LIBRARY O" THE UNIVERSITY OF CALIFORNIA. Received c^^^. ' , i8^^ zAccessions No./0^^^ . G ass No. Digitized by tine Internet Archive in 2007 witin funding from IVIicrosoft Corporation littp://www.arcliive.org/details/chemicalmanures.OOvillrich CHEMICAL MANURES. DELIVERED AGRICULTURAL-^ iffiQTJJRE^ AT THE EXPERIMENTAL FARM AT VmCENNES, IN THE YEAR 186Y. BY GEORGE VILLE. TRANSLATED BY MISS E. L. HOWARD, NEAR KINGSTON, 35ARTOW COUNTY, GA. TBCIE.I> EJI>ITI01Sr, ATLANTA, GEORGIA: PLANTATION PUBLISHING COMPANY. 1871. Entered according to Act of Congress, in the year 1871, by MISS E. L. HOWARD, In the Office of the Librarian of Congress, at Washington. ihi'jZ Westcott & Thomson, Stereotypers, PMlada. Chemical Manures. PREFACE. These admirable lectures of George Yille were originally translated from the French by Miss E. L. Howard for the columns of Tlie Plantation, a weekly agricultural paper pub- lished in Atlanta, Georgia. This was, perhaps, the first instance in this country in which an agricultural paper had ventured upon the translation of a foreign scientific work to be published in its columns. It was also, ])erhaps, the first instance in which a scientific agricultural work had been translated by a Southern — we may add an American — lady. It was a task of much difficulty, requiring not only a thorough knowledge of the French language and familiarity with scientific terms, but a change from French weights, measures and currency to our own. The whole work has been patiently and skillfully execi^ted. So great was the impression made by this translation that the State Agricultural Society of Georgia, at its recent Convention, held October 8th at Rome in Georgia, took the following com- plimentary notice of it : " Mr. Barnett, of Wilkes, offered the following preamble and resolution : " WhereaSj The exceedingly interesting work of George Yille, wUo has done so much to advance the science of Agriculture among mankind, and to promote it almost to the rank of an exact science by his wonderful combination of skill, knowledge and common sense, has been translated by a Southern lady — a native Georgian — in a style of great elegance and perspicuity ; 6 PIIEFACE. " Resolved J That this body, in the event of the publication of the translation, earnestly recommend its circulation, as furnish- ing the means of enlightenment to the most advanced farmers, both in the knowledge of facts and of the principles of investigation and experiment leading to the further increase of knowledge.'' The resolution was adopted by a rising vote of the Convention, " as a mark of respect for the fair translator." Mr. Fannin, of Troup, offered the following resolution, which was adopted : " Resolved y That we, as representatives of the County Agri- cultural Societies, will endeavor to promote the circulation of the work of the distinguished agricultural writer and thinker, George Ville, and will recommend to the societies to subscribe liberally, and to take not less than six copies each ; that in addition to this, the County Societies, instead of offering cups for premiums, will offer a copy of this work or a year's subscription to some good agricultural periodical." After this strong endorsement by one of the most numerous, dignified and intelligent assemblages which has ever met in Georgia, it is unnecessary for the writer to add further remark. H. ; i. 1 B K A K V I UNIVERSITY OF LCAIJFOKNIA. i CHEMICAL MANURES. A TRANSLATION OF AGRICULTURAL LECTURES GIVEN BY GEORGE, VILLE, IN 1867, AT THE EXPERIMENTAL FARM OF VINCENNES. LECTURE FIRST. GENTLEMEN" :— Since 1861 I have been in the habit of giving in a series of lectures the results of my studies on the means of husbanding and increasing the fertility of the soil, outside of those traditions consecrated by the experience of the past. My method belongs essentially to science, both in character and origin. From the beginning it has been conceived in the hope of giving a guide to Practice upon which she can safely rely. My efforts have been directed to freeing it as much as possible from all theoretic formulae which are not imposed by the nature of the subject. Since commercial liberty has become the economy of nations, we feel with added force the importance of agricultural questions. Under this new rule a nation can have a sound prosperity, but in proportion as it surpasses those nations to whom its interior is thrown open, it must produce more and more cheaply. By what process can we obtain this end ? We will now seek it together, building upon the facts to which I here bear witness. Entering on my subject under its new aspect carries my thoughts back, and not without