TS 38.0 IRLF HANDBOOK ON - GIFT OF Steel Hammer. Used for general forging, such as billets, shafts, special shapes, etc. SHOP HANDBOOK ON ALLOY STEELS A technical subject treated in a non-technical way BY G. VAN DYKE Manager, Special Steel Department Joseph T. Ryerson & Son JOSEPH T. RYERSON & SON ESTABLISHED 1842 INCORPORATED 1888 IRON STEEL MACHINERY CHICAGO ST. LOUIS DETROIT BUFFALO NEW YORK COPTRIOHT, 1921 JOSEPH T. RTEBSON A SON CHICAGO TABLE OF CONTENTS Detailed index will be found on the following page CHAPTER PAGE I Quality (Analysis not the only factor) ... 12 II Method of Manufacture 15 III Elements and the Part They Play 16 IV How to Buy and Select Alloy Steels 21 V Shop Equipment 28 VI Furnaces 29 VII Quenching Equipment 33 VIII Heat Measurement . ..... V !7!, . . 1 36 IX Heating ...- ;.-.;...-..-. 39 X Cooling and Quenching. . , 43 XI Drawing 48 XII Annealing .^. . '.'. . ','*. 50 XIII Testing Heat Treated Steel . .^. ^ . . . . 54 XIV Case Hardening or Carbonizing 58 XV General Remarks . .66 [7] 494487 DETAILED INDEX Alloy Steel PAGE Untreated ................... 25 Low Carbon ................. 26 High Carbon ................. 26 Analyses 01 Alloy Annealing ............... 50, 61, 52 Overheated Steel ............. 53 Axles ......................... 21 Ball Bearing Steel ..... , ....... 19 Lead, Salt, Oil 30 Barium Chloride 31 Bolts 21. 23, 26 Brinell Hardness 55 Buying Alloy Steels 12, 13, 66 Calcium Chloride... .. 31 Cams 21 Carbon Effect of 16 Steels 16, 17, 93 Crucible Machinery 16 Carbonizing 58 Case Hardening 58 Mixtures 69, 60 Boxes 60 Temperature 59, 61 Furnaces 61 Depth of 59, 61, 62 Heat Treatment Following 62 Formulae 92 Experiments 63 Packing 64, 71 Common Steel 71 Chromium Effectof 19,20 Amount In Different Steels 19 Nickel 19,95 Vanadium 19, 94 Connecting Rods 21, 27 Cooling 43 Rate of 44,45 Core Examination 65 Cost 12, 15 Countershafts 27 Cracking, Cause of 69, 70 Crankshafts 21, 27 Critical Temperature 17, 43, 44 Range 43, 44 Crucible Process ; 15 Crystallization 26 Cyanide of Potassium 31 Cyanide Hardening 64 D Dead Soft Steel 16 Drawing 48, 49, 70 E Electric Furnace Process 15 Elements, Refer under Names. Expansion 39, 40 Fatigue 26 Forging Alloy Steels 72 Fuel, Amount Used 41 Furnaces 29 Atmosphere 41, 50, 72 Constant Temperature 40 Using Two In Heat Treatment 40, 41 Temperature, Excessive 70 Gears 21,27 Hardening Tool Steel 12 Hardness 17, 55 Relation to Strength 56, 57 Heating 39, 67 Effect of Rapid 69 H Continued PAGE Heat Treater, Duty of 38 Heat Treatment, Records 68 Heat Measurement 36, 37 High Speed Steel 19 Hot Working Die Steel 19 Initial Cost .. 13 Inspection 12 J Jack Shaft 21 L Lathe Spindles 27 Lead Bath 30 M Machinery Steel 16 Tools 27 Manganese, Effect of 18 Steel 18,95 Manufacture, Method of 12, 15 Mild Steel 16 Nickel, Effectof... .. 20 Nickel Steels 20. 93 Nuts 21, 23 Oil Bath (for Heating) 30, 31 Open Hearth Process 15 Ordering 15, 21 P Packing for Case Hardening 64 Phosphorus, Effect of 17 Physical Properties, Definitions of 79 Properties of Alloy Steels. . .22, 26, 27 Pyrometer Electric 36,37 Optical 36.37 Checking 37, 73 Q Quality 12, 15 Quenching Equipment 33 What Happens 33 Medium 34, 45 Tanks 34 Points to Watch 34, 45, 46, 47 Medium, Agitation of 46 Rising and Falling Temperature. 68 R Roller Bearing Steel 19 Rolling 12 S S. A. E. Specifications 22, 23, 74, 93, 94, 95 Salt Bath 30, 31 Scleroscope Hardness 55 Selection of Alloy Steels 21 Shop Equipment 28 Silicon, Effect of 18 Size, Effect of 45 Sodium Chloride 31 Spring Clips 26 Substitutions 24, 25 Sulphur, Effect of . . 18 Surface Defects 12 T Tensile Strength 54, 55, 79 Testing 54 Testing Machines 54 Tool Steel 12 U Uniform Furnace Temperature ... 