MINERALS OF CALIFORNIA BULLETIN No 113 STATE DlViSIi ; . .. : BUILDIN COLLEGE OF AGRICULTURE DAVIS, CALIFORNIA STATE OF CAUFORNIA DEPABTMENT OF NATURAL RESOURCES GEORGE D. NORDENHOLT, Director DIVISION OF MINES WALTER W. BRADLEY State Mineralogist GEOLOGIC BFL^NCH OIAF P. JENKINS Ferry Building, San Francisco Chief Geologist San Francisco BULLETIN No. 113 February, 1938 MINERALS OF CALIFORNIA By ADOLF PABST Associate Professor of Mineralogy University of California BERKELEY CALIFORNIA STATE PRINTING OFFICE GEORGE H. MOORE. State Printer SACRAMENTO. 1938 51440 TABLE OF CONTENTS Page Letter of Transmittal 5 Outline Map o['. California 6 Preface 7 Introduction 11 Native Elements 15 Sulphides and Tellurides of the Semi-metals 36 Sulphides, Selenides, Tellurides, and Arsenides of the Metals 4-} Oxysulphides 78 Sulphosalts 79 Haloids 86 Oxides 92 Cai'bonates 136 Borates 161 Nitrates 163 Sulphates 170 TeUurites 197 Chromates. Molybdates, Tungstates, and Uranates 198 Niobatos. Tantalates 203 Phosphates, Arsenates, Vanadates, and Antimonates 205 Hydrocarbons 220 Silicates 222 Glossary 312 Bibliograpliy 316 Index 339 (3) ^V^.\' LETTER OF TRANSMITTAL To His Excellency, the Honorable Frank F. Merriam, Governor of California. Sir: I have the honor to transmit herewith Bulletin No. 113 of the Di\ision of IMines of the Department of Natural Resources, on the "JVIinerals of California." California is known the ^vorld over for the remarkable number and diversity of her mineral substances that are annually produced and utilized for commercial and other beneficial purposes. She is equally well known among: scientists, mineralogists, teachers, and plain- citizen hobby collectors of minerals as a most fertile field for the study and collection of a long and varied list of mineral species. In fact, many new and rare species liave first been found and described from Californian localities. There is a growing interest among all classes of people of this State in the study of minerals. To have a record of the 'what' and 'where' is an important starting point to a knowledge of the mineral resources of possible commercial value. Previous editions of the "Minerals of California" have long since been exhausted, and the present work has been one of the items in the program of coordinated study and survey conducted by the Division of IMines to make available to the public a record of California's resources. The assembling and preparation of the text has been done by Dr. Adolf Pabst, Associate Professor of ]\Iineralogv, Universitv of Call- fornia, who also supervised the gathering of new data and revisions in cooperation with Dr. Olaf P. Jenkins, Chief Geologist of the Division of Mines, and with clerical assistance furnished by the Federal Works Progress Administration. Many contributions have been received from various individuals and organizations cooperating to make this bulletin an outstanding piece of work, complete, and up to date. Respectfully submitted. George D. Nokdenholt, Director, Department of Natural Resources. November 1, 1937. (5) [.' / • I M D ^SISKIYOU /I -STATE- 0F•CAL1F0RN[A■ •DEPARTMENT•DF■NATURAL•RES0URCE3• ■GEQRGE D. NDRDENHOLT - DIRECTOR- ■DIVISION ■ OF -MINES- •WALTER "W. BRADLEV- -STATE MmERALOQIBT- OUTLINE MAP ■ OF :Z1 iimT., \ -"•■--•■'/ 5 H A S T A i - 'trinity S ^ LASSEN / _ ^ -^ 1 SUS»NV1H.E CALIFORNIA I J T E H A M AJ Fp L U M A S >. I IMENOOCIHO _6 LE N n/B°UTT \ >' V r^'''sS."-l»'» ^'""■•"'^l '^g)^!^'•^ / T U I U M N [V 'g>_...X '.SJNJOAQlliliV ,' I u uiu MUL-y '*£' — .-»\ » /fsVuMtOA! /'ST»„"^SUU5>»MAR1P0SA /r K. ^V ) 9\ S»N \ , "'J''"\BtNlT0\ ^ \ I < I ^ ./k I •'"»''*"( *T U L A R E , r:::. x °\ s_ SSANTA BARBARA i»KCBSFltLO • Z R \ f SAN, BERNARDINO 'O .to j^^'»-f"''*\L0SAN6tLCS , V E R 5 1 D E J •LEGEND- -^ Mining Division Boundaries. O Mining Division Offices. MEXICO (6) PREFACE Tlie first list of California minerals was published by W. P. Blake in 1866, and it comprised about seventy-five mineral species. At that early time California was a new and largely unexplored field, and only a few scattered localities were known for mineral speci- mens; consequently, the list was short and not at all representative. The second list appeared in 1884 as a part of the Fourth Annual Report of the State Mining Bureau, by Henry G. Hanks, who was then State Mineralogist. This list included double the number of pre^aously known minerals, and gave detailed descriptions of some of the localities, and much instructive matter relating to minerals of economic value. The third list compiled by Dr. A. S. Eakle, was issued in 1914 as Bulletin 67, ''Minerals of California," of the California State Mining Bureau. In the thirty years which had elapsed since the api^earance of the second list, knowledge of the geology and mineralogy of the State greatly increased. The ore deposits of many of the counties, the gem and borate deposits of the southern counties, and the petrog- raphy of many districts, had been investigated and described, so that the third list contained more than double the number of definite mineral species given by Hanks, besides many subspecies and varieties. In 1923 a second edition of "Minerals of California" was pub- lished as Bulletin 91 of the California State Mining Bureau. Many additional species were included, and the list of localities in which some of the more common economic minerals occur was greatly increased. The present bulletin is a further revision. IMany occurrences described in the literature since the second edition have been included, and some material has been obtained from other sources. All of the older literature on the occurrence of minerals in California has been rechecked to eliminate errors. The number of citations to literature both before and after the date of the last edition has been greatly increased. Even with these changes, much material for which no good authority can be given has been retained in the new bulletin. Over 400 different minerals, not including varieties, are described in this bulletin. Of these 54 were discovered in California, including several that have proved to be of great importance. Colemanite. discovered in 1882, and kernite, discovered in flm are without 1927, (7) 8 MINERALS OF CALIFORNIA doubt the most important commercial borates. Lawsonite, first found in Marin county in 1895, has proved to be of great petrographic interest. The first new minerals discovered in California came from the gold mining region of the Sierra Nevada, beginning with the nickel telluride, melonite, found in Calaveras County in 1867. New minerals and new mineral localities are still being discovered so that such a catalogue as this is necessarily incomplete. Many minerals are so commonly dis- tributed throughout the State in small bodies or as rock-forming minerals that it would be impossible to cite all of their occurrences. The minerals first found in California and the dates of their pub- lished descriptions are as follows : *Parteite, 1867 Melonite, 1867 *Mariposite, 1868 Calaverite, 1868 Metacinnabar, 1870 *Aragotite, 1873 Roscoelite, 1875 *Posepnyte, 1877 *Iouite, 1878 *Tincalcoiiite, 1878 Colemanite. 1883 *Hanksite, 1884 *Napalite. 1888 Sulphohalite, 1888 *Knoxvillite, 1890 *Redingtonite, 1890 Iddingsite, 1893 Lawsonite, 1895 *Northupite. 1895 Pirssonite, 1896 *Bakerite, 1903 *Bootiiite, 1903 *Tychite, 1905 *Benitoite, 1907 'Moaquinite, 1909 *Palaite, 1912 *Salmonsite, 1912 *Sicklerite, 1912 *Stewartite, 1912 Tnyoite, 1914 *Me,yerbofferite, 1914 Searlesite, 1914 *Wilkeite, 1914 *Crestmoreite, 1917 *Griffithite, 1917 *Riversideite, 1917 *Plazolite, 1920 *Yonsenite, 1920 *.Jurupaite, 1921 Mei-winite, 1921 *Kempite, 1924 *Foshagite, 1925 *Kernite, 1927 *Probertite, 1929 *Curtisite, 1930 Krausite, 1931 *Sanbornite, 1931 *Scbairerite, 1931 *Tilleyite, 1933 *Burkeite, 1935 *Woodbouseite, 1937 *EIlestadite. 1937 *Teepleite, 1938 *Veatcbite, 1938 So many minerals and localities are included in the list that geological and petrographieal descriptions in detail have had to be omitted, and reference must be made to the bibliography at the end of the work under the author's name and number. This bibliography includes, with few exceptions, only those articles which deal directly with minerals of the State, omitting the literature of a general nature on the geology and mining industry of California. For this, reference should be made to Bulletin 104, "Bibliography of the Geology and Mineral Eesources of California to December 31, 1930", of the Division of Mines, and also to Bulletin 115, a forthcoming bibliography for the years 1931 to 1936, inclusive. The work of preparing this revision has been carried on in part with the aid of a Federal Works Progress Administration project. Many mineral collectors and mineralogists have also contributed material for the revision. Two assistants, Mr. George L. Gary and Miss Alice Gilbertson have helped me faithfully throughout. Mr. Gary has done a large part of the work on the literature and has prepared the new bibliography. "THe writer is also greatly indebted to Mr. Walter W. * Minerals not yet been found, so far as known, outside of the State of California. PREFACE y Bradley and Dr. Olaf P. Jenkins of the State Division of Mines, Dr. Ian Campbell, of the California Institute of Technology, to Professor Austin F. Kogers of Stanford University, Mr. M. Vonsen of Petaluma, Mr. John Melhase of Berkeley, Professor A. 0. Woodford of Clare- mont, California, Dr. "W. T. Schaller of the United States Geological Survey, and to Dr. "W. F. Foshag of the United States National Museum, all of whom have given much valuable advice and information. Adolf Pabst. Berkeley, California, January, 1938. INTRODUCTION In Dana's "Textbook of Mineralogy," a mineral is defined as a body produced by the processes of inorganic nature, usually having a definite chemical composition and, if formed under favorable conditions, a certain characteristic crystal structure which is expressed in its form and other properties. Practically all of the inorganic part of the earth's crust is made up of what we would ordinarily call minerals. These minerals occur together in various combinations and are associated in larger masses or bodies, some of great extent, which we usually call rocks. Rocks are the aggregates. Minerals are the individual components, often easily recognizable with the unaided eye. Rocks are usualh^ classified broadly according to their origin. There are three principal groups: Igneous, sedimentary, and metamorphic. Igneous rocks are formed by the cooling of molten material. Examples of the formation of igneous rocks are familiar to all, in the cooling of lava emitted by active volcanoes. Such rocks cover great parts of the earth and are widely distributed in California. Not all igneous rocks have formed at the surface. Some have formed by the cooling and consolidation of molten masses beneath the surface. In the main, the granular igneous rocks such as granite have formed in this fashion. They are spoken of as intrusive rocks. Granitic rocks also occur in California making up a large part of the Sierra Nevada and of several other ranges. Sedimentary rocks are mostly formed by the deposition of frag- mental materials of either inorganic origin, such as gravels, sands and claj^s, or of organic origin, such as shells and other parts of animals and plants. Some sedimentary rocks have formed by chemical precipitation either from the ocean or from the waters of salt lakes. The principal kinds of sedimentary rocks are sandstone, shale, and limestone. They are often characterized by a bedded or laminated appearance, and sometimes carry recognizable remains of plants or animals. Metamorphic rocks are formed by physical or chemical changes in igneous or sedimentary rocks. Some of them greatly resemble certain igneous rocks. Most common rocks are simple in cr. Soluble in nitric acid, giving green solution, which turns blue on the addition of ammonia. Sayi Dieyo County: Violarite occurs with pyrrhotite and chalcopy- rite in the nickel ores of the Friday mine at Julian, Short and Shan- non (30). CHALCOPYRITE— Copper Pyrites A sulphide of copper and iron, CuFeS-. Tetragonal ; -scalenohedral. Generally massive. Metallic luster. Color deep brass-yellow, often with iride.scent tarnish. Streak greenish- black. H. =:3i — 4. G. = 4.1 — 4.3. Fusible and soluble. Ammonia added to a nitric acid solution pre- cipitates reddish ferric liydrate and turns solution blue. Becomes magnetic after roasting and small globules of copper are obtained by reduction with soda. Distinguished from pyrite by deeper color and presence of copper ; from bornite by its brass color ; and from gold by its ready solubility in nitric acid. Chalcopyrite is the commonest of the copper minerals, and forms the principal source of copper in the State. The copper deposits are SULPHIDES, SELENIDES, TELLURIDES, ARSENIDES OF THE METALS 67 largely bodies of pyrite in which ehalcopyrite is intermingled. Most of the deposits have a capping of earthy limonite and hematite result- ing from the oxidation of the iron sulphides. Practically all of the large bodies of pyrite in the State carry some ehalcopyrite, but those in Shasta, Phmuus, and Calaveras counties have been most important in the production of copper. Chalcopyrite in small patches and seams has a wide distribution, and in consequence of its alteration, green stains and coatings of copper carbonate are common. A general report on the copper resources of the State is contained in Bulletin No. 50 of the State Division of Mines. Alameda County: A body of pyrite containing a small amount of chalcopyrite was mined at Leona Heights, East Oakland, Schaller (03). Alpine County: Chalcopyrite occurs with the pyrite and enargite in the ]\Iogul district. Amador County: Chalcopyrite was the chief ore mineral in the Newton mine near Kanlett and in the Copper Hill mine. Chalcopyrite has been found in the gold ores of the Argonaut mine, Jullum (32). Butte County: It occurs near Bangor; with quartz, chalcocite, and gold on Berry Creek. Calaveras County: Chalcopyrite was the chief ore mineral in the copper mines near Copperopolis and Campo Seco. Contra Costa County: Chalcopyrite occurs with gold and bornite at a prospect in a ravine tributary to Mitchell Canyon on Mount Diablo, Turner (91). Bel Norte County: Deposits of chalcopyrite with pyrite and pyrrhotite occur at Low Di%dde, Diamond Creek and Shelly Creek, in the serpentine area of the northern portion of the countj- near Smith River and its tributaries. El Dorado County: Good specimens of chalcopyrite with bornite, molybdenite, garnet, epidoto, and axinite have come from the old Cosumnes copper mine on the Amador County line. Chalcopyrite occurs in small amounts in a hornblende schist near Rescue; with }\yrrhotite and pyrite at the Noonday mine; in gold-bearing quartz with galena at the Rose Kimberley mine; with malachite, azurite, and r.ative copper at the Cambrian mine, 13 miles northwest of Placerville ; in an amphibole schist at the Copper Lead mine, Martinos Creek; at the Pyramid and Boneset mines near Shingle Springs; with galena, magnetite, calcite, quartz, and garnet in the Lilyoma mine and in the Pioneer mine, Pilot Hill ; with bornite, azurite, and malachite at the Alabaster Cave mine, Pilot Hill; with chalcocite in serpentine at the Boston mine, Latrobe. 68 MINERALS OF CALIFORNIA Fresno County: Chalcopyrite occurs with pyrrhotite at the Fresno copper mines ; with pyrite at the Copper King mine ; and in the gold district of the northeastern part of the county. Humboldt County : Deposits of chalcopyrite occur on the eastern slope of Horse Mountain with chalcocite, native copper, and cuprite. It was found in small amounts near Trinidad, on the seacoast, and sparingly on Red Cap Creek. Imperial County: The copper claims near Ogilby, Hedges, and in the Picacho district contain some chalcopyrite with oxidized ores. Inyo County: Chalcopyrite occurs near Darwin at contact of granite and limestone and in the Ubehebe Mountains with chalcocite. It occurs with galena, cerusite, and native copper in limestone at Chloride Cliff, Grapevine Range ; at contact of limestone and diorite at Gold Belt in the Panamint Range; with pyrrhotite, bornite, and pyrite in Marble Canyon, 25 miles east of Big Pine; in garnet rock in Mazourka Canyon; as banded masses with galena at the Custer mine; with gold quartz at the Golden Treasure mine; in the Argus Range; with galena and pyrite 5 miles southeast of Keeler. It was found at the Wilshire gold mine, 25 miles southwest of Laws, Turner (22). Kern County: Chalcopyrite occurs with pyrite in the gold mines of the eastern part of the county near Randsburg and Garlock; with sphalerite and pyrrhotite near Lebec; with wolframite near Woody. It was found at the Greenback Copper mine, 18 miles east of Jasmin, Turner (02a). Lake County: Chalcopyrite occurred with pyrrhotite on the Lang- try ranch, 7 miles south of Middletown. Los Angeles County: It occurs intimately mixed with pyrrhotite near San Fernando ; with pyrite and malachite, 2 miles north of Camp Rincon, San Gabriel Canyon. Madera County: It is found in small masses at the old Buchanan mine, at the Ne Plus Ultra and other claims near Daulton. It occurs as thin seams in massive pyrrhotite in chlorite and actinolite at the Heiskell mine ; with sphalerite in quartz in the Nellie mine, Hildreth ; in intimate mixture with sphalerite and i)yrrhotite at the IMatilda and Best Chance mines. Minaret district. Marin County: Small deposits of pyrite mixed with chalcopyrite occur in the schists between Mount Tamalpais and Bolinas Bay. A small deposit occurred about 1 mile east of Woodville and north of Bolinas. SULPHIDES, SELENIDES, TELLURIDES, ARSENIDES OF THE METALS 69 Mariposa County: The Green Mountain Copper Group 8 miles northwest of Raymond, the old Pocahontas mine near Lewis, the Cop- per Hill mines in Indian Gulch, the old Beretta mines and other claims near the Merced River, contain massive chaleopyrite with auriferous pyrite. It occurs with tetrahedrite at the Bunker Hill mine; with pyrite and arsenopyrite at Hornitos; at the Peterson, Comet, "White Rock, and Donaway mines. Mendocino County: It occurs with malachite in small quartz veins at the Eden Valley mine and in the Red Mountain district. Napa County: It was found in the gold-silver ores of the Palisades mine, 2 miles north of Calistoga. Nevada County: Chaleopyrite claims have been worked at Spence- ville. Mineral Hill, Pine Hill, Iron Mountain, French Corral, and North San Juan. Good masses of pure chaleopyrite are found in the Meadow Lake district. It occurs with pyrite in quartz veins in the schists extending from Birchville northward to Bullard's Bar, Sierra County. Placer County: Chaleopyrite occurs with pyrite near Auburn, Newcastle, "Valley View, and at Dairy Farm. Plumas County: Chaleopyrite is one of the principal ore minerals at the Walker mine and at the Engels and Superior mines, Anderson (31), which have been the leading copper producers in the State since 1915. Riverside County: Chaleopyrite occurs in copper prospects in the Palen and McCoy mountains. It is common in the auriferous quartz veins of the Monte Negro district. It occurs with pyrite and galena at the Crestmore limestone quarry, Eakle (17). San Benito County: It occurs in small amounts on Lewis Creek. 8a7i Bernardino County: Chaleopyrite occurs with oxidized copper ores on Clark Mountain, in the New York Mountains, near Ivanpah, Manvel, Vontrigger, Sunrise, Needles, on IMount Whipple, IMonument Mountain, Turtle Mountain, and in the Providence Mountains. It is found in the Lava Beds district, in the Oro Grande district, and in the Morrow district north of Barstow. It occurs in limestone at the Three States mine. Silver Lake district. Large specimens of chaleo- pyrite have come from the Kingston Range. It is found with specular hematite, quartz and pyrite in the Bullion district. It occurs with galena, argentite and pyrite in the Goldstone district. It was found in a quartz vein with sphalerite, galena, and wolframite at the Saga- more mine, New York Mountains. 70 - MINERALS OF CALIFORNIA San Diego County: Masses of chalcopyrite occur in the Encinitas group of mines, a few miles east of Encinitas and in the Banna mines near Lakeside. It was found in the Julian district, Calkins (16a), Hudson (22). It was found in gold-bearing quartz veins on Barker Mountain, San Luis Ohispo County: It was observed at Cambria. Santa Barbara County: It occurs with quartz in shale at several i^oints along the southern slope of the San Rafael Mountains, northeast of Los Olivos. Shasta County: Chalcopyrite was the prineii)al ore mineral in the Shasta County copper belt which included the Iron Mountain, Shasta King, Balaklala, Golinsky, Mammoth, Afterthought, Copper City and Bully Hill mines. Sierra County: Small masses of chalcopyrite with other sulphides occur near Poker Flat, Sierra City and in the Mohawk Valley. It occurred at the Black Jack mine. Kanaka Creek; at Four Hills, Sierra City district ; in the Alaska mine and tlie Gold Canyon mine, Alle- ghany district. Si.