LIBRARY OF THE UNIVERSITY OF CALIFORNIA. Class' THE OCCURRENCE OF ALUMINIUM IN VEGETABLE PRODUCTS, ANIMAL PRODUCTS, AND NATURAL WATERS. A CONTRIBUTION TO THE BIBLIOGRAPHY OF THE SUBJECT. BY C. F. LANGWORTHY, PH.D., ^ * AND PETER T. AUSTEN, PH.D. FIRS T ED I TION. NEW YORK: JOHN WILEY & SONS. LONDON : CHAPMAN & HALL, LIMITED. 1904. * Copyright, 1904, BY JOHN WILEY & SONS. ROBERT DKUMMOND, PRINTER, NEW YORK. INTRODUCTION. THE material included in this contribution to the bibliog- raphy of aluminium deals only with the occurrence of this element in vegetable products, animal products, natural waters, and a few miscellaneous materials, such as edible earths. The general purpose has been to include only reference to such articles as report separate determinations of aluminium or some of its salts, and to omit the very large number in which iron and aluminium are reported together. In a few cases analyses have been cited which report "traces" of aluminium, but the bulk of this material also has been omitted. In older investigations, particularly those dealing with the mineral constituents of plants, data regarding aluminium are more abundant than in later works, and doubtless some of the alu- minium reported came from impure reagents, from dirt con- taminating the sample, or some similar cause. Such a criticism would not be limited to the constituent under consideration, but applies more or less, in principle at least, to many of the determinations included in early analytical work. The greater part of the material included in the compilation does not seem open to that objection, for, as time has progressed, analytical methods and chemical manipulations have improved, and there is no reason why determinations of aluminium made within recent years should not be fairly good. No attempt has been made to comment on the value of individual analyses cited, as the object of this bibliography was the collection of data rather than the critical examination of them. In collecting the data, a systematic search has been made of the files of the Journal of the London Chemical Society, IV IN TROD UCTION. The American Journal of Pharmacy, The Analyst, Jahres- bericht der Thier-Chemie, Jahresbericht der Agricultur-Chemie, Just's Botanischer Jahresbericht, Chemical News, Zeitschrift fur Untersuchung der Nahrungs- und Genussmittel, Experi- ment Station Record, the later volumes of the Comptes Rendus, de 1' Academic des Sciences, Paris, Zeitschrift fur Physiologische Chemie, the bulletins and other publications of the United States Geological Survey, and the reports of the Geological Survey of Canada, as well as numerous scientific journals, bulletins and reports of the Agricultural Experiment Stations, reports of State Boards of Geology and of Agriculture, and miscellaneous volumes on chemistry, mineral .waters, foods, and other topics, including such works as Wolff's "Aschen- Analysen von Landwirtschaftlichen Producten, Fabrik-Aus- f alien, und Wildwachsenden Pflanzen," Konig's " Chemie der Menschlichen Nahrungs- und Genussmittel," etc. In a great many instances the data found in a periodical or work of reference have been verified in the original publication and so cited. All possible precautions have been taken to insure accuracy, but those who have engaged in similar work know how difficult it is to eliminate all error. TABLE OF CONTENTS. PAGE INTRODUCTION iii ALUMINIUM IN VEGETABLE PRODUCTS I ALUMINIUM IN ANIMAL PRODUCTS 49 ALUMINIUM IN NATURAL WATERS 51 ALUMINIUM IN MISCELLANEOUS MATERIALS 131 INDEX 133 OF THE ( UNIVERSITY OF JFORNl^.* ALUMINIUM IN VEGETABLE PRODUCTS. Aderholdt (Ann. Chem. u. Pharm., 82 (1852), p. in) reports 6.1 per cent ash in the dry matter of a club moss (Lycopodium chamaecyparissus) gathered in March, of which 51.85 per cent was said to be A1 2 3 , and 57.364 per cent A1 2 O 3 in the ash (4.5 per cent total) of a sample gathered in November. A club moss (L. dcwatum) was found to contain in dry matter 4.7 per cent ash, 26.65 P er ceirt being alumina. No alumina was found in other plants of the same region (near Bonn), such as oak, fir, and beech. Allen, A. H. (Analyst, 13 (1888), p. 41; Jour. Chem. Soc. London, 54 (1888), p. 631), concedes on the statements of analysts that aluminium is present in minute proportions as a normal constituent of wheat, the amount corresponding to about 8 grains of alum in a four-pound loaf of bread. A method for determining the alumina present is proposed. Andreasch, R. (Jour. Prakt. Chem., n. ser., 18 (1878), pp. 204-207), studied the ash of different parts of the garden pink and rose. The following is quoted: ALUMINIUM IN CERTAIN PLANTS. Total Ash. A1 2 3 . Garden pink (Dianthus caryophyllus) : Root Per Cent. 5.64 Per Cent. 2 . ;6 Stem q 26 trace Leaves 4 44 Flower c . en Garden rose (Rosa remontana) : Root 2 04. trace Stem . . . 2 ^I Leaves 0.47 Flowers 6.27 Apoiger (Vierteljahressch. Prakt. Chem., 6, p. 481; Jahresb. Chem.. 1857, p. 530) found 7.76 per cent ash in the seed of Maesapic'a dried at 100. This contained 0.98 per cent A1 2 O 3 . 2 ALUMINIUM IN VEGETABLE PRODUCTS. Athenstaed, W. (Ber. Deut. Bot. Gesell., 3 (1885), p. 57; Just's Bot. Jahresbericht, 1885, pt. i, p. 81), reports the ash analyses of a mixtiire of leaves, flowers, and fruit of Labrador tea (Ledum palustre) according to the method of Grandeau and Fresenius. The crude ash constituted 3.95 per cent of the total dry matter and of this 1.17 per cent was A1 2 O 3 . The pure ash constituted 2.77 per cent of the total dry matter and of this 1.67 per cent was A1 2 O 3 . Baer, W. (Arch. Pharm., 2d ser., 66, p. 285; Pharm. Centbl., 1851, p. 826; Jahresb. Chem., 1851, p. 710, Tab's C and C, p. 708), reports in rape-seed (dry material) 6.98, 5.97, 5.93, and 4.58 per cent ash respectively, containing 0.56, 1.02, 0.60, and 0.49 per cent alumina respectively. He also reports 4.47 and 4.41 per cent total ash in rape-straw (dry material) with respect- ively 0.63 and 0.22 per cent alumina. Bailey, E. H. S. (Trans. Kansas Acad. Sci., n (1887-8), p. 49), found that the ash of corn-cobs contained a " little over one per cent of ash," 2.02 per cent of this being A1 2 O 3 . Bastin, E. S., and H. Trimble (Amer. Jour. Pharm., 69 (1897), pp. 9097), in an article on North American Coniferae, report that the bark of hemlock (Tsuga canadensis) (air-dry) con- tains 1.42 per cent ash. Alumina was a consituent of this; the amount not reported. Baudrimont, E. (Jour. Pharm., 3d ser., 42, p. 388; Jahresb. Chem., 1862, p. 512), reports 23.28 per cent ash in eel-grass (Zostera marina}. Of this 0.26 per cent was A1 2 O 3 . Be*champ, A. (Compt. Rend. Acad. Sci. Paris, 73, p. 337; Jour. Chem. Soc. London, 24 (1871), p. 855), notes a trace of alumina in the ash of yeast* the total ash in the dry yeast being 9.730 per cent. Bell, J. Carter (Analyst. 4 (1879), pp. 126-133), reports that in four analyses of flour called No. 2 Crown and ground from a mixture of English and California wheat, he found 0.021 and 0.017, 0-020 and 0.024 per cent respectively of aluminium phosphate. Five pounds was made into bread, the crumb containing, according to analyses, o.on per cent aluminium phosphate. A Russian and a Ghirka flour, which the author states were "coarse grains flours such as a good baker would not like to use," contained respectively 0.58 and ALUMINIUM IN VEGETABLE PRODUCTS. 3 0.592 per cent ash, with 0.016 per cent aluminium phosphate in each case. Bread was made from 2.75 pounds of the Russian flour. The coarse brown loaf contained o.oio per cent of aluminium phosphate. Other samples of flour were examined as follows (the ash content and aluminium phos- phate content only being quoted) ALUMINIUM PHOSPHATE IN FLOUR. Kind of Flour. Ash. Aluminium Phosphate. i One Crown flour Per Cent. 0.628 .604 5 2 .448 .488 .484 438 .492 .380 .368 .476 .488 .610 .580 .700 59 2 .440 .400 .672 1-44 .680 .500 .516 .480 .368 Per Cent, o .018 .0204 .009 .007 .005 .004 .010 .013 .007 .OO2 .OIO .012 .Oil .Ol62 .0059 .0163 .OO62 .OOI .0023 .0058 ,00l8 .OOI .0008 .0078 .0049 .0015 .009 .0087 .016 .0106 .004 .004 .001 2 Two Crown flour 3 Three Crown flour . . . 4 Four Crown flour. 5 Five Crown flour 6 White English wheat, 1877 7 Red English wheat 1877 8 American spring wheat 9 American red winter wheat to Empress Hungarian ii. Residue flour, from 1,2,3 mixture of Crown.. 1 2 Bran flour 1 3 Ijxhaust flour 14 Russian flour i =5 Egyptian flour 1 8. Flour, English and foreign wheat, f English, \ foreign principally Californian .... 19 Straws made in Salford . 