30 W Warehouse Stocks 21 [8] INTRODUCTION THE alloy steel industry has shown remarkable growth and development during the last five or six years. The World War and the automobile industry have been the principal factors in this development. The advent of the automobile made it necessary to produce steels having great strength and also a ductility or toughness far beyond that of the better known carbon steels. Alloy steel research work has therefore been carried on by certain steel manu- facturers and also by the members of the automobile industry, and as a consequence remarkable results have been obtained in a short time. To the steel using fraternity in general the highly successful nature of the results of this experimental work in alloy steels has been fairly well known, but coupled with this knowledge has too often come the belief that the use of alloy steel involved the handling of various mysterious and secret processes which were summed up under the general heading of "heat treatment." As a result, while many people recognized the decided advantages of alloy steels, they hesitated to use them, believing that satisfactory results could only be obtained by the maintenance of large, expensive laboratories coupled with the services of highly trained technical men. While more general use of alloy steels had been making itself apparent prior to the great war, progress has been extremely slow. Coupled with the entrance of our country into the conflict came the heavy demand for automobile trucks, ordnance, armor plate, steel helmets, and the many other army [9] JOSEPH T. ^RYERSON & SON and navy requirements which could only be manu- factured successfully by the use of the highest types and best grades of alloy steels, and then only when these steels were subjected to careful and accurate heat treatment. Our government arsenals, of course, have long been familiar with the use of alloy steels in the manufacture of guns, armor piercing shells, rifle barrels, and other naval and military equipment, but their productive capacity was naturally too small to turn out the large quantity of material necessary to meet the emergency. To supplement the manu- facturing facilities of the few highly specialized shops, it was necessary for the manufacturers of the country in general to take up the production of government material, and thus it followed that many shops that had never before used alloy steels found themselves buying, machining, and heat treating these special steels, and found also that they could obtain entirely satisfactory results. The present situation is such that alloy steel parts are in demand by all industries and that these steels are coming into more general use every day. Representative steel-service plants of the country are carrying alloy steel bars in stock the same as any other standard steel product. Alloy steels have come to stay, and every day finds some heavy part which had previously been made of carbon steel replaced with a lighter, tougher, and better part made from one of the various com- mercial grades of 3J^ per cent nickel, chrome nickel, or other special steels. It is the purpose of this book to avoid all tech- nicalities and to condense in a small space sufficient information to enable the average shop superin- tendent to take hold of a special job, select and buy the steel for it, and finally to give it such heat treatment as will produce the desired result. [10] ALLOY STEEL I N STOCK Free and generous exchange of views and ideas by members of the trade are always of value and interest. The various heat treaters organizations about the country have done much along this line, and will undoubtedly do much more to spread practical information in the future. During our association with many of the leaders in the manufacture and use of alloy steel, and membership in various societies and associations, we have built up a fund of information, data and experience which