emotion, to the time when my labors were first thought worthy of encouragement by his gracious Majesty. Many doubted the results, as my efforts were founded on the studies of the laboratory. The emperor thought differently, and the founding of the experimental farm at Vincennes is an additional proof of the enlightened solicitude of our sovereign for our agricul- tural interests. As I have already said, our Agriculture must increase her products if she would reduce their cost. The laws which permit her so to do require me to begin with the most intricate problems of vegetation — in a word, to unveil to you the very elements of which plants are composed, since it is to these she must have recourse if she would increase her returns. In the composition of plants nothing is permanent. Their ele- ments experience, in different organs, certain movements, veritable migrations, whose order and succession are regulated by fixed laws. 8 CHEMICAL MANUJKES. The structure of a plant depends on imponderable agents — light, heat, electricity. Now, to use these as auxiliaries it is absolutely necessary we know the effects of each. This can only be known by basing our deductions and laws upon the theories which precede them. The first question is : Of what is the substance of plants formed ? From whence comes it? How do the combinations of elements which chemists show, operate ? Upon this point Chemistry is as clear as decided. She answers : Of fourteen invariable elements, w^hich, for conveni- ence, are arranged in two parallel series : Organic Elements. Mineral Elements. Carbon, Phosphorus, Hydrogen, Sulphur, Oxygen, ' Chlorine, Azote. Silicium, Iron, Manganese, Calcium, Magnesia, Sodium, Potassium. Why are tlie first elements called organic and the second mineral? Because the first are found combined only in living beings, and the second belong by their nature to the solid crust of the earth. But how is it, we ask, that so limited a number of elements suffices for so many dissimilar productions ? The answer is very simple : Because they possess the power of in- definite combination, like the letters of the alphabet — though small in number, yet enough to form all the words of a language. Another question arises : Is the composition of a plant the same in all its parts ? Do its varied organs differ but in form ? Are the stem, the bark, the leaves and the fruit l)ut different impressions of the same substance ? Far from that. In a certain degree, each organ has its own com- position. But these variations, the result of conditions absolut(^ly necessary to the reproduction of the species, can be reduced to a few simple propositions. We begin with the mineral elements. In general the leafy parts of a plant contain more minerals than do the tougher parts. This is only because the aqueous parts of tlie sap evaporate quickest in the first organs. Evaporation is active in proportion to looseness of tissue and directness of contact with the atmosphere. Thus we find more min- erals in grasses tlian in trees, more in leaves than in bark, and more in bark than sap-wood or in heart-wood. In the fruit of a leguminose there are two distinct parts — the shell and the pea. The shell, which is in more immediate contact with the atmosphere than the pea, contaiiis most minerals. Following CHEMICAL MANURES. U the same order, the leaves of an evergreen hold fewer minerals than do those of a deciduons tree, being renewed at a season least favor- able to evaporation. The following figures show the proportions : Driod Vegetable Matter, Coutaiuiiig KX) parta Mineral. Grasses 7.84 Trees 0.94 Wood 0.55 Sap-wood 2.65 Bark ' 7.47 Leaves 14.20 Deciduous leaves 6.60 Evergreen " 2.00 Pea-shells 5.50 Peas 3.10 If we make as exact a study of each mmeral element as we now do of the whole, we will arrive at an analogous conclusion, to find that by a species of election each of these elements centres by prefer- ence in a certain set of organs. Thus we find more silica, lime, oxide of iron, sulphates and chlorides in the stem and leaves than in the fruit and seed, where, on the contrary, suli)huric acid, potash and magnesia become the predominant elements. Take wheat for example. In the ashes of the seed there is 46 per cent, of phosphoric acid, in the chaff, 2.54, in the straw, 2.26, and only 1.70 in the roots. What I have just said of phosphoric acid is equally true of mag- nesia and potash, the proportions of which change from one organ to another, as will be seen by the following table : IN 100 PARTS OP ASHES OP ' • ' lloota. straw. Seed. . . Phosphoric acid 1.70 2.20 46.00 • Magnesia. ,.... 