antimonous oxide. Obs. At Braiinsdorf , near Freiberg in Saxony ; Felsobanya (kenngottite) ; Przibram in Bohemia ; Clausthal (hy par gy rite) ; Guadalajara in Spain ; at Parenos, and the mine Sta. M. de Catorce, near Potosi ; also at Molinares, Mexico. SARTORITB. SCLEKOCLASE. Orthorhombic. 7 A 1= 123 21', O A 14 = 131 3' ; c : I : a = 1-1483 : 1'8553 : 1. Crystals slender. Cleavage : 447 quite distinct. H.=3. G.=5-393. Lustre metallic. Color dark lead-gray. Streak reddish- brown. Opaque. Brittle. Comp. PbAs. 2 S 4 (PbS+AR 2 S 3 )=Sulphur 26 '4, arsenic 30 '9, lead 42-7=100. Fyr,, etc. Nearly the same as for dufrenoy- site (q. v.), but differing in strong decrepitation. Obs. From the Binnen valley with dufrenoy- site and binnite. As the name Scleroclase is inapplicable, and the mineral was first an- nounced by Sartorius v. Waltershausen, the species may be appropriately called Sartorite. It is the binnite of Heusser. ZINKENITE. Orthorhombic. If\ 1= 120 39', Rose. Usual in twins, as hexagonal prisms, with a low hexagonal pyramid at summit. Lateral faces longitudi- nally striated. Sometimes columnar, fibrous, or massive. Cleavage not distinct. H.= 3-3-5. G. = 5-30-5-35. Lustre metallic. Color and streak steel- gray. Opaque. Fracture slightly uneven. Comp. PbSb 2 S 4 (or PbS + SboS 3 ) = Sulphur 22'1, antimony 42'2, lead 35 '7=100. Pyr., etc. Decrepitates and fuses very easily ; in the closed tube gives a faint sublimate of sulphur and antimonous sulphide ; in the open tube sulphurous fumes and a white subli- mate of oxide of antimony. B. B. on charcoal is almost entirely volatilized, giving a coating which on the outer edge is white, and near the assay dark-yellow ; with soda in R. F. yields globules of lead. Soluble in hot hydrochloric acid with evolution of sulphuretted hydrogen and separation of lead chloride on cooling. Resembles stibnite and bournonite, but may be distinguished by its superior hardness and specific gravity. Obs. Occurs at Wolfsberg in the Harz. CHALCOSTIBITE (Kupferantimonglanz, Germ.). Composition CuSbS 2 (or Cu 2 S f SboS s ) Sulphur 25 '7, antimony 48 '9, copper 25 -4 Color lead -gray to iron-gray. Wolfsberg in the Harz. EMPLECTITE (Kupferwismuthglanz, Germ.). Composition CuBiS 2 (or Cu,S+Bi 2 S 3 )=Sul- phur 19*1, bismuth 62*0, copper 18'9=100. Color grayish to tin-white. Schwarzenberg, S-txony; Copiapo, Chili. SULPHARSENITES, SULPHANTIMONITES, ETC. 251 BERTHIERITE. Composition approximately FeSb 2 S 4 (orFeS4-Sb 2 S 3 )=Sulr;hur30-0, anti- mony 57 '0, iron 13-0=100. Color dark steel-gray. Auvergne ; Braunsdorf, Saxony; Corn- wall, etc. ; San Antonio, Cal. (b) SUB-GBOUP. Formula K 3 ( As,Sb,Bi) 4 S 9 = 3RS + 2(As,Sb,Bi) 2 S 3 . PLAGIONITE. Composition (Rose) Pb 4 Sb 6 S 13 (or 4PbS + 3Sb 2 S 3 )= Sulphur 21;1, antimony 37'0, lead 41 '9. Monoclinic. Gr. =5 '4. Found at Wolfsberg in the Harz. JORDANITE (v. Rath). Composition Pb 3 As 4 S9 (or 3PbS+2As 2 S 3 ) = Sulphur 23-8, arsenic 24 - 8, lead 51 '4. Orthorhombic. Resembles sartorite, but distinguished by its black streak, its six-sided twins, and by not decrepitating B.B. Binnenthal, Switzerland. BINNITE. Composition probably Cu 6 As 4 S 9 (or 3Cu 2 S+2As 2 S 3 ) = Sulphur 29*7, arsenic 31 '0, copper 39 '3 = 100. Isometric. Streak cherry -red. Binnenthal in dolomite (dufrenoysite of v. Walter shausen). KLAPJIOTHOLITE (Petersen). Composition Cu 6 Bi 4 Sb 9 (or 3Cu 2 S-f-2Bi 2 S 3 ). Orthorhombic. Cleavage i-l distinct. Color steel-gray. G.=4'6. Wittichen, Baden. ScmitMEiUTE (Gentfi). Composition R 3 Bi 4 S 9 (or 3RS + 2Bi 2 S 3 ), with R=Ag 2 : Pb 2 : 1. This requires sulphur 1(>'4, bismuth 47'3, silver 24 '5, lead 11 '8=100. Massive, disseminated in quartz. Color lead-gray. Red Cloud mine, Colorado. (G) GKOUP II. Formula JAMESONITE. Federerz, Germ. Orthorhombic. /A 1= 101 20' and 78 40'. Cleavage basal, highly perfect; /and i-l less perfect. Usually in acicnlar crystals. Also fibrous massive, parallel or divergent ; also in capillary forms ; also amorphous massive. H.=:2-3. G.=5'5-5-8. Color steel-gray to dark lead-gray. Streak gray. Comp. Pb 2 Sb 2 S 5 (or 2PbS + Sb 2 S 3 ) ; more strictly 2PbS=2 (or Pb,Fe)S. If Fe : Pb=l : 4, Sulphur 21-1, antimony 32 '2, lead 43 '7, iron 3'0=100. Small quantities of zinc, bis- muth, silver, and copper are also sometimes present. Fyr. Same as for zinkenite. Diff. Distinguished from other related species by its perfect basal cleavage. Obs. Jamesonite occurs principally in Cornwall, in Siberia, Hungary, at Valentia, d' Alcan- tara in Spain, and Brazil. The feather ore occurs at Wolfsberg in the Eastern Harz ; also at Andreasberg and Glaus- thai ; at Freiberg and Schemnitz ; at Pf affenberg and Meiseberg ; in Tuscany, near Bottino ; at Chonta in Peru. DUFRBNOYSITB. Orthorhombic. 7 A 7= 93 39', A 14 = 121 30', c : I : & = 1-6318 : 1*0658 : 1. Usual in thick rectan- gular tables. Cleavage: perfect. Also massive. H.=:3. G.=5-549-5-569. Lustre metallic. Color blackish lead-gray. Streak reddish-brown. Opaque. Brit- tle. Comp. Pb 2 As 2 S 5 (or 2PbS+2As 3 S,)=Sul- phur 22-10, arsenic 20'72, lead 57-18=100. Fyr., etc. Easily fuses and gives a subli- mate of sulphur and arsenous sulphide ; in the open tube a smell of sulphur only, with a sublimate of sulphur in upper part ot tube, and 252 DESCRIPTIVE MINERALOGY. of arsenous oxide below. On charcoal decrepitates, melts, yields fumes of arsenic and 8 globule of lead, which on cupellation yields silver. Obs From the Binnenthal in the Alps, in crystalline dolomite, along with sartorite, Jordan- ite, binnite, etc. Damour, who first studied the arsenic-sulphides of the Binnenthal, analyzed the massive ore and named it dufrenoysite. He inferred that the crystallization was isometric from some associated crystals, and so published it. This led von Waltershausen and Heusser to call the isometric mineral dufrenoysite, and the latter to na.ne the orthorhombic species binnite. "Von Waltershausen, after studying the prismatic mineral, made out of the species ameuomeUtn and sclerodase, yet partly on hypothetical grounds. Recently it has been found that three ortho- rhombic minerals exist at the locality, as announced by vom Rath, who identifies one, by speci- fic gravity and composition, with Dam our' s dufrenoysite ; another he makes sclerodase of von Waltershausen (sartorite, p. 250) ; and the other he names jorda-nite (p. 251). The isometric mineral was called binnite by DesCloizeaux. FREIESLEBENITE. Schilfglaserz, Germ. Monoclinic. O = 87 46', /A 1= 119 12', A 14 = 137 10' (B. & M.) ; cil:d = 1-5802 : 1-7032 : 1. A \4 = 123 55'. 449 Prisms longitudinally striated. Cleavage : / perfect. H. = 2-2-5. G. = 6-6-4. Lustre metallic. Color and streak light steel-gray, inclining to silver-white, also blackish lead-gray. Yields easily to the knife, and is rather brittle. Fracture subconchoidal uneven. Comp Pb 2 AgsSb 3 S e , Ramm. (or 7RS+3Sb 2 S 3 , with7RS=4PbS + 3 Ag 2 S) = Sulphur 18'8, antimony 20'9, lead 30'5, silver 23 -8 =100. Pyr In the open tube gives sulphurous and antimonial fumes, the latter condensing as a white sublimate. B. B. on charcoal fuses easily, giving a coating on the outer edge white, from antimonous oxide, and near the assay yellow, from oxide of lead ; continued blowing leaves a globule of silver. Obs. Occurs at Freiberg in Saxony and Kapnikin Transylvania; at Ratieborzitz ; atPrzibram ; at Felsbbanya; at Hiendelencina in Spain. According to v. Zepharovich, the mineral from Przibram and Braunsdorf, and part of that from Freiberg, while identical in composition with freies- lebenite, has an ortharhombic form. It is called by him DIAPHORITE. BRONGNIARDITE. Composition Ag 2 PbSb 2 S 5 (or PbS-f-Ag 2 S+SbgS 3 )r=Sulphur 194, anti- mony 29-5, silver 2(M, lead 25'0=100. Isometric ; in octahedrons, also massive. Color gray- ish-black. Mexico. COSALITE ( Genth). Composition Pb 2 Bi 2 S 5 (or 2PbS+Bi 2 S 3 )= Sulphur 16 -1, bismuth 42'2, lead 41-7=100. Color lead-gray. Soft and brittle. Cosala, Sinaloa, Mexico. Identical (Frenzel) with Hermann's retebanyite. PYROSTILPNITE (Feuerblende, Germ.}. In delicate crystals; color hyacinth-red. Con- tains 62 - 3 p. c. silver, also sulphur and antimony. Freiberg ; Andreasberg ; Przibram. RITTINGERITE. In minute tabular crystals. Color black Streak orange-yellow. Con- tains sulphur, antimony, and silver. JoachimsthaL (d) GBOUP IIL Formula :Rj(As,Sb) 2 S 6 =: 3ES + (As,Sb) 2 S 3 . PYRARGYRTTE. Ruby Silver. Dark Red Silver Ore. Dunkles RothgiUtigerz, Germ. Rhombohedral. Opposite extremities of crystals often unlike. R A R = 108 42' (B. & M.) ; Of^B = 137 42' ; c = 0'788. A I 3 = 112 33', 6>A1 7 = 100 U', Rl\\ = \ 21'. Cleavage: R rather imperfect. STJLPHARSENITES, SULPHANTIMONITES, ETC. 253 Twins: composition-face^; or basal plane, as in f. 290, p. 95; also It and /. Also massive, structure 450 451 granular, sometimes impalpable. ' Ii.=2-2-5. G.=5-7-5-9. Lustre metallic-adamantine. Color black, sometimes approaching cochineal-red. Streak cochineal-red. Translucent opaque. Fracture conchoidal. Comp. Ag 3 SbS 3 (or 3Ag 2 S+Sb a S 3 )=Sul- phur 17-7, antiiuony 22 '5, silver 59-8 = 100. Pyr., etc. In the closed tube fuses and gives a reddish sublimate of antimonous sulphide ; in the open tube sulphurous fumes and a white sublimate of antimonous oxide. B.B. on charcoal fuses with spirting to a globule, gives off antimonous sulphide, coats the coal white, and the assay is converted into silver sulphide, which, treated in O.F., or with soda in B.F., gives a globule of fine silver. In case arsenic is present it may be detected by fusing the pulverized mineral with soda on charcoal in R.F. Decomposed by nitric acid with separation of sulphur and antimonous oxide. Obs. Occurs principally with calcite, native arsenic and galenite, at Andreasberg ; also in Saxony, Hungary, Norway, at G-audalcanal in Spain, and in Cornwall. In Mexico abundant. In Chili; in Nevada, at Wash oe in DaneyMine; abundant about Austin, Reese river; at Poor Man lode, Idaho. PROUSTITE. Light Red Silver Ore. Lichtes Rothgultigerz, Germ. 48', 9' c = 0-78506. Khombohedral. Also granular massive. H. 2-2-5. G.= 5 -422-5-56. Lustre adamantine. Color cochineal-red. Streak cochineal-red, sometimes inclined to aurora-red. Subtransparent- subtranslncent. Fracture conchoidal uneven. Comp.-Ag 3 AsS 3 (or 3Ag 2 S+As 2 S 3 ) = Sulphur 19-4, arsenic 15'1, silver 65 "5=100. Pyr., etc. In the closed tube fuses easily, and gives a faint sublimate of arsenous sulphide ; in the open tube sulphurous fumes and a white crystalline sublimate of arsenous oxide. B.B. on charcoal fuses and emits odors of sulphur and arsenic; by prolonged heating in O.F., or with seda in R.F., gives a globule of pure silver. Some varieties contain antimony. Decomposed by nitric acid, with separation of sulphur and arsenous oxide. Obs. Occurs at Freiberg and elsewhere in Saxony ; at Joachimsthal ; Wolfach m Baden ; Chalanches in Dauphin^ ; Guadalcanal in Spain ; in Mexico : Peru ; Chili, at Chanarcillo, in magnificent crystals. In Nevada, in the Daney mine, and in Comstock lode, but rare ; in veins about Austin, Lander Co. ; in microscopic crystals in Cabarrus Co., N. C., at the McMakin mine : in Idaho, at the Poor Man lode. BOURNONITE. Radelerz, Germ.(= Wheel Ore). Orthorhombic. I^ 1= 93 40', O A 14 = 136 IT (Miller) ; I I : & == 0-95618 : 1-0662 : 1. O A 1-5 = 133 26', O A 1 = 127 20', A 1-t = 13b 6'. Cleavao-e: i>l imperfect ; i4 and O less distinct. Twins: twinnmg- plane face 1; crystals often cruciform (f. 453), crossing at angles of 93 40' and 86 20' ; hence, also, cog-wheel shaped. Also massive ; granular, compact. 254 DESCRIPTIVE MINERALOGY. H.= 2-5-3. G.= 5-7-5-9. Lustre metallic. Color and streak steel-gray, inclining to blackish lead-gray or iron-black. Opaque. Fracture con- choidal or uneven. Brittle. 452 Oomp., Var. CuPbSbS 3 Ramm. (or 3RS+Sb 2 S 3 , with3RS=2PbS+Cu 2 S)=Suhphur 19 6, antimony 25 0, lead 42-4, copper 13-0=100. Pyr., etc. In the closed tube decrepitates, and gives a dark-red sublimate. In the open tube gives sulphurous oxide, and a white sublimate of antimonous oxide. B.B. on charcoal fuses easily, and at first coats the aoal white, from antimonous oxide ; continued blowing gives a yellow coating of lead oxide; the residue, treated with soda in R.F., gives a globule of copper. Decomposed by nitric acid, affording a blue solution, and leaving a residue of sulphur, and a white powder containing antim >ny and lead. Obs. Occurs in the Harz ; at Kapnik in Transylvania; at Servoz in Piedmont; Brauns- dorf and Gersdorf in Saxony, Olsa in Corinthia, etc. ; in Cornwall ; in Mexico ; at Huasco- Alto in Chili ; at Machacamarca in Bolivia ; in Peru. STYLOTYPITB. An iron-silver-copper bournonite ; Copiapo, Chili. BOULANGERITE. In plumose masses, exhibiting in the fracture a crystalline structure ; also granular and compact. H.= 2-5-3. G. 5.75-6-0. Lustre metallic. Color bluish lead-gray; often covered with yellow spots from oxidation. Comp. Pb 3 Sb 2 S 6 (or 3PbS+Sb 2 S 3 )=Sulphur 18'2, antimony 23'1, lead 587=100. Pyr. Same as for zinkenite. Obs Quite abundant at Molieres, department of Gard, in France ; also found at Nasaf jeld in Lapland ; at Nertschinsk : Ober-Lahr in Sayn-Altenkirchen ; Wolfsberg in the Harz ; near Bottino in Tuscany. EPIBOULANGERITE. Probably a decomposition product of boulangerite (Websky) ; it con- tains more sulphur and less antimony. Altenberg, Silesia. WITTICHENITE. Composition Cu 3 BiS 3 (or 3Cu Q S + Bi 2 Ss)= Sulphur 19'4, bismuth 43.1, copper 38-5 = 100. Color steel-gray. Wittichen, Baden. KOBELLITE. Pb 3 BiSbS 6 (or 3PbS + (Bi,Sb) 2 S 3 ) Ramm. = Sulphur 16'8, antimony 10'7, bis- muth 18 2, lead 54-3 = 100. Color lead-gray to steel-gray. Hvena, Sweden. AIKINITE (NadUerz, Germ.). CuPbBiS 3 (or Cu 2 S+2PbS+Bi 2 S 3 )=Sulphur 167, bismuth 86-2, lead 30-0, cooper 111 = 100. In acicular crystals, also massive. Color blackish lead- gray. Beresof, Urals ; Gold Hill, North Carolina. SULPHAKSENITES, SULPHANTIMONITES, ETC. 255 (e) GEOUP IT. Formula E 4 (As,Sb,Bi) 2 S 7 =4rRS + (As,Sb,Bi) 2 S 3 , TETRAHEDRITE.* Gray Copper Ore. Fahlerz; Antimon- and Quecksilberfalilerz, Germ Isometric ; tetrahedral. Twins : twinning-plane octahedral, producing, when the composition is repeated, the form in f. 456. Also massive ; gran- ular, coarse, or fine ; compact or crypto-crystalline. 454 456 Color between lisrht flint- color ; sometimes H.=3-4-5. G.=4-5-5-56. Lustre metallic. gray and iron-black. Streak generally same as the inclined to brown and cherry-red. Opaque ; sometimes subtranslucent in very thin splinters, transmitted color cherry-red. Fracture subconchoidal uneven. Rather brittle. Comp., Var.-Cu 8 Sb 2 S 7 (or 4Cu 2 S+ Sb 2 S 3 ), with part of the copper (C^) often replaced by iron (Fe) zinc (Zn), silver (Ag a ), or quicksilver (Hg), and rarely cobalt (Co and part of the antimony by arsenic, and rarely bismuth. Katio Ag 2 +Cu 2 : Zn+Fe generally =2.1. . are^thus: ^ arsenio-antimonial series; C. A bismuthic arsenio-anti. mortal; besides an arsenical, in which arsenic replaces all the antimony, and which is made into a distinct species named tennantite. Var 1 Ordinary Containing little or no silver. Color steel-gray to dark-gray. 2. Argentiferous; Freibergite. Light steel-gray, sometimes iron-black. 3. Mercuriferous ; Schwatzite. Color gray to iron-black. The following analyses will serve as examples of these varieties : Ag 0'60 Ni Col-64=98 '59 Eammelsberg. Zn 3 -50 3-89 10.48 Pb 0'78=:100-00 0-69 - Hg 17-27, Pb 0'21 Bi 0'81=100 v. Rath. S Sb As Cu Fe ID Miisen 25 '46 19 -15 4'93 39 -88 3 "43 (2) Meiseberg 24 '80 25 "56 30 '47 3 "52 (3) Kotterbach 22 "53 19 "34 2 -94 35 '34 0'S7 Pyr., etc. Differ in the different varieties. In the closed .. red sublimate of antimonous sulphide ; when containing mercury, appears at a low red heat ; and if much arsenic, a sublimate of arsenous In the open tube fuses, gives sulphurous fumes and a white sublimate of - . arsenic is present a crystalline volatile sublimate condenses with the antimo ny it the ore contains mercury it condenses in the tube in minute metallic globules. B.B. 01 fuses gives a coating of antimonous oxide and sometimes arsenous acid oxide; the arsenic may be detected by the odor when the coating is zinc oxide assumes a green color when heated with cobalt solution gives with the fluxes reactions for iron and copper; with soda yields copper To determine the presence of a trace of arsenic by th< fc f e gives wiiiu. ijii UUACS icdvu^iio iv... rr f j . - ~A n - if io Vipsfr t,n fuse copper. To determine the presence of a trace of arsenic by the ^*^J; * ' ^ mineral on charcoal with soda. The presence of mercury is best ascertained by ti 256 DESCRIPTIVE MINEKJLLOGY. pulverized ore in a closed tube with about three times its weight of dry soda, the metal subliming and condensing in minute globules. The silver is determined by cupellation. Decomposed by nitric acid, with separation of sulphur, and antimonous and arsenous oxides, Obs. The Cornish mines, near St. Aust. ; at Andreasberg and Clausthal in the Harz ; Kremnitz in Hungary ; Freiberg in Saxony ; Przibram in Bohemia ; Kahl in Spessart ; Kap- nik in Transylvania ; Dillenburg in Nassau ; and other localities. The ore containing mer- cury occurs in Schmolnitz, Hungary ; at Schwatz in the Tyrol ; and in the valleys of Angina and Costello in Tuscany. Found in Mexico, at Durango, etc. ; at various mines in Chili ; in Bolivi* ; at the Kellogg mines, Arkansas ; at Newburyport, Mass. In California in Mariposa Co. ; in Shasta Co. In Nevada, abundant at the Sheba and De Soto mines, Humboldt Co. ; near Austin in Lander Co. ; in Arizona at the Heintzelman mine, containing ! p. c. of silver ; at the Sana Rita mine. EJONITE (Brauns). A bismuth tetrahedrite from Cremenz. Einfischthal, Switzerland. MALINOWSKITE. A tetrahedrite containing 9-13 p. c. lead, and 10-13 p. c. silver. District of Eocuay, Peru. (5th Append. Min. Chili.) TENNANTITE.* Graukupfererz, Germ. Isometric ; holohedral, Phillips. Cleavage : dodecahedral imperfect. Twins as in tetrahedrite. Massive forms unknown. H.:=3-5-4. G.= 4-37-4-53. Lustre metallic. Color blackish lead-gray to iron-black. Streak dark reddish-gray. Fracture uneven. Comp. Cu*As 2 S 7 (or 4Cn 2 S-4-A8 2 S 3 ), with Cu 2 replaced in part by Fe, Ag 2 , etc., as in tetra- hedrite, with which it agrees in crystalline form. Fyr. In the closed tube gives a sublimate of arsenous sulphide. In the open tube givea sulphurous fumes, and a sublimate of arsenous oxide. B.B. on charcoal fuses with intumes- cence and emission of arsenic and sulphur fumes to a dark-gray magnetic globule. The roasted mineral gives reactions for copper and iron with the fluxes; with soda on charcoal gives metallic copper with iron. Obs. Found in the Cornish mines. Also at Skutterud in Norway, and in Algeria. JULIANITE (Websky) is near tennantite. G.=5-12. Budelstadt, Silesia. MENEGIIINITE has the composition Pb 4 Sb2S 1 (4PbS4-Sb 2 S3)= Sulphur 17 '3, antimony 16*8, iead 63 '9 =100. Kesembles boulangerite, Bottino, Tuscany ; Schwarzenberg, Saxony. (/) GROUP Y. Formula E 8 (As,Sb) 8 S 8 =5ES + (AB,Sb) 1 S 8 . STEPHANITE. Sprodglaserz, Germ. Orthorhombic. 1 A 1 = 115 39', O A I-l = 132 32f ' ; c : I : & = 1-0897 : 1-5844:1. O Al = 127 51', 0Al-S = 145 34. Cleav- age: 2- and i-l imperfect. Twins: twinning-plane I ; forms like those of aragonite frequent. Also massive, compact, and disseminated. H.= 2-2-5. G.=6-269, Przibram. Lustre metallic. Color and streak iron-black. Fracture uneven. Comp. Ag 5 SbS 4 (or 5 Ag 2 S+Sb 2 S,)=: Sulphur 16 '2, antimony 15'3, silver 68 '5 =100. Pyr. In the closed tube decrepitates, fuses, and after long heating gives a faint sublimate of antimonous sulphide. In the open tube fuses, giving off antimonial fumes and sulphurous oxide. B.B. on charcoal fuses with projection of small particles, coats the coal with antimonous oxide, which after long blowing is colored red from oxidized silver, and a globule of metallic silver is obtained. Soluble in dilute heated nitric acid, sulphur and oxide of antimony being deposited. BTJLPHAR8ENITES, 8TJLPHANTIMONITES, ETC. 257 Obs. At Freiberg and elsewhere in Saxony ; at Przibram in Bohemia ; in Hungary ; at Indreasberg ; at Zacatecas in Mexico ; and in Peru. In Nevada, an abundant silver ore in ihe Corastock lode ; at Ophir and Mexican mines in fine crystals ; in the Reese river and EEumboldt and other regions. In Idaho, at the silver mines. GEOCRONITE. Composition Pb 3 Sb.S 6 (or 5PbS-t-Sb 2 S 3 )= Sulphur 16*7, antimony 15'9, lead 57 '4 100 (also contains a little arsenic). Color light lead-gray. Sala, Sweden; Merido, Spain ; Val di Castello, Tuscany. POLYBASITB. Orthorhombic, DesCl. 7 A / nearly 120, A 1 = 121 30'. Crystals usually short tabular prisms, with the bases triangularly striated parallel to alternate edges. Cleavage : basal imperfect. Also massive and dis- seminated. H.=2-3. G.=6*214. Lustre metallic. Color iron-black; in thin crys- tals cherry-red by transmitted light. Streak iron-black. Opaque except when quite thin. Fracture uneven. Comp. AggSbSe (or 9Ag 2 S+Sb 2 S 3 ), if containing silver without copper or arsenic, Sulphur 14 '8, antimony 9*7, silver 95 5=100. But with Ag 2 replaced in part by Cu a (ratio Ag : Cu= 1 : 4 to 1 : 11), and Sb replaced by As (ratio 1:1, etc.). Pyr., etc. In the open tube fuses, gives sulphurous and antimonial fumes, the latter forming a white sublimate, sometimes mixed with crystalline arsenous oxide. B.B. fuses with spirting to a globule, gives off sulphur (sometimes arsenic), and coats the coal with anti- monous oxide ; with long-continued blowing some varieties give a faint yellowish-white coat- ing of zinc oxide, and a metallic globule, which with salt of phosphorus reacts for copper, and cupelled with lead gives pure silver. Decomposed by nitric acid. Obs. Occurs in Mexico ; at Tres Puiitos, Chili ; at Freiberg and Przibram. In Nevada, at the Reese mines ; in Idaho, at the silver mines of the Owhyhee district. POLYARGYRITE. Isometric. Cleavage cubic. Malleable. Comp. 12Ag 2 S+Sb a Ss. Wol- fach, Baden. ENARGITE. Orthorhombic. /A 7 = 97 53', O A 14 = 136 37' (Dauber) ; c : I : d = 0-94510 : 1-1480 : 1. O A 1-* = 140 20', A 1 = 128 35'. Cleavage : 1 perfect ; *4, i-l distinct ; indistinct. Also massive, granular or columnar. II. =3. G. 4-43-4-45 ; 4-362, Kenngott. Lustre metallic. Color gray- ish to iron-black ; streak grayish-black, powder having a metallic lustre. Brittle. Fracture uneven. Comp. Cu 3 As 4 = Sulphur 32 '5, arsenic 191, copper 48-4=100, usually containing also a little antimony, and zinc, and sometimes silver. Fyr. In the close-! tube decrepitates, and gives a sublimate of sulphur ; at a higher tem- perature fuses, and gives a sublimate of arsenous sulphide. In the open tube, heated gently, the powdered mineral gives off sulphurous and arsenous oxides, the latter condensing to a sublimate containing some antirnonous oxide. B. B. on charcoal fuses, and gives a faint coat- ing of arsenous oxide, antimonous oxide, and zinc oxide ; the roasted mineral with the fluxea gives a globule of metallic copper. Soluble in nitro-hydrochloric acid. 17 258 DESCRIPTIVE MINERALOGY. Obs. From Morococha, Cordilleras of Peru ; Famatina Mts.. Argentine Republic ; from Chili; mines of Santa Anna, N. Granada ; at Cosihuirachi in Mexico ; Brewster's gold mine, Chesterfield district, S. Carolina ; in Colorado ; at Willis's Gulch, near Black Hawk ; southen Utah ; Morning Star mine, Cal. FAMATINITE (titelsner). An antiinonial euargite. Massive. Color reddish gray. Fama- tina Mts. , Argentine Republic ; Cerro de Pasca, Peru. LUZONITE. Similar to enargite in composition, but unlike inform, according to Weisbach. Mancayan Island, Luzon. CLARITE (Sandberger}. Also similar to enargite in composition, but in form monoclinic, and having a perfect cleavage parallel to the clinopinacoid. Schapbaeh, Black Forest. ETIGENITE. Composition S 32-24, As 12-78, Cu 4068, Fe 14'20=100. Orthorhombio. Color steel-gray. Neugliick mine, Wittichen, COMPOUNDS OF CHLORINE, B-ttOMINE, IODINE. 259 IIJ. COMPOUNDS OF CHLORINE, BROMINE, IODINE 1. ANHYDROUS CHLORIDES, ETC. HALITE!. COMMON SALT. Kochsalz, Steinsalz, Germ. Isometric. Usually in cubes ; rarely in octahedrons ; faces of crystals sometimes cavernous, as in f. 458. Cleavage : cubic, perfect. Massive and granular, rarely columnar. H.=2-5. G.= 2 -1-2-257. Lustre vitreous. Streak white. Color white, also sometimes yellowish, red- dish, bluish, purplish; often colorless. Transparent translucent. Fracture conchoidal. Eather brittle. Soluble ; taste purely saline. Oomp. NaCl= Chlorine 60 '7, sodium 39 '3 = 100. Commonly mixed with some calcium sulphate, calcium chloride, and magne- sium chloride, and sometimes magnesium sulphate, which render it liable to deliquesce. Pyr., etc. In the closed tube fuses, often with decrepitation ; when fused on the platinum loop colors the flame deep yellow. Diff. Distinguished by its taste, solubility, and perfect cubic cleavage. Obs. Common salt occurs in extensive but irregular beds in rocks of various ages, associ- ated with gypsum, polyhalite, calcite, clay, and sandstone ; also in solution, and forming mines of Europe are at Wieliczka, in Poland; at Hall, in the Tyrol; Stass- furt in Prussian Saxony ; and along the range through Reichenthal in Bavaria, Hallein in Salzburg Hallstadt, Ischl, and Ebensee, in upper Austria, and Aussee in Styria ; in Transyl- vania ; Wallachia, G-alicia, and upper Silesia ; Vic and Dieuze in France ; Valley of Cardona and elsewhere in Spain, forming hills 300 to 400 feet high ; Bex in Switzerland ; and North- wich in Cheshire, England. It also occurs near Lake Oroomiah, the Caspian Lake., etc. In Vle-eria in Abyssinia in India in the province of Lahore, and in the valley of Cashmere ; xn China and Asiatic Russia ; in South America, in Peru, and at Zipaquera and Nemocon. In the United States, salt has been found forming beds with gypsum, in Virginia, Wash- ino-ton Co in the Salmon River Mts. of Oregon ; in Louisiana. Brine springs are very numerous m the Middle and Western States. These springs are worked at Salina and Syra- cuse N Y in the Kanawha Valley, Va. ; Muskingum, Ohio; Michigan, at Sagmaw and elsewhere '; and in Kentucky. Vast lakes of salt water exist in many parts of the world Lake Timpanogos in the Rocky Mountains, 4,200 feet above the level of the sea, now called the Great Salt Lake, is 2,000 square miles in area. L. Gale found in this water 20'196 per cent of sodium chloride in 1852 ; but the greater rainfall of the last few years has dimin- ished the proportion of saline matter. The Dead and Caspian Seas are salt, and the waters of the former contain 20 to 26 parts of solid matter in 100 parts. . HUANTAJAYTTE.-Composition 20Nad + AgCl. Occurs in white cubes m the mine of Sao Simon, Cerro de Huantajaya, Peru. 260 DESCRIPTIVE MINERALOGY. SYLV1TE. Isometric. Cleavage cubic. Also compact. H.=2. G.=l'9-2. White or colorless. Yitieous. Soluble; tasle like that of common salt. Comp. KC1= Chlorine 47 '65, potassium 52 -35 = 100. But often containing impurities. Pyr., etc. B.B. in the platinum loop fuses, and gives a violet color to the outer flame. Added to a salt of phosphorus bead, which has been previously saturated with copper oxide, colors the O.F. deep azure-blue. Water completely dissolves it. Obs. Occurs at Vesuvius, about the fumaroles of the volcano. Also at Stassfurt ; at Leo- poldshall (leopoldite) ; at Kalusz, Galicia. CERARGYRITE. Kerargyrite. Horn Silver. Silberhornerz, Germ. Isometric. Cleavage none. Twins: twimiing-plane octahedral. Usually massive and looking like wax ; sometimes columnar, or bent columnar ; often in crusts. H.=1-1'5. G.=5'552. Lustre resinous, passing into adamantine. Color pearl-gray, grayish-green, whitish, rarely violet-blue, colorless sometimes when perfectly pure; brown or violet-brown on exposure. Streak shin- ing. Transparent feebly subtranslucent. Fracture somewhat conchoidal. Sectile. Comp. AgCl=Chlorine 247, silver 75-3=100. Pyr., etc. In the closed tube fuses without decomposition. B.B. on charcoal gives a globule of metallic silver. Added to a bead of salt of phosphorus, previously saturated with copper oxide, and heated in O.F. , imparts an intense azure -blue to the flame. A fragment placed on a strip of zinc, and moistened with a drop of water, swells up, turns black, and finally is entirely reduced to metallic silver, which shows the metallic lustre on being pressed with the point of a knife. Insoluble in nitric acid, but soluble in ammonia. Obs. Occurs in veins of clay slate, accompanying other ores of silver, and usually only in the higher parts of these veins. It has also been observed with ochreous varieties of brown iron ore ; also with several copper ores, with calcite, barite, etc. The largest masses are brought from Peru, Chili, and Mexico. Also occurs in Nicaragua near Ocotal ; in Honduras. It was formerly obtained in the Saxon mining districts of Johanngeorgenstadt and Freiberg, but is now rare. Found in the Altai; at Kongsberg in Norway ; in Alsace ; rarely in Cornwall, and at Huelgoet in Brittany. In Nevada, about Austin, Lander Co., abundant ; at mines of Comstock lode. In Arizona, in the Willow Springs dist. , veins of El Dorado canon, and San Francisco dist. In Idaho, at the Poor Man lode. Named from Kt/jac, horn, and ap^upof, silver. CALOMEL (Quecksilberhornerz, Germ.). Composition HgCl Chlorine 15*1, mercury 84*9 = 100. Color white, grayish, brown. Spain. SAL AMMONIAC (Salmiak, Germ.}. Ammonium chloride, NH 4 C1= Ammonium 33 '7, chlo- rine 66 '3 =100. Vesuvius, Etna, and many volcanoes. NANTOKITE (Breithaupt). Composition CuCl=Chlorine 35 '9, copper 641=100. Cleavage cubic. Color white. Nantoko, Chili. EMBOLITE. Ag(Cl,Br) ; the ratio of Cl : Br varying from 3 : 1 to 1 : 3. Color grayish- green. At various mines in Chili ; also Mexico ; Honduras. BKOMYRITE, Bromargyrite (Bromsilber, Germ.). Silver bromide, AgBr=Bromine 42'6, silver 57 '4=100. Color when pure bright yellow, slightly greenish. Chili ; Mexico. IODYRITE, lodargyrite (lodsilber, Germ.). Silver iodide, Agl = Iodine 54'0, silver 46 '0= 100. Color yellow. Mexico ; Chili ; Spain ; Cerro Colorado mine in Arizona. TOCORNALITE (Domeyko). Composition AgI-{-HgI. Amorphous. Color pale yellow. Chanarcillo, Chill CHLOROCALCITE (Scacchi). From Vesuvius, contained 58*76 p. c. CaCl* ; with also KC1, NaCl,MgCl 2 . CHLORALLUMINITE, CIILORMAGNESITE, and CHLOKOTHIONITE are also from Vesuvius. COMPOUNDS OF CHLORINE, BROMINE, IODINE. 261 COTUNNITE. Lead chloride, PbCl 2 = Chlorine 25 '5, lead 74 '5=100. Soft. White. Vera- vins. PSEUDOCOTUNNITE (Scacchi), Vesuvius. MOLYSITE. Composition FeCl 6 = Chlorine 65-5, iron 34-5=100. Vesuvius. 2. HTDKOUS CHLOKIDES. CARNALLITE. Massive, granular ; flat planes developed by action of water, but no dis- tinct traces of cleavage ; lines of striae sometimes distinguished, which indicate twin- composition. Lustre shining, greasy. Color milk-white, but often reddish from mix- ture of oxide of iron. Fracture conchoidal. Soluble. Strongly phosphor escent. Comp. KMgCl 3 .6aq=KCl-|-MgCl2 + 6aq=Magnesium chloride 34 '2, potassium chloride 26-9, water 38 -9 100. The brown and red color of the mineral is due partly to iron sesquioxide, which is in hex- agonal tables, and partly to organic matters (water-plants, infusoria, sponges, etc.). Pyr., etc. B.B. fuses easily. Soluble in water, 100 parts of water at 18'75 C. taking up 64-5 parts. Obs. Occurs at Stassfurt, where it forms beds in the upper part of the salt formation, alternating with thinner beds of common salt and kieserite, and also mixed with the common salt. Its beds consist of subordinate beds of different colors, reddish, bluish, brown, deep red, sometimes colorless. Sylvite occurs in the carnallite. Also found at Westeregeln ; with salt at Maman in Persia. Its richness in potassium makes it valuable for exploration. TACHHYDRITE. Composition CaMg a Cl 6 + 12aq=CaCl 2 +2MgCl 2 + 12aq (Ramm.)= Chlorine 40'3, magnesium 9*5, calcium 7 '5, water 427=100. Color yellowish. Deliquescent. Stass- furt. KREMERSITE. Probably 2NH 4 Cl-f-2KCl4-FeCl 6 +3aq. Vesuvius. ERYTHROSIDERITE, also from Vesuvius, is 2KCl+FeCl 6 +2aq. 3. OXYCHLOKIDES. ATACAMITB. 29'; DESCRIPTIVE MINERALOGY. Comp.--CuCl 2 +3H 2 CuO 2 = Chlorine 16-64, copper 59'45, oxygen 11-25, water 12'66=100. Also other compounds with more water (18 and 22$ p. c.). Pyr., etc. In the closed- tube gives off much water, and forms a gray sublimate. B.B. or, charcoal fuses, coloring the O.F. azure-Blue, with a green edge, and giving two coatings, one brownish and the other grayish-white ; continued blowing yields a globule of metallic copper ; the coatings touched with the R.F. volatilize, coloring the flame azure -blue. In acide easily soluble. Obs. Occurs in different parts of Chili ; in the district of Tarapaca, Bolivia ; at Tocopilla in Bolivia ; with malachite in South Australia ; Serro do Bembe, near Ambriz, on the west coast of Africa ; at the Bstrella mine in southern Spain ; at St. Just in Cornwall. TALLINGITE. Composition CuCl 2 +4H 2 CuO a +4aq. In thin crusts. Color blue. Botal- lack mine, Cornwall. ATELITE. Composition CuCl 2 +2H 2 Cu0 2 + aq. Formed from tenorite. Vesuvius. PERCYLITE. An oxychloride of lead and copper. Occurs in minute sky-blue cubes. Sonora, Mexico ; So. Africa. MATLOCKITE. Composition PbCl a +PbO= Lead chloride 55-5, lead oxide 44*5=100. Crom- ford, near Matlock, Derbyshire. MENDIPITE. Composition PbCl a +2PbO=Lead chloride 38*4, lead oxide 61'6=100. In columnar masses, often radiated. Color white. Mendip Hills, Somersetshire; Brillon, Westphalia. SCHWAIITZEMBERGITE. Composition Pb(I,Cl) 2 +2PbO. Color yellow. Desert of Ata- cama. DAUBREITE. Composition (Bi 2 O 3 )4BiCl3=Bi 2 O 8 76-16, BiCls 23'84=100. Amorphous. Structure earthy, sometimes fibrous. Color yellowish-gray. H.=2'5. G. =6 "4-6 '5. From the mine Constancia, Cerro de Tanza, Bolivia (Domeyko). FLTTOBINE COMPOUNDS. 263 IV. FLUORINE COMPOUNDS. 1. ANHYDKOUS FLUOKIDES. FLUORITE or FLUOR SPAR* Flusspath, Germ. Isometric; forms usually cubic (see f. 39, 40, 41, 52, 55, etc., pp. 1G to 19). Cleavage : octahedral, perfect. Twins : twinning-plane, 1, f. 266, p. 91. Massive. Rarely columnar ; usually granular, coarse or fine. Crystals often having the surfaces made up of small cubes, or cavernous with rectangular ca vities. [.=4. G.:=3-01-3-25. Lustre vitreous ; bometimes splendent ; usually glimmering in the massive varieties. Color white, yellow, green, rose, and crimson-red, violet-blue, sky-blue, and brown : wine-yellow, greenish and violet-blue, most common ; red, rare. Streak white. Trans- parent subtranslucent. Brittle. Fracture of fine massive varieties flat- conchoidal and splintery. Sometimes presenting a bluish fluorescence. Phosphoresces when heated. Comp., Var. Calcium fluoride, CaF 2 = Fluorine 48'7, calcium 51 '3=100. Berzelius found -5 of calcium phosphate in the fluorite of Derbyshire. The presence of chlorine was detected early by Scheele. Kersten found it in fluor from Marienberg and Freiberg. The bright colors, as shown by Kenngott, are lost on heating the mineral ; they are attributed mainly to different hydrocarbon compounds by Wyrouboff, the crystallization having taken place from aqueous solution. Var. Ordinary ; (a) cleavable or crystallized, very various in colors ; (b) coarse to fine granular ; (c) earthy, dull, and sometimes very soft. A soft earthy variety from Ratofka, Russia, of a lavender-blue color, is the ratofkite. The finely-colored fluorites have been called, according to their colors, false ruby, topaz, emerald, amethyst, etc. The colors of the phosphorescent light are various, and are independent of the actual color ; and the kind affording a green color is (d) the chloropliane. Pyr., etc. In the closed tube decrepitates and phosphoresces. B.B. in the 1 on charcoal fuses, coloring the flame red, to an enamel which reacts alkaline to test paper. With soda on platinum foil or charcoal fuses to a clear bead, becoming opaque on cooling ; with an excess of soda on charcoal yields a residue of a difficultly fusible enamel, while most of the soda sinks into the coal ; with gypsum fuses to a transparent bead, becoming opaque on cooling. Fused in an open tube with fused salt of phosphorus gives the reaction for fluor- ine. Treated with sulphuric acid gives fumes of hydrofluoric acid which etch glass. Phoe- 264 DESCRIPTIVE MINERALOGY. phorescence is obtained from the coarsely powdered spar below a red heat. At a high tem- perature it ceases, but is partially restored by an electric discharge. Diff. Recognized by its octahedral cleavage, its etching power when heated in the glasa tube, etc. Obs. Sometimes in beds, but generally in veins, in gneiss, mica slate, clay slate, and also in limestones, both crystalline and uncrystalline, and sandstones. Often occurs as the gangue of metallic ores. In the North of England, it is the gangue of the lead veins. In Derby- shire it is abundant, and also in Cornwall. Common in the mining district of Saxony ; fine near Kongsberg in Norway. In the dolomites of St. Gothard it occurs in pink octahedrons Some American localities are : Trumbull and Plymouth, Conn. ; Muscolonge Lake, Jeffer- son Co., N.Y., in gigantic cubes ; Rossie, St. Lawrence Co. ; near the Fianklin furnace, N. J. ; Gallatin Co., 111. ; Thunder Bay, Lake Superior; Missouri. SELLAITE (Striiver). Magnesium fluoride, MgF 2 . Tetragonal. Colorless. Occurs with anhydrite at Gerbulaz in Savoy. YTTKOCERITE. Composition 2(9CaF 2 +2YF 2 +CeF 2 )+3aq (Ramm.). Color violet-blue, white. Near Fahlun, Sweden ; Amity, N. Y. ; Paris, Me. ; etc. FLUOCERITE. Contains (Berzelius) -GeOs 82 '64, YO 1'12. Sweden. FLUELLITE. Contains (Wollaston) fluorine and aluminum. Cornwall. CRYPTOHALITE. Fluosilicate of ammonium. Vesuvius. Also observed at Vesuvius, kydrofluorite, HF, and proidonite, SiF 4 (Scacchi). CRYOLITE.* Triclinic (DesCloizeanx and Websky). Form approaching very closely in appearance and angles to the cube and cnbo- octahedron of the isometric system. General habit as in f. 460 ; P(O] A T(I) = 90 2', P(O] A M(l') = 90 24', M/\ T(I/\ T) = 91 57' ; also I (14') A $L (/') = 124 30', I (14') A T(l) = 124 14' (angles by Websky). Twins common. Cleavage parallel to the three planes P, M, T; in crystals most com- plete parallel to T 7 , in masses parallel to P. Com- monly massive, cleavable. H.=2-5. O. = 2-9-3-077. Lnstre vitreous; slightly pearly on O. Color snow-white ; sometimes reddish or brownish to brick-red and even black. Sub- transparent translucent. Immersion in water in- creases the transparency. Brittle. Comp. Na 6 AlF 12 (or 6NaF+AlF 6 )= Aluminum 13-0, sodium 32-8, fluorine 54-2=100. Pyr., etc. Fusible in the flame of a candle. B.B. in the open tube heated so that the flame enters the tube, gives off hydrofluoric acid, etching the glass ; the water which con- denses at the upper end of the tube reacts for fluorine with Brazil-wood paper. In the for- ceps fuses very easily, coloring the flame yellow. On the charcoal fuses easily to a clear bead, which on cooling becomes opaque ; after long blowing, the assay spreads out, the sodium fluoride is absorbed by the coal, a suffocating odor of fluorine is given off, and a crust of alumina rerc ains, which, when heated with cobalt solution in O. F. , gives a blue color. Soluble in sulphuric acid, with evolution of hydrofluoric acid. Diff. Distinguished by its extreme fusibility, and its yielding hydrofluoric acid in the open tube. Obs, Occurs in a bay in Arksut-fiord, in West Greenland, at Evigtok, where it constitutes a large bed or vein in gneiss. It is used for making soda, and soda and alumina salts ; also in Pennsylvania, for the manufacture of a white glass which is a very good imitation of porcelain. CHIOLITE. G. =2-84-2-90. Na 3 AlF 9 (or 3NaF+AlF 6 ). CHODNEFFITE. G.=3-01. Na*AJ P,o (or4NaF + A!F 6 ) Ramm. The two minerals are alike in physical characters, occurring In minute tetragonal pyramids ; both from Miask. FLUORINE COMPOUNDS. 265 2. HYDKOUS FLUORIDES. PAOHNOLTTB. Thomsenolibe.* Monoclinic. with the lateral axes equal (" clino-qnadratic " Norden* kiold). 6:b:d = 1-044 : 1 : 1 ; C7 = 92 30'. Prisms slender a little tapering ; / horizontally striated. Cleavage : basal very perfect. Also massive, opal or chalcedony-like. li. = 2'5-4. G.=2'929-3-008, of crystals. Lustre vitreous, of a cleavage-face a little pearly, of massive waxy. Color white, or with a reddish tinge. Transparent to translucent. Comp.-Na 2 Ca 2 AlF 12 + 2aq, or 2XaF + 2CaF 2 + A1F 6 4- 2aq = 51 28 aluminum 12*28, calcium 17'99, sodium 103o, water 8'10=100. ^ Pvr. etc. Fuses more easily than cryolite to a clear glass. The massive decrepitates remarkably in the flame of a candle. In powder easily decom- posed by sulphuric acid. . Obs. Found incrusting the cryolite of Greenland, and a result of its alteration The crystals often have an ochre-colored coating, especially the terminal portion: they are sometimes quite large, and have much tne appearance of cryolite. The mineral was first described by Knop, and though his ^scnptic n of the crystals does nob agree with that given above, there seems to be no doubt that the material was .the same, which has since been investigated by Hagemann (dimetnc packnohte ^thomsenolite), Wohler (pyroconite) and Koemg, as urged by the latter. Knop originally described two varieties of the mineral, to which he gave the name pachno. lite The variety, A, appeared in large, cuboidal crystals, with cleavage planes parallel to the faces intersLting at angles of approximately 9(P . These cleavage planes seemed to be con- b.^ the possibility that the crystals of r reall wd obtained theangles quoted on the preceding page, were really variety A of palhnolite. The crystallographic relation of the two species is not GEARKSUTITE, all from Greenland; and PROSOPITE from related to those which precede, but whose exact nature RLSTON (Brwh).-An hydrous aluminum fluoride, containing also a little magnet andtodium! Ocfurs in minute regular octahedrons on the cryolite from Greenland. 266 DESCRIPTIVE MINERALOGY. V. OXYGEN COMPOUNDS. 1. OXIDES OF METALS OF THE GOLD, IKON, OR TIN GROUPS. A. ANHYDROUS OXIDES, (a) PROTOXIDES, RO(or R 8 O). CUPRITE. Bed Copper Ore. Rothkupfererz, Germ. Isometric (see figures on p. 17). Cleavage: octahedral. Sometimes cubes lengthened into capillary forms. Also 461 massive, granular; sometimes earthy. H.^3-5-4. G.=5-85-6-15. Lustre ada- mantine or submetallic to earthy. Color red, of various shades, particularly cochineal-red : occasionally crimson-red by transmitted light Streak several shades of brownish-red, shin ing. Subtransparent subtranslueent. Frac- ture conchoidal, uneven. Brittle. Comp., Var. Cu 2 0=Oxygenll-2, copper 88 '8 100 Sometimes affords traces of selenium. Chalcotrichitt is a variety which occurs in capillary or acicular crys- tallizations, which are cubes elongated in the direction of the octahedral axis. It also occurs earthy; Tilt Ore (Ziegelerz Germ.). Brick-red or reddish-brown and earthy, often mixed with red oxide of iron ; some- times nearly black. Fyr., etc. Unaltered in the closed tube. B.B. in the forceps fuses and colors the flame emerald-green; if previously moistened with hydrochloric acid, the color imparted to the flame is momentarily azure-blue from copper chloride. On charcoal first blackens, then fuses, and is reduced to metallic copper. With the fluxes gives reactions for copper oxide. Soluble in concentrated hydrochloric acid. Obs. Occurs in Thuringia ; on Elba, in cubes ; in Cornwall ; in Devonshire ; in isolated crystals, in litbomarpe, at Chessy, near Lyons, which are generally coated with malachite, etc. At the Somerville, and Flemington copper mines, N. J. ; at Cornwall, Lebanon Co., Pa. ; in the Lake Superior region. HTDFOCUPRITE (Oenth). A hydrous cuprite. Occurs in orange-yellow coatings on mrgnetite. Cornwall, Lebanon Co., Pa. ZINCITE. Eed Zinc Ore. Rothzinkerz, Germ. Hexagonal. O A 1 = 118 V ; c = 1-6208. In quartzoids with truncated summits, and prismatic faces I. Cleavage : basal, eminent ; prismatic, sometimes distinct. Usual in foliated grains or coarse particles and masses ; also granular. H. 4-4-5. G. =5-43-5-7. Lustre subadamantine. Streak orange-yel- low. Color deep red, also orange-yellow. Translucent subtranslucent. Fracture subconchoidal. Brittle. Comp. ZnO= Oxygen 19 '74, zinc 80*26=100; containing manganese as an unessential ingredient. The red color is due probably to the presence of manganese sesquioxide, cer- tainly not to scales of hematite. OXYGEN COMPOUNDS ANHYDROUS OXIDES. 267 Pyr., etc. Heated in the closed tube blackens, but on cooling resumes the original color B. B, inf usib .e ; with the fluxes, on the platinum wire, gives reactions for manganese, and on charcoal in R. F. gives a coating of zinc oxide, yellow while hot, and white on cooling. The coating, moistened with cobalt solution and treated in R.F., assumes a green color. Soluble in acids without effervescence. Obs. Occurs with franklinite and also with calcite at Stirling Hill and Mine Hill, Sussex Co.,N. J. CALCOZINCITE. Impure zincite (mixed with CaC0 3 , etc.). Stirling Hill, N. J. TENORITE.* MELACONITE. Schwarzkupfererz (Kupferschwarze), Germ. Orthorhombic (tenorite), crystals from Vesuvius. Earthy; massive; pulverulent (melaconite) ; also in shining flexible scales ; also rarely in cubes with truncated angles (pseudomorphous ?). H.=3. G. 6-25, massive (Whitney). Lustre metallic, and color steel or iron-gray when in thin scales ; dull and earthy, with a black or grayish- black color, and ordinarily soiling the fingers when massive or pulverulent. Comp CuO=Oxygen 20 '15, copper 79 '85 =100 Pyr., etc. B.B. in O.F. infusible; other reactions as for cuprite (p. 244). Soluble in hydrochloric and nitric acids. Obs. Found on lava at Vesuvius in minute scales ; and also pulverulent (Scacchi, who uses the name melaconise for the mineral). Common in the earthy form (mdaconite) about copper mines, as a result of the decomposition of chalcopyrite and other copper ores. Duck- town mines in Tennessee, and Keweenaw Point, L. Superior. PERICLASITE. Essentially magnesium oxide, MgO, or more exactly (Mg,Fe)0, where Mg : Fe=20 : 1, or 30 : 1. Mt. Somma. BUNSENITE. NiO. Found at Johanngeorgenstadt. The compound MnO has been found recently in Wermland, in masses of a green color, and with cubic cleavage. See mangano- site, p. 431. MASSICOT (Bleiglatte). PbO, but generally impure. Baden weiler, Baden. Mexico. Austin's mines, Va. HYDRARGYRITE. HgO ; with BOUDOSITE, AgCl + HgCl, at Los Bordos, Chili. ~ (fy SESQUIOXIDES. GENERAL FORMULA CORUNDUM.* EhombohedraL E A R = 86 4', O A \(R) = 122 26' ; (122 25', Kok- gcharof) ; c = 1-363. Cleavage : basal, some- times perfect, but interrupted, commonly im- perfect in the blue variety ; rhombohedral, often perfect. Large crystals usually rough. Twins : composition-face It. Also massive granular or impalpable ; often in layers from composition parallel to /?. H.=9. G.=3-909-4-16. Lustre vitreous; sometimes pearly on the basal planes, and occa- sionally exhibiting a bright opalescent star of BIX rays in the direction of the axis. Color blue, >-ed, yellow, brown, gray, and nearly wlite; Btreak uncolored. Transparent translucent. Fracture conchoidal uneven. Exceedingly tough when compact. Comp., Var Pure alumina AlO 3 =Oxygen 46 '8, aluminum 53'2=100. There are threr 268 DESCRIPTIVE MINERALOGY. subdivisions of the species prominently recognized in the arts, and until eaily in this century regarded as distinct species ; but which actually differ only in purity and state of crystalliza- tion or structure. YAK. 1. SAPPHIRE Includes the purer kinds of fine colors, transparent to translucent, useful as gems. Stones are named according to their colors ; true Ruby, or Oriental Ruby, red; Toprut, yellow ; 0. Emerald,. green; 0. Amethyst, purple. 2. CORUNDUM. Includes the kinds of dark or dull colors and not transparent, colors light blue to gray, brown, and black. The original adamantine spar from India has a dark gray- ish smoky-brown tint, but greenish or bluish by transmitted light, when translucent, and either in distinct crystals often large, or cleavable-massive. It is ground and u^ed as a polish- ing material, and being purer, is superior in this respect to emery. It was thus employed in ancient times, both in India and Europe. 3. EMERY, Schmirgel, Germ. Includes granular corundum, of black or grayish-black color, and contains magnetite or hematite intimately mixed. Feels and looks much like a black fine-grained iron ore, which it was long considered to be. There are gradations from the evenly fine-grained emery to kinds in which the corundum is in distinct crystals. This last is the case with part of ihat at Chester, Massachusetts. Pyr., etc. B.B. unaltered ; slowly dissolved in borax and salt of phosphorus to a clear glass, which is colorless when free from iron ; not acted upon by soda. The finely pulverized mineral, after heating with cobalt solution, gives a beautiful blue color. Not acted upon by acids, but converted into a soluble compound by fusion with potassium bisulphate or soda. Friction excites electricity, and in polished specimens the electrical attraction, con- tinues for a considerable length of time. Diff. Distinguished by its hardness, scratching quartz and topaz ; its infusibility and its high specific gravity. Obs. This species is associated with crystalline rocks, as granular limestone or dolomite, gneiss, granite, mica slate, chlorite slate. The fine sapphires are usually obtained from the beds of rivers, either in modified hexagonal prisms or in rolled masses, accompanied by grains of magnetic iron ore, and several species of gems. The emery of Asia Minor, according to Dr. Smith, occurs in granular limestone. Sapphires occur in Ceylon ; the East Indies ; China. Corundum, at St. Gothard ; in Pied- mont ; Urals ; Bohemia. Emery is found in large boulders on some of the Grecian islands ; also in Asia Minor, near Ephesus, etc. In N. America, in Massachusetts, at Chester, corun- dum and emery in a large vein ; also in Westchester Co. , N. Y. In New York, at Warwick and Amity. In Pennsylvania, in Delaware Co., and Chester Co. In western N. Carolina^ at many localities in large quantities, and sometimes in crystals of immense size. In Georgia^ in Cherokee Co. In California, in Los Angeles Co. ; in the gravel on the Upper Missouri .River in Montana. HEMATITE. Specular Iron. Eisenglanz, Rotheisenerz, Germ. Rhombohedral. 7? A 7? = 86 10', A E = 122 30'; c = 1-3591. O A f 2 = 118 53', O A I 3 = 103 32, R A f 2 = 154 V. Cleavage : par- allel to R and Of often indistinct. Twins: twinning-plane R ; also ' 468 469 Elba. Elba. Vesuvius. (f . 267, p. 91). Also columnar granular, botryoidal, and stalactitic shapes ; also lamellar, laminae joined parallel to O, and variously bent, thick or thin ; also granular, friable or compact. OXYGEN COMPOUNDS ANHYDROUS OXIDES. 269 H. 5'5-6'5. G.=4-5-5'3; of some compact varieties, as low as 4*2. Lustre metallic and occasionally splendent ; sometimes earthy. Color dark steel-gray or iron-black ; in very thin particles blood-red by transmitted light ; when earthy, red. Streak cherry-red or reddish-brown. Opaque, except when in very thin laminae, which are faintly translucent and blood- red. Fracture subconchoidal, uneven. Sometimes attractable by the magnet, and occasionally even magnet ipolar. Comp., Var. Iron sesquioxide, Fe0 3 = Oxygen 30, iron 70=100. Sometimes containing titanium and magnesium. The varieties depend on texture or state of aggregation, and in some cases the presence v ' impurities. Var. 1. Specular. Lustre metallic, and crystals often splendent, whence the name specular iron, (b) When the structure is foliated or micaceous, the ore is called micaceous hematito (Eisenglimmer). 2. Compact columnar ; or fibrous. The masses of ten long radiating ; lustre submetallic to metallic ; color brownish-red to iron-black. Sometimes called rtd hematite, the name hematite among- the older mineralogists including the fibrous, stalactitic, and other solid massive varieties of this species, limonite, and turgite. 3. Red Ochreous. Bed and earthy. Often specimens of the preceding are red ochreous on some parts. Reddle and red chalk are red ochre, mixed with more or less clay. 4. Glay Iron-stone ; Argillaceous hematite. Hard, brownish-black to reddish-brown, heavy stone ; often in part deep-red ; of submetallic to unmetallic lustre ; and affording, like all the preceding, a red streak. It consists of iron sesquioxide with clay or sand, and sometimes other impurities. Pyr., etc. B.B. infusible; on charcoal in R.F. becomes magnetic; with borax in O.F. gives a bead, which is yellow while hot and colorless on cooling ; if saturated, the bead appears red while hot and yellow on cooling ; in R.F. gives a bottle-green color, and if treated oil charcoal with metallic tin, assumes a vitriol-green color. With soda on charcoal in R.F. is reduced to a gray magnetic metallic powder. Soluble in concentrated hydrochloric acid. Diff. Distinguished from magnetite by its red streak, also from limonite by the same means, as well as by its not containing water ; from turgite by its greater hardness and by its not decrepitating B.B. It is hard; and infusible. Obs. This ore occurs in rocks of all ages. The specular variety is mostly confined to crys- talline or metamorphic rocks, but is also a result of igneous action about some volcanoes, aa at Vesuvius. Traversella in Piedmont ; the island of Elba, afford fine specimens ; also St. Gothard, of ten in the form of rosettes (Eisenrose , and Cavradi in Tavetsch; and near Limogei, France. At Etna and Vesuvius it is the result of volcanic action. Arendal in Norway, Long- ban in Sweden, Framont in Lorraine, Dauphiny, also Cleator Moor in Cumberland, are other localities. In N. America, widely distributed, and sometimes in beds of vast thickness in rooks of the Archgean age, as in the Marquette region in northern Michigan ; and in Missouri, at the Pilot Knob and the Iron Mtn. ; in Arizona and Nftw Mexico. Some of the localities, interesting for their specimens, are in northern New York, etc.; Woodstock and Aroostook, Me.; at Hawley, Mass. ; at Piermont, N. H. This ore affords a considerable portion of the iron manufactured in different countries. The varieties, especially the specular, require a greater degree of heat to melt than other ores, but the iron obtained is of good quality. Pulverized red hematite is employed in polishing metals, and also as a coloring material. The fine-grained massive variety from England (bloodstone), showing often beautiful conchoidal fracture, is much used for burnishing metals. Eed ochre is valuable in making paint. MARTITE is iron sesquioxide under an isometric form, occurring in octahedrons or dodeca- hedrons like magnetite, and supposed to be pseudomorphous, mostly after magnetite. H. 6-7. G. =4 -809-4 -832, Brazil, Breith. ; 5 '33, Monroe, N. Y., Hunt. Lustre submetallic. Color iron-black, sometimes with a bronzed tarnish. Streak reddish-brown or purplish-brown. Fracture couchoidal. Not magnetic, or only feebly so. The crystals are sometimes imbed- ded in the massive sesquioxide. They are distinguished from magnetite by their red streak, and very feeble, if any, action on the magnetic needle. Found in Vermont at Chittenden; in the Marquette iron region south of L. Superior; Bass lake, Canada West; Digby Neck, Nova Scotia; at Monroe, N. Y. ; in Moravia, neaj Schonberg, in granite. MENACCANITE.* ILMENIFE. Titanic Iron Ore. Titaneisen, Germ. Khombohedral ; tetartohedral to the hexagonal type. It A R = 85 30' 270 DESCRIPTIVE MINERALOGY. 56" (Koksch.), c = 1-38458. Angles nearly as cleavage parallel with in hematite. Often a a the terminal plane, but ue to planes of composition. Crystals usually tabular. Twins : twinning-plane O ; sometimes producing, when repeated, a form resembling f. 468. Often in thin plates or lamina} ; massive ; in loose grains as sand. II. 5-6. G.=4r'5-5. Lustre submetallic. Color iron-black. Streak submetallic, powder black to brownish-red. Opaque. Fracture con- choidal. Influences slightly the magnetic needle. Comp., Var. (Ti,Fe) 2 3 (or hematite, with part of the iron replaced by titanium), the pro portion of Ti to Fe varying. Mosander assumes the proportion of FeO : TiO 2 to be always 1:1, and that in addition variable amounts of Fe0 3 are present in the different varieties. The extensive investigations of Rammelsberg have led him to write the formula like Mosan- der (FeO,TiO 2 )+nFeO 3 (notice here that FeO,TiO 2 =tt0 3 ). This method has the advantage of explaining the presence of the magnesium, occurring sometimes in considerable amount, it replacing the iron (FeO). The first formula given requires the assumption of Mg 2 3 . Friedel and Guerin have recently discussed the same subject (Ann. Ch. Phys., V., viii., 38, 1876). Sometimes contains manganese. The varieties recognized arise mainly from the proportions of iron to titanium. No satisfactory external distinctions have yet been made out. The following analyses will illustrate the wide range in composition : TiO* FeO 3 FeO MnO 1. IlmenMts., Ilmenite W-92 10 '74 37 '86 2 "73 2. Snarum 10 '02 77" 17 8-52 3. Warwick, N. Y. 57'71 26 '82 0'90 MgO 1-14=99-39, Mosander. 1-33, AlO a 1-46=98-50, Ramm. 13-71=9914, Ramm. Pyr., etc. B.B. infusible in O.F. although slightly rounded on the edges in R. F. With borax and salt of phosphorus reacts for iron in O.F., and with the latter flux assumes a more or less intense brownish-red color in R.F. ; this treated with tin on charcoal changes to a violet-red color when the amount of titanium is not too small. The pulverized mineral, heated with hydrochloric acid, is slowly dissolved to a yellow solution, which, filtered from the undecomposed mineral and boiled with the addition of tin-foil, assumes a beautiful blue or violet color. Decomposed by fusion with sodium or potassium bisulphate. Diff. Resembles hematite, but has a submetallic, nearly black, streak. Obs. Some of the principal European localities of this species are : Krageroe, Egersnnd, Arendal, Norway; Uddewalla, Sweden ; Ilmen Mts. (ilmenite) ; Iserwiese, Riesengebirge (iaer- ine) ; Aschaffenburg ; Eisenach ; St. Cristophe (orichtonite). Occurs in Warwick, Amity, and Monroe, Orange Co., N. Y. ; also near Edenville ; at Ches- ter and South Royalston, Mass. ; at Bay Sb. Paul in Canada; also with labradorite at Chateau Richer. Grains are found in the gold sands of California. PEROFSKTTE.* Isometric, Eose (fr. Ural). Habit cubic, with secondary planes incom- pletely developed ; in cubes, octahedrons, and cubo-octahedrons, from Arkansas. Twins: twinning-plane octahedral, Magnet Cove, Ark.; also like f. 276, p. 93, Achmatovsk. Cleavage : parallel to the cubic faces rather perfect. IT.r=5-5. G.=4'02-4:'04:. Lustre metallic adamantine. Color pale ye* low, honey-yellow, orange-yellow, reddish-brown, grayish-black to iron- black. Streak colorless, grayish. Transparent to opaque. Double refract- ing. OXYGEN COMPOUNDS. ANHYDROUS OXIDES. 271 Oomp. (Ca+Ti)0 3 =KO 3 =Titanic oxide 59'4, lime 40'6=100. Pyr., etc. In the forceps and on charcoal infusible. With salt of phosphorus in O.F. dis solves easily, giving a bead greenish while hot, which becomes colorless on cooling; in R.F. the bead changes to grayish-green, and on cooling assumes a violet-blue color. Entirely de- composed by boiling sulphuric acid. Obs. Occurs at Achmatovsk, in the Ural ; in the valley of Zermatt ; at Wildkreuzjoch in the Tyrol. Also at Magnet Cove, Arkansas. DesCloizeaux has found that the yellow crystals from Zermatt have a complex twinned structure, and are optically biaxial. Kokscharof, in his latest investigations, has shown that the Russian specimens also exhibit phenomena in polarized light analogous to those of biaxial crystals, though irregular. He proves, however, that crystallographically the crystals ex- amined by him were unquestionably isometric, and adds also that almost all the Russian perofskite crystals are penetration -twins. The latter fact explains the commonly observed striations on the cubic planes, as also the incompleteness in the development of the other forms. He refers the optical irregularities to the want of homogeneity in the crystals. Des- Cloizeaux speaks of inclosed lamellae of a doubly-refracting substance analogous to the para- site in boracite crystals (p. 170). HYDROTITANITE. A decomposition-product of perofskite crystals from Magnet Cove, Arkansas. Form retained but color changed to yellowish-gray (Koenig). (c) COMPOUNDS OP PROTOXIDES AND SESQUIOXIDES,* KBO 4 (or RO+RO 3 ). Spinel Group. Isometric (Octahedral). SPINEL. Isometric. Habit octahedral. Faces of octahedron sometimes convex. Cleavage : octahedral. Twins : twinning-plane 1. H.=8. G.=3-5-4'l. Lustre vitreous ; splendent 471 nearly dull. Color red of various shades, passing into blue, green, yellow, brown, and black; occasionally almost white. Streak white. Transparent nearly opaque. Fracture conchoidal. Comp., Var. The spinels proper have the formula MgA10 4 (=MgO 4-rtl0 3 ), or in other words contain chiefly magnesium and aluminum, with the former replaced in part by iron (Fe), calcium (Ca), and man- ganese (Mn) ; and the latter by iron (Fe). There is hence a grada- tion into kinds containing little or no magnesium, which stand as distinct species, viz., Hercynite and Gahnite. MgA10 4 Alumina ^ma^esw. Magnesia Spinel. Clear red or reddish; transparent to translucent; sometimes subtranslucent. Gk =3 '52-3 '58. Composition MgAlO 4 , with little or no Fe, and sometimes chromium as a source of the red color. 2. Ceywnite, or Iron-Magnesia Spinel. Color dark-green, brown to black, mostly opaque or nearly so. 0. =8 -8-8-6. Composition M"Al0 4 + FeM0 4 . Sometimes the Al is replaced in part by Fe. 3. Pic-otite. Contains over 7 p. c. of chromium oxide. Color black. Lustre brilliant. G.=4'08. The original was from a rock occurring about L. Lherz, called Lherzolite. Pyr., etc. B B. alone infusible ; the red variety turns brown, and even black and opaque as the temperature increases, and on cooling becomes first green, and then nearly colorless and at last resumes the red color. Slowly soluble in borax, more readily in salt of phosphorus, with which it gives a reddish bead while hot, becoming faint chrome-green on * The compounds here considered are sometimes regarded as salts of the acide. HatlO* that is, as aluminates, ferrates, etc. 272 DESCRIPTIVE MINERALOGY. cooling. The black varieties give reactions for iron with the fluxes. Soluble with difficulty in concentrated sulphuric acid. Decomposed by fusion with sodium or potassium bisulphate. Diff. Distinguished by its octahedral form, hardness, and inf usibility ; magnetite is attracted by the mag-net, and zircon has a higher specific gravity. ' Obs Spinel occurs imbedded in granular limestone, and with calcite in serpentine, gneiss, and allied rocks. It also occupies the cavities of masses ejected from some volcanoes, e.g., Mt. Somma. Fine spinels are found in Ceylon ; in Siam, as rolled pebbles in the channels of rivers. Occur at Aker in Sweden ; also at Monzoni in the Fassathal. From Amity, N. Y., to Andover, N. J., a distance of about 30 miles, is a region of granular limestone and serpentine, in which localities of spinel abound ; numerous about Warwick, and at Monroe and Cornwall. Franklin, Sterling, Sparta, Hamburgh, and Vernon, N. J., are other localities. At Antwerp, Jefferson Co., N. Y. ; at Bolton and elsewhere in Mass. HERCYNTTE. FeAlO 4 (or FeO+AlO 3 ). Color black. Massive. Bohemia. JACOBSITE (Damour). RfK) 4 , or (Mn,Mg) (Fe,Mn)0 4 . Color deep black. Occurs in dis- torted octahedrons (magnetic) in a crystalline limestone at Jacobsberg, Sweden. GAHNITE. Zinc Spinel. Isometric. In octahedrons, dodecahedrons, etc., like spinel. H.=7'5-8. G.=4-4'6. Lustre vitreous, or somewhat greasy. Color dark green, grayish-green, deep leek-green, greenish-black, bluish-black, yellowish- or grayish-brown ; streak grayish. Subtranslucent to opaque. Comp., Var. Zn:MO 4 = Alumina 61 -3, oxide of zinc 38'7=100 ; with little or no magnesium. The zinc sometimes replaced in small part by manganese or iron (Mn,Fe), and the aluminum in part by iron (Fe). Var. 1. A utomolite, or Zinc GaJmite; with sometimes a little iron. G. =4'l-4'6. Colors as above given. 2. Dysluite, or Zinc-Manganese-Iron Gahnite. Composition (Zn,Fe,Mn) (Al,Fe)O 4 . Color yellowish-brown or grayish-brown. G. =4-4 "6. Form the octahedron, or the same with truncated edges. 3. Kreittonite, or Zinc- Iron OaJinite. Composition (Zn, Fe,Mg)(Al,Fe,O 4 . Occurs in crystals, and granular massive. H.=7-8. G. =4 '48-4 "89. Color velvet to greenish-black ; powder grayish-green. Opaque. Pyr., etc. Gives a coating of zinc oxide when treated with a mixture of borax and soda on charcoal. Otherwise like spinel. Obs. Automolite is found at Fahlun, Sweden ; Franklin, N. Jersey ; Canton mine, Ga. ; Dysluite at Sterling, N. J. ; Kreittonite at Bodenmais in Bavaria. MAGNETITE. Magnetic Iron Ore. Magneteisenstein, Magneteisenerz, Germ. Isometric. The octahedron and dodecahedron the most common forms. 475 Achmatovsk. Haddam. Fig. 75 is a distorted dodecahedron. Cleavage : octahedral, perfect tc OXYGEN COMPOUNDS. ANHYDROUS OXIDES. 273 imperfect. Dodecahedral faces commonly striated parallel to the longer diagonal. Twins : twinning-plane, 1 ; also in dendrites, branching at angles of 60 (f. 277, p. 93). Massive, structure granular particles of various sizes, sometimes impalpable. II.=:5'5-6'5. G.=4'9-5'2. Lustre metallic submetallic. Color iron- black ; streak black. Opaque ; but in mica sometimes transparent or | nearly so ; and varying from almost colorless to pale smoky-brown and black. Fracture subconchoidal, shining. Brittle. Strongly magnetic, sometimes possessing polarity. Comp., Var. FeFe0 4 (or Fe 8 4 )=FeO+Fe0 3 =Oxygen 27'6, iron 72'4=100 ; or iron ses- quioxide 68-97, iron protoxide 31-03=100. The iron sometimes replaced in small part by magnesium. Also sometimes titaniferous. From the normal proportion of Fe to Fe, 1:1, there is occasionally a wide variation, and thus a gradual passage to the sesquioxide Fe0 3 ; and this fact may be regarded as evidence that the octahedral Fe0 3 , martite, is only an altered magnetite. Pyr., etc. B. B. very difficultly fusible. In O.F. loses its influence on the magnet. With the fluxes reacts like hematite. Soluble in hydrochloric acid.' DifF. Distinguished from other members of the spinel group, as also from garnet, by its being attracted by the magnet, as well as by its high specific, gravity. Also, when massive, by its black streak from hematite and limonite. Obs. Magnetite is mostly confined to crystalline rocks, and is most abundant in metamor- phic rocks, though found also in grains in eruptive rocks. In the Archaean rocks the beds are of immense extent, and occur under the same conditions as" those of hematite. It is an ingre- dient in most of the massive variety of corundum called emery. The earthy magnetite is found in bogs like bog-iron ore. Extensive deposits occur at Arendal, Norway ; Dannemora and the Taberg in Smaoland ; in Lapland. Fahlun in Sweden, and Corsica, afford octahedral crystals. In N. America, it constitutes vast beds in the Archaean, in the Adirondack region, in Northern N. York ; also in Canada ; at Cornwall in Pennsylvania, and at Magnet Cove, Arkansas. Also found in Putnam Co, (Tilly Foster Mine), N. Y., etc. In Conn., at Haddam. In Penn., at Chester Co. ; in mica at Pennsbury. In California^ in Sierra Co. ; in Plumaa Co., and elsewhere. In M. Scotia, Digby Co., Nichol's Mt. MAGNESIOFEKRITB (ma.gnoferrite). MgFe0 4 . In octahedrons; resembling magnetite. Vesuvius. FRANKLJNITE. Isometric. Habit octahedral. Cleavage: octahedral, indistinct. Also massive, coarse or fine granular to compact. H.=5-5-6-5. G.=5-069. Lustre metallic. Color iron-black. Streak dark reddish-brown. Opaque. Fracture conchoidal. Brittle. Acts slightly on the magnet. Comp. (Fe,Zn,Mn) (Fe,Mn)O 4 , or corresponding to the general formula of the spinel group, though varying much in relative amounts of iron, zinc, and manganese. Analysis, Sterling Hill, N. J., *Fe0 3 67 '42, A1O 3 0'65, FeO 15 -65, ZnO 6-78, MnO 9'53=100'12, Seyms. Q. ratio for B : R=l : 1 nearly. In a crystal from Mine Hill, N. J., Seyms found 4' 44 p. c. MnO 3 . The evolution of chlorine in the treatment of the mineral is attributed by v. Kobell to the presence of a little Mn0 3 (0.80 p. c.) as mixture, which Rammelsberg observes may have come from the oxidation of some of the protoxide of manganese. Pyr., etc. B.B. infusible. With borax in O.F. gives a reddish amethystine bead (man- ganese), and in R.F. this becomes bottle-green (iron). With soda gives a bluish-green man- ganate, and on charcoal a faint coating of zinc oxide, which is much more marked when a mixture of borax and soda is used. Soluble in hydrochloric acid, with evolution of a smali amount of chlorine. Diff. Resembles magnetite, but is only slightly attracted by the magnet ; it also reacti for zinc on charcoal B.B. 18 274 DESCRIPTIVE MINERALOGY. Obs. Occurs in cubic crystals near Eibach in Nassau ; in amorphous masses at Altenberg, near Aix la Chapelle. Abundant at Hamburg, N. J., near the Franklin furnace; also at Stirling Hill, in the same region. CHROMITE.* Chromic Iron. Chromeisenstein, Germ. Isometric. In octahedrons. Commonly massive ; structure fine granu- lar or compact. H.=5-5. G.=4-321-4-568. Lustre submetallic. Streak brown. Color between iron-black and brownish-black. Opaque. Fracture uneven. Brittle. Sometimes magnetic. Comp. Fe6r0 4 , or (Fe,Mg,Cr) (Al,Fe,<3r)0 4 . Fe6r0 4 =Iron protoxide 32, chromium ses- quioxide 68=100. Magnesia is generally present, and in amounts varying from 6-24 p. c. Pyr., etc. B. B. in O. F. infusible ; in R. F. slightly rounded on the edges, and becomes magnetic. With borax and salt of phosphorus gives beads, which, while hot, show O7ily a reaction for iron, but on cooling become chrome-green ; the green color is heightened by fusion on charcoal with metallic tin. Not acted upon by acids, but decomposed by fusion with potassium or sodium bisulphate. Diff. Distinguished from magnetite by the reaction for chromic acid with the blowpipe. Obs. Occurs in serpentine, forming veins, or in imbedded masses. It assists in giving the variegated color to verde-antique marble. Also occurs in meteorites. Occurs in Syria ; Shetland ; in Norway ; in the Department du Var in France ; in Silesia and Bohemia ; in the Urals; in New Caledonia. At Baltimore, Md., in the Bare Hills ; at Cooptown. In Pennsylvania, in Chester Co. ; at Wood's Mine, near Texas, Lancaster Co. , etc. Chester, Mass. In California, in Monterey Co., etc. This ore affords the chromium oxide, used in painting, etc. The ore employed in England is obtained mostly from Baltimore, Drontheim in Norway, and the Shetland Isles. CHROMPICOTITE (Petersen). A magnesian chromite. Color black. New Zealand. URANINITE* (Pitchblende ; Uranpecherz, Oerm.}. Saxony, etc. Massive. Black. OHRYSOBBRYL. Orthorhombic. /A I 129 38', O A l-l = 129 1 .' ; , near Boonville. RUTILE. 4 Tetragonal. O A I-i = 147 12|', c = 0-6442. 1 A 1, pyr., = 123 7J', /A 1 = 132 20'. Cleavage: /and i-i, distinct; 1, in traces. Vertical planes usually striated. Crystals often acicular. Twins : (1) twinning-plane l-i (see p. 94). (2) 3-, making a wedge-shaped crystal consisting of two individuals. (3) 1-i and 3-i in the same crystal (fr. Magnet Cove, liessen- berg). Occasionally compact, massive. 481 t3 483 Graves Mtn., Ga. H.=6-6-5. G.= 4-18-4-25. Lustre metallic- adamantine. Color red- dish-brown, passing into red ; sometimes yellowish, bluish, violet, black ; rarely grass-green. Streak pale brown. Subtransparent opaque. Frac- ture subconchoidal, uneven. Brittle. Comp., Var Titanic oxide, Ti0 2 = Oxygen 39, titanium 61 =100. Sometimes a little iron is present. Pyr., etc. B.B. infusible. With salt of phosphorus gives a colorless bead, which in R.F. assumes a violet color on cooling. Most varieties contain iron, and give a brownish -yellow or red bead in R.F., the violet only appearing after treatment of the bead with metallic tin on charcoal. Insoluble in acids ; made soluble by fusion with an alkali or alkaline carbonate. The solution containing an excess of acid, with the addition of tin-foil, gives a beautiful riolet-color when concentrated. OXYGEN COMPOUNDS. ANHYDKOUS OXIDES. 277 Diff. Characterized by its peculiar sub-adamantine lustre, and brownish-red color. Differs horn V armaline, vesuvianite, augite in being entirely unaltered when heated alone B.B. Spec; Re gravity about 4, cassiterite 6 '5. O T oa. -Rutile occurs in granite, gneiss, mica slate, and syenitic rocks, and sometimes in granula^ limestone and dolomite. It is generally found in imbedded crystals, often in masses of quartz or feldspar, and frequently in acicular crystals penetrating quartz. Very commonly implanted in regular position upon crystals of hematite, as from Cavradi in the Tavetschthal. Occurs in Norway; Finland ; Saualpe, Carinthia; in the Urals ; in the Tyrol ; at St. Gothard near Freiberg ; at Ohlapian in Transylvania. In Maine, at Warren. In Vermont, at Waterbury and elsewhere. In Mass. , at Barre , Shelburne; Sheffield. In Conn., at Lane's mine, Monroe. In N. York, in Orange Co.; Edenville ; Warwick. In Penn., Chester Co. In N. Car., at Crowder's Mountain. In Georgia, in Habersham Co. ; in Lincoln Co., at Graves' Mountain. In Arkansas, at Magnet Cove. Titanium oxide is employed for a yellow color in painting porcelain, and also for giving the requisite tint to artificial teeth. Binnenthal. OCTAHEDRITE.* Anatase. Tetragonal. Al-i = 119 22'; c = 1 '77771. Commonly octahedral or tabular. 1 A 1, pyr., = 97 51'. 7M = 158 18'. Cleavage: 1 and 0, per- fect. H.=5-5-6. G.=3-82- 3-95 ; sometimes 4-11-4-16 after heating. Lustre metallic-adamantine. Col- or various shades of brown, passing into indigo-blue, and black ; greenish-yellow by transmitted light. Streak uncolored. Fracture subconchoidal. Brittle. Comp. Like rutile and brookite, pure titanic oxide. Pyr., etc. Same as for rutile. Obs. Abundant at Bourg d'Oisans, in Dauphiny ; also in the Bin- nenthal (including here Kenngott's wiserinfi, f. 484, as shown by Klein, Jahrb. Min., 1875, 337); at Pfitsch Joch, Tyrol; near Hof in the Fichtelgebirge ; Norway; the Urals; in Devonshire, near Tavistock ; at Tremadoc, in North Wales ; in Cornwall ; in Brazil in quartz. In the U. States, at Smithfield, R. I. HAUSMANNITE. Mn 3 O 4 =2MnO,Mn0 2 . Tetragonal, A 1-i =130 25'. Color brownish- black. Thuringia ; Harz, etc. BKAUNITE. 2(2MnO,MnO 2 )+MnO 2 ,SiO,. Tetragonal, 0Al-=135 26'. Color dark brownish-black. Thuringia ; Norway, etc. MINIUM (Mennige, Germ.). PbaO 4 =PbO a +2PbO. Badenweiler; Wythe Co., Va., etc. BROOKITE* Orthorhombic (?). /A 7=99 50' (-100 50') : O A 1-^ = 131 42'; i : I : d = 1-1620 : 1*1883 : 1. Cleavage : /, indistinct ; O, still more so. H.=5-5-6. G.=4-12-4-23, brookite; 4-03-4-085, arkansite. Hair-brown, yellowish, or reddish, with metallic adamantine lustre, and translucent 278 DESCKIKnVE MINERALOGY. (brookite); also ircm-black, opaque, and submetallic (arkaneite). Streak uneolored grayish, yellowish. Brittle. 487 488 Arkansas. if EUenville, N. Y. Miask, TJral. Comp. Pure titanic oxide, Ti0 2 , like rutile and octahedrite. Pyr., etc. Same as for rutile. Obs. Brookite occurs at Bourg d'Oisans in Dauphiny ; at St. Gothard ; in the Urals, near Miask ; in thick black crystals (arkansite f. 486) at Magnet Cove, Arkansas, sometimes altered to rutile by paramorphism ; at Ellenville, Ulster Co., N. Y. ; at Paris, Maine. Schrauf has announced (Atlas Min., Reich. IV.) that he has found brookite to be monodinie (and isomorphous with wolframite). He distinguishes three types having different axial relations. The measurements of v. Rath, however, seem to show that in part it must be orthorhombio. EUMANITE. From Chesterfield, Mass., may be identical with brookite. Orthorhombic. PYROLUSITE.* Polianite. IM = 93 40', O A 14 = 142 11' ; t : I : & = 0-776 : 1*066 : 1. Cleavage /and i-4. Also columnar, often divergent ; also granular massive, and frequently in renifonn coats. Often soils. H.=2-2-5. G.=4-82. Turner. Lustre metallic. Color iron-black, dark steel-gray, sometimes bluish. Streak black or bluish-black, sometimes submetallic. Opaque. Rather brittle. Comp. MnO 2 =Manganese 63'2, oxygen 36*8-100. Fyr., etc B.B. alone infusible; on charcoal loses oxygen. A manganese reaction with borax. Affords chlorine with hydrochloric acid. Diflf. Hardness less than that of psilomelane. Differs from iron ores in its reaction for manganese B. B. Easily distinguished from psilomelane by its inferior hardness, and usually by being crystalline. Obs. Occurs extensively at Elgersberg near Ilmenau in Thuringia ; at Vorderehrensdorf in Moravia ; at Platten in Bohemia, and elsewhere. Occurs in the United States in Vermont, at Brandon, etc. ; at Con way, Mass. ; at Winchester, N. H. ; at Salisbury and Kent, Conn. In California, on Red island, bay of San Francisco. In New Brunswick, near Bathurst. In Nova Scotia, at Walton ; Pictou, etc. Pyrolusite and manganite are the most important of the ores of manganese. Pyrolusite parts with its oxygen at a red heat, and is extensively employed for discharging the brown and green tints of glass. It hence received its name from irvp, fire, and /i'u, to wash. C.REDNERITE. Cu 3 Mn 2 O 9 , or 3CuO+2MnO s . Foliated. Color black. Thuringia. OXYGEN COMPOUNDS. HYDKOUS OXIDES. 279 B. HYDKOUS OXIDES. TURGITE. Compact fibrous and divergent, to massive ; often botryoidal and sta- lactitic like limonite. Also earthy, as red ochre. H.=5-6. G.=: 3-56-3-74, from Ural; 4-29-4-49, fr. Hof; 4-681, fr. Horhausen ; 4-14, fr. Salisbury. Lustre submetallic and somewhat satin- like in the direction of the fibrous structure; also dull earthy. Color reddish-black, to dark red ; bright-red when earthy ; botryoidal surface often lustrous, like much lirnonite. Opaque. Comp. H 2 Fe,O 7 =Iron sesquioxide 94 '7, water 5 '3 100. Pyr., etc. Heated in a closed tube, flies to pieces in a remarkable manner ; yields water. Otherwise like hematite. Diff. Distinguished from hematite and limonite by its superior hardness, the color of its streak, and B.B. its decrepitation. Obs. A very common ore of iron. Occurs at the Turginsk copper mine near Bosgolovsk, in the Ural ; near Hof in Bavaria, and Siegen in Prussia ; at Horhausen. In the U. S. it occurs at Salisbury, Ct. DIASPORE. Orthorhombic. I A 1= 93 42f, A l-l =147 0-64425 : 1-067 : 1. i-lM-l = 121 7^, a A 1-2 = 104 14J', i-lM = 116 54^. Crystals usually thin, flattened parallel to i-l, sometimes acicular; commonly implanted. Cleavage : i4 eminent ; i-2 less perfect. Occurs foliated massive and in thin scales; sometimes stalactitic. H. = 6-5-7. G.= 3-3-3-5. Lustre brilliant and pearly on cleavage-face ; elsewhere vitreous. Color whitish, grayish- white, greenish-array, hair-brown, yellowish, to colorless ; sometimes violet-blue in one direction, reddish plumb-blue in another, and pale asparagus-green in a third. When thin, translucent subtranslucent. Very brittle. Comp H 2 A10 4 = Alumina 85'1, water 14'9=100 ; a little phosphorus pentoxide is often present. Pyr., etc. In the closed tube decrepitates strongly, separating into pearly white scales, and at a high temperature yields water. The variety from Schemnitz does not decrepitate. Infusible ; with cobalt solution gives a deep blue color. Some varieties react for iron with the fluxes. Not attacked by acids, but after ignition becomes soluble in sulphuric acid. Diff, Distinguished (B.B.) by its decrepitation and yielding water ; as also by the reaction for alumina with cobalt solution. Resembles some varieties of hornblende, but is harder. Obs. Commonly found with corundum or emery. Occurs in the Ural ; at Schemnitz ; at Broddbo near Fahlun ; in Switzerland ; in Asia Minor, and the Grecian islands ; in Chester Co., Pa. ; at the emery mines of Chester, Mass. ; N. Carolina. IHaspore was named by Haiiy from diaarreipcj, to scatter, alluding to the usual decrepitation before the blowpipe. iz iz 280 DESCRIPTIVE MINERALOGY. GOTHITE. Orthorhombic. I^I= 94 52' (B. & M.) ; A 14 = 146 33' ; c : I : d = 0-66 : 1*089 : 1. in prisms longitudinally striated, and often flattened into scales or tables parallel to the shorter diagonal. Cleavage : brachydiagonal, very perfect. Also fibrous; foliated or in scales; massive; reniform; stalac- titic. H. =5-5-5. G.=4-0-4*4. Lustre imperfect adamantine. Color yellowish, reddish, and blackish-brown. Often blood- red by transmitted light. Streak brownish-yellow ochre- yellow. Var. 1. In thin scale-like or tabular crystals, usually attached by one edge. 2. In acicular or capillary (not flexible) crystals, or slender prisms, often radiately grouped : the Needle- Ironstone (Nadeleuemteiii). It passes into (b) a variety with a velvety surface : the Przibramite (Sammelblende) of Przibram is of this kind. Other varieties are columnar or fibrous, scaly-fibrous, or feathery columnar ; compact massive, with a flat con- choidal fracture ; and sometimes reniform or stalactitic. Comp. H 2 FeO4=H 6 Fe06 + 2Fe0 3 Iron sesquioxide 89'9, water 10-1 = 100. Pyr., etc. In the closed tube gives off water and is converted into red iron sesquioxide. With the fluxes like hematite ; most varieties give a manganese reaction, and some treated in the forceps in O.F., after moistening in sulphuric acid, impart a bluish-green color to the flame (phosphoric acid). Soluble in hydrochloric acid. Obs. Found with the other iron oxides, especially hematite or limonite. Occurs at Eiser feld ; in Nassau ; at Zwickau in Saxony ; in Cornwall ; in Somersetshire, at the Providence iron mines. In the U. States, near Marquette, L. Superior; in Penn., near Easton; in California, at Burns Creek, Mariposa Co. Named Gothite after the poet-philosopher G-othe; and Pyrrliosiderite from nvppog, fire-red, and cidrjpos, iron. MANGANITE. Orthorhombic. 7 A 1= 99 40', O A l-l 147 9J' ; c : I : d 0-6455 : 1-185 : 1. Twins: twinn ing-plane 1-2 (f. 296, p. 96). Cleavage: i-l very perfect, 1 perfect. Crystals longitudinally striated, and often grouped in bundles. Also columnar; seldom granular; stalactitic. Ii.=4. G. =4-2-4-4. Lustre submetallic. Color dark steel-gray iron- black. Streak reddish-brown, sometimes nearly black. Opaque ; minute splinters sometimes brown by transmitted light. Fracture uneven. Comp. H 2 Mn0 4 =H 8 Mn06 + 2Mn0 3 =Manganese sesquioxide 89 "8 (=Mn 62 '5, O 27 '3), Pyr., etc In the closed tube yields water ; otherwise like braunite. Obs Occurs in veins traversing porphyry, at Ilefeld in the Harz ; in Thuringia ; Undenaea in Sweden; Christiansand in Norway; Cornwall, at various places; also in Cumberland, Devonshire, eta In Nova Scotia, at Cheverie, etc. In New Brunswick, at Shepody moun- tain, Albert Co., etc. LIMONITE. Brown Hematite. Brauneisenstein, Germ. Usually in stalactitic and botryoidal or mammillary forms, having a fibrous or subfibrous structure; also concretionary, massive; and occasionally earthy. OXYGEN COMPOUNDS. HYDROUS OXIDES. 281 H. = 5-5*5. G. =3-6-4:. Lustre silky, often subraetallic ; sometimes dull and earthy. Color of surface of fracture various shades of brown, com- monly dark, and none bright ; sometimes with a nearly black varnish-like*" exterior ; when earthy, brownish-yellow, ochre-yellow. Streak yellowish- brown. Var.- (1) Compact. Submetallic to silky in lustre ; often stalactitic, botryoidal, etc. (2) OcJireous or earthy, brownish-yellow to ochre-yellow, often impure from the presence of clay, sand, etc. (3) Bog ore. The ore from marshy places, generally loose or porous in texture, often petrifying leaves, wood, nuts. etc. (4) Brown day -ironstone, in compact masses, often in concretionary nodules, having a brownish-yellow streak, and thus distinguishable from the clay- ironstone of the species hematite and siderite ; it is sometimes (a) pisolitic, or an aggre- gation of concretions of the size of small peas (Bohnerz, Qerm.}\ or (b) oolitic. Comp. H 6 Fe 2 09=H 6 Fe06 + Fe03=Iron sesquioxide 85 '6, water 14'4=100. In the bog ores and ochres, sand, clay, phosphates, manganese oxides, and humic or other acids of organic origin are very common impurities. Fyr., etc. Like gothite. Some varieties give a skeleton of silica when fused with salt of phosphorus, and leave a siliceous residue when attacked by acids. Diff. Distinguished from hematite by its yellowish streak, inferior hardness, and its reac- tion for water. Does not decrepitate, B.B., like turgite. Obs. Limonite occurs in secondary or more recent deposit*, in beds associated at times with barite, siderite, calcite, aragonite, and quartz ; and often with ores of manganese ; also 'as a modern marsh deposit. It is in all cases a result of the alteration of other ores, through exposure to moisture, air, and carbonic or organic acids ; and is derived largely from the change of pyrite, siderite, magnetite, and various mineral species (such as mica, augite, horn- blende, etc. }, which contain iron in the protoxide state. Abundant in the United States. Extensive beds exist at Salisbury and Kent, Conn. , also in the neighboring towns of N. Y., and in a similar situation north; at Richmond and Lenox, Mass. ; in Vermont, at Bennington, etc. Limonite is one of the most important ores of iron. The pig iron, from the purer varieties, * obtained by smelting with charcoal, is of superior quality. That yielded by bog ore is what is termed cold short, owing to the phosphorus present, and cannot therefore be employed in the manufacture of wire, or even of sheet iron, but is valuable for casting. The hard and compact nodular varieties are employed in polishing metallic buttons, etc. MELANOSIDERITE. Near limonite, but containing 7 '39 p. c. SiO -2, perhaps as an impurity. Cooke regards it as a very basic silicate of iron. G. 3*39. Westchester, Penn. XANTHOSIDERITE. H 4 Fe05=FeO 3 81 '6, H 2 18'4100; or H 6 Fe0 8 (Ramm.). In fine needles. Color yellow, brown. Ilmenau ; the Harz. BEAUXITE. Occurs in concretionary grains. Color whitish to brown. Composition doubt- ful, perhaps Al(Fe)O 3 +2aq. Beaux, near Aries, France; near Lake Wochein, Styria (woch&i- nite) ; French Guiana. BRUOITE.* Khombohedral. K/\R = W 22*', O/\ = 119 39*'; c = 1-52078 (Hessenberg). Crystals often broad tabular. Cleavage: basal, eminent 492 493 Low's Mine, Texas. Wood's Mine, Texas. folia easily separable, nearly as in gypsum. Usually foliated massive, Also fibrous, fibres separable and elastic. 232 DESCRIPTIVE MINERALOGY. H. = 2-5. G. = 2-35-2-44. Lustre pearly on a cleavage-face, elsewhere between waxy and vitreous ; the fibrous silky. Color white, inclining to gray, blue, or green. Streak white. Translucent subtranslncent. Sectile. Thin laminae flexible. Comp. H 2 Mg0 2 Magnesia 69, water 31 = 100. Var. 1. Foliated. 2. Fibrous ; called nemalite, containing 4 or 5 p. c. of FeO. Pyr., etc. In the closed tube gives off water, becoming opaque and friable, sometimes turning gray to brown. B.B. infusible, glows with a bright light, and the ignited mineral reacts alkaline to test paper. With cobalt solution gives the violet-red color of magnesia. The pure mineral is soluble in acids without effervescence. DifF. Distinguished by its infusibility. Differs from talc in its solubility in acids. Obs. Brucite accompanies other magnesian minerals in serpentine, and has also been found in limestone. Occurs at Swinaness in Unst, Shetland Isles ; in the Urals ; at Goujot in France ; near Filipstadt in Wermland. It occurs at Hoboken, N. J. ; in Richmond Co. , N. Y. ; at Brewster, N. Y. ; at Texas, Pa. The fibrous variety (nemalite) occurs at Hoboken, and at Xettes in the Vosges. GIBBSITE. Monoclini.c (DesCl.). In small hexagonal crystals with replaced lateral edges. Planes vertically striated. Cleavage : basal or eminent. Occa- sionally in lamello-radiate spheroidal concretions. Usually stalactitic, or small mammilla^ and incrusting, with smooth surface, and often a faint fibrous structure within. H.=: 2-5-3-5. G. = 2-3-2-4. Color white, grayish, greenish, or reddish- white ; also reddish-yellow when impure. Lustre of O pearly ; of other faces vitreous ; of surface of stalactites faint. Translucent ; sometimes transparent in crystals. A strong argillaceous odor when breathed on. Tough. Var. 1. In crystals : the original hydraryillite. 2. Stalactitic ; gibbsite. Comp. H 8 A10 6 Alumina 65-5, water 34-5 = 100. Pyr., etc. In the closed tube becomes white and opaque, and yields water. B.B. infusible, whitens, and does not impart a green color to the flame. With cobalt solution gives a deep- blue color. Soluble in concentrated sulphuric acid. Diff. --Resembles chalcedony in appearance, but is softer. Obs. The crystallized gibbsite occurs near Slatoust in the "Oral; at Gumuchdagh, Asia Minor; on corundum at Unionville, Pa.; in Brazil. The stalactitic occurs at Richmond, Mass.; at the Clove mine, Duchess Co., N. Y.; in Orange Co., N. Y. Rose's hydrargillite (Urals, 1839) is identical with gibbsite (Torrey, 1822), and must receive this name. An uncertain mineral from Richmond afforded Hermann 38 p. c. of phosphoric acid, but a phosphate, if it really occurs there, is not gibbsite. PYROCHROITE. H 2 MnO 2 =Manganese protoxide 79 '8, water 20-2=100. Foliated. Color white. Mine of Paisberg. Filipstadt, Sweden. HYDROTALCITE from Snarum, Norway, and VOLKNERITE from the Urals, contain alumina, magnesia, and water with more or less carbon dioxide. Probably mixtures, containing brucite, gibbsite, etc. HOUGHITE from Oxbow and Rossie, N. Y., is a similar mineral derived from the alteration of spinel. NAMAQUALITE (Church}. A related mineral; from Namaqualand, So. Africa. FSILOMELANE.