of necessity can not all be included in this small book, but which is available for all who seek it. [11] JOSEPH T. RYERSON & SON CHAPTER I QUALITY (Analysis not the only factor) IT seems appropriate at the start to call the attention of the reader to the matter of quality of the alloy steel which he may contemplate buying and using. Practically all users of alloy steels have been in the past, or are at present, users of tool steels, and they will therefore understand that chemical anal- ysis is far from being the only factor governing the ultimate result to be obtained from the use of any steel. All tool and die makers know the difference be- tween a piece of common grade tool steel and a piece of special grade tool steel, even if the carbon content of each is exactly the same and general analysis very close in both grades. The real differ- ence in the two steels mentioned is in the method of manufacture. This is governed by such factors as the kind of raw material used, the method of melting and casting, the amount of steel cut off the end of the original ingot, the amount of rolling or hammering done and the care used in annealing and inspecting the finished bars. A mild steel bar is in the majority of cases used just as it is received from the mill. If, therefore, it satisfactorily passes mill inspection for size and freedom from surface defects it will generally be satisfactory to the ultimate consumer. Tool steel, on the other hand, as received from the mill has only started its journey, and it may be said that its [12] ALLOY STEEL IN STOCK manufacture is not completed until it has passed through its final process, which consists of heat treatment or hardening. Inasmuch as practically all of the alloy steel purchased is subject to heat treatment before use, it would therefore seem that alloy steels, like tool steels, cannot be judged entirely by their analysis. It is well known to alloy steel manufacturers that the ability of these steels to withstand the severe stresses put upon them by heat treatment depends not only on their analysis or composition, but also on the various processes through which they have passed during the period of manufacture at the mill. For these reasons it should be clearly remembered that in purchasing alloy steels the reliability and reputation of the manufacturer should be given full consideration. The element of original cost must not be overlooked in order to secure econom- ical production; but it is equally important to remember that each finished part represents just so much money spent for machine work and heat treat- ing, and in most cases a cent or a fraction of a cent per pound in the initial cost is a very small factor when compared with the money expended on machine work, heat treating, freight, and other elements of the total cost. [13] JOSEPH T. RYERSON & SON Casting. Molten steel being poured from ladle into molds. [14] ALLOY STEEL IN STOCK CHAPTER II METHOD OF MANUFACTURE AXOY steels are being manufactured by the following processes : Crucible Process. Open Hearth Process. Electric Furnace Process. The crucible process, owing to extreme cost, is not used for heavy tonnage production, and need not be considered by the average manufacturer, it being impossible to produce a strictly crucible melted alloy steel at a price sufficiently low to enable the user to compete with others who are using steel made by one of the other methods. A discussion of the relative merits of the open hearth process and electric furnace process would cover far more space than is permitted in this book and would also of necessity be extremely technical. Steel of the very best quality can be made by either the electric furnace or the open hearth process, and it is perhaps safe to assume that the ultimate quality depends more on the selection of raw