^kiyou County: The Richie mine and claims near Callahan show chalcopyrite. It occurred at the Dewey and Oak Hollow mines, Happy Cam]i; in the Buckeye district; at the Hunter mine. Cherry Creek; massive fine-grained about 4 miles southeast of Fort Jones; at the Yellow Butte mine. Weed ; massive mixed with pyrrhotite and pyrite at the Carlson mine, Dutch Creek; in quartz at the New York Gulch mine, Indian Creek; at the Blue Ledge mine, Elliot district; at the Apex mine, head of Cottonwood Creek; with pyrrhotite in schist on the South Fork of Salmon River and on Preston Peak ; at the Maryland mine, Quartz Valley; at the Bonanza mine near Honolulu; mixed with }->yrrhotite 8 miles east of Callahan : at the Doolittle and Gazelle mines. Sonoma County: Chalcopyrite occurs in small crystals with mala- chite and azurite at the Sonoma Copper mine, half a mile east of Tyrone ; with pyrite on Black Mountain ; in the Cornucopia mine, 14 miles northeast of Cloverdale ; in the Grizzly mine, 18 miles northeast of Healdsburg. Tehama County: It was found 5 miles northwest of Paskenta; with pyrite on the northern slope of Tom Hood Mountain, 40 miles west of Red Bluff. Trinity County : Deposits of chalcopyrite occur in the western part of the county along New River, at the mouth of Rattlesnake Creek and on the Cold Fork of Indian Valley Creek ; in the Copper Queen SULPHroES, SELENIDES, TELLURmES, ARSENIDES OF THE METALS 71 and Headlight mines, Carrville district; witli pyrite in schists near Kuth ; in the quartz of the Gambrinins and Craig gold mines ; at the Bear Tooth mine, New River district ; near Zenia ; with pyrrhotite at Island Mountain. Tulare County: Chalcopyrite with pyrite is found on the Middle Fork of Tule River, a few miles east of Porterville and near Kearsarge Peak. Tuolumne County: Masses of chalcopyrite occur with pyrite in quartz at the Union, Conrad and Society mines. Big Oak Flat ; with other sulphides at the Keltz mine, 10 miles north of Soulsbyville ; in auriferous quartz at the Black Oak mine, Soulsbyville; at Chinese Camp ; near Rawhide ; at the Experimental mine, 2 miles northwest of Columbia ; at the Mann Copper mine, 3 miles south of Jamestown ; at the Golden Gate mine near Sonora ; at tlie Greenstone, San Guiseppe, Mount Dana, Piatt and Golden Treasure mines. Yuha Couniii: It occurs in auriferous quartz in the Bi-ownsvillc district, in the Golden Mary mine; in the Ayer mine, 4 miles west of Sniartsville. PYRITE— Iron Pyrites Iron disulphide, FeSa. Isometric ; diploidal. Crystals common ; usually cubes, pyritohedrons and octahedrons. Generally compact and granular massive. Brittle. Metallic luster. Color brass-yellow. Streak greenish-black. H. := 6 — 6J. G. = 5. Easily fusible. Roasted on charcoal, it burns with a blue flame and gives a strong sulphur odor. The residue becomes magnetic. Soluble in nitric acid and reddish ferric hydrate is precipitated by ammonia. Pyrite is the commonest of the sulphide minerals and is found in all kinds of rock, but is especially prominent in metamorphic schists, slates, and quartzites, and in unaltered sandstones. It is commonly found in distinct crystals and in granular masses. Cubes several inches in diameter are frequent in gold districts, but in general the smaller crystals and granular masses are more highly auriferous. All of the localities given for chalcopyrite, and many more, might be cited for pyrite since it is present in every county. The oxidation of pyrite I)roduees limonite and hematite, and the 'gossan' of mineral veins is mostl}' formed by its alteration. Cubes of limonite as pseudomorphs after pyrite are exceedingly common. Alameda County: Crystals from the Alma mine, Leona Heights, have the forms: (110), (100), (340), (120), (140), (111), (252), (121), (241), and (231), Schaller (03). Calaveras County: Cubes and pyritohedrons occur with the gold ou Carson Hill, but the long needles from the Stanislaus mine, described as distorted pyrite crystals by Jackson (86) are millerite. Good cubes are found at Murphy in the Masonia mine. 72 MINERALS OF CALIFORNIA Colusa County: Hexagonal plates of pyrite occur as pseudomorphs after pyrrhotite at the Sulphur Creek deposit, Genth (87). Mendocino County: A large deposit of pyrite carrying chalco- pyrite occurs in Anderson Valley. Riverside County: Pyrite is present in the Crestmore limestone as grains, cubes and pyritohedrons ; some of the crystals are large. Limo- nite pseudomorphs after the pyrite are common. Santa Clara County: Crystals from the New Almaden cinnabar mine had the forms: (100) and (470), Jackson (86). Shasta County: It was found by Day and Allen (25) in the hot springs and mud pots of Lassen Volcanic National Park. Pyrite used for sulphuric acid occurs in commercial quantities and is produced at the Hornet mine in the NB. ^ of Sec. 34, T. 33 N., R. 6 W., M. D. M. Sonoma County: Large octahedrons have been found on Austin Creek, near Healdsburg. Trinity County: It occurs with pyrrhotite at Island Mountain. Tuolumne County: Small cubes are common at the Norwegian mine. COBALTITE Sulpharsenide of cobalt, CoAsS. Isometric. Commonly in cubes and pyritohedrons ; also massive. Cleavage perfect cubic. Metallic luster. Color reddish-white. Streak grayish-black. H. = 5i. G. = 6 — 6.3. On charcoal it gives sulphur odor and white coating of arsenic oxide when roa.sted. The residue becomes magnetic. Borax bead of the roasted material is cobalt blue. Ammonia colors a nitric acid solution of cobaltite pink. Mariposa County: Good cobaltite crystals were found in the Cop- per Chieftain mine. Mono County: It occurred with gold in the Tioga mine, Turner (94). Nevada County: Small seams of cobaltite with ehalcopyrite occur in a schist on Rattlesnake Creek, south of Signal Peak. Placer County: It was found with arsenopyrite in the Metallic mine, near Cisco ; with ehalcopyrite about 4 miles northeast of Alta. SMALTITE Cobalt arsenide, CoAss. Isometric ; diploidal. Generally massive. Brittle. Metallic luster. Color tin-white. Streak grayish-black. H. z=5i — 6. G. z= 5.9 — 6.8. The roasted mineral becomes magnetic. Gives a white coating of arsenic trioxide on charcoal. A cobalt-blue bead of borax is obtained, using the roasted mineral. Calaveras County: Smaltite has been found with erythrite in a small stringer at the Mar John mine near Sheepranch, Logan (24). SULPHroES, SELENIDES, TELLURIDES, ARSENIDES OF THE METALS 73 Los Angeles County: Smaltite coated with eiythrite occurred with the native silver and argentite at the old Kelsey and 0. K. mines near San Gabriel Canyon. Napa County: Smaltite has been found in thin seams with eryth- rite in the serpentine rock of Berryessa Valley. Nevada County: It occurs in the Meadow Lake district. MARCASITE Iron disulphide, FeS2. Orthorhombic. Commonly in tabular crystals. Massive ; radiating fibrous ; in stalactites. Brittle. Metallic luster. Color pale brass-yellow. Streak brownish-black. H. = 6 — 6i. G. = 4.85 — 4.90. Roasted on charcoal, it gives sulphur odor and yields a magnetic residue. Distinguished from pyrite by crystal form. Marcasite is rarer than pyrite, and is characteristic of the upper or altered parts of certain sulphide deposits. Inyo County: Marcasite has been found with pyrite, pyrrhotite and chalcopyrite in the Curran mine, near Panamint, Sampson (32). Napa County: Marcasite occurred abundantly with cinnabar at the old Redington mine, Knoxville. Marcasite has been found in the Palisades mine, about 2 miles north of Calistoga. Nevada County: It is mentioned as one of the minerals of the Grass Valley mines by Lindgren (96). LOLLINGITE Iron diarsenide, FeAs2. Orthorhombic. Small crystals. Usually massive. Metallic luster. Color silver-white to light steel-gray. Streak grayish-black. H. = 5 — 5i. G. = 7.0 — 7.4. Similar to arsenopyrite in its reactions except that it gives no sulphur deposit in a closed tube. Amador County: Small crystals of lollingite Avere found in the black slate at the Mayflower mine, Amador City. ARSENOPYRITE Sulpharsenide of iron, FeAsS. Orthorhombic. Common in crystals. Generally compact to granular massive. Brittle. Metallic luster. Color silver-white to steel-gray. Streak grayish-black. H. = 5J — 6. G. = 5.9 — 6.2. Copious white volatile fumes of arsenic oxide and a strong garlic odor are obtained when arsenopyrite is roasted on charcoal. Residue becomes magnetic. Borax bead is yellow to pale-green. Decomposed by nitric acid with the separation of sulphur. Arsenopyrite is a common vein mineral. The concentrates from most of the mining regions of the State generally contain arsenopyrite and in some districts it is the chief gold-bearing mineral. Danaite is a variety containing from 3 to 9 per cent of cobalt. 74 MINERALS OF CATjIFORNIA Amador County: Arsenopyrite occurs with tlie gold ores in the Argonaut mine near Jackson, Josephson (32). Calaveras County: Arsenopyrite, high in gold content, has been found near Angels Camp and in mines along the Mother Lode. Cobalt- iferous arsenopyrite has been found on a claim known as the Hauselt Patent, 2 miles southeast of Sheepranch, Hess (27). Del Norte County: It was found at Monkey Creek. El Dorado County: It ()eeiirrt.'(l ;it the Florence mine, near Placer- ville. Auriferous arsenopyrite occurs at the Frog Pond mine, half a mile north of Garden Valley ; at the Barnes Eureka mine, near Shingle Springs; in the Mount Pleasant district. Fresno County: Large amounts of arsenopyrite with pyrite and chalcopyrite occur in auriferous quartz in the NW-^ See. 16, T. 13 S., R. 27 E., M. D. M. Imperial County: It is found in the mines of the Cargo Muchacho district. Inyo Count If: It was found iu the Wilshire gold mine, 25 miles southwest of Laws, Turner (22). Kern County: Good crystallized specimens of arsenopyrite occurred at the Long Tom mine ; with quartz in the Amalie district ; with galena and pyrite in quartz at the Bright Star mine, Piute dis- trict. Arsenopyrite occurs in the Big Blue-Sumner lode, half a mile north of Kernville, Tucker (34). It is common in the gold ores near Randsburg, Hulin (25). Madera County: It occurs in small amounts on Iron Mountain. Mariposa County: It occurs in the mines near Coulterville ; dana- ite with erythrite was found in the Josephine mine, Bear Valley, Turner (96). Arsenopyrite with calcite and quartz in the Smith mine, Bear Valley; with magnetite in the Cave mining district; with chalco- pyrite and pyrite at Ilornitos. It was found at the Kite's Cove mine, R. W. Raymond (74). Mono County: It is common in the Lundy district, carrying gold. Monterey County: It occurs in auriferous quartz at the Oregon mine, Sec. 2, T. 24 S., R. 5 W., M. D. ]\I. Napa County: It occurs in the Palisades mine, 2 miles north of Calistoga. Nevada County: A 2-foot ledge containing arsenopyrite was found at the Porcupine mine, Cisco. Fine crystals in schist were found on Poorman Creek; crystals on quartz at the Delhi mine, Columbia Hill. SULPHIDES, SELENroER, TELLURIDES, ARSENIDES OF THE METALS 75 Danaite was found in the Meadow Lake district, W. P. Blake (67). It was abundant in the veins of the Federal Loan mine, near Nevada City; crystals occur in the Osborne Hill vein. The veins of Forest Springs, 4 miles south of Grass Valley, also carry much arsenopyrite, Lindgren (96). Placer County: Arsenopyrite is one of the minerals in the mines of the Ophir district, Lindgren (94). It occurs in the Canada Hill and Dutch Flat districts. Arsenopyrite containing nickel and cobalt has been found 3 miles from Cisco. Plumas County: It occurred in the Pilot Hill gold mine, 6 miles Tjorthwest of Gibson ville, and has been found in Genesee Valley. Riverside County: Small crystals occur in the limestone quarry at Crestmore, Eakle (17). Arsenopyrite occurs at the Cajalco tin mine, near Corona, West (28), San Bernardino County: It occurs on San Antonio Peak. Small crystals of arsenopyrite occur abundantly in the silver ores of the Hand district, Hulin (25). San Diego County: It occurs Avith the gold f)ros oF the Julian dis- trict. Donnelly (34). Santa Cruz County: Arsenopyrite occurs in the quarry of the I\icific Limestone Products Company at Santa Cruz. Sierra County: Arsenopyrite is the chief gold-bearing mineral at Alleghany, containing a high percentage of gold. In the Golden King mine on Kanaka Creek it is said to have occurred with a gold telluride. it is common in the mines of the Forest Hill district, the Oriental, Osceola Lode, Uncle Sam, Rainbow, Bonanza, Mammoth Springs, Lost Treasure, Kate Hardy, and El Dorado mines ; in the Eagle and Docile mines, Kanaka Creek; at the Mexican Elcy and High Commission mines, Downieville district; at Gold Canyon, 3 miles from Moores Flat; at the Kenton, Ironsides, and Four Hills mines with chalcopyrite and Galena. ' ^'^ ' Tehama County: It occurs with quartz and pyrite at Sarkenita. Trinity County: Gold-bearing arsenopyrite occurs in the Craig mine, 2 miles east of Dedrick; on Lowden's ranch and Burnt ranch with gold ; near Weaverville. Tulare County: It is found in the Mineral King district. Tuolumne County: Crystals of arsenopyrite having crystallized gold deposited on them occur at the Alameda mine. Rawhide mining district. NiCo Pb Ag 20.98 0.72 4.08 r= 99.21% 18.31 0.86:= 99.92% 76 MINERALS OF CALIFORNIA MELONITE Nickel telluride. NiTez. Hexagonal. Commonly granular and foliated. Cleavage perfect basal. Metallic luster. Color reddish-white. Streak dark-gray. H. = 1 — li. G.r=7.3. The tellurium is readily driven off in white oxide fumes when heated on charcoal. The roasted residue yields the brown bead of nickel with borax. Melonite also gives the characteristic violet solution of a telluride when boiled in strong sulphuric acid. Calaveras County: Melonite was discovered among the other tellu- rides of the Melones mine on Carson Hill in 1867 and was named by Genth (67), (68), A similar mineral was later found in the Stanislaus mine and analyzed by Hillebrand (99). Te Genth 73.43 Hillebrand 80.75 SYLVANITE— Grap-hic Tellurium Telluride of gold and silver, (Au,Ag)Te2. Monoclinic. Bladed crystals and massive. Cleavage perfect clino- pinacoidal. Metallic luster. Color silver-white to yellow. Streak silver- gray. H. — IJ — 2. G. r=7.9 — 8.3. The tellurium is easily driven off as an oxide by heat, leaving a button of gold and silver. Gives a deep-violet solution when boiled with concentrated sulphuric acid. The silver can be extracted from the button by nitric acid and precipitated as silver chloride by hydrochloric acid. Though sylvanite may be present in many of the gold districts where tellurium is found, it has been identified in but few localities in California. Calaveras County: Sylvanite was one of the tellurides ocurring in the Carson Hill mines and was especially prominent in the Melones and Stanislaus mines. An analysis of sylvanite from the Stanislaus mine was made by Stetefeldt (65). Te Au Ap 59.6 25.5 13.9 Trinity County: Sylvanite has been found with gold in the Yellow Jacket mine ; with nagyagite at the Dorleska mine, Coffee Creek dis- trict, Stines (07) ; and in the Golden Jubilee mine, 5 miles northwest of Carrville, Averill (31). Tuolumne County : It occurs in the Sugarman and Nigger mine, 2 miles north of Sonora, Yuba County: It occurs with the gold in the Red Raven mine, Dobbins district. SULPHIDES, SELENIDES, TELLURmES, ARSENIDES OF THE METALS 77 CALAVERITE Gold telluride. AuTes. Monoclinic. Crystals with striated faces ; also massive granular. Brittle. Metallic luster. Color uale bronze-yellow to yellowish silver- gray. Streak yellowish-gray. H. z=2i. G. = 9.04. Similar to sylvanite in its reactions. Calaveras County: Calaverite was discovered at the old Stanislaus mine on Carson Hill. Analyzed and named by Genth (68). Au Ag Te 40.70 3.52 55.89 = 100.11% It was also found in the Melones mine on Carson Hill, El Dorado County: It was found with petzite in the Darling mine near Rock Creek, about 3 miles northeast of American Flat, Siskiyou County: It was reported from the northern part of the county near the State line, associated with free gold and petzite. NAGYAGITE Sulpho-telluride of lead and gold. Orthorhombic. Generally foliated and granular massive. Perfect' cleavage into thin flexible laminae. Metallic luster. Color and streak dark lead -gray. H. = 1 — 1^. G. = 6.85 — 7.2. Gives the yellow and white coatings of lead and tellurium oxides, when roasted on charcoal, with a slight odor of surphur. The presence of tellurium can best be tested by boiling in sulphuric acid and obtaining the violet color. Trinity County: Nagyagite was observed with hessite at the Dor- leska mine, Coffee Creek district. 78 MINERALS OF CAIJFORNIA OXYSULPHIDES KERMESITE Antiiiiuny (jxysiiliDhiile, Slj-.ijO. Monoclinic. Usually in hair-like tufts. Cleavaj^e (100) perfect. Metallic to adamantine luster. Color cherry-red. Streak brownish-red. H. — 1 — U. G. = 4.5 — 4.6. Gives a reaction similar to stibnite. Kern County: Fine red needles of kermesite were found on stib- nite at the Mojave antimony mine, about 15 miles north of Mojave. SULPIIOSALTS 79 SULPHOSALTS Ag Cu Fe I'b Sb As S Insol. 36.20 0.02 0.56 0.95 42.46 tr. 19.27 0.80 Miargyrite Pyrargyrite Geocronite Berthierite Proustite I'olybasite .lamesonite Stylotypite Enargite iJufrenoy.site Tetrahedrite BournDiiiti; Stephanite MIARGYRITE Sulphantimonite of silver, AgSbSa. Monoclinic. In complex monoclinic crystals ; also massive. Luster metallic-adamantine. Color iron-bhick to steel-gray, in thin splinters deep blood red. Streak cherry-red. H. =: 2 — 21. G. = 5.1 — 5.3. San Bernardino County: Miargyrite is probabh' the most abun- dant silver mineral in the deposits of the Randsburg district. VVell- I'ormed crystals are found in open drusy cavities in the veins, Hulin (25). Shannon (29) lias described ci-ystals from the California Rand Silver mine showing the forms (001), (100), (Oil), (101), (101), (105), (111), (122K (211), (311), (522), (922), (411), (611), (711), (124) (413), and (213). Analysis by Shannon gave: sol. 100.26% BERTHIERITE Sulphantimonite of iron, FeSbsSi. Long prismatic. Usually fibrous massive. Metallic luster. Color dark steel-gray. Streak grayish-black. H. = 2 — 3. G. := 4 — 4.3. A slight coatins of white oxide of antimony and a slight odor of sulphur can be obtained by roasting on charcoal. The roasted mineral becomes magnetic. Tuolumne County: Heavy ledges of dark ore occur in an area of schists on the southeastern slope of Mount Gibbs, which appear to be an impure l)erthierite mixed with oalciui. i»\rite, and quartz, Turner (96). JAMESONITE Sulphantjnionite of lead, PbaSbiiSr.. Monoclinic. In acicular and capillary crystals. Generally fibrous massive. Cleavagct perfect basal. Brittle. Metallic luster. Color lead- gray. Streak grayish-black. H. ::=: 2 — 3. G.c= 5.5 — 6.0. The yellow and white coating on charcoal, of lead and antimony oxides, and odor of sulphur are obtained by heating. Dissolved in nitric acid, the lead goes into solution, while the antimony is precipitated as an oxide. Calaveras County: Jamesonite was found at Mokelumne Hill, Hanks (84). 