20. Coarse flour, or seconds, containing bran 21 White flour made in Salford 22. Peerless flour made by Banaman, Sherman & Co Rochester New York 23. Gilt Edge, made by Chase, Bristol and Bide, Rochester , . . . . 24 Californian flour 25. White English 1878 26 Purchased in Salford . . . 27 Purchased in Salford .... 28. Two Crown flour, total produce of wheat 40 per cent Red English, 30 per cent Californian White 30 per cent Canadian White . .260 .76 .26 .300 .448 .520 29. Bran flour from Two Crown Mixture. 30. Two Crown flour, less 5 per cent bran flour.. . 31 PA Campbell San Francisco 32 J F Salem Mills United States 33 Albany City Mills United States 4 ALUMINIUM IN VEGETABLE PRODUCTS. Thirty-two samples of bread purchased from bakers in Salford were analyzed, the crumb being used. The amount of moisture and aluminium phosphate follows : ALUMINIUM PHOSPHATE IN BREAD * Kind of Bread. Moisture. Aluminium Phosphate. Sample No i Per Cent. 46 10 Per Cent. Sample No 2 4 ^ OO Sample No 3 4 ^ ^O Sample No 4 . . 40 30 OO2 2 Sample No. 5 OO 3O Sample No 6 46 oo Sample No 7 44 ^O Sample No 8 , 4.6 OO Sample No 9 46 oo OO4O Sample No. 10 4 ^ ^O oo 3 1 Sample No. 1 1 46 50 oo c; 2 Sample No 1 2 46 oo Sample No 13 .... 46 oo Sample No 14. . 46 oo 0026 Sample No. 15. . 4.6 20 0028 Sample No. 16 OO4 ^ Sample No 17 46 ^o Sample No 18 4.Q ^O Sample No 19 4-7 ^O Sample No 20. . 46 ^o OO ^7 Sample No. 21. . 4.7 2O OO42 Sample No. 22 46 <0 OO68 Sample No 23 AC CQ Sample No 24 4.6 OO Sample No 25 4 ^ 3O Sample No. 26 46 2O OO4.A Sample No. 27 44 50 oo 38 Sample No 28 Sample No 29 A r eo Sample No 30 4.4 ^O Sample No 31 44 OO Sample No. 32 4.6 OO ^ The amount of aluminium phosphate found in some samples of bread which did not contain alum was as follows: 0.005, 0.004, -5> 0.003, o.oio, o.oio, 0.009, o-oio, 0.009, an d 0.008 per cent. *The inference is that these breads contained no added alum. ALUMINIUM IN VEGETABLE PRODUCTS. In the following table the amount of total moisture and aluminium phosphate in a number of samples of bread known to contain no added alum is quoted from more complete analyses reported by Bell. ALUMINIUM PHOSPHATE IN BREAD. Bread made from Ash Moisture. Aluminium Phosphate. One Crown flour Per Cent. 4C OO Per Cent. O .003 Two Crown flour 4C .OO .01 1 Three Crown flour . 40 . oo .ooq Four Crown flour 38 .00 .004 Five Crown flour 16 co OO22 White English wheat T.6 QO 004 Red English wheat ju . yw 7.Q SO .OOC T, Russian Flour 42 . 7O .OOC 3 50 per cent English Red, 50 per cent Canadian White . 42 . co .0082 Pure ^Vhite Canadian 42 CO oo3C Canadian Semolina AT. OO OOT.2 50 per cent English Red, 50 per cent Semolina. . . . California flour 43.00 47 . co .009 .0100 One Crown flour 46 . co .0031 Four Crown flour 4C .00 OOC3 The author states that in view of these results he thought it would be of interest to trace the aluminium from the wheat through the various milling products. He, therefore, had flour, bran, etc., especially prepared from wheat which he procured. From the analyses reported the ash content and aluminium phosphate are quoted as follows: ALUMINIUM PHOSPHATE IN WHEAT AND ITS MILLING PRODUCTS. Whe at and its Milling Products. Ash. Aluminium Phosphate. English wheat grown upon chalk soil Per Cent. I 72O Per Cent. O OI T. Bran ( 1 8 c per cent of the wheat) c 640 .016 Sharps (8 c per cent of the wheat) 2 OOO .017 One Crown flour (26 per cent of the wheat) Four Crown flour (45 per cent of the wheat) 5 .368 .007 .006 Bell, J. Carter (Analyst, 6 (1881), pp. 197-201), reports analyses of eleven grape-juices and of various samples of un- fermented and other wines. Among other constituents, the aluminium phosphate was determined. The amount of this ALUMINIUM IN VEGETABLE PRODUCTS. constituent and the total ash found in the different samples follows. ALUMINIUM IN GRAPE-JUICE, FERMENTED AND UNFER- MENTED WINES. Total Ash in 100 cc. Aluminium Phosphate. Pure Grape-juices. Black English hot-house grapes . . . Per Cent, o 3 ?6 Per Cent. o 084 White English hot-house grapes 331 O s I Almeira 1879 311 160 Almeira, 1880 .258 2CI French cluster, 1878. Chiefly used in the pro- duction of ordinary wine 273 C i 2 Portugese cluster, 1879. Purchased in England; juice expressed 2 C 2 4.33 Bordeaux, 1880. Mixture of Carfoenet Sauvignion, Malbec and Verdat 208 2 cro Oporto, 1880. "The Bastardo" from the Alta Douro 26l I O2O Pineau (Champagne grape). From the Cot d'or... Folly Blanc. (Cognac grape) .289 .266 .653 I .178 Blanquette 284 760 Grenach No. i . 2QI / 78o Grenach No. 2 . . ... 280 I 70^ Grenachft 30* 3 8qo Clairette .348 2 .<&2 Congress (from Vineland, N. J.) 3Q C > . 22O Madeira Videilho ovo 267 642 Madeira Tinta 318 .431 Fermented and Unfermented Wines. "Bell's unfermented juice of the vine," pure, uncolored fruit O 3 3 2 085 Unfermented sherry. . O 3O 2 2 16 Unfermented port O34. 3Q ^6 guaranteed fruit I OO ?i8 Selected unfermented wine for communion ser- vice 261 ;> A0 I 002 " Pure and unfermented fruit of the vine " . . . 34.2 I 244. Castle Tent, an unfermented sweet wine . . ^03 I 34.1 Castle Rota Tent. Similar to Castle Tent " Unfermented wine, free from alcohol, and unin- toxicating " 570 2QO I .360 AO2 Greek wine from island of Scio, "unfermented ". . White grape wine, fermented, from island of Scio . Deidesbeimer, pale alcoholic wine .368 .158 IS? .642. 377 071 Deidesheimer Aucolee, a pale alcoholic wine Italian juice, from Palmi, Calabria .194 347 .684 008 Bergstrand, C. F. ("Ofversicht K. Svenska Vetensk. Akad. Forhandl., 1875, PP- 2 7~37)> studied the effect of Swedish soils, ALUMINIUM IN VEGETABLE PRODUCTS. J containing alum, on vegetation. When the soil contained 0.5 per cent alum, the common cultivated plants would not grow. Mountain raspberry (Rubus articus), however, grew and pro- duced fine-tasting fruit. The entire plant when thus grown contained 4.68 per cent pure ash with 3.47 to 5.59 per cent A1 2 O 3 . Berthelot and G. Andr6 (Compt. Rend. Acad. Sci. Paris, 120 (1895), p. 288, and Ann. Chim. Phys., ;th ser., 5 (1895), p. 429) report, among other data regarding the existence of alumina in plants, the following determinations: Carefully washed alfalfa roots, 0.127 m - or -5 P er cent f P ure alumina, second sample 0.48 per cent; convolvulus roots, 0.0596 gm. or 0.4 per cent; Bermuda-grass roots, o.on gm. or 0.12 per cent; lupine leaves, 0.013 gm. or 0.037 per cent; and linden leaves, 0.0012 gm. or 0.0025 per cent. "These results indicate that alumina is present in con- siderable amounts in plants with extensive root systems, but that it remains largely in the roots and is found in only minute quantities in the leaves." Bevan, E. J., and C. F. Cross (Chem. News, 42 (1880), pp. 77, 91; Jahresb. Chem., 1880, p. 1064) report 0.6 to 2.0 per cent ash in jute fiber; of this, on an average, 5.51 per cent was A1 2 O 3 . Bitto, B. von (Landw. Vers. Stat., 42 (1893), 369; Jour. Chem. Soc. London, 64 (1893), II, p. 546), notes 6.71? per cent ash in the whole fruit of red peppers (Capsicum), and 5.66 per cent in the husk of the ripe fruit; these contained respectively a trace and 0.22 per cent A1 2 O 3 . Bitto, B. von (Landw. Vers. Stat., 46 (1895), p. 327), re- ports traces of A1 2 O 3 in the ash of red-pepper fruit, "paprika." Block, H. (Arch. Pharm., 226 (1888), p. 953), reports the ash content of the root, stem, and leaves of English ivy to be 6.34, 4.92, and 12.6 per cent, respectively, of the dry matter. Of this 0.371, 0.637, and 0.312 per cent, respectively, was made up of A1 2 O 3 . In this and a majority of similar analyses the other ash constituents are reported also. Blythe, A. W. (Foods: Composition and Analysis. London, 1888, p. 177), is of the opinion that properly cleaned wheat contains no alumina. He believes, however, that particles of clay and sand from millstones find their way into flour, "and 8 ALUMINIUM IN VEGETABLE PRODUCTS. there is no second-class flour in commerce which does not contain some small percentage of alumina." He is of the opinion that the aluminium is present as silicate. Bobierre (Barral. Jour. Agr., 1876, p. 175; Jahresb. Agr. Chem., 1875-76, p. 133) reports 0.35 per cent A1 2 O 3 in the material remaining after breaking hemp. Bondurant, C. S. (Amer. Jour. Pharm., 59(1887), pp. 122-124), finds that the hydrangea (Hydrangea arborescens) contains 3.41 per cent ash, one of the constituents being aluminium (amount not stated). Bondurant, C. S. (Amer. Jour. Pharm., 59 (1887), pp. 340-342), states that the leaves of coltsfoot (Tussilago farfara) contain 17.10 per cent ash, one of its constituents being aluminium (amount not stated). Brandes, R. (Arch. Pharm., 2d ser., 75 (1853), p. 269; Pharm. Centbl., 1853, p. 739; Jahresb. Chem., 