material , care used in manufacturing, and knowledge and experience of the maker rather than the particular method which he follows in making the steel. After all, the best solution of this problem for the average shop is to buy material from an entirely reliable source of supply, specifying the purpose for which the material is to be used and leaving it to the sellers to furnish steel in which they have confidence and on which they are willing to stake their reputa- tion. [15] JOSEPH T. RYERSON & SON CHAPTER III ELEMENTS, AND THE PART THEY PLAY IN this chapter we will endeavor briefly to outline the various properties imparted to steel by the addition of the most commonly used metals, such as nickel, chromium and vanadium, also the effect of the presence of carbon, manganese, silicon, phosphorus, and sulphur. CARBON One of the most important elements in any steel is carbon. The effect not only makes itself apparent in the steel itself and the results obtained from its use, but is also of primary importance in the deter- mination of the correct heat treatment. In straight carbon steels, that is, steels composed of iron, carbon, and small percentages of such ele- ments as manganese, silicon, phosphorus, and sulphur, the varying amounts of carbon produce steels which may be roughly listed as follows: Dead soft steel, carbon not over 0.10 per cent. Mild steel, carbon not over 0.25 per cent. Machinery steel, carbon 0.25 to 0.40 per cent. Crucible machinery steel (not necessarily a crucible product), carbon 0.40 to 0.60 per cent. Low carbon tool steel, carbon 0.60 to 0.75 per cent. Carbon over 0.75 per cent is used in various grades of tool steel, sometimes running as high as 2 per cent. The most common range of carbon in tool steel is 0.75 per cent to 1.20 per cent. [16] ALLOY STEEL IN STOCK From these figures it will be readily understood that the greater the amount of carbon used in steel the harder the steel becomes. This is true for steel either in the annealed condition, the natural or untreated condition, or the heat treated or tempered condition. Straight carbon steel which is cooled rapidly from above its critical point No. 1 (this term is explained on page 43) begins to show an increased hardness when the carbon content is over 0.25 per cent. The amount of hardening, while increasing with greater carbon content, does not tend to produce any great degree of brittleness until the carbon content has reached about 0.50 per cent. When steel containing more than about 0.50 per cent carbon is suddenly cooled from above its critical temperature, it becomes intensely hard and also develops extreme brittleness. Therefore, for the great majority of purposes, alloy steels do not contain much more than about 0.45 per cent carbon. The reason for this is that alloy steels are principally used where great strength, toughness, and freedom from brittleness are required. PHOSPHORUS In practically all steels the presence of phos- phorus may be considered a detrimental impurity. The great danger of high phosphorus content is that it renders a steel liable to fracture when subjected to intense vibration or sudden shock. High phos- phorus does not seem to give any particular trouble during the course of manufacture, and high phos- phorus steel can be successfully worked as long as it is at a relatively high temperature. From this explanation it is obvious that alloy steels must not contain excessive phosphorus. The gen- erally accepted maximum limit is in the neighbor- hood of 0.04 per cent for commercial alloy steels. [17] JOSEPH T. RYERSON & SON In good tool steel 0.025 per cent is about the per- missible maximum. SULPHUR Sulphur may be considered an undesirable impurity in all steels, but its effect is more or less tho opposite of that produced by phosphorus, inasmuch as steel containing