80 MINERALS OK CALIKOKNIA Inyo County: Compact massive specimens of jamesonite associated with argentiferous galena have come from the Cerro Gordo mine. Napa County: Delicate capillary or hair-like crystals of jamesonite were found with cinnabar at the Manhattan mine, near Knoxville. Sierra County: Crystal clusters and needles of jamesonite have been found in small vugs in quartz in the Rainbow and Plumbago mines, Alleghany district, Ferguson and Gannett (32). DUFRENOYSITE Sulpharsenite of lead, Pb2As2So. Monoclinic. Generally massive. Cleavage (010) perfect. Brittle. Metallic luster. Color dark lead-gray. Streak reddish-brown. H. :;= 3. G. = 5.55 — 5.57. Like jamesonite in its reactions, except that the more volatile fume.s of arsenic trioxide, instead of the antimony, are given off. Inyo County: Dufrenoysite was reported to have been found in the Cerro Gordo district, Hanks (84). BOURNONITE Sulphantlmonite of lead and copper, (Pb,Cu2)3Sb2Sa. Orthorhombic. Short prismatic and tabular crystals ; massive. Metallic luster. Color and streak lead-gray. H. = 2i — 3. G. = 5.7 — 5.9. Fuses easily and on charcoal gives a white coating, at first of anti- mony oxide, followed by a yellow coating of lead oxide nearer the assay. Dissolved in nitric acid and ammonia added, the solution turns blue ; soluble in hydrochloric acid with odor of hydrogen sulphide. Inyo County: Massive bournonite occurs at Cerro Gordo, Reid (07). PYRARGYRITE— Dark Ruby Silver Ore Sulphantlmonite of silver, AgsSbSa. Hexagonal-rhombohedral. Prismatic crystals ; also massive. Cleavage (lOfl) distinct. Brittle. Metallic luster. Color grayish-black, or dark-red. Streak purplish-red. H. :=2J. G. =: 5.85. Gives a white antimony oxide coating on charcoal and reduces to a globule of metallic silver. The sulphur can best be detected by fusion in a closed tube. Pyrargyrite is found in silver veins with argentite, polybasite, stephanite, tetrahedrite and other silver minerals. It is often embedded in quartz and good crystals of pyrargyrite may occur in cavities in quartz. Alpine County: Pyrargyrite occurred in the old I X L and Exchequer mines of the Silver Mountain district. It was observed in the Monitor mining district, Eakle (19). Kern County: It was found with argentite at the Amalie mine. Mariposa Comity : It was found with argentite and proustite in the Bryant Silver mine. SULPHOSALTS 81 Mono County: Fyrargyrite and stepliauite were abundant in the Oro, Addenda, Fortuna and other mines south of Bodie. Crystals of pyrargyrite were found in a vug in the Bodie mine. It also occurred in the Blind Spring mines, in the Tower mine, and in other mines near Benton, Whiting (88). Napa County: It is a constituent of the gold and silver ore in the Palisades mine, 2 miles north of Calistoga. Nevada County: It was found with pyrite, chalcopyrite, and galena in the Allison Ranch mine ; also in the Central mine of the Lava Cap Company, south of Banner Hill, and is probably present in other mines of the Grass Valley and Nevada City district as indicated by the silver-rich concentrates, Lindgren (96). San Bernardino County: Pyrargyrite occurs with miargyrite in the silver ores of the Rand district, Hulin (25). Shasta County: Small amounts of pyrargyrite were occasionally found in the mines near Igo. PROUSTITE— Ruby Silver Ore Sulpharsenite of silver, AgaAsSs. Hexagonal-rhombohedral. Prismatic crystals and massive. Cleav- age (1011) distinct. Brittle. Adamantine luster. Color and streak scarlet-red. H. = 2 — 2i. G. n: 5.57 — 5.64. The reactions of proustite are similar to those of pyrargyrite. The two minerals often are intermixed or grade into each other. The term 'ruby silver' is given indiscriminately to proustite and pyrargyrite. Both minerals usually contain arsenic and antimony. The metallic gray pyrargyrite is more common than the transparent red proustite, but the two are often associated. Kern County: Specimens of proustite with pyrargyrite have come from the old Amalie district. Mariposa County: It occurred with pyrargyrite and argentite in the Bryant Silver mine. Mono County: It was found in the Oro and Bodie mines, Bodie district. Hanks (84). Napa County: Proustite li;is hccii found in the Palisades mine, about 2 miles north of Calistoga. San Bernardino County: Proustite is a minor constituent of the silver ores of the Rand district, Hulin (25). Shasta County: It occurred with galena, pyrite and quartz in tlic Chicago mine, near Igo. 6—51440 82 MINERALS OF CALIFORNIA STYLOTYPITE Sulphanliiiiuiiite nl' copper and silver, u (CuL',Ag;;,Fe) S.Sb:;S:!. Monoclinic. Granular or niassivt\ Brittle. Metallic luster. Color dark-gray to iron -black. Streak black. H. = 3 — 3^. G.r= 4.7 — 5.2. Saii Bernardino County: Stylotypite occurs with miargyrite as au important constituent of the silver ores of the Rand district, Hulin (25). TETRAHEDRITE— Gray Copper Ore Sulphantlmonite of copper, CuaSbSs. Isometric; bextetrahedral. Also massive; granular. Metallic luster. Color darii steel-gray. Streak black, sometimes cherry-red. H. :=: 3 — 4. G. = 4.4 — 5.1. Gives a slight white coating on charcoal and a faint odor of sulphur. The roasted mineral gives the blue bead of copper with borax. Soluble in nitric acid and the antimony precipitates as trioxide. Ammonia added to nitric acid solution will give the characteristic blue solution of copper, and will precipitate any iron present. Tetrahedrite is common in many of the gold and copper mines ol the .State. It is, however, seldom prominent but occurs in small amounts mixed with galena, sphalerite, chalcopyrite and other common sulphides. Freibrrgitc is the argentiferous variety and is pei'haps the most common form of the mineral in California. Alpine County: Considerable tetrahedrite has been found in the Silver Mountain district. It was observed in the Monitor mining dis- trict, Eakle (19). Calaveras County: Small amounts of tetrahedrite were found in the mines on Carson Hill. It was present in the ore at the Jones mine, Carson Creek. Del Norte County: It was found at Crookeshine. Imperial County: It occurred in tlie Blue Jacket and other mines of the Picacho district. Inyo County: Tetrahedrite containing a large percentage of silver was an imi)ortant mineral in the Cerro Gordo district. It also occurred in some of the mines of the White Mountains and the Button Range. It was found in the old San Carlos mine. Freibergite is the principal sulphide in the silver ores of the Panamint district. Murphy (80a). Tennantitc, the arseuic-lx'ai-ing eciuivaleiit of tetrahedrite, has been rri)ort('d from the Darwin disli-ict by KcUey (-37). Los Angeles County: It was found in the Zapate mine in San Gabriel Canyon. Mariposa Comity: Freibergite was found in large masses in wdiite quartz, at the Live Oak mine, near Mariposa, Hanks (84). It also occurred in the Pine Tree mine, near Coulterville and in the Louisa and Bunker Hill mines. SULPHOSALTS 83 Mendocino County: It was found with chalcopyrite, gold, and sil- ver ill the Kedwood Copper Queen mine. Mono County: It occurred massive associated with partzite in the Diana, Comet, Comanche, and other mines of the Blind Spring Hill district ; also found in the Bodie district. Nevadu County: A heavy mass of tetrahedrite associated with zinc- lilende and chalcopyrite was found in the Osborn Hill vein. Tetra- hedrite was found in small quantities at the North Banner and at other mines of the Banner Hill and Willow Valley districts, Lindgren (96). It is present in the ore in the Badger Hill mining district. Argentiferous tetrahedrite is abundant in the Central mine of the Lava Cap Gold ^Mining Coi*poration at Nevada City, Johnston (38). Placer County: Dark steel-gray tetrahedrite associated with other sulphide minerals and with electrum was common in the Ophir district, having been noticed in the Boulder, Gold Blossom, Pine Tree and Golden Stag mines, Lindgren (94). It was also observed at Michigan Bluff. Plumas County: It was found at the Irby Holt mine in Indian Valley. Argentiferous tetrahedrite was found at the Trask and Coffer mine. It was observed in small amounts in the ore at Engels. Riverside County: A small amount of tetrahedrite was found with chalcopyrite, pyrite, and galena, at Crestmore, Eakle (17). San Bernardino County: It has been found massive in the New York and other mines in the New York Mountains. . Shasta County: Tetrahedrite is of rather common occurrence in the copper mines of the county although in small amounts. It has been found in a barite gangue in the Bully Hill mine. Sierra County: Tetrahedrite occurs in tetraliedral crystals with crystallized gold in the IG to 1 mine at Alleghan.v. Tuolumne County: It occurred as one of the minerals on Whiskey Hill, Silliman (67a). Massive tetrahedrite was found in the Golden Rule mine, near Jamestown. STEPHANITE— Brittle Silver Ore Sulphantimonite of silver, AgsSbSi. Orthorhombic. Crystals common, showing at times striations on the prism faces ; also massive. Brittle. Metallic luster. Color and streak iron black. H. = 2 — 25. G. r= 6.2 — 6.3. The reactions are similar to those for pyrargyrite, but the streak or powder is black, whereas that of pyrargyrite is reddish. Stephanite is an important and usually prominent silver mineral in silver districts, but it is not common in California. It is often asso- ciated with argentite and polybasite as an original mineral of the veins. 84 MINERALS OF CALIFORNIA Alpine County: Stephanite was reported to have been found in the Morning Star mine, J. D, Dana (49). Mono County: Stephanite occurred in the Blind Spring Hill dis- trict. Large masses of it were found with pyrargyrite in the Oro, Addenda, and Fortuna mines, Bodie district. Whiting (88). It is found in the Patterson district, Sweetwater Range. Nevada County: Stephanite was one of the minerals found in the Grass Valley mines, Lindgren (96). Shasta County: It occurs with native silver, galena, and sphalerite in a ealcite-quartz gangue at the Igo Consolidated Mines. GEOCRONITE Sulphantimonite of lead, Pbr.SbsSs. Orthorhombic. Generally massive, granular, or earthy. Metallic luster. Color and streak lead-gray. H. = 2 — 3. G. = 6.4. Gives the same reactions as jamesonite. Inyo County: According to Hanks (84), small masses of geo- eronite were found with galena in the Inyo Mountains. 3Iono County: It was observed with galena and sphalerite in the Garibaldi mine, Prescott district. POLYBASITE Sulphantimonite of silver, AgoSbSa. Monoclinic. Tabular crystals and massive. Metallic luster. Color iron black. Streak black. H. z= 2 — 3. G. rr: 6.0 — 6.2. In its blowpipe reactions polybasite is like stephanite and pyrargy- rite. Polybasite closely resembles stephanite; the two are often mixed and are seldom differentiated. When in good crystals they can be dis- tinguished, but when massive their separate identification is difficult. Alpine County: Specimens of polybasite have come from the Pennsylvania mine in the Silver Mountain district, and Hanks (84) observed it in microscopical crystals from the Monitor and Mogul districts. ENARGITE Sulphar.senate of copper, Cn3AsS4. Orthorhombic. Crystals and massive. Cleavage perfect prismatic. Brittle. Metallic luster. Color and streak grayish-black. H. r= 3. G. = 4.4. Fuses and gives a faint coating on charcoal. The roasted mineral can be reduced to metallic copper by fusion with sodium carbonate. The borax bead is blue. Soluble in nitric acid with the precipitation of a small amount of antimony trioxide. Alpine County: Enargite was found in large masses associated with massive pyrite in the Mogul district and formed the chief copper mineral of the Morning Star and a few other mines. An analysis of enargite from the Morning Star mine by Root (68) gave: S Cu As Sb 31.68 47.21 14.06 6.19 = 99.14% G. = 4.34. SULPHOSALTS 85 Crystals have the forms: (110), (001), (100), (010), Silliman (73b), and (130), (250), (101), Eakle (08). El Dorado County: Enargite was found in the Ford mines, near Georgetown. hiyo County: The variety luzonite is found in the silver-lead ores of the Darwdn district, Kelley (37). Plumas County: Small amounts of enargite occur with bornite and ehalcopyrite at Engels. 86 MINERALS OP CALIFORNIA HALOIDS Anhydrous Chlorides, Bromides and Fluorides Calomel Halite Sal Ammoniac Cerargyrite Embolite Fluorite Chloromagnesite Oxychlorides Atacamite Kempite Eglestonite ANHYDROUS CHLORIDES, BROMIDES AND FLUORIDES CALOMEL Mercurous chloride, HgCl. Tetragonal. Small crystals. Sectile. Adamantine luster. Color white, gray, brown. Streak pale yellowish-white. H. := 1 — 2. G. = 6.48. Volatilizes easily on charcoal and coats the coal white, easily reduced to mercury globules by fusion with soda. Calomel is Napa County : White coatings of calomel on metacinnabar occurred at the Oat Hill mine. San Mateo County: Small amounts of calomel with cinnabar, native mercurj^ and eglestonite occur about 5 miles west of Palo Alto, Rogers (11a). HALITE — Common or Rock Salt Sodium chloride, NaCl. Isometric. Cubes, massive, granular, and crusts. Cleavage perfect cubic. Rather brittle. Vitreous luster. Colorless, white, yellowish, reddish, bluish. H. =:2J. G. = 2.1 — 2.6. Fuses with intumescence and gives a strong yellow flame. Easily soluble in water and has a saline taste. Most of the salt produced in the State is obtained by the evapora- tion of the water of San Francisco Bay ; also at San Diego and Mon- terey Bays; yet extensive deposits of the mineral exist in the southern counties and some of them are mined. Salt is common in the desert regions, where former lakes existed, and the deposits reach considerable thickness in some localities, often alternating with beds of sulphates, borates, carbonates, and mud shales. Salt wells, salt springs, salt marshes, and salt rivers occur in these arid plains, and white incrusta- tions of salt are often found along their borders. Alameda County: The salt works near Alvarado evaporate the water of San Francisco Bay on a large scale. Imperial County: Efflorescences of salt occur on the dry plains of the Great Colorado Desert. Inyo County: Halite is common in the dry valleys as white efflo- rescences. It is common in the borax district of Death Valley, Gale HALOIDS 87 (14). White crusts of salt in Saline Valley have been analyzed by Bailey, Oale (14a), and shown to be lai-gely halite. Nh K CI SO4 HjO Iiisol. 39.09 O.U 59. 7(; U.9ri 0.12 0.17 := 100.20% Kern County: Numerous salt lakes and wells occur in the Mojave Desert reiiion on the east side of the county. Salt and borax are asso- ciated at Buckthorn, Indian, and Mesquite springs. LaJxC County: Halite is found in minute crystals with borax and gay-lussite at Borax Lake, Melliase (35). Modoc County: Salt is produced in commercial quantities near Odarville, in Surprise Valley. Riverside County: The Salton Sea is an extensive depression in the south -central part of the county which was noted for its immense deposits of white salt, of which thousands of tons have been mined. An analysis of this salt was made by E. T. Allen, Clarke (03). NaCl KCl NaaSO* Gj'psum H;;0 Insol. 94.54 0.31 3.53 0.79 0.14 0.50 = 99.81% San Bernardino County: Numerous dry lakes exist in this county, ;dl of which contain salt. Some of the salt neai- Daggett has been mined for chloridizing the silver ores of the district. A large lake deposit of salt occur-s in the desert about 25 miles southeast of Danby nnd the Surprise salt mines liave ])roduced large quantities. Bailey (02) reports a vein of rock salt 12 to 16 feet thick on the Avawatz Moun- tains. Crusts of halite with sodium, magnesium, and calcium sulphate occur at the Mojave sink. Salt and borax with nitrates occur along the Amargosa Kiver, near the Inyo County line. Cubic and octahedral crystals of halite, with hanksite, trona, and glaserite, occur in the salt crust of Searles Xiake. Clear cubical crystals and cleavable masses of halite occur with gypsum on the muds of Bristol Lake, near Amboy. San Luis Ohispo County: White crusts of salt can be found in many places along the shores of the Salinas River. Soda Lake in Carrizo Plain is a dry lake in the eastern part of the county, the surface of which contains crusts of salt and sodium sulphate. Shasta County: Sandstones which are slightly impregnated with salt occur on Salt Creek, about 12 miles east of Redding. SAL AMMONIAC Ammonium chloride, NHiCI. Isometric. Crystals, crusts, and efflorescences. Rather brittle. Vitreous. White, yellowish, grayish. H.=::1J — 2. G. = 1.528. Very easily volatile without fusion wlien heated and is wholly con- verted into dense white fumes. Heated in a closed tube with soda or lime, ammonia is given off which can be detected by odor. Soluble in water. Inyo C aunty: According to Bailey (02), sal ammoniac is found as efflorescences at some of the fissure springs in Deatli Valley. 88 MINERALS OF CALIFORNIA Los Angeles County: A white crystalline incrustation of sal ammo- niac Avas found in the Monterey shale of Burning Mountain, Rogers (12), Santa Barhara County: Crusts of sal ammoniac 5 mm. thick, asso- ciated with sulphur, came from burning oil-shales on the Hope ranch, Rogers (12). CERARGYRITE— Horn Silver Silver chloride, AgCl. Isometric. Usually in crusts, resembling wax or horn ; sometimes columnar. Highly sectile. Luster resinous to adamantine. Color gray, but generally tarnished brown. H. =r 1 — 1|. G. = 5.55. Easily reduced on charcoal to metallic silver. Mixed with copper oxide it imparts to tlie flame the azure-blue color of the copper chloride flame. Insoluble in acids, but soluble in ammonia. Cerargyrite has been among the important silver ores of the State. It is characteristic of silver deposits located in arid regions and may be abundant in such regions. It is usually accompanied by embolite and occasionally by iodyrite; barite is a common gangue mineral. Calaveras County: W. P. Blake (67) reported the occurrence of thin crusts of cerargyrite on quartz in the Morgan mine at Carson Hill. Inyo County: Horn silver with argentiferous galena, argentite, and copper minerals has been found abundantly in the Argus and Coso Ranges and to some extent in the Darwin and Cerro Gordo districts. Hanks (84) mentions it from the Slate Range, and as microscopical crystals from the Modoc mine near Darwin. Cerargyrite with cerusite occurs in the Noonday mine, Tecopa, and associated with chrysocolla at the Bonanza King mine, Sherman district. Kern County: Cerargyrite has been found in the Amalie mine with pyrargyrite and native silver. It occurs at the Golden Queen mine, 7 miles south of Mojave, Tucker (34). Mono County: Cerargyrite has been found in the Blind Spring Hill district near Benton and in some of the mines of the Bodie dis- trict, but never in large masses. It occurs in the Sweetwater Range. Placer County: Cerargyrite is abundant in the gold-silver veins of the Ophir district, Lindgren (94). San Bernardino County: Horn silver has been a very important silver mineral in the Calico and Barstow mines, Lindgren (87), Storms (90). The minerals associated with the horn silver of this region are embolite, cerusite, barite, pyrolusite, chrysocolla, malachite, and jasper. Cerargyrite occurs in limestone with embolite, wulfenite, sphalerite, galena, cerusite, and pyrite in the Silver Reef district, about 40 miles east of Victorville ; and with argentite at the Bonanza King mine on HALOIDS 89 Providence Mountain and in the Imperial mine, Lnva Beds district, about 9 miles from Lavic. Cerargyrite is the principal secondary ore mineral in the silver mines of the Rand district, Ilulin (25). EMBOLITE Silver chloro-bromide, Ag(Br,Cl). Isometric. Generally massive. Sectile. Resinous luster. Color grayisli-green, yellow. H. := 1 — IJ. G. :=5.31 — 5.43. Heated in a closed tube with potassium bisulphate and pyrolusite, red vapors of bromine are set free. Heated in closed tube with galena, yellow lead bromide forms, which turns white on cooling. Silver nitrate will precipitate silver bromide from a nitric acid solution. Embolite has only been found in association with cerargyrite but in much smaller amounts. Inyo County: Embolite is found with cerargyrite in the Indiana mine, near Swansea, Hanks (84). Mono County: Embolite occurs with cerargyrite in the Minnie mine, Sweetwater Range, Hanks (84). San Bernardino County: Embolite is an associate of the cerargy- rite in the Calico, Grapevine, and Silver Reef districts. FLUORITE Calcium fluoride, CaFs. Isometric. Usually in cubes ; also massive, granular, or compact. Cleavage perfect octahedral. Brittle. Vitreous luster. Green, purple, blue, white, yellow, colorless. Streak white. H.= 4. G. = 3.01 — 3.25. Fuses with some decrepitation. Gives reddish flame of calcium. Sol- uble in acids and calcium is precipitated by ammonium oxalate. Mixed with potassium sulphate and fused in a closed tube, the glass becomes etched. Fluorite is a common mineral, especially as gangue in lead dis- tricts with galena. It sometimes forms thick veins. Contra Costa County: Small cubes of white fluorite were found on Mount Diablo with some copper minerals, Hanks (84). Inyo County: Fluorite is found as a gangue mineral with argentif- erous galena in the Cerro Gordo, Darwin and other districts. Kern County: Fluorite veins occur in the west end of the Rand Mountains near Randsburg. Los Angeles County: Fine specimens of fluorite consisting of purple and green masses and cubes have come from the Felix mine near Azusa. White fluorite occurred on Santa Catalina Island with galena and chalcopyrite. Mono County: Green and violet crystals and masses of fluorite occur in Ferris Canyon on the eastern slope of the Sweetwater Moun- tains. Fluorite occurs with andalusite in the mine of Champion Silli- 90 MINERALS OF CALIFORNIA manite, lucorporated, on the western slope of the White Mountains, 7 miles east of Mocalno, Woodhouse and Jeffery (32). Riverside County: Transparent crystals of fluorite were marketed for optical purposes in 1917-1918, from the Floyd Brown mine, near Blythe. A small tonnage was also shipped for industrial use. San Bernardino County: Green and purple fluorite with some ice- land spar comes from the Kings Fluorspar mine, Cave Canyon dis- trict, Tucker and Sampson (31). Light-green fluorite occurs near Barstow. Fluorite is also found near Ludh)W and near Needles. San Diego County: Green fluorite occurs at Oak Grove, Palomar Mountains. A small amount of fluorite is found at the Mountain Lily Gem mine, Aguanga Mountain. Tulare County: A deposit of massive fluorite occurs in Sec. 34, T. 20 S., R. 31 E., M. D. M., 18 miles east of Springville, Franke (30a). CHLOROMAGNESITE Magne.siuni chloride, MgCb. Efflorescent'^. Color white. Soft. Soluble in water, i'^asily fusible Magnesium chloride exists in soiutiuii in the waters of some springs and lakes, but its solubility prevents it from forming as a mineral except in the driest places. San Bernardino County: White efflorescences of chloromagnesite occur at Saratoga Springs, near the south end of Death Valley, Bailey (02). HALoros 01 OXYCHLORIDES ATACAMITE Hydrous copper oxychloride, Cu2Cl(OH)3. Orthorhombic. Slender needles and fibrous reticulated masses. Cleavage (010) highly perfect. Brittle. Luster adamantine to vitreous. Color bright to black-green. Streak apple-green. H. := 3 — 3|. G. r= 3.7. Fuses and imparts an azure-blue color to the flame. Readily reduced on charcoal to metallic copper. Gives much acid water in a closed tube, and forms a gray sublimate. Easily soluble in acids. Atacamite is very rare and its occurrence in California has not been definitely established. Inyo County: J. D. Dana (68) recorded atacamite from an unknown locality in this county. As the Cerro Gordo mine was the best known for rare minerals, the atacamite, if correctly identified, perhaps came from this mine. KEMPITE Hydrous manganese oxychloride, MnCl:;.3IMn02.3H20. Orthorhombic. Minute prismatic crystals. Color emerald-green. H. = 3^. G. = 2.94. Soluble in dilute acids. Gives water in the closed tube. Santa Clara County: Kempite was