BERKELEY LIBRARY UNIVERSITY OF CALIFORNIA ITY OP I RNIA J EARTH SCIENCES LIBRARY TREATISE ON CRYSTALLOGRAPHY, BY W. H.jMILLER, M.A., F.R.S., F.G.S., F.C.P.S., FELLOW AND TUTOR OF ST JOHN'S COLLEGE, AND PROFESSOR OF MINERALOGY IN THE UNIVERSITY OF CAMBRIDGE. CAMBRIDGE: PRINTED AT THE PITT PRESS: FOR J. & J. J. DEIGHTON, TRINITY STREET LONDON: JOHN W. PARKER, WEST STRAND. M.DCCC.XXXIX. I EOLOGICAL SCIENCES M SOENCES LIBRARY ADVERTISEMENT. THE Crystallographic Notation adopted in the fol- lowing Treatise is taken, with a few unimportant alterations, from Professor WhewelPs Memoir "On a general method of calculating the angles of Crystals," printed in the Transactions of the Royal Society for 1825. The method of indicating the positions of the faces of a Crystal hy the points in which radii drawn per- pendicular to the faces meet the surface of a sphere, was invented by Professor Neumann of Konigsberg (Beitrage zur Krystallonomie) and afterwards, together with the notation, re-invented independently by Grass- mann (Zur Krystallonomie und geometrischen Combi- nationslehre). The use of this method led to the substitution of spherical trigonometry for the processes of solid and analytical geometry in deducing expressions for determining the positions of the faces of crystals and the angles they make with each other. The ex- pressions which in this Treatise have thus been obtained, 477 IV ADVERTISEMENT. are remarkable for their symmetry and simplicity, and are all adapted to logarithmic computation. They are, it is believed, for the most part new. For the conveni- ence of calculation the position of one face with respect to another is represented by the angle between normals to the faces, or by the supplement of the angle be- tween the faces, according to the commonly received definition of the angle between two of the planes that bound a solid. Arts. 22 24, 28 31, may be omitted by those readers who are satisfied with such a knowledge of the subject as is sufficient for the purpose of finding the elements and the symbols of the faces of a given crystal, or of determining the form and angles of a crystal, having given its elements and the symbols of its faces. CONTENTS. CHAPTER I. IMG! GENERAL GEOMETRICAL PROPERTIES OF CRYSTALS 1 Arts. 1. CRYSTAL. Faces. Cleavage Planes. 2. Law to which the mutual inclinations of the faces and cleavage planes are subject. 3 Cleavage planes are parallel to possible faces. 4. Axes. Parameters. Indices. Symbol of a face. 5. Elements of a Crystal. 6. Different systems of Axes and Parame- ters. 7- Position of a face determined by points in the axes. 8. Angles between a normal to any face and the axes. 9 Sphere of projection. Poles. 10, 11. Signs of the Indices. 12 14. Condition that a point may be in a great circle passing through two poles. 15. Symbol of the^ point in which two such great circles intersect. 16, 17- Indices of a zone in terms of the indices of two of its faces, and of a face common to two zones in terms of the indices of the zones, have the same form. 18 20. Indices of a face common to two zones in terms of the indices of two faces of each of the two zones. 21. Con- dition that a face may belong to a zone. 22. To find the poles in a given zone-circle, and the zone-circles passing through a given pole. 23, 24. Any pole having indices greater than unity is the intersection of zone-circles through poles having lower indices. 25 27. Relations between the distances and indices of four poles in the same zone-circle. 28 To change the axes. 29. To change the parameters. 30, 31. Having given the symbols of four poles referred to each of two systems of axes, and the symbol of a fifth pole referred to one of the system of axes; to find its symbol when referred to the other. 32. Systems of Crystallization. 33. Distinguished by their sym- metry. 34 Forms. Holohedral forms. HemiKedral forms. Combinations. 35 Elements of a crystal. 36 Data requisite for the determination of the elements of a crystal. CHAPTER II. OCTAHEDRAL SYSTESI 22 Arts. 37. Axes and Parameters. 38. Holohedral forms. 39 41. Hemi- hedral forms. 42 46. Position of any pole, and distance between any two poles. 47 51. Arrangement of the poles of holohedral and hemihedral forms. 52, 53. To find the indices of a form. 5467- To find the figures and angles of different forms. 68. Table of the distances of the poles of different forms from the nearest poles of the cube, dodecahedron and octahedron. 69 79. Examples. VI CONTENTS. CHAPTER III. PYRAMIDAL SYSTEM 41 Arts. 80. Axes and parameters. 81. Holohedral forms. 8284. Hemi- hedral forms. 85. To find the position of any pole. 8690. Arrangement of the poles of holohedral and hemihedral forms. 91 94. To find the distance between two poles of the same form. 95, 96. To find the indices of a form. 97 99. To find the distance between any two poles. 100. To find the para- meters. 101. To change the axes. 102 117- To determine the figures and angles of different forms. 118121. Examples. CHAPTER IV. RHOMBOHEDRAL SYSTEM 55 Arts. 122. Axes and parameters. 123. Holohedral forms. 124126. Hemi- hedral forms. 127129. To determine the position of any pole. 130132. Ar- rangement of the poles of holohedral and hemihedral forms. 133135. Dirhom- bohedral forms. 136 137- Direct and inverse zones and forms. 138 140. To find the distances between poles of the same form. 141 143. To find the indices of a form. 144. To find the distance between any two poles. 145. Hav- ing given the distance between any two poles ; to find the distance of a pole of {100} from the nearest pole of {111}. 146. To find the position of any pole, hav- ing given its distances from two of three equidistant poles of a form. 147- To change the axes. 148 164. To determine the figures and angles of different forms. 165 171. Examples. CHAPTER V. PRISMATIC SYSTEM 77 Arts. 172. Axes. 173. Holohedral forms. 174, 175. Hemihedral forms. 176. To determine the position of any pole. 177 179. Arrangement of the poles of holohedral and hemihedral forms. 180 183. To find the distance between two poles of the same form. 184, 185. To find the distance between any two poles. 186, 187- To find the indices. 188, 189. To find the para- meters. 190 198. To determine the figures and angles of different forms. 199201. Examples. CHAPTER VI. OBLIQUE PRISMATIC SYSTEM 87 Arts. 202. Axes. 203. Holohedral forms. 204. Hemihedral forms. 205. To determine the position of any pole. 206. Arrangement of the poles. 207, 208. To find the distance between any two poles. 209 212. To find the inclination of the axes and the parameters. 213. To change the axes. 214 217. To determine the figures and angles of different forms. 218 220. Examples. CHAPTER VII. DOUBLY-OBLIQUE PRISMATIC SYSTEM 95 Arts. 221. Forms. 222 224. To determine the position of any pole. 225. To find the distance between any two poles. 226, 227. To find the inclinations of the axes and the parameters. 228, 229. Examples. CONTENTS. Vll CHAPTER VIII. PAGE TWIN CRYSTALS 103 Arts. 230. Law according to which the two crystals constituting a twin are united. Twin axis. 231. Arrangement of the poles of a twin. 232. To find the twin axis. 233. Distance between the poles of a twin crystal. 234 263. Examples. CHAPTER IX. GONIOMETERS, &c 113 Arts. 264. Carangeau's Goniometer. 265 Wollaston's Goniometer. 266. To measure the angle between two faces of a crystal. 267. To determine the faces in a given zone. 268. Adjustments of Wollaston's Goniometer. 269. Signals. 270. Error arising from excentricity. 271. To eliminate the error. 272. Expansion of -crystals when heated unequal in different directions. 273. Plane angles of the faces of crystals. 274. Optical properties of crystals belonging to different systems. 275. Elements of a crystal in terms of the distances between certain poles. 276. Table shewing how poles which have no index greater than 7 may be determined by the intersection of zone-circles through poles having lower indices. 277. Comparison of different systems of crystallographic notation . CHAPTER X. DRAWING CRYSTALS AND PROJECTIONS 129 Arts. 278282. Drawing crystals. 283. Projection of the sphere on which the poles of a crystal are laid down. 284295. Stereographic projection. 296 302. Gnomonic projection. ERRATA. PAGE LINK 36 8 after Let insert the. 39 8 from bottom, insert a comma after Octahedron. 39 6 from bottom, for p'e' read p',e'. 50 2 for { 4 1 } read {430}. 81 19 for (182) read (183). 86 6 after o, a?, />, / insert belong. 86 8 for wanting read want. 87 5 from bottom, for 87 read 88. 88 7 from bottom, /or K reac? , ->_!, -O 2 ? -O-25 ->33 -O-3?5 -O 5 ^5 i",!' 25 ^-25 C 3 , C_ 3 ,..., C , be determined in the same manner from b and c respectively. Then, any face of the crystal will be parallel to a plane drawn through three points thus deter- mined, one being taken in each of the three axes. For if the face (h k /) meet the axes OX, OF, OZ in H, K, L. Then (2) l OA _ 1 OB _ 1 OC ~hOH~~k~OK~~l~OL' But, according to the notation we have adopted, , these distances being measured towards X, F, Z, or in the opposite directions, according as the corresponding indices /, k, /, are positive or negative; OA h OB k OCt .-. the face (h k I) is parallel to the plane passing through the three points A h , B k , C t . 8. To find the ratios of the cosines of the angles which a perpendicular to the face (h k I) makes with the axes of the crystal, in terms of the indices of the face and the para- meters of the crystal. Let the axes OX, OF, OZ, (fig. 3) meet the surface of a sphere described round O as a center in X, Y 9 Z, and let OP, drawn perpendicular to the face HKL, the symbol of which is (hkl), meet HKL in p, and the surface of the sphere in P. Then, Therefore, substituting these values of HO, KO, LO in (2), if AO = a, BO = 6, CO = c, we have 7 cos PX = - cos PY = C - cos PZ. h k I In all problems of Crystallography which may hereafter present themselves, we shall refer the faces of crystals to the surface of a sphere by means of radii drawn perpendicular to the faces, and all our calculations will be performed by spherical trigonometry applied to expressions deduced from the above equations. 9. The sphere to the surface of which the faces of a crystal are referred, will be called the sphere of projection. The extremity of a radius of the sphere drawn perpendicular to any face, will be called the pole of that face. A face and its pole will be usually denoted by the same letter and by the same symbol. The points in which the axes of the crystal meet the surface of the sphere of projection will be invariably denoted by X, F, Z. 10. Let the axes of any crystal meet the surface of the sphere of projection in X, Y, Z, (fig. 4). Let a, 6, c be the parameters of the crystal, ABC the polar triangle of XYZ. Then, AY, AZ are quadrants, .-. cos AY=0, cos AZ = ; .-. - cos AX = - cos AY - - cos AZ; 1 .-. (8) A is the pole of (l 0). Similarly, B is the pole of (0 1 0), and C is the pole of (0 1). 11. Let P be the pole of the face (h k 1). Then, (8) - cos PX = - cos PF= - cos PZ. h k I When P and A are on the same side of the great circle EC, PX is less than a quadrant, therefore cos PX is posi- tive. When P and A are on opposite sides of BC, PX is greater than a quadrant, therefore cos PX is negative. Hence, if we assume h to be positive in the former case, it will be negative in the latter. In like manner Jc will be positive or negative according as P and B are on the same or opposite sides of CA. And I will be positive or negative according as P and C are on the same or opposite sides of AB. When P is in the great circle BC, PX is a quadrant, therefore cos PX = ; therefore h = 0. When P is in CA, cos PY = 0, therefore k = 0. When P is in AB, cos PZ = 0, therefore I = 0. Hence, if diameters AA', BB f , CC', PP' be drawn, the symbols of the points A, B, C, P being A (l 0), B (0 1 0), C (0 1), P (h k I), those of A', B', C', P' will be A'(l 0), B' (oTo), C'(ooi), p'(hk~l). 12. X, Y, Z (fig. 5.) are any three points on the surface of a sphere; P, Q, R any three points in a great circle; to find the relation between the distances of P, Q, R from each of the points X, F, Z. 6 From the spherical triangles PQAT, J?QA", we have cos PX = cos QX cos PQ + sin QX sin PQ cos PQA", cos RX= cos QX cos QR + sin QX sin QR cos RQX. Multiply the first equation by sin Qj?, the second by sin PQ, and add, observing that cos PQA" + cos R QX = 0, and that sin QR cos PQ + cos QR sin PQ = sin PR. The equation thus obtained, and two others deducible from it by writing Y and Z successively in the place of X, cos PA" sin QR + cos R X sin PQ = cos QA" sin PR, cos PF sin QR + cos R Y sin PQ = cos QF sin PR, cos PZ sin QR + cos RZ sin PQ = cos QZ sin PR. Whence, eliminating sin PQ, sin PR, sin QR, successively, [cos PA" cos Q F - cos PF cos are [cos PA" cos ^ F - cos PF cos s sin - cos sin/> [cos PZ cos Q^T - cos PX cos QZ] [cos PZ cos .ff JT - cos PA" cos 7? Zl cos ^^ - cos Q^T cos . sin [cos PF cos QZ - cos PZ cos QF] t cos PycosRZ- cos PZ cos R F] 1 sinQ7g [cos QF cos ,RZ - cos QZ cos RY] Eliminating two of the quantities sin PQ, sin PR, sin QR, between two of the preceding equations, we obtain (cos PY cos RZ - cos PZ cos R Y) cos Q X + (cos PZ cos RX - cos PXcos R Z) cos QY + (cos PX cosRY- cos PF cos RX) cos QZ = 0. 13. Let X, F, Z be the points in which the axes of a crystal meet the surface of the sphere of projection ; P, R the poles (h k /), (p q r) ; a, 6, c the parameters of the crystal. Then (8) - cos PX= - cos PF = - cos PZ, h k I - cos R X= - cos R Y = C - cos RZ. p q r Therefore eliminating cos PX, cos PF, cos PZ, cos RX, cos R F, cosRZ between the above equations and the equation at the end of (12), we have ua cos QX + vb cos QY+ we cos QZ = 0, where u = kr Iq, v = Ip hr, w = hq - kp. 14. The great circle passing through the poles (hk I), (p q r), may be denoted by the symbol [u v w], where u, v, w have the values assigned to them in (13). Since the poles P, R may be denoted by the indices h, k, I; p, q, r, or by any numbers proportional to A, k, /; p, q, r respectively, it follows, that the great circle PR may be denoted by any three numbers proportional to u, v, w. When u, v, w have a common measure, it will be found convenient to employ as indices, the lowest whole numbers in the required ratio. 15. Let [hkl], [p q r] be the symbols of two great circles, each of which passes through the poles of any two faces not parallel to each other ; and let the great circle [h k 1] meet the great circle [p q r] in the point Q. Then, since Q is a point in each of the great circles, (13) ha cosQX + kb cosQF+lc cos QZ = 0, pa cos QX + q&cos QF + rc cos QZ = 0. Whence, eliminating cos QJf, cos QF, cos QZ succes- sively, we obtain - cos QX = - cos QF = - cos QZ, u v w where The indices h, k, 1, p, q, r are integers; .-. u, v, w are integers, and therefore (8) Q is the pole of the face (uvw). Hence, it appears that a face may always exist having its pole in the intersection of any two great circles, each of which passes through the poles of any two faces not parallel to each other. 16. When three or more faces of a crystal have their poles in the same great circle, they are said to form a zone. The great circle passing through the poles of any two faces not parallel to each other, and which, therefore, passes through the pole of any other face in the same zone with them, will be called a zone-circle. The diameter which joins its poles will be called the axis of the zone. A zone and its zone-circle will be denoted by the same symbol. 17. It appears from (13) that if [u v w] be the symbol of the zone containing the faces (hkT), (pqr), u = kr-lq, v = lp-hr, w = hq - kp, and from (13) that if (u v w) be the symbol of the face com- mon to the zones [h k 1], [p q r], 7* = kr-lq, w = lp-hr, ^ = hq-kp, 5) or, that the expressions for u, v, w, in terms of h, k, I* p, 7, r, are precisely similar to the expressions for u y v, w, in terms of h, k, 1, p, q, r. We shall sometimes find it convenient to denote the zone containing the faces (h k I), (p q r), by the symbol [Iik I, pqr~\, and the face common to the zones [hkl], [p q r], by the symbol (hkl, p q r). 18. The intersections of the faces of a zone, or of the faces produced, are parallel to the axis of the zone, and therefore, to one another. In many cases the parallelisms of the edges resulting from the intersections of a series of faces belonging to the same zone can be ascertained by simple inspection. The method of determining by observation whether a face does or does not belong to a zone contain- ing two given faces, when it does not meet them, or when the edges it makes with them are so short that their parallelism is doubtful, will be described when we come to explain the use of Wollastori's Goniometer. When, by observing the parallelism of the edges or other- wise, it has been ascertained that a face is in the same zone with two given faces, and that it is also in the same zone with two other given faces, the symbols of the two zones, and, from these, the symbol of the face which is common to them, may be found by the methods of (14) and (15). 19. The points in which any two zone-circles intersect are the opposite extremities of a diameter of the sphere of projection. Hence, (ll) the symbol of one point of intersection is obtained from that of the other by merely changing the signs of all the indices. 20. If [u v w] be the symbol of the zone-circle through the poles (h k I), (p q r), it is easily seen that [u v wj will be the symbol of the zone-circle through the poles (hkl), (pqr)\ and also that if the zone-circles [h k 1], [p q r] in- tersect (u v w)> the zone-circles [h k 1], [p q r] will intersect 2 10 in (uvw). Hence, if the zone-circles [h k I, pqr], [h 1 k f 1' 9 p q' T~\, intersect in (uvw), the zone-circles [h k I, pqr\, [h'k'l', p'q'r] will intersect in (uvw). If the zone-circles [h k I, pqr], [h'k'l', p 1 q' r'} intersect in (uvw), it is manifest that [Ihk, rpq], \l r tik', r p q'] intersect in (wuv), and that [h Ik, p r q], [h'l'k', p r q] intersect in (u w v). 21. Let Q be the pole of a face (uvw), in the zone [u v w]. Then, (IS), (8) ua cos QX + vb cos QF-f- we cos QZ 0, - cos QX = - cos QY = - cos QZ ; U' V W This equation expresses the condition that the face (u v w) may be in the zone [u v w]. Any whole numbers which, when substituted for u, v, w, satisfy the above equation, are the indices of a face in the zone [uvw]; and any three whole numbers which, when substituted for u, v, w, satisfy the same equation, are the indices of a zone containing the face (uvw). 