excessive sulphur develops cracks, flaws and weaknesses when worked hot. The detrimental effect is nevertheless present in cold steel, and for this reason it is not usual to permit a percentage of sulphur exceeding .045 per cent. MANGANESE Manganese is present in all steels, and, when added in relatively large proportions, produ special steel with properties entirely different from those of any other known analysis. This steel is known as manganese steel and may contain as much as 14 per cent to 15 per cent of manganese. Manganese steels are not in the class of material to which this book particularly refers, and no further mention will, therefore, be made of them. When present in small quantities such as 0.25 per cent to 0.80 per cent, manganese serves as a cleanser or purifier of the steel. This action is brought about by the manganese forming a chemical union with the dissolved oxygen which is present in the steel, thus forming an oxide of manganese which is carried off in the slag. It has also been found that in steels where the phosphorus and sulphur might tend to produce a rather coarse grain the presence of manganese tends to reduce this grain to a more normal and desirable size. SILICON When present in small quantities silicon has very uch the same effect as similar percentages of is ALLOY STEEL IN STOCK manganese. When present in larger quantities silicon, like manganese, produces steels of unique Characteristics, the principal among these being the effect on the magnetic properties of the steel. CHROMIUM This is, perhaps, one of the most important ele- ments to be considered from the standpoint of alloy steels, and it is used in the production of many classes of material, among which may be mentioned high speed steels, certain grades of water hardening tool steels, hot working die steels, ball and roller bearing steels, chrome nickel steels, chrome vana- dium steels, etc. Chromium has in general the effect of producing hardness in properly treated steels, and when added in the correct proportions and in suitable relation to the balance of the analysis, takes the place of a certain portion of the carbon in producing a harden- ing and strengthening effect. The amounts of chromium used in different classes of steel vary widely, although the following list will give an approximate idea of the more generally accepted percentages: Kind of Steel Percentage of Chromium. Chrome Nickel Steels | W3 | <^> .. .0.35 to 1 . 25 Ball and Roller Bearing Steels 0.80 to 1.25 Hot Working Die Steels 3.00 to 4.50 Chrome Vanadium Steels . 75 to 1 . 25 Certain Water Hardening Tool Steels . . . 20 to . 50 High Speed Steel 3.00 to 5.00 The presence of chromium having, as before men- tioned, a somewhat similar effect to carbon in pro- ducing hardness under heat treatment, it is very essential that the percentage of chromium be known and given full consideration when any heat treat- ment formula is being developed. [19] JOSEPH T. RYERSON & SON Chromium increases the susceptibility of steel to heat treatment, and it also has the property of carrying the hardness produced by quenching to a greater depth so that steels of a fairly high chro- mium content after quenching will, in medium sized sections, be found to have hardened all the way through to the center. When present in rather large proportions, such as are found in hot working steels, chromium enables the steel to retain its hardness at relatively high temperatures, and it is this prop- erty that makes these steels particularly suitable for gripper dies and other work where the steel will be used at high temperatures and must still retain a reasonable degree of hardness. NICKEL Nickel is the best known of all the elements used in the manufacture of alloy steels. Nickel steel was one of the first alloy steels generally used and