* Massive and botryoidal. Reniform. Stalactitic. H.=r5-6. G.=3-7-4-7. Lustre submetallic. Streak brownish-black, Binning. Color iron-black, passing into dark steel-gray. Opaque. OXYGEN COMPOUNDS. HYDROUS OXIDES. 283 Oomp. Somewhat doubtful. Contains manganese oxide, with varying amounts of baryta, and potash (lithia), and also water. General formula, according to Rammelsberg, R 5 9 =RG +4Mn0 2 , where R is Ka 2 , Ba or Mn. Analyses: O MnO BaO K 2 O H 2 O 1. Thuringen 11-48 6576 16 '59 5-25 CuO 0-59, CoO 0'79, CaO 0'51=100-7S Olschewsky. 2. Ilmenau 15 '82 77'23 0'12 5'29 CaO 0'91, CuO 0'40=99-77 Clausbruch. Pyr., etc. In the closed tube most varieties yield water, and all lose oxygen on ignition; with the fluxes reacts for manganese. Soluble in hydrochloric acid, with evolution of chlorine. Ob*. This is a common ore of manganese. It occurs in Devonshire and Cornwall ; at Ilefeld in the Harz ; also at Johanngeorgenstadt ; Schneeberg ; Ilmenau ; Siegen, etc. It forms mammillary masses at Chittenden, Irasburg, and Brandon, Vt. WAD. The manganese ores here included occur in amorphous and reniform masses, either earthy or compact, and sometimes incrusting or 'as stains. They are mixtures of different oxides, and cannot be considered chemical compounds or distinct mineral species. H.=0-5-6. G.=3-4-26 ; often loosely aggregated, and feeling very light to the hands. Color dull black, bluish or brownish-black. Comp., Var. Perhaps H 2 Mn 2 5 =:2Mn0 2 +aq (Rammelsberg), but in all cases mixed with Other ingredients. Varieties : (A) Manganesian ; (B) Cobaltiferous ; (C) Cupriferous. A. BOG MANGANESE. Consists mainly of manganese dioxide and water, with some iron sesquioxide, and of hen silica, alumina, baryta. B. ASBOLITE, or Earthy Cobalt, is wad containing cobalt oxide, which sometimes amounts to 32 p. c. LithiopTwritt, heterogenite, and rabdionite belong near here. C. LAMPADITE, or Cupreous Manganese. A wad containing 4 to 18 p. c. of copper oxide, and often cobalt oxide also. It graduates into black copper (Melaconite). G. =3' 1-8*2. Pyr., etc. Wad reacts like psilomelane. Earthy cobalt gives a blue bead with salt of phosphorus, and when heated in R. F. on charcoal with tin, some specimens yield a red opaque bead (copper). Cupreous manganese gives similar reactions, and three varieties give a strong manganese reaction with soda, and evolve chlorine when treated with hydrochloric acid. Obs. The above ores are results of the decomposition of other ores partly of oxides, and partly of manganesian carbonates. Wad or bog manganese is abundant in the counties of Columbia and Dutchess, JS". Y. There are large deposits of bog manganese at Blue Hill Bay, Dover, and other places in Maine. Earthy cobalt occurs at Rieehelsdorf in Hesse ; Saalf eld in Thuringia ; at Nertschinsk in Siberia ; at Alderly Edge in Cheshire. CHALCOPHANITE. Rhombohedral. In druses of minute tabular crystals ; also in stalacti- tic aggregates. H. =2 '5. G. 3 "907. Lustre metallic. Color bluish-black. Analysis gave MnO a 59*94, MnO 6 "58, ZnO 21-70, FeO 3 0'25, H a O 11-58=100-05. Composition 2Mn0 2 -H (Mn,Zn)0 + 2aq. If half the water were basic, the formula might be written 2RMn0 3 +aq, where R = Mn,Zn and H-,. B.B. becomes of a copper color, hence the name fcoAxof, brass, bronze, and or stalactitic surface ; also passing into translucent, and whitish. 10. Fiorite, Siliceous Sinter. Includes translucent to opaque, grayish, whitish, or brownish incrustations, porous to firm in texture ; sometimes fibrous -like or filamentous, and, when so, pearly in lustre, formed from the decomposition of the siliceous minerals of volcanic rocks about fumaroles, or from the siliceous waters of hot springs. It graduates at times into hyalite. Geyserite constitutes concretionary deposits about the Iceland and Yellowstone (pealite) geysers, presenting white or grayish, porous, stalactitic, filamentous, cauliflower- like forms; also compact-massive, and scaly - massi ve ; H. =5; rarely transparent, usually opaque ; sometimes falling to powder on drying in the air. 11. Float-stone. In light concretionary or tuberose masses, white or grayish, sometimes cavernous, rough in fracture. So light, owing to its spongy texture, as to float on water. The concretions sometimes have a flint-like nucleus. 12. Tripolite. Formed from the siliceous shells of Diatoms and other microscopic species, as first made known by Ehrenberg, and occurring in deposits, often many miles in area, either uncompacted, or moderately hard. Infusorial Earth, or Earthy Tripolite, a very fine-grained earth looking often like an eartny chalk, or a clay, but harsh to the feel, and scratching glass when rubbed on it. Pyr., etc. Yields water. B.B. infusible, but becomes opaque. Some yellow varieties, containing iron, turn red. Oba. Occurs filling cavities and fissures or seams in igneous rocks, porphyry, and some metallic veins. Also imbedded, like flint, in limestone, and sometimes, like other quartz concretions, in argillaceous beds ; also formed from the siliceous waters of some hot springs ; also resulting from the mere accumulation, or accumulation and partial solution and solidifi- cation, of the siliceous shells of infusoria which consist essentially of opal-silica. Precious opal occurs in Hungary ; in Honduras ; and Mexico. Fire opal occurs at Zimapaii in Mexico ; Faroe ; near San Antonio, Honduras. Common opal is abundant at Telkebanya in Hungary; in Moravia; in Bohemia ; Stenzelberg in the Siebengebirge ; Faroe, Iceland; the Giant's Causeway, at many localities. In U. S., hyalite occurs sparingly in N. York, at the Phillips ore bed, Putnam Co. ; in Georgia, in Burke and Scriven Cos.; in Washington Co., good fire opal. At the Geysers on the Fire Hole river, Yellowstone Park, geyserite is abundant. The precious opal, when large, and exhibiting its peculiar play of colors in perfection, is a gem of high value. It is cut with a convex surface. MELANOPHLOGITE (Lasauix). Occurs in minute, colorless, cubes coating sulphur crystal! from Girgeuti, Sicily. Contains SiO 2 86 '3 p. c., SO 3 7 , H 2 O 2 '9 ; chemical nature doubt* ful. Turns black upon ignition, hence the name. 19 290 DESCRIPTIVE MINERALOGY. II. TEENAEY OXYGEN COMPOUNDS. 1. SILICATES. A. ANHYDROUS SILICATES. a. BISILICATES. GENERAL FORMULA RSiO 3 . (a) Amphibole Group. Pyroxene Section. ENSTATTTE. BRONZITE. Protobaetite. Orthorhombic. 508 1 A 1= 88 16' and 91 44:' (Breitenbach meteorite, v. Lang}-, c:t>:d = 0-58853 : 1-03086 : 1. Cleavage: /, easy ; i-i, i-i, less so. Sometimes a fibrous appearance on the cleavage-surface. Also massive and lamellar. H.=5-5. G.=3-l-3-3. Lustre a little pearly on cleavage-surfaces to vitreous ; often metalloidal in the bronzite variety. Color grayish- white, yellowish-white, greenish- white, to olive-green and brown. Streak 1111- colored, grayish. Double refraction positive ; optic- axial plane brachydiagonal ; axes very divergent. Bamle Norway Comp., Var. MgSiO s = Silica 60, magnesia 40 = 1 00 ; also (Mg, Fe) SiO 3 . Var. 1. With little or no iron; Emtatite. Color white, yellowish, grayish, or greenish- white; lustre pearly- vitreous ; G. =3 '10-3 '13. Chladnite, which makes up 90 p. c. of the Bishopville meteorite, belongs here and is the purest kind ; Victorite (Meunier), from the Deesa (Chili) meteoric iron is probably identical. 2. Ferriferous ; Bronzite. Color grayish -green to olive-green and brown; lustre of cleav- age-surface adamantine pearly to subtnetallic or bronze-like. The ratio of Mg : Fe varies from 11 : 1 to 3 : 1. Analysis of bronzite from Leiperville by Pisani, Si0 2 57-08, A1O 3 0'28, FeO 5-77, MgO 35 -59, H 2 O 0-90=99-62. Pyr., etc. B.B. almost infusible, being only slightly rounded on the thin edges ; F.=6. Insoluble in hydrochloric acid. Diff. Distinguished by its infusibility from varieties of amphibole, which it resembles. Obs. Occurs near Aloysthal in Moravia ; in the Vosges ; at Kupf erberg in Bavaria ; at Baste in the Harz (Protobastite) ; in the chrysolite bombs in the Eifel ; in immense crystals with apatite, near Bamle, Norway. In Pennsylvania, at Leiperville and Texas ; at Brewster, N. Y. Bronzite is quite common in meteorites. DesCloizeaux first defined the limits of this species, as here laid down. Named from 'fva-rdr-ns, an opponent, because so refractory. The name bronzite has priority, but a bronze lustre is not essential, and is far from universal. HYPERSTHENB. Orthorhombic. /A 1= 91 32, DesCloizeaux (Mt. Dor6); 91 40' T. Eath (amblystegite). Cleavage : i-l perfect, 1 and i-l distinct but inter rupted. Usually foliated massive. H.=5-6. Gr.= 3-392. Lustre somewhat pearly on a cleavage-surface, and sometimes a little metalloidal ; often with a peculiar iridescence due OXYGEN COMPOUNDS ANHYDROUS SILICATES. 291 509 to the presence of minute enclosed tabular crystals (brookite?) in parallel position (Kosmann). Color dark brownish -green, gray- ish-black, greenish- black, pinchbeck-brown. Streak S*ayish, brownish-gray. Translucent to nearly opaque, rittle. Optic-axial plane brachydiagonal ; axes very divergent; bisectrix negative. if Me. Dora. Comp. (Mg-,Fe}Si0 3 with Fe : Mg 1 : 5, 1:3, etc. If Fc to Mg=l : 2 the formula requires SiO 2 54 -2, FeO 21-7, MgO 24-1 = 100. Pyr., etc. B.B. fuses to a black enamel, and on charcoal yields a magnetic mass. Partially decomposed by hydrochloric acid. Obs. Hypersthene occurs at Isle St. Paul, Labrador in Canada ; at the Isle of Skye ; in Greenland ; Norway ; Ronsberg in Bohemia ; the Tyrol ; Elfdalen in Sweden ; Laacher See (amblystegite] ; Voigt- land ; in trachyte of Mt. Dore, Auvergne. In chemical composition, emtatite (and bronzite), and hypersthene belong together, since they grade insensibly into each other ; and in crystalline form they are identical. The essential difference between them, according to DesCloizeaux, lies in the axial dispersion which is uniformly p < v f 01 enstatite, and p > v f or hypersthene. DIACLASITE. Near bronzite ; differs in optical characters. (Mg,Fe,Ca)Si0 3 . Harzburg; Guadarrama, Spain. WOLLASTONITE. Tabular Spar. Tafelspath, Gem. Monoclinic. O= 69 48', I A 1 = 87 28', A 2-i = 137 48' ; c : I : d = 0-4338 : 0-89789 : 1. Fig. 510 in the pyroxene or normal position, but wi" 1 "* 1 the edge O fi-i the obtuse edge ; f. 511 in the position given the crys- tals u\ authors who make i-i the plane O, and 24 the plane"/. O A 1-^ = 160 30', A l-i = 154 25', i-i A - 2 = 132 54', i-i A 2 = 93 52'. Rarely in distinct tabular crystals. Cleavage : most distinct ; i-i less so ; l-i and l-i in traces. Twins : twinning-plane i-i. Usually cleav- able massive, with the surface appearing long fibrous, fibres parallel or reticulated, rather strongly coherent 510 511 H.= 4-5-5. G.== 2-78-2 '9. Lustre vitreous, inclining to pearly upon the faces of perfect cleavage. Color white, inclining to gray, yellow, red, or brown. Streak white. Subtransparent translucent. Fracture uneven, sometimes *ery tough. Optic-axial plane i-i ; divergence 70 40' for the red rays ; bisectrix of the acute angle negative ; inclined to a normal to i-i 57 48', and to a normal to O 12/De801. 292 DESCRIPTIVE MINERALOGY. Comp. CaSi0 3 =Silica 517, lime 48 '3=100. Pyr., etc. In the matrass no change. B.B. fuses easily on the edges; with some soda, a blebby glass, with more, swells up and is infusible. With hydrochloric acid gelatinizes ; most varieties effervesce slightly from the presence of calcite. Diff. Differs from asbestus, and tremolite in forming a jelly with acids, as also by its more vitreous fracture ; fuses less readily than natrolite and scolecite ; when pure does not effer- vesce with acids like the carbonates. Obs. Wollastonite is found in regions of granite and granular limestone ; also in basalt and lavas. Occurs in Hungary ; in Finland ; and in Norway ; at Gockum in Sweden ; in the Harz ; at Auerbach, in granular limestone ; at Vesuvius. In the U. S., in H. York, at Wills- borough ; at Lewis ; Diana, Lewis Co. In Penn. , Bucks Co. At the Cliff Mine, Keweenaw Point, Lake Superior. In Canada, at Grenville. PYROXENE. Monoclinic. O = 73 59', /A / = 87 5', A 24 = 131 IT ; c : b : d = 0-5412 : 0-91346 : 1. 0/\I= 100 57', A l-i = 155 51', O A l-i = 148 35', 0A -1 = 146 9', 6>Al = 137 49', -1 A -1 = 131 24'. Cleavage : / rather perfect, often interrupted ; i-i sometimes nearly per- 517 lit 519 feet ; i-i imperfect ; sometimes easy. Crystals usually thick and stout. Twins: t winning-plane i-i (f. 521). Often coarse lamellar, in large masses, parallel to O or i-i. Also granular, particles coarse or line ; and fibrous, fibres often fine and long. H.=5-6. G. = 3-23-3-5. Lustre vitreous, inclining to resinous ; some pearly. Color green of various shades, verging on one side to white or grayish- white, and on the other to brown and black. Streak white to gray and grayish-green. Transparent opaque. Fracture conchoidal uneven. Brittle. In crystals from Fassa, optic-axial plane i-\\ divergence 110 to 113; bisec- inclined 51 6' to a normal to i4 and 22 C trix of the acute angle positive, 55' to a normal to O, DesCl. OXYGEN COMPOUNDS ANHYDROUS SILICATES. 293 Comp., Var A bisilicate, having the general formula RSi0 3 , where E may be Ca,Mg, Fe,Mn, sometimes also Zn,Kao,Na 2 . Usually two or more of these bases are present. The first three are most common ; but calci im is the only one that is present always and in large percentage. Besides the substitutions of the above bases for one another, these same basea are at times replaced by Al,Fe,Mn, though sparingly, and the silicon occasionally by alumi- num. The varieties proceeding from these isomorphous substitutions are many and diverse ; and there are still others depending on the state of crystallization. The foliated and fibrous kinds early received separate names, and for a while were regarded as distinct species. Fibrous or columnar forms are very much less common than in hornblende, and lamellar or foliated kinds more common. The crystals are rarely long and slender, or bladed, like those of that species. The most prominent division of the species is into (A) the non-aluminous ; (B) the alumi- nous. But the former of these groups shades imperceptibly into the latter. These two groups are generally subdivided according to the prevalence of the different protoxide elements. Yet here, also, the gradation from one series to another is in general by almost insensible shades as to composition and chemical characters, as well as all physical qualities. I. CONTAINING LITTLE OH NO ALUMINA. 1. Lime-Magnesia Pyroxene; MALACOLITE. Diopside, Alalite, White Coccolite. Color white, yellowish, grayish- white to pale green. In crystals: cleavable and granular massive. Sometimes transparent and colorless. G. =3'2-3'38. Formula, CaMgSi 2 O 6 Silica 55 '6, mag- nesia 18 '5, lime 25-9. Sometimes Ca : Mg=l : 2 ; less than 4 p. c. of iron are present. 2. Lime- Magnesia- Iron Pyroxene ; SAIILITE. Color grayish -green to deep green and black ; sometimes grayish and yellowish-white. In crystals ; also cleavable and granular massive G. =3 25-3-4. Named from Sala in Sweden, one of its localities, where the mineral occurs in masses of a grayish-green color, having a perfect cleavage parallel to the basal plane (0). Formula (Ca,Mg,Fe)SiO 3 . The ratio of Ca : Mg : Fe varies much, =3 : 3 : 1, 2 : 2 : l,etc. The ratio=4 : 3 : 1, corresponds to silica 53'7, magnesia 13 4, lime 24*9, iron protoxide 8'0=lO(X DIALLAGE. Part of the so-called diallage, or thin foliated pyroxene, belongs here, and the rest under the corresponding division of the aluminous pyroxenes. Color grayish-green to bright grass-green, and deep green; lustre of cleavage surface pearly, sometimes metalioidal or brassy. H.=4. G-.=3'2-3'35. Composition near the preceding ; analysis by vom Rath, Neurode, Si0 2 53 '60, A10 3 1'99, FeO 8 '95, MnO 0'28, MgO 13'08, CaO 21'0(>, H.O p-8t>=99'82. With this variety belongs part also of what has been called hypersthene and bronzite the part that is easily fusible. Common especially in serpentine rocks. Named from dici'Mayy, dif- ference, in allusion to the dissimilar cleavages. 3. Iron- Lime Pyroxene. HEDENBERGITE. Color black. In crystals, and also lamellar massive ; cleavage easy parallel to i-i. G-. =3 '5-3 -58. Formula CaFeSi.jO 8 (Mg being absent) ^Silica 4839, lime 2218, iron protoxide 29 '43 =100. Asteroite is a similar pyroxene con- taining also Mn (Igelstrom), Sweden. 4. Lime-Iron-Manganese-Zinc Pyroxene ; JEPFERSONITE. Color greenish-black. Crystals often very large (3-4 in. thick), with the angles generally rounded, and the faces uneven, as if corroded. G.=3'36. Analysis, Franklin, N. J., by Pisani, SiO a 45-95, itt0 3 0-85, FeO 8-91, MnO 10-20, ZnO 1015, CaO 21-55, MgO 3 -61, ign 0'35=101-57. II. ALUMINOUS. Aluminous Lime-Magnesia Pyroxene; LEUC AUGITE (Dana). Color white or grayish. Analysis, Bathurst, C., by Hunt, SiO, 51 '50, A1O 3 6-15, FeO 3 0'35, MgO 17 '69, CaO 23 '80 H.O 1-10= 100-59. Looks like diopside. H.=6-5. G.=319. Hunt. Named from Aewco;, white. Aluminous \time-Magnesia.-Iron Pyroxene; FASSAITE, AUGITE. Color clear deep-green to greenish-black and black ; in crystals, and also massive ; subtranslucent to opaque. G. =3 25-3 -5. Contains iron, with calcium and magnesium, also aluminum. Analysis of augite from Montreal by Hunt, SiO 2 49-40, A10 3 G"70, ^eO 3 7'83, MgO 13-06, CaO 21 '88, Na 2 0'74, H a O 0-50=100- 11. a. Fassaitd (or Pyrgom). Includes the green kinds found in metamorphic rocks. Named from the locality at Fassa in Piedmont, which affords deep-green crystals, sometimes pistachio- green, like the epidote of the locality. b. Augite. Includes the greenish or brownish-black and black kinds, occurring mostly in eruptive rocks, but also in metamorphic. Named from av-yq, lustre. 294 DESCRIPTIVE MINERALOGY. Pyr., etc. Varying widely, owing to the wide variations in composition in the different varieties, and often by insensible gradations. Fusibility, from the almost infusible dialiage to 3 '75 in diopside ; 8 "5 in sahlite ; 3 in jeffersonite and augite ; 2 '5 in hedenbergite. Va- rieties rich in iron afford a magnetic globule when fused on charcoal, and in general their fusibility varies with the amount of iron. Jeffersonite gives with soda on charcoal a reaction for zinc and manganese ; many others also give with the fluxes reactions for manganese. Most varieties are unacted upon by acids. Diff. See Amphibole, p. 297. Obs. Pyroxene is a common mineral in crystalline limestone and dolomite, in serpentine, and in volcanic rocks ; and occurs also, but less abundantly, in connection with granitic rocks and metamorphic schists. The pyroxene of limestone is mostly the white and light-green or gray varieties ; that of most other metamorphic rock, sometimes white or colorless, but usually green of different shades, from pale green to greenish- black, and occasionally black; that of serpentine is sometimes in fine crystals, but often of the foliated green kind called diallage ; that of eruptive rocks is the black to greenish-black augite. Prominent foreign localities are : malacolite (diopaide], Traversella, Ala in Piedmont ; Sala, Tunaberg. Sweden ; Pargas ; Achmatovsk ; etc. Sahlite, Sala ; Arendal ; Degeroe ; Schwarzen- berg; etc. Hedenbergite, Tunaberg; Arendal Augite, Fassathal ; Vesuvius; etc. inmost dolerytio igneous rocks. In N. America common (see list of localities at the close of the volume). Some localities are: In Ma&s., at the Bolton quarries. In Conn., at Canaan. In N. York, at Warwick, Mon- roe, Edenville, Diana. In N. Jersey, in Franklin. In Perm., near Attleboro'. In Canada, at Bytown, at Calumet I. , at Grenville. . ACMITE. Monoclinic. In slender pointed crystals (hence name) in quartz. H. =6. G-. = 3 -2-3 '53. Color brownish to reddish-brown, in the fracture blackish-green. Opaque. Frac- ture uneven. Brittle. RSiO 3 ,R=Na 2 ,Fe, or Fe(Fe=3R); analysis by Rammelsberg, SiO a 51-66, FeO 3 28'28, FeO 5 '23, MnO 0-69, Na 2 12 46, K 3 O 0'43, TiO I'll, ign 0'39=100'25. Kongsberg, Norway. ^GIBITE. Near pyroxene in form, but contains alkalies. H. =5-5-6. G.=3'45-3'58. Color greenish-black. Subtranslucent to opaque. Analysis Ramm., Brevig, SiO-> 50 '25, A10 S 1-22, FeO 8 22-07, FeO 8-80, MnO 1'40, CaO 5 '47. MgO 1-28, Na.O 9 29, K 2 O 94 =100 '72. Also from Magnet Cove, Arkansas. RHODONITE. Triclinic, but approximately isomorphous with pyroxene. Cleavage : 1 perfect ; 'O less perfect. Usually massive. H.=5*5-6-5. Gr.= 3-4-3-68. Lustre vitreous. Color light brownish-red, flesh-red, sometimes greenish or yellowish, when impure ; often black outside from ex- posure. Streak white. Transparent opaque. Frac- ture conchoidal uneven. Very tough when massive. Comp., Var. MnSiO 3 = Silica 45*9, manganese protoxide 54 -1 = 100. Usually some Fe and Ca, and occasionally Zn replace part of the Mn. Ordinary, (a) Crystallized. Either in crystals or foliated. The ore in crystals from Paisberg, Sweden, was named Paisbergite under the idea that it was a distinct species, (b) Granular massive. Calciferous ; BUSTAMITE. Contains 9 to 15 p. c. of lime replacing part of the manganese. Often also impure from the presence of cal- cium carbonate, which suggests that part of the lime replacing the manganese may have come from partial alteration. Grayish-red. Zinciferous ; FOWLEHITE. In crystals and foliated, the latter looking much like cleavable red feldspar ; the crystals sometimes half an inch to an inch through. JA 7=86 30', Torrey. G.= 3 '44, Thomson. Pyr., etc. B.B. blackens and fuses with slight intumescence at 2*5 ; with the fluxes givea reactions for manganese ; fowlerite gives with soda on charcoal a reaction for zinc. Slightly acted upon by acids. The calciferous varieties often effervesce from mechanical admix- ture with calcium carbonate. In powder, partly dissolves in hydrochloric acid, and the in soluble part becomes of a white color. Darkens on exposure to the air, and sometimes becomes nearly black. Obs. Occurs at Longban, near Ptiilipstadt in Sweden ; also in the Harz ; in the district of OXYGEN COMPOUNDS ANHYDROUS SILICATES. 295 Katherinenberg in the Ural ; in Cornwall, etc. Occurs in Warwick, Mass. ; Blue Hill Bay, Maine ; near Hinsdale, N. H. ; fowlerite (keatingine) at Hamburg and Sterling, New Jersey. Named from podov, a rose, in allusion to the color. BABINGTONITE. Triclinic. 9RSi0 3 +FeSi 3 9 , with R=Fe(Mn) : Ca(Mg)=2 : 3 (Eamm.). Analysis, Rammelsberg, SiO 2 51 '22, Fe0 3 H'OO, FeO 10 '26, MnO 7 "91, MgO 077, Cap 19*32, ign=0-44 IGO'92. Color greenish-black. Arendal; Nassau; Devonshire; Baveno. SPODUMENE.* Monoclinic. 6"= 69 40' 7A/= 87, A 24 = 130 30'. Crystals large. Cleavage: i-i very perfect; / also perfect; 14 in traces ; in striae on i-\. Twins : twinning-plane i-i. Also massive, with broad cleavage surface. H.:=6-5-7. G.:= 3- 13-3-19. Lustre pearly. Cross fracture vitreous. Color grayish-green, passing into greenish-white and grayish- white, rarely faint-reddish. Streak mi colored. Translucent subtranslucent. Frac- ture uneven. Oomp 3RSi0 3 +4AlSi 3 9 ; R=Li 2 mostly. Silica 64 '2, alu- mina 29-4, lithia 6 -4= 100. Sometimes Li : Na(K) = 20 : 1, Ramm. Pyr., etc. B. B. becomes white and opaque, swells up, imparts a purple red color (lithia) to the flame, and fuses at 3 5 to a clear or white glass. The powdered mineral, fused with a mixture of potassium bisulphate and fluor on platinum wire, gives a more in- tense lithia reaction. Not acted upon by acids. Diflf. Distinguished by its perfect orthodiagonal, as well as prismatic, cleavage ; has a higher specific gravity and more pearly lustre than feldspar or scapolite. Gives a red flame B.B. Obs. Occurs on the island of Tito, Sweden; near Sterzing and Lisens in the Tyrol; at Killiney Bay, near Dublin, and at Peterhead in Scotland. At Goshen, Mass. ; also at Chesterfield and Norwich, Mass. ; at Windham, Maine ; at Winchester, N. H. ; at Brookfield, Ct. PETALITE. 3Li 2 Si 2 O 5 +4A]Si 6 15 --Silica 77'97, alumina 17'79, lithia 3'57, soda 067= 100. Ramm. Q. ratio Li : Al : Si=l : 4 : 20, or for bases to silicon^! ; 4. H.=6-6'5. O. Colorless; white. Uto, Sweden; Elba (castorite) ; Bolton, Mass. Norwich, Mass. Ampliibole Section. ANTHOPHYLLITE. Orthorhombic. 7A/= 125 to 125 25'. Cleavage: 14 perfect, 1 lesa so, i-l difficult. Commonly lamellar, or fibrous massive ; fibres often very slender. H.=5'5. Gr.= 3-1-3-2. Lustre somewhat pearly upon a cleavage sur- face. Color brownish-gray, yellowish-brown, brownish-green, sometimes submetallic. Streak nncolored or grayish. Translucent to subtranslucent. Brittle. Double refraction positive; optical axes in the brachydiagonal section. 296 DESCRIPTIVE MINERALOGY. Oomp (Fe,Mg)Si0 3 , Fe : Mg=l : 3=Silica 55 -5, magnesia 27*8, iron protoxide IQ'7 100. Pyr., etc. B.B. fuses with great difficulty to a black magnetic enamel; with the fluxes gives reactions for iron ; unacted upon by acids. Obs. Occurs near Kongsberg in Norway, and near Modum. Also at Hermannschlag, Moravia. Anthophyllite Taears the same relation to the Amphibole Group that enstatite and hyper- sthene do to the Pyroxene Group. KUPFPERITE. Probably MgSiO 3 , with a little Fe. 1 A 7=124 30', hence an enstatite-Jiorn- blende. Color emerald-green (chrome). Tunkinsk Mts. , Miask. Analysis of a similar min- eral from Perth, Canada, Thomson, Si0 2 57-60, A10 3 3 "20, FeO 210, MgO 29" 30, CaO 3 -55, ign. 3-55=99 30. AMPHIBOLE.* HORNBLENDE. Monoclinic. O= 75 2', I/\ 1= 124 30', 0Al-i = 164 1.0', c : I : d =0-5527 : 1*8825 : 1. Crystals sometimes stout, often long and bladed. Cleavage : / highly perfect ; i-i, i-l sometimes distinct. Lateral planes often longitudinally striated. Twins: i winning-plane i-i^ as in f. 527 (simple form f. 526), and 530. Imperfect crystallizations : fibrous or columnar, coarse or fine, fibres often like flax ; sometimes lamellar ; also granular massive, coarse or fine, and usually strongly coherent, but sometimes friable. 525 528 530 H.=5-6. G.=2'9-3'4. Lustre vitreous to pearly on cleavage-faces; fibrous varieties often silky. Color between black and white, through vari- ous shades of green, inclining to blackish-green. Streak uncolored, or paler than color. Sometimes nearly transparent ; usually subtranslucent opaque. Fracture subconchoidal, uneven. Bisectrix, in most varieties, inclined about 60 to a normal to O, and 15 to a normal to i-i\ and double refraction negative. Comp., Var. General formula RSi0 3 , as for pyroxene. Aluminum is present in most amphibole, and when so it usually replaces silicon. R may correspond to two or more of the basic elements Mg,Ca,Fe,Mn,Na 2 ,K 2 ,H.,; and ft to 7\:1, Fe or Mn. Fe sometimes replaces silicon, like Al. Much amphibole, especially the aluminous, contains some fluorine. The base calcium is absent from some varieties, or nearly so. The varieties of amphibole are as numerous as those of pyroxene, and for the same reasons; and they lead in general to similar subdivisions. OXYGEN COMPOUNDS ANHYDROUS SILICATES. 297 I. CONTAINING LITTLE on NO ALUMINA. Magnesia-. Lime Amphibole ; TREMOLITE. Grammatite. Colors white to dark-gray. Iq distinct crystals, either long bladed or short and stout ; long and thin columnar, or fibrous ; also compact granular massive. 1 A /=124 30'. H. =5"0-6'5. G. =29-3*1. Sometimes transparent and colorless. Contains magnesia and lime with little or no iron ; formula (Ca. Mg)Si0 3 , Ca : Mg=l : 3 = Silica 57*70, magnesia 28 85, lime 13'35 = 100. Named Tremoltteby Pini, from the locality at Tremola in Switzerland. NEPHRITE. In part a tough, compact, fine grained tremolite, having a tinge of green or blue, and breaking with a splintery fracture and glistening lustre. H. =6-6*5. G. =2 96-3*1. Named from a supposed efficacy in diseases of the kidney, from ve^pdf, kidney. It occurs usually associated with talcose or magnesian rocks. Nephrite or jade was brought in the form of carved ornaments from Mexico or Peru soon after the discovery of America. A simi- lar stone comes from China and New Zealand. A nephrite-like mineral, called bowenite, from Smithfield, R. I., having the hardness 5-5 is serpentine in composition. The jade of de Saussure is the saussurite (see under ZOISITE) of the younger de Saussure. Another aluminous jade has been called jadeite (q. v.) by Damour. Magnesia- Lime -Iron Amphibole; ACTINOLITE. Strahlstein, Germ. Color bright-green and grayish -green. In crystals, either short or long-bladed, as in tremolite ; columnar or fibrous; granular massive. G. =3-32. Sometimes transparent. Contains magnesia and lime, with some iron protoxide, but seldom more than 6 p. c. ; formula (Ca,Mg. Fe)Si0 3 . The variety in long bright-green crystals is called glassy actinolite ; the crystals break easily across the prism. The fibrous and radiated kinds are often called asbestiform actinolite and radiated actinolite. Actinolite owes its green color to the iron present. Iron-Magnesia Amphibole ; CUMMINGTONITE. Color gray to brown. Usually fibrous or fibro-lamellar, often radiated. G. =3 '1-3 '32. Contains much iron, with some magnesia, and little or no lime. Formula (Fe,Mg)SiO 3 . Named from the locality, Cummington, Mass, ASBKSTUS. Tremolite, actinolite, and other varieties of amphibole, excepting those (Con- taining much alumina, pass into fibrous varieties, the fibres of which are sometimes very long, fine, flexible, and easily separable by the fingers, and look like flax. These kinds, like the corresponding of pyroxene, are called asbestus (fr. the Greek for incombustible). The colors vary from white to green and wood- brown. The name amianthus is now applied usu- ally to the finer and more silky kinds. Much that is so called is chrysolite, or fibrous serpen- tine, it containing 12 to 14 p. c. of water. Mountain leather is a kind in thin flexible sheets, made of interlaced fibres ; and mountain cork (Bergkork) the same in thicker pieces ; both are so light as to float on water, and they are often hydrous. Mountain wood (Bergholz, Holzasbest, Germ ) is compact fibrous, and gray to brown in color, looking a little like dry wood. II. ALUMINOUS. Aluminous Magnesia- Lime Amphibole. (a) EDENITE. Color white to gray and pale-green, and also colorless ; G. =3 '0-3-059, Ram in. Resembles an thophyllite and tremolite. Named from the locality at Edenville, N. Y. (for analysis, see below.) To this variety belong various pale-colored amphiboles, having less than five p. c. of oxide of iron. (b) SMARAGDITE Saussure. A thin -foliated variety, of a light grass-green color, resembling much common green diallage. According to Boulanger it is an aluminous magnes a-lime amphibole, containing less than 3 p. c. iron protoxide, and is hence related to edenite and the light green Pargas mineral. DesCloizeaux observes that it has the cleavage, and appar- ently the optical characters, of amphibole. H.=5; G.=3. It forms, along with whitish or gree*nish saussurite, a rock. irgasite is usually made to include green and bluish-green in stout lustrous crystals, or granular; and liornblende the greenish-black and black kinds, whether in stout crystals or long bladed, columnar, fibrous, or massive granular. But no line can be drawn between them. Pargasite occurs at Pargas, Finland, in bluish -green and grayish-black crystals. Composition shown by the following analyses by Rammelsberg ; (1) from Edenville ; (3) Wolfaborg, Bohemia ; (3) Brevig. 298 DESCRIPTIVE MINERALOGY. Si0 3 A1O 8 Fe0 3 FeO MnO MgO CaO Na,O K 2 () H 2 0(ign) (1) 51-67 5-75 2-86 23M7 12-42 0-75 0'84 0-46^98-12 (2) 41-98 14-31 5-81 7'18 14-06 12-55 1-64 1'54 0'26=99'10 (8) 43-28* 6-31 6-62 2172 1-13 3-62 9 '68 314 2 -65 "48 =98 63 * With I'Ol TiO 2 . Pyr., etc. The observations under pyroxene apply also to this species, it being impossible to distinguish the varieties by blowpipe characters alone. Diflf. Distinguished from pyroxene (and tourmaline) by its distinct prismatic cleavage, yielding an angle of 124. Also in colored varieties by its dichroism, when examined in thin sections. Fibrous and columnar forms are much more common than with pyroxene, lamellar and foliated forms rare. Crystals often long, slender, or bladed. Differs from the fibrous zeolites in not gelatinizing with acids. Isomorphous and Dimorphous relations to Pyroxene. The analogy in composition between pyroxene and hornblende has been abundantly illustrated. They have the same general formula ; and under this formula there is but one difference of any importance, viz. , that lime is a prominent ingredient in all the varieties of pyroxene, while it is wanting, or nearly so, in some of those of hornblende. The analogy between the two species in crystallization, or their essential isomorphism, was pointed out by G. Rose in 1831, who showed that the forms of both were referable to one and the same fundamental form. The prism / of horn- blende corresponds in angle to e'-2 of pyroxene. Calculating from the angle I A /in pyroxene, 87 5', the angle of i-2 is precisely 124 J 30 , or the angle /A /in hornblende. But while thus isomorphous in axial relations or form, they are also dimorphous. For ( 1 ) the cleavage in pyroxene is parallel to the prism of 87 5', and in hornblende to that of 124|. (2) The occur- ring secondary planes of the latter are in general diverse from those of the former, so that the crystals differ strikingly in habit or system of modifications. Moreover, in pyroxene colum- nar and fine fibrous forms are uncommon ; in hornblende, exceedingly common. (3) The several chemical compounds under pyroxene have one-tenth higher specific gravity than the corresponding ones under hornblende. Vom Rath has described the occurrence of minute crystals of hornblende in parallel posi- tion upon crystals of pyroxene (Vesuvius), and in consequence of the relation between the two fonns, thus brought out, suggests a change in the commonly accepted fundamental form of the latter. ( Jahrb. Min., 1876.) This association of crystals of the two species in parallel position is not uncommon. Obs. Amphibole occurs in many crystalline limestones, and metamorphic granitic and schistose rocks, and sparingly in serpentine, and volcanic or igneous rocks. Tremolite, the magnesia-lime variety, is especially common in limestones, particularly magnesian or dolomi- tic ; actinolite, the magnesia lime-iron variety, in steatitic rocks; and brown, dark-green, and black hornblende, in chlorite schists, mica schist, gneiss, and in various other rocks (syenyte, dioryte, etc.), of which it forms a constituent part. Asbestus is often found in con- nection with serpentine. Hornblende is often disseminated in black prismatic crystals through trachyte, and also through other igneous rocks, especially the feldspathic kinds. AuBsig and Teplitz in Bohemia, Tunaberg in Sweden, and Parg-as in Finland, afford fine specimens of the dark-colored hornblendes. Actinolite in the Zillerthal; tremolite at St. Gothard, in granular limestone or dolomite ; the Tyrol ; the Bannat, etc. Asbestus is found in Savoy, Salzburg, the Tyrol; in the island of Cor.-ica. Some localities in the U. S. are : Carlisle, Pelham, etc., Mass., cummingtonite at Cummington. In Conn., white crystals of tremolite in dolomite, Canaan. In N. York, Willsboro', St. Lawrence Co. ; Warwick ; with pyroxene at Edenv'le; near Amity ; in Rossie ; the variety pargaxite in large white crystals at Diana, Lewis Co. In Penn., actinolite at Mineral Hill, in Delaware Co.; at Unionville. In Maryland, actinolite and asbestus at the Bare Hills ; assbestus at Cooptown. HEXAGONITE. Described as a new mineral by Goldsmith, but shown by Koenig to be only a variety of tremolite. From Edwards. St. Lawrence Co., N. Y. ARFVEDSONITE:^ Near hornblende, but contains alkalies. Analysis, Ramm., Greenland. SiO a 51-22, A1O 3 tr.. F-e0 3 2375, FeO 7 -80, MuO 112, CaO 2'08, MgO 0-90, Na 2 O 10-58, K,O 68, ign 0'16=98'29. Greenland ; Brevig ; Arendal. CROCIDOLITE. Composition uncertain, near arfvedsonite. Analysis, Stromeyer, SiO 2 51-22, FeO 34 -08, MnO O'lO, MgO 2 -48, CaO 0'03, Na.O 7'07, H.O 4'80=99-?8. Fibrous, asbestus-like. Sometimes altered to " Faserquarz." Color lavender-blue or leek-green. Orange river, So. Africa. Vosges Mts. GASTALDTTE. Monoclinic. Cleavage prismatic, lf\l = 124 25' (like amphibole). H. = 6-7. G.=3'044. Color dark-blue to azure-blue Streak greenish-blue. Q. ratio R : ft : Si =1:2:6; formula R 3 M,Si.O.7, with R=Fe.Mg.Ca Na,. Analysis, Struver, SiO 2 5855, A1O 3 21-40, FeO 9 '04, MgO 8 92, CaO 2 03, Na.O 4-77, K,0 tr=9971. Occurs in chlorite late in the valleys of Aosta and Looano. GLAUCOPHAN E.- Monoclinic. Cleavage prismatic, 2 A /=124 51'. H. =6'5. G. 3 -0907 OXYGEN COMPOUNDS ANHYDROUS SILICATES. 299 Color blue, bluish-black. Q. ratio for bases to silicon 1 : 2. Analysis from Zermatt by Bodewig, SiO, 57-81, A10 3 12'03, Fe0 3 2-17, FeO 5 '78, MgO 13'07, CaO 2'20, Na.O 7'33 ^100-45. Also from island of Syra. WICHTISITE, Finland. Perhaps identical with glaucophane. BERYL.* Hexagonal. 6>Al = 150 3'; c = 0499. Habit prismatic, the prism often vertically striated. Cleavage : basal imperfect ; lateral indistinct. Occasionally coarse columnar and large granular. H. = 7-5-8. G. = 2-63-2-76. Lustre vitreous, sometimes resin- ous. Color emerald -green, pale green, passing into light-blue, yel- low, and white. Streak white. Transparent subtranslucent. Fracture conchoidal, uneven. Brit- tle. Double refraction feeble; axis negative. Haddam, Ct. Siberia. Var. This species is one of the few that occur only in crystals, and that have no es- sential variations in chemical composition. There are, however, two prominent groups depend- ent on color, the color varying as chrome or iron is present ; but only the merest trace of either exists in any case. The crystals are usually oblong prisms. 1. Emerald. Color bright emerald-green, owing to the presence of chromium. Hardness a little less than for beryl, according to the lapidaries. 2. Beryl. Colors those of the species, excepting emerald-green, and due mainly to iron. The varieties of beryl depending on color are of importance in the arts, when the crystals are transparent enough to be of value as gems. The transparent bluish-green lands are called aquamarine; also apple -green ; greenish-yellow to iron-yel- low and honey -yellow. Davidsonite is nothing but greenish-yellow beryl from near Aberdeen ; and gouhenite is a colorless or white variety from Goshen, Mass. Comp Be 3 MSi 6 O 18 Silica 60-8, alumina 19'1, glucina 14-1=100. Pyr,, etc. B. B. alone unchanged or becomes clouded ; at a high temperature the edges are rounded, and ultimately a vesicular scoria is formed. Fusibility =5 '5 (Kobell). Glass with borax clear and colorless for beryl, a fine green for emerald. Slowly soluble with salt of phosphorus without leaving a siliceous skeleton. A yellowish variety from Broddbo and Finbo yields with soda traces of tin. Unacted upon by acids. Diff. Distinguished from apatite by its hardness, not being scratched by a knife, also harder than green tourmaline ; from chrysoberyl by its form, and from euclase and topaz by its imperfect cleavage ; never massive. Obs. Emeralds occur in clay slate, in isolated crystals or in nests (not in veins), near Muso, etc. , in N. Granada ; in Siberia. Transparent beryls (aquamarines) are found in Siberia, Hindostan, and Brazil. Beautiful crystals also occur at Elba ; Ehrenfriedersdorf ; Schlacken- wald ; at St. Michael's Mount in Cornwall ; Limoges in France ; in Sweden ; Fossuni in Nor- way ; and elsewhere. Berylf? of gigantic dimensions have been found in the United States, in N. Hamp.^ at Acworth and Grafton, and in Mass.. at Royalston ; but they are mostly poor in quality. A crystal from Grafton, according to Prof. Hubbard, measures 45 in. by 24 in its diameter, and a single foot in length by calculation weighs l,07o Ibs., making it in all nearly 2^ tons. Other localities are in Mass., at Barre; at Goshen ; at Chesterfield. In Conn., at Haddam; Middletown ; at Madison. In Penn. , at Leiperville and Chester ; at Mineral Hill. EUDIALYTE. RhombohedraL Color rose-red. Exact composition uncertain. Analysis, Damour, SiO 2 50'38, ZrO a 15-60, Ta.O 6 0'35, FeO 6 '37, MnO 1-61, CuO 9 23, Na 2 O 13-10, Cl T48, H,O 1-25=99 -37. West Greenland. EUCOLITE is similar, but contains also some of the cerium metals. Norway. POLLUCITE.* 3R.AlSi 4 O 12 -t-2aq with R = mostly Cs(Na,Li). If Na : Cs=l : 2, then SiO, 42 0, AJO. 18-2, Cs.O 33 4, Na a O 3'7, H 2 2-1=100. Isornetric. Colorless. Island oi Elba with castcrite. 300 DESCRIPTIVE MINERALOGY. Orthorhombic. 533 ft. UNISILICATES. GENERAL FORMULA Chrysolite Group. CHRYSOLITE.* Olivine. Peridot. /A 1= 94 2'; A 14 =128 28'; c : I: a -= 1-2588 : 534 1-0729 : 1. A 1-i = 130 26J'. A i-2, ov. 4, = 130 2 r . Cleavage : *- rather distinct. Massive and compact, or granular; usually in imbedded grains. H. = 6-7. G.= 3-33-3-5. Lustre vitreous. Color green commonly olive-green, sometimes yellow, brownish, grayish- red, grayish- green. Streak usually uncolored, rarely yellowish. Transparent translucent. Fracture conchoidal. Comp., Var. (Mg.Fe) 2 SiO 4 , with traces at times of Mn, Ca, Ni. The amount of iron varies much. If Mg : Fe=12 : 1, the formula requires Silica 41 '39, magnesia 50-90, iron protoxide 7 71 =100 ; Mg : Fe=9 : 1, 6 : 1, etc., and in hyalosiderite 2 : 1. Pyr., etc. B.B. whitens, but is infusible ; with the fluxes gives reactions for iron. Hya- losiderite and other varieties rich in iron fuse to a black magnetic globule. Some varieties give reactions for titanium and manganese. Decomposed by hydrochloric acid with separa- tion of gelatinous silica. Diff. Distinguished by its infusibility. Commonly observed in small yellow imbedded grains. Obs. A common constituent of some eruptive rocks ; and also occurring in or among meta- morphic rocks, with talcose schist, hypersthene rocks, and serpentine ; or as a rock formation ; also a constituent of many meteorites (e.g., the Pallas iron). Occurs in eruptive rocks at Vesuvius, Sicily, Hecla, Sandwich Islands, and most volcanic islands or regions ; in Auvergne ; at Unkel, on the Rhine ; at the Laacher See ; in dolerite or basalt in Canada. Also in labradorite rocks in the White Mountains, IS'. H. (hyalosiderite) ; in Loudon Co., Va. ; in Lancaster Co., Pa., at Wood's Mine. The following are members of the Chrysolite Group : FORSTERITE. Mg 2 SiO 4 . Like chrysolite in physical characters. Vesuvius. BOLTONITE, essentially the same. Bolton, Mass. MONTICKLLITE, from Mt. Somma, and BATRACIIITE, from the Tyrol, are (Ca,Mg) 2 SiO 4 , with Ca : Mg=l : 1. H. =5-5 '5. G. =3'03-8-25. Monticellibe also occurs in large quantities (v. Rath) on the Pesmeda Alp, Tyrol, altered to serpentine and fassaite. FAYALTTE. Fe a SiO 4 . G. =4-4 14. Color black. In volcanic rocks at Fayal, Azores ; Mourne M'.ts., Ireland. HORTONOLITE. (Fe,Mg),SiO 4 , with Fe : Mg=3 : 2. O'Neil mine, Orange Co., N. T. TEPHROITE- Mn 2 SiO 4 . G. =4-4 '12. Color reddish-brown. Sterling Hill, N. J.; Sweden. ROEPPERITE. An iron-manganese-zinc chrysolite. H.=5*5-6. G. =3 '95-4 '08. Color dark-green to black. Stirling Hill, N. J. KNEBELITE. (Fe,Mn),Si0 4 , with Fe : Mn=l : 1. G.=4-12. Color gray. Dannemora. LEUCOPHANITE.* Composition given by the analysis (Ramm.) SiO 2 47*03, A10 3 1 '03, BoO 10-70, CaO 23-37, MgO 0'17, Na,O 11-26, K,O 0'30, F 6-57=100-43. Orthorhombic. G.= 2 "97. Color greenish-yellow. Occurs in syenite on the island of Lamoe, Norway. MELIPHANITE (Melinophan). Composition given by the analysis (Rarnm.) SiO 2 43 66, AlO,(FeOs) 1-57, BeO 11 '74, CaO 26-74, MgO (HI, Na 2 8-55, K,O 1'40, H 2 0'30, F 5'73 =99-80. G.=3'018. Orthorhombic. Color yellow. Fredriksvarn, Norwa/. WOHLERITE. Composition given by the analysis (Ramm. ) SiO 2 28-43, CboO 6 14-41, ZrO 1 19 -63, CaO 26-18, FeO(MnO) 2 "50, Na 2 7' 78=98 -93. Monoclinic. G. =3 '41. Color light- yellow. Near Brevig, Norway. OXYGEN COMPOUNDS ANHYDROUS SILICATES. 301 Willemite Group. WILLEMITE. Ehombohedral. R A E = 116 V, A E = 142 IT ; c = 0-67378. Cleav- age: -2 easy in N". Jersey crystals; easy in those of Moresnet. Also massive and in disseminated grains. Sometimes fibrous. H.=5-5. G.=3-89-4-18 ; 4'27, transparent crystals 535 (Cornwall). Lustre vitreo-resinous, rather weak. Color whitish or greenish-yellow, when purest; apple-green, flesh-red, grayish-white, yellowish-brown ; often dark- brown when impure. Streak uncolored. Transparent to opaque. Brittle. Fracture conchoidal. Double refraction strong ; axis positive. \ Var. The crystals of Moresnet and New Jersey differ in occurring forms. The latter are often quite large, and pass under the name of troostite ; they are commonly impure from the presence of man- ganese and iron. Comp.Zn 2 Si0 4 = Silica 27-1, zinc oxide 72 "9 =100. Pyr., etc. B.B. in the forceps glows and fuses with difficulty to a white enamel ; the varieties from New Jersey fuse from 3 '5 to 4. The powdered mineral on charcoal in R.F. gives a coating yellow while hot and white on cooling, which, moistened with solution of cobalt, and treated in O. I\, is colored bright green. With soda the coating is more readily obtained. Decomposed by hydrochloric acid with separation of gelatinous silica. Obs From Vieille-Montagne near Moresnet ; also at Stolberg ; at Raibel in Carinthia; at Kucsaina in Servia, and in Greenland. In New Jersey, at both Franklin and Stirling in such quantity as to constitute an important ore of zinc. It occurs intimately mixed with zincite and franklinite, and is found massive of a great variety of colors, from pale honey- yellow and light green to dark ash-gray and flesh-red ; sometimes in crystals (troostite). DIOPTASE. Emerald-Copper. Ehombohedral; tetartohedral. 72 A 72 =126 24'; <9 A 72 = 148 38'; c= 0-5281. Cleavage: R perfect. Twins: twinning- plane R. Also massive. 536 H.=5. G.=3-27S-3-348. Lustre vitreous. Color emerald-green. Streak green. Transparent subtrans- lucent. Fracture conchoidal, uneven. Brittle. Double refraction strong, positive. Comp Q. ratio for Cu : Si : H=l : 2 : 1 ; formula H 2 CuSi0 4 (Ramm.) = Silica 38 '1, copper oxide 50-4, water 11-5 = 100. Pyr., etc. In the closed tube blackens and yields water. B.B. decrepitates, colors tne flame emerald-green, but is infusible. With the fluxes gives the reactions for copper. With soda on charcoal a globule of metallic copper. Decomposed by acids with gelatinization. Obs. Dioptase occurs disposed in well-defined crystals and amor- phous on quartz, occupying seams in a compact limestone west of the hill of Altyn-Tubeh in the Kirghese Steppes ; also in the Siberian gold-washings. From Chase Creek, near Clifton, Arizona, in fine crystals, on a "mahogany ore," consisting of limonite and copper oxide. PHENACITE. Be. 2 Si0 4 . Rhombohedral. Colorless. Resembles quartz. Takovaja ; Miask j Durango, Mexico. 302 DESCRIPTIVE MINERALOGY. FRIEDELITE. Rhombohedral. 0/\R=\tf\ R A 12=123 42'. Cleavage: easy. H. 4.75. G. 3.07. Also massive, saccharoidal. Color rose-red. Translucent. Double refraction strong, axis negative. Analysis, Si0 2 36.12, MnO (FeO tr) 53 '05, MgO, CaO 2-96, H 2 O 7*87=100 This corresponds to the formula Mn 4 Si3Oio+2H 2 O. If the water is basic, as in dioptase, with which it seems to be related in form, the formula is H 4 Mn 4 Si 3 Oi',= R,Si0 4 . This requires SiO 2 30 "00, MnO 56 -80, H 2 O 7" 20= 100. f Occurs with diallogite and alabandite at the manganese mine of Adervielle, Hautes-Pyrenees. (Bertrand, C. R. , May, 1876.) HELVITE.* Isometric : tetrahedral. Cleavage : octahedral, in traces. H.=6-6'5. G.=3'l-3'3. Lustre vitreous, inclining to resinous. Color honey-yellow, inclining to yellowish-brown, and siskin-green. Streak un- colored. Subtranslucent. Fracture uneven. Comp. Q. ratio for R : Si=l : 2 ; for Mn + Fe : Be=l : 1 ; formula 3(Be,Mn,Fe) 2 Si0 4 + (Mn.Fe)S (Ramm.). Analysis by Teich, Lupikko, Finland, SiO 2 30'31, BeO 10-51, MnO 37-87, FeO 10-37, CaO 4-72, ign 0'22, S 5 95=99-95. Pyr., etc. Fuses at 3 in R.F. with intumescence to a yellowish-brown opaque bead, becom- ing darker in R.F. With the fluxes gives the manganese reaction. Decomposed by hydro- chloric acid, with evolution of sulphuretted hydrogen, and separation of gelatinous silica. Obs. Occurs in gneiss at Schwarzenberg in Saxony ; at Breitenbrunn. Saxony ; at Horte- kulle near Modum, and also at Brevig in Norway, in zircon-syenite. DANALITE.* Isometric. In octahedrons, with planes of the dodecahedron ; the dode- cahedral faces striated parallel to the longer diagonal. H.=5'5-6. G.=3*427. Lustre vitreo-resinous. Color flesh-red to gray. Streak similar, but lighter. Translucent. Fracture subconchoidal, uneven. Brittle. Comp. 3(Be,Fe,Mn,Zn) a SiO 4 +(Fe,Mn,Zn)S. Analysis : J. P. Cooke, Rockport, SiO 2 81-73, FeO 27'40, MnO 628, ZnO 17'51, BeO 13'83. S 5'48=102'23. By subtracting from the analysis oxygen 2'74, equivalent to the sulphur, the sum is 99-49. Pyr., etc. B.B. fuses readily on the edges to a black enamel. With soda on charcoal gives a slight coating of zinc oxide. Perfectly decomposed by hydrochloric acid, with evolution of sulphuretted hydrogen and separation of gelatinous silica. Obs. Occurs in the Rockport granite, Cape Ann, Mass. , small grains being disseminated through this rock ; also near Gloucester, Mass. EaLTTiTE (Kieselwis:nuth, Germ.). Isometric, tetrahedral; in minute crystals often aggregated together. H. =4-5-5. GK =6-106. Color grayish-white to brown. Comp. A uni- silicate of bismuth, Bi 4 Si 3 Oi 2 . Schneeberg. Agricolite. Composition similar, but form monoclinic. Occurs in globular masses having a radiated structure, and in indistinct groups of crystals. Schneeberg (color hair-brown) and Johanngeorgenstadt (color wine -yellow). BISMDTOPERRITE. Cryptocrystalline; generally massive. H.=35. G.=4-47. Color olive-green. Analysis (Frenzel) Si0 2 24 '05, FeOs 33-12, Bi 2 O 8 42 83=100. Schneeberg. HypocJdorite is hornstone mixed with the above mineral and other impurities. Garnet O~roup. GARNET.* Granat, Germ. leometric; dodecahedron, f. 537, and the trapezohedron 2-2, f. 538, Uio most common forms; octahedral form very rare. Distorted form? OXYGEN COMPOUNDS ANHTDKOCS SILICATES. 303 shown in f. 345-352, pp. 105, 106. Cleavage : dodecahedral, sometimes quite distinct. Twins: twinning-plane octahedral. Also massive; granular, coarse, or fine, and sometimes friable ; lamellar, lamellae thick and bent. Also very compact, crypto-crystalline like saussurite. 539 H.=6*5-7'5. G.=3*15-4'3. Lustre vitreous resinous. Color red, brown, yellow, white, apple-green, black ; some red and green colors often bright. Streak white. Transparent subtranslucent. Fracture subcon- choidal, uneven. Brittle, and sometimes friable when granular massive; very tough when compact cryptocrystalline. Sometimes doubly refracting in consequence of lamellar structure, or in some cases from alteration. Comp., Var. Garnet is a unisilicate of elements in the sesquioxide and protoxide states, having- the general formula R 3 ftSi 3 Oi2. There are three prominent groups, based on the nature of the predominating sesquioxide. I. ALUMINA GARNET, in which aluminum (Al) predominates. II. IRON GARNET, in which iron (Fe) predominates, usually with some aluminum. III. CHROME GARNET in which chromium (r) is most prominent. There are the following varieties or subspecies, based on the predominance of one or another of the protoxides : A. GROSSULARITE, or Lime- Alumina garnet. B. PYROPE, or Magnesia- Alumina garnet. C. ALMANDITE, or Iron- Alumina garnet. D. SPESSARTITE, or Manganese- Alumina garnet. E. ANDRADITE, or Lime-Iron garnet, including 1, ordinary; 2, manganesian, or Sothoffite ; 3, yttriferous, or Ytter-garnet. F. BREDBERGITE, or Lime- Magnesia- Iron garnet. G. OUVAROVITE, or Lime- Chrome gar net. Excepting the last, these subdivisions blend with one another more or less completely. A. Lime- Alumina garnet ; GROSSULARITE. Cinnamon stone. A silicate mainly of aluminum and calcium ; formula mostly Ca 3 AlSi 3 Oi2 = Silica 40*0, alumina 22'8, lime 37-2=100. But some calcium often replaced by iron, and thus graduating toward the Almandite group. Color (a) white ; (b) pale green ; (c) amber- and honey-yellow ; (d) wine-yellow, brownish-yellow, cinnamon-brown; rarely (e) emerald-green from the presence of chromium. G. =3 '4-3*75. B. Mr gnesia- Alumina garnet ; PYROPE. A silicate of aluminum, with various protoxide bases, among which magnesium predominates much in atomic proportions, while in small pro- portion in other garnets, or absent. Formula (Mg,Ca,Fe,Mn)3^:lSi30i 2 . The original pyrope is the kind containing chromium. In the analysis of the Arendal magnesia-garnet, Mg : Ca : Fe+Mn=3 : 1 : 2; SiO, 42'45, A10 3 22 '47, FeO 9 29, MnO 6 '27, MgO 13 "43, CaO 6 '53= 100-44 Wacht. G. =3 '157. The name pyrope is from 7rvpw7rg called jargons in jewelry, in allusion to the fact that, while resembling the diamond in lustre, they were comparatively worthless ; and thence came the name zircon. The brownish, orange, and reddish kinds were called distinctively hyacinths a name applied also in jewelry to some topaz and light- colored garnet. Comp. ZrSiO 4 = Silica 33, zirconia 67=100. Klaproth discovered the earth zirconia in this species in 1789. Pyr., etc. Infusible ; the colorless varieties are unaltered, the red become colorless, while dark-colored varieties are made white ; some varieties glow and increase in density by igni- tion. Not perceptibly acted upon by salt of phosphorus. In powder is decomposed when fused with soda on the platinum wire, and if the product is dissolved in dilute hydrochloric acid it gives the orange color characteristic of zirconia when tested with turmeric paper. Not acted upon by acids except in fine powder with concentrated sulphuric acid. Decomposed by fusion with alkaline carbonates and bisulphates. Diff. Distinguished by its adamantine lustre, hardness, and infusibility ; the occurrence of square prismatic forms is also characteristic. Obs. Occurs in crystalline rocks, especially granular limestone, chloritic and other schists ; gneiss, syenite ; also in granite ; sometimes in iron-ore beds. Found in alluvial sands in Ceylon ; in the gold regions of the Ural ; at Arendal in Norway ; at Fredericksvarn, in zircon-syenite ; in Transylvania ; at Bilin in Bohemia. In N. America, in N. York, at Moriah, Essex Co. , and in Orange Co. ; in Warwick ; near Amity ; at Diana in Lewis Co. ; also at Rossie. In N. Jersey, at Franklin ; at Trenton in gneiss. In N. Car., in Buncombe Co.; in the sands of the gold washings of McDowell Co. In California, in the auriferous gravel of the north fork of the American river, and else- where. In Canada, at Grenville, etc. VESUVTANITE.* IDOCRASE. Tetragonal. O A 1-* = 151 45'; c = 0-537199 (v. Kokscharof). O Al = 142 46i' 1 A 1, ov. 1-t, = 129 21'. Cleavage : / not very distinct, Btill less so. Columnar structure rare, straight and divergent, or irregular. Sometimes granular massive. Prisms usually terminating in the basal piano O ; rarely in a pyramid or zirconoid ; sometimes the prism nearly wanting, and the form short pyramidal with truncated summit and edges. 20 306 DESCRIPTIVE MINERALOGY. XL =6-5. G. = 3-349-3-45. 548 651 2 /:: Sandford, Me. Lustre vitreous ; often inclining to re inous. Color brown to green, and the latter frequently bright and clear ; occasionally sulphur- yellow, and also pale blue ; some- times green along the axis, and pistachio-green transversely. Streak white. Subtransparent faintly subtranslucent. Fracture subconchoidal -uneven. Double refraction feeble, axis negative. Oomp., Var, Q. ratio f or R : R : Si= 4:3:7 (according to the latest investi- gations of Rammelsberg). R=Ca (also Mg, Fe, or H 2 ,K 2 ,Na 2 ); ft=Al and also Fe. If we neglect the water the empirical for- mula is R 8 ft. 2 Si 7 O..8, where the quantivalent ratio of bases to silicon is 1 : 1. The ratio of R : R varies much, which, as stated by Rammelsberg. is the explanation of the different varieties. Analyses by Rammelsberg. (1) Monzoni ; (2) Wilui, Siberia. (1) (2) SiO a 37-82 38-40 16-08 13-72 Fe0 3 3-75 5-54 FeO 2-91 MgO 2-11 6-88 CaO 3/3-34 35-04 NaO(K 2 O) 016 0-66 H 2 O 2-08= 99-75 0.82=101-06. Pyr., etc B.B. fuses at 3 with intumescence to a greenish or brownish glass. Magnus states that the density after fusion is 2 '93-2 945. With the fluxes gives reactions for iron, And a variety from St. Marcel gives a strong manganese reaction. Cyprine gives a reaction for copper with salt of phosphorus. Partially decomposed by hydrochloric acid, and completely when the mineral has been previously ignited. Diff. Resembles some brown varieties of garnet, tourmaline, and epidote, but its tetragonal form and easy fusibility distinguish it. Obs. Vesuvianite was first found among the ancient ejections of Vesuvius and the dolo- mitic blocks of Somma. It has since been met with most abundantly in granular limestone ; also in serpentine, chlorite schist, gneiss, and related rocks. It is often associated with lime- garnet and pyroxene. It has been observed imbedded in opal. - Occurs at Vesuvius ; at Ala, in Piedmont ; at Monzoni in the Fassathal ; near Christiansand, Norway ; on the Wilui river, near L. Baikal ; in the Urals, and elsewhere. . In N. America, in Maine, at Phippsburg and Rumford, abundant ; Sandford (f. 551). In N. York, at Amity. In 2f. Jersey, at Newton. In Canada, at Calumet Falls ; at Grenville. MELILITE from Capo di Bove, and HUMBOLDTILTTE from Mt. Somma, are similar in com- jition. Analysis of the melilite by Damour. SiO > 38 '34, A10 3 861, Fe0 3 10 '02, CaO 32 "05, 6*71, Na 2 O 2-12, K,O 1-51=99-36. Tetragonal. Color honey-yellow. Epidote Group. The species of the Epidote Group are characterized by high specific gravity, above 3 ; hardness above 5 ; fusibility B,B. below 4 ; anisometric crystallization, and therefore biaxial polarization ; the dominant prismatic angle 112 to 117 ; fibrous forms, when they occur, always brittle ; colors .white, gray, browir yellowish -green, and deep green to black, and some- times reddish. The prismatic angle in zoisite and other orthorhombic species is I A /; but in epidote it ia the angle over a horizontal edge between the planes and i-i, the orthodiagonal of epidote corresponding .to the vertical axis of zoisite, as explained under the latter species. OXYGEN COMPOUNDS ANHYDROUS SILICATES. 307 EPIDOTE. Pistazite. Monoclinic. 6 r = 89 27' ; *-2 A i-2 = 63 8', <9 A 14 = 122 C 23'; c : I : a = 0-43436 : 0-30719 : 1. O M-i = 154 3', O f\ -l-i = 154 15', ^ A -1 = 104 48', i-iM = 104 15'. Crystals usually lengthened in the direc- tion of the orthodiagonal, or parallel to i-i; sometimes long acicular. Cleavage: i-i perfect; 1-i less so. Twins : twinning-plane I-ij also i-i. Also fibrous, divergent, or parallel ; also granular, particles of various sizes, sometimes fine granular, and forming rock-masses. 552 553 H. = 6-7. G.=3*25-3'5. Lustre vitreous, on i-i inclining to pearly or resinous. Color pistachio-green or yellowish-green to brownish-green, greenish-black, and black ; sometimes clear red and yellow ; also gray and grayish- white. Pleochroism often distinct, the crystals being usually least yellow in a direction through \-i (see p. 166). Streak 1111 colored, grayish. Subtransparent opaque ; generally subtranslucent. Fracture uneven. Brittle. Var. Epidote has ordinarily a peculiar yellowish-green (pistachio) color, seldom found in other minerals. But this color passes into dark and light shades black on one side, and brown on the other. Most of the brown and nearly all the gray epidote belongs to the species Zoisite ; and the reddish-brown or reddish-black, containing much oxide of manganese, to the species Piedmontite, or Manganepidot ; while the black is mainly of the species Allanite^ or Ceriurn-epidote. Comp. Quantivalent ratio for Ca : R : Si =4 : 9 : 12, and H : Ca=l : 4. The formula is then H-iCa^sSicO^G. R is Fe or Al, the ratio varying from 1 : 2 to 1 : 6. Analysis, Unter- eulzbach, Tyrol, by Ludwig : SiO 2 37 '8:3, A1O 3 22'63, FeO 3 15 '05, FeO 0"93, CaO 23 '27, H.,0 2 -05 =100 '76. As first shown by Ludwig, epidote contains about 2 p. c. water, which is given off only at high temperatures. Pyr., etc. In the closed tube gives water at a high temperature. B. B. fuses with intumes- cence at 3-3 '5 to a dark brown or black mass which is generally magnetic. Reacts for iron and sometimes for manganese with the fluxes. Partially decomposed by hydrochloric acid, but when previously ignited, gelatinizes with acid. Decomposed on fusion with alkaline car- bonates. Diff. Distinguished often by its peculiar yellowish-green color ; yields a magnetic globule, B.B. Prismatic forms often longitudinally striated, but they have not the angle, cleavage, or brittleness of trernolite. Obs. Epidote is common in many crystalline rocks, as syenite, gneiss, mica schist, horn- blendic schist, serpentine, and especially those that contain the ferriferous mineral horn- blende. It often accompanies beds of magnetite or hematite in such rocks. It is sometimes found in geodes in trap ; and also in sandstone adjoining trap dikes, where it has been formed by metamorphism through the heat of the trap at the time of its ejection. It also occurs at times in nodules in different quartz-rocks or altered sandstones. It is associated often with quartz, pyroxene, feldspar, axinite, chlorite, etc., in the Piedmontese Alps. Beautiful crystallizations come from Bourg d'Oisans, Ala, and Traversella, in Piedmont , Zcrmatt and elsewhere in Switzerland ; Monzoni in the Fassathal ; the Untersulzbachthal and Zillerthal in the Tyrol. In N. America, occurs in Mass., at Chester ; at Athol ; at Rome. In Conn., at Haddaxn. 308 DESCRIPTIVE MINERALOGY. 555 In N. York, at Amity ; near Monroe, Orange Co. ; at Warwick. In N. Jersey, at Franklin, In Penn., at E. Bradford. In Michigan, in the Lake Superior region. In Canada, at Sfc, Joseph. PIEDMONTITE (Manganepidot, Germ.). A manganese epidote ; formula, HsCaiRsSieOae, with R principally Mn (also Al,Fe). Color reddish-brown. St. Marcel, Aosta valley, Pied- mont. ALLANITE. Monoclinic, isomorphous with epidote. C = 89 1' ; A 14 = 122 50J', a-2 A a-2 = C3 58' ; c : I : d = 0-483755 : 0-312187 : 1. Crystals either short, flat tabular, or long and slender, sometimes acicnlar. Twins like those of epidote. Cleav- age : i-i in traces. Also massive, and in angular or rounded grains. H.=5-5-6. GL=: 3-0-4-2. Lustre siibmetallic, pitchy, or resinous occasionally vitreous. Color pitch- brown to black, either brownish, greenish, grayish, or yellowish. Streak gray, sometimes slightly greenish or brownish. Subtranslucent opaque. Fracture uneven or subconchoidal. Brittle. Double refraction either dis- tinct, or wanting. Allanite (Cerine). In tabular crystals or plates. Color black or brownish-black. G. =3 50-3 '95; found among specimens from East Greenland, brought to Scotland by C. Giesecke. Bucklandite is anhydrous allanite in small black crystals from a mine of magnetite near Arendal, Norway. Referred here by v. Rath on the ground of the angles and physical characters. Orthite. Including, in its original use, the slender or acicular prismatic crystals, often a foot long, containing some water. But these graduate into massive forms, and some orthites are anhydrous, or as nearly so as much of the allanite. The name is from bp66s, straight. The tendency to alteration 'and hydration may be due to the slenderuess of the crystals, and the consequent great exposure to the action of moisture and the atmosphere. II. =5-6. G. =2 '80-3- 75. Lustre vitreous to greasy. Comp. Not altogether certain, as analyses vary considerably, some showing the presence of considerable water. According to Rammelsberg the Q. ratio for bases to silicon 1 : 1 (epidote^l^ : 1). Allanite has then the garnet formula, R 3 RSi 3 Oi 2 , where R=Ce(La,Di), Fe(Mn), Ca(Mg), and occasionally Y,Na 2 ,K 2 , etc.; R=A1 or Fe. Analysis, allanite (Ramm.), Fredrikshaab, Si0 2 33'78, A10 3 14'03, FeO 3 6 -36, FeO 13'63, CeO 12-63, LaO(DiO) 5 '07, CaO 1212, H 2 O 1-78=100. Pyr., etc. Some varieties give water in the closed tube. B.B. fuses easily and swells up (F. 2*5) to a dark, blebby, magnetic glass. With the fluxes reacts for iron. Most varieties gelatinize with hydrochloric acid, but if previously ignited are not decomposed by acid. Obs. Occurs in albitic and common feldspathic granite, syenite, zircon- syenite, porphyrj, white limestone, and often in mines of magnetic iron. Allanite occurs in Greenland ; at Criffel in Scotland ; at Jotun Fjeld in Norway ; at Snarum, near Dresden ; near Schmiede- feld in the Thiiringerwald. Cerine occurs at Bastnas in Sweden. Orthite occurs at Finbo and Ytterby in Sweden ; also at Krageroe, etc. , in Norway ; at Miask in the Ural. In Mass., at the Bolton quarry. In Conn., at Haddam. In N. York, Moriah, Essex Co.; at Monroe, Orange Co. In _ZV". Jersey ', at Franklin. In Penn. , at E. Bradford in Chester Co. ; at Easton. Amherst Co., Va. In Canada, at St. Paul's, C. W. MUROMONTITE and BODENITE from Marienberg, Saxony ; and MICHAELSONITE from Brevig, are minerals related to allanite. ZOISITE. Orthorhombic. /A 1 = lld 40', O A l-l = 131 If ; c : I : d = 1-1493 * 1 '6 21 25 : 1. Crystals lengthened in the direction of the vertical axis, and OXYGEN COMPOUNDS ANHYDROUS SILICATES. 309 550 vertically deeply striated or furrowed. Cleavage: i-$ very perfect. monly in crystalline masses longitudinally furrowed. Also compact massive. H. = 6-6-5. G.=3-ll-3-3S. Lustre pearly on i-l\ vitreous on surface of fracture. Color grayish-white, gray, yellowish, brown, greenish-gray, apple-green; also peach-blossom-red to rose-red. Streak uricolored. Transparent to sub translucent. Double refraction feeble, optic-axial plane i-i ; bisectrix positive, normal to i-i ; DesCl. Com r. LIME-ZOISITE. 1. Ordinary. Colors gray to Avhite rown. 2. Rose-red, or Thulite. G. =3'1 24; fragile; dichro- Var. and brown. ism strong, especially in the direction of the vertical axis ; in this direction reddish, transversely colorless ; from Norway, Piedmont. Saussurite, which forms with smaragdite the euphotideof the Alps, is a lime -soda zoisite. Comp. A lime-epidote, with little or no iron, and thus differing from epidote. Q. ratio as in epidote, H : Ca=l : 4, and Ca : It : Si=4 : 9 : 12, whence the formula H. 2 Ca4R s Si 6 O2 e> . Analysis, Ramm., Goshen (G.=3'341) SiO> 40'06,rUO 3 3067, Fe0 3 2 '45. CaO 23'91, MgO 0'49, HaO 2'25=99 83. The amount of iron sesquioxide varies from to 6'33 p. c. ; if much more is present, amounting to a sixth atomically of the protoxide bases, the compound appears to take the monoclinic form of epidote, instead of the orthorhombic of zoisite. Pyr., etc, B.B. swells up and fuses at 3-3 '5 to a white blebby mass. Not decomposed by acid ; when previously ignited gelatinizes with hydrochloric acid. Obs Occurs at Saualpe in Carinthia ; Baireuth in the Fichtelgebirse ; Sterzing, Tyrol; Lake Geneva ; Schwarzwald ; Arendal, etc. In the United States, found in Vermont, at Willsboro and Montpelier. In Mass., at Goshen, Chesterfield, etc. In Penn., in Chester Co.; at Unionville, white (Unionite). In Tenn., at the Ducktown copper mines. JADEITE is one of the kinds of pale green stones used in China for making ornaments, and passing under the general name of jade or nephrite. Mr. Pumpelly remarks that the fdtmi is perhaps the most priced of all stones among the Chinese. In composition mainly a silicate of aluminum and sodium. In its high specific gravity like zoisite. GADOLINITE. Monoclinic (DesCl.). Color greenish-black. Contains yttrium, cerium, and generally beryllium ; though the last is sometimes absent, through alteration (DesCl.). Sweden ; Greenland ; Norway. MOSANDRITE. A silicate containing titanium, cerium, and calcium. Brevig, Norway. ILVAITB. Lievrite. Yenite. Orthorhombic. 2/\ 7 ^112 38', A 1-i = 146 24' ; c : I 1-5004 : 1. Of\l = 141 24', O A 2-i = 138 29'. Lateral faces usually striated longitudinally. Cleavage : parallel to the longer diagonal, indistinct. Also columnar or com- pact massive. H.:=5-5-6. G.=3-7-4'2. Lustre submetallic. Color iron-black, or dark grayish-black. Streak black, inclining to green or brown. Opaque. Fracture uneven. Brittle. Comp. Q. ratio, for R+R : Si : H=9 : 8 : 1, and for bases, including hydrogen, to silicon 5 : 4 (Stadeler). Sipocz by the analysis of entirely unaltered crystals (G. 4'037) from Elba confirms the conclusions of Stadeler in regard to the presence of chemically combined water, and adopts the same formula, viz.: H 2 Ca2Fe4FeSi 4 Oi8. This requires : Silica 29 '34, iron sesquioxide 19*56, iron protoxide 35 21, lime 13 '69, water 2 '20 100 ; manganese protoxide is also sometimes present in small quantities, mflsberg considered the water as due to alteration. = 0-66608 : 557 Rani 310 DESCRIPTIVE MINERALOGY Pyr., etc. B.B. fuses quietly at 2 '5 to a black magnetic bead. With the fluxes reacts foi iron. Some varieties give also a reaction for manganese. Gelatinizes with hydrochloric a<;id. Obs. Found in Elba, and at the mine of Temperino in Tuscany. Also at Fossum and at Skeen in Norway ; in Siberia ; near Andreasberg ; near Predazzo, Tyrol ; at Schneeberg ; at Hebrun in Nassau ; at Kangerdluarsuk in Greenland. Reported as formerly found at Cumberland, R. I.; also at Milk Row quarry, Somerville, Mass. ARDENNITE (Dewalquite). Near ilvaite in form. Habit prismatic; vertically striated. Composition given by the analyses, Lasaulx and Bettendorf, SiO 2 29 '60, A10 3 23 '50, MnO 2/5-88, Fe0 3 1'08, CaO 1'81, MgO 3'38, V,O 5 9'20, ign. 4 04=99'09. Color dark rosin-brown. In thin splinters transparent. Other varieties, of a bright sulphur-yellow color (but opaque and dull), contain arsenic (9-33 p. c. As 2 O 6 ) instead of vanadium. Between these two ex- tremes are a series of compounds containing both arsenic and vanadium. Lasaulx regards the arsenic-ardennite as having come from the other through alteration. Locality, Ottrez ir> the Ardennes, Belgium. ROSCOELITE (p. 367) is another silicate containing vanadium. AXINITE. Triclinic. Crystals usually broad, and acute-edged. Making m = 0, P = 'I,u = l',a (brachyd.) : I (macrod.) : c = 0-49266 : 1 : 0-45112. Cleav age: i-i (v) quite distinct; in other directions indistinct. Also massive, lamellar, lamellae, often curved ; sometimes granular. 558 V Dauphiny. Dauphiny. Cornwall. H.=6-5-Y. G.=3'271, Haidinger ; a Cornish specimen. Lustre highly glassy. Color clove-brown, plum-blue, and pearl-gray; exhibits trichroism, different colors, as cinnamon -brown, violet-blue, olive-green, being seen in different directions. Streak uncolored. Transparent to subtranslucent. Fracture conchoidal. Brittle. Pyroelectric, with two axes, the analogue (L) and antilogue (T) poles being situated as indicated in f. 558 (G. Kose). Comp. Analyses vary. If it contains 2 p. c. water (Ramm.), and if B 2 replaces Al, then it is a unisilicate with the formula RTftsSisO^s, R=Fe,Mn,Ca,Mg, and K 2 , while ft=B 2 ,Al (B 2 : ^1=1 : 2). Analysis (Ramm.), Oisans. Dauphine, SiO 2 43'46, B,O 3 5'61, A1O 3 IG'33, Fe0 3 2-80, FeO 6-78, MnO 2-62, CaO 2019, MgO 1-73, K 2 0-11, H 2 1-45=101 -08. Pyr., etc. B.B. fuses readily with intumescence, imparts a pale green color to the O.F. , and fuses at 2 to a dark green to black glass ; with borax in O. F. gives an amethystine Dead (manganese), which in R.F. becomes yellow (iron). Fused with a mixture of potassium bisul- OXYGEN COMPOUNDS ANHYDROUS SILICATES. 311 phate and fluor on the platinum loop colors the flame green (boron). Not decomposed by acids, but when previously ignited, gelatinizes with hydrochloric acid. Obs. Axinite occurs near Bourg d'Oisans in Dauphiny ; at Santa Maria, Switzerland; at Kongsberg ; in Normark in Sweden ; in Cornwall ; in Devonshire, near Tavistock ; at Phips- burg, Maine ; at Wales, Maine ; at Cold Spring, N. Y. DANBURITE.* Triclinia CaB 2 Si 2 8 =Silica 48'8, boron trioxide 28-5, lime 227=100. Occurs with feldspar in imbedded masses of yellow color in dolomite, at Danbury, Ct. and 561 IOLITE. Cordierite. Dichroite. Orthorhombic. In stout prisms often hexagonal. /A 1 = 119 10' 60 50', O A \-l =150 49'. Cleavage : i-l distinct ; i-l and indistinct. Crystals often transversely divided or foliated parallel with O. Twins : twinning-plane I. Also massive, compact. H.=7-7'5. Gr.=2-56-2-67. Lustre vitreous. Color various shades of blue, light or dark, smoky-blue ; pleo- chroic, being often deep blue along the vertical axis, and brownish -yellow or yellowish-gray perpendicular to it. Streak uncolored. Transparent translucent. Frac- ture subconchoidal. Comp. Q. ratio for bases and silicon 4 : 5 or 1 : 1. The state of oxidation of the iron ia still unascertained, and hence there is uncertainty as to the proportion between the protoxides and sesquioxides. The ratio usually deduced for R : ft : Si is 1 : 3 : 5. The formula R,ft.jSi 3 O], which corresponds to this ratio, =, if R=Mg,Fe and Mg : Fe=2 : 1, Silica 49 '4, alumina 33'9, magnesia 8'8, iron protoxide 7 '9=10*0. Pyr., etc B.B. loses transparency and fuses at 5-5 '5. Only partially decomposed by acids. Decomposed on fusion with alkaline carbonates. Obs. lolite occurs in granite, gneiss, hornblendic, chlorite and hydro-mica sohist, and allied rocks, with quartz, orthoclase or albite, tourmaline, hornblende, andalusite, and sometimes beryl. Also rarely in volcanic rocks. Occurs at Bodenmais, Bavaria ; at Ujordlersoak in Greenland ; at Krageroein Norway ; Tunaberg in Sweden ; Lake Laach. At Haddam, Conn.; at Brirnfield, Mass. ; also at Richmond, N . H. Alt. The alteration of iolite takes place so readily by ordinary exposure, that the mineral is most commonly found in an altered state, or enclosed hi the altered iolite. For the dis- tinguishing characters of the different kinds of altered iolite, see FINITE, FAHLUNITE, etc., under HYDROUS SILICATES. Mica Group* The minerals of the Mica group are alike in having (1) the prismatic angle 120 ; (2) eminently perfect basal cleavage, affording readily very thin, tough laminae ; (3) potash almost invariably among the protoxide bases and alumina among the sesquioxide ; (4) the crystallization approxi- mately either hexagonal or orthorhombic, and therefore the optic axis, or optic-axial plane, at right angles (or nearly so) to the cleavage surface. Sodium is sparingly present in some micas, and is characteristic of the hydrous species paragon! te (p. 354). Lithium, rubidium, and caesium occur in lepidolite, and lithium in soina biotite. Fluorine is often present, probably replacing oxygen. Titanium is found sparingly in several kinds, and is a prominent ingredient of one species, astrophylli te. It is usually regarded as in the state of titanium dioxide replacing silica ; but it is here made basic. 312 DESCRIPTIVE MINERALOGY. The species of the Mica group graduate into the hydrous micas of the Margarodite group (p. 331) ; and through these they also approach the foliated species of the Talc and Chlorite groups, especially the latter. PHLOGOPITE.* Orthorhombic. 7A/=120, and habit hexagonal. Prisms usually oblong six-sided prisms, more or less tapering, with irregular 562 sides ; rarely, when small, with polished lateral planes. Cleavage basal, highly eminent. Not known in compact massive forms. H.=2-5-3. G. 2-78-2-85. Lustre pearly, often sub- metallic, on cleavage surface. Color yellowish-brown to brownish-red, with often something of a copper-like reflec- tion ; also pale brownish-yellow, green, white, colorless. Transparent to translucent in thin folia. Thin laminae tough and elastic. Optical-axial divergence 3-20, rarely less than 5. Comp. The bases include magnesium and little or no iron. Q. ratio R : Si=l : 1. Formula probably (Ramm.) K 2 Mg 6 AlSi 6 O2o= Silica 4073, alumina 13-93, magnesia 32 57, potash 12 '77 100. Pyr,, etc. In the closed tube gives a little water. Some varieties give the reaction for fluorine in the open tube, while most give little or no reaction for iron with the fluxes. B. B. whitens and fuses on the thin edges. Completely decomposed by sulphuric acid, leaving the silica in thin scales. Obs. Phlogopite is especially characteristic of serpentine and crystalline limestone or dolomite. Occurs in limestone in the Vosges. Includes probably the mica found in limestone at Alt- Kemnitz, near Hirschberg ; that of Baritti, Brazil, of a golden-yellow color, having the optical angle 5 30' and parallel to the shorter diagonal (Grailich) ; and a brown mica from limestone of Upper Hungary, affording Grailich the angle 4 '-5. Occurs in New York, at Gouverneur ; at Pope's Mills. St. Lawrence Co. ; at Edwards ; Warwick; Natural Bridge; at Sterling Mine, Morris Co., N. J. ; Newton, N. J.; at St. Je- rome, Canada; at Burgess, Canada West. ASPIDOLITE (v. Kobell). Approaches in composition a soda-phlogopite. Green. Foliated. Zillerthal, Tyrol. MANGANOPHYLLITE. Q. ratio f or R : R : Si=3 : 1 : 4 (nearly). Foliated like the micas. Color bronze-red. Analysis, Igelstrom, Si0 2 38-50, A1O 3 ll'OO, FeO 378, MnO 21'40, CaO 3-20, MgO 15-01, K 2 O(Na 2 O) 5 -51, igu. 1'60=100. Paisberg, Sweden. BIOTITE.* Hexagonal (?). R A R = 62 57' (crystals f r. Vesuvius, Hessenberg) ; c = 4:*911126. Habit often monoclinic. Prisms commonly tabular. Cleavage : basal highly eminent. Often in disseminated scales, sometimes in massive aggregations of cleavable scales. H.=2-5-3. G.=2-7-3'l. Lustre splendent, and more or less pearly on a cleavage surface, and sometimes submetallic when black ; lateral surfaces vitreous when smooth and shining. Colors usually green to black, often deep black in thick crystals, and sometimes even in thin laminae, unless the laminae are very thin ; such thin laminae green, blood-red, or brown bv transmitted light ; rarely white. OXYGEN COMPOUNDS ANHYDROUS SILICATES. 313 Streak uncolored. Transparent to opaque. Optically uniaxial. Some- times biaxial with slight axial divergence, from exceptional irregularities; but the angle not exceeding 5 and seldom 1. Oomp., Var. Biotite is a magnesia-iron mica, part of the aluminum (Al) being replace^ by iron (Fe), and Fe and Mg existing among the protoxide bases. Black is the prevailing color, but brown to white also occur. The results of analyses vary much, and for the rea-on already stated the non- determination, in most cases, of the degree of oxidation of the iron ; and the exact atomic ratio for the species and its limits of variation are therefore not precisely understood. The Q. ratio of bases to silicon is generally 1:1, that is the formula in general ~,SiO 4 , where R=K,(Na 2 ,Li 2 )Fe,Mg(Ca), or iVl,Fe^3R=R). Analyses : 1, Ballyellin ; 2, Vesuvius ; 3, Portland, Conn. : SiO 2 A1O 3 FeO 3 FeO CaO MgO K 2 Na 2 Li 2 O ign (1) 35-55 17-08 23-70 5'50 368 9-45 0'35 4'30=99'61, Haughton. (2) 40-91 17*79 3-00 7 '03 0'30 19 "04 9 96 =98-03, Chodnew. (3j|35'61 20-03 0-13 21 '85 119MnO 5'23 9-69 0-52 93 1'87, F 0'76, Ti0 2 1'46, 01 tr. =99 -27, Hawes. The above analyses give the ratio of unisilicates, when the water is neglected ; in others the ratio of 1 : 1 is obtained only when the water is brought into account. Pyr., etc. Same as phlogopite, but with the fluxes it gives strong reactions for iron. Obs. A common constituent of many volcanic rocks. Fine specimens obtained at Vesu- vius ; L. Baikal; Zillerthal; Pargas ; Miask ; Sala. Also from Greenwood Furnace, N. Y.j Moriah, N. Y. ; Easton, Penn. ; Topsham, Me., etc. The biotite of Vesuvius, according to the optical examination of Hintze, is monodinic. (See also Tschermak, Min. Mitth., 1876, 187.) LEPIDOMELANE. Hexagonal (?). In small six-sided tables, or an aggregate of minute scales. Cleavage : basal, eminent, as in other micas. H.=3. G.r=3-0. Lustre adamantine, inclining to vitreous, pearly. Color black, with occasionally a leek-green reflection. Streak grayish- green. Opaque, or translucent in very thin laminae. Somewhat brittle, or but little elastic. Optically uniaxial ; or biaxial with a very small axial angle. Oomp, An iron-potash mica. Q. ratio for bases and silicon 1:1; f or R : R, mostly 1 : 3, but varying to 1 to more than 3 ; of doubtful limits, on account of the doubts as to the state of the iron in most of the analyses. Differs from biotite in the smaller proportion of prot- oxides and little Al and Mg, but appears to agree with it in optical characters. Pyr., etc, B.B. at a red heat becomes brown and fuses to a black magnetic globule. Easily decomposed by hydrochloric acid, depositing silica in scales. Analysis, Cooke, Rock- port, Mass., SiO., 39-91, A10 3 16'73, FeO 3 12'07, FeO 17-48, MnO 0-54, MgO 0-62, K 2 O 10'66, Na 2 O(Li 2 O) 0-59, H 2 O 1'50, F0'45=100. Obs. Occurs at Persberg in Wermland, Sweden ; at Abborf orss in Finland ; in Ireland, in Donegal and Leinster Cos. ; at Ballyellin, etc. From Cape Ann, Mass. (Annite). ASTKOPHYLLITE. Usually in tabular prisms. Color bronze-yellow. Analysis, Pisani, SiOi 33-22, TiO, 7-66, A1O 3 4'32, FeO 3 4'05, FeO 25'48, MnO 10 70, MgO 1'37, CaO 1'22, Na a O 8-71, K 2 O 6-29, HiO 2-01=99'03. Brevig, Norway ; El Paso County, Colorado. MUSCOVITE. Kaliglimmer, Germ.* Monoclinic (Tschermak). 1 1\ I =120. Cleavage: basal eminent, occasionally also separating in fibres parallel to a diagonal. Twins : often observable "by internal markings, or by polarized light ; composition parallel 314 DESCRIPTIVE MINERALOGY. to 1 consisting of six individuals thus united ; sometimes a union of / to i4. Folia often aggregated in stellate, plumose, or globular forms ; or in scales, and scaly massive. 564 565 566 Miask, Ural. Binnenthal. H.= 2-2-5. G.=2'75-3'l. Lustre more or less pearly. Color white, gray, brown, hair-brown, pale green, and violet, yellow, dark olive-green, rarely rose-red ; often different for transmitted and reflected light, and dif- ferent also in vertical and transverse directions. Streak uncolored. Trans- parent to translucent. Thin laminae flexible and elastic, very tough. Double refraction strong; optic-axial angle 44: -78 ; the axial plane makes an angle of 88 20' (Tschermak) with the base. Ooinp. The quantivalent ratio for bases and silicon is generally 4 : 5 (1 . !), rarely 3 . 4, etc. Water is generally present, sometimes as much as 5 p. c.; and the kinds containing from 3 to 5 p. c. water have been referred to the species margarodite (p. 353). If the i water is regarded as chemically combined, that is, as basic, the Q. ratio for R : R : Si is then =1 : 3 : 4 (B : Si=l : 1), also 1:6:8, 1:2:4, 1:3:5, etc. B, here is potassium (K) mostly, but also hydrogen (H). R=aluminum mostly, also iron. Fluorine is often present, but at most not more than about 1 p. c. Analysis, Smith and Brush, Monroe, Ct., SiO. 46 '50, :MO 3 33-91. Fe0 3 2'69, MgO 0'90 Na 2 O 2'70, K.O 7*32, H,O 4 "63, F 0'82, Cl 0'31=99-?8. Pyr., etc. In the closed tube gives water, .which with brazil-wood often reacts for tluorine. B.B. whitens and fuses on the thin edges (F. =5-7, v. Kobell) to a gray or yeilow glass. With fluxes gives reactions for iron and sometimes manganese, rarely chromium. Not decomposed by acids. Decomposed on fusion with alkaline carbonates. Obs. Muscovite is the most common of the micas. It is one of the constituents of granite, gneiss, mica schist, and other related rocks, and is occasionally met with in granular lime- stone, trachyte, basalt, iava; and occurs also disseminated sparingly in many fragmental rocks. Coarse lamellar aggregations often form the matrix of topaz, tourmaline, and other mineral species in granitic veins. Siberia affords lamina of mica sometimes exceeding a yard in diameter ; and other remark- able foreign localities are Finbo in Sweden, and Skutterud in Norway. Fuchsite or chromium mica occurs at Greiner in the Zillerthal, at Passeyr in the Tyrol, and on the Dorfner Alp, as well as at Schwarzenstein. In N. Hamp., at Acworth, Grafton, etc., in granite, the plates at times a yard across and perfectly transparent. In Maine, at Paris ; at Buckfield. In Mass. , at Chesterfield ; at Goshen. In Conn., in Portland ; near Middletown. In N. York, near Warwick; Edenville ; in the town of Edwards, In Pcnn., at Pennsbury ; at Unionville ; Delaware Co., at Middletown. In Maryland, at Jones's Falls. In western North Carolina, where it is mined. I LEPIDOLITE.* Lithia Mica. Lithionglimmer, Germ. Orthorhombic. /A 1 = 120. Forms like those of mnscovite. Cleav- age : basal, highly eminent. Also massive scaly-granular, coarse or tine. H.= 2-5-4. G.= 2-84-3. Lustre pearly. Color rose-red, violet-gray, 01 OXYGEN COMPOUNDS. ANHYDROUS SILICATES. 315 lilac, yellowish, grayish-white, wliite. Translucent. Optic-axial angle 70-78 ; sometimes 45-GO. i Comp. Q. ratio for bases and silicon mostly 1 : l ; and for R : R : Si=l : 3 : 6, or 1 : 4 : 8 ; the formula in the latter case is R 6 Al 4 Sii 2 O39. R includes potassium, also lithium, rubidium, and caesium ; and, in the Zinnwald mica, thallium has been detected. Fluorine is present, and the ratio to oxygen mostly 1 : 12. Analysis, Reuter, from Rozena, SiO 2 50 '43, 510 3 28-07, Mn0 3 0'88, MgO 1'42, K,O 10'59, Na.O 1-46, Li,O 1-23, P 4'8(5=98'94. Pyr., etc. In the^closed tube gives water and reaction for fluorine. B. B. fuses with in- tumescence at 2-2-5 to a white or grayish glass, sometimes magnetic, coloring the flame purplish-red at the moment of fusion (lithia). With the fluxes some varieties give reactions for iron and manganese. Attacked but not completely decomposed by acids. After fusion, gelatinizes with hydrochloric acid. Obs Occurs in granite and gneiss, especially in granitic veins, and is associated some- times with cassiterite, red, green, or black tourmaline, amblygonite, etc. Found near Uto in Sweden ; at Zinnwald in Bohemia ; Penig, etc. in Saxony ; in the Ural ; at Rozena in Moravia ; on Elba ; at St. Michael's Mount in Cornwall. In the United States, at Paris and Hebron, Me. ; near Middletown, Conn. Named lepidolite from Ae/r/f, scale, after the earlier German name Sc?iuppenstein, alluding to the scaly structure of the massive variety of Rozena. CRYOPHYLLITE (Cooke). Q. ratio R : ft : Si=3 : 4 : 14, with R=Fe,K 2 ,Li 2 (Na,Rb,Cs,) a and R-= Al. Orthorhombic. In scales like the micas. Color by transmitted light emerald green. Cape Ann, Mass. Sea/polite Group. group, the quantivalent ratio varies from 2 : 4 and 1 : 2 : 6, but the species are In the species of the Scapolite 1 : 1 : 2, 1 : 2 : 3, 1 : 3 : 4, to 1 : closely alike in the square-prismatic forms of their crystals, in the small number and the kinds of occurring planes, and in their angles. The species are white, or grayish-white, in color, except when impure, and then rarely of dark color ; the hardness 5-6'5. G. = 2'5-2'8. The alkali-metal present, when any, is sodium, with only traces of potassium. An increase in the amount of alkali is accompanied by an increase in the silica. MEIONITE.* Tetragonal : O A l-i = 156 18' ; c 0-439. Sometimes hemihedral in the planes 3-3, the alternate being wanting. Cleavage : i-i and / rather perfect, but often interrupted. H.=5'5-6. G.=2*6~2'T4. Lustre vitreous. Colorless to white. Transparent to translucent ; often much cracked within. Comp. Q. ratio f or R : R : Si=l : 2 : 3 ; formula RsRjSiaOae. If R= Ca : Na 2 = 10 : 1, and R=:A:1 ; this is equivalent to Silica 41-6, alumina 31*7, lime 24 '1, soda 2'6 = 100. Neminar has found that meionite loses 1 p. c. water at a very high temperature, so that R must be also replaced by Hi ; his analysis gives approximately the ratio 1 : 2 : 3. Pyr., etc. B. B. fuses with intumescence at 3 to P, white blebby glass. Decomposed by acid without gelatinizing (v. Rath). Obs. Occurs in small crystals in geodes, usually in limestone blocks, on Monte Somma, near Naples. 316 DESCRIPTIVE MINERALOGY. WERNERITE,* Scapolite. Tetragonal: O A 1-i = 156 14J' ; c = 04398. Often hemihedrai in planes 3-3 and i-2 (p. 30). Cleavage: i-i and /rather distinct, but interrupted. Also massive, granular, or with a faint fibrous appearance ; sometimes columnar, II. =5-6. G.= 2-63-2-8. Lustre vitreous to pearly externally, inclining to resinous ; cleavage and cross- fracture surface vitreous. Color white, gray, bluish, greenish, and reddish, usually light. Streak uncolored. Transparent faintly subtranslucent. Fracture sub- conchoidal. Brittle. Comp Q. ratio for R : R : Si=l : 3 : 4 (R+R : Si=l : 1); formula RRSi 2 O 8 =Ca(Na 2 )AlSi 2 O e . Analysis, v. Rath. Pargas, Si0 2 45 '46, A10 3 30'96, CaO 17-22, Na 2 O 2-29, K 2 1-31, H 2 1-29=98 '53. Some varieties vary widely from the above ratio. Pyr., etc. B.B. fuses easily with intumescence to a white blebby glass. Imperfectly de- composed by hydrochloric acid. Diff. Recognized by its square form ; resembles feldspar when massive, but has a charac- teristic fibrous appearance on the cleavage surface ; it is also more fusible, and has a highei specific gravity. Obs. Occurs in rnetamorphic rocks ; sometimes ia beds of maguetite accompanying lime- stone. Some localities are : Arendal, Norway ; Wermland ; Pargas, Finland ; L. Baikal, etc. In the following those of the wernerite and ekebergite are not yet distinguished. In Ma*9., at Bolton; Westfield. In Conn., at Monroe. In N. York, in Warwick; in Orange and Essex Co., etc. In N. Jersey, at Franklin and Newton. In Canada, at Gr. Calumet Id. ; at Hunterstown ; Grenville. The following are other members of the scapolite group : SARCOLifE. Q. ratio for R : R : Si=l : 1 : 2. In minute flesh-red crystals at Mt Somma. PARANTHITE. Q. ratio=l : 3 : 4. EKEBERGITE. Q. ratio=l : 2 : 4|, containing 6-8 p. c. soda. MIZZONITE. Q. ratio^l : 2 : 5, containing 10 p. c. soda. In crystals at Mt. Somma, DIPYRE. Q. ratio=l : 2 : 6, and for Ca : Na^l : 1. MARIALITE. Q. ratio=l : 2 : 6, and for Ca : Na 2 =l : 2. Hexagonal. 