22. When the zone-circle [u v w] passes through the pole (uvw), (21) UM + \v + vfw = 0. Hence, in order to find the poles which lie in a given zone-circle, or the zone-circles passing through a given pole, we must find the integral values (one or two of which may be zero), of at, y, %, which satisfy the equation ax + by + c% 0; where a, b, c are the indices of the given zone-circle in the former case, and of the given pole in the latter. Let the coefficients c, b be prime to each other. Trans- form c-r-6 into a continued fraction, and let c'b' be the 11 last but one of the resulting converging fractions. Then, by the rule for solving indeterminate equations of the first degree, y =t (cax me), % = =t (mb b'ax) ; where the upper or lower sign is to be taken, according as cb' is greater or less than be. The value of x being assumed, the corre- sponding values of y and % may be obtained by substituting different positive or negative whole numbers for m. 23. If the zone-circle [h k 1] passing through the poles (h k /), (h r k 1 1'), intersect the zone-circle [p q r] passing through the poles (pqr), (pV r ') ^ n ^ e P^ e (www); values of A, fc 9 /, h', &', I', p, q, r, p', q', r', can always be found, such that the three indices of each pole shall be severally numerically less than the indices u, v, w, or not greater than unity. The values of h, k> I, h' 9 k', 1' 9 p, q, r, p\ q', r must satisfy the equations uh + vk + wl = 0> up + wq + wr = 0, hh + kk + H = 0, ipp + qin SR* by the corresponding equation between sin PQ, 14 sin QR, and substituting for the ratios of the cosines the values given above, [P, Q] [S^ff ] = [Q,fl] [P,S] sin PQ sin SR sin QR sin P# ' where [P, Q] _fl-gk gh-el _ek-fh [Q, jR] "" kr-lq ~ Ip-hr ~ hq-kp ' *, j vr wg' ^jt> ur uq up Sin PQ sin SR, sin QR sin P^ must be to each other as some whole numbers. Let sin PQ sin SR _ m [S, R] _ m [Q, R] sinQR sin PS ~ n" [P, S] ~ ~n [P, Q] " Whence, , Q], , Q], When P*^ is greater than Pjff, we have [P, Q] [j, ^] = [Q, Jg] [P, ^ sin PQ sin RS sin Q# sin PS ' where [P, S] _fw -gv ^gu - ew _ ev -* fu [-ff, S] qw - rv ru-pw pv - qu Whence , R'] -np[P, Q], ] -nr[P, Q]. 26. Having given the symbols of four poles in the same zone-circle, and the distances between three of them ; to find the fourth. 15 Let [P,Qm*]s _ ~' - tan (PS - %PR) = tan 1P# tan (- - 0\ . 27. Sin Q# = sin PR sin PQ [cot PQ - cot PR], sin # = sin PR sin P#[cot PS - cot PR]. Therefore cot PS - cot P# _ [P, Q] [tf, #] cotPQ-cotPtf " [Q, fl] [P, S] ' 28. The axes of any three possible zones, not being in one plane, may be employed as crystallographic axes. Let X> Y 9 Z (fig. 7) be the points in which the axes of the crystal meet the surface of the sphere of projection ; a, ft, c the parameters of the crystal; X'^ Y', 7! the poles of any three zone-circles intersecting in A, B, (7; P the pole of any face of the crystal ; M the intersection of CA, BP-, N the intersection "of AB, CP. Let the symbols of the poles be A(efg), B(hkl), C(pqr), P(uvw), v), Nfrpv). Then (14), (15), X = (re - pg) (hv - ku) - (pf - qe) (lu - hw), u - hw ) ~ ( - Pg)(kw - Iv), TT = (gh - el)(pv - qu) - (ek -fh)(ru - pw), . p = (ek-fh)(qw-rv) -(fl-gk)(pv - qu). A N B 9 AM C are great circles ; therefore, writing X'i K, Z' for X) F, Z in (12), and dividing the equations containing JT, Y, Z' by the corresponding equations con- taining X) F, Z, we have 16 cos AX' cos NY' - cos AY' cos NX* cos AX cos NY cos A Y cos NX cos BY' cos jyjT - cos EX' cos JVT' cos AX' cos J/Z' - cos AT! cos AX cos Jf Z cos AZi cos JWJf cos CZ' cos J/Jf - cos CX' cosMZ' cosCZcosMX-cosCXcosMZ But - cos AX = - cos AY = cos e f g - cos EX = - cos #F A A; ^ - cos CX = - cos CF = - cos CZ, p q r - cos J/JT a - cos Jlf F = - cos J/Z, A yU V - cos J^^ = - cos NY - cos NZ, TT p a- = 0, cos AZ' =0, cos EX' = 0, Also cos MX' sin MB cosMZ' cos NX' sin JVC __ cosJVF' cos PX' = sin P5 * cos PZ' ' cos P^T' ~ sin PC = cos PT ' ^ (ep - fir) cos cos AX cos P.], ev - g\ = (pg re) [pw + qw + r0]. Where e = kr-lq, f=lp-hr, g = hq - kp, h = qg-rf, k = re-pg, l=pf-qe, Hence /i/ r a -, cos PX' = , cos PY' = , cos w r w ' where a', 6', c' depend only upon the angles between the old and new axes, and u = eu + fv + gw, v = hu + kv + !?, z^' = pw + qv + r^. w', u', w' are whole numbers, and therefore OX ', OF', OZ' may be taken for crystallographic axes. The coefficients of w, v, w> in the expressions for u ', t>', w', are the indices of the zone-circles BC, CA, JB, their sym- bols being EC [efg], CA [h k 1], J5 [pqr]. 29. To change the parameters of a crystal. Let (h k I) be the symbol of a face P, with parameters , 6, c; (ti k' I') the symbol of P, when referred to the same axes, with parameters a', 6', c'* Then and cos P^ = cos PF = - cos PZ, h k I a b c -,cosPX=- cosPF=-7 cosPZ; ' ~L r 1 f a a o b c c ' ' i/ t" ' 7^ ** 7" ' T^ =I T * h h k k I I 18 30. P, Q, .ft, S are four poles in the same zone-circle. When they are referred to a system of axes meeting the sur- face of the sphere of projection in X, F, Z, their symbols are P(efg), Q(hkl) R(pqr), S(uvw). When they are referred to a system of axes meeting the surface of the sphere of projection in X\ F', Z', their symbols are P(ef'g), 'A?'0, R(pq'r') 9 S(u'vw). If [P, Q] fl-gk gh -el _ ek - fh -Ar = hq-kp' [Q, R] kr-lq [P, ] /w ^" - ew ev - fu j?] vrwq wp ur uq vp we have (25) [P, Q] [P, sin PQ sin sn sin PS And if [P ; , Q'] -g'k' qti - el' e'k' -fh' [P, S'] f'w'-g'v g'u'-e'w e'v'-g'u [S r , R'] = v'r' - w'q' = w'p' - u'i> = u'q' - v'p' we have Let [p [Q, g] [P,S] [F, Q'] m [P, Q] [5, 5] [Q', R'] n ' whence [*". n 19 31. Having given the symbols of four poles P, Q, R, S, (fig. 8.) when referred to each of two systems of axes OX, OF, OZ; OX', OF', OZ', and the symbol of any other pole referred to the axes OX, OF, OZ ; to find its symbol when referred to OX', OF', OZ'. Let P, Q, R, S be the poles ; ABC the polar triangle of X' F' Z'. Therefore the symbols of A, B, C, when referred to OX', OF', OZ', will be A (l 0), B(0 1 0), C(0 l). Let PQ, RS meet each other in T, and let them meet EC in U, V. The symbol of T may be found when referred to OX, OF, OZ and also when referred to OX', OF', OZ'; and the symbols of 7, V may be found when referred to OX', OV, OZ'. The symbols of P, Q, T when referred to OX, OF, OZ, and to OX', OF', OZ', and the symbol of U when referred to OX', OF', OZ', being known, the symbol of U may be found when referred to OX, OF, OZ. In like manner may be found the symbol of V when referred to OX, OF, OZ. Hence may be found the symbol of the zone- circle BC when referred to OX, OF, OZ. In like manner may be found the symbols of CA, AB referred to OX, OF, OZ. Hence, the symbols of the zone-circles being known, the symbol of any pole when referred to OX', OF', OZ' may be found by (28). 32. In many crystals axes may be discovered which make right angles with each other ; in others, axes of which one is perpendicular to the other two, and in others axes making equal angles with each other. In the crystals with equiangular axes, and in some of the crystals with rectangular axes, equal parameters may be found, and, among the remain- ing crystals with rectangular axes, some which have two of the parameters equal. Upon the differences in the positions of the axes with respect to each other, and in the relation between the parameters, above enumerated, is founded the arrangement of crystals in systems. 1. In the Octahedral system the axes are rectangular and the parameters equal. 20 2. In the Pyramidal system the axes are rectangular and two of the parameters equal. In this system we shall always suppose a and b equal. 3. In the Rhombohedral system the axes make equal angles with each other, and the parameters are equal. 4. In the Prismatic system the axes are rectangular. 5. In the Oblique-Prismatic system one axis is perpen- dicular to each of the other two. We shall always suppose the axis OF perpendicular to each of the axes OZ and OX. 6. The Doubly-Oblique-Prismatic system includes all crystals which cannot be referred to either of the preceding systems. 33. The different systems of crystallization are further distinguished by the various kinds of symmetry observable in the distribution of the faces of the crystals belonging to them. For, if a face occur having the symbol (h k I), it will generally be accompanied by the faces having for their symbols certain arrangements of A, i k, /, determined by laws peculiar to each system, and which will be fully explained when we come to describe each system separately. 34. " A form " in crystallography is the figure bounded by a given face and the faces which, by the laws of symmetry of the system of crystallization, are required to coexist with it. A form will be denoted by the symbol of any one of its faces enclosed in braces. Thus, the symbol JA k l\ will be used to express the form bounded by the face (h k I) and its coexistent faces. The " holohedral forms " of any system are those which possess the highest degree of symmetry of which the system admits. " Hemihedral forms" are those which may be derived from a holohedral form by supposing half of the faces of the latter omitted according to a certain law. The figure bounded by the faces of any number of forms, is called a " combination" of those forms. 21 35. The elements of a crystal are the inclinations of the axes FZ, ZX, XY, and the ratios of two of the parameters a, 9 by c to the third. In the octahedral system, where the axes Are rectangular and parameters equal, all the elements are determined. In the pyramidal system, where the axes are rectangular and two of the parameters are equal, the ratio of either of them to the third, is the only variable element. In the rhombohedral system, where the axes make equal angles and the parameters are equal, the angle between any two of the axes is the only variable element. In the prismatic system, where the axes are rectangular, the ratios of two of the parameters to the third, are two variable elements. In the oblique-prismatic system, where one of the axes is at right angles to the other two, the inclination of the two axes which are perpendicular to the third, and the ratios of two of the parameters to the third, are three variable elements. In the doubly-oblique-prismatic system, the angles between the axes, and the ratios of two of the parameters to the third, are all variable. 36. The angle between two faces, the symbols of which are known, may be expressed in terms of the indices of the faces, the inclinations of the axes, and the ratios of the parameters. Therefore, one observed angle between two known faces, in the pyramidal and rhombohedral systems; two observed angles in the prismatic; three in the oblique prismatic, and five in the doubly-oblique-prismatic system, are sufficient to determine the variable elements in the re- spective systems. In the three latter systems, however, except in particular cases, the above direct method of find- ing the elements of a crystal is impracticable on account of the high dimensions of the resulting equations. Methods of deducing the elements of a crystal from the requisite number of angles between faces properly selected, adapted to each particular system, will be given in the chapter devoted to that system. CHAPTER II. OCTAHEDRAL SYSTEM. 37. IN the octahedral system the crystallographic axes are at right angles to each other, and the parameters , 6, c are all equal. 38. The holohedral form \hkl\ is bounded by all the faces having for their symbols the different arrangements of =t A, J= &, /, taken three at a time. When A, A;, / are all different, they afford the forty-eight arrangements con- tained in the annexed table. When the values of any two of the indices are equal, or when one of them is zero, the number of arrangements will reduce itself to twenty-four. When two of the indices are equal, and the third is zero, the number will be twelve. When the three indices are equal, it will be eight, and when two indices are zero, it will be six. h k I k I h Ihk Ikh k h I h Ik hll klh Ihk Ikh khl hll hkl h I h Ihk Ikh Ihl h I h hi I klh Ihk Ikh kh I hlk 111 klh Ihk Ikh khl hll hk I k Hi Ihk Ikh kh I h Ik hi I klh Ihk I kh kh I hlk hkl k 1 7i I hi I k h khl h I I -23 If we suppose // to be the greatest, and / the least of the three unequal indices /*, &, /, fig. 9, will represent the dis- tribution of the poles of the form {hkl\ on the surface of the sphere of projection. Fig. 10. exhibits the poles of the forms obtained by substituting zero for one of the indices, or by making two of them equal. Both figures shew the poles of the forms {lOOJ, {ill} and {011^. 39. The form bounded either by all the faces of \hkl\ which have an odd number of positive indices, or by all the faces of {h k 1} which have an odd number of negative in- dices, is said to be hemihedral with inclined faces, and will be denoted by the symbol ic{hkl} 9 where (h k I) is the symbol of any one of its faces. The hemihedral form bounded by the faces which have an odd number of positive indices, is said to be direct. The form bounded by the faces which have an odd number of negative indices, is said to be in- verse. The upper and lower halves of the table in (38), contain the symbols of the faces of the direct and inverse forms respectively. If the surface of the sphere of projection be divided into eight triangles by zone-circles through every two of the poles of the form {l 00}, the poles of the direct hemi- hedral form will be found in four alternate triangles, one of which contains the poles of (ill); and the poles of the inverse hemihedral form will be found in the remaining four alternate triangles 40. The form bounded either by all the faces of {h k l\ the indices of which stand in the order h k I h k, or by all the faces of \h k /} the indices of which stand in the order Ik h I k, is said to be hemihedral with parallel faces, and will be denoted by the symbol ir\hkl\^ where (h k I) is the sym- bol of any one of its faces. The form is said to be direct or inverse according as the numerical values of the indices of one of its faces are in ascending or descending order. The symbols of the faces of the direct and inverse forms are 24 contained respectively in the right and left halves of the table in (38). If the surface of the sphere of projection be divided into twenty-four triangles by zone-circles passing through every two of the poles of the form {l 1 1^, the poles of the direct hemihedral form will be found in twelve alternate triangles one of which is (l 1 1) (0 1 0) (i i 7), and the poles of the inverse form will be found in the remaining twelve alternate triangles. 41. Any number of holohedral forms may occur in combination with each other, and with any hemihedral forms with inclined faces, or with any hemihedral forms with parallel faces. It is said that hemihedral forms with in- clined faces have never been observed in combination with hemihedral forms with parallel faces. 42. To find the position of the pole of any face. Let the axes of the crystal meet the surface of the sphere of projection in X^ F, Z, (fig. 11); and let P be the pole of the face (h k 1). The axes are rectangular ; therefore FZ, Z X> XY are quadrants, therefore cos FZ = 0, cos ZX = 0, cos XY = 0, therefore X, F, Z are the poles of the faces (100), (010), (0 1) respectively. The quadrantal tri- angles PYX, PYZ give (cos PY) 2 = (sin PX) 2 (cos PXY)\ (cos pzy = (sin p^) 2 (cos pxzy. Add, observing that (cos PXY)* + (cosP^Z) 2 = 1, and that (cos PX)* + (sin PX) Z =1, and we have (cos PX)~ + (cos PY) 2 + (cos PZ) 2 = 1. The parameters are equal, therefore (8), - cos PX = - cos PY = - cos PZ, h K I 25 h* 43. To find the distance between the poles of any two faces. Let P (fig. 11) be the pole of (h k I), Q the pole of (p q r). cos PXQ = cos PXY cos QXY + sin PXY sin QXY, = cos P^Fcos QXY + cos PXZ cos QXZ. Substituting this value of cos PXQ in the equation cos PQ = cos PX cos QX + sin PX sin Q X cos PXQ, and observing that sin P^cos PXY = cos PF, sin Q^cos Q^F= cos QF, sin P^Tcos PXZ = cos PZ, sin Q^T cos QJTZ = cos QZ, we get cos PQ = cos P^cos QX + cos PFcos QF + cos PZ cos QZ. But (42) .-. cos PQ 4 44. The three quadrantal triangles FPZ, ZPX, XPY, give cos PX = sin PY cos PYX = sin PZ cos PZX, cos PF = sin PZ cos PZF = sin PXcos PJfF, cos PZ = sin PXcos PXZ = sin PFcos PFZ. Whence tanP^F=- 5 tan PFZ =7, tanPZ^=^. k I h 45. Let be the pole of the face (l 1 l), /. (42), = , (cos OF) 2 = 1, (cosOZ) 2 = l; whence (43), OJT=OF=OZ, and FZ, Z^T, -^F are quadrants. Hence, the angles FOZ, ZOX, XOY are each equal to 120, and OX, OF, OZ bisect the right angles F^Z, ZYX 9 XZY. From the triangle POX we have cot P-^sin XO = cos XO cos OJTP + sin O^TPcot POX. If we write F, Z successively in the place of X, and sub- titute for the trigonometrical ratios their values in terms of h, k> I, we obtain 46. It appears from the form of the expressions in (43), that the distance between the poles of the faces (hkl)> (pq r) is equal to the distance between the pole of any face of the form [hkl], and the pole of any face 27 of the form {pqr}, in the symbols of which the order and signs of h, k, I are the same as the order and signs of p, q, r. 47. It appears from the expressions in (42), that if the symbols of two poles of the form \h kl\ differ only in the sign of h, the two poles will be equidistant from (0 1 0) and also from (0 l), therefore the arc joining the two poles will be bisected at right angles by the zone-circle [0 1 0, 00 l]. Hence the poles of \h k l\ are symmetri- cally arranged with respect to the zone-circle [0 1 0, l]. In like manner it may be shewn, that the poles of \hkl\ are symmetrically situated with respect to any one of the three zone-circles that can be drawn through every two of the poles of {l 00^. 48. It appears from (43), that if the symbols of two poles of the form {h k l^ differ only in the arrangement of the 2nd and 3rd indices, the poles will be equidistant from (I i i) and also from (l 1 l), therefore the arc joining the two poles will be bisected at right angles by the zone- circle [111, ill]. Hence the poles of \h k 1} are sym- metrically arranged with respect to the zone-circle [I l l, l l l]* In like manner it may be shewn, that the poles of {A k 1} are symmetrically arranged with respect to any one of the six zone-circles that can be drawn through every two of the poles of {l 1 l}. 49. If zone-circles be drawn through every two of the poles of |lOO|, and through every two of the poles of { 1 1 1 J , they will divide the surface of the sphere of pro- jection into forty-eight right-angled triangles. The poles of ^h k /| are symmetrically arranged with respect to any side of any one of the triangles. Hence the arrangement of the poles will be symmetrical in any two adjacent triangles, and similar in any two alternate triangles. 50. If zone-circles be drawn through every two of the poles of {100} , and through every two of the poles of 28 ^ 1 1 1 } , the zone-circles of one set bisect symmetrically the triangles formed by the zone-circles of the second set. Hence, the poles of K \hkfy are symmetrically arranged with respect to the zone-circles drawn through every two of the poles of {l 1 ij; and the poles of TT \hkl} are symmetrically arranged with respect to the zone-circles drawn through every two of the poles of {lOO}. 51. If we examine the situations of the poles of two hemihedral forms, either with inclined or parallel faces, de- rived from the same holohedral form, one of them being direct and the other inverse, we shall find that the two forms are identical in all respects, position excepted, and that one of them may be brought into the position of the other by making it revolve through a right angle round any one of its crystallographic axes. In like manner, the combinations of a holohedral form with a direct and inverse hemihedral form differ only in position. But in the combinations of any two hemihedral forms with inclined faces, or of any two hemihedral forms with parallel faces, with each other, the poles of the two forms lie in the same or in different tri- angles according as they are of the same or different deno- minations. Hence a combination of two direct, or of two inverse hemihedral forms, is essentially different from the combination of the same hemihedral forms, when one of them is direct and the other inverse. 52. If the distance between the poles of any two faces of either of the forms {hkO\, {hkk} be given, and we ex- press the cosine of the given distance in terms of the indices of the faces, we obtain an equation from which the ratio of the indices may be deduced. 