still continues to be extremely popular. Various percentages of nickel have been tried, and it has been found that for general all round work about 3^ per cent nickel seems to give the best results, both in the way of producing a high tensile strength and elastic limit and at the same time leaving the steel ductile and tough. The presence of nickel may be said to increase the toughness and strength of the steel and also to increase its resistance to sudden shock and excessive vibration. Steels containing nickel respond very readily to heat treatment, so much so that a bar of 3}/ per cent nickel steel containing 0.40 carbon will have an elastic limit of about 60,000 pounds per square inch in the annealed condition and about 200,000 pounds per square inch in the maximum heat treated condition. [20] ALLOY STEEL IN STOCK CHAPTER IV HOW TO BUY AND SELECT ALLOY STEELS PERHAPS one of the most difficult problems that must be solved by the user of alloy steels is the selection of a suitable grade to use for a certain piece of work. A study of the table on page 22 (Table A) will show that somewhat similar physical characteristics may be obtained from the use of any one of the sev- eral commercial grades of alloy steel mentioned, and the user will, therefore, perhaps, be at a loss to de- cide which class of steel to select. For this reason we call attention to the following. There are many elements which must be taken into consideration besides the actual physical prop- erties which may be obtained from any one grade of steel. Among these may be mentioned availability, cost, machine qualities, equipment necessary for heat treatment, and past experience of the user in handling the steel selected. The largest warehouse tonnages of alloy steel are confined to the chrome nickel steels, containing about 1 to 1.5 per cent nickel and .40 to .75 per cent chromium, and the 3}/ per cenF nickel steels (car- bon contents varying in both). These two alloy steels are suitable when properly heat treated for the manufacture of such parts as axles, jack shafts, oil hardened and case hardened gears, high duty bolts and nuts, cams, crank shafts, connecting rods, and the thousand and one different [21] JOSEPH R Y E R S O N SON parts entering into the manufacture of automobiles, trucks, tractors, and other special machines. TABLE A COMPARATIVE PROPERTIES OF ALLOY STEELS The following are the approximate physical prop- erties which may be obtained from some of the alloy steels under ideal conditions of heat treatment. GRADE OF STEEL ELASTIC LIMIT Lbs. per sq. inch REDACTION OP AREA Per cent of Original area ELONGATION Per cent in 2 inch C'HKOMK NICKEL S. A. E. 3120 Natural Condition. Heat Treated.. *.- ic co o r>- ^# I-H < co^us uscitx **< Tjl 1C O ?J **< Oi-H CO 1C ^t- C5 f^ CO t^CCCOUS IC-^CCCM -H < cncot^i-H icost^us co< I(MCO -*-*iO!C C to ic oo rH eo c o O5 00 00 t^i-iiO CO (M O O O OO [88] ALLOY STEEL IN STOCK 90 3 00 O 3 go O IQ .0 'OcOt>-O^fr l l>OTfrtOt>-' I cOOOO. 00 O"i i OOO o-^ o - Oi O (N "^ (NO5 1C K ii !00-<*r-.CO&'cOCO (MCOCO-^iO4OCOl>t>.OOOOO5Oi i(MO SOCO CO I [89] JOSEPH T . R Y R S O N SON TYPICAL TENSILE STRENGTHS OF HEAT TREATED STEEL OF DIFFERENT CARBON CONTENT Carbon per Cent. Approximate Tensile Strength in Lbs. per Square Inch. .05to .10 47,040 to 60,480 .lOto .15 53,760 to 64,960 .15 to .20 60,480 to 71,680 .20 to .25 64,690 to 76,160 .25 to .30 67,200 to 78,400 .30 to .35 69,440 to 82,800 .35 to .40 78,400 to 91,840 .40 to .45 87,360 to 100,800 .45 to .50 96,320 to 107,520 .50to .55 105,280 to 118,920 .55 to .60 112,000 to 123,200 .60 to .65 116,480 to 127,680 .65 to .70 123,200 to 134,400 .70 to .75 129,920 to 138,880 .75 to .80 134,400 to 143,360 .80 to .85 136,640 to 145,600 .85 to .90 141,120 to 150,800 WORKING TEMPERATURES FOR CARBON STEELS NAME Carbon Content Appro*. Critical Temp. Forging Temp. Quenching Temp. Machinery 25 1475 1650 1525-1575 Machinery Machinery. 