569 Nephelite Group. NEPHELITE. Nepheline. A 1 = 135 55' ; c = 0'839. Usual forms six-sided and twelve-sided prisms with plane or modified sum- mits. Fig. 569, summit planes of a crystal. Cleav- age: /distinct, O imperfect. Also massive, com- pact ; also thin columnar. II. =5 5-6. G.= 2.5-2-65. Lustre vitreous- greasy ; a little opalescent in some varieties. Color- less, white, or yellowish ; also when massive, dark- green, greenish or bluish-gray, brownish and brick- red. "Transparent opaque. Fracture subcon- choidal. Double refraction feeble ; axis negative, Vesuvius. Var. 1. Glassy, or Sommite. Usually in small crystals 01 grains, with vitreous lustre, first found on Mt. Somma, in the region of Vesuvius. Davyne and cawlinite belong 1 i. ElcBolile. In large coarse crystals, or massive, with a greasy lustre. here. OXYGEN COMPOUNDS. ANHYDROUS SILICATES. 317 Comp. Somewhat uncertain, as all analyses give a little excess of silica beyond what ii required for a unisilicate. Assuming that nephelite is a true unisilicate, the Q. ratio for R : R : Si=l : 3 : 4, and the formula is (Na,K) 2 A-lSi 2 8 (Ramm. ); some of the Na 2 being replaced by Ca. Analysis, Scheerer, Vesuvius, SiO 2 44'03, A1O 3 38 '28, Fe0 3 (MnO 3 ) 0'05, CaO 1-77. Na 2 O 15'44, K 2 O 4-94, H 2 0-21=100-32. The variety Elceolite has the same composition. Pyr., etc. B.B. fuses quietly at 3 '5 to a colorless glass. Gelatinizes with acids. Diff Distinguished by its gelatinizing with acids from scapolite and feldspar, as also from apatite, from which it differs too in its greater hardness. Massive varieties have a character- istic greasy lustre. Obs Nephelite occurs both in ancient and modern volcanic rocks, and also metamorphic rocks allied to granite and gneiss, the former mostly in glassy crystals or grains (sommite), the latter massive or in stout crystals (elceolite). Nephelite occurs in crystals in the older lavas of Somma ; at Capo di Bove, near Rome ; in doleryte of Katzenbuckel, near Heidelberg, etc. Eleeolite is found in Norway ; in the Ilmen Mts. ; Urals ; at Litchfield, Me. ; in the Ozark Mts. , Arkansas. Named nepkeline by Haiiy (1801), from ve^ety, a cloud, in allusion to its becoming cloudy when immersed in strong acid ; elceolite (by Klaproth), from EACUOV, oil, in allusion to its greasy lustre. GIESECKITE is shown by Blum to be a pseudomorph after this species (see p. 330). C AN CRIN IT E.'^ Hexagonal, and in six- and twelve-sided prisms, sometimes with basal edges replaced; also thin columnar and massive. H. =5-6. G. =2'42-2'5. Color white, gray, yellow, green, blue, reddish; streak uncolored. Lustre subvitreous, or a little pearly or greasy. Transparent to translucent. COMP. Same as for nephelite, with some RC0 3 and water. Analysis, Whitney, Litchfield, Me., SiO, 37-42, A10 3 27'70, CaO 3D1, Na.O 20'9S, K,0 0'67, C0 2 5'95. H 2 2'82, FeO 3 (MnO 3 ) 0-86=100-31. PYR., ETC. In the closed tube gives water. B.B. loses color, and fuses (F.=2) with intu- mescence to a white blebby glass, the very easy fusibility distinguishing it readily from nephelite. Effervesces with hydrochloric acid, and forms a jelly on heating, but not before. OBS. Found at Miask in the Urals ; at Barkevig, Norway ; at Ditro in Transylvania (ditroyte) ; at Litchfield, Me. SODALITE. Isometric. In dodecahedrons. Cleavage : dodecahedral, more or less distinct. Twins : see f. 272, p. 93. Also massive. H.= 5:5-6. G.= 2 '136-2*4:01. Lustre vitreous, sometimes inclining to greasy. Color gray, greenish, yellowish, white ; sometimes blue, lavender- blue, light red. Subtransparent translucent. Streak uncolored. Frac- ture conchoidal uneven. Comp. 3Na 2 AlSi. 2 8 +2NaCl=Silica 371, alumina 31 '71, soda 25 -55, chlorine 7 "31 =101 '65, fiome varieties contain considerably less chlorine. Pyr., etc, In the closed tube the blue varieties become white and opaque. B.B. fuse* with intumescence, at 3*5-4, to a colorless glass. Decomposed by hydrochloric acid, with (separation of gelatinous silica. Obs. Occurs in mica slate, granite, pyenite, trap, basalt, and volcanic rocks, and is often associated with nephelite (or eleeolite) and eudialyte. Found in West Greenland ; on Monte Somma; in Sicily; at Miask, in the Ural; near Bre^ig, Norway. A blue variety occurt at Litchfield, Me., and at Salem, Mass. MICROSOMMITE. Occurs in very minute hexagonal crystals in masses of leucitic lava ejected from Mt. Somma. Composition : a unisilicate of potassium, calcium, and aluminum, with small quantities of sodium chloride and calcium sulphate. 318 DESCRIPTIVE MINERALOGY. HAUYNITE. Isometric. In dodecahedrons, octahedrons, etc. Cleavage : dodecahe- dral distinct. Commonly in rounded grains often looking like crystals with a fused surface. H.= 5*5-6. G.=2'4-2'5. Lustre vitreous, to somewhat greasy. Coloi bright blue, sky-blue, greenish-blue ; asparagus-green. Streak slightly bluish to colorless. Subtransparent to translucent. Fracture flat conchoi- dal to uneven. Comp. 2Na 2 (Ca)AlSi20 8 +CaSO4 ; if in the silicate Na 2 is replaced by Ca, the atomic ratio here being 5 : 1, this gives Silica 34 '13, alumina 2918, lime 10'62, soda 14-69, sulphur trioxide=100. A little potassium is also often present. Pyr., etc. In the closed tube retains its color. B.B. in the forceps fuses at 4 '5 to a white glass. Fused with soda on charcoal affords a sulphide, which blackens silver. Decomposed by hydrochloric acid with separation of gelatinous silica. Obs. Occurs in the Vesuvian lavas, on Somma ; in the lavas of the Campagna, Rome ; in basalt at Niedermendig and Mayen, L. Laach, etc. NOSITE (Nosean). A plious mixtures of these two members irt different proportions. They have then the general formula j ^a.AlSieO'e)' Forlabradc ^ te the ratio of m : tt is mostly 3 : 2, also 3 : 1, etc.; for andesite the ratio of m : n varies about 1 : 2, and f or oligoclase the ratio of m : n is 3 : 10, also 1 : 3, etc. In accordance with the above formula, if Ca : Na=6 : 1, then Al : Si= 1 : 2-308; for Ca : Na=3 : 1, Al : Si=l : 1'257; for Ca : Na=l : 1, Al : Si=l : 3'33 ; for Ca : Na=l : 3, Al : Si=l : 4'4 ; for Ca : Na=i : 6, Al : Si=l : 5. This method of vie wing the feldspar species has the advantage of explaining the wide varia- tion in their composition, and is generally accepted among German mineralogists. DesCloi- eeaux regards his observations upon the optical characters of the feldspars (see p. 298) ai showing that they are in fact distinct species, and not indeterminate isomorphous mixtures 320 DESCRIPTIVE MINERALOGY. Optical properties of the triclinic feldspars. The following table contains the more import' ant optical properties of the feldspar species as determined by DesCloizeaux (C. K,., Feb. 8. 1875, and April 17, 1876). Bx= Bisectrix. Acute bisectrix. ... ... ANOBTHITE. always LABKADOBITE. always + OLIGOCLASE. generally ALBITE. always 4- MlCBOCLINE. always Angle made by the+Bx. with a normal to i-l (g) Same, with normal to 0(p) Position of the Bx. has no simple relation to the planes 30 40' 56 sometimes + 18 10' 68 15 78 35' 15 26' Angle made by the line in which the plane of . the optic-axes cuts i-l, with edge i-l/0(g' /p). Same, with edge i-l I (a 1 m) observed on the crvs- tals. 27-28 3725'-36~25' Line parallel to the edge 0\i-l. U U 20 96 28' (front) 5 6' Ordinary dispersion. . . . Parallel or perpendicular to plane of polariza- tion. Optic-axial angle (in air) for red rays. p < *(-Bx.) Inclined. 84 58' p > ?(+Bx.) Crossed; also slight in- clined. 88 15' p < 0(4- Bx.) Crossed; also slight ill" dined. 89 35' p < ?(4-Bx.) Inclined ; probably also slight hori- zontal. 80 39' P < 0(4- Bx.) Horizontal (-Bx.) also inclined (+BX.) 87 54' for blue rays 85 59' (Somma) 87 48' (Labrador) 88 C 31' (Sunstone, Tvedestrand) 81 59' (Roc tourne) Amazonst'ne, Mursinsk. The axial divergence is quite constant for albite, labradorite, and anorthite, but varies for oligoclase even in different sections taken from the same specimen. Andesine (q. v.) ia regarded by DesCloizeaux as an altered oligoclase. DesCloizeaux gives the following method of distinguishing between the feldspars by optical means : It is necessary to obtain a transparent plate parallel to the easiest cleavage ( 0). Such sections obtained from crystals or lamellar masses of albite, oligoclase, labradorite, and the majority of those of microcline, show hemitropic bauds, more or less close together, arranged along the plane parallel to the second cleavage (i-l) for orthoclase and microline in simple crystals, two sections placed in opposite positions serve to produce the same effect. These sections are thus brought between the crossed Nicols of a polarization-microscope. (1) For orthoclase the maximum extinction takes place when the two sections are parallel to their plane of contact ; the edge 0/i-l being in the plane of polarization of the micro- scope. (2) For microcline, the whole structure consists of a multitude of very fine parallel bands ; the section may show microcline alone, either hemitropic or not hemitropic, or microcline and orthoclase ; the extinction can take place at 30 54' between the adjoining bands of the same plate of the macle (microcline alone), at 30 54' between the two plates of the made (micro- cline in bands), or at 15 C 27' between the adjoining bands (microcline and orthoclase). In the last case the whole of two lamellae of the macle show at the same time an extinction oblique to the plane of composition, belonging to the microcline, and one parallel to this plane for the orthoclase. (3) For albite, the extinction between two bands takes place at an angle of 6 32'. (4) For oligoclase, the extinction is simultaneous in the two bands, and when the plane of composition coincides with the plane of polarization of the polariscope, it shows that the structure is homogeneous. (5) For labradorite, the extinction takes place at 10 24' between the alternate lines of the hemitropic lamellae. It follows from this tha* a plane normal to the plane of the axes cuts the base along a line making with the edge Q/i-l the following angles: in orthoclase, 15 27' in microcline, 3 16' in albite, 5 12' in labradorite. A variation of one or two degrees from the above mean angles was observed in some pcoimens. See further on p. 426. OXYGEN COMPOUNDS ANHYDEOUS SILICATES. 321 Diff. The feldspars are distinguished from other species by the characters already stateu. prominent among which are : cleavage in two directions, nearly or quite at right angles tc each other ; also hardness, etc. The triclinic feldspars can in most cases be distinguished from orthoclase by the fine stria- ;ion due to repeated twinning. This striation can often be seen by the unaided eye upon the cleavage face (0). And its existence can always be surely tested by the examination of a thin section in polarized light, the alternate bands of color showing the same fact. The separation of the different triclmic species can be surely made by complete analysis only, or at least by the determination of the amount of alkali present. The degree of fusi- bility, the color of the flame, and the effect produced by digestion in acids, are often import- ant aids. In the hands of a skilled observer the optical examination may give decisive results. ANORTHITE. Indianite. Triclinic. i : I : a = 0-86663 : 1-57548 : 1. /A 1' = 120 (over 24) = 94 10', O f\ ! = 114 6', O A I '= 110 40', A 24 = 98 46' ; a = 93 13^', j3 = 115 55J', 7 = 91 Hi' Cleavage : 0, i4 perfect, the latter least so. Twins similar to those of albite. Also mas- sive. Structure granular, or coarse lamellar. H.=6-7. G. 2-66-2-78. Lustre of cleavage planes inclining to pearly ; of other faces vitreous. Color white, grayish, reddish. Streak uncolored. Transparent translucent. Fracture conchoidal. Brittle. Var. Anorthite was described from the glassy crystals of Som- ma. Indianite is a white, grayish, or reddish granular anorthite from India, first described in 1802 by Count Bournon. Oomp Q. ratio for R : Al : Si=l : 3 : 4. Formula CaAlSi 2 8 = Silica 43-1, alumina 36-8, lime 20-1=100. The alkalies are sometimes present in very small amounts. Pyr., etc. B.B. fuses at 5 to a colorless glass. Decomposed by hydrochloric acid, with separation of gelatinous silica. Obs. Occurs in some granites; occasionally in connection with gabbro and serpentine rocks ; in some cases along with corundum ; in many volcanic rocks. Found in the old lavas in the ravines of Monte Somma ; Pesmeda-Alp, Tyrol ; in the Faroe islands ; in Iceland ; near Bogoslovsk in the Ural, etc. BYTOWNITE has been shown by Zirkel to be a mixture. Bytown, Canada. LABRADORITE. Triclinic. lhf = 121 ' 37', r\i-l 93 20', O l\ 1 110 50', = 113 34' ; Marignac. Twins : similar to those of albite. Cleavage : O easy ; i-l less so ; /traces. Good crystals rare ; generally massive granular, and in grains cleavable ; sometimes cryptocrystalline or hornstone-like. , H. 6. G.=2-67-2'76. Lustre of O pearly, passing into vitreous; elsewhere vitreous or subresinous. Color gray, brown, or greenish, some- times colorless and glassy; rarely porcelain-white; usually a change of colors in cleavable varieties. Streak uncolored. Translucent subtrans- lucent. Comp., Var Q. ratio for R : Al : Si=l : 3 : 6, but varying somewhat (see p. 319). Formula RAlSi 3 Oi ; here R=Ca and Na 2 . The atomic ratio for Na : Ca~ 2 : 3 generally, this corresponds to Silica 52-9, alumina 30 '3, lime 12 '3, soda 4'5=100. Var. 1. Cleavable. (a) Well crystallized to (b) massive. PJay of colors either -wanting, M 21 322 DESCRIPTIVE MINERALOGY. in some colorless crystals ; or pale ; or deep ; blue and green are the predominant colors ; but yellow, fire-red, and pearl-gray also occur.' By cutting very thin slices, parallel to i-i, from the original labradorite, they are seen under the microscope to contain, besides striae, great numbers of minute scales, like the aventurine oligoclase, which are probably gothite or hema- tite. These scales produce an aventurine effect which is quite independent of the play of colors which arises from the interference of the rays of light reflected by innumerable inter- nal lamellae (ReuxGh). The various forms of minerals (micropktkites, microphyllites, etc. ) en- closed in the labradorite, and their relation to it in position, have been thoroughly investigated by Schrauf (Ber. Ak., Wien, Dec., 1869). Pyr,, etc. B. B. fuses at 3 to a colorless glass. Decomposed with difficulty by hydrochloric acM generally leaving a portion of undecomposed mineral. Otys. Labradorite is a constituent of some rocks, both metamorphic and igneous; e.g., diabase, doleryte, basalt, etc. The labradoritic metamorphic rocks are most common among the fcibmationb of the Archaean or pre-Silurian era. Such are part of those of British America, northern New York, Pennsylvania, Arkansas; those of Greenland, Norway, Finland, Sweden, and pifobably of the Vosges. Being a feldspar containing comparatively little silica, it occurs mainly in rocks which include little or no quartz (free silica). Kiev/ .has furnished fine specimens ; also Labrador. It is met with in many places in Car-iia East. Occurs at Essex Co., N. Y. ; also in St. Lawrence, Warren, Scoharie, and (*ren Cos. In Pennsylvania, at Mineral Hill, Chester Co. ; in the Witchita Mts., Arkansas, etc.' Labradorite was first brought from the Isle of Paul, on the coast of Labrador, by Mr. Wolfe, a Moravian missionary, about the year 1770, and was called by the early mineralogists Labra- dor stone (LabradoTistdri), and also chatoyant, opaline, or Labrador feldspar. Labradorite receives a fine polish, and owing to the chatoyant reflections, the specimens ar often highly beautiful. It is sometimes used in jewelry. MASKELYNITE. Occurs in transparent, isometric, grains in the meteorite of Shergotty. Same composition as labradorite. ANDESITE. Andesine. Triclinic. Approximate angles from Esterel crystals (DesCl.) : A i-l, left, S7-88, O A /= 111-112, O/\T = 115, I l\i-l = 119-120, /' Ai-l =120, ^A2-i = 101-102. Twins: resembling those of albite. Sel- dom in crystals. Cleavage more uneven than in albite. Also granular massive. II. =5- 6. G.^2'61-2'74:. Color white, gray, greenish, yellowish, flesh- red. Lustre subvitreous, inclining to pearly. Comp. Q. ratio 1:3:8, but varying to 1 : 3 : 7. General formula KAlSi 4 Oi 2 ; R=Na 2 and Ca in the ratio 1 : 1 to 3 : 1 ; if the ratio is 1 : 1, the formula corresponds to Silica 59 '8, alu- mina 25-5, lime 7'0, soda 7-7=100. Pyr., etc. Andesite fuses in thin splinters before the blowpipe. Saccharite melts only on thin edges ; with borax forms a clear glass. Imperfectly soluble in acids. Obs. Occurs in many rocks, especially some trachytes. The original locality was in the Andes, at Marmato ; also in the porphyry of TEsterel, France ; in the Vosges Mts. ; at Vap- nefiord, Iceland, in honey-yellow transparent crystals, etc. In North America, found at Chateau Richer, Canada, forming with hypersthene and ilmenite a wide-spread rock ; color flesh-red. Andesite is regarded by DesCloizeaux as an altered oligoclase, but many careful analyse! point to a feldspar having the composition given above. HYALOPHANE. Monoclinic, like orthoclase, and angles nearly the same. 6 r =6-i16', f A /= 118 41', A l-i = 130 55'. Cleavage : O perfect, iA somewhat less so. In small crystals, single, or in groups of two or three. OXYGEN COMPOUNDS ANHYDROUS SILICATES. 323 II. 6-6*5. G.=2'SO, transparent ; 2'905, translucent. Lustre vitreous like that of adularia. Color white, or colorless ; also flesh-red. Trans- parent to translucent. Comp. Q. ratio f or R : R : Si=l : 3 : 8. Formula (Ba,K 2 )AlSi 4 12 . Analysis of hyalo- phane from the Binnenthal by Stockar-Escher, Si0 2 52'67, A10 3 21-12, MgO 0'04. CaO 0'4G, BaO 15-05, Na 2 214, K 2 O 7-82, H 2 O "58 = 99 "88. Pyr., etc. B.B. fuses with difficulty to a blebby glass. Unacted upon by acids. Obs Occurs in a granular dolomite near Imfeld, in the Binnenthal, Switzerland ; also i\i Jakobsberg in Sweden. OLIGOCLASE. Triclinic. /A T = 120 42', A H ov. 24' = 93 50', A 1= 110 55', A T = 114 40'. Cleavage : O, i-l perfect, the latter least so. Twins : similar to those of albite. Also massive. H. = 6-7. G.=2-56-2-72; mostly 2-65-2-69. Lustre vitreo-pearly or waxy, to vitreous. Color usually whitish, with a faint tinge of grayish- green, grayish-white, reddish-white, greenish, reddish ; sometimes aventnrine. Transparent, subtranslucent. Fracture conchoidal to uneven. Comp., Var. Q. ratio for R : Al : Si 1 : 3 : 9, though with some variations (see p. 297). Formula RAlSi^Ou, with R=Na2(K 2 ),Ca The rat'O of 3 : 1 for Na : Ca corresponds in this formula to Silica 61-9, alumina 24'1, lime 5 "2, soda 8 '8=100. Var. 1. Cleavable ; in crystals or massive. 2. Compact massive ; oUgodase-felsite; includes part, at least, of the so-called compact feldspar orfelsite, consisting of the feldspar in acorn- pact, either fine granular or flint-like state. 3. Aventurine oUgockise, or sunstone. Color grayish-white to reddish-gray, usually the latter, with internal yellowish or reddish fire-like reflections proceeding from disseminated crystals of probably either hematite or gothite. 4. Moonstone pt. A whitish opalescence. Pyr., etc. B.B. fuses at 3'5 to a clear or enamel-like glass. Not materially acted upon by acids. Obs. Occurs in porphyry, granite, syenite, serpentine, and also in different eruptive rocks. It is sometimes associated with orthoclase in granite, or other gTanit s-like rocks. Among its localities are Pargas in Finland ; Schaitansk, Ural ; in protogine of the Mer-de-Glace, in the Alps ; in fine crystals at Mt. Somma ; as sunstone at Tvedestrand, Norway ; in Iceland, colorless, at Hafnefjord (Jiafnefiordite). In the United States, at Unionville, Pa. ; also at Haddam, Ct. ; Mineral Hill, Delaware Co., Pa. ; at the emery mine, Chester, Mass. Named in 1826 by Breithaupt from oA/yw;, little, and /c/liw, to cleave. TSCHERMAKITE (v. Kobell). Supposed to be a magnesia-feldspar, but the conclusion was probably based on the analysis of impure material. Later investigations (Hawes, Pisani) make it an oligoclase. Occurs with kjerulfine from Bamle, Norway. ALBITE.* Triclinic, 7 A I = 120 47', O A i-l = 93 36', A T = 114 42', A / .= 110 50', O A 24' = 136 50', O A 2-2 = 133 14'. Cleavage: 0, i-l perfect, the first most so ; 14 sometimes distinct. Twins: twinning-planc i-iy axis of revolution normal to i-i, this is the most common method, and its repetition gives rise to the fine striations (p. 91) upon the plane A l-i = 129 41', 6> A 2-* = 99 38', O A 2 98 4'. Cleavage : (9 perfect; i-l less distinct; ^' faint; also imperfect in the direction of one of the faces I. Twins: twinning-plane, i-i (Carlsbad twins) f. 582, but the clinopinacoid (i-i) the composition-face (see p. 98) ; twinning-plane the base (O) f. 583 ; also the clinodorne, 2-i (Baveno twins), as in f. 588, in which the prism is made up of two adjoining planes O and two i-i, and is nearly square, because A i-i = 90, and A 24 = 135 3' ; /A /= 169 28' ; also the same in a twin of 4 crystals, f . 587, each side of the prism then an O (see also p. 99). Often massive, granular ; sometimes lamellar. Also compact crypto-crystalline, and sometimes flint-like or jasper-like. 580 581 582 Loxoclase. H.=6-6-5. G. = 2-44-2-62, mostly 2-5-2-6. Lustre vitreous; on cleav- age-surface sometimes pearly. Color white, gray, flesh-red, common; greenish-white, bright-green. Streak nncolored. Transparent to trans- lucent. Fracture conchoidal to uneven. Optic-axial plane sometimes in the orthodiagonal section and sometimes in the clinodiagonal ; acute bisec- trix always negative, normal to the orthodiagonal. Oomp., Var. Q. ratio for K : Al : Si=l : 3 : 12. Formula K 2 AlSi 6 O 16 =Silica 64'7, alu- mina 18'4, potash 16'9 = 100; with sodium sometimes replacing- part of the potassium. The orthoclase of Carlsbad contains rubidium. The varieties depend mainly on structure, varia- tions in angles, the presence of soda, and the presence of impurities. The amount of sodium detected by analyses varies greatly, the variety sanidin, (see below) sometimes containing 6 per cent. The variations in angles are large, and they occur some- times even in specimens of the same locality. The crystal] ization is normally monocJinic, and the variations are simply irregularities. There are also large optical variations in ortho- clase, on which see DesCl. Min., i., 329. Var. 1. Ordinary. In crystals, or cleavable massive. Adularia (adular). Transparent, cleavable, usually with pearly opalescent reflections, and sometimes with a play of colors like labradorite, though paler in shade. Moonstone belongs in part here, the rest being al bite and oligoclase. Sunstone, or aventurine feldftpar : In part orthoclase, rest albite or oligoclase (q. v.). Amazonstone: Bright verdigris-green, and cleavable, mostly mixtures of orthoclase and microcline (Dx.). Koenig concludes that the coloring matter of the Pike's Peak amazon- etone is an organic compound of iron, which has been infiliTated into the mass. Sanidin of Nose, or glassy feldspar (including much of the Ice-spar, part of which is anor- 326 DESCRIPTIVE MINERALOGY. thit?). Occurs in transparent glassy crystals, mostly tabular (whence the name from cavi^, a board), in lava, pumice, trachyte, phonolite, etc. Proportion of soda to potash varies from 1 : 20 to 2 : 1. Mhyacolite is the same ; the name was applied to glassy crystals from Mt. Somma (Eisspath, 'Wern.). Ghesterlite. In white crystals, smooth, but feebly lustrous, implanted on dolomite in Ches- ter Co. , Penn., and having wide variations in its angles. It contains but little soda. Accord- ing to DesCloizeaux the chesterlite consists of a union of parallel bands of orthoclase and a triclinic feldspar of the same composition, which he calls microcline (see below). Loxodase. In grayish- white or yellowish crystals, a little pearly or greasy in lustre, often large, feebly shining, lengthened usually in the direction of the clinodiagonal. A 7=112" 80', 0A/' = 112 50', jAi'^120 20', 0/\i-l (cleavage angle) =90 D , Breith. G.=2'6-2'62, Plattner. The analyses find much more soda than potash, the ratio being about 3:1, but how far this is due to mixture with albite has not been ascertained. From Hammond, St. Lawrence Co., N. Y. Named from A.o|J>, transverse, and /cAaw, / cleave, under the idea that the crystals are peculiar in having cleavage parallel to the orthodiagonal section. Perthite. A flesh-red aventurine feldspar, consisting of interlaminated albite and orthoclase, as shown by Breithaupt. From Perth, Canada East. COMPACT ORTHOCLASK or ORTHOCLASE-HELSITE. This crypto-crystalline variety is com- mon and occurs of various colors, from white and brown to deep red. There are two kinds (a) fhe jasper-like, with a subvitreous lustre ; and (b) the ceratoid or wax-like, with a waxy lustre. Some red kinds look closely like red jasper, but are easily distinguished by the fusi- bility. The orthoclase differs from the albite felsite in containing much more potash than soda. The Swedish name Halleflinta means false flint. Pyr., etc. B.B. fuses at 5 ; varieties containing much soda are more fusible. Loxoclase fuses at 4. Not acted upon by acids. Obs. Orthoclase is an essential constituent of many rocks ; here are included granite, gneiss, and mica schist; also syenite, trachyte, phonolyte, etc., etc. Fine crystals are found at Carlsbad in Bohemia ; Katherinenburg, Siberia ; Arendal, Nor- way ; Baveno in Piedmont ; in Cornwall ; in the Urals ; the Mourne mountains, Ireland, etc.; in the trachyte of the Drachenf els on the Rhine. In the U. States, orthoclase is found in N. Hamp., at Acworth. In Conn., at Haddam and Middletown. In N. York, at Rossie ; in the town of Hammond ; in Lewis Co. ; near Natural Bridge ; in Warwick ; and at Amity and Edenville. In Penn., in crystals at Leiperville, Delaware Co., etc. In N. Car., at Washington Mine, Davidson Co.; beautiful Amazonstone at Pike's Peak, Col. Massive ortho- clase is abundant at many localities. MICROCLINE.* A triclinic potash feldspar. The name microcline was originally given by Breithaupt to a whitish or reddish feldspar from the zircon-syenite of Fredericksvarn and Brevig, Norway, on the ground that it was triclinic. It was shown by DesCloizeaux that this feldspar was merely a variety of orthoclase remarkable for its large amount of soda. Recently the latter author has proposed to retain this name for a feldspar found in the midst of gran- ites, pegmatite, and gneiss, which is shown both by the angle between its cleavage planes, and also by its optical properties, to be really triclinic. Form generally like that of orthoclase. Cleavage basal and clinodiagonal, and also easy parallel to both prismatic faces (1 and 1") ; for the optical properties see p. 298. Often asso- ciated with orthoclase in regular parallel bands, especially in the amazonstone ; albite is also hometimes present, though irregularly. Analysis of a "pure microcline " from Magnet Cove byPisani. GK=2'54. Si0 2 A10 3 FeO 3 KoO NaoO ign. 6430 19-70 0-74 15 "60 0'48 0'35 =101 '17 The association of orthoclase and microcline was observed in specimens from the Ilmen Bits.; Urals ; Arendal ; Greenland; Labrador; Leverett,Mass.; Delaware, Chester Co., Penn.; Pike's Peak, Col. The purest microcline was that of a greenish color from Magnet Cove, /brk. ; it enclosed crystals of asgirite, and was not mixed with orthoclase. SUBSILICATES. Humite or Chondrodite Groivp, including three snb-species : L Humite j II. Chondrodite ; III. Clinohumite. The existence of three types of forms among the crystals of humite (Vesuvius) was early tthown by Scacchi ; they have since then been further investigated by vom Rath (Pogg. Erg., OXYGEN COMPOUNDS ANHYDROUS SILICATES. 327 Bd. -v., 321, 1871 ; ibid., vi., 385, 1873). The chemical identity of the species humite and chondrodite was shown by llamrnelsberg ; later Kokscharof proved that the crystals of chon- drodite from Pargas, Finland, were identical in form and angles with Scacchi's type II, of humite, and the same has also been shown of the Swedish crystals by vom Rath. In 1870 the author described crystals of chondrodite from Brewster, N. Y. , belonging to each of the three types of humite ; he showed, moreover, then and later (Feb., 1876), that contrary to what had been previously assumed, the crystals of both type II. and type III. were monoclinic, not orthorhombic. DesCloizeaux and Klein have since proved (Jahrb. Min., 1876, No. 0) the monoclinic character of type III. of the Vesuvian humite, and the former that of the, Swedish crystals (type II.) ; he, moreover, proved the orthorhombic character of the crystals of type I. , Vesuvius. In accordance with these facts DesCloizeaux has proposed that the three types be regarded as distinct species, with the names given above. I. HUMITE.* In eluding type L, Scacchi, Vesuvius. Also rare crystals from Brewster, N. Y. The latter large, coarse, and having suffered more or less alteration. Orthorhombic. Holohedral. i-2 (o 2 ) A i -2 130 19' ; 6> (J.) A 34 (^ 3 ) = 16' ; 6> A 3-2 (e 5 ) = 103 47' ; 6> A l-S ( e 3 ) = 126 , v, /x ^ -* (y 3 ) = 121 44'. Twins : twinning-plane -|-2, also -f-2, in both cases the angle of the horizontal prism is nearly 120. Optic-axial plane parallel to the base, acute bisectrix positive, normal to i-l. Dispersion almost zero. 2Ha = 7S 18' -79 for red rays. (DesCl.) 102 48' ; O A 14 (**) = 124 21' O A 1-2 (V 3 ) = 121 Vesuvius. Brewster. Brewster. El. CHONDRODITE.* Including type II. of Scacchi, Vesuvius ; also crystals from Finland, Sweden, and with few exceptions those of Brewster, N. Y. Monoclinic. Ar\i= 122 29' ; A A # = 109 5' ; Ah#' = 108 58' ; A:n*=W3 12'; A A?i 2 ' = 103 9'; A A r 1 = 135 20' ; ^A/* = 125' 50'; C A r* = 146 24'; 6 y A n 2 = 135 40' : C f\n j = 135 41'. The letters (those employed by Scacchi) correspond to the following symbols A=O i = l-l 4 47' ; =132 56 X 6 r A r 4 = 137 25 X . DesCloizeaux. These letters (those employed by Scacchi) correspond to the following symbols : A=O =4 n= C =i4 r 8 = 8-2 DesCloizeaux makes the plane e*' i-i, ^ = /, and r 4 = 1, and r 5 = 1. Twins: twinning-plane J-^; also the basal plane (Brewster). Optic-axial plane makes an angle of 7i with the base, Brewster (Dana) ; same angle for Vesuvian crystals equals 12 28' (Klein), about 11 (DesCl.X Acute bisectrix positive, normal to clinopinacoid. 2Ha=84 40'-85 15', yellow (Kl.).=84 38'-85 4' white crystals, and =86 40'-87 14' brown crystals (DesCl.). Sections of crystals often shows a complex twinned structure. In other physical and in chemical characters these three sub-species are hardly to be distinguished. H.:=6-6-5. G.=3-118-3-24. Lustre vitreous resinons. Color of crystals yellowish-white, citron -yellow, honey -yellow, hyacinth-red, brownish (Vesuvius); also deep garnet-red (Brewster)." Color of the mineral occur- ring massive and in rounded imbedded grains (chondrodite at least in part) as of crystals, also sometimes olive-green, apple-green, gray, black. Streak white, or slightly yellowish, or grayish. Transparent subtransluceut Fracture subconchoidal uneven. OXYGEN COMPOUNDS ANHYDROUS SILICATES. 329 Comp. The chemical investigations of Rammelsberg and vom Rath have served to show a considerable variation in composition in the different varieties, but do not give decidedly different formulas to the three types of Scacchi, that is, the three minerals described above. In general Q. ratio for Mg : Si=4 : 3 (!$ : 1), and the formula then MgeSiaOu ; or, as pre- ferred by Rammelsberg, Mg : Si=5 : 4 (1 : 1), and the formula is then Mg 3 Si 2 O B . In all cases part of the magnesium is replaced by iron, and part of the oxygen by fluorine (F 2 ), the amount varying from 2 to 8J p. c., but certainly not dependent (v. Rath and Ramm.) upon the three types. Analyses : I. Humite, Vesuvius, II. Chondrodite, Vesuvius, II. Chondrodite, Brewster, II. Chondrodite, Sweden, III. Clinohumite, Vesuvius, SiO 2 35-63 33-26 3410 33-96 36-82 Chondrodite (?), N. Jersey, 33 -97 FeO 5-12 2-30 7-28 6-83 5-48 3-48 MgO 54-45 57-92 53-72 53-51 54-92 56-97 F 2-43 5-04 4-14 4-24 2-40 7-44 CaO 0-23 A10 3 0'82=99-68, v. Rath. CaO 0-74 A1O 3 1'06=1 00-32, Ramm. A1O 3 0-48=99-72, Hawes. 3 0-72=99-26, v. Rath. 3 0-24=99-86, v. Rath. =101-68, Ramm. Pyr., etc. B.B. infusible ; some varieties blacken and then burn white. Fused with salt of phosphorus in the open tube gives a reaction for fluorine. With the fluxes a reaction for iron. Gelatinizes with acids. Heated with sulphuric acid gives off silicon fluoride. Diff. Distinguishing characters are : infusibility ; gelatinizing with acids ; fluorine reac- tion with sulphuric acid. Obs. The localities of the crystallized minerals have already been mentioned. The granular Chondrodite (?) occurs mostly in limestone. It is found in Finland and in Sweden ; at Taberg in Wermland ; at Boden in Saxony ; on Loch Ness in Scotland ; at Achmatovsk in the Ural, etc. Abundant in the counties of Sussex, N. J. , and Orange, N. Y., where it is associated with spinel. In N. Jersey, at Bryam ; at Sparta ; at Vernon, Lockwood, and Franklin. In N. York, in Orange Co. , in Warwick, Monroe, etc. ; near Edenville ; at the Tilly Foster Iron Mine, Brewster, Putnam Co. In Mass. , at Chelmsf ord. In Penn. , near Chadsford. In Canada, in limestone at St. Crosby ; St. Jerome ; St. Adele ; Grenville, etc., abundant TOURMALINE.* Turmalin, Germ. Khombohedral. fif\R = 103, O Ml = 134 3' ; = 0-89526. J A J =. 596 597 598 599 600 Gouverneur, N. Y. St. Lawrence Co. , N. Y. 154: 59', i A i = 133 8', *-2 A g = 155 14', i-2 A i 3 = H2 26'. Usually 330 DESCRIPTIVE MINERALOGY. hemihedral, being often unlike at the opposite extremities, or hernimorphic, and the prisms often triangular. Cleavage : 72, J. and *-2, difficult. Sometimes massive compact; also columnar, coarse or fine, parallel or divergent. 11.=: 7-7*5. G. 2'94-3'3. Lustre vitreous. Color black, brownish- black, bluish-black, most common ; blue, green, red, and sometimes of rich shades ; rarely white or colorless ; some specimens red internally and green externally ; and others red at one extremity, and green, blue, or black at the other. Dichroic (p. 165). Streak uncolored. Transparent opaque ; greater transparency across the prism than in the line of the axis. Frac- ture subconchoidal uneven. Brittle. Pyroelectric (p. 169). Var. 1. Ordinary. In crystals, (a) Rubellite ; the red sometimes transparent, (b) Indi- colite ; the blue, either pale or bluish -black ; named from the indigo-blue color, (c) Brazilian Sapphire (in jewelry) ; Berlin-blue and transparent ; (d) Brazilian Emerald^ Chrysolite (or Peridot) of Brazil ; green and transparent, (e) Peridot of Ctylon ; honey-yellow. (/) Ach- roite ; colorless tourmaline, from Elba, (g) Aphrizite; black tourmaline", from Krageroe, Norway, (h) Columnar and black ; coarse columnar. Resembles somewhat ho>nblende, but nas a more resinous fracture, and is without distinct cleavage or anything like a fibrous appearance in the texture. Comp. Q. ratio of all varieties for R : Si=3 : 2 (Rammelsberg), consequently the general nil ii formula is R 3 (R 6 ,R)SiO 6 . R may represent here H, K, Na, Li ; also R=Mg(Ca).Fe,Mn, and R=A1,B.2 ; further than this the Si is often in part replaced by F 2 . Rammelsberg distin- guishes two groups, where the Q. ratio for B : iVl : Si 3 : G : 8, and (2) with the Q. ratio for B : Al : Si=l : 3 : 3. In the first group fall most of the yellow, brown, and black varieties, ii i the bivalent elements (Mg,Fe) predominating, the general formula being R 3 (Re)RnSi 4 2 o. The second group includes the colorless, red, and slightly green kinds, the univalent elements appearing most prominent, especially lithium. The general formula is R 6 (R 3 )RbSiuO4 5 . Several distinct varieties are made under these groups, which will be sufficiently illustrated by the following analyses, by Rammelsberg. I. Gouverneur, brown.; G. =3*049. II. Haddam, black; G.=3"136. III. Goshen, bluish-black; G.=3 203. IV. Paris, Me., red; G.=3'019. V. Chesterfield, Mass., green; G.=3'069. SiO 2 B 2 3 A10 3 FeO MnO MgO CaO Na 2 O K 2 O Li 2 O F H 2 O I. 38-85 (8-35) 31'32 114 1489 1-60 1-28 0-26 2'31=100'00 II. 37-50 (9-02) 30-87 8'54 8-60 1-33 1'GO 0'73 1-81 = 100-00 III. 36-22 10-65 33-35 11-95 1'25 0'63 1-75 0'40 0'84 082 2-21 = 100-82 IV. 38-19 9-97 42-63 1-94 0'39 0-45 2'60 0"68 1-17 1-18 2 00=100'20 V. 38-46 9-73 36-80 6-38 078 1-68 2-47 0'47 0-72 0'55 2-31 = 100-55 Fyr., etc. I. fuse rather easily to a white blebby glass or slag ; II. fuse with a strong heat to a blebby slag or enamel ; III. fuse with difficulty, or, in some, only on the edges ; IV. fuse on the edges, and often with great difficulty, and some are infusible ; V. infusible, but becom- ing white or paler. With the fluxes many varieties give reactions for iron and manganese. Fused with a mixture of potassium bisulphate and fluorite gives a strong reaction for boracic acid. By heat alone tourmaline loses weight from the evolution of silicon fluoride and per- haps also boron fluoride ; and only after previous ignition is the mineral completely decom- posed by fluohydric acid. Not decomposed by acids (Ramm. ). After fusion perfectly decom- posed by sulphuric acid (v*. Kobell). Diff. Distinguished by its form, occurring commonly in three-sided, or six-sided prisms ; absence of cleavage (unlike hornblende). It is less easily fusible than garnet or vesuvianite. B.B. (see above) gives a green flame (boron). Obs. Tourmaline is usually found in granite, gneiss, syenite, mica, chloritic or talcose schist, dolomite, granular limestone, and sometimes in sandstone near dykes of igneous rocks. The variety in granular limestone or dolomite is commonly brown. Prominent localities are Katherinenburg in Siberia ; Elba ; Windisch Kappell in Carinthia ; Rozena ; Airolo, Switzerland ; St. Gothard. In Great Britain. Bovey Tracey in Devon ; Cornwall, at different localities ; Aberdeen in Scotland, etc. In the U. States, in Maine, at Paris and Hebron. In Mass., at Chesterfield ; at Goshen, blue. In N. Hamp. t Graf ton ; Acworth, etc. In Conn., at Monroe and Haddam, black, in 2f. York, OXYGEN COMPOUNDS ANHYDROUS SILICATES. 331 aear Gouverneur; near Port Henry, Essex Co., enclosing orthoclase (see p. 109) ; Pierrepont; near Edenville. In Penn. , near Unionville; at Chester; Middletown, and elsewhere. In Canada, at G. Calumet Id. ; at Fitzroy, C. W. ; at Hunterstown, C. E. ; at Bathurst an EJmsley, C. W. GEIILENITE. Tetragonal. Color grayish-green. Q. ratio for R : R : Si=3 : 3 : : 4, or 3 ! : 2 for bases and silicon. Formula Ca 3 RSi 2 10 , with ft=rVl : Fe=5 : 1 ; this requires Silica 29'9, *iumina 21 '5, iron sesquioxide 6'6. lime 4 '20=100. Mt. Monzoni, Fassathal, Tyrol. ANDALUSITE. Orthorhombic. /A 7= 90 48', OM-l= 144 32' ; i : I : d = 0-71241 : 1-01405 : 1. Cleavage : 7 perfect in crystals from Brazil ; i-l less perfect ; i-l in traces. Massive, im 603 - perfectly columnar, sometimes radiated, and granular. H. f-5 ; in some opaque kinds 3-6. G.=3'05- 3-35, mostly 3-1-3-2. Lustre vitreous ; often weak. Color whitish, rose-red, flesh-red, violet, pearl-gray, reddish-brown, olive-green. Streak uncolored.^ Trans- parent to opaque, usually subtranslucent. Fracture uneven, subconchoidal. Var. 1. Ordinary. H. 7-5 on the basal face, if not elsewhere. 2. Ghiastolite (made), Sterling, Mass. Stout crystals having the axis and angles of a different color from the rest, owing to a regu- lar ar-angement of impurities through the interior, and hence ex- haling a colored cross, or a tesselated appearance in a transverse section. H.=3-7'5, varying much with the degree of impurity. The following figure shows sections of some crystals (see also p. 110). it \ Comp. Q. ratio for R : Si=3 : 2 ; AlSi0 6 =Silica 36 -9, alumina 63 -I =100. Sometimes a Ut pyr!^et 3 c! P RB 81 infusible. With cobalt solution gives a blue color. Not decomposed by acids Decomposed on fusion with caustic alkalies and alkaline carbonates. Diff. Distinguishing characters: inf usibility ; hardness; and the form, being n< of a square t>rism, unlike staurolite. , . Obs. Most common in argillaceous schist, or other schists imperfectly crystalline s ; also gneiss, mica schist, and related rocks. Found in Spain, in Andalusia, and thence th( of the species ; in the Tyrol, Lisens valley; in Saxony, at Braunsdorf, and elsewhere. In Ireland. In Brazil, province of Minas Geraes (transparent). Common m crystalline i New England and Canada; good crystals have been obtained in Delaware Co., renn., ew. also in California; in Mass., at Sterling (chiaslolite). FIBROLITE. Bucholzite. Sillimanite. Orthorhombic. /A I 96 to 98 in the smoothest crystals ; usually large;, the faces I striated, and passing into i-z. Cleavage : irt very perfect, b liant. Crystals commonly long and slender, massive, sometimes radiating. Also fibrous or columnar 332 DESCRIPTIVE MINERALOGY. H.=6-7. G.= 3*2-3-3. Lustre vitreous, approaching subadamantine Color hair-brown, grayish-brown, grayish-white, grayish-green, pale olive green. Streak uncolored. Transparent to translucent. Var. 1. SUlimanite In long, slender crystals, passing into fibrous, with the fibres separ- able. 2. Fibrolile. Fibrous or fine columnar, firm and compact, sometimes radiated ; gray ish- white to pale brown, and pale olive-green or greenish- gray. Bucholzite and monrolite are here included ; the latter is radiated columnar, and of the greenish color mentioned. Comp. AlSiOs, as for andalusite^ Silica 36 "9, alumina 63 '1 = 100. Fyr., etc. Same as given under andalusite. Dift Distinguished from tremolite by its infusibility ; also by its brilliant diagonal cleav- age, in which and in its specific gravity it differs from cyanite. Obs. Occurs in gneiss, mica schist, and related metamorphic rocks. In the Fassathal, Tyrol (bucMzite) ; at Bodenmais in Bavaria, etc. In the United States, at Worcester, Mass. Near Norwich, Conn. ; at Chester, near Saybrook (sillimanite). In N. York, in Monroe, Orange Co. (monrolite). In Penn. , at Chester on the Delaware; in Delaware Co., etc. In Delaware, at Brandywine Springs. In N. Carolina, with corundum. Fibrolite was much used for stone implements in western Europe in the " Stone age." W6RTHITE, a hydrous fibrolite ; WESTANITE (Sweden) is related in composition. CYANITE.* Kyanite. Disthene. Triclinic. In flattened prisms ; O rarely observed. Crystals oblong, usually very long and blade-like. Cleavage : i-l distinct ; i-i less so ; O imperfect. Also coarsely bladed columnar to subfibrous. H.=5-7'25, the least on the lateral planes. G.=3'45-3'7. Lustre vit- reous pearly. Color blue, white, blue along the centre of the blades or crystals with white margins ; also gray, green, black. Streak uncolored. Translucent transparent. Var. The white cyanite is sometimes called RTiattizite. Comp. AlSiO 5 = Silica 36'9, alumina 63*1=100, like andalusite and fibrolite. Fyr., etc. Same as for andalusite. Diff, Unlike the amphibole group of minerals in its infusibility ; occurrence in thin-bladed prisms characteristic. Obs. Occurs principally in gneiss and mica slate. Found at St. G-othard in Switzerland ; at Greiner and Pfitsch in the Tyrol; also in Styria ; Carinthia ; Bohemia. In Mass., at Chesterfield, etc. In Conn., at Litchfield ; at Oxford. In Vermont, at Thetford. in Chester Co. ; and Delaware Co. In JW. Carolina. TOPAZ. 3 * Orthorhombic. /A 1 = 124 IT, A 1-i = 138 3' ; c : I : a =0-90243 : 1-8920 : 1. O A 1 = 134 25', 1 A 1, inacr., = 141 0'. Crystals usually hemihedral, the extremities being unlike; habit prismatic. Cleavage; basal, highly perfect. Also firm columnar ; also granular, coarse or fine. H.=8. G-. =3-4-3-65. Lustre vitreous. Color straw-yellow, wine- yellow, white, grayish, greenish, bluish, reddish ; pale. Streak uncolored Transparent subtranslucent. Fracture subconchoidal, uneven. Pyro- OXYGEN COMPOUNDS ANHYDROUS SILICATES. 333 electric. Optic-axial plane i-l ; divergence very variable, sometimes differ- ing much in different parts of the same crystal ; bisectrix positive, noimal to O. 600 610 ' } i Trumbull, Ct. Schneckenstein. O=l : 5 = Oomp. AlSiOs, with part of the oxygen replaced by fluorine (F 2 ) ; ratio of F 2 Silicon 15-17, almninum 29 '58, oxygen 34'67, fluorine 20'58=100. Pyr., etc. B.B. infusible. Some varieties take a wine-yellow or pink tinge when heated. Fused in the open tube with salt of phosphorus gives the reaction for fluorine. With cobalt solution the pulverized mineral gives a fine blue on heating. Only partially attacked by sul- phuric acid. Diff. Distinguishing characters: hardness, greater than that of quartz; inf usibility ; perfect basal cleavage. B.B. yields fluorine. Obs. Topaz occurs in gneiss or granite, with tourmaline, mica, and beryl, occasionally with apatite, fluorite, and tin ore ; also in talcose rock, as in Brazil, with euclase, etc., or in mica slate. Fine topazes come from, the Urals; Kamschatka ; Brazil; in Cairngorm, Aberdeenshire ; at the tin mines of Bohemia and Saxony. Physalite (a coarse variety), occurs at Fossum, Norway ; also in Durango, Mexico ; at La Paz, province of Guanaxuato. In the United States, in Conn., at Trumbull. In N. Car., at Crowder's Mountain. In Utah, in Thomas's Mts. ; from gold washings of Oregon. EUCLASE.* Monoclinic. C = 79 44'= O A i4, If\ f= 115 0', A 14 = 146 45' ; c:b:d = 1-02943 : 1-5446 : 1 = 1 : 1-50043 : 0-97135. Cleavage : i-4 very perfect and brilliant ; O^ i-i much less distinct. Found only in crystals. H. 7'5. G.= 3-098 (Haid.)/ Lustre vitreous, some- what pearly on the cleavage-face. Colorless, pale moun- tain-green, passing into blue and white. Streak un- colored. Transparent ; occasionally subtransparent. Fracture conchoidal. very brittle. r # a 12 Comp. Q. ratio for H : Be : Al : Si=l : 2 : 3 : 4, for R : Si=3 : 2 (H 2 =R, and 3R-:M), formula, H 2 Be a AlSi 2 Oi = Silica 41 '20, alumina 85-22, glucina 17 '39, water 619=100. Pyr., etc. In the closed tube, when strongly ignited, B.B. gives off water (Damour). B.B. in the forceps cracks and whitens, throws out points, and fuses at 5 '5 to a white enamel. Not acted on by acids. ; Obs. Occurs in Brazil, at Villa Rica ; in southern Ural, near the river Sanarka. 334 DESCRIPTIVE MINERALOGY. DATOLITE. Humboldtite. Monoclinic. C= 89 54'= (below) A i-i, /A 7 = 115 3', A 14 = 162 27' ; c:b:d = 0-49695 : 1-5712 : 1. (9 A - 2-*' = 135 13', A 1 ^ 149 33', /A /front = 115 3', 24 A 24, ov. 6>, = 115 21', i-t A *-&, ov. f ?. = 76 18', 44 A 44, ov. #, = 76 88. Cleavage : O distinct. Also botry- oidal and globular, having a columnar structure ; also divergent and radi- ating ; also massive, granular to compact. 612 613 Bergen Hill. Bergen Hill. Arendal. H.=5-5-5. G.=2-8-3 ; 2-989, Arendal,. Haidinger. Lustre vitreous, rarely subresinous on a surface of fracture ; color white ; sometimes gray- ish, pale-green, yellow, red, or amethystine, rarely dirty olive-green or honey-yellow. Streak white. Translucent; rarely opaque white. Frac- ture uneven, subconchoidal. Brittle. Plane of optic-axes 4; angle of divergence very obtuse ; bisectrix makes an angle of 4 with a normal to i-i Var. 1. Ordinary. In crystals, glassy in aspect. Usual forms as in figures. 2. Cojnpact OXYGEN COMPOUNDS ANHYDKOUS SILICATES. 335 massive. White opaque, breaking with the surface of porcelain or Wedgewood ware. From the L. Superior region. 3. Botryoidal ; Botryolite. Radiated columnar, having a botryoidal surface, and containing more water than the crystals. The original locality of both the crys- tallized and botryoidal was Arendal, Norway. Haytorite is datolite altered to chalcedony, from the Hay tor Iron Mine, England. Comp Q. ratio f or H : Ca : B : Sir=l : 2 : 3 : 4, like euclase: formula HoCa 2 B a SiaOio Silica 37-5, boron trioxide 21-9, lime 35-0, water 5 '6 = 100. Botryolite contains 10 -64 p. c. water. Pyr., etc. In the closed tube gives off much water. B.B. fuses at 2 with intumescence to a clear glass, coloring the flame bright green. Gelatinizes with hydrochloric acid. Diff. Distinguishing characters: glassy lustre; usually complex crystallization; B.B. fuses easily with a green flame ; gelatinizes with acids. Obs. Datolite is found in trappean rocks ; also in gneiss, dioryte, and serpentine ; in me- tallic veins ; sometimes also in beds of iron ore. Found in Scotland ; at Arendal ; at Andreas- berg ; at Baveno near Lago Maggiore ; at the Seisser Alp, Tyrol ; at Toggiana in Modena, in serpentine. In good specimens at Roaring Brook, near New Haven ; also at many other localities in the trap rocks of Connecticut ; in N. Jersey, at Bergen Bill ; in the Lake Superior region, and on Isle Royale. San Carlos, Inyo Co., Cal., with garnet and vesuvianite. TITANITE.* SPHENE. Monoclinic. C 60 17' = A i-i ; /A I = 113 31', A l-l = 159 39'; c : b : d 0-56586 : 1-3251 : 1. Cleavage: / sometimes nearly per- fect ; i-i and 1 much less so ; rarely (in greenovite) 2 easy, 2 less so ; sometimes hemimorphic. Twins : twinning-plane i-i ; usually producing thin tables with a reentering angle along one side ; sometimes elongated, as in f. 623. Sometimes massive, compact ; rarely lamellar. Lederite. SpinthSre. Schwarzensteiu. H.=5-5-5. G.=3-4-3-56. Lustre adamantine resinous. Color brown, gray, yellow, green, and black. Streak white, slightly reddish in greenovite 336 DESCRIPTIVE MINERALOGY. Transparent opaque. Brittle. Optic-axial plane i-l ; bisectrix positive, closely normal to l-i (x) ; double refraction strong ; axi{ " very c 53-56 for the red rays, 46-45 for the blue ; DesCl. divergence Oomp., Var. Q. ratio for Ca : Ti : Si 1 : 2 : 2, or making the Ti basic (Ti=2R), U : Si =3:2; formula (equivalent to RSi0 5 ) CaTiSiO s = Silica 30'61, titanic oxide 40'82, lime 28 -57 =100. Var. Ordinary, (a) Titanite ; brown to black, the original being thus colored, also opaque or subtranslucent. (b) Sphene (named from a^v,awedge) ; of light shades, as yellow, green- ish, etc. , and often translucent ; the original was yellow. Manganesian ; Greenomte. Red or rose- colored, owing to the presence of a little manganese. In the crystals there is a great diversity of form, arising from an elongation or not into a prism, and from the occurrence of the elongation in the direction of different diameters of the fundamental form. Pyr., etc. B.B. some varieties change color, becoming yellow, and fuse at 3 with intu- mescence, to a yellow, brown, or black glass. With borax they afford a clear yellowish-green glass. Imperfectly soluble in heated hydrochloric acid ; and if the solution be concentrated along with tin, it becomes of a fine violet color. With salt of phosphorus in R.F. gives a violet bead ; varieties containing much iron require to be treated with the flux on charcoal with metallic tin. Completely decomposed by sulphuric and fluohydric acids. Diff. The resinous lustre is very characteristic ; and its commonly occurring wedge-shaped form. B.B. gives a titanium reaction. Obs. Titanite occurs in imbedded crystals, in granite, gneiss, mica schist, syenite, chlorite schist, and granular limestone ; also in beds of iron ore, and volcanic rocks, and often asso- ciated with pyroxene, hornblende, chlorite, scapolite, zircon, etc. Found at St. Gothard, and elsewhere in the Alps ; in the protogine of Chamouni (pittite, Saus. ) ; at Ala, Piedmont (liqurile) ; at Arendal, in Norway ; at Achmatovsk, Urals ; at St. Marcel in Piedmont (green- ovite, Duf .) ; at Schwarzenstein. Tyrol ; in the Untersulzbachthal in Pinzgau ; near Tavistock ; near Tremadoc, in North Wales. Occurs in Canada, at Grenville, Elmsley, etc. In Maine, at Sanford. In Mass., at Bol- ton ; at Pelham. In N. York, at Gouverneur ; at Diana, in dark-brown crystals (lederite} ; in Orange Co.; near Edenville ; near Warwick. In N. Jersey, at Franklin. In Penn. t Bucks Co., near Attleboro'. GUABINITE. Same composition as titanite, but orthorhombic (v. Lang and Guiscardi) in crystallization. Color yellow.- Mt. Somma. KEILHAUITE (Yttrotitanite). Near sphene in form and composition, but containing alu- mina and yttria. Arendal, Norway. TSCHEFFKINITE. Analogous to keilhauite in composition, containing, besides titanium, also cerium (La,Di). Occurs massive, llmen Mts. STAUROLITE. Orthorhombic. /A 1 = 129 20', A 1-t = 124 46' ; c : I : a, = 1-4406 M1233 : 1. Cleavage: i-l distinct, but interrupted; 1 in traces. Twins 627 629 630 cruciform : twinning-plane *-f (f. 628) ; f -J (f. 629) ; and J-f (f. 630). Fig, OXYGEN COMPOUNDS HYDROUS SILICATES. 337 831 is a drilling according to the last method of twinning, and in f. 632 both methods are combined. See also p. 90 and p. 98. with rough surfaces. Crystals often Massive forms unobserved. H.=7-7;5. G. = 3-4-3-8. Sub- | vitreous, inclining to resinous. Color dark reddish-brown ^ to brownish-black, and yellowish- brown. Streak uncolored to grayish. Translucent nearly or quite opaque. Fracture conchoidal. Oomp., Var.-Q. ratio, according to Rammelsberg, for R : R : Si=2 : 9 : 6 (where R is Fe and Mg P and also includes H a , withH 2 : E=l : 3). Formula H 2 R 3 AlePi 6 O 3; (if Mg : ^=1:3) -Silica 30-37 alumina 51 92, iron protoxide 13 '66, magnesia 2 53, water I "52= 00. The kon was first taken as Fe0 3 , but Mitscherlich showed that it was really FeO. Staurolite often includes impurities, especially free quartz, as first shown by Lechartier, and since then by Fischer, Lasaulx, and Rammelsberg. This is the cause of the variation in the amount of silica appearing in most analyses, there being sometimes as much as 50 p. c. Pvr.; etc. B B. infusible, excepting the man ganesian variety, which fuses easily to a black magnetic glass. With the fluxes gives reactions for iron, and sometimes for manganese. Imperfectly decomposed by sulphuric acid. Diff. Always in crystals ; the prisms obtuse, having an angle of l^i) . Obs.-Usually found in mica schist, argillaceous schist, and gneiss ; often associated with garnet cyanite, and tourmaline. Occurs with cyanite in paragomte schist at Mt Campione, Switzerland ; at the Greiner mountain, and elsewhere in the Tyrol ; in Brittany ; in Ireland. Abundant throughout the mica slate of New England. In Maine, at Windham, and elsewhere. In Mass., at Chesterfield, etc. In Penn. In Georgia, at Canton ; and in Fannm Co. SCIIORLOMITE.-Q. ratio for Ca+Fe+Ti : Si=2 : 1, nearly. Analysis by Ramm ,., Arkan- gas Si0 3 26-09, KoTaiH4, Fe0 3 20-11, FeO 1-57, CaO 29'38, MgO 1 -86=99-85. Color black. Fracture conchoidaJL Magnet Cove, Arkansas ; Kaiserstuhlgebirge in Breisgau. HYDROUS SILICATES. L GENERAL SECTION. A. BISILIOATES. PBOTOLITB. Monoclinic, isomorphous with wollastonite, Greg. Cleavage : i-i (orthoa.) perfect. Twins : twinning-plane i4. Usually in close aggregations oJ cular crystals. Fibrous massive, radiated to stellate. H _5 G.=2-68-2-T8. Lustre of the surface of fracture silky or sub vitreous. Color whitish or grayish. Subtranslucent to opaque. Tough. For Bergen mineral optic-axial plane parallel to orthodiagonal, and very nearly normal to i-i ; acute bisectrix positive, parallel to orthodiagonal, and obtuse bisectrix nearly normal to cleavage-plane or t-* ; axial angle >u, through cleavage-plates, 143-H5 ; DesCl. Var.- Almost always columnar or fibrous, and divergent, the fibres of ten 5 or 3 ^ 8 lo ^, and sometimes, as in Ayrshire, Scotland, a yard. Resembles in aspect fibrous varieties oJ natrolite, okenite, thomsonite, treuioUte, and wollastonite. 22 338 DESCRIPTIVE MINERALOGY. Comp. Q. ratio for H : Na : Ca : Si=l : 1 . 4 : 12, and for R : Si (where R includes C% and H a ,Na a ') = l : 2, like wollastonite ; hence formula HNaGa 2 Si 3 Oj Silica 54 '2, lime 33'8, soda 9'3, water 2-7=100. If the H does not belong with the bases, then the formula may be (Ramm.) NaoCa 4 Si 6 Oi 7 +aq. Pyr., etc. In the closed tube yields water. B.B. fuses at 2 to a white enamel. Gela- tinizes with hydrochloric acid. Often gives out a light when broken in the dark. Obs. Occurs mostly in trap and related rocks, in cavities or seams ; occasionally in meta- morphia rocks. Found in Scotland, near Edinburgh; in Ayrshire; and at Tali ver, etc., L Skye ; at Mt. Baldo and Mt. Monzoni in the Tyrol ; in Wermland ; at Bergen Hill, N. J. ; compact at Isle Royale, L. Superior. LAUMONTITE. Caporcianite. Monoclinic. 0= 68 40', I/\I= 86 16', O A 14 = 151 9' ; c : I : d = 0*516 : 0-8727 : 1. Prism with very oblique terminal plane %-ij the most common form. Cleavage : i-\ and ./perfect; -t imperfect. Twins: twinning-plane i-i. Also columnar, radiating or divergent. H.=3'5-4. G. = 2-25-2-36. Lustre vitreous, inclining to pearly upon the faces of cleavage. Color white, passing into yellow or gray, sometimes red. Streak uncolored. Transparent translucent; becoming opaque and usually pulverulent on exposure. Fracture scarcely observable, uneven. Not very brittle. Double refraction weak ; optic- axial plane i-\\ divergence 52 24' for the red rays; bisec- trix negative, making an angle of 20 to 25 with a normal to i-i ; JDesCl. Oomp Q. ratio for R : R : Si : H 1 : 3 : 8 : 4 ; and R : Si=l : 2 (3R=R). R=Ca, R =A1, and the formula is hence CaAlSi 4 Oi 2 +4aq- Silica 50'0, alumina 2T8, lime 11'9, water 16-3=100. Pyr., etc. Loses part of its water over sulphuric acid, bat a red heat is needed to drive off all. B.B. swells up and fuses at 2*7-3 to a white enamel. Gelatinizes with hydrochloric acid. Obs. Laumontite occurs in the cavities of trap or amygdaloid ; also in porphyry and sye nite, and occasionally in veins traversing clay slate with calcite. Its principal localities are at the Faroe Islands ; Disko in Greenland ; in Bohemia, at Eule ; St. Gothard in Switzer- land ; the Fassathal ; the Kilpatrick hills, near Glasgow. Nova Scotia affords fine specimens ; also Lake Superior, in the copper region, and on I. Royale ; also Bergen Hill, N. J. OKENITE. Formula H 2 CaSi 2 O 8 +aq, having half the water basic = Silica 50 'G, lime 26 '4, water 17 '0=1 00. Commonly fibrous. Color white, Faroe Is.; Disco, Greenland; Iceland. GYROLITE. Occurs in radiated concretions at the Isle of Skye ; Nova Scotia. Formula perhaps H.2Ca 2 Si 3 O 9 +aq. CENTRALLASSITE. Related to okenite, but contains 1 molecule more water. In trap of Nova Scotia. CHRYSOCOLLA.* Kieselkupfer, Germ. Cryptocrystalline ; often opal-like or enamel-like in texture ; earthy. Incrusting, or filling seams. Sometimes botryoidal. H.=2-4. G. 2-2-238. Lustre vitreous, shining, earthy. Color moun- tain-green, bluish-green, passing into sky-blue and turquois-blue; brown to impure. Streak, when p^ure, white. Translucent opaque, Rather sectile ; translucent varieties brittle. black when Fracture conchoidal. OXYGEN COMPOUNDS HYDROUS SILICATES. 339 Comp.-- Composition varies much through impurities, as with other amorphous substances, esulting from alteration. As the silica has been derived from the decomposition of othei ilicates it is natural that an excess should appear in many analyses. True chrysocolla cor- esponds to the Q ratio for Cu : Si : H, 1:2: 2=CuSiO 3 +2aq= Silica 34-2, copper oxide 15-3, water 20 "5 = 100. But some analyses afford 1:2:3, and 1:2:4. Impure chrysocolla nay contain, besides free silica, various other impurities, the color varying from bluish-green ;o brown and black, the last especially when manganese or copper is present. Pyr., etc, In the closed tube blackens and yields water. B.B. decrepitates, colors the 3ame emerald-green, but is infusible. With the fluxes gives the reactions for copper. With joda and charcoal a globule of metallic copper. Decomposed by acids without gelatinization. Diff Color more bluish-green than that of malachite, and it does not effervesce with icids. Obs. Accompanies other copper ores, occurring especially in the upper part of veins. Found in most copper mines in Cornwall ; at Libethen in Hungary ; at Falkenstein and Sehwatz in the Tyrol; in Siberia; the Bannat; Thuringia; Schneeberg, Saxony; Kupfer- oerg, Bavaria; South Australia ; Chili, etc. In Somerville and Schuyler's mines, New Jersey ; it Morgantown, Pa. ; at Cornwall, Lebanon Co. ; 'Nova Scotia, at the Basin of Mines ; also in Wisconsin and Michigan. DKMIDOFPITE ; CYANOCHALCITE ; RESANITE ; near chrysocolla. CATAPLEiiTE.-Analysis (Ramm.), SiO a 39'78, Zr0 2 40-12, CaO 3 '45, Na a O 7-59, H 2 9'24 e=100'18. Hexagonal Color yellowish-brown, Lamoe, near Brevig, Norway. B. UNISILICATES. CALAMINE. Galmei; Kieselzinkerz, Germ. Orthorhombic ; hemimorphic-hemihedral. 148 31', Daubar ; c : I : a = 6124 : 1-2850 7A 7= 104 : 1. Cleav- 13', 0A1-I age : 7, perfect ; O, in traces. Also stalactitic, mammil- lated, botryoidal, and fibrous forms; also massive and granular. H.=4-5-5, the latter when crystallized. G.=3'16-3'9. Lustre vitreous, O subpearly, sometimes adamantine. Color white ; sometimes with a delicate bluish or greenish shade ; also yellowish to brown. Streak white. Transparent translucent. Fracture uneven. Brittle. Pyroelectric. |; Zn 2 Si0 4 H-aq=: Silica 25 '0, Comp. Q. ratio f or R : Si : H=l : 1 zinc oxide 67 "5, water 7 "5 =100. Pyr., etc. In the closed tube decrepitates, whitens, and gives off water. B.B. almost infusible (P. =6); moistened with cobalt solution gives a green color when heated. On charcoal with soda gives a coating which is yellow while hot, and white on cooling. Moistened with cobalt solution, and heated in O.F., this coating assumes a bright green color. Gelatinizes with acids even when previously ignited. Decom- posed by acetic acid with gelatinization. Soluble in a strong solution of caustic potash. Diff. Distinguishing characters: gelatinizing with acids; infusibility ; reaction for zinc. Obs. Calamine and smithsonite are usually found associated in veins or beds in stratified calcareous rocks accompanying blende, ores of iron, and lead, as at Aix la Chapelle; Bleiberg hi Carinthia ; Retzbanya ; Schemnitz. At Roughten G-ill in Cumberland ; at Alston Moor j near Matlock in Derbyshire ; at Castleton ; Lead hills, Scotland. In the United States occurs with smithsonite in Jefferson county, Missouri. At Stirling Hill, N. J. In Pennsylvania, at the Perkiomen and Phenixville lead mines; at Bethlehem; at Friedensville. Abundant in Virginia, at Austin's mines. 340 DESCRIPTIVE MINERALOGY PREHNITE. Orthorhombic. / A 1= 99 56', O A 14 = 146 11J' ; c : I : & = 0-66963 : 1*19035 : 1. Cleavage: basal, distinct. Tabular crystals often united by O, making broken forms, often barrel-shaped. Usually reniform, globular, and stalactitic with a crystalline surface. Structure imperfectly columnar or lamellar, strongly coherent ; also compact granular or impalpable. H.=6-6'5. G.=2-S-2-953. Lustre vitreous; O weak pearly. Color light green, oil-green, passing into white and gray ; often fading on expo- sure. Subtransparent translucent ; streak uncolored. Fracture uneven. Somewhat brittle. Comp. Q. ratio f or R : R : Si : H=2 : 3 : 6 : 1, whence, if the water is basic, for bases and silicon, 1:1; formula H 2 Ca 2 AlSi 3 O ia or Ca 3 AlSi 3 Ou+aq= Silica 43 '6, alumina 24-9, lime 27-1, water 4 "4=100. Pyr., etc. In the closed tube yields water. B. B. fuses at 2 with intumescence to a blebby enamel-like glass. Decomposed by hydrochloric acid without gelatinizing. ( 'oupholite, which often contains dust or vegetable matter, blackens and emits a burnt odor. Diff. B. B. fuses readily, unlike beryl and chalcedony. Its hardness is greater than that of the zeolites. Obs. Occurs in granite, gneiss, syenite, dioryte, and trappean rocks especially the last. At Bourg d'Oisans in Isere ; in the Fassathal, Tyrol ; Ala in Piedmont ; Joachimsthal in Bohemia ; near Andreasberg ; Arendal, Norway ; ^Edelfors in Sweden ; in Dumbartonshire ; in Renfrewshire. In the United States, in Connecticut ; Bergen Hill, N. J. ; on north shore of Lake Superior ; in large veins in the Lake Superior copper region. CHLORASTROLITE and ZONOCHLORITE from Lake Superior are mixtures, as shown by Hawes. VILLARSITE. Probably an altered chrysolite. Formula R 2 SiO 4 +|aq (or aq) R=Mg : Fe =11 : 1. Traversella. CERITE, Sweden, and TRITOMITE, Norway, contain cerium, lanthanum, and didymium. THORITE and ORANGITE contain thorium. Norway. PARATHORITE. In minute orthorhombic crystals, imbedded in danburite at Danbury, Ct. Chemical nature unknown. PYROSMALITE. Analysis by Ludwig, SiO 3 34'66, FeO 27-05, MnO 25-60, CaO 0-52, MgO 0'93, H..O8-31, 014-88=101-85. In hexagonal tables. Color blackish-green. Nya-Koppai- berg, etc. , Sweden. APOPHYLUTE.* Tetragonal. A 1-i = 128 38'; c = 1-2515. Crystals sometimes nearly cylindrical or barrel- shaped. Twins : twin- ning-plane the octahe- dron 1. Cleavage : highly perfect; / less so. Also massive and lamellar. H.= 4-5-5. G.=2-3- 2-4. Lustre of O pearly ; of the other faces vitre- ous. Color white, or grayish ; occasionally with a greenish, yellow- ish, or rose- red tint, flesh rarely opaque. Brittle. red. Streak uncolored. Transparent OXYGEN COMPOUNDS HYDKOU8 SILICATES. iSrfne 2'10=100 m It may be taken as a unisilicate if part of the silica is considered ^ flame violet (pota 8 h), and fuses to a white vesicular enamel. F. - ^^^^-, - p- Of , BaO 36-84, CaO tr, Na,O t,, ^ ^ ta .e Ha,, Bases mostly in sesquioxide state (Al,Mn,Fe). SUBSILICATES. ALLOPHANE. Amorphous. In incrustations, usually thin, with a mammillary surface, and hyalite-like ; sometimes stalactitic. Occasionally almost P^erulen H 3 Q -1-85-1-89 Lustre vitreous to subresmous ; bright and waxv internally. Color pale sky-blue, sometimes greenish to deep green, brown TOllowJ or colorless. Streak uncolored. Translucent. Fracture imperfectly conchoidal and shining, to earthy. Very brittle. nosdy=3 : 2 : 6 (or 5) ; AlSiO 6 +6aq, or AlSi0 6 +5aq= 35-63 = 100. Plumbattophane, from Sardinia, contains a the blue variety is due to traces of chrysocolla, the green to mala- B.B. crumbles, but is infusible. Gives CoLLTKiTiS. A hydrous silicate of aluminum. Clay-like i En Sp? A NM rom SUesia, and UBANOIILE , from WoUendorf , Bavaria, are silicates oo tainiug uranium. 342 DESCRIPTIVE MINERALOGY. II. ZEOLITE SECTION. THOMSONITE. Comptonne. /A 1= 90 40' ; O A 14 = 144 9' ; c : I : a =0-7225 : 1-0117 : 1. Cleavage: i-l easily obtained ; i- less sc , O in traces. Twins : cruciform, having the vertical axis in common. Also columnar, structure radiated ; in radiated spherical concretions ; also amorphous and compact. H. 5-5-5. G. 2-3-2-4. Yitreous, more or less pearly. Snow-white ; impure varieties brown. Streak nncolored. Transparent translucent. Fracture uneven. Brittle. Pyroelectric. Double refraction weak ; optic- axial plane parallel to O\ bisectrix positive, normal to i-l ; divergence 82-82i for red rays, from Dumbarton ; DesCl. Var. Ordinary, (a) In regular crystals, usually more or less rectangular in outline. (1} Tn slender prisms, often vesicular to radiated, (c) Radiated fibrous, (d) Spherical concre- itons, consisting of radiated fibres or slender crystals, (e) Massive, granular to impalpable, and white to reddish-brown. Ozarkite is massive thomsonite ; rauite (Norway) is related. Comp. Q. ratio for R( = Ca,Na a ) : R(A1) : Si : H=1 : 3 : 4 : 2, Ca : Na 2 =2 : 1, or 3 : 1 ; formula 2(Ca,Na 2 )AlSi 2 O i< -f-5aq. Analysis, Rammelsberg, Dumbarton, Si0 2 38'09, A10 3 31-62, CaO 12-60, Na.O 4'62, H,O 13-40=100-20. Pyr., etc. At a red heat loses 13 - 3 p. c. of water, and the mineral becomes fused to white enamel. B. B. fuses with intumescence at 2 to a white enamel. G-elatinizes with hydrochloric acid. " Obs. Found in cavities in lava and other igneous rocks ; and also in some metamorphic rocks, with elasolite. Occurs near Kilpatrick, Scotland ; in the lavas of Somma (comptonitfi) ; in Bohemia ; in Sicily ; in Faroe ; the Tyrol, at Theiss ; at Monzoni, Fassathal ; at Peter's Point, Nova Scotia ; at Magnet Cove, Arkansas (ozarkite). NATROLITE. Mesotype. Nadelzeolith, Germ. Orthorhombic. 1 A 7= 91, O A 14 = 144 23'; c : I : d = 0-35825 640 1'0176 : 1. Crystals usually slender, often acicular ; fre- quently interlacing ; divergent, or stellate. Also .fibrous, radiating, massive, granular, or compact. H.=5-5-5. G. =2-17-2-25 ; 2-249, Bergen Hill, Brush. Lustre vitreous, sometimes inclining to pearly, especially in fibrous varieties. Color white, or colorless ; also grayish, yellowish, reddish to red. Streak uncolored. Transparent translucent. Double refraction weak ; op- tic-axial plane i-%\ bisectrix positive, parallel to edge ///; axial divergence 94~96, red rays, for Auvergne crystals ; 95 12 X for brevicite ; DesCl. Comp. Q. ratio for R : R : Si : H=l : 3 : 6 : 2 ; and for R : Si= 2 : 3(R=Na 2 ,3R=R) ; formula Na a AlSi 3 10 +2aq= Silica 47'29, alumina 26 '90, soda 16-30, water 9 -45 =100. Pyr., etc. In the closed tube loses water, whitens and becomes opaque. B.B. fuses quietlj at 2 to a colorless glass. Fusible in the lame of an ordinary stearine or wax candle. Geia tinizes with acids. OXYGEN COMPOUNDS HYDROUS SILICATES. 34) Ditf, Some varieties resemble pectolite, thomsonite, but distinguished B.B. Obs. Occurs in cavities in amygdaloidal trap, basalt, and other igneous rocks ; and some times in seams in granite, gneiss, and syenite. It is found in Bohemia ; in Auvergne ; Fassa thai, Tyrol ; Kapnik ; at Glen Farg in Fifeshire ; in Dumbartonshire. In North America, occurs in the trap of Nova Scotia ; at Bergen Hill, N. J. ; at Copper Falls, Lake Superior. SCOLECITE. Poonahlite. Monoclinic. C= 89 6', /A 1= 91 36', O A 14 = 161 16*' = 0-34:85 : 1-0282 : 1. Crystals long or short prisms, or acicular, rarely well terminated, and always compound. Twins: twinn ing-plane i-i. Cleavage: /nearly perfect. Also in nodules or massive; fibrous and radiated. IL 5-5-5. G. 2-16-2-4. Lustre vitreous, or silky when fibrous. Transparent to subtranslucent. Pyro- electric, the free end of the crystals the antilogne pole. Double refraction weak ; optic-axial plane normal to i-l ; divergence 53 41', for the red rays ; bisectrix negative, aralFel to i-l ; plane of the axis of the red rays and their isectrix inclined about 17 8' to i-i, and 93 3' to I-i. 641 pa bis Comp, Q. ratio f or R : R : Si : H=l : 3 : 6 : 3 ; forR(3R=R) : Si=2 : 3, as innatrolite ; R=Ca,R=^l; formula Ca^lSi 3 10 +3aq= Silica 45 '85, alumina 2G'13, lime 1423, water 13-76=100. Pyr., etc. B.B. sometimes curls up like a worm (whence the name from er/cwXij^, a worm, which gives scolecite, and not scolesite or scolezite) ; other varieties intumesce but slightly, and all fuse at 2-2 '2 to a white blebby enamel. Gelatinizes with acids like natrolite. Diff. Characterized by its pyrognostics. Obs. Occurs in the Berufiord, Iceland ; also at Staffa ; inSkye, atTalisker ; nearPoonah, Hindostan (Poonahlite} ; in Greenland ; at Pargas, Finland, etc. MESOLITE. (Ca,3S"a 2 )AlSi 3 O 10 +3aq (5 p. c. Na a O). Near scolecite. Iceland ; Nova Scotia. LEVYNITE Rhombohedr il. Q. ratio forR : R : Si : H=l : 3 : 6 : 4. Analysis, Damour, Iceland, SiO 2 4576, A1O 3 23'56, CaO 10 57, Na 2 O 1'36, K 2 O 1'64, H 2 17'33=100-22. Ire- land ; Faroe ; Iceland. ANALCITE.* Isometric (?) . Usually in trapezohedrons (f. 54, p. 18). Cleavage, cubic, in traces. Also massive granular. H.=5-5-5. G.=2-22-2-29 ; 2-278, Thomson. Lustre vitreous. Color- less ; white ; occasionally grayish, greenish, yellowish, or reddish- white. Streak white. Transparent nearly opaque. Fracture subconchoidal, uneven. Brittle. 2. For Gelati- Comp.-Q. ratio for R : R : Si : H=l : ?, : 8 : 2, R=Na Q , R= A1=3R ; R : Bi=J : mulaNa 2 AlSi 4 12 -f2aq=Silica54-47, alumina 23 '29, soda 14'07, water 817=100. Pyr., etc. Yields water in the closed tube. B.B. fuses at 2'5 to a colorless glass, nizes with hydrochloric acid. Diff. Distinguishing characters : crystalline form ; absence of cleavage ; fusion B.B. vut intumescence to a clear glass (unlike chabaziteX Obs. Some localities are : the Tyrol ; the Kilpaorick Hills in Scotland ; the Faroe Islands ; Iceland ; Aussig, Bohemia ; Nova Scotia ; Bergen Hill, New Jersey ; the Lake Superior region. ^Schrauf has found that the analcite oi rrieueck, Bohemia, is properly tetragonal ; the simplest crystals showing evidence of repeated twinning. DESCRIPTIVE MINERALOGY. FAUJASITE. An octahedral zeolite from the Kaiserstuhlgebirge. Analysis, Damour, Sid 46-12, A1O 3 16-81, CaO 4 "79, Na 2 O 5 "09, H 2 O 27 '02 =99 -83. EUDNOPHITE. Near analcite. In syenite near Brevig, Norway. PILINITE. In slender needles (orthorhombic) ; white ; lustre silky. Analysis SiO 2 55 *70, AlO 3 (FeO 3 ) 18-64, CaO 19.51, Li 2 O (1-18), H 2 4 "97=100. In granite of Striegau, Silesia CHABAZITE* Khornbohedral. E A E = 94 46', Ot\fi = 129 15' ; c = 1'06. Twins : twinning-plane O, very common, and usually in compound twins, as in f. 644 ; also -Z2, rare. Cleavage rhombohedral, rather distinct. 643 Haydenite. H.=4-5. G.=2-08-2-19. Lustre vitreous. Color white, flesh-red ; streak uncolored. Transparent translucent. Fracture uneven. Brittle. Double refraction weak ; in polarized light, images rather confused ; axis in some crystals (Bohemia) negative, in others (from Andreasberg) posi- tive ; DesCl. Var. 1. Ordinary. The most common form is the fundamental rhombohedron, in which the angle is so near 90 that the crystals were at first mistaken for cubes. Acadialite, from Nova Scotia (Acadia of the French of last century), is only a reddish chabazite ; sometimes nearly colorless. In some specimens the coloring matter is arranged in a tesselated manner, or in layers, with the angles almost colorless. 2. Phacolite is a colorless variety occurring in twins of mostly a hexagonal form, and often much modified so as to be lenticular in shape (whence the name, from *a/cos, a bean} ; the original was from Leipa in Bohemia; li/\R =94 24', fr. Oberstein, Breith. Comp. Making part of the water basic (at 300 C. loses 17-19 p. c.) Rammelsberg writes the formula (I^KhCaAzlSisOis+eaq, where the Q. ratio f or R : ft : Si =2 : 3 : 10, R-H,,Na 2 , Ca; or (3R=ft), R : Si=l : 2. The formula corresponds to Silica 50 '50, alumina 17 '26, lime 9-43, potash 1'98, water 20'83=100. Pyr., etc. B.B. intumesces and fuses to a blebby glass, nearly opaque. Decomposed by hydrochloric acid, with separation of slimy silica. Diff. Its rhombohedral form, resembling a cube, is characteristic ; is harder, and does not effervesce with acids like calcite ; is unlike fluorite in cleavage ; fuses B. B. with intumes- cence to a blebby glass, unlike analcite. Obs. Chabazite occurs mostly in trap, basalt, or amygdaloid, and occasionally in gneiss, syenite, mica schist, hornblendic schist. At the Faroe Islands, Greenland, and Iceland ; at Aussig in Bohemia ; Striegau, Silesia. In Nova Scotia, wine-yellow or flesh-red (the last the acadiatite), etc.; at Bergen Hill, N. J.; at Jones's Falls, near Baltimore (haydenite}. SEEBACHITE (Bauer) from Richmond, Victoria, is, according to v. Rath, identical with phaooUte ; and he suggests the same may be true of HERSCHELITE, from Aci Castello, Sicily. OXYGEN COMPOUNDS HYDROUS SILICATES. 345 GMELINITE. lihombohedral. E A E = 112 26', O A E = O A-l = 140 3 3' ; Ny "^ V or (b) in radiated stars or hemispheres, with the radiating individual* \___,s showing a pearly cleavage surface. Sphcerostiibite, Beud, is in spheres, radiated within with a pearly fracture, rather soft externally. Comp Q. ratio for R : ft : Si : H=l : 3 : 12 : G ; R^Ca(Na 2 ),ii Al. Formula RrVlSi 6 O 18 4 6aq. If two parts of water are basic (Ramm. ) the ratio becomes (R=Ca,H 2 ,Na.,) 3 : 3 : 13 : 4, or R : Si=l : 2, and the formula is H,RAlSi 6 Oi8+4aq. Analysis, Petersen, Seisser Alp, SiO 2 55-61, A1O 3 15-62, CaO7'33, Na 2 O 2 -01, K 2 O 0'47, H 2 O 18'19=9fl-23. Pyr., etc. B.B. exfoliates, swells up, curves into fan-like or vermicular forms, and fuses OXYGEN COMPOUNDS HYDROUS SILICATES. 347 to a white .enamel. F. =2-2'5. Decomposed by hydrochloric acid, without gelatinizing. The sphcerostttbite gelatinizes, but Heddle says this is owing to a mixture of mesolite with the stil- bite. Diff. Prominent characters: occurrence in sheaf -like forms, and in the rectangular tabular crystals ; luscre on cleavage-face pearly ; does not gelatinize with acids. Obs. Stilbite .occurs mostly in cavities in amygdaloid. It is also found in some metal- liferous veins, and in granite and gneiss. The Faroe Islands, Iceland, and the Isle of Skye ; in Dumbartonshire, Scotland ; at Andreasberg ; Arendal in Norway ; in the Syhadree Mts., Bombay ; near Fahlun, in Sweden. In North America, at Bergen Hill, New Jersey ; at the Michipicoten Islands, Lake Superior ; Nova Scotia, etc. The name stilbite is from an'A/fy, lustre; and dexmine from ^toyz??, a bundle. The species stilbite, as adopted by Haiiy, included Strahlzeolith Wern. (radiated zeolite, or the above), and Blatterzeolith Wern. (foliated zeolite, or the species heulaudite beyond). The former wap the typical part of the species, and is the first mentioned in the description ; and the lattei he added to the species, as he observes, with much hesitation. In 1817, Breithaupb separated the two zeolites, and called the former ties'/nine and the latter euzeolite, thus throwing aside entirely, contrary to rule and propriety, Haiiy's name stilbite^ which should have been accepted by him in place of desmine. it being the typical part of his species In 1822, Brooke (ap- parently unaware of what Breithaupt had done) used stilbite for the first, and named the other heuldndit*. In this he has been followed by the French and English mineralogists, while the Germans have unfortunately followed Breithaupt. EPISTILBITE (Reixsite). Composition like heulandite, but form orthorhombic. Iceland; Faroe ; Poonah, India, etc. ; Bergen Hill, N". J. FORESITE. Resembles stilbite in form. Q. ratio for B : R : Si : H 1 : 6 : 12 : 6. Formula RAl 3 Si 6 Oi9-f-6aq. (R = Na 2 : Ca=i : 3). Occurs hi crystalline crusts on tourmaline, in cavities in granite. Island of Elba. HEULANDITE. Stilbit, Germ. Monoclinic. O = 88 35', /A 1= 136 4', O A 14 = 156 45' ; c : I : d = 1-065 : 2-4785 : 1. Cleavage : clinodiagonal (i4) emi- nent. Also in globular forms ; also granular. 651 H.=3'5 4. G.=2*2. Lustre of i-l strong pearly ; of other faces vitreous. Color various shades of white, passing into red, gray, and brown. Streak white. Transparent subtranslucent. Fracture subconchoidal, uneven. Brittle. Double refraction weak ; optic-axial plane normal to i-l ; bisectrix positive, parallel to the horizontal diagonal of the base ; DesCl. Comp. Q. ratio for R : R : Si : H=l : 3 : 12 : 5 ; R=Ca(Na 2 ). Formula Ca^lSieOi 6 4-5 aq, or if 2H O be basic (Ramm.) then the ratio becomes 1:1:4 (R=Ca and H 2 ), and the formula H 4 CaAlSi 6 Ois+Baq. Both require Silica 59-06, alumina 16*83, lime 7 -88, soda 1-46, water 14-77=100. Pyr. B.B. same as with stilbite. Diff. Distinguished by its crystalline form. Pearly lustre of i-\ a prominent character. Obs. Heulandite occurs principally in amygdaloidal rocks. Also in gneiss, and occasionally in metalliferous veins. Occurs in Iceland ; the Faroe Islands ; the Vendayah Mountains, Hindostan. Also in the Kilpatrick Hills, near Glasgow ; in the Fassa Valley, Tyrol ; An- dreasberg; Nova Scotia, etc. ; at Bergen Hill, New Jersey ; on north shore of Lake Superior ; at Jones's Falls, near Baltimore (Levy's beaumontite). For the relation of the synonymes see stilbit, above. BREWSTERITE. Q. ratio same as for heulandite, but R is here Ba or Sr (Ca). Formula requires SiO 2 53 -5, A1O 3 15 "3, BaO 7 -6, SrO 10 '2, H 2 O 13 '4= 100. Monoclinic. Strontian in Argyleshire, etc. 348 DESCRIPTIVE MINERALOGY. III. MARGAROPHYLLITE SECTION. BISILICATES. The Margarophyllites are often foliated like the micas, and the name alludes to the pearly folia. Massive varieties are, however, the most com- mon with a large part of the species, and they often have the compactness of clay or wax. Talc, pyrophyllite, serpentine, are examples of species pre- senting both extremes of structure ; while pinite occurs, as thus far known, only in the compact condition. The true Margarophyllites are below 5 in hardness ; greasy to the feel, at least when finely powdered. TALC. Orthorhombic. /A 7 = 120. Occurs rarely in hexagonal prisms and plates. Cleavage : basal, eminent. Foliated massive, sometimes in globu- lar and stellated groups; also granular massive, coarse or fine ; also com- pact or cryptocrystalline. H.=l-l*5. (r.=2'565-2'8. Lustre pearly. Color apple-green to white, or silvery-white ; also greenish-gray and dark green ; sometimes bright green perpendicular to cleavage surface, and brown and less translucent at right angles to this direction ; brownish to blackish-green and reddisli when impure. Streak usually white ; of dark green varieties, lighter than the color. Subtransparent subtranslucent. Sectile. Thin laminse flexible, but not elastic. Feel greasy. Optic-axial plane i-l ; bisectrix negative, nor- mal to the base ; DesCl. Var. Foliated, Talc. Consists of folia, usually easily separated, having a greasy feel, and presenting ordinarily light green, greenish -white, and white colors. Gr. =2 '55-2 '78. (a) Massive, Steatite or Soapstone (Speckstein, Germ. ). Coarse granular, gray, grayish-green, and brownish-gray in colors. H. =1-2 '5. (b) Fine granular or cryptocrystalline. and soft enough to be used as chalk, as the French cJialk (Craie de Brianq&ri), which is milk-white, with a pearly lustre. Comp. Q. ratio forMg : Si=2 : 5, or 3 : 4, with a varying amount of water in both talc and steatite, from a fraction of a per cent, to 7 p. c. If the water is basic, the ratio becomes for K : Si=l : 2, (R=Mg(Fe)and H 2 ), and the formula is H 2 Mg s Si 4 O 12 (Ramm.) = Silica 63'49, magnesia 31*75, water 4*76 = 100 ; the analyses show generally 1 or 2 p. c. of FeO. Pyr., etc. In the closed tube B.B., when intensely ignited, most varieties yield water. In the platinum forceps whitens, exfoliates, and fuses with difficulty on the thin edges to a white enamel. Moistened with cobalt solution, assumes* on ignition a pale red color. Not decom- posed by acids. Diff. Recognized by its extreme softness, unctuous feel, and usually foliated structure. Inelastic though flexible. Yields water only on intense ignition. Obs. Talc or steatite is a very common mineral, and in the latter form constitutes exten- sive beds in some regions. It is often associated with serpentine and dolomite, and frequently contains crystals of dolomite, breunerite, asbestus, actinolite, tourmaline, magnetite. Steatite is the material of many pseudomorphs, among which the most common are those after pyroxene, hornblende, mica, scapolite, and spinel. The magnesian minerals are those which commonly afford steatite by alteration ; while those, like scapolite and nephelite, which contain soda and no magnesia, most frequently change to pinite-like pseudomorphs. liensstlaerite and vyraUolite are pseudomorphous varieties. Applfi-green talc occurs near Salzburg ; in the Valais ; also in Cornwall, near Lizard Point, with serpentine ; in Scotland, with serpentine, at Portsoy and elsewhere ; etc. In N. America, some localities are: Vermont, at Bridgewater; Grafton, etc. In New Hampshire, at Pelham, etc. In R. Inland, at Smithfield. In N. York, near Amity. In Penn., at Texas; at Chestnut Hill, on the SchuylkilL In Maryland, at Cooptown. OXYGEN COMPOUNDS HYDROUS SILICATES. 349 PYROPHYLLITE. Agalmatolite or Pagodite pt. Orthorliombic. Not observed in distinct crystals. Cleavage: basal eminent. Foliated, radiated lamellar; also granular, to compact or cry pto- crystalline ; the latter sometimes slaty. H. = i-2. G.=2-75-2-92. Lnsfcreof folia pearly, like that of talc; of massive kinds dull or glistening. Color white, apple-green, grayish and brownish-green, yellowish to ochre-yellow, grayish- white. Subtransparent to opaque. Laminae flexible, not elastic. Feel greasy. Optic-axial angle large (about 108) ; bisectrix negative, normal to the cleavage-plane. Var. (I) Foliated, and often radiated, closely resembling talc in color, feel, lustre, and structure. (2) Compact, massive, white, grayish, and greenish, somewhat resembling com- pact steatite, or French chalk. This compact variety, as Brush has shown, includes part of what has gone under the name of agalmatolite, from China ; it is used for slate-pencils, and is sometimes called pencil-stone. Comp. Q. ratio for Al : Si=l : 2, also in other cases 3 : 8, Formula for the first case = AlSi 3 O 9 +aq (Bamm.). Analysis, Chesterfield, S. C., by Genth, SiO a 64 '82, A1O 8 28'48, FeO 8 0-96, MgO 0-33, CaO 0'55, H,O 5-25=100';J9. Pyr., etc. Yields water. B.B. whitens, and fuses with difficulty on the edges. The radiated varieties exfoliate in fan-like forms, swelling up to many times the original volume of the assay. Heated with cobalt solution gives a deep bide color (alumina). Partially decom- posed by sulphuric acid, and completely on fusion with alkaline carbonates. Obs. Compact pyrophyllite is the material or base of some schistose rocks. The foliated variety is often the gangue of cyanite. Occurs in the Urals ; at Westana, Sweden; near Ottrez in Luxembourg ; in Chesterfield Dist., S. C. ; in Lincoln Co., Ga. ; in Arkansas. The compact pyrophyllite of Deep River, N. C. , is extensively used for making slate pencils. PIHLITE (cymatolite), near pyrophyllite. SEPIOLITE.* Meerschaum, Germ. L'Ecume de Mer, Fr. Compact, with a smooth feel, and fine earthy texture, or clay-like. H.=2-2'5. Impressible by the nail. In dry masses floats on water. Color grayish- white, white, or with a faint yellowish or reddish tinge. Opaque. Comp. Q. ratio for R : Si : H=l : 3 : 1, corresponding to Mg 2 Si 3 8 + 2aq ; or, if half the water is basic, 1:2: i=H 2 Mg 2 Si s O 9 + aq=Silica 60-8, magnesia 27'1, water 121=100. The amount of water present is somewhat uncertain. Pyr., etc. In the closed tube yields first hygroscopic moisture, and at a higher temperature gives much water and a burnt smell. B. B. some varieties blacken, then burn white, and fuse with difficulty on the thin edges. With cobalt solution a pink color on ignition. Decomposed by hydrochloric acid with gelatinization. Obs. Occurs in Asia Minor, in masses in stratified earthy or alluvial deposits at the plains of Eskihi-sher ; a]so found in Greece ; at Hrubsohitz in Moravia ; in Morocco ; at Vallecas in Spain, in extensive beds. The word meerschaum is German for sea-froth, and alludes to its lightness and color. Sepio- Ute, Glocker, is from or/xia, cuttle-fish, the bone of which is light and porous, and also a pro- duction of the sea. APHRODITE. 4MgSi0 3 +3aq. Resembles sepiolite. Longban, Sweden. SMECTITE. Fuller's earth pt. A greenish clay from Styria. MONTMORILLONITE. A rose-red clay containing more alumina than smectite, from Mont- morillon, France. CELADONITE. A variety of "green earth" from Mt. Baldo, near Verona. GLAUCONITE. Green earth pt. A hydrous silicate of iron and potassium, but alwayi impure. Constitutes the green sand of the chalk and other formations (e.g in New Jersey). STILPNOMELANK. la foliated plates, or aa a velvety coating. Eiwentially a hydrous iton 350 DESCRIPTIVE MINERALOGY. (Fe) silicate. Color black to yellowish-bronze. Silesia; Weilburg; Nassau; Sterling iron mine; Antwerp, N. Y. (chalcodite}. CHLOROPAL. Compact, earthy. Color greenish -yellow. A hydrated iron silicate. Formula FeSi 3 9 4-5aq. Andreasberg"; Steinberg near Gottingen ; Nontron (nontronite\ France, etc. AERIKITE. Perhaps related to chloropal (Lasaulx). Color blue. Spain. UNISILICATES. Serpentine Group. SERPENTINE.* Orthorhombic (?). In distinct crystals, but only as psendomorphs. Some- times foliated, folia rarely separable ; also delicately fibrous, the fibres often easily separable, and either flexible or brittle. Usually massive, fine granu- lar to impalpable or cryptocrystalline ; also slaty. H.