53. If the distances between the pole of any face of the form \hkl\, and the poles of each of two other faces of the same form be given, and we express the cosines of the given distances in terms of the indices of the faces, we shall obtain two equations from which the ratios of the indices may be readily found. 54. To determine the figure and angles of the form \hkl\, when h, k, I take particular values. The angle between normals to any two faces, which is measured by the angular distance between their poles, is found by substituting the indices of the faces for A, A;, /, p, q, r in the expressions of (43). The letter placed upon the edge resulting from the intersection of any two faces, in the figures which accompany the description of each par- ticular form, will be used to denote the angle between nor- mals to the two faces. The same letter will be placed upon all the edges at which equal angles are formed by the in- tersecting faces. The relative positions of the poles of the different forms are shewn in figs. 9, 10, and in fig. 37, which is the gnomonic projection of one of the octants into which the surface of the sphere of projection is divided by the zone-circles through every two of the poles of the form {l 00}. The number of faces of each holohedral form has been already determined in (38). 55. The form {lOO} (fig. 12) has six faces, and is called a cube. Hence, the faces of the form {l 00} are parallel to those of a cube. 56. The form {ill} (fig. 13) has eight faces, and is called an octahedron. cosZ> = l, .-. Z> = 70.3l',7. Hence, the faces of the form {ill} are parallel to those of a regular octahedron. The cosine of the angle between normals to any face of the octahedron and either of the adjacent faces of the cube is \^%. Hence, a normal to any face of the octahedron makes an angle of 54. 44', 15 with the normals to each of the adjacent faces of the cube, and an angle of 125.15',85 with the normals to each of the three opposite faces of the cube. 30 57- In the hemioctahedron with inclined faces /c{l 1 l} (fig. 14), cos T = - ^, .'. T = 109.28',3. Hence, the hemihedral form K \ 1 1 1 } is a regular tetrahedron. 58. The form {01 l (fig. 15) has twelve faces, and is called a dodecahedron. cos If normals to any two alternate faces, meeting at their acute angles, make an angle D with each other, cos D = 0, The cosine of the angle between normals to any face of the dodecahedron and either of the adjacent faces of the cube is i> -y^' The cosine of the angle between normals to any face of the dodecahedron and either of the faces of the cube, not parallel to the two adjacent faces, is 0. Hence, a normal to any face of the dodecahedron makes an angle of 45 with the normals to each of the two adjacent faces of the cube; an angle of 135 with the normals to each of the two opposite faces, and an angle of 90 with the normals to each of the two remaining faces. The cosine of the angle between normals to any face of the dodecahedron and either of the adjacent faces of the octahedron is -^ ^/6. The cosine of the angle between normals to any face of the dodecahedron and either of the faces of the octahedron, not parallel to the adjacent faces, is 0. Hence, a normal to any face of the dodecahedron makes an angle of 35.15',85 with the normals to each of the two adjacent faces of the octahedron; an angle of 144. 44', 15 with the normals to each of the two opposite faces, and an angle of 90 with the normals to each of the four remain- ing faces. 59. The form \h k 0} (fig. 16) has twenty-four faces and is called a tetrakishexahedron. 2 hk h 2 cos F = , cos G = . 31 In 1 2 1 oj, cos F = - , cos G = - , 5 5 .\ F=36.52',2, G = 36.52',2. In {310}, cos.F = , cosG= , .'. / 1 =53.7',8, G = 25.50',5. 12 In {3 20}, cosF = , cos (3 = , 1 > 13 20 25 In {520|, cosF= , cosG = , 29 29 .'. F = 46.23 ; ,8, G = 30.27'. The tangent of the angle between normals to any face of {hko} and the nearest face of {100} is k-r-h. 60. In the hemitetrakishexahedron with parallel faces (fig. 17), h being greater than A;, A 9 = -, cos{7=-, 5 5 In7r{023|, cosD= , cos (7= , 13 13 7 12 In 7r{034{, cos D = , cos U = , 25 25 ' .-. D=x 73. 44,4, f7 = 6l 32 61. The form {h k k} (fig. 18), h being greater than A?, has twenty-four faces, and is called an icositessarahedron. cos D = - - , cos F = 4< 5 In |21l}, cosZ> = -, cosF=-, .'. D = 48. 11,5, .F=33 .33',4. Q 7 In {311}, cosZ> = , cos/" = , .-./> = 35. 5', 8, F= 50.28',7. 62. In the hemiicositessarahedron with inclined faces K [hkk} (fig. 19), In:{21l}, cosF=-, cosT 7 ^:-, .-. F=33.33',4, 7 7 =70.3l',7. 7 7 In/c{31l}, cosF= , 0087" = , .*. jP = 50. 28',7, T = 50. 28',7. 63. The form {h h k} (fig. 20), h being greater than A:, has twenty-four faces, and is called a triakisoctahedron. cos D = -T T cos 8 7 In {22lJ, cosG=- ? cosZ)=- 5 i/ y .-. G = 27.l6', Z)=38 .56,5. 33 15 17 In J331}, cosG= , cosD= , ^ i/ J-J/ .-. G = 37. 51' ,8, D = 26. 3l',5. 64. In the hemitriakisoctahedron with inclined faces K {hhk} (%. 21), o In /e{22l, cosG = -, cosjP=0, y .-. G = 27. 16', 7 7 =90. 65. The form {h kl\ (fig. 22) has forty-eight faces, and is called a hexakisoctahedron. h 2 +k 2 +l 2 12 13 13 , cosD= , cosF= , 008^ = , 14 14 14* = 31.0',2, J F=21.47',2, 6? = 21.47',2. 24 25 22 InH3l}, cosZ> = , cosF = , cosG= , 2o 26 26 .-. D = 22. 37',2, F = 15. 56 r ,5, G = 32. 12',2. 19 17 20 In {4 2l}, cosZ>= , cosF= , cosG= , A /) = 25. 12',5, F = 35. 57', G = 17. 45,1. 57 43 55 In{731J, cos/> = , cosjF= , cos G = , .'. D = 14. 57',7, F = 43. 12 ; ,8, G = 21. 13',2. 5 34 Injll53|, cosZ)= , cosF= , cos G = , 155 155 155 .-. D = 27. 53',2, JF = 39. 50',9, G=13.2',7. 66. In the hemihexakisoctahedron with inclined faces *Jj (fig. 23), 13 13 5 In;{32l}, cosj^ , cosG J = , cos T= , 14 14 14 .-. jP = 21. 4/,2, 6r = 21.47',2, 7 7 =69. 4',5. 31 SI 1 Q In/c{53l}, cos^, cosG= , 087"= , o5 35 35 .-. F = 27. 39' 5 7, G = 27. S9',7, T=577 / ,3. 67. In the hemihexakisoctahedron with parallel faces, Tr{lkh} (fig. 24), h*+k*-l* h*-k*+P kl + lh ' cosw = In7r{l23|, cos W= , cosZ> = , cosC7= .-. J7=64.37',3, Z) = 30.0' ? 3, C7=38. 12',8. In TT \ 1 2 4 } , cos W= , cos D = , cos U = , 21 21 21 /. PT= 51.45',3, D = 25. 12',7, U= 48. 11 ',3. 17 ^? ^? Q Q In7r{l35}, cos TF= , cosZ>= , 008^7 = , 35 35 35 .-. PT=29.3,5, Z>=19.27',8, U=*8.5!>'. 35 68. Of the preceding forms, those which have the simplest indices, the cube {lOO}, octahedron {ill} and dodeca- hedron {oil} occur much more frequently than the others. It does not appear that any cleavages have been observed except parallel to the faces of one or more of the three forms {100}, .{Hi}, {OH}. TABLE of the distances between the poles of the common- est forms, and the nearest poles of the forms JlOOj, {Oil}, {111}. 100 010 001 Oil 101 110 111 210 ' 26.34 o / 63.26 ' 90. i 71.34 / 50.46 f 18.26 t 39.44 310 18.26 61.34 90. 77. 5 47.52 26.34 43. 5 320 33.41 56.19 90. 66.54 53.58 11.19 36.49 410 14. 2 75.58 90. o 80. 7 46.41 30.58 45.34 430 36.52 53. 8 90. 64.54 55.33 8. 8 36. 4 520 21.48 68.12 90. 74.47 48.58 23.12 41.22 540 38.40 51.20 90. 63.47 56.29 6.20 35.45 211 35.16 65.54 65.54 54.44 30. 30. 19.28 311 25.14 72.27 72.27 64.46 31.29 31.29 29.30 122 70.31 48.11 48.11 19.28 45. 45. 15.48 133 76.44 46.30 46.30 13.16 49.33 49.33 22. 321 36.42 57.41 74.30 55.28 40.54 19. 6 22.13 421 29.12 64. 7 77.24 62.25 39-31 22.13 28. 8 431 38.20 53.58 78.41 56.19 46. 6 13.54 25. 4 531 32.19 59-32 80.16 61.26 44.11 17. 1 28.35 731 24.18 67. 1 82.31 68.24 42.34 22.59 34.14 36 EXAMPLES. 69. In a crystal of Tin-white Cobalt Pyrites, (fig. 25.) the normals to the faces a, a', &c. make right angles with each other, and a normal to any of the faces d, d', &c. makes an angle of 45 with a normal to either of the adjacent faces a, a', &c. Hence, (55), (58), a, a', &c. are the faces of the cube {lOOJ, and d, d', &c. are the faces of the dodecahedron \ 1 1 } . Let symbols of the faces be a (100), a' (010), a" (001). Therefore d (Oil), d' (l 1), d" (110). o is in the zone ad, and also in the zone ad'. The symbols of these zones are ad [o 1 T] ad' [Tlo](l4). Therefore (15) o is (l 1 1), therefore o is a face of the octahedron Jill}. Hence the crystal is a com- bination of the forms {l 0}, {011}, {in}. 70. In a crystal of Fluor (fig. 26), normals to any two adjacent faces o make with each other an angle of 70. 3l'l, therefore (56) o, o', &c. are the faces of the octahedron {ill}. A normal to any face / makes an angle of 22 with a normal to the adjacent face o. The edges in which any two adjacent faces f meet each other and the adjacent faces o are parallel, therefore the faces f are in the same zone with two adjacent faces o. Let o be (l 1 1), o (I l 1), there- fore the zone oo will be [o 1 I], therefore (21) the symbol of / will be (khh), and that of / (khh). If P 9 Q be the poles of /, /, PQ = 70. 31' 1-2.22= 26. Si' 1 , and 2 A 8 -A? 8 17 h 2 h ^-^ = cosPQ = cos260.31 i = -, ,.-= 9 , - - 3. Therefore / is a face of the triakisoctahedron { 3 3 1 } . Hence the crystal is a combination of the forms |lll}, {33l}. It is cleavable parallel to the faces of {ill}. 71. In a crystal of Fluor (fig. 27), the angle between normals to any two adjacent faces n are alternately 35. 57' and 17. 45', the angle between the normals to the faces 37 that meet in a long edge being the greater of the two. Let X, O be the poles of (l 0), (ill); {hkl\ the symbol of the form bounded by the faces n; P the pole of (hkl), Q the pole of (k h I) and R the pole of (hlk). Then PQ = 35.57', PR = 17. 45'. cosPQ > = 1Z ' 21' 20 - cosPJZ- (A -&) (A;-/) Whence (ft-0 2 h 2 +k 2 +l* 9_ 21 k*+2hl 12 (h+k+l) 21 Whence & = 2/, A = 4/, .-./=!, A; = 2, A w, w', &c. are faces of the form {42l|. 49 21 4. Hence 72. In a crystal of Boracite (fig. 28), normals to any two adjacent faces a makes right angles with each other, they are therefore the faces of a cube. Let their symbols be a (l 0), a (0 1 0), a" (0 l). A normal to d'' makes an angle of 45 with a normal to either of the faces a, a', therefore (58), d" is (l 1 0). Similarly d' is (l l), and d is (0 1 1). o is common to the zones ad, ad', therefore (56) o is (l 1 1). The number of faces o is four. But the ho- lohedral form {ill} has eight faces. Therefore o, o, &c. are the faces of the hemioctahedron AC { 1 1 1 } . Hence the crystal is a combination of the forms ^100}, Jl!0},/c{lll}. 73. In a crystal of Magnetic Iron Oxide, (fig. 29), normals to any two adjacent faces o make with each other an angle of 70. 31 7 ^. Therefore o, o', SEC. are the faces of the octahedron { 1 1 1 \ . Let the symbols of the faces be o (1 1 1), o' (i i l), o" (l 1 1), o" (III). A normal to any face d makes angles of 35. 16' with normals to any two adjacent faces o, therefore d, d' 9 &c. are the faces of the 38 dodecahedron JO 1 lj, e is common to the zones oo'", do", the symbols of which are oo"' [Toi], do" [21 l], therefore (15), e is (131); therefore e, e, &c. are faces of the ico- sitetrahedron ^3 1 l\. Hence the crystal is a combination of of the forms {ill}, {oil}, {31]}. 74. In a crystal of Garnet (fig. 30), the normals to any two adjacent faces d make with each other an angle of 60, therefore d, d' ', &c. are the faces of the dodecahedron {Oil}. Let their symbols be d (01 l), d' (l 1), d" (1 1 0). e is in the zone dd', and makes equal angles with d, d'. The zone-circle [ill, ill] bisects the arc dd f (48), there- fore it contains the pole of e. Therefore e is (l 2 1). Similarly e t is (12!). s is in the zone e'e t \ it is also in the zone dd', therefore (15), s is (12 3). Hence the crystal is a combination of the forms {oil}, {21l}, {l23}. It is cleavable parallel to the faces of {0 1 l}. 75. In a crystal of Silver-white Cobalt from Tunaberg (fig. 31), normals to any two adjacent faces a make an angle of 90 with each other, they are therefore the faces of the cube. Let their symbols be a (l 00), a (0 1 0), a" (001). The angle between a normal to any face o and a normal to any of the adjacent faces a is 54. 44, therefore (56) o is (l 1 1). The edges which d" make with a and a are parallel, therefore d" is in the same zone with , a'; therefore the symbol of d" will be (hkO). It is found that normals to #', d" make an angle of 26. 34'. Therefore (42) k 2 h - = (cos 26. 34 X ) 2 , .-. - = tan 26. 34' = -L .'. d" is (1 2 0). A 2 + k* k The number of faces d is twelve, the number in the holohc- dral form {012} being twenty-four. Hence the crystal is a combination of the forms {lOO}, {ill}, ?r{oi2}. The crystal is cleavable parallel to the faces of {l 0}. 76. In a crystal of Silver- white Cobalt (fig. 32), the symbols of p, a, r, k are p (l 0), a (l 1 l), c (l 2 0), k (l 40). 39 i is in the zone ac, and normals to a, i make, according to Phillips, an angle of l6.33'. Let (h k I) be the symbol of i The symbol of the zone ac is [2 1 l], therefore (21) 2A = k + /. Als () * 2 + + = < cos 16 - 33 ') 2 - whence 7 - T' ver y /*+/+ I i nearly, therefore / = 7, & = 15, ^ = 11. The number of faces e, adjacent to* , is three, therefore e is a face of the form 7r{7 11 15}. 77- In a crystal of Yellow Iron Pyrites (fig. 33), a is a face of the cube, o a face of the octahedron. Normals to s, a make with each other an angle of 57. 41, and normals to s, o make with each other an angle of 22. 13'. Let the symbols of the faces be a (l 0), o (l 1 l), s (h k I) ; and let J, O, S be the poles of a, o, s. Then SA = 57. 4l', SO = Whence 2& = 3h, 2l = h, .'. I = 1, ^ = 2, & = 3, .-. sis (231). In the holohedral form { 1 2 3 ^ , and in the hemihedral form with inclined faces, there are six faces on one angle of the cube. In the present case there are only three. Hence s, s', s" are faces of the direct hemihexakisoctahedron with parallel faces ?r{l23}. The crystal is cleavable parallel to the faces of the forms }l 00}, {ill}- 78. In a crystal of Yellow Iron Pyrites (fig. 34), p, p\ p" are faces of the cube, d a face of the octahedron py" e" p', p" sfds'e", p'f'y", pod, dfe are zones; and the normals to p f e' make an angle of 26. 34'. Let the symbols of p 9 p', p" be (1 0), (0 I 0), (0 1), then d will be (l 1 1). e" is in the zone pp', therefore its symbol will be of the form (hkO); therefore if F, P be the poles of p' 9 e", (cos PF) 2 = ** , rt -f- rC .'. - =tanPF=tan26.34' = i, .-. e" is (120). In like K manner e' is (201), and e is (012). o is common to the 40 zones pd, p'e, therefore o is (2 1 1). s is common to the zones pe, p" e\ therefore s is (1 2 4). /is common to the zones de, p"e") therefore f is (l 2 3). y is common to the zones pf, p'p", therefore y is (0 2 S). There is only one face e, and one face y, between every two adjacent faces of the cube ; and only three faces/, and three faces s, round each of the faces d; therefore e, q, /, s belong to hemihedral forms with parallel faces. Hence, the crystal is a combination of the forms Jill}, {100}, {211}, 7r{012}, 7r{023}, 7r{l2S}, 7r{l24}. 79. In a crystal of Fahlerz (fig. 35), /, /, /' are the faces of the cube. Each of the faces d, d', &c. is in the same zone with the two adjacent faces a, and makes equal angles with them, therefore d, d', Sec. are faces of the dodecahedron. Let /, /, /" be (1 0), (0 10), (003) respectively, therefore d, d', &c. will be d (0 1 1), d f (l l), d" (l 1 0), d t (l o I), p is com- mon to the zones f f d^f'd r > therefore p is (i i 1). r" is com- mon to the zones dd f , f ft d", therefore r" is (112). In like manner we have / (l 2 1), r t (2 1 T) ? r n (l 2 I), s is common to the zones//', rV, therefore s is (l 3 0). n is common to the zones f ff d" 9 r f r ff9 therefore n is (3 3 1). The edges and solid angles formed by r, /, T" are not truncated by any faces corresponding to p, n, therefore p 9 n belong to hemihedral forms with inclined faces. Hence the crystal is a combination of the forms {lOO}, {no}, /c{lll} ? {310}, {21]}, ~ CHAPTER III. PYRAMIDAL SYSTEM. 80. IN the pyramidal system the crystallographic axes make right angles with each other, and two of the parameters, a, b are equal. 81. The holohedral form {hkl} is bounded by all the faces which have for their symbols the different arrangements of =fc h 9 A;, /, in which / holds the last place. When h, k 9 I are all different they afford the sixteen arrangements contained in the annexed table. When one of the indices is zero, or when h, k are equal, the number will be eight. When I is zero and h = k, or when one of the indices h 9 k is zero, the number will be four. When h and k are zero it will be two. Jik I kh I hkl khl hk I khl hkl khl khl hkl kh I hkl khl hkl kh I hk I n> iv v lit n i> n, it/ v 10 n / If we suppose h to be greater than k 9 fig. 38 will represent the arrangement of the poles of the form {h k l\ on the surface of the sphere of projection. 82. The form bounded either by all the faces of {hk 1} which have an odd number of positive indices, or by all the faces of \h k l\ which have an odd number of negative indices, is said to be hemihedral with inclined faces, and will be denoted by the symbol K\h k /}, where (h k I) is the symbol of any one 6 42 of its faces. The hemihedral form bounded by faces which have an odd number of positive indices is said to be direct. The form bounded by faces having an odd number of negative indices is said to be inverse. The symbols of the direct form are contained in the first and second columns, those of the in- verse form in the third and fourth columns of the table in (81). If the surface of the sphere of projection be divided into eight triangles by zone-circles through the poles of { 1 } and {lOO}, the poles of the direct form will be found in four alternate triangles one of which contains the pole of (ill). The pole of the inverse form will be contained in the remain- ing four alternate triangles. 83. The pyramidal system admits of a second hemihedral form with inclined faces, which is bounded by all the faces of {hkl\, in which the order of h, k changes with the sign of I, and which will be denoted by the symbol K '{h kl}, where (h k I) is the symbol of any one of its faces. The form is said to be direct or inverse, according as the first index is greater or less than the second, when the three indices have the same sign. The symbols of the faces of the direct form are contained in the first and fourth columns, those of the inverse form in the second and third columns of the table in (81). If the surface of the sphere of projection be divided into eight triangles by great circles through the poles of {001} and \1 1 0}, the poles of the direct form will be found in four alternate triangles, one of which contains the pole of (l 1). The poles of the inverse form will be found in the remaining four alternate triangles. 84. The form bounded by all the faces of {h kl}, in which the order of h, k is the same or different according as A, k have the same or different signs, is said to be hemihe- dral with parallel faces, and will be denoted by the symbol 7r{h k l^j where (h k 1) is the symbol of any one of its faces. The form is called direct or inverse according as the first index is greater or less than the second, when the two indices have 43 the same sign. The symbols of the faces of the direct form are contained in the first and third columns, those of the in- verse form in the second and fourth columns of the table in (81). If the surface of the sphere of projection be divided into eight lunes by zfcne-circles through the poles of (0 1) and the poles of Jl Oof, {ll Q}J the poles of the direct hemihedral form will be found in four alternate lunes, one of which is (l 0), (110); and those of the inverse form in the remaining four alternate lunes. 