found with pyrochroite, haus- mannite, and rhodochrosite in a boulder of manganese ore in Alum Rock Park, 5 miles east of San Jose. It was discovered and named, and the crystal forms (110), (Oil), (121), (100), and (010) identified by Rogers (24). Analj^sis by Crook. H2O o* 100% Mn CI H2O 0* 50.59 16.41 11.60 21.40 * By difference. EGLESTONITE Mercury oxychloride, HgiCkO. Isometric. Minute crystals. Resinous to adamantine luster. Color yellowish-brown, changing to black. H r= 2 — 3. G. = 8.327. Volatilizes completely and does not give water in the closed tube. San Mateo County: Minute yellow crystals of eglestonite asso- ciated with cinnabar, mercury, calomel, dolomite, magnesite, opal, and quartz occur about 5 miles west of Palo Alto in seams and cavities in the siliceous material so common in the serpentine of the cinnabar districts. The crystals were described and analyzed by Rogers (11a). Forms: cube (100), octahedron (111), dodecahedron (110), and trape- zohedron (211). Hg ci 88.00 7.43 92 MINERALS OF CALIFORNIA OXIDES Anhydrous Quartz Chalcedony Tridymite Cristobalite Opal Aisenolite Claudetite Valentinite Bismite Ilsemannite Cervantite Stibiconite Partzite Cuprite Periclase Massicot Litharg-e Tenorite Montroydite Hematite Group Corundum Hematite Ilmenite Himiel Grovit Spinel Magnetite Chromite Chrysoberyl Hausmannite Minium Crednerite Braunite Cassiterite Rutile Anatase Brnokite Hydrous Pyrolusite Diaspore Group Diaspore Goethite Manganite Limonite Bauxite Brucite Pyrochroite Psilomelane ANHYDROUS OXIDES QUARTZ Silicon dioxide. SiOi}. Hexagonal-rhombohedral ; trigonal-trapezohedral. Hexagonal prisms with pyramids very common and sometimes large. Compact and granular massive. Prominent conchoidal fracture. Brittle. Vitreous luster. Colorless, white, yellow, red, brown, green, blue, black. Streak white. H. = 7. G. r=2.65. Infusible and insoluble in nitric or hydrochloric acids. Soluble in hydro- fluoric acid. Fused well with a flux of sodium carbonate, the fusion dissolved in water and hydrochloric acid, when evaporated to dryness, will leave the silica as an insoluble residue. The hydrochloric acid solution, after all silica is removed, will give no precipitates of aluminum, calcium or magnesium when treated successively with ammonium, ammonium oxalate and sodium phosphate, proving the mineral to be silica and not a silicate. Common quartz is an essential constituent of granites, granodio- rites, quartz-porphyries, rhyolites, gneisses, schists, quartzites and sandstones, and is an accessory mineral in many other kinds of rock, either volcanic, metamorpliic, or sedimentary. Veins, ledges, seams, and pockety masses of white quartz are common in volcanic and meta- morpliic rocks. Rock crystal is a clear colorless variety which is found as hex- agonal crystals. Amethyst is a violet-colored variety sometimes used as a gem. It occurs in groups of crystals; rarely massive. Very little good amethyst has been found in the State. OXIDES 93 Rose quartz is a massive pink variety. Smoky quartz or Cairngorm stone is a hair-brown transparent variety occurring as crystals. The color is readily discharged or converted into citrine-yellow by heat. This is a common variety of quartz and some excellent large crystals have been found in the State. Inclusions of other minerals in quartz are common and have sev- eral varietal names. Thetis hairstone is rock crystal containing long hair-like fibers of asbestos or actinolite. Phantom crystals show the outlines of one crystal within another ; they are caused by inclusions of green ehloritic matter or brownish earthy material arranged about the boundaries of the crystal during growth. Alameda County: Yellow crystals of quartz occur with glassy albite at the Newman mine on Cedar Mountain, 12 miles southeast of Livermore. Alpine County: Rose quartz has been found in Hope Valley and in the Mogul and Monitor districts. Amador County: Fine large specimens of rock crystal have come from Volcano and Oleta. This section has also produced good speci- mens of amethyst, smoky, and rose quartz. Thetis hairstone has been found at Oleta. Butte County: Smoky quartz occurs on the North Fork of the Feather River. Fine rose quartz occurs near Forbestown. Cal-averas County: Good rock crystal in fine large aggregates has been found in many of the gold mines. Mokelumne Hill, Green Moun- tain gravel mine near Murphy, Angels Camp, and Westpoint have produced large crystals. Clear quartz crystals occur at the Jennie Lind mine. El Dorado County: The best rock crystal, phantom crystals, and smoky quartz in the State have come from near Placerville. A fairly pure white quartz is found on the McDonald ranch near Shingle Springs. Clear crystals are found in White Rock Canyon near George- town. Quartz with actinolite occurs near Fairplay. A blue variety of quartz occurring in pegmatite in this county has been named El Dora- doit e by Watkins (17). Inyo County: Good rock crystal has been found in the Cerro Gordo and Darwin districts. Kern County: Rose quartz has been reported north of Kemville. 94 MINERALS OF CALIFORNIA Lake County: Quartz inclusions in basalt near Clear Lake High- lands, Anderson (36), have been called 'Clear Lake diamonds.' Ame- thystine quartz has been mined for gems in Sees. 10, 20, and 21, T. 12 N., R. 7 W., M. D. M., Averill (29). Los Angeles County: Thetis hairstone has been found near Los Angeles. Vein quartz 30 feet thick has been reported 6 miles north- west of Acton. Psevidomorphs of quartz after fluorite have been found in sandstone and breccia near Encino and near the head of Higgins Canyon on the northern slope of the Santa Monica Mountains, Mur- doch (36). Marin County: Quartz amygdules occur on Mount Tamalpais. Mariposa County: F.ine rock crystal occurs at Mount Bullion. Rogers (35) has described the ocurrence of a large mass of quartz showing prominent parting, at White Rock on the Helm ranch, about 25 miles east of Merced. Mono County: Rock crystal, amethyst, and tabular drusy quartz have come from the Bodie district. Monterey County: White quartz sand occurs in dunes at Del Monte and Carmel Bay. Napa County: Good rock crystal occurs near Calistoga. Nevada County: Good specimens of rock crystal have come from Grass Valley and Nevada City. Large crystals occur near Washington. Placer County: Rock crystal occurs in the Ophir district. Quartz and rock crystals, some with inclusions of green chlorite, occur at Shady Run. Plumas County: Rock crystal has come from the Granite Basin. Deep-colored rose quartz has come from Meadow Valley. Riverside County: Rock crystal, smoky quartz, and pink quartz are associated with the gem tourmaline at Coahuila. Granular quartz occurs in the Crestmore limestone quarry, Eakle (17). Massive quartz- ite occurs in large quantity on the Eagle Mountains. White quartz is obtained from a pegmatite at the Southern Pacific Silica quarry near Nuevo. Sacramento County: Rock crystal of fine qualit}- is found at Folsom. ■ San Benito County: Amethyst crystals of fair color were found in vugs in the San Carlos mine of the New Idria Quicksilver Company. Sa7i Bernardino County: Quartz with rutile needles has been found in the San Bernardino Range. It is found as pseudomorphs after calcite at Hart. Clear white quartz occurs in the Fremont min- OXIDES 95 iug district. It occurs with specular hematite and epidote in the San Bernardino Mountains about 30 miles northeast of San Bernardino. San Dieyo County: Rock crystals, smoky quartz, and pink quartz are associated with the green and pink tourmaline of the county. Large groups of crystals of a deep-rose color occur in the pegmatite veins which carry the tourmaline at Pala, Mesa Grande, and Rincon. Rock crystal with long and almost black needles of tourmaline occurs at Pala. Crystals from Pala and Rincon have the forms: (3031), (4041), (50ol), (1121), (3141), (4151), and (5161), G. A. Waring (05). Smoky and ordinary quartz from Rincon have been spectro- scopically examined by Kennard (35). An opalescent rose quartz occurs at Escondido. Tourmalinated quartz has been found on the east side of Chihuahua Valley. Santa Clara County: Rogers (31a) lias described paramorphs of quartz after tridymite in rhj^olite at Lone Hill, near Los Gatos. Stanlshiuf; County: A large ledge of (piartz occurs about 12 miles above Pattersoti on El Puerto Creek. Analysis: SiOj AI2O3 Fe:i03 99.78 0.21 none Tulare County: Rock crystal occurs at Three Rivers and in Drum Valley. Rose quartz is found at Bull Run Meadows and at Yokohl. Quartz with inclusions of hornblende is found at Deer Creek. Beau- tiful rose quartz occurs at the Summer Rose Quartz claim, 8 miles southeast of California Hot Springs near the Kern County line. Rose quartz occurs on the west side of Bull Run Ridge ; near Badger ; in pegmatite on ridge west of Dry Creek, about 5 miles north of Lemon Cove. Rose quartz occurs in a pegmatite with massive black allanite on the Gasenberger ranch near Exeter. CHALCEDONY Silicon dioxide, SiOi>. Cryptocrystalline. Waxy luster. Translucent to opaque. White, gray, blue, brown, black. H. = 7. G. = 2.6. Reaction.s the same a.s for quartz. Chalcedony occurs in dense masses and layers, often banded. Many large masses of chalcedony and jasper have been deposited by springs. Chalcedony is a common secondary filling of cavities and fissures in volcanic rock, and may form large geodes in tins way. Many names are given to the varieties of cry|)tocrystalline quartz that may be classed under chalcedony, most of them based on color and structure. They include chalcedony, agate, cornelian, mrd, prase, heliotrope or bloodstone, chrysoprase, onyx, sardonyx, jasper, and flint, all of which are found in the State. Ordinary petrified wood is largely agate or chalcedony. 96 MINERALS OF CALIFORNIA Myrickite is a local name applied to chalcedony having blood-red spots and patches of cinnabar. Kinradite is a local name given to a spherulitic jasper. Alameda County: Small geodes of chalcedony are common in the Berkeley Hills. Alpine County: Red jasper is common in" the Monitor district. Amador County: Bluish chalcedony occurs at Volcano. Calaveras County: Red, green, and brown jasper is found near Murphy. Petrified wood occurs at Angels Camp. Del Norte County: Agate, chalcedony, and jasper pebbles are common beach pebbles at Crescent City. Fresno County: Banded, delicately-veined masses of white chal- cedony occur at Panoche. Jasper occurs in Stone Canyon and Jasper Canyon near Coalinga, Melhase (34). Hianholdt County: The beach pebbles at Big Lagoon are agate, chalcedony, jasper, prase, and carnelian. Red jasper is common at Shelter Cove. Imperial County: Fine agates are found as drift pebbles in the Colorado Desert near Canyon Springs. Inyo County: Porcelain jasper has been found in the Coso dis- trict. Blue agate and myrickite are found near Meerschaum Springs in the Death Valley region, Melhase (34). Kern County: Deep-blue and sky-blue masses of chalcedony occur near Cane Springs. Petrified wood and agate occur at Red Rock Canyon, Melhase (34). Los Angeles County: The beach pebbles at Redondo are largely chalcedony. Jasper and onyx form a mottled stone found on Santa Catalina Island, Randolph (35) ; locally known as 'Catalinite.' Agates and geodes occur abundantly near Vasquez Rocks in Mint Canyon, Patton (36). Marin County: The beach pebbles at Bolinas are in part agate and chalcedony. Red jasper outcrops on the Reed ranch. Kinradite occurs on the shore west of Sausalito between Point Bonita and Lime Point. Napa County: Red jasper is found on Mount St. Helena. Chal- cedony is common at the Manhattan cinnabar mine, Knoxville. Pine, banded onyx is also obtained there. Nevada County : Brown jasper occurs at Nevada City. Good moss agate is found near Indian Flat. OXIDES 97 Placer County: Fine geodal masses of chalcedony have been found at the Spanish mine, Ophir district. The beach pebbles at Lake Tahoe contain chalcedony, agate, jasper, carnelian, and prase. Plumas County: Banded green and red jasper occurs in the slates and schists west of Meadow Valley. San Benito Comity: Bluish-gray chalcedony occurred as pseudo- morphs after elongated crystals of barite and also formed shells about oily bituminous matter, in the Phipps Quicksilver mine, east of Emmett. San Bernardino County: Moss agate has come from the San Ber- nardino Mountains. Bluish chalcedony is associated with opal in the Black Mountains north of Barstow. Myrickite occurred in bunches and small masses 15 miles northeast of Lead Pipe Springs. Fine blue chalcedony occurs 2 miles northeast of Lead Pipe Springs. Blood- stone occurs in vesicular basalt with jasper near Lead Pipe Springs. San Diego County: Red and white banded chalcedony occurs southeast of Dalzura and east of the Donohue mine. The amethystine- colored chalcedony found east of San Diego has been called 'violite.' San Francisco County: Red, green, and brown jasper is common in the serpentine of San Francisco. Kinradite is found near Land's End. San Mateo County: The beach pebbles at Pescadero contain chal- cedony, agate, carnelian, and jasper. Sa7ita Barhara County: The beach pebbles of this county contain agate and chalcedony. Santa Clara County: Fine orbicular jasper is found near Morgan Hill, Melhase (34). Siskiyou County: Jasper is common with the numerous serpentine masses of the county. Sonoma County: Red jasper is found at Windsor. The petrified wood of the Petrified Forest west of Calistoga is Iftrgely chalcedony. Trinity County: Jasper occurs on Red IVIountain at the head of Prospect Peak. Tulare County: Fine moss agate occurs on Deer Creek. Chryso- prase is found at Yokohl. Chrysoprase was mined on the eastern slope of the Venice Hills; at Stokes Mountain; on the Tule River; on Deer Creek; and 1 mile east of Lindsay. Tuolumne County: Yellow and brown jasper occurs at Shaws Flat. 7—51440 98 MINERALS OF CALIFORNIA TRIDYMITE Silicon dioxide, Si02. Ortliorhombic. Thin pseudo-hexagonal plates, often overlapping. Brittle. Vitreous luster. Colorless to white. H. = 7. G. = 2.28 — 2.33. Reactions the same as for quartz. Tridymite is a form of silica which is found in recent volcanic rocks. It is generally of microscopic size and therefore is rarely seen, except in thin sections of rocks. As a rock mineral it may occur in all of the recent volcanics. Imperial County: Tridymite with cristobalite and feldspar is a principal constituent of an altered rhyolite obsidian which makes up Cormorant Island in the Salton Sea, Rogers (26). Inyo County: Tridymite occurs in lithophysae in obsidian at Little Lake, 40 miles south of Owens Lake, Wright (16). Lake County: Druses and groups of sharp tridymite crystals occur in vugs and seams in andesite in Seigler Canyon, near Lower Lake. Mono County: Schaller, (05a) has described small plates of tri- dymite with the forms: (0001), (1010), (3250), (54'90), (3034), and (l6T2), in the cavities of lava near Bridgeport. Ban Luis Obispo Coimty: Tridymite is found in lithophysae in rhyolite on Black Mountain in tlie southern Santa Lucia Range, Talia- ferro and Turner (32). Shasta County: Tridymite has been described by Andereon (35) as a secondary mineral at Bumpass Hell and other hot springs in Lassen Volcanic National Park. It occurs abundantly in vesicular basalts on the road to Terry's Mill, east of Round Mountain. Tuolumne County: It occurs as very thin, wliilc |)lfites iti cavities of an andesite, near Jamestown, Rogers (12). CRISTOBALITE Silicon dioxide, Si02. Isometric. -* Small octahedrons. Dull luster. Color white. H. = 6 — 7. G. = 2.27. Infusible and insoluble like quartz. Imperial County: Cristobalite occurs with tridymite and feldspar in an obsidian metamorphosed by hot gases on Cormorant Island, Salton Sea, Rogers (26). Inyo County: Cristobalite is associated with orthoclase, tridymite, opal, fayalite, and magnetite in the lining of small spherical cavities in obsidian near Little Lake, about 8 miles west of Coso Hot Springs, Rogers (22), (28). OXIDES 99 Siskiyou County: Cristobalite occurs with fayalite in litliophysae in spherulitic obsidian, near Canyon Butte in Sec. 13, T. 44 N., R. 43 E., M. D. M. Tehama County : Cristobalite is a constituent of volcanic rock near Tuscan Springs, Rogers (18). Tuolumne County: Distinct octahedral crystals of cristobalite occur ill augite andesite, near Jamestown, Rogers (18). OPAL Silicon dioxide, with a varying amount of water, Si02.nH20. Amorphous. Colloidal massive; also earthy. Prominent conchoidal fracture. Waxy or glassy luster. Color yellow, brown, green, blue, red, white, gray, and colorless. Streak white. H. = 5| — 6i. G. r= 2.1 — 2.2. Gives a slight amount of water in a closed tube, otherwise like quartz and chalcedony in its reactions. Opal is colloidal silica containing from 2 to 10 per cent of water. It occurs as veins, nodules, and coatings. Common opal occurs in white, yellow, brown, bluish, or greenish masses having a prominent conchoidal fracture. Fire opal is opal with fire-like reflections. Hyalite is transparent glassy opal found in the cavities of volcanic rock. Chrysopal or prase opal is a greenish opal found with chrysoprase. Moss opal is common opal with moss-like inclusions of pyrolusite 01- chlorite. Wood opal is petrified wood. Geyserite is a hydrous silica formed about the vents of geysers and hot springs. Diatomaceous earth, and infusorial earth are deposits of silica formed by diatoms. Alpine County: Wood opal occurs at Red Lake Peak. Amador County: Wood opal was found at Volcano; diatomaceous earth in lone Valley. Butte County: Wood opal occurs at the Dodson mine. Calaveras County: Common and hyalite opal have been found at Mokelumne Hill. Wood opal occured at Cliilo Gulch, Bald Hill, Angels Cam]), and other mining camps. Contra Costa County: Hyalite and common opal have been found on Mount Diablo. ]00 MINERALS OF CALIFORNIA Fresno County: Moss opal has come from the mountains east of Fresno. Diatomaceous earth is reported to occur a few miles south- west of Mendota. Inyo County: Diatomaceous earth is reported from Independence Valley near the main highway. Kern County: White opal is found on the summit of Tehaehapi Mountain. Fine moss opal occurs 18 miles northwest of Johannesburg. Lewis (33) has reported the occurrence of 'milk opal' and 'resin opal' near Rosamond. Lake County: Large white masses of opal which have replaced basalt occur at Sulphur Bank. Hyalite has come from Middletown and Kelseyville. Diatomaceous earth occurs on the Lost Spring ranch. Lassen County: Wood opal is found in Surprise Valley. Yellow and white opal have been found near Honey Lake. Diatomaceous earth is found at Butte Lake in Lassen Volcanic National Park, Finch and Anderson (30), Los Angeles County: Diatomaceous earth occurs at Santa Monica and on Santa Catalina Island. Diatomaceous earth is reported to occur near Bairdstown ; in the bluffs 3 miles south of Redondo ; at Point Duma, northwest of Santa Monica; at Palos Verdes ranch, San Pedro Hills; and near Acton. Merced County: Diatomaceous earth of good quality occurs in the hills west of Newman. Mono County: Diatomaceous earth has come from near Bodie. Geyserite occurs near Casa Diablo, Lewis (33). Monterey County: Diatomaceous earth occurs 9 miles northwest of Bradley; also near Del Monte. Napa County: Diatomaceous earth occurs in Friend's Valley west of Calistoga ; also 4 miles southeast of St. Helena. Nevada County: Wood opal occurs at Chalk Bluff, Nevada City, North Bloomfield, and Shelly Hill. Masses of moss opal were found at Newton. Orange County: Diatomaceous earth occurs near Allison Creek south of El Toro. Placer County: Wood opal occurs at Gold Run and near Roseville. Diatomaceous earth was found at Dutch Flat. Plumas County : Wood opal occurs in the Gravel Range. OXIDES 101 Riverside County: White hyalite coats the Avails of some of the small cavities in the feldspathic pegmatite at Crestmore ; dark-brown and black wood opal occurs with calcite in Sky Blue Hill, Eakle (17). San Bernardino County: Good gem opal is obtained in the Black Mountains about 25 miles north of Barstow; some clear hyalite occurs with it. Common white, colorless hyalite, red, and gem opal occur in cavities in rhyolite 2 miles northeast of Lead Pipe Springs. An opal deposit occurs about 25 miles north of Barstow, in Copper Mountain. San Diego County: Thin coatings of glassy hyalite occur on the quartz and albite at Rincon, Rogers (10). San Francisco County: Nodular masses of common opal occur in the serpentine of San Francisco. Moss opal occurs in the Black Hills. San Luis Obispo County: Diatomaceous earth occurs near Port San Luis, near Arroyo Grande, and near Edna. Occurrences of diatomaceous earth are reported in the mountains back of Pismo, in the hills on the south side of San Luis Valley, in the San Luis Range south of Morro Bay, and in the Salinas Valley as far north as Rin- conada. San Mateo County: Diatomaceous earth occurs at San Gregorio. Santa Barbara County: A large deposit of diatomaceous earth occurs at Lompoc. Diatomaceous earth also occurs on the southern slope of the Santa Ynez Mountains and near Santa Barbara. It is exposed in the low hills south of Surf and along the coast south of Goleta. Shasta County: Diatomaceous earth is found in extensive beds along the Pit River and on Hat Creek. A pure white diatomaceous earth occurs a few miles southwest of Bartle in T. 37 N., R. 3 E., M. D. M. Opal occurs with alnnite and kaolin in thick and incoherent deposits on the lower flanks of Brokeoff Mountain, H. Williams (32). Sierra County: Wood opal has come from Downieville. Siskiyou County: Fire opal has been found near Dunsmuir. Sonoma County: Wood opal occurs near Santa Rosa; diatoma- ceous earth about 10 miles north of Petaluma ; geyserite at the Geysers. Yellow masses of opal occur on the hills north of Sonoma. Opal of gem quality has been found near Glen Ellen. Fire opal has been found in a clay deposit on the Weise ranch, between Glen Ellen and Kenwood. Infusorial earth occurs as a bed five feet thick 1 mile north of Mark West Springs and 6 miles east of Windsor. A deposit of infusorial earth occurs 2 miles northeast of Agua Caliente. Wood opal in large trees occurs in the Petrified Forest west of Calistoga. 