1853, p. 581), notes in roots of Russian, Chinese, old Austrian, and new Austrian rhubarb (air-dry) 18.2, 8.82, 5.8, and 5.54 per cent ash, con- taining respectively 0.008, 0.015, 0.060, and 0.015 P er ceirt alumina. The Austrian roots were grown near Bilitz. Brandt (Wittstein's Vierteljahressch., 13, p. 322; Jahresber. Agr. Chem., 1865, p. 108) finds that the best Rheinpfalz to- bacco leaves contain 20.24 P er cent ash. Of this 0.216 per cent was found to be A1 2 O 3 . Bromeis (Ann. Landw., etc., 14, p. 2; Jour. Prakt. Chem. r 48, p. 447; Pharm. Centbl., 1849, pp. 753, 769; Jahresb. Chem., 1849, p. 667 and Tab. B, p. 656) notes 2.10 per cent ash in peas (dry matter) from Frankenfelde. Of this 0.17 per cent was alumina. Brown, L. P. (Amer. Chem. Jour., n (1889), p. 37; Jour. Chem. Soc. London, 56 (1889), p. 543), notes in the ash of tobacco screenings, composed of the small fragments of stems and leaves which, with the dust, are sifted from tobacco during manufacture 43.40 per cent total mineral matter. This con- tained 0.47 per cent A1 2 O 3 . Browne, C. A., Jr. (Pennsylvania Dept. Agr. Bui., 58; Jour. Amer. Chem. Soc., 23 (1901), p. 869), reports 0.30 per cent ash in the flesh of ripe apple. This contained 0.80 per cent alumina. ALUMINIUM IN VEGETABLE PRODUCTS, 9 Bunge, G. von (Ztschr. Biol., 41 (1901), p. 155), gives a detailed analysis of honey. It contains (when fresh) 0.0046 per cent A1 2 O 3 . Clarkson, P. S. (Amer. Jour. Pharm., 59 (1887), pp. 277-278), reports upon an analysis of cocoa shells. The total ash amounted to 9.07 per cent. The author states that in addi- tion to the usual constituents, it contained aluminium. He says: "This element has not been reported in some analyses of the ash, but was found by Wanklyn in the ash of cacao." Clinch, J. H. M. (Amer. Jour. Pharm., 56 (1884), p. 131), reports an analysis of the leaves of New Jersey tea (Ceanothus americanus). The dry leaves contained 10.9 per cent moisture and 5.31 per cent ash. This was made up, according to the author, of chlorides, sulphates, phosphates, and carbonates of potassium, calcium, magnesium, aluminium, etc. with silicates. Colby, G. E. (California Station Rpt., 1898-1901, pt. II, p. 25 2), reports analyses of hops grown in California. Ukiah hops contained 5.80 per cent ash and Wheatland hops 8.65 per cent. The ash contained respectively 2.15 and 2.16 per cent Al. 2 O 3 .Fe 2 O 3 . The Wheatland hop soil (fine earth) con- tained from 6.24 to 15.42 per cent Fe 2 O 3 and from 2.57 to 9.79 per cent A1 2 O 3 according to analyses made by F. J. Snow. Coppola, M. (Gaz. Chim. Ital., 10, p. 9; Jour. Chem. Soc. London, 37 (1880), p. 382), found 11.16 per cent ash in Stereo- caulon vesuvianum. Of this 11.13 per cent was A1 2 O 3 . Chassevent, A., and C. Richet (Compt. Rend. Acad. Sci. Paris, 117 (1893), p. 673; Jour. Chem. Soc. London, 66 (1894), II, p. 63), in a paper on the influences of metallic salts on lactic fermentation, found that the order of toxicity of the metals studied was as follows: Mg, Li, Ca, Sr, Ba, Al, Mn, Fe, Pb, Zn, Cu, Cd, Pt, Hg, Ni, Au, and Co. Chatin, A. (Compt. Rend. Acad. Sci. Paris, no (1890), p. 376, Jour. Chem. Soc. London, 58 (1890), p. 659), states that truffles, contain from 20.84 to 24.26 per cent dry matter with 5.62 to 9.88 ash. This contained traces of aluminium. Church, A. H. (Chem. News, 30 (1874), p. 137, in a paper on the occurrence of aluminium in certain cryptogams), reports IO ALUMINIUM IN VEGETABLE PRODUCTS. investigations on the aluminium content of a number of varie- ties. A summary follows. ALUMINIUM IN CRYPTOGAMS. Kind of Cryptogam! Ash in Dry Plant. A1 2 O 3 in Ash. Club moss (Lycopodium alpinum Per Cent. ^ 68 Per Cent. 5-5 r o Club moss (L clavatum) 2 80 I c 24 Club moss (L selago) 320 7 20 Selaginella martensii . . ii 66 o 26 5 spinulosa . . 344- none Horsetail (Equisetum maximum) 2O O2 none Adder's tongue (Ophiglossum vulgatum) 8 2< none Psilotum tTiquctTum f 06 trace ^ Church, A. H. (Jour. Botany, n. ser., 4 (1875), P- reports that the ash of a club moss (Lycopodium billardieri) (5.46 per cent of the dry matter) contained no alumina. This he considered the first instance in which alumina has not been found in lycopodium ash. Church, A. H. (Proc. Royal Soc. London, 44 (1888), p. 121), in an article on the occurrence of aluminium in certain vascular cryptogams discusses at length the occurrence of aluminium in plants and reports a number of analyses. The results follow. ALUMINIUM IN CRYPTOGAMS. Kind of Plant. Ash in Dry Plant. A1 2 O 3 in Ash. Club moss (Lycopodium cernuum) Per Cent. Per Cent. 1 6 OQ Club moss (Lycopodium phlegm-arid) A 08 O A P- 3 8 3J Jahresb. Chem., 1850, p. 647, 666, 671, Tab. A, B and D, p. 661), notes the occurrence of a trace of alumina in the ash of wheat, the total ash in dry material being 2.30 per cent, and 0.07 per cent alumina in the ash of oats, the total ash in the dry material being 3.06 per cent. He also reports a trace of alumina in the ash of horse bean (Vicia faba) seed, total ash, 4.3 per cent of dry material and traces in ash of eddoes or taro (Arum (Colocasia) esculentum) and yams (sweet potato) (Convolvulus batatas) containing respectively 1.647 P er cent asn and 1.51 per cent ash in the fresh materials. Hermann, J. C. (Viertel. Prakt. Pharm., 18, p. 481; Jahresb. Chem. Will., 1869, p. 796), notes 0.5851 per cent alumina in the ash of ergot (Secale cornutum) ; the amount of total ash is not stated. Herrmann, J. C. (Viertel. Prakt. Pharm., 1869, p. 481 ; Amer. Jour. Pharm., 42 (1870), p. 143), reports 2.201 per cent ash in ergot. Aluminium phosphate is noted as a constituent of the. ash. Hertwig (Chevallier et Baudrimont's Dictionnaire des altera- tions, Paris, 1878, p. 1132) notes the occurrence of 9.04 per cent calcium, magnesium, iron, manganese phosphates and aluminium phosphates in Havana tobacco and 17.95 P er cent of calcium, magnesium, iron, manganese, and aluminium phos- phates in the ash of Hanover tobacco. ALUMINIUM IN VEGETABLE PRODUCTS. 19 Herzberg, W. (Dingler's Polytech. Jour., 277, p. 478 (Ausz); Jour. Soc. Chem. Ind., 9, p. 758 (Ausz); Chem. Centbl., 1890, II, p. 186; Jahresb. Chem., 1890, p. 2877), reports 17.47 per cent ash in the fibers of the baobab tree (Andansonia digitata) used for paper making. Of this 0.14 per cent was alumina. Hoeven, J. (Amer. Jour. Pharm., 55 (1888), p. 253), in a study of cheken leaves, reports 9.48 per cent ash. The portion insoluble in H 2 O, but soluble in HC1, amounted to 5.61 per cent. This contained aluminium ; amount not stated. Hohn, H. (Arch. Pharm., 2d ser., 139 (1869), p. 213; Jahresb. Chem. Will., 1869, p. 771), reports 3.24 per cent ash in the stem and 6.61 in the leaf of Ophelia chirata; of this 1.47 and 4.35 per cent was A1 2 O 3 . Hollandt, H. (Vierteljahressch. Prakt. Pharm., 10, p. 321! Jahresber. Agr. Chem., 1861-62, p. 60), reports 1.2035 percent A1 2 O 3 in the ash of the bark of Millingtonia hortensis. Hooper, D. (Pharm. Jour, and Trans., 1887, Jan. 8; Amer. Jour. Pharm., 59 (1887), p. 86), reports a study of the ash of cinchona bark. As shown by the average of three hundred determinations, such bark (from India), contained 3.42 per cent ash. The ash of C. officinalia and C. succirubra grown on the Nilgiris contained respectively 2.70 and 4.24 per cent A1 2 O 3 . Huber, L. (Arch. Pharm., 3d ser. 7 (1875), p. 394; Jahresb. Agr. Chem., 1875-76, p. 136), reports 0.250 per cent A1 2 O 3 in the ash of the rind of the root of elder (Sambucus nigra), the ash being equal to 11.717 per cent. Irby, J. R. McD., and J. A. Cabell (Chemical News, 1874, p. 117, Centbl. Agr. Chem., 6 (1874), p. 366) note the presence of some A1 2 O 3 with the Fe 2 O 3 in six sorts of Virginia tobacco. Jackson, D. D. (Jour. Soc. Chem. Ind., 21 (1902), p. 681), reports the results of a study of the precipitation of iron, man- ganese and aluminium from natural waters by the action of bacteria, viz., Crenothrix kuhniana, C. manganifera, and C. ochracea, respectively. Dr. Jackson states that each of the three species seems to exercise a selective power in precipitat- ing the special oxid ascribed to it, and that about one-third of the dry organism is composed of the oxid selected, whether iron, manganese, or aluminium. He reports analyses of the precipitate due to the three species in three different waters: 20 ALUMINIUM IN VEGETABLE PRODUCTS. PRECIPITATE CAUSED BY CRENOTHRIX SP. FROM DIFFERENT WATERS. Fe 2 O 3 . Mn 2 O 3 . A1 2 3 . Si0 2 . Alumin- ium Sili- cate. Unde- termin- able Mineral Matter. Organic Matter. Crenothrix kiihniana from filter gallery, Ipswich River, Mass Per Ct. *i 6 Per Ct. Per Ct. c . 