85. To find the position of any pole. Let the axes of the crystal meet the surface of the sphere of projection in X, F, Z (fig. 39). Let a, a, c be the parame- ters of the crystal ; P the pole of (hkl). Since the axes of the crystal are rectangular, FZ, ZJT, XY are quadrants, therefore cos FZ = 0, cosZ^T=0, cosJ5TF=0, therefore JT, F, Z are the poles of (l 0), (0 1 0), (0 1), and the angles at X^ F, Z right angles. cos PX = sin PY cos PYX = sin PZ cos PZX, cos PY = sin PZ cos PZF = sin PJTcos PXY, cos PZ = sinPJTcosP^Z = sin PFcos PFZ. cot PX = tan PZF cos P^F - tan PFZ cos PXZ, cot PF = tan PXZ cos PFZ = tan PZXcos PF^, cot PZ = tan PYX cos PZ^T = tan P^Fcos PZF. But - cos PX = ? cos PF = - cos PZ. h k I Whence tan P^F= \ - , tan PF^= [ - , tan PZX = \ . kc he h 44 cot PX= - cos PXY = h - cos k la cot PF = - cos PF^T = - - cos PFZ, A e a cot PZ = - - cos PZJT = - - cos PZF, ^ c k c 86. The poles of { 1 1 0} bisect the arcs joining any two adjacent poles of {l 00^. For if N be any pole of {l 1 OJ; X> Y the adjacent poles of {lOO}, it will be found that cot NX =1, cotJVF=l, therefore NX, NY are each 45, therefore N bisects XY. 87- It appears from the form of the expressions in (85), that the distances of the poles of \hkl} from the nearest of the two poles (001), (ool) are all equal; and that the angles subtended at (0 l) or (o 1) by the arcs joining any pole of {h kl} and the nearest pole of {lOO} are all equal. Hence, it may be easily shewn, that the poles of the form | A k /| are symmetrically arranged with respect to each of the five zone-circles that can be drawn through every two of the poles of the three forms {00 l}, {l 00}, {l 1 0}. 88. If the surface of the sphere of projection be di- vided into sixteen triangles, by the five zone-circles drawn through the poles of every two of the forms {O0lj, {lOOj, {l 1 o}, the poles of {h k /} will be symmetrically arranged with respect to any side of any one of the triangles. Hence the arrangement of the poles of ^hkl\ will be symmetrical, in any two adjacent triangles, and similar in any two alternate triangles. 89- The poles of x{hkl} are symmetrically arranged with respect to the two zone-circles, drawn through the poles 45 of {001} and the poles of {l 1 0}. The poles of K '\hkl\ are symmetrically arranged with respect to the two zone-circles through the poles of {001} and the poles of {l 00}. The poles of Tr\hkl\ are symmetrically arranged with respect to the zone-circle passing through the poles of {lOO}. The arrangement of the poles of ir\hkl\ will be similar in any two triangles on the same side of the zone-circle through the poles of [l oj, and symmetrical in any two triangles on oppo- site sides of it. 90. The direct and inverse forms differ only in position. For, if the sphere of projection be made to revolve through two right angles round any two opposite poles of {l OOj, the poles of the direct form will change places with the poles of the inverse form in the hemihedral form with parallel faces and in the first hemihedral form with inclined faces. And, in the second hemihedral form with inclined faces, if the sphere of projection be made to revolve through two right angles round any two opposite poles of {l 1 0}, the poles of the direct form will change places with the poles of the inverse form. 91. In the form {h k 0} , if the distance between two poles be JT, F or Jf, according as their symbols differ only in the sign of k, the order of the indices h, k, or in the order of the indices h, k, and sign of one of them, then (85) 92. In the form |AO/|, if L be the distance between two poles differing only in the sign of /, F the distance between two poles differing only in the arrangement of A, 0, tan \L = - - , cos F = (sin A) c . he 93. In the form \h h l\ , if JT, L be the distances between two poles differing only in the signs of h, I respectively, tan !/,= -- cos 45, cos K = (sin I/,) 2 . 46 94. Let H, K, L be the distances between any two poles of the form \h kl\, differing only in the signs of h, fc, I re- spectively. Let F be the distance between any two poles having the indices h, k in different order, and the signs of the first, second and third indices in one, the same as the signs of the first, second and third indices in the other. Let G be the distance between any two poles having the indices A, k in different order, the signs of the first and second indices in one, different from the signs of the first and second indices in the other, and the sign of the third index the same in both ; and let M be the distance between any two poles differing only in the order of the indices A, &, and in the sign of one of them. Then 90-^, 90 -Iff, \L will be the distances of any pole of {h k 1} from the nearest two poles of {l 0} and the nearest pole of {O0l}. F, G subtend at (0 1) angles of 90- 20, 90+ 20 respectively, where is the angle subtended at (001) by the distance of any pole of {hkl} from the nearest pole of Jl 0^. M subtends an angle of 90 at (001). Hence (85) if tan = - , tan \L = cos d>, h he sin \K = cos \L sin 0, sin ^H = cos ^L cos 0, sin ^G cos ^L sin (45 + 0), sin i>F = cos ^L cos (45 -f 0). cos M = (sin 95. If the distance between two poles of either of the forms \hko}, {hQl}, {h hi} be given, the distance between the two poles, or its supplement, will be one of the arcs -F, K, L, whence, from the expressions in (91) (93), the ratio of the indices may be found. 96. If the distance between any pole of the form {hkl} and each of two other poles of the same form be given, the 47 three poles not being in a great circle, the given distances, or their supplements, will be two of the arcs H 9 K> L, F, G, M 9 which being known, (f> and Z/, and thence, from the expres- sions in (94), the ratios of the indices may be found. 97. Let P be the pole of (h k /), Q the pole of (p q r). Then (85) tan PX = - cos PXY = - - cos PXZ, K la tan QX = ? cos QXY = - - cos QXZ. q r a Let Q be in the zone-circle PX. Then QXY=PXY, QXZ = PXZ, therefore h tan PX _ k _ I p tan Q X q r ' Similarly, when Q is in the zone-circle PF, k tan PY I _ h q tan QY ~ r ~ p ' And when Q is in the zone-circle PZ, / tanPZ _ h _ k r tan QZ p q ' 98. Let P be the pole of (h k /), Q the pole of (p q r), Z the pole of (0 1). Then (85) Z 2 (tanPZ) 2 99. To find the distance between any two poles. Let the axes of the crystal meet the surface of the sphere of projection in X, Y, Z, therefore (85) X is the 48 pole of (1 0), F the pole of (0 1 0), X the pole of (0 1). Let P, Q (fig. 39) be the poles of (h kl), (pqr); and let PQ meet the zone-circle XY in M. Then, the symbol of M, and the tangents of MZX, PZX, QZX, PZM, QZM may be found in terms of h, k, I, p, q, r. PZ may be found in terms of a, c, h, k, L ZJf=90, /. cosPJf = cos PZM sinPZ, tan QM : tan PM = tan QZM : tan PZM. Whence PQ, which is either the sum or difference of PM, QM, is known. 100. Having given the distance between any two poles, not both in the zone-circle l 0, 1 o], to find the ratio of the parameters a, c. Let (hkl), (pqr) be the symbols of P, Q (fig. 39), and let tan PZJf, tan QZM be expressed in terms of A, k, /, p, q, r. Then tan QM : tan PM = tan QZM : tan PZM , therefore sin(QJ/ + PJ/) _ tan QZM + tan PZM sin(QJf-Pilf) ~ tan QZM -tan PZM' The given distance PQ is either QM + PM or QM - PM, .-. PM, QM are both known. Cos PM = cos PZM sin PZ. PZ being known, the ratio of c to is given by the equa- tion 101. To find the indices of any face when referred to the axes of the zones [T l 0, l], [l 1 0, l], [l 0, l] as crystallographic axes. The symbols of the three zones are [l 1 o], [l I o]> [0 l] respectively, -'. (28) e=l, f=l, g=0, h=l, k = -l, 1=0, p=0, q=0, r=l. Hence, if w, v, w be the indices of any face when referred to the original axes, u ', ', w' its indices when referred to the new axes, u = u + v, v'=u v, w'=w. 102. To determine the figure and angles of the form \hkl\ 9 when h, k, I take particular values. The angle between normals to any two faces is obtained from the expressions in (91)... (94), and will be denoted by the letter which, in the accompanying figure, is placed upon the edge formed by the intersection of the given faces. The arrangement of the poles of the different forms is shewn in (fig, 38). The number of faces is given in (81). 103. The form { 1 } has two faces (0 1), (o 1), which are parallel to each other. 104. The form {l 0} (fig. 40) has four faces. Normals to any two adjacent faces of Jl 00}, and to either face of {00 l}, make right angles with each other, therefore F = 90. 105. The form {l 1 0} (fig. 41) has four faces. tanlJT=l, therefore K'= 90. A normal to any face of {l 1 o| makes an angle of 45 with a normal to an adjacent face of {l 0^, and an angle of 90 with a normal to either face of {o l}. For (85) the co- tangents of the angles are 1 and respectively. 106. The form {h k 0} (fig. 42) has eight faces. In {2 1 0} , tan K = - , .\ K = 53. 7',8, F = 36. 52',2. 3 In {$ 10}, tan^T=-, .-. AT.= 36.52',2, F==53.7>8. 7 50 lu {320}, tanJT=- , .-. K = 67.22',8, F = 22.37',2. 5 In {410}, tanJST= , /. JT = 73.44',4, F = l6.15',6. In {510}, tanJT= , .-. JT= 22.37',2, F = 67. 22',8. In {530}, ttmK= , .-. ^T= 6l.55',7, / T =28.4',3. 8 In {710}, tan JT = , .-. JSr= l6.15',6, F = 73. 4d',4. A normal to any face of {^A;0} makes with normals to either face of {0 1 } , and the nearest faces of{lOO}, {lio}, angles of 90, 1JT, \F respectively. 107. The hemihedral form with parallel faces ir\h k 0} is bounded by the alternate faces of \hkQ}, the normals to which make right angles with each other, 108. The form {h 1} (fig. 43) has eight faces. I a tan ^ L - - , cos F = (sin ^L) 2 . h/ c 109. In the hemihedral form with inclined faces K {h /} (fig. 44), Z, F= 180- F. 110. The form {h h l\ (fig. 45) has eight faces. tan 1L = - - cos 45, cos K = (sin i) ? . h, c 111. In the hemihedral form with inclined faces x{h h l\ (fig. 46), 112. Let P 9 Q be two adjacent poles of either of the forms {hhl} 9 {pOr} 9 equidistant from Z 9 the pole of (0 l) ; 51 and let the arc of the zone-circle joining P, Q, contain S, a pole of the other form. Then SZ bisects the right angle PZQ, and the angle PSZ is a right angle, 113. The form {h k 1} (fig. 4-7) has sixteen faces. * k Id If tan = itan&p= ^tanrp ; .'. bp=56.33 f , rp=71.43'. 2 1 From (98) we have tan cp = -> tan wp = tan ep = A/2 2 1 2 - tan vp = -- tan op = -r- tan sp = j tan cp. 2 /Y/5 -y/5 \/17 .'. wp = 50. 6', ep = 67.19', v/> = 28.9' 5 6^ = 40. 14', sp = 59. 25'. From (85) we have cos cm = sin cp cos 45, cos bm 53 sin bp cos 45, cos r m = sin rp cos 45, therefore cm = 65. 44^, bm = 53. 5l', rm = 47. 49', tan cm = 2 tan wm = 3 tan 5m = 4tanwm(97). IK w?m = 46.40', sm=35.14 / l, ram = 27 .55'. tan fem = 2 tan em, therefore em = 34. 23'^. tan wm= 2 tan 6m', therefore wm 69. 56'. tan rm' = ^tan em'=^tar\nm', .'.em' = 65.37'-|, wm'= 77. 14'. , s are in the zone-circle hp, km = 18. 26', .-. cosam=sina^cosl8.26', cosam'= sinjocos71<34', cossw'= sin sjo cos 71. 34', .-. am - 52 .13', am'=78.13', sm = 74. 12'. The distance between the poles of (001) and (l 1 1) is 37. ?'j therefore (100), a, a, c being the parameters of the crystal, if a = 1, c = 0,53511. 119. In a crystal of Anatase (fig. 53), the face c makes equal angles with each of the four faces p, p, p" 9 p'" 9 and of these any two adjacent faces make the same angle with each other. We may therefore assume c to be (0 1), p (l l 1), p (l 1 l). v is in the zone cp, and s in the zone vp'. Let c i P) P'-> ^5 * be the poles of the faces c, p, p, v, s. Then, by measuring, it is found, that pc = 68.18' ? vc = 19.45', sc = 25.30'. Let the symbol of v be (p q r), v is in the zone-circle pc. , r 2 (tansc) 2 (tanpc) 2 Let s be (;? ? r), .-. (98) ^ /- = ^ i-i- , p + q 2 26 r 2 = 361 (p 2 + q 2 ). s is in the zone-circle vp, the symbol of which is [3 4 T] 5 therefore (21) 3p + 4>q - r = 0. Whence p = 5, g = 1, r = 19. Hence the crystal is a combination of the forms JOO l}, {l 1 l}, {l 1 7}, {5 1 19}. The crystal is cleavable parallel to the faces df j 1 1 1 J. The parameters of the crystal being a, a, c, if a = 1, c = 1,777- 120. In a crystal of Copper Pyrites, (fig. 54), c, c', c", c'" are the faces of a square pyramid. Let their symbols be c (1 1 1), c (1 1 1), c" (IT i), c'" (ill), p is in the zone cc'", and makes equal angles with c, c"', therefore (87), jo is also in 54 the zone [001, 1 o] ; therefore p is (1 1). Similarly p is (o 1 1). b t is common to the zones c' V", pp; therefore b t is (1 1 2). There is no face of jl 1 j, between c and c', in the zone c e', therefore p belongs to the hemihedral form with inclined faces K'\I ij. Hence the crystal is a combination of the forms {l 1 l}, {l 1 2}, K ' {l l}. It is cleavable pa- rallel to the faces of the forms {ill}, {o 1 J . If we change the axes by the rule in (101), the symbols of the faces will become c (021), b / (ToT) 5 p (111). By changing the axes, the hemihedral form, of which p is a face, becomes /c{l 1 l}. 121. In a crystal of Scheelate of Lime, (fig. 55), pis (l 1 1), n is (0 2 l). p, g, n, a are in one zone. If p, g, n, a be the poles of p, g, n, a, it is found by measuring that pg= 22. 8l' 9 pn = 39.40', pa = 68.6 f . Let X, K, Z be the poles of (l 0), (0 1 0), (0 1). Let pn meet the zone-circle ^Fin m. Then m will be (l 1 0), and pm = 90. If (u v w) be the symbol of any pole S in the zone-circle pm, substituting p, n^ m and their indices, for P, Q, R and their indices, in (27), we have tan pS v w tan pn w Hence, if (u v w) be the symbol of g, we have = - . The symbol of the zone-circle pm is [l l 2]? " (21) u Whence w= l,w = 3, = 2; therefore g is (I 3 2). In like manner a is (2 4 l). Of the faces g, a y those only occur which have their poles in alternate lunes of the sphere of projection, therefore g, a belong to the hemihedral forms with parallel faces 7r{3 I 2^, 7r{24l}. CHAPTER IV. RHOMBOHEDRAL SYSTEM. 122. IN the rhombohedral system the axes make equal angles with each other, and the parameters are equal. 123. The holohedral form {h kl\ is bounded by all the faces which have for their symbols the different arrangements of + h, + k, + /, together with those of h, k, /. When h, k, I are all different, the number of arrangements will be twelve, as shewn in the annexed table, except when the indices are 0, 1, 1. In this case, and also when two of the indices are equal, the number will be six, and when all three are equal, the number will be two. hkl Ikh hk I Ikh klh kh I klh khl Ihk h Ik ~lhk hlk If h be algebraically the greatest, and I the least of three unequal indices A, &, /, fig. 56 will represent the arrangement of the poles of the form [hkl} on the surface of the sphere of projection. 124. The form bounded either by all the faces which have for their symbols the different arrangements of 4- h, + k, + 1 9 or by all the faces which have for their symbols the different arrangements of h, k, - /, is said to be hemihedral with inclined symmetric faces, and will be denoted by the symbol K\hkl}, where (h k I) is the symbol of any one of its faces. A form is said to be direct or inverse according as the alge- 56 braic sum of its indices is positive or negative. When the sum of the indices is zero, the form will be called direct or inverse according as the largest index is positive or negative. The symbols of the faces of the direct form are contained in the first and second columns, those of the inverse form in the third and fourth columns of the table in (123). If the surface of the sphere of projection be divided into two hemispheres by the zone-circle through the poles of {oil}, the poles of the direct form, when the sum of its indices is finite, will be found in the hemisphere which con- tains the pole of (l 1 l), and the poles of the inverse form in the other hemisphere. When the sum of the indices is zero, if the surface of the sphere of projection be divided into six lunes by great circles through the poles of { 1 1 1 } and those of {oil}, the poles of the direct form will be found in three alternate lunes, one of which contains the pole of (l 0), and the poles of the inverse form will be found in the remaining three alternate lunes. 125. The form bounded either by all the faces of {h k 1} , the indices of which stand in the order hklhk, or by all the faces of [h k l\ , the indices of which stand in the order Ikhlk, is said to be hemihedral with parallel faces, and will be de- noted by the symbol ir\hkl\, where (h k I) is the symbol of any one of its faces. The symbols of the faces are contained either in the first and third, or in the second and fourth columns of the table in (123). If the surface of the sphere of projection be divided into twelve lunes by zone-circles through the poles of j l 1 l } , and those of each of the forms {2 1 1}, {oil}, the poles of ir\hkl} will be found in six alternate lunes, except when the algebraic sum of two of the indices is equal to twice the third. And if the sphere of projection be divided into twelve triangles by zone-circles through every two of the poles of j 1 1 1 1 , {sTT}, the poles of Tr\hkl\ will be found in six alternate triangles, except when the sum of the indices is zero. 57 126. The form bounded either by all the faces of {h k l\ which have for their symbols the arrangements of +A, + k 9 4- /, which stand in the order hklhk, and those of - A, &, I, which stand in the order Ikhlk, or by all the faces which have for their symbols the arrangements of + h, + &, + I which stand in the order Ik hi k, and those of - A, A;, - / which stand in the order hklhk, is said to be hemihedral with inclined asymmetric faces, and will be denoted by the symbol a{hkty, where (hkl) is the symbol of any one of its faces. The symbols of the faces are contained either in the first and fourth, or in the second and third columns of the table in (123). If the surface of the sphere of projection be divided into six lunes by zone-circles through the poles of {ill} and I those of ^2 1 7}, the poles of a\hkl\ will be found in three alternate lunes. 127. To determine the position of any pole. Let the axes of the crystal meet the surface of the sphere of projection in X, F, Z, (fig. 57), let O be the pole of (1 1 1), P the pole of (hkl). Since O is the pole of (ill), and a = 6 = f, cos O^T=cosOF=cosOZ, .-. OJT=OF=OZ. The axes make equal angles with each other, therefore FZ = ZX=XY. Hence FOZ, ZOX, XOY are each equal to I 120; .-. cos PO Y - cos POZ = ,y/3 sin POX, cos POY + cos POZ = - cos POX. cos PX = cos PO cos XO + sin PO sin XO cos POX, cos PY = cos PO cos YO + sin PO sin YO cos POY, cos PZ = cos POcos ZO + sin PO sin ZO cos POZ. 8 58 Whence cos PF - cos PZ = i/S sin PO sin XO sin POX, cos PF + cos PZ = 2 cos PO cos XO - sin PO sin XO cos PO^T, cos PX + cos PF + cos PZ = 3 cos PO cos XO, 3 sin PO sin XO cos POX = 2 cos PX - cos PF - cos PZ. P is the pole of (h k /), therefore - cos PX = - cos PF = - cos PZ. ^ k I Whence tan PO tan ^TO cos PO X = h + k + I Similarly tan PO tan FO cos POF = - ~ , h + k + / and tan PO tan ZO cos POZ = , (tan PO) 2 (tan .TO) 2 =4 I) 128. Let A, B, C be the poles of (l 0), (0 l 0), (0 1). Then (127) tan AOX = 0, tan BOY = 0, tan COZ = 0, tan AO tan XO = 2, tan BO tan FO = 2, tan CO tan ZO = 2. Therefore A, B, C lie in the great circles OX, OF, OZ, OA = O# = OC, and the expressions in (127) become tan POA 59 A;-/ 2 tan PO cot AO cos POA = -, - - - - 2k- l-h 2 tan PO cot BO cos FOB = - - - , h + k + / 2 tan PO cot CO cos POC = - - - - r , h + k + I /tanPO\ 2 _ VtanJOJ = 129. If Jf , JV be any poles of the forms {2 T 1} , {o 1 1 } ; A any pole of {l 0}, O a pole of {l 1 l}, the expressions in (128) shew that M O, NO are quadrants ; that MO A is a mul- tiple of 60, and that NO A is an odd multiple of 30. Hence the poles of [2 IT} are six equidistant points in which a zone- circle having (l 1 l) for one of its poles, is intersected by the zone-circles through the poles of \l 1 l} and those of {l OOj; and the poles of {oil} bisect the arcs joining every two adjacent poles of {all}. 