=2-5-4, rarely 5'5. Gr. 2'5-2'65 ; some fibrous varieties 2-2-2-3 ; retinalite, 2'36-2*55. Lustre subresinous to greasy, pearly, earthy ; resin- like, or wax-like ; usually feeble. Color leek-green, blackish-green, oil and siskin-green, brownish-red, brownish-yellow ; none bright ; sometimes nearly white. On exposure, often becoming yellowish-gray. Streak white, slightly shining. Translucent opaque. Feel smooth, sometimes greasy. Fracture corichoidal or splintery. Var. Many unsustained species have been made out of serpentine, differing in structure (massive, slaty, foliated, fibrous), or, as supposed, in chemical composition. MASSIVE. (1) Ordinary massive, (a) Precious or Noble Serpentine (E&zr Serpentin, Germ.) is of a rich oil-green color, of pale or dark shades, and translucent even when in thick pieces ; and (b) Common Serpentine, when of dark shades of color, and subtranslucent. The former has a hardness of 2 5-3; the latter often of 4 or beyond, owing to impurities. Bowenitt (Smithfield, R. I.), is a jade-like variety with the hardness 5'5. FOLIATED. Marmolite is thin foliated ; the laminse brittle but easily separable, yet gradu- ating into a variety in which they are not separable. G. =2 '41 ; lustre pearly ; colors green- ish-white, bluish- white, or pale asparagus-green. From Hoboken, N. J. FIBROUS. Chrysotile is delicately fibrous, the fibres usually flexible and easily separating ; lustre silky, or silky metallic ; color greenish -white, green, olive-green, yellow, and brownish ; G. =2'219. Often constitutes seams in serpentine. It includes most of the silky amianthus of serpentine rocks. The original chrysotile was from Eeichenstein. Any serpentine rock cut into slabs and polished is called serpentine marble. Comp Q. ratio for Mg : Si : H=3 : 4 : 2, corresponding to Mg 3 SioO 7 +2aq= Silica 43 '48, magnesia 43 '48, water 13*04. But as chrysolite is especially liable to the change to serpen- tine, and chrysolite is a unisilicate, and the change consists in a loss of some Mg 1 , and the addition of water, it is probable that part of the water takes the place of the lost Mg, so that the mineral is essentially a hydrated chrysolite of the formula H 2 Mg 3 Si 2 O8 + aq. The rela- tion in ratio to kaolinite and pinite corresponds with this view of the formula. Pyr.j eto. In the closed tube yields water. B B. fuses on the edges with difficulty. F. 6. Gives usually an iron reaction. Decomposed by hydrochloric and sulphuric acids. Chry- sotile leaves the silica in fine fibres. Diff. Distinguishing characters : compact structure ; softness, being easily cut with a knife ; low specific gravity ; and resinous lustre. Obs. Serpentine often constitutes mountain masses. It frequently occurs mixed with more or less of dolomite, magnesite, or calcite, making a rock of clouded green, sometimes veined with white or pale green, called verd antique, or ophiolite. It results from the altera- tion of other rocks, frequently chrysolite rocks. Crystals of serpentine (pseudomorphous) occur in the Fass? valley, Tyrol; near Miask; Katharinenberg, and elsewhere; in Norway, OXYGEN COMPOUNDS HYDROUS SILICATES. 351 at bnarum, etc. Precious serpentines corne from Sweden ; the Isle of Man ; Corsica ; Siberia ; Saxony, etc. In N. America, in Vermont, at New Fane; Roxbury, etc. In Mass., at Newburyport and elsewhere. In Conn., near New Haven and Milford, at the verd-antique quarries. In JV. York, at Brewster, Putnam Co. ; at Antwerp, Jefferson Co. ; in Gonver- neur, St. Lawrence Co. ; in Orange Co. ; Richmond Co. In N. Jersey, at Hoboken. Iu Penn.. at Texas, Lancaster Co. ; also in Chester Co. ; in Delaware Co. In Maryland, at Bare Hills ; at Cooptown, Harf ord Co. The following are varieties of serpentine : retinalite, G-renville, C. W. ; vorhaiLserite, Tyrol ; porcellophite ; bowenite, Smithfield, R. I. ; antigorite, Piedmont ; wttliamzite, Texas, Pa. ; marmoiite, Hoboken ; picrolite ; metaxite ; refdanskite (containing Ni) ; aquacreptite. BASTITE or SCHILLER SPAR. An impure serpentine, a result of the alteration of a foliated pyroxene. Baste ; Todtmoos in the Schwarzwald. ANTILLITE is similar. DEWEYLITE (Gymnite). HMg4Si30, 2 +4aq. Occurs with serpentine at Middlefield and Texas, Penn. HYDROPHITE (Jenkinsite), near deweylite, but Mg replaced in part by Fe. CEROLITE. H 2 Mg2Si 2 07+aq. Silesia. LIMBACHITE from Limbach, and ZOBLITZITH from Zoblitz, are varieties of cerolite. GENTHITE. Nickel-Gymnite. Amorphous, with a delicately hemispherical or stalactitic surface, in crusting. H.=3-4: ; sometimes (as at Michipicoten) so soft as to be polished under the nail, and fall to pieces in water. G.= 2-409. Lustre resinous. Color pale apple-green, or yellowish. Streak greenish- white. Opaque to translucent. Comp. Q. ratio for R : Si : H=2 : 3 : 3, or the same as for deweylite ; formula H 4 (Ni, Mg) 4 Si 3 O 12 , being a nickel-gymnite. Analysis: Genth, Texas, Pa., Si0 2 35 '30, MO 30'04, FeO 0-24, MgO 14'60, CaO 26, H 2 O 19 '09 =100 -19. Pyr., etc In the closed tube blackens and gives off water. B.B. infusible. With borax in O.F. gives a violet bead, becoming gray in R.F. (Nickel). Decomposed by hydrochloric acid without gelatinizing. Obs From Texas, Lancaster Co. , Pa. , in thin crusts on chromic iron ; from Webster, Jackson Co., N. C.; on Michipicoten Id., Lake Superior. ALTPITE and PIMELITE, an apple-green silicates containing some nickel. GARNIERITK and NOUMEITE, from New Caledonia are similar, aud have been shown by Liversidge to be mixtures. Kaolinite Group. KAOLINITE. Orthorhombic. lt\ T 120. In rhombic, rhomboidal, or hexagonal scales or plates ; sometimes in fan-shaped aggregations ; usually constitut- ing a clay-like mass, either compact, friable, or mealy ; base of crystals lined, arising from the edges of superimposed plates. Cleavage : basal, perfect. Twins : the hexagonal plates made up of six sectors. H. = 1-2-5. G.=2'4-2*63. Lustre of plates pearly ; of mass, pearly to dull earthy. Color white, grayish-white, yellowish, sometimes brownish, bluish, or reddish. Scales transparent to translucent. Scales flexible, inelastic ; usually unctuous and plastic. Var 1. Argilttform. Soft, clay-like ; ordinary kaolinite ; under the microscope, if not without, showing that it is made up largely of pearly scales. The constituent of most, if not 352 DESCRIPTIVE MINERALOGY. all, pure kaolin. 2. Fariniform. Mealy, hardly coherent, consisting of pearly augula scales. 3. Indurated; Lithomarge (Steinmark, Germ.). Firm and compact; H.=2-2'5 When pulverized, often shows a scaly texture. Comp. Q. ratio for ft : Si : H=3 : 4 : 2 ; formula AlSio0 7 +2aq, or making part of thi water basic, H 2 AlSi 2 8 +aq= Silica 46-4, alumina 39 '7, water 13-9 = 100. Pyr., etc. Yields water. B.B. infusible. Gives a blue color with cobalt solution. Insol nble in acids. Diff. Characterized by its unctuous, soapy feel ; alumina reaction B B. Obs. Ordinary kaolin is a result of the decomposition of aluminous minerals, especially the feldspars of granitic and gneissoid rocks and porphyries. In some regions where thes* rocks have decomposed on a large scale, the resulting clay remains in vast beds of kaolin usually more or less mixed with free quartz, and sometimes with oxide of iron from some o the other minerals present. Occurs at Cache-Apres in Belgium ; also in Bohemia ; in Saxony. At Yrieix, near Limoges is the best locality of kaolin in Europe, it affords material for the famous Sevres porcelaii manufactory. In the U. States, kaolin occurs at Newcastle and Wilmington, Del. ; at various localities ii the liinonite region of Vermont (at Branford, etc.) ; Massachusetts ; Pennsylvania; Jackson ville, Ala.; Edgefield, S. C.; near Augusta, Ga. PHOLERITE, HALLOYSITE, clays allied to kaolinite. SAPONITE. A soft magnesian silicate ; occurs in cavities in trap. Pinite Group. FINITE. Amorphous ; granular to cryptocrystalline ; usually the latter. Also ir crystals, and sometimes with cleavage, but only because pseudomorphs, th< form and cleavage being those of the minerals from which derived. Rarely a submicaceous cleavage, which may belong to the species. ( H.= 2-5-3*5. G.=2'6-2*85. Lustre feeble, waxy. Color grayish-white grayish -green, pea-green, dull green, brownish, reddish. Translucent opaque. Acts like a gum on polarized light ; DesCl. Comp., Var. Pinite is essentially a hydrous alkaline silicate. Being a result of alteration, and amorphous, the mineral varies much in composition, and numerous species have beer made of the mineral in its various conditions. The varieties of pinite here admitted agree closely in physical characters, and in the amount of potash and water present. Average com- position : Silica 46, alumina 30, potash 10, water 6 ; formula (Ramm.) HeKaAloSisOao. The mineral is related chemically, as it is also physically, to serpentine ; and it is an alkali- alumina serpentine, as pyrophyllite is an alumina talc. The different kinds are either pseudomorphous crystals after (1) iolite ; (2) nephelite ; (3) scapolite ; (4) some kind of feldspar; (5) spodumene ; or (6) other aluminous mineral; or (7) disseminated masses resembling indurated talc, steatite, lithomarge, or kaolinite, also a result of alteration ; or (8) the prominent or sole constituent of a metamorphic rock, which is some- times a pinite schist (analogous to, and often much resembling, t'tkose schist, and still more closely related to pyrophyllite schixt). Some prominent varieties are : PINITE. Speckstein [fr. the Pini mine at Aue, near Schneeberg]. Occurs in granite, and is supposed to be pseudomorphous after iolite. G-IESECKITK. In 6-sided prisms, probably pseudomorphous after nephelite. It =3 5. G. =2'78-2'85. Color grayish-green, olive-green, to brownish. Brought by (iieseoke from Greenland. Also of similar characters from Diana, N. Y. AGALMATOLITE. Like ordinary massive pinite in its amorphous compact texture, lustre, and other physical characters, but contains more silica, so as to afford the formula of a bisili- cate, or nearly, and it may be a distinct species. Agalmatolite was named from (ryaA/xo, an image, and payodite from pagoda, the Chinese carving the soft atone into miniature pagodas OXYGEN COMPOUNDS HYDROUS SILICATES. 353 Images, etc. Part of the so-called agalmatolite of China is true pinite in eompo&iUon, anothei part is compact pyrophyllite (p. 349), and still another steatite (p. 348). Other minerals belonging in or near the pinite group are : dyssyntribite (=gieseckite) ; parophite ; wilsonite ; polyargite ; rosite ; killinite ; gigcmto'ite ; hygrophiiite ; gumbelite ; rcstormelite. Also cataspilite ; biharite ; palagonite. Hydro-mica Group. FAHLUNITE. In six- or twelve-sided prisms, but derived from pseudomorphism alter iolite. Cleavage : basal sometimes perfect. H.=3'5-5. G.=2'6-2'8. Lustre of surface of basal cleavage pearly to waxy, glimmering. Color grayish-green, to greenish-brown, olive- or oil- green ; sometimes blackish-green to black ; streak colorless. Var. This species is a result of alteration, and considerable variation in the results of analyses should be expected. The crystalline form is that of the original iolite, while the basal cleavage when distinct is that of the new species fahlunite. Comp Q. ratio for R : R : Si : H=l : 3 : 5 : 1 ; whence the formula H 4 R2R-2Si 5 20 , the water being considered as basic, and as entering to make up the deficiency of bases in the unisilicate. In some kinds, the same with the addition of H 2 O. The Q. ratio of iolite, the original of the species, is 1:3:5. Analysis by Wachtmeister, from Fahlun, Si0 2 44-60, MO, 30-10, FeO 3'86, MnO 2'24, MgO 6 "75, CaO 1-35, K 2 1'98, H 2 O 9'35, F tr=100-23. Pyr., etc. Yields water. B.B. fuses to a white blebby glass. Not acted upon by acids. Pyrargillite is difficultly fusible, but is completely decomposed by hydrochloric acid. Obs. Fahlunite (and tridasite) from Fahlun, Sweden. The following are identical, or nearly so : Esmarkite and praseolite, Brevig ; raumite, Raumo, Finland ; cMorophyttite^ Unity, Me. ; pyrargttlite, Helsingfors ; polychroilite, Krageroe, and aspasiolite, Norway ; huronitc, Lake Huron ( Weissite, Fahlun). MARGARODITE. Like muscovite or common mica in crystallization, and in optical and other physical characters, except usually a more pearly lustre, and the color more commonly whitish or silvery. Comp. Q. ratio for R : R : Si : H mostly 1:6:9:2; whence the formula H b R 2 Al 4 Si 9 03o, the water being basic. Sometimes Q. ratio 1 : 9 : 12 : 2 ; but this division belongs with damourite, if the two are distinguishable. This species appears to be often, if not always, a result of the hydration of muscovite, there being all shades of gradation between it and that species. Muscovite has the Q. ratio for bases and silicon of 4 : 5, or nearly. Analysis, Smith and Brush, Litchfield, Ct., Si0 2 44'GO, A1 2 O 3 36'23,Fe 2 O 3 l-34,MgO 0'37, CaO 0'50, Na 2 04'lO, K 2 6 20, H a O 5-26, F tr. =--100-60. For pyrognostics and localities, see muscovite, p. 313. GILBERTITE. Essentially identical with margarodite ; tin mines, Saxony. DAMOURITE. An aggregate of fine scales, mica-like in structure. H.=:2-3. G. = 2-792. Lustre pearly. Color yellow or yellowish-white. Optic-axial divergence 10 to 12 degrees ; for sterlingite 70. Comp. A hydrous potash-mica, like margarodite, to which tt is closely related. Q. ratio 23 354 DESCRIPTIVE MINERALOGY. for R : 51 : Si : H=l : 9 : 12 : 2, or 1 : 1 for bases to silicon, if the water is basic. Formula H 4 K 2 Al s SieO 24 . Analysis, Monroe, from Sterling, Mass, (sterlingite) , Si0 2 43 '87, A1O 3 36 '45. FeO 3 3-36, K 2 O 10 86, H 2 O 5'19=99'73. It is the gangue of cyanite at Pontivy in Brittany; and the same at Horrsjoberg, Werm- land. Associated with corundum in North Carolina ; with spodumene, at Sterling, Mass. PARAGONITB. Pregrattite. Cossaite. Massive, sometimes consisting distinctly of fine scales ; the rock slaty 01 schistose. Cleavage of scales in one direction eminent, mica-like. H.=2'5-3. G. 2779, paragonite; 2 895, pregrattite, (Ellacher. Lustre strong pearly. Color yellowish, grayish, grayish-white, greenish, light apple- green. Translucent ; single scales transparent. i Comp. A hydrous sodium mica. Q. ratio f or R : R : Si : H 1 : 9 : 12 : 2, or 1 : 1 for bases and silicon, if the water be made basic. Formula B^Na^lsSieOs^K : Na=l : 6)= Silica 46-60, alumina 39-96, soda 6 "90, potash 1'74, water 4*80=100. Pyr. B.B. the paragonite is stated to be infusible. The pregrattite exfoliates somewhat like vermiculite (a property of some clinochlore and other species), and becomes milk-white on the edges. Obs. Paragonite constitutes the mass of the rock at Monte Campione, in the region of St. Gothard, containing cyanite and staurolite, called paragonitic or talcose schist. The pregrattite is from Pregratten in the Pusterthal, Tyrol ; co^saite, from mines of Borgofranco, near Ivrea. IVIGTITE. Occurs in yellow scales, also granular, with cryolite from Greenland. EUPHYLLITE. Associated with tourmaline and corundum at Unionville, Penn. Q. ratio for R : R- : Si : H=l : 8 : 9 : 2. Average composition, Silica 41 -6, alumina 42 - 3, lime 1'5, potash 3 2, soda 5-9, water 5 "6 = 100. EPHESITE, LESLEYITE. Hydro-micas, perhaps identical with damourite. Occur with corundum, and impure from admixture with it. (ELLACHEBITE. A hydro-mica, containing 5 p. c. baryta. Pfitschthal, Tyrol. COOKEITE. A hydrous lithium mica. From Hebron and Paris, Me., apparently a pro- duct of the alteration of ru belli te. HISINQERITE. Amorphous, compact, without cleavage. II. =3. G.=3-045. Lustre greasy, inclining to vitreous. Color black to brownish-black. Streak yellowish-brown. Fracture conchoidal. Comp. Q. ratio for R+ft : Si : H=2 : 3 : 3 ; formula R 6 : R 2 Si 3 Oi8-f4aq (with one-third of the water basic). R=Fe,H 2 ; ft=Fe. Analysis, Cleve, from Solberg, Norway, Si0 2 35'33, Fe0 8 32-14, FeO 7-08, MgO 3'60, H 2 O 22'04=100;19. Pyr., etc. Yields much water. B. B. fuses with difficulty to a black magnetic slag. With the fluxes gives reactions for iron. In hydrochloric acid easily decomposed without gelatin- izing. Obs. Found at Longban, Tunaberg, Sweden ; Riddarhyttan ; at Degero (degeroite), near Helsingfors, Finland. EKMANNITE. Foliated, also radiated. Color green, resembles chlorite. Analysis, Igel- Btrom, SiO 2 34'80, FeO 8 4'97, FeO 35'78, MiiO 11 '45, MgO 2-99, H 2 10'51=100. With magnetite at Grythyttan, Sweden. NEOTOCITE. Uncertain alteration-products of rhodonite ; amorphous. Contains 20-30 p. c. MnO. Paisberg, near Filipstadt, Sweden ; Finland, etc. GILLINGITE ; Sweden. JOLLYTE ; Bodenmais, Bavaria. OXYGEN COMPOUNDS HYDROUS SILICATES. 355 Vemni&Mte Group.* The VERMICULITKS have a micaceous structure. They are all unisilicates, having the general quantivalent ratio R-J-R : Si : 11=: 2 : 2 : 1, the water being solely water of crystallization. The varieties differ in the ratio of the bases present in the protoxide and sesquioxide states.* JEFFERISITE. Orthorhombic (?). In broad crystals or crystalline plates. Cleavage : basal eminent, affording easily very thin folia, like mica. Surface of plates often triangularly marked, by the crossing of lines at angles of 60 and 120. H.=l*5. G.=:2'30. Lustre pearly on cleavage surface. Color dark yellowish-brown and brownish-yellow; light yellow by transmitted light. Transparent only in very thin folia. Flexible, almost brittle. Optically biaxial ; DcsCl. Comp. Q. ratio for R : R : Si : H=2 : 3 : 5 : 2|, and R-l-R : Si : H=2 : 2 : 1 ; whence R 4 RaSi 6 O !i +5aq. Analysis: Brush, Westchester, SiO 2 37-10, A10 3 17'57, Fe0 3 10'54, FeO 1-26, MgO 19-65, CaO 0'56, Na a O tr., K 2 O 0'43, H 2 O 13-76=100'87. Pyr., etc. When heated to 300 C. exfoliates very remarkably (like vermiculite) ; B.B. in forceps after exfoliation becomes pearly-white and opaque, and ultimately fuses to a dar* gray mass. With the fluxes reactions for silica and iron. Decomposed by hydrochloric acid. Obs. Occurs in veins in serpentine at Westchester, Pa. Plates often several inches across. PYROSCLERITE. Q. ratio for R : ft : Si : H=4 : 2 : 6 : 3, and for R+ft : Si : H=2 : 2 : 1. Silica 38-0, alumina 14-8, magnesia 34-6, water 11'7 = 100. Color green. Elba. CHONICRITE, also Elba, has the ratio 3:2:5:2. VERMICULITE. Q. ratio for R : ft : Si : H=:4 : 2 : 6 : 3. Milbury, Mass. CULSAGEEITE. Q. ratio R : R : Si : H=2 : 1 : 1 : 1. Jenk's mine, N. C. HALLITE, same ratio=2 : 1 : 3 : 2. East Nottingham, Chester Co., Penn. PELIIAMITE, same ratio=6 : 4 : 10 : 5. Pelham, Mass. Similar mineral from Lenni, Delaware Co., Pa., above ratio=6 : 4 : 10 : 5. In all of the above R=Mg mostly, and R=A1 and Fe. KERRITE. Q. ratio=6 : 3 : 10 : 10 ; and MACONITE, Q. ratio 3 : 6 : 8 : 5, are both from Culsagee mine, Macon Co., N. C. VAALITE, Q. ratio=6 : 3 : 10 : 4. South Africa. DIABANTITE, Hawes (diabantachronnyn, Liebe). Fills cavities in amygdaloidal trap. Color dark green. Q. ratio for R : ft : Si : H=;4 : 2 : 6 : 3, but iron a more prominent ingre- dient than in pyrosclerite (see above). Analysis : Hawes, Farmington, Ct., f SiOj 33 '68, A1O S 10-84, FeO 3 2-86, FeO 24-33, MnO 0'38, CaO 073, MgO 16'52, Na 2 0-33, H 2 O 10'02=99-69. SUBSILICATES. Chlorite Group. PENNINITE. Kammererite. Khombohedral. R A R = 65 36', O A R = 103 55 ; c = 3-4951. Cleavage; basal, highly perfect. Crystals often tabular, and in crested groups. Also massive, consisting of an aggregation of scales ; also com- pact cryptocry stall in e. * These relations were brought out by Cooke. Proc. Amer. Acad., Boston, 187 i, 35; ibid., 1875, 453. 356 DESCRIPTIVE MINERALOGY. 652 653 H.=2-2-5 ; 3, at times, on edges. G.=2-6-2-85. Lustre of cleavage surface pearly ; of lateral plates vitreous, and sometimes brilliant. Color green, apple-green, grass- green, grayish-green, olive-green; also reddish, violet, rose-red, pink, grayish-red ; occasionally yellowish and silver- white; violet crystals, and sometimes the green, hyacinth-red by trans- mitted light along the vertical axis. Transparent to subtranslucent. Laminae flexible, not elastic. Double refraction feeble ; axis either negative or- positive, and sometimes positive and negative in different laminse of the same plate or crystal. Comp. Q. ratio for bases and silicon 4 : 3, but varying 1 from 4 : 3 to 5 : 4. Exact deduc- tions from the analyses cannot be made until the state of oxidation of the iron in all cases is ascertained. Analysis: Schweizer, from Zermatt, Si0 2 33'07, A10 3 9 -69, FeO 11 '36, MgO 32-34, H 2 12-58=99-08. Pyr., etc. In the closed tube yields water. B.B. exfoliates somewhat and is difficultly fusible. With the fluxes all varieties give reactions for iron, and many varieties react for chromium. Partially decomposed by acids. Obs. Occurs with serpentine in the region of Zermatt, Valais, near Mt. Rosa ; at Ala, Piedmont ; at Schwarzenstein in the Tyrol ; at Taberg in Wermland ; at Snarum. Kam- mererite is found near Miask in the Urals; at Haroldswick in "Dnst, Shetland Isles. Abun- dant at Texas, Lancaster Co., Pa., along with clinochlore, some crystals being imbedded in clinochlore, or the reverse. The following names belong here : tabergite ; pscvdopfiite, compact, massive (allophite} ; loganite. Delessite, euralite, aphrosiderite, chlorophceite are chloritic minerals, occurring under simi- lar conditions, in amygdaloid, etc RIPIDOLITE. Clinochlore. Klinochlor, Germ. Monoclinic. C = 62 51' = A i-i, 1 A / = 125 37', A 44 = 108 14' : c : I : d = 1-47756 : 6- r >4 655 1-73195 : 1. Cleavage : eminent ; crystals often tab- ular, also oblong ; frequent- ly rhombohedral in aspect, the plane angles of the base being 60 and 120. Twins: twinning-plane 3 , making stellate groups, as in f. 656, 657, very common. Crystals often grouped in rosettes. Massive coarse scaly granular to fine granular and earthy. H.=2-2-5. G.=2-65-2-78. Lustre of cleavage-face somewhat pearly. Color deep grass-green to olive- green ; also rose-red. Often strongly dichroic. Streak greenish- white to uncoJored. Transparent to translucent. Flexible and somewhat elastic. Achmatovsk. Achmatovsk. OXYGEN COMPOUNDS HYDKOTJS SILICATES. 357 Westchester. Comp. Q. ratio for R : R : Si : H=5 : 3 : 6 : 4 ; corresponding to Mg 5 7VlSi 3 Ou-t-4aq=.: Silica 82-5, alumina 18 '6, magnesia 36-0, water 12 -9 = 100. Sometimes part of the Mg is replaced by Fe. Pyr., etc. Yields water. B.B. in the platinum forceps whitens and fuses with difficulty on the edges to a grayish-black glass. With borax a clear glass colored by iron, and sometimes chromium. In sul- phuric acid wholly decomposed. The variety from Willimantic, Ct., exfoliates in worm- like forms, like vermicuiite. Obs. Occurs in connection with chloritic and talcose rocks or schist, and serpentine. Found at Achmatovsk ; Schwarzenstein ; Zillerthal, etc. ; red (kotschubeite) in the dis- trict of Ufaleisk, Southern Ural ; at Ala, Piedmont ; at Zermatt ; at Marienberg, Saxony. In the U. S. , at Westchester and Unionville, and Texas, Pa. ; Brewster, N. Y. Named ripidolUe from pints, a fan, in allusion to a common mode of grouping of the crys- tals. LEUCHTENBERGITE. A prochlorite with the protoxide base almost wholly magnesia. Slatoust, Urals. PROCHLORITE. Hexagonal (?). Cleavage : basal, eminent. Crystals often implanted hy their sides, and in divergent groups, fan-shaped, or spheroidal. Also in large folia. Massive granular. H. = l-2. GL = 2-78-2-96. Translucent to opaque; transparent only in very thin folia. Lustre of cleavage surface feebly pearly. Color green, grass-green, olive-green, blackish-green ; across the axis by transmitted light sometimes red. Streak un colored or greenish. Laminae flexible, not. elastic. Double refraction very weak ; one optical negative axis (Dauphiny) ; or two very slightly diverging, apparently normal to plane of cleavage. Comp. Q. ratio for R : ft : Si : H=12 : 9 : 14 : 9 ; for bases and silicon 3 : 2. Average compositi on = Silica 26 -8, alumina 19'7, iron protoxide 27 '5, magnesia 15 '3, water 10-7=100. Pyr., etc. Same as for ripidolite. Obs. Like other chlorites in mode of occurrence. Sometimes in implanted crystals, as at St. Gothard, etc. ; in the Zillerthal, Tyrol; Traversella in Piedmont; in Styria, Bohemia. Also massive in Cornwall, in tin veins (where it is called peach] ; at Arendal in Norway. CRONSTEDTITE. Q. ratio R : ft : Si : H=3 : 3 : 4 : 8. Przibram; Cornwall. STRIGOVITE. Q. ratio=3 : 2 : 4 : 2. In granite of Striegan, Silesia. GROCHAUITE same locality. MARGARITE. Perlglimmer, Germ. Orthorhombic (?) ; hemihedral, with a rnonoclinic aspect. /A /= 119- 120. Lateral planes horizontally striated. Cleavage : basal, eminent. Twins : common, composition-face /, and forming, by the crossing of 3 crystals, groups of 6 sectors. Usually in intersecting or aggregated laminae ; sometimes massive, with a scaly structure. H.=3-5-4-5. GK=2-99, Hermann. Lustre of base pearly, laterally vitreous. Color grayish, red- dish-white, yellowish. Translucent, subtranslucent. Laminae rather brittle 358 DESCRIPTIVE MINERALOGY. Optic-axial angle very obtuse ; plane of axes parallel to the longer diagonal ; dispersion feeble. f Comp. Q. ratio for R : R- : Si : H=l : 6 : 4 : 1 ; whence, if the water be basic, for bases and silicon =2 : 1, formula RRSiOe ; that is, H 2 CaAl 2 Si2O, 2 . Analysis, Smith, Chester, Mass., SiO, 32-21, A1O 3 48-87, FeO s 2-50, MgO 0'32, CaO 10'02, Na 2 O(K 2 0) 1*91, H 2 O 4'61, Li.,0 0-32, MnO 0-20 = 100-96. Pyr., etc. Yields water in the closed tube. B.B. whitens and fuses on the edges. Obs. Margarite occurs in chlorite from the Greiner Mts. ; near Sterzing in the Tyrol ; at different localities of emery in Asia Minor and the Grecian Archipelago ; with corundum in Delaware Co., Pa.; at Unionville, Chester Co., Pa, (corunddlite} ; in Madison Co. }) and elsewhere in North Carolina ; at the emery mines of Chester, Mass. CHLORITOID. Monoclinic, or triclinic. I/\ I' about 100 ; (or cleavage surface) on lateral planes 93-95, DesCl. Cleavage : basal perfect : parallel to a lateral plane imperfect. Usually coarsely foliated massive ; folia oftei curved or bent, and brittle ; also in thin scales or small plates disseminatec through the containing rock. H.:= 5*5-6. G.= 3*5-3*6. Color dark gray, greenish-gray, greenish- black, grayish-black, often grass-green in very thin plates ; strongly dichroic. Streak uncolored, or grayish, or very slightly greenish. Lustre of surface of cleavage somewhat pearly. Brittle. Var. 1. The original chloritoid (or chloritspath) from Kossoibrod, near Katharinenburg in he Ural. 2. The Simiondine, from St. Marcel. 3. Masonite, from Natic, R. I., in very proad plates of a dark grayish-green color. The Canada mineral is in small plates, one-fourth in. wide and half this thick, disseminated through a schist (like phyllite), and also in nodules of radiated structure, half an inch through. That of Gumuch-Dagh resembles sismondine, is dark green in thick folia and grass-green in very thin. Comp. Q. ratio for R : ft : Si : H 1 : 3 : 2 : 1, for most analyses. Analysis by v. Kobell, Bregratten, SiO, 26'19, A10 3 38'30, Fe0 3 6 00, FeO 21 11, MgO 3'30, H 2 O 5 '50=100 "40. Pyr., etc In a matrass yields water. B.B. nearly infusible ; becomes darker and magne- tic. Completely decomposed by sulphuric acid. The masonite fuses with difficulty to a dark green enamel. Obs. The Kossoibrod chloritoid is associated with mica and cyanite ; the St. Marcel occurs in a dark green chlorite schist, with garnets, magnetite, and pyrite ; the Rhode Island, in an argillaceous schist ; the Chester, Mass. , in talcose schist, with emery, diaspore. etc. PhyUite (said ottrelite) closely resembles chloritoid, though the analyses hitherto made show a wide discrepancy, perhaps from want of purity in the material analyzed. Occurs in small, oblong, shining scales or plates, in argillaceous schist. Color blackish gray, greenish-gray, black. Phyllite occurs in the schist of Sterling, Goshen, Chesterfield, Plainfield, etc., in Massachusetts, and Newport, R. I. (newportite). Ottrelite is from a similar rock near Ottrez. SEYBERTITE. Orthorhombic. I,\l = 120. In tabular crystals, sometimes hexagonal; also foliated massive ; sometimes lamellar radiate. Cleavage : basal perfect. Structure thin foliated, or micaceous parallel to the base. H. =4-5. G. =3-3-1. Lustre pearly submetallic. Color reddish-brown, yellowish, copper-red. Folia brittle. Analysis. Brush, Amity, Si0 2 20-24, riJO 3 39-13, FeO 3 3'27, MgO20'84, CaO 13'69, H 2 O 1-04, Na 2 O,K 2 O) 1*43, ZrO 3 0-?5= 100-39. Amity, N. Y. (clintonite) ; Fassathal (brandmte}; Slatoust (xanthophyttite}. CORUNDOPHILITE. A chlorite with the Q. ratio=l : 1 : 1 : f . Occurs with ccrundum at Asheville. N. C.; Chester, Mass. DUDLEYITE. Alteration product of margarite. Clay Co., N. C. ; Dudleyville, Ala. WILLCOXITE. Near margarite. Decomposition product of corundum. Q. ratio f or R : R : Si : H=3 : 6 : 5 : 1. THURLNGITE. Q. ratio 2:3:3:2. Contains principally iron (Fe and Fe). Hot Springs, Arkansas ; Harper's Ferry (owenite). Pattersonite from Unionville, Pa. , near thuringite. OXYGEN COMPOUNDS. TANTALATES, COLUMBATE8. 359 2. TANTALATES, COLUMBATES. PYROCHLORE.* Isometric. Commonly in octahedrons. Cleavage: octahedral, some- times distinct, especially in the smaller crystals. H.=5-5'5. G. 4-2-4-35. Lustre vitreous or resinous. Color brown, dark reddish- or blackish-brown. Streak light brown, yellowish- brov//i. Subtranslucent opaque. Fracture conchoidal. Comp. A columbate of calcium, cerium, and other bases in varying 1 amounts. Analysis, by Rammelsberg. Brevig, Cb 2 O 5 58 '27, TiO 2 5 '38, ThO 2 4 '96, CeO 5 '50, CaO 10 "93, FeO;U0 2 ) 5-53, Na 2 O 5 31, F 3 '75, H 2 1-53 = 101-16. Obs. Occurs in syenite at Friederichsvarn and Laurvig, Norway; at Brevig; near Miask in the Urals ; Kaiserstuhlgebirge in Breisgau (koppite) ; with samarskite in N. Carolina (G-.= 4*794, chemical character unknown). MICROLITE.* In minute yellow octahedrons in feldspar. G.=5'5. Near pyrochlore, bufc probably containing more tantalum pentoxide. Chesterfield, Mass. PYRRHITE. In isometric octahedrons. Color orange-yellow. Chemical character un- known. From Mursinsk in the Ural. A mineral supposed to be similar from the Azores contains essentially, according to Hayes, columbium, zirconium, etc. AZOKITE. In minute tetragonal octahedrons resembling zircon. From the Azores in albifcu. Chemical character unknown. TANTALITB.* Orthorhombic. Observed planes as in O A 14 = 122 3' ; c : I : d = 1-5967 : 1-2247 : 1. A f-i = 117 2', a A 1-2 = 143 6i', 1-2 A 1-2, adj., = 141 48', i4 A *'-!== 11 8 33'. Twins: twinning-plane i-l, common. Also massive. H.=6-6'5. G.=7-8. Lustre nearly pure metallic, somewhat adamantine. Color iron-black. Streak red- dish-brown to black. Opaque. Brittle. the figure. /A7=101 C 35s', IT Comp., Var A tantalate either (1) of iron, or (2) of iron and manganese, or (3) a stanno- tantalate of these two bases. Formula Fe(Mn)Ta 2 6 . Sn is also often present (as FeSnO 3 . according to Ram- in elsberg\ and some of the tantalum is often replaced by columbium. Analysis. Ramm., Tammela (G.=7'384), Ta 2 O 5 70 '34, Cb 2 O 5 7 '54, SnO* 0'70.FeO 13-90, MnO 1-42=99'90. Other varieties contain much more Cb 2 O 6 , the kinds shade into one another. Pyr., etc. B.B. unaltered. With borax slowly dissolved, yielding an iron glass, which, ati a certain point of saturation, gives, when treated in R.F. and subsequently flamed, a gray- ish-white bead ; if completely saturated becomes of itself cloudy on cooling. With salt of phosphorus dissolves slowly, giving an iron glass, which in R.F., if free from tungsten, is pale yellow on cooling ; treated with tin on charcoal it becomes green. If tungsten is present the bead is dark red, and is unchanged in color when treated with tin on charcoal. With soda and nitre gives a greenish-blue manganese reaction. On charcoal, with soda and suffi- cient borax to dissolve the iron, gives in R.F. metallic tin. Decomposed on fusion with 360 DESCRIPTIVE MINERALOGY. potassium bisulphate in the platinum spoon, and gives on treatment with dilute hydrochloric acid a yellow solution and a heavy white powder, which, on addition of metallic zinc, assumes u ^malt-blue color ; on dilution with water the blue color soon disappears (v. Kobell). Obs. Tantalite is confined mostly to albite or oligoclase granite, and is usually associated with beryl. Occurs in Finland, at several places ; in Sweden, in Fahlun, at Broddbo and Finbo ; in France, at Chanteloube near Limoges, in pegmatite ; in North Carolina. Named Tantalite by Ekeberg, from the mythic Tantalus, in playful allusion to the difficul- ties (tantalizing) he encountered in his attempts to make a solution of the Finland mineral in acids. COLUMBITE.* Niobile. Ferroilmenite. Orthorhombic. 7 A 7= 101 26', A 14 = 134 53i' ; c:l\d = 1-0038 : 1-2225 : 1. A 1-2 = 140 36', A 1-3 = 138 26', i-l A 1-3 = 104 30', 1-S A 1-5, adj., = 151, i-3 A i-%, ov. i-t, 135 40', *'-2 A *-2, ov. i-i, = 135 30'. Twins : twinning-plane 2-1 Cleavage : i-l and i-$, the former most distinct. Occurs also rarely massive. 661 '62 663 Haddam. Middletown, Conn. Greenland. H.=6. G.=5'4-6'5. Lustre submetallic ; a little shin irig. black, brownish-black, grayish-black ; often iridescent black. Opaque. Fracture subconchoidal, uneven. Color iron- Streak dark red to Brittle. Comp., Var. FeCb 2 (Ta 2 )0 6 , with some manganese replacing part of the iron. The ratio of Cb : Ta generally=3 : 1 (Bodenmais, Haddam), sometimes 4 : 1, 8 : 1, 10 : 1, etc.; in the Greenland columbite the Ta 2 5 is almost entirely absent. Analyses, Blomstrand, (1) Haddam ^G.=615), (2) Greenland (G.=5'395). Cb 2 5 Ta 2 5 W0 8 SD0 2 ZrO 2 FeO MnO H 2 O (1) 51-53 28-55 0-76 0-34 0'34 13-54 497 0-16=100-19 (2) 77-97 0-13 0-73 013 17*33 3 51 = 99 -80 Pyr., etc. Like tantalite. Von Kobell states that when decomposed by fusion with caustic potash, and treated with hydrochloric and sulphuric acids, it gives, on the addition of zinc, a blue color much more lasting than with tantalite ; and the variety dianite, when similarly treated, gives, on boiling with tin-foil, and dilution with its volume of water, sapphire-blue fluid, while, with tantalite and ordinary columbite, the metallic acid remains undissolved. The variety from Haddam, Ct., is partially decomposed when the powdered mineral is evaporated to dryness with concentrated sulphuric acid, its color is changed to white, light gray, or yellow, and when boiled with hydrochloric acid and metallic zinc it gives a beautiful blue. The remarkably pure and unaltered columbite from Arksut-fiord in Green- land is also partially decomposed by sulphuric acid, and the product gives the reaction test with zinc, as above. Obs. Occurs at Rabenstein, Bavaria ; at Tirschenreuth, Bavaria ; at Tammela in Finland ; at Chanteloube, near Limoges ; near Miask in the Hmen Mts. ; at Hermanskar, near Bjorskar, in Finland ; in Greenland, at Evigtok. OXYGEN COMPOUNDS. TANTALATES, COLUMBATES. 361 In the United States, at Haddam, in a granite vein, and near Middletown, Conn. ; at Chesterfield, Mass. ; Standish, Me. ; Acworth, N. H. ; also Beverly, Mass.; Northfield, Mass, j Plymouth, N. H. ; Greenfield, N. Y. The Connecticut crystals are usually rather fragile from partial change ; while those of Greenland and of Maine are very firm and hard. HEKMANNOLITE (Shepard). From the columbite locality at Haddam, Ct., and a variety of columbite due to alteration. G. =5 '85. Supposed by Hermann to contain " ilmenium " pent oxide (I1 2 5 ). TAPIOLITE. Tetragonal. c=-6464 (rutile c=*6442). FeTa 2 (Cb 2 )O 6 , \\ith Ta : Cb=4 : 1. Tammela, Finland. HJELMITE. A stanno-tantalate of iron, uranium and yttrium. Massive. Color black. Near Fahlun, Sweden. YTTROTANTALITE. Black Yttrotantalite. Orthorhoinbic. 7A 7= 123 10' ; A 2-1 = 103 26'; c : I : d = 2-0934 : 1-8482 : 1. Crystals often tabular parallel to i-L 664 Also massive ; amorphous. H.=5-5'5. G.=5'4-5-9. Lustre submetallic to vitreous and greasy. Color black, brown. Streak gray to colorless. Opaque to subtranslucent. Frac- ture small conchoidal to granular. Comp. Mostly Jl 2 (Ta,Cb)y0 7 , with two equivalents of water, perhaps from alteration ; R=Fe : Ca : Y(Er,Ce)^l : 2 : 4. Con- taining also W0 3 and Sn0 2 . Analysis (Rainm.), Ytterby, Ta 2 6 46-25, Cb 2 O 6 12 32, SnO 2 M2, W0 3 2'36, U0 2 1*61,YO 10 ; 52, ErO 6-71, FeO 3-80, CeO 2'22, Ca 5-73, H 2 O 6'31=98'95. Pyr., etc. In the closed tube yields water and turns yellow. Ytterby. On intense ignition becomes white. B.B. infusible. With salt of , phosphorus dissolves with at first a separation of a white skeleton of tantalum pentoxid, which with a strong heat is also dissolved ; the black variety from Ytterby gives a glass faintly tinted rose-red from the presence of tungsten. With soda and borax on charcoal gives traces of metallic tin (Berzelius). Not decomposed by acids. Decomposed on fusion with potas- sium bisulphate, and when the product is boiled with hydry chloric acid, metallic zinc gives a pale blue color to the solution which soon fades. Obs. Occurs in Sweden at Ytterby ; at the Korarfvet mine, etc., near Fahlun. SAMARSKITE.* Uranotantalite. Orthorhombic. 7A7=122 46' 1-833 : 1. Crystals often flattened parallel to i-l, also less often to i-l. Also in large irregular masses (N. Carolina). In flattened imbedded grains (Urals). H.=5-5-6. G.=5-614-5-75 ; 5-45 -5-69, North Carolina. Lustre of surface of fracture shining and sub- metallic. Color velvet-black. Streak dark reddish-brown. Opaque. Frac- ture subconchoidal. Comp. Analyses : 1. Allen (priv. trib.) ; 2. Finkener anil Stephaus : l-l A l-l = 93 C 665 I : d = 0-949 . North Carolina. 362 DESCRIPTIVE MINERALOGY. CbaOs Ta 2 6 W0 3 Sn0 2 ThOiZrO.UOs MnO FeO CeO* YO CaO H 2 1. Mitchell Co., N. C., 37-20 18.60 0-08 12 46 0*75 10-90 4'25 14'45 0-55 1-12= U0 2 100-36 2. Miask, 47*47 1'36 0'05 6'05 4-35 10-950-96 ll*33f 3-31 12-61 0'73 0-45 MgO 0-14=99 -76 * With LaO, DiO. t With 0-JJ5 CuO. Pyr., etc. In the closed tube decrepitates, glows like gadolinite, cracks open, and turns black, and is of diminished density. B.B. fuses on the edges to a black glass. With borax in O.F. gives a yellowish-green to red bead, in R.F. a yellow to greenish-black, which on flaming becomes opaque and yellowish-brown. With salt of phosphorus in both flames an emerald -green bead. With soda yields a manganese reaction. Decomposed on fusion with potassium bisulphate, yielding a yellow mass which on treatment with dilute hydrochloric acid separates white tantalic acid, and on boiling with metallic zinc gives a fine blue color. Samarskite in powder is also sufficiently decomposed on boiling with concentrated sulphuric acid to give the blue reduction test when the acid fluid is treated with metallic zinc or tin. Obs. Occurs in reddish-brown feldspar, near Miask in the Ural ; the pieces having the size of hazel-nuts. In masses, sometimes weighing 20 Ibs.. in the decomposed feldspar of the mica mines of western North Carolina, especially in Mitchell Co. At both localities it is often intimately associated with columbite ; at Miask the crystals of the latter species are eometimes implanted in parallel position upon those of the samarskite. NOHLITE. Xear samarskite, but contains 4 "62 p. c. water. Nohl, Sweden. EUXEJNITJB. Orthorhombic. Form a rectangular prism with lateral edges replaced, and a pyramid at summit. Cleavage none. Commonly massive. 11.= 6*5. G.= 4*60-4*99. Lustre brilliant, metallic-vitreous, or some- what greasy. Color brownish-Mack ; in thin splinters a reddish-brown translucence lighter than the streak. Streak-powder yellowish to reddish- brown. Fracture subconchoidal. Comp. According to Rammelsberg 2RTi03 + RCb 2 6 +aq ; here R=Y,Fe,U mostly. Analysis, Ramm., Arendal, Cb 2 8 35*09, TiO a 2116, YO27'48, ErO3'40, U0 2 4 -78. CeO 3-17, FeO 1-38, H 2 O 2-63=99*63. Obs. Occurs at Jolster in Norway ; near Tvedestrand ; at Alve, island of Tromoen, near Arendal ; at Moretjar, near Naskilen. Named by Scheerer from etil-evos, a stranger, in allusion to the rarity of its occurrence. -, to deceive, older mineralogists having referred it to aquamarine, chrysolite, amethyst, fluor, schorl, etc OSTEOLITB is massive impure altered apatite. The ordinary compact variety looks like lithographic stone of white to gray color. It also occurs earthy. Hanau. GUANO. Guano is bone-phosphate of calcium, or osteolite, mixed with the hydrous phos- phate, brushite, and generally with some carbonate of calcium, and often a little magnesia, alumina, iron, silica, gypsum, and other impurities. It often contains 9 or 10 p. c. of water. It is often granular or oolitic ; also compact through consolidation produced by infiltrating waters, in which case it is frequently lamellar in structure, and also occasionally stalagmitic and stalactitic. Its colors are usually grayish-white, yellowish and dark brown, and some- times reddish, and the lustre of a surface of fracture earthy to resinous. 368 DESCRIPTIVE MINERALOGY. PHOSPHATIC NODULES. COPROLITES. Phosphatic nodules occur in many fossiliferous rocks, which are probably in all cases of organic origin. They sometimes present a spiral 01 other interior structure, derived from the animal organization that afforded them, and in such cases their coprolitic origin is unquestionable. In other cases there is no structure to aid in deciding whether they are true coprolites or not. FYROMORPHITE* Griinbleierz, Germ. Hexagonal. Hemihedral. O A 1 139 38' ; c = 0-7362. Cleavage : 1 and 1 in traces. / commonly striated horizontally. Often globular, reniform, and hotryoidal or verruciform, with usually a subcolumnar struc- ture ; also fibrous, and granular. H.=3'5-4. G.:=6'5-7-l, mostly when without lime; 5-6*5, when con- taming lime. Lustre resinous. Color green, yellow, and brown, of differ- ent shades; sometimes wax-yellow and fine orange-yellow; also grayish- white to milk-white. Streak white, sometimes yellowish. Subtransparent subtranslucent. Fracture subconchoidal, uneven. Brittle. Comp Analogous to apatite, 3Pb 3 P 2 8 +PbCl 2 = Phosphorus pentoxide 1571, lead oxide 82 '27, chlorine 2-62=100-60. Some varieties contain arsenic replacing part of the phosphorus, and others calcium replacing the lead. Pyr., etc. In the closed tube gives a white sublimate of lead chloride. B.B. in the forceps fuses easily (F.=1'5), coloring the flame bluish-green ; on charcoal fuses without reduction to a globule, which on cooling assumes a crystalline polyhedral form, while the coal is coated white from the chloride, and, nearer the assay, yellow from lead oxide. With soda on charcoal yields metallic lead ; some varieties contain arsenic, and give the odor of garlic in R.F. on charcoal. With salt of phosphorus, previously saturated with copper oxide, gives an azure- blue color to the flame when treated in O.F. (chlorine). Soluble in nitric acid. Diflf. Characterized by its high specific gravity, and pyrognostics. Leadhills in Scotland ; Wicklow, and elsewhere, Ireland. In the U. S. at Phenixville Penn also in Maine, at Lubec and Lenox ; in Davidson Co., N. C. The figures produced by etching (see p. 118) show that pyromorphite is hemihedral like apatite (Baumhauer). Named from rip, fire, popf-fi, form, alluding to the crystalline form the globule assumes on cooling. Hexagonal, MIMETITE.* Mimetesite. O A 1 = 139 58' ; c = 0-7276. Cleavage : 1, imperfect. H.=3'5. G.=7'0-7'25, mimetite ; 5'4-5'5, hedy- phane. Lustre resinous. Color pale yellow, passing into brown; orange-yellow; white or colorless. Streak white or nearly so. Subtransparent translucent. Comp. Formula 3Pb 3 As 2 8 -j-PbCl 2 =Arsemc pentoxide 23-20, lead oxide 74-96, chlorine 2'39=100'55. Generally part of the arsenic is replaced by phosphorus, and often the lead in part by cal- cium. Pyr., etc. In the closed tube like pyromorphite. B.B. fuses at 1, and on charcoal gives in R. F. an arsenical odor, and is easily reduced to metallic lead, coating the coal at first with lead chloride, and later with arsenous oxide and lead oxide. Gives the chlorine reac- tions as under pyromorphite. Soluble in nitric acid. Obs. Occurs at several of the mines in Cornwall ; in Cumberland. At St. Prix in France T at Johanngeorgenstadt ; at Nertschinsk, Siberia. At the Brookdale mine, Phenixville, Pa. OXYGEN COMPOUNDS. PHOSPHATES, AESENATES, ETC. 367 Mimetite is hemihedral like apatite and pyromorphite, as shown by etching (Baumhauer), Named from iiiu-nriis, imitator, it closely resembling pyromorphite. HEPYpS^.S variety containing much calcium. CAMPYLITE contains much lead phc* phate. VANADINITE.* Hexagonal. In simple hexagonal prisms, and prisms terminating in planes of the pyramids ; 1 A 1, over terminal edge, 142 58', A 1 = 140 34/ /A 1 = 130. Usually in implanted globules or incrustations. H =2-75-3 G.= 6-6623-7.23. Lustre of surface of fracture resinous. Color light brownish-yellow, straw-yellow, reddish-brown. Streak white or yellowish. Subtranslucent opaque. Fracture uneven, or flat concnoi brittle. Comp,-Formula 3Pb 3 V 2 8 +PbCl 2 =Vanadium pentoxide 10-86, lead oxide 7870 chlorine P Pvr!, eto^In the closed tube decrepitates and yields a faint white sublimate B.B. fusea easily and on charcoal to a black lustrous mass, which in R. P. yields metallic lead and a cpat- LTof chloride of lead; after completely oxidizing the lead in O.F the black residue give* with salt of phosphorus an emerald-green bead in R.F., which becomes light yellow in O.F. Gives the chlorine reaction with the copper test. Decomposed by hydrochloric acid. If nitric acid be dropped on the crystals they become first deep red from the separation of vanadium pentoxide, and then yellow upon its solution. -.T-MM c- ^ O i Obs.-This mineral was first discovered at Zimapan in Mexico, by Del Rio. Since obtained at Waniockhead in Dumfriesshire ; also at Beresof in the Ural ; and near Kappel in Carmthia. DECBENITE. PbV 2 8 (or with some Zn)= Vanadium pentoxide 451, lead oxide 54 -9-100 Massive. Color deep red. Dahn, near Niederschlettenbach, Rhenish Bavaria. pentoxide 29'1, lead oxide 70 9=100. Orthorhombic. c near brookite in form ( W**fl* Occurs m small implanted crystals. Color reddish-brown. In composition a bismuth vanadate, BiVO 4 - Vanadium pentoxide 28-3. bismuth oxide 71 '7. Pucher mine, Schneeberg, Saxony. ROSCOELITE. Occurs in thin micaceous scales, arranged in stellate or fan-shaped &P*' Color dark brownish-green. Soft. G.=2 938 (Genth) ; 2-902 (Roscoe). Analyses : 1. Ros- coe (Proc. Roy. Soc., May 10, 1876); 2. Genth (Am. J. Sci., July, 1876). Si0 2 V 2 5 A10 3 Fe0 3 Mn0 3 MgO CaO K 2 O Na.0 1. |41-25 28-60 14-14 113 115 2*01 0'61 2. 47-69 2202V 6 On 1410 1-67 FeO 2'00 to. The above analyses, made upon material derived from the same source differ widely, especially in regard to the state of oxidation of the vanadium. Genth makes it V.On - 2V 2 3 ,V;0, The formula given by Roscoe is 2MV,O. t K,Si 9 O 20 + aq. Found *Bh the porphyry and in cavities in quartz at the gold mine at Granite Creek, El Dorado Uo., Cal. Named by Dr. Blake, who discovered it. See further on p. 435. 368 DESCRIPTIVE MINERALOGY. WAGNERTTB. f Monoclimc. C= 71 53', /A 1= 95 25', 6> A l-l = 144 25', B.&M.; c : b : d = O7S654: : 1-045 : 1. Most of the prismatic planes deeply striated. Cleavage : 7, and the orthodiagonal, imperfect ; O in traces. H.=5-5'5. Gr.= 3-068, transparent crystal; 2-9S5, untraiisparent, Ram- melsberg. Lustre vitreous. Streak white. Color yellow, of different shades ; often grayish. Translucent. Fracture uneven and splintery acrosa the prism. Oomp. Mg 3 P 2 8 +MgF 2 = Phosphorus pentoxide 43 '8, magnesia 371, fluorine 11 '7, mag- nesium 7 '4 =100. Pyr., etc. B.B. in the forceps fuses at 4 to a greenish-gray glass ; moistened with sulphu- ric acid colors the flame bluish-green. With borax reacts for iron. On fusion with soda effervesces, but is not completely dissolved ; gives a faint manganese reaction. Fused with salt of phosphorus in an open glass tube reacts for fluorine. Soluble in nitric and hydro- chloric acids. With sulphuric acid evolves fumes of fluohydric acid. Obs. Occurs in the valley of Hollgraben, near Werfen, in Salzburg, Austria. KJERULFINE (v. Kobell). Stands near wagnerite, but exact nature uncertain. In masses of a pale red color at Bamle, Norway. MONAZITE.* Monoclinic. C= 76 14', /A 7=93 10', A 14 = 138 8'; c : b : d = 0-94715 : 1-0265 : 1. Crys- tals usually flattened parallel" to i-i. Cleavage : very perfect, and brilliant. Twins: twin- ning plane O. H. = 5-5-5. G. = 4-9-5-26. Lustre inclining to resinous. Color brownish-hyacinth-red, clove-brown, or yellowish- brown. Subtransparent sub- translucent. Rather brittle. Norwich, Ct. ii Watertown, Ct. Comp. According to Rammelsberg, 5R 3 P 2 O 8 +Th 2 P.,O 9 , where R=Ce,La, Di. Analysis by Kersten, Slatoust, P 2 5 28-50, Th0 2 17-95, Sn0 2 210, CeO 26'00, LaO 23'40, MnO 1'86, CaO l'b'8, K 2 O and TiO, Jr. =101 -49. Pyr., etc. B.B. infusible, turns gray, and when moistened with sulphuric acid colors the flame bluish-green. With borax gives a bead yellow while hot and colorless on cooling ; a saturated bead becomes enamel-white on flaming. Difficultly soluble in hydrochloric acid. Diflf. Its brilliant basal cleavage is a prominent character, distinguishing it from tita- nite. Obs. Monazite occurs near Slatoust in the Ilmen Mtn. ; also in the Ural ; near Notero in Norway ; at Schreiberhau. In the United States, with sillimanite at Norwich ; at Yorktown, Westchester Co., N.Y.; near Cfowder's Mountain, N. C. Named from //omCw, to be solitary, in allusion to its rare occurrence. TURNERITE. Identical with monazite, as first suggested by Prof. J. D. Dana. Occurs in minute yellow to brown crystals, rarely twins, at Mt Sorel. Dauphiny ; Santa Brigritta, Tavetsch; Lercheltiny Alp, Binnenthal ; Laacher See (v. Rath.), c : b : d= '921696 : 1 ; 0-958444. 01=77 18' (Trechmann). KORABPVEITE (Rodominski). A cerium phosphate containing fluorine; near monazite Occurs in large crystalline masses of a yellowish color at Korarfvet, near Fahlun, Sweden. OXYGEN COMPOUNDS. PHOSPHATES, AKSENATES, ETC. 369 TRIFHYLITE.* Triphyline. Orthorliombic. /A 1= 98, A l-l = 129 33', Tschermak ; c : I : d = 1-211 : 1-1504 : 1. Faces of crystals usually uneven. Cleavage : nearly perfect in unaltered crystals. Massive. H.=5. G.=3'54-3*6. Subresinous. Color greenish- gray ; also bluish ; often brownish-black externally. Streak grayish-white. Translucent in thin fragments. Comp. R 3 P 2 8 , where R=Fe, Mn, (Ca) and Li 2 (K 2 , Na 2 ). Analysis by Oesten, from Bgdenmais, P 2 O 6 44 -19, FeO 38 "21, MnO 5 "63, MgO 2-39, CaO 0-76, Li 2 O 7'69, Na 2 O 0'74, K 2 O 0'04, SiO, 40 =100 '05. The analyses vary much, owing to the impure material employed. Pyr., etc. In the closed tube sometimes decrepitates, turns to a Norwich, dark color, and gives off traces of water. B.B. fuses at 1/5, coloring the flame beautiful lithia-red in streaks, with a pale bluish-green on the exterior of the cone of flame. The coloration of the flame is best seen when the pulverized mineral, moistened with sulphuric acid, is treated on a loop of platinum wire. With borax gives an iron bead ; with soda a reaction for manganese. Soluble in hydrochloric acid. Ob*. Triphylite occurs at Rabenstein near Zwiesel in Bavaria ; also at Keityo in Finland ; Norwich, Mass. Named from r/o/f, three-fold, and QvW, family, in allusion to its containing three phos- phates. TRIFLITE.* Zwieselite. Orthorhombic. Imperfectly crystalline. Cleavage : unequal in three directions perpendicular to each other, one much the most distinct. H.=5-5-5. G. = 3'44r-3'8. Lustre resinous, inclining to adamantine. Color brown or blackish-brown to almost black. Streak yellowish- gray or brown. Subtranslucent opaque. Fracture small conchoidal. Comp. R 3 P 2 O s -fRF 2 ; R=Fe, Mn(Ca). Analysis, v. Kobell, Schlackenwald, P 2 O 8 33 85, Fe0 3 3-50, FeO 23'38, MnO 30'00, CaO 2 20, MgO 3 05, F=810=104-08. Pyr., etc. B.B. fuses easily at 1/5 to a black magnetic globule; moistened with sulphuric acid colors the flame bluish-green. With borax in O.F. gives an amethystine colored glass (manganese) ; in R.F. a strong reaction for iron. With soda reacts for manganese. With eulphuric acid evolves fluohydric acid. Soluble in hydrochloric acid. Obs. Found by Alluaud at Limoges in France, with apatite ; at Peilau in Sdesia. Zwieselile, a clove-brown variety, was found near Rabenstein, near Zwiesel in Bavaria, m quartz (Gk=3'97, Fuchs). SARCOPSIDE. Near triplite. Valley of the Muhlbach, Silesia. AMBLYGONTTE.* Triclinic. Cleavage : O perfect ; i-l nearly perfect, angle between these cleavages 104 J ; also /imperfect. Usually massive, cleavable ; sometimes columnar. /xlx H.=6. G.= 3-3*11. Lustre pearly on face of perfect cleavage (U)\ vitreous on i-l, less perfect cleavage-face ; on cross-fracture a little greasy. Color pale mountain or sea-green, white, grayish, brownish-white, bub- transparent translucent. Fracture uneven. Optical axes very divergent ; plane of axes nearly at right angles toi; bisectrix of the acute angle negative, and parallel to the edge O/i-l; Dead. 370 DESCRIPTIVE MINERALOGY. Oomp. According to Rammelsberg, 2MP 2 Oe+3Li(Na)F. If Na : Li=l : 4, the formula requires : Phosphorus pentoxide 49 '24, alumina 35-58, lithia 6 '24. soda 3-23, fluorine 9 "88 = 104 -17. Pyr., etc. In the closed tube yields water, which at a high heat is acid and corrodes the glass. B. B. fuses easily at 2, with intumescence, and becomes opaque -white on cooling. Colors the flame yellowish- red with traces of green ; the Hebron variety gives an intense lithia-red ; moistened with sulphuric acid gives a bluish-green to the flame. With cobalt solution assumes a deep blue color (alumina). With borax and salt of phosphorus forms a transparent colorless glass. In fine powdei dissolves easily in sulphuric acid, more slowly in hydrochloric. Diff. Distinguished by its easy fusibility ; reaction for fluorine and lithia ; greasy lustre in the mass, etc. Obs. Occurs at Chursdorf and Arnsdorf , near Penig in Saxony ; also at Arendal, Norway. In the U. States, in Maine, at Hebron (hebronite), imbedded in a coarse granite with lepidolite, albite,, quartz, red, green, and black tourmaline ; also at Mt. Mica in Paris, 8m. from Hebron, with tourmaline. The name is from a///3/\wf, blunt, and y6v\\ angle. HEBRONITE. The mineral from Hebron, Me. (see above), has been shown by DesCloizeaux to diifer in optical character (v > p) from the , Penig amblygonite. On this ground, as well as oh account of a variation in the composition, it has been proposed (v. Kobell) to make it a new species. The sam optical character and composition belong to the mineral from Montebras (called montebrasiti on the basis of an erroneous analysis). Analysis of hebronite, Pisani, P 2 O 3 46'65, :MO< 3G-00, Li 2 O 9-75, H 2 4 '20, F 5 '22 =101 -82. HERDERITE. Supposed to be an anhydrous aluminum-calcium phosphate, with fluorine. Color yellowish-white. Ehrenfriedersdorf. DURANGITE. Monoclinic Cleavage prismatic (110 10'). H.=5. G. =3 '937-4 -07. Coloi bright orange-red. Analysis, Hawes, Arsenic pentoxide 53 '11, alumina 1719, iron sesqui- oxide 9'23, manganese sesquioxide 2 -08, soda 13'0b', lithia 0'05, fluorine 7 -67=102-99. Hebronite, Maine. Formula HaRAs^Ou (with one-ninth of the oxygen replaced by fluorine), or Here R Na : Li^lO : 1 ; ft=Al : Fe : Mn=15 : 5 : 1. Other varieties, having a lighter color, have Al : Fe=5 : 1. Occurs with cassiterite, near Durango, Mexico (Brush). ANHYDROUS ANTIMONATES. MONIMOLITE. Mainly an antimonate of lead. Yellow. G.=5'94. Paisberg, Sweden. NADORITE. PbSb >0 4 + PbCl 2 . In yellow translucent crystals. H. =3. G. =7 -02. Djebel Nador, province of Constantino, Algiers. ROMEITE. An antimonate (or antimonite) of calcium. Occurs in groups of minute tetra- gonal crystals. Color yellow. St. Marcel, Piedmont. RIVOTITE. Contains antimonic oxide, carbon dioxide, and copper. Amorphous. ColoJ yellowish-green. Sierra del Cadi. STIBIOFERRITE. Amorphous coating on stibnite, from Santa Clara Co., Cal. Mixture (?). HYDROUS PHOSPHATES, ARSENATES, ETC. PHARMACOLITB. Monoclinic. /A 1= 111 6', i-l A a-2 = 109 26', 1 A 1 = 117 24', Cleavage : ?<4 eminent. One of the faces 1 often obliterated by the exten eion of the other. Surfaces i-i and i-2 usually striated parallel to theii mutual intersection. Rarely in crystals; commonly in delicate silky fibres or acicular crystallizations, in stellated groups. Also botryoidal and stalac- titic, and sometimes massive. OXYGEN COMPOUNDS. PHOSPHATES, ARSENATES, ETC. 371 H.==2-2'5. G. = 2'64r-2'73. Lustre vitreous ; on i-l inclining to pearly Color white or grayish ; frequently tinged red )y arsenate of cobalt. Streak white. Trans- .11 cent opaque. Fracture uneven. USB flexible. Thin lam i- Comp. 2HCaAs04+5aq= Arsenic pentoxide 51 '1, lime 34-9, water 24-0= 100. Pyr., etc. In the closed tube yields water and becomes Dpaque. B.B. in O.F. fuses with intumescence to a white anamel, and colors the flame light blue (arsenic). On char- 3oal in R.F. gives arsenical funus, and fuses to a semi-transparent globule, sometimes tinged >lue from traces of cobalt. The ignited mineral reacts alkaline to test paper. Insoluble in water, but readily soluble in acids. Obs. Found with arsenical ores of cobalt and silver at Wittichen, Baden ; at Andreasberg, and at Riechelsdorf and Bieber ; at Joaohimsthal. This species was named, in allusion to its containing arsenic, from (pdpnatcov, poison. STRUVITE. An ammonium-magnesium phosphate containing 12 equivalents of water. In guano from Saldanha Bay, Africa. HAIDINGERITE. HCaAs0 4 +aq.= Arsenic pentoxide 58'1, lime 28'3, water 13 6=100. Foachimsthal (?). BRUSHITE. HCaP0 4 (R 3 P.O 8 )-j-2aq=Pho8phorup pentoxide 41-3, lime 32'6, water 61 = [00. Monoclinic. G-.=2 208. On guano at Aves Island and Sombrero. METABKUSIIITE. 2HCaP0 4 +3aq. G.=2'35. Sombrero. ORNITHRITE. Probably altered brushite. CHUROIIITE. R 3 Pi0 8 +4aq, with R=Ce(Di),Ca. Cornwall. WAPPLERITE (Frenzd). Triclinic. In minute crystals and in incrustations. Color white. Composition H,Ca.Mg)As0 4 +7aq=(Ca : Mg=4 : 3) arsenic pentoxide 48'7, lime 13-5, mag- nesia 7'3, water 30 '5 =100. Found with pharmacolite at Joachimsthal. Schrauf states that r&sslerite is a pseudomorph after wapplerite. HOERNESITE. Monoclinic. Color snow-white. Composition Mg 3 As 2 8 +8aq. From the Banat. PICROPHARMACOLITE. Monoclinic. Ca 3 (Mg 3 )As 2 O 8 -l-Gaq. Riechelsdorf; Freiberg. VTVIANITE. Monoclinic. O = 75 34', /A 7 = 108 2', 1 A 1 = 120 26', 935792 : 1-33369 : 1 ; v. Rath. Surface i-l smooth, others striated. Cleavage : i-l, highly perfect ; i-i and \-i in traces. Often reniform and globular. Structure diver- gent, fibrous, or earthy ; also incrusting. II. = 1-5-2. G.=2-58-2-68. Lustre, i-l pearly or me- tallic pearly ; other faces vitreous. Color white or color- less, or nearly so, when unaltered ; often blue to green, deepening on exposure; usually green when seen per- pendicularly to the cleavage-face, and blue transversely ; the two colors mingled, producing the ordinary dirty blue color. Streak colorless to bluish-white, soon changing to indigo-blue; color of the dry powder often liver-brown. Transparent translucent; becoming opaque on expo- sure. Fracture not observable. Thin laminae flexible. Sectile. Comp FeP 2 6 -f 8aq= Phosphorus pentoxide 28*3, iron protoxide 43 '0, water 28 '7 =130 ?&* 372 DESCRIPTIVE MINERALOGY. Pyr., etc. In the closed tube yields neutral water, whitens and exfoliates. B.B. fuses at 1*5, coloring the flame bluish- green, to a grayish-black magnetic globule. With the fluxeg reacts for iron. Soluble in hydrochloric acid. Diff. Distinguishing characters : deep-blue color ; softness ; solubility in acid. Obs Occurs associated with pyrrhotite and pyrite in copper and tin veins ; in beds of clay, and sometimes associated with limonite, or bog iron ore; often in cavities of fossils or buried bones. Occurs at Wheal Falmouth, and elsewhere in Cornwall ; in Devonshire, near Tavistock ; at Bodenmais. The earthy variety, called blae iron earth or native Prussian blue occurs in Greenland, Carinthia, Cornwall, etc. At Cransac, Prance. In N. America, it occurs in New Jersey, at Allentown ; at Franklin. Also in Delaware, near Middletown ; near Cape flenlopen. In Maryland, in the north part of Somerset and Wor- cester Cos. In Virginia, in Stafford Co. In Canada, with limonite at Vandreuil, abundant. LUDLAMITE (Field). Monoclinic. H.=3 4. G.=3-12. Color clear green, from pale to dark. Transparent, brilliant. Composition 2Fe 3 P v ,O 8 + H 2 FeO 2 + 8aq=Phosphorus pentoxide 29-88, iron protoxide 53 "06, water 17-06=100. Cornwall. ERYTHRITE. Cobalt Bloom. Kobaltbliithe, Germ. Monoclinic. C= 70 54', /A 1= 111 16' O A 14 = 146 19'; c : I : d = 0-9747 : 1-3818 : 1. Surfaces i-i and I-i vertically striated. Cleavage : i-\ highly perfect, i-i and \-i indis- tinct. Also in globular and reniform shapes, having a drusy surface and a columnar structure ; sometimes stel- late. Also pulverulent and earthy, incr listing. H. 1-5-2-5 ; the lowest on i-i. G.= 2-948. Lustre of i-i pearly ; other faces adamantine, inclining to vitre- ous ; also dull and earthy. Color crimson and peach- red, sometimes pearl- or greenish-gray ; red tints incline to blue, perpendicular to cleavage-face. Streak a little paler than the color ; the dry powder deep lavender- blue. Transparent subtranslucent. Fracture not ob- Schneeberg. servable. Thin laminae flexible in one direction. Sectile, Comp. Co 3 As 2 O 8 +8aq= Arsenic pentoxide 38 '40, cobalt oxide 37 '56, water 2404; Co often partly replaced by Fe,Ca, or Ni. Pyr., etc. In the closed tube yields water at a gentle heat and turns bluish ; at a highei heat gives off arsenous oxide, which condenses in crystals on the cool glass, and the residue has a dark gray or black color. B. B. in the forceps fuses at 2 to a gray bead, and colors the flame light blue (arsenic). B.B. on charcoal gives an arsenical odor, and fuses to a dark gray arsenide, which with borax gives the deep blue color characteristic of cobalt. Soluble in hydrochloric acid, giving a rose-red solution. Obs. Occurs at Schneeberg in Saxony ; at Saalfeld in Thuringia ; Wolfach and Witticher in Baden; Modum in Norway; at Allemont in Dauphiny; in Cornwall, at the Botallack mine, etc. Erythrite, when abundant, is valuable for the manufacture of smalt. Named from 3pv6p6s, red. ROSELITE.* Triclinic (Schrauf). Usually in complex twin crystals. H.=3'5. G. =3-585 -3'738. Color rose-red. Composition R 3 As 2 O 8 +2aq (or 3aq), with R=Ca,Mg, and Co. Ana- lysis, Winkler, As 2 O 6 49'96, CoO 12'45, CaO 23-72, MgO 4 '67, H 2 O 9-69=100 "49. Found at Schneeberg, Saxony ; the crystals from the Daniel Mine have a lighter color than those of the Rappold Mine, the latter containing less cobalt and more calcium. WINKLEKITE. Contains As 2 6 ,Cu,eo,Fe,Co,Ni,Ca,H,O,CO 2 , etc. Mixture (?). Pria, Spain. KOTTIGITR. Near erythrite, but contains zinc. Schneeberg. ANNABERGITE (Nickelbliithe, Germ.}. Ni 3 As 2 O 8 f-8aq= Arsenic pentoxide 38'6, nickel oxide 37 "2, water 24-2=100. Soft, earthy. Color apple-green. Allemont; Annaberg ; Biechelsdorf. HUKEAULITE. A hydrous iron-manganese phosphate, O3curing in cavities in triphylit* at Limoges, France. CHONDRARSEKITE. Yellow grains in barite ; probably a manganese arsenate. Paisberg, Sweden. OXYGEN COMPOUNDS. PHOSPHATES, AKSENATES, ETC. 373 = 0-7311 LEBETHENITB. Orthorhombic. /A 1= 92 20', O A l-l = 143 50' ; 1*0410 : 1. Crystals usually octahedral in aspect. leavage : diagonal, i-l, i-%, very indistinct. Also globu- ar or reniform, and compact. .^4. G.=3'6-3-8. Lustre resinous. Color olive- green, generally dark. Streak olive-green. Translucent. io subtranslucent. Fracture subconchoidal uneven. Brittle. Comp. Cu 4 P 2 O 9 -f-aq, or Cu 3 P 2 8 -hH 2 Cu0 2 (Ramm.)= Phosphorus pentoxide 29 '7, copper oxide 66 '5, water 3 '8 =100. Pyr., etc. In the closed tube yields water and turns black. B.B. 'fuses at 2 and colors the flame emerald-green. On charcoal with soda gives metallic copper, sometimes also an arsenical odor. Fused with metallic lead on charcoal is reduced to metallic copper, with the forma- tion of lead phosphate, which treated in R.F. gives a crystalline polyhedral bead on cooling. With the fluxes reacts for copper. Soluble in nitric acid. Obs. Occurs at Libethen, in Hungary ; at Rhembreitenbach and Ehl on the Rhine ; at Nischne Tagilsk in the Ural ; in Bolivia ; Chili \ = 0-72 : 680 if OLIVBNITE. Orthoi-hombic. /A 1= 92 30', A 14 - 144 14' ; c : 1*044:6 : 1. Cleavage: / and 14 in traces. Sometimes aci- cular. Also globular and reuiform, indistinctly fibrous, fibres straight and divergent, rarely promiscuous; also curved lamellar and granular. H.=3. Gr.=4-l-4-4. Lustre adamantine vitreous ; of some fibrous varieties pearly. Color various shades of olive- green, passing into leek-, siskin-, pistachio-, and blackish- green ; also liver- and wood- brown ; sometimes straw-yellow and grayish-white. Streak olive-green brown. Subtrans- parent opaque. Fracture, when observable, conchoidal uneven. Brittle. Com P .-Cu 4 As 2 O a +aq=Cu 3 As 2 8 +H 2 Cu0 2 (Ramm.)= Arsenic pentoxide 40'66, coppei X pyr! etl' Tnlhe closed tube gives water. B.B. fuses at 2, coloring the flame bluish-green, and on cooling the fused mass appears crystalline. B. B. on charcoal fuses with deflagration, gives off arsenical fumes, and yields a metallic arsenide, which, with soda yields a globule copper. With the fluxes reacts for copper. Soluble in nitric acid. . . Obs. The crystallized varieties occur in many of the Cornwall mines ; near Tavistock in Devonshire ; also at Alston Moor in Cumberland ; at Camsdorf and Saalf eld in Thunngia ; tJ: Tyrol; the Banat; Siberia; Chili; and other places. oi_inn ADAMITE. Zn3AsoO 8 +H 2 ZnO 2 =:Arsenic pentoxide 40'2, zinc oxide 56 '7, water d Color yellow. Chanarcillo, Chili ; Cap Garonne. TAGILITE -Cu 4 P 2 O 9 +3aq (=Cu 3 P 2 O8+H 2 CuO.+2aq). Color emerald-green. Tagilsk. ISOCLASITE. Ca 4 P-,0 9 +5aq (=Ca 3 P 2 O 8 + H 2 CaO 2 + 4aq). Colorless to snow-white. EucnROirE. Cu 3 AsoO 8 +H 2 CuO 2 -H6aq (Ramm.)= Arsenic pentoxide 34'1, copper oxide 47-2. water 18 '7= 100. Color emerald -green. Libethen, Hungary. CHLOKOTILE. Cu s As 2 O 8 + 6aq. In capillary crystals. Also fibrous^; massive. Color apple- green. In quartz at Schneeberg and Zinnwald ; Thuringia; Chili (^ re ^ff>- K VESZELYITE (Schranf).-A hydrous copper phosphate ; composition 4Cu 3 l 2 O 8 +oaq. clinic. Occurs in crystalline crusts on a garnet-rock at Morawicza in the Banat. Tri- 374: DESCRIPTIVE MINER ALOOY. LIROCONITE. Linsenerz, Germ. Monoclinic. /A 7 -=74 21', DesCl. C = 88 33'. Cleavage lateral, but obtained with difficulty. Rarely granular. Ii. 2-2-5. G. = 2'88-2*98. Lustre vitreous, inclining to resinous. Color and streak sky-blue verdigris-green. Fracture imperfectly 'on- choidal, uneven. Imperfectly sectile. Comp. Formula Cu 3 (rU) As 2 (P.,)0 8 +H 6 (Cu3.Al)0 6 -l-9aq, with Cu 3 : Al=3 : 2, and As : P=l : 4. This requires arsenic pentoxide 23 *1, phosphorus pentoxide 3 "6, copper oxide 35 '9 alumina 10 '3, water 27 '1100. Fyr-, etc. In the closed tube gives much water and turns olive-green. B.B. cracks open, out does not decrepitate ; fuses less readily than olivenite to a dark gray slag ; on charcoal cracks open, deflagrates, and gives reactions like olivenite. Soluble in nitric acid. Obs. With various ores of copper, pyrite, and quartz, at Wheal Gorland, Wheal Muttrell, etc.. in Cornwall; also in minute crystals at Herrengrund in Hungary ; and in Voigtland. PSEUDOMALACHITE Phosphochaltite. Cu 6 P.Oi i +3aq=:Cu 3 P,O 8 +3H 2 Cu0 2 =:P 2 O5 21 1 , CuO 70-9, H 2 O 8*0=100. Triclinic (Schrauf). G.=4'34. Color emerald-green. Related sub-species: EHLITE (Prasine), Cu 3 P-iO 8 + 2H 1 CuO^ + aq (Ramm.) ; DIIIYDKITE, Cu 3 PiO ri + 2H 2 CuO 2 . Eh.1, near Liuz, on the Rhine ; Libethen, Hungary ; Nischne Tagilsk ; Cornwall. ERINITE. Cu 3 As 2 O8+2H 2 CuO 2 . In mammillated crystalline groups. Color green. Corn- wall. CORN WALL ITE. Cu 6 AB 2 Oio+3aq (=Cu 3 As 2 08+2H 2 Cu0 2 + aq). Amorphous. Color green. Cornwall (Church). PSITTACINTTE. Occurs in thin crypto-crystalline coatings, sometimes having a botryoidaJ structure ; also pulverulent. Color siskin green to olive-green. Formula 2R 3 V-.'O 8 -I- 3H 2 CuO a +6aq, with R=Pb : Cu=3 : 1. This requires : Vanadium pentoxide 19'32, lead oxide 53*15, copper oxide 18*95, water 8 58=100. Found at the gold mines in Silver Star District, Mon- tana (Genth. Am. J. Sci., III., xii., 35, 1870). MOTTKAMITE. Occurs as a thin crystalline incrustation, which is sometimes velvety, con- sisting of minute crystals ; more generally compact H. =3. G. =5 '894. Color black by reflected light, in thin particles yellowish, translucent (crystals) ; purplish-brown, opaque, (compact). Formula (Pb,Cu) 3 V 2 O8 + 2H 2 (Pb,Cu)O_>, which requires vanadium pentoxide 18*74, copper oxide 20 '39, lead oxide 57'18, water 3 '69= 100. Related to dihydrite and srinite. Found in Keuper sandstone at Alderley Edge and Mottram St. Andrew's, in Cheshire, England (Roscoe, Proc. Roy. Soc., xxv./III., 1876). VOLBORTHITE. R 4 V 2 O 9 -i-aq, with R^Ca : Cu=2 : 3 (or 3 : 7), Ramm. From the Urals. Kalk-volborthit (Germ.), Friedrichsrode, contains calcium. OLINOOLASITE. Strahlerz, Germ. Monoclinic. C= 80 30 r , /A/, front, = 56. Cleavage : basal, highly perfect. Also massive, hemispherical, or reniform*; 681 structure radiated fibrous. H.=2-5-3. G.=4-19-4-36. Lustre: pearly; elsewhere vitreous to resinous. Color internally dark verdigris-green; externally blackish-blue green. Streak bluish-green. Subtranslucent. Not very brittle. Comp. Cu3As 2 8 4-3H 2 Cu0 2 :=Arsenic pentoxide 30-2, conpei oxide 62*7, water 7 1-100. Fyr., etc. Same as for olivenibe. Obs. Occurs in Cornwall, with other ores of copper, at several mines. Also found in the Erzgebirge TYROLITE (Kupferschaum). A hydrous arsenate of copper (Ou t containing also calcium carbonate (as an impurity ? ) Color pale apple-green. Libethen. Hungary ; Schneeberg, etc. OXYGEN COMPOUNDS. PHOSPHATES, AiiSENATES, ETC, 375 CHALCOPHYLLITE (Copper mica; Kupferglimmer, Germ.). Cu 3 As 2 0845H 2 Cu0 2 + 7H 2 O- Arsenic pentoxide 21 '3, copper oxide 58 '7, water 20 "0=100. Copper mines of Cornwall, Hungary ; Moldawa. LAZULITE. Blauspath, Germ. Monoclinic. C = 88- 15', / A 1 = 91 30', A 14 --= 139 45', Priifer ; c : b : d = 0-86904 : 1-0260 : 1. Twins : twiuning-plane i-i\ also 0. Cleav- age : lateral, indistinct. Also massive. 683 684 -2 H =5-6 G.=3-057, Fuchs. Lustre vitreous. Color azure- bl ue ; com- monly a fine deep blue viewed along one axis, and a pale greenish-blue along another. Streak white. Subtranslucent opaque. Fracture uneven. Brittle. Comp. (Dana) = Phosphorus pentoxide 46 "8, alu- RAlP 2 9 +aq=AlP 2 8 +H 2 (Mg,Fe)0 2 -!n e the* clirtube"^*! and yields water. B.B. with cobalt solution the , in Krieglach, i :Sj^ft2^iSB!SsBBM-w N C ; and on Graves Mt., Lincoln Co, Ga, 50 m. above Augusta. SCORODITE. 1 A /= 98 2', 0A1-I _ 7 132 20'; d Cleavage : i-2 imperfect, i-i and i-l in Orthorhombic. 1-1511 : 1, Miller, traces. jj 3.5-4 G.=3-l-3-3. Lustre vitreous subadaman- tine and subresinous. Color pale leek-green or liver-brown. Streak white. Subtransparent translucent. Comp.-FeAs 2 8 +4aq=Arseiiic pentoxide 49'8, iron sesquioxide -r Va etl In~the closed tube yields neutral water and turns yellow. BB fuses easily, coloring the flame blue. B.B. on ^ c al fl ^ arsenical fumes, and with soda a black magnetic scona. With the fluxes reacts for iron. Soluble in hydrochloric acid. 376 DESCRIPTIVE MINERALOGY. Obs. Found at Schwarzenberg in Saxony ; at Nertschinsk, Siberia ; Dernbach in Nassau ; in the Cornish mines ; at the Minas Geraes, in Brazil ; in Popayan ; at the gold mines of Vic- toria in An; tralia. Occurs in minute crystals and druses, near Edeiiville, N. Y. : in Cabarras Co., N. C. WAVELLITE. Orthorhombic. /A I 126 25', A 14 = 143 23' ; c : I : & = O7431 : 1*494:3 : 1. Cleavage : 1 rather perfect ; also brachydia- 686 gonal. Usually in hemispherical or globular concretions, having a radiated structure. H.=3-25-4. G.=:2-316-2-337. Lustre vitreous, inclin- ing to pearly and resinous. Color white, passing into yel- low, green, gray, brown, and black. Streak white. Trans- lucent. Comp Al 3 P 4 O ide3516, alumina 38 10, water 26 '74=100; 1 to 2 p. c. fluorine is often present, replacing the oxygen. Pyr., etc. In the closed tube gives off much water, the last portions of which react acid and color Brazil-wood paper yellow (fluorine), and also etch the tube. B B. in the forceps swells up and splits frequently into fine acicular particles, which are infusible, but color the flame pale green ; moistened with sulphuric acid the green becomes more intense. Gives a blue with cobalt solution. Some varieties react for iron and manganese with the fluxes. Heated with sulphuric acid gives off fumes of fluo- hydric acid, which etch glass. Soluble in hydrochloric acid, and also in caustic potash. Diff. Distinguished from the zeolites and from gibbsite by its giving a phosphorus reac- tion ; it dissolves in acid without gelatinization. Obs. Found near Barnstaple, Devonshire ; at Clonmel and Cork, Ireland ; in the Shiant Isles of Scotland ; at Zbirow in Bohemia; Zajecovin Bohemia; at Frankenberg and Langen- striegis, Saxony ; Diensberg, near Giessen, Hesse Darmstadt ; in a manganese mine in Wein- bach, near Weilburg, in Nassau ; at Villa Rica, Minas Geraes, Brazil. In the United States, at the slate quarries of York Co., Pa.; at Washington mine, Davidson Co., N. C.; at White Horse Station, Chester Co., Pa ; Magnet Cove, Ark. ZEPIIAROVICHITE. Near wavellite. Composition A1P 2 8 + 6aq (or 5aq, Kamm.). Compact. Color greenish to grayish. Occurs in sandstone at Trenic, Bohemia. CCERULEOLACTITE. Crypto-crysta'lline. Color milk-white to light blue. Composition (Petersen) Al 3 P 4 Oi9 + 10aq. Katzenellnbogen. Nassau. Also Chester Co., Penn. (Genth, who regards the copper, 4 p. c., as belonging to the mineral.) PHARMACOSIDERITE. Wiirfelerz, Gain. Isometric ; tetrahedral. Crystals modified cubes and tetrahedrons. Cleavage: cubic, imperfect. O sometimes striated parallel to its edge of intersection with plane 1 ; planes often curved. Rarely granular. H. = 2'5. G.=2'9-3. Lustre adamantine to greasy, not very distinct Color olive-green, passing into yellowish-brown, bordering sometimes upon hyacinth-red and blackish-brown ; also passing into grass-green, emerald- green, and honey -yellow. Streak green brown, yellow, pale. Subtrans- parent subtranslucent. Rather sectile. Fyroelectric. Oomp Fe 4 A3 6 027,15aq=3FeAs 2 8 +H 6 Fe0 6 + 12H 2 0- Arsenic pentoxide 43'13, iron esquioxide 40 '00, water 16 '87 =100. Pyr., etc. Same as for scorodite. Obs.- -Formerly obtained at the mines of Wheal Gorland, Wheal Unity, and Carharrack, in Cornwall ; now found at Burdle Gill in Cumberland ; in minute tetrahedral crystals at Wheal Jane ; also in Australia ; at St. Leonard in I ranee and at Sv oneeberg and Sch war- sen berg in Saxony. OXYGEN COMPOUNDS. PHOSPHATES, AKSENATE8, ETC. 377 Named from ^dp/LLaKov, poison (in allusion to the arsenic present), and ov, iron. Wurfd- erz, of the Germans, means cube-ore. RIIAGITE (Wdsbach}. Composition Bi 10 As40 2 5-f 9aq=2BiAsO 4 +3H 3 Bi0 3 :=Arsenic pent- oxide 15'6, bismuth oxide ?8'9, water 5'5=100. Spherical crystalline aggregates. Coloi bright green. Schneeberg, Saxony. PLUMBOGUMMITE. Composition uncertain. Contains essentially alumina, lead, water, and phosphorus pentoxide. Huelgoeb ; Cumberland ; Mine la Motte, Mo. CHILDRENITE.* Orthorhombic. 1 A /= 111 54', A 14 = 136 26' ; c : I : d = 0-9512 1-4798 : 1. Plane O sometimes wanting, and the form a double six- eided pyramid, made up of the planes 1, 2-, with i-l small. Cleavage : i-$ 9 imperfect. H.=4'5-5. G. 3-18-3-24. Lustre vitreous, inclining to resinous. Color yellowish-white and pale yellowish-brown, also brownish-black Streak white, yellowish. Translucent. Fracture uneven. Comp. Formula somewhat uncertain. Analysis: Rammelsberg, P 2 O 5 28 92, A10 3 14 '44, FeO 30-68, MnO 9'07, MgO (H4, H. 2 O 16'98=100'23. Pyr., etc In the closed tube gives off neutral water. B.B. swells up into ramifications, and fuses on the edges to a black mass, coloring the flame pale green. Heated on charcoal turns black and becomes magnetic. With soda gives a reaction for manganese. With borax and salt of phosphorus reacts for iron and manganese. Soluble in hydrochloric acid. Obs. Occurs near Tavistock ; also at Wheal Crebor, in Devonshire ; on slate at Crinnia mine in Cornwall. Hebron, Me. (f. 688.). TJRQUOIS. Callaite. Kallait, Kalait, Germ. Reniform, stalactitic or incrusting. Cleavage none. H.=6. G-.rr 2*6-2-83. Lustre somewhat waxy, feeble. Color sky-blue, bluish-green to apple-green. Streak white or greenish. Feebly subtrans- lucent opaque. Fracture small conchoidal. Comp. Hydrous aluminum phosphate, perhaps AlaPsOn+Saq^: Phosphorus pentoxide 32'G, alumina 46-9, water 20-5 = 100 Pyr., etc. In the closed tube decrepitates, yields water, and turns brown or black. B.B. in the forceps becomes brown and assumes a glassy appearance, but does not fuse ; colora the flame green; moistened with hydrochloric acid the color is at first blue (copper chloride). With the sodium test gives phosphuretted hydrogen. With borax and salt of phosphorus gives beads in 0. F. which are yellowish green while hot, and pure green on cooling. With salt of phosphorus and tin on charcoal gives an opaque red bead (copper). Soluble in hydrochloric acid. Obs. Occurs in clay slate in a mountainous district in Persia, not far from Nichabour. According to Agaphi, the only naturalist who has visited the locality, turquois occurs only in veins, which traverse the mountain in all directions. An impure variety is found in Silesia, 378 DESCRIPTOR MINERALOGY. and at Oelsnitz in Saxony. W. P. Blake refers here to a hard yellowish- to bluish-green stone (which he identifies with the clmlcWmitl of the Mexicans) from the mountains Los Cerillas, 20 m. S. E. of Santa Fe. A pale green turquois occurs in the Columbus district, Nevada. Turquois receives a good polish, and is highly esteemed as a gem. The Persian king is said to retain for his own use all the larger and finely tinted specimens. PEGANITE. Composition AljP 2 Ou -t-6aq= Phosphorus pentoxide 31 1, alumina 31 '1, water 23 7= 100. Striegis, Saxony. DUFRENITE. Composition Fe 2 P,O u +3aq (FeP.20,i+H 6 FeO 6 ) = Phosphorus pentoxide 27*5, iron sesquioxide 62'0, water 10-5=100. Anglar, Dept. of Haute Vieune ; Hirschberg, Westphalia ; Allentown, N. J. In deposits of nodules 1 to 6 in. thick, in Rockbridge Co., Va ANDREWSITE. In globular forms, having a radiated structure. H.=4. G.=3'475. Color dark green. Analysis, Plight. P 2 5 26-09, FeO 3 44-64, A1O 3 0'92, CuO 10 86, FeO 711, MnO 0-60, CaO 0'09, Si0 2 0'49, H 2 8 -79 =99 '59. In a tin lode, West Phenix mine, near Liskeard, Cornwall. CHALCOSIDERITE. In bright green crystals (triclinic) on Andrewsite (see above). H. = 4-5. G.=3108. Analysis, Flight, P 2 O 5 29 93, As,0 5 0'61, Fe0 3 42 -81, A1O 3 4-45. CuO 8 '14, H,0 15-00, UO 3 tr.=100-94. Also as a coating on dufrenite. Cornwall. Sayn, Westphalia. HENWOODITE. In globular forms, with a radiated structure. H.=4-4 5. G. = 2-67. Color turquois-blue to bluish -green. B.B. infusible. Analysis, P& 5 48'94, A10 3 18'24, FeO 3 2-74, CuO 710, CaO 54, H 2 O 1710, SiO 2 1-37, loss 3 '97=100. Occurs on limonite at the West Phenix mine, Cornwall (Collins^ Min. Mag., 1, p. 11). CACOXEN IT E. Supposed to be an iron wavellite. Composition FeaP.jOj.+lSaq. In ra- diated tufts. Color yellow. Hrbeck mine, Bohemia. ARSENIOSIDERITE. Analysis by Church, As 2 O 6 39*86, Fe0 3 35-75, CaO 15'53, MgO 018, K 2 O 0-47, H,O 7-87=9966. Formula (Eamm.) 2Ca 3 As 2 O 8 +FeAs i 8 + 3H 6 Fe0 6 . Ro- maneche. ATELESTITE. Essentially a bismuth arsenate. In minute yellow crystals at Schneeberg. TORBERNTTE. Chalcolite. Kupfer-Uranit, Germ. Tetragonal. O A 14 = 134: 8' ; c = 1-03069. Forms square tables, with often replaced edges ; rarely suboctahedral. Cleav- age : basal highly perfect, micaceous. Unknown massive or earthy. H. = 2-2-5. G.=3-4-3-6. Lustre of O pearly, of other faces subadamantine. Color emerald- and grass green, and sometimes leek-, apple-, and sis- Cornwall, kin-green. Streak somewhat paler than the color. Transparent subtranslncent. Fracture not ob- servable. Sectile. Laminae brittle and not flexible. Optically uniaxial ; double refraction negative. Comp. Q. ratio f or R : U : P : O=l : 6 : 5 : 8 ; formula CuU 2 P 2 O 12 + 8aq=2(UOo) 3 P,O + Cu 3 P.,0 8 +24aq. The formula requires: Phosphorus pentoxide 151, uranium tricside 61-2, copper oxide 8 '4, water 15 '3 = 100. Pyr., etc. In the closed tube yields water. In the forceps fuses at 2 '5 to a blackish mass, and colors the flame green. With salt of phosphorus gives a green bead, which with tin on charcoal becomes on cooling opaque red (< opper). With soda on charcoal gives a globule of copper. Affords a phosphide with the sodium test. Soluble in nitric acid. Obs. Grunnis Lake, Tincroft and Wheal Buller, near Redruth, and elsewhere in Cornwall. Found also at Johanngeorgenstadt, Eibenstock, and Schneeberg, in Saxony ; in Bohemia, at Joachimsthal and Zinnwald ; in Belgium, at Vielsalm. Both this species and the autunite have gone under the common name of uranite ; the former also as Copper-uranite^ the latter Lime-uranite. OXYGEN COMPOUNDS. PHOSPHATES, ARSENATES, ETC. 379 AUTUNITE.* Uranit; Kalk-Uranglimmer, Kalk-Uranit, Germ. Orthorhombic ; but form very nearly square, and crystals resembling closely those of torbernite. Cleavage : basal eminent, as in torbernite. H. = 2-2'5. Gr.^3'05-3'19. Lustre of pearly ; elsewhere subadaman- tine. Color citron- to sulphur-yellow. Streak yellowish. Translucent. Optically biaxial, DesCl. Comp. Q. ratio f or R : U : P : H=l : 6 : 5 : 10. Formula CaU 2 P 2 Oi 2 + 10aq, which may be written 2(U0 2 ) 3 P...O8 + Ca 3 P 2 084-30aq. The formula requires : Phosphorus pentoxide 14 '9, uranium fcrioxide (U0 3 ) 60'4, lime 5 % 9, water 18-8=100. Pyr., etc. Same as for torbernite, but no reaction for copper. Obs. Occurs at Johanngeorgenstadt ; at Lake Onega, Wolf Island, Russia; near Limoges; near Autun ; formerly at South Basset, Wheal Edwards, and near St. Day, England. Occura sparingly at Middletown, Ct. ; also in minute crystals at Chesterfield, Mass. ; at Acworth, N. H. TROGERITE. Composition TJ 3 As 2 Oi4 -I- 12aq=(U0 2 ) 3 As 2 O 8 + 12aq. This requires : Arsenic pentoxide 17*6, uranium trioxide 05 "9, water 16 '5= 100. Monoclinic. In thin tabular crys- tals of a lemon-yellow color. Schneebertf, Saxony. WALPURGITE. Composition Bi 1 oy 3 As40 3 4 + 12aq=(U0 2 ) 3 As,O 8 -f2BiAs04+8H,Bi03. This requires: Arsenic pentoxide 11 '9, bismuth oxide (>0'0, uranium trioxide 22'4, water 5 '7= 100. Monoclinic. In thin scaly crystals. Color wax-yellow. Schneeberg, Saxony. URANOSPINITE. An arsenic autunite. Composition CaU 2 As 2 12 + 8aq3=2(UO,)sAs 2 08 + Ca 3 As 2 8 +24aq=Arsenic pentoxide 22'9, uranium trioxide 57 '2, lime 5'6, water 14'3 = 100. Color green. Schneeberg, Saxony. URANOSPH^RITE. Color yellow. Analysis, Winkler : U 3 50-88, Bi 2 3 44'34, H 2 O 4-75. Schneeberg. ZEUNERITE. According to Winkler, an arsenic chalcolite, with which it is isomorphous. Composition CuU 2 As 2 Oi 2 +8aq=2(U0 2 ) 3 As.208 + Cu 3 As 2 8 +24aq=Arsenic pentoxide 22'3, uranium trioxide 56'0, copper oxide 7 '7, water 14'0=100. Color bright green. Schneeberg, Zinnwald, Saxony ; Cornwall. PITTICITE. Iron-sinter. Composition uncertain, contains As^Os, Fe0 3 , S0 3 , H 2 0. DlA- DOCHITB is similar, but contains P 2 5 instead of As 2 O 6 . HYDROUS ANTIMONATES. BINDHEIMITE (Blemiere). Amorphous, reniform, or spheroidal ; also earthy or incrusting. H.:=4. G. 4 '60-4 '76. Color white, gray, brownish, yellowish. Composition uncertain; analysis by Hermann : Sb-O 5 31-71, PbO 61 '83, H 2 O 6'46=100. Results from the decompo- sition of other antimonial ores. From Nertschinsk in Siberia ; Horhausen ; near Endelliou in Cornwall, with jamesonite, from which it is derived. NITRATES. The nitrates are all soluble, and hence are rarely met with in nature. They inr lude : NITRE, potassium nitrate (KNO 3 ). Found generally in crusts on the surface of the soil, on walls, rocks, etc. Also found in numerous caves in the Mississippi Valley. SODA NITRE, sodium nitrate (NaNO,). Tarapaca, Chili. NITROCALCITE. calcium nitrate (CaN 2 6 ). Occurs in silky efflorescences in limestone caverns. NITROMAGNESITE, magnesium nitrate (MgN 2 O a ). From limestone caves. NITBO- OLAUBERITE, nitro- sulphate of sodium. Desert of Atacama, Chili. 380 DESCRIPTIVE MINERALOGY. 4. EQUATES. SASSOLTTE. Triclinic. /A/' == 118 30', 6> A 7= 95 3', O A /' = 80 33', B. & M. Twins: composition -face O. Cleavage: basal very perfect. Usually in Binall scales, apparently six-sided tables, and also in stalactitic forms, com- posed of small scales. H.:=l. G.= 1*4:8. Lustre pearly. Color white, except when tinged yellow by sulphur; sometimes gray. Feel smooth and unctuous. Taste acidulous, and slightly saline and bitter. Comp. H 6 Bi0 6 =Boron trioxide (B 2 3 ) 56 '46, water 43 '54=100. The native stalactitic salt contains, mechanically mixed, various impurities, as sulphate of magnesium and iron, sulphate of calcium, silica, etc. Pyr., etc. In the closed tube gives water. B. B. on platinum wire fuses to a clear glass and tinges the flame yellowish-green. Soluble in water and alcohol. Obs. First detected in nature by Heifer in the waters of the Tuscan lagoons of Monte Rotondo and Castelnuovo, and afterward in the solid state at Sasso by Mascagni. The hot papers of the lagoons consist largely of it. Exists also in other natural waters, as at Wies- baden ; Aachen; Krankenheil near Folz ; Clear Lake in Lake Co., California; and it has been detected in the waters of the ocean. Occurs also abundantly in the crater of Vulcano, one of the Lipari islands, forming a layer on sulphur and about the fumaroles, where it was iiscovered by Dr. Holland in 1813. SUSSEXITE (Brush). In fibrous seams or veins. H.=3. Gr.= 3*4:2. Lustre silky to pearly. Color white, with a tinge of pink or yellow. Translucent. Comp. ILBoOs+aq, with R=rMn : Mg=4 : 8=Boron trioxide 34'3, manganese protoxide J9-9. magnesia 16'9, water 8'9 = 100. Pyr., etc. In the closed tube darkens in color and yields neutral water. If turmeric paper B moistened with this water and then with dilute hydrochloric acid it assumes a red color ;boron). Fuses in the flame of a candle, and B.B. in O.F. yields a black crystalline mass ioloring the flame intensely yellowish-green. Reacts for manganese with the fluxes. Soluble n hydrochloric acid. Oba Found on Mine Hill, Franklin Furnace, Sussex Co., N. J.; associated with franklin- ,te. zincite, willemite, and other manganese and zinc minerals. SZAIPELYITE. A hydrous magnesium borate, Mg 5 B 4 Oi i +3aq (or f aq). Occurs in acicular crystals. Color white. Hungary. LUDWIGITE ( Tschennak}. Finely fibrous masses. H. =5. G-. =3'907-4'016. Color black sh-green to black. Composition R 4 FeB 2 O 10 , with R=Fe : Mg^l : 5, or 1 : 3. For the atter the formula requires : Boron trioxide 16 6, iron sesquioxide 37 '9, iron protoxide 17*1, magnesia 28 '4. Occurs in a crystalline limestone with magnetite at Morawicza in the Banat. ilso altered to limonite. OXYGEJS COMPOUNDS. BORATE8. 381 BORACITE.* Isometric; tetrahedral. Cleavage: octahedral, in traces. Cubic faces sometimes striated parallel to alternate pairs of edges, as in pyrite. H. 7, in crystals; 4'5, massive. G.=2'974, Haidinger. Lustre vitre- ous, inclining to adamantine. Color white, inclining to gray, yellow, and green. Streak white. Sub- 69 transparent translucent. Fracture conchoidal, un- even. Pyroelectric, and polar along the four octa- hedral axes. (. rl \ Comp. Mg 7 Bi 6 CL0 8 o = 2Mg s B 6 Oi6+MgCl 2 = Boron trioxide 62 57, magnesia 31 -28, chlorine 7 "93 =101 "78. Pyr., etc. The massive variety gives water in the closed tube. B.B. both varieties fuse at 2 with intumescence to a white crys- talline pearl, coloring the flame green ; heated after moistening with cobalt solution assumes a deep pink color. Mixed with copper oxide and heated on char- coal colors the flame deep azure-blue (copper chloride). Soluble in hydrochloric acid. Alters very slowly on exposure, owing to the magnesium chloride present, which takes up water. Obs. Observed in beds of anhydrite, gypsum, or salt. In crystals at Kalkberg and Schild- stein in Liineberg, Hanover ; at Segeberg, near Kiel, in Holstein ; at Luneville, La Meurthe, France ; massive and crystallized at Stassfurt, Prussia. BORAX. Tinkal of India. Monoclinic. (7= 73 25', /A 1= 87, A 24 = 132 49' ; t : I : d = 0*4:906 : 0-9095 : 1. Cleavage: i-i perfect; /less so; i-l in traces. H.=2-2*5. G. = l*716. Lustre vitreous resinous; sometimes earthy. Color white; sometimes grayish, bluish, or greenish. Streak white. Translucent opaque. Fracture conchoidal. Rather brittle. Taste sweet- ish-alkaline, feeble. Oomp Na 2 B 4 O 7 +10aq=2(NaBO a -|-HBO.)-h9aq=Boron trioxide 36 '6, soda 16 '2, water 47-2. Pyr., etc. B.B. puffs up, and afterwards fuses to a transparent globule, called the glass of borax. Soluble in water, yielding a faintly alkaline solution. Boiling water dissolves double its weight of this salt. Obs. Borax was originally brought from a salt lake in Thibet. It is announced by Dr. J. A. Veatch as existing in the waters of the sea along the California coast, and in those of many of the mineral springs of California. Occurs in the mud of Borax Lake, near Clear Lake, Cal. Also found in Peru ; at Halberstadt in Transylvania ; in Ceylon. It occurs in solution in the mineral springs of Chambly, St. Ours, etc., Canada East. The waters of Borax Lake, California, contain, according to G. E. Moore, 535*08 grains of crystallized borax to the gallon. ULEXITE. Boronatrocalcite. Natronborocalclte. In rounded masses, loose in texture, consisting of fine fibres, which aro acicular or capillary crystals. H.=l. G.