1.97 3.92 13.77 Potash 2.87 15.18 32.59 •/ Lime 0.88 3.00 1.19 , The differences here found in wheat exist in all plants without exception. Thus, the distribution of minerals is not left to chance, but is sub- ject to fixed laws ; all aid in the general structure of the plant, but each centres in a fixed organ or system of organs. We will now find the cause ofHhis unequal distribution. In the economy of living beings all the functions, varied as they are, tend to one end — viz., the reproduction of the species for all time. They are ordered with a view to this important result. But to gain this object, the embryo contained in the seed must have within its reach all those minerals necessary to the first acts of vegetable life. Hence, the seed is so abundantly supplied with phosphoric acid, potash and magnesia. It is a kind of reserve laid by for the first movements of the embryo. , 10 CUKMICAL MANURES. If you carefully read the preceding table, you will be struck by the contrast between the potash and phosphoric acid. Phosphoric acid is pretty uniformly distributed through all the organs, the seed excepted. Not so with potash. The concentration of phosphoric acid in the seed is sudden ; the proportions of ])otash increase by degrees, and, you will observe, in proportion as the organ nears the seed. Why this sudden increase on the one side and gradual progress on the other? An old remark of Theodore de Saussure informs us : The phosphates of lime and magnesia are insoluble in water; but there is a double phosphate of potash and lime, and a double phos- phate of potash and magnesia, both of which are soluble in water. Potash — or, to speak more exactly, alkaline phosphates — favors, if it does not determine, the change of terraqueous phosphates into tissues. Now, at the time the seed forms vegetation is retarded and the organs begin to dry. It is evident, then, that the superabundance of alkaline salts must favor the passage of terraqueous phosphates ; therefore, the nearer the seed the greater the quantity of potash, and consequent increase of terraqueous phosphates. Let us look, now, to the distribution of the organic elements. Here a fact strikes us. These elements, four in number, represent at least ninety-five per cent, of vegetable matter. Here let me say that although the minerals do not figure largely, wt may not from that conclude they are less important than the organic elements. Want- ing them, vegetation would be impossible ; it would be languishing and uncertain if the soil were not sufficiently supplied with them. In their distribution through vegetation the organic elements present another contrast to the mineral elements ; three of them — carbon, hydrogen and oxygen — are exhibited in almost unvarying propor- tions. All plants and all organs, without distinction, contain the same quantities of these. Trees, shrubs, simple plants, roots, stems, barks, branches, leaves, fruits and seeds maintain an invariable balance in proportions of carbon, hydrogen and oxygen. AVith azote it is different. We may say of that what has already been said of phosphoric acid potash — fruits and seeds contain more of it than the other organs, because during germination the embryo lives on the seed, and within its small circumference it must find azote as well as minerals. In vegetable matter carbon and oxygen are exhibited, each at 40 to 45 per cent., hydrogen from 5 to 6 per cent., and azote from 1 to 2 per cent. I have promised to define vegetable composition with exactness and clearness. It seems to me that the preceding data do so. But it is not enough to know what composes vegetable matter ; we must also know how it is formed, and how those elements combine which shape and increase its organs. Here the process differs at all points from that proper to minerals. If a solution of marine salt is exposed to the sun, as tlie liquid evaporates crystals are deposited too fine to be seen but with a mag- nifying glass. Soon, however, their forms become visible, and we CHEMICAL MANURES. 