7 Per Ct. II . I Per Ct. 10 .4 Per Ct. 4 . 2 Per Ct. ?7 O Crenothrix mangani- fera, filter gallery, Charles River, Newton, Mass Crenothrix ochracea, driven wells at Oconee, Brooklyn, New York 14.4 14. 7 33-9 i-5 2-2 . -2 12.5 C . Q 8.0 7.6 1.8 2 . T, 27.9 36 2 The waters in which the crenothrix species grew were an- alyzed. They contained alumina (parts per million) as follows : Water from filter gallery, shore Ipswich River, Reading, Massa- chusetts, 0.6; water from filter gallery, shore Charles River, Newton, Massachusetts, 0.5, and water from driven wells, Oconee, Brooklyn, N. Y., 2.0. Jessler, A. (Vierteljahressch. Prakt. Pharm., 17, p. 266, Jahresber. Chem. Will., 1868, p. 807), reports 13.18 per cent ash in the rhizome of dog-bane (Cynanchum monspeliacum). This is reported to contain alumina; the amount is not stated. Hassall, J. (Food Adulteration, p. 617), reports 4.80 per cent ash in anatto. This contained 0.20 per cent alumina (with a trace of iron). Kane (Phil. Mag., 3d ser., 31, pp. 36, 105 ; Jour. Prakt. Chim., 41, p. 434; 32, p. 354; Jahresb. Chem., 1847-48, p. 1085) reports total ash as follows in flax stems (treated in different ways) from Ireland, Holland, Belgium, etc., 4.237, 5.434, 3.670, 5.151, and 5.000 per cent. Of this 0.44, 0.44, 0.72, 1.44, and 6.08 per cent respectively was alumina. Karmrodt, C. (Ztschr. Landw. Ver. Rheinpreussen, 1864, p. 427; Jahresb. Agr. Chem., 1864, p. 98), determined the constituents of the ash of a number of Coniferae. Larch needles (Pinus larix) contained 0.264 per cent; Scotch pine needles ALUMINIUM IN VEGETABLE PRODUCTS. 21 (P. sylvestris) 0.125 P er cent, and fir needles (Abies excclsa] 1.427 per cent A1 2 O 3 . Kayser, R. (Repert. Analyt. Chem., 1883, p. 289; Jahresb. Agr. Chem., 1883, p. 349), in an article on fruit and fruit juices, reports traces of A1 2 O 3 in the juice of red and white currants (containing respectively 0.38 and 0.5 per cent ash) and of strawberries. Kayser, R. (Repert. Analyt. Chem., 1883, p. 182; Jahresb. Chem., 1883, p. 1407), analyzed dry blueberries, reporting in them 0.005 per cent alumina. Kayser (Repert. Analyt. Chem., 1882, p. 242) finds that the presence of 0.3-0.4 grain of alumina per liter in wine cannot :safely be taken as a proof that alum has been added because it takes into solution during its course of manufacture some alumina. This is especially the case when the wine has been cleared with kaolin (silicate of alumina), as some wines dissolve small amounts of the kaolin, and hence contain alumina in the form of a soluble salt. Kebler, L. F. (Amer. Jour. Pharm., 67 (1895), p. 3 9 8), in a study of the determination of morphine in opium, reports that the ash of crude morphine (percentage amount not given) 'Contained 0.43 per cent aluminium phosphate. Keim, W. (Ztschr. Analyt. Chem., 30 (1891), p. 401), reports the following amounts of pure ash in cherry (Prunus cerasus) fruit at different times: May 21, 0.516 per cent; May 28, 0.646 per cent; June 19 (ripe), 0.739 per cent. Of these, 2.55, 0.80, and 0.81 per cent respectively was A1 2 O 3 . Khittel (Vierteljahressch. Prakt. Pharm., 7, p. 348, Jahresb. Chem., 1858, p. 530) found 7.91 per cent ash in leaves of poison- ivy (Rhus toxicodcndron) (dried at 100). Of this 0.49 per cent was A1 2 O 3 . Knop (Kreislauf des Stories, 1868, p. 263) states that the roots of the Lycopodiae secrete besides carbonic acid strong organic acids, which dissolve the alumina of soils, and this solution enters the root. The lichens also contain in their structures peculiar crystallizable acids which, by the action of reagents, break up into oxalic acid and a new organic acid. The oxalic acid thus formed dissolves the alumina and iron oxid, 22 ALUMINIUM IN VEGETABLE PRODUCTS. and thus the mosses corrode the surfaces on which they grow r the hard rock as well as the dust that clings to it. In this way the dissolved alumina passes into the interior of the moss. It would seem a principle that plants secreting strong organic acids, whicji act on surrounding material, will contain alumina and show it in their ash. Knop, W. (Landw. Vers. Stat., 7 (1865), pp. 436-450), reports 31.01 per cent ash (including 15.00 per cent sand) in Chlorangium jussuffii; this included 1.90 per cent A1 2 O 3 . Other ash analyses of lichens which he reports are quoted in part as follows: ALUMINA IN CERTAIN LICHENS. Kind of Lichen. Pure Ash in Dry Matter. A1 2 3 . Gyrophora pustulata Per Cent. I 666 Per Cent. O 34.4, Ramalina jraxinea from quartz porphyry 2 34.6 O O 1 1 Kresling, K. (Arch. Pharm., 3d ser., 229 (1891), p. 389; Jour. Chem. Soc. London, 62 (1892), II, p. 232), in the pollen of Scotch pine (Pinus sylvestris), reports 5.51 per cent crude ash, equivalent to 3.0 pure ash. This contained 1.86 per cent A1 2 3 . Krutzsch, H. (Tharander forstl. Jahrb., 6 (1850), p. 88), as cited by Wolf! (Aschen Analysen, Berlin, 1880, pt. 2, pp. 87, 130), determined the ash constituents of freshly fallen fir needles, and of dry twigs, dry bark, dry cones, and moss, found in the litter. The pure ash in the several materials was equal to 1.601, 1.043, I - 2 75 -477> an d 2.884 per cent respectively. Of the pure ash 4.20, 8.33, 7.86, 9.20, and 20.5 per cent respec- tively was A1 2 O 3 . The A1 2 O 3 is regarded as due to earth present in the material. Wolff states that on an average (based on fourteen analyses) fir-needle litter contains 1.410 per cent pure ash; from o to 9.98 per cent or on an average 3.58 per cent of this being A1 2 O 3 . In this and all the other analyses cited from Wolff the complete ash analyses are given. / or THE \ I UNIVERSITY ) V OF /' \8ftUE2?^' ALUMINIUM IN VEGETABLE PRODUCTS. 2$ Longer, A. (Ueber Bestandtheile der Lycopodiumsporen. Inaug. Diss. Erlangen, 1889; Just's Bot. Jahresb., 1889, I, p. 39), reports an analysis of the spores of a club moss (Lycopodium clavatum). These contained on an average 1.155 per cent of mineral matter with 24.41 per cent of A1 2 (P0 4 ) 2 . Longer, A. (Arch. Pharm., 3d ser., 27 (1889), p. 289; Jah- resb. Agr. Chem., 1889, p. 383), reports 1.15 per cent ash in commercial lycopodium powder (L. clavatum) which was 96.67 per cent pure. Of this 15.30 per cent was A1 2 O 3 . La Wall, C. H. (Amer. Jour. Pharm., 69 (1897), p. 137), in a study of the ash of various drugs, reports aluminium as a constituent of aconitum root, belladonna leaves, calumba roots, castanea leaves, chimaphila leaves, cinchona, calisaya bark, digitalis leaves, frangula bark, gelsemium root, geranium rhizome, glycyrrhiza root, guarana seed (crushed), hops, hy- drangea root, hydrastis rhizome, hyoscyamus leaves, jalap tuberous root, kola-nut, Piscidia erythrina bark, choke-cherry (Prunus virginiana) bark, cascara (Rhamnus purshiana) bark, ruta herba, sabadilla seed, bloodroot (Sanguinaria) rhizome, dandelion (Taraxicum) root, red clover (Trifolium pratense) flowering tops, elm (Ulmus) bark, hellebore (Veratrum viride) rhizome rootlets, and prickly ash (Xanthoxylum) bark. The amount of this and other constituents was not determined. The total ash was generally determined. Lermer, J. (Dingler's Polytech. Jour., 179, p. 71; Bui. Soc. Chim., 2d ser., 6, p. 429; Jahresb. Chem. Will., 1866, p. 882), reports 6.91 per cent ash in Hungarian malt (barley) sprouts and 6.19 per cent in German. The ash contained respectively i. 06 and 0.45 A1 2 O 3 . Lermer (Wittstein Viertel. Jahressch., 13, p. 182; Jahresb. Agr. Chem., 1865, p. 117) reports 7.135 per cent ash in air-dry hops; 0.763 per cent of this was found to be A1 2 O 3 . Lewitsky, J. (Arbeiten der dritten Versammlung russischer Naturforscher zu Kiew. Vereinigte Sectionen der Botanik und Chemie; Just's Bot. Jahresber., 2 (1874), II, p. 866), reported a series of studies of the relation of the phosphates of iron, calcium, and aluminium to plant growth. Investigations have shown that the addition of calcium phosphate to the soil results 24 ALUMINIUM IN VEGETABLE PRODUCTS. in the formation of ferric phosphate and aluminium phosphate, so that after a time, even under the most favorable conditions, practically only a trace of calcium phosphate remains. On the basis of this conclusion, the author believes that under normal conditions the roots of plants have access only to iron phosphate and aluminium phospha'te and must derive their phosphates from these salts. To test the theory, culture experiments were made with barley by Hellriegel's method (Ann. Landw., 38, p. 296). Briefly stated, the grain was sown in quartz sand to which nutrient solutions were added. These were made up of KN0 3 (or under certain conditions, Ca(N0 