=1'65, N. Scotia, How. Lustre silky within* Color white, Tasteless. Oomp NaCaB 6 9 +5aq=Boron trioxide 49 '7, lime 15*9, soda 8'8, water 525'(3=100. Pyr., etc Yields water. B,B. fuses at 1 with intumescence to a clear blebby glass, color 382 DESCRIPTIVE MINERALOGY. ing the flame deep yellow. Moistened with sulphuric acid the color of the flame is moment- arily changed to deep green. Not soluble in cold water, and but little so in hot ; the solution alkaline in its reactions. Obs Occurs in the dry plains of Iquique, Southern Peru ; in the province of Tarapaca (where it is called liza), in whitish rounded masses, from a hazelnut to a potato in size, which consist of interwoven fibres of the ulexite, with pickeringite, glauberite, halite, gypsum, and other imparities; on the West Africa coast; in Nova Scotia, at Windsor, Brookville, and Newport (H. How), filling narrow cavities, or constituting distinct nodules or mammillattd masses imbedded in white gypsum, and associated at Windsor with glauber salt, the lustre internally silky and the color very white ; in Nevada, in the salt marsh of the Columbus Mining District, forming layers 2-5 in. thick alternating with layers of salt, and in balls 3-4 in. through in the salt. BECHILITE. (Borocalcite). An incrustation at the Tuscany lagoons. Composition CaB^, + 4aq. Also similar from South America. LARDERELLITE, LAGONITE, rare borates from the Tuscan lagoons. PRICEITE (SiUiman). Compact, chalky. Color milk-white. Composition Ca 3 B & Oj 5 + 6aq. This requires : Boron trioxide 49 '8, lime 29 '9, water 20 '3 = 100. Occurs in layers between a bed of slate above and one of steatite below. Near Chetko, Curry Co., Oregon. HOWLITE, SiUcoborocalcite. A hydrous calcium borate (like bechilite), with one-sixth of a silicate analogous to danburite. Near Brookville, and elsewhere in Hants Co. , Nova Scotia, in nodules imbedded in anhydrite or gypsum ; these nodules sometimes made up of pearly crystalline scales. WINKWORTHITE. In imbedded crystalline nodules from Winkworth, N. S. In composition between selenite and howlite ; a mixture (?). CRYPTOMORPIIITE. Near ulexite in composition. In microscopic rhombic tables. Nova Scotia. LUNEBURGIIE. A phospho-borate of magnesium. Flattened masses in gypsiferous marl at Liineburg. WARWICKTTE. Monoclinic. 7"A/=:91 20', DesCl. Usual in rhombic prisms with obtuse edges truncated, and the acute bevelled, summits generally rounded ; surfaces of larger crystals not polished. Cleavage : macrodiagonal per- fect, affording a surface with vertical striae and traces of oblique cross cleavage. H.=3-4. G.=3-19-3*43. Lustre of cleavage surface submetallic-pearly to subvitreous ; often nearly dull. Color dark hair-brown to dull black, sometimes a copper-red tinge on cleavage surface. Streak bluish-black. Fracture uneven. Brittle. Comp. Essentially a borotitanate of masfnesium and iron. Analysis, Smith, B 2 3 27 '80, TiO a 23-82, FeO 3 7 02, MgO 36 -80, Si0 2 1-00, A10 3 2 -21 =98 '65. Pyr., etc. Yields water. B.B. infusible, but becomes lighter in water ; moistened with sulphuric acid gives a pale green color to the flame. With salt of phosphorus in O.F. a cleat bead, yeilow while hot and colorless on cooling; in R.F. on charcoal with tin a violet color (titanium). With soda a slight manganese reaction. Decomposed by sulphuric acid ; the product, treated with alcohol and ignited, gives a green flame, and boiled with hydrochloric acid and metallic tin gives on evaporation a violet-colored solution. Obs. Occurs in granular limestone 2^ m. S. W. of Edenville, N. Y., with spinel, chondro- dite, serpentine, etc. Crystals usually small and slender; sometimes over 2 in. long and in. broad. OXYGEN COMPOUNDS TUNG STATES. MOLYBDATES, ETC. 383 5. TUJSTGSTATES MOLYBDATES, CHEOMATES. WOLFRAMITE. Monoclinic. C = 89 22', 1 A 1= 100 37', i-i ^%-i = 118 6', * A + f i = 117 6', 14 A 14 = 98 6', DesOloizeaux. Cleavage: i-l perfect, i-i imperfect. Twins: planes of twinning i-i (f. 692), |4, and rarely -J4. Also irregular lamellar; coarse divergent columnar; massive granular, tho particles strongly coherent. 691 692 693 H.=5-5'5. G.=7'l-7'55. Lustre submetallic. Color dark grayish or brownish-black. Streak dark reddish-brown to black. Opaque. Sometimes weak magnetic. Var. The most important varieties depend on the proportions of the iron and manganese. Those rich in manganese have G. =7 '19-7 54, but generally below 7 '25, and the streak is mostly black. Those rich in iron have G.=r7-2-7'54, and a dark reddish-brown streak, and they are sometimes feebly attractable by the magnet. Comp. (Fe,Mn)WO,, Fe : Mn=2 : 3, mostly ; also 4 : 1 and 2 : 1, 3 : 1, 5 : 1, etc. The ratio 2 : 3 corresponds to : Tungsten trioxide 76'47, iron protoxide 9 '49, manganese protoxide 14-04=100. Pyr., etc B.B. fuses easily (F.=2'5-3) to a globule, which has a crystalline surface and is magnetic. With salt of phosphorus gives a clear reddish-yellow glass while hot, which is paler on cooling; in R.F. becomes dark red ; on charcoal with tin, if not too saturated, the bead assumes on cooling a green color, which continued treatment in R. F. changes to reddish yellow. With soda and nitre on platinum foil fuses to a bluish-green manganate. Decom- posed by aqua regia with separation of tungsten trioxide as a yellow powder, which when treated B.B. reacts as under tungstite (p. 284). Wolfram is sufficiently decomposed by con- centrated sulphuric acid, or even hydrochloric acid, to give a colorless solution, which, treated with metallic zinc, becomes intensely blue, but soon bleaches on dilution. Diff. Characterized by its high specific gravity and pyrognostics. Obs. Wolfram is often associated with tin ores ; also in o.uartz, with native bismuth, scheelite, pyrite, galenite, blende, etc. ; and in trachyte, as at Felsobanya, in Hungary. It occurs at Schlackenwald ; ScHneeberg ; Freiberg ; Ehrenfriedersdprf ; Zinnwald, and Nert- schinsk ; at Chanteloup, near Limoges, and at Meymac, Correze, in France ; near Redruth and elsewhere in Cornwall ; in Cumberland. Also in S. America, at Oruro in Bolivia. In the U. States, occurs at Lane's mine, Monroe, Conn. ; at Trumbull, Conn. ; on Camdage farm, near Blue Hill Bay, Me.; at the Flowe mine, Mecklenburg Co., N. C.; in Missouri, near Mine la Motte, and in St. Francis Co. ; at Mammoth mining district, Nevada. HUBNERITE.* A manganese wolframite, MnW0 4 = Tungsten trioxide 76 9, manganese protoxide 23'1 = 100. Mammoth dist., Nevada. MEGABASITE. A manganese tungstate, with a little iron. Schlackenwald. 384 DESCRIPTIVE MINERALOGY. SCHEELITE. Tetragonal ; hemihedral. O A l-i = 123 3' ; c = 1-5369. Cleavage : 1 most distinct, ~L-i interrupted, O traces. Twins; twinning-plane 7; also i-i. Crystals usually octahe- dral in form. Also reniform with columnar struc- ture ; and massive granular. H.=4-5-5. G.= 5 -9-6-076. Lustre vitreous, in- clining to adamantine. Color white, yellowish-white, pale yellow, brownish, greenish, reddish ; sometimes almost orange-yellow. Streak white. Transparent translucent. Fracture uneven. Brittle. Comp. CaW0 4 = Tungsten trioxide 80'6, lime 19-4=100. A variety from Coquimbo, Chili, contained 6 '2 p. c. vanadium pent- oxide ; another from Traversella contained didymium. Pyr., etc. B.B. in the forceps fuses at 5 to a semi-transparent glass. Soluble with borax to a transparent glass, which after- ward becomes opaque and crystalline. With salt of phosphorus forms a glass, colorless in outer flame, in inner green when hot and fine blue cold ; varieties containing iron require to be treated on charcoal with tin before the blue color appears. In hydro chloric or nitric acid decomposed, leaving a yellow powder soluble in ammonia. Diff. Remarkable among non-metallic minerals for its high specific gravity. Obs. Usually associated with crystalline rocks, and commonly found in connection with tin ore, topaz, fluorite, apatite, molybdenite, wolframite, in quartz. Occurs at Schlacken- wald and Zinnwald in Bohemia ; in the Riesengebirge ; at Caldbeck Fell, near Keswick ; Neudorf in the Harz ; Ehreufriedersdorf ; Posing in Hungary ; Traversella in Piedmont, etc. Llamuco, near Chuapa in Chili. In the U. S., at Lane's mine, Monroe, and Huntington, Conn.; at Chesterfield, Mass.; in the Mammoth mining district, Nevada ; at Bangle mine, in Cabarras Co., N. C. ; and Flowe mine. Mecklenburg Co. CUPROSCHEELITE. A scheelite containing about 6 p. c. copper oxide. Color bright green. La Paz, Lower California. Llamuco, near Santiago, Chili. CUPKOTUNGSTITE. A copper tungstate, CusWOsH-aq. Amorphous. Color yellowish- green. With cuproscheelite at the copper mines of Llamuco, Chili. STOLZITE. Pb WO 4 = Tungsten trioxide 51, lead oxide 49=100. Tetragonal. Zinnwald ; Bleiberg; Coquimbo, Chili. Schlackenwald. WULFENITE.* Gelbbleierz, Gvrm. Tetragonal. Sometimes hemihedral. O A 1-^=123 26'; c = l' 695 697 Przibram. Phenixville. In modified square tables and sometimes very thin octahedrons, Cleavage OXYGEN COMPOUNDS. TUNGSTATES, MOLYBDATES, ETC. 385 1 very smooth ; and \ much less distinct. Also granular!}* massive, coarse or fine, firmly cohesive. Often hemihedral in the octagonal prisms, producing thus tables like f. 696, and octahedral forms having the prisma- tic planes similarly oblique. H.=2-75-3. Gr.= 6-03-7-01. Lustre resinous or adamantine. Color wax-yellow, passing into orange-yellow; also siskin- and olive-green, yel- lowish-gray, grayish-white, brown; also orange to bright red. Streak white. Subtransparent subtranslucent. Fracture subconchoidal. Brittle. Var. 1. Ordinary. Color yellow. 2. Vanadiferom. Color orange to bright red, a variety occurring at Phenixville, Pa. Comp. PbMoO, = Molybdenum trioxide 38'5, lead oxide 61 '5 =100. Some varieties contain chromium. Pyr., etc. B.B. decrepitates and fuses below 2; with borax in O. F. gives a colorless glass, in R.F. it becomes opaque black or dirty green with black flocks. With salt of phosphorus hi O.F. gives a yellowish-green glass, which in R.F. becomes dark green. With soda on char- coal yields metallic lead. Decomposed on evaporation with hydrochloric acid, with the formation of lead chloride and molybdic oxide ; on moistening the residue with water and adding metallic zinc, it gives an intense blue color, which does not fade on dilution of the liquid. Obs. This species occurs in veins with other ores of lead. Found at Bleiberg, etc., in Carinthia ; at Retzbanya ; at Przibram ; Schneeberg and Johanngeorgenstadt ; at Moldava ; in the Kirghis Steppes in Russia ; at Badenweiler in Baden ; in the gold sands of Rio Chico in Antioquia, Columbia, S. A. ; Wheatley's mine, near Phenixville, Pa.; at the Comstocklode in Nevada. In fine specimens from the Empire mine, Lucin District, Box Elder County, Utah ; at Empire mine, Inyo Co., Cal. ; in the Weaver dist., Arizona. EOSITE (Schrauf). In minute tetragonal octahedrons. Color deep-red. Probably a vana- dio-molybdate of lead. Leadhills, Scotland. ACII HEMATITE. An arsenio-molybdate of lead. Analysis, As 2 5 18 '25, Mo0 3 5'01, Cl 215, Pb 6'28, PbO 68'31=100'00. Compact; structure indistinctly crystalline. H.=3-4. Gr. =5 -965, 6-178 (powder). Color liver-brown, translucent ; in minute grains transparent and color yellow. Brittle. Guanacere, State of Chihuahua, Mexico. (Mallet, J. Ch. Soc., xiii., 1141, New Series.) CROOOITB. Crocoisite. Rothbleierz, Uerm. Monoclinic. C= 77 27', /A I = 93 42', O A 14 = 138 10' ; c 0-95507 : 1*0414: : 1, Dauber. Cleavage : /toler- ably distinct; O and i-i less so. Surface /streaked longitudinally ; the faces mostly smooth and shin- ing. Also imperfectly columnar and granular. II. =2-5-3. G.=: 5-9-6*1. Lustre adamantine vitreous. Color various shades of bright hyacinth- red. Streak orange-yellow. Translucent. Sectile. Comp. PbCrO 4 =Lead oxide 69'0, chromium trioxide 31'0= 100. Fyr., etc. In the closed tube decrepitates, blackens, but re- jovers its original color on cooling. B.B. fuses at 15, and on nharcoal is reduced to metallic lead with deflagration, leaving a residue of chromic oxide, and giving a lead coating. With salt of phosphorus gives an emerald-green bead in both flames. Fused with potassium bisulphate in the platinum spoon forms a dark violet mass, which on solidifying becomes reddish, and when cold greenish-white, thus differing from vanadinite, which on similar treatment- yellow mass (Plattner). 25 Ura:s. 386 DESCRIPTIVE MINERALOGY. Obs. First found at Beresof in Siberia ; at Mursinsk anl near Nischne Tagilsk in the Ural ; in Brazil; at Retzbanya; Moldawa ; on Luzon, one of the Philippines. PHCENICOCHROITE. Melanochroite. Orthorhombic (?). Crystals usually tabular, and reticularly interwoven. Cleavage in one direction perfect. Also massive. H.=:3-3-5. G.=5'75. Lustre resinous or adamantine, glimmering. Color between cochineal- and hyacinth-red; becomes lemon-yellow on exposure. Streak brick-red. Subtranslucent opaque. Comp. Pb 3 Cr 2 O 9 =2PbCrO +PbO= Chromium trioxide 23 '0, lead oxide 77-0=100. Pyr., etc. B.B. on charcoal fuses readily to a dark mass, which is crystalline when cold. In B.F. on charcoal gives a coating of lead oxide, with globules of lead and a residue of chromic oxide. Gives the reaction of chrome with fluxes. Obs. Occurs in limestone at Beresof in the Ural, with crocoite, vauquelinite, pyromorphite, and galenite. VAUQUELINITE. Monoclinic. Crystals usually minute, irregularly aggregated. Also reniform or botryoidal, and granular ; amorphous. tl.=2'5 3. G.r= 5*5 5*78. Lustre adamantine to resinous, often faint. Color green to brown, apple-green, siskin-green, olive-green, ochre-brown, liver-brown; sometimes pearly black. Streak greenish or brownish. Faintly translucent opaque. Fracture uneven. Rather brittle. Comp. Pb a CuCr 2 9 =2BCr0 4 +BO. B=Pb : Cu=2 : 1. The formula requires: Chro- mium trioxide 27'6, lead oxide 61 '5, copper oxide 10'9 100. Pyr., etc. B.B. on charcoal slightly intumesces and fuses to a gray submetallic globule, yielding at the same time small globules of metal. With borax or salt of phosphorus affords a green transparent glass in the outer flame, which in the inner after cooling is red to black, according to the amount of mineral in the assay ; the red color is more distinct with tin. Partly soluble in nitric acid. Obs. Occurs with crocoite at Beresof in Siberia, generally in mammillated or amorphous masses, or thin crusts ; also at Pont Gibaud in the Puy de Dome ; and with the crocoite of Brazil. In the U. States it has been found at the lead mine near Sing Sing, in green and brownish -green mammillary concretions, and also nearly pulverulent ; and at the Pequa lead mine in Lancaster Co., Pa., in minute crystals and radiated aggregations on quartz and galenite, of a siskin- to appJe-green color, with cerussite. LAXMANKITE (phoepJtochrmuW. Near vauquelinite, but held to be a pi oepho-chi ornate. Beresof. OXYGEN COMPOUNDS. SULPHATES. 387 6. SULPHATES. ANHYDROUS SULPHATES. Barite Group. BARITE. Barytes. Heavy Spar. Schwerspath, Germ. Orthorhombic. /A /= 101 40', O A 14 = 121 50' ; c : I : A = 1-6107 700 Cheshire. : 1-2276 : 1. A 1 = 115 42' ; \-l A 4, top, - 102 17' ; 14 A 14, top, = 74 36. Crystals usu- ally tabular, as in figures; sometimes prismatic in the direction of the different axes. Cleavage : basal rather perfect ; /somewhat less so; i4 imperfect. Also in globular forms, fibrous or lamellar, crested ; coarsely laminated, laminae convergent and often curved ; also granular ; colors sometimes banded, as in stalagmite. H.=2'5-3'5. G.=4'3-4'72. Lustre vitreous, inclining to resinous; sometimes pearly. Streak white. Color white ; also inclining to yellow, fray, blue, red, or brown, dark brown. Transparent to translucent opaque, ometiines fetid, when rubbed. Optic-axial plane brachy diagonal. Comp. BaSO 4 =Sulphur trioxide 34 '3, baryta 65 '7=100. Strontium and sometimes cal- cium replace part of the barium ; also silica, clay, bituminous or carbonaceous substances are often present as impurities. Pyr., etc. B.B. decrepitates and fuses at 3, coloring the flame yellowish-green ; the fused mass reacts alkaline with test paper. On charcoal reduced to a sulphide. With soda gives at first a clear pearl, but on continued blowing yields a hepatic mass, which spreads out and soaks into the coal. If a portion of this mass be removed, placed on a clean silver surface, and moistened, it gives a black spot of silver sulphide. Should the barite contain calcium Bulphate, this will not be absorbed by the coal when treated in powder with soda. Insoluble in acids. Diff. Distinguishing characters : high specific gravity, higher than celestite or aragonite ; cleavage ; insolubility ; green coloration of the blowpipe flame. Obs. Occurs commonly in connection with beds or veins of metallic ores, as part of the gangue of the ore. It is met with in secondary limestone, sometimes forming distinct veins. and often in crystals along with calcite and celestite. At Dufton, in Westmoreland. Eng 388 DESCRIPTIVE MINERALOGY. land ; in Cornwall, near Liskeard, etc., in Cumberland and Lancashire, in Derbyshire, Staf- fordshire, etc.; in Scotland, in Argyleshire, at Strontian. Some of the most important European localities are at Felsobanya and Kremnitz, at Freiberg, Marienberg, Clausthal, Przibram. and at Roya and Roure in Auvergne. In the U. S., in Conn., at Cheshire. In N. York, at Pillar Point; at Scoharie ; in St. Lawrence Co.; at Fowler; at Hammond. In Virginia, at Eldridge's gold mine in Buckingham Co.; near Lexington, in Rockbridge Co.; Fauquier Co. In Kentucky, near Paris ; in the W. end of I. Royale, L. Superior, and on Spar Id., N. shore. In Canada, at Landsdown. In fine crystals near Fort Wallace, New Mexico. The white varieties of barite are ground up and employed as a white paint, either alone or mixed with white lead. CELESTITE. Ortborhombic. /A 7= 104 2' (103 30'-104 30'), A 1-5- = 121 19J' ; c : I ; a = 1-6432 : 1-2807 : 1. A 1 = 115 38', O A \-l = 127 56', 1 A 1, mac., = 112 35', 1 A 1, brack, = 89 26'. Cleavage : O perfect ; 1 distinct ; i-l less distinct. Also fibrous and radiated ; sometimes globu- lar; occasionally granular. 702 703 L. Erie. H.= 3-3*5. G.=3'92-3*975. Lustre vitreous, sometimes inclining to pearly. Streak white. Color white, often faint bluish, and sometimes red- dish. Transparent subtranslucent. Fracture imperfectly conchoidal uneven. Yery brittle. Trichroism sometimes very distinct. Comp. SrSO 4 = Sulphur trioxide 43 '6, strontia 56*4=100. Wittstein finds that the blue color of the celestite of Jena is due to a trace of a phosphate of iron. Fyr., etc. B.B. frequently decrepitates, fuses at 3 to a white pearl, coloring the flame strontia-red ; the fused mass reacts alkaline. On charcoal fuses, and in R.F. is converted into a difficultly fusible hepatic mass; this treated with hydrochloric acid and alcohol gives an intensely red flame. With soda on charcoal reacts like barite. Insoluble in acids. Diff. Does not effervesce with acids like the carbonates ; specific gravity lower than that of barite ; colors the blowpipe flame red. Obs. Celestite is usually associated with limestone or sandstone. Occurs also in beds of gypsum, rock salt, and clay ; and with sulphur in some volcanic regions. Found in Sicily, at Girgenti and elsewhere ; at Bex in Switzerland, and Conil in Spain ; at Dornburg, near Jena ; in the department of the Garonne, France ; in the Tyrol ; Retzbanya ; in rock salt, at Ischl, Austria. Found in the Trenton limestone about Lake Huron, particularly on Strontian Island, and at Kingston in Canada ; Chaumont Bay, Scoharie, and Lockport, N. Y. ; also the Rossie lead mine ; at Bell's Mills, Blair Co. . Penn. Named from calestis, celestial, in allusion to the faint shade of blue often presented by the mineral. BARYTOCELESTITE. Celestite containing barium sulphate 26 p. c. (Griiner), 20 '4 p. c. (Turner). l- A 1-1=74 544', HA-H=100 J 35', on crystals from Imfeld in the BinnenthaJ (Neminar). Drammond I. , Lake Erie* Norten, Hanover. OXYGEN COMPOUNDS. SULPHATES, ETC. 389 ANHYDRITE. Orthorhombic. 7A 1= 100 30', A 14 = 127 19' ; c : I : d = 1-3122 : 1-2024 : 1. l- A 1-2, top, = 85. Cleavage : ?4 very per- 704 feet ; i-i also perfect ; O somewhat less so. Also librous, lamellar, granular, and sometimes impalpable. The lamellar and columnar varieties of ten curved or contorted. H.=3-3-5. G.=2-899-2-985. Lustre: i-itiud i-i some- what pearly ; vitreous ; in massive varieties, vitreous inclining to pearly. Color white, sometimes a grayish, bluish, or reddish tinge; also brick-red. Streak grayish- white. Fracture uneven; of finely lamellar and fibrous varieties, splintery. Optic-axial plane parallel to i-i, or Stassfurt. plane of most perfect cleavage; bisectrix normal to 0\ Grailich. Var. (a) Crystallized ; cleavable in its three rectangular directions, (b) fibrous ; either parallel, or radiated, or plumose, (c) Fine granular, (d) Scaly granular. Vulpiniteia a scaly granular kind from Vulpino in Lombardy ; it is cut and polished for ornamental purposes. It does not ordinarily contain more silica than common anhydrite. A kind in contorted concre- tionary forms Ls the tripestone (Qekrosslein). Oomp CaSO 4 = Sulphur trioxide 58 '8, lime 41 -2=100. Pyr., etc. B.B. fuses at 3, coloring the flame reddish-yellow, and yielding an enamel-like bead which reacts alkaline. On charcoal in R. F. reduced to a sulphide ; with soda does not fuse to a clear globule, and is not absorbed by the coal like barite ; it is, however, decomposed, and yields a mass which blackens silver ; with fluorite fuses to a clear pearl, which is enamel- white on cooling, and by long blowing swells up and becomes infusible. Soluble in hydrochloric acid. Diff. Characterized by its cleavage in three rectangular directions; harder than gypsum; does not effervesce with acids like the carbonates. Obs. Occurs in rocks of various ages, especially in limestone strata, and often the same that contain ordinary gypsum, and also very commonly in beds of rock salt. Occurs near Hall in Tyrol ; at Sulz on the Neckar, in Wiirtemberg ; Bleiberg in Carinthia ; Liineberg, Hanover ; Kapnik in Hungary ; Ischl ; Aussee in Styria ; Berchtesgaden ; Stassfurt, in fine crystals. In the U. States, at Lockport, N. Y. In Nova Scotia. ANGLESITB. Bleivitriol, Germ. Orthorhombic. 7 A 7=103 43', 0Al-i = 121 20J', Kokscharof; c : I : d = 1-64223 : 1-273634: : 1. O A 1-i = 127 48' ; A 1 = 115 35J' ; \-l A 14, top, = 75 35'. Crystals sometimes tabular ; often oblong pris- matic, and elongated in the direction of either of the axes (as seen in the figures). Cleavage: 7, O, but interrupted. The planes 7 and i-l often vertically striated, and \-~% horizontally. Also massive, granular, or hardly BO. Sometimes stalactitic. H.= 2-75-3. G.= 6-12-6-39. Lustre highly adamantine in some speci- mens, in others inclining to resinous and vitreous. Color white, tinged yellow, gray, green, and sometimes blue. Streak uncolored. Transparent paque. Fracture conchoidal. Very brittle. Comp. PbSO 4 Sulphur trioxide 26 '4, lead oxide 73 '6 =100. Pyr., etc. B.B. decrepitates, fuses in the flame of a candle (P.=1'5). On charcoal in 0. F. fuses to a clear pearl, which on cooling becomes milk-white ; in R. F. is reduced with effer- vescence to metallic lead. With soda on charcoal in R. F. gives metallic lead, and the soda is absorbed by the coal ; when the surface of the coal is removed and placed on bright silvei and moistened with water it tarnishes the metal black. Difficultly soluble in nitric acid. 390 DESCRIPTIVE MINERALOGY. Diff. Does not effervesce with acid like cerussite (lead carbonate) ; listinguished by blow- pipe tests from other resembling species. 705 707 Siegen. Anglesea. Siegen. Obs. This ore of lead was first observed by Monnet as a result of the decomposition of galenite, and it is often found in its cavities. Occurs in crystals at Leadhills ; at Pary's mine in Anglesea ; also at Melanoweth in Cornwall ; in Derbyshire and in Cumberland : Clausthal, Zillerfeld, and Giepenbach in the Harz ; near Siegen in Prussia ; Schapbach in the Black Forest ; in Sardinia ; massive in Siberia. Andalusia, Alston Moor in Cumberland ; in Aus- tralia. In the U. S., in large crystals at Wheatley's mine, Phenixville, Pa. ; in Missouri lead mines ; at the lead mines of Southampton, Mass. ; at Rossie, N. Y. ; at the Walton gold mine, Louisa Co., Va. Compact in Arizona, and Cerro Gordo, Cal. DREELITE. Rhombohedral. H.=3'5. G-. 3'2-3'4. Color white. Composition given as CaSO-4-f 3BaS0 4 . Occurs in small crystals at Beaujeau, France; Badenweiler, Baden. DOLEROPHANITB (Scacchi). Cu 2 SO 3 . In minute crystals. Monoclimc. Color brown. Vesuvius. HYDROCTANITE (Scacchi). Anhydrous copper sulphate, CuS0 4 . Color sky-blue. Very soluble. Vesuvius. APHTHIT ALITE, Arcanite. K 2 SO 4 =Potash 54-1, sulphuric acid 45 "9 = 100. Vesuvius. THENAKDITE. Sodium sulphate, Na 2 S0 4 . Spain; Vesuvius. LEADHILLITE. Orthorhombic. I^ 1= 103 16', O A 14 = 120 10' ; c : I : d = 1'7205 : 1-2632 : 1. Heinihedral in 1 and some other planes ; hence monoclinic in aspect, or rhombohedral when in compound crystals. Cleavage : i4 verj perfect ; i-l in traces. Twins, f . 712, consisting of three crystals ; twinning plane, l-i (see f . 298, p. 97) ; also parallel with /. OXYGEN COMPOUNDS. SULPHATES. 391 H. = 2*5. G. 6*26-6*4:4. Lustre of i-4 pearly, other parts resinous, some- what adamantine. Color white, passing into yellow, green, 711 712 or gray. Streak uncolored. Transparent translucent. Conchoidal fracture scarcely observable. Rather sectile. Comp. Formerly accepted for- T " mula, PbSO 4 +3PbC0 3 =Lead sul- phate 27 '45, lead carbonate 72 '55 = 100. Recent investigations by Las- peyres (J. pr., Ch. II., v., 470; vii., 127; xiii., 370), and Hintze (Pogg. Ann., clii., 156), though not entirely accordant, give different results, both show the presence of some water. Laspeyres writes the formula empirically, 5H 2 0, and Hintze, Pb 7 C 4 S 2 O i i+2H 2 O. Analyses: 1. Laspeyres; 2, Hintze: S0 3 C0 3 PbO H 2 O 1. 8-14 8-08 81-91 1-87=100, Laspeyres. 2. 817 918 80-80 2'00=100'15, Hintze. Pyr., etc. B.B. intumesces, fuses at 1'5, and turns yellow ; but white on cooling. Easily reduced on charcoal. With soda affords the reaction for sulphuric acid. Effervesces briskly in nitric acid, and leaves white lead sulphate undissolved. Obs, This ore has been found at Leadhills with other ores of lead ; also in crystals at Red Gill, Cumberland, and near Taunton in Somersetshire ; at Iglesias, Sardinia (maxite). SUSANNITE. Composition as for leadhillite, but form rhornbohedral. Leadhills; Nert- schinsk, Siberia. CONNELLITE. Hexagonal. In slender needle-like blue crystals. Contains copper sulphate and copper chloride. Exact c -imposition uncertain. Cornwall. CALKDONITE. Monoclinic (Schrauf). H. =2-5-3. G. =6'4. Color bluish-green. R 2 S0 5 + aq (Flight), with R=Pb : Cu=7 : 3, or 5PbS0 4 +3H,CuO,+2H.^PbO 2 . This requires : Sulphuric trioxide 19-1, lead oxide 05 '2, copper oxide 11 '4, water 4 3=100. Leadhills, Scot- land ; Red Gill ; Retzbanya ; Mine la Motte, Missouri. LANAUKITE. Monoclinic. H. =2-2*5. G. =6-3-6 '4. Color pale yellow, or greenish- white. Transparent. Composition as formerly accepted, PbSO 4 +PbC0 3 . New analyses by Flight, and by Pisani, show the absence of both carbon dioxide and water ; composition accordingly Pb 2 SO 5 =PbS0 4 +PbO, which requires : Lead sulphate 57'6, lead oxide 42'4=100. Leadhills ; Siberia, etc. GLAUBERITE. 7A7=8320', Monoclinic. (7=68 16', 0-84:54: : 0*8267 : 1. Cleavage : O perfect! H.= 2-5-3. G.=2*64r-2-85. Lustre vitreous. Color pale yellow or gray; sometimes brick-red. Streak white. Fracture conchoidal ; brittle. Taste slightly saline. Comp. Na 2 CaS 2 B = Sulphur trioxide 57-6, lime 20'1, soda 22 3= 100. Pyr., etc. B.B. decrepitates, turns white, and fuses at 1'5 to a white enamel, coloring the flame intensely yellow. On charcoal fuses in O.F. to a clear bead ; in R. F. a portion is absorbed by the charcoal, leaving an infusibe hepatic residue. With soda on charcoal gives the reaction for sulphur. Soluble in hydrochloric acid. In water it loses its transparency, is partially dissolved, leaving a residue of calcium sulphate, and in a large excess this is completely dissolved. On long exposure absorbs moisture and falls to pieces. Obs. In crystals in rock salt at Villa Rubia in New Castile ; also at Aussee in Upper Austria ; in Bavaria ; at the salt mines of Vic in France ; and at Borax Lake, California; Province of Tarapaca, Peru. A 14 = 136 30'; c:l>\a 713 392 DESCRIPTIVE MINERALOGY. HYDROUS SULPHATES. MIRABILITE. Glauber Salt. Monoclinic. C = 72 15', /A 1= 86 31', 6> A 14 = 130 19' ; c:b: ,i = 1'10S9 : 0-8962 : 1. Cleavage : i-i perfect. Usually in efflorescent crusts. H.= 1*5-2. G.= 1*4:81. Lustre vitreous. Color white. Transparent opaque. Taste cool, then feebly saline and bitter. Very Falls Comp. Na,S0 4 H-10aq=Sulphur trioxide 24 "8, soda 19 '3, water 55-9=100. Pyr., etc. In the closed tube much water ; gives an intense yellow to the flame, soluble in water ; the solution gives with barium salts the reaction for sulphuric acid, to powder on exposure to the air, and becomes anhydrous. Obs. Occurs at Ischl and Hallstadt ; also in Hungary ; Switzerland ; Italy ; at Guipuzcoa in Spain, etc. ; at Kailua on Hawaii ; at Windsor, Nova Scotia ; also near Sweetwater Kiver, Rocky Mountains. MASCAGNITE, BOUSSINGAULTITE (cerbolite), LECONTITE, and GDANOVULITE are hydrous sulphates containing ammonium. GYPSUM. Monoclinic. O= 66 14', if the vertical prism / (see f. 716) correspond to the cleavage prism (second cleavage), and the basal plane O to the direction of the third cleavage. /A / = 138 28', \\l\ 14 = 128 31' ; i : b : d = 0-9 : 2-4135 : 1. A 1 = 125 35', O A 24=145 41', 1 A 1 = 143 42', 24 A 2-1=111 42'. 715 716 Cleavage : (1) i-l, or clinodiagonal, eminent, affording easily smooth pol- ished folia ; (2) I, imperfect, fibrous, and often apparent in internal rifts or linings, making with O (or the edge 24/24) the angles 66 14', and 113 46', corresponding to the obliquity of the fundamental prism ; (3) 6>, or basal, imperfect, but affording a nearly smooth surface. Twins : 1, Twin- ning-plane O common (f. 717) ; also !-&', or edge 1/1. Simple crystals often with warped as well as curved surfaces. Also foliated massive ; lamellar stellate; often granular massive; and sometimes nearly impalpable. OXYGEN COMPOUNDS. SULPHATES. 393 fl.= 1-5-2. G.=2-314-2-32S, when pure crystals. Lustre of. i-l pearly and shining, other faces subvitreous. Massive varieties often glistening, sometimes dull earthy. Color usually white ; sometimes gray, flesh-red, honey-yellow, ochre-yellow, blue ; impure varieties often black, brown, red or reddish- brown. Streak white. Transparent opaque. Var. 1. Crystallized, or Selenite ; either in distinct crystals or in broad folia, the folia sometimes a yard across and transparent throughout. 2. Fibrous ; coarse or fine, (a) Satin spar, when fine-fibrous a variety which has the pearly opalescence of moonstone ; (b) plumose, when radiately arranged. 3. Massive; Alabaster, a fine-grained variety, either white or delicately shaded ; scaly- granular ; earthy or rock-gypsum, a dull-colored rock, often impure with clay or calcium carbonate, and sometimes with anhydrite. Comp CaSO 4 + 2aq= Sulphur trioxide 46 '5, lime 32'tf, water 20-9 = 100. Pyr., etc. In the closed tube gives off water and becomes opaque. Fuses at 2 '5-3, color- ing the flame reddish-yellow. For other reactions, see ANHYDRITE, p. 389. Ignited at a temperature not exceeding 260 C., it again combines with water when moistened, and becomes firmly solid. Soluble in hydrochloric acid, and also in 400 to 500 parts of water. Diff. Characterized by its softness ; it does not effervesce nor gelatinize with acids. Some varieties resemble heulandite, stilbite, talc, etc.; and in its fibrous forms it is like some calcite. Obs. Gypsum often forms extensive beds in connection with various stratified rocks, espe- cially limestone, and marlytes or clay beds. It occurs occasionally in crystalline rocks. Itia also a product of volcanoes ; produced by the decomposition of pyrite when lime is present ; and often about sulphur springs ; also deposited on the evaporation of sea-water and brines, in which it exists in solution. Fine specimens are found in the salt mines of Bex in Switzerland ; at Hall in the Tyrol ; in the sulphur mines of Sicily ; in the gypsum formation near Oqana in Spain ; in the clay of Shotover Hill, near Oxford ; at Montmartre, near Paris. A noted locality of alabaster occurs at Castelino, 35 m. from Leghorn. In the U. S. this species occurs in extensive beds in N. York, Ohio, Illinois, Virginia, Tennessee, and Arkansas ; it is usually associated with salt springs. Also in Nova Scotia, Peru, etc. It is characteristic of the so-called triassic, or red beds, of the Rocky Mountain region ; also of the Cretaceous in the west, particularly of the clays of the Fort Pierre group, in which it occurs in the form of transparent plates. Handsome selenite and snowy gypsum occur in N. York, near Lockport ; also near Camil- lus, Onoudaga Co. In Maryland, on the St. Mary's, in clay. In Ohio, large transparent crystals have been found at Poland and Cantield, Trumbull Co. In Tenn., selenite and ala- baster in Davidson Co. In Kentucky, in Mammoth Cave, in the form of rosettes, etc. In N. Scotia, in Sussex, King's Co., large crystals, often containing much symmetrically dis- seminated sand (Marsh). Plaster of Paris (or gypsum which has been heated and ground up) is used for making moulds, taking casts of statues, medals, etc. ; for producing a hard finish on walls; also in the manufacture of artificial marble, as the scagliola tables of Leghorn, and in the glazing of porcelain. FOLYHALITE. Monoclinic (?). A prism of 115, with acute edges truncated. Usually iu compact fibrous masses. 11.= 2-5-3. Gr. 2-7689. Lustre resinous or slightly pearly. Streak red. Color flesh- or brick-red, sometimes yellowish. Translucent opaque Taste bitter and astringent, but very weak. Oomp. 2RS0 4 +aq, where R^Ca : Mg : K 2 in the ratio 2:1:1; that is, +2aq=Calcium sulphate 45 '2, magnesium sulphate 19 9, potassium sulphate 28 '9, water 6-0=100. Pyr., etc. In the closed tube gives water. B.B fuses at 1'5, colors the flame yellow. On charcoal fuses to a reddish globule, which in R.F. becomes white, and on cooling has a saline hepatic taste ; with soda like glauberite. With fluor does not give a clear bead. Partially soluble in water, leaving a residue of calcium sulphate, which dissolves in a large amount of water 394 DESCRIPTIVE MINERALOGY. Obs. Occurs at the mines of Ischl, Ebensee, Aussee, Hallstatt, and Hallein in Austria^ with common salt, gypsum, and anhydrite ; at Berchtesgaden in Bavaria ; at Vic in Lorraine. The name Polyhalite is derived from H-OA.WS, many, and oAs, salt, in allusion to the numbel of salts in the constitution of the mineral. SYNGENITB, v. Zepharovich; Kaluszite, Rumpf. Near polyhalite. Composition RSO 4 + aq, with R=Ca : K 2 = l : 1, that is, K 2 CaSoO8-|-aq=Potassium sulphate 53 '1, calcium sul- phate 41 '4, water 5 -5 = 100. Monoclinic. Occurs in small tabular crystals in cavities in halito at Kalusz, East Galicia. KIESERITE. MgSO.,+aq= Sulphur trioxide 58 -0, magnesia 28 -0, water 13 '0=100. Sfcass- furt. PICROMERITE is K 2 MgS 2 O 8 +6aq=Sulphur trioxide 39 '8, magnesia 9 '9, potash 23 4, water 26-9=100. Vesuvius; Stassfurt. BLOEDITE. Composition Na 2 MgSi0 8 + 4aq= Sulphur trioxide 47-9, magnesia 12-0, soda 18-6, water 21'5=100. Salt mines of Ischl ; also in the Andes. SIMOKVITE (Txcliermak) is identical. LCEWEITE. 2Na 2 MgS 2 O 8 +5aq= Sulphur trioxide 52'1, magnesia 13 0, soda 20 2, water 14-7=100. From IschL EPSOMITE. Epsom Salt. Bittersalz, Gtrrm. Orthorhombic, and generally hemihedral in the octahedral modifications. IM= 90 3', A 1-t = 150 2' ; c:b:& = 0'57t>6 : 1-01 : 1. l-l A l-, basal, = 59 27', 1-t A 14, basal, = 59 56'. Cleavage: brae hy diagonal, perfect. Also in botrj'oidal masses and delicately iibrous crusts. II. 2*25. Gr.=l'751 ; 1*685, artificial salt. Lustre vitreous earthy Streak and color white. Transparent translucent. Taste bitter and saline. Comp. MgSO 4 +7aq, when pure = Sulphur trioxide 32'5, magucsia 16 '3, water 51-2=100. Pyr., etc. Liquifies in its water of crystallization. Gives much water in the closed tube at a high temperature; the water is acid. B.B. on charcoal fuses at first, and finally yields an infusible alkaline mass, which, with cobalt solution, gives a pink color on ignition. Very soluble in water, and has a very bitter taste. Obs. Common in mineral waters, and as a delicate fibrous or capillary efflorescence on rocks, in the galleries of mines, and elsewhere. In the former state it exists at Epsom, Eng- land, and at Sedlitz and Saidschutz in Bohemia. At Idria in Carniola it occurs in silky fibres, and is hence called hairsalt by the workmen. Also obtained at the gypsum quarries of Mont- martre, near Paris ; in Aragon and Catalonia in Spain ; in Chili ; found at Vesuvius, etc. The floors of the limestone caves of Kentucky, Tennessee, and Indiana, are in many instances covered with epsomite, in minute crystals, mingled with the earth. In the Mam- moth Cave, Ky., it adheres to the roof in loose masses like snowballs. FAUSERITE. A hydrous manganese-magnesium sulphate. Hungary. Copperas Group. OHALOANTHITE. Blue Vitriol. Kupfervitriol, Germ. Triclinic. O A 1= 109 32', O A 1' = 127 40', /A T = 123 10', A 1 =125 38', n graphite from Mugrau, Bohemia (Schrauf). ALUMINITE. H =1-2 =1-60. Luscre dull, earthy. Color white. Opaque. Fracture earthy. Adheres to the tongue ; meagre to the 396 DESCRIPTIVE MINERALOGY. Comp AlSO 6 +9aq= Sulphur trioxide 23'2, alumina 29'8, water 47*0=100. Pyr., etc. In the closed tube gives much water, which, at a high temperature, becomes acid from the evolution of sulphurous and sulphuric oxides. B.B. infusible. With cobalt solution a fine blue color. With soda on charcoal a hepatic mass. Soluble in acids. Obs. Occurs in connection with beds of clay in the Tertiary and Post- tertiary formations. Found near Halle ; at Newhaven, Sussex ; Epernay, in Lunel Vieil, and Auteuil, in France. WERTHEMANITE. ^lS0 6 -f-3aq. G.=2'80. Occurs near Chachapoyas, in Peru. ALUNITE, Alaunstein, Oei'm. Composition K 2 Al 3 S 4 0.. 2 + 6aq. Rhombohedral. Also massive, fibrous. Forms seams in trachyte and allied rocks. Tolfa, near Rome ; Tuscany; Hungary ; Mt. Dore, France, etc. LOWIQITE. Same composition as alunite, but contains 3 parts more of water. Tabrze, Silesia. LINARITE. Bleilasur, Kupferbleispath, Germ. Monoclinic. C= 77 27' ; /A I, over i-i, = 61 36', O A 14 = 141 5', c : T> : d = 0*48134 : 0-5819 : 1, Hessenberg. Twins: twin n ing-plane i-i common ; O A O' 154 54'. *j Cleavage : i-i very perfect ; O less so. J H.r=2'5. G.=5.3-5'45. Lustre vitreous or ada- mantine. Color deep azure-blue. Streak pale blue. Translucent. Fracture conchoidal. Brittle. Comp. PbCuS0 5 +aq=(Pb,Cu)S0 4 +H 2 (Pb,Cu)0 :2 Sulphur trioxide 20 0, lead oxide 55 7, copper oxide 19 '8, water 4 '5 =100. Pyr., etc, In the closed tube yields water and loses its blue color. B.B. on charcoal fuses easily to a pearl, and in R.F. is reduced to a metallic globule which by continued treatment coats the coal with lead oxide, and if fused boron trioxide is added yields a pure globule of copper. With soda gives the reaction for sulphur. Decomposed with nitric acid, leaving a white residue of lead sulphate. Obs. Formerly found at Leadhills. Occurs at Roughten Gill, Red Gill, etc. , in Cumber- laud ; near Schneeberg, rare; in Dillenburg ; atRetzbanya; in Nertschinsk ; and near Beresof in the Ural ; and supposed formerly to be found at Linares in Spain, whence the name. BROCHANTITE. Monoclinic. O = 89 27i'. 1 A / = 104 6f, O A 14 = 154 12*' ; 1, f , f , , 2, 3, 4, 5, 10. The varieties having the five higher values of x he calls paran- kerite, while the others are normal ankerite. If a?=l, the formula is equivalent to 2CaCO 3 + MgCO 3 +FeC0 3 , and requires: Calcium carbonate 50, magnesium carbonate 21, iron carbon- ate 29=100. Manganese is also sometimes present. Pyr., etc. B.B. like dolomite, but darkens in color, and on charcoal becomes black and magnetic ; with the fluxes reacts for iron and manganese. Soluble with effervescence in the acids. Obs. Occurs with siderite at the Styrian mines ; in Bohemia; Siegen ; Schneeberg ; Nova Scotia, etc. MAGNESITE. Khombohedral. R/\R = 107 29', Of\K = 136 56' ; c = 0-8095. Cleavage: rhombohedral, perfect. Also massive; granular, to very com- pact. H.=3'5-4-5. G.=3-3-OS, cryst. ; 2-8, earthy; 3-3 -2, when ferriferous, Lustre vitreous; fibrous varieties sometimes silky. Color white, yellowish or grayish-white, brown. Transparent opaque. Fracture flat conchoid al Var. Ferriferous, Breunerite; containing several p. c. of iron protoxide; G. 3-3'2; white, yellowish, brownish, rarely black and bituminous; often becoming brown on exposure and hence called Brown Spar. Comp. Magnesium carbonate, MgC0 3 Carbon dioxide 52 '4, magnesia 47 '6 = 100; butiroi often replacing some magnesium. Pyr., etc. B. H. resembles calcite and dolomite, and like the latter is but slightly actec upon by cold acids ; in powder is readily dissolved with effervescence in warm hydrochlori< acid. Obs. Found in talcose schist, serpentine, and other magnesian rocks ; as veins in serpen tine, or mixed with it so as to form a variety of verd-antique marble (magnesitic ophiolite o OXYGEN COMPOUNDS. CARBONATES. 403 ilunt) ; also in Canada, as a rock, more or less pure, associated with steatite, serpentine, and dolomite. Occurs at Hrubschiitz in Moravia ; in Styria, and in the Tyrol ; at Frankenstein in Silesia ; Snarum, Norway ; Baudissero and Castellamonte in Piedmont. In America, at Bolton, Mass.; at Barehllls, near Baltimore, Md. ; in Penn., at West G-oshen, Chester Co. ; near Texas, Lan- caster Co. ; California. MESITITE and PISTOMESITE come under the general formula (Mg,Fe)C0 3 ; with the formei Mg : Fe=2 : 1 ; with the latter=l : 1. SIDERITE. Spathic Iron. Chalybite. Eisenspath, Germ. Rhombohedntl. Rf\R= 107, Ol\R = 136 37' ; c = 0-81715. The faces often curved, as below. Cleavage : rhom- bohedral, perfect. Twins : twinning-piane . 735 Also in botryoidal and globular forms, sub- fibrous within, occasionally silky fibrous. Often cleavable massive, with cleavage planes undu- lating. Coarse or fine granular. H. = 3-5-4-5. G. =3-7-3-9. Lustre vitreous, more or less pearly. Streak white. Color ash- gray, yellowish-gray, greenish-gray, also brown and brownish-red, rarely green ; and sometimes white. Translucent subtranslucent. Fracture uneven. Brittle. Comp., Var. Iron carbonate, FeC0 3 = Carbon dioxide 37'9, iron protoxide 62'1. But part of the iron usually replaced by manganese, and often by magnesium or calcium. Somo varieties contain 8-10 p. c. MnO. The principal varieties are the following : (1) Ordinary, (a) Crystallized, (b) Goner etionary = Splier osiderite ; in globular concretions, either solid or concentric scaly, with usually a fibrous structure, (c) Granular to compact mas- sive, (d) Oolitic, like oolitic limestone in structure. (e) Earthy, or stony, impure from mixture with clay or sand, constituting a large part of the clay iron stone of the coal forma- tion and other stratified deposits ; H. =3 to 7, the last from the silica present ; G-. =3'0-3'8, or mostly 3 '15 -3 '65. Pyr., etc. In the closed tube decrepitates, evolves carbon oxide and carbon dioxide, blackens and becomes magnetic. B.B. blackens and fuses at 4'5. With the fluxes reacts for iron, and with soda and nitre on platinum foil generally gives a manganese reaction. Only slowly acted upon by cold acid, but dissolves with brisk effervescence in hot hydrochloric acid. Diff. Specific gravity higher than that of calcite and dolomite. B.B. becomes magnetic readily. Obs. Siderite occurs in many of the rock strata, in gneiss, mica slate, clay slate, and aa clay iron-stone in connection with the Coal formation and many other stratified deposits. It is often associated with metallic ores. At Freiberg it occurs in silver mines. In Cornwall it accompanies tin. It is also found accompanying copper and iron pyrites, galenite, vitreous copper, etc. In New York, according to Beck, it is almost always associated with specular iron. In the region in and about Styria and Carinthia this ore forms extensive tracts in gneiss. At Harzgerode in the Harz, it occurs in fine crystals ; also in Cornwall, Alston-Moor, and Devonshire ; near Glasgow ; also at Mouillar, Magescote, etc., in France, etc. In the U. States, in Vermont, at Plymouth. In Mass., at Sterling. In Conn., at Roxbury. In N. York, at the Sterling ore bed in Antwerp, Jefferson Co. ; at the Rossie iron mines, St. Lawrence Co. In N. Carolina, at Fentress and Harlem mines. The argillaceous carbonate, in nodules and beds (clay iron-stone), is abundant in the coal regions of Penn. , Ohio, and manj parts of the country. RHODOCHROSITE .* Dialogite. Manganspath, Germ. Ehombohedral. Rf\R = 106 51', O f\ R = 136 31i' ; c = 0-8211. Cleavage : R, perfect. Also globular and botryoidal, having a columnai structure, sometimes indistinct. Also granular massive ; occasionally ira palpable; incr listing. 404 DESCRIPTIVE MINERALOGY. H. =3-5-4-5. G.= 3-4-3-7. Lustre vitreous, inclining to pearly. Color shades of rose-red, yellowish-gray, fawn-colored, dark red, brown. Streak white. Translucent subtranslucent. Fracture uneven. Brittle. Comp MnC0 3 =: Carbon dioxide 38 '3, manganese protoxide 61 '7 ; but part of the man- ganese usually replaced by calcium, and often also by magnesium or iron ; and sometimes by cobalt. Pyr., etc. B.B. changes to gray, brown, and black, and decrepitates strongly, but is in- fusible. With salt of phosphorus and borax in O.F. gives an amethystine -colored bead in R.F. becomes colorless. With soda on platinum foil a bluish-green manganate. Dissolve? with effervescence in warm hydrochloric acid. On exposure to the air changes to brown, and pome bright rose-red varieties become paler. Obs. Occurs commonly in veins along with ores of silver, lead, and copper, and with other ores of manganese. Found at Schemuitz and Kapnik hi Hungary ; Nagyag in Transylvania ; near Elbingerode in the Harz ; at Freiberg in Saxony. Occurs in New Jersey, at Mine Hill, Franklin Furnace. Abundant at the silver mines oi Austin, Nevada ; at Placentia Bay, Newfoundland. Named rJwdochrosite f rom /M5oi>, a rose, and xpcStrts, color; and dialogite, from 8(0X07^, doubt, SMITHSONITE. Calamine pt. Galmei pt. Zinkspath, Germ. Khombohedral. Rf\R= 107 40', 0/\R = 137 3' ; c = 0-8062. E generally curved and rough. Cleavage : R perfect. Also reniform, botry- oidal, or stalactitic, and in crystalline incrustations; also granular, and sometimes impalpable, occasionally earthy and friable. H. 5. G.= 4-4-45. Lustre vitreous, inclining to pearly. Streak white, Color white, often grayish, greenish, brownish- white, sometimes green and brown. Subtransparent translucent. Fracture uneven imperfect!}' conchoidal. Brittle. Comp., Var.ZnCO 3 = Carbon dioxide 35 "2, zinc oxide 64 '8 =100; but part of the zinc often replaced by iron or manganese, and by traces of calcium and magnesium ; sometimes by cadmium. Varieties. (1) Ordinary, (a) Crystallized; (b) botry oidal and stalactitic, common; (c] granular to compact massive; (d) earthy, impure, in nodular and cavernous masses, varying from grayish-white to dark gray, brown, brownish-red, brownish-black, and often with drusj surfaces in the cavities ; " dry-bone " of American miners. Pyr., etc. In the closed tube loses carbon dioxide, and, if pure, is yellow while hot and colorless on cooling. B.B. infusible; moistened with cobalt solution and heated in O.F. gives a green color on cooling. With soda on charcoal gives zinc vapors, and coats the coal yellow while hot, becoming white on cooling ; this coating, moistened with cobalt solution, gives a green color after heating in O.F. Cadmiferous varieties, when treated with soda, give at first a deep yellow or brown coating before the zinc coating appears. With the fluxes some varieties react for iron, copper, and manganese. Soluble in hydrochloric acid with efferves- cence. Diff. Distinguished from calarnine by its effervescence in acids. Obs. Smithsonite is found both in veins and beds, especially in company with galeuite and blende ; also with copper and iron ores. It usually occurs in calcareous rocks, and is generally associated with calamine, and sometimes with limonite. It is often produced by the action of zinc sulphate upon calcium or magnesium carbonate. Found at Nertschinsk in Siberia ; at Dognatzka in Hungary ; Bleiberg and Eaibel in Cariu- thia ; Moresnet in Belgium. In England, at Roughten Gill, Alston Moor, near Matlock, in the Mendip Hills, and elsewhere ; in Scotland, at Leadhills; in Ireland, at Donegal. In the U. States, in N. Jersey, at Mine Hill, near the Franklin Furnace. In Penn. , at Lancaster abundant ; at the Perkiomen lead mine ; at the Ueberroth mine, near Bethlehem. In Wisconsin, at Mineral Point, Shullsburg, etc. In Minnesota, at Ewing's diggings, N. W. of Dubuque, etc. In Missouri and Arkansas, along with the lead ores in Lower Silurian limestone. OXYGEN COMPOUNDS. CARBONATES. 405 Aragonite Group. ARAGONITB. Ortliorhombic /A 7 = 116 10', O A 14 = 130 50' ; c : 3 : = 1-1571 : 1-6055 : 1. O A 1 = 126 15', A 1-2 = 137 15', 14 A 14, top, := 108 26'. Crystals usually having O striated parallel to the shorter diagonal ; often tapering from the presence of acute domes and pyramids, which have unusual indices. Cleavage: I imperfect; i-i distinct; l-# imperfect. Twins : twinning-plane 7, producing often hexagonal forms, f . 738, compare figures on pp. 96, 97. Twinning often many times repeated in the same crystal, producing successive reversed layers, the alternate of which may be exceedingly thin ; often so delicate as to produce by the succession a fine striation of the faces of a prism or of a cleavage plane. Also globular, reniform, and coralloidal shapes; sometimes columnar, composed of Etraight and divergent fibres ; also stalactitic ; incrusting. 737 738 it /If H.i=3*5-4. G.= 2-931, Haidinger. Lustre vitreous, sometimes inclin- ing to resinous on surfaces of fracture. Color white ; also gray ^yellow, green, and violet ; streak uncolored. subconchoidal. Brittle. Transparent translucent. Fracture Var. 1. Ordinary, (a] Crystallized in simple or compound crystals, the latter much the most common ; often in radiating groups of acicular crystals, (b) Columnar ; a fine fibrous variety with silky lustre is called Satin spar, (c) Massive. Stalactitic or stalagmitic (either compact or fibrous in structure), as with calcite ; Sprudelstein is stalactitic from Carlsbad. Coralloidal ; in groupings of delicate interlacing and coalescing stems, of a snow-white color, and looking a little like coral. Comp CaC0 3 , like calcite, = Carbon dioxide 44, lime 56100. Pyr., etc. B. B. whitens and falls to pieces, and sometimes, when containing strontia, im- parts a more intensely red color to the flame than lime ; otherwise reacts like calcite. Diflf. See calcite, p. 401. Obs. The most common repositories of aragonite are beds of gypsum, beds of iron ore (where it occurs in coralloidal forms, and is denominated flos-ferri, "flower of iron," Eisen- bliithe, Germ.), basalt, and trap rock; occasionally it occurs in lavas. It is often associated with copper and pyrite, galenite, and malachite. First discovered in Aragon, Spain (whence its name), at Molina and Valencia. Since found at Bilin in Bohemia ; at Herrengrund in Hungary, f. 738 ; at Baumgarten in Silesia ; 406 DESCRIPTIVE MINERALOGY. at Leogang in Salzburg ; in Waltsch, Bohemia, and many other places. The flosferri variety is found in great perfection in the Styrian mines. In Buckinghamshire, Devonshire, in caverns ; at Leadhills in Lanarkshire. Occurs in serpentine at Hoboken, N. J.; at Edenville, N. Y.; at the Parish ore bed, Rossie, N. Y.; at Haddam, Conn.; at New Garden, in Chester Co., Penn.; at Wood's Mine, Lancas- ter Co., Penn.; at Warsaw, 111., lining geodes. MANGANOCALCITE. Composition 2MnC0 3 -HCa,Mg)C0 3 , with a little iron replacing part of the manganese. G. =3-037. Color flesh-red to reddish-white. Schemnitz, Hungary. WITHERITE. Orthorhombic. /A 1= 118 30', A 14 = 128 45' ; c:b:d = 1-246 : 1'6808 : 1. Twins : all the annexed figures, com- position parallel to I\ reentering angles some- times observed. Cleavage : / distinct ; also in globular, tuberose, and botryoidal forms; struc- ture either columnar or granular ; also amor- phous. H. = 3-3-75. G. 4-29-4-35. Lustre vitreous, inclining to resinous, on surfaces of fracture. Color white, often yellowish, or grayish. Streak white. Subtransparent translucent. Fracture uneven. Brittle. Comp. BaCO 3 = Carbon dioxide 22 '3, baryta 77'7-100. Pyr. 3 etc. B.B. fuses at 2 to a bead, coloring the flame yel- lowish-green; after fusion reacts alkaline. B.B. on charcoal with soda fuses easily, and is absorbed by the coal. Soluble in dilute hydrochloric acid; this solution, even when very much diluted, gives with sulphuric- acid a white precipitate which is insoluble in acids. Diff. Distinguishing characters : high specific gravity ; effervescence with acids ; green coloration of the flame B.B. Obs. Occurs at Alston-Moor in Cumberland ; at Fallowfield, near Hexham in Northumber- land ; Tarnowitz in Silesia ; Leogang in Salzburg ; Peggau in Styria ; some places in Sicily ; the mine of Arqueros, near Coquimbo, Chili ; near Lexington, Ky., with barite. Witherite is extensively mined at Fallowfield, and is used in chemical works in the manu- facture of plate-glass, and in France in making beet- sugar. BHOMLITE.- Formula as for barytocalcite, but orthorhombic in form. STRONTIANITE. Orthorhombic. I^ 1= 117 19', A 1-t = 130 5' ; c:l:d = MS83 : 1-6421 : 1. O A 1 = 125 43', O A 1-2 = 144 6', 1 A 1, mac., = 130 1', 1 A 1, brack, = 92 IV. Cleavage : 1 nearly perfect, i-l in traces. Crys- tals often acicular and in divergent groups. Twins : like those of aragonite. O usually stri- ated parallel to the shorter diagonal. Also in columnar globular forms ; fibrous and granular. H.=3-5-4. G. 3-605-3-713. Lustre vitre- ous ; inclining to resinous on uneven faces of fracture. Color pale asparagus-green, apple-green ; also white, gray, yel- low, and yellowish-brown. Streak white. Transparent translucent. Fracture uneven. Brittle. OXYGEN COMPOUNDS. CARBONATES. 407 Comp. SrCO 3 =: Carbon dioxide 297, strontia 70'3 ; but a small part of the strontium often replaced by calcium. Pyr., etc. B.B. swells up, throws out minute sprouts, fuses only on the thin edges, and colors the flame strontia-red ; the assay reacts alkaline after ignition. Moistened with hydro- chloric acid and treated either B.B. or in the naked lamp gives an intense red color. With soda on charcoal the pure mineral fuses to a clear glass, and is entirely absorbed by the coal ; if lime or iron be present they are separated and remain on the surface of the coal. Soluble in hydrochloric acid ; the dilute solution when treated with sulphuric acid gives a white pre- cipitate. DifT. Differs from related minerals, not carbonates, in effervescing with acids ; lower specific gravity than witherite, and colors the flame red. Obs. Occurs at Strontian in Argyleshire ; in Yorkshire, England ; Giant's Causeway, Ire- land ; Clausthal in the Harz ; Briiunsdorf , Saxony ; Leogang in Salzburg. In the U. States it occurs at Schoharie, N. Y., in granular and columnar masses, and also in crystals. At Muscalonge Lake; at Chaumont Bay and Theresa, in Jefferson Co., N. Y. ; MifflinCo., Penn CERUSSITE. Weissbleierz, Bleispath, Germ. 745 Orthorhombic. /A 1= 117 13', A 14 = 130 9f ; c:t>:d= 1-1852 : 1-6388 : 1. O A 1 = 125 46', 0Al--& = 144: 8', lAl, mac., = 130, 1 A 1, brach., = 92 19'. Cleavage: /often imperfect ; 2-i hardly less so. Crystals usually thin, broad, and brittle ; sometimes stout. Twins : very common ; twin- ning-plane I, producing usu- ally cruciform or stellate forms ; also less commonly, ^winning-plane i-&. Rarely fibrous, often granular mas- sive and compact. Sometimes stalactitic. II. = 3-3-5. G. = 6*465-6 '480 ; some earthy varieties as low as 5'4. Lustre adamantine, inclining to vitreous or resinous; sometimes pearly; sometimes sub metallic, if the colors are dark, or from a superficial change. Color white, gray, grayish-black, sometimes tinged blue or green by some of the salts of copper; streak uncolored. Transparent subtranslucent. Fracture conchoidal. Very brittle. Comp. PbC0 3 = Carbon dioxide 16 '5, lead oxide 83 '5 =100. Pyr., etc. In the closed tube decrepitates, loses carbon dioxide, turns first yellow, and at a higher temperature dark red, but becomes yellow again on cooling. B.B. on charcoal fuses very easily, and in R. F. yields metallic lead. Soluble in dilute nitric acid with effervescence. Diff. Unlike anglesite, it effervesces with nitric acid. Characterized by high specific gravity, and yielding lead B.B. Obs Occurs in connection with other lead minerals, and is formed from galenite, which, as it passes to a sulphate, may be changed to carbonate by means of solutions of calcium bicarbonate. It is found at Johanngeorgenstadt ; at Nertschinsk and Beresof in Siberia ; at Clausthal in the Harz ; at Bleiberg in Carinthia ; at Mies and Przibram in Bohemia ; at Retz- hanya. Hungary; in England, in Cornwall; near Matlock and Wirksworth, Derbyshire; at Leadhills, Scotland ; in Wicklow, Ireland. Found in Penn. , at Phenixville ; at Perkiomen. In N. York, at the Rossie lead mine. In Virginia, at Austin's mines, Wythe Co. In N. Carolina, at King's mine, Davidson Co. , good. In Wisconsin and other lead mines of the northwestern States, rarelv in crystals ; near the Blue Mounds, Wise. , in stalactites. 408 DESCRIPTIVE MINERALOGY. BARYTOCALCITE. Monoclinie. C = 73 52', I^ 1= 106 54', A 14 = 149 W ; c : I : d =-. 0-81035 : 1'295S3 : 1. Cleavage : /, perfect ; O, less perfect ; also massive. H.=4:. G. =3-6363-3*66. Lustre vitreous, inclining to resinous. Color white, grayish, greenish, or yellowish. Streak white. Transparent translucent. Fracture uneven. Comp (Ba,Ca)C0 3 , where Ba : Ca=l : l=Barium carbonate 66 -3, calcium carbonate 33-7=100. Pyr., etc. B.B. colors the flame yellowish -green, and at a higher temperature fuses on the thin edges and assumes a pale green color ; the assay reacts alkaline after ignition. With the fluxes reacts for manganese. With soda on charcoal the lime is separated as an infusible mass, while the remainder is absorbed by the coal. Soluble in dilute hydrochloric acid. Obs. Occurs at Alston-Moor in Cumberland, in the Subcarboniferous or mountain lime- stone. PAKISITE. A carbonate containing cerium (also La,Di), and calcium with 6 p. c. fluorine. Exact composition uncertain. In hexagonal crystals. Color brownish-yellow. Muso valley, New Granada. KISCIITIMITE, from the gold washing of the Barsovska river, Urals, is similar in composition, but contains no calcium. BASTNASITE (Hamartite). Composition 2RCO 3 +RF, with R=Ce : La =2 : 3. Analysis, Nordenskiolil, CO, 19'50, LaO 45-77, CeO 28'49, H,O I'Ol, F,0, (5 '23)=100. Found in small masses imbedded between allanite crystals. Riddarhyttan, Sweden. PHOSGENITE. Bleihornerz, Germ. Tetragonal. 6>Al-a = 132 37'; c = 1-0871. Cleavage: / and i-i bright ; also basal. H.=2'75-3. G.=6-6'31. Lustre adamantine. Color white, gray, and yellow. Streak white Transparent translucent. Rather sectile. Comp. PbC0 3 +PbCl 2 =Lead carbonate 49, lead chloride 51=100, or lead oxide 81 -9, car- bon dioxide 8-1, chlorine 13'0=102'9. Pyr., etc. B.B. melts readily to a yellow globule, which on cooling becomes white and crystalline. On charcoal in R.F. gives metallic lead, with a white coating of lead chloride. With a salt of phosphorus bead previously saturated with copper oxide gives the chlorine reaction. Dissolves with effervescence in nitric acid. Obs. At Cromford near Matlock in Derbyshire ; very rare in Cornwall ; in large crystals at Gibbas and Monteponi in Sardinia ; near Bobrek in Upper Silesia. HYDEOUS CARBONATE. TRONA. Monoclinic. A i-i = 103 15'. Clea\ 7 age : i-i perfect. Often fibrous or columnar massive. H.= 2-5-3. G. 2-11. Lustre vitreous, glistening. Color gray or yel- lowish-white. Translucent. Taste alkaline. Not altered by exposure to a dry atmosphere. Comp Na 4 C 3 8 +3aq=Carbon dioxide 40-2, soda 37'8, water 22 '0. Pyr., etc. In the closed tube yields water and carbon dioxide. B.B. imparts an intensely yellow color to the flame. Soluble in water, and effervesces with acids. Reacts alkaline with moistened test paper. Obs. The specimen analyzed by Klaproth came from the province of Suckenna, two days' journey from Fezzen, ica. To this species belongs the urao found at ths bottom of a lake OXYGEN COMPOUNDS. CARBONATES. 409 In Maracaibo, S. A. , a day's journey from Merida. Efflorescences of trona occur near the Sweetwater river, Rocky Mountains, mixed with sodium sulphate and common salt. NATRON or Soda (sodium carbonate, Na a CO 3 +10aq). THEKMONATIUTE, Na 2 C0 8 +a(i. TESCIIEMACHERITE, Ammonium carbonate. Maracaibo. Nevada. GAY-LUSSITE. Monoclinic. C = 78 27', /A 1= 68 50' and 111 10' 0*14 = 125 15' ; c:b:d = 0-96945 : 0-67137 : 1. 14 A 14, adj., = 109 30', A i = 110 30'. Crystals often lengthened, and prismatic in the direction of 14; also in that of ^ ; also (fr.. Nevada) not elongate, but thin in the direction of the orthodia- gonal, O being very narrow or wanting ; surfaces usually uneven, being formed of minute subordinate planes. Cleav- age : I perfect ; less so, but giving a reflected image in a strong light. H.=2-3. G.=l-92-l-99. Lustre vitreous. Color white, yellowish- white. Streak uncolored to grayish. Translucent. Fracture conchoidal. Extremely brittle. Not phosphorescent by friction or heat. Comp. Na 2 COs + CaC0 3 + 5aq=: Sodium carbonate 35-9, calcium carbonate 33*8, water 30-3 = 100. Pyr., etc. Heated in a matrass the crystals decrepitate and become opaque. B B fuses easily to a white enamel, and colors the flame intensely yellow. With the fluxes it behaves like calcium carbonate. Dissolves in acids with a brisk effervescence ; partly soluble in water, and reddens turmeric. Obs. Abundant at Lagunilla, near Merida, in Maracaibo, where its crystals are dissemi- nated at the bottom of a small lake, in a bed of clay, covering urao ; the natives call it davos or natts, in allusion to its crystalline form. Also on a small island in Little Salt Lake, near Ragtown, Nevada, about H in. S. of the main emigrant road to Humboldt. The lake is in a crater-shaped basin, and its waters are dense and strongly saline. The distorted crystals from Sangerhausen have been long considered pseudomorphs after gay-lussite, though Des Cloizeaux regards them as pseudomorphs after celestite. Groth regards them as perhaps pseudomorphs after anhydrite. See also thinolite, p. 438. H Y DROM AGNE SITE. Monoclinic. <7=82-83, 7 A 1= 87 52 / -88, O A 24 = 137; : d = (nearly) 0-455 : 1-0973 : 1. Crystals small, usually acicular or bladed, and tufted. Also amorphous ; as chalky or mealy crusts. H. of crystals 3-5. G.=2-l 45-2-18, Smith & Brush. Lustre vitreous to silky or subpearly ; also earthy. Color and streak white. Brittle. Comp. 3MgCO 3 +H 2 MgO 2 +3aq:= Carbon dioxide 36 '3, magnesia 43-9, water 19 -6= 100. Pyr., etc. In the closed tube gives off water and carbon dioxide. B.B. infusible, but whitens, and the assay reacts alkaline totuimeric paper. Soluble in acids ; the crystalline compact varieties are but slowly acted upon by cold acid, but dissolves with effervescence in hot acid. 410 DESCRIPTIVE MINERALOGY. Obs Occurs at Hrubschitz, in Moravia, in serpentine ; in Negroponte, near Kami ; at Kaiserstuhl, in Baden, impure. In the U. States, near Texas, Lancaster Co., Penn. ; at Hoboken, N. J. HYDKODOLOMITE. Composition 3(CaMg)C0 3 -i-aq. From Mt Somma. PKNNITE from Texas, Pa. , is similar. PREDAZZITE and PENCATITE are mixtures of calcite and brucite. Tyrol. DAWSONITE. In thin-bladed, white, transparent crystals on trachyte. H. =3. G.=2'40- Analysis, Harrington, A10 3 32 84, MgO tr., CaO 5*1)5, Na.O 20'20, K.O 38, H 2 O 11-91, CO, 29 '88, Si0 2 '40 = 101*56. Regarded as ' a hydrous carbonate of aluminum, calcium, and aodium ; or perhaps as a hydrate of aluminum with carbonates of calcium and sodium." Montreal, Canada. HOVITE. Supposed to be a hydrous carbonate of aluminum and calcium. Soft, white, and friable ; earthy in fracture. From Hove, near Brighton, with colly rite. LANTHANITB. Orthorhombic. /A 1= 93 30'-94, Blake, 92 46', v. Lang ; /A 1 142 36' ; c:l>:d = 0-99898 : 1-0496 : 1, v. Lang. In thin four-sided plates or minute tables, with bevelled edges. Cleavage micaceous. Also hue granular or earthy. II. =2-5 3. G.=2'666. Lustre pearly or dull. Color grayish-white, delicate pink, or yellowish. Comp. LaCO 3 +3aq=Lanthana 52-6, carbon dioxide 21 '3, water 26*1=100. There is some oxide of didyrnium with the lanthana, according to Smith. Pyr., etc. In the closed tube yields water. B.B. infusible ; but whitens and becomes opaque, silvery, and brownish; with borax, a glass, slightly bluish, reddish, or "amethystine, on cooling ; with salt of phosphorus a glass, bluish amethystine while hot, red cold, the bead becoming opaque when but slightly heated, and retaining a pink color. Effervesces in the acids. Obs. Found coating cerite at Bastniis, Sweden ; also with the zinc ores of the Saucon valley,. Lehigh Co., Pa. ; at the Sandford iron-ore bed, Moriah, Essex Co., N. Y. TENGERITE. Yttrium carbonate. As a coating on gadolinite from Ytterby. ZARATITE. Emerald Nickel, tiiUiman. Nickelsmaragd, Germ. Composition Ni 3 CO 5 f- (Jaq, or NiCO 3 + 2H NiO.+4aq. This requires: Carbon dioxide 11*8, nickel oxide 59 3, water 28 '9 = 100. Usually as an emerald-green coating; thus on chromite at Texas, Penn., where it was first noticed ; Swinaness, Shetland ; Cape Ortegal, Spain. BEMINGTONITE. A hydrous cobalt carbonate. Finksburg, Md. HYDROZINCITE. Zinkbliithe, Germ. Massive, earthy or compact. As incrustations, the crusts sometimes con- centric and agate-like. At times reniform, pisolitic, stalactitic. IL 2-2-5. G.=3-58-3-8. Lustre dull. Color pure white, grayish or yellowish. Streak shining. Usually earthy or chalk-like. Comp. In part ZnC0 3 +2H 2 ZnO, = Carbon dioxide 13'6, zinc oxide 75-3, water 11'1=100. Pyr., etc. In the closed tube yields water ; in other respects resembles smithsonite. Obs. Occurs at most mines of zinc, and is a result of the alteration of the other ores of this metal. Found in great quantities at the Dolores mine, Udias valley, province of Santan- der, in Spain ; at Bleiberg and Raibel in Carinthia ; near Reimsbeck, in Westphalia In the U. States, at Friedensville, Pa.; at Linden, in Wisconsin; in Marion Co., Arkansas (marionite). AURICHALCITE. A cupreous hydrozincite. Usually in drusy incrustations. Altai; Matlock, Derbyshire; Spain; Lancaster, Pa. OXYGEN COMPOUNDS. CAEBONATE8. 411 MALACHITE. Monoclinic. G= 88 32', /A 1= 104 28', i-* A -1-i = 118 15', Zepharo dch ; c : I : d = 0-51155 : 1-2903 : 1. Common form f. 750 ; also same with other terminal planes; also with i-i wanting ; also with i-i, i-l very large, making a rect- angular prism ; also with the vertical prism very short, as in f. 321. Crystals rarely simple. Twins : twinning- plane i-i, f. 750 ; often penetration twins, as in f. 321, 322, p. 99. Cleavage : basal, highly perfect ; clino- diagonal less distinct. Usually massive or incrnsting, with surface tuberose, botryoidal, or stalactitic, and struc- ture divergent ; often delicately compact fibrous, and banded in color ; frequently granular or earthy. PL 3-5-4. G.=3-7-4-01. Lustre of crystals adaman- tine, inclining to vitreous ; of fibrous varieties more or less silky ; often dull and earthy. Color bright green. Streak paler green. Translucent subtranslucent opaque. Fracture subconchoidal, uneven. Comp. Cu 2 C0 4 4-H 2 0=CuC0 3 +H 2 CuO a = Carbon dioxide 19'9, copper oxide 71'9, water 8-2=100. Pyr., etc. In the closed tube blackens and yields water. B.B. fuses at 2, coloring the flame emerald-green ; on charcoal is reduced to metallic copper ; with the fluxes reacts like tenorite. Soluble in acids with effervescence. Diff. Differs from other copper ores of a green color in its effervescence with acids. Obs. Green malachite accompanies other ores of copper. Perfect crystals are quite rare. Occurs abundantly in the Urals ; at Chessy in France ; at Schwatz in the Tyrol ; in Cornwall and in Cumberland, England ; Sandlodge copper mine, Scotland ; Limerick, Waterf ord. and elsewhere, Ireland ; at Grimberg, near Siegen in Germany. At the copper mines of Nischne- Tagilsk, belonging to M. Demidoff, a bed of malachite was opened which yielded many tons of malachite. Also in handsome masses at Bembe, on the west coast of Africa ; with the copper ores of Cuba ; Chili ; Australia. In N. Jersey, at New Brunswick. In Pennsylvania, near Morgan town, Berks County ; at Cornwall, Lebanon Co. ; at the Perkiomen and Phenixville lead mines. In Wisconsin, at the copper mines of Mineral Point, and elswhere. In California, at Hughes's mine in Calaveras Co. Green malachite admits of a high polish, and when in large masses is cut into tables, snuff- boxes, vases, etc. Named from //aAa^, mallows, in allusion to the green color. CUPBOCALCITE. Massive. H.=3. G.=3'90. Color vermilion-red. Analysis, Raymondi, Cu 2 50-45, CaO 2016, C0 2 24 '00, H 2 O 3-20, Fe0 3 0'60, A1O 3 0'20, MgO 0'97, SiO a 99 '86. Occurs with a ferruginous calcite at the copper mines of Canza in Peru. AZURITE. Kupferlasur, Germ. Monoclinic. 7= 87 39'; /A/= 99 3 -32', O A 14 = 138 41'; c : t> : d == 1-039 : 1*181 : 1. O usually striated parallel with the clinodiagonal. Cleavage : 2-i rather perfect ; i-i less distinct ; I in traces. Also massive, and presenting imitative shapes, having a columnar composition ; also dull and earthy. H. = 3-5-4'25. G.=3'5-3'S31. Lustre vitreous, almost adamantine. Color various shades of azure-blue, passing into Berlin-blue. Streak blue, lighter than the color. Transparent subtranslucent. Fracture conchoidal. Brittle. 412 DESCRIPTIVE MINERALOGY. Comp. Cu 3 C 2 O T +H 2 0=2CuCO 3 +H 3 Cu0 3 =Carbon dioxide 25*6, copper oxide 69-2, water 5 '2= 100. Pyr., etc. Same as in malachite. Obs. Occurs at Chessy, near Lyons, whence its name Chessy Copper. Also in Siberia ; at Moldava in the Banat ; at Wheal Buller, near Redruth in Cornwall also in Devonshire and Derbyshire. In Peini. , at the Perkiomen lead mine ; at Phenixville, in crystals ; at Cornwall. In Wif> connn, near Mineral Point In California, Calaveras Co. , at Hughes's mine. According to Schrauf, who has given a crystallographic monograph of the species, the f oruc la closely related to that of epidote (Ber. Ak. Wien, July 3, 1871). BISMUTITE. Wismuthspath, Germ. In implanted acicular crystallizations (pseudomorphons) ; also incrusting or amorphous ; pulverulent. H.=4-4:*5. (jr.=6'86-6-909. Lust-re vitreous, when pure; sometimes dull. Color white, mountain-green, and dirty siskin-green ; occasionally &traw-yellow and yellowish-gray. Streak greenish-gray to colorless. Sub- translucent opaque. Brittle. Comp. 2Bi e C 3 18 f 9H 2 0, Eamm. (S. Carolina) = Carbon dioxide 6-38, bismuth oxide 89-75, water 3-87=100. Pyr., etc. In the closed tube decrepitates and gives off water. B.B. fuses readily, and on charcoal is reduced to bismuth, and coats the coal with yellow bismuth oxide. Dissolves in nitric acid, with slight effervescence. Dissolves in hydrochloric acid, affording a deep yellow solution. Obs. Bismutite occurs at Schneebarg and Johanngeorgenstadt ; at Joachimsthal ; near Baden ; also in the gold district of Chesterfield, S. C. ; in Gaston Co., N. C., in yellowish- white concretions. LIEBIGITE ; VOGLITE (Urankalk, Germ.). Carbonates of uranium and calcium, from the decomposition of uraninite. Exact composition doubtful. SCHROCKINGERITE is an oxycar- bonate of uranium (Schrauf). Orthorhombic. Occurs in six-sided tabular crystals. Joachims- thai. WHEWELLITE. An oxalate of calcium. In minute monoclinic crystals on calcite. HUMBOLDTITE. A hydrous oxalate of iron, 2FeC a O 4 + 3aq. Compact ; earthy. In' brown - coal of Koloseruk, near Bilin; also in black shales at Kettle Point ; in Bosanquet, Canada. MELLITE (Honigstein, Germ.). Tetragonal. In octahedrons ; also massive, honey -yellow, reddish, or brownish, rarely white. Al CiaOn+lSaq^ Alumina 14'36. mellitic acid 40'30, water 45 '34= 100. Arteru, Thuringia; Luschitz, Bohemia ; Walchow, Morav^i ; Nertschinsk, etc. HYDROCARBON COMPOUNDS. 413 VI. HYDROCARBON COMPOUNDS The Hydrogen-Carbon Compounds include (1) the SIMPLE HYDROCARBONS ; and (2) the OXYGENATED HYDROCARBONS. 1. The SIMPLE HYDRO CARBONS embrace : (a) The Marsh Gas series. General formula CnTI^.^. Here belong the liquid naphthas, the more volatile parts of petroleum ; also the butter-like solids scheererite and chrismatite. PETROLEUM. Mineral oil. Kerosene. Bergol, Steinjl, Erdjl, Germ. Petroleum is a thick to thin fluid. Color yellow or brown, or colorless ; translucent to transparent. The specific gravity varies from 0'7 to 0'9. Chemically it consists essentially of carbon and hydrogen ; contain- ing several members of the naphtha group, as also the oils of the ethylene series, and the paraffins. The proportion of the latter constituents increases with the increase of the density or viscidity of the fluid. It grades insensibly into pittasphalt. and that into solid bitumen. Occurs in rocks or deposits of nearly all geological ages, from the Lower Silurian to the present epoch. It is associated most abundantly with argillaceous shales and sandstones, but is found also permeating limestones, giving them a bituminous odor, and rendering them sometimes a considerable source of oil. From these oliierous shales and limestones the oil often exudes, and appears floating on the streams or lakes of the region, or rises in oil springs. It also exists collected in subterranean cavities in certain rocks, whence it issues in jets or fountains whenever an outlet is made by boring. These cavities are situated mostly along the course of gentle anticlinals in the rocks of the region ; and it is therefore probable, as has been suggested, that they originated for the most part in the displacements of the strata caused by the slight uplift. The oil which fills the cavities has ordinarily been derived from the subjacent rocks ; for the strata, in which the cavities exist, are frequently barren sandstones. Obtained in large quantities from the oil wells of Pennsylvania ; also found in eastern Vir- ginia, Kentucky, Ohio, Illinois, Michigan, and .New York. In Canada, at several places; in southern California ; in Mexico ; Trinidad. Some well-known foreign localities are : Rangoon, Burmah ; western shore of the Caspian Sea ; in Parma, Italy ; Sicily ; Galicia ; Tegernsee, Bavaria ; Hanover. (b) The defiant or Ethylene series. General formula C n H 2n . Here belong the pittoliuin group of liquids, or pittas phalt 8 (mineral tar), and the marajfins. PARAFFIN GROUP. Wax-like in consistence ; white and translucent. Sparingly soluble in alcohol, rather easily in ether, and crystallizing more or less perfectly from the solutions. Gr. about 085-0-98. Melting point for the following species, 33M)0\ The different species varying in the value of n, vary also in boiling point, and other characters. Paraffins occur in the Pennsylvania petroleum, a freezing mixture reducing the tempera- ture being sufficient to separate it in crystals. Also in the naphtha of the Caspian, in Ran- goon tar, and many other liquid bitumens. It is a result of the destructive distillation of peat, bituminous coal, lignite, coaly or bituminous shales, most viscid bitumens, wood-tar, and many other substances. The name is from the Latin parum, little, and affinis, alluding to the feeble affinity for othei substances, or, in other words, its chemical indifference. To the Paraffin Group belong : , URPETHITE. Consistency of soft tallow. Melting point 39 C. Soluble in cold ether. Urpeth Colliery. 414 DESCRIPTIVE MINER ALOGi. HATCHETTITE. In thin plates or massive. Color yellowish, or greenish- white ; blacken* on exposure. Melting point 46 C. In the coal-measures of Glamorganshire ; Rossitz, Moravia. OZOCERITE. Like wax or spermaceti in appearance and consistency. G. =0-85-0 '90. Calorless to white when pure; often leek-green, yellowish, brownish-yellow, brown. Trans lucent. Greasy to the touch. Fusing point 56 to 63 C. Occurs in beds of coal, or associ- ated bituminous deposits ; that of Slanik, Moldavia, beneath a bed of bituminous clay shale ; in masses of sometimes 80 to 100 Ibs., at the foot of the Carpathians, not far from beds oJ coal and salt ; that of Boryslaw in a bituminous clay associated with calciferous beds in the formation of the Carpathians, in masses. The same compound has been obtained from mine ral coal, peat, and petroleum, mineral tar, etc., by destructive distillation. Named from bC,u. smett, and mjpoq , wax, in allusion to the odor. ELATERITE. Massive, soft, elastic; of ten like india-rubber, though sometimes hard anc brittle. It is found at Castleton in Derbyshire, in the lead mine of Odin, along with lead or( and calcite, in compact reniform or fungoid masses, and is abundant. Also reported from St Bernard's Well, Edinburgh, etc. ZIETRISIKITE and PYROPISSITE belong here. (c) The Camphene Series. General Formula CjJ^zn-t- FICHTELITK. In white monoclinic crystals. Brittle. Solidifies at 36 C. Soluble in ether The mineral occurs in the form of shining scales, flat crystals, and thin layers between th< rings of growth and throughout the texture of pine wood (identical in species with the moden Pinus sylvestris) from peat beds in the vicinity of Redwitz in the Fichtelgebirge, Nortl Bavaria. In peat near Sobeslau ; in a log of Pinus Australis. HARTITE. Resembles fichtelite, but melts at 74-75 C. Found in a. kind of pine, lik< fichtelite. but of a different species, the Pence acerosa Unger, belonging to an earlier geologica epoch. From the brown-coal beds of Oberhart, near Gloggnitz, not far from Vienna. Reportec also from Rosenthal near Koflach in Styria, and Pravali in Carinthia. DINITE and IXOLYTE belong here. (d) The Benzole Series, General Formula CnH^.g. Including the Benzole liquids and KONLITE from Uznach, and Redwitz. (e) The Naphthalin Series. General Formula NAPHTHALIN. Occurs in Rangoon tar. IDRIALITE, crystalline in the pure state. Ooloi white. In nature found only impure, being mixed with cinnabar, clay, and some pynte anc gypsum in a brownish -black earthy material, called from its combustibility and the presence of mercury, inflammable cinnabar (Quecksilberbranderz). Idria, Spain. ARAGOTITE, front New Almaden Mine, Cal., is related to idrialite. 2. The OXYGENATED HYDROCARBONS embrace different groups having ratios of C : H varying from 1 : 2 to 5 : 5, or less. Some of the more important are : GEOCERITE. Wax-like. Color white. Melting point near 80 C. ; after fusion solidifies ai a yellowish wax, hard but not very brittle. Soluble in alcohol of 80 p. c. CaeHBeOa^Carboi 79'24, hydrogen 13 '21, oxygen 7 '55=100. From the same dark-brown brown coal of Gester witz that afforded the geomyricite, and from the same solution. GEOMYRICITE. Wax-like. Obtained in a pulverulent form from a solution, the grains con eisting of acicular crystals. Color white. Melting point 80-83 C. After fusion has th( aspect of a yellowish brittle wax. Soluble easily in hot absolute alcohol and ether, bu1 slightly in alcohol of 80 p. c. C 3 4He&0 2 = Carbon 80;59, hydrogen 13*42, oxygen 5 99=100, Burns with a bright flame. Occurs at the Gesterwitz brown coal deposit, in a dark brow* layer. HYDROCARBON COMPOUNDS*, 415 SUCCINITE. Amber. Succin, Ambre, Fr. Bernstein, Germ. In irregular masses, without cleavage. H. = 2-2*5. G.=1*065-1'081, Lustre resinous. Color yellow, sometimes reddish, brownish, and whitish, often clouded. Streak white. Transparent translucent. Tasteless. Elec- rc on friction. Fuses at 287 C., but without becoming a flowing liquid. Comp. Ratio for C : H : O=40 : 64 : 4=Carbon 78*94, hydrogen 10'53, oxygen 10'53= 100. But amber is not a simple resin. According to Berzclius, it consists mainly (85 to 90 p. c.) of a resin which resists all solvents (properly the species succinite), along with two othex resins soluble in alcohol and ether, an oil, and 2^ to 6 p. c. of succinic acid. Amber is hardly acted on by alcohol. Burns readily with a yellow flame, emitting an agreeable odor, and leaves a black, shining, carbonaceous residue. Obs. Occurs abundantly on the Prussian coast of the Baltic ; occurring from Dantzig to Memel ; also on the coast of Denmark and Sweden ; in Galicia, near Lemberg, and at Miszau ; in Poland ; in Moravia, at Boskowitz, etc. ; in the Urals, .Russia ; near Christiania, Norway ; in Switzerland, near Bale; in France, near Paris, in clay. Jn England, near London, and on the coast of Norfolk, Essex, and Suffolk. In various parts of Asia. Also near Catania, on the Sicilian coast. It has been found in various parts of the Green sand formation of the United States, either loosely imbedded in the soil, or engaged in marl or lignite, as at Gay Head or Martha's Vineyard, near Trenton, and also at Camden in New Jersey, and at Cape Sable, near Magothy river in Maryland. In the royal museum at Berlin there is a mass weighing- 18 Ibs. Another in the kingdom of Ava, India, is nearly as large as a child's head, and weighs 2^ Ibs. It is now fully ascertained that amber is a vegetable resin altered by fossilization. This is inferred both from its native situation with coal, or fossil wood, arid from the occurrence of insects incased in it. Of these insects, some appear evidently to have struggled after being entangled in the then viscous fluid ; and occasionally a leg or a wing is found some distance from the body, which had been detached in the effort to escape. Amber was early known to the ancients, and called rj'/EK-pov^ electrum, whence, on account of its electrical susceptibilities, we have derived the word electricity. It was named by some lyncurium, though this name was applied by Theophrastus also to a stone, probably to zircon or tourmaline, both minerals^f remarkable electrical properties. Other related resins are: COPALITE (retinite pt.) from Highgate Hill, near London; KRANTZITE, Nienburg ; WALCHOWITE, Walchow, Moravia ; AMBRITE, N. Zealand ; BATH- VILLITE, occurring in the torbanite, or Boghead coal of Bathviile, Scotland ; torbanite is related to it. SIEQBDRGITE, ^CHRAUFITE, AMBROSINE, DUXITE. XYLORETLNITE (hartine). C : H : O=40 : 64 : 4. BOMBI^CITE, C : H : O=13 : 7 : 1, in lignite in the valley of the Arno, Tuscany. LEDCOPETRITE. C : H : 0=50 : 84 : 3. Ges- terwitz, near Weissenf els. EUOSMITE. C : H : O=34 : 29 : 2, from the brown coal at Baiershoi in the Fichtelgebirge. ROSTHORNITE. C : H : O=24 : 40 : 1. In coal at Sonnberg, Carin- thia. The above species are soluble in ether. SCLERETINITE. C : H : 0=40 : 64 : 4. Insoluble in ether. Wigan, England. PYRORETINITE, JAULINGITE, REUSSINITE, GUYAQUILLITE, WHEELERITE (New Mexico), etc. Ratio of C : H=5 : 7 to 5 : 6*. MlDDLETONITE, STANEKITE, ANTHRACOXENITE. Ratio of C : H=5 : 5^ Or less. IttSOlu- able in ether or alcohol. TASMANITE and DYSODILE are remarkable in containing sulphur, replacing part of the oxygen. The ACID OXYGENATED HYDROCARBONS include Butyrellite (Bogbutter), Succinellite, Dopplerite, etc., etc. 416 DESCRIPTIVE MINEKALOGY. APPENDIX TO HYDEOCAEBOISrS. ASPHALTUM. Bitumen. Asphalt, Mineral Pitch. Bergpech, E -dpech, Oeivn. Asphaltum, or mineral pitch, is a mixture of different hydrocarbons, part of which are oxygenated. Its ordinary characters are as follows: Amorphous. G. 1-1*8 ; sometimes higher from impurities. Lustre like that of black pitch. Color brownish-black and black. Odor bitumi- nous. Melts ordinarily at 90 to 100 C., and burns with a bright flame. Soluble mostly or wholly in oil of turpentine, and partly or wholly in ether ; commonly partly in alcohol. The more solid kinds graduate into the pittasphalts or mineral tar, and through these there is a gradation to petroleum. The fluid kinds change into the solid by the loss of a vaporizable portion on exposure, and also by a process of oxidation, which consists first in a loss of hydrogen, and finally in the oxygenation of a portion of the mass. Obs. Asphaltum belongs to rocks of no particular age. The most abundant deposits are superficial. But these are generally, if not always, connected with rock deposits containing some kind of bituminous material or vegetable remains. Some of the noted localities of asphaltum are the region of the Dead Sea, or Lake Asphal- tites, on Trinidad ; at various places in S. America, as at Caxitambo, Peru ; at Berengela, Peru, not far from Arica (S.) ; in California, near the coast of St. Barbara. Also in smaller quantities, sometimes disseminated through shale, and sandstone rocks, and occasionally lime- stones, or collected in cavities or seams in these rocks ; near Matlock, Derbyshire ; Poldice mine in Cornwall ; Val de Travers, Neuchatel ; impregnating dolomite on the island of Brazza in Dalmatia ; in the Caucasus ; in gneiss and mica schist in Sweden. The following substances are closely related to asphaltum, and, like it, are mixtures of un- determined carbohydrogens. GRAHAMITE, Wurte. Resembles the preceding in its pitch-black, lustrous appearance; H. 2; G-. = 1'145. Soluble mostly in oil of turpentine ; partly in ether, naphtha, or benzole ; not at all in alcohol ; wholly in chloroform and carbon disulphide. No action with alkalies or hot nitric or hydrochloric acid. Melts only imperfectly, and with a decomposition of the surface ; but in this state the interior may be drawn into long threads. Occurs in W. Vir- ginia, about 20 m. in an air line S. of Parkersburg, filling a fissure (shrinkage fissure) in a sandstone of the Carboniferous formation ; and supposed to be, like the albertite, an inspis- sated and oxygenated petroleum. ALBERTITE, Robb. Differs from ordinary asphaltum in being only partially soluble in oil of turpentine, and hi its very imperfect fusion when heated. It has H. =1-2 ; G. =1 '097: lustre brilliant, pitch-like ; color jet-black. Softens a little in boiling water ; in the flame of a candle shows incipient fusion. According to imperfect determinations, only a trace soluble in alcohol ; 4 p. c. in ether ; 30 in oil of turpentine. Occurs filling an irregular fissure in rocks of the Subcarboniferous age (or Lower Carboniferous) in Nova Scotia, and is regarded as an inspissated and oxygenated petroleum. This and the above are very valuable in gas- making. PIAUZITE. An asphalt-like substance, remarkable for its high melting point, 315 C. II occurs slaty massive ; color brownish- or greenish-black ; thin splinters colophonite-brown by transmitted light ; streak light brown, amber-brown ; H. = 1'5 ; G.=1'220 ; 1'18G, Kenngott. It comes from a bed of brown coal at Piauze, near Neustadt in Carniola ; on Mt. Chum, neai Tiiffer in Styria WOLLONGONGITE, SilUman. Occurs in cubic blocks without lamination. Fracture broad conchoidal. Color greenish- to brownish-black. Lustre resinous. In the tute does nDt melt, but decrepitates and gives off oil and gas ; yields by dry distillation 82 '5 p. c. volatile matter Insoluble in ether or benzole. New South Wales, HTDKOCARBON COMPOUNDS. 417 MINERAL COAL The distinguishing characters of Mineral Coal are as follows : Compact massive, without crystalline structure or cleavage ; sometimes breaking with a degree of regularity, but from a jointed rather than a cleavage struc- ture. Sometimes laminated ; often faintly and delicately banded, successive layers differing slightly in lustre. H.z-05-2-5. Gr.=l-l'80. Lustre dull to' brilliant, and either earthy, resinous, or submetallic. Color black, grayish-black, brownish-black, and occasionally iridescent ; also sometimes dark brown. Opaque. Fracture eonchoidal uneven. Brittle ; rarely somewhat sectile. Without taste, except from impurities present. Insoluble or nearly so in alcohol, ether, naphtha, and benzole. Infusible to snbf usible ; but often becoming a soft, pliant, or paste-like mass when heated. On distillation most kinds afford more or less of oily and tarry substances, which are mixtures of hydrocar- bons and paraffin. Mineral coal is made up of different kinds of hydrocarbons, with perhaps In some cases free carbon. Var. The variations depend partly (1) on the amount of the volatile ingredients afforded Dn destructive destination ; or (2) on the nature of these volatile compounds, for ingredients Df similar composition may differ widely in volatility, etc. ; (3) on structure, lustre, and other physical characters. 1. ANTHRACITE. H. =2-2-5. G. =1'32- 1'7, Pennsylvania; 1'81, Rhode Island ; 1-26-1 '36, South Wales. Lustre bright, often submetallic, iron blacK. and frequently iridescent. Frac- bure eonchoidal. Volatile matter after drying 3 to 6 p. c. Burns with a feeble flame of a pale color. The anthracites of Pennsylvania contain ordinarily 85 to 93 pencent. of carbon ; those of South Wales, 88 to 95 ; of France, 80 to 83; of Saxony, 81 ; of southern Russia, some- times 94 per cent. Anthracite graduates into bituminous coal, becoming less hard, and con- baining more volatile matter ; and an intermediate variety is called free-burning anthracite. BITUMINOUS COALS (Steinkohie pt. , Germ.