11 can watch their growth from day to day, which we will soon find is governed by a geometrical regularity not to be thrown off. Here the growth is .made by successive and continued deposits of salt, the first crystals being centres of attraction for the molecules of sugar and salt diffused through the liquid. The work of vegetable growth is not so simple, though the phases through which a vegetable passes before its full development have a character of fixedness and persistency which excludes all idea of chance and whim. The laws governing it are not less inflexible than those governing minerals, and their principles and details are equally well known. I have told you that plants owe their formation to fourteen different elements. I now add that some of these elements are in the form of aerial gases, while others, liquid or solid, issue from the soil. The first are absorbed by the leaves, the second by the roots. Thus, plants are formed from many and very different principles, drawn from varied sources. But these principles do not at once build up tissues and organs ; they first pass through a stage belonging rather to inorganic than to organic nature. The formation of a plant is, then, in reality an operation of two degrees. These compounds of uncertain form are divided into two groups, the one comprehending those compounds into which only carbon, hydrogen and oxygen enter ; the other, those in which most azote, sulphur and phosphorus are found. Here is a list of these products, which I will call traiuitory products of active vegetation, to recall at once their origin, principal character and true distinction. • Transitory Products. Hydrocarbonates. Azotes. I"^"'"''^^^"^^*''"-' lAmWoT(starch). Fibrin. r Gum-dragon, Semi-solubles, -< Pectin, y Inulin. Casein. I Gum-arabic, Mucilage, Grape sugar. Cane sugar. Albumen. We will take first the products of the first group. All these pro- ducts, to which we will give the name hydrates of carbon, have a common character ; their composition is the same. For greater dis- tinctness, we will express them by the common formula, C12 (HO)n. In all there are tw^elve equivalents of carbon, always in combina- tion with hydrogen and oxygen in proportions to form water. Although unlike in appearance, all these bodies are, in reality, but reproductions of the same type. The proof of this is the impossi- bility to draw a line of demarkation between them; so, instead of taking them separately in a single plant, we will notice the variations 12 CHEMICAL MANUKES. they exhibit in plants in general. A deeper study of these products shows us the point at which it is impossible to make clear and exact distinctions between them. We have placed the cellulose (so called because it forms the warp of vegetable tissue) at the head of the first group ; immediately after comes the starch or amidon, then the gums, and lastly the sugars. Between the cellulose and the sugar there are great and numerous differences, and if one did not know the other terms of the series — pectin, inulin, gums, etc. — it would not occur to one to see in these two bodies dissimilar forms of an unique type. Cellulose is insoluble in water — the sugar, on the contrary, melts away in it. Cellulose is not easily attacked by acids or alkalies slightly diluted. Sugar is easily changed by both. Su^ar has a sweet taste, cellulose no taste. How did we get the idea of assimilating these two bodies, so as to make of them one and the same body ? The identity becomes manifest, and almost forces itself upon us, if we do not confine our observations to the cellulose of woody tissue, but look also at the properties of the other terms in the series, and at the changes to which the cellulose itself is subject. Cellulose in the form of woody tissue is insoluble in cold water, and even in boiling water. But in Iceland moss cellulose, being less compact, jellies as soon as boiled. Hard as ivory in the kernels of some fruit, it becomes edible in the mushroom. There is no greater difference between the edible part of the mushroom and a piece of the wood of an oak than between the sugar and cellulose of the lichen. The cellulose in the tubercles of the Irish i)otato is in isolated grains, formed by concentric layers fitting into each other. Between the amidon and the cellulose there is little apparent analogy ; but if we add that the amidon swells in boiling w^ater to such a degree as to form a true jelly, like Iceland moss, the analogy between the two products becomes incontestable. Amidon swells in boiling water without dissolving; but inulin, which is found in the tubercles of the Jerusalem artichoke, and which is a species of amidon, dissolves in boiling water, from which it sep- arates itself in independent grains as the water cools. If we add that gum-dragon forms jelly in cold water without dis- solving, and that gum-arabic swells and dissolves in it, and has a slight taste of sugar, the change of the gum into sugar becomes evident, and the analogy which joins the sugar to the cellulose, though at first concealed, can no longer be doubted. To prove this conclusion, I will add, that the cellulose itself, even when most compact, can be changed into gum and to sugar, and to do this it is only to be treated with sulphuric acid — that it is the same with all the other terms of the series, which can all be turned into sugar by the same means. These transformations are incessant in vegetation ; the economy of vegetable nutrition depends upon them, as I will show when I come to speak of albuminous substances. The CHEMICAL MANURES. 