102 MINERALS OF CAIilKORNIA Tehama County: Opal stalactites and stalagmites have been found in a lava tube in basalt on the north side of Inskip Hill, Ander- son (30). Tulare County: Wood opal occurs in Kings River Canyon. Diatomaceous earth occurs near Exeter. Chrysopal or prase opal v^^as found with chrysoprase in the hills east of Visalia and Porterville. Yellow opal occurred with chrysoprase at Yokohl. T)iohi))ine County: Wood opal has been found near Columbia. ARSENOLITE— White Arsenic Arsenic oxide, AS2O3. Isometric, commonly in fibrous crusts and earthy. Octaliedral cleav- age. Silky or vitreous luster. Colorless or v^^hite. H. ^= IJ. G. — 3.7. Fusible, yielding- white fumes and garlic odor. Alpine County: Arsenolite is found as an alteration of enargite at the Exchequer mine. Small white octahedrons of arsenolite with realgar occur in the pj^rite and enargite at the Monitor mine. San Bernardino County: Large masses of arsenolite occurred with gold at the Amargosa mine, W. P. Blake (66). CLAUDETITE Arsenic oxide, As^Os. Monoclinic. Platy crystals. Perfect clinopinacoidal cleavage. Lus- ter pearly to vitreous. Colorless to white. H. = 2*. G. ^ 3.85 — 4.15. Dense white fumes and garlic odor when heated on charcoal. Imperial County: Kelley (36) has described the occurrence of claudetite crystals in a vein of kaolin, gypsum, halloysite; and sulphur, at a sulphur prospect 6 miles north of the 4 S ranch and Iv miles west of the Colorado River. Foi-ms: (110), (101), (111), and (111), Palache (34). Trinity County: Claudetite occurs as crusts of well-formed mono- clinic crystals in the pyrrhotite deposit at Island Mountain. VALENTINITE Antimony oxide, Sb20:i. Orthorhombic. In prismatic crystals. Generally columnar masse.'?. Perfect brachypinacoidal cleavage. Adamantine luster. Color snow- white to ash-gray, lemon-yellow. Streak white. H. r=2l. G. :=5.76. Gives white coating, but no odor on charcoal. Gives no sulphur in closed tube. Valentinite is an oxidation product of antimony minerals, espe- cially of stibnite. Kern County: Valentinite occurs with antimony and stibiconite along Erskine Creek, Behre (21). OXIDES 103 San Benito County: Lemon-yellow bladed aggregates of valen- tinite, probably pseudomorplis after stibnite, with cinnabar, quartz, and chalcedony, occur at the I'icahotes [Picachos] mine, Rogers (12). BISMITE— Bismuth Ocher Bismuth oxide, Bi203.3H20. Hexagonal-rhomhohedral. Commonly occurs as an earthy coating. Color yellow to gray. G. = 4.36. Gives yellow coating on charcoal, wliich becomes bright-red when fused with potassium iodide and .siilpluir. Bismite occurs generally as a j^ellowisli ])()wder or coating on bismuth minerals, especially on native bismuth. 8a7i Diego County: Bismuth ocher was found as a yellow and gray powder with native bismuth at Pala, Kunz (03b). This powder is, according to Schaller (11a), in part bismuth hydroxide, bismuth vanadate, and mixtures of the two. An analysis of the yellow ocher from the Stewart mine showed it to be a mixture of the hydroxide and the vanadate. Gangue H2O Bi203 V2O5 Sol. in HNO3 Insol. in HNOs 107° 210° Ign 64.43 12.11 2.27 17.63 0.32 0.24 3.43 100.43% An analysis of the gray ocher from the Stewart mine showed it to be probably bismuth hydroxide with the formula Bi20;j.3Il20. Gangue H2O Bi203 V2O5 Sol. in HNOs Insol. in HNO3 107° 210° Ign. 64.9 0.8 9.5 13.5 0.4 0.3 11.4 100.8% Yellow bismite in small irregular particles and minute tabular crystals with the forms (100) and (Oil) occur at the Victor mine, Kincon, Rogers (10). ILSEMANNITE Molybdenum compound, formula uncertain. Cryptocrystalline. Color blue-black to black. Soluble in water. Shasta County: Ilsemannite has been found with molybdenite and pyrite 4 miles west of Gibson, Cook (22). CERVANTITE Antimony oxide, Sb203.Sb20.-,. Orthorhombic. Acicular crystals rare ; usually a crust or powder. Sometimes massive. Color yellow to white. H. :=4J. G. =i 4. Infusible. The antimony oxide coating on charcoal is obtained only with the aid of a flux like sodium carbonate. Cervantite occurs as an alteration product of stibnite or native antimony. 104 MINERALS OF CALTFORNIA Inyo County: Massive yellow cervantite has been found at the Lottie mine, Wild Rose district, and at the St. Ignacio mine. Kern County: Cervantite occurred with stibnite at the San Emidio mine. STIBICONITE Hydrous antimony oxide, H2Sb205. Mostly amorphous. Massive or as a crust or powder. Color yellow- ish-white. H. = 4 — 5|. G. = 5.1 — 5.28. Reacts like cervantite. but yields water in a closed tube. Occurs as an alteration product of stibnite or native antimony. Kern County: Stibconite has been found with native antimony at Little Caliente Springs and on Erskine Creek. PARTZITE Hydrous oxide of antimony, copper and other bases. Massive. Color blackish-green to black. H. = 3 — 4. G. = 3.8. Stetefeldtite is similar to partzite with more silver. ' Mono County: Partzite was found with argentiferous galena in veins in the Kerrick, Comanche, Diana, and Comet mines of the Blind Spring Hill district and described as a new mineral and analyzed by Arents (67). It was considered, however, by W. P. Blake (67a) to be a mechanical mixture of the hydrous oxide of antimony with other metallic bases. SbaOs CU2O AgeO PbO FeO H2O 47.65 32.11 6.12 2.01 2.33 8.29 = 98.51% A specimen labeled ''stetefeldtite" has come from the Giant mine. CUPRITE— Red Copper Ore Cuprous oxide, CU2O. Isometric. Small cubes and octahedrons. Generally massive. Brit- tle. Adamantine to submetallic luster. Color red. Streak brownish-red. H. = 3J. G. = 5.85 — 6.15. Mixed with sodium carbonate, it is easily reduced on charcoal to metallic copper. Soluble in concentrated hydrochloric acid, and when cooled and diluted with cold water, yields a heavy white precipitate of cuprous chloride. Cuprite is an important ore of copper. It occurs in most of the copper localities as a secondary mineral in the oxidized portions of the deposits. Massive specimens have come from various counties but no large bodies of cuprite are known in California. Chalcotrichite is a long hair-like variety. Calaveras County: Masses of cuprite with chalcopyrite are occa- sionally found at Copperopolis and Campo Seco. It is mentioned by Silliman (67a) from Quail Hill. OXIDES 105 Colusa County: Cuprite occurred at the old Candace and Union mines. The capillary variety, chalcotrichite, was found with massive cuprite in the Lion mine. Del Norte County: Masses of cuprite with native copper occurred at the Pearl copper mine. Cuprite is common in the Rockland district. El Dorado County: Cuprite occurred with malachite, chalcopyrite, and native copper at the Cambrian mine. Fresno County: It was prominent in the Gordon-Fresno copper mine. Humholdt County: Cuprite occurs with native copper and mala- chite on Horse Mountain. It was found with melaconite, chalcocite, and malachite on the Fields Lebanon property. Red Cap Creek. Kern County: Cuprite occurred in the Greenback mine. Woody district, 30 miles northeast of Bakersfield, Storms (13). Lassen County: Cuprite occurs in the Lummis mine. Modoc County: Excellent specimens of cuprite with malachite, native copper, and chrysocolla have come from the Christy mine, Fort Bidwell, and from the Leitz mine, 7 miles south of Fort Bidwell. Mono County: Massive cuprite was found at the Eclipse, Kerrick, and Mammoth mines; also near Lundy with cerargyrite and chryso- colla. It occurred with native copper at the Cavin mine, Copper Mountain, 22 miles southwest of Bodie. Cuprite is found with mala- chite and melaconite in the Detroit Copper mine, Jordan district, about 6 miles northeast of Lundy. Napa County: Cuprite was found near Calistoga and St. Helena, some of it the chalcotrichite variety. Nevada County: Cuprite occurs with chalcocite and native copper at Meadow Lake; with chalcocite and malachite at the Oro Grande mine. Placer County: Massive cuprite occurs near Lincoln; it is found with chalcopyrite at the Elder mine. Plumas County: It occurs in Light's Canyon; with native silver at the Pocahontas mine, Indian VaUey. Riverside County: It occurred in quantity at the Red Cloud mine, Chuckawalla Mountains. San Bernardino County: Massive cuprite was found in Holcombe Valley; common at the Copper World mine, Clark Mountain. Shasta County: Cuprite has been found at the Peck, Afterthought, Copper City, Greenhorn, and other mines of this county. 106 MINERALS OF CALTFORNIA Tr'mUy County: It occurs massive at Trinity Center. Tulare County: Cuprite occurs in the Mineral King district. Tuolumne County: It was found at Whiskey Hill, Silliman (67a). PERICLASE Magnesium oxide, MgO. Isometric. Cubes and octaliedrons. Cubic cleavage. White or colorless. H.= G. G. r= 3.67 — 3.90. Infusible, but completely soluble. Ammonia and sodium phosphate added to hydrochloric acid solution precipitates magnesia. Alters to Ijrucite. Riverside County: Periclase was found in the city (juarry at Riv- erside, Rogers (18a). It was later reported by Rogers (29) from the AVet AA^eather quarry at Crestmore. MASSICOT Lead monoxide, PbO. Orthorhombic. Usually in scales or scaly masses. Color brownish orange-red. Soft. G. = 9.29. Puses easily to a yellowish glass. Easily reduced on charcoal to metallic lead, yielding yellow coating. San Bernardino County: Crystalline scaly masses of massicot with litharge occur on Cucamonga Peak, and were described by Lar- sen (17a). LITHARGE Lead monoxide, PbO Tetragonal. Scaly masses. Color lemon-yellow to orange-yellow. H. = 2. G. = 9.13. Fuses easily to a yellow glass. Easily reduced on charcoal to metallic lead, and gives yellow coating. San Bernardino County: Litharge occurred with massicot on Cuca- monga peak, Larsen (17a). TENORITE— Melaconite Cupric oxide, CuO. Triclinic. In minute scales: also as an earthy powder; massive. Metallic to dull luster. Color and streak black. H. = 3 — 4. G. =.5.82 — 6.5. Same reactions as obtained from cuprite. Distinguished by color. Calaveras County: Tenorite is a common alteration product of clialcopyrite at Copperopolis and Campo Seco. Large nodular masses of it have come from the Satellite mine. It is found with malachite at the Telegraph mine. Hog Hill. Colusa County: Tenorite was found in serpentine with native copper and cuprite at the Gray Eagle mine. Del Norte County: It occurred with the chalcopyrite at the Alta and Pearl mines. OXIDES 107 Inyo County: Tenorite occurred wilii elirysocolla, azurite, and malachite in the Greenwater district. Mono County: It was found with cuprite at the Detroit copper mine. Nevada County: Tenorite occurred at the Excelsior mine. Shasta County: It occurs at the Afterthought and other chalco- pyrite mines of this county. MONTROYDITE IMercairic oxide, HgO. OiUiurhombic. Prismatic crystals. Perfect piiiiu^oidal cleavage. Brilliant luster. Color and streak deep-red. H. = 1?; — 2. Volatile. San Mateo County: Montroj'dite has been found in long prismatic and bent crystals with eglestonite, calomel, native mercury, and cin- nabar in joints and fissures in a siliceous rock replacing serpentine about two miles west of Redwood City, Woodhouse (34). HEMATITE GROUP CORUNDUM Aluminum oxide, AI2O:!. Hexagonal-rhombohedral. Prismatic crystals and massive. Brittle ; when compact very tough. Adamantine to vitreous luster. Color generally bluish-gray; also blue, red, yellow, brown, gray. Streak uncolored. H. r=9. G. = 3.95 — 4.10. Infusible and insoluble. Fragments moistened with cobalt nitrate and intensely heated assume a sky-blue color. Corundum-bearing rocks are rare in the State and no workable deposits of this useful mineral are known. The gem varieties, ruby and sapphire, have not been found in good clear crystals. Butte County: A few .sapj)liires are said to liave been found with diamonds in stream gravels in this county. Los Angeles County: The first mention of coruiidum in the State was of some sapphirp-l)]iio ])ebbles found in San Francisquito Pass, W. P. Blake (66). Mono County: Coarse nodular masse.s of corundum occur with the andalusite at the mine of Champion Sillimanite, Incorporated, on the western slope of the White Mountains, 7 miles east of ]\Iocalno, Kerr (32). Plumas County: Large violet-blue crystals occur in the plumas- ite of Spanish Peak, Lawson (03). Riverside County: Large crystals of corundum have been found near the summit of the San Jacinto Mountains. 108 MINERALS OF CALIFORNIA Sa7i Bernardino County: Corundum was found in the Kingston Range, Kunz (05). Pale-rose to deep-lilac crystals of corundum occur in metamorphosed limestone in Cascade Canyon, a branch of San Antonio Canj^on, in the San Gabriel Mountains, Louderbaek and Blasdale (10), Merriam and Laudermilk (36). San Diego County: It is a constituent of the dumortierite schist of Dehesa, Schaller (05). Pink and gray crystals of corundum occur in a vein with garnet in mica schist on the northern slope of the San Miguel Mountains, 26 miles east of San Diego. Blue corundum is reported from Tule Mountain, north of Jacumba. HEMATITE— Red Ocher Iron oxide, Fe203. Hexagonal-rhombohedral. Crystals, compact massive, lamellar, ^anular, micaceous, and earthy. Luster metallic, submetallic, or dull. Color black, red, brown. Streak red and reddish-brown. H. = 51- — 6^. G. =^4.9 — 5.3. Gradually acted on by strong acids ; ammonia precipitates ferric hydrate. Becomes magnetic on heating. Gives little or no water in closed tube. Hematite is the chief ore of iron. Crj^stalline black masses of hema- tite are found with metamorphic and intrusive igneous rocks. The flaky variety, specular hematite, often termed 'speeularite,' is a com- mon constituent of the crystalline rocks of the State. Red hematite mixed with brown limonite forms the capping of manj^ iron sulphide deposits. Martite is a pseudomorph of hematite after magnetite. Much of the magnetite of the State shows a change into hematite and martite is common in the magnetite-hematite deposits. Alameda County: Massive red earthy hematite mixed with lim- onite forms the capping of the pyrite body at Leona Heights. Alpine County: Massive black hematite occurs at Monitor. Amador County: Impure hematite occurs 2 miles west of lone, and also half a mile northwest of Clinton. Butte County: It is common in the gravels at Magalia, Butte Creek, Oroville, and Stirling City. Specular hematite is found at Bangor. Calaveras County: Hematite was found at Douglas Plat, Mur- phy, Wallace, and Quail Hill. Colusa County: Good massive hematite occurs 40 miles west of Willows. A red hematite suitable for mineral paint occurs in a deposit 4 miles southwest of Lodoga. oxroES 109 Del Norte County: It was found at tlie Kelsey Tunnel, 14 miles southeast of Crescent City. El Dorado County: Hematite occurred in masses at Shingle Springs. It also occurred in the gravels at Diamond Springs, Green Valley, and Virner. Humholdt County: It occurs in a large vein 3 miles south of Centerville. Red ocherous hematite is found near Garberville and also 8 miles from Ferndale. Soft red ocherous hematite occurs on Jones Creek, 2 miles northeast of Areata. Specular hematite occurs in the Humboldt mine at Orleans. Massive red hematite occurs on Rainbow Ridge. Inyo County: ]\Iassive specular hematite occurs at the Defiance mine. Hematite is also found in Owens Valley, Hanks (84). A large deposit of specular hematite is found near Alvord Station. The specular variety is found in large masses in the Inyo Mountains, 7 miles east of Kearsarge. Red hematite occurs five miles north of Shoshone. Fine specular hematite occurs in the Grapevine Range. Kern County: Hematite occurs at Cane Springs and Ricardo. A deposit of specularite occurs in mica schist at the foot of Mount Breckenridge, about 20 miles north of Caliente. Red ocherous hem- atite occurs in the Red Rock district. Lake County: Massive red hematite occurs near Glenbrook. A deposit of red ocherous hematite occurs in Jerusalem Vallej', near Dollar Springs. Pseudomorphs of hematite after marcasite have been described from the Baker mine, 6 miles from Lower Lake, by Rogers (10a). Lassen County: Excellent specimens of specular hematite have come from near Susanville. Marin County: Massive specimens of hematite have come from the Mailliard ranch, about 2 miles southwest of San Geronimo. Mendocino County: Large crystalline masses of hematite occur 7 miles east of Round Valley on the Eel River. Red ocherous hema- tite is found in Anderson Valley and near Covelo. Mono County: It is common in the Blind Spring Hill district. Abundant masses of specular hematite occur in the audalusite mass on the western slope of the White Mountains, Knopf (17a). Napa County: Massive red hematite occurs near St. Helena, at White Sulphur Springs, and Blaisville. Red and brown masses of hematite and limonite occur at the Sterling Iron mine, St. Helena. 110 MINERALS OP CALIFORNIA There is a red oclierous hematite deposit on Benoli Mountain, 2 miles south of Calistoga. Nevada County: It was found with gokl at Meadow Lake, Lind- gren (93). Small dejoosits of hematite occur at Indian Springs and at Newtown. Orange Count ji: It was observe*] at Pullerton. Placer County: Hematite occurs with magnetite at the Hotaling deposit about 6 miles nortli of Auburn. Small amounts of it occur at Clipper Gap, Red Hill, and Jiear Weimar. Plumas County: Hematite occurs with magnetite near Crescent Mills; at jMumford's Hill, Light's Canyon, Genesee Valley, and Nel- son Point. Foliated masses of specular hematite occur in quartz on the north side of the Diamond Range. Specular hematite mixed with magnetite occurs as a vein very close to the Diadem lode. Black masses of hematite occur with magnetite near Moonlight, 11 miles north of Taylorville. Hematite is common at the Engels copper mine. Riverside County: Considerable hematite is associated with, and has been formed from magnetite, at the extensive deposits in the Eagle Mountains. The specular variety associated with green epi- dote is common in the Monte Negro district. Some of tlie cellular cavities formed by leaching out of brucite are filled with red hema- tite, at Crestmore, Eakle (17). San Benito County: It was reported to occur at tlie old Quilty Iron mine. San Bernardino County: IMie numerous iron deposits of the Mojave Desert have hematite and magnetite in heavy black masses. The deposits near Dale, on Iron Mountain, in the Kingston Range, at Cave Canyon, Newberry, on Providence Mountain near Kelso, and elsewhere in the county, are massive hematite after magnetite, or raartite. A soft red ocherous hematite occurs in the Calico district, 5 miles west of Yermo. Hematite is found massive on Sheephole Mountain. San Diego County: Black massive hematite occurs in Eagle Peak Canyon. San Joaquin County: Earthy red liematite as shale occurs at the Ladd manganese mine. Sa}i Luis Ohispo County: An extensive deposit of hematite witli limonite occurs iu the Irish Hills southwest of San Luis Obispo, Franke (35). OXIDES 111 Shasta County: The Redding or Pit River deposit of hematite has been utilized at the electric smelting furnace at Heroult. Thick deposits of earthy hematite and limonite cap the pyrite beds of this county. Siskiijou County: The gravels of the Shasta River contain spec- ular hematite. Sonoma County: Deposits of hematite are reported near Port Ross and near tlie Avest fork of the Gualala River. Hematite occurs on the Lancaster ranch, east of Pisk's j\Iills. Siliceous hematite occurs on Porter Creek, about 10 miles southwest of Healdsburg. Stanislaus County: Poliated hematite occurs near La Grange. Tehama County: Deposits of hematite occur at Beegum. Trinity County: It is found in the sands at Trinity Center. Spec- ular hematite occurs near Burnt Ranch. Yuha County: It is found in the sands of the Brownsville district. ILMENITE — Menaccanite Oxide of iron and titanium, FeTlOa. Hexagonal-rhombohedral. Plates, massive, in rounded pebbles and grains. Submetallic luster. Color black. Streak dark-brown to black. H. = 5 — 6. G. = 4.5 — 5. Magnetism usually increased by heating. Wlion ilmenite is fused with sodium carbonate and the flux dissolved in hydrochloric acid, the solution turns reddish or bluish violet when reduced with metallic tin. Ilmenite resembles hematite and magnetite so closely that it is not often differentiated from them. The black beach sands and the black- sand coiu'cntrates in the gold fields contain much ilmenite in small L'rains and rolU'd pebbles. In most of the localities given below it exists in the sands. Amador County: Ilmenite occurs near Volcano. Butte County: It occurs at Oroville, Cherokee, Little Rock Creek, Brush Creek, and Inskip. Calaveras County: Ilmenite occurs in considerable amounts at San Andreas, Murphy, and Wallace. Del Norte Coimty: It occurs at Crescent Cit3^ El Dorado County: It occurs in the Brownsville district, at Green Valley, Placerville, and Grizzly Plats. It occurs at Georgetown, W. P. BlMke (58). Fresno Counhi: Ilmenite occurs with rutile, near Priant. Humholdt County: It occurs at Upper Gold Bluff. Imperial County: Massive ilmenite occurs near Niland. 