}. Under the head of Bituminous Coals, a number of kinds are included which differ strikingly in the action of heat, and which there- fore are of unlike constitution. They have the common characteristic of burning in the fire with a yellow, smoky flame, and giving out on distillation hydrocarbon oils or tar, and hence bhe name bituminous. The ordinary bituminous coals contain from 5 to 15 p. c. (rarely 16 or 17) of oxygen (ash excluded) ; while the so-called brown coal or lignite contains from 20 to 36 p. c., after the expulsion, at 100 C., of 15 to 36 p. c. of water. The amount of hydrogen in each is from 4 to 7 p. c. Both have usually a bright, pitchy, greasy lustre (whence often called PeohkoJde in German), a firm compact texture, are rather fragile compared with anthra- rite, and have G. 1'14-1'40. The brown coals have often a brownish-black color, whence bhe name, and more oxygen, but in these respects and others they shade into ordinary bitu- minous coals. The ordinary bituminous coal of Pennsylvania has G. =1 '26-1 '37 ; of New- castle, England, 1-27; of Scotland, 1 '27-1 '32; of France, 1 '2-1 '33; of Belgium, 1-27-1 '3. The most prominent kinds are the following: 2. CAKING C >AL. A bituminous coal which softens and becomes pasty or semi-viscid in bhe fire. This softening takes place at the temperature of incipient decomposition, and is attended with the escape of bubbles of gas. On increasing the heat, the volatile products which result from the ultimate decomposition of the softened mass are driven off, and a coherent, grayish-black, cellular, or fritted mass (coke] is left. Amount of coke left (or part not volatile) varies from GO to 85 p. c. Byerite is from Middle Park, Colorado. 3. NON-CAKING COAL. Like the preceding in all external characters, and often in ultimate composition ; but burning freely without softening or any appearance of incipient fusion. 4. CANNEL COAL (Parrot Coal). A variety of bituminous coal, and often caking ; but dii- fering from the preceding in texture, and to some extent in composition, as shown by its products on distillation. It is compact, with little or no lustre, and without any appearance of a banded structure; and it breaks with a eonchoidal fracture and smooth surfaces; coloi dull black or grayish-black. On distillation it affords, after drying, 40 to 66 ol volatile mat- fcr, and the material volatilized includes a large proportion of burning and lubricating oils, 27 418 DESCRIPTIVE MINERALOGY. much larger than the above kinds of bituminous coal ; whence it is extensively used for th( manufacture of such oils. It graduates into oil-producing coaly shales, the more compact o which it much resembles. 5. TORBANITE. A variety of cannel coal of a dark brown color, yellowish streak, withou lustre, having a subconchoidal fracture; H.=225; G. = 1-17-1 -2. Yields over GO p. c. o; volatile matter, and is used for the production of burning and lubricating oils, paraffin, ilia minating gas. From Torbane Hill, near Bathgate in Linlithgowshire, Scotland. Also calle( Boghead Cannel. 6. BROWN COAL (Braunkohle Germ.. Pechkohle pt. Germ., Lignite^ The prominen characteristics of brown coal have already been mentioned. They are non-caking, but affon a large proportion of volatile matter They are sometimes pitch-black (whence Pechkohli pt. Germ.}, but often rather dull and brownish-black. G.=l'15-l '3 ; sometimes higner fron impurities. It is occasionally somewhat lamellar in structure. Brown coal is often callec lignite. But this term is sometimes restricted to masses of coal which still retain the form o: the original wood. Jet is a black variety of brown coal, compact in texture, and taking i good polish, whence its use in jewelry. 7. EARTHY BROWN COAL (E)-dige BraunkoJile) is a brown friable material, sometimes form ing layers in beds of brown coal. But it is in general not a true coal, a considerable part o: it being soluble in ether and benzole, and often even in alcohol ; besides affording largely o: oils and paraffin on distillation. Comp. Most mineral coal consists mainly, as the best chemists now hold, of oxygenates hydrocarbons. Besides oxygenated hydrocarbons, there may also be present simple hydrocar bons (that is, containing no oxygen). Sulphur is present in nearly all coals. It is supposed to be usually combined with iron, and when the coal affords a red ash on burning, there is reason for believing this true. Bui Percy mentions a coal from New Zealand (anal. 18) which gave a peculiarly white ash although containing 2 to 3 p. c. of sulphur, a fact showing that it is present not as a sulphide of iron, but as a constituent of an organic compound. The discovery by Church of a resir containing sulphur (see TASMANITE, p. 415), gives reason for inferring that it may exist ir this coal in that state, although its presence as a constituent of other organic compounds is quite possible. The chemical relations of the different kinds of coals will be understood from the follow- ing analyses: Carbon. Hydrogen. Oxygen. Nitrogen. Sulphur. Ash. 1. Anthracite, S. Wales 92-56 338 2 '53 1-56 2. Caking Coal, Northumberland 78-69 6 -00 10-07 2 -37 1T>1 1'36 3. Non-Caking Coal, Zwickau 80'25 4 "01 1098 0'49 2-99 1-51 4. Cannel Coal, Wigan 80*07 553 8'10 2-12 1 -50 2-7C 5. Torbanite. Torbane Hill 64-02 8-90 5 "66 0'55 50 20 32 6. Brown Coal, Meissen, Sax. 58 '90 5-36 21-63 6 "61 7 '50 Coal occurs in beds, interstratified with shales, sandstones, and conglomerates, and some- times limestones, forming distinct layers, which vary from a fraction of an inch to 30 feet or more in thickness. In the United States, the anthracites occur east of the Alleghany range, in rocks that have undergone great contortions and f racturings, while the bituminous are found farther west, in rocks that have been less disturbed ; and this fact and other observa- tions have led some geologists to the view that the anthracites have lost their bitumen by the action of heat. The origin of coal is mainly vegetable, though animal life has contributed somewhat to the result. The beds were once beds of vegetation, analogous, in most respects, in mode of formation to the paat beds of modern times, yet in mode of burial often of a very different character. This vegetable origin is proved not only by the occurrence of the leaves, stems, and logs of plants in the coal, but also by the presence throughout its texture, in many cases, of the forms of the original fibres; also by the direct observation that peat is a transition state between unaltered vegetable debris and brown coal, being sometimes found passing completely into true brown coal. Peat differs from true coal in want of homo- geneity, it visibly containing vegetable fibres only partially altered ; and wherever changed to a fine-textured homogeneous material, even though hardly consolidated, it may be true brown coal. Extensive beds of mineral coal occur in Great Britain, covering 11,859 square miles; in France about 1,719 sq. m. ; in Spain about 3,408 sq. m. ; in Belgium 518 sq. m. ; in Nether- lands, Prussia, Bavaria, Austria, northern Italy, Silesia, Spain, Russia on the south near the Azof, and also in the Altai. It is found in Asia, abundantly in China, etc., etc. In the United States there are four separate coal areas. One of these areas, the Appala- chian coal field, commences on the north, in Pennsylvania and southeastern Ohio, and sweep HYDROCARBON COMPOUNDS. 419 Ing south over western Virginia and eastern Kentucky and Tennessee to the west of the Appalachians, or partly involved in their ridges, it continues to Alabama, near Tuscaloosa, where a bed of coal has been opened. It has been estimated to cover 60,000 sq. m. A sec- ond coal area (the Illinois) lies adjoining the Mississippi, and covers the larger part of Illinois, though much broken into patches, and a small northwest part of Kentucky. A third covers the central portion of Michigan, not far from 5,000 sq. m. in area. Besides these, there is a smaller coal region (a fourth) in Rhode Island. The total area of workable coal measures in the United States is about 125,000 sq. m. Out of the borders of the United States, on the northeast, commences a fifth coal area, that of Nova Scotia and New Brunswick, which covers, in connection with that of Newfoundland, 18,000 sq. m. The mines of western Pennsylvania, those of the States west, and those of Cumberland or Frostburg, Maryland, Richmond or Chesterfield, Va. , and other mines south, are bituminous. Those of eastern Pennsylvania constituting several detached areas one, the SchuylkiU coal field another, the Wyoming coal field those of Rhode Island and Massachusetts, and tome patches in Virginia, are anthracites. Cantel coal is found near Greensburg, Beaver Co., Pa., in Kenawha Co , Va., atPeytona. etc. ; also in Kentucky, Ohio, Illinois, Missouri, and Indiana ; but part of the so-called cannel is a coaly shale. Brown coal comes from coal beds more recent than those of the Carboniferous age. But much of this more recent coal is not distinguishable from other bituminous coals. The coal of Richmond, Virginia, is supposed to be of the Liassic or Triassic era ; the coal of Brora, in Sutherland, and of Gristhorpe, Yorkshire, is Oolitic in age. Cretaceous coal occurs on Van- couver Island, and Cretaceous and Tertiary coal in many places over the Rocky Mountains, where a " Lignitic formation" is very widely distributed. PART III. DESCRIPTIVE MINERALOGY. SUPPLEMENTARY CHAPTER.* ABRIACHANITE, Heddle. A soft blue clay-like substance, filling seams and cavities in granite. Probably near crocidolite (p. 298) in composition. From the Abriachan district near Loch Ness, Scotland. ADAMITE p. 373. Occurs in colorless to deep green crystals, and in mammillary groups, at the ancient mines, recently reopened, at Laurium, Greece. AGLAITE. Same as cymatolite ; that is, an alteration product of spodumene, consisting oi' an intimate mixture of albite and muscovite. From Goshen, Mass. ALASKAITE, Ko'nig. Massive. G. = 6*878. Lustre metallic. Color whitish lead-gray. Composition probably (Ag 2 ,Cu 2 ,Pb)S + Bi 2 S 3 . Analysis after deducting impurities, S 17-63, Bi 56-97, Sb 0'62, Pb 11 79, Ag 8'74, Cu 3'46, Zn 0'79 = 100. From the Alaska mine, Poughkeepsie Gulch, Colorado. SILBERWISMUTHGLANZ of Rainmelsberg, from Moro- cocha, Peru, is pure Ag 2 S -f Bi 2 S 3 . ALBITE, p. 323. Has been made artificially, identical in form and composition with natu- ral crystals, by Haute feuille. AMBLYGONITE, p. 369. Penfield has analyzed specimens from Penig, Monte bras, Hebron and Auburn, Me., Branchville, Ct. (including "hebronite" and " montebrasite "\ He shows that, while the varieties vary from F 11'26,H 2 1'75 in one sample to F 1'75, H 2 6 '61 , in another, they ail conform to the general formula: Al a P 3 B 4- 2R(F,OH), differing only in the extent to which the hydroxyl replaces the fluorine. AMPHIBOLE, p. 296. A variety containing only 0'9 p.c. MgO, has been called lergamas- Tcite by Lucchetti Occurs in a hornblende porphyry. Monte Altino, Bergamo, Italy. Phdactinite (Bertels) is a chloritic alteration product from a rock called isenite. Nassau, Germany. ANALCITE, p. 343. On the crystalline system, see p. 189. Picranalcite, of Bechi, is identical with ordinary analcite, containing only a trace of magnesia, according to Bamberger, ANIMIKITE, Wurtz. An impure massive mineral supposed to be a silver antimonide (Sb 11-18, Ag 77-58). Silver Islet, Lake Superior. ANNERODITE, Brogger. A rare columbate, almost identical with samarskite in composi- tion, but in form very near columbite. From a pegmatite vein at Annerod, near Moss, Norway. APATITE, p. 364. Large deposits of apatite, affording sometimes gigantic crystals, and sometimes mined for commercial purposes, occur in Ottawa County, Quebec, Canada ; also large crystals, with zircon, titanite and amphibole in Renfrew County, Ontario, and else- where ; there are similar deposits at Kjorrestad, Bamle, Norway. A variety from San Roque. Argentine Republic, containing 6'7 p.c. MnO, has been called mangdnapatite by Siewert. Penfield found 10'6 p.c. MnO in a bluish-green specimen from Branchville, Ct. Pseudo-hexagonal, Mallard, see p. 187. * For fuller descriptions of new species, references to original papers, etc., see Appendix III. (1882), System of Mineralogy. 420 DESCRIPTIVE MINERALOGY. 421 APOPHYLLITE, p. 340. Pseudo-tetragonal (monoclinic), according to Mallard and Rumpf, but the correctness of their conclusions is doubtful ; see p. 185 et seq. ARAGONITE, p. 405. A variety from the Austin mine, Wythe Co., Va., afforded 7 '29 p.c. PbC0 3 . ARCTOLITE, Blomstrand. A doubtful silicate, composition near prehnite, prismatic angle near hornblende. Hvitholm, near Spitzhergen. AREQUIPITE, Raimondi. A honey-yellow compact substance, supposed to be a silico-anti- monate of lead, but probably a mixture. Victoria mine, Province of Arequipa, Peru. ARFVEDSONITE, p. 298. Occurs with zircon and astrophyllite in El Paso Co., Colorado. ARRHENITE, Nordenskiold. A silico-tantalate of yttrium, erbium, etc., resembling feld- spar in appearance. Probably an uncertain decomposition product. Ytterby, Sweden. ARSENARGENTITE, Hannay. An uncertain silver arsenide of doubtful source. ASMANITE, p. 288. According to Weisbach and v. Lasaulx, identical with tridymite ; observed in the meteoric iron of Rittersgriin, Saxony. ASTROPHYLLITE, p. 313. Referred to the triclinic system by Brogger ; properly a mem- ber of the pyroxene group, not one of the true micas. Occurs with arfvedsonite and zircon in El Paso Co., Colorado. ATELINE (or atelite\ Scacchi. An alteration product of tenorite at Vesuvius ; near ata- camite in composition. ATOPITE, Nordenskiold. In isometric octahedrons. H. = 5*5-6, G. = 5 03. Color yellow to brown. Composition essentially Ca 2 Sb a 7 (near romeite). Imbedded in hedyphane at Langban, Sweden. AUTUNITE, p. 379. Monoclinic (or triclinic), according to Brezina. BALVRATDITE, Heddle. A doubtful substance having a saccharoidal structure, and pale purplish-brown color G. 2'9. An analysis gave, Si0 2 46 04, A1 2 3 20*11, Fe 2 3 2*52, MnO 0-79, MgO 8-30, CaO 13'47, Na 2 2*72, K 2 O 1'36, H 2 4-71 = 1(JO'02. In limestone atBalvraid, Inverness-shire, Scotland. BARCENITE, Mallet. An uncertain alteration product of livingstonite, massive, earthy, color dark gray. G. = 5*343. Huitzuco, Guerrero, Mexico. BARYLITE, Blomstrand. In groups of prismatic crystals. Two distinct cleavages (84). H. = 7. G. = 4;03. White. BB. infusible. A silicate of aluminum and barium (46 p.c. BaO). In limestone at Langban, Sweden. BEEGERITE, Konig. In elongated isometric crystals. Cleavage cubic. G. = 7*273. ay. Lustre metallic. Composition, 6Pbb'+ Bi,S 3 = S 14-78, Bi 21 36, Pb 63*84 = 100. From the Baltic Lode, Park Co., Colorado. Color gray. Lustre BERYL, p. 299. Pseudo-hexagonal, according to Mallard, see p. 186. A variety in short prismatic to tabular crystals has been called rosterite by Grattarola. Locality, Elba. Found (W. E. Hidden) in fine crystals of large size (to 10 inches in length), and emerald color, in Alexander Co., N. C., also in highly modified crystals of pale green color. BERZELIITE. This arsenate from Langban, Sweden, is isometric according to Sjfigren ; honey to sulphur yellow, lustre resinous. Lindgren regards the ortho-arsenate of calcium and magnesium, anisotrope, of the same locality, as distinct, and says that earlier descrip- tions of berzeliite belong to it. 422 DESCRIPTIVE MINERALOGY. BHRECKITE (or Vreckite), Heddle. A doubtful soft apple-green substance, coating quartz crystals. A hydrous silicate of alumina, iron, magnesia and lime. From the hill Ben Bhreck, Sutherland, Scotland. BISMUTOSPH^ERITE, Weisbach. Tn spherical forms, with concentric, fine fibrous radiated structure. Regarded as an anhydrous bismuth carbonate. From Neustadtel, Schneeberg, Saxony. BLOMSTRANDITE, Lindstro'm. A columbo-titanate of uranium, allied to samarskite. From Nohl, Sweden. BOLIVITE, Domeyko. An alteration product of bismuthinite, probably a mechanical mixture of Bi 2 3 and Bi 2 S 3 . Mines of Tazna, Province of Choroloque, Bolivia. BORACITE, p. 381. On the crystalline system, see p. 189. BOWLINGITE, Hannay. A soft, soapy, green substance, containing silica, alumina, iron, magnesia, lime, water ; doubtless heterogeneous. Bowling on the Clyde, Scotland. BRAVAISITE, Mallard. In fine crystalline fibres, of a grayish color, forming layers in the coal schists at Noyant, Allier Dep't, France. G. = 2-6. Analysis, Si0 2 51 -4, A1 2 3 18*9, Fe 2 3 40, CaO 2-0, MgO 3-3, K 2 6-5, H 2 13 3 = 99'4. BROOKITE, p. 277. In Mallard's view, brookite, rutile and octahedrite are all monoclinic, having the same primitive form, but differing in the way in which the individuals are grouped, see p. 186. BRUCITE, p. 281. Manganbrucite (Igelstrom) is a manganesian variety of brucite (14'16 MnO) from the manganese mines of the Jakobsberg, Wermland, Sweden. In fine granular form with hausmannite in calcite. Eisenbrucite, Sandberger. A doubtful substance resulting from the alteration of bru cite. Sieberlehn near Freiberg. CABRERITE. Occurs in crystals (isomorphous with erythrite) at the zinc mines of Lau- rium, Greece. An analysis by Damour corresponds to Ni 3 As 2 8 -\-S aq. CALAMINE, p. 329. According to Groth, the formula should be written H 2 Zn 2 Si0 5 . CALAVERITE, p. 249. Occurs at the Keystone and Mountain Lion mines, Colorado. Com- position (Genth) : (Au,Ag/Te 2 , with Au : Ag = 7 : 1. H. = 2'5. G. = 9'043. CANCRINITE, p. 317. An original species (Rauff, Koch), and not an alteration product of nephelite, the carbon dioxide being essential and not due to calcite. CARYINITE, Lundstrom. Massive, monoclinic ; two cleavages (130). H. = 3-3-5. G. = 4-25. Color, brown. Composition, R 3 As 2 0, with R = Pb,Mn,Ca,Mg. Occurs with calcite and hausmannite at Langban, Sweden. CHABAZITE, p. 344. Triclinic, according to Becke, the crystals being complex twins of several individuals. CHALCOMENITE, Des Cloizeaux and Damour. Monoclinic. / A /= 108 20'. A *- - 89 9'. G. = 3-76. Color, bright blue. Composition, CuSe0 3 + 2 aq, or a copper sele- nite. From the Cerro de Cacheuta, Mendoza, Argentine Republic. CHALCOPYRITE, p. 244. Found well crystallized, often coated with crystals of tetrahe- drite in parallel position, near Central City, Gilpin Co , Colorado. CHILDRENITE, p. 377. Formula, as shown by Penfield, R 2 A1 2 P 2 10 + 4H 2 0. or A1 2 P 2 8 + 2RH 2 + 2aq, with R = Fe principally, also Mn. This requires: P 3 6 30'80, A10 3 22'31 FeO 26-37, Mn04'87, H 2 15-65. DESCRIPTIVE MINERALOGY. 423 A mineral closely related to childrenite has been called eospliorite by Brush and E S. Dana. Orthorhombic. In prismatic crystals (see fig.), near chil- drenite. I/\I= 104 19' ; p /\p (1 A!) = 133 32' (front), = 118 58' (side). Here /, and a (i-l) = 2-1 and of childrenite. Also mass- ive, cleavable to compact. Cleavage parallel a (i-l) nearly perfect. H. 5. G. = 3 11-3145. Lustre vitreous to sub-resinous, also greasy. Color rose pink, yellowish, colorless, when compact various shades of white. Streak white. Transparent to translucent. (General formula like childrenite (see above), but with much man- ganese and little iron (10 : :j). Percentage composition : P 2 5 30-93, A1 2 3 2-2 -35, MnO 23-80, FeO 7'24, H 2 O 15-68 = 100. B. B. in the forceps cracks opens, sprouts and whitens, colors the flame pale green and fuses at 4 to a black magnetic mass. Reacts for manga- nese and iron ; is soluble in acids. Occurs with other manganesian phosphates in a vein of pegmatite at Branchvilie, Conn. CHLORALLUMINITE, Scacchi. Hydrous aluminum chloride from Vesuvius. CHLOROMAGNESITE, Scacchi. Hydrous magnesium chloride from Vesuvius. Bischofite /Ochscnius and Pfeiffer) from Leopoldshall, Prussia, has the composition MgCl 2 + 6 aq. Crystalline, massive, foliated or fibrous. Color white. Forms thin layers in halite, with kieserite and carnallite. Readily assumes water on exposure. CHLOROTHIONITE, Scacchi. Regarded as a compound salt, K 2 S0 4 + CuCl 2 , forming thin mammillary crusts of a blue color. Vesuvius. CHONDRODITE, HUMITE, CLINOHUMITE, p. 327. H. SjOgren has described humite, well crystallized, from the Ladu mine, Wermland, Sweden, and chondrodite from Kaveltorp. CHROMITE, p. 274. Not opaque, but in thin sections transmits a yellowish red color, Thoulet. Identified in meteoric irons by J. Lawrence Smith. CIIRYSOCOLLA, p. 338. Pilarite, from Chili, is an aluminous variety, 16 f 9 p.c. A1 2 3 . CHRYSOLITE, p. 300. Neochrysolite (Scacchi) is a manganesian variety from Vesuvius. A variety from Zermatt, containing 6 p.c. Ti0 2 , has been called titanolivine. CLEVEITE, Nordenskiold. A mineral closely related to uraninite, but besides uranium (and lead) contains yttrium, erbium, cerium, etc. In isometric crystals. H. 55. G. = 7'49. Color iron black. A decomposition product of a yellow color is called yttro- aummite (analogous to ordinary gummite). Occurs in feldspar at Garta, near Arendal, Norway. CLINOCROCITE, Sandberger, Singer. An imperfectly described sulphate of iron, etc., occurring in saffron-yellow microscopic crystals, derived from the decomposition of pyrite at the Bauersberg, near Bischofsheim vor der Rho'n. Clinoph&ite, from the same source, occurs in blackish green microscopic crystals; formula 5RsS0 4 -f [R 2 ]H 6 6 + 5 aq, with [R 2 ] = Fe 2 ,Al 2 , and R 2 = Fe,K 2 ,Na 2 . CLINTONITE, p. 358. On the relations of the "clintonite group" of minerals, see Tscher- mak and Sipocz, Z. Kryst., iii., 496. COLORADOITE, Genth. Massive, granular. H. 3. G. = 8-627. Lustre metallic. Color iron black. Composition HgTe = tellurium 39, mercury 61 = 100. Occurs with native tellurium, sylvanite, gold, at the Keystone, Mountain Lion, and Smuggler mines in Colorado. COLUMBITE, p. 360. Occurs sparingly in small translucent crystals at Branchvilie, Conn., having the composition MnCb 2 + MnTa 2 ; containing 15-58 pc.MnO, and 0-43 FeO. Also the ordinary variety in groups of very large, though rough, crystals, weighing some- times 50 pounds, at the same locality. Found with amazonstone at Pike's Peak, Colorado, 424 DESCRIPTIVE MINERALOGY. and in Yancey Co., N. C. Also with monazite, orthite, etc., in Amelia County, Virginia, allied in composition to the above manganesian variety from Branchville. COROXGUITE, Raimondi. An earthy, pulverulent substance of a gray to black color. Containing antimony pentoxide, lead, and silver oxides, water, but of doubtful homogeneity. District of Corongo and elsewhere in Peru. CORUNDOPHILITE, p. 358. Amesite of Shepard, from Chester, Mass., is very near corun- dophilite. CORUNDUM, p. 267. Monoclinic according to Tschermak (orthorhombic, Mallard) ; often optically biaxial. See p. 18 > et seq. Made artificially, with the colors of rubies and sapphires, by Fremy and Feil. COSALITE, p. 252. Bjelkite of H. Sjogren is identical with cosalite. From the Bjelke mine, Nordmark, Sweden. COSSYRITE, Foerstner. Near amphibole in form, but triclinic, and with I /\ I' = 114 5'. Cleavage prismatic. G. = 3 '75. Color black. An analysis gave : Si0 2 43 '55, A1 2 3 4-96, Fe 2 3 7'97, FeO, 32 -87, MnO 1-98. CuO 0'39, MgO 0'86, CaO 2 01, Na 2 5-29, K 2 0'33 = 100*21. In minute crystals weathered out of the ground mass of the liparite lavas of the Island Pantellaria (ancient name Cossyra). CBAIGTONITE, Heddle. Doubtful mineral, contains A1 2 3 , Fe 2 3 , MgO, etc. Dendritea in granite at Craigton, Aberdeenshire, Scotland. CROCOITE, p. 385. Described by B. Silliman as occurring at the Phenix and other mines in Yavapai Co., Arizona. CRYOLITE, p. 264. Observations of Krenner make cryolite monoclinic instead of triclinic. Cryolite and some related fluorides have been found (Cross and Hillebrand) in the Pike's Peak region, El Paso Co., Colorado. CUPROCALCITE, p. 411. Mechanical mixture of CaC0 3 and Cu 2 0, Damour. ^ CUSPIDINE, Scacchi. In spear-shaped monoclinic crystals ; color pale rose red. A calcium silicate containing fluorine. Vesuvius. CYANITE, p. 332. Recently found in well terminated crystals, Bauer, vom Rath. CYPRUSITE, Reinsch A supposed anhydrous iron sulphate, occurring in the western part of the island of Cyprus. Soft. Color yellow. Analysis : S0 3 21 '5, Fe 2 O 3 (A1 2 3 tr.) 51-5, insol. silica (shells of Radiolaria) 25, H 2 (hygrosc.) 2 = 100. DANALITE, p. 302. Occurs at the iron mine of Baitlett, N. H. (Wadsworth). DANBURITE, p. 311. Occurs (G. J. Brush and E. S. Dana) well crystallized and abundant at Russell, N. Y. Orthorhombic, homoeomorphous with topaz and like it in habit. I /\1 = 122 52' (topaz = 124 17'), w A w = 54 58' (topaz = 55 20'), d /\d = 97 7' (topaz = 96 6'). Common forms as in figures, w = 4-2, d = l-i, l=i-2, n = i-4, r = 2-2. Color pale wine or honey yellow, colorless. Transparent. Composition CaB 2 Si 2 8 , as of Danbury mineral. Also from the Skopi, Switzerland, in transparent crystals. DESCRIPTIVE MINERALOGY. 425 DAVREUXITE, de Koninck. In aggregates of minute acicular crystals. Color white, with tinge of red. Calculated composition : Si0 2 46 -89, A1 2 3 40'19, MnO 6-93, MgO 1 30, H 2 4'69 = 100. Occurs in quartz veins in the Ardennes schists at Ottre, Belgium. DAWSONITE, p. 410. Occurs (C'haper) in the province of Siena, Pian Castagnaio, Tuscany. Analysis gave Friedel : (|) C0 2 29 "09, A1 2 3 3589, Na 2 1913, H 2 O 12-00, MgO l'B9, CaO 0-42. DELESSITE, p. 3o6. More or less related to the chloritic delessite are : Subdelessite from the Thiiringer Walcl ; Hullite, Carnmoney Hill, near Belfast, Ireland. DESCLOIZITE, p. 367. Occurs in the Sierra de Cordoba, Argentine Republic ; perhaps also in Arizona. Composition of South American mineral (Ramrnelsberg) R 3 V 2 O 8 + RH 2 2 , with R -= Pb (56 p.c.), Zn (17 p.c.) Srac-kebuschite from Cordoba, Argentine Republic, occurs in small striated crystals. Color black. Com position perhaps R 3 V 2 8 + H 2 O, with R = Pb : Fe : Mn = 4:1:1. DESTINEZITE, Forir and Jorissen. An iron phosphate from Argenteau, Belgium ; occurs in yellowish white earthy masses. DIAMOND, p. 228. Has been made artificially, in the form of a fine sand, by J. B. Hannay. DICKINSONITE, G. J. Brush and E. S. Dana. Monoclinic, pseudo-rhombohedral, (3= 61 30 . c /\a 118 30', c /\p = 118 52', c^s = 97 58' ; c = 0,p =1, s = 2, x 3-^. Com- monly foliated to micaceous. Cleavage basal perfect. H. = 3 '5-4. G. = 3-338-3-343. Lustre vitreous, on c pearly. Color various shades of green. Composition 4R 3 P 2 8 + 3aq. with R = Mn,Fe,< a,Ka 2 , requiring: P,,0 5 40-05, FeO 12-69, MnO 25'04, CaO 11-85, Na 2 6*56, H 2 3-81 = 10 ). Occurs with eosphorite, triploidite, etc., in pegmatite at Branchville, Conn. DIETRICHITE, v. Schrockinger. A zinc-iron-manganese alum, related to mendozite, etc. A recent formation at Felsobanya, Transylvania. DOPPLERITE, p. 415. A black gelatinous hydrocarbon from a stratum of muck below a peat bed at Scranton, Penn., is called by H. C. Lewis phytocollite ; empirical formula DOUGLASITE, Ochsenius, Precht. From Douglasshall, formula, 2KCl,FeCl 2 ,2H 2 0. DUMORTIERITE, Damour, Bertrand. In minute prismatic crystals of a cobalt blue color, imbedded in gneiss. Analysis (Damour) : SiO 2 29 -85, A1 2 3 66 02, Fe 2 O 3 I'Ol, MgO 0'45, ign. 2 25 = 99-58 ; near andalusite. From the gneiss at Chaponost, near Lyons, France. DUPORTHITE, Collins. An asbestiform mineral filling fissures in serpentine. Color green- ish to brownish gray. Contains silica, alumina, iron, magnesia, and water. Duporth, St. Austell, Cornwall. DURFELDTITE, Raimondi. Massive, indistinctly fibrous. Color light gray. Metallic. Composition 3RS + Sb 2 S 3 (if the results of an analysis after deducting 31 p.c. gangue can be trusted), with R = Pb,Ag 2 ,Mn, also Fe,Cu 2 . From the Irismachay mine, Anquimarca, Peru. DYSAXALYTE, Knop. The perpfskite of the Kaiserstuhl is, according to Knop, a new columbo-titanate of calcium and iron (with also Ce,Na). EGGONITE, Schrauf. In minute, grayish-brown crystals (triclinic) near barite in habit. Supposed to be a cadmium silicate. Occurs with calamine and smithsonite at Altenberg. EKDEMITE, Nordenskiold. Massive, coarsely granular, also incrusting. Cleavage basal. H. = 2-5-3. G. 7-14. Color bright yellow to green Composition Pb 5 As. 2 O ft + 2PbCl a = As 2 3 10-59, PbO 59-67, Cl 7*58, Pb 22-16 = 100. Found at L&ngban, Sweden. 426 DESCRIPTIVE MINERALOGY. ELEONORITE, JTies. Monoclinic ; often in druses and in radiated crusts. Cleavage ortho- diagonal. H. = 3-4. Lustre vitreous. Color red brown to dark hyacinth red. Streak yellow. Composition (Streng) 2Fe 2 P 2 O 8 + Fe 2 H 6 6 +5 aq. From the Eleonore mine on the Diinsberg, near Giessen, and the Rothlaufchen mine near Waldgirmes. Perhaps identical with the iron phosphate beraunite from Benigna, Bohemia. ELLONITE, Heddle. Impure silicate of magnesia, containing Si0 2 . In gneiss near Ellon, Aberdeenshire, Scotland. ELBOQUITE, Shepard. A heterogeneous substance containing silica, alumina, iron oxide, water and (as an impurity; 32 p.c. P 2 5 . Island of Elroque, Caribbean Sea. ENYSITE, Collins. A bluish-green stalagmitic substance consisting of aluminum hydrate, basic copper sulphate, calcite, etc. St. Agnes, Cornwall. EPISTILBITE, p. 347. Monoclinic, Des Cloizeaux. Parastilbite and reissite are probably 1 A 1 " identical. EPSOMITE, p. 394. Reichardtite (Krause) is a massive variety from Stassfurt and Leo- poldshali. ERILITE, Lewis. Acicular, wool-like crystals of unknown nature occurring in a cavity in the quartz from HerkimerCo., N. Y. ERIOCHALCITE, Scacchi. Copper chloride from Vesuvius. ERYTHROZINCITE, Damour. In thin crystalline plates. Color red. Perhaps (Des Cloi- zeaux) a manganesian variety of wurtzite. EUCLASE, p. 328. Found in good crystals in the Tyrol, from the Hohe Tauern, perhaps at Kauris. EUCRASITE, Paijkull. A mineral from Brevig, Norway, near thorite. EUCRYPTITE, G. J. Brush and E. S. Dana. Hexag- onal. In regularly arranged crystals imbedded in albite (like graphic granite, see fig.) both of which have resulted from the alteration of spodumene. G. = 2 '667. Composition Li 2 Al 2 Si 2 8 = Si0 2 47*51, Al,0 3 40 61, Li 2 11 -88 - 100. Branchville, Conn. EULYTITE, p. to Bertrand. 5. Pseudo rhombohedral according ETJSYNCHITE is (Rammelsberg) 4Pb 3 V 2 8 + 3Zn 3 V 2 8 . Araoxene is 2(Pb,Zn) 3 V 2 8 + (Pb,Zn) 3 As ? 8 . Tritochorite (Frenzel) is related, composition R 3 V 2 8 , with R = Pb (54 p.c.), Cu (7 p.c.), Zn (11 p.c.). Lo- cality uncertain. FAIRFIELDTTE. G. J. Brush and E. S. Dana. Triclinic. Foliated or lamellar, crystalline; also in radiating masses, curved foliated or fibrous. Cleavage brachydiagonal perfect. Lustre pearly to subadamantine. Color white to pale straw yellow. Transparent. Com- position R 3 P 2 0* + ^aq, with R = Ca : (Mn + Fe) = 2 : 1. This requires : P 2 5 39'30, FeO 6-64. MnO 13-10, CaO 30-99, H 2 9-97 = 100. Occurs with other manganesian phosphates at Branchville, Conn. Leucomanganite (Sandberger) from Rabenstein, Bavaria, may be identical ; not yet described. FELDSPAR GROUP. Schuster has shown that in the series of triclinic feldspars there is DESCRIPTIVE MINERALOGY. 427 in optical relations the same gradual transition from the one extreme (albite) to the other (anorthite) as exists in composition. Thus, he finds that the directions of light-extinction, as observed on the basal and clinodiagonal sections, the position of the axes of elasticity, the dispersion of the axes, and the axial angle all fchow this gradual change in the same direction. These results confirm the accepted view of Tschermak that the intermediate triclinic feldspars are to be regarded as isomorphous mixtures of albite and anorthite in varying proportions ; moreover, they explain the apparent difficulties raised by the obser- vations of Des Cloizeaux (p. 319). The angles given on p. 320 are then true only in special cases, since in the varieties varying in composition these values will also vary. The values for angles (given by Schuster) made by the extinction-directions with O and i-i are as follows : With With i-i Albite -f4 to +3 +18 Varieties between Albite) 9 o < -,<> 19 o and Oligoclase f Oligoclase +2 to +1 +3 to +2 Andesite -1 to -2 -4 to -6 Labradorite -4 to -5 -17 Varieties between Labra- dorite and Anorthite.... f ~ 16 to Anorthite -38 -40 FERGTJSONITE, p. 362. New localities : Rockport, Mass. (J. L. Smith) ; Burke Co., N. C. [Hidden) ; Mitchell Co., N. C. (Shepard). FEKROTELLURITE, Genth. In delicate radiating crystalline tufts of a yellow color. Per- haps an iron tellurate. Keystone mine, Magnolia District, Colorado. FILLOWITE, G. J. Brush and E. S_ Dana. Monoclinic ; pseudo-rhombohedral. Gener- it 70 = 100. Occurs with other manganesian phosphates in pegmatite at Branchville, Conn. FLUORITE, p. 263. Pseudo-isometric, according to Mallard ; see p. 186. FORESITE, p. 347. Probably identical with stilbite. FRANKLANDITE, Reynolds. Near ulexite. Massive. White. G. = 1'65. Composition NTa 4 Ca 2 B 12 22 , 15H 2 0. Tarapaca, Peru. FREYALITE, Esmark, Damour. A silicate of cerium, thorium, etc. G. = 4-06-4-17. Color brown. From Brevig, Norway. GADOLINITE, p. 309. Contains the new earth ytterbium (Marignac), also scandium (Cleve). GALENOBISMUTITE, H. Sj5gren. Massive, compact. H. = 3-4. G. 6'88. Lustre me- tallic. Color tin white. Streak grayish black. Composition PbBi 2 S 4 or PbS + Bi 2 S 3 , requiring, S 16 '95, Bi 55 '62, Pb 27 '43 100. Occurs with bismutite at the Kogrufva, Nordmark, Sweden. GANOMALITE, Nordenskiold. Massive. H. = 4. G. = 4'98. Lustre greasy. Colorless to white or whitish gray. Transparent. Composition (Pb,Mn)Si0 3 ; analysis (Lind- strOm : Si0 2 34'55, PbO 34'89, MnO 2001, CaO 4'89, MgO 3'68, alk., ign. 1 S8=99'58. Occurs with tephroite, native lead, etc., at Langban, Sweden. GARNET, p. 302. Pseudo-isometric, according to Mallard and Bertrand, see p. 186. Nearly colorless garnets occur at Hull, Canada ; others containing 5p.c. Cr 2 3 at Wakefield, Quebec. Large perfect crystals in mica schist near Fort Wrangell, Alaska. GARNIERITE, p. 351. An allied hydrated silicate of magnesium and nickel has been found in Southern Oregon, at Piney Mountain, Cow Creek, Douglas County. 428 DESCRIPTIVE MINERALOGY. GINILSITE, Fischer. A doubtful silicate from the Ginilsalp, Graubiinden, Switzerland. GISMONDITE, p. 341. Triclinic, complex twins, according to Schrauf and v. Lasaulx. GUANAJUATITE, Fernandez, 1873. The same mineral as that afterward called frenzeli (p. 223). Composition (Mallet), Bi 2 Se 3 , with a little Se replaced by S. Sttaonite is mechanical mixture of this mineral and native bismuth. GUNNISONTTE, Clarke and Perry (Am. Chem. Journ., iv., 140). A massive substance, < a deep purple color, mixed with calcite. An analysis, after deducting 12 '75 CaC0 3 , yieldt CaF 2 74-89, CaO 11'44, Si0 2 6'87, A1 2 3 5 '95, Na 2 O'So = 100. Probably an impu fluorite ; perhaps altered ; certainly not a homogeneous mineral. GUEJARITE, Cumenge. Orthorhombic ; in prismatic crystals, form near that of chalc< stibite. H. = 3'5. G. = 5 '03. Color steel gray. Composition Cu 2 Sb 4 S 7 or Cu 2 S + 2Sb 2 S From me copper mines in the district of Guejar, Andalusia. GUMMITE. This decomposition product of uraninite occurs in considerable masses j the Flat Rock mine, Mitchell Co., N. C. GYROLTTE, p. 328. Tobermorite of Heddle, is near gyrolite and okenite. Massive. Col< pinkish white. G. = 2'423. Analysis : Si0 2 46'62, A1 2 3 3'99, F 2 3 0-66, FeO 1-08, Ca 33'98, K 2 0-57, Na 2 0'89, H 2 1211 = 99 '81. Filling cavities in rocks near Tobermor Island of Mull. HALLOYSITE, p. 352. Indianaite of Cox, is a white porcelain clay, useful in the art occurring in considerable beds in Lawrence Co., Indiana. HANNAYITE, vom Rath. In triclinic prismatic crystals. G. = 1*893. Compositic H 4 (NH 4 )Mg 3 P40 16 4- 8 aq. Occurs in guano of the Skipton Caves, Victoria. HATCHETTOLITE, J.L. Smith. Isometric, habit octahedral. H. = 5. G. = 4-77-4-90. Lust] resinous. Color yellowish brown. Translucent. Fracture conchoidal. A columbo-tai talate of uranium and calcium, containing 5 p.c. water ; closely related to pyrochlon With samarskite in the mica mines of Mitchell Co., N. C. HAYESINE. According toN. H. Barton, this borate occurs sparingly with datolite andca cite at Bergen Hill, N. J. HEDYPHANE, p. 367. A variety from Langban contains (Lindstrom) 8 p.c. BaO. Mom clinic (Des Cloizeaux), and perhaps isomorphous with caryinite, p. 422 ; this would sepi rate it from mimetite. HELDBURQITE, Liidecke. In minute tetragonal crystals, resembling guarinite. Cok yellow. H. = 6 '5. Composition unknown. In feldspar of the phonolyte of the Heldbur^ near Coburg. HELVITE, p. 302. Occurs at the mica mine near Amelia Court House, Amelia Co., Vii ginia. In crystals and crystalline masses, of a sulphur-yellow color, imbedded in orth< clase. HENWOODITE. Collins. In botryoidal globular masses, crystalline. H. = 4-4 '5. G = 2 '67. Color turquoise blue. A hydrous phosphate of aluminum and copper (7 p.< CuO). West Phenix mine, Cornwall. HERRENGRUNDITE, Brezina (= Urvolgyite, Szabo). In spherical groups of six-sided tabi lar crystals (monoclinic). Cleavage basal perfect. H. = 2 '5. G. = 3 '132. Lustre vitreoui pearly on cleavage face. Color emerald to bluish green. A hydrous basic sulphate < copper, allied to langite. From Herrengrund (= Urvolgy) in Hungary. DESCRIPTIVE MINERALOGY. 429 HESSITE, p. 228. Pseudo-isometric (triclinic) according to Becke, but the conclusion is ot beyond question. HET^ROLITE (Hetairite), G. E. Moore. In botryoidal coatings, with radiated structure. [. = 5. G. = 4 '933. Stated to be a zinc hausmannite. Occurs with chalcophanite at terling Hill, New Jersey. HEUBACHITE, Sandberger. In thin soot-like incrustations, also dendritic. Color black. i hydrous oxide of cobalt and nickel. Heubachthal, near Wittiehen, Baden. HEULANDITE, p. 347. Oryzite of Grattarola may be identical with heulMNiite. In ninute white crystals, resembling rice grains (opv^a, rice). Elba. HIBBERTITE, Heddle. A lemon-yellow powder in kammererite ; in composition probably i mixture of magnesium hydrate and calcium carbonate. From the chromite quarry in -he island of Unst, Scotland. HIERATITE, Cossa (Trans. Acad. Line., III., vi., 14). A potassium fluo-silicate, 2KF + >iF 4 , obtained in octahedral crystals from an aqueous solution of part of stalactitic concre- ions found at the fumarolesof the crater of Vulcano. The concretions have a grayish color, t spongy texture, rarely compact, and consist of hieratite, lamellae of boracic acid, with elensulphur, arsenic sulphide, etc. HOMILTTE, Paijkull. Near gadolinite and datolite in angles and habit. H. = 4 '5-5. r. = 3'34. Lustre resinous to vitreous. Color black or blackish brown. Translucent in hin splinters. Composition FeCaB 2 Si 2 Oi , or analogous to datolite. From the Stocko, lear Brevig, Norway. HOPEITE. Composition probably Zn 3 P 2 8 + 4 aq. Orthorhombic. Altenberg. HUBNERITE, p. 383. Found (Jenney) near Deadwood, Black Hills, Dakota. Also in rho- lochrosite at Adervielle, in the Hautes Pyrenees. HUNTILITE, Wurtz. An impure massive mineral from Silver Islet, Lake Superior, re- jarded as a basic silver arsenide. HYALOTEKITE, Nordenskiold. Coarsely crystalline, massive. H. = 5-5*5. Gr. = 8*81. Lustre vitreous to greasy. Color white to pearly gray. Analysis (incomplete) : SiO a 39 62, ?bO 25-30, BaO 20 66, CaO 7 '00, ign. 0-82, A1 2 3 K 2 O, etc., tr. From Langban, Sweden. HYDROCERUSSITE, NordenskiSld. A hydrous lead carbonate, occurring in white or color- ess crystalline plates on native lead at Langban, Sweden. HYDROFRANKLINITE, Rcepper. A hydrous oxide of zinc, manganese and iron, occurring n brilliant regular octahedrons, with perfect octahedral cleavage. Sterling Hill, N. J. Sever completely described. HYDROPHILITE, Adam. Calcium chloride ; see chlorocalcite, p. 260. HYDRORHODONITE, Engstrom. A hydrous silicate of manganese (MnSi0 3 + aq). Massive, crystalline. Color red brown. Langban, Sweden. ILESITE, Wuensch. In loosely adherent crystalline aggregates. Color white. Taste jitter, astringent. Composition (M. W. lies) RSO 4 + 4 aq, with R Mn : Zn : Fe = 5 : L : 1. Occurs in a siliceous gangue in Hall Valley, Park Co., Colorado. IOCOBROMITE, v. Lasaulx. Isometric, octahedral. G. = 5'713. Color sulphur yellow, sometimes greenish. Composition 2Ag(Cl,Br) -f- Agl. From the mine "Schone Aus- sicht," Dernbach, Nassau. IRON, p 226. The later investigations of the so-called meteoric iron of Ovifak, Disco 430 DESCRIPTIVE MINERALOGY. Bay, Greenland, more especially by Tornebohm and J. Lawrence Smith, leave no doubt thai it is in fact terrestrial. JAMESONITE, p. 251. Occurs in Sevier Co., Arkansas, with other ores of antimony. JAROSITE. Occurs in tabular rhombohedral crystals at the Vulture mine, Arizona (Silliman), and at the Arrow mine, Chaff ee Co., Colorado (Konig). Composition K 2 S0 4 -f Fe 2 S 3 12 + 2Fe 2 H 6 O 6 . KENTROLITE, Damour and vom Rath. In minute orthorhombic crystals, grouped ir sheaf -like forms like stilbite. H. = 5. G. 6*19. Color dark reddish brown. Compositior probably Pb 2 Mn 2 Si 2 9 . From Southern Chili. KRENNERITE, vom Rath (Bunsenin, Krenner). Orthorhombic ; in vertically striatec prismatic crystals. Color silver white to brass yellow. Lustre metallic, brilliant. A tellu ride of gold, perhaps related to calaverite. Nagyag, Transylvania. LAUTITE, Frenzel. Generally massive. H. =3-3 '5. G. = 4*96. Metallic. Color iror black. Formula given CuAsS, but very probably a mixture. Lauta, Marienberg, Saxony. LAWEENCITE, Daubree. Iron protochloride occurring in the Greenland native iron, etc, LEADHILLITE, p. 390. Susannite is very probably identical with leadhillite. LEIDYITE, Konig. In verruciform incrustations, consisting of fine scales. Color various shades of green. A hydrous silicate of aluminum, iron, magnesium, and calcium. Leiper ville, Delaware Co., Penn. LEUCITE, p. 318. Has been made artificially by Fouque and Levy ; also an iron leucit< has been made by Hautef euille ; optical character as of natural crystals. LEUCocriALCiTE, Sandbcrger. In slender, nearly white crystals. According to an imper feet description, an arsenical tagilite. Wilhelmine mine in the Spessart. LEUCOPHANTTE, p. 300. Monoclinic (Bertrand, Groth), twins analogous to those of har motome. LEUCOTILE, Hare. In irregularly grouped silky fibres of a green color. Analysis : SiO 28-98, Al a O, 6-99, Fe 9 3 8'16, MgO 29'78, CaO 7 '37, Na 2 1'32, K 2 tr., H 2 17"29 = 99'89. Reichenstein, Silesia. LIBETHENITE, p. 373. Pseudo-orthorhombic, monoclinic, according to Schrauf. LISKEAEDITE, Maskelyne. Massive, incrusting. Color white. Stated to have the compo- sition Al 6 As 2 14 ,16H 2 0. Not fully described. Liskeard, Cornwall. LIVINGSTONITE, p. 232. Composition probably Hg 2 S + 4Sb 2 S 3 . LOUISITE, Honey mann. A transparent, glassy, leek-green mineral. H. = 6 -5. G. = 2-41. Analysis (H. Louis) : Si0 2 63'74, A1 2 S 57, FeO 1 25, MnO tr., CaO 17-27, MgO 0'38, K 2 3 38, Na 2 OO-08, H,0 12-96 = 99-63. MACFARLANITE, Sibley. A name given to the complex granular silver ore of Silver Islet, Lake Superior, which has yielded the supposed huntilite. MAGNOLITE, F. A. Genth. In radiating tufts of minute acicular crystals. Color white. Lustre silky. Composition perhaps Hg 2 TeO 4 . A decomposition product of coloradoite, Keystone mine, Magnolia District, Colorado. DESCRIPTIVE MINERALOGY. 431 MALLARDITE, Carnot. In colorless cystalline fibrous masses. Composition MnS0 4 4- 7aq. From the "Lucky Boy" silver mine, Butterfield Canon, near Salt Lake, Utah. MANGANOSITE, Blomstrand. Isometric. Cleavage cubic. H. = 5-6. G. = 5'118. Lustre vitreous. Color emerald green on fresh fracture, becoming black on exposure. Composition MnO. From Langban, and from the Mossgrufva, Nordmark, Sweden. MARMAIROLITE. Hoist. In fine crystalline needles. H. = 5. G. = 3 07. Color pale yellow. Composition near enstatite, but with 6 p.c.Na 2 and 1-9 p.c. K 2 0. Langban, sweden. MATRICITE, Hoist. In crystalline masses. H. = 3-4. G. = 2 '53. Color gray. Feel Creasy. A hydrous silicate of magnesium, near villarsite, but with one molecule H 2 0. ?rom the Krangrufva, Wermland, Sweden. MELANOTEKITE, Lindstrom. Massive, cleavable. H. = 65. G. = 5 - 73. Lustre metallic ;o resinous. Color black to blackish gray. Composition Pb 2 Fe 2 Si<.0 9 (analogous to ken- brolite). With magnetite and yeilow garnet at L&ngban, Sweden. MELANOTHALLITE, Scacchi. Copper chloride from Vesuvius. MELANTERITE, p. 395. Luckite of Carnot is a variety containing 1*9 p.c. MnO. " Lucky Boy " silver mine, Butterfield Canon, near Salt Lake, Utah. MELIPHANITE, p. 300. Tetragonal according to Bertrand. MENACCANITE, p. 269. Hydroilmenite of Blomstrand is a partially altered variety, con- taining a little water. From Smaland, Sweden. MICA GROUP, pp. 311 to 315. Tschermak has shown that all the species of the mica group are monoclinic, an axis of elasticity being inclined a few degrees to the plane of cleavage ; these conclusions are confirmed by Bauer ; and von Kokscharof shows that in angle there is no sensible deviation from the orthorhombic type. Tschermak divides the species into two groups as follows : I. II. Biotites: Anomite. Meroxene, Lepidomelane. Phlogopiles : Phlogopite, Zinnwaldite. ( Lepidolite, Muscovites : < Muscovite, ( Paragonite. Margarites : Margarite. In group I. are included all the micas in which the optic axial plane is perpendicular to the plane of symmetry ; and group II. includes those in which it is parallel to the plane of symmetry. Thus, the former species biotite is divided on this principle into anomite (dvojuof, contrary to law) and meroxene (Breithaupt's name for the Vesuvian biotite). For example, the mica occurring with diopside in granular calcite at Lake Baikal is anomite, as also that from Greenwood Furnace, N. Y. Meroxene is represented by the Vesuvian magnesian mica. Muscovite includes also some of the "hydro-micas" to all of which belong the formula (H,K)oAl 2 SinO* ; plien'/ite is a name given to some muscovites approach- ing lepidolite in composition, and thus not conforming to the unisilicate type. For the full discussion of the subject, see the original memoirs of Tschermak and also those of Rammels- berg, etc , referred to in Appendix III. Haui'htonit* (Meddle), from Scotch granite, etc., is a variety of biotite, characterized by containing much FeO (to 19 p.c ) and little MgO. Siderophyttite (H. C. Lewis) from Col- orado contains all FeO (25-5 p.c.) and only a trace of magnesia. MICROLITE, p. 359 In small brilliant octahedrons, light grayish yellow to blackish brown (Nordenskiold), at Uto, Sweden. G. - 5-25. Composition Ca' 2 Ta 2 7 , with also MnO and MgO. 432 ^ DESCRIPTIVE MINERALOGY. Occurs at the mica mines of Amelia Co., Virginia (Dunnington). In modified octa- hedrons, also in large (to 4 Ibs.) imperfect crystals. G. = 5*656. Composition essentially GfcsTftsOi) with also -$ CbOF 3 . Also occurs at Branchville, Conn. (Brush and Dana). Haddamite of Shepard, from Haddam, Conn., is related, perhaps identical. MILARITE. Orthorhombic, pseudo-hexagonal. Composition HKCa 2 Al 2 Si 2 20 8 o. Origin- ally described from Val Milar, but really (Kuschel) from Val Giuf, Switzerland (giufite). MIMETITE, p. 366. According to Bertrand and Jannettaz, crystals of pure lead arsenate are biaxial ; as the amount of lead phosphate increases the angle diminishes and pure lead phosphate (pyromorphite) is uniaxial ; but this may be due to the grouping of uniaxial crystals in positions not quite parallel. Occurs with vanadinite in Yuma Co., Arizona (Silliman, Blake). MIXITE, Schrauf. Incrusting, crypto crystalline. Color emerald to bluish green. H. = 3-4. G. = 2*66. A hydrous arsenate of copper and bismuth. Joachimsthal. MOLYBDENITE, p. 233. Perhaps orthorhombic (Groth). MOLYBDOMENITE, CoBALTOMEXiTE, Bertrand (Bull. Soc. Min., v. 90). Minerals belonging to the same group of selenites as chalcomenite. Molybdomenite is a lead selenite, occur- ring in thin white lamellae, nearly transparent, orthorhombic, two cleavages. Cobaltome- nite is a cobalt selenite in minute* rose-red crystals occurring in the midst of the selenides of lead and cobalt. From Cacheuta, Argentine Republic. MONAZITE, p. 363. From Arendal, a normal phosphate (Rammelsberg) of cerium, lan- thanum and didyinium, containing no thorium nor zirconium. Pentield has proved that the thorium sometimes found is due to admixed thorite. Turnerite, according to Pisani, has the same composition. Occurs in very brilliant highly modified crystals at Milholland's Mill, Alexander Co., N. C. ; also at other localities in North Carolina (Hidden). In large masses with microlite at the mica mines of Amelia Co., Va. ; also at Portland (near Middletown) Conn. MOXETITE, C. U. Shepard and C. U. Shepard, Jr. In irregular aggregates of small tri- clinic crystals. H. 3'5. G. = 2*75. Lustre vitreous. Color pale yellowish white. Semi- transparent. Composition HCaP0 4 , requiring P 2 5 52' 20, CaO 41 '18, H 2 6'62 = 100. Occurs with gypsum and monite at the guano islands, Moneta and Mona, in the West Indies. MONITE occurs as a slightly coherent, uncrystalline, snow-white mineral. G. 21. Composition perhaps Ca 3 P 2 8 + H 2 0. MORDENITE. Steeleite of How is an altered mordenite from Cape Split, N. S. Mor- denite (How) has the composition Si0 2 68 '40, A1 2 3 12 '77, CaO 3 '46, Na 2 2'35, H 2 13-02 = 100. NAGYAGITE, p. 249. Perhaps orthorhombic (Schrauf). NATROLITE, p. 342. Monoclinic, according to Ludecke. NEOCYANITE, Scacchi. In minute tabular crystals of a blue color. Supposed to be an anhydrous copper silicate. Mt. Vesuvius. NEPHRITE, p. 297. The general subject of nephrite and jadeite in their mineralogical and archaeological relations has been exhaustively discussed by Fischer in a special work on that subject. NEWBERYITE, vom Rath. In rather large tabular orthorhombic crystals. Composition Mg 2 H a P 2 Os + 6 aq. From the guano of the Skipton Caves, Victoria, DESCRIPTIVE MINERALOGY. 433 NITROBARITE. Crystals of native barium nitrate have been obtained from Chili; in apparent octahedrons formed of the two tetrahedrons. NOCERINE, Scacchi. In white acicular crystals, perhaps rhombohedral ; regarded as a double fluoride of calcium and magnesium. From the volcanic bombs of Nocera. OCTAHEDRITE (Anatase), p. 277. Belongs to the monoclinic system, according to Mal- lard's view (see p. 186). Found in nearly colorless transparent crystals at Brindletown, Burke Co., N. C. (Hidden). ONOFRITE. A massive mineral (G. = 7 62 \ from Marysvale, Utah, has the composition Hg(S,Se), with S : Se = 6 : 1. It thus corresponds nearly with Haidinger's onofrite, which has S : Se = 4 : 1. ORPIMENT (p. 231) and realgar (p. 231) occur in Iron Co., Utah (Blake). ORTHOCLASE, p. 325. Klockmann (Z. Kryst., vi., 493) has described twins of orthoclase from the Scholzenberg, near Warmbrunn, in Silesia, the twinning planes in different cases were i-i, 0, 2-i, 24, /, *'-3. ORTHITE, p. 308. Found in imperfect bladed crystals at the mica mines in Amelia Co., Virginia, with inonazite, columbite, etc. OTTRELITE, p. 358. A variety of ottrelite from Venasque, in the Pyrenees, has been called venasquite (Damour). OXAMMITE. Ammonium oxalate (Shepard) from the Guanape Islands. Also called guana- pile by Raimondi. OZOCEEITE. A related mineral wax has been found in large quantities in Utah. PACHNOLITE, p. 265. See thomsenolite, p. 438. PECKHAMITE, J. L. Smith. From the Estherville, Emmet Co., Iowa, meteorite. In rounded nodules, with greasy lustre, and light greenish-yellow color. G. = 3 '23. Compo- sition equivalent to two molecules of enstatite and one of chrysolite. PECTOLITE, p. 327. Walkerite (Heddle) is a closely related mineral from the Corstor- phine Hill, near Edinburgh, Scotland. PELAGITE, Church. A name given to the composite manganese nodules obtained by the " Challenger" from the bottom of the Pacific. PENWITHITE, Collins. Described as a hydrated silicate of manganese (MnSi0 8 + 2 aq) from Penwith, Cornwall. PEROFSKITE, p. 270. Recent observations refer it to the orthorhombic system, the crys- tals being complex twins. Ben-Saude, however, regards it as isometric and parallel hemihedral, the observed double refraction being due to secondary causes, see p. 190. PETALITE, p. 295. Hydrocastorite is an alteration product of castorite from Elba (Grat- fcarola). PHARMACOSIDEBITE, p. 376. Pseudo-isometric, according to Bertrand, see p. 186. PHENACITE, p. 301. Obtained well crystallized from Switzerland, perhaps from Val Giuf. Also (Cross and Hillebrand) from near Pike's Peak, El Paso Co., Colorado. PHILLIPSITE, p. 345. Crystalline system monoclinic (Streng), with a higher degree of pseudo-symmetry due to twinning. 28 434 DESCRIPTIVE MINERALOGY. PHOSPHURANYLITE, G-enth. As a pulverulent incrustation, of deep lemon-yellow color Composition probably (UO 2 ) 3 P 2 O 8 + 6 an. Occurs with other uranium minerals at thi Flat Rock mine, Mitchell Co., N. C. PICITE, Nies. An amorphous, dark brown hydrous iron phosphate from the Eleonon mine and the Rothlaufchen mine, near Giessen'. Of doubtful homogeneity. PICKERINGITE, p. 395. Sonomaite (Goldsmith), from the Geysers, California, andpicroal lumogene (Roster), from Elba, are closely related minerals. PILOLITE, Heddie. A name suggested for some minerals from Scottish localities of nearl; related composition, which have gone by the names "mountain leather" and ''mountaii cork." PLAGIOCITRITE, Sandberger, Singer. A hydrous sulphate of alumina, iron, potassium sodium, etc., occurring in lemon-yellow microscopic crystals, and formed from the decom position of pyrite at the Bauersberg, near Bischofsheim vor der Rhon. PLATINUM, p. 223. A nugget weighing 104 grams, and consisting of 46 p.c. platinun and 54 p.c. chromite, was found near Plattsburgh, N. Y. (Collier). PLUMBOMANGANITE, Hannay. Described as a sulphide of manganese and lead, but doubt less a mixture. Source unknown. PLUMBOSTANNITE, Raimondi. An impure massive mineral, described as a sulph-antimo nite of tin, lead and iron, but of doubtful homogeneity. From the district of Moho, Peru POLYDYMITE, Laspeyres. Isometric, octahedral. H. = 4-5. G-. = 4'808-4'816. Com position Ni 4 S 5 . From Grlinau, Westphalia. Laspeyres regards the saynite of von Kobell grunauite of Nicol, as an impure polydymite. POLYHALITE, p. 393. Krugite (Precht) is a related mineral from New Stassfurt. Com position, if homogeneous, K 2 S0 4 + MgS0 4 + 4CaSO 4 + 2 aq. PRICETTE, p. 382. Pandermite (yom Rath) is a borate from Panderma on the Black Sea near priceite, if not identical with it. PSEUDOBKOOKITE, Koch. In thin tabular striated crystals, orthorhombic. H. = 6, G. = 4 -98. Lustre adamantine, on crystalline faces. Color dark brown to black. Con tains principally the oxides of iron and titanium. From the andesite of the Aranyer Berg Transylvania, and Riveau Grand, Monte Dore, also with the asparagus stone of Jumilla Spain '(Lewis). Near brookite. PSEUDONATROLITE, Grattarola. In minute acicular crystals. Colorless. A hydroui silicate (62 '6 p.c. Si0 2 ) of aluminum and calcium. From San Piero, Elba. PSILOMELANE, p. 282. Calvonigrite (Laspeyres) from Kalteborn is a variety. PYRITE, p. 243. Occurs in highly modified crystals in Gil pin Co., Colorado. PYROLUSITE, p. 278. According to Groth, the prismatic angle is 99 30'. PYROPHOSPHORITE, C. U. Shepard, Jr. A massive, earthy, snow-white mineral from th< West Indies. Described as a pyrophosphate of calcium and magnesium. PYRRHOTITE, p. 241. Perhaps only pseudo-hexagonal, the apparent form due to twin ning. QUARTZ, p. 284. The smoky quartz of Branchville, Conn. , contains very large quanti ties of liquid C0 a (Hawes), also N,H 2 S,S0 2 ,H 8 N,F (A. W. Wright). DESCRIPTITE MINERALOGY. 435 RALSTONITE, p. 265. Composition (Brandl) 3(Na 2 ,Mg,Ca)F 2 + 8A1 2 F 6 + 6H 2 0. RANDITE, Konig. A canary yellow incrustation on granite at Frankford, near Phila- delphia. Contains calcium and uranium, but composition doubtful. REDDINGITE, G. J. Brush and E. S. Dana. Orthorhombic ; habit octahedral ; form near that of scorodite. H. = 3-3'5. G. =3'lO. Lustre vitreous to sub-resinous. Color pale rose pink to yellowish white. Composition Mn 3 P 2 Op + 3 aq, with a varying amount of iron ;5-8 p.c.FeO). With other manganesian phosphates at Branchville, Conn. REINITE, K. v. Fritsch, Liidecke. A tetragonal iron tungstate (FeW0 4 ) near scheelite in form, and perhaps a pseudomorph. From Kimbosan, Japan. RESIN. The following are names recently given to various hydrocarbon compounds : ajkite, bernardinite, celestialite, duxite, gedanite, hofmannite, huminite, ionite, koflachite, muckite, neudorflte, phytocollite, posepnyte. RHABDOPHANE, Lettsom. A cerium phosphate, perhaps the same as phosphocerite. RHODOCHROSITE, p. 403. A Hungarian variety, containing 39 p.c. FeC0 3 , has been called maMganosiderit? (Bayer). Occurs at Branchville, Conn., containing 16*76 p.c. FeO (Penficld). RHODIZITE. According to Damour, rhodizite of Rose, from the Ural, is an alkaline boro- aluminate. Pseudo-isometric according to Bertrand. ROGERSITE, J. L. Smith. A thin mammillary crust, of a white color, on samarskite. A hydrous columbate of yttrium, etc., exact composition undetermined. Mitchell Co., N. C. ROSCOELITE, p. 367. A silicate, according to recent analyses by Genth, having the for- mula K(Mg,Fej(Al 2 ,V 2 ) 2 Si 12 32 + 4 aq ; also (Hanks) from Big Red Ravine, near Sutter's Mill, Gal. ROSELITE, p. 872. True composition R 3 As 2 8 + 2 aq (Winkler), hence analogous to fair- fieldite, p. 426. RUBISLITE, Heddle. An uncertain chloritic substance from the granite of Rubislaw, near Aberdeen, Scotland. RUTILE, p. 276. Pseudo-tetragonal according to the view of Mallard (see p. 186). Occurs in splendent crystals in Alexander Co., N. C (Hidden). SAMARSKITE, p. 361. The North Carolina mineral has been shown to contain erbium, ter- bium, phillipium, decipium (Delafontaine, Marignac). A supposed new element, mosan- drum. was also announced by Smith. Vietinghofite is a ferruginous variety from Lake Baikal, in the Ural. SARAWAKITE, Frenzel. Occurs in minute crystals in the native antimony of Borneo; perhaps senarmontite. SCAPOLITE, p. 317. The scapolites have been shown by Adams to contain chlorine (up to 2'48 p. c.) when quite unaltered. The analyses of Neminar, Sipocz, and Becke prove the same. Ontariolite (Shepard) is a variety occurring in limestone at Galway, Ontario, Canada. SOHNEEBERGITE, Brezina. In isometric octahedrons of a honey-yellow color from Schnee- berg, Tyrol. Contains lime and antimony, but exact composition unknown. SCHORLOMITE, p. 337. Theso-called schorlomite of the Kaiserstuhl is, according to Knop, either a titaniferous melanite or pyroxene. 436 DESCRIPTIVE MINERALOGY. SEMSEYITE, Krenner. Stated to be related to plagionite ; from Felsobanya. Not yet described. SENARMONTITE, p. 284. Pseudo-isometric according to Mallard (p. 186). Grosse-Bohle, who has investigated the subject, suggests the same for arsenolite. SEPIOLITE, p. 349. Chester has analyzed a fibrous variety from Utah. SERPENTINE, p. 350. Schrauf (Z. Kryst., vi., 321) has studied the magnesia silicates from the serpentine region near Budweis, Southern Bohemia. He introduces the following new names : Kelyphite, a serpentinous coating of altered crystals of pyrope ; Enophite. a chloritic variety of serpentine ; Lernilite (wrong orthography for lennilite) in composition near the vermiculite of Lenni (Cooke), hence name ; Siliciophite, a heterogeneous substance high in silica ; Hydrobiotite (same name used by Lewis) a hydrated biotite ; Berlauite, a chloritic substance filling cavities between the granite and serpentine ; Schuchardtite, the so-called chrysopraserde from Glasendorf, Silesia. He also uses the general name parachlorite for substances conforming to wA! 2 Si 3 Oi 2 -f nR 2 Si0 4 + p&q, and protochlorite for those corre- sponding to wAUSiOs 4- n(R 2 Si0 4 ) + paq. Totaigite (Heddle) is an uncertain serpentinous mineral, derived from the decomposition of malacolite. From Totaig, Rosshire, Scotland. SERPIERTTE, Des Cloizeaux. In minute tabular crystals ; orthorhombic. Color greenish. Stated to be a basic sulphate of copper (Damour). From Laurium, Greece. STDERAZOT, Silvestrl Iron nitride, a coating on lava at Etna. SIDERONATRITE, Raimondi. Sideronatrite, from Huantajaya, Peru, and urusite (Frenzel) from the island Tschleken, Caspian Sea, are hydrous sulphates of iron and sodium, near each other and related to the doubtful bartholomite. SIPYLITE, Mallet. Tetragonal, in octahedrons. Form near that of fergusonite. Cleav- age octahedral ; usually massive, crystalline. H = 6. G. = 4'89. Color brownish black tc brownish orange. Essentially a columbate of erbium, cerium, lanthanum, didymiunx uranium, etc. With allanite on the Little Friar Mt., Amherst Co., Va. SMALTITE, p. 245. Occurs near Gothic, Gunnison County, Colorado. SPH^EROCOBALTITE, Weisbach. In small spherical masses, concentric, radiated. Coloi within rose-red. H. =4. G. = 4 '02-4 13. Composition CoC0 3 . With roselite al Schneeberg, Saxony. SPODIOSITE, Tiberg. In flattened prismatic crystals. A calcium phosphate, and per haps pseudomorphous. From the Krangrufra, Wermland, Sweden. SPHALERITE, p. 237. The sphalerite from the Pierrefitte mine, Vallee Argeles, Pyrenees, contains gallium (L. de Boisbaudran), and various American (Cornwall) and Norwegiar (Wleugel) varieties afford indium. SPODUMENE, p. 295. The true composition is expressed by the formula Li 2 Al 2 Si 4 Oi 2 , as proved by numerous recent analyses. Occurs in small prismatic crystals of a deep emerald green to yellowish green color, witl beryl (emerald), rutile, monazite, etc., in Alexander Co., N. C. This variety, which ha; been extensively introduced as a gem, was called hiddenite by J. L. Smith, after W. E Hidden. The alteration products of the spodumene of Chesterfield and Gosh en, Mass., have beer described by A. A. Julien. Occurs in immense crystals at Branchville, Conn. (Brush and Dana). The unaltered min eral is of an amethystine purple color and perfectly transparent, but the crystals are mostl] altered. This alteration nas yielded (1) a substance called y^-spodumene, apparently homo geneous, but in fact an intimate mixture of albite and eucryptite (q. v. , p. 420) ; also cymatolite a mixture of albite and muscovite ; also albite alone ; muscovite ; microcline, and killinite DESCRIPTIVE MINERALOGY. 437 STAUROLITE, p. 336. Xantholite (Heddle) from near Milltown, Loch Ness, Scotland, is a jlosely related mineral. STERNBERGITE, p. 240. Argentopyrile, Argyropyrite and Frieseite are varieties, or at .east closely related minerals. They are essentially identical in form, while Streng shows ;hat the composition of the series may be expressed by the general formula Ag 2 S + STIBIANITE, Goldsmith. A doubtful decomposition product of stibnite, near stibiconite. Prom Victoria. STIBICONITE. Extensive deposits of an antimony oxide, near stibiconite, occur at Sonora, Mexico. The ore carries silver chloride. STIBNITE, p. 232. Occurs with other antimony minerals in Sevier Co., Arkansas. In groups of large splendent crystals on an island in western Japan. STILBITE, p. 346. Monoclinic, and isomorphous with harmotome and phillipsite (v. Lasaulx). STRENGITE, Nies. Orthorhombic, and isomorphous with scorodite. Generally in spherical md botryoidal aggregates. H. = 3-4. G. = 2 '87. Lustre vitreous. Color various shades of red to colorless. Composition Fe^PsOs + 4 aq. From the Eleonore mine near Seissen, the Rothliiufchen mine near Waldgirmes ; also in cavities in the dufrenite from Rockbridge Co., Va. (Konig). STRONTIANITE, p. 406. Occurs at Hamm, Westphalia, sometimes in highly modified pseudo-hexagonal crystals, resembling common forms of aragonite (Laspeyres). STUTZITE, Schrauf. A silver telluride, occurring in pseudo-hexagonal crystals of a lead sp-ay color. Named from a single specimen probably from Napyag. SZABOITE, Koch. In minute triclinic crystals, near rhodonite in form. H. = 6-7. G. = 3-505. Lustre vitreous ; sometimes tending to metallic and pearly. Color hair brown ; in very thin translucent crystals brownish red. A silicate of calcium and iron (RSi0 2 ) re- lated to babingtonite. Occurs with pseudobrookite in the andesite of the Aranyer Berg, Transylvania; Mt. Calvario, Etna ; Riveau Grand, Monte Dore. SZMIKITE, v. Schrockinger. Amorphous, stalactitic. Color whitish to reddish. Com- position MnS0 4 + H 2 0. Felsobanya, Transylvania. TALKTRIPLITE (Igelstrom). A phosphate of iron, manganese, magnesium and calcium ; probably a triplite remarkable as containing MgO (17*42 p.c.) and CaO (14-91). From Horrsjoberg in Wermland, Sweden. TANTALITE, p. 359. Occurs in North Carolina; in CoosaCo., Ala. MangantantoMte (Nordenskiold) is a manganesian variety (9 p c. MnO) from Uto, Sweden. TARAPACAITE, Raimondi. A supposed potassium chromate, occurring in bright yellow fragments in the midst of the soda nitre from Tarapaca, Peru. TAZNITE, Domeyko. Regarded as an arsenio-antimonate of bismuth, but probably a heterogeneous substance. TELLURITE. The tellurium oxide (Te0 2 ) occurs in minute prismatic, yellow to white crystals, imbedded in native tellurium ; also incrusting. Keystone, Smuggler and John Jay mines in Colorado. TELLURIUM, p. 227. An impure variety from the Mountain Lion mine, Colorado, has been called LIGNITE. 438 DESCRIPTIVE MINEKALOGY. TENNANTITE, p. 256. Fredricite (H. Sjogren) is a variety from Falu, Sweden, con- taining lead (o p.c.), tin (1'4 p.c.) and silver (-3*9 p.c.). TENORITE, p. 267. Made triclinic, on optical grounds, by Kalkowsky. TEQUESQUITE. A corruption of tequixquitl, a name used in Mexico to designate a mix- ture of different salts. TETRAHEDRITE, p. 255. Occurs near Central City, Gilpin Co., Colorado, in crystals coating chalcopyrite in parallel position. Also at Newburyport, Mass.; in Arizona (16*23 p.c. Pb). Frigidite (D'Achiardi) is a variety with 12*7 p.c. Fe, etc., from the Valle del Frigido, Apuan Alps. THAUMASITE, Nordenskiold. Massive, compact. H. 3*5. G. = 1*877. Color white. Lustre greasy, dull. Composition deduced CaSi0 3 + CaC0 3 + CaS0 4 + 14 aq, but it is very doubtful whether the material analyzed was homogeneous. THENAEDITE, p. C90. Occurs in large deposits on the Rio Verde, Arizona (Silliman). THOMSENOLITE, p. 265. According to Klein and, later, Brandl and Groth, thomsenolite and pachnolite are distinct minerals. Thomsenolite is monoclinic, ft = 89 37', and c (vert.) : b : a = 1'0877 : 1 : 9959, and has the composition (Na + Ca)F 3 + A1 2 F 6 + H 2 0. PaeJinolite is monoclinic,^ = 89 40', c (vert.) : b : a = 1-5320: 1 : 1 626, and has the compo- sition (Na + Ca)F 3 + A1 2 F 6 . Pachnolite is a cryolite with two sodium atoms replaced by one calcium atom, and thomsenolite is the same, with also one molecule of water. THOMSONITE, p. 342. Occurs in amygdules in the diabase of Grand Marais, Lake Supe- rior ; also in polished pebbles on the lake shore. The pebbles are sometimes opaque white, like porcelain ; sometimes green in color and granular (variety called lintonite) ; some- times with fibrous radiated structure, of various colors, and of great beauty. The last are valued as ornaments. THIXOLITE. Calcium carbonate, forming large tufa-like deposits in Nevada, a shore formation of the former Lake Lahontan. Regarded by King as pseudomorph after gay- lussite, but this is doubtful. THORITE, p. 340. A variety of thorite is called uranothorite by Collier ; it contains 9-96 U Z 3 . Massive. G. = 4'126. Color dark red-brown. From the Champlain iron region, N. Y. TITANITE, p. 335. Occurs, often in enormous crystals or groups of crystals, at Renfrew, Canada, with zircon (twins), apatite andamphibole. Alshedite (Blomstrand) is a variety from Smaland, Sweden, containing 2 '8 p.c. YO. Titanomorphite is a name given by v. Lasaulx to a part of the white granular aggregates surrounding rutile and menaccanite/and derived from their alteration. It is a calcium tita- nate, according to Bettendorff's analysis, but Cathrein (Z. Kryst.. vi., 244) shows that it is really a variety of titanite. Leucoxene is a name earlier (1374) given by Giimbel for a similar substance of doubtful chemical nature often observed in rocks ; according to Cathrein it is a titanite with or without a mixture of rutile microlites. TOPAZ, p. 332. Pseudo-orthorhombic (monoclinic), according to the view of Mallard (see p. 186). Occurs near Pike's Peak, El Paso Co., Colorado, and at Stoneham, Maine. TORBANITE, p. 4l8.WoUongongite (p. 416) is referred to torbanite by Liversidge ; it is from Hartley, New South Wales, not Wollongong, so that the name is inappropriate. TOURMALINE, p. 329. Pseudo-rhombohedral. according to the view of Mallard (see p. 186). Occurs in white, nearly colorless crystals, at De Kalb, St. Lawrence Co. , N. Y. DESCRIPTIVE MINERALOGY. 439 TRIDYMITE. p. 288. Pseudo-hexagonal (triclinic), according to Schuster and also v. Lasaulx. Asmanite is probably identical with it. Hautefeuille has made it artificially ; and it has been observed with zinc spinel as a result of the alteration of zinc muffles. TRIPHYLITE, p. 369. The composition (Penfield) is LiFePO 4 = Li 3 P0 4 + Fe 3 P 2 8 , with the iron replaced by manganese in part. Lithiophilite (Brush and Dana) is a variety almost free from iron (down to 4 p.c.), and corresponding to the formula LiMnP0 4 = Li 3 P0 4 + Mn 3 P 2 8 . Massive, cleavable (0, /, i-V). Color salmon, honey yellow, yellowish brown, light clove brown. Occurs with other manganesian phosphates in pegmatite, at Branch ville, Fairlield Co., Conn. TRIPLOIDITE (G. J. Brush and E. S. Dana). Monoclinic, near wagnerite in form. Gen- erally in fibrous crystalline aggregates H. =4-5-5. G. = 8 697. Lustre vitreous to greasy adamantine. Color yellowish to reddish brown, topaz yellow, hyacinth red. Trans- parent. Composition R 3 P 2 8 -+- R(OH) 2 . with R = Mn : Fe =3: 1; hence analogous to triplite, but with (OH) replacing F. With other manganesian phosphates (eosphorite, lithiophilite, etc.) from Branch ville, Conn. TRIPPKEITE, Damour and vom Rath. In small brilliant crystals, tetragonal. Color bluish green. Stated to be a hydrous arsenito of copper. \Vith olivenite in cuprite from Copiapo, Chili. TYSONITE, Allen and Comstock. Hexagonal. Cleavage basal. H. =4'5-5. G. = 6'13. Lustre vitreous to resinous. Color pale wax yellow. Composition (Ce,La,Di) 2 F 6 . From near Pike's Peak, Colorado. The crystals are mostly altered to baslnasite (also called hamartite), which is a fluo-carbonate, near parisite. URANINITE, p 274. Occurs in brilliant black octahedral crystals at Branchville, Conn. G = 9-25. Analysis: U0 3 40'08, UO 2 5451, PbO 427, FeO 0'49, H 2 -88 = 100-23. AJso from Mitchell Co., N. C. ; mostly altered to gummite. UKANOCIRCITE, Weisbach. Orthorhombic, like autunite. Cleavage basal perfect. G. = 3-53. C'olor yellow green. Composition BaU 2 P 2 J2 + 8 aq. In quartz veins, Saxon Voightland. URANOTHALLITE, Schrauf (Z. Kryst., vi., 410). A uranium carbonate from Joachims- thai, originally mentioned by Vogl. Occurs in confused aggregates of orthorhombic crys- tals. Calculated formula UC 2 6 + 2CaC0 3 + 10 aq. URANOTILE, p. 341. Occurs in Mitchell Co., N. C. Genth writes the formula, Ca 3 (U0 2 ) 6 Si 21 + 18 aq. VANADINITE, p. 367. Occurs in highly modified crystals in the State of Cordoba, Argen- tine Republic. Also in very beautiful ruby-red crystals at the Hamburg and other mines in Yuma Co., Arizona (Silliman; Blake), and in yellow to nearly white crystals at other localities in Arizona. VARISCITE. The so-called pcganite from Montgomery Co., Ark., is shown by Chester to be identical with Breithaupt's variscite. Composition A1 2 P 2 8 + 4 aq. VENERITE, Hunt. An impure chloritic mineral containing copper ; mined as copper ore at Jones' mine, near Springfield, Berks Co., Penn. VERMICTTLITE, p. 355. Protovermiculite (KGnig) and pMladelphite (Lewis) are minerals related to the other " vermiculites," the whole group being decomposition products of other micas. VESBINE, Scacchi. Forms thin yellow crusts on lava of 1631, Vesuvius ; supposed to contain a new element, vesbium. 440 DESCRIPTIVE MINERALOGY. VESUVIANITE, p. 405. Pseudo-tetragonal, according to the view of Mallard (see p. 186). A variety from Jordansmuhl contains 3 p.c. MnO (manganidocrase). VESZELYITE, p. 373. Composition, according to Schrauf, 2(Zn,Cu) 3 As208+9(Zn,Cu)H 2 02 + 9 aq, with Cu : Zu = 3 : 2, and As : P = 1 : 1. WAD, p. 283. Lepidophceite (Weisbach) is a related mineral from Kamsdorf, Thuringia. Composition stated to be CuMn 6 Oi 2 + 9 aq. WAGNERITE, p. 368. Kjerulfine has been shown to be identical with wagnerite in form and composition ; often partially altered. WALPURGITE, p. 379. Triclinic (pseudo-monoclinic), according to Weisbach. WATTEVILLITE, Singer. In minute acicular snow-white crystals. A hydrous sulphate of calcium, sodium, potassium, etc Formed from the decomposition of pyrite at the Bauersberg, near Bischofsheim vor der Rhon. WULFENITE, p. 384. Occurs in fine crystals in the Eureka district, Nevada ; also in Yuma Co., Arizona, sometimes in simple octahedral crystals (Silliman). XANTHOPHYLLITE, p. 358. Waluewite (v. Kokscharof) is a well crystallized variety from Achmatovsk, Ural. XENOTIME, p. 364. Occurs compounded with zircon in Burke Co., N. C. (Hidden). YOUNGITE, Hannay. Described as a sulphide of lead, zinc, iron and manganese, but doubtless a mixture. ZINCALUMINITE, Bertrand and Damour. In thin hexagonal plates, minute. H. =2 '5-3. G. =i 2-26. Composition 2ZnS0 4 + 4ZnH 2 2 + 3A1 2 H 6 6 + 5 aq. From the zinc mines of Laurium, Greece. ZIRCON, p. 304. Occurs in fine twin crystals (1-t, like rutile and cassiterite) with titanite and apatite, in Renfrew Co., Canada (Hidden). Also with astrophyllite and arfvedsonite in El Paso Co., Colorado. Pseudo-tetragonal, according to the view of Mallard (see p. 186). Beccarite (Grattarola) is a variety from Ceylon. APPENDIX A. SYNOPSIS OF MILLER'S SYSTEM OF CRYSTALLOGRAPHY. THE following pages contain a concise presentation of the System of Crystallography pro- posed by Prof. W. H. Miller in 1839, and now employed by a large proportion of the workers in Mineralogy. The attempt has been made to present the subject briefly, and yet with suffi- cient fulness to enable any one having some previous knowledge of Crystallography not only to understand the System, but also to use it himself. For the full development of the subject, especially of its theoretical side, reference must be made to the works of Miller, Grailich, von Lang, Schrauf and Bauerman (see the Introduction), as also to the admirable Lectures of Prof. Maskelyne, printed in the Chemical News for 1873 (vol. xxxi., 3, 13, 24,63, lUl, 111, 121, 153, 200, 232). GENERAL PRINCIPLES. The indices of Milkr and their relation to those of Naumann.The position of a plane ABC (. 751) is determined when the distances OA, OB, OC are known, which it cuts off in the assumed axes X, Y, Z from their point of intersection O. The lengths of these axes for a ningle plane of a crystal being taken as units, thus OA a, OB = b, OC c, it is found that the lengths of the corresponding lines OH, OK, OL for any other plane, IDCL, of the same crys- 442 APPENDIX. tal always bear some simple relation, expressed in whole numbers, to these assumed units This relation may be expressed as follows : OH or in the more common form _L JL h ' OH *- k OK (1) The numbers represented by 7*, &, I are called the indices of the plane and determine its position, when the elements of the crystal the lengths and mutual inclinations of the axes are known. When the lines are taken in the opposite direction from O, they are called nega- tive ; the corresponding negative character of the indices is indicated by the minus sign placed over the index, thus, #, &, or /. When the unit, or fundamental form, is appropriately chosen, the numbers representing 7i, &, I seldom exceed six. The above relation may also be written in the form : OH a OK b PL c Here ?', n, m, which are obviously the reciprocals of the indices A, k, I respectively, are itially identical with the symbols of Naumann. For example, if h = 3, k = 2, / 2, then r = , n , m = i, and the symbol (322) of Miller becomes i : $b : & but by Nau- mann' s usage this is so transformed that r = 1, and n > 1 (or sometimes n = 1, and />!), in other words, by multiplying through by 3, in this case, the symbol takes the form a : %b : fc,* or, as abbreviated, $-$ (fPf). The symbol a : $ b : \c properly belongs to the plane MNR (f. 751), which is parallel to, and hence crystallographically identical (p. 11) with the plane HKL. Special values of the indices h, k, I. It is obvious that several distinct cases are possible : (1) The three indices ^, &, I are all greater than unity, then including the various pyramidal planes. The number of similar planes corresponding to the general form -j hkl I depends upon the degree of symmetry of the crystalline system, and upon the special values of h, k, I, e.g., h = k, etc. These cases are considered later in their proper place. (2) One of the three indices may be equal to zero, indicating then that the plane is parallel to the axis correspond big to this index. Thus the symbol (MO), = a : nb : oo e, or na : b : oo e (p. 11), belongs to the planes parallel to the vertical axis (', as shown in f. 752. They are called prismatic planes. The symbol (hOl), = a : oo b : me (p. 11) belongs to the planes par- allel to the axis o, as in f. 753. The symbol (Qkl), oo a : b : me, belongs to the planes parallel to the axis , f . 754. 752 753 (3) Two of the indices may be zero, the symbol (hkl} then becomes (001), = CD a : y>b : 5, the basal plane, f. 755 ; (010), = oo a : b : ooc; and (100), a : b : x> c. These are the three diametral or pinacoid planes. The symbol (010) represents the clinopinacoid (i-l)ot the Monoclinic system, and (following Groth) the brachypinacoid (i-%) of the Orthorhombic. Similarly (MM) belongs to the orlho- * The symbol is written here in this order to correspond with the (7i k I) of Miller ; on page 10, and subsequently, the reverse order \c : %b : a was adopted for the sake of uni- formity with Naumann' s abbreviated symbols. MILLER S SYSTEM OF CRYSTALLOGRAPHY. 443 domes of the Monoclimc, and the macrodomes of the Orthorhombic system ; also (0# belongs to the clinodomes of the former, and the brachydomes of the latter. See also p. 457. Spherical Projection. If the centre of a crystal, that is, the point of intersection of the three axes, be taken as the centre of a sphere, and normals be drawn from it to the successive planes of the crystals, the points, where they meet the surface of the sphere, will be the polos of the respective planes. For example, in f. 756 the com- mon centre of the crystal and sphere is at O, the normal to the plane b meets the surface of the sphere at B, of b' at B', of d and e at D and E respectively, and so on. These poles evidently determine the position of the plane in each case. It is obvious that the pole of the plane b' (010) opposite b (010), will be at the oppo- site extremity of the diameter of the sphere, and so in general, (120) and (120), etc. It is seen also that all the poles, or normal points, of planes in the same zone, that is, planes whose intersection-lines are parallel, are in the same great circle, for instance the planes b (010), d (110), a (100), c (110), and so on. It is customary* in the use of the sphere to regard it as projected upon a horizontal plane, usually that normal to the prismatic zone, so that, as in f. 759, the prismatic planes lie in the circumference of the circle, and the other planes within it. The eye being supposed to bt- situated at the opposite extremity of the diameter of the sphere normal to this plane, the great circles then appear either as arcs of circles, or as straight lines, i. e. , diameters. It will be further obvious from f. 756 that the arc BD, between the poles of b and d, mea- sures an angle at the centre (BOD), which is the supplement of the actual interior angle bnd between the two planes. This fact, that the arc of a great circle intercepted between the poles of two planes always gives the supplement of the actual angle between the planes them- selves, is most important, and does much to facilitate the ease of calculation. In consequence of this, it is customary with many cry stall ographers to give for the angle between two planes, not the interfacial angle, but that between their normals. It is one of the great advantages of this method of projection that it may be employed to show not only the relative positions of the planes, but also those of the optic axes, and the axes of elasticity. Relation between the indices of a plane and the angle made by it with the axes. When the assumed axes are at right angles to each other they coincide with the normals to the piuacoid planes (001, 010, 100). and 757 consequently meet the spherical surface at their poles. When the axial angles are not 90, this is no longer true. In all cases, however, the following relation holds good between the cosines of the angles made by a plane with the axes : op OK = cos PY But from the equation (1) before given, by the introduction of the values of OH, OK, OL, we obtain : -f cos PX = -|- cos PY = 4- cos PZ. . (2) II K I This equation is fundamental, and many of the relations given beyond are deduced from it. It will be seen that in the case of the orthometric systems the angles PX. PY, PZ are the supplement-angles between any plane (hkl) and the pinacoids (001), (010), (100). llelations between planes in the same zone. By the use of the equation (2), it may be shown * On the construction of the spherical projection, see p. 58. 444 APPENDIX. that if two planes (hJd) and ( pgr) lie in the same zone, that the following equation must hold good : nk>l. 2. [hkk] 3. [hkk] 4. [Ill] 5. [MA] 6. [110] NAUMANN. a ma : ma h>k. .k = \ I = 0. a a : ma a a : a a na : a a a : ooa 7. [100] ; h ^ 1, k = I = 0. a a : a [m-n], [m-m]. [m].' [I]. [*']. The seven distinct forms corresponding to these symbols are as follows, taken in the same order as on pp. 14-20, where the forms are described : Cube (f. 761). Symbol [100], including the six planes (100), (010), (100), (010), (001), (001). See also the spherical projection (f. 766). 761 762 763 704 765 [100] [111] [HO] [100] [111] [100] [110] [111] Octahedron _(f. 762X Symbol [11 l],_including the eight planes taken in order shown in f. 762, (111), (111), (111), (111), (111), (111), (lilj, (111). *In general the indices of any individual plane are written (hkt), whereas the general symbol [hkl] indicates all the planes belonging to the form, varying in number in the different systems ; thus, in this system, [100] is the general symbol for the six similar planes of the cube. 448 APPENDIX. iJodewhedron (f. 763). Symbol [110], including the twelve planes, (110), (110), (110) (110), (101), (Oil), (101), (Oil), (101), (Oil), (101), (Oil). The relations between these three forms are given in full on pp. 15, 16, and need not be and (111), 109 28'. 766 Tetragonal trisoGtahedron (f. 767, 768). Symbol [kkk], with h>lc, comprising twenty-foui similar planes. Trigonal trisoctahedron (f. 769). Symbol [M/fc], with h >&, also embracing twenty-four like planes. [321] [210] [310] [321] Tetrakexahedron (f. 770. 771). Symbol [/i&Ol including twenty-four like planes. As seen on the spherical projection (f. 766), the planes of the form [MOJ lie in a zone with the dodeca- hedral planes, between two pinacoid planes. Hexoctahedron (f. 772), [hJd] . This is the most general form in the system, including the forty-eight planes enumerated on p. 447. Their position (h = 8, k = 2, I = 1) is shown on the spherical projection (f. 766). B. ffemihedral Forms* There are two kinds of hemihedral forms observed, as shown on p. 20: (1) tbehemiholo. liedral, where half the quadrants have the whole number of planes ; and (2) the holohemihedral where all the quadrants have half the full number of planes. The first kind produces inclined hemihedrons, indicated by the symbol K\hJd], and the second kind produces parnUd hemihe- drone, indicated by the symbol K[hkt\. The resulting forms in the several oases are as follows MILLER'S SYSTEM OF CRYSTALLOGRAPHY. 449 INCLINED HEMIHEDRISM. Tetrahedron^ (1). _ (f. 773) includes the four planes (111), (111), (111), (111), includes the planes (111), (111), (111), (111). Symbol [111]. The plus tetrahedron The minus tetrahedon (f . 774) 773 774 [121] /c[321] Hemi-fr'isoctahedrons. The symbol K[7tkk] denotes the solid shown in f. 775, and K\hM\ the solid shown in f . 776. They are the hemihedral forms of the tetragonal and trigonal trisoctahedrona respectively. Hemi-hexoctahedron. The same kind of hemihedrism applied to the hexoctahedron pro- duces the form shown in f. 777, having the general symbol n[hkl\. Inclined hemihedrism as applied to the three other solids of this system produces forms in no way different, in outward appearance, from the holohedral forms. PARALLEL HEMIHEDRISM produces distinct, independent, forms only in the case of the tetrahexahedron and the hexoctahedron. The symbol of the former is v [MO], and of the latter, ir[hkf\ ; they are shown in f. 778-782. 778 779 780 781 7T[210] 7T[210] 7T[120] [210] [100] 77 [321] Tetartohedral forms of several kinds are possible in this system, but they are of small practical interest. MatJiematical Relations of the Isometric System. (1) The distance of the pole of any plane P(hkl) from the cubic (or pinacoid) planes is given by the following equations. These are derived from equation (2), p. 443. Here PX(=PA) is the distance between (hkl) and (100) ; PY(=PB) is the distance between (hkl) and (010) ; ar.d PZ(:=PC) that between (hkl) and (001). The following equations admit of much simplification in special cases, for (MO), (hhk), etc. cos 3 PA = + I* ' cos 2 PB = /j2 4. 2 + 1-2 ' cos 2 PC = (2) The distance between the poles of any two planes (hkl) and (pqr) is given by the fol- lowing equation, which in special cases may also be more or less simplified : ty + kq+lr cosPQ- (3) Calculation of the values of h, k, I, for the several forms. (a) Tetragonal trisoctdh* dron (f. 767). B and are the supplement angles of the edges as lettered in the figure. cosB=: cosC = 2hk + 29 450 APPENDIX. For the hemihedral form (f . 775), cos B = ~ fit ~7~ &K (b) Trigonal trisoctaJiedron. The angles A and C are, as before, the supplements of the iiiterf acial angles of the edges lettered as in f . 769. W + 2hk 27i 8 - k 3 For the hemihedral form (f. 776), cos B = L TetrdhexaTiedron (L 770), A* 2hk For the hemihedral form (f. 778), cos A* = Eexoctcihedron (f. 772). A - - A = 08 B = 8 c = For the hemihedral fonn /t[A] (f. 777), cos B' = n,,, m+m For ^[A*q, cos A =. .i cos C = For planes lying in the same zone the methods of calculation given on p. 444 and p. 440 are made use of. In many cases, however, the simplest method of solution of a given prob- lem is by means of the spherical triangles on the projection (f. 766). IL TETRAGONAL SYSTEM. In the Tetragonal System, since the vertical axis c has a different length from the two equal lateral axes, the index , referring to it, is never exchangeable for the other indices, h and k. The general form [hkl] consequently embraces all the planes which have as their symbols the different arrangements of A, k, 1, in which I always holds the Last place. We thus obtain ! jiu iiU m hki m m m km m m m m m m m w A. Hohhedral Forms. According to the values of #, ^, and I in this general form (h = 0, k =h, etc.), different cases may arise. By this means we obtain a list of all the possible distinct holohedral forma in this system. They are analogous to those of the Isometric System. MILLER. NAUMANN. 1. [hkl\\ h>k. a 2. \m\ ; h = k. a 3. [hOl] ; h or k = 0. a 4. [MO]; h>k, 1 = 0. a 5. [110]; h = k = l, 1 = 0. a 6. [100] ; k = 0, I = 0. a 7. [001] ; h = k = 0. na : me [m-n] a : mo [m]. co a : mo [m-i]. na:ccc a : c [/]. ooarooc [*-]. MILLER'S SYSTEM OF CRYSTALLOGRAPHY. 451 The forms answering to these general symbols (compare f . 790) are as follows : Based planes, Symbol [001], including the planes (001) and (001). Prisms. (a) Diametral prism, or_that of the second series (f. 783). Symbol [100], in sluding the four planes (100), (010), (100), (010). (b) Unit prism, or prism of the first series (f. 784). Symbol [110], embracing the foui planes (110). (110), (110), (110). The relation of these two prisms is shown on p. 26. (c) Octagonal prism (f. 785). Symbol [hkQ], including the eight planes (MO), (MO), (AO). (MO), (MO), (MO), (MO), (MO). Octahedrons or Pyramids. There are two series of octahedral planes, corresponding to the two square prisms, (a) Octahedrons of the second, or diametral series. Symbol [hQl] , in- cluding eight similar planes. The form [101] is shown in f. 786. (b) Octahedrons of the first, or unit series. Symbol [MZ], embracing eight similar planes. The form [111] is shown in f. 787. 784 785 T ^* 12 ^ 1/2 i i T ; |/2 | ^^ i-- 1 i .. "* [100] [001] [110] [210] [101] [111] Octagonal Pyramids. The general symbol [hkl] embraces, as already shown, sixteen like planes, whioh together form the octagonal pyramid shown in f . 788. 788 789 Meionite. The relations of the various tetragonal forms will be understood by reference to f. 790, showing the projection for the crystal represented in f. 789. B. Hemihedral Forms. Among the hemihedral forms there are to be distinguished three classes, us shown on p. 28 et seq. .1. Sphenoidal hemihedrons, corresponding to the inclined hemihedrons of the isometric system. They are indicated by the symbol ^[hkl]. The sphenoid 7r[lll] is shown in f. 791. 2. Pyramidal hemihedrons, that is, those which are hemiholohedral, and vertically direct. These are indicated by the symbol x\kkX\. 