130. From the form of the expression for tan PO, it appears that the distances of the poles of {h kl\, which have the indices + h, + k, + I, from (l 1 l), and of those which have the indices - h, - k 9 -I, from (TIT), are all equal. By interchanging the indices A, A;, /, and changing their signs in the expressions for tan POA, tan PO#, tan POC, it appears that the angles subtended at (l 1 l), by the arcs joining any pole of |/i kl\ and the nearest pole of |l OOj, are all equal. Hence, the poles of ]hkl^ are symmetrically arranged with respect to each of the three zone-circles passing through the poles of {l 1 1 \ and those of \2 TIj . 60 131. If the surface of the sphere of projection be divided into twelve triangles, by zone-circles through every two of the poles of |l 1 1 j and J2 i i}, the arrangement of the poles of {A k / j will be symmetrical in any two adjacent triangles on the same side of the zone-circle [2 1 1, T I 2], or in any two alternate triangles on different sides of it ; and similar in any two adjacent triangles on different sides of the zone-circle [211,11 2]? or in any two alternate triangles on the same side of it. 132. The arrangement of the poles of /c{& k l\ will be symmetrical in any two adjacent lunes, composed of two adja- cent triangles on different sides of [2 IT? IT 2]? and similar in any two alternate lunes. The arrangement of the poles of 7r\h k /} in any two triangles is similar or symmetrical, accord- ing as the triangles are on the same side of the zone-circle [2 IT, IT 2] or on different sides of it. The poles of a {h k l^ are similarly arranged in each of the triangles in which they occur. 133. If P be the pole of any face, and if in PO produced OQ be taken equal to OP, a face may always exist of which Q is the pole. We have from (127) 2 cos QX - cos QY - cos QZ = 3 sin QO sin OX cos QOX, cos Q X + cos QY + cos QZ = 3 cos QO cos OX, cos QZ - cos QY = ^/s sin QO sin OXsinQ OX, sinQO=sinPO, cosQO^= - cosPO^T, sin QOX= - sin POX. Hence, if (h k I) be the symbol of P, 2 cos QX - cos QF - cos QZ Zh-k-l cos QX + cos QF+ cos QZ " ~h~+~k + I ' cos QZ - cos QF l-k cos QX + cos QF-f cos QZ = " 7T+T+'/ ' 61 Whence 3 cos QA^ cos QX+ cos QY+ cos QZ h + k + I ScosQY Qh-k + 2l cos QXTcos QF + cos QZ " h + k + l ScosQZ _ 2 A + 2Ar-/ cos QJ5T + cos QF + cos QZ h + fc + I .-. - cos Q^T - - cos QY = - cos QZ, p 7 r where j9 = - h + Zk + 2/, g = 2A - k + 2/, r = 2A + 2A; - I. p, q, r are whole numbers, therefore a face may exist of which Q is the pole. 134. When A, k, /, /?, w ^l ^ e symmetrically arranged in any two adjacent triangles, and similarly arranged in any two alternate triangles. The poles of the dirhombohedral combination 7r{hk l},7r\p qr\ will be similarly or symmetrically arranged in any two tri- angles, according as the triangles are on the same side of the 62 zone-circle [jj i i, i i 2]? or on different sides of it. The pole* of the dirhombohedral combination a\h k Zj, a\p q r\ are simi- larly arranged in all the triangles in which they are found. 136. In the hemihedral forms with parallel faces, and in the hemihedral forms with inclined asymmetric faces, the faces of different forms of the same kind occasionally occur in zones. If MQM' (fig. 59) be the zone-circle of one of these zones ; MLM' the zone-circle through the poles of {2 IT}, and QML an acute angle, the zone is called direct or inverse, according as the poles of its faces lie nearer to M or M' . The zones in a combination of hemihedral forms with parallel faces are direct on one side of the zone-circle through the poles of ^2 ~\\\ , and inverse on the other side of it. In a combination of hemihe- dral forms with inclined asymmetric faces, the zones are either all direct or all inverse, and the combination is named accord- ingly. 137- The direct and inverse hemihedral forms with in- clined symmetric faces, and the two hemihedral forms with parallel faces differ only in position. For if the sphere of projection be made to revolve through two right angles round any two opposite poles of {o 1 l} ? the poles of one half form change places with those of the other half form. The direct and inverse hemihedral forms with inclined asymmetric faces are essentially different. 138. Let P, A be any two adjacent poles of \h k &}, {l 00], O the nearest pole of {l 1 l}. Then (128) tanP0J=0, therefore P, A, O are in one zone-circle. Let PO= T, AO = D. Therefore, making / = k in (128), we have h-k tan T = - - tan D. h + 2k The signs of tan T, tan />, will be the same or different ac- cording as the directions in which PO, AO are measured from O are the same or different. 63 If V be the distance between any two of three poles of | h k k^ which have the indices h, k, k, V subtends an angle of 120 at (ill); and the two sides that include the angle of 120 are each equal to T 7 , therefore sin -| V = sin 60 sin T. The distance between any two adjacent poles one of which has the indices 4- A, + k, + Z, and the other the indices _ h, -k, -I, will be 180 - V. 139. If P be any pole of \fikl}, where h + k + I = 0, A the nearest pole of {l 00}, PO = 90 (128). Therefore, if H be the distance between any two adjacent poles of {hkl} having the indices A, k, 1 9 ^H = POA, therefore k I tan = Zh - k - I 140. Let the arc joining any two poles of [h k /}, having the indices + h, + k, + 1 9 be H, 7T, L or F, according as h, k, I or neither of the indices holds the same place in the symbols of the two poles ; T the distance of either of the poles from (ill); D the distance of any pole of \ 1 0} from the nearest pole of {ill}; 20, 20, 2>|/ the angles subtended at (1 1 1) by H, K, L. The angle subtended by F will be 120. Then (128) k-l l-k 64 The triangles having the vertex (ill), and bases //, L 9 V are isosceles, therefore sin Ijy = sin 9 sin Y 1 , sin K = sin

-0 = 60, ^ + 0=60, we have tan 9 _ tan 1 (K - L) sin 9 _ sin tan 6'0 ~ tan 1 (JT + Z) ' sin 60 ~ ^ir tan

, \js may be found ; and then the ratios of the indices may be found from the equations k I %h k I tan = A/ 3 -i - ; - , > 2 tan T cos = - tan Z>, 2h-k-l h+k + l , l-h zk-l-h tan = A/3 - - - , 2 tan T 7 cos = - - tan D, 2k -l-h h + k + l h-k Ql-h-k tan \(, = A/3 - - - , 2 tan T 1 cos \k = - tan D. 21 -h-k h + k + l 144. To find the distance between any two poles. Let P, Q (fig. 60) be the poles of (h k /), (p q r) ; O, A poles of {ill}, {lOO}. Let PQ meet the zone-circle [o 1 1, T l] in M. Then, the symbol of M, and the tangents of MOA, POA, QOA 9 POM, QOM may be found in terms of h, k 9 /, jo, q, r ; and PO may be found in terms of h, k, I. MO is a quadrant, therefore cos PM = cos POM sin PO, tan QM _ tan tanPJW ~ tan POM ' Whence PQ, which is either the sum or difference of PJ/, QJ/, is known. 145. Having given the distance between any two poles, not both in the zone-circle [o 1 T, To l], to find D, the dis- tance of any pole of { 1 J from the nearest pole of 1 1 1 1 } . Let P, Q (fig. 60) be the given poles, (h k /), (p q r) their symbols, then, retaining the construction in (144), let tan POM, tan QOM be expressed in terms of h, k, I, p 9 g, r. tan QM tan QOM tan PM = tan POM ' 66 therefore sin (QM + PM ) _ tan QOM + tan POM sin (QM - PM) ~ tan QOM - tan POM ' One of the arcs QM - PM, QM + PM is the given distance PQ, therefore PM, QM are both known. cos PM = cos POM sin PO. PO being known, D is given by the equation h* + k 2 + P-kl-lh- hk ^ p y = - pnnrfoi - (tan *> ' 146. To determine the position of any pole, having given its distances from two of three equidistant poles of any form. Let P (fig. 61) be the given pole; A, B, C three equidis- tant poles of any known form ; O the pole of (l 1 1). Let AE meet the zone-circles [o 1 1, I l], CO in M, E, and let PM meet CO in N. AE is bisected in E ; and ME, MN are perpendicular to EO. sin AE = sin 60 sin AO, tan EO = cos 60 tan AO, cos PA = cos JE cos PE + sin JE sin PE cos PE J, cos P5 = cos BE cos PJ + sin BE sin PE cos FEB. If we express cos PA - cos PI?, cos PA + cos PJ? in terms of products of trigonometrical ratios, observing that BE = AE, - cos PEB = cos PEA = sin PEN, and that sin PJV = sin PE sin PEN, we obtain sin JE sin PN = sin 1(PJ5 + PA) sin cos AE cos PE = cos (PB + PJ) cos Whence, PE, PN being known, JVE and therefore NO may be found. cos PO = cos PJVcos NO, cot POJV = sin NO cot PJV. 67 147. To find the indices of any face when referred to the axes of the zones containing the faces (hkk), (k h A?), (k k it), as crystallographic axes. The indices of the three zones reduced to their simplest terms are h + k, k, - k ; - k, h + k, - k ; A;, - A?, h + k, therefore (28), e = h + k, f = - k, g = - k, h = - k, k = h + k, 1 = - &, p= - k, q=-&, r =h+ k. Therefore, if u, v, w be the indices of any face when referred to the original axes, u, v', w' 9 its indices when referred to the new axes, u (h + k) u kv - kw, v'= - ku + (h 4- k) v - kw, w'= - ku - kv + (h + k)w. 148. To determine the figure and angles of the form {h k fy, when A, k, I take particular values. The angle between normals to any two faces of the same form may be computed by the formulae in (138), (139), (140), and will be denoted by the letter placed upon the correspond- ing edge of the accompanying figure. The arrangement of the poles, when the three indices are unequal, is shewn in fig. 56. The poles of {A k k} lie in zone-circles through the poles of {ill} and those of {2 1 1}. The number of faces is given in (123). 149. The form { 1 1 1] has two parallel faces. A normal to the faces makes equal angles with the three axes. 150. The hemihedral forms K{I I l}, K {TIT} consist of the faces (l 1 1), (TIT), respectively. 151. The form [hkk\ has six faces, and is called a rhombohedron. The three poles which have the indices + A, + k, + k are equidistant from each other, and are dia- 68 metrically opposite to the three poles having the indices h, k, k. Hence, a rhombohedron is bounded by three pairs of parallel faces making equal angles with each other. Let T be the distance of any pole of {h k k} from the nearest pole of { 1 1 1 } ; ' V the distance between two adjacent poles equidistant from (ill); W the distance between two adjacent poles not equally distant from (l 1 l), and D the distance of a pole of {100} from the nearest pole of {l 1 l}. Then (138) h-k tan T = - tan D, h + 2k sin 1 V = sin 60 sin T, W = 180 - V. The position of the rhombohedron [h k k} is said to be parallel or transverse according as tan T, tan D have the same or different signs, that is, according as T, D are mea- sured from (l 1 l) in the same direction or in different direc- tions. If we take fig. 62 to represent { 1 0} , then ^01 1 \ , which is in transverse position, will resemble fig. 63. In {o 1 ij, tan T = - fL tanD. The poles of {o 1 1 } bisect the arcs join- ing the adjacent poles of {l oj. In {211} which is in parallel position, tan T = J tan D. The poles of \Z 1 ij bisect the arcs joining the adjacent poles of {Oil}. In {31l}, which is in parallel position, tan T = ^j- tan D. In {I 2 2\, which is in transverse position, tan 7 7 = - tanD. Hence, position excepted, the form of {I 2 2] is the same as that of {l 00^. In {111} (fig- 64), which is in transverse position, tan T = - 2 tan D. The poles of { l o] bisect the arcs join- ing the adjacent poles of {I i i J . In {3 IT}, which is in parallel position, tan T= 4 tan IX The poles of Jl l ij bisect the arcs joining the adjacent poles of {3 1 l|. 69 152. The hemihedral form with inclined symmetric faces ic{h k k\, has the three faces having the indices + h, + A;, + A;, and which make equal angles with each other. The other half form, has the three faces with the indices -A, A?, - k. 153. Let P, Q, R be three poles of a rhombohedron, equidistant from 0, the pole of (ill); and let the zone- circle through P, Q, contain S, a pole of another rhombohe- dron. S is in the zone-circle RO which bisects the angle POQ, and the arc PQ. POQ = 120, therefore POS = 60 ; PSO = 90. Whence tan PO = 2 tan #0. 154. The form {2 1 l} has six faces, the poles of which (129) are the six equidistant points in which a great circle, having (ill), (TIT) for its poles, is intersected by the zone- circles through the poles of Jill}, and those of |lOOJ. Therefore the distance between any two adjacent poles of {21 l} is 60. 155. The hemihedral form with inclined symmetric faces /c{2 1 l} is bounded by the alternate faces of |<2 i i}. The distance between any two of its poles will be 120. 156. The form {o 1 l} has six faces the poles of which (129) bisect the arcs joining every two adjacent poles of {21 l}- The distance between any two adjacent poles of {oil} is 60. 157. The form {h kl}, where h + k + I = 0, (fig. 65) has twelve faces, the poles of which lie in the zone-circle through the poles of {21 l}. If H be the distance between any two poles adjacent to a pole of {2 1 l} ? h the largest index, - k- I The distances of any pole from the adjacent poles of {2 1 {oil} are I//, ^G respectively. 70 In {2 13}, tan ^H = ^3, .: H = 21. 4?',2. In {si 4}, tan^JET^v/3, .-. H= 32. 12',3. In {4 15}, tan |- # = j .y/3, .'. #= 38. 12',8. In {325}, tan| J H' = ^ v / 3, . #= 13. 10',4. In {5 16}, tan^ J H r =| v /3 5 .-. #= 42. 6',4. In { 5 2 ?} , tan \ H = \ ^/3, .'. H = 27. 4/,7. In {7 18}, tan H = PP intersect in #, therefore t is (31 0), t' (3 l). tt f , p"c" intersect in 0", therefore (2 1 2), 5 (3 1 3), b (7 3 5), q (5 3 5). Let p, p', p" be the poles of (l 0), (0 1 0), (0 l) ; o the pole of (ill), and let the poles in op' and the sector eoc /5 op" and the sector c'oc y , be distinguished by one and two accents respectively. pp"= 74. 55', pop" 120. og bisects pp" and pop", therefore, since po=p"o, sinlpp" = sin 60 sinpo. Whence po = 44. 36',6. Tan go = ^ tan po (138), therefore go =26. 15'. Sin lg-# = sm60sin#o, there- fore gg'= 45. 3'. In like manner no = 13. 52', nn'= 23. 56'; fo = 63. 7', //= 101. 9' ; mo = 75. 47', m m'= 114. 10'; lo = 38. 17, ^'=64. 53'; 0o = 50. 58', 00'= 84. 33'; do =82. 47', dd'= 118. 27'; Ao = 55. 57', hti= 91. 42'. eo = 90, ec'= 90, therefore e^'= 90, p#'= 37. 27',5, pe = 52. 32',5. Let (u v w) be the symbol of any pole S in the zone-circle pp", between e and g. Therefore, substituting e, p, g and their indices for p, q, r and their indices in (27), we have tan Se tan pe. Whence, since 0, cr, y, r, X, w', ', v f are in the zone-circle pp", 0e = 6. 46', ere =10. 34', ye = 14. 38', re =23. 3l', \e = 33. 8', therefore bop = 40. 53',6, sin sin 6op sin bo, therefore bb f = 72. 22',5, |6o&" = 19. 6', 4, whence 66" = 34. 20'. In like manner, zo = 76. 32', %op = 19. 6',4, ##'=37. 8'. q, a?, S, /" are in the zone-circle ep', ep = 90 Q , ef'= 34. 25', 5. If (wvw) be the symbol of any pole S in the zone-circle ep', then (27) tan Se - - tan ef". Whence ge = 22. 2l' 5 #e = 18. 55', Se =12. 52'. 169. In a crystal of Tourmaline, the two ends of which are represented in figs. 71, 72, c, p, p', p" are (l 1 1), (100), (01 0), (0 1) respectively. n" is common to the zones pp, cp", therefore n" is (1 1 0). Similarly n is (l 1), and n is (0 1 1). s is common to the zones pp", nn", there- fore is (i o I)- Similarly s" is (o 1 T), and s' is (l i o). I is common to the zones ss', cp, therefore I is (211). In fig. 72. p, Pp p^ are respectively parallel to p, p', p", there- fore p is (To 0), p / (0 1 0), p lt (0 T). g is common to the zones sp' 9 sp", therefore g is (ill). The faces parallel to c, /, g are wanting, therefore (124) c, /, g belong to hemihe- dral forms with inclined symmetric faces. Hence the crystal is a combination of the forms {l 0^, {o 1 l}, /cjsll}, /c|oi 1 J ? 170. p, m os, Szc. (fig. 74), are the poles of the faces p, m, a?, &c. of a crystal of Apatite (fig. 73). Let #, #', at" be the poles of (100), (0 1 0), (001) respectively; and let p be the pole of (ill). ODX', px" intersect in r 3 , therefore r 3 is (l 1 0). In like manner r 2 is (1 l), and r t is (0 1 1). m is in pa?, and pm = 90, therefore (129) m is (2 IT), m is (1 2 I), m" is (IT 2)? and m 3 is (l 1 2). mx, px" intersect in #3, therefore ,v 3 is (2 2 I). wr 3 , px intersect in r, therefore r is (l 1 4). woo", mm' intersect in e, therefore e is (i o T). ex, px" intersect in % 3 therefore %. A is (i 1 1). m% 3 , px in- tersect in %, therefore % is (5 IT). mx f , xm z intersect in s, therefore s is (41 2). ww' 9 mx" intersect in u ', therefore 75 **' is (2 1 o). im>Zy> xm 3 intersect in w, therefore u is (524). pu 9 mm' intersect in c, therefore c is (5 4, i). The arcs rr , *',, a?* /5 w^ are bisected in /?, therefore (134) the forms to which the faces r, <#, &c. belong are dirhombohedral. If twelve lunes be formed by zone-circles through p and each of the poles ra, e, the poles c, c y , u 9 u^ in the alter- nate lunes are wanting, therefore (125) c, c f &c. belong to hemihedral forms with parallel faces. Hence the crystal (fig. 73) is a combination of the forms {ill}, {2llj 5 {oil}, {100}, {T22},_{011},_{411}, {Til}, {5lT}, {412J, 7r{2 1 o}, 7r\5 2 4} 5 7TJ5 4 1 \. It is cleavable parallel to the faces of the forms {ill}, {2!!}. The faces u 9 s, at form an inverse zone. The symbols of the other poles shewn in (fig. 74) are a (5 2 I), d (7 i 5), / (3 I 2~), b (2 1 2~), V (8 4~I). The expressions in (128) give tan epm = ^\/3 9 there- fore the zone-circle pasde makes an angle of 30 with pm. tan cpm = \\/3-> therefore the zone-circle cu t puc makes an angle of 40. 53 r ,6 with pm. tan bpm = |\/3, therefore the zone-circle b^pb makes an angle of 46. 6' with pm. If xp=D, 2 we have from (128), tan D = 2 tan rp = ^ tan zp = -j- tan ap 1111 tan sp = - tan dp = tan up = - tan op. mpm 3 60, .-. e^m 3 = 30, up m 3 19. 6',4, bpm 3 13. 4'. Sin ap = cos a f m 3 e f - tan 60 cot xm z = tan 30 cot sm 3 = tan 19.6',4 cot um 3 = tan 13. 4' cot &ra 3 = tan 40. 53 ; ,6 cot urn. Sin sp = cos s'm 3 e'= tan 60 cot #w 3 = tan 30 cot dm 3 . Cos rm 3 = cos 60 sin r^>, cos am 3 = cos 30 sin ap. 171. f? P? *> &c. (fig. 76) are the poles of the faces r, p, *, &c. of a crystal of Quartz (fig. 75). The distance between any two adjacent poles r, r 2 , r 3 , &c. is 60. The arcs pr, p'r, p"r" are each 38. 13', and are perpendicular to rr a , therefore they pass through o, the pole of rr 2 . There- 76 fore, if p be (10 0), p (0 1_0), p" (0 l), o will be (l 1 1), r (2 T T), r' (I 2 !),_ r" (I I 2). rp', r> intersect in #", therefore #" is (2 2 l)- f*p 5 r"p intersect in *, therefore s is (4 2 l). ar = 18. ll', therefore tanao = 4 tan po, therefore (138) a is (3 1 1). ar l = ar, therefore ao = ao, therefore (133) a t is (755). n, x are in the zone-circle pr 2 . xr 2 = 18. 29', nr 2 = 12. If (uvw) be the symbol of any pole S in ^r 2 , substituting r 2 , ^, ^ /r and their indices for P, Q, 7? 5 and their indices in (27), and observing that cot#'V 2 =-cotpr 2 , we have (Zu 5v) tan Sr 2 = (2u + v) tan pr 2 . The symbol of the zone-circle pr 2 is [0 1 2], .-. v+2w=0, tan pr 2 = 7tan<2?r 2 , .*. at is (22l), tan^r 2 = 13 tanwr 2 , .*. n is (s 10 5). pz, aa i are bisected in o, therefore (134) p, a belong to dirhombohedral combinations. There are no poles s, #, w in the alternate lunes formed by zone-circles through o and each of the poles r, therefore (126) s 9 a, n belong to hemi- hedral forms with inclined asymmetric faces. Hence the crys- tal (fig. 75) is a combination of the forms {21!}, {lOO}, {122}, {3 IT}, {755}, {42l},a{22l} 5 a{8lo5}. The zone formed by the faces p, s, #, n, r 2 is direct. The symbols of the other poles shewn in (fig. 76) are 6 (i32_2), &, (78 8), m (722), m t (54J^), e (i65_5), e t (433), c (5 2 2), c t (13 8 8), w (5 4 2), y (7 8 4), # (3 4 2). CHAPTER V. PRISMATIC SYSTEM. 