112 MINERALS OF CALIFORNIA Kern County: It is an important constituent of the black sands at Vaughn. Los Angeles Comity: Ilmenite occurs in the beach sands at Ocean Park and Ilermosa Beach. Important deposits of ilmenite occur in the San Gabriel Mountains. Madera County: Plates of ilmenite are found with pyrophyllite and quartz at Beach Creek on the North Fork of San Joaquin River, and platy masses of ilmenite occur just west of Agnew Pass, Erwin (34). Mariposa County: Ilmenite occurs near Princeton, and as crystals in dolomite near Mariposa. Mono County: Minute flakes of ilmenite occur in andalusite at the mine of Champion Sillimanite, Incorporated, on the western slope of the White Mountains, 7 miles east of Mocalno, Woodhouse (36). Nevada County: Ilmenite occurs at Rough and Ready, Nevada City, North Bloomfield, and Relief Hill. Orange County: Ilmenite occurs at Fullerton. Placer County: Ilmenite occurs at Gold Run. Plumas County: Ilmenite occurs at Spanish Ranch, Crescent Mills, La Porte, and Nelson Point. It is intergrown with hematite and magnetite at Engels. Good crystals have been found at Genesee. San Bernardino County: Ilmenite occurs near Needles. San Luis Ohispo County: It is found in the beach sands of the county. Santa Barbara County: It occurs at Point Sal. Santa Cruz County: It is a constituent of the black sands at Aptos, Hess (27). Shasta County: It is found at Round Mountain, French Gulch, and Redding. Siskiyou County: It occurs in the sands of Jackson Creek, Happy Camp, Forks of the Salmon, Sawyers Bar, Scott River, and Shasta River. Trinity County: It occurs at Junction City, Carrville, Minersville, and on the Trinity River. Tidare County: It occurs with specular hematite and magnetite, near Orosi. Tuolumne County: It occurs at American Camp. Yuha County: It occurs at Marysville, Brownsville, Yuba River, Strawberry Valley, Indian Hill, and Oregon House. OXIDES 113 SPINEL GROUP SPINEL Magnesium, aluminum oxide, MgO.AlsOs. Isometric. Usually in octahedrons ; rounded grains. Brittle. Vitreous luster. Color ruby-red, blue, green, brown, black. Streak white. H. = 8. G. = 3.5 — 4.1. Infusible. Fused with sodium carbonate, dissolved in hydrochloric acid, the solution yields aluminum hydroxide on the addition of ammonia, and white magnesium phosphate on the further addition of sodium phos- phate, thus distinguishing- it from corundum. Spinel occurs only as a rock constituent and exists in some of the gold-placer sands as rubj^-red grains resembling- red garnet. Picotite is a brown spinel containing chromium and iron ; it occurs in the serpentine rocks. Pleonaste is a dark-green iron-magnesium spinel. Butte County: Small crystals of ruby spinel have been found in the rock of the diamond mine near Oroville. Humholdt County: Ruby spinel occurs in the beach sands at Gold Bluff. Lassen County: Brown octahedral crystals of picotite have been found in quartz basalt at Cinder Cone, Lassen Volcanic National Park, Finch and Anderson (30). Placer County: Picotite has been found at Rocklin, Hanks (84). San Bernardino County: Black spinel occurs in the basalt flows south of Pipes Canyon, Sees. 21 and 22, T. 1 N., R. 4 E., S. B. M., in basalt near Quail Springs, T. 1 S., R. 7 E., S. B. M. San Diego County: Blue spinel was reported to occur in the Mack mine near Rincon ; the deep-green, pleonaste variety, in small octa hedrons, occurs there with garnet, Rogers (10). San Luis Ohispo County: Ruby spinel has been observed near San Luis Obispo, Kunz (05). Siskiyou County: Picotite occurs in the basalts of Mount Shasta, Hanks (84). Tulare County: Granular green spinel occurs in metamorphosed serpentine on the southwest side of Rocky Hill and in metamorphosed basic volcanic roclis on the southern slope of Woodlake Mountain. 8—51440 114 MINERALS OF CALIFORNIA MAGNETITE Iron oxide, FesOj. Isometric. Octahedral crystals, compact and granular massive. Metallic luster. Color iron-black. Streak black. H. = 5J — 6|. G. :=5.1. Strongly magnetic. Soluble in hydrochloric acid, and reddish ferric hydrate precipitated on the addition of ammonia. Distinguished from hematite by streak and magnetism. Magnetite is one of the most abundant of the iron minerals, and good deposits of it occur in tlie State. It is a constituent of most igneous rocks and in sncli condition exists in all of the counties. It forms the bulk of the black sands. Most magnetite occurs with the metamorphic schists and gneisses, and in igneous rocks. It often occurs along the contact of igneous intrusions through metamorphic or sedimentary rocks. Some magnetite is titaniferous, grading toward ilmenite. Lodestone is a variety possessing polarity; it forms a natural magnet. Alameda County: Octahedral crystals occur in the schists of North Berkeley. Butte County: Magnetite is abundant in the drift workings at Magalia, in the gravels on Butte Creek, and in the dredging sands at Oroville. It is found in the concentrates at Stirling City, Little Rock Creek, Brush Creek, Lovelock, and Inskip. Masses of it occur near Oroville. (kdaveras County: It is found in the concentrates at Douglas Flat, San Andreas, Murphy, and Wallace. Massive magnetite occurs on Cai'- son Hill. ]>il Norte County: It is found at (h-escent City, (jilbert Creek, and Smith River. Masses of pure magnetite occur in the French Hill min- ing district. El Dorado County: Magnetite occurs massive and as fine octa- hedrons in chlorite about 2 miles northeast of Shingle Springs. Lode- stone has been found at Colma. Magnetite is common in the concen- trates at Virner, Green Valley, Clrizzly Flats, the Reliance mine, and ill the Brownsville district. It occurs with galena, chalcopyrite, cal- cite, quartz, and garnet as a contact deposit at the Lilyoma mine, Pilot Hill. Large masses of magnetite occur near Volcanoville, W. P. P>lake (58). Masses of magnetite are found near Fallen Leaf Lake. Fresno County: Lodestone has been found at the Sparkling Iron mine, Kings Creek district. Octahedral crystals associated with bornite occur in the Uncle Sam mine on Crown Creek opposite Tehipite Dome, the Kings River. Pure masses of magnetite occur in Cinnamon Bear district, Pine Flat. OXIDES 115 Humholdt County: The greater part of the black constituent of the beach sands at Gold Bluif and Upper Gold Bluff is magnetite. It is common at Orleans and Trinidad. Imperial County: It is found massive near Palo Verde. Inyu County: Large deposits of magnetite are reported to occur in the Olancha district near the Haiwee Dam. Kern County: It is abundant in the black concentrates at Ricardo, Kane Springs, and Vaughn. Granular masses of magnetite occur in the San Emigdio mining district. Magnetite occurs with mica schist, 1^ miles south of Woody. Los Angeles County: Several deposits of titaniferous magnetite occur in T. 4 N., R. 14 W., S. B. M., south of Soledad Canyon, Tucker (27). W. J. Miller (31), (31), has described the occurrence of massive titaniferous magnetite in gabbro and diorite 1 mile southwest and 3 miles east of the Monte Cristo Gold mines near the headwaters of Mill Creek in the San Gabriel Mountains. It occurs in the black sands at Ocean Park, and with garnet in the black sands of Santa Monica Bay. Madera County: Large deposits of magnetite occur on the western slope of Iron Mountain in the Minaret district, "Weeks (15), Erwin (34). Deposits of it occur on the western slope of Mount Raymond. Mariposa County: ]\Iasses of magnetite occur at the base of J\Iount Hoffman. Modoc County: It is found in the drift and black sands of the Pit River. Mono County: It is found massive in the Benton, Bodie, and Lundy districts, Whiting (88). Nevada County: Deposits of magnetite occur about 1 mile west of Newtown, and about 4 miles south of Indian Springs at the contact between granodiorite and diabase. Magnetite is common in the con- centrates at Nevada City, Grass Valley, North Bloomfield, Relief Hill, and Rough and Ready. A small deposit of magnetite occurs in place at Diamond Creek, about 1 mile east of the Omaha mine. Orange County: It is found in the sands at Fullerton. Placer County: A deposit of magnetite which was worked in 1881- 1886 by blast furnace, occurs at Hotaling, 5 miles west of Clipper Gap, on contact between diabase and quartzite. Octahedrons are com- mon at Forest Hill. It is common in the black sands and concentrates at Butcher Ranch, Michigan Bluff, Gold Run, East Auburn, in Blue Canyon, and on the North Fork of American River. 116 MINERALS OF CALIFORNIA Plumas County: Magnetite is common at Spanish Ranch, Genesee, La Porte, Nelson Point, Crescent Mills, and on Rock Island Hill, but only in small amounts. A large body of the ore occurs close to the west shore of Wades Lake. It is found with hematite at Moonlight. Mag- netite is common in the rocks at Engels, sometimes intergrown with ilmenite, Knopf and Anderson (30). Rwerside County: One of the largest deposits of iron in the State occurs on the Eagle Mountains. It is magnetite-hematite or mar- tite ore. Sacramento County: It occurs in the black sands at Michigan Bar. San Benito County: A large deposit of magnetite is reported near Hollister. San Bernardino County: Magnetite occurs at the Iron Age iron- ore deposit 6 miles east of Dale, Harder and Rich (10). It occurs at Owl Holes, on the Kingston Range, at Cave Canyon, Garlic Springs, Newberry, and on Providence Mountain. Massive lodestone exhibiting strong polarity has come from a deposit 30 miles southeast of Daggett. San Francisco County: It is a constituent of the beach sands. San Luis Ohispo County: It is common at La Panza. Santa Barbara County: It is common in the beach sands at Point Sal. Santa Cruz County: Magnetite makes up 25 to 50 per cent of the stratified beach sands 2 miles southeast of Aptos, where an experi- mental plant has been operated for the production of sponge iron, Laizure (26). Shasta County: A large deposit of magnetite at Heroult, on con- tact between diabase and slate, was worked by electric smelter. Mag- netite occurs near Baird, with hematite at Iron Mountain, and at most of the copper mines. It is found in the sands at French Gulch, Red- ding, and Round Mountain. It occurs on contact between diabase and carboniferous limestone at Gray Rock and on the McCloud River. A large deposit of magnetite occurs between quartz diorite and lime- stone about 5 miles east of Pitt on the Sacramento Valley and Eastern Railroad. It occurs as a contact mineral with pyrrhotite and chalco- pyrite at the Black Diamond mine. Sierra County: Large beds of magnetite are reported in this county, W. P. Blake (66). Perfect octahedrons have come from Forest City. A massive deposit of magnetite occurs south of Lake Hawley in the Calaveras formation, and also southeast of Spencer Lakes. OXIDES 117 Siskiyou County: It is common in the black sands at Happy Camp, Seiad, Cecilville, Forks of the Salmon, Sawyers Bar, Scott River, Oro Fino, Castella, Shasta River, Beaver Creek, Henley, and Klamath River. Lodestone occurs near Weed. Tehama County: Titaniferous magnetite occurs in the Beegum district. Trinity County: It is found in the black sands at Trinity Center, Douglas City, Junction City, Carrville, Minersville, and along the Trinity River. Massive magnetite occurs at Douglas City, and on the northwest side of Chauckelulla Mountain, Tulare County: A massive deposit of magnetite occurs at New Pass, W. P. Blake (58). It is found massive near Three Rivers and on Greenhorn Mountain. Tuolumne County: It occurs in the black sand concentrates at all of the mines. Yulta County: It is common at Marysville, Brownsville, Straw- berry Valley, Indian Hill, Oregon House, Camptonville, and on the Yuba River. It occurs massive with hematite 4 miles from Clipper Mills. CHROMITE Oxide of chromium and iron, FeCr204. Isometric. In octahedrons. Generally massive ; fine granular to compact. Brittle. Metallic luster. Color black. Streak brown. H. = 5i. G. = 4.1 — 4.9. Infusible. Gives an emerald-^een bead of chromium with borax. Insoluble. In much of the chromite of the State magnesium replaces the iron, forming magnesian chromite. The mineral is often found as large boulder-like or irregular masses, and is abundant in the serpen- tine areas of the State. Diller (21). Its distribution and production have been described in detail in Bulletin No. 76 of the State Division of Mines. Alameda County: Pockets of massive chromite, sometimes coated with zaratite, occur at the Mendenhall mine and other mines about 16 miles southeast of Livermore, in the Cedar Mountain district. Kramm (10) has analyzed chromite from Cedar Mountain: CrsOs AhOa FeO MnO MgO CaO SiOa H:0 55.74 18.79 16.99 tr. 8.41 tr. none 0.09 = 100.02% Amador County: Chromite is found near Jackson; deposits occur near lone ; about 8 miles northeast of Carbondale ; 5 miles southwest of Plymouth, near "Willow Creek. Butte Comity: It is a constituent of the black sands at Magalia, OrovUle, Cherokee, Buchanan Hill, Lovelock, and Pentz. It occurs 118 MINERALS OF CATilPORNIA massive near Forbestowu. Deposits of eliromite occur about 1 mile southwest of Big Bar ; 1 mile east of Yankee Hill ; 5 miles southwest of Magalia; 1 mile north of Woodleaf; east of Brush Creek; near Twin Cedars, 6 miles east of Paradise; 2| miles northeast of Forbes- town. Small bodies of chromite occur at the Powell manganese mine, 1 mile north of Clipper Mills, and at Pentz. Calaveras Coiiniy: It occurs in the serpentine about 5 miles east of Valley Springs. It is found in the concentrates at Forest Gulch. Deposits of chromite occur near Copperopolis ; about 7 miles west of Angels Camp ; 4 miles west of Fostoria ; 5 miles southwest of Valley Springs ; 10 miles northeast of Angels Camp ; 14 miles east of Milton. Deposits of it occur on the Tower ranch, 9 miles east of Milton, and on the Wright ranch, in Salt Spring Valley, 10 miles northeast of Milton. Colusa County: It is found massive at Newville. It occurs near Stonyf ord ; near Wilbur Springs ; 1^ miles northwest of Cook Springs. Del Norte County: Chromite is found in the black sands of the Smith Kiver, on Gilbert Creek and at Crescent City. Good deposits of it occur on Rattlesnake Mountain, 20 miles east of Crescent City. Deposits of chromite occur in lenses 8 feet thick at French Hill, near Smith River. El Dorado County: Chromite occurs near Coloma and at Shingle Springs ; 3 miles northeast of Georgetown, near Latrobe ; 2 miles south of Georgetown ; in Marble Valley, near Clarksville. Analysis of chro- mite from the Donnelly deposit, 10 miles northeast of Folsom, gave: CvzOf. SiO- FeO AI2O3 MgO CaO Ign. 46.52 6.60 17.63 11.66 15.80 1.23 0.50r=99.94% Large deposits of granular masses of chromite occur in serpentine at Flagstaff Hill, 8 miles south of Auburn. Chromite occurs at the Pilli- ken Chrome mine, 10 miles northeast of Folsom. A large deposit of chromite occurs on the Williamson property, 6 miles east of Shingle Springs. Fresno County: Deposits of chromite occur in the southwestern part of the county in the Mount Diablo Range, and in the hills east of Fresno, from Letcher to Piedra. Deposits of it occur in Watt Valley, on Hog Mountain, and at Pine Flat. • Glenn County: Deposits of chromite occur near Millsaps ; at Bed- ford, 5 miles east of Chrome; about 6 miles east of Newville; near Orland. Humholdt County: It is a constituent of the beach sands at Gold Bluff, and of the concentrates at Orleans and Trinidad. It occurs OXIDES 119 massive near Blocksburg. Small masses o£ chromite occur on Horse Mountain; and in the serpentine east of Orleans. Chromite is found on the Hoopa Valley Indian Reservation. Kei^n County: Small deposits of chromite occur on the Kern River. Kings County: Masses of chromite have been found near Park- Reld. Lake Coinihj: Pockets of chromite occur on the Pardee i-aiich, near Middletown. Masses of it have been found in the mountains near Adams and Siegler Springs. A large body of chromite occurs 1^ miles northeast of ITullville. Chromite is reported from Jerusalem ^^^lley. Los Angeles County: Chromite has been reported near Acton ; also near Harold Station. Madera County: It is found near Madera in masses coated with zaratite. Marin County: It occurs on the Mailliard ranch near San Geron- imo, about 8 miles northwest of San Rafael. Mariposa County: A deposit of chromite occurs near Pleasant Valley Station. Mendocino County: It is found coated with green uvarovite garnet about 11 miles north of Willits. It has been found at several points in the hills west of the Russian River. It occurs about Ih miles west of TTkiah, on Red Mountain, and in Potter Valley. Monterey Coiivfj/: Chromite is common in small masses in the serpentine of this county, and specimens have been analyzed, Gold- smith (73a). CrsOs AhOa FeeOa IMsO CaO SiO- 52.12 2.18 15.24 12.29 5.65 12.12 = 99.60% G. = 4.1647. Masses of chromite occur about 3 miles east of Parkfield on Table ]\Iountain. Napa County: Small bodies of chromite have been found near Knoxville. It occurs 8 miles northwest of Monticello. Nevada Cainify: Fine octahedrons occur in llio serpentine ne;ir Indian Springs. Chromite is fouiiresent in every county in some form, but only a few of its occurrences are cited. Alameda County: Earthy limonite mixed with hematite is com- mon as a 'gossan' capping of the pyrite deposit at Leona Heights. 9—51440 130 MINERALS OF CALIFORNIA Amador County: It is found in concretions and earthy masses at Pine Grove ; with liematite and magnetite at Volcano. Butte County: Thick masses of limonite occurred at the Mon- arch mine; cnbes at Red Hill and at Magalia. Calaveras County: It forms tlie capi)ing of a hill about 1^ miles north of Murphy. The Detert limonite deposit near Valley Springs was formerly worked, Harder (10b). Massive and earthy limonite occurs at the Eureka mine, near Valley Springs. Yellow and red ocherous limonite occurs at Campo Seco. A deposit occurs on Bonanza Creek, 7 miles southeast of Mokelumne Hill. Massive limonite has come from the Dieffenbach ranch, 25 miles northeast of Valley Spring. Colusa County: Yellow ocherous limonite occurs in a large out- crop 4^ miles west of Stonyford. Limonite suitable for mineral paint occurs 4 miles south of Lodoga. El Dorado County: Massive limonite occurs near Diamond Springs. Inyo County: Pseudomorphs after long prisms of stibnite have been found at the Cerro Gordo mine. Lake County: Yellow and brown limonite suitable for paint occur 2 miles north of Hough Springs. Massive specimens of limonite have come from the hills near Glenbrook. Mariposa County: Fine large cubes of limonite have come from the Chowchilla Valley. It occurs as 'gossan' at Burns Creek, W. P. Blake (58). Napa County: A deposit of limonite occurs 1| miles east of Calistoga. Placer County: Massive limonite occurs at the Clipper Gap mine, and at Gold Run. Plumas County: It occurs massive in Lights Canyon and at Nelson Point. Red and yellow ocherous limonite occurs near Quincy. Riverside County: Yellow and brown limonite is common in the pisolitic cavities formed by the brucite, at Crestmore, Eakle (17). Massive limonite with .some goethite occurs on the Eagle ]\Iountains. Sacramento County: Yellow ocherous limonite occurs at Michi- gan Bar. San Luis Ohispo County: Brown banded masses of limonite occurring with hematite interbedded with Franciscan shales and sand- stones have come from the Prefumo ranch in the Los Osos Mountains, Harder (10b). Dark-brown massive limonite is found at the Har- rington mine, 4 miles southwest of San Luis Obispo. OXIDES 131 Shasta County: It is common as cappings of the pyrite deposits of the county. Psendomorphs after liedenbergite have been found at YdaliH^m. ITiglily ii-idoscoiit specimoiis have come from Copper City. Excellent l)n)uze-eolor<>(l stalactitos occurred at the Lost Confidence mine, Iron Mountain. Sonoina County: Yellow ochorous limonite occurs at the Occi- dental mine and on the Lancaster ranch, east of Fisk's Mills. Stanislaus County: A deposit of yellow ocherous limouito used for paint occurs at Knights Ferry on the Stanislaus River. Tulare CoiDily: It is common in the Mineral King district. Tuohimne County: Pure earthy limonite occurs at the Volunteer mine, on Five Mile Creek, 7 miles east of Columbia. Yolo Cmmty: It is found in the sands at Capay. BAUXITE llydrous oxide of aluniimim, A IjOs. (iHaO. Massive, earthy, pisolitic. Color wliite, yellow, red, or brown. H. = li. G.r=:2.55. Infusible and insoluble. Moistened by a few drops of cobalt nitrate and intensely heated, the powder assumes a sky-blue color. Fused with sodium carbonate and the mass dissolved in hydrochloric acid, leaves no silica residue. Ammonia precipitates flocculent aluminum hydroxide from the solution. The absence of silica differentiates it from clay. « Bauxite closely resembles clay and is only distinguished at sight from clay by its characteristic pea-shaped, or pisolitic structure. Riverside County: Red and gray pisolitic bauxite occurs in Sec. 26, T. 4 S., R. 6 W., S. B. M., Richard (22). BRUCITE Magnesium hydroxide, Mg(OH)2. Hexagonal-rhombohedral. Crystals usually broad tabular. Foliated plates and fibrous masses. Cleavag'e perfect basal. Sectile. Pearly luster. Color white, gray, pink, blue, green. H. = 2J. G. — 2.38 — 2.4. B. B. infusible. Yields a small amount of water in a closed tube. Easily soluble in dilute hydrochloric acid, and magnesia is precipitated by sodium phosphate. Gives a pink color characteristic of magnesia when intensely heated with cobalt nitrate. Brucite occurs as thin veins in serpentine, but very little has been observed in the State as an alteration of serpentine. It also occurs as a metamor])hic mineral in crystalline magnesian limestone. Riverside County: Brucite is abundant in small globular masses in the white crystalline limestone at Crestmore, formed probably as a hydration product of periclase. Analysis by Eakle (17) : MgO Fe20s H:0 67.48 0.55 31.73 = 99.76% San Francisco County: Brucite was found MJtli xonotlite in serpentine in cuts made by the Western Pacific Railroad on Army Street, San Francisco. 