3. Trapezoidal hemihedrons, hemiholohedral like those just mentioned, but' vertically alternate. They have the symbol " 791 452 APPENDIX. Mathematical Relations of the Tetragonal System. (1) The distances of the pole of any plane P(hkl) from the pinacoid planes 100 (= PA), 010 = PB), 001 (= PC) are given by the following equations: c08 ' PA = AV+W+W ; cos ' PB = ; 08 ' PC = These may also be expressed in the form : (2) For the distance between the poles of any two planes (hkl), (pqr), we have in general : cosPQ= hpc* + kqc? + lra* The above equations take a simpler form for special cases often occurring. (3) Planes in the same zone. For the general case of planes (hkl) and (pqr) the re lation given in equation 4 (p. 446) is made use of. In the special cases, practically of the most importance, where the planes lie in a zone with a pinacoid plane, the simplified formula* are employed. For the octagonal prism this relation becomes : tan (100) (MO) = cot (010) (7*&0) = -|. Determination of the axis c. This follows from equation (1), p. 446, which, for this case , becomes : \ cos PA = -. cos PC, (a = 1). fl L For an octahedron (hW) in the diametral series, we have : tan (Ml) (001) = y. For the unit octahedron (111), we have : tan (111) (001). cos 45 = c. ILL HEXAGONAL SYSTEM. The Hexagonal System and its hemihedral, or rhombohedral, division are both included by Miller in his RHOMBOHEDRAL SYSTEM (see p. 462). All hexagonal and rhombohedral forma are referred by him to three equal axes, oblique to one another, and normal to the faces of the unit rhombohedron. This method has the great disadvantage of failing to exhibit the hexagonal symmetry existing in the holohedral forms, since in this way the similar planes of a hexagonal pyramid receive two different sets of symbols, having no apparent connection with each other. It, moreover, hides the relation between this system and the tetragonal system, which, optically, are identical, since they possess alike one axis of optical symmetry. The latter difficulty was avoided by Schrauf, who introduced the ORTHOHEXAGONAL SYS- TEM. In this the optical axis was made the crystallographical vertical axis, and otherwise two lateral axes, at right angles to each other, were assumed, a and a V3. This method, how- ever, does not overcome the other objection named above. In the method of Weiss and Naumann a vertical axis, coinciding with the optical axis, was adopted, and three lateral axes in a plane at right angles to it, they intersecting at angles of 60, corresponding to the planes of symmetry in the holohedral forms (see p. 462). In this way only can the symmetry of the hexagonal forms be clearly brought out, and at the same MILLER'S SYSTEM OF CRYSTALLOGRAPHY. 453 792 time the relation between the hexagonal and tetragonal systems exhibited. Recently Groth (Tsch. Min. Mitth., 1874, 223, and Phys. Kryst., 1876, p. 252) has shown that the complete symbols of Weiss and Naumann could be translated into a reciprocal, integral form after the manner of Miller. The symbols then obtained, as was also shown, admit of a like con- venient use in calculation. Essentially the same method was proposed in 1800 by Bravais, and his suggestion is followed here; the more important equations, expressing the relations between the poles of the planes, their indices, and the axes of the crystal are also added. They are given somewhat in detail, since they are not included in any of the works on Miller's System before referred to. All hexagonal forms are referred to a vertical axis, e, and three equal lateral axes in a plane at right angles to it, intersecting at angles of 60 and 120 (f. 792). The general symbol for a plane in this system is (hkli), where it is always true that the alge- braic sum of h, k, I is zero, that is, h + k + I = 0. The indices here are the reciprocals of those of Naumann, except that the index I has the opposite sign, and the order of two of the indices is inverted. According to him the general symbol of any plane is m-n (=mPri), or, in full, - a : a : na : me. Thus the plane 3-| (3P|) has the full symbol, 3a : a : \a : 3c, or to correspond with the other symbols it must be written, '3a : \a : a : 3c. The reciprocals of the latter indices are : f : 1 : , or, reduced to integers (and changing the sign of I) (1231), which is the symbol according to the plan here fol- lowed. Similarly the plane (2243) gives, on taking the reciprocals, \a : \a, : %a : $c, which is equivalent to 2a : 2a : a : ^c, or in Naumann's abbreviated form f { -2 (=^P2). It is the great advantage of this method that it makes it possible to change the almost uni- versally adopted symbols of Weiss and Naumann into a form which allow of all the readiness of calculation and the appli- cation to the spherical projection which are the characteristics of Miller's System. In calculations, both by zone equations and other methods, only two of the indices h, k, or I of the form (hkli) need be employed, with the remaining index i (re- ferring to the vertical axis). This is ob- viously true, since the three indices named are connected by the equation h + k + I 0. Disregarding, then, in calculation the third index I, as shown beyond, the planes are referred to two equal lateral axes, intersecting at an angle of 120, and a third vertical axis c. The symbol [hkli] in its more gen- eral form embraces twenty-four planes, as is evident from an inspection of the spherical projection, f. 793. Here h, k y I are of equal value and mutually exchange- able, with the condition, however, that their algebraic sum shall always equal zero. Of the twenty -four planes of the dihexagonal pyramid, the following are those of the upper quadrants mentioned in order from left to right around the circle (f . 793). Those below have the same symbols, except that the index i in each case is minus : on (hkli) (hkli) (Wei) (hlki) (klU) (klhi) (Ikhi) (Ikhi) (Ihki) (khli) (khh) In this general form [hkli] the following special cases are possible, each one giving rise to an independent form or group of forms, as seen below : 454: APPENDIX. BRAVAIS-MILLEB. NAUMANN.' [hkli] [7ih2h2i] [1122] ; [Ohhi] : [0111] ; [1120] ; [0110] ; [0001] ; a = 0, 7i = k = l.\ 1=2 = 0, k = 0, h = 1 .-. J =1 h = k = I = 0. -- : na : a : mo n-l [m-n] 2a :2a : a :mc [m-2] 2a :2a : a : c [1-2] oo a : a : a : mo [m] ooa : a : a : c [1] n r a : na : a : oo c r-7fci n-l 2a :2a a : oo c [*] aa : a : a : ccc M a : oo a : oo a : o [0] A. HoloJiedral Forms. The forms to which these symbols belong have been already mentioned on pp. 32-34. They may be briefly recapitulated here. They are taken in the reverse order from that given in the table. Basal virtues. Symbol (0001) and (0001). Prisms. -,a) The unit prism (/). General symbol [0110], including (sf j e f. 793. 794) the six planes with the following symbols: (0110), (1100), (1010), (0110), (1100), (1010). (b) The diagonal prism (i-2). General symbol [1120], including (f. 793, 795) the follow- ing six planes : (1120), (1210), (2110), (1120), (1210), (2110). (c) The dihexagonal prism (i-n). General symbol [AHO], embracing the following twelve planes mentioned in order : (ftH, (MO), (MO), (77^0), (ZfcfcO), (MZO), (ABO), (7tM), (*Z&0), (ZMO), (ZMO), (MJO). Hexagonal pyramids, or Quartzoids. (a) The pyramids of the first or unit series. General symbol [Qhhi] embracing twelve_ similar planes. All the pyramids of this series lie in a zone between the unit prism [0110] and the base [0001]. A special case of this is when A = k = i = 1. The planes of this form (f. 796) are shown on the projection, f. 793. 794 795 [0110] [1120] [0111] [AtiQ (b) Pyramids of the second, or diagonal series. General symbol [h7i2h2i], including twel ye planes, analogous to those of the pyramid unit series. All the pyramids of this series lie in a zone between the diagonal prism, whose general symbol is [1120], and the basal plane [0001]. Twelve-sided pyramids, or Berylloids (f. 797). General symbol [hkli\, including the twenty- four planes enumerated on p. 453. * The order of the terms in the symbols below is made to correspond to that of the indices MILLER S SYSTEM OF CRYSTALLOGRAPHY. 455 798 B. Hemihedral Farms. The most important of the hemihedral forms in this system are as follows : 1. PYRAMIDAL hemihedrism. This comes under the head of holohemihedral forms, which are vertically direct (see pp. 34, 35). It is indicated like the corresponding hemihedrism in the tetragonal system v[hkli\. It is common on apatite. 2. RHOMBOKEDRAL hemihedrism. These included here are hemiholohedral, and vertically alternate. They are indicated in general by K\Jikli\. This class is import- ant, since it embraces the RHOMBOHEDRAL DIVISION. (a) Rhoiribohedrom. Symbol x[Qhhi\ ; the unit, or fundamental rhombohedron (+-K, f. 798) has the symbol K[0111], including^ the six planes: (0)11), (1011), (1101), (1011), (1101), (0111). The negative rhombohe- dron ( 7?, f . 799) includes the planes: (1101), (0111), (lOli), (0111), (1011), (.1101). (b) Scalenoltedrons (f. 800). Symbol K\hkU\. 3. GYROIDAL, or trapezohedral hemihedrism. The forms here included are holohemihedral, and vertically alternate. They are indicated by K" [hkli] . see p. 39. 4. TETRATOHEDRISM. This may be (1) rJiombohedral, indicated by mr[hkli] \ or (2) traptzohedral (sryroidal), as common on quartz, having the gen* eral symbol Mathematical Relations of the Hexagonal System. In the Hexagonal System, as has been explained, the symbol in general has the form [hkli] . where the algebraic sum of li , h, and I is zero. This general symbol has four in- dices, referring respectively to the three equal lateral axes and the vertical axis, as shown in f. 792, thus showing the fundamental hexagonal symmetry of the forms. Since, however, the position of a plane is known by its intersection with three axes aione, two of the three indices 7i, &, I are all that are needed in calculation, the third, , being a function, as given above, of h and k. The mathematical relations of the planes in this system are brought out by referring them to three axes, viz., two equal lateral axes //, K, (= a = \) oblique (120 and 60) to one another, and a third axis (c) of unequal length perpendicular to their plane. This applies also to the calculation by zonal equations. The indices (u, v, w) of the zone in which the planes (hldi), (pqrt) lie, are given by the scheme : h k i h k XXX p q t p q u = let qi v = ip ht w = hq kp. (1) The distances (see f . 793) of the pole of any plane (hkli) from the poles of the plane* (1010), (0110), (1100), and (0001) are given by the following equations: cos PA = cos (1010) = hk)' cos PB = ooa (OtlO) = oo. PC = ooa (UK) (0001) = 456 APPENDIX. (2) The distance (PQ) between the poles of any two planes (hkli) and (pqrt) is giveu by tht equation : cos po = 8ft + 2?(hq + pk + 2hp + 2kq} 4#(A a + k* + hkj\ [3 a + 4c 2 (p a + q* + pq)}' (3) For special cases the above formula becomes simplified ; it serves to give the value oi the normal angles for the several forms in the system. They are as follows : (a) Hexagonal Pyramid [0/i/w], f. 790, Si 2 + 2/A;* 47*^* - S* 2 cos X (terminal) = ^ + ^ J cos Z < basal ) = w For the hexagonal pyramids of the second series [Qh2h2l] the angles have the same value. (&) Dihexagonal Pyramid \hkli], cos X fsee f 7W - cos X (see f. 797) _ cos Y (see f . 797) = 4c(A a + ** cos Z (basal) = (f) Dihexagonal Prism [A*20], A 8 + A ! + 4A* oosX(ax la l) = - cos Y Rhombohedron () Scalenohedron K[7Mi\, St 8 + W(2k* + 27ik - ?*) cos Y (see f . 800; = -^77 - . ,, /7 . - j-. - rrr. Si- + 4c*(A s + k 2 + hk) r, n. n cos Z (basal) = (4) Relations of planes in a zone. The general equation (3, p. 446) is to be employed. For the pyramidal zones passing through the pole (0001) it takes a simpler form, viz. : h L __k = i tan PC p ~ q~ t 'tan QC* If Q = (0111), then : tan_PC_,& tanQC" ' Determination of the axis c. The value of c may be determined from any one of the equations which have beer: given. The following are simple cases : tan (Mi 27i 2i) (0001) = ^. Also tan (QhJii) (0001) . sin 60 = ^, or tan (0111) (0001) . sin 60 = i. MILLER'S SYSTEM OF CRYSTALLOGRAPHY. 457 IV. ORTHORHOMBIC SYSTEM. The Orthorhombic System is characterized by three unequal rectangular axes c I tL* hP indices h k I may be either plus or minus, in the general form [hkl], but they are not JShJ^ftblo; B^fcey refer to axes of different lengths. This general symbol then embraces .he following planes : (hkl) (hkl) (Ml) (Ml) hkl As different values are given to h, k, I, this general form becomes more or less specialized. The possible forms are as follows : 1. 2. 3. 4. 5. 6. 7. ( [hM] ; \ \kM] ; ( [hhl] ; [hW] ; ([hkQ]', UMOJ; (lllO] ; [100] ; [010] ; [001] ; h h h I I h k h > k. 0. 0, 0, k I h>Jc. h > k. = 1, 1 = 0. = 0. = 0. & : nb nd:_b: & \ b 11 & : oo5 me me 1C me ooc : ooc d:nb nti'^l A : b :_ooc (t : ccb : ooc 00$ : b : ooc cod : oo& : c [w-w] [m-n [m]. [m-l]. [m-*]. [ill [a]. [0]. These symbols belong to the various distinct forms of this system, as follows : Pinactids (a) Basal plane. Symbol [001], including the two planes (001) and 001). (b) Macropinaeoid. Symbol [100], including the plane [100], and [100] opposite to it. (c) Srachypinacoid. Symbol [010], including the planes [010] and [010]. Prisms,-(a) Unit prism (/). Symbol 110, including four planes, (110), (110), (HO), (110). (b) Macrodiagonal and brachydiagonal prisms, having respectively the symbols [JM] and [MO], if h is greater than k. Thus the symbol i-2 corresponds to [210], and i-2 to [120]. Domes. (a) Macrodiagonal, or macro- domes, having the symbol [hW] ; and (b) brachydiagonal, or brachydomes, with the symbol [Qkl]. In each case the symbol embraces four similar planes. Octahedrons or Pyramids. Tine sym- bol [hhl] belongs to the eight planes of the unit pyramids, all lying in the zone be- tween the unit prism [110], and the base [001]. If h = I the form is then [111], and the eight planes are : (111), (111), (111), (111), (111), (HI), (HI), (111)- Of the general pyramids two cases are possible, either [hkl] or [khl], when h>k, these correspond respectively to the prisms [hkO] and [MO]. They are the macrodiagonal and brachydiagonal pyra- mids of Naumann ; thus 2-2 (= ft: 26 : 2c) is [211], according to Miller, and 2-2 (= 2df : b : 2b) is [121]. * The same lettering is employed here as in the early part of this work ; it differs from that of Miller in that with him a is the macrodiagonal, and b the brachydiagonal axis Following Groth, and later writers (Bauerman, etc.), the macropmacoid has the symbol (100\ and the brachypinacoid the symbol (010) ; similarly the macrodomes are m general ()l)', wod the brachydomes (Qkl). 110 458 APPENDIX. For the figures of the above-mentioned forms see pp. 42-44. Their relations will be under- stood from an examination of f. 801, showing the projection of the crystals in f . 758, p. 444. It will be seen that all the macrodiagonal planes lie between the zonal circles (diameters) (110) (001), and (100) (001), and the brachydiagonal planes between (110) (001; and (010) (001). Mathematical Relations of the Orthorhomlic System. (1) For the distance between the pole of any plane P (Ml) and the pinacoid planes we have in general : cos' PA = cos' PB = cos' (W) (010) = >w + cos* PC = cos' (Ml) (001) = (2) For the distance (PQ) between the poles of any two planes (hkl) and (pqr) : cosPQ= (3) For planes lying in a zone, the general relation (p. 446) is to be employed. For the " 5 simplified equations which follow a general equation may be employed : \vj A'ui jjiiiic -ijiug iii a. ziuiie, ilia general reiaiiiuji special cases, practically of most importance, the simplified equations which follow are used, (4) To determine the lengths of the axes, the genera' ~ cos PA = 4 cos PB = 4 cos PC. h lc I Here PA, PB, PC are the distances from the pole of any plane (hJcl) to the pinacoid planes (100), (010), (001) respectively. The brachydiagonal axis* a, is made the unit. If the angle between any dome or prism and the adjoining pinacoid plane is given, the relations follow immediately : tan PA = tan (MO) (100) = ~ oh tan PB = tan (OJcl) (010) = ^ CK tan PC = tan (hQl) (001) = V. MONOCLINIC SYSTEM. In the Monoclinic System there are three unequal axes, and one of these makes an oblique angle with a second. The axes are lettered as uhown in f. 802, QQO c is vertical, b the orthodiagonal axis, and d the clinodiagonal axis oblique to , but at right angles to b. The symbol [h/d,] embraces only four similar planes in the most general case, for ^90 i n consequence of the obliquity of one of the axes, the quajranta above in front correspond alone to those below and behind, and those above behind correspond to those below in front. This is / $ seen clearly in the projection of f. 803. For h, k, 1 the symbol [hid} includes two distinct forms, viz. : (1) (hkf) (Wei) (hkl) (7wB) and (2) (hkl) (hkl} (hkf) (JM, The various forms are as follows : MILLER'S SYSTEM OF CRYSTALLOGRAPHY. 459 Pinacoids. Base [001]. Orthopinacoid [100]. Clinopinacoid [010]. Each symbol, of xmrse, comprehending two planes only. 80i Crocoite. Prisms.-(a) Unit prism [110], = d : b : oo c (I) of Naumann. This symbol embraces four similar prismatic planes, (b) Orthodiagonal prisms &*>}<"*** h f >*' ^ThW^es^nd prisms fall on the prismatic zonal circle between 100 and 110 (see f 803). Th ^*f. d to the prisms i-n = d : nb : *c) of Naumann. (c) Clinodiagonal prisms. ^ol [MO], h > k lyimr between (110) and (010). They correspond to i-n (= nd : b: oo c) of ISaumann. Lorn is -(a) Hemi-orthodomes, including two cases, (101) _and (10h|, the minus *?\* Naumann (opposite the obtuse angle) ; and also (101) and (101)), the plus domes of Naumann (opposite thfacute angle ft), (b) Clinodomes. Symbol [OAQ. e mbracmg our sim lar pi anes \0kl) (OH), (0/W), (OH). The clinodome [Oil], equivalent to 1-* (=00 d : b : me}, is ox pa:-The pyramids are all hemi-pyramids. (a) The symbol [^includes theunit pyf/mids in a zone between [110] and [001]. (b) The symbol [M*\ includes two sets of hemi- pyramids, whose indices have been given on p. 416, corresponding respectively to - + ff h i^SteTthan k these are orthodiagonal pyramids, corresponding to (d: J 1 ^^ Naumann. The symbol [Ml] on the same supposition includes two sets of planes, like those of p. 458, and differing only in being ^^^JJ?^^* % ( ^ ^0^ whL the^Hno- The orthodiagonal planes lie between the zone (100), (001) and (110), (^>JJJf !?VPS tha diagonal are between the latter zone and (010) (001), as is seen on f. 803, which gives projection for f. 804. Mathematical Relations for the Mbnoclinic System. (1) The distances of the pole of any plane (hM) from the pinacoid planes are given by the ing equations : Tile + lab cos )8 __ t following equations : cos PA = cos (AM) (100) = o cos cos PB = cos (hid) (010) = cos PC = coa (hkl) (001^ = 27 kac sin )3 lab + hbc cos 3 ____ + 2hlaVc cos/3 * 460 APPENDIX. (2) The distance between any two planes may be expressed ia general form, but in all practically arising cases the end can be attained by the solution of one or more spherical tri- angles on the projection. (3) For the relation between the planes in a zone the general equation before given holds good: cot PS -cot PR _ (PQ) . (SB) cot PQ - cot PR (QR) . (PS)* (4) For all zones passing through the clinopinacoid (010), the value of PR may be taken aa 90, and the above equation consequently simplified : tanPB l p q tan QB r This equation is especially valuable for determining the indices of planes in the prismatic and clinodome series. (5) To determine the axial relations the general equation admits of being transformed so aa to read : h sin PYA _ p sin QYA _ a T* sin PYC ~ 7" ' sinQYC~T' *_ sinpYA _ 9_ s I ' cotPY ~ r ' cotQY " c' The angles PYA, PYC are angles which may be calculated directly by spherical triangles from the measured angles. Similarly for QYA, QYC. PY and QY are the angles betweer the given plane P or Q with the clinopinacoid. VL TRICLINIC SYSTEM. In the Triclinic System, since the axes are unequal and all mutually oblique, there can be no plane of symmetry, and there can in no case be more than two planes included in a single form. The three axes are distinguished as a vertical, c, a longer lateral, or macrodiagonal axis, b, and a shorter lateral, or brachydiagonal axis, a. The position assumed for the axea is shown in f. 259, p. 80. The general symbol \hJd\ , which includes eight similar planes in the orthorhombic system, is here resolved into four independent forms, embracing two opposite planes only. They are thus : i9\ W (^ (**$ (A.\ (2) (Tiki) < 3) (MO (4) These correspond respectively to rri?'n (1), m'Pn (2), mP,n (3), m,Pn (4) of Naumann, 01 m-ri, m-n, m-n! , m-n! , as the abbreviated symbols are written in the earlier part of this work. Contrary to the usage in the orthorhombic system, it is customary to make [100] the macropinacoid (i-l = a : oo b : oo c), and [010] the brachypinacoid (i-l = oo a : b : occ >. Planes having the symbol [7iOf] are then macrodoines ; and those of the symbol [Qkl] are brachy- domes. Similarly then pyramids (h > k) of the form [hkl] are macrodiagonal planes, and those of the form (Jtkl) are brachydiagonal planes. The unit prism consists of two independent forms (110), (110) (I'=ooP/), and (110), (110) (I =00 ',P). Mathematical Relation* of the Triclinic System. In consequence of the obliquity of the axes in the Triclinic System the mathematical rela- tions are less simple, and the general equations deduced as before become so complicated as to be seldom of much practical value. Most problems which arise may be solved by the zonal relations, or by the solution of the spherical triangles in the projection. Some of the most important relations (given by Schrauf ) are as follows : MILLER'S SYSTEM OF CRYSTALLOGRAPHY. 461 If the angle between the axes X and Z = rj, between X and Y = , and between Y and Z = | (see f. 757) ; if also a, j8, y are the corresponding angles between the pinacoid planes hen cos $ cos 7 cos a cos 7 cos a cos . COS t\ = : sin sin 7 sin 7 sin a COS COS a COS ) -- where Also AW A! and cos- PX - cos 9 PY = cos 2 PZ = Mi MI AI = [1 + 2 cos a cos cos 7 (cos 2 a 4- cos 2 + cos 9 7)]. Mi = Ji-o-e 12 sin 2 a 4- &Vc 9 sin 2 + 1-aW sin 2 7 + 2rcfte (Jilb cos sin a sin 7 + 7ic cos 7 sin a sin + kla cos a sin sin 7). cos 9 AX = cos BY = A, cos CZ = When PX, PY, PZ have been found by calculation, then the following equation gives th* relation of the axes : 2- cos PX = ~ cos PY = 4- cos PZ. h k I As seen in f . 805. cos PX = sin PBC sin PB = sin PCB sin PC ; cos PY = sin PGA sin PC = sin PAC sin PA ; cos PZ sin PAB sin PA = sin PBA sin PB ; and also from these it follows that 4- sin PAC = -f sin PAB ; /C I sin PBA = sin PBC ; sin PCB = - sin PGA. h h - 180 - CAB ; 7, = 180 - ABC ; = 180 - ACB. RELATIONS OF THE Six CRYSTALLINE SYSTEMS IN RESPECT TO SYMMETRY. From a careful study of the spherical projections for the successive systems a very clear idea may be obtained of the degree of symmetry which characterizes each. It is well under- stood that in the Isometric System there are nine planes of symmetry ; in the Tetragonal, five ; in the Hexagonal, seven ; in the Orthorhombic, three ; and in the Monoclinic only one. These relations are shown on the projections by the symmetrical distribution of the poles about the respective great circles. These zone-circles of symmetry are as follows : Isometric System (f . 766) : 1st, the three diametral zones 1. (100), (010), (TOO). Also the diagonal zones : 4. (110), (001), (110). 5. (110), (001), (110). Tetragonal System (f . 790) 1. (100), (010), (100). 2. (100), (001), (100). 6. (100), (Oil), (100). 7. (100), (Oil), (100). 3. (010), (001), (010). 8. (010), (101), (010). 0. (010), (101), (010). 2. (100), (001), (100). 3. (010), (001), (010^ Also: 4. (110), (001), (110). 5. (110), (001), (110). 462 APPENDIX. Hexagonal System (f. 793) : 1. (1010), (0001), (1010). 4. (1120), (0001), (1120). Orttiorhombic System (f. 801) : 1. (100), (010), (100). Monodinic System (f. 804) : 1. (100), (001), (100). In the Triclinic System there is no plane of symmetry. 2. (0110), (0001), (0110). 5. (1210), (0001) (1210). 7. (1010), (0110), (1100). 3. (1100), (0001), (1100). 6. (2110), (0001), (2110). 2. (100), (001), (100). 3. (010), (001), (010). 51 THE BHOMBOHEDRAL DIVISION OF MILLER. The following projection (f. 806) is added in order to show the relation of the forms in the Hexagonal and Rhombohedral Systems a referred to the three equal oblique axes of Miller. The forms are as follows : The planes having the indices (100), (010), (001) are those of the (plus) funda- mental rhombohedron, while the plane (111) is the base. The planes (221), (121), (122) are those of the minus fundamental rhombohedron; with the planes (100), (010), (001) they form the unit hexagonal pyramid. The hexagonal unit prism (1= [0110]) has the symbols : (2J1), (121), (112), (211), (121), (112). The second, or diagonal hexa- gonal prism (i-2_= [1120]) has the symbols : (101), (110), (Oil), (101), (110), (Oil). The dihexagonal pyramid embraces, like the simple hexagonal pyramid, two forms, [hkl] and [efg] ; the symbol [hfd] hence belongs to the plus scatenohedron, and [tfff] to the minus. In this as in other cases it is true that : e = h + 2k + 2L f = 2h-k + 2l,g = 27* + 2k - I. The dihexagonal prism includes the six ing six of the form [efO]. ^^ ** f0rm C ** ] and the remain ' Most of the problems arising under this system can be solved by the zone equations, or by the working out of the spherical triangles on the sphere of projection. APPENDIX B. ON THE DRAWING OF FIGURES OF CRYSTALS. IN the projection of crystals, the eye is supposed to be at an infinite distance i avs of light fall from it on the crystal in parallel lines. The plane on which the crystal is Ejected is termed the plane of projection. This plane may be at ^Mangles to the ver ical axis may pass through the vertical axis, or may intersect it at an oblique angle. These Uffer^t potions give rise, respectively, to the HORIZONTAL, VERTICAL, and OBLIQUE pro- ections The rays of light may fall perpendicularly on the plane of projection, or may be obliquely inclined to it; in the former case the projection is termed ORTHOGRAPH ^, m wie second CLINOGRAPHIC In the horizontal position of the plane of projection, the projection L always orthographic. In the other positions, it may be either o rtho ^. a P hl ^ o %f ft ^ o f^ P ^ s It is generally preferable to employ the vertical position and clmographic projection, and 1 method is elucidated in the following pages. PROJECTION OF THE AXES. The projection of the axes of a crystal is the first step preliminary to the projection of the form of P the costal itself. The projection of the axes in the isometric svstem, which are equal and intersect at right angles, is here first given. The projection ot ------, systems, with the exception of the hexagonal, may be obtained by varying the lengths projected isometric axes, and also, when oblique, their inclinations as shown beyond Isometric ^m.-When the eye is directly in front of a face of a cube, neither the sidee nor top of the crystal are visible, nor the planes that may be situated on the intermediate edges. On turning the crystal a few degrees from right to left, a side lateral plane is brought in view, and by elevating the eye slightly, the terminal plane becomes apparent. In the following demonstration, the angle of revolution is designated 5, andr the angle of the ele- vation of the eye, e. Fig. 807 represents the normal position of the horizontal axes, supposing the eye to be in the direc- tion of the axis BB ; BB is seen as a mere point, while CO appears of its actual length. On revolving the whole through a number of degrees equal to BMB' (8) the axes have the position exhibited in the dotted lines. The projection of the semiaxis MB is now lengthened to MN, and that of the semi- axis MO is shortened to MH. If the eye be elevated (at any angle, e), the lines B N, BM, and C'H will be projected respectively below N, M, and H, and the lengths of these projections (which we may designate b N, ftM, and c H) will be di- rpot.lv nronortional to the lengths of the lines B N, BM, and C'H. It is P uSo^dopt such a Evolution and such an elevation of the eye as may be expressed by a simple ratio between the projected axes. The ratio Between the two axes MN: Mil, as projected after the revolution, is designated by 1 : r ; and the ratio of b N to MN by 1 . Suppose r to equal 3 and a to equal 2, then proceed as follows : 464 APPENDIX. Draw two lines AA', H'H (f. 808), intersecting one another at right angles. Make MH = MH' = b. Divide HH' into 8 (r) parts, and through the points, N, N', thus determined, draw perpendiculars to HH'. On the left hand vertical, set off, below H', a part H'R, equal to b = H M ; and from R draw RM, and extend the same to the vertical N'. B B is the pro- jection of the front horizontal axis. Draw BS parallel with MH' and connect SM. From the point T in which SM intersects BN, draw TO par- allel with MH. A line (CO") drawn from C through M, and extended to the left vertical, is the projection of the side horizontal axis. Lay off on the right vertical, a part HQ equal tc ^MH, and make MA = MA'= MQ ; A A' is the vertical o axis. If, as here, r 3, and s = 2, then 8 = 18 26', and e = 9 28', for cot 5 = r, and cot e = rs. Tetragonal and OrthorJiombic Systems. The axes AA', CO', BB, constructed in the mannei described, are equal and at right angles to each other. The projection of the axes of a tetra- gonal crystal is obtained by simply laying off, with a scale of proportional parts, on MA and MA' taken as units, the value of the vertical axis (c) for the given species. Thus for zircon, where c = "04, we must lay off '64 of MA above M and the same length below. For an orthorhombic crystal, where the three axes are unequal, the length of c must as before be laid off above and below from M, and that of b to the right and left of M, on CC , MC being taken as the unit. It is usual to make the front axis MB = a = 1. Monodinic System. The axes c and a in the monoclinic system are inclined to one another at an obliqe angle = . To project this inclination, and thus adapt the isometric axes to a monoclinic form, lay off (f . 809) on the axis MA, M = MA cos 0, and on the axis BB' (before or behind M, according as the inclination of a on c, in front, is acute or obtuse) M6 = MB x sin /8. From the points b and , draw lines parallel respectively with the axes AA' and BB', and from their intersection D , draw through M, D'D, making MD = MD'. The line DD' is the clinodiagonal, and the lines AA, CO, DD' re- present the axes in a monoclinic solid in which a = b = c = 1. The points a and b and the position of the axis DD' will vary with the angle 0. The relative values of the axes may be given them as above explained ; that is, if d 1, lay off in the direction of MA and MA' a line equal to c, and in the direction of MC and MC' a line equal to 6, etc. T-nclinio System. The vertical sections through the horizontal axes in the triclinic system are obliquely in- clined ; also the inclination of the axis a to each axis b In the adaptation of the isometric axes to the triclinic forms, it is there- fore necessary, in the first place, to give the requisite obliquity to the mutual inclination of the vertical sec- tions, and afterwards to adapt the horizontal axes. The inclination of these sections we may designate A, and as heretofore, the angle between a and 6, 7, and a and c, 0. BB' is the analogue of the brachydiagonal, and GC of the macrodiagonal. An oblique inclination may be given the vertical sections, by varying the position of either of these sections. Permitting the brachydiagonal section ABA'B' to remain unaltered, we may vary the other sec- tion as follows : Lay off (f. 810) on MB, W)'= MB x cos A, and on the axis C C (to the right or left of M, according as the acute angle A is to the right or left), Me = MC x sin A ; completing the parallelogram M6' DC, and drawing the diagonal MD, extending the same to D' so as to make MD' MD, we obtain the line DD' , the vertical station and c, is oblique. 810 A ON THE DRAWING OF FIGTJKES OF CRYSTALS. 465 passing through this line is the correct macrodiagonal section. The inclination of a to the new macrodiagonal DD' is still a right angle ; as also the inclination of a to 5, their oblique inclinations may be given them as follows : Lay off on MA (f. 810), Ma = MA x cos , and on the axis BB' (brachy diagonal), M# MB' x sin #. By completing the parallelogram Ma, K'J, the point E' is determined. Make ME = ME ; EE is the projected brachy diagonal. Again lay off on MA, Ma'= MA x cos o, and on MD', to the left. Mrf =. MD' x sin o. Dra\ lines from a! and d parallel to MD and MA ; F', the intersection of these lines, is one extremity of the macrodiagonal; and the line FF', in which MF = MF', is the macrodiagonal. The vertical axis AA' and the horizontal axes EE' (brachy diagonal) and FF' (macrodiagonal) thus obtained, are the axes in a triclinic form, in which a = b = c = 1. Different values may be given these axes, according to the method heretofore illustrated. Hexagonal System. In this system there are three equal horizontal axes, at right angles to the vertical axis. The normal position of the horizontal axes is represented in f. 811. The eye, placed in the line of the axis YY, observes two of the semiaxes, MZ and MU, projected in the same straight line, while the third, MY, appears a mere point. To give the axes a more eligible position for a representation of the various planes on the solid, we revolve them from right to left through a certain number of degrees 8, and elevate the eye at an angle e. The dotted lines in the figure repre- sent the axes in their new situation, resulting from a revolution through a number of degrees equal to 5 = YMY'. In this position the axis MY is projected upon MP, MU' upon MN, and MZ on MH. Des gnating the intermediate axis I, that to the right II, that to the left III, if the revolution is such as to give the projections of I and II the ratio of 1 : 2, the relations of the three projections will be as follows : I : II : III = 1 : 2 : 3. Let us take r ( = PM : HM) equal to 3, and * (= b'P : PM) equal to 2, these being the most convenient ratios for representing the hexagonal crystalline forms. The following will be the mode of construc- tion : 1. Draw the lines AA, HH (f. 812) at right angles with, and bisecting, each other. Let HM = , or HH 2b Divide HH into six parts by vertical lines. These lines, including the left-' and right-hand verticals, may be numbered from one to six, as in the figure. In the first vertical, below H, lay off HS = -6, and from S draw a line through M to the fourth vertical. YY' is the projection of the axis I. 2. From Y draw a line to the sixth vertical and parallel with HH. From T, the extremity of this line, draw a line to N in the second vertical. Then from the point U, in which TN intersects the fifth vertical, draw a line through M to the second vertical ; TJU' is the projection of the axis II. 3. From R, where TN intersects the third verti- cal, draw RZ to the first vertical parallel with HH. Then from Z draw a line through M to the sixth vertical : this line ZZ' is the projection of the axis III. 4. For the vertical axis, lay off from N on the sec- ond vertical (f. 812) a line of any length, and con- struct upon this line an equilateral triangle ; one side (NQ) of this triangle will intersect the first vertical at a distance, HV, from H, corresponding to Z H in f. 811 ; for in the triangle NHV, the angle HNV is an angle of 30, and HN = |MH. MV is therefore the radius of the circle (f. 811). Make therefore MA = MA' MV ; AA' is the vertical axis, and YY', riU , ZZ' are the projected horizontal axes. , . The vertical axis has been constructed equal to the horizontal axes. Its actual 1< different hexagonal or rhombohedral forms may be laid off according to the method sut The projection of the isometric and hexagonal axes, having been once accurately made, and that on a conveniently large scale, may be kept on a piece of cardboard, and will all subsequent requirements. Whenever needed for use, these axes may be transferred sheet of paper, and then adapted in length, or inclination, or both, to the case 11 30 466 APPENDIX. PROJECTION OF THE FORMS OP CRYSTALS. ' , Simple forms. When the axial cross has been constructed for the given species, the anil octahedron is obtained at once by joining the extremities of the axes, AA', BB', CO', as in f. 813. Here as in all cases the lines which fall in front are drawn strongly, while those behind are simply dotted. For the diametral prisms draw through B, B', C, C', of the projected axes of any species, lines parallel to the axes BB', CC', until they meet; they make the parallelogram, abed, which is a transverse section of the prism, par- allel to the base. Through a, 6, c, d draw lines parallel and equal to the vertical axis, making the parts above and below these points equal to the vertical semiaxis. Then, connect the extremities of these lines by lines parallel to ab, be, cd, da, and the figure will be that ol the diametral prism, corresponding to the axes projected. In the case of the isometric system this dia- metral prism is the cube, whose faces are represented by the letter H; in the tetragonal system it is the prism 0, i-i ; in the orthorhombic, the prism 0, i-i, i-i ; in the monoclinic, the prism 0, i-i* i-i ; in the triclinic, 0, i-1, i-l. The unit vertical prism in the tetragonal, orthorhombic, and clinometnc systems may be projected by drawing lines parallel to the vertical axis AA' through B, C, B', C , making the parts above and below these points equal to the vertical semiaxis ; and then connecting the extremities of these lines by lines parallel to BC, CB', B'C , C B. The plane BOB C is a transverse section of such a prism parallel to its base. It is the prism 0, /, in each of the systems excepting the triclinic, and in that 0, /, /' ; a square prism in the tetragonal system ; a right rhombic in the orthorhombic ; an oblique rhombic in the monoclinic ; an oblique rhom- boidal in the triclinic. Other simple forms under the different systems are constructed in essentially the same way. It is only necessary to lay down upon the axes each plane of the form, in lightly drawn lines, note the points where it intersects the adjoining planes, and draw these in more strongly. When the process is complete the construction lines may be erased. The process will be illustrated by f . 814 and f. 815. In the former case it is required to draw the trigonal trisoo tahedron, whose symbol is 2 ON THE DRAWING OF FIGURES OF CRYSTALfl. 467 In f. 814 the three planes of the first octant are represented, they are 2 : 1 : 1, 1 : 2 : 1, and 1:1: 2. It will be seen here, what is always true, that the two points of intersection required to determine the line of intersection, lie in ike axial planes. These lines of intersec- tion are represen'ed by the dotted lines in f. 814. If the same process be performed for the other octants, the complete form, as in f. 816, will be obtained. Similarly in f. 815, the octagonal pyramid 1-2 is constructed; the figure shows the planes of one octant only, c : 2a : a, and c : a : 2a, and the dotted line gives their line of intersec- tion. Carry out the same plane of construction in the other octants, and the form of f. 817 will result. The construction of the various crystalline forms, by this method, especially those of the isometric system, will be found an interesting and instructive process, and will lead to a clear understanding of the forms themselves and their relations to each other. Another and quicker, though more mechanical method of constructing the isometric forms may also be given. Projection of Simple Isometric Forms. This method depends upon the principle that in the different isometric forms the vertices of the solid angles are occupied by one or more of the interaxes (p. 16). If, therefore, these points (the extremities of the interaxes), can be deter- mined in the several crystalline forms, it is only necessary to connect them in order to obtain the projection of the solid itself. As a preparation for the construction of figures of isometric crystals, it is desirable to have at hand the figure of a cube projected on a large scale, with its axes, and its trigonal (octahe- dral), and rhombic (dodecahedral) interaxes. The values of the interaxes t and r, for a given form, are obtained by adding to their nor- mal length the values of t' and r' respectively given by the following equations ; those of th octahedron being taken as a unit : 2mn (m + ri) , n \ mn + (m + n) ~ n + 1 * The proportion to be added to the interaxes for some of the common forms is as follows; t r t r 2 i t-3 1 * i i i-3 8-| i 3-3 j * 4-2 f i 3-3 f i To construct the form 4-2, the octahedron is first to be projected, and its axes and inter- axes drawn. Then add to each half of each trigonal interaxis, five-sevenths of its length ; and to each half of each rhombic interaxis, one-third of its length. The extremities of the lines thus extended are situated in the vertices of the solid angles of the hexoctahedron 4-2, and by connecting them, the projection of this form is completed. In the inclined hemihedral isometric forms (p, 20), the rhombic interaxes do not terminate In the vertices of the solid angles, and may therefore be thrown out of view in the projection of these solids. The two halves of each trigonal interaxis terminate in the vertices of dis- similar angles, and are of unequal lengths. One is identical with the corresponding interaxis in the holohedral forms, and is called the holohedral portion of the interaxis ; the other is the hemihedral portion. The length of the latter may be determined by adding to the half of the octahedral interaxis that portion of the same indicated in the formula : 2mn (m n) mn + (m n) ' If the different halves of the trigonal interaxes be assumed at one time, as the holohedral, and again as the hemihedral portion, the reverse forms -^~ and ^^ may be projected. The following table contains the values cf the above fraction for several of the inclined hemihedral forms, and also the corresponding values for the holohedral portion of the inter- Axis : Hoi. interax. Hem. interax. Hoi. interax. Hem. interax, ( -^- (f. 76, p. 20) 02^- (f. 85) i 1 9181) * 2 <>(f.87) i * 2 468 APPENDIX. The parallel hemihedrons (for example, the pentagonal dodecahedron, or hemi-tetrahexahe- dron) contain a solid angle, situated in a line between the extremities of each pair of semiaxes, which is called an unsymmetrical solid angle. The vertices of these angles are at unequal distances from the two adjacent axes, and therefore are not in the line of the rhombic inter- axes. The co-ordinates of this solid angle for any form, as - , may be found by the for- mulas p and - Y . By means of these formulas, the situation of two points, a and 5 (f. 818), in each of the axes may be determined : and if lines are drawn through a and b in each semiaxis parallel to the other axes, the intersections c, c', of these lines will be the vertices of the unsymmetrical solid angles, those marked c of the form and those marked f of the form _^. The trigonal interaxes are of the same length as in the holohedral forms. The values of these interaxes, and of the coordinates of the unsymmetrical solid angle for different parallel hemihedrons, are contained in the following table : Trigonal interaxis. Coord, of the unsym. S. A. Trigonal interaxis. (sim. f. 92) Coord, of the unsym. S. A. ^ * * f -BJU*, i i * 5s Projection of a Rhombohedron. To construct a rhombohedron, lay off verticals through the extremities of the horizontal axes, and make the parts both above and below these extremities equal to the third of the vertical semiaxis (f. 819). The points E, E, E', E', etc., are thus determined ; and if the extremities of the vertical axis be connected with the points E or E , rhombohedrons in different positions, wR, or raR, will be constructed. Scalenohedron. The scalenohedron m n admits of a similar construction with the rhombohe dron raR. The only variation required, is to multiply the vertical axis by the number of units in n, after the points E and E' in the rhombohedron raR have been determined ; then connect the points E, or the points E', with one another and with the extremities of the ver- tical axis. 2. Complex Forms. When it is required to figure not only the planes of one form, that is, those embraced in one symbol, but also those of a number modifying one another, a some- what different process is found desirable. It is possible indeed to construct a complex form in the way mentioned on p. 466, each plane being laid off on the given axes, and its intersec- tion-edges with adjoining planes determined by two points, always in the axial sections, which it has in common with each. In this way, however, the figure will soon become so complex as to be extremely perplexing, and thus lead to error and consequent loss of time. This difficulty is in part avoided by the use of one projection of the axes on a larger scale, apon which the directions of the intersection-lines are determined, while a second smaller one, ON THE DRAWING OF FIGURES OF CRYSTALS. 469 placed below and parallel to it on the same sheet of paper, is used for the actual drawing of the crystal. In most cases, however, the crystal may be drawn as conveniently without the use of the second set of axes. The size of the figure may be either that which is to be finally required, or, more advantageously, it maybe drawn two or three times larger and then reduced by photography. This method is especially to be recommended when the figures are finally to be engraved on wood, since from the enlarged drawing they may be photographed directly upon the wood of any required size, and thus a very high degree of accuracy attained. Application of Quenstedfs Projection. The process of determining the direction of the intersection-edges is much simplified if the principles of Quenstedt's Projection (p. 55) are made use of. In other words, the symbol of every plane is so transformed that for it the length of the vertical axis is -unity. This extremity of the vertical axis is then one point of intersection for all planes whatsoever, and the second point will always lie in the horizontal plane, that of the lateral axes. The change in the symbol requires nothing but that the symbol, expressed in full, should be divided by the coefficient of the vertical axis. The direc- tion of each intersection-edge, when determined, is transferred to the figure in process of construction by means of a small triangle sliding against a ruler some 8 inches in length. It will be found in practice that, especially when this method is employed, it is not necessary to actually draw all the lines representing each plane, but to note simply the required points of intersection. This method and its advantages (see Klein, Einleitung in die Krystallberech- nun, II., p. 387) will be made clear by an example. It is required to project a crystal of andalusite of prismatic habit, showing also the planes '-, t4, !*, 1,2-2, 1-i, and 0. It is evident that an indefinite number of figures may be made, including the planes men- tioned, and yet of very different appearance according to the relative size of ea.ch. It is usually desirable, however, to represent the actual appearance of the crystal in nature, only in ideal symmetry, hence it is very important in all cases to have a sketch of the crystal to be represented, showing the relative development of the different planes. If this sketch is made with a little care, so as to show also the parallelism of the intersection-edges in the occurring zones, it will give material aid. The zones, it is to be noted, are a great help in drawing figures of crystals, and they should be carefully studied, since the common direction of the intersection-edge once determined for any two planes in it, will answer for all others. The first step is to take the projection of the isometric axes already made once for all on a conveniently large scale, and which, as before suggested, is kept on a card of large size, and ready to be pierced through on to the paper employed. These axes, now of equal 'engtn, must be adapted to the species in hand. For andalusite the axial ratio is \ e : b :a- u i 1-014 : 1 : hence the vertical axis e must have a length -71 of what it now has, and the late! axis one I'Ol : these required lengths are determined in a moment with a scale otequa The nexb step is to draw the predominating form, the prism /. Obviously its intersection, edges are parallel to the vertical axis, and its basal edges, intersecting are paral tq in the projection (f . 820). The planes i-l, and * 2 are now to be added, whose intersections with each other and with 1 are parallel to c. The position of one edge, //M. having ^ beei taken, that of the other on the other side is determined by the point where a line paraiie 470 APPENDIX. , nn. the axis b meets the basal edge of the pri?m. Similarly the position of the same prismat edges behind are given by the intersection of lines from front to rear parallel to the axis . The prisms drawn, it remains to add the terminal planes, and as they thus modify one an- other's position, they are drawn together. The required intersection-lines are easily obtained. The macrodome 14 is the plane passing through the point c and intersecting the horizontal plane in the line paq ; this line is obviously the direction of its intersection-edge with i-1 and with 0. The prism i-'2 appears (f. 820) as the two lines mm', nri ; the line mm produced beyond m meets paq at 2, this will be one common point for the two planes 14 and i-2 ; the second common point is, as always, the point c, hence the line joining these two points, trans- ferred to the crystal in the way described, gives the required intersection- edge for -2 and 14. Similarly for i-2 on the right, the two points of intersection are c, and the point where n'n and qap, produced, meet, and this gives the second intersection-edge. The planes 14 and 1 (right) meet at d and c ; hence the line cd gives the direction of their intersection- edge, which is also the direction of that of 14 and 1 (left), and of 1 and 2-2, right and left on both sides. Still again, the plane 2-2 has the full symbol 2J : b : 2 2, or c : \b : d ; and hence intersects the horizontal plane (f. 820) in the lines as (right), at (left), and a'q, a'p (behind). Hence the intersection-edge of 7, 2-2, 1-2 has the direction of the line joining the points c, and s (right), and similarly to the left and behind. The intersection- edge of 2-2 front, and 2-2 behind, has the direction of the line joining the points c and x (right) and c and y (left). The method of obtaining the intersection-edges of the planes will be clear from this ex- ample. Practical facility in drawing figures by this or any other method is only to be obtained by practice. It will be found that at almost every step there is an opportunity to test the accuracy of the work thus every point of intersection on the basal plane behind must lie on a line drawn from the cor- responding point in front on the basal plane, in the direction of the axis a; so, too, the point of intersection of 2-2 and 1 (front), 2-2 and 7 (behind), on one side, must be in the line of the horizontal axis (b) with that on the other side, and similarly in other cases. If it were required, as is generally necessary, to complete the form (f . 821) below, it is unnecessary to obtain any new intersec- tion lines, since every line above has its corresponding line oppo- site and parallel to it below. Moreover, in an orthorhombic crys- tal every point above has a corresponding point below on a line parallel to the vertical axis. This, as above, will serve as a control of the accuracy of the work. There is another method of drawing complex crystalline forms which has many advantages and is sometimes to be preferred to any other ; it can be explained in a very few words. After the axes have been obtained the diametral prism is constructed upon them. Upon the solid angles of this each plane of the required form is laid off, the edges being taken instead of the 822 824 6 P M :M axes. Suppose that f. 822 repre_sents the diametral prism of an orthorhombic crystal. Here obviously the edge e = 2c, e = 2b, e = 21. The plane 1 (c : b : a) may be laid off on it by taking from the angle a equal portions of the edges , e, e, for instance, conveniently one ON THE DRAWING OF FIGUEES OF CRYSTALS. 471 ialf of each, hence the plane appears as mno. Again the plane 2 (2c : b : a) is laid off by taking :he unit lengths of the edges e (b), and e (a) and twice the unit length of e (c), the plane is then mnb. Again, the plane 4-2 (4 : b : 21) takes the position npb, since ap = 2c, ap = 2 b, and an = a, the ratio of the edges (axes) being the same as in the symbol. So also the plane 2-2 (2c : 2b : a) has the position rmo, since ao = c, am = 5, and ar = J, here, too, the ratio of the axes being preserved. By plotting the successive planes of the crystal in this way, each solid angle corresponding to an octant, the direction of the intersection-edges :'or the given f orm are at once obtained. For example, the intersection- edge for 1, and the basal slane, as also for 1 and 2, it is the line mn ; for 1 and 4-2 it is the dotted line joining the common joints )i and a ; for 1 and 2-2 it is the line mo ; for 2 and 4-2, also for 2 and 2-2, it is the line joining the common points a. The direction of the required intersection- edges being obtained in this way, they are used ;o construct the crystal itself, being transferred to it in the usual way. In f. 823 they have aeen placed upon the diametral prism, and when this process has been completed for the other angles, and, too, the domes e i', e\ are added, the form in f. 824 results. ON THE DRAWING OF TWIN CRYSTALS. In order to project a compound or twinned crystal it is generally necessary to obtain first ihe axes of the second individual, or semi -individual, in the position in which they are brought Dy the re volution of 180. This is accomplished in the following manner. In f. 825 a com- pound crystal of staurolite is represented, in which twinning has taken place (1) on an axis normal to f -, and (2) on an axis normal to f-if-. The second, being the more general case, is of the greater importance for the sake of example. In f. 825, cc', bb', aa' represent the rect- angular axes of staurolite (c = 1 '441, b 2'112, d = 1). The twinning-plane f-| (fc : b : $a) 825 has the position MNR. It is first necessary to construct a normal from the centre to this plane. If perpendiculars be drawn from the centre to the lines MN, NB, MR, they will meei them at the points x, y< z, dividing eachline into segments proportional to the squares adjacent axes ;* or N* : Ma = ON 2 : OM 2 . In this way the points a?, y, z are fixed, and linei * This is true since the axial angles are right angles. In the Monoclinic System two of ihe axial intersections are perpendicular, and they are sufficient to allow of the < tion of the point T, as above. In the Triclinic System the method needs to b< modified. 472 APPENDIX. 827 drawn from any two of them to the opposite angles R, N, or M will fix the point T. A line joining T and O is normal to the plane (MNR = f-|). Furthermore, it is obvious that if a revolution of 180 about TO take place, that every point in the plane MNR will remain equally distant from T. Thus, the point M will take the place /*(MT = T^u), the point b the place ft' (NT T'), and so on. The lines joining these points /it, ', #, and the common centre O will be the new axes corresponding to MO, NO, RO. In order to obtain the unit axes corresponding to c, b, a it is merely necessary to draw through c a line parallel to MT,u, meeting /*O at 7, then 707' is the new vertical axis corresponding to cOe , also &Q&' corresponds to bOb', and aOa' corresponds to aOa'. These three axes then are the axes for the second individual in its twinned position ; upon them, in the usual way, the new figure may be constructed and then transferred to its proper position with reference to the normal crystal. For the second method of twinning, when the axis is normal to f-2, the construction is more simple. It is obvious the axis is the line O#, and using this, as before, the new axes are found ; /cO/c' corresponds to cOc (sensibly coinciding with bb), since (Mf- 134 21', and so on. In many cases the simplest method is to construct first the normal crystal, then draw through its centre the twinning-plane and the axis of revolution, and determine the angular points of the reversed crystal in the principle alluded to above : that by the revolution every point remains at the same distance from the axis, measured in a plane at right angle to the axis. Calcite. Thus in f. 827 when the scalenohedron has been drawn, since the twinning-plane is the basal plane, each angular point, by the revolution of 180, obtains a position equidistant from this plane and directly below it. In this way each angular point is determined, and the com- pound crystal is completed in a moment. APPENDIX C. CATALOGUE OF AMERICAN LOCALITIES OF MINERALS. The following catalogue * may aid the mineralogical tourist in selecting his routes and arranging the plan of his journeys. Only important localities, which have afforded cabinet specimens, are in general included ; and the names of those minerals which have been obtained in good specimens are distinguished by italics, the addition of an exclamation mark (!), or of two (!!), indicates the degree of excellence of the specimens. Many of the localities mentioned have been exhausted, others will now yield good specimens only when further explored with blasting, etc. In general, only those of the localities mentioned can be relied upon as likely to reward the visitor liberally where active work is being continually carried on. MAINE. ALBANY. Beryl! green and black tourmaline, feldspar, rose quartz, rutile. AROOSTOOK. Red hematite. AUBURN. Lepidolite, amblygonite (hebronite), green tourmaline. BATH. Vesuvianite, garnet* magnetite, graphite. BETHEL. Cinnamon garnet, calcite, sphene, beryl, pyroxene, hornblende, epidote, graphite, talc, pyrite, arsenopyrite, magnetite, wad. BINGHAM. Massive pyrite, galenite, blende, andalusite. BLUE HILL BAY. Arsenical iron, molybdenite! galenite, apatite! fiuorite! black tourma- line (Long Cove), black oxide of manganese (Osgood's farm), rhodonite, bog manganese, wolframite. BOWDOIN. Rose quartz. BOWUOINUAM. Beryl, molybdenite. BRUNSWICK. Green, mica, garnet/ black tourmaline/ molybdenite, epidote, cakite, mua covite, feldspar, beryl. BUCKFIELD. Garnet (estates of Waterman and Lowe), iron ore, muscovite! tourmaline! magnetite. CAMDAGE FARM. (Near the tide mills), molybdenite, wolframite CAMDEN. Made, galenite, epidote, black tourmaline, pyrite, talc, magnetite. CARMEL (Penobscot Co.). Stibnite, pyrite, made. CORINNA. Pyrite, arsenopyrite. DEER ISLE. Serpentine, verd- antique, asbestus, diallage, magnetite. DEXTER. Galenite, pyrite, blende, chalcopyrite, green talc. DIXFIELD. Native copperas, graphite. EAST WOODSTOCK. Muscovite. FARMINGTON. (Norton's ledge), pyrite, graphite, bog ore, garnet, staurolite. FBEEPORT. Rose quartz, garnet, feldspar, scapolite, graphite, muscomte. FRYEBURG. Garnet, beryl. GEORGETOWN. (Parker's island), beryl! black tourmaline. GREENWOOD. Graphite, black manganese, beryl! arsenopyrite, cassiterite, mica, rose quartz, garnet, corundum, albite, zircon, molybdenite, magnetite, copperas. * The catalogue is essentially the same as that published in the 5th Edition of Dana's Sys tern of Mineralogy, 18G8. The names of a considerable number of new localities have been added, however, which have been derived from various printed sources, and also from private contributions from Prof. G. J. Brush, Mr. G. W. Hawes, Mr. J. Willcox, and others. See further on pp. 503 to 508. 474 APPENDIX. HEBRON. Cassiterite, arsenppyrite, idocrase, lepidolite, amblygonite (Jtebron'te)^ rubettite! indicolite, green tourmaline, mica, beryl, apatite, albite, childrenite, cookeite. JEWELL'S ISLAND. -Pyrite. KATAHDIN IRON WORKS. Bog-iron ore, pyrite, magnetite, quartz. LETTER E, Oxford Co. Staurolite, made, copperas. LINN/EUS. Hematite, limonite, pyrite, bog-iron ore. LITCHFIELD. Sodalit.e, cancrinite, elceolite, zircon, spodumene, muscovite, pyrrhotite. LUBEC LEAD MINES. Galenite, chalc(/pyrite, blende. MACHIASPORT. Jaspei\ epidote, laumontite. MADAWASKA SETTLEMENTS. Vivianite. MINOT. Beryl smoky quartz. MONMOUTH. Actinolite, apatite, elceolite, zircon, staurolite, plumose mica, beryl, rutile. MT. ABRAHAM. Andalusite, staurolite. NORWAY. Chrysoberyl! molybdenite, beryl, rose quartz, orthodase, cinnamon garnet. ORR'S ISLAND. Steatite, garnet andalusite. OXFORD. Garnet, beryl, apatite, wad, zircon, muscovite, orthoclase. PARIS. Green! red! black, and blue tourmaline! mica! lepidolite! feldspar, albite, quartz crystals ! rose quartz, cassiterite, amblygonite, zircon, brookite, beryl, smoky quartz, spodu- mene, cookcite, leucopyrite. PARSONSFIELD. Vesucianite ! yellow garnet, par gasite, adularia, scapolite, galenite, blende, chalcopyrite. PERU Crystallized pynte. PHIPPSBURG. Yellow garnet ! manganesian garjiet, vesuvianite, pargasile, axinite, laumon- tite ! chabazite, an ore of cerium ? POLAND. Vesuvianite, smoky quartz, cinnamon garnet. PORTLAND. Prehnite, actinolite, garnet, epidote, amethyst, calcite. POWNAL. Black tourmaline, feldspar, scapolite, pyrite. actinolite, apatite, rose quartz. RAYMOND. Magnetite, scapolite, pyroxene, lepidolite, tremolite, hornblende, epidote, ortho- clase, yellow garnet, pyrite, vesuvianite. ROCKLAND. Hematite, tremolite, quartz, wad, talc. RUMFORD. Yellow garnet, vesuvianite, pyroxene, apatite, scapolite, graphite. RUTLAND. Allanite. SANDY RIVER. Auriferous sand. SANFORD, York Co. Vesuvianite! albite, calcite, molybdenite, epidote, black tourmaline, labradorite. SEARSMONT. Andalusite, tourmaline. SOUTH BERWICK. Made. STANDISII. Columbite ! STREAKED MOUNTAIN. Beryl! black tourmaline, mica, garnet. THOMASTON. Calcite, tremolite, hornblende, sphene, arsenical iron (Owl's head), black manganese (Dodge's mountain), thomsonite, talc, blende, pyrite, galenite. TOPSHAM. Quartz, galenite, blende, tungstite ? beryl, apatite, molybdenite, columbite. UNION. Magnetite, bog-iron ore. WALES. Axinite in boulder, alum, copperas. WATERVILLE Crystallized pynte. WINDHAM (near the bridge).' Slaurolite, spodumene, garnet, beryl, amethyst, cyanite, tourmaline. WIN SLOW. Cassiterite. WINTHROP. Staurolite, pyrite, hornblende, garnet, copperas. WOODSTOCK. Graphite, hematite, prehnite, epidote, calcite. YORK. Beryl, vivianite,, oxide of manganese. NEW HAMPSHIRE. ACWORTH. Beryl!! mica! tourmaline, feldspar, albite, rose quartz, columbite! cyanite, autunite. ALSTEAD. Mica! ! albite, black tourmaline, molybdenite, andalusite, staurolite. AMHERST. Vesuvianite, yellow garnet, pargasite, calcite, amethyst, magnetite. BARTLETT. Magnetite, hematite, brown iron ore in large veins near Jackson (on tl Bald face mountain "), quartz crystals, smoky quartz. BATH. Galenite, chalcopyrite. BEDFORD. Tremolite, epidote, graphite, mica, tourmaline, alum, quartz. BELLOWS FALLS. Cyanite, staurolite, wavellite. BBISTOL. Graphite. AMERICAN LOCALITIES. 475 C AMPTON. Beryl ! CANAAN. Gold in pyrites, garnet. CHARLESTON. Staurolite made, andalusite made, bog-iron ore, prehnite, cyanite. CORNISH. Stibnite, tetrahedrite, rutile in quartz! (rare), staurolite. CROYDEN. lolite ! chalcopyrite, pyrite, pyrrhotite, blonde. ENFIELD. Gold, galenite, staurolite, greeu quartz. FRANCESTON. Soapstotie, arsenopyrite, quartz crystals. FRANCONIA. Hornblende, staurolite ! epidote ! zoisite, hematite, magnetite, black and red manganesian gnrnets, arsenopyrite (danaite], chalcopyrite, molybdenite, prehnite, green quartz, malachite, azurite. GILFORD (Gunstock Mt.). Magnetic iron ore, native "loadstone." GOSHEN. Graphite, black tourmaline. GILMANTOWN. Tremolite, epidote, muscovite, tourmaline, limonite, red and yellow quartz crystals. GRAFTON. Mica ! (extensively quarried at Glass Hill, 2m. S. of Orange Summit), albite ' blue, green, and yellow beryls! (1 in. S. of O. Summit), tourmaline, garnets, triphylite, apa- tite, fluorite. GRANTHAM. Gray staurolite! GROTON. Arsenopyrite, blue beryl, muscovite crystals. HANOVER. Garnet, a boulder of quirtz containing rutilc ! black tourmaline, quartz, cya- nite, labradorite, epidote. HAVERIIILL. Garnet! arsenopyrite, native arsenic, galenite, blende, pyrite, chalcopy- rite, magnetite, marcasite, steatite. HILLSBORO' (Campbel.'s mountain). Graphite. HINSDALE. RJiodonite, black oxide of manganese, molybdenite, indicolite, black tour- maline. JACKSON. Drusy quartz, tin ore, arsenopyrite, native arsenic, fluorite, apatite, magnetite, molybdenite, wolframite, chalcopyrite, arsenate of iron. JAFFREY (Monadnock Mb.). Cyanite, limonite. KEENE. Graphite, soapstone, milky quartz, rose quartz. LANDAFF. Molybdenite, lead and iron ores. LEBANON. Bog-iron ore, arsenopyrite, galenite, magnetite, pyrite. LISBON. Staurolite, black and red garnets, granular magnetite, hornblende, epidote, zoisit^ hematite, arsenopyrite, galenite, gold, ankerite. LITTLETON. Ankerite, gold, bornite, chalcopyrite. malachite, menaccanite, chlorite. LYMAN. Gold, arsenopyrite, ankerite, dolomite, galenite, pyrite, copper, pyrrhotite. LYME. Cyanite (N. W. part), black tourmaline, rutile, pyrite, chalcopyrite (E. of E. vil- lage), stibnite, molybdenite, cassiterite. MADISON. Galenite, blende, chalcopyrite, limonite. MERKTMACK. Rutile! (in gneiss nodules in granite vein). MlDDLETOWN. Rutile. MONADNOCK MOUNTAIN. Andalusite, hornblende, garnet, graphite, tourmaline, ortho- clase. MOOSILAUKE MT. Tourmaline. MOULTONBOROUGH (Red Hill). Hornbende, bog ore, pyrite, tourmaline. NEWINGTON. Garnet, tourmaline. NEW LONDON. Beryl, molybdenite, muscovite crystals. NEWPORT. Molybdenite. ORANGE. Blue beryl*! Orange Summit, chrysoberyl, mica (W. side of mountain), apatite, galenite, limonite. ORFORD. Brown tourmaline (now obtained with difficulty), steatite, rutile, cyanite, brown iron ore, native copper, malachite, galenite, garnet, graphite, molybdenite, pyrrhotite, mela- conite, chalcocite, ripidolite. P E LII AM . Steatite. PIERMONT. Micaceous iron, barite, green, white, and brown mica, apatite, titanic iron. PLYMOUTH. Columbite, beryl. RICHMOND. lolite! rutile, steatite, pyrite, anthophyllite, talc. RYE. Chiastolite. SADDLEBACK MT. Black tourmaline, garnet, spinel. SHELBURNE. Galenite, black blende, chalcopyrite, pyrite, pyrolusite. SPRINGFIELD. Beryls (very large, eight inches diameter), manganesian garnets! otOM tourmaline ! in mica slate, albite, mica. SULLIVAN. Tourmaline (black), in quartz, beryl. SURREY. Amethyst, calcite, galenite, limonite, tourmaline. SWANZEY (near Keene). Magnetic iron (in masses in granite). 476 APPENDIX. TAMWORTH (near White Pond). Galenite. JrfS ( f/ tate f J . aD ?v 3 ^V'-CoPper an d *> Pities, cJforophyttite, green, mica, rod* ated actinohte, garnet, titamferous iron ore, magnetite, tourmaline WALPOLE (near BeUows Falls). Made, staurolite, mica, graphite WARE. Graphite. WAXnHK.Chai&>pyrite, blende, epidote, quartz, pyrite, tremolite, galenite, rutile, talc molybdenite, cinnamon stone ! pyroxene, hornblende, beryl, cyanite, tourmaline (massive) W ATERVILLE Labradorite, chrysolite. WESTMORELAND (south part). Molybdenite! apatite! blue feldspar, bog manganese (north village), quartz, fiuorite, chalcopyrite, oxide of molybdenum and uranium WHITE MTS. (Notch near the " Crawford House"). Green octahedral fluorite quarts crystals, black tourmaline, chiastolite, beryl, calcite, amethyst, ainazonstone. W I Li MOT. WINCHESTER. Pyrolusite, rhodochrosite, psilomelane, magnetite, granular quartz, spodu- VERMONT. ADDISON. Iron sand, pyrite. ALBURGH. Quartz crystals on calcite, pyrite. ATHENS. Steatite, rhomb spar, actinolite, garnet. BALTIMORE. Serpentine, pyrite! BARNET. Graphite. BELVIDERE. --Steatite, chlorite. BENNINGTON. Pyrolusite, brown iron ore, pipe clay, yellow ochre BERKSHIRE. Epidole, hematite, magnetite. BETHEL. ActinoUte! talc, chlorite, octahedral iron, rutile, brown spar in steatite. RANDON. Braunite, pyrolusite, psilomelane, limonite, lignite, white clay, statuary marble ; fossil fruits in the lignite, graphite, chalcopyrite. BRATTLEBOROUGH. Black tourmaline in quartz, mica, zoisite, rutile, actinolite sea polite spodumene, roofing slate. BRIDGEWATER. -Tate, dolomite, magnetite, steatite, chlorite, gold, native copper, blende galenite, blue spinel, chalcopyrite. BRISTOL. RutUe, limonite, manganese ores, magnetite. BROOKFIELD. Arsenopyrite, pyrite. CABOT. Garnet, staurolite, hornblende, albite. CASTLETON. Roofing slate, jasper, manganese ores, chlorite. CAVENDISH. Garnet, serpentine, talc, steatite, tourmaline, asbestus, tremolite. CHESTER. Asbestus, feldspar, chlorite, quartz. f CHITTENDEN. Psilomelane, pyrolusite, brown iron ore, hematite and magnetite, galenite, lOlluG. COLCHESTER. Brown iron ore, iron sand, jasper, alum. CORINTH. Chalcopyrite (has been mined), pyrrhotite, pyrite, rutile, quartz. COVENTRY. Rhodonite. CRAPTSBURY. Mica in concentric balls, calcite, rutile. DERBY. Mica (adamsite). DUMMERSTON. Rutile, roofing slate. FAIR HAVEN. Roofing slate, pyrite. ' FLETCHER. Pyrite, magnetite, acicular tourmaline. GRAFTON. The steatite quarry referred to Graf ton is properly in Athens ; quartz, acti- GUILFORD. Scapolite, rutile, roofing slate. HARTFORD. Calcite, pyrite! cyanite in mica slate, quartz, tourmaline. IR ASBURGH . Rhodonite, psilomelane. JAY. Chromic iron, serpentine, amianthus, dolomite. LOWELL. Picrosmine, amianthus, serpentine, cerolite, talc, chlorite. MARLBORO'. Rhomb spar, steatite, garnet, magnetite, chlorite. MENDON. Magnetic iron ore. MIDDLEBURY. Zircon. MIDDLESEX. Rutile ! (exhausted). MONKTON. Pyrolusite, brown iron ore, pipe clay, feldspar.. MORF-TOWN. Smoky quartz! steatite, talc, wad, rutile, serpentine. MORRISTOWN. Galenite. MOUNT HOLLY. Asbestus, chlorite. NEW FANE. Glassy and axbextiform actinolite, steatite, green quartz (called chrysoprase AMERICAN LOCALITIES. 477 t the locality), chalcedony, drusy quartz, garnet, chromic and titanic iron, rhomb par, o^nc^- Actinolite. feldspar, brown spar in talc, cyanite, zoisite, chalcopyrite, pyrite. PiTTSFOiiD.- Brown iron ore, manganese ores. PLYMOUTH. Siderite, magnetite, hematite, gold, galemte. PLYMPTON. Massive hornblende. PUTNEY. Fluorite, brawn iron ore, rutile, and zoisite, in boulders, staurohte. READING. Glassy 'actinolite in talc. _ READSBORO'. Ulassy actinolite, steatite, hematite RIPTON Brown iron ore, augite in boulders, octahedral pyrite. ROCHESTER. ttutile, hematite cryst., magnetite in chlorite slate. ROCKINGHAM (Bellows Falls). Cyanite, indicolite, feldspar, tourmaline, fluorite, caloite, torehuite, staurolite. ROXBURY. Dolomite, talc, serpentine, asbestus, quartz. RUTLAND. Magnetite, white marble, hematite, serpentine, pipe clay. SALISBURY. Brown iron ore. SHARON. Quartz crystals, cyanite. SHOREHAM. Pyrite, black marble, calcite. SHREWSBURY. Magnetite and chalcopyrite. STARKSBORO'. Brown iron ore. STIRLING. Chalcopyrite, talc, serpentine. STOCKBRIDGE Arsenopyrite, magnetite. STRAPFORD. -Magnetite and chalcopyrite (has been worked), native copper, hornblende, ^HETFORD.-Blende, galenite, cyanite, chrysolite in basalt, pyrrhotite, feldspar, roofing TOWNSHENIX ^Actinolite, black mica, talc, steatite, feldspar. TR ? -Magnetite, talc, serpentine, picrosmine, amianthus steatite, one mile southeast of village of South Troy, on the farm of Mr. Pierce, east side of Missisco, chromite, zaratite. VERSHIRE Pyrite, chalcopyrite, tourmaline, arsenopyrite, quartz. \V\RDSBOKO'. Zowte, tourmaline, tremohte, hematite. WARREN. Actinolite, magnetite, wad, serpentine. WATERBURY. -Arsenopyrite, chalcopyrite, rutile, quartz, serpentine. WATERVILLE Steatite, actinolite, talc. WEATHERSFIELD. -Steatite, hematite, pyrite, tremohte. WELLS' RIVER. Graphite. WESTFIELD. Steatite, chromite, serpentine. WESTMINSTER. Zoisite in boulders. WINDHAM. lassy actinolite, steatite, garnet, serpentine. WOODBURY. Massive pyrite. WOODSTOCK. Quartz crystals, garnet, zoisite. MASSACHUSETTS. ALPORD. Galenite, pyrite. ATliois.Allanite, fibrolite (?), epidote! babmgtomte ? AUBURN. Masonite. BARRE. Entile! mica, pyrite, beryl, feldspar, garnet. GREAT BARRINGTON. Tremolite. BEDFORD. Garnet. BELCHERTON. Allanite. BERNARDSTON. Magnetite. o.- jrtdto, .*, , nesite rhomb spar, alianite, yttroceriU! cerium ochre? (on the scapo BoxBOROUen. Scapolite, spinel, garnet, augite, actinolite, apat to Warren). lolite, adularia, molybdenite, mica, garnet. garnet/ scapolite, actinoh'te. , Q i TinlifA e, laumontite, stilbite, chabazite, quartz crystals, ^elanolite. (chelmsfordite), chmdrodite, blu* spinel, amianU quartz. 478 APPENDIX. CHESTER. Hornblende, scapolite, zoisite, spodumene, indicolite, apatite, magnetite, chro mite, stilbite, heulandite, analcits and chabazite. At the Emery Mine, Chester Factories. Corundum, margarite, diaspore, epidote, corundophilite, chloritoid, tourmaline, menaccan* ite ! rutile, biotite, indianite ? andesite ? cyanite, amesite. CHEST KRFIELD. Blue, green, and red tourmaline, cleavelandite (albite), lepidolite, smofo, quartz, microlite, spodumene, cyanite, apatite, rose beryl, garnet, quartz crystals, stanrolite> cassiterite, columbite, zoisite, uranite, brookite (eumanite), scheelite, anthophyllite, bornite, CONWAY. -Pyrolusite, fluorite, zoisite, rutile! ! native alum, galenite. CUMMIN GTON. Rhodonite! cummingtonite (hornblende), marcasite, garnet. DEDHAM. Asbestus, galeiiite. DEERFIELD. Chabazite, heulandite, stilbite, amethyst, carnelian, chalcedony, agate. FITCHBDHG (Pearl Hill). Beryl, staurolite! garnets, molybdenite. FOXBOROUGH. Pyrite, anthracite. FRANKLIN. Amethyst. GOSHEN. Mica, albite, spodumene! blue and green tourmaline, beryl, zoisite, smoky quartz, columbite, tin ore, galenite, beryl (goshenite), pihlite (cymatolite). GREENFIELD (in sandstone quarry, half mile east of village). Allophane, white and greenish. HATFIELD. Barite, yellow quartz crystals, galenite, blende, chalcopyrite. HAWLEY. Micaceous iron,, massive pyrite, magnetite, zoisite. HEATH. Pyrite, zoisite. HINSDALE. Brown iron ore, apatite, zoisite. HUBBARDSTON. Massive pyrite. LANCASTER. Cyanite, chiastolite! apatite, staurolite, pinite, andalusite. LEE. Tremolite! sphene! (east part). LENOX. Brown hematite, gibbsite(?) LEVERETT. Barite, galenite, blende, chalcopyrite. LEYDEN. Zoisite, rutile. LITTLEFIELD. Spinel, scapolite, apatite. LYNNFIELD. Magnesite on serpentine. MARTHA'S VINEYARD. Brown iron ore, amber, selenite, radiated pyrite. MENDON. Mica ! chlorite. MIDDLEFIELD. Olassy actinolite, rhomb spar, steatite, serpentine, feldspar, drusy quartz, apatite, zoisite, nacrite, chalcedony, talc/ deweylite. MILUURY. Vermicidite. MONTAGUE. Hematite. NEWBURY. Serpentine, chrysotile, epidote, massive garnet, siderite. NEWBURYPORT. Serpentine, nemalite, uranite. Argentiferous galenite, tetrahedrite, chalcopyrite, pyrargyrite, etc. NEW BRAINTREE. Black tourmaline. NORWICH. Apatite! black tourmaline, beryl, spodumene! triphylite (altered), blende, quartz crystals, cassiterite. NORTHFIELD. Columbite, fibrolite, cyanite. PALMER (Three Rivers). Feldspar, prehnite, calc spar. PELHAM. Asbestus, serpentine, quartz crystals, beryl, molybdenite, green hornstone, epidote, amethvst, corundum, vermiculite (pelhamite). PLAINFIELD. Cummingtonite,, pyrolutite, rhodonite. RICHMOND. Brown iron ore, gibbsite! allophane. ROCKPORT. Danalite, cryophyllite,. annite, cyrtoUte (altered zircon), green and white ortJio- dase. ROWE. Epidote, talc. SOUTH ROYALSTON. Beryl ff (now obtained with great difficulty), mica/ f feldspar/ allanite. Four miles beyond old loc., on farm of Solomon Hey wood, mica / beryl / j eldspar! menaccanite. RUSSEL. Schiller spar (diallage ?), mica, serpentine, beryl, galenite, chalcopyrite. SALEM. In a boulder, cancrinite, sodalite, elaeolite. SAUGUS. Porphyry, jasper. SHEFFIELD. Asbestus, pyrite, native alum, pyrolusite, rutile. SHELBURNE. Rutile. SHUTESBURY (east of Locke's Pond). Molybdenite. SOUTHAMPTON. Galenite, cerussite, anglesite, wulfenite, fluorite, barite, pyrite, chalcopy- rite, blende, corneous lead, pyromorphite, stolzite, chrysocolla. STERLING. Spodumene, chiastolite, siderite, arsenopyrite, blende, galenite, chalcopyrite. pyrite, sterlingite (damourite). STONEHAM. Nephrite. AMERICAN LOCALITIES. STURBRIDGE. Graphite, garnet, apatite, bog ore. SWAMPSCOT. Orthite, feldspar. TAUNTON (one mile south). Paracolumbite (titanic iron). TURNER'S FALLS (Conn. River). Chalcopyrite, prehnite, chlorite, chtorojhaite siderite raalachite, magnetic iron sand, anthracite. TYRINGHAM. Pyroxene, scapolite. UXBRIDGE. Galenite. WARWICK. Massive garnet, radiated black tourmaline, magnetite, beryl, epidote. WASHINGTON. Graphite. WESTFIELD. Schiller spar (diailage), serpentine, steatite, cyanite, scapolite, actinolite. WESTPORD. Andalusite ! WEST HAMPTON. Galenite, argentine, pseudomorpJwus quartz. WEST SPRINGFIELD. Prehnite, ankerite, satin spar, celestite, bituminous coal. WEST STOCKBRIDGE. Hematite, fibrous pyrolusite, siderite. WHATELY. Native copper, galenite. WILLIAMSBURG. Zoisite, pseudomorphous quartz, apatite, rose and smoky quartz, galeaite pyrolusite, chalcopyrite. WILLIAMSTOWN. Cryst. quartz. WINDSOR. Zoisite, actinolite, rutile! WORCESTER. Arsenopyrite, idocrase, pyroxene, garnet, amianthus, bucholzite, siderite, galenite. WORTHTNGTON. Cyanite. ZOAR. Bitter spar, talc. RHODE ISLAND. BRISTOL. Amethyst. COVENTRY. Mica, tourmaline. CRANSTON. Actinolite in talc, graphite, cyanite, mica, melanterite, bog iron. CUMBERLAND. Manganese, epidote, actinolite, garnet, titaniferous iron, magnetite, red hematite, chalcopyrite, bornite, malachite, azurite, calcite, apatite, feldspar, zoisite, mica, quartz crystals, ilvaite. DIAMOND HILL. Quartz crystals, hematite. FOSTER. Cyanite, hematite. GLOUCESTER. Magnetite in chlorite slate, feldspar. JOHNSTON. Talc, brown spar, calcite, garnet, epidote, pyrite, hematite, magnetite, chal- copyrite, malachite, azurite. LIME ROCK. Calcite crystals, quartz pyrite. LINCOLN. Calcite dolomite. NATIC. See WARWICK. NEWPORT. Serpentine, quartz crystals. PORTSMOUTH Anthracite, graphite, asbestus, pyrite, chalcopyrite. SMITHFIELD. Dolomite, calcite, bitter spar, siderite, nacrite, serpentine (bowenite), tremo- lite, asbestus, quartz, magnetic iron in chlorite slate, talc! octahedrite, feldspar, beryl. VALLEY FALLS. Graphite, pyrite, hematite. WARWICK (Natic village). Masonite, garnet, graphite, bog iron ore. WESTERLY. Menaccanite. Woo NSOCKET. Cyanite . CONNECTICUT. BEKLIN. Barite, datolite, blende, quartz crystals. BOLTON. Staurolite, chaloopyrite . BRADLEYVILLE (Litchfield). Laumontite. BRISTOL. Chalcocite! chakopyrite, barite, bornite, talc, attophane, pyromorphite, calcify malachite, galenite, quartz. BROOKFIELD. Galenite, calamine, blende, spodumene, pyrrhotite. CANAAN. Tremolite and white augite! in dolomite, canaanite (massive pyroxene). CHATHAM. Arsenopyrite, smaltite, chloanthite (ehathamite), scorodite, niccolite, ueryt, erythrite. CHESHIRE. Barite, chalcocite, bornite cryst>, malachite, kaolin, natrclite, prehnite, cba isite, datolite. CHESTER. Sillimanite/ zircon, epidote. 480 APPENDIX. CORNWALL. Graphite, pyroxene, actinolite, sphene, scapolite. D ANBURY. Danburite, oligodase, moonstone, brown tourmaline, orthoclase, pyroxene, parathorite. FARMINGTON. Prehnite, chabazite, agate, native copper ; in trap, diabantite. GRANBY. Green malachite. GREENWICH. Black tourmaline. HADDAM. Chrysoberyl ! beryl! epidote! tourmaline! feldspar, garnet! iolite! oligoctage, thlorophyttite ! automolite, magnetite, adularia, apatite, columbite ! (hermannolite), zircon (calyptolite), mica, pyrite, marcasite, molybdenite, allanite, bismuth, bismuth ochre, bismn- tite. HADLYME. Chabazite and stilbite in gneiss, with epidote and garnet. HARTFORD. Datolite (Rocky Hill quarry). KENT. Brown iron ore, pyrolusite, ochrey iron ore. LITCHFIELD. Cyanite with corundum, apatite, and andalusite, menaccanite (Washington- ite), chalcopyrite, diaspore, niccoliferous pyrrhotite, margarodite. LYME. Garnet, sunstone. MERIDEN. Datolite. MIDDLEFIELD FALLS. Datolite, chlorite, etc., in amygdaloid. MIDDLETOWN. Mica, lepidolitt with green and red tourmaline, albite, feldspar, columbite! prehnite, garnet (sometimes octahedral), beryl, topaz, uranite, apatite, pitchblende ; at lead mine, galenite, chalcopyrite, blende, quartz, calcite, fluorite, pyrite, sometimes capillary. MILFORD. Sahlite, pyroxene, asbestus, zoisite, verd-antique, marble, pyrite. NEW HAVEN. Serpentine, asbestus, chromic iron, sahlite, stilbite, prehnite, chabazite, gmelinite, apophyllite, topazalite. NEWTOWN. Cyanite, diaspore, rutile, damourite, cinnabar. NORWICH. Sittimanite, monazite ! zircon, iolite, corundum, feldspar. OXFORD, near Humphreys ville. Cyanite, chalcopyrite. PLYMOUTH. Galenite, heulandite, fluorite, chlorophyUite ! garnet. READING (near the line of Danbury). Pyroxene, garnet. ROARING BROOK (Cheshire). Datolite ! calcite, prehnite, saponite. ROXBURY. Siderite, blende, pyrite! ! galenite. quartz, chalcopyrite, arsenopyrite, limon- le. SALISBURY. Brown iron ore, ochrey iron, pyrolusite, triplite, turgite. SAYBKOOK. Molybdenite, stilbite, plumbago. SEYMOUR. Native bismuth, arsenopyrite, pyrite. STMSBURY. Copper glance, green malachite. SOUTHBURY. Rose quartz, laumontite, prehnite, calcite, barite. SOUTHINGTON. Barite, datolite, asteriated quartz crystals. STAFFORD. Massive pyrites, alum, copperas. STONINGTON. Stilbite and chabazite on gneiss. TARIFFVILLE. Datolite. THATCHERSVILLE (near Bridgeport). Stilbite on gneiss, babingtonite ? TOLLAND. Staurolite, massive pyrites. TRUMBULL and MONROE. Chlorophane, topaz, beryl, diaspore, pyrrhotite, pyrite, nicco- lite, scheelite, wolframite (pseudomorph of scheelite), rutile, native bismuth, tungstic acid, siderite, mispickel, argentiferous galenite, blende, scapolite, tourmaline, garnet, albite, augite, graphic tellurium (?), margarodite. WASHINGTON. Triplite, menaccanite! (washingtonite of Shepard), rhodochrosite, natro- lite, andalusite (New Preston), cyanite. WATERTOWN, near the Naugatuck. White sahlite, monazite. WEST FARMS. Asbestus. WILLIMANTIC. Topaz, monazite, ripidolite. WINCHESTER and WILTON. Asbestus, garnet. NEW YORK. ALBANY CO. BETHLEHEM. Calcite, stalactite, stalagmite, calcareous sinter, snowy gypsum. COEYMAN'S LANDING, Gypsum, epsom salt, quartz crystals at Crystal Hill, three milea outh of Albany. QUILDERLAND. Petroleum, anthracite, and calcite, on the banks of the Norman's Kill ; two miles south of Albany. WATERVLIKT. Quarto crystals^ yellow dnisy quarto. AMERICAN LOCALITIES. 481 ULLEGHANY CO. CUBA. Calcareous tula, petroleum, 3* miles from the village. CATT ARAUGUS CO. FREEDOM. Petroleum. CAYUGA CO. AUBURN. Celestite, calcite, fluorspar, epsomite. CAYUGA LAKE. Sulphur. LUDLOWVILLE. Epsomite. UNION SPRINGS. Selenite, gypsum. SpRWGPORT.-At Thompson's plaster beds, sulphur! selemte. SPRINGVILLE. Nitrogen springs. CLINTON CO ARNOLD IRON MINE. Magnetite, epidote, molybdenite. FINCH ORE BED.-C&Wfc, green and purple fluor. CHATAUQUE CO. FREDONIA. Petroleum, carburetted hydrogen. L AON A. Petroleum. SHERIDAN. Alum. COLUMBIA CO. AuOTERLiTE.-2Rir% manganese, wnlfenite, chalcocite ; Livingstor m cubic crystals in slate (Hillsdale). . Chalcocite, chalcopyrite. eps'om salt, brown spar, wad. DUTCHESS CO AMENIA. Dolomite, Umonite, turgite. =:H!^ lite hydrous anthophyllite, Umonite. NORTH EAST. -Chalcocite, chalcopyrite, galemte, blende. H.-', green feldspar, epidote, tourmaline. UNION VALE. At the Clove mine, gibbsite, limomte. Sgj^SS|3Sft^^^^ epidote, mica. , garnet, taMMU, ******, aotinoUte; too miles , **,// ^, magnetite, * ; in the toWD OT albit; in the toWD of Moriah, magnetite, 6tecfc m^a ; Barton Hil Ore Bed atoto. Xvwco*LV.-Labrne mile south of Little Falls, calcite. brown spar, feldspar. MIDDLE VILTK. Quartz crystals! r.alcite, brown and pearl spar, anthracite. NEWPORT. Quartz crystals. SALISBURY. Quartz crystals f blende, galenite, pyrite, chalcopyrite. STARK. Fibrous celestite, gypsum. HAM [LTON CO. LONG LAKE. Blue calcite. JEFFERSON CO. ADAMS. Fluor, calc tufa, barite. ALEXANDRIA. On the S.E. bank of Muscolonge Lake, fluorite, phlogopite, chalcopyrite, apatite; on High Island, in the St. Lawrence River, feldspar, tourmaline, hornblende, ortho- clase. celestite. ANTWERP. Stirling iron mine, hematite, chalcodite, siderite, miUerite, red hematite, crys taJiized quartz, yellow aragonite, niccolit'erous pyrite, quartz crystals, pyrite ; at Oxbow, col- cite ! porous coralloidal heavy spar ; near Vrooman's lake, calcite ! vesuvianite, phtoffvpite ! pyroxene, sphene, fluorite, pyrite, chalcopyrite ; also feldspar, bog-iron ore, scapolite (farm ol David Eggleson), serpentine, tourmaline (yellow, rare). BROWNSVILLE. Celestite in slender crystals, calcite (four miles from Watertown). NATURAL BRIDGE. Feldspar, gieseckite! steatite pseudomoj-phous after pyroxene, apatite. NEW CONNECTICUT. Sphene, brown phlogopite. OMAR. Beryl, feldspar, hematite. PHILADELPHIA. Garnets on Indian river, in the village. PAMELIA. Agaric mineral, calc tufa. PIERREPONT. Tourmaline, sphene, scapolite, hornblende. PILLAR POINT. Massice barite (exhausted). THERESA. Fluorite, calcite, hematite, hornblende, quartz crystals, serpentine (associated with hematite), celestite, strontianite ; the Muscolonge Lake locality of fluoris exhausted. WATERTOWN. Tremolite, agaric mineral, calc tufa, celestite. WILNA. One mile north of Natural Bridge, calcite. LEWIS CO. DIANA (localities mostly near junction of crystalline and sedimentary rocks, and within two miles of Natural Bridge). Scapolite! wollastonite, green coccolite, feldspar, tremolite, pyroxene ! sphene.! ! mica, quartz crystals, drusy quartz, cryst. pyrite, pyrrhotite. blue calcite, serpentine, renssefaerite, zircon, graphite, chlorite, hematite, bog-iron ore, iron Band, apatite. GREIG. Magnetite, pyrite. LOWVILLE. Calcite, fluorite, pyrite, galenito, blende, calc tufa. MARTINSBIJRGH. Wad, galenite, etc., but mine not now opened, calcite. WATSON, BREMEN. Bog-iron ore. MONROE CO. ROCHESTER. Pearl spar, calcite, snowy gypsum, fluor, celestite, galenite, blende, barite, hornstone. MONTGOMERY CO. CAN A JOH ABIE. Anthracite. PALATINE. Quartz crystals, drusy quartz, anthracite, hornstone, agate, garnet. ROOT. Drusy quartz, blende, barite, stalactite, stalagmite, galenite, pyrite. NEW YORK CO. CORLEAR'S HOOK. Apatite, brown and yellow feldspar, sphene. KINGSBRIDGE. Tremolite, pyroxene, mica, tourmaline, pyrites, rutile, dolomite. HARLKM. Epidote, apophyilite, stilbite, tourmaline, vivianite, lamellar feldspar, mica. NEW YORK. Serpentine, amianthus, actinolite, pyroxene, hydrous anthophyllite, garnet, staurolite, molybdenite, graphite, chlorite, jasper, necronite, feldspar. In the excavations foi tlio 4th Avenue tunnel, 1875, harmotome, stilbite, chabazite, heulandite, etc. AMERICAN LOCALITIES. 483 NIAGARA CO. LEWISTON. Epsomite. LOCKPORT. Celestite, calcite, selenite, anhydrite, fluonte, dolomite, blende. NIAGARA FALLS.- -Calcite, fluorite, blende, dolomite. ONEIDA CO. BOONVILLE. Calcite-. wollastonite, coccoUte. CLINTON. Blende, lenticular argillaceous iron ore ; in rocks of the Clinton Group, Btronti anite, celestite, the former covering the latter. OXOXDAGA CO CAMILLUS. Selenite and fibrous gypsum. COLD SPRING. Axinite. MAN LI us. Gypsum and fluor. SYRACUSE. Serpentine, celestite, selenite, bante. ORAXGE CO. CORNWALL. Zircon, chondrodite, Jwrnblende, spind, massive feldspar, fibrous epidote, hudsonite, menaccanite, serpentine, coccolite. DEER PARK. Cryst. pyrite, galenite. MONROE. Mica! sphene ! garnet, colophonite, epidote, chondrodite, allanite, bucholzite, brown spar, spinel, hornblende, talc, menaccanite, pyrrlwtite, pyrite, chromite, graphite, raa- tolyte, moronolite. At WILKS and O'NEIL Mine in Monroe. Aragomte, magnetite, dimagnetite (pseud. ?), jen kinsite, asbestus, serpentine, mica, hortonolite. At Two PONDS in Monroe. Pyroxene! chondrodite, Jwrnblende, scapohte ! zircon, sphene, At GREENWOOD FURNACE in Monroe. Chondrodite, pyroxene ! mica, hornblende, spinel, scapolite, biotite! menaccanite. At FOREST OF DEAN. Puroxene, spinel, zircon, scapohte, hornblende. TOWN OF WARWICK, WARWICK VILLAGE. Spinel! zircon, serpentine! brown spar, pyrox- ene ' hornblende! pseudomorphous steatite, feldspar ! (Rock Hill), menaccanite, dintomte, tourmaline (R. H.), rutile, sphene, molybdenite, arsenopyrite, marcasite, pyrite, yellow 11 uartz iasper, mica, coccolite. ' Spinel f garnet, scapolite, hornblende, vesuvianite, epidote! dintomte! magnetite, tourmaline warwickite, apatite, chondrodite, talc! pyroxene! rutile, menaccanite, zircon, corundum, 'feldspar, sphene, calcite, serpentine, schiller spar (?) silvery mica. E3ENVILLE Apatite, chondrodite! hair-brown hornblende ! tremolite, spinel, tourmaline, wancickite, pyroxene, sphene, mica, feldspar, mispickel, orpiment, rutile, menaccanite, sc dite, chalcopyrite, leucopyrite (or lollingite), allanite WEST POINT. Feldspar, mica, scapolite, sphene, hornblende, allanite. PUTXAM CO BREWSTER. Tilly Foster Iron Mine. Ghondrodite! (also humite and olino- humite) crystals very rare, magnetite, dolomite, serpentine pseudomorphs, brucite, enstatite, ripidolite, biotite, actinolite, apatite, pyrrhotite, fluorite, albite, epidote sphene. CAHMEL (Brown's quarry ).