3 ) 2 ), CaCO 3 , NaCl, MgSO 4 , and Fe 2 O 3 , in what were deemed the proper proportions. With such a basal mixture, Fe 2 (PO 4 ) 2 , Ca 3 (PO 4 ) 2 , and PO 4 KH 2 were added in the first test of the experiments, while in a control experiment, which is described in less detail, A1 2 (PO 4 ) 2 was also used. The plants were watered with water containing CO 2 . Their growth and seed production is described in detail. In the principal test, the best growth was made by the barley grown with a nutrient mixture containing Fe 2 (PO 4 ) 2 . The next best results were obtained with KH 2 PO 4 ; the least satisfactory, with Ca 3 (PO 4 ) 2 . The remaining test was not regarded as entirely satisfactory and gave results somewhat at variance with those already obtained; but in general it showed, according to the auth6r, that A1 2 (PO 4 ) 2 had practically the same effect as a corresponding iron salt and that the corresponding calcium salt was not as satisfactory for the plants as the iron salt. L'Hote (Compt. Rend. Acad. Sci. Paris, 104 (1887), p. 853), reported an investigation dealing with the detection and esti- mation of alumina in wine and grapes. Wines from seven localities were found to contain alumina per liter as follows: From Bourgogne, 0.02 gm. ; Cher, 0.036 gm. ; Touraine, o.ooo gm. ; Roussillon, 0.032 gm.; Spain, 0.016 gm. ; Sicily, 0.012 gm.; and from Aude, 0.016 gm. When prepared in the laboratory, wine from grapes from Huesca contained per liter 0.012 gm. From 479 gms. of red grapes 0.013 gm. alumina was obtained, while the stalks weighed 6.482 gms. and contained 0.003 gm. alumina. ALUMINIUM IN VEGETABLE PRODUCTS. 2$ Light, W. W. (Amer. Jour. Pharm., 56 (1884), p. 3), reports the analysis of the fruit of prickly pear (Opuntia vulgaris). The ripe fruit contained 68.2 per cent moisture and 1.76 per cent ash, and contained phosphate of aluminium. Lindenmeyer, G. (Vierteljahressch. Prak. Pharm., 17, p. 290; Jahrb. Chem. Will., 1868, p. 814), reports 3.5878 per cent ash in China bark (Cinchona) from Puerto Cabello, containing 0.488 per cent alumina. Huschke, O. (Vierteljahressch. Prak, Pharm., 17, p. 284; Jahresb. Chem. Will., 1868, p. 814), reports 1.21 per cent ash in orange peel. This contained 0.069 P er cent alumina. Loew, 0. (The Physiological Role of Mineral Nutrients: U. S. Dept. Agr., Division of Vegetable Physiology and Path- ology Bui. 1 8 (1899), p. 9). The possibility of the occurrence of aluminium salts in plants is frequently spoken of by botanical writers. Thus the author cited says regarding mineral compounds found in living organisms :" Occasionally there are present in plants small quantities of titanic and boracic acids, lithia, and alumina, and of the oxids of lead, zinc, and copper. " Luca, S. de (Compt. Rend. Acad. Sci. Paris, 51 (1860), p. 176), reported 6 per cent ash in Spanish moss (Tillandsia dian- thoidea), an aerial parasite. This contained a trace of A1 2 O 3 . Ludwig, H. (Arch. Pharm., 2d ser., 52 (1847), p. 61; Pharm. Centbl., 1848, p. 669; Jahresb. Chem., 1847-48, p. 1095), found 2.36 per cent ash in so-called "Caraccas" Sarsaparilla root, purchased in Honduras. Of this 5.11 per cent was alumina. Ludwig, H. (Arch. Pharm., 3d ser., i (1872), p. 482; Jour. Chem. Soc. London, 26 (1873), p. 525), notes A1 2 O 3 in the ash of different parts of the coffee tree as follows: Root of young tree in bearing, 7.85; root of old tree, 1.59; leaves, 9.11; pulp of pericup, trace; parchment-like coating of coffee bean, 4.19; coffee beans grown in gneiss soil, 2.78 per cent, and coffee beans grown on limestone soil, a trace. MacDonald, J. W. (Chem. News, 37, p. 127,; Jour. Chem. Soc. London, 1878, II, p. 624), examined the ash of cane and beet sugar accumulated from the analyses made in a year in a large sugar refinery, reporting among other constituents, 6.90 per cent ferric oxid and alumina in cane-sugar ash and 0.28 per cent in beet-sugar ash. 26 ALUMINIUM IN VEGETABLE PRODUCTS. Maiden, J. H., and H. G. Smith (Jour, and Proc. Roy. Soc. New South Wales, 29 (1895), p. 325) report, in a silky oak log (Grevillea robusta), a large amount of a white substance having the appearance of whiting. Some six ounces were secured, but it is stated that a large proportion of the substance must have been lost and that there is no means of knowing the total quantity originally present in the cavity in the log. Analysis showed this material to consist of basic aluminium succinate. The authors regard it probable that the aluminium was originally present in the sap of the tree as a malate. No inorganic acid was detected in the sample analyzed. Malaguti, F. J., and J. Durocher (Ann. Chim. et Phys., 3d ser., 54 (1858), p. 257, tables i to 4) report detailed studies of the ash of one hundred and fifteen wild plants of different families growing on a variety of soils in France. The oxids of iron, aluminium, and manganese are reported together. This work is of especial interest historically. Mariani, G. (Studi chimico-agrari sugli equiseti, Studi e ricerche istituite nel R. Laboratorio di Chim. Agrar. di Pisa, 7 (1888), p. 69; Staz. Sper. Agrar. Ital., 14 (1888), p. 355; Just's Bot. Jahresber., 1888, pt. i, p. 58), reports an analysis of a horse tail (Equisetum telmateja) grown in Pisa. This had a water con- tent of 78.033 per cent. The CO 2 free ash (amount not given) contained 0.963 per cent A1 2 O 3 . Matusow, H. (Amer. Jour. Pharm., 69 (1897), p. 341), reports aluminium as one of the constituents of the ash of broad-leaved laurel (Kalmia latifolia) root; amount not stated. The total ash was 1.24 per cent. Mayer, A., (Lehrbuch der Agricultur Chemie 3d Ed., 1886, p. 280) states that aluminium is found in a seriesof plants as a regular constituent, and frequently in not subordinate amounts. In Lycopodiuin complanatum acetate of aluminium occurs in such quantities that a lye made from the plant can be used directly in dyeing as a mordant. This same salt has been found in wine grapes; and it is an assured fact that various parts of the grapevine on incineration leave in the residuum aluminium compounds. Vauquelin states that he found acetate of aluminium in the sap of the birch, which at best must be considered as an anomaly. ALUMINIUM IN VEGETABLE PRODUCTS. 2/ Minas, M. (Zur Frage uber den Einfluss pasteurisierten Traubensaftes auf den allgemeinen Stickstoffumsatz, das Kor- pergewicht und die Darmfaulniss beim gesunden Menschen bei gemischter Kost. Inaug. Diss. Dorpat, 1900; Ztschr. Untersuch. Nahr. u. Genussmtl., 4 (1901), p. 204), analyzed a pasteurized grape juice (prepared by a Russian firm for medic- inal use) and found that it contained 0.004 per cent of A1 9 O 3 . Mitscherlich (Berlin. Acad. Ber., 1847, Nov., p. 430; Jour. Prak. Chem., 43, p. 158; Pharm. Centbl., 1848, p. 337; Inst., 1848, p. 186; Jahresb. Chem., 1847-48, p. 832) found in one of the marine Algae (Conferva glomerata) (dried at 130), 12.27 per cent ash; of this 0.42 per cent was alumina. Moritz, J. (Ann. Oenologie. 4, p. 153; Just's Bot. Jahresber., 1874, II, p. 855), studied the draft on soil made by grapes of the variety "Sylvaner. " The fresh wood contained 50 per cent more ash than the fresh fruit. He calculated that the grape plants withdrew 35.343 pounds mineral matter per morgen (0.63 acre) from the soil; of this 0.05 pound was A1 2 O 3 . Muck (Vierteljahressch. Prak. Pharm., 5, p. 544; Chem Centbl., 1856, p. 848; Jahresb. Chem., 1856, p. 690) notes 12.5 per cent ash in the leaves of belladonna (Atropa belladonna) (dried at 100) containing o.oi per cent A1 2 O 3 . Munroe, W. R. (Amer. Jour. Pharm., 70 (1898), p. 489), in an analysis of the rhizome of an aralia (Aralia calif or nica) , reports 2.22 per cent ash in which aluminium was present in the form of phosphate. Nettlefold, P. (Chem. News, 55, p. 191; Jahresb. Chem., 1887, p. 2304), reports 0.571 per cent ash in an edible fungus (Bovista gigantaea). Of this 15.66 per cent was alumina. Parodi, D. (Pharm. Jour. Trans., 3d ser., 10, p. 667; Jour. Chem. Soc. London, 37 (1880), p. 721), in a cucurbitaceous plant, tayuya (Trianosperma ficifolia), found 1.23 per cent iron and aluminium. Payen (Compt. Rend. Acad. Sci. Paris, 28, p. 613; Pharm. Centbl., 1849, p. 516; Jahresb. Chem., 1849, P- 4^i) notes 0.12 per cent insoluble, and 0.16 per cent soluble ash in sugar cane. One of the ash constituents was alumina. Peckolt, T. (Pharm. Jour. Trans., 3d ser., 10, pp. 343, 383; Ztschr. Oesterr. Apoth. Verein, 1879, pp. 361, 373; Jahresb. 