172. IN the prismatic system the axes make right angles with each other. 173. The holohedral form \h k 1} is bounded by all the faces having for their symbols the different combinations of A, &, =M, each index having always the same place, When h 9 A;, I are all finite, the form {h k /J will have the eight faces hkl Jill hkl hll ll~l hkl Jill hlcl When one of the indices is zero, the number of faces will be four. When two of the indices are zero, the number of faces will be two. The arrangement of the poles of \hkl\ on the surface of the sphere of projection is shewn in fig. 77. The form bounded by all the faces of {hkl} which have either an odd number of positive indices, or an odd number of negative indices, is said to be hemihedral with in- clined faces, and will be denoted by *\hkl\, where h k Us the symbol of any one of its faces. The forms are said to be direct or inverse according as they have an odd number of positive or of negative indices, and their symbols are con- tained respectively in the upper and lower lines of the table above. If the surface of the sphere of projection be divided into eight triangles by zone-circles through every two of the poles 78 of (1 0), (0 1 0), (0 1), the poles of the direct form will be found in four alternate triangles, one of which contains (1 1 1), and those of the inverse form in the four remaining triangles. 175. The form bounded by all the faces of {/*&/}, in the symbols of which the sign of one of the indices re- mains unchanged, is said to be hemihedral with symmetric faces, and may be denoted by prefixing to {A&/J, where (h k 1} is the symbol of one of its faces, o^, a~ 2 or o- 3 , accord- ing as the first, second or third index preserves its sign unchanged, and may be called direct or inverse according as that index is positive or negative. The poles of the hemihedral form with symmetric faces will be found in one of the hemispheres into which the sur- face of the sphere is divided by a zone-circle through two of the three poles (100), (0 1 0), (001). 176. To determine the position of any pole. Let the axes of the crystal meet the surface of the sphere of projection in X, F, Z (fig. 78). Let a, 6, c be the parameters of the crystal. P the pole of (hkl). Since the axes of the crystal are rectangular, FZ, ZX, XY are quadrants, .*. cos YZ = 0, cos ZX = 0, cos^TF=0, therefore X, F, Z are the poles of (l 0), (0 1 0), (0 l), and the angles at Jf, F, Z right angles. cos PX = sin PY cos PYX = sin PZ cos PZX, cos PY = sin PZ cos PZF = sin PXcos PXY, cos PZ = sin PX cos PXZ = sin PY cos PFZ. cot PX = tan PZFcos PXY = tan PFZ cos PXZ, cot PF = tan PXZ cos PFZ = tan PZ^cos PYX, cot PZ = tan PYXcos PZX = tan PXYcos PZF 79 But - cos PX = - cos PY = - cos PZ. h k I Whence tanP^F=--, tanPFZ=--, tanPZ^=--. A; c /a h b cot PX=-- cos P^TF = - - cos PJTZ, A; a /a cot PF = - - cos PFZ = 7 - cos PYX, I b h b cot PZ = - - cos PZ^ = - - cos PZF. he k c 177- It appears from (l?6), that the distance of any pole of \hkl\ from the three nearest poles of {lOO}, {pioj, {O0lj are respectively equal to the distances of any other pole of \h k 1} from the three nearest poles of {l 0}, {0 1 0}, |001}. Hence the poles of {hkl} are symmetrically ar- ranged with respect to each of the three zone-circles through every two of the poles of the forms {l 0), {Oio}, {O0l. 178. The arrangement of the poles of {&/!, and of a \hfcl\y will be symmetrical in any two adjacent triangles formed by zone-circles through every two of the poles of {100^, {OIO}, {O0l}, and similar in any two alternate triangles. The arrangement of the poles of K\hkl\ will be similar in each of the triangles in which they occur. 179. In either of the hemihedral forms, the poles of the direct and inverse forms may be made to change places with each other, by causing the sphere of projection to revolve through two right angles round the poles of one of the forms {l 00}, {01 0}, {O0l}. 80 180. In the form {okl}, if L be the distance between two poles differing only in the sign of Z, . k c 181. In the form {hoty, if L be the distance between two poles differing only in the sign of I, i lo, tan \L = --- he 182. In the form {hkO}, if H be the distance between two poles differing only in the sign of /&, hb tan IH = - - . k a 183. In the form \hkl\, if H, K, L be the distances between any two poles, the symbols of which differ only in the signs of h, k, I respectively, if tan = , tan \L - - cos 0, ho he sin 1/T = cos ^L sin <, sin H = cos L cos . 184. Let P be the pole of [h k 1} , Q the pole of {p q r } . Then as in (97), when Q is in the zone-circle h tan PX _ k_l_ p tan Q X ~ q~ r* When Q is in the zone-circle PF, k tan PY I _h q tan QY r q When Q is in the zone-circle PZ, I tan PZ _ h _ k r tan QZ p q ' 81 185. To find the distance between any two poles. Let P 9 Q (fig. 78) be the poles of (h k /), (p q r) ; X, F, Z poles of the forms {O0l}, {o 1 0}, {lOO}. Let PQ meet the zone-circle of which Z is a pole in M. Then the tangents of MZX, PZX, QZXcau be found in terms of h, k, I, p, q, r and of two of the parameters a, 6, c ; therefore PZM, QZM are known. PZ can be found in terms of h> k, I, and of the parameters a, 6, c. MZ is a quadrant, therefore cos PM = sin PZ cos PZM , tan QM _ tan QZM tan PM ~ tan PZM ' Therefore, PM, QM being known, PQ which is their sum or difference is known. 186. If the distance between any two poles of either of the forms {okl}, \7iOl}, {hko} be given, the ratio of the indices may be obtained from the expressions in (l 80)... (182). 187- In the form {h k I], the distances between any pole and each of two others, or their supplements, will be two of the arcs H, K, L ; therefore two of the arcs H, JT, L being known, and thence the ratios of h, k, I may be found from (182). 188. The ratios of the parameters may be found from the expressions in (180)... (182), having given the distances between the poles of two of the forms {o k I}, {h l\, {h k 0}; or from the expressions in (183), having given the distance between any pole of \h k I], and each of two others not all in the same zone-circle. 189. The ratios of the parameters may also be found from the distances between three given poles in one zone- circle. Let P, Q, R (fig. 79) be the three poles. Let PR meet FZ, ZX, XY in L, M, N respectively. Then, the symbols of P, Q, R being known, the symbols of the poles L, M, N 11 82 may be found by (17). Therefore, PL, PM, PN may be found by (27). Therefore the distances between Z, M 9 N are known. tan LY _ tan NL tan M Z _ tan LM tan NX _ tanMN tan LZ ~ tan L M ' tan M. X ~ tan M N ' tan NY ~ tan NL ' Hence, the places and symbols of Z, M> N being known, the ratios of a, b, c may be found by (180)... (182). 190. To determine the figure and angles of the form {hkty, when h, k, I take particular values. The angle between normals to any two faces of the same form is obtained from the expressions in (180)... (183), and will be denoted by the letter which, in the accompanying figure, is placed upon the edge formed by their intersection. The arrangement of the poles is shewn in fig. 77- The number of faces is given in (173). 191. The three forms {l 00}, {o 1 o}, {00 l}, have each two parallel faces, the faces of any one form being perpen- dicular to those of each of the other two. Either of these forms may become hemihedral according to the second law. 192. The form \0kl} (fig. 80), has four faces perpen- dicular to the faces of Jl 0}. I b kc ' 193. The form [h ty (fig. 81), has four faces perpen- dicular to the faces of {o 1 o}. I a he' 194. The form {h k o} (fig. 82) has four faces perpen- dicular to the faces of {o 1 ] . 83 195. Either of the preceding forms may become hemi- hedral with symmetric faces. The half-form will consist of any two adjacent faces. 196. The form {h k 1} (%. 83) has eight faces. If tan = - - , tan \L = - - cos 0, ho he sin ^K = cos ^L sin 0, sin \H = cos JZ, cos 0. 197 The hemihedral form with inclined faces K\hkl\ is an irregular tetrahedron, the edges of which are parallel to the faces (l 0), (0 1 0), (0 l). If normals to the faces that meet in these edges make with each other the angles T, V, W respectively, 198. The hemihedral form with symmetric faces consists of four faces which make one of the solid angles of fig. 83. 84 EXAMPLES. 199. LET m, k, p, &c. (fig. 85), be the poles of the faces m, k, p, &c. of a crystal of Aragonite (fig. 84). It is found that the zone-circles mm ', k k r intersect at right angles in h, and that the poles of the faces are symmetrically arranged with respect to each of the circles mm ', kk' and a circle YZ which intersects mm', kk' at right angles in F, Z. Let h be (1 0), k (10 1), m (1 1 0). Then F, Z will be (0 1 0), (0 l) respectively. It appears from the symmetrical arrangement of the poles with respect to the great circles mm', kk', YZ, that pp"i pp" pass through F, Z respectively, k, m are in pp", pp' respectively. Hence p is the intersection of Yk, Zm, therefore p is (l 1 l). s is the intersection of hp, mk, therefore s is (211). s" is (2ll), s m is (2 T l). i is the intersection of hk, ss" f , therefore i is (201). n is the inter- section of pk, ss", therefore n is (21 2). x is the intersection of mn, hk, therefore a? is (10 2). Hence the crystal is a com- bination of the forms {l 00}, {l l}, {20l}, {l 02}, {l 1 o}, {ill}, {21l}, {212}. The crystal is cleavable parallel to the faces of {lOO}. {l Ol}, {l 10}. It is found that mm'= 63. 5 0', kk'= 71. 34/ 9 very nearly. Therefore mh=58. 5', M=54. 13'. tan kh=2 tan ih = -J tan Then o" will be (111), o"' (l 1 1). m, m f will be (l 1 0), (i l o) respectively, n will be (2 1), u (3 1 0), y (40l). If m> m ', /, I' be the poles of the faces m, m', I, t, it is found that tan ^11' = 2 tan^ww', therefore I is (210). Hence x is (423), of (423), s (223). Hence the crystal 86 is a combination of the forms {O0l}, {lio}, J2 1 o}, {SIO}, {201}, {401}, {ill}? {223}, {423}. The crystal is cleavable parallel to the faces of {O0l|, {20l}, {021}. The forms of Topaz are sometimes hemihedral with sym- metric faces (174). Thus the forms to which o, <#, p, t (t is common to the zones oo'", nn', its symbol is (101)) occa- sionally wanting the faces on one side of the zone mm'; and the form of which i is a face (i is common to the zones mo', m'o, its symbol is (021)), has been observed to want the faces on one side of the zone nn '. If m, u, p, Sec. be the poles of the faces m, u, p, &c., mm'= 55. 4l', ll'= 93. 8', uu'= 115. 29', pn = 43. 30',5, py = 62. 13', po = 45. 27',5, ps = 34. f, psc = 41. 4'. CHAPTER VI. OBLIQUE PRISMATIC SYSTEM. 202. IN the oblique prismatic system one axis OF, is perpendicular to each of the other two axes. 203. The holohedral form {h k 1} is bounded by all the faces which have for their symbols the different combinations of h, k y I, in which each of the three indices has always the same place, and the first and second indices are taken with the same signs. When k is finite the form has the four faces hie I hkl hi I hll When k is zero, or when each of the other two indices are zero the number of faces will be two. 204. The hemihedral form which we shall denote by \hkl\, where (hkl) is the symbol of one of its faces, is bounded by the faces of \hkl\ in the symbols of which k has the same sign. The poles of the two half-forms lie on different sides of the zone-circle [100, 001]. 205. To determine the position of any pole. Let the axes of the crystal meet the surface of the sphere of projection in X, F, Z (fig. 87). Let C be the pole (001), A the pole of (l 0), P the pole of (h k I). The axis OF is perpendicular to each of the other two axes, therefore X F, YZ are quadrants ; therefore cos XY 0, cos ZZ = 0. Therefore F is the pole of (0 l 0). cos CX = 0, 88 cosCF=0, cosJZ = 0, cos AY = 0. Therefore CX, CF, AZ, AY are quadrants. Therefore C, A are in the great circle ZX, and CA + ZX = 180. cosPX= sin PFcos PFJT= sin PFsin PFC, cos PZ = sin PFcos PFZ = sin PFsin PYA. But ?cosP^=-cosPF=-cosPZ; h k I .-. - sin PFC = - sin PYA, .-. if tan = - - , hi la tan 1 (PFC - PYA) = tan 1C^ tan (45- 9). cot PF= \- sin PFC = 7 7 sin h b to cos PJ = sin PFcos PFJ, cos PC = sin PFcos PFC. 206. The arc joining two poles of \hkl\> the symbols of which differ only in the sign of &, is manifestly bisected at right angles by the zone-circle [001, 100]. Hence, if the surface of the sphere of projection be divided into two hemi- spheres by the great circle [00 1, 1 00], the arrangement of the poles of \h k 1} in the two hemispheres will be symmetrical. The arc joining the two poles of K{!I kl^ will be bisected in a pole of the form {o 1 oj. 207. Let P be the pole of (h k /), Q the pole of (p q r), and let Q be in the zone-circle PF. Then PFC = QFC, PYA = QYA, therefore (205). &tanPF_ I _ h q tan QF r ~ p ' 208. To find the distance between any two poles. 89 Let P, Q (fig. 89) be the poles of (h k /), (p q r), A, Y, C the poles of (l 0), (0 1 0), (0 l). Let PQ meet CA in M. Then the symbol of M may be found, and MY A, PYA, QYA, PY may be found in terms of A, k, /, p, q, r, , c and the angle between the axes. MY is a quadrant, therefore cos PM = cos PFM sin PF, tanQJf tanQFJf tan PM tan whence, PM, QM being known, PQ is known. 209. Having given the distances of the pole of (h k I) from the poles of (l 0), (0 1 0), (0 1) ; to find ZJT, and the ratios of a, 6, c. Let P, A, F, C (fig. 88) be the poles of (h k I), (l 0), (0 1 0), (0 1). Then (205) cos PA = sin PFcos PYA, cos PC = sin PFcos PFC. Whence PYA, PFC, and, therefore, AC and ZX become known. The ratio of a to c is given by the equation - sin PFC = 7 sin PF^ ; h I and the ratio of b to a or c by the equations cot PF = - - sin PFC = 7 - sin PF^. h b I b 210. P, Q, R (fig. 90) are three poles in the zone-circle CA, C, A being the poles of (001), (100); T, T r are two poles of the same form. Having given PQ, Q/?, TT', and the symbols of P, Q, R', T, to find the inclination of the axes and the ratios of the parameters. Let TT f meet PQR in S. P, Q, R, S, A, C are in the same zone-circle, and their symbols are known, therefore (26), 12 90 the distances of S 9 C 9 A from P and R may be found. Whence, CA being known, the inclination of the axes is known. Y bisects TT', therefore, TV, CS 9 AS being known, TC, TA may be found, and the ratios of the parameters determined as in (209). 211. M, M' (fig. 91) are the poles of two faces of any form equidistant from Y"; N 9 N r are the poles of two faces of any other form, also equidistant from F. Having given MM', NN', MN; to find the inclination of the axes, and the ratios of the parameters. Let MM', NN f , MN meet CA in P, Q, R, C, A being the poles of (00 l), (l 00). The symbols of M, N being known, those of P, Q, R may be found. MN, YM, YN be- ing known, PQ, which measures the angle MYN, may be found. sin PR = cot R cot YM, sin QR = cot R cot YN, tan 1 (PR - QR) sin (NY -MY) tan 1 (PR + QR) " sin (NY + MY) ' Whence, knowing PQ, PR, QR are found. PQ, Q# be- ing known, the places of C, A 9 and the ratios of the parameters may be found by the methods of (209) and (210). 212. P, Q, R (fig. 92) are three poles in the same zone- circlec T, T' two poles of the same form equidistant from Y. Having given PQ, QR, TT f , and the symbols of P, Q, R, T ', to find the elements of the crystal. Let PR meet ZX in M and TF in S\ and let TF, RY, PY meet ZJT in s 9 r, p. Then the symbols of M, S, p, r, s can be found. PQ, PR and the symbols of M, P, Q, R, S, are known, therefore NP, MR, SP, SR may be found by (26). R Y, RM determine RM Y. RMY, PM, RM, SM determine pM, rM, sM. Whence, knowing the symbols of p, r, s, the places of C, A can be found by (210), the elements of the crystal may then be found by the methods already given. 91 213. To find the indices of any face when referred to the axes of the zones [e Og, 01 o], [0 1, 10 o], [pOr, 1 o] as crystallographic axes. The symbols of the three zones are [r p\, [0 1 0], [gO #], therefore (28) e = - r, f = 0, g = p, h = 0, k = 1, 1 = 0, p = g, q 0, r = - e, Hence, if u, v, w be the indices of any face when referred to the old axes, u f , v', w its indices when referred to the new axes, ru, v' = v 9 w'gu ew. 214. The form {o 1 0} has two parallel faces. 215. The form \hQl\ has two faces parallel to each other, and perpendicular to the faces of {010|. 216. The form [h kl\ has four faces. Normals to two faces adjacent to (0 1 0) make with each other an angle 180 JT, where 90 - \ K = PY. 217. The hemihedral form a^h k 1} has two faces, normals to which make with each other an angle 180 - K. 92 EXAMPLES. 218. IN a crystal of Epidote (fig. 93), the zones which determine the symbols of the faces are metlrm, mkoo'k'm', tuxz'u't', lyqqyl'i ln%'l\ rnn'r', mdzqnocm, muym', ryxox'r', tynod't', edd'e. Let m be (100), I (001), n (ill), n (ii i). Therefore (17) the symbols of the faces will be r (1 0_l), q (0 1 l), % (l 1 1), t (l l), o (2 1 0), y (0 1 2), tf (3 1 l), i (l 3), M (2 J 2), A; (4 1 0), d (3 1 l), e (30 l). In some crystals a face / has been observed common to the zones mt, un\ a face s common to the zones mt, ky, and a face b common to the zones mo, lg. Therefore / is (103), s is (201), and 6 is (0 1 0). The crystal is cleavable parallel to the faces m, t. Let m, I, r, &c. (fig. 94), be the poles of the faces m, /, r, &c. Having given rt = 5l. 4l', tm = 64>. 36', nn 70. 33'; to find the positions of the remaining poles. Let (u v w) be the symbol of any pole S in the zone-circle rtm\ then, substituting r, t, m and their indices for P, Q, R and their indices in (27), tan rS tanrm 2w tan r t tan rm u + w .'. (u + w) tanr*S'= 2w tanr+ (u - w) tanrwz. Whence Zr=25. 44',5 ; /r=34. 55'5 ; er=Sl. 34 ; ir=29. 2l',5 ; sr=18. 6'. If nml (j), tan wr = tan ^>sinmr, tanzv = tan sin m^. Whence t> = 41. S9',5, 0t/= 96. 4l'. In like manner qq = 64. 46', **'= 70. 9', dd'= 96. 10'. It ntr=^, tan^r = tan>|/sin #r, tanom = tan\|/sin #m. Whence ow = 58. 26', oo'= 63. 8'. Tan % = 2tan bq (207), therefore by = 51. 45', yy'= 103. 30'. Tan b u = 2tan bz, tan 6A; = 2 tan&o. Whence 6^=54. 33 X , w^'= 109. 6', bk=50. 5l',5, ^^=101. 43'. If the zones which intersect mt in/, 5, had not been found, the distances of /, s from the poles of some known face in mt would have been requisite in order to determine their symbols, 93 Suppose /, ts had been measured, and that we had found tf= 19. 37', ts = 69. 47'. We have tr = 51. 4l', rm'= 63. 43'. Therefore, substituting #, r, m' and their indices for P, Q, 7? and their indices, and /for S in (27), if (u v w) be the symbol of /, u = 1, v = 0, w = 3. Therefore / is (103). In like manner 5 will be (201). To find the inclination of the axes OZ, OX, and the parameters. Let OZ, OX meet the surface of the sphere of projection in Z, X. Then, since I is (00 1) and m is (l 00), mZ = 90, IX = 90. ml = 90. 32',5, therefore ZX *= 89. 27',5. The axis OF meets the surface of the sphere of projection in b. If the parameters of the crystal be a, 6, c, since u is (212), ^acos uX = b cos ub = ^c cos ^ Z. Sec w X sec ^ cosec tl, secuZ = sec ut cosec tm. Therefore a, 6, c are proportional to Zsecut cosec /, secwo, sec ^ cosec ?w. To find the symbols of the faces referred to the axes of the zones %%\ mt, oo' as crystallographic axes. The symbols of the zones ##', mt, oo', when referred to the old axes, are [1 l], [0 1 0], [001] respectively. Therefore (28), if (u v w) be the symbol of any face referred to the old axes, (u 1 v w 1 ) its symbol when referred to the new axes, v! u w, v'= v 9 w w. If the new axes OZ', OX' meet the surface of the sphere of projection in Z', X ', Z'X'= 180- mt = 115. 