13 materials which form the second group of transitory products of vegetable activity are three in number ; they are distinguished from the hydrates of carbon by the azote, sulphur and phosphorus they contain, which are wanting in the first. Their composition is then one more degree complicated. We will observe the same of them as has already been said of the hydrates of carbon : in spite of their dissimilarity, they are in reality the same body under three different conditions. Their composition is the same and is expressed by the same formula. Cm, Hm, Az^g, S2, O44. Is it objected that fibrin is insoluble in water while casein and albumen are soluble ? But I say. Bring water to the boiling point and these two bodies will be equally insoluble. But you will say. Heat does not dissolve albumen as it does casein — that albumen coagulates in masses, while casein coagulates but in part, in the form of a skin on the surface of the liquid. To refute this objection, we need only communicate the properties of whichever one of these materials we please to the other two. Fibrin is insoluble. To make it soluble we have only to pound it in a marble mortar and add a fiftieth part of its weight in caustic soda. The dissolution thus produced possesses all the properties of albumen, and its most characteristic one, that of coagulating in a mass under the action of heat. If you pour a few drops of caustic soda into a solution of albumen, it will acquire the property of coagulating in parts and forming a skin like casein. If I add finally, that these bodies, like the hydrates of carbon, are continually changing into each other during the periods of vegetable life, you will agree with what I have already said, that they are varied forms of the same type. Let us pause a minute at these transformations, which make the very essence of vegetable life. Wheat, before germinating, contains from ten to fifteen per cent, of fibrin and one or two per cent, of albumen, more or less. As soon as germination begins, the proportion of fibrin diminishes and that of albumen increases. Beans and lentils contain no fibrin, but casein has, like cheese, a very little albumen ; now during germination the casein disappears and the albumen takes its place. It is the same with amidon, contained in abundance in seeds : it is changed into gum and sugar, and they in their turn become cellulose in the leaves, branches and roots. The plant in its first period is but the seed transformed. After germination, when vegetation may properly be said to commence, it receives more and more albumen until the time of flowering, when in wlieat the albumen becomes fibrin, and casein in beans and lentils. Let us return to the hydrates of carbon, taking the beet fi)r ex- ample. Before flowering it contains eight or ten per cent, of sugar ; after the seed is formed the sugar disappears, amidon having taken its place. I therefore repeat, vegetable nutrition is a phenomenon of two stages, the first corresponding to tho formation of transitorjr pr6- 14 CHEMICAL MANURES. ducts ; the second, to their transformation into vegetable tissues and organs. Lastly, I add that the mechanism of vegetable nutrition rests en- tirely on these two orders of phenomena, which are both independent and united. From the foregoing it results that plants are known to be under the double relation of their composition and manner of formation. To complete this general view of vegetable production, I must show you the conditions which regulate its movements, and which, in practice, make their cultivation certain or precarious, expensive or remunerative. These conditions are three in number : 1st. Climate. 2d. The nature of the soil and the choice and quantity of manures. 