132 MINERALS OF OAIJFORNIA PYROCHROITE Manganese hydroxide, Mn(OH)2. Hexagonal-rhombohedral. In hexagonal plates. Perfect basal cleavage. Pearly luster. Color white, but alters to brown and black. H. z=:2i. G. r=3.26. B. B. infusible. Heated in a closed tube, it becomes green, then black, and yields water. Gives green bead with sodium carbonate. Santa Clara County: Pyrochroite was a prominent constituent of a boulder of manganese ore near Alum Rock Park, 5 miles east of San Jose, Rogers (19a). PSILOMELANE A manganese oxide, usually impure. Massive, botryoidal, stalactitic. Prominent conchoidal fracture. Lus- ter submetallic, dull. Color black. Streak brownish-black. H. := 5 — 7. G.=r 3.3 — 4.7. Yields the manganese reactions as given under hausmannite, as well as water in a closed tube, and tests for impurities, especially barium. Psilomelane is the chief ore of manganese in the State. It is usually associated with manganite or pyrolusite, and often with limo- nite. The characteristic occurrence of the more important deposits is in seams and irregular masses in jasper. Wad is a soft, impure variety. Asholite is a wad containing cobalt. A detailed report on the manganese deposits of California has been issued by the State Division of Mines as Bulletin No. 76. Alameda County: Psilomelane is the chief mineral in the man- ganese deposits near Corral Hollow and the Arroyo Mocho. Amador County: Deposits of psilomelane mixed with pyrolusite occur 1| miles south of Volcano; 4 miles east of Pine Grove; and about a half mile southeast of Defender. Butte County: Psilomelane occurs in several localities near Clip- per Mills. Calaveras County: Dei)osits of psilomelane occur 2 miles north- east of San Andreas and 6 miles southeast of Valley Spriugs. Psilome- lane with pyrolusite occurs 3 miles northeast of Milton. Colusa County: Psilomelane occurs in small amounts on the eastern slope of St. Johns Mountain, west of Stonyford. Co7itra Costa Count)/: Psilomelane was formerh^ mined on Red Rock in San Francisco Bay. Fresno County: Psilomelane occurs on Pine Flat, near Piedra. Glenn County: It occurred with pyrolusite at the Black Diamond and Rattlesnake mines, about 30 miles southwest of Fruto. Some siliceous psilomelane is reported from Millsaps. OXIDES 133 Hutnholdt County: Tt occurs with pyrolusite in good ma.ssive ore on the Porter ranch, Fort Baker. Imperial County: Psilonielane deposits have been reported in the Chocolate IMountains. Inyo County: It is found at tlie southeast end of the Panamint Range, 25 miles south of Bennett 's wells on the Death Valley Slope. Kern County: Wad has been fouiul as a jjseudomoiph aftci- cal- cite at the Echo mine near IMojave, Kogers (10a). Lake County: Small amounts of good manganese ore come from Glenbrook. Psilomelane occurs on the Phillips ranch about 1| miles south of Laurel Dell, and on Dry Creek about 3 miles west of Middle- town. A large deposit of it occurs about 10 milies north of Upper Lake on the southwestern slope of the Horse Mountains. The man- ganese ore of the Smythe manganese prospect is mainly psilomelane with some pyrolusite. Los Angeles County: Asbolite occurred in the K mine, San Gabriel Canyon. Deposits of siliceous psilomelane occur about 5 miles west of Palmdale. Marin County: Small streaks and pockets of psilomelane occur near Sausalito and Fort Baker. Psilomelane is found in masses on the Mailliard ranch, about 8 miles northwest of San Rafael. Mariposa County: Small masses of psilomelane occur in Hunters Valley. Mendocino County: Large deposits of psilomelane occur in Potter Valley. It is reported to have been found in large amounts on Pieta Creek, near Pieta. Deposits of psilomelane occur at the Cleveland mine, 3 miles east of Calpella, and at the Independent mine, 14 miles east of "Willits. It occurs in the hills east of the Middle Fork of Eel River. Psilomelane with rhodochrosite occurs on Mount Sanhedrin. Psilomelane in jasper is found at the Thomas and Wild Devil mines, about 6 miles northeast of Redwood Station. Merced County: Manganese ore deposits occur about 26 miles east of Tres Pinos. Monterey County: It occurs about 3 miles north of the mouth of San Carpojaro Creek and 1 mile inland; also in the Chalone district, near Soledad. Napa County: A dei)Osit of psilomelane occurs 5 miles west of Oakville, and another 6 miles northeast of St. Helena. Small amounts of manganese nunerals occur on Mount St. Helena : on ]\Ioore Creek, and 3 miles west of Oakville. 134 MINERALS OF CALIFORNIA Nevada County: Wad occurs near the North Banner mine. Psi- lomelane occurs near the west bank of the Bear River, 7 miles from Colfax. A large body of psilomelane occurs in the Limekiln district. Placer County: Masses of it are found at IMichigan Bluff. Depos- its of psilomelane occur about nine miles north of Colfax, near Yankee Jim. Plumas County: Large masses of it occur on Mumford Hill. Psi- lomelane, manganite, and rhodonite occur in the Diadem and Penrose lodes, near Edmanton, in the Meadow Valley district. Deposits of it occur near Crescent Mills. Riverside County: Deposits of psilomelane occur in the McCoy Mountains about 12 miles northwest of Mineral Station. Psilomelane occurs about 7 miles southwest of Perris intetbedded with jasper. Black massive psilomelane occurs in the Palen Mountains, about 22 miles northwest of Mineral. It occurs about 6 miles northeast of Elsinore with rhodonite. It is found at the base of the Santa Maria Mountains, Hud about 8 miles northwest of Palo Verde. Pine specimens have come from Winchester. ^ort. (lood crystals have come from the Bodie district. A mass of white marble occurs in a canyon southeast of Topaz. Laj'ers of inter- laced calcite crystals found about Mono Lake have been called thinolite by E. S. Dana (84). Iceland spar has been found in limestone in the upper Convict basin near Mammotli Tjakes, Mayo (34). . Monterey County: Large ])ert'ect crystals occur near Soledad. A deposit of limestone occurs near Natividad, 9^ miles from Salinas. Sand-calcite crystals have been described from the Cholame Hills, Sec. 14, T. 23 S., R. 13 E., :\I. D. M., by Rogers and Reed (26). Napa County: Onyx marble has come from near Knoxville. Nevada County: Calcite is common in the Grass Valley and Nevada City mines. Pine scalenohedrons have come from the Pitts- burg mine. It is found northeast of Nevada City on the banks of the South Fork of Yuba River. Calcite crystals occur with kammererite at the Red Ledge mine, near Washington. Orange County: Greenish and white marbles occur in Cool Can- yon on the west side of Mount Downey, Santa Ana Range. Placer County: Calcite is one of the minerals of the Ophir dis- trict, Lindgren (94). White marble occurs near Hotaling. A fine black marble with occasional white veinlets occurs near Colfax. Plumas County: Large divergent masses of calcite occur in the Genessee Valley. Marble occurs on the sides of the Middle Fork of Feather River. Riverside County: Blue calcite occurs at Crestmore, Eakle (17). CARBONATES 139 San Benito County: Calcite is found in the rocks adjoining the benitoite veins near the headwaters of the San Benito River, Louderback (09). San Bernardino County: A large deposit of beantiful variegated marble occurs at the Gem marble quarries in the Silver JNIountain dis- trict about 5 miles south of Oro Grande. Gray limestone is quarried for cement on Slover Mountain, near Colton. Large calcite cleavage masses with black carbonaceous matter arranged zonally occur 6 miles northwest of Ludlow. A large deposit of white, pink, and blue calcite occurs near Baxter. Iceland spar occurs in the Cave Canyon district, near Yermo. San Diego County: White and gray banded marble occurs on Los Peiiasquitas Creek. Dark-gray marble occurs near Jacumba; a large bed of white speckled marble occurs 4^ miles northeast of Dos Cabezas Springs. San Francisco County: Schaller (11) has described calcite crys- tals from Fort Point_showiug the forms (1011), (0112), (2131), (5382), (2358), (416.20.3), and (1.6.7.13). San Luis Ohispo County: Beautiful onyx marble with moss-like inclusions of greenish chlorite which impart a landscape effect to translucent thin slabs, occurs at tlie Kessler deposit, about 17 miles northeast of Arroyo Grande. San Mateo County: Crystals have come from near San Pedro. Calcite occurs as crystalline veins in limestone at jMontara. Santa Clara County: Yellow, white, and brown marble occurs 5 miles southeast of New Almaden. Santa Cruz County: In the area between Santa Cruz, Felton, and Davenport there are numerous quarries in coarsely crystalline limestone, Eckel (33). Calcite crystals showing the forms, (0112), (1011), and (4041) have been found in the Vicente Creek tunnel near Davenport. Shasta County: liarge stalactites and tubular aggregates of calcite occur in Potters ('ave near Baird, Eakle (07). Siskiyou County: Large depo.sits of white and variegated mar- ble occur on Marble Mountain. Solano County: Onyx marble and massive limestone occur near Tolenas. A brown banded onyx marble occurred near Suisun. Sonomu County: Calcite occurs in geodes near Petaluma. There is a deposit of limestone on the Black ranch on Inttle Sulphur Creek, 6 miles north of Geyserville whieli has been mined commercially. W. W. Bradley (16). 140 MINERALS OF CALIFORNIA Trinity County: Calcite occurs with garnet and epidote at Red Mountain. Tulare County: Dark-gray marble occurs on the James ranch, 8 miles southeast of Porterville. Tuolumne County: White and blue-veined marbles occur in an extensive deposit on the Stanislaus River a few miles north of Colum- bia. Fine crystals with the forms (1010), (OlTl), and (3121) were found at the Keltz mine. Large stalactites were found at the Crystal Palace Cave near Columbia. White granular calcite showing bright .scarlet triboluminescence has been found near Columbia, Melhase (35). Yuba County.: Marble occurs on the north and south sides of the Yuba River, and on Oregon Creek. MAGNESITE Magnesium carbonate, MgCO;;. Hexagonal -rhombohedral ; scalenohedral. Crystals are rare. Gen- erally compact massive ; sometimes earthy. Cleavage perfect rhombohedral. The compact massive variety shows no cleavage, but shows a flat con- choidal fracture. Brittle. Luster vitreous, sometimes silky. Color snow- white to brown. H. = 31 — 4J. G. r=3.0 — 3.12. Cold dilute hydrochloric acid has little effect on magnesite, but when heated causes it to effervesce freely. The solution, when treated by ammonia, amonium oxalate, and sodium phosphate, will give an important precipitate only when the last reagent is used. Magnesite moistened with cobalt nitrate and intensely heated, will turn pink. Magnesite is widespread in California because of the great areas of serpentine, of which it is an alteration product. The serpentine is commonly intersected by A^eins and i")atclies of snow-white to light- buff magnesite. Some of these veins are commercially important. The main deposits lie in the serpentine belts of the Coast Ranges, but deposits also occur in serpentines in the foothills of the Sierra Nevada and elsewhere. The mineral is mostly in cryptocrystalline masses with prominent conchoidal fracture, and the siliceous varie- ties are very hard. The magnesite deposits of California have been described in Bulletin No. 79 of the State Division of Mines. Alameda County: Small veins of magnesite occur in the serpen- tine on Cedar Mountain, about 22 miles southeast of Livermore. Stray boulders have been found on Hoyle's ranch, 11 miles southeast of Liv- ermore. Calaveras Cou7ity: Veins of magnesite occur near San Andreas. Fresno County: A very pure magnesite occurs in veins on Kings River at Piedra, 9 miles east of Sanger. Deposits showing peculiar surface jointage cracks occur in Watt Valley. Kern County: Some veins of magnesite were found near Walkers Pass, east of Bakersfield. A sedimentary bedded deposit of magne- CARBONATES 141 site interstratitied with clay and clay shales occurs about three-fourths of a mile northeast of Bissell Station, 11 miles east of ]\Iojave, Gale (14d). The magnesite from Bissell was analyzed by Fairchild, Clarke (15). SiOa MgO CaO CO2 (Al,Fe)203 6.03 42.78 1.56 45.78 1.40=97.55% 4.75 44.20 tr. 47.32 0.76 = 97.03% Kings County: Magnesite occurs in tlie southwest corner of the county, near Parkfield, Bradley (25). Los Angeles County: A small deposit of magnesite occurs in ser- pentine on a branch of San Francisquito Canyon. Mendocino County: Pure white veins of magnesite occur on the liixon ranch, about 12 miles north of Cloverdale. Analysis by Peters, Hess (08a). Si02 AI2O3 FeaOa CaO MgO CO2 0.41 0.28 0.12 0.03 47.16 51.88 r=r 99.88% A deposit of it also occurs 15 miles northwest of Cloverdale. Modoc. County: Specimens of magnesite liave come from near Adin. Monterey County: Magnesite was found 3 miles east of Park- field. Napa County: A large number of veins of magnesite occur in the serpentine of the count}'. It is prominent at the Bartlett and Stanley mine in Chiles Valley, about 10 miles north of Rutherford. Analyzed by: 1, Bates. 2 and 3, Hanks, Hess (08a). SiOs AI2O3 Fe203 CaO MgO CO2 H2O 1. 2.15 1.22 1.16 5.28 41.01 48.72 ___= 99.54% 2 1.81 0.08 tr. 46.55 51.25 0.^2 — 100.01% 3. 6. 68 15.10 ."{7.2;^ 40.9 8 ___= 99.99% Veins of it Jilso occiir (in ll'.c (>;is1 side of Pope Valley, in Soda Creek Canyon, and in the serpentine of Berryessa Valley. Large veins of it occur at the AYln'te Rock mine in Popo Valley. Nevada County: Narrow veins of magnesite occur in the serpen- tine at Nevada City. Placer County: Veins of magnesite occur 1 mile east of Damas- cus and near Michigan P>]uff ; also at Gold Run. Deposits of it occur about 5 miles northeast of Iowa Hill, and near Towle. Analysis of the Damascus material by Wells, Gale (14d). Si02(Al,Fe)203 CaO MgO COi H2O 0.2 none 47.3 51.6 0.6 = 99.7% 142 MINERALS OF CALIFORNIA Riverside County: Veins of magnesite are found in a hill of serpentine ahoiit '^l miles sontli of AVineliester. Analysis liy Bates, Hess (08a). Si02 AI2O3 V<-2n,. CaO MgO <'(), 4.73 0.12 0.08 0.43 44.77 ID. 40 — ItlL. <:.;'.% tSan Benito County: Large deposils (»!' magnesite oeeur on the western slope of Sampson Peak, 3 miles southwest of New Idria. Some of the magnesite at the Sampson mine is coated with dolomite. Analy- sis by Hicks, Gale (14d). SiO:; FeOs CaO MgO CO2 0.81 0.52 1.04 46.67 50.60 = 99.64% San Bernardino County: Magnesite occurs at the Quaker group of claims in the Providence Mountains, 12 miles southeast of Cima; also near Needles. A deposit of bedded magnesite occurs on the south side of Cave Canyon of the Mojave River, 1^ miles southeast of Afton, 3| miles west of Baxter; Hewett, Callaghan, Moore, Nolan, Ruby, and Schaller (36). 8cin Francisco County: Small veins of magnesite occur in the serpentine at Fort Point and in the Potrero district in San Francisco. San Luis Obispo County: Small veins of magnesite occur on tile Kiser ranch about 9 miles northwest of Cambria. 8a7ita Barbara County: Deposits of magnesite occur about 12 miles southeast of Los Olivos, near the base of the San Rafael Mountains. Santa Clara County: Large veins of magnesite exist in Red Mountain, 32 miles southeast of Livermore. An analysis by Peters, Hess (08a), of pure magnesite from the Alameda claim gave: SiOa AI2O3 Fe203 CaO MgO CO2 0.73. 0.14 0.21 0.40 46.61 51.52=99.61% Magnesite from Red Mountain was analyzed by Wells (37). The Western Magnesite Development Company has been an important producer at Red Mountain. Si02 Al203Fe203 CaO MgO CO2 1120 0.03 0.07 0.85 46.70 51.94 0.29 r:^ 99.88% All analysis by Peters, Hess (08a), of buff-colored siliceous mag- nesite from the ('ochrane ranch, about 3| miles from Morgan Hill Station, gave : SiOa AI2O3 Fe203 CaO MgO CO2 49.85 3.45 9il8 0.48 21.53 23.96 = 99.45% Analysis by Peters, Hess (08a), of magnesite from veins in ser- pentine at Burnetts ranch, 3 miles northeast of Coyote, gave: Si02 AbOs Fe203 CaO MgO CO2 0.30 0.16 0.38 1.34 45.86 51.80 = 99.84% It occurred at the Madrone Magnesite mine, near Madrone. Euhe- dral magnesite crystals up to 8_mm in length showing the forms (2131), (0001), (1120), and (0221) were described by Rogers (23) CARBONATES 143 from the San Juan quicksilver mine, 5 miles south of San Jose. An analysis by K. S. Boynton gave: MgO raO VeO COn IIdO iiisiol. 46.26 1.74 1.27 50. 4S nil nil = 90.75% Sonoma County: Tlierc arc numerous veins of magnesite in the serpentine of the county. Analyses : 1. Veins 4 miles north of Clover- dale, called the Creon deposit, occur in serpentine dikes; 2. Eekert ranch deposit 2 miles east of Cloverdale; 3. Uillam Creek deposit on steep west side of creek, about 7 miles northwest of Guerneville; 4. lied Slide deposit in valley of East Austin Creek, about 8^ miles north of Gazadero. Analyses by Peters, Hess (08a). Si02 AI2O3 Fe203 CaO MgO CO2 1. 1.60 0.25 1.09 1.04 45.20 50.43 = 99.61% 2. {0.51 1.98 0.16 0.59 45.84 50.80 = 99.88% 10.23 0.04 0.20 0.19 46.88 51.57 =99.11% 3. 3.51 1.10 0.80 1.46 43.65 49.16=99.68% 4. 7.67 0.26 0.29 0.0 4 43.42 48.08 = 99.76% A ik'posit of luagncsile occurs (i miles north oL* llealdsburg. Stanislau>i County: The Bahl Eagle and Quinto claims on Quiiito Creek in See. 82, T. 8 S., K. 7 K., M. D. M., near Gustine, have been leading producers of magnesite in recent years. The Smith mine near Patterson has also produced magnesite. Several deposits have been worked on the east side of Red Mountain near the Santa Clara County line. Tulare County: A large amount of magnesite has been mined from veins on hills about 4 miles northeast of Porterville. Analyses: 1. From the Deer Creek deposit, about 8 miles southeast of Porterville, analyzed by Bates; 2. On the hills about 4 miles northeast of Porter- ville, analyzed by (a) Peters, (b) Hanks; 3. From veins in Sees. 30 and 31, T. 22 S., R. 29 E., M. D. M., on the South Fork of Tule River, analyzed by Peters, Hess (OSa). SiO.- AIjOs Fei'Oa raO MgO COi- H2O 1. 0.31 0.11 0.08 0.24 47.22 51.64 — _ = 99.607o 9 (a) 2.28 0.03 0.26 1.32 45.17 50.74 -__ = 99.80% 2- (b) 0.90 0.49 1.49 44.39 50.06 2.57 = 99.90% . n.so 0.42 0.20 1.02 4. '■..9 4 5i.no ___ = 99.68% SinaJl veins of it also occur in Hound Valley, about 4 miles east of Lindsay; on Rocky Hill, about 2 miles east of Exeter, with califor- nite ; near Xaranjo with white opal ; and near Auckland. A deposit of magnesite at the Alpha claim 3| miles east of Strathmore is of high grade. Tuolumne Count}/: There are several deposits of magnesite in T. 1 S., R. 14 E., M. D. M., near Chinese Camp, from at least two of which commercial shipments have been made, Bradley (25). 144 MINERALS OF CALIFORNIA SIDERITE Ferrous carbonate, FeCOs. Hexagonal-rliombohedral ; scalenohedral. Crystals with curved faces ; also massive, granular. Cleavage perfect rhombohedral. Brittle. Vitreous to pearly luster. Color ash-gray to dark-brown. Streak white. U.