24'. 219. In a crystal of Felspar (fig. 95), the zones which determine the symbols of the faces are tzmz't', pqxyp, pnmn'p, xomox, qoznq, potp, yonty^ m is perpendicular to the faces p, q, #, y, therefore m is (010). Let t be (1 10), t' (Tio), o (111). Then (17) the symbols of the remaining faces will be p (001), w (0 2 l), y (20 1), as (l 1), x (130), g (203). Hence the crystal is a combination of the forms Joio}, {OOl}, {lio}, {l30}, {02l}, {20l}, {lOl}, {203}, {l 1 l}. It is cleavable parallel to the faces of the forms J00l}, {l 1 0}, {o 1 0^. 94 Having given tt', pt, px, t, p, or, &c. (fig. 96), being the poles of the faces t, p, x, &c., to determine the positions of the poles q, y, n, o, ss. Let tt f , px meet in a. Then a will be (100). mt = \tt\ cospt = sin mt cos pa. The right-angled triangles xpo, apt, having a common angle at p, give sinpacotom = sin pa; cottm. 2 cotpq 3 cot poo cot pa, 2 cot py = cot px + cot pa (27). Tan mt = 3 tan m% (207). The right-angled triangles tya, n'yp', having a common angle at y, give sin aycotmn'= sin p'y cot mt. If tt'= 118. 49', p = 67. 44', p<# = 60.20', we shall have pa = 63.5S / , OTW = 63. 7', ^ = 34. 13', py = 80 Q .23 f , m% = 29. 25', raw' =45. 3'. 220. In a crystal of Oxalic acid (fig. 97), the zones pacp', peep' have their axes at right angles to each other. a em a', cemc are zones, p, a, c, &c. being the poles of the faces p, a, c, &c. pa = 50. 40', |?c = 76. 45, raw'= 63. 5'. If the zone-circles ^a, mm' meet in d, it appears from ap- proximate measurements that 2 cot^d = cot pa cot pc (27). Whence pd=73.4<3'. The right-angled triangles ecp, mcd, having a common angle at c, give sinpccotjpe = sin dc cot md. Whence pe = 72. 44', ee- 34. 32'. It fre- quently happens that there are no faces parallel to the faces , e'. In this case (204) the form to which the faces e be- long is hemihedral. CHAPTER VII. DOUBLY OBLIQUE PRISMATIC SYSTEM. 221. In the doubly oblique prismatic system the form {h k 1} has the two faces (h k I) (hk 7). 222. To determine the position of any pole. Let the axes of the crystal meet the surface of the sphere of projection in X, F, Z (fig. 98). Let A, B, C be the poles of (1 0), (1 1), (0 1), P the pole of (h k I). XYZ, ABC are supplemental triangles. cos PX = sin PEC sin PB = sin PCS sin PC, cos PY - sin PC A sin PC = sin PAC sin PA, cos PZ = sin PAB sin PA = sin PBA sin PB. But - = - cos PY= - cos PZ. h k I Whence - sin PAC = j sin PAB, K v f* CL - sin PB A = - sin PBC, I h a b - sin PCB = - sin PC A. h k .-. tan 1 (PAB - PAC) = tan \BAC tan (45 - 0), k c where tan - - - ; / o 96 tan 1 (PBC - PEA) = tan \CEA tan (45 - 0), where tan d> = ; A c tan 1 (PCJ - PCB) = tan 1JC5 tan (45 - >/,), h b where tan v//- = . k a Whence, knowing the angles A, B, C, the segments into which they are divided by PA, PB, PC become known. 223. Let PX, PF, PZ meet the sides of ABC opposite to Ay B, C, in #, y, %. The angles at ; cot me = 2 cot mf cot ra^ ; cotfg = 2 cotfy cotfv ; cot ms = 2 cot m r . The faces qq form a re-entering angle. 239. A twin crystal of Diamond (fig. 109) is composed of two hemioctahedrons, the faces of which are parallel to the alternate faces of the same octahedron. One half form comes into the position of the other by revolving through 180 round a normal to a face of the form {o 1 l}, which is therefore the twin axis. 14 106 240. A twin crystal of Yellow Iron Pyrites (fig. 110) is composed of two hemitetrakishexahedrons, the faces of which are parallel to the faces of the same holohedral form. It is easily seen by inspecting fig. 10, that the poles of one form will coin- cide with those of the other after revolving through 180 round any two opposite poles of {oil}. Therefore the twin axis is a normal to any face of {o 1 l}. 241. In the first four of the preceding examples we have found the twin axis to be perpendicular to a face of the octa- hedron. This is perhaps the only way in which the individuals of this system composing twin crystals are united. Twins analagous to the last two examples, in which the twin axis is perpendicular to a face of {o 1 l}, can only be produced by the union of hemihedral forms. In such crystals, (Mohs Naturgeschichte des Mineralreichs 154 158), the crystallogra- phic axes of one of the presumed individuals are parallel to those of the other, and the cleavages of one are parallel to those of the other, or continued into it without interruption. We cannot therefore determine with certainty whether such crystals are to be considered as twins or as single crystals the faces of which are repeated with a certain degree of regularity. Examples of Twin Crystals belonging to the Pyramidal System. 242. In twin crystals belonging to the pyramidal sys- tem, the twin axis is perpendicular to a face of one of the forms {l 00}, {l 1 o}, {h O/}, [hhl\. 243. In a twin crystal of Oxide of Tin (fig. Ill), the two pyramidal faces s, s' of one crystal are respectively pa- rallel to the corresponding faces s', s of the other. One crystal comes into the position of the other by making a half revolution round an axis perpendicular to the face which belongs to the zone ss' 9 and makes equal angles with the faces s, s. This line, therefore, is the twin axis. Let c be the pole of (0 1), t the pole of the face which truncates the edge formed by s, s'. cs 43. 38'; whence (112) ct = 107 .33. 59', s = 29. 12', ts"= 71. 23', tg = 63. 35', *#"= 119. 12'. Whence ^= 52. 50', g"g"= - 58. 12', 5^= 121. 36', s'V'= 37. 14'. If we assume the symbols of the faces s, s f to be (l 1 l), (l 1 1), the symbol of t will be (l 1). If we assume s, s to be (101), (Oil), t will be (112). 244. In a twin crystal of Copper Pyrites (fig. 112), the zone pp coincides with the zone p,p/j and the face p is parallel to the face p^ In this case the twin axis is mani- festly perpendicular to p, a face of the form {ill}. If p, p, p", &c. be the poles of the faces p, p, p", &c., pa = 54. 20', pp"= 108. 40', pp'= 70. ?', pp"' = 109. 53', pb = 29. 45', pc = 39. 5',5. Hence ,= 71. 20', p"p'/= - 37. 20', p'pf= 39. 46', p'"p/"= - 39. 46', &X= 20. 30', cc,= 109. ll'. 245. The individuals composing a twin crystal of Copper Pyrites (fig. 113) are square pyramids, having a hemihedral character in consequence of the very unequal size of their alternate faces. The large faces of one crystal are parallel to the small faces of the other. One crystal will evidently come into the place of the other by revolving through 180, round an axis perpendicular to any one of the faces of a square prism truncating the edges pp 9 p'p'. The twin axis will, therefore, be a normal to a face of|lOO}or|llo}, according as we consider p to be a face of 1 1 1 } or of {ill}. 246. In a twin crystal of Scheelale of Lime (fig. 114), the individuals are similar to the crystal represented in fig. 55, and are joined so that the faces p of the two crystals coincide with each other. One crystal will come into the place of the other by revolving through 180 round an axis perpendicular to any one of the faces of a square prism truncating the edges PP> P'P'J or nn - H e ce the twin axis is a normal to a face of either of the forms { 1 0}, { 1 1 0} . 247. In the last two examples the axes and cleavage planes of the two crystals are parallel. The propriety of con- 108 sidering them twin crystals is, therefore, doubtful. On the other hand, in the last example, the hemihedral forms are dis- similar, and striae, which run parallel to the intersection of a with p 9 meet in a line which divides the faces pp^ p'pf into two parts each of which appears to belong to a different crystal. Examples of Twin Crystals belonging to the Rhorabohedral System. 248. In twin crystals belonging to the rhombohedral system, the twin axis is either perpendicular to a face of { 1 1 1 } , or to a face of one of the rhombohedrons. 249. In a twin crystal of Calc Spar (fig. 115), the in- dividuals of which are combinations of the forms {o 1 1^ (#), {l!2^ (c), the faces c of the two crystals coincide with each other. One crystal comes into the position of the other by revolving through two right angles round a line parallel to the intersection of c, c. But this line is perpendicular to the face (l 1 l), and is, therefore, the twin axis. 250. The individuals composing the twin crystal of Calc Spar (fig. 116), are rhombohedrons, the faces of which are parallel to the cleavage planes. The two obtuse angles which the faces of one crystal make with those of the other are equal ; and the angle between normals to the two faces p, p / is equal to twice the angle between a normal to p 9 and a nor- mal to the face (l l 1). Hence one crystal will come into the place of the other by revolving through two right angles round a normal to (l 1 l), which, therefore, is the twin axis. 251. The individuals composing the twin crystal of Calc Spar (fig. 117), are combinations of the forms |l 1 l| (o), {112} (c). The zone co coincides with the zone cp t . cc = 52. 30',5. Let the arcs cc /5 cV, through the poles of opposite faces of the two crystals meet in , t'. t'c t - 90 - \cc = 63. 45'. ot = 90- t'c = 26. 15'. Therefore t is the pole of a face of the form ^01 l}. Hence the twin axis is perpendicular to a face of the form $01 l}. 109 252. In the twin crystal of Calc Spar (fig. 118), the indi- viduals of which are combinations of {112} (c), {20l| (r), {110} (#), {ill} (/)> the zone#c in one crystal coincides with the zone gp t in the other, and the distance between the poles of g, g t =38. l6',4. Let t be the intersection of the circles gg^ rr drawn through the poles of opposite faces of the two crystals. Then tg=90- \gg = 70. 5l',8, therefore t is the pole of a face of the cleavage rhombohedron { 1 0} . Hence the twin axis is perpendicular to a cleavage plane. C 3 > r > f being the poles of the faces c, g, r, /, tc = 45. 23',4, therefore cc y = 89. 13',2. tc = 68. 5?', therefore cV= 42. 6'. tg'= 37. 27',5, therefore gg f '= 105. 5'. tf= 107. 44', therefore ff= - 35. 28'. */'=50. 34',5, therefore ///= 78. 5l'. 253. The individuals composing a twin crystal of Calc Spar (fig. 119) have the form ^20l}- The faces r, r of one crystal are respectively parallel to the faces r /5 r' t of the other. The places of r, r are interchanged, and one crystal comes into the position of the other by revolving through two right angles round a normal to a face of { i i i } , the pole of which bisects the arc joining the poles of r, r. Hence the twin axis is per- pendicular to that face of {ill} which truncates the edge formed by r, r. 254. In a twin crystal of Ruby Silver (fig. 120), the faces ss 9 z of one crystal coincide with the faces # /5 xj of the other. One crystal will therefore come into the place of the other by revolving through two right angles round a per- pendicular to a face, the pole of which bisects the arc joining the poles of % 9 %'. The poles of bisect the arcs joining the ad- jacent poles of the cleavage planes. %%' 42. 2l'. If we make the cleavage rhombohedron {l 00}, #, % will be poles of the form J 1 1 1 , and the twin axis will be perpendicular to a face of {21 l}. Examples of Twin Crystals belonging to the Prismatic System. 255. In a twin crystal of Aragonite (fig. 121), the zone mm' of one crystal coincides with the zone mm\ of the other. 110 and the faces m, m t of the two crystals are parallel. Hence one crystal will come into the place of the other by revolving through two right angles round a normal to m, which is, therefore, the twin axis. m, h, k being the poles of the faces m, h, k, we have wm'=63. 50', mh=58.5 f , hk=54?.13 f . cosmk therefore mk = 71. 59,5, mk'= 108. o',5. Whence 52. 20', hh = 62. 50', ,= 36. l', k'k'= - 36. l'. 256. In a twin crystal of Staurolite (fig. 122), the zone or of one crystal coincides with the zone or t of the other, and the distance between the poles of 00= 60. 36'. mm'= 50. 40', 2>r = 55. 22'. From these data it appears that, if we make o (100), p (001), m (110), r (Oil), a point in the great circle oo /? 90 from the bisection of oo /? and therefore 120. 18' from o, in the zone-circle or, will be the pole of (3 2 2). Hence the twin axis is perpendicular to the face (322). Let t be the pole of the twin face, m, p, r the poles of the faces m, p, r, tfm = 64. 46', tm'= 115. 14', tp = 6, which, therefore, is the twin axis. p, , %, x being the poles of the faces p, t, #, #, we have px = 50. 19', pt = 112. 16', p% = 102. 29'. Therefore xx = 79. 22', tt= - 44. 32', xx= - 24. 58'. 112 Example of a Twin Crystal belonging to the Doubly Oblique System. 262. In a twin crystal of Cleavlandite (fig. 128), the zone Imt of one crystal coincides with the zone l^J, of the other, and the faces m, m i are parallel. Hence one crystal will come into the position of the other by revolving through two right angles round a normal to w, which, therefore, is the twin axis. Let p, m, , / be the poles of the faces p, m, t, /, the faces p 9 m being parallel to the two most perfect cleavages. It is found that mt = 62. ?', ml = 60. 8', mp = 93. 36'. Therefore tt = 54. 56', //,= 59. 44', pp = - 7. 12'. 263. Occasionally several crystals are joined together in such a manner that every two adjacent crystals are united according to the law stated in (230). In many twin crystals, as the preceding examples shew, faces of the two individuals make with each other re-entering angles. The occurrence, however, of such angles is not always to be taken for a character of a twin crystal ; for two or more faces of a simple crystal may be repeated, and thus form a re-entering angle In some instances the faces are repeated several times, forming a corresponding number of parallel grooves, which, when the faces are very narrow, produce the striae observed upon the faces of certain forms of some crystals. CHAPTER IX. GONIOMETERS, &c. 264. CARANGEAU'S Goniometer consists of two small metal rulers (fig. 129), fastened together by a pin so as to move stiffly on each other. In order to measure the mutual inclina- tion of two faces of a crystal, the rulers are placed with their edges touching the faces of the crystal in lines perpendicu- lar to the intersection of the faces. The rulers are then applied to a graduated semi-circle (fig. 130), without altering their position with respect to each other, so that the intersec- tion of their edges may coincide with the center of the gradu- ation. The portion of the graduated arc, contained between the edges of the rulers, will then measure the inclination of the planes, or the supplement of the distance between their poles. This instrument is obviously incapable of affording accurate results. 265. The Reflective Goniometer of Wollaston is repre- sented in fig. 131. A graduated circle L, the divisions of which may be read off to minutes by means of a vernier N 9 is fixed on a hollow axle which may be turned round by the milled head M. An axle CS passing through the hol- low axle of L 9 and which either turns with the circle L 9 or may be turned independently by means of the milled head at S, carries a crooked arm CF. The part FG is connected with 'CF by a joint which permits it to turn round an axis perpendicular to CS, passing through CS produced, and has a collar at G in which the pin HK turns and slides with its axis perpendicular to the axis of FG, and passing through the point in which SC produced intersects the axis of FG. The crystal is fastened by means of a soft cement to a thin plate of metal, fixed in a slit at K. 15 114 266. To measure the angle between two faces of a crystal. Let p, q be two faces of a crystal, (p,q) the angle be- tween lines drawn from any point within the crystal perpen- dicular to p, q respectively, or the distance between the poles of p, q. Make the intersection of p, q parallel to the axis of the circle, and as nearly coincident with it as possible, by means of the angular motion of FG, and the angular and sliding motion of HK. Place the instrument upon a firm stand ; and let A, B (fig. 132) be two signals in a plane pass- ing through a point C in the intersection of the faces p, q, and perpendicular to the axis of the circle. Turn the circle till the image of one of the signals A, seen by reflexion in the face p, coincides with B viewed directly, and read off the arc at which zero of the vernier stands. Now turn the circle till the image of A, seen by reflexion in 41 i 01 1 10 Ti 2 1 751 111 1 10 1 1 1 121 42 i 00 021 1 10 102 752 1 10 101 1 1 1 310 i43 i 1 1 10! 101 120 753 1 1 1 10! 1 1 1 120 144 i 1 1 1 00 1 20 112 754 1 1 1 Tl 2 1 21 iTo 51 i 1 1 001 2ll 120 755 1 1 1 1 00 1 2T lT3 152 i 1 1 001 321 ilo 760 100 010 1 03 22 1 >53 i 1 1 00 1 121 2 To 761 101 1 10 I 2 1 31 1 16 122 762 I 1 102 1 2 1 201 772 l 1 00 1 1 30 1 1 763 00 121 1 1 1 1 03 773 1 1 001 2lo 1 31 764 00 032 1 1 1 2 ll 774 L 1 001 121 3 To 765 1 1 10! 1 2 1 20 1 775 i 1 001 1 2 1 3 Ti 766 1 1 100 22 1 103 776 i 1 001 1 2 1 C 2 3 1 771 1 1 00 1 13 1 32 1 If we commence with (l 1 1), (l 00), (0 1 0), (00 1), from which the positions of the poles of crystals belonging to the rhombohedral system are most obviously deducible, we must substitute for the first two lines of the table 110 111001 100010 llo 011101 1 00 01 Tii 001110 100011 277- Tables for converting the symbol of any form in different systems of crystallographic notation into the equiva- lent symbol in the notation used in the preceding pages. If the indices, when expressed in numbers, appear as fractions, they must be multiplied by the least common multiple of their denominators. 1. Modified notation of Hauy employed by Mr Brooke, (Enc. Metropolitana, Art. Crystallography). The same table serves also to translate the notation of M. Levy, (Description d'une Collection de Mineraux formee par M. H. Heuland), the indices of which have the same ratios as in the preceding notation, but often differ in magnitude. Octahedral System. P \\ 00} A {vll} B {vio} B,B 9 'B r " {qr,rp,pq 123 Pyramidal System. M {ioo\ B [iov\ P {001} G {vio} A {llv} B p B q 'G r {qr,rp,pq\. Rhombohedral System. i 100 * E (Levy) {- t) E |.. } V O f-.l 1} V B \v 1 0} (Prisme hexaedre ; Levy) P {111} i" + 3 '"'- Prismatic System. J/ {110} A, {-!, + !,!} P I 001 ! ^ {-I, + l,o} ^ {0, 2t), 1} ^ {o + l, -1,0} B {lie} B p B,'H r {qr-rp,qr+rp,pq\ E {8., 0,1} B,S 5 "G + !, 0-1, lj 124 Oblique Prismatic System. Jf {110} A n {0 + 1, 0-1, -if V O ^2 00 1 ' i ^ ~~ ^? ^ ~i~ ^5 -^ ( O, {0 + 1,0-1, 1} JJ {0 + 1, -.1,0} 4 {20, 0, ij G {0- 1, + 1. 0} V f B p B q 'H r ' \rp + qr,rp-qr,-pq\ B p D q G, (rp-qr,rp+qr,pq\ jj x E {0,20,1} Doubly-oblique Prismatic System. T 7 jlOOl ^ {I J/ {010} P {001^ ^ {i O H D [oiv] p q B p D q G r F The first, second and third indices become respectively negative when E, I and A are substituted for O. 2. Notation of Mohs. 125 Octahedral System. H {100} B> {332} O {111} c, {211} D {011} C 2 {311} 4 \320\ T, {231} A., \210\ T {531} A, \310} T 3 {421} Pyramidal System. [P+co] { 10 } P-CC 5001} P+OC 5110} (P+oo)* {mio} [(P+ co)'"] \m + l, P ,:-- {111} jr2 n ,0,l} |r2 R + 1 ,0,l} - 1 {r2",r2 M , l} { (rP + 2n- l) m \(m 126 Rhombohedral System. {in} R {100} {21l} P m \m + l,0,l-w| {oil} (P+co) w {3m + l,-2,l -3m] rf + rais {h k k}, where (A - k) -~- (A + 2 &) = r2". If Q be a pole of any rhombohedron, (Q) its symbol in the notation of Mohs or Naumann ; D an adjacent pole of |o 7 1 } ; S a pole of {& + /, - A;, - /J adjacent to Q and Z>; O a pole of {l 1 1 }; T the intersection of QZ>, OA^, the symbol of T, in the notation of Mohs or Naumann, will be (Q)" 7 ? where m = (k + 2l)-r-3Jc. Prismatic System. P + n {2",2%l} {0, (m {(m+ l)2 n ,0,2} (Pr-f ri) m \(m- l)2",(m + 1)2%2} (Pr + n) m {(m + l)2 n 5 (m - l)2",2}. Oblique Prismatic System. Let (P) denote the symbol, according to Mohs, of the (P) (P) form \h kl} in the prismatic system. Then --- , - will be [hkl], [hJcl] respectively, in the oblique prismatic system. When the form \h k 1} has the same number of faces in either system the 2 in the denominator is omitted. 