3d. The choice of seed. The influence of climates. That is indisputable. "VVho has not marked the changes of vegetation in passing from the foot of a moun- tain to its summit ? At the distance of a mile or two we distinctly see the bands of verdure on the inclinations of the Alps, contrasting through thickness and coloring as well as by difference in flora. The same thing takes place on a grander scale in going from the equator to the poles. At the equator, vegetation is marked by an appearance of vigor and majesty which strikes a European traveler with admiration. The number of trees, compared to that of the grasses, is greater than in Europe. The trees are also remarkable for height and the size of trunk, as well as for richness and variety of foliage. Seventy degrees of latitude from the equator we see only small trees, shrubs and grasses ; and near the pole plants are represented by a few brittle byssus and lichens creeping over the surface of the ground. Climate, therefore, exercises a considerable influence on vegetation, and he would be wanting indeed who ignored it in practice. Would it not be folly to cultivate the vine at Dunkirk, maize at Valenciennes, and the olive on the plains of Beauce? These are exaggerations, I know, but under them there is a truth it would be well to remember, that in our day agriculture tends to specializations, and we should always have the climate in our favor. AVith a free commerce and facility of exchange, each region should create a mo- nopoly of its products in which it may defy competition. The English, an enlightened people, understood this long ago: wherever too great moisture of climate made the cultivation of grain unprofitable, they have substituted grasses and herds. Among the conditions acting on vegetation we have placed the composition of the soil, and in the same order of ideas the choice of manures in the second rank. You know that two fields touching each other may often be of unequal fertility. The cause of these differences is in the presence or absence of certain agents. Add to the one the elements wanting, and it will become as fertile as the other. Under this view, by the CHEMICAL MANURES. 15 use of manures man acquires an almost limitless control of nature. It is to the study of this second condition that the teaching of Vin- cennes is especially devoted. As to the second condition, that is regulated by the vegetable itself. All species are subject to certain variations, which may become hereditary. Races, varieties of small importance in a botanical point of view, but of great import in agriculture, have often the same origin. Under the same conditions of soil and manures one variety will often yield double the quantity of another. I will show you a remarkable example of this. For three years I have had blue wheat and English wheat (with red straw) under parallel culture, the soil and manures exactly alike. The blue wheat did not succeed at all ; the English wheat grew wonderfully. In autumn the blue wheat has a marked advantage over the English wheat, but in spring, affected by late frosts, it is also violently attacked by rust, while the English wheat, being more backward, escapes both entirely. There is, then, a means resting entirely upon ourselves, and to which w^e have perhaps not given sufficient attention. For myself, I believe our vegetables are susceptible of as varied changes as are our domestic animals. But I repeat, gentlemen, that of the three conditions which rule the activity and the products of vegetation, we should occupy our- selves solely with the second — the choice and the quantities of manures. I have recalled the other two, but to show the subject on all sides, and to leave nothing in obscurity, I promised you an analysis of vegetation, its agents and cause. I think I have fully kept that promise. Are you tempted to reproach me with the too scientific character of my study ? Our path was traced out by the light of these ideas. Henceforth there can be no question of empiric results. Besides, if practice is our object, science should be our guide, its methods our auxiliaries, and its principles the foundation of our deductions. Until the last twenty years it has been asserted that the farmyard was our agent " par excellence " of fertility. We maintain that to be erroneous, and that it is possible to produce better and cheaper artificial manures than can the farmyard. It has been said : The meadow is the foundation of all good agri- culture, because with the meadow we have cattle, and with the cattle, manure. These axioms are now veritable heresies. I hope to show you that agriculture to be remunerative must be founded on artificial manures. With farmyard manures it is now but a question of con- venience and cost. To determine these important views with certainty we must remain faithful to the plan traced out. In the first place, we must define the degrees of utility of the different elements of which vegetation is composed, seek the forms under which their assimilation is easiest and the useful effects the most certain, and last, form from them rules by which we may associate them to make the most powerfVil manures; 16 CHEMICAL MANURES. In our next we will broach the subject under its new view, which , . ?vill bring us into the domain of practice. L 1 11 11 A l\ f FNITER'^JTY