0.35 45 1395 1385 1650 1650 1450-1500 1435-1485 Crucible Machy . Crucible Machy . Tool Steel Tool Steel 50 55 60 70 1380 1375 1365 1355 1625 1625 1600 1600 1430-1480 1425-1475 1400-1460 1400-1460 Tool Steel . 80 1350 1600 1375-1450 Tool Steel Tool Steel 0.90 1 00 1350 1350 1575 1575 1375-1450 1375-1450 Tool Steel 1.10 1350 1500 1375-1430 Tool Steel 1.20 1350 1500 1375-1420 Tool Steel. 1 30 1350 1500 1375-1420 [90] ALLOY T E E L I N STOCK MILLIMETER EQUIVALENTS IN INCHES Millimeters Inches Millimeters Inches Millimeters Inches 10 _ .0039 29 m 1 .1417 66 = 2 5984 20 = .0079 30 = 1 .1811 67 = 2 6378 30 = .0118 31 = 1 .2205 68 = 2 6772 40 = .0157 32 = 1 .2599 69 = 2 7165 50 = .0197 33 = 1 .2992 70 = 2 7559 00 = .0236 34 = 1 .3386 71 = 2 7953 70 M .0276 35 = 1 .3780 72 = 2 8346 80 M .0315 36 = .4173 73 = 2 8740 90 M .0354 37 = .4567 74 m 2 9134 1 = .0394 38 = .4961 75 = 2 9528 2 = .0787 39 = .5354 76 =s 2 9921 3 = .1181 40 = .5748 77 = 3 0315 4 = .1575 41 = .6142 78 = 3 0/709 5 = .1969 42 = .6536 79 = 3 1102 6 = .2362 43 = .6929 80 = 3 1496 7 = .2756 44 = .7323 81 = 3 1890 8 .3150 45 = .7717 82 = 3.2283 9 a- .3543 46 .8110 83 = 3 2677 10 tp .3937 47 = .8504 84 = 3 3071 11 = .4331 48 = 1 .8988 85 = 3 3465 12 . .4724 49 = 1 .9291 86 = 3 3858 13 = .5118 50 = 1 .9685 87 = 3 4252 14 = .5512 51 = 2 .0079 88 = 3 4646 15 . .5906 52 = 2 .0472 89 = 3 5039 16 .6299 53 m 2 .0866 90 = 3 5433 17 M .6693 54 2 .1260 91 = 3 5827 18 .7087 55 = 2 .1654 92 = 3 6221 19 = .7480 56 =. 2 .2047 93 = 3 6614 20 = .7874 57 = 2 .2441 94 = 3 7008 21 = .8268 58 = 2 .2835 95 = 3 7402 22 = .8661 59 = 2 .3228 96 = 3 7795 23 = .9055 60 = 2 .3622 97 M 3 8189 24 Mfc .9449 61 = 2 .4016 98 = 3.8583 25 = .9843 62 = 2 .4409 99 = 3.8976 26 m 1.0236 63 M 2 .4803 100 = 3 9370 27 1 0630 64 _ 2 .5197 28 = 1 . 1024 65 = 2 .5591 [91] JOSEPH T. RYER80N & SON TYPICAL FORMULA FOR CARBONIZING CHBOME NICKEL STEEL SAE 3120: Carbonise at 1625 to 1700 degrees. Cool in box and remove. Re-heat to 1550 to 1600 degrees. Quench in oil. Re-heat to 1300 to 1400 degrees. Quench in oil or water. Draw to from 300 to 450 degrees. 3^% NICKEL STEEL SAB 2320: Carbonize at 1625 to 1675. Cool in boxes and remove. Re-heat to 1550 to 1575. Quench in oil. Re-heat to 1300 to 1400 degrees. Quench in oil or water. Draw to from 300 to 450 degrees. CARBON STEEL SAE 1020: Carbonize at 1650 to 1700. Cool in boxes and remove. Re-heat to 1550 to 1600. Quench in oil. Re-heat to 1400 to 1450. Quench in oil or water. Draw to about 400 degrees. The above formulae are approximate and will be subject to change according to the size of pieces being carbonized and also the depth of penetration required. The final drawing tem- perature will have to be modified, depending on the degree of hardness required in the finished article. As in all other heat treating operations, definite formulae for carbonizing can best be obtained by actual experiment and a little time and money spent in this way will be well invested inasmuch as it will save the possible damaging of valuable work. [92] ALLOY STEEL I N STOCK a II ggg sss 888888 333 333 333 1 II Hg eoecco eocoeo eoeoeo eoeoeo 333 333 cccoeo eococo 333 333 333 333 O 1C >O OlOO -H r-icq eceoTti 33 (M 1-1- 33 l 33 1 J3 33 [93] JOSEPH T RYER8ON SON l! SJ2J2 g 333 3 la s 5S S 333 3 823 1 3* '*V l ll Is oS Id ososos ooco 888 sss an m Min M .H^^H ^H^HW O eocoeo coeoeo coeoeo has [95] THIS BOOK IS DUE ON THE LAST DATE STAMPED BELOW AN INITIAL FINE OF 25 CENTS WILL BE ASSESSED FOR FAILURE TO RETURN THIS BOOK ON THE DATE DUE. THE PENALTY WILL INCREASE TO 5O CENTS ON THE FOURTH DAY AND TO $1.OO ON THE SEVENTH DAY OVERDUE. APR 12 1933 OCT 21 1933 V** '57T8 RECTO APR 1319SI REC'D Z.D MAR 10 1959 YB 1 62 49448? UNIVERSITY OF CALIFORNIA LIBRARY