127 Doubly-oblique Prismatic System. Let (P) be the symbol, according to Mohs, of the form \hkl\ in the prismatic system. Then -r will be [h k /}; -I- - \hll}', r^ * - {ft&7{; l{hJcl\,iu the doubly- oblique system. When \hk 1} has twice as many faces in one system as in the other the denominator is changed to 2, and when it has the same number of faces in either system it is omitted. 3. Notation of Naumann. Octahedral System. coOco {100} mOm {mil} O \ lll \ O {mml} co O { 011 } mOn {m,mn<,n]. co On \n I 0} Pyramidal System. co Pco I 100 } >P \mml\ OP { 01 } mPco {mOl} co P I 110 } co Pw \n 1 0} P I 111 } mPra |m,m^,n|. Pco {101} Rhombohedral System. OR {ill} R" 1 {m + 1,0, 1-m} co R {sll} 2R m {m, 1, -m} coP2 {oil? coP'" {-m, m-1, 1} 128 Prismatic System. P {HI? mPn \r OP { l \ ^ n [lnn\ co P { 110 } mPn \mn,m,n\ mP \mm\\ p n \nln\. Oblique Prismatic System. OP \ 001 \ -mPn [-mn,m,n} P [ lll \ Pn {nln} mP \mrnl} (mPn) \m,mn,n] mP \-mm\\ (P^) \lnn\. C * ' C 3 mPn \mn,m,n\ Doubly-oblique Prismatic System. P' {ill}; ; P {Til}; P t {ill?; f {ill}. The symbols of the other faces are derived from P', 'P, P , P as in the prismatic system. 4. Notation of Weiss. Octahedral System. 1 1 l - a : Q ', ', \h k l\ . h k I Pyramidal System. i l 1 JL ' !* kl}. Rhombohedral System. c h + k a Prismatic System. h a: CHAPTER X. DRAWING CRYSTALS AND PROJECTIONS. 278. THE figures of crystals are usually projections, upon a plane, of the edges in which their faces intersect, by lines pa- rallel to a given straight line. Since the lengths of the edges of a crystal are not subject to any known law, the edges in the figure need not be either equal or proportional to the projec- tions of the edges of any given crystal. In the rhombohedral system the plane of projection is generally parallel to one axis, and makes equal angles with each of the other two axes. In the remaining systems the plane of projection is generally parallel to two of the axes. The following rules for drawing crystals will not require any demonstration. 279. To draw the axes of a crystal. When a plane of projection is parallel to the axes OZ, OX-> draw ZOZ', XOX' (fig. 135), making with each other an angle equal to the angle between the corresponding axes of the crys- tal, and any line YOY' making finite angles with ZOZ', XOX'. Then, the three lines XOX', YOY', ZOZ' will represent the three axes of the crystal. If in OZ, OX, we take OC, OA proportional to the parameters c, a respectively, and OB of any magnitude, OA, OB, OC will represent the parameters of the crystal. In the rhombohedral system, make the angle ROC (fig. 136) equal to the angle between a normal to (l 1 l) and either of the axes of the crystal. Draw CRS perpendicular to OR, making RS - ^ CR. Through S draw ASB making any angle with CS, and in ASB take A, B at any equal distances 17 130 from 5. Then, the three straight lines OA, OB, OC will represent the axes, and the distances OA, OB, OC will re- present the parameters. When the position of the plane of projection with respect to the axes is arbitrary, the axes may be represented by any three lines meeting in one point. 280. To draw lines parallel to the intersections of the plane of the face (h k I) with the planes through the axes. Let OA, OB, OC (fig. 135.) represent the parameters of the crystal. Take OH, OK, OL respectively proportional to - OA, - OB, - OC. Then KL, LH, HK will be parallel ft r ' to the lines in which the plane of the face (h k I) intersects the planes YOZ, ZOX, XOY. When one of the indices h, k, I is zero, the corresponding axis will be parallel to two of the intersections. 281. Let the sides of the triangles HKL, PQR (fig. 137.) be parallel to the intersections of the planes of two given faces with the planes YOZ, ZOX, XOY. Let the intersections with YOZ, ZOX, ^OFmeet in U, V, ^respectively. Then a line through any two of the three points U, V, W, will pass through the third, and will be parallel to the projection of the edge formed by the intersection of the two given faces. If we draw lines, by the above method, parallel to the projections of all the edges of a crystal, meeting each other in the order in which the edges meet, the figure thus obtained will be the figure of the crystal. 282. To draw the axes of a twin crystal. Construct fig. 138. so that OU, 0V, OW may be propor- tional to the parts of the axes of either crystal cut off by the twin plane, and VOW, WOU, UOV equal to the angles YOZ, ZOX, XOY respectively. From the points O draw lines per- pendicular to the adjacent sides of the triangle UVW, meeting 131 in T, and draw the lines UTu, VTv, WTw. Let OX, OF, OZ (fig. 139.) represent the axes of one of the crystals; U 9 V 9 W the points in which they are intersected by the twin face. Divide two of the sides of UVW into segments proportional to the corresponding sides of UVW (fig. 138.), and let the lines through the points of division and the opposite angles intersect in T. Then OT represents a perpendicular on the plane UVW. Take OO'=<2OT. Then O'U, O'V, O'W will re- present the axes of the second crystal. Let (u v w) be the symbol of the twin face. Take O'A'= u . OU, O'B'= v.O'V, O'C'=w.O'W-, then 'A ', O'J9', O'C' will represent the pa- rameters of the second crystal. The axes and parameters having been projected, the faces of the two crystals may be drawn by the rules already given. 283. No representation of a crystal is capable of exhi- biting the relative positions of its faces, the zones which they form, and the kind of symmetry with which they are arranged, so clearly as the figure of a sphere having the poles of the faces of the crystal laid down upon its surface. This method of representing a crystal, which was invented by Professor Neu- mann of Konigsberg, possesses the additional advantage of enabling us to investigate all the geometrical properties of crystals by spherical trigonometry alone, without the aid of either solid or analytical geometry. When the figure of the sphere is either its stereographic or gnomonic projection, many problems of crystallography may be very expeditiously solved by simple geometrical construc- tions. On this account the following investigation of the principal properties of the stereographic and gnomonic pro- jections has been given. 284. In the stereographic projection, points and circles upon the surface of a sphere are referred to the plane of a great circle of the sphere, called the primitive, by lines drawn to one of the poles of the great circle. To an eye placed in this pole of the primitive, the projection of any point will be the picture of that point on the plane of the primitive. 132 285. Let O (fig. 140) be the center of a sphere which is to be projected stereographically ; E, C the poles of the pri- mitive, the eye being at E ; P 7 , Q' any two points on the surface of the sphere. The straight line EC meets the plane of the primitive in 0; .-.0 is the projection of C. Draw the straight lines EP, EQ' meeting the plane of the primitive in P, Q; .'. P, Q are the projections of P', Q'. Let r be the radius of the sphere. Then OP = r tan OEP = r tan 1 CP'. In like manner OQ = r tan 1 CQ'. The angles QOP, Q'CP' are manifestly equal. A straight line drawn from E to any point in the great circle CP' will meet the plane of the primitive in OP. Hence a great circle passing through the poles of the primitive is projected into a straight line passing through the center of the primitive. 286. Let Q' be any point in a circle of which P' is the farther pole; P, Q the projections of P', Q'. Then cos P'Q' = cos P'C cos Q'C + sin P'C sin Q'C cos Q'CP' r QO whence, (cos P'Q' + cos P'C) QO 2 - 2r sin P'C cos QOP. QO + r 2 (cos P'Q 7 - cos P'C) = 0. Therefore Q is a point in a circle having its center in OP. 287- Let the given circle meet CP' in M', N' ; and let M, N be the projections of M', N'. Then M'N will be a diameter of the projection of the circle. Let K be the center of the circle M QN. Then 2^Q = r tan 1 (P'Q' + CP') + r tan 1 (P'Q' - CP'), 2 .fiTO = r tan \ (P'Q' + CP') - r tan 1 (P'Q' - CP'). When Q' is a point in a great circle, P'Q' is a quadrant. Therefore KQ, = r sec CP', ^TO = r tan CP'. 133 When Q r is a point in a small circle the pole of which is in the primitive, CP' is a quadrant. Therefore KQ, = r tan P'Q', KO = r sec P'Q'. A circle passing through E, the place of the eye, will manifestly be projected into a straight line. 288. To draw the projection of a great circle through two given points. Let Q be the most distant of the two points P, Q (fig. 141); O the center of the projection. Draw OE perpendicular to OQ meeting the primitive in E ; EQ meeting the primitive in q; q O meeting the primitive in s ; Es meeting QO in S. A circle through QRS will be the projection of a great circle. For QS is the projection of an arc equal to qs ; .'. Q, S are the projec- tions of opposite points of the two extremities of a diameter of the sphere. Therefore the circle projected into QRS is a great circle. 289. Having given the projection of a great circle; to find the projection of its pole. Let GMH (fig. 142) be the projection of a great circle, meeting the primitive in G 9 H, and, therefore, GH a diameter of the primitive. Through O, the center of the primitive, draw MO perpendicular to GH. Draw GM meeting the primitive in m. Make mp a quadrant ; and draw Gp meet- ing M O in P. Then P will be the point required. For MP is the projection of a quadrant mp, and G, H are the poles of the circle projected into MP. Therefore GMH, P are the projections of a great circle and its pole. 290. If a great circle and its pole be projected into GQH and P (fig 143) ; and if straight lines PQ, PR be drawn meeting the primitive in q, r, the arc qr will be equal to the arc projected into RQ. For PQq, PRr are the projections of small circles passing through the pole of the circle projected 134 into GQH and through the place of the eye, which is one pole of GqH. But two small circles drawn through the poles of two equal circles manifestly intercept equal arcs of the equal circles. Therefore rq is equal to the arc projected into RQ. 291. To find the angle between two great circles; having given their projections. Let GR, LR (fig. 144) be the projections of two great circles intersecting in R. Let the poles of the circles be projected into P, Q. Draw the straight lines RP, RQ meet- ing the primitive in p, q. The angle between the circles projected into GR, LR is measured by pq. For R is the projection of the pole of the great circle projected into PQ. Therefore pq measures the distance between P, Q, the poles of the circles projected into GR, LR, and therefore it measures the angle between the circles which are projected into GR, LR. 292. Let O be the center of the primitive MN (fig. 145) ; MQ the projection of a great circle MQ' ; K its center; C the farther pole of the primitive; CQ' a great circle meeting MQ' in Q' and the primitive in N. Then the straight line OQ will be the projection of CQ' ; OQ = r tan 1 CQ' ; KQ = r sec Q'MN; KO = r tan Q[MN. The spherical tri- angle MNQ' is right-angled at N. Whence KO sin KQO = -- sin KOL = sin Q'MN cos MN = cos MQ'N. KQ LO = KO sin MN = r tan Q'MN sin MN = r tan NQ'. Hence, when the arc CQ' and the angle MQ'C are given, if we make = rtanlCQ'; OL = r cot CQ' ; OQK = 90 - MQ'C, and draw LK perpendicular to ON; the circle MQ described round K as a center, with the radius KQ, will be the pro- jection of MQ'. 135 293. Let SQ be the projection of any other great circle S'Q' passing through Q', R its center. Then OQR = 90 - S'Q'C. But 0^ = 90- JJ/Q'C; . Therefore the angle between any two great circles is equal to the angle which their projections make with each other at the point in which they intersect. 294. When a crystal belongs to the octahedral system, the projection of the sphere, upon which its poles are laid down, may have either the zone-circle through two adjacent poles of JO 1 1 j, or the zone-circle through two adjacent poles of {lOO}, for its primitive. When the crystal belongs to the pyramidal or prismatic system, it will be found convenient to take the zone-circle through the poles (l 00), (0 1 0) for the primitive. When the crystal belongs to the rhombohedral system, the primitive should be the zone-circle containing the poles of {oT]J- When the crystal belongs to the oblique- prismatic system, the primitive should be the zone-circle through (001) and (100). When the crystal belongs to the doubly-oblique system, any zone-circle may be taken for the primitive. 295. To draw the stereographic projection of the poles of a crystal of Axinite (fig. 100), having given mp = 45. 12', pf= 44. 43', mx = 49. 32', my = 79. 24', fas 64. 5?'. Let the zone-circle mp (fig. 101) be taken for the primitive; and let O be its center, r its radius. Make mp = 45. 12', pf = 44. 53', and draw diameters mOm , pOp', fOf. In Of take OK = r sec 64. 5?', and in Om take OL = r sec 49. 32', and with centers JT, L and radii Kfc-rism 64. 5?', L oo = r tan 49. 32' describe circles intersecting in x. Draw the circles mxm ^ poop, foof- Draw OM perpendicular to Om, meeting mxm in M; m'M meeting the primitive in J/'; take M'N' a quad- rant, and draw m'N' meeting OM in N. In mpm take mY = 79. 24', and draw the straight line ^F meeting mxm in y. Draw pyp', and fyf meeting posp in v. Draw 136 mvm meeting foof in , and pyp in w ; fw'f meeting mxni in c, and pxp in w, and ptp meeting mxm in s. Draw OT perpendicular to Ot meeting the primitive in T 7 ; draw TU perpendicular to t T meeting Ot in U 9 and draw the circle Uyt meeting mpm in e, and fwf in o. Draw eve' meeting pyp' in g; fsf meeting mvm in Z; pip meeting mxm in r, and mom meeting fyf in g. Then m 9 p, at, &c. will be the projections of the poles of the faces m, p, #, &c. 296. In the gnomonic projection of the sphere, points upon the surface of the sphere are referred to a plane touching the sphere by lines drawn through them from the center of the sphere. To an eye placed in the center of the sphere, the projection of any point will be the picture of the point upon the plane of projection. 297. Let O (fig. 146) be the center of a sphere ; C the point in which the sphere touches the plane of projection, and which is termed the center of the projection ; P, Q any two points on the sphere. Draw straight lines OP', OQ' meeting the plane of projection in P, Q. Therefore P, Q are the projections of P', Q'. Let r be the radius of the sphere. Then CP = r tan CP', CQ = r tan CQ', and QCP = Q'CP . The plane of every great circle passes through O, and intersects the plane of projection in a straight line. Hence the projection of a great circle is a straight line. Let PQ be the projection of a great circle P' Q' having its poles in the great circle CP'. Then, since the planes CPQ, OPQ are perpendicular to the plane CPO, their intersection PQ will be perpendicular to CPO, and, therefore, PQ will be perpendicular to CP. 298. Let O (fig. 14?) be the center of the sphere; C the center of the projection ; Q'/?' an arc of a great circle ; QR its projection. Draw ECB perpendicular to QR. Make DB = CO, EB = CD. QR is perpendicular to BE and BO, and BE=CD = BO. Whence QER = QOR. Therefore QER measures the arc Q'R'. 137 Hence we can measure the arc of a great circle projected into a given straight line ; or cut off' a portion of a given straight line, which shall be the projection of a given arc of a great circle. 299. Let C (fig. 148.) be the center of the projection ; O the center of the sphere ; CQ, PQ the projections of two great circles CQ', P'Q'; CP f perpendicular to CQ', and, there- fore, ECP perpendicular to CQ. Take CE = CO. Draw CF perpendicular to QE 9 and make CG = CF. Then, CG = CQ cos CQ', tan PQC = cos CQ' tan CGP. Therefore CGP = CQ'P'. Hence we may either find the angle between two great circles of which the projections are given ; or, having given the angle between two great circles, the projection of one of them may be drawn through a given point in the projection of the other. When CQ' is small, the above method of comparing the angle between two great circles with the angle between their projections is not so accurate as the following. 300. Let C (fig. 149) be the center of the projection ; CQ, PQ the projections of two great circles CQ', P'Q'. Draw HQ perpendicular to CQ, and make HQ equal to the radius of the sphere. Make KQ = CH ; bisect HK in Z,, and let PQ meet HK in P. HQ KP KP HL - LP Hence tan Q = .. HL I + tan Q' 18 138 no If / = Q0 - CO' (sin *)*} For the purpose of facilitating the above construction sectors are provided with a scale called " inclination of meridians," in which the distance between the divisions 0, ra = c{l - tan (45 - m) J, and with a scale called "lati- tudes," in which the distance between the divisions 0, 1 2c sin Z Let rad. sphere = CQ tan 1. Draw QH perpendicular to CQ, making QH = (0, 1) of the line of latitudes. With center H, and radius HK = (O n , 90') of the line of inclination of meridians, describe a circle cutting CQ in K. Then, it will be easily seen that, if KM = (0, m a ) of the line of inclination of meridians, MQ will be the projection of a great circle that makes an angle of m with the great circle projected into CQ. 301. The gnomonic projection may be used with ad- vantage in projecting the poles of a crystal belonging to either of the three systems in which the three axes make right angles with each other. The plane of projection is most conveniently situated when it meets the three axes at equal distances from their intersection. The axes FZ, ZJf, XY will then be pro- jected into the three sides of an equilateral triangle. When the crystal belongs to the rhombohedral system, the plane of projection may be parallel to a face of {l 1 ij, or of {2 IT}- When the crystal belongs to the oblique prismatic system, the plane of projection may be parallel to the faces of {010J ; and when it belongs to the doubly-oblique system, the plane of projection may be parallel to any face. 302. To draw the gnomonic projection of the poles of a crystal of Topaz (fig. 8?) on a plane meeting the axes at equal distances from their intersections ; having given ru 22. 15', rZ = 43.26', rm = 62.10' ? pn = 43. 30', py = 62. 13', o = 45. 27'.- 139 Let/ be the pole (010). Then r,/, p will coincide with X, F, Z, and the arcs joining the poles of r, f, p will be pro- jected into the equilateral triangle r, /, p (fig. 134). Let C be the middle point of the triangle. Draw /C, pC meeting pr, r/in M 9 N. Let O be the centre of the sphere. Then OC will be perpendicular to the plane rfp. Or = O/, and rO/= 90, whence ON = Nr. With centre C and radius Nr describe a circle cutting Nr in Q. CN is common to the triangles QNC, OCN 9 QC = N0 9 QNC = OCN, therefore OC = Q^. In Np take NR = Nr, and make uRr = 32.l5 f , IRr = 43. 26', ratfr = 62.10'. In J// take MS = Nr 9 and make w ^jo = 43. 30', 2/ > = 62. 1 3'. Draw C T 7 perpendicular to p m. In 7> take TU = OC. In TC take TFrz: C7C, and make o Vp = 45.27'. Let wo meet jZ in x and pf in i. Let r# meet pm in s ; and let/o meet pr in . Then |?, r, m, &c. will be the projections of the poles of the faces p 9 r, m, &c. THE END. PLATE I J. Grizve, J. PLATE VI. 76. , , zincopf J. Grieve,, Zutcog. T 105. PLJLTEVBL. 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