28 ALUMINIUM IN VEGETABLE PRODUCTS. Chem., 1879, p. 931), in a study of the fruit of paw-paw (Carica papaya), states that the dry flesh of the fruit of one variety, Mamao femea, contained 8.457 per cent ash. Of this 3.857 per cent was alumina. Peckolt, T. (Wiener. Akad. Ber. 54 (2. Abt.) p. 462; Jahresb. Chem. Will., 1866, p. 708), reports 10.19 P er ceirt asn m shells of seeds of Guarana (Paulina sorbilis); 1.704 per cent in seeds without shells and 2.6 per cent in Guarana paste; the last two contained respectively 1.06 and 0.82 per cent A1 2 O 3 . Penney, M. D. (Chem. News, 39, p. 80; Jour. Chem. Soc. London, 36 (1879), II, p. 556), studied the occurrence of alumina in flour and wheat, finding, he states, larger quantities than are generally supposed to be present. Part of this he attributes to careless packing of the wheat. The Egyptian wheat noted below was largely contaminated with clay owing to the manner of packing in Nile boats. In six samples of flour, he found alumina as follows, the amount representing grains in four pounds: No. i, 24.30; No. 2, 21.75; No. 3, 21.25; No. 4, 17.00; No. 5, 12.40, and No. 6, 6.34. The aluminium phosphate (milligrams per 100 grams) found in twenty-two samples of wheat was as follows: No. i, Cal- cutta, 24.30; No. 2, Calcutta, 21.00; No. 3, Calcutta, 18.50; No. 4, Kourish, 27.20; No. 5, Kourish, 31.00; No. 6, Russian, 17.20; No. 7, Russian, 24.45; No. 8, Russian, 13.10; No. 9, Russian, 16.35; No. 10, Chicago, 4.00; No. n, Oregon, 4.00; No. 12, English, 5.12; No. 13, English, 6.40; No. 14, English, 7.30; No. 15, English, 3.80; No. 16, Stein, 16.33; No. 17, Stein, 13.24; No. 18, California, 3.00; No. 19, Mixed (eleven varieties), 15.10; No. 20, Egyptian, as imported, 167.00; No. 21, Egyptian, hand-picked, 49.49; No. 22, Egyptian, washed, 14.10. Percival, J. (Agricultural Botany, New York, 1900, p. 167), notes the occasional presence of alumina in small amounts in certain plants. In sea-weeds bromine and iodine, he states, are present, and many other elements such as aluminium, zinc, and copper have been occasionally discovered in small quantities in certain species of plants. Petter, K. (Vierteljahressch. Prak. Pharm., n, p. 545; Jahresb. Chem., 1862, p. 511), found 23.15 per cent ash in one ALUMINIUM TN VEGETABLE PRODUCTS. 29 of the common Algae (Cladophora glomerata) (dried at 110). Of this 0.225 per cent was A1 2 O 3 . Pfeffer, W. (Pflanzen-Physiologie, 2d ed., 1897, Vol. I, p. 43 2), in discussing the nutrients of plants, makes in effect the following statement: Aluminium, although it is so generally distributed, occurs in the ash of most plants only in small amounts. In the case of Lyco podium chamaecyparissus and alpinum, it constitutes 22 to 27 per cent of the ash. It is also abundantly present in Chlorangium jussuffii according to Wolff (Aschen Analysen, 1871, pp. 134, 136), while Church found only traces of it in Lyco podium phlegmaria, in Sclaginella, etc. Whether or not aluminium occurs in Lycopodium, as Arosenius states in the form of tartrate, is not definitely known. Pizzi, A. (Staz. Sper. Agr. Ital., 16 (1888), p. 737; 17 V i889 , p. i; Centbl. Agr. Chem., 19 (1890), p. 353; Jahresb. Agr. Chem., 1890, pp. 287, 288), reports 1.80 per cent ash in white truffle (Tuber magnatum) from the Apennines, of which 6.9 per cent was A1 2 O 3 . In black truffle (T. melanosporum), from the same region, he found 2.09 per cent ash of which 5.3 per cent was ALjOg. Pizzi, A. (Staz. Sper. Agr. Ital., 17, p. 167; Jahresb. Chem., 1889, p. 2109), reports 1.342 per cent ash in the morel (Morchella esculenta). Of this 3.120 per cent was A1 2 O 3 . Ramdohr (Arch. Pharm., 2d ser., 91 (1857), p. 129; Ztschr. Pharm., 1857, p. 70; Chem. Centbl., 1857, p. 705; Jahresb. Chem., 1857, p. 515) notes 3.62 per cent ash in air-dry ergot (Secale cornutum) from cheat or chess (Bromus secalinus) and 2.91 per cent in ergot from rye (Secale cereale). These con- tained respectively 1.09 and 0.33 per cent A1 2 O 3 . Reichardt, E. (Arch. Pharm., 2d ser., 73 (1853), p. 257; Pharm. Centbl., 1853, p. 267; Jahresb. Chem., 1853, p. 581), examined the leaves, bark, and wood of willow (Salix vitellina) in autumn and spring, reporting (per 1000 parts fresh material) 0.05 A1 2 O 3 in autumn leaves, and 0.03 in autumn bark and wood, 0.03 in spring leaves, and 0.06 in spring bark and wood. He found also (Arch. Pharm., 2d ser., 75 (1853), p. 19; Pharm. Centbl., 1853, p. 566; Jahresb. Chem., 1853, p. 584) 0.39 and 0.46 A1 2 O 3 .PO 5 per 1000 parts dry matter in thick 3O ALUMINIUM IN VEGETABLE PRODUCTS. (old) and thin (young) bark, from a willow, about five years old, gathered near the end of October, 1852. Reichardt, E. (Chem. Bestandtheile der Chinarinden, Braun- schweig, 1855; Pharm. Centbl., 1855, p. 631; Ztschr. Pharm., 1856, p. 25; Jahresb. Chem., 1855, p. 720), reports ash in the following drugs: China flava fibrosa (this and all the others dried at 100) 1.6338 per cent; C. rubra, 1.6607 P er cent; C. huanuco, 2.5134 per cent; C. regia sine epid., 1.2236 per cent; C. regia cum epid., 1.6449 per cent. He reports alu- minium phosphate in these as follows: 0.0473, -5 2 8, 0.0467, 0.0465, and 0.0403, or re-calculated and expressed in percentage of total ash (according to abstracts for Jahresb. Chem.) 1.203, 1.324, 0.771, 1.580, and 1.017 per cent alumina. Reithner (Vierteljahressch. Prakt. Pharm., 4, p. 382 ; Jahresb. Chem., 1855, p. 723) notes 4.3 per cent ash in the leaves of holly (Ilex aquifolium) dried at 100. Of this 0.66 per cent was A1 2 O 3 . Reithner (Vierteljahressch. Prakt. Pharm., 4, p. 481 ; Pharm. Chem., 1855, p. 834; Jahresb. Chem., 1855, p. 724) notes 4.05 per cent ash in the dry flowers, without anthers, of colchicum or autumn crocus (Colchicum autumnale) and 4.15 per cent in the dry anthers. The ash contained respectively 0.27 per cent and a trace of A1 2 O 3 . Ricciardi, L. (Gaz. Chim. Ital., 19 (1889), p. 150), studied the aluminium content of the ash of different portions of several plants. He found that the ash of grape-vines grown on clay soil contained 0.85 per cent alumina; on soil containing an abun- dance of lime, 0.81 per cent; and on soil with a medium lime content, 1.14 per cent. He also found 0.218 per cent alumina present in the ash of the branches and twigs, 0.093 m the skins and seeds, and 0.022 in the leaves of the mandarin orange. The ash of Indian fig fruit, "prickly pear" from Bari, contained 0.063 P er cent; from Catania, 0.092. The ash of the rind of the prickly-pear fruit from Bari contained 0.148 per cent; from Catania, 0.167. The ash from the flesh of St. John's breadfruit (Ceratonia siliqua) from Bari contained 0.503 per cent; from Catania, 0.607; the ash of the seeds from Bari, 0.062; from Catania, 0.064. The ash of almond shells grown near Bari contained 0.695 P er cent A1 2 O 3 , the ash of the kernels ALUMINIUM IN VEGETABLE PRODUCTS. 31 0.138. The ash of tobacco leaves contained 2.151 per cent alumina. The seeds and skin of mandarin oranges grown near Cara contained in the ash 0.121 per cent A1 2 O 3 , and white lupine ash 0.042 per cent A1 2 O 3 . Further, wine was found to con- tain 0.022 gm. A1 2 O 3 per liter. The author concludes that the assimilation of alumina does not depend on the percentage in the soil, and that, generally speaking, alumina is most abundant in the trunk and branches, less so in the husks and seeds, and least of all in the leaves. Ringer, F. A., and E. Brooke (Amer. Jour. Pharm., 64 (1892), p. 255) report 4.29 and 1.32 per cent ash in roots of true and commercial pareira respectively. Both contained A1 2 O 3 ; the amount not stated. Ritthausen, H. (Jour. Prakt. Chem., 53 (1851), p. 413) reports 36.250 per cent A1 2 O 3 in the pure ash of a club-moss (Lycopo- dium complanatum) . Ritthausen, H. (Jour. Prakt. Pharm., 58, p. 133; Pharm. Centbl., 1853, p. 531; Jahresb. Chem., 1853, p. 586) reports 39.07 and 20.69 per cent A1 2 O 3 in ash of club-mosses (Lycopo- dium chamaecyparissns and L. clavatum). The amount of total ash was not stated. Rode, C. (Vierteljahres. Prakt. Pharm., 9, p. 530; Jahresb. Agr. Chem., 1861-62, p. 6 1), reports 0.15 per cent A1 2 O 3 in the ash of the leaves of cuckoo-pint (Arum maculatum). The leaves contained a total of 88 per cent water; the water-free material, 10.12 per cent ash. Rotondi, E. (Rel. lav. esequiti. lab. Chim. R. Staz. enoL Asti, 1878, p. in; Centbl. Agr. Chem., 8 (1879), p. 530), studied the ash constituents of grape must, branches, and leaves from two vineyards near Asti. In every case the vine and leaves were selected after the grape harvest from vines which had borne fruit. The branches of Pinot grapes from Galletria d'Asti contained 2.91 per cent pure ash in dry matter, of which 0.13 per