=z2h — 4. G. — 3.8. Becomes magnetic on heating. Dissolves with brisk effervescence in hot hydrochloric acid. 8iderite is occasionally found in the mining regions in drusy crystallizations associated with pyrite and galena, but does not appear to be common in California. Calaveras County: Siderite occurs with albite, calcite, and quartz at Campo Seco. El Dorado County: It occurs with calcite and albite at the Red Hill mine, Kelsey mining district. Imperial County: It occurs with specular hematite in quartz, near Bard. Inyo County: Masses of siderite have been found at the Custer mine, (Joso district. Siderite occurs with pj^rite, pyrrhotite, and chal- copyrite in a quartz vein at the Curran mine, half a mile northeast of Panamint, Sampson (32). Los Angeles County: Massive siderite occurs in the Tujunga Canyon. Mariposa Courity: It was found with calcite at Devils Gulch. Mono County: It occurs with limonite and hematite near Benton. Plumas County: It was found with the copper minerals of the Engels mine. Santa Clara County: A deposit of siderite occurs on the Weber ranch, in Los Animns Hills, 3 miles northeast of IMadrone ; large masses on Red Mountain ; on Coyote Creek 4^- miles east of JMadrone ; small irregular bunches 3 miles east of Coyote on the western slope of Metcalf Canyon. Shasta Couniij: According to B"'airbanks (93) siderite occurs in large masses in this county east of the Stilhvater region. RHODOCHROSITE Manganese carbonate, MnCOa. Hexagonal-rhonibohedral ; scalenfihedral. Small crystals and massive. Cleavage perfect rhombohedral. Brittle. Vitreous luster. Color rose-red or gray. Streak white. H. z=3i — 4J. G. nz 3.45 — 3.60. Its effervescense with acid, and wine or amethystine bead with borax serve to distinguish it. Alameda County: Rhodochrosite, both gray and pink, occurs commonly in the psilomelane mines of the Tesla district, southeast of Livermore. It occurs with psilomelane on the Arroyo Mocho road, CARBONATES 145 southeast of Livermore. It Avas i'ouiid at tiie Mercliaiit juine, 9 miles southeast of Livermore, Bradley, et al (18). Alpine County: Pink crystals of rliodochrosite were found in the Colorado mine No. 2, Monitor district, Irelan (87). Amador County: It occurs with psilomelane 4 miles east of Pine Grove. Butte County: It was found on the North Fork of Feather River. Madera County: It occurs near Coarse Gold. Mariposa County: Gray and red rliodochrosite is associated with psilomelane in Indian Gulch, Mendocino County: It occurs in the Mount Sanhedrin group at Impassable Rock. Placer County: Small druses of rhodochrosite have been found in some of the mines of the county. San Bernardino Coioih/: It occurs at the New York mine near Manvel. It ha.s been reported as a vein mineral in quartz at the Sagamore mine, New York Mountains. Sail Joaquin County: It occurs in the Ladd mine of Corral Hollow. Santa Clara County: Rliodochrosite occurred as pink crystals showing the steep negative rhombohedron (0221) with occasionally the unit rhombohedron (1011), in the manganese boulder near Alum Rock Park, 5 miles east of San Jose, Rogers (19a). Sonoma County: Massive gray rhodochrosite occurs with psi- lomelane at the Aho ])roperty fi miles west of Cazadero. Stanislaus Count y: It was found witli calcite and pyrolusite in the Buckeye Manganese mine. Hospital Creek. SMITHSONITE Zinc ciirbunate, ZnOOs. Hexagonal-rhombohedral ; scalenohedral. Drusy crystals, usually reniform, botryoidal or stalaclitic; often bone-like. Cleavage perfect rhom- bohedral. Brittle. Vitreous luster. Color white, grayish, blui-sh, greenish, brownish. Streak white. H. = 51- G. = 4.30 — 4.45. B. B. infusible. With sodium carbonate on charcoal, becomes yellow while hot and white when cold. Moistened with cobalt nitrate and intensely heated, assumes the yellowish-green color characteristic of zinc minerals, effervesces readily in hydrochloric acid. Smitlisonite is a secondary mineral often found in silver-lead dis- tricts. It is usually associated with galena, sphalerite, hemimorphite (calamine), and cerusite. 10—51440 146 MINERALS OF CALIFORNIA. Inyo County: Smillisonite was found witli cerusite at the Modoc mine, Cerro Gordo, Hanks (84). It was also present at the Iguacio mine with hemimorphite and willemite. An unusual stalactite form of smithsonitc occurs at (Vrro (lordo. It occurs with hemimorphite at Camp Burjiess. It was found in the limestone footwall of the Cerro Gordo mine. It occurred with cerusite and galena in limestone at the Redwing and Noonday mines, Resting Springs district. It was common at the Mineatta mine. It occurred with galena and cerusite in lime- stone at the Ophir mine. Yellow, cadmium-bearing smithsonite was obtained in the Cerro Gordo mine. Kern County: Smithsonite occurred in drusy veins at the Jewett mine on Cottonwood Creek. San Bernardino County: It occurred with hemimorphite at the Cuticura mine, near Daggett. It occurred with cerusite, anglesite, linarite, and galena in dolomite at the Ibex mine, Black Mountains, 6 miles north of Sai-atoga Springs. It was found at the Ophir mine, in the Slate Range. DOLOMITE Carbonate of calcium and magnesium, CaMg(C03)2. Hexagonal-rliombohedral ; rhomboiiedral. Crystals usually with curved faces ; also granular, coarse or fine. Cleavage perfect rhombohedral. Brittle. Vitreous luster. Color vi^hite, pink, green, brown, gray, black. H. = 3J — 4. G. r=2.8 — 2.9. Effervesces feebly in cold dilute acids. Best distinguished from calcite in the wet way. After removal of the calcium by its precipitation with ammonium oxalate, the magnesium is obtained from the filtered solu- tion by precipitating with sodium phosphate. Dolomite is a common mineral, but is not so abundant as calcite. Much of the limestone and marble af the State is dolomitic. Dolomite is commonly associated with serpentine and other magnesian rocks, in Avhich it is often found as white veins. Alameda Count!/: Dolomite occurs in the manganese district about 15 miles southeast of Livermore. Calaveras County: White crystals of dolomite occurred in the gold-bearing schist of Carson Hill. El Dorado County: A large vein of dolomite occurs at the Las- kin mine, half a mile east of Diamond Springs. Inyo County: The variegated and white marbles of the Inyo Mountains are dolomitic. Good crystals of dolomite were found in the San Felipe mine. A commercial body of dolomite occurs at the Bodg- ley quarry, 4 miles north of Keeler. Monterey County: It occurs at Natividad. A large deposit of dolomite occurs along the foothills, 6 miles east of Salinas. CARBONATES 147 Nevada Connty: Dolomite occurs as veins in the serpentine rocks at Nevada City. Orange County: A mass of dolomite with gypsum occurs in Gyp- sum Canj'on on the western slope of the Santa Ana Range. Plumrown color which, when reduced, becomes gray and cloudy. Effervesces in hot acid. Gives water in closed tube. Zaratite is always accom])aiiied by chromite, occurring as an incrustation on massive chi'omite. Most of the green coatings on the chromite of the State, however, consist of small uvarovite garnet crystals or green chlorite. Alameda County: Green coatings of zaratite occur on the chromite at the Mendenhall mine on Cedar Mountain. Madera County: It was found as a coating on chromite near Madera. Monterey County: It was found on the chromite in this county, W. P. Blake (66). San Benito County: Zaratite was found on chromite near Ilolli.s- ter and near Panoche. 160 MINERALS OF CALIFORNIA Shasta County: It was observed on the chromite at Castella. Siskiyou County: Green coatings of zaratite occur on the chromite near Callahan. BISMUTITE Basic bismuth carbonate, Bi2O3.CO2.H2O.? Incrusting fibrous, or earthy and pulverulent. Vitreous to dull luster. "White, green, yellow and gray. Streak greenish-gray. H. r= 4. G. = 7. Fused on charcoal with potassium iodide and sulphur, it gives a red coating. A small amount of water is obtained by heating in a closed tube. Effervesces in acid. Bismutite is of secondary origin, being derived chiefly by the alteration of bismuthinite and native bi.smiith. Fresno County: Bismutite occurred at the Second Sierra and Lot One mines, Kings River district. Inyo County: It was found at Big Pine Creek, Hanks (84) ; al^o at Antelope Springs, Deep Spi-ing Valley. Fibrous and crypto- crystalline specimens of bismutite have come from near Lone Pine. Los Angeles County: White earthy bismutite has been found in this county. Mono County: It was found at Oasis. San Bernardino County: It occurs as an alteration of bismuthinite at the United Tungsten Copper mine, Morongo district. ADDENDUM TO BORATES (see pp. 161 and 162) VEATCHITE ,, Hydrous calcium borate, Ca2B60ii.2HaO. Monoclinic. Fibrous veins. Cleavage perfect clinopinacoidal and imperfect basal. Vitreous luster. Colorless. H.-= 2. G. = 2.69. Fuses easily with intumescence. Yields water in closed tube. Los Angeles County: Veatchite occurs in small amount with how- lite and colemanite at the old colemanite mine at Lang. It was named and described, with analysis by F. A. Gonyer, by Switzer (38). CaO B2O3 H2O Insol. . ; 31.08 59.03 9.50 0.62 100.23% BORATES 161 BORATES Ludwigite Vonsenite Camsellite Howlite Bakerite Veatchite Coleraanite Meyerhofferite Inyoite Priceite Kernite LUDWIGITE Tincalconite Borax Probertite Ulexite Hydroboracite Teepleite Magnesium and iron borate, 3MgO.B203.PeO,Fe203. Orthorhombic. Small fibrous masses. Silky luster. Color blackish- green to black. H. r=5. G. = 3.91 — 4.02. Fusible into a magnetic mass. Soluble in hydrochloric and sulphuric acids, but insoluble in nitric acid. Yellow turmeric paper dipped into the hydrochloric acid solution, turns red when dried. Magnesia can be pre- cipitated by sodium phosphate after the boron and iron have been removed. El Dorado County: Scaly masses of black . ludwigite, associated with calcite, epidote, molybdenite, and chalcopyrite occur at the old Cosumnes copper mine, near Fairplay, Rogers (12). VONSENITE Iron and magnesium borate, 3(Fe,Mg)O.B203FeO.Fe203. Orthorhombic. Imperfect crystals and granular masses. Very brittle. Brilliant metallic luster. Color black. Streak brownish-black. Perfectly opaque and non-magnetic. H. rr: 5. G. r=: 4.21. Fuses easily to a black magnetic mass and gives green flame of boron. Soluble in hydrochloric and sulphuric acids, but unattacked by nitric acid. Riverside County: Vonsenite was discovered by j\I. Vonsen in the old city quarrj^ at Riverside and described and named by Eakle (20). Forms on the imperfect crystals are: (010), (110), (210), (140), and (160). The analysis gave : FeO MgO B2O3 Fe^Os 39.73 10.71 14.12 34.82 = 99.40% CAMSELLITE Hydrous magnesium borate, 2AIgO.B2O3.H2O. Orthorhombic? Fibrous. White. H. < 3. G. =2.60. Readily fusible. Soluble in acids. Marin County: Camsellite occurs as impregnations and coatings on serpentine near Stinson Beach. An analysis by Eakle (25a) gave: MgO FeO B-O.". SiOc H-O 46.07 2.46 33.34- 7.16 10.94 = 99. 97%. which leads to the formula 2(MgO, FeO). (B,0,.SiOo)H,0. Schaller (28a) considers camsellite to be identical witli szaibelyite, 2Mg-,B.,0ii. srijO. 11—51440 162 MINERALS OF CALIFORNIA HOWLITE Hydrous calcium silico-borate, HGCa2B5S10]i. Monoclinlc. Round nodules, massive, chalky. Dull luster. Color white. H. = 1 — 3i. G. = 2.5. Fuses easily and colors the flame green. Easily soluble and precipi- tates silica. Calcium is precipitated with ammonium oxalate from a weak hydrochloric acid solution. Yields water in a closed tube. Gives the boron reaction with turmeric paper. Howlite is au associate of the otlier borates, but owiug to the silica pre.sent it is not utilized, although it contains a large amount of boric oxide. It has been mistaken for pandermite at several borate localities in California. Inyo County: White scaly masses of howlite occur in veins in Gov^er Gulch near Ryan. Los Angeles County: Large masses of compact white howlite are common in the colemanite deposit near Lang. It was described and analyzed by E aide (11). B-Os CaO Si02 H2O 45.56 28.26 14.81 11.37 r= 100% G. = 2.531. 8an Bernardino County: Large masses of howlite are associated with bakerite and ulexite in the Mojave desert, 16 miles northeast of Daggett, Giles (03). Analysis No. 1 is of soft scaly, and No. 2 of hard rock-like material, made by Giles. Analysis No. 3 is of soft white material, made by Wm. Lawson. B^On CaO SiO- H2O MgONa20 1. 44. 3S 28.45 15.50 11.58 0.09 2. 43.78 28.44 15.33 11.39 1.06 3. 44.32 29.22 15.31 11.44 ___=r 100.29% BAKERITE llydr.ui.s calcium silico-borate, 8CH().r.Ba03.6SiO::.6H2n. Amorphou.s. Mas.sive. <'(il(i|- wliilc In l':i iul Krccn. H. r~r 4i. G. = 2.7 — 2.9. Reactions the same as fur howlite. Inyo County: Bakerite occurs in Death Valley at the entrance to Corkscrew Canyon. San Bernardino County: Bakerite was found in the Mojave Desert, 16 miles northeast of Daggett, associated with howlite and ulexite. It was described and named by Giles (03). B-jOa V^^hite 27.74 Faint-green 26.85 VEATCHITE (see p. 160) COLEMANITE Hydrous calcium borate. Ca^BoOn.BHiO. • Monoclinic. Crystals usually short prismatic. Massive, granular and compact. Cleavage perfect clinopinacoidal. Vitreous to adamantine luster. Colorlops, white, yellowish-white, gray. H. = 4 — 4J. G. ^ 2.42. Decrepitates violently when touched with hot flame, but finally fuses to a clear glass. Powder on platinum wire, moistened with sulphuric acid, CaO Si02 H2O Al203Fe203 34.88 28.45 8.30 0.63 35.22 28.05 8.66 0.22 BORATES 163 will give a momentary green flame of boron mixed witli reddish flame of calcium. Yields water in a closed tube. Soluble in hot hydrocliloric acid with separation of boric acid on cooling. Inyo County: Colemanite was discovered in the Deatli Valley region where immense deposits of it occur along Furnace Creek in the Amargosa Range, and near Ryan, Gale (12), Foshag (24). Cole- manite was first described by Hanks (83), with analysis No. 1 by rhomjis Price. Analyses 2, 3 and 4 by Wliitfiold (87). m B:iO:! CaO Al-.():i Fe^'Oa MgO SiO- Hl-O 1. (48.12) 28.43 0.60 0.65 22.20 2. 50.70 27.31 0.10 21.87= 99.98% 3. 49. 5G 27.36 0.25 0.44 22.66 = 100.27% 4. 49.62 27.40 0.26 0.47 22.70 = 100.45% Some colemanite crystals from the Biddy JMcCarthj- mine were shown by Rogers (19) to be pseudomorphs after inyoite. The forms occurring were: (001), (110), (010), and (111). Tabular parallel to base. The ciystals were formed by dehydration of inyoite. Important deposits of colemanite witli idcxite occur in clay shale near Shoshone, Noble (26). Keni County: Colemanite occurs Avith kernite and borax in the Kramer district, Schaller (30). Los Angeles County: An important and extensive deposit of colemanite which Eakle (11) described as a variety, and called 'neo- colemanite,' occurs near Lang. Hutchinson (12) shows it to be identi- cal with colemanite. It occurs as thin and thick seams, almost verti- cal, and has considerable howlite associated with it. The colemanite has been described and analyzed by Eakle (11). Forms: (001), (010), (100), (210), (110), (230), (Oil), (021), (201), (301), (241), (231), (221), (661), (221). (^23), (211), and (263). B2O3 CaO 1 \>0 49.45 27.76 22.48 = 99.69% G. = 2.423 Riverside County: Colemanite occurs in the foothills of the San Bernardino Range northeast of Salton Sea. San Bernardino County: The extensive deposit of colemanite at Borate, in the Calico district near Yermo was discovered in the spring of 1883 and became the principal source of borax before the Death Valley deposits were worked. Beautiful crystals of colemanite in large geodal masses occur with celestite crj^stals. The colemanite crystals were first described by Jackson (84, 85, 86). Forms: (001), (010), (100), (210), (110), (120), (130), (370), (10.19.0), (Oil), (021), (201), (101), (101), (201), (301), (401), (601), (111), (311), (711), (10.1.1), (771), (19.19.6), (331), (7_31), (131), (121), (111), (221), (331), (411), (111), (211), (721), (321), (231), (121), (241), (131), (232), and (412). Additional forms described by Eakle (02) are: (310), (301), (502), (801), (522), (142), (141), (164), (165), ]64 MINERALS OF CALIFORNIA (232), (123), (182), and (341). Analyses: No. 1, Hiortdalil (85); No. 2, Bodewig and vom Rath (85). B2O3 CaO AI2O3 FeL'Os MgO SiOa H2O 1. 47.64 27.97 0.19 0.13 1.28 22.79 2. 49.70 27.42 22.26 = 99.38% Ventura County: Deposits of colemaiiite, similar to those at Lang, in Los Angeles County, occur on Frazier Mountain, Gale (14c). Additional references to the literature on colemanite: Arzruni (84), Baumhauer (99), Campbell (02), (03), Evans (84), (85), Foshag (21), Gale (13), Miilheims (88). MEYERHOFFERITE Hydrous calcium borate, Ca2B(iOii.7HaO. Triclinic. Long prismatic crystals, sometimes tabular parallel to the macropinacoid. Fibrous. Cleavasre brachypinacoidal. Vitreous luster. Colorless to white. H. := 2. G. = 2.12. Fuses readily with intumescence to an opaque white enamel, giving the green flame of boron. Gives water in a closed tube. Easily soluble in acids. Inyo County: Meyerhoiferite occurs as an alteration of the glassy inyoite crystals in the colemanite deposit of the Mount Blanco dis- trict on Furnace Creek. It was described, analyzed and named by Schaller (16). Forms: (100), (010), (001), (110), (210), (120), (370), (350), (450), (520), (310), (510), (810), (350), (110), (430), (310), (101), (12.0.11), (706), (605), (504), (705), (302), (12.0.1), (101), (111). Analysis: H2O H2O CaO B2O3 under 110° ab. 110° 25.45 46.40 1.01 27,75 = 100.61% INYOITE Hydrous calcium borate, Ca2BoOu.l3H20. Monoclinic. In large glassy transparent crystals. Cleavage basal. Brittle. H. = 2. G. =1.875. Decrepitates on fusing and intumesces, giving the green boron flame. Easily soluble in acids. Gives water in a closed tube. Inyoite is a borate from the colemanite deposits of the Death Valley region. It was described and named for Inyo County by Schaller (16). Inyo County: Inyoite occurs in the Mount Blanco district on r^urnace Creek associated with colemanite and its alteration product, meyerhofferite. Forms: (001), (010), (110), and (111). Crystals tabular par- allel to base. Analvsis: H2O H2O OaO B2O3 under 1 1 0° ab. 13 0° 20.5 [37.2] 26.1 16.2- : 100.00% BORATES 165 PRICEITE— Pandermite Hydrous calcium borate, Ca5Bii'Oa.9H:;0. Triclinic. Massive, challiy. Cleavage (001) perfect. Color snow- white. H. = Z — Zh. G. = 2.43. Easily fusible and gives green flame. Soluble in dilute hydrochloric acid. Gives water in a closed tube. Inyo County: Priceite occurs as iiodules and irregular masses iu soft gray shale in the Furnace Creek wash. Analysis by Foshag (24b) gave: SiOa CaO AI2O3 Bi-Os H2O — H2O + 0.58 32.20 0.20 49.03 0.38 17.86 = 100.25% G. = 2.43. KERNITE Hydrous sodium borate, Na2B407.4H20. Monoclinic. Cleavage (001), (100) perfect; (101) distinct. Vitreous to pearly luster. Colorless to white. Transparent. H. = 3. G.:= 1.953. Fuses with swelling to a clear glass. Slowly soluble in cold water. Kern County: Kernite was described by Schaller (27) as a new mineral from the Kramer district, where it is the principal constituent of the borate deposits. Locally called 'rasorite.' Analysis by Schaller gave: NasO CaO B2O3 H2O Insol. 22.63 50.76 26.50 = 99.89% TINCALCONITE— Mohavite Hydrous sodium borate, Na2B40-.5H20. Hexagonal-rhombohedral. Fine-grained crystalline powder. Dull white. Soft. G. = 1.88. The name tincalconite was given by Sliepard (78) to a pulveru- lent and efflorescent sodium borate from California containing 32 per cent of water. Kern County: Tincalconite occurs as a coating on borax and hernite in the Kramer district. Analysis by Schaller (80) : NasO BsOa H2O Insol. 21.28 47.26 30.78 0.37 = 99.69% BORAX Hydrous sodium borate, Na2B4O7.10H2O. Monoclinic. Crystals prismatic. Powder, incrustations. Cleavage (100) perfect. Vitreous to dull luster. Colorless, white, grayish, bluish. Streak white. H. = 2 — 2J. G. = 1.69 — 1.72. Fuses with strong yellow flame to a clear glass. Turmeric paper dipped in a hydrochloric acid solution, turns deep red on drying. Soluble in water. Gives much water in a closed tube. Sweetish alkaline taste. The natural borax, usually accompanied by sulphates of lime and soda, is common at many of the depressions or sinks of the deserts. Inyo County: The mines on Furnace Creek and at Resting Springs produced large quantities of borax which were hauled to Mojave by the famous 20-mule teams. Kern County: Borax has been obtained from Kane Springs and Desert Wells. It occurs with kernite and colemanite in the Kramer district, Schaller (30). 166 MINERALS OF CATjTFORNIA LaTie County: The first discovery of borax in tlie State was made at Borax Lake, near Clear Lake, Veatcli (67). Fine large crystals were obtained from the mnd of the lake bottom, and considerable borax was dredged from this lake before the more important deposits of San Bernardino County Avere found. Hanks (83), Vonsen and llanna (36). Riverside County: Incrustations of borax are rather common at some of the playas or dry lakes of this county, but none is produced. San Bernardino County: Tlio most important deposit of 1)orax in the State occurs at Searles Ijake in the northern part oF the county. Hanks (89) and others have described this deposit. 11 consists of a pan-like depression about 10 miles long by 5 miles wide; borax occurs with numerous other salts deposited by the evaporated waters of the lake. The associated minerals forming layers in the deposit are principally sulphates and carbonates of sodium, and it is now mainly for these and for tlie potash associated with them that the deposit is worked. This locality is noted for the great variety of interesting salts that have formed by the evaporation of the waters. Borax has been found with colemanite near Yermo, and at many of the numerous depressions in the Mojave Desert and in the lower end of Death Valley. PROBE RTITE—Kramerite Hydrous sodium and calcium borate, NaCaBsOo.BHaO. Monoclinic. In radial glassy aggregates. Perfect prismatic cleav- age. Brittle. Vitreous luster. Colorless. H. — 2i — 3J. G. = 2.14. Easily fusilDle. Decrepitates and yields water in a closed tube. Sol- uble in acids ; slightly soluble in water. Inyo County: Probertite occurs with colemanite and ulexite in the Widow and Upper Biddy McCarthy mines near Ryan. Analysis by Foshag (31a). CaO MgO (Fe,Al)203 NaaO B2O3 H2O Insol. 15.88 0.06 0.38 9.00 49.10 25.64 0.20 = 100.26%. G. = 2.135. Kern County: Probertite was described by Eakle (29) as a new mineral from the Kramer district where it occurs in clay with borax and kernite. Schaller (30) reported the crystal forms (100), (110), (101), (111), (010), (Oil), (101), and (111). Analysis by Schaller gave: Na2< > CaO B2O.V* HoO 8.12 15.42 50.73 25.73 = 100.00% * By difference. G. = 2.141. ULEXITE Hydrous sodium and calcium borate, NaCaBsOii.SHsO. Monoclinic. Usually in nodules or compact fibrous masses. Sill