-Anthophyllite, schiller spar (?), orpiment, arsenopyrite, ept- dote. COLD SPRING. Chabazite, mica, sphene, epidote. . PATTERSON. W/tite pyroxene f calcite, asbestm, trenwlite, dolomite massive pyrite PIIILLIPSTOWN Treinolite, amianthm, serpentine, sphene, diopside, green coccohte, n< blende, scapolite, stilbite, mica, laumontite, gurhofite, calcite, magnetite, chroi PHILLIPS Ore Bed. Hyalite, actinolite, massive pyrite. REXSSELAER CO. Hoosic. Xitrogen springs. LANSINGP.URGH. Epsomite. quartz crystals, pyrite. TROY. Quartz crystals, pyrite, selenite. RICHMOND CO. ROSSVILLE. Lignite, cryst. pyrite. QUARANTINE. Asbestus, amianthus, aragonite, dolomite, gurlwjite, ttilc, magnesite. ROCKLAND CO. CALDWELL. Calcite. GRASSY POINT. Serpentine, actinolite. , HAVERSTRAW. Hornblende, barite. LADENTOWN. Zircon, malachite, cuprite. .iitfl r.yia.bftaite PiERMONT.-Datolite, stilbite, apophyllite, strllite, prehmte, thomsomte ; ca ite, CB STONY POINT. Cerolite, lamellar hornblende, asbestus. 484 APPENDIX. ST. LAWRENCE CO. CANTON. Massiv . pyrite, calcite, brown tourmaline, sphene, ser- pentine, talc, rensselaerite, pyroxene, hematite, chalcopyrite. DEKALB. Hornblende, barite, fluorite, tremolite, tourmaline, blende, graphite, pyroxene, quartz (spongy), serpentine. EDWARDS. Brown and silvery mica ! scapolite, apatite, quartz crystals, actinolite, treno- lite! hematite, serpentine, magnetite. FINE. Black mica, hornblende. FOWLER. Barite, quartz crystals! hematite, blende, galenite, tremolite, chalcedony, bog ore, satin spar (assoc. with serpentine), pyrite, chalcopyrite, actinolite, rensselaerite (neai Somerville). GOUVERNEUR. Calcite ! serpentine! hornblende! scapolite! orthockise, tourmaline! ido- crase (one mile south of G-.), pyroxene, malacolite, apatite, rensselaerite, serpentine, sphene, fluorite, barite (farm of Judge Dodge), black mica, phlogopite, tremolite ! asbestus, hematite, graphite, vesuvianite (near Somerville in serpentine), spinel, houghite, scapolite, phlogopite, dolomite ; three-quarters of a mile west of Somerville, chondrodite, spinel ; two miles north of Somerville, apatite, pyrite, brown tourmaline! ! HAMMOND. Apatite! zircon! (farm of Mr. Hardy), ortfioclase (loxocase), pargasite, barite, pyrite, purple fluorite, dolomite. HERMON. Quartz crystals, hematite, siderite, pargasite, pyroxene, serpentine, tourma- line, bog- iron ore. MACOMB. Blende, mica, galenite (on land of James Averil), sphene. MINERAL POINT, Morristown. Fluorite, blende, galenite, phlogojMe (Pope's Mills), barite. OGDENSBURG. Labradorite. PITCAIRN. Satin spar, associated with serpentine. POTSDAM. Hornblende! eight miles from Potsdam, on road to Pierrepont, feldspar, i/mrmaline, black mica, hornblende. ROSSIE (Iron Mines). Barite, hematite, coralloidal aragonite in mines near Somerville, limonite, quartz (sometimes stalactitic at Parish iron mine), pyrite, pearl spar. ROSSIE Lead Mine. Galcite! galenite! pyrite, celestite, chalcopyrite, hematite, cerussite, anglesite, octahedral ' fluor, black phlogopite. Elsewhere in ROSSTE. Calcite, barite, quartz crystals, chondrodite (near Yellow Lake), feldspar ! pargasite ! apatite, pyroxene, hornblende, sphene, zircon, mica, fluorite, serpen- tine, automolite, pearl spar, graphite. RUSSEL. Pargasite, specular iron, quartz (dodec.), calcite, serpentine, rensselaerite, magnetite. SARATOGA CO. GREENFIELD. Chrysoberyl! garnet! tourmaline! mica, feldspar l apatite, graphite, aragonite (in iron mines). SCHOHARIE- CO. BALL'S CAVE, and others. Calcite, stalactites. CARLISLE. Fibrous barite, cryst. and fib. calcite. MIDDLEBURY. Anthracite, calcite. SHARON. Calcareous tufa. SCHOHARIE. Fibrous celestite, strontianite ! cryst. pyrite! SENECA CO. CANOQA. Nitrogen springs. SULLIVAN CO. WURTZBORO'. Galenite, blende, pyrite, chalcopyrite. TOMPKINS CO ITHACA. Calcareous tufa. ULSTER CO. ELLENVILLE. Galenite, blende, chalcopyrite ! quartz, brookite. MARBLETOWN. Pyrite. WARREN CO. CALDWELL. Massive feldspar. CHESTER. Pyrite, tourmaline, rutile, chalcopyrite. DIAMOND ISLE (Lake George). Galcite, quartz crystals. GLENN'S FALLS. Rhomb spar. JOHNSBURG. Fluorite! zircon! ! graphite, serpentine, pyrite. WASHINGTON CO. FORT ANN. Graphite, serpentine. GRANVILLE. LameUar pyroxene, massive feldspar, epidute. WAYNE CO. WOLCOTT. Barite. AMERICAN LOCALITIES. 485 WESTCHESTFR CO. ANTHONY'S NOSE. Apatite, pyrite, calcite! in very large tabulai crystals, grouped, and sometimes incrusted with drusy quartz. DAVENPORT'S NECK. Serpentine, garnet, sphene. E A STCIIESTER.- Blende, pyrite, chalcopyrite, dolomite. HASTINGS. Tremolite, white pyroxene. NEW ROCIIELLE. Serpentine, brucite, quaitz, mica, tremolite, garnet, magnesite. PEEKSKILL. Mica, feldspar, hornblende, stilbite, sphene; three miles south, emery. R YE Serpentine, chlorite, black tourmaline, tremolite. SINGSING. Pyroxene, tremolite, pyrite. beryl, azurite, green malachite, cerussite, pyromor phite, anglesite, vauquelinite, gaJenite, native silver, chalcopyrite. WEST FARMS. Apatite, tremolite, garnet, stilbite, heulandite, chabazite, epidote, sphene YONKERS Tremolite, apatite, calcite, analcite, pyrite, tourmaline. YORKTOWN. Sitttmamte, monazile, magnetite. NEW JERSEY. ANDOVER IRON MINE (Sussex Co.). Willemite, brown garnet. ALLEN TOWN (Monmouth Co.). Vivianite, dufrenite. BELVILLE. Copper mines. BERGEN. Calcite! datolite! pectolite (called stellite) ! analcite, apophyllite! gmelimte, prehnite, sphene, stilbite, natrolite, heulandite, laumontite, chabazite, pyrite, pseudomorphons steatite, imitative of apophyllite, diabantite. BRUNSWICK. Copper mines; native copper, malachite, mountain leather. BRYAM. Chondrodite, spinel, at Roseville, epidote. CANTWELL'S BRIDGE (Newcastle Co.), three miles west. Vivian ite. DANVILLE (Jemmy Jump Ridge). Graphite, chondrodite, augite, mica. FLEMINGTON. Copper mines. FRANKFORT. Serpentine. v. FRANKLIN and STERLING. Spinel! garnet! rhodonite f willemite! frankhnite! zincite! dwluite >' hornblende, tremolite. chondrodite, white scapolite, black tourmaline, epidote, pink calcite 'mica, actinolite, augite, sahlite, coccolite, asbestus, jeffersonite (augite), ealamine, srraphite fluorite, beryl, galenite, serpentine, honey-colored sphene, quartz, chalcedony amethyst zircon, molybdenite, vivianite, tephroite, rhodochrosite, aragonite, sussexite, chal cophanite, roepperite, calcozincite, vanuxemite, gahnite. Also algerite in gran, limestone. FRANKLIN and WARWICK MTS. Pyrite. GREENBROOK. Copper mines. GRIGGSTOWN. Copper mines. HAMBURGH One mile north, spinel/ tourmaline, phlogopite, hornblende, hmonite, hematite. HOBOKEN. Serpentine (marmolite), brucite, nemalite (or fibrous brucite), aragonite, dol mite. HURDSTOWN. Apatite, pyrrhotite, magnetite. IMLEYTOWN. Vivianite. LOCKWOOD. Graphite, chondrodite, talc, augitt, quartz, green spinel. MONTVILLE (Morris Co.). Serpentine, chrysotile. MULLICA HILL (Gloucester Co. }, Vivianite lining belemnites and other iossils NEWTON. Spinel, blue, pink, and white corundum, mica, vesuviamte, hornblende,^ line, scapolite, rutile, pyrite, talc, calcite, barite, pseudomorplwus steatite. PATERSON. Datolite. VERNON. Serpentine, spinel, hydrotalcite. PENNSYLVANIA.* ADAMS CO. GETTYSBURG. Epidote, fibrous and massive. BERKS CO -MoRGANTOWN.-At Jones's mines, one mile east of molaMe, native copper, chrytocolla, magnetite, allophane pyrite ^ ch apatite, talc; two miles N.E. from Jones's mine, graphite, sphene; at mile N.W. from St. Mary's. Chester Co., magnetite, micaceous ^on, coccolite brown garnet. READiNG.-^/n^^/ quartz crystals, zircon, stilbite, iron ore, near Prv cetown , nw ^ ai a ite, epidote; at Eckhardt's Furnace, allanite with zircon ; at Zion s Church, molybc ~* See also the Report on the Mineralogy of Pennsylvania, by Dr. F A. Genth, 187o. 486 APPENDIX. near Kutztown, in the Crystal Cave, stalactites ; at Fritz Island, apophyttite, thomsonite, chaba \ite, calcite, azurite, malachite, magnetite, chalcopyrite, stibnite, prochlorite, precious ser pentine. BUCKS CO. BUCKINGHAM TOWNSHIP. Crystallized quartz; near New Hope, vesuvian ite, epidote, barite. SOUTHAMPTON. Near the village of Feasterville, in the quarry of George Van Arsdale graphite, pyroxene, sahlite, eoccolite, sphcne, green mica, calcite, wollastonite, glassy feid spar sometimes opalescent, phlogopite, blue quartz, garnet, zircon, pyrite. moroxite, scapolite NEW BRITAIN. Dolomite, galenite, blende, malachite. CARBON CO. SUMMIT HILL, in coal mines. Kaolinite. CHESTER CO. AVONDALE. Asbestus, tremolite, garnet, opal. BIRMINGHAM TOWNSHIP. Amethyst, smoky quartz, serpentine, beryl ; in Ab'm Darling ton's lime quarry, calcite. EAST BRADFORD. Near Buffington's bridge, on the Brandywine, green, blue, and gra; cyanite, the gray cyanite is found loose in the soil, in crystals ; on the farms of Dr. Elwyn Mrs. Foulke, Wm. Gibbons, and Saml. Entrikin, amethyst. At Strode's mill, asbestus. mag nesite, anthophyllite, epidote, aquacrepitite, oligoclase, drusy quartz, collyritef on Os borne's Hill, wad, manganesian garnet (massive), sphene, schorl ; at Caleb Cope's lime quarry fetid dolomite, necronite, garnets, blue cyanite, yellow actinolite in talc; near the Blacl Horse Inn, indurated talc, rutile ; on Amor Davis' farm, orthite! massive, from a grain t lumps of one pound weight ; near the paper-mill on the Braudywine, zircon, associated wit] titaniferous iron in blue quartz. WEST BRADFORD. Near the village of Marshalton, green cyanite, rutile, scapolite, pyrite Btaurolite ; at the Chester County Poor-house limestone quarry, chesterlite ! in crystals ira planted on dolomite, rutile ! in brilliant acicular crystals, which are finely terminated, cal cite in scalenohedrons, zoisite, damouritef in radiated groups of crystals on dolomite, quart crystals ; on Smith & McMullin's farm, epidote. CHARLESTOWN. Pyromorphite, wrussite, galenite, quartz. COVENTRY. Allanite, near Pughtown. SOUTH COVENTRY. In Chrisman's limestone quarry, near Coventry village, augiu sphene, graphite, zircon in iron ore (about half a mile from the village). EAST FALLOWFIELD. Soapstone. EAST GOSHEN. Serpentine, asbtxtus, magnetite (loadstone), garnet. ELK. Menaccanite with muscovite, chromite ; at Lewisville, black tourmaline. WEST GOSHEN. On the Barrens, one mile north of West Chester, amianthus, serpentine cellular quartz, jasper, chalcedony, drusy quartz, chlorite, marmolite. indurated talc, mag nesite in radiated crystals on serpentine, hematite, asbestus ; near R. Taylor's mill, chromit in octahedral crystals, deweylite, radiated mag nesite, aragonite, staurolite, garnet, asbestua epidote; zoisite on hornblende at West Chester water- works (not accessible at present). NEW GARDEN. At Nivin's limestone quarry, brown tourmaline, necronite, scapolite, apa tite, brown and green mica, rutile, aragonite, fibrolite, kaolinite, tremolite. KENNETT. Actinolite, brown tourmaline, browu mica, epidote, tremolite, scapolite, ara gonite ; on Wm. Cloud's farm, sunstone! ! ehabazite, spheue. At Pearce's old-mill, zoisite epidote, sunstone ; sunstone occurs in good specimens at various places in the range of horn blende rocks running through this township from N E. to S.W. LOWER OXFORD. Garnets, pyrite in cubic crystals. LONDON GROVE. Rutile, jasper, chalcedony (botryoidal), large and rough quartz crystals epidote ; on Wm. Jackson's farm, yellow and black tourmaline, tremolite, rutile, green mica apatite, at Pusey's quarry, rutile, tremolite. EAST MARLBORO UGH. On the farm of Baily & Brothers, one mile south of Union ville bright yellow and nearly white tourmaline, chesterlite, albite, pyrite ; near Maryborough meet ing-house, epidote, serpentine, acicular black tourmaline in white quartz; zircon in smal perfect crystals, loose in the soil at Pusey's saw-mill, two miles S.W. of Unionville. WEST MARLBOROUGH. Near Logan's quarry, staurolite, cyanite, yellow tourmaline, rutik garnets ; near Doe Run village, hemati'e, scapolite, tremolite ; in R. Baily's limestone quarry two and a half miles S.W. of Unionville, fibrous tremolite, cyanite, scapolite. NEWLIN. On the serpentine barrens, one and a half mile N.E. of Unionville, corundum massive and crystallized, also in crystals in albite, often in loose crystals covered with a thi coating of steatite, spinel (black), talc, picrolite, brucite, green tourmaline with flat pyram idol terminations in albite, unionite (rare) euphyUite* mica in hexagonal crystals, fddspat AMERICAN LOCALITIES. 487 beryl! in hexagonal crystals, one of which weighs 51 Ibs., pyrite in c,-bic crystals, chromic iron, drusy quartz, green quartz, actinolite, emerylite, chloritoid, diallage, oligoclitse ou Johnson Patterson's farm, massive corundum, titaniferous iron, clinochlore, emerylitf crystals in the euphyllite, orthoclase; two miles N. of Unionville, magnetite in octahedral crystals; one mile E. of Unionville, hematite; in Edwards's old limestone quarry, purple fluorite, rutile. EAST NOTTINGHAM. Sand chrome, asbestus, chromite in octahedral crystals, hallite, beryl. WEST NOTTINGHAM. At Scott's chrome mine, chromite, foliated talc, marmolite, serpeu tine, chalcedony, rJwdochrome ; near Moro Phillip's chrome mine, asbextus ; at the magnesia quarry, detceylite, marmolite, magnesite, leelite, serpentine, sand chrome; near Fremont P.O., corundum. EAST PIKELAND. Iron ore. WEST PIKELAND. In the iron mines near Chester Springs, gitjbsite, zircon, turgite, hesna tite (stalactitical and in geodes), gothite. PENN. Garnets, agalmatolite. PENNSBURY. On John Craig's farm, brown garnets, mica; on J. Dil worth's farm, near Fairville, Muscovite! in hexagonal prisms from one-quarter to seven inches in diameter ; in the village of Fairville, sunstone ; near Brinton's ford, on the Brandy wine, chondroditf, sphene t diopside. aufjite. coccolite ; at MendenhalTs old limestone quarry, fetid quartz, sunstone ; at Swain's quarry, crystals of orthoclase. POCOPSON. On the farms of John Entrikin and Jos. B. Darlington, amethyst. SADSBURY. Rutile! ! splendid geniculated crystals are found loose in the soil for seven miles along the valley, and particularly near the village of Parkesburg, where they sometimes occur weighing one pound, doubly geniculated arid of a deep red color; near Sadsbury village, amethyst, tourmaline, epidote, milk quartz. SCHUYLKILL. In the railroad tunnel at PIIOZNIXVILLE, dolomite! sometimes coated with pyrite, quartz crystals, yellow blende, bro>Aite, calcite in hexagonal crystals enclosing pyrile ; at the WHEATLEY, BROOKDALE, and CHESTER COUNTY LEAD MINKS, one and a half mile S. of Phcenixville, pyromorphite! cerussite! galenite, angleite! ! quartz crystals, chalcopy- rite, barite, fluorite (white), stolzite, wulfenite! calcimine, vanadinite, blende! mimetite! descloizite, gothite, chrysocolla, native copper, malachite, azurite, limonite, calcite, sulphur, pyrite, melaconite, pseudomalachite, gersdorffite, chalcocite? covellite. THORNBDRY. On Jos. H. Brinton's farm, muscovite containing acicular crystals of tour- maline, rutile, titaniferous iron. TREDYFFRIN. Pyrite in cubic crystals loose in the soil. UwcnLAN. Massive blue quartz, graphite. WARREN. Melanite, feldspar. WEST G-OSHEN (one mile from West Chester). Chromite. WILLISTOWN. Magnetite, chromite, actinolite, asbestus. WEST-TOWN. On the serpentine rocks, 3 miles S. of West Chester, clinocJilore ! jeffermte! mica, asbestus, actinolite, magnesite, talc, titaniferous iron, magnetite and massive tourma- line. EAST WHITELAND. Pyrite, in very perfect cubic crystals, is found on nearly every farm in this township, quartz crystals found loose in the soil. WEST WHITELAND. At Gen. Trimble's iron mine (south-east), stalactitic hematite! wavellite ! ! in radiated stalactites, gibbsite, coeruleolactile. WARWICK. At the Elizabeth mine and Keim's old iron mine adjoining, one mile JN. ol Knauertown, aplome garnet! in brilliant dodecahedrons. Jto*fcrri, pyroxene, micaceous liemo- tite, pyrite in bright octahedral crystals in calcite, chrysocolla, chalcopyrite massive single tetrahedral crystals, magnetite, fasciailar hornblende! bornite, malachite, brown 9 ( "'^ calcite, byssolite! serpentine; near the village of St. Mary's, magnetite in dodecahedra crystals, melanite, garnet, actinolite in small radiated nodulea ; at the Hopewell iron n me, one mile N.W. of St. Mary's, magnetite in octahedral crystals. COLUMBIA CO. At Webb's mine, yellow blende in calcite ; near Bloomburg, cryst. mag netite. DAUPHIN CO. NEAR HUMMERSTOWN. Green garnets, cryst. smoky quartz, feldspar. DELAWARE CO. ASTON TOWNSHIP. Amethyst, corundum, emerylite lite, black tourmaline, margarite, sunstone, asbestus, anthophyllite, steatite- mill, garnet, staurolite ; at Peter's mill-dam in the creek, pyrope garnet. 488 APPENDIX. BIRMINGHAM. Fibrolite, kaolin (abundant), crystals of rutile, amethyst; at Bullock's old quarry, zircon, bucJwlzite, nacrite, yellow crystallized quartz, feldspar. BLUE HILL. Green quartz crystals, spinel. CHESTER. Amethyst , black tourmaline, beryl, crystals of feldspar, garnet, cryst. pyrite, molybdenite, molybdite, chalcopyrite, kaolin, uraninite, muscocite, orthoclase, bismutite. CHICIIESTER. Near Trainer's mill-dam, beryl, tourmaline, crystals of feldspar, kaolin; on Wm. Eyre's farm, tourmaline. CONCORD. Crystals of mica, crystals of feldspar, kaolin abundant, drusy quartz of a bluf and green color, meerschaum, stellated tremolite, some of the rays 6| in. diameter, antho- phyttite, fibrolite, acicular crystals of rutile, pyrope in quartz, amethyst, actinolite, mangane- sian garnet, be>yl : in Green's creek, pyrope ganiet. DARBY. Blue and gray cyanite, garnet, staurolite, zoisite, quartz, beryl, chlorite, mica, limonite. EDGEMONT. Amethyst, oxide of manganese, crystals of feldspar ; one mile east of Edge mont Hall, rutile in quartz. ( GREEN'S CREEK. Garnet (so-called pyrope). HAVERPORD. Staurolite with garnet. MAUPLE. Tourmaline, andalusite, amethyst, actinolite, antJiophyllite, talc, radiated actin- olite in talc, chromite, drusy quartz, beryl, cryst. pyrite, menac&aniie in quartz, chlorite. MIDDLETOWN. Amethyst, beryl, black mica, mica with reticulated magnetite between the plates, manganesian garnets ! large trapezohedral crysials, some 3 in. in diameter, indurated talc, hexagonal crystals of rutile, crystals of mica, green quartz! anthophylhte, radiated tour- maline, staurolite, titanic iron, fibrolite, serpentine ; at Lenni, chlorite, gieen and bronze vermiculite ! green feldspar ; at Mineral Hill, fine crystals of corundum, one of which weighs 1 lb., actinolite in great variety, bronzite, green feldspar, moonstone, sunstone, graphic granite, magnesite, octahedral crystals of chromite in great quantity, beryl, chalcedony, asbestus, fibrous Jiornblende, rutile, staurolite, melanosiderite, hallite ; at Painter's Farm, near Dismal Run, zircon wiih oligoclase, tremolite^ tourmaline ; at the Black Horse, near Media, corundum ; at Hibbard's Farm and at Fairlamb's Hill, chromite in brilliant octahe- drons. NEWTOWN. Serpentine, hematite, enstatite, tremolite. UPPER PROVIDENCE. AnthophyUite, tremolite, radiated asbe.stus, rad>ated actinolite, tour- maline, beryl, green feldspar, amethyst (one found on Morgan Hunter's farm weighing over 7 Ibs.), andalusite ! (one terminated crystal found on the farm of Jas. Worrall weighs 7.? Ibs.) ; at Blue Hill, very fine crystals of blue quartz in chlorite, amianthus in serpentine, zircon. LOWER PROVIDENCE. Amethyst, green mica, garnet, large crystals of feldspar/ (some over 100 Ibs. in weight). RADNOR. Garnet, marmolite, deweylite, chromite, asbestus, magnesite, talc, blue quartz, picrolite, limonite, magnetite. SPRINGFIELD. Andalusite, tourmaline, beryl, titanic iron, garnet; on Fell's Laurel Hill, beryl, garnet ; near Beattie's mill, staurolite, apatite ; near Lewis's paper-mill, tourmaline, mica. THORNBURY. Amethyst. HUNTINGDON CO. NEAR FRANKSTOWN. In the bed of a stream and on the side of a hill, fibrous celeslite (abundant), quartz crystals. LANCASTER CO. DRUMORE TOWNSHIP Quartz crystals. FULTON. At Wood's chrome mine, near the village of Texas, brucite ! ! zaratite (emerald nickel), pennite! ripidolitc! kdmmererite! baltimorite, chromic iron, williamsite, chrysolite! marmolite, picrolite, hydromagnesite, dolomite, magnesite, arayonite, calcite, serpentine, hematite, menaccanite, genthite, chrome-garnet, bronzite, millerite ; at Low's mine, hydro- ma.gnesite, brucite (lancasterite), picrolite, magnesite, williamsite, chromic iron, ta'c, zaratite, baltimorite, serpentine, hematite ; on M. Boice's farm, one mile N.W. of the village, pyritt in cubes and various modifications, anthophyllite ; near Rock Springs, chalcedony, carnelian, m<>ss agate, green tourmaline in talc, titanic iron, chromite, octahedral magnetite in chlorite ; at Reynolds's old mine, calcite, talc, picrolite, cliromite. ; at Carter's chrome mine, brookite. GAP MINES. Chalcopyrite, pyrrhotite (niccoliferous), millerite in botryoidal radiations, vfciartiff f (rare), actinolite, siderite, hisingerite, pyrite. PEQUEA VALLEY. Eight miles south of Lancaster, argentiferous galenite (said to contain 250 to oOO ounces of silver to the ton ?), vauqueliriile, rutile at Pequea mine ; four miles N.W. of Lancaster, on the Lancaster and Harrissburg Railroa^, calimite, galenite, blende ; pyrite in cubic crystals is found in great abundance near the city of Lancaster ; at the Lancaster zinc mines, calamine, blende, tennantite? sriithsonite (pseud, of dolomite), aurichalcite. AMERICAN LOCALITIES. 489 LEBANON CO. CORNWALL. Magnetite, pyrite (cobaltiferous), chalcopyrite, native cop- ver azurite malachite, chrysocolla, cuprite (hydrocuprite), attophane, brochantite, serpentine, quartz pseudomorphs ; galenite (with octahedral cleavage), fluorite, covellite, hema:ite (mi caceous), opal, asbestus. LEHIGH CO _ FRIEDENSVILLE. At the zinc mines, salamine, smithsonite, hydrozincite, massive blende greenockite, quartz, allophane, zinciferous clay, mountain leather, aragonite, sauconite near Allentown, magnetite, pipe-iron ore ; near Bethlehem, on S. Mountain, alianite, with zircon and altered sphene in a single isolated mass of syenite, magnetite, mar- tite, black spinel, tourmaline, chalcocite. MIFFLIN CO. Strontianite. MONROE CO. In CHERRY VALLEY. Calcite, chalcedony, quartz; in Poconac Valley, near Judge Mervine's, cryst. quartz. MONTGOMERY CO. CONSIIOIIOCKEN. Fibrous tourmaline, menaccanite, aventurine auartz phyllite- in the quarry of Geo. Bullock, calcite in hexagonal prisms, aragonite. LOWER PROVIDENCE. At the Perkiomen lead and copper mines, near the village of Shannonville, azurite, blende, gaknite, pyromorphite, cerussite, wulfenite, anglesite bante, calamine chalcopyrite, malachite, chrysocolla, brown spar, cuprite, covellite (rare), m iron mine, five and a half miles from Spnng Mills limonite in geodes and stalactites, gdthite, pyrolusite, wad lepidocro cite ; at Edge Hill IS reet North Pennsylvania Railroad, titanic iron, braumte, pyrolusite; one mile b.W. ot Hitnera Son mine Umonite, velvety, stalactitic, and fibrous, fibres three inches long, turgite matite ; at the Cowpens, limonite, graphite limestone, copperas ; Morgan mine, leadhillite, pyromorphite, cerussite. SUMTER DIST. Agate. UNION DIST. Fairforest gold mines, pyrite, chalcopyrite. YORK DIST. Limestones, whetstones, witherite, barite, tetradymite. AMERICAN LOCALITIES. 493 GEORGIA. BtJRKE AND SCRIVEN Cos. Hyalite. CHEROKEE Co. At Canton Mine, chalcopyrite, galenite, clausthalite, plumbogummite aitchoockite, arsenopyrite, lantbanite, harrisite, cT Co Crvptomorphite. INGO Co. Ingo district, galenite, cerussite, anglesite, barite, atacamite, calcite, giossulai K*AKE Co Borax Lake, borax' sassolite, glauberite ; Pioneer mine, cinnabar, native mer- ury, selenide of mercury ; near the Geysers, sulphur, hyalite ; Redington mine, metacinna- ANGELES Co -Near Santa Anna 'River, anhydrite ; Williams Pass, chalcedony ; mines, chalcopyrite, garnet., gypsum; Mountain Meadows, garnet, m cooper ore >A Co -Chalcopyrite, itacolumyte ; Centreville, cinnabar; Pine Tree Mine, tet , ,- .***.*. (\^^ f^i^v, rvirrhvnii-,fi La Victoria mine, azuntef n PA Co -Chalcopyrite, itacoumye ; enreve, cinna , tetra- Burn! fcreek lim^nite; Geyer Gulch, pyrophyllite ; La Victoria mine., azuntef neai CJoulterville. cinnabar, gold. MoN?EKE7co"-Atisal Mine, arsenic; near Paneches, chalcedony; New Idria mine cm- aabar near New Idria, chromite, zaratite, chrome garnet; near Pacheco's Pas stibnite NEVADA Co -Grass Valley gold! in quartz veins, with pyrite, chalcopyrite, blende, .rsenopyrfte, galenite g^r^fbiotite ; near Truckee Pass gypsum ; Excelsior Mine, molyb- denite, with molybdenite and gold ; Sweet Land, pyrolusite. PLACEH Co. -Miner's Ravine, epidote! with quartz, gold. AT c A co- N e W , , quartz arfgotSe; Nort^ TlTmaden, ctaomite; Ml. Diabolo Range, magues.te, datohte, wit. OAJ-X JLJJ^Afc-l.^ /ii^JL^J-J.^ V/- W^. ' trict galenite, cerussite ; Francis mine, cerargyrite. SHASTA Co .-Near Shasta City, hematite, in large masses. SISKIYOU Co. Surprise Valley, selenite, in large slabs. SONOMA Co. Actinolite, garnets. Co. Cassiterite, a single specimen found. LOWER CALIFORNIA. LA PAZ.-Cuproscheelite. LoRETTO.-Natrolite, siderite, selenite. UTAH. BEAVER Co Bismuthinite, bismite, bismutite Mammoth velu, TINTIC DISTRICT. At the Shoebridge mine, the Dragon m enargite with pyrite. Box ELDER Co. -Empire mine, wulfenite! a - tpTurive m ines especially of ores of In the Wahsatch and OquiiTh mountains there are ext< ve mi , ce usgi wu if e nite ; lead rich in silver. At the Emma mine occur W*"^*^,^ ' arg entite, stephanite, azurite, malachite, calamine, anglesite, linante, spha^rite, pyme, etc. At the Lucky Boy mine, Butterfield Canon.. . orp naenV ** .^^ found in color One hundred and twenty miles south-west of bait Lake i/ity, ^ less crystals. NEVADA. 498 APPENDIX. ESMERALDA Co. Alum, 12 m. north of Silver Creek ; at Aurora, fluorite, stibnite nea Mono Lake, native copper and cuprite, obsidian ; Columbus district, ulexite ; Walker Lake gypsum, hematite ; Silver Peak, salt, saltpetre, sulphur, silver ores. _ HUMBOLDT DISTRICT. Sheba mine, native silver, jamexotiite, stibnite, tetraJiedrite, proua tite. blende, cernssite, calcite, bournonite, pyrite, galenite, malachite, xanthocone (?) MAMMOTH DISTRICT. Orthoclase, turquois, Jiubnerite, scheelite. REESE RIVKR DISTRICT. Native silver, proustite, pyravgyrite, stephanite, blende poly! basite, rhodochrosite, embolite, teti ahedrite ! cerargyrite, embolite. SAN ANTONIA. Belmont mine, stetefeldtite. Six MILE CANON. tielenite. ORMSBY Co. W. of Carson, epidote. STOREY Co. Alum, natrolite, scolezite. ARIZONA. On and near the Colorado, gold, silver, and copper mines ; at Bill Williams' Fork, chry- socolla. malachite, atacamite, brochantite ; Dayton Lode, gold, fluorite, cerargyrite Skinnei Lode, octahedral fluorite ; at various places in the southern part of the territory, silver and copper mines ; Heintzelmann mine, stromeyerite, chalcocite, tetraheclrite, atacamite. Mont- gomery mine, Harsayampa Dist., tetradymite. Whitneyite, in Southern Arizona. OREGON. Gold is obtained from beach washings on the southern coast ; quartz mines and placei mines in the Josephine district ; also on the Powder, Burnt, and John Day's rivers, and othei places in eastern Oregon ; platinum, iridosmine, laurite, on the Rogue River, at Port Oxford and Cape Blanco. In Curry Co. , priceite. IDAHO. In the Owyhee, Boise, and Flint districts, gold, also extensive silver mines ; Poor Man Lode eerargynte! prouatite, pyrargyrite! native silver, gold, pyromorphite, quartz, malachite- polybasite; on Jordan Creek, stream tin; Rising Star mine, stephanite, argentite, pyrargy rite. MONTANA. Many mines of gold, etc., west of the Missouri R. HIGHLAND DISTRICT. Tetradymitc SILVER STAR DIST. Psittacinite. In the Yellowstone Park, in Montana and Wyoming Territories. Geysente. Amethyst chalcedony, quartz crystals, quartz on calcite, etc. COLORADO.* The principal gold mines of Colorado are in Boulder, Gilpin, Clear Creek, and Jefferson Cos., on a line of country a few miles W. of Denver, extending from Long's Peak to Pike's Peak. A large portion of the gold is associated with veins of pyrite and chalcopyrite ; silver and lead mines are at and near Georgetown, Clear Creek Co., and to the westward in Sum- mit Co., on Snake and Swan rivers. At the GEORGETOWN mines are found : -native silver, pyrargyrite, argentite, tetrahedrite, pyromorphite, galenite, sphalerite, azurite, aragonite, barite, fluorite, mica. TRAIL CREEK. Garnet, epidote, hornblende, chlorite; at the Freeland Lode, tetrahedrite, tennantite, anglesite. caledonite, cerussite, tenorite, siderite, azurite, minium ; at the Cham- pion Lode, tonorite, azurite, chrysocolla, malachite; at the Gold Belt Lode, vivianite; at the Kelly Lode, tenorite ; at the Coyote Lode, malachite, cyanotrichite. Near JJLACK HAWK. At Willis Gulch, enargite, fluorite, pyrite ; at the Gilpin County Lode, cerargyrite ; on Gregory Hill, feldspar; North Clear Creek, iievrite. Galenite! * See the Catalogue of Minerals of Colorado by J. Alden Smith. AMERICAN LOCALITIES. 499 BEAK CREEK. Fluorite, beryl; near the Malachite Lode, malachite, cuprite, vesurianite, topazolite ; Liberty Lode, chalcocite. SNAKE RIVER. Penn District, embolite ; at several lodes, pyrargyrite, native silver. RUSSELL DISTRICT. Delaware Lode, cliakopyrite, crystallized galenite. Epidote, pyrite VIRGINIA CANON. Epidote, fluorite ; at the Crystal Lode, native silver, spinel. SUGAR LOAF DISTRICT. Chalcocite, pyrrhotite, garnet (manganesian). CENTRAL CITY. Garnet, terorite ; at Leavitt Lode, molybdenite; on Gunnell till, mag netite ; at the Pleasantview mine, cerussite. GOLDEN CITY. Aragonite. BERGEN'S RANCHE. Garnet, actinolite, calcite. BOULDER Co., Red Cloud Mine. Native tellurium, altaite, hessite (petzite), sylvamte, calaverite, schirmerite. LAKK CITY, at the Hotchkiss Lode. Petzite, calaverite (?), etc PIKE'S PEAK, on Elk Creek. Amazon tone! ! smoky quartz! aventunne felspar, ame thyst, albite, fluorite, hematite, anhydrite (rare), columbite. CANADA. CANADA EAST. ABERCROMBIE. Labradorite. BAY ST. PAm.-M&wnwtnite! apatite, allamte, rutile (or brookite ?) AUBERT. - Gold, iridosmine, platinum. BOLTON - Chromite, magnesite, serpentine, picrolite, steatite, bitter spar, wad. menaccanite, phyllite, sodalite, cancrinite, .-, chabazite and calcite in trachyte, menaccanite. CHATEAU RICHER. Labradorite, hypertthene, andesite. oalcite ' pyroxene ' 8teatite etibnite. INVERNESS. Variegated copper. LAKE ST. FRANCIS. Andalusite in mica slate. LANDSDO WN. Barite. LEEDS Dolomite, chalcopyrite, gold, ehlontoid. MILLE IsmiLabradorfot menaccanite, hypersthene, andesite, i f rc0 ^ MoNTHEAi,-(7 tb "ach at e^t end, on Evans' farm, chlorite, talc, qwrtz cryital* ; half a mile west, chalcop^rk, rnagnesite vein,, magnetite ; Point Wolf and Salmon River, asbestus, iasper; at mouth south side galenit* ;; at mouS "of Wapskanegln. gypsum, salt spring ; three miles above, stalactites (abundant); Ta ^ s farm ' Tf e -v irrlt ne on \v?es's farm, asphaltum, petroleum spring; Grandlance apatite, selenite (in tin py rite*? in granite (rare). NOVA SCOTIA. p Bro SS^O^K^Si, East River, to*;/ -^-^^^^"dt' River, barite in limestone). o anf jidte apophyUite ! ! chaba- CLMBEHLAND Co.-Cape Cbiegnecto, ^^^^^^^ obsidian, red copper tite, fardelite, laumontite, m/*fe, malachite ^^ o f Ca ^^Or analcite, calcite, stilbite; (rare), vivianite (rare) ; Horse-shoe Cove east side of Cape D Or. an^ ^ meftoiite ^ Isle Haute, south side, ana cite a^phyllt^ // toto^ ^^ te at Seaman's Brook: Wrt/ Joggins, coal, hematite, limonrte; ^^^^TS^^ < rare ^' ?****" Partridge Island, analcite, a^ophylhtef (rare) ' l ^; m a ^; mat i?e, /wtondfl / magne- chabazite (acadialite). chalcedony cat s^ye ^^^^^a^m heulandite, pyrite : tite,*^^/// 8w ^lS?*lfS^^Sfa// M0Dh*mu! (T*Te},calctte.ch'A \i=^**7i ~~ ' . GUYSBORO' Co. Cape Canseau, andalimU. artn . hwegfc of HaUfax. garnet, rtaurolite, HALIFAX Co. -Gay's river, galemte in limestone ,^ ^??te ^ociated with auriferous pyrites, tourmaline : Tangier, go'd! m quartz veins in claj ^*. foand * the same form* t!HSS.S:E-o'iT^r- -" - 502 APPENDIX. HANTS Co. Cheverie, oxide of manganese (in limestone) ; Petite River, gypsum, oxide of manganese ; Windsor, calcite, cryptomorphite (boronatrocalcite), howlite, glauber riiilt. The last three minerals are found in beds of gypsum. KINGS Co. Black Rock, centrallassite, cerinite ; cyanolite ; a few miles east of Black Rock, prehnite ? stilbite ! ; Cape Blomidon, on the coast between the cape and Cape Split, the following minerals occur in many places (some of the best localities are nearly opposite Cape Sharp): analcite! ! agate, amethyst! apophyllite! calcite, chalcedony, chabazite, gme- Unite (ledererite), hematite, heulandite ! laumontite, magnetite, malachite, mesolite, native copper (rare), natrolite ! psilomelane, stilbite ! thomsonite, faroelite, quartz; North Moun- tains, amethyst, bloodstone (rare), ferruginous quartz, mesolite (in soil) ; Long Point, five miles west of Black Rock, heulandite, laumontite! ! stilbite! !; Morden, apophyllite, mor- denite ; Scot's Bay, agate, amethyst, chalcedony, mesolite, natrolite ; Woodworth's Cove, a few miles west of Scot's Bay, agate ! chalcedony ! jasper. LUNKNBURG Co. Chester, Gold River, gold in quartz, pyrite, mispickel ; Cape la Have, pyrite ; The u Ovens," gold, pyrite, arsenopyrite ; Petite River, gold in slate. PICTOU Co. Pictou, jet, oxide of manganese, limonite ; at Roder's Hill, six miles west of Pictou, barite ; on Carribou River, gray copper and malachite in lignite ; at Albion mines, coal, limonite ; East River, limonite. QUEENS Co. Westfield, gold in quartz, pyrite, arsenopyrite ; Five Rivers, near Big Fall, gold in quartz, pyrite, arsenopyrite, limonite. RICHMOND Co. West of Plaister Cove, barite and calcite in sandstone ; nearer the Cove, calcite, fluorite (blue), siderite. SHELBURNE Co. Shelburne, near mouth of harbor, garnets (in gneiss); near the town, rose quartz ; at Jordan and Sable River, staurolite (abundant), schiller spar. SYDNEY Co. Hills east of Lochaber Lake, pyrite, chalcopyrite, sideride, hematite ; Mor- ristown, epidote in trap, gypsum. YARMOUTH Co. Cream Pot, above Cranberry Hill, gold in quartz, pyrite; Cat Rock, Fouchu Point, asbestus, calcite. NEWFOUNDLAND. ANTONY'S ISLAND. Pyrite. CATALINA HARBOR. On the shore, pyrite ! CHALKY HILL. Feldspar. COPPER ISLAND, one of the Wadham group. Chalcopynte. CONCEPTION BAY. On the shore south of Brigus, bornite and gray copper in trap. BAY OF ISLANDS. Southern shore, pyrite in slate. LAWN. Galenite, cerargyrite, proustite, argentite. PLACENTIA BAY. AtLaManche, two miles eastward of Little Southern Harbor, g 'lenite! ; on the opposite side of the isthmus from Placentia Bay, barite, in a large vein, occasions llj accompanied by chalcopyrite. SHOAL BAY. South of St. John's, chalcopyrite. TRINITY BAY. Western extremity, barite. HARBOR GREAT ST. LAWRENCE. West side, fluo ide, galenite. APPENDIX D. SUPPLEMENTARY CATALOGUE OP AMERICAN LOCALITIES OF MINERALS. MAINE. NORWAY. Triphylite (lithiophilite), chrysoberyl, cookeite. PARIS. Columbite, mica, triphyhte. PARSONFIELD. Labradorite, crystallized PERU -Triphylite (crystallized), columbite, beryl, spodumene. STONEUAM. Triplite, columbite, topaz, curved NEW HAMPSHIRE. BARTLETT. At the iron mine, danalite. MASSACHUSETTS. phteite, kaolin, pyrite, malachite, limomte, wad. ROOKPORT. Fergusonite. CONNECTICUT. BRANCHVILLE. -In a large vein of pegmatite in gneiss mica (curved ^^^^ albite' (also crystallized), quartz (inclosing liqu id ^X^pod^ a ( lso mangana patite), products (eucryptite, cymatohte ki Imite^ f S,)' c Xkms'onT reddiugite, fairfieldite, Lblygonite, lithiophilite, eosphonte, ^^^^^^^ phosphates, fillowite, rhodochrosite, urammte (crystals\ cyrolite, i chabazite, stilbite, heulandite and other species. LITCHFIELD. Staurolite in mica schist. sandstone, garnet (topazolite) ; NEW HAVEN.-At Mill Rock, contact surface of ,^ a P ^ S ^ n etitef pyroxene, apatite, at East Rock, on columnar surfaces of trap, garnet (mete Ca pTLAND. At Pelton's feldspar quarry, monazite. NEW YORK. I CLINTON CO.-PLATTSBURG, nugget of P^^^ O rthoclase; Champlain iron ESSEX CO. PORT HENRY, black tourmaline < re ST?'LAWRENCE CO.-DEKALB, white tourmaline. PICTAIRN. Titanite. ^.vUp with Dvroxene, titanite, black mica. RUSSELL. -In veins in a granitic rock, danbunte wit NEW JERSEY. PSSSSS and STERL^-Chalcophanite, het.rolite, pyrochroit, ^ 504 APPENDIX. PENNSYLVANIA. BEDFORD CO. BRIDGEPORT, barite. BERKS CO. Jones's mine, aurichalcite, melaconite, byssolite. BUCKS CO. PHENIXVILLE, ankerite. BRIDGEWATER STATION. Titanite. CHESTER CO. YELLOW SPRINGS, allanite. DELAWARE CO. WATERVILLE, near Chester, and Upland, chabazite. MINERAL HILL, columbitc. LEIPERVILLE, garnet, zoisitc, heulandite, leidyite. FRANKLIN CO. LANCASTER STATION, barite. HUNTING TON CO. BROAD TOP MOUNTAIN, barite. LEH1GH CO. SHIMERVILLE, corundum. LUZERNE CO. SCRANTON, under a peat-bed, phytocollite (dopplerite). DRIFTON, pyrophyllite. MIFFLIN 'CO. Strontianite. MONTGOMERY CO.- -Upper Salford mine, azurite. NORTHAMPTON CO. BETHLEHEM, axinite. PHILADELPHIA CO. GERMANTOWN, fahlunite. SCHUYLKILL CO., near MAHANOY CITY, pyrophyllite, alunogen, copiapite, in coal mines. DELAWARE. DIXON'S QUARRY. Columbite. NEWARK. Quartz crystals, doubly terminated, loose in soil. VIRGINIA. AMELIA CO. From a granite vein (mica mine) in gneiss near Amelia Court House, mica in large sheets, quartz, orthoclase, microlite, monazite, columbite, orthite, helvite with topazolite, beryl, fluorite, amethyst, apatite (rare). AMHERST CO. From a feldspar vein in a gneissoid rock on the northwest slope of Little Friar Mt., allanite, sipylite, magnetite, zircon. ROCKBRIDGE CO. Underlying limonite, dufrenite in an irregular bed ten inches deep, strengite in cavities in dufrenite. WYTHE CO. Austin mine, aragonite (7 p. c. PbC0 3 ). NORTH CAROLINA.* ALEXANDER Co. Near Stony Point, in narrow veins or pockets in a gneissoid rock (in part also loose in overlying soil), spodumene (hiddenite), beryl (emerald), rutile, monazite, allanite, quartz. At White Plains, quartz crystals, spodumene (hiddenite), beryl, rutile, scorodite, columbite, tourmaline. At Milholland's mill, rutile, monazite, muscovite, quartz. BURKE Co. In the auriferous gravels at Brindletown, cctahedrite (transparent), brookite, zircon, fergusonite, monazite, xenotime (compounded with zircon), garnet, tourmaline, magnetite and other species. MITCHELL Co. At the mica mines, muscovite in large quantities, orthoclase, albite, samarskite, columbite, hatchettolite, rogersite, fergusonite, monazite, uraninite, gummite, phosphuranvlite, uranotile, allanite, beryl, zoisite, garnet, menaccanite. YANCEY Co. At the Ray mica mine, muscovite, tantalite (columbite), monazite, beryl, garnet, zircon, rutile, etc. At Hampton's, chromite, epidote, enstatite, tr^molite, chrysolite, serpentine, talc, magnesite, etc. ALABAMA. COOS A CO. Cassiterite, tantalite. * For a complete list of the minerals and mineral localities of North Carolina, see Geology of North Carolina, vol. II., chap. I.. Mineralogy by F. A. Genth and W. C. Kerr, with notes by W. E. Hidden; 122 pp., 8vo, Raleigh, 1881. AMERICAN LOCALITIES. 505 MICHIGAN. NEGAUNEE. Manganite, gftthite, hematite, barite, kaolinite. GRAND MARAIS. Thomsonite (lintonite). MISSOURI.* AD AIR CO. Gothite with calcite in concretionary masses of clay iron-stone. BAitTON CO. McCarrow's coal bank, pickeringite, as a white efflorescence on sandy shales of coal measures. BENTON CO Limonite. BOLLINurER CO. Limonite, bog manganese, psilomelane. CALLAWAY CO. Hematite, clay iron ore. CHARiTON CO Selenite. COLE CO Barite. At the Eureka mines, galenite, smithsonite. COOPEli CO. Collins mine, malachite, azurite, chalcopyrite, smithsonite, galenite sphalerite, limonite. CRAWFORD CO. Scotia iron banks, hematite, quartz, jasper, amethyst, gothite, malachite. DADB CO. Smithsonite. DENT CO. Simmon's Mountain, hematite. FRANKLIN CO. Cove mines, galenite, cerussite, anglesite, barite. Mine-a-Burton, galenite, cerussite, anglesite. Moselle, limonite. Mount Hope mine, galenite, sphalerite, calamine, smithsonite. Stanton Copper mines, native copper, chalcotrichite, malachite, azurite, chalcopyrite. Virginia mines, galenite, anglesite, cerussite, minium. IRON CO. PILOT KNOB, hematite, serpentine, magnetite, quartz, manganese ore. JASPER CO. Joplin mines, galenite, sphalerite, pyrite. marcasite, cerussite, bitumen. OROXOGO. Galenite, sphalerite, cerussite, smithsonite, anglesite. WEBB CITY. Galenite, sphalerite. JEFFERSON CO. Palmer mines, galenite, cerussite, plumbogummite. Valle mines, galenite, cerussite, anglesite, calamine, smithsonite, hydrozincite, mala- chite, azurite. MADISON CO. Enistein silver mine, galenite, sphalerite, wolframite, pyrite, quartz, muscovite, actinolite, fiuorite. MINE-LA-MOTTE. Galenite, linnaeite (siegenite\ cerussite, anglesite, pyrrhotite, earthy cobalt, bog manganese, plumbogummite, chalcopyrite, annabergite. In granites, porphyries, etc., quartz, agate, hornblende, asbestos, serpentine, chlorite, epidote, feldspar. MONLTEAU CO Sampson's coal mine, galenite and sphalerite in cannel coal. MORGAN CO. Buffalo mines, galenite. Humes Hill, barite. NEWTON CO. Granby mines, galenite, cerussite, pyromorphite, calamine, greeno- chite. sphalerite, smithsonite, hydrozincite, buratite, dolomite, calcite. PHELPS CO Hematite, siderite, limonite, ankerite. ST. FRANCOIS CO. Iron mountain, hematite, apatite, tungstite, wolframite, magne- tite, menaccanite. ST. GENEVIEVE CO. St. Genevieve copper mines, chalcopyrite, cuprite, malachite, azurite, covellite, chalcocite, bornite, melaconite, chalcanthite. ST. LOUIS CO. ST. Louis. In cavities in limestone, millerite, dolomite, calcite, fiuorite, anhydite, gypsum, strontianite. SALINE CO. Halite in incrustations. WAYNE CO. Limonite. KANSAS. BROWN CO. Celestite. ARKANSAS. SEVIER Co. Stibnite, stibiconite, bindheimite, jamesonite. HOT SPRINGS Co. Rutile in eightlings, variscite. *See Notes on the Mineralogy of Missouri, by Alexander V. Leonhard, St. Louis, 1882. 506 APPENDIX. COLORADO. BOULDER Co Magnolia district (especially the Keystone, Mountain Lion and Smuggler mines), native tellurium, coloradoite, calaverite, tellurite, magnolite, ferrotellurite, sylvanite. CHAFFEE Co. Arrow mine, jarosite with turgite. CUSTER Co. Silver cliff, niecolite. EL PASO COUNTY. Near Pike's Peak, arfvedsonite, astro phyl lite, zircon; siderophyllite, topaz, phenacite, cryolite, thomsenolite (and other tluorides), tysonite, bastnasite. GILPIN Co Near Central City, pyrite in moailied crystals, "chalcopyrite oiten coated by tetrahedrite in parallel position, crystallized gold on pyrite, GUNNISON Co. Near Gothic, smaltite. JEFFERSON Co. Near Golden, in basalt of Table Mountain, chabazite, thomsonite, analcite, apophyllite, calcite, mesolite, laumontite. LA PLATA Co. Poughkeepsie Gulch, Alaska mine, alaskaite with tetrahedite, chalco- pyrite, barite. LAKE Co. Leadville, cerussite carrying silver, anglesite, pyromorphite, sphalerite, calamine, minium, dechenite (?), rhodochrosite with galenite, chalcopyrite. Golden Queen mine, scheelite with gold. Ute and Ule silver mine, stephanite, galenite, sphalerite, chalcocite. PARK Co. Grant P. 0., Baltic lode, beegerite. Hall Valley, ilesite. CALIFORNIA. INTO Co. San Carlos, datolite with grossular garnet and vesuvianite. Los ANGELES Co. Brea Ranch, vivianite in nodules with asphaltum. OREGON. DOUGLAS Co. Cow Creek, Pkiey Mountain, considerable deposits of a hydrous nickel silicate, allied to garnierite. GRANT Co. Canyon City, cinnabar with calcite. UTAH. IRON Co. Coyote District, orpiment and realgar in a thin bed in the horizontal sediment- ary formations underlying lava. PIUTE Co. Marysvale, onofrite. SALT LAKE Co. Butterfield Canon, mallardite, luckite. Wahsatch Range, head waters of Spanish Fork, ozocerite in considerable beds. NEVADA. ELKO Co. Emma mine, chrysocolla; Blue Hill mine, azurite, malachite. LANDER Co. Austin, polybasite, chalcopyrite, azurite, whitneyite. LINCOLN Co. Halite, cerargyrite. NYE Co. Anglesite, stetefeldtite, azurite. cerussite, silver ore, cerargyrite. WHITE PINE Co. Eberhardt mine, cerargyrite; Paymaster mine, freieslebenite. NEW MEXICO.* DONA ANA Co. Lake Valley, cerargyrite in the Sierra mines in large masses, rarely crystallized, associated with embolite, cerussite. galenite, vanadinite in small canary-yellow crystals, native silver, pyrolusite, manganite, fluorite, ankerite, apatite, chert. Victoria mine, 40 miles below Nutt, massive anglesite. Kingston, in Black Range, argentite in large masses. SOCORRO Co.- Socorro Mt., 3 miles from town of Socorro, large veins of barite carrying cerargyrite, vanadiferous mimetite, vanadinite in barrel-shaped crystals resembling pyromor- phite. Magdalena Mountains, 27 miles west of Socorro, cerussite in heavy veins with galenite, sphalerite, etc. Green and blue calamine on the Kelly location. Sophia mine, stromeyerite? Grafton, on a large quartz vein, Ivanhoe mine, gold in black cerussite, chalcocite, bornite, malachite, azurite, chalcopyrite, cerargyrite, amethystine quartz. New Elk Mountain, 100 miles south of Socorro, cerussite carrying silver. * The author is indebted for the following notes, as also for others under Arizona and Montana, to Prof. B. Silliman. AMERICAN LOCALITIES. 507 GRANT Co. Silver City, Bremen's mine, argentite, cerargyrite, argentite pseudomorph >f mollusca, barite with cerargyrite, native silver in filagree and dendrites on slate; Santa Sita copper' mines, native copper, tenorite. Mogollon and Burro mountains, Coony mining listrict, Dry Creek; in Mundo mine, melaconite; Silver Twigg mine, bornite, copper; Alba- ross mine, bornite, malachite; Cooney mine, chalcopyrite, azurite, bornite; Clifton mine, mtive copper, cuprite, azurite, malachite, wulfenite. Georgetown, Naiad Queen mine, irffentite pseudomorph of mollusca. cerargyrite, native silver in dendritic form on slate. SAN MIGUEL Co. Cerillos, Mt. Chalchuitl, turquoise in tuff. In the Cerillos district are lumerous mineral veins, carrying silver lead and salts of lead, rarely wulfenite and vanadinite, azurite, malachite, sphalerite, etc. ARIZONA. In the Silver District, YUMA Co., at the Hamburg, Princess and Red Cloud mines, in connection with quartz veins carrying argentiferous galena, fine ruby-red _ vanadmite, red wulfenite massive anglesite. Silent District, Black Rock mine, vanadmite. At the Castle Dome 'mines, vanadinite, mimetite, wulfenite, cerussite, galenite, fluorite. Also wulfenite at the Melissa mine and Rover mine. In the Vulture District (also called White Picacho District, YAVAPAI and MARICOPA Cos numerous veins of gold-bearing quartz, carrying lead. Vulture mine, cryst gold, iarosite, wulfenite. Hunter's Rest mine, gold in tourmaline rock Farley s Collateral mine and the Phenix mine, 20 miles north-east of Vulture, yellow vanadmite with calcite, wulfenite, cerussite, descloizite (?), volborthite (?) crocoite, vauquelmite, phoem- cochroite Montezuma mine, vanadinite, cerussite. Sante Domingo mine, mimetite, argentite' Silver Star mine, native silver, cerussite, argentite, crocoite, vanadmite. Tiger mine, native silver, cerargyrite. Tip Top mine, native silver, sphalerite, argentite, pvrargyrite. From the Rio Verde, MARICOPA Co., thenardite in large deposits. MOHAVE Co Moss lode, gold in crystalline plates; fluorite a frequent gangue material. FINAL Co. Mule Pass, Bisbey, Copper Queen mine, native copper, copper oxide, m mine, Pioneer District, FINAL Co. -Fine crystallized native silver, areentite sphalerite, pyrite. Stonewall Jackson mine, cryst. silver, argentite. f rom the P Bon Ton mines, Chase Creek, near Clifton, dioptase with cuprite and hmomte. MONTANA. BUTTE Co.-Butte Citv, Alice silver mine, rhodonite, a common gangue of and other silver ores, rhodochrosite. Same in Magna ^^^1 Bell, and other copper veins yield various copper salts and arsenical coe Sil Original Butte mine," wurtzite with pyrite. Clear Grit mine native silver, argentite, chalcopyrite, sphalerite, calcite, rhodochrosite. Colusa mine, chalcc ALASKA. Ft. Wrangell at mouth ol the Stickeen River, fine garnets in mica schist. CANADA PROVINCE OF QUEBEC. MONTREAL. Analcite, sodalite, nephelite (in nephelite-syenite). OTTAWA Co.- Veins carrying apatite and pyroxene in large ^uant ^ s Buckingham, Burgess, Templeton, and other townships, y^f^fS scapolite, garnet, tourmaline, titanite, zircon, ortlioclase, phlogopiti Templeton, vesuvianite, garnet (cinnamonstone), pyroxene. Hull, colorless garnets, vesuvianite, white pyroxene. Wakefield, chrome garnet. CANADA PROVINCE OF OTTAWA. FRONTENAC Co. Scapolite, apatite. fitnnitp zircon (also twins), RENFREW Co.-Eganville, large crystals of apatite, titanite, , amphibole. APPENDIX. NOVA SCOTIA. CUMBERLAND Co. Alunogen. COLCHESTER Co. New Annan, covellite. KINGS Co. Black Rock, in trap with stilbite, ulexite, heulandite. CANADA KEEWATIN DISTRICT. CHURCHILL RIVER. Lazulite. KNEE LAKE. Magnetite Island, magnetite. CANADA BRITISH COLUMBIA. CARIBOO DISTRICT. Native gold, galenite Th^mpfon A lSver R c7a R niTe GOld ' argentiferous ^rahedrite, cerargyrite, cinnabar. North HOWE SOUND. Bornite, chalcopyrite, molybdenite, mica. OMINICA DISTRICT. Gold, galenite, silver, silver amalgam CASSIAR DISTRICT. Gold. TEXADA ISLAND. Magnetite. QUEEN CHARLOTTE ISLANDS. -Skincuttle Inlet, Harriet Harbor, magnetite, chalcopyrite. GENERAL INDEX TO MINERAL SPECIES Abriachanite, 420. Acadialite, 344. Acanthite, 239. Achrematite, 385. Achroitc, 330. Acmitc, 294. Actinclite, 297. Adamine, Adamite, 373; 420. Adelpholite, 363. Adular, Adularia, 325. ^Egirine, ^Erite, 294. Aerinite, M50. BSschynite, 362. Agalmatolite, 349, 352. Agaric mineral, 400. Agate, 286. Aglaite, 420. Agricolite, 302. Aikinite, 254. Ajkite, 4:J5. Akanthit, v. Acanthite. Akmit, v. Acmite. Alabandite, '^37. Alabaster, 393. Alalite, 293. Alaskaite, 420. Alaun v. Alum. Alaunstein, 396. Albertite, 416. Albite 323; 420. Alexandrite, 275. Algodonite, 235. Alipite, 351. Allanite, 308. Allemontite, 227. Allochroite, v. Andradite. Alloclasite, 248. Allophane, 341. Allophite, 806 Almandin, Almandite, 303. Alshedite, 438. Alstonite. D. Bromlite. Altaite, 237. Alum, Native, 895. Alumina = Aluminum oxide Aluminum carbonate, 410. chloride, 260. fluoride, 264, 265 fluo-silicate, 332 Uuminum hydrate, 279, 282. hydro - sulphate, 395. mellate, 412. oxide (Alumina), 267. phosphate, 875, 376, 377, 378, 431). silicate, 831, 332, 341, 349, 351. sulphate, 395, 396. Aluminite, 395. Alunite, 396. Alunogen, 895. Amalgam, 225. Amazonstone, 325. Amber, 415. Amblygonite, 369; 420. Amblystegite, 290. Ambrite, 415. Ambrosine, 415. Amesite, 424. Amethyst, 286. Amianthus, 297, 350. Ammonia, v. Ammonium. Ammonium chloride, 260. oxalate, 433. phosphate, 371. sulphate, 39.2. Amphibole, 293; 420. Analcite, Analcime, 343. Anatase, 277. Andalusite, 331. Andesine, Andesite, 322, Andradite, 304. Andrewsite, 878. Anglesite, 389. Anhydrite, 389. Animikite, 420. Ankerite, 402. Annabergite, 372. Innerodite, 423. Annite, 313. Anomite, 431 . Anorthite, 321. Antholite, v. Anthophyllite, Anthophyllite, 295. Anthracite, 417. Lnthracoxenite, 415. intigorite. 351. intillite, 351. \ntimonblende, 284. \ntimonbluthe, . Valentin- ite. Antimonglanz, 232. Antimonite, 232. Antimonsilber, 234. Antimony, Arsenical, 227. Gray, 232. Native, 226. Red Kermesite, 284. White -Valentin- ite, 284. Antimony blende, 284. bloom, 284. glance, 282. ochre, 437. oxide, 284, 437. sulphide, 232. Apatite, 364; 420. Aphanesite . Clinoclasite. Aphrite, 400. Aphrizite, 330. Aphrodite, 349. Aphrosiderite, 356. Aphthalose,Aphthitahte,390. Apjohnite, 395. Aplome, 304. Apophyllite, 340; 421. Aquacreptite, 851. Aquamarine, 299. Arseoxene, 426. Aragonite, 405; 421. Aragotite, 414. Arcanite, 390. Arctolite, 421. Ardennite, 310. Arequipite, 421, Arfvedsonite, 298; 421. Argentine, 4 0. Argentite, 235, Argentopyrite, 437. Argyropyrite, 437. Arite, 243. Arkansite, 278. Arksutite, 265. 509 510 GENERAL INDEX. Arquerite, 225. Arragonite, 405. Arrhenite, 421. Arsenargentite, 421. Arseneisen, v. Leucopyrite. Arseneisensinter, v. Pitticite. Arsenic, Antimonial, 227. Native, 226. Red, 284. Yellow, 284. White, 284. Arsenic oxide, 284. sulphide, 231. Arsenical Antimony, 227. Arsenikkics, 247. Arsenikkupfer, 234. Arsennickelglanz, 246. Arseniosiderite, 378. Arsenite, v. Arsenolite. Arsenolite, 284. Arsenopyrite, 247. Asbestus, 297. Blue,t>. Crocidolite. Asbolan, Asbolite, 283. Asraanite, 288; 421. Asparagus-stone, 365. Aspasiolite, 353. Asphaltum, 416. Aspidolite, 312. Astrakanite, v. BISdite. Astrophyllite, 313; 421. Atacamite, 261. Atelestite, 378. Ateline, Atelite, 262; 421. Atopite, 421. Augite, 29:j. Aurichalcite, 410. Auriferous pyrite, 220. Auripigmentum, 232. Automolite, 272. Autunite, M79; 421. Aventurine quartz, 286. feldspar, 322, 323, 3J5. Axinite, 310. Azorite, 859. Azurite, 411. Babingtonite, 295. Bagrationite, v. Allanite. Baikalite, v. Sahlite. Balvraidite, 421. Barcenite, 421. Barnhardtite, 245. Barite, 387. Barium carbonate, 406, 408. nitrate, 433. (and uranium) phos- phate, 439. silicate, 322, 346, 420. sulphate, 387. Bartholomite, 395. Barylite, 421. Baryt, Barytes, 387. Baryta Barium oxide. Barytocalcite, 408. Barytocelestite, 388. Basanite, 287. Bastite, 151. Bastmisite, 408, 438. Bathvillite, 415. Batrachite, 300. Beaumontite, 347. Beauxite, 281. Beccarite, 440. Bechilite, 382. Beegerite, 421. Beilstein, v. Nephrite. Bell metal ore = Stannite, 245. Belonite, 110. Benzole, 414. Beraunite, v. Vivianite. Bergamaskite, 420. Bergholz, 297. Bergkrystall, v. Quartz. Bergmehl, 401. Bergmilch, 400. Bergol, 413. Bergpech, 416. Bergseife, v. Halloysite. Bergtheer, V. Pittasphalt. Berlauite, 436. Bernardinite, 435. Bernstein, 415. Beryl, 299; 421. Beryllium aluminate, 274. silicate, 299, 300, 801, 302, 333. Berthierite, ',51. Berzelianite, 237. Berzeliite, 421. Beyrichite, 241. Bhreckite, 4^2. Bieberite, 395. Biharite, 353. Bimsstein, t>. Pumice. Bindheimite, 379. Binnite, 251; 250. Biotite, 31-2. Bischofite, 423. Bismite, 284. Bismuth, Acicular (aikinite), 254. Native, 227. Telluric, 2 S3. Bismuth arsenate, 377, 379. blende(eulytite),302. carbonate, *412, 422. chloride. 262. glance, 232. nickel (griinauite), 237. ochre, 284. oxide, 284. selenide, 233. silicate, 302. silver, 420. Bismuth sulphide, 232. tellurate, 397. telluride, 233. Bismuthinite, 232. Bismutite, 412. Bismutoferrite, 302. Bismutosphaerite, 422. Bittersalz, 394. Bitter spar, Bitterspath, 1 Dolomite. Bitumen, 416. Bituminous coal, 417. Bjelkite, 424. Black jack, 237. Blattererz, Blattertellur, 24! Bliitterzeoiith, t. Heulanditi Blaueisenerz. v. Vivianite. Blaueisenstein, v. Crocidolit Blauspath, ii75. Blei, Gediegen, 226. Bleiglanz, 235. Bleiglatte, 267. Bleigumme, v. Plumbogun mite. Bleilasur, 396. Bleihornerz, 4C8. Bleiniere, 379. Bleinierite, v. Bindheimite. Bleispath, 407. Blei vitriol, 389. Blende, 237. Blodite, 394. Blomstrandite, 422. Bloodstone, 286. Blue vitriol, 394. Bodenite, 308. Bog-butter, 415. Bog-iron ore, 281. manganese, 283. Bole, Bolus - Halloysite. Bolivite, 422. Boltonite, 300. Bombiccite, 415. Boracic acid. 380. Boracite, 381 ; 422. Borax, 381. Bordosite, 267. Bornite, 237. Borocalcite, 382. Boron trioxide, 380. Boronatrocalcite, 381. Bort, 2", 9. Bosjemanite, 395. Botallackite, #. Atacamite. Botryogen, b95. Botryolite, 325. Boulangerite, 254. Bournonite, 253. Boussingaultite, 392. Bowenite, 297, 350. Bowlingite, 422. Brackebuschite, 425. Bragite, 362. Branderz, v. Idrialite. GENERAL INDEX. 511 Brandisite, 358. Brauneisenstein, 280. Braunite, 277. Braunkohle, 418. Braunspath, 401. Bra vai site, 422. Bredbergite, 304. Breislakite, D. Pyroxene. Breithauptite, 243. Breunerite, 402. Brewstcrite, ;-47. Brittle silver ore, v. Stephan- ite. Brochantite, 396. Bromargyrite, 260. Bromlite, 406. Bromsilber, 260. Bromyrite, 260. Brogniardite, 252. Brongnartine, 397. Bronzite, 290. Brookite, 277; 422. Brown coal, 418. iron ore, 280. spar, 401, 402. Brucite, 2*1 ; 422. Brushite, 371. Bucholzite, 331. Bucklandite, 308. Bunsenin, 430. Bunsenite, 207. Buntkupfererz, 237. Bnstamite, '294. Butyrellite, 415. Byerite, 417. Bytownite, 321. Cabrerite, 422. Cacholong, 289. Cacoxenite, Cacoxene, 378. Cadmium sulphide, 242. Cairngorm stone, 286. Calaite, v. Callaite. Calaminc, 339, 422; 404. Calaverite, 249; 422. Calcareous spar, tufa, 398 ; 400. Calcite, 398. Calcium arsenate, 370, 371. antimonate, 370, 421. borate, 382. boro-silicate, 334. carbonate, 398, 405. chloride, 2(50. fluoride, 26H. nitrate, 379. oxalate, 412. phosphate, 364, 371, 426, 432. silicate, 291, 338; 321. sulphate, 389, 392; 891. sulphide, 235. Calcium tantalate, 359, 431. titanate, 270. tungstate, 384. Calcozincite, 267. Calc-sinter, 400. Caledonite, 391. Callais, Callaite, 377. Calomel, 260. 3alvonigrite, 434. Campy lite, 367. Canaanite = White Pyroxene Cancrinite, 317; 422. Cannel Coal, 417. Capillary pyrites, 241. Caporcianite, 338. Carbonado, 229. Carbon diamantaire, 229. Carnallite, 261. Darnelian, 2s6. Carpholite, 341. Caryinite, 422. Cassiterite, 275. Castor, Castorite, 295. Catapleiite, 339. Cataspilite, 353. Cat's eye, 2 6. Cavolinite, 316. Celadonite, 349. Celestialite, 435. Celestite, Celestine, 388. Centrallassite, 338. Cerargyrite, 260. Cerbolite, 392. Cerine, 8u8. Cerite, 340. Cerium carbonate, 408. fluoride, 439. phosphate, 364, 368. silicates, 308, 330. Cerolite, 351. Cerussite, 407. Cervantite, 284. Ceylanite, Ceylonite, 271. Chabazite, 344; 422. Chalcanthite, 394. Chalcedony, 286. Chalcocite, 2H9. Chalcodite, 350. Chalcolite, 378. Chalcomenite, 422. Chalcomorphite, 351. Chalcophanite, 283. Chalcophyllite, 375. Chalcopyrite, 244; 422. Chalcosiderite, 378. Chalcosine, 239. Chalcostibite, 250. Chalcotrichite, 266, Chalk, 400. Chalybite, 403. Chathamite, 246. Chert, 287. Chester! ite, 326. [41 Chessy Copper, Chessylit hiastolitc, 831. hiidrenite, 377; 422. hiolite, 264. hladnite, 290. hloanthite, 245. hloralluminite, 260. hlor-apatite, 365. hlorastrolite, 340. hlorite Group. 355. hloritoid. 358. hloritspath, 358. hlormagnesite, 260; 423. hlorocalcite, 260. hloropal, 350. hlorophaeite, 356. hlorophane, 263. hlorophyllite, 353. Chlorothionite, 2CO. Chloroti'e, 373. Chodneffitc, 264. Chondrarsenite, 372. Chondrodite, 327; 423. Chonicrite, 355. Chrismatite, 413. Chromeisenstein, 274. Chrom glimmer, v. Fuch- site. Chromic iron, 274. Chromite, 27 \ ; 423. Chroinpicotite, 274. Chromium oxide, 274. sulphide, 242. Chrysoberyl, 274. Chrysocolla, 838; 423. Chrysolite, 800; 423. Chrysoprase, '286. Chrysotile, ; 50. Churchite, 371. Cinnabar, 240. Cinnamon stone, 303. Clarite, 258. Claucletite 284. Clausthalite, 236. Clay, 351, et seq. Cleavelandite, 324. Cleveite, 423. Clingmanite, 358. Clinoclase, Clinoclosite, 3<4. Clinochlore, 356. Clinocrocite, 423. Clinohumite, 328. Clinophaeite, 423. Clintonite, 358; 423. Cloanthite, 245. Coal, Mineral, 417. Boghead, 48. Brown, 418. Cannel, 417. Cobalt, Arsenical 245 246 Black (asbohte), 283. Earthy, 283. Gray (smaltite), 245. Red(erythrite), 372. White (cobaltite), 246. 512 GENERAL INDEX. Cobalt bloom, 372. glance, 246. arsenate, 372. arsenide, 246 ; 248. carbonate, 436. oxide, 283. selenite, 432. sulphate, 394. sulphide, 245. Cobaltine, Cobaltite, 246. Cobaltomenite, 432. Coccolite, 293. Coke, 417. Colestine, 4. Cryptomorphite, 382. Cuban, Cubanite, 245. Culsageeite, 355. Cummingtonite, 297. Cuprocalcite, 411; 424. Cuprite, ^66. Cupromagnesite, 395. Cuproscheelite, 384. Cuprotungstite, 384. Cuspidine, 424. Cyanite, 332; 424. Cyanochalcite, 339. Cyanotrichite, 397. Cymatolite, 349, 436. Cyprusite, 424. Damourite, 353. Danaite, 248. Danalite, 302; 424. Danburite, 311 ; 424. Datholite, Datolite, 334. Daubreelite, 242. Daubreite, 262. Davids >nite, 299. Davreuxite, 425. Davyne, Davina, 316. Dawsonite, 410; 425. Dechenite, 367. Degeroite, 354. Delessite, 356; 425. Delvauxite, v. Dufrenite. Demidoffite, 339. Derbyshire spar, . Fluorite Descloizite, 367; 425. Desmine, 346. Destinezite, 425. Dewalquite, 310. | Deweylite, 351. Diabantachronnyn, 355. Diabantite, 355.' Diaclasite, 291. Diaclochite, 379. ; Diallage, Green, 293. | Diallogite, Dialogite, 403, , Diamond, 228; 425. i Dianite, v. Columbite. ! Diaphorite, 252. Diaspore, 279. Dichroite, 311. Dickinsonite, 425. Dietrichite, 425. Dihydrite, 874. Dimorphite, 232. Dinite, 414. Diopside, 293. Dioptase, 301. Dipyre, 816. Discrasite, v. Dyscrasite. Disterrite = Brandisite. Disthene, 332. Ditrovte, 317. Dog-T ooth Spar, 400. Dolerophanite, 390. Dolomite, 401. Domeykite, 234. Doppelspath, 899. Dopplerite, 415; 425. Douglasite, 425. Dreelite, 890. Dry-bone, 404. Dudleyite, 358. Dufrenite, 378. Dufrenoysite, 251. Dumortierite, 425. Duporthite, 425. Durangite, 370. Durfeldtite, 425. Duxite, 415. Dysanalyte, 425. Dyscrasite, 234. Dysluite, 272. Dysodile, 415. Dysyntribite, 353. Earthy Cobalt, 283. Edenite, 297. Edingtonite, 341. Edwardsite, v. Monazite, Eggonite, 425. Ehlite, 374. Eisenbliithe, 405. Eisenbrucite, 422. Eisenglanz, 268. Eisenglimmer, 269. Eisenkies, 243. Eisenkiesel, v. Quartz. Eisenrpse, 269. Eisensinter, v. Pitticite. Eisenspath, 403. Eisspath, 326. Ekdeinite, 4'25. Ekebergitc. 3.6. Ekmannite, 354. Eljcolite, 316. Elaterite, 414. Elcctruin, 221. Eleonorite, 423. Elroquite, 423. Embolite, 260. Embrithitc, v. Boulangerite. Emerald, ^90. Emerald nickel, 410. Emery, 268. Emplectite, 250. Enargite, 257. Enceladite, v. Warwickite. Enophite, 433. Enstatite, 2;;0. Enysite, 3D7. Eosite, 885. Eosphorite, 423. Ephesite, 35 k Epiboulangerite, 254. Epidote, 307. Epigenite, 253. Epistilbite, 347; 426. Epsom Salt, Epsomite, 394; 423. Erbsenstein, 400. Erdkoba.lt, 283. Erdol, 416. Erdpech, 416. Eremite, v. Monazite. Erilite, 426. Erinite, 374. Eriochalcite, 426. Erubescite, 2 ,7. Erythrite, 37 .. Erythrosiderite, 261. Erythrozincite, 4^6. Esmarkite 353. Essonite. 304. Ettringite, 395. Eucairite, 235. Euchroite, 373. Euclase. 333, 426. Eucolite, 299. Eucrasite, 426. Eucryptite. 426. Eudialyte, Eudyalite, 299. Eudnophite, 344. Eugeng'anz, v Polybasite. Eukairite, v. Eucairite, Euklas, 8-3. Eulytine, Eulytite, 302; 426. Eumanite, 276. Euosmite, 415. Euphyliite, 354. GENERAL INDEX. Eusynchite, 426. Euxenite, 362. Fahlerz, 255. Fahlunite, 808. Fairfieldite, 426. Famatinite, 258. Faserquarz, 298. Fassaite, 29-5. Faujasite, 344. Fauserite, ;, 9k Fayalite, 300. Feather ore. 251. Federerz, 251. Feitsui, 309. Feldspar Group, 319; 426. Felsite, 323, 326. Feldspath, v. Feldspar. Fergusonite, 362; 4.7. Ferroilmenite, 860. Ferrotellurite. 427. Feuerblende, 252. Feuerstein, 287. Fibroferrite, 395. Fibrolite, 331. Fichtelitc, 41 k Fillowite, 4\!7. Fiorite, 289. Fireblende, 252. Flint, 287. Float-stone, 2 C 9. Flos ferri, 405. Fluellitc, 2o4. Fluocerite, 204 Fluor-apatite. 865. Fluor, Fluorite, 203; 427. Fluor Spar, 2(53. Flussspath, 203. Foliated tellurium, u. Nagya- gite. Fontaincbleau limestone, 400. Foresite, 347; 4.7- Forsterite, 300. Fovvlerite, 294 Francolite, 365. Franklandite. 4" 7. Frank inite, 273. Fredricite 438. Freibergite. 255. Freieslebenite. 252. Frenzelite, 233. Freyalite, 427. Friedelite, 302. Frieseite, 437. Frigidite, 438. Fuchsite, 314. GadoMn, Gadol inite, 309; 427. Gahnite, 272. Galena, Galenite, 235. Galenobismutite, 427. Galmei. 339, 40k Ganomalite, 427. Garnet, 302; 427. 513 1 Garnierite, 351 ; 427. j Gastaldite, 298. Guanovulite, 392. Gay-Lussite, 400. Gearksutite, 265. Gedanite, 435. Gehlenite, 331. Geierite, v. Geyerite. Gekrosstein, 389. Gelbbleierz.384. Genthite, 351. Geoccrite, 414. Geocronite, 257. Geomyricite, 414. Gersdorffite, 240. Geyerite, 248. Geyserite, 28D. Gibbsite, 282. Gieseckite, 352; 317. Gigantolite, 353. Gilbertite, 353. Gillingite, 354. Ginilsite, 428. Girasol, 289. Gismondinc, Gismondite, 341 ; 428. Giufite, 432. Glaazkobalt, -c. Cobaltite. Glaseritc, v. Arcanite. Glaserz, Glanzerz, v. Argen- tite. Glauber salt, 392. Glauberite, 391. Glaucodot, 248. Glauconite, 349. Glaucophane, 298. Glimmer, v. Mica. Globulites, 110. Gmelinite, 345. Gold, 221. Gold telluride, 248, 249, 430. Goldtellur, . Sylvanite. Goshenite, 299. Goslarite. 395. Gothite, 280. Grahamite, 416. Grammatite, 2y7. Granat, 302. Graphic tellurium, 248. Graphite, 280. Graukupfererz, v. Tennantite. Gray antimony, 232. copper, .255. Greenockite, 2 :2. Greenovite, 335. Grenat, v. Garnet. Grochauite, 357. Grossularite, 803. Griinauite, 237. Grunbleierz, 366. Guadalcazarite. 241. Guanajuatite. 2-i3; 428. Guanipite. 433. Guano, 365. 514 GENERAL INDEX. Guarinite, 336. Guejarite, 428. Giimbelite, 353. Gummite, 428. Gunnisonite, 428. Guyaquillite, 415. Gymmte, 351. Gyps, v. Gypsum. Gypsum, 392. Gyrolite, 338; 428. Haarkies, 241 ; 247. Haarsalz, 395. Haddamite, 433. Hafnefiordite, :,23. Hagemannite, 2G5. Haidingerite, 371. Halite, 2r>9. Hallite, 355. Halloysite, 352; 428. Halotrichite, 385. Hamartite, 408, 438. Hannayite, 428. Harmotome, 346. Harrisite, 240. Hartite, 4U. Hatchettite, Hatchettine, 414. Hatchettolite, 428. Hauerite, 244 Haughtonite, 431. Hausmannite, 277. Haiiyne, Haiiynite, 318. Haydenite, 34 i. Hayesine, 428. Haytorite, 335. Heavy spar, :-!87. Hebronite, 370; 420. Hedenbergite. 293. Hedyphane, 367; 428. Heldburgite, 42S. Heliotrope, 286. Kelvin, Helvite, 302; 428. Hematite, 26 <. Brown, 280. Henwoodite, 378. Hercynite, 272. Herderite, 370. Hermannolite, 361. Herrengnmdite, 423. Herschelite, 844. Hessite, 238; 429. Hessonite, v. Essonite. Hetaerolite, Hetairite, 429. Heteromorphite, v. Jameson- ite. Heubachite, 4C9. Heulandite, 347; 429. Hexagonite. 298. Hibbertite, 42D. Hiddenite, 436. Hielmite, 361. Hieratite. 429. Highgate resin, 415. Hisingerite, 354. Hoernesite, 371. Hofmannite, 485. Holzopal, v. Wood Opal. Holz Zinn, 275. Homilite, 429. Honey-stone, Honigstein,412. Hopeite, 429. Horbachite. 241. Hornblende, 296. Horn silver, 2GO. Hornstone, 287. Horse-flesh ore, v. Bornite Hortonolite. 300. Houghite, 282. Hovite, 410. Howlite, 382. Huantajayite, 259. Hiibnerite, 383; 429. Huilite, 425. Humboldtine, 412. Hum bo dtilite, 306. Humboldtite, 334. Hurainite, 4 5. Humite, 327, 328, 423. Huntilite. 420. Bureau 1 . ite, 372. Huronite, 353. Hyacinth, 304, 305. Hyalite, 289. Hyalophane, 322. Hyalosiderite, 3 0. Hyalotekite, 429. Hydrargiilite, 282. Hydrargyrite, 267. Hydraulic limestone, 400. Hydrobiotite. 436. Hydrocastorite, 433. Hydrocerussits, 429. Hydrocuprite, 266. Hydrocyanite, 390. Hydrodolomite, 410. Hydrofluorite, 264. Hydrofranklinite, 429. HydroiJmenite. 481. Hydromagnesite, 409. Hydro-mica Group, 353. Hydrophilite, 429. Hydrophite, 351. Hydrorhodonite, 429. . Hydrotalcite. 282. Hydrotitanite, 271. Hytlrozincite, 410. Hygrophilite, 353. Hypargyrite, 250. Hypersthene, 290. Hypochlorite, 802. Ice spar, 3?5. Iceland spar, 399. Idocrase, '205. Idrialine, Idrialite, 314. Ihleite, 395. Ilesite, 429. Ilmenite, 269. Ilsemannite, 284. i llvaite, 309. j Indianaite, 428. Indianite, 321. Indicolite, 330. lodargyrite, 2 -0. lodobromite, 429. lodsilber, 260. lodyrite, '260. lolite, 311. lonite, 485. Iridosmine, 224. Iron, Arsenical, 247. Magnetic, 241, 272. Meteoric, 226. Native, 226, 429. Oligist (hematite), 268. Iron aluminate, 272. arsenate, 375, 376. arsenide, 247, 248. borate, 380. boro-silicate, 429. carbonate, 403. chloride, 261. columbate, 360. oxalate, 412. oxide, 268, 272, 279, 280. phosphate, 369, 371, 372, 378, 426, 437. silicate, 300, 334 sulphate, 895. sulphide, 2; 1, 243,247. sulph-antimonite, 251. tantalate, 359. tellurate(?)4.7. tungstate, 388. Iron pyrites, 243. White, 247. Ironstone, Clay, 269, 281, 403. Iserine, Iserite, 270. Isoclasite, 373. Itacolumyte, 229. Ivigtite, 354. Ixolyte, 414. Jacobsite, 272. Jade, Common, 297. Jadeite, 409. Jamesonite, 251; 430. Jargon, 3('5. Jarosite, 430. Jasper, 287. Jaulingite, 415. Jefferisite, 355. Jeffersonite, 293. Jenkinsite, 351. Jet, 418. Johannite, 397. Jollyte, 354. Jordanite, '251. Joseite, 233. Julianite, 256. GENERAL INDEX. 515 N. B. Many names spelt with an initial K in German, begin with C in English. Kalait, 377. Kaliglimmer, 313. Kalinite, 395. Kalk-Harmotome, v. Phillips- ite. Kalk-uranit, 379. Kalkspath, 398. Kalk-volborthit, 374. Kallait, 77. Kaluszite. 394. Kammererite, 355. Kammkies, 247. Kaolin. Kaolinite, 351. Karelinite, v84. Karyinite, 422. Katzenauge, 286. Keatingine, 295. Keilhauite, 333. Kelyphitc. 433. Kenngottite, 250. Kentrolite, 430. Kerargyrite. 260. Kermes Kerraesite, 284. Kerolith, t>. Cerolite. Kerrite, 355. Kiesel, v. Quartz. Kieselkupfer, 338. Kieselwismuth, 302. Kieselzinkerz, 339. Kieserite, 394. Killinite, 353, 436. Kischtimite, 408. Kjerulflne, 36 S. Klaprotholite, 251. Klinochlor, 353. Knebelita, 300. Kobaltbliithe, 372. Kobaltglanz, 246. Kobaltkics. v. LinnaBite Kobaltnickelkies, 245. Kobellite, 254. Kochelite, 363. Kochsalz, 259. Koflachite. 435. Kohle, v. Coal. Kokkolit V. Coccolite. Kongsbergite, 225. Konigine, 396. Konlite, 414. Koppite, 339. Korarfveite, 368. K6ttigite, 372. Korund, v. Corundum. Kotschubeite, 357. Koupholite, 340. Krantzit3, 415. Kreittonite, 272. Kremersite, 261. Krennerile, 430. Krisuvigite, 397. Kronkite, 397. Krugite, 434. Kupferantimonglanz, 250. Kupferbleispatti, 396. Kupferglanz, 239. Kupferglimmer, 375. Kupferindig, 249. Kupferkies, 244. Kupferlasur, 411. Kupfernickel. 243. Kupfersammterz, 397. Kupferschaum, 374. Kupferschwiirze, ^67. Kupfferite, 29(>. Kupfer-uranit, 378. Kupfer-vitriol, 394. Kupferwismuthglanz, 250. Kyanite, 3-J2. Labradorite, 321. Labrador feldspar, 321. Lagonite, 382. Lampadite, 283. Lanarkite, 391. Langite, 397. Lanthanite, 410. Lapis-lazuli, 418. Larderellite, 383. Lasurstein, 418. Latrobite, v. Anorthite. Laumonite, Laumontite, 338. Laurite, 247. Lautite, 43J. Lavvrencite, 430. Laxmannite, 386. Lazulite, 375. Lead, Argentiferous, 2C3. Black (graphite), 230. Corneous (phosgeriite), 408. Native, 226. Leadantimonate, 370, 379. arsenate, 3(50. arsenio-molybdate, 385. carbonate, 407. chloride, ~61. chloro-carbonate, 408. chromate, 3s5, 386. molybdate 384. oxichloride, 262. oxide. 267, 277. phosphate, 366. selenide. 236. selenite, 432. silicate, 427, 429, 430, 431. sulphate. 389, 390, 391. sulphate-carbonate, 3Jl. sulphide, 235. sulpharsenite, 250, 251. sulphantimonite, 250, 251, 253, 254. sulpho-bismuthite, 252, 431,427. Lead telluride, 237, 249. tungstate, 38k vanadate, 367 ; 374, 426 Leadhillite, 390; 430. Leberkies, . Marcasite. Lecontite, 392. Ledererite. 345 Lederite. 336. Lehrbachite, 237. Leidyite, 430. Lennilite, 436. Leopoldite, 260. Lepidolite, 314. Lepidomelane, 313. Lepidophaeite, 440. Lernilite, 436. Lesleyite, 354. Lettsomite, 397. Leucaugite, 293. Leuchtenbergite, 357. Leucite, 318; 430. Leucochalcite, 430. Leucomanganite, 426. Leucopetrite, 315. Leucophanite, 300; 430. Leucopyrite, 248. Leucotile, 430. Leviglianite, 241. Levyne, Levynite, 343. Lherzolyte, 271. Libethenite, 373; 430. 'Liebigite, 412. Lievrite, 309. Lignite, 418. Ligurite, 336. Limbachite, 351. Lime = Calcium oxide, v. Calcium. Limestone, 400, 401 Limonite, 280. Linarite, 396. LinnaBite, 245. Linsenerz, 374. Lintonite, 438. Lionite, 437. Liroconite, 374. Liskeardite, 430. Lithionglimmer, 314. Lithiophilite, 438. Lithographic Stone, 400. Lithomarge, 352. Livingstonite, 232; 430. Loganite, 358. Loliingite, 248. Louisite, 430. Loweite, 394. Lowigite, 396. Loxoclase, 326. Luckite, 431. Ludlamite, 372. Ludwigite, 38". Luneburgite, 382. Luzonite, 258. Lydian stone, 287. 516 GENERAL INDEX. Macfarlanite, 430. Made, 331. Maconite, 355. Magnesia = Magnesium ox- ide, v. Magnesium. Magnesioferrite, 273. Magnesite, 402. Magnesium aluminate, 271. arsenate, 371. borate, 380, 381. carbonate, 402, 409. chloride, 2GO,261, 423. fluoride, 264. fluo - phosphate, 368. fluo-silicate, 327. hydrate, 281. nitrate, 379. oxide, 267. phosphate, 368, 432. silicate, 290, 300, 348, 349, 350. sulphate, 394. Magneteisenstem, 272. Magnetic iron ore, 272. Magnetic pyrites, 241. Magnetite, 212. Magnetkies, 241. Magnoferrite, 273. Magnolite, 430. Malachite, Blue, 411. Green, 411. Malacolite, 293. Maldonite, 221. ' Malinovvskite, 256. Mallardite, 431. Manganapatite, 420. Manganblende, v. Alabandite. Manganbrucite, 422. Manganepidot, 308. Manganese borate, 380. carbonate, 403. columbate, 423. oxide, 277, 278, 280, 282, 283, 431. phosphate, 369, 435, 439. silicate, 294, 300, SOI. sulphide, 237, 244. sulphate, 431, 437. tantalate, 359, 437. tungstate, 883. Manganglanz, 237. Manganite, 280. Manganocalcite, 406. Manganophyllite, 312. Manganosiderite, 435. Manganosite, 431. Manganspath, 403. Mangantantalite, 437. Marble, 400. Verd-antique, 350. Marcasite, 247. Margarite, 357. Margarites, 110. Margarodite, 353; 314. Margarophyllites, 348, et seq. Marialite, 316. Marionite. 410. Marmairolite, 431. Mannatite, 238. Marmolite, 350. Martite, 269. Mascagnine. Mascagnite, 392. Maskelynite, 322. Masonite, 358. Massicot, 267. Matlockite, 262. Matricite, 431. Maxite, 391. Medjidite, 397. Meerschaum, 349. Megabasite, :-.88. Meionite, 315. Melaconite, 267. Melanglanz, v. Stephanite. Melanite, 304. Melanochroite, 386. Melanophlogite, 289. Melanosiderite, 281. Melanotekite, 431. Melunothallite, 431. Melanterite, 395; 431. Melilite, Mellilite, 306. Melinophane, 300. Meliphanite, 300; 431. Mellite, 412. Meionite, 2^9. Menaccanite, 269, 431. Mendipite, 262. Mendozite, 395. Meneghinite, 256. Mengite, 36->. Mennige, 277. Meroxene, 431. Mercury, Native, 224. Mercury chloride, 260. iodide, 260. selenide, 237. sulphide, 240, 241. telluride, 423. tellurate, 430. sulph -antimonite, 232. Mesitine, Mesitite, 403. Mesolite, 343. Mesotype, 342. Metabrushite, 371. Metacinnabarite, 241. Metaxite, 351. Meymacite, 234. Miargyrite, 249. Mica Group, 301; 431. Michaelsonite, 308. Microcline, 326. Wicrolite, 359; 431. Microphyllites,Microplakites, 322. Microsommite, 317. Middletonite, 415. Mikroklin, v. Microcline. Milarite, 432. Millerite, 241. Mimetene, Mimetite, 366 ; 432. Mimetese, Mimetesite, 366. Mineral coal, 417. oil, 413. pitch, 416. tar, 413. Minium, 277. Mirabilite, 392. Mispickel, 247. Misy, 395. Mixite, 432. Mizzonite, 316. Molybdanglanz, 283. Molybdanocker, 284. Molybdenite, 233; 432. Molybdenum oxide, 284. sulphide, 233. Molybdite, 284. Molybdomenite, 432. Molysite, 261. Monazite, 368: 432. Mondstein, v. Moonstone. Monetite, 432. Monimolite, 370. Monite, 4:i2. Monrolite, 332. Montanite, 397. Montebrasite, 370; 420. Monticellite, 300. Montmartite, v. Gypsum. Montmorillonite, 349.. Moonstone, 323, 324, 825. Mordenite, 432. Morenosite, 895. Moroxite, 365. Mosandrite, 309. Mottramite, 374. Mountain cork, 297. leather, 297. Muckite, 435. Muromontite, 308. Muscovite, 313. Musenite, v. Siegenite. Nadeleisenstein, 280. Nadelerz, 254. Nadelzeolith, 342. Nadorite, 370. Nagyagite, 249; 432. Namaqualite, 282. Nantokite, 2GO. Naphtha. 413. Naphthaline, 414. GENERAL INDEX. 517 Natrolite, 342; 432. Natron, 409. Natronborocalcite, 381. Naumannite, 235. Needle ore, v. Aikinite. Nemalite, 282. Neochrysolite, 423. Neocyanite, 432. Neotocite, 354. Nepheline, Nephelite, 316. Nephrite, 297, 432. Neudorfite, 435. Newberyite, 432. Newjanskite, 224. Newport! te, 358. Niccolite, 242. Nickel antimonide, 243, 247. arsenate, 372. arsenide, 242 ; 246. carbonate, 410. oxide, 267. silicate, 351, 427. sulphate, 395. sulphide, 241. telluride, 249. Nickel glance, v. Gersdorffite. Nickelarsenikglanz, 246. Nickelarsenikkies, 246. Nickelbliithe, 372. Nickel-Gymnite, 351. Nickelkies, 241. Nickelsmaragd, 410. Niobife, 860. Nitre, 379. Nitrobarite, 433. Nitrocalcite, 379. Nitroglauberite, 379. Nitromagnesite, 379. Nocerine, Nocerite, 433. Nohlite, S62. Nontronite, 350. Nosean. Nosite, 318. Noumeaite, Noumeite, 351. Nuttalite, v. Wernerite. Ochre, red, 269. Octahedrite, 277; 433. CEllacherite, 854. Okenite, 338. Oldhamite, 235. Oligoclase, 323. Olivenite, 373. Olivine, 300. Onofrite, 433. Ontariolite, 435. Onyx, 287. Oolite, 400. Opal, 288. Ophiolite, 350, 402. Orangite, 340. Orpiment, 231 ; 433. Orthite, 308; 433. Orthoclase, 325; 433. Oryzite, 429. Osmiridium, 224. Osteolite, 365. Ottrelite, 358; 433. Ouvarovite, 304. Owenite, 358. Oxammite, 433. Ozarkite, 342. Ozocerite, Ozokerit, 414; 433. Pachnolite, 205; 438. Pagodite, 349, 352. Paisbergite, 294. Palagonite, 353. Palladium, Native, 224. Pandermite, 434. Parachlorite, 436. Paraffin, 413. Paragonite, 354. Parankerite, 402. Paranthite, 316. Parasite, v. Boracite. Parastilbite, 426. Parathorite, 340. Pargasite, 297. Parisite, 408. Parophite, 353. Pattersonite, 358. Pealite, 289. Pearl -mica, v. Margarite. Pearl-spar, 401. Pechkohle, 417. Pechopal, 289. Peckhamite, 433. Pectolite, 337; 433. Peganite, 378. Pegmatolite, v. Orthoclase. Pelagite, 433. Pelhamite, 355. Pencatite, 410. Pennine, Penninite, 55. Penwithite, 433. Percylite, 262. Periclase. Periclasite, 267. Peridot, 300, 830. Perikline, Periklin, 324. Peristerite, 324. Perlglimmer, 357. Perthite, 326. Perofskite, 270; 433. Perowskit, 270. Petalite, 295; 433. Petroleum, 413. Petzite, 2- 9. Phacolite, 344. Phamctinite, 420. Pharmacolite, 870. Pharmacosiderite, 376; 433. Phenacite, Phenakit; 301 433. Phengite, 431. Philadelphia, 439. Phillipite, 397. Phillipsite, 345; 433. Phlogopite, 312. Phcenicochroite, 386. Pholerite, 352. Phosgenite, 408. Phosphocerite, 364. Phosphochalcite, 374. Phosphochromite, 386. Phosphorite, 365. Phosphuranylite, 434. Phyllite, 358. Physalite, 333. Phytocollite, 425. Piauzite, 416. Picite, 431. Pickeringite, 395; 434. Picotite, 271. Picranalcite, 420. Picroallumogene, 434. Picrolite, 351. Picromerite, 394. Picropharmacolite, 371. Pictite, 336. Piedmontitc, COS. Pihlite, 349. Pilarite, 423. Pilinite, 344. Pilolite, 434. Pimelite, 351. Finite, 352. Pisanite, 395. Pisolite, 400. Pistacite, Pistazit, 307. Pistomesite, 403. Pitchblende, 274. Pittasphalt, 413. Pitticite, Pittizit, 379. Plagiocitrite, 484. Plagioclase, 319. Plagionite, 251. Plasma, 286. Plaster of Paris, 393. Platinum, Native, 223; 434. Platiniridium, 224. Pleonaste, v. Spinel. Plumbago, 230. Plumballophane, 341. Plumbogummite, 377. Plumbomanganite, 484. Plumbostannite. 434. Plumbostib, v. Boulangerite. Polianite, 278. Pollucite, Pollux, 299. Polyargite, 353. Polyargyrite, 257. Polybasite, 257. Polycrase, 362. Polychroilite, 353. Pol vdy mite, 434. Polyhalite, 393; 434. Polym ignite, 302. Poonahlite,343. Porcellophite, 851. Posepnyte, 435. Potassium chloride, 260. chromate (?), 437. 518 GENERAL INDEX. Potassium nitrate, 379. silicate, 313, 325. sulphate, 390. Potash = Potassium oxide, v. Potassium. Prase, 286. Prasine, 374. Praseolite, 353. Predazzite, 410. Pregattite, 354. Prehnite, 340. Priceite, 382; 434. Prochlorite, 357. Proidonite, 264. Prosopite, 265. Protobastite, 290. Protochlorite, 436. Protovermiculite, 439. Proustite, 25:5. Prussian blue, Native, 372. Przibramite, 218, 280. Pseudobrookite, 434. Pseudocotunnite, 261. Pseudomalachite, 374. Pseudonatrolite, 434. Pseudophite, 356. Psilomelane, 282 ; 434. Psittacinite, 374. Pucherite, 367. Purple copper, 237. Pycnite, v. Topaz. PyraUolite, 348. Pyrargillite, 353. Pyragyrite, 252. Pyreneite, 304. Pyrgom, 293; 434. Pyrite, 243. Pyrites, Arsenical, 247. Auriferous, 220. Capillary, 241. Cockscomb, 247. Copper, 244. Iron, 243. Magnetic, 241. Radiated, 247. Spear, 247. White iron, 247. Pyrochlore, 359. Pyroehroite, 282. Pyroconite, 265. Pyrolusite, 278; 434. Pyromorphite, 366. Pyrope, 303. Pyrophosphorite, 434. Pyrophyllite, 349. Pyropissite, 414. Pyroretinite, 415. Pyrosclerite, 355. Pyrosmalite, 340. Pyrostilpnite, 252. Pyroxene, 292. Pyrrhite, 359. Pyrrhosiderite, 280. Pyrrhotite, 241; 434. Quartz, 284; 434. Quecksilberbranderz, 414. Quecksil berhornerz, 260. Quicksilver, 224. Radelerz, 253. Radiated Pyrites, 247. Raimondite, 395. Ralstonite, 265, 435. Randite, 43"). Ratofkite, 263. Rauite, 342. Raumite, 353. Realgar, 231. Red copper ore, 266. hematite, 209. iron ore, 269 . ochre, 269. silver ore, 252, 253. zinc ore, 266. Reddingite, 435. Refdanskite, 851. Reichardtite, 426. Reinite, 4 5. Reissite, 426. Remingtonite, 410. Rensselaerite, 348. Resanite, 339. Resin, Mineral, 415, 435. Restorm elite, 353. Retinalite, 351. Retinite, 415. Reussinite, 415. Rhabdophane, 435. Rhsetizite, 332. Rhagite, 377. Rhodizite, 435. Rhodochrosite, 403; 435. Rhodonite, 294. Rhomb-spar, 401. Rhyacolite, 326. Rionite, 256. Ripidolite, 356. Rittingerite, 252. Rivotite, 370. Rock cork, v. Hornblende, crystal, 286. meal, 401. milk, 400. salt, 259. Roemerite, 395. Roapperite, 300. Rcesslerite, 371. Rogenstein, 400. Rogersite, 435. Romeine, Ifomeite, 370. Roscoelite, 367; 435 Rose quartz, 286. Roselite, 372; 435. Rosterite, 420. Rosthornite, 415. Rosite, 353. Rothbleierz, 385. Rotheisenerz, 268. Rothgiiltigerz, 252, 253. Rothkupiererz, 266. Rothnickelkies, 242. Rothoffite, 303. Rothzinkerz, 266. Rubellite, 330. Rubislite, 435. Ruby, Spinel, Almandine,271. Oriental, ^68. Ruby-blende, v. Pyrargyrite. Ruby silver 25 - J . 253. Rutherfordite, 362. Rutile. 276; 435. Ryacolite, v. Rhyacolite. Sahlite, 293. Sal ammoniac, 260. Salmiak. 2(iO. Salt, Common, 259. Samarskite, 301 ; 435. Sammetblende, 280. Sanidin, 325. Saponite, 352. Sapphire 3r>8; 330. Sarawakite, 435. Sarcolite, 316. Sarcopside, 369. Sard, 287. Sardonyx, 287. Sartorite, 250. Sassolite, Sassolin, 380. Satin-spar, 398, 400, 405. Saussurite, 309. Savite, v. Natrolite. Scapolite Group, 315; 435. Schaumspath, 4(JO. Scheelite, 384. Scheereite, 413. Schieferspath, 400. Schilfglaserz, 252. Schiller-spar, 351. Schirmerite, 251. Schmirgel, 2' 8. Schneebergite, 431. Schorlomite, 337; 435. Schraufite. 415. Schreibersite, 242. Schrifterz, Schrift-tellur, 248. Schrockingerite, 412. Schuchardtite, 436. Schuppenstein, 415. Schwartzembergite, 262. Schwarzkupfererz, 267. Schwatzite, 255. Schwefelkies, 243. Schwerspath, 387. Scleretinite, 415. Scleroclase, 250. Scolecite, Scolezite, 343. Scorodite, 375. Seebachite, 344. Selenblei, 236. Selenite, 393. Selenquecksilber, 237. GENERAL INDEX. 519 Sellaite, 264. Semeline, 335. Semseyite, 436. Senarmontite, 284; 436. Sepiolite, 349; 436. Serpentine, 350 ; 436. Serpierite, 436. Seybertite, 358. Shepardite, 242. Siderazot, 436. Siderite, 403. Sideronatrite, 436. Siderophyllite, 431. Siegburgite, 415. Siegenite. 24o. Silaonitc, 233: 428. Silberamalgam, 225. Silberglanz, 2 : >5. Silberhorncrz, 260. Silberkupt'erglanz, 240. Silberwismuthglanz, 420. Silex. v. Quartz. Silicified wood, 286. Siliceous sinter, 287, 289. Siliciophite, 4:!6. Silicoborocalcite, 382. Sillimanite, 331. Silver, 223. Antimonial. 234. Bismuth, 420. Horn, 260. Native, 223. Ruby, 252, 253. Vitreous, 2^5. Silver antimonide, 234. chloride, 260. bromide, 260. iodide, 260. selenide, 235. sulph-antimonite, 250, 252, 256, 257. sulph-arsenite, 253. sulphide, 235, 239. sulpho-bismuthite,420. telluride, 238; 248, 437 Silver glance, 235. Simonyite, 394. Sinter, Siliceous, 287, 289. Sipylite, 436. Sismondine, 358. Sisserskite, 224. Skapolith, v. Scapolite. Skleroklas, v. Sartorite. Skolezit, v. Scolecite. Skutterudite, 246. Smaltine, Smaltite, 245; 436. Smaragdite, 297. Smectite, 349. Smithsonite, 404. Soapstone, 348. Soda = Sodium oxide, v. So- dium. Soda nitre, 381. Sodalite, 317. Sodium borate, 381. carbonate, 408, 409. chloride, 259. fluoride, 264. nitrate, 379. silicate, 323, 342. sulphate, 390, 391, 892. Sommite, 316. Sonnenstein, v. Sunstone. Sonomaite, 434. Spargelstein, 365. Spathic iron, 403. Spathiopyrite, 246. Spear pyrites, 247. Speckstein. 348, 352. Specular iron, ^68. Speerkies, 247. Spessartite, 304. Speiskobalt, 245. Sphaerocobaltite, 436. Sphaerosiderite, 403. Sphaerostilbite, 340. Sphalerite, 237; 436. Sphene, 335. Spiauterite, 242. Spinel. 271. Spinthere, 335. Spodiosite, 430. Spodumene. 295; 436. Sprodglascrz, 256. Sprudelstein, 405. Staffelite, v. Phosphorite. Stalactite, 400. Stalagmite, 400. Stanekite, 415. Stannite, 245. Staurolite, Staurotide, 336; 437. Steatite, 348. Steeleite, 432. Steinkohle, 417. Steinmark, 352. Steinol, 413. Steinsalz, 259. Stephanite, 256. Sterlingite, 354. Sternbergite. 240; 437. Stibianite, 437. Stibiconite, 437. Stibioferrite, 370. Stibnite, 232; 437. Stilbite. 346,437; 347. Stilpnomelane, 349. Stolzite, 384. Strahlerz, 374. Strahlkies, 247. Strahlstein. 297. Strahlzeolith, v. Stilbite. Strengite, 437. Strigovite, 357. Stromeyerite, 240. Strontianite, 406; 437. Strontium carbonate, 406. Strontium sulphate, 388. Struvite, 371. Stiizite, 437. Stylotyp, Stylotypite, 254. Subdelessite, 425. Succinellite, 415. Succinite. 415. Sulphur, Native, 228. Sunstone, 3-'3, 325. Susannite, 391. Sussexite, 380. Sylvanite, 248. Sylvine, Sylvite, 260. Syngenite, 394. Szaboite, 437. Szaibelyite, 380. Szmikite, 437. Tabergite, 356. Tabular spar, 291. Tachhydrite, 261. Tafelspath, 291. Tagilite, 873. Talc, :i48. Talktriplite, 437. Tallingite, 262. Tantalite, 359; 437. Tapalpite, 239. Tapiolite, 361. Tarapacaite, 437. Tasmanite, 415. Taznite, 437. Tellur, Gediegen, 227. Tellurite, 437. Tellurium, Bismuthic, 233. Foliated, 249. Graphic, 24$. Native, 22 7; 437. Tellurium oxide, 437. Tellursilber, 238. Tellurwismuth, 233. Tengerite. 410. Tennantite, 256; 438. Tenorite, 207; 438. Tephroite, 300. Tequesquite, 438. Tequixquitl, 438. Tesseralkies, 246. Tetradymite, 233. Tetrahedrite, 255; 438. Thaumasite, 438. Thenardite, 390; 438. Thinolite, 438. Thomsenolite, 205; 438. Thomsonite, 342; 438. Thorite, 340; 438. Thulite, 309. Thuringite, 358. Tiemannite, 237. Tile ore, 2(56. Tin, Native, 220. Tin ore, Tin stone, 275. oxide, 275. pyrites, v. Stannite. 520 GENERAL INDEX. Tin sulphide, 245. Tinkal, 381. Titaneisen, 269. Titanic iron, 269. Titanite, 335; 438. Titanium oxide, 270; 276, 277. Titanolivine, 423. Titanomorphite, 438. Tiza, 0. Ulexite. Tobermorite, 428. Tocornalite, 260. Topaz, 332 ; 438. False. 286. Topazolite, 304. Torbanite. 415, 418; 438. Torbernite, Torberite, 378. Totaigite. 436. Tourmaline, 329, 438. Travertine, 400. Tremolite, 297. Trichite, 110. Triclasite, J353. Tridymite, 288; 439. Triphylite, Triphyline, 369; 439. Triplite, 369. Triploidite, 439. Tripolite, 289. Trippkeite. 439. Tritochorite, 426. Tritomite, 340. Trogerite, 379. Troilite, 242. Trona. 408. Troostite, 301. Tscheffkinite, 336. Tschermakite, 323. Tschermigite, 395. Tufa, Calcareous, 400. Tungsten oxide, 284. Tungstite, 284. Turgite, 279. Turmalin, 3?9. Turnerite, 368, 432. Turquois, 377. Tyrite, 362. Tyrolite, 374. Tysonite, 439. Ulexite, 381. Ullmannite, 247. Ultramarine, 318. Unionite, 309. Uraconise, Uraconite, 397. Uranglimmer, 378, 379; 439. Uranin, Uraninite, 272. Uranite, 378, 379. Uranium arsenate. 379. carbonate, 412,439. oxide, 274. phosphate, 378, 379, 434. silicate, 341. sulphate, 397. Urankalk, 412. Uranmica. 378, 379. Uranochalcite, 397. Uranocircite, 439. Uranophane, 341. Uranospinite, 379. Uranotantalite, 361. Uranothallite, 439. Uranothorite, 438. Uranotile, 341; 439. Uranpecherz, 274. Urao, 409. Urpethite, 413. Urusite, 436. Urvolgyite, 428. Uwarowit, 304. Vaalite, 355. Valentinite, 284. Vanadinite, 367; 439. Variscite, 439. Vauqueline, Vauquelinite, 386. Venasquite, 433. Venerite, 439. Verd-antique, 350. Vermiculite, 355 ; 439. Vesbine, 439. Vesuvianite, 305, 440. Veszelyite, 373, 440. Victorite, 290. Vietinghofite. 435. Villarsite, 340. Vitreous copper, 239. silver, 235. Vitriol. Blue, 394. Vivianite, 371. Voglianite. 397. Voglite, 412. Volknerite, 282. Volborthite, 374. Voltaite, 895. Vorhauserite, 351. Vreckite, 422. Vulpinite, 389. Wad, 283, 440. Wagnerite, 368; 440. Walchowite, 415. Walkerite, 433. Walpurgite, 379, 440. Waluewite, 440. Wapplerite, 371. Warringtonite, 396. Warwickite, 382. Wattevillite, 440. Wavellite, 376. Websterite. v. Aluminite. Wehr'ite, 233. Weissbleierz, 407. Weissite, 353. Weisspiessglaserz, 284. Wernerite, 316. Werthemanite. 396. Westanite, ;i32. Wheelerite, 415. Wheel-ore, 253. Whewellite, 412. Whitneyite, '235. Wichtine, Wichtisite, 299. Willcoxite, 358. Willemite. 301. Williamsite, 351. Wilsonite, 353. Winklerite, 372. Winkworthite, 382. Wiserine, 277, 364. Wismuth, Gediegen, 227. Wismuthglanz, 232. Wismuthocker, 284. Wismuthspath, 412. Witherite, 406. Wittichenite, 254. Wocheinite, 281. Wohlerite, 300. Wolfachite, 247. Wolfram, 383. Wolframite, 383. Wollastonite. 291. Wollongongite, 416; 438. Wood-opal, 289. Wood tin, 275. Woodwardite, 397. Worthite 332. Wulfenite, 384; 440. Wurfelerz, 376. Wurtzite, 242, 426. Xantholite, 437. Xanthophyllite, 358; 440. Xanthosiderite, 281. Xenotime, 364; 440. Xyloretinite, 415. Yenite, 309. Youngite, 440. Yttergranat, 303. Ytterspath, 364. Yttrium phosphate, 364. Yttrocerite, 264. Yttrogummite, 423. Yttrotantalite, 361, 362. Yttrotitanite, 336. Zaratite, 410. Zeolite section. 342. Zepharovichite, 376. Zeunerite, 379. Ziegelerz, 266. Zietrisikite, 414. Zinc, Native, 226. Zinc aluminate 272. arsenate, 373. blende, 237. bloom, v. Hydrozincite, carbonate, 404, 410. Zinc ore, Red, 266. oxide, 266, 273. silicate, 801, 339. sulphate, 395, 440. sulphide, 237, 242. Zincaluminite, 440. Zincite, 266. GENERAL INDEX. Zinkbl lithe, 410. Zinkenite, 250. Zinkspath, 404. Zinnerz, Zirmstein, 275. Zinnkies, 245. Zinnober, 240. Zinnwaldite, v. Lepidolite. 521 I Zippeite, 397. ] Zircon, 304; 440. Zoisite, 308. i Zoblitzite, 351. ! Zonochlorite, 340. Zorgite, 237. Zwieselite, 369. UNIVERSITY OF CALIFORNIA I.BRARY 3*1 LeConte Hall LIBRARY OF THE UNIVERSITY OF CALIFORNIA L 642-312! ALL BOOKS MAY BE RECALLED AFTER 7 DAYS Overdue books are subject to replacemei "rniTAS STAMPED BELOVV FORM NO. 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