cent was A1 2 O 3 . Branches of Barbara grapes from Costigliole d'Asti contained 3.37 per cent pure ash in dry matter; of this 0.02 per cent was A1 2 O 3 . Traces of alumina are also reported in branches and leaves of Barbara and Grignolino grapes from Galleria d'Asti and in must of Barbara and must and branches from Fresia grapes from Costigliole d'Asti. 32 ALUMINIUM IN VEGETABLE PRODUCTS. Ruge, G. (Apoth. Ztg., 1891, p. 208; Jahresb. Agr. Chem., 1891, p. 244), states that floating buttercup (Ranunculus flui- tans) contains 14.349 per cent ash in the dry matter; 0.33 per cent of this being A1 2 O 3 . de Saussure, T. (Recherches Chimiques sur la Vegetation, Paris, 1804) discusses the ash constituents of plants, and in tables at the end of the volume reports the ash constituents of a considerable number. From these tables the following is quoted: In the leaves and other portions of a large number of trees and plants the amount of aluminium in the ash was less than o.oi per cent. The leaves of a rhododendron (Rhodo- dendron ferrugineum) contained 3 per cent ash in the dry matter ; of this 0.12 per cent was alumina. Another sample contained 2.5 per cent ash in the dry matter, 0.12 per cent of this also being alumina. The branches of the same plants contained 0.8 per cent dry matter; of this 0.12 per cent was alumina. Saussure 's investigation is interesting chiefly from an histori- cal standpoint. Sayre, L. E. (Amer. Jour. Pharm., 69 (1897), p. 543), reports a study of the composition of dandelion (Taraxacum) root. A sample dried at 100 contained 11.13 P er ceirt asn - Of this 18.07 per cent was A1 2 O 3 . Schazler, M. (Vierteljahressch. Prakt. Pharm., n, p. 270; Jahresb. Chem., 1862, p. 514), found 5.12 per cent ash in the finest Ceylon cinnamon bark (dried at 110). Of this 0.55 per cent was A1 2 O 3 . Schlegel, C. E. (Amer. Jour. Pharm., 57 (1885), p. 426), reports the analysis of the fruit of star anise (Illicium anisatum) . The seed capsules contained 10.36 per cent moisture and 3.5 per cent ash. This was made up, according to the author, of potassium, sodium, iron, aluminium, hydrochloric acid, and phosphoric acid. Schreiner (Vierteljahressch. Prakt. Pharm., 5, p. 207; Jahresb. Chem., 1856, p. 691), reports 0.72 per cent ash in the fresh fruit of sloe or black thorn (Prunus spinosa). Of this 0.5 per cent was A1 2 O 3 . Schriddl, P. (Arch. Pharm., 1873, p. 375; Centbl. Agr. Chem., 5 (1874), p. 50) , reports the percentage of A1 2 O 3 in the ash of four samples of tea leaves and two of wood as follows: 0.810, 1.015, ALUMINIUM IN VEGETABLE PRODUCTS. 33 2.226, 2.072, 4.093, and 2.834. They were from Java and in the case of Nos. 3, 4, and 6 were affected with a tea disease. Sestini, F. (Gaz. Chim. Ital., 4 (1874), p. 182; Jahresb. Chem., 1874, p. 906), notes a trace of alumina in the ash of a seaweed (Posidonia oceanica) which is used as a fertilizer. Sestini, F. (Gaz. Chim. Ital., 15 (1885), p. 107; Landw. Vers. Stat., 32 (1886), p. 197; Jahresb. Chem., 1885, p. 1848), studied the relation between the atomic weight and the physio- logical functions of the elements. He says in effect regarding certain elements, "Many elements which are not yet regarded as necessary for plants are found in plant ash, as aluminium, lithium, and fluorine." He believes that no element with an atomic weight over 56 enters directly into the formation of living material. Sestini, F. (Stud, e Ricer. Inst. Lab. Chim. Agr. Pisa, 6, p. 87; Chem. Centbl., 1887, p. 939; Jahresb. Chem., 1887, p. 2647), determined the aluminium content of a number of wines. He found per 1000 cc. in ordinary red wine, from Peccioli (1884), 0.017 g m -5 i n ordinary red wine from Ghez- zano (1884), 0.034 gm. ; in red wine from Calci (1884), 0.038 gm.; from Collesalvetti (1883), 0.006 gm. ; from Collesalvetti (1884), 0.002 gm. ; from S. Giuliano (1884), 0.005 g m - ' an( ^ from S. Giuhano (1885), 0.009 g m - He concludes, therefore, that a natural wine does not contain more than 0.03 gm. alumina per liter and that alumina will never exceed 0.2 per cent of the pure ash. Shepard, C. U. (Trans. N. Y. State Agr. Soc., 1844, p. 343), reports traces of alumina in the ash of rice straw. He also reports traces in the ash of corn (grains) as quoted by J. H. Salisbury (Trans. N. Y. State Agr. Soc., 1848, p. 726). Smith, H. G., in an article entitled "Aluminium, the Chief Inorganic Element in a Proteaceous Tree, and the Occurrence of Aluminium Succinate in Trees of this Species" (Chem. News, SB (1903), p. 135), reports the occurrence of a large deposit of basic aluminium succinate of the formula A1 2 (C 4 H 4 O 4 )3A1 2 O 3 in the center of a silky oak tree 3 feet in diameter (Orites eoccelsa) from Queensland. The ash of the wood farthest from the deposit contained 79.61 per cent alumina. The large deposit was regarded as a natural effort to get rid of a surplus of alumina not needed by the tree. 34 ALUMINIUM IN VEGETABLE PRODUCTS. Three other samples of the same kind of tree from northern New South Wales were examined and in the ash of all a large amount of alumina was found, the quantity ranging from 36 to 43 per cent. Much of the alumina in the ash was present as a potash salt soluble in water, and as no carbonate of potash was found "it is supposed that the potassium aluminate was originally present in the tree as such." As no alumina was found in the ash of Grevillea robusta, G. helliana, and G. striata, the author believes that it is probable that the tree reported to contain it in an earlier article by J. H. Maiden and himself (see page 26) was O. excelsa and not G. robusta, as stated at the time. Smith, A. Percy (Chem. News, 28, p. 261, 324; Jahresber. Chem., 1873, p. 851), reports (by difference) 1.459 per cent alumina and lithium carbonate in the ash of Havana tobacco. Smith, Watson (Jour. Chem. Soc. London, 37 (1880), II, p. 416), analyzed the ash of two varieties of eucalyptus wood, E. rostrata contained 2.25 per cent ash and E. globuhts 2.01 per cent. The former contained 0.78 per cent ferric and aluminic phosphate, the latter 1.07 per cent. In the latter a trace of A1 2 O 3 was also noted. Snyder, H. (Chemistry of Plant and Animal Life, 1903, Easton, Pa., p. 168), says: "Aluminium is found in the ash of many plants, as wheat, peas, beans, and rice, although it occurs in very small amounts and, so far as known, is not essential for plant growth. Most soils contain traces of soluble silicates of aluminium, and hence plants cannot well be free from it." Solms-Laubach, Graf (Ann. Chem. u. Pharm., 100 (1856), p. 297), reports 2 per cent A1 2 O 3 in the ash of a lycopod (Lyco- podium denticulatum) . Speiss, E. (Wittstein's Vierteljahresschrift, 9, p. 392; Jahr- esber. Agr. Chem., 1 860-61, p. 59), analyzed the ash of the bark of the root of the pomegranate and the root-stalks of male fern. The ash of the former contained a trace of A1 2 O 3 and that of the latter 0.071 per cent. Staffel, E. (Preisschrift. Arch. Pharm., 2d ser., 64, I, p. 129; Ann. Chem. Pharm., 76, p. 379; Pharm. Centbl., 1850, p. 897, 1851, p. 146; Jahresb. Chem., 1850, p. 661 and Table D, p. 66i) r ALUMINIUM IN VEGETABLE PRODUCTS. 35 in a study of the question whether the inorganic constituents of different organs of a green plant varied at different seasons, reports alumina in ash as follows: Horse-chestnut wood (autumn), 0.23 per cent; bark, 0.18 per cent; leaves (spring), 0.41 per cent; leaves (autumn), 0.51 per cent. The total ash in the above (dry material) was 3.38, 6.57, 7.69, and 7.52 per cent respectively. He also reports alumina in ash of English walnut bark (autumn), 0.29 per cent; leaves (spring), 0.18 per cent; leaves (autumn), 0.06 per cent. The total ash in the above (dry material) was 6.403, 7.719, and 7.005 per cent respectively. Stoklasa, J. (Ann. Agron., 23 (1897), p. 588), in connection with a study of the condition of phosphoric acid in the soil made laboratory experiments with salts of known composition which led to the conclusion that the water-soluble portion of superphosphates never contains acid ferrous phosphate, this salt changing almost immediately upon its formation into di-tri-ferriphosphates of varying composition insoluble in water. The addition of ferrous salts to soluble phosphates results in the formation of di-tri-ferriphosphates unless an excess of free phosphoric acid is present. Acid ferric phos- phate may be found in superphosphates only when there is at least 30 per cent of free phosphoric acid present. If this is not the case, the acid ferric phosphate may be transformed into mono-di-tri-ferriphosphate, Fe 2 O 3 (P 2 O 5 ) 2 .8H 2 O. "It is thus seen that the retrogression of phosphoric acid in superphosphate is very largely dependent upon the free phosphoric acid present. Aluminium salts do not behave like iron salts in superphosphate, but like the salts of lime and magnesia. "Pot experiments with barley on a fertile soil containing 0.63 per cent calcium carbonate and 2 per cent of humus and treated with different phosphates of calcium, aluminium, and iron showed that the effect of the acid phosphates of these elements was almost the same. The tribasic phosphates were about one-half as effective as the acid phosphates. The effect of the normal reverted phosphates was about one-half greater than that of the tribasic phosphates." Other conclusions regarding phosphates were drawn. ALUMINIUM IN VEGETABLE PRODUCTS. Strawinski, J. Frank (Amer. Jour. Pharm., 70 (1898), p. 189), finds that the ash of the rhizome and rootlets of plantain (Plantago major) amounted to 24.70 per cent and contained alumina in addition to other constituents. Strohecker, R. (Arch. Pharm., 26. ser., 145, p. 131; Jour. Chem. Soc. London, 24 (1871), p. 428), in an article on chemical substitution in plants discusses analyses by Wittstein of water from the Ohe and Isar rivers and of the ash of Fontinalis anti- pyretica taken from these waters. The river waters contained respectively 0.016 and 0.2250 per cent total solids; in that of the Ohe water 0.108 per cent was A1 2 O 3 . The plants from the two rivers contained 22.60 and 9.88 per cent ash respectively, of which 9.272 and 1.6 1 6 per cent was A1 2 O 3 . Struckmann (Ann. Chim. Pharm., 97, p. 143; Jour. Prakt. Chem., 68, p. 379; Chem. Centbl., 1856, p. 187; Jahresb. Chem., 1856, p. 687) found 9.2 per cent ash in the root (Wedel) of male fern (Aspidium filix mas) (dried at 100), and 8.1 per cent in that of asplenium (A. filix femina), the ash containing respectively 2.40 and 2.20 per cent A1 2 O 3 . Teller, G. L. (Arkansas Station Bulletin 42, pp. 75, 77), reports complete analyses of whole wheat, wheat flour, and other milling products, the samples being all obtained from the same lot of winter wheat grown in Arkansas. The data regarding alumina follow: ALUMINA IN ASH OF WINTER WHEAT AND ITS MILLING PRODUCTS. Patent Flour Straight Flour. Low Grade Dust- room. Ship- stuff. Bran. Wheat. Total ash PerCt O 31 Per Ct. o 40 Per Ct. o . 70 Per Ct. 2 . tro Per Ct. 3.o8 Per Ct. C ,2Z Per Ct. 1.62 Aluminium oxid in ash .41 I "> . 12 .04 .18 .07 . II The presence of alumina in wheat has been attributed to the wearing down of the millstones. On this point Professor Teller says: ' ' This could not have been a source of the material in these mill products, as the wheat was crushed entirely by iron rollers, and an examination of the amounts of alumina found in the ALUMINIUM IN VEGETABLE PRODUCTS. tf mill products and in the whole grain indicate that it is no more foreign to the true ash than any of the other constituents named. To bring further proof on this point, 100 gms. of the unground wheat was carefully washed with distilled water and, after drying, was burned without being pulverized. The same amounts of both alumina and zinc were found as in the wheat which had not been washed. It seems a little remarkable that the zinc should have accumulated to the greatest extent in the ash of the bran, while the alumina and silica should have reached their largest proportion in the ash of the finer flours. Alumina is found to be of frequent occurrence in the mineral waters of this State." To ascertain whether alumina is present in the ash of wheat grown on a very sandy soil, a sample of wheat was obtained which had grown on a sandy soil in Michigan. This was examined for alumina and none was found Thielau (Vierteljahresschr. Prakt. Pharm., 4, p. 537; Pharm. Centbl., 1855, p. 8n; Jahresb. Chem., 1855, p. 728) found 3.33 per cent ash in ergot (Secale cornutum) dried at 100. Of this 0.29 per cent was A1 2 O 3 . Thomas, Mason B. (Proc. Indiana Acad. Science, 1893, p. 239), in a report on the study of the ash of trees makes the following statements: "The substances usually found in the ashes of all trees when burned at a low temperature are potash, soda, lime, magnesia, and iron (K 2 O, Na 2 O, CaO, MgO, Fe 2 O 3 ) in com- bination with phosphoric acid (P 2 O 5 ), sulphuric acid (SO 3 ), chlorine (Cl), carbon dioxide (CO 2 ), and silica (Si0 2 ); iodine (I), aluminium (Al), and manganese (Mn) are often present. One portion of these mineral constituents exists in solution in the sap and the other in the tissue of the plant in the solid form." The author reports the ash constituents usually deter- mined, but does not report the amount of aluminium present. His experiments were made with common forest and fruit trees. Tod, W. (Arch. Pharm., 2d ser., 78 (1854), p. 136; Jour. Prakt. Chem., 62, p. 503; Pharm. Centbl., 1854, p. 452; Jahresb. Chem., 1854, p. 665), found that the flesh of plum (Prunus domestica) made up 93 per cent of the fruit and the pit 7 per 38 ALUMINIUM IN VEGETABLE PRODUCTS. cent. The fresh flesh contained 0.407 per cent ash, 0.003 per cent being A1 2 O 3 . Tollens (Jour. Landw., 50 (1902), p. 231) states that alu- minium is always present in very small quantities in grain. Trimble, H., and H. J. Schuchard (Amer. Jour. Pharm., 57 (1885), p. 21) report the analysis of the tops and leaves of water pepperwort (Polygonum hydropiper). The ash consti- tuted 7.4 per cent of the total plant and contained aluminium phosphate. Tschirch, A. (Gartenzeitung, 1883, p. 34), reports in hyacinth (Hyacinikus orientalis) io.ii per cent dry matter and 8.5787 per cent pure ash. The A1 2 O 3 in the ash was 0.8871 per cent. Tucker, G. M., and B. Tollens (Ber. Deut. Chem. Gesellsch., 32 (1899), p. 2575; Jour. Chem. Soc. London, 78 (1900), II. p. 35) note Al 2 O 3 .Fe 2 O 3 in plane-tree leaves. Vielguth (Vierteljahressch. Prakt. Pharm., 5, p. 187; Chem. Centbl., 1856, p. 423; Jahresb. Chem., 1856, p. 690) notes 7.6 per cent ash in bed straw (Galium mollugo) (whole plant). This contained 0.3 per cent A1 2 O 3 . Volcker, A. (Rpt. i9th Meeting British Association; Notes and Abstracts, p. 43, Jahresb. Chem., 1850, p, 672 and Table D, p. 661), notes 1.97 per cent alumina in the ash of Armeria maritima (green plant?). The amount of total ash was not stated. Wallace (Analyst, 3 (1878), p. 243) reports that the ash of sugar made from cane growing near the seacoast in Demerara contained, in addition to other constituents enumerated, 0.65 per cent aluminium. The amount of total ash is not stated. Walz (Jahrb. Prakt. Pharm., 15, p. 65; Jahresb. Chem., 1847-48, p. 1083; and Table B, p. 1074) reports ash as follows in grapevine and leaf : Clevner, 6.19 per cent; Riesling, 7.74 per cent; Drollinger, 6.00 per cent. Of this 1.15, 0.91, and i.oo per cent respectively was aluminium phosphate. Wanklyn, J. A., and W. J. Cooper (Bread Analysis, London, 1886, pp. 22, 24, 25) state that according to their analyses the ash of flour contains 1.3 per cent Fe 2 O 3 and A1 2 O 3 together. In eight samples of flour analyzed, 100 gms. of material yielded from o.oi to 0.02 gm. of phosphate of iron and alumina. In ALUMINIUM IN VEGETABLE PRODUCTS. 39 eight samples of bread, the ash in 100 gins, of material .ranged from 0.890 gm. to 1.742 gms. ; the phosphates of iron and alumina from 0.006 gm. to 0.014 gm. Warden, C. J. H. (Chem. News, 38, p. 146; Jahresber. Agr. Chem., 1878, p. 1 06), reports a trace of A1 2 O 3 in the ash of opium from Behar, India. Warden, C. J. H. (Chem. News, 39, p. 27; Jahresb. Chem., 1879, p. 927), reports 0.9701 per cent A1 2 O 3 in the ash of poppy leaves or petals used to wrap up opium. The total amount of ash is not stated. Warden, C. J. H. (Chem. News, 64 (1891), p. 161), reports 24.334 per cent ash in the leaves (dried at 100) of prickly chaff flower (Achyranthes aspera), an Indian weed. Of this 2.0651 per cent was A1 2 O 3 . The author says that there was considerable soil which it was not possible to separate from the leaves. This would, of course, increase the A1 2 O 3 content. Wasowicz, D.v. (Pharm. Jour. Trans., 3dser., io,pp. 301, 341, 463; Arch. Pharm., 3d ser., 14 (1879), p. 193; Jahresb. Chem., 1879, p. 927), notes the presence of aluminium in the ash of the root of an aconite (Aconitum heterophyllum). The total ash was equal to 2.331 per cent. The root of another aconite (Aconitum japonicnm) contains 2.799 percent ash. Aluminium is reported as a constituent of this also. Watts, H. (Phil. Mag., 3d ser., 32, p. 54; Jahresb. Chem., 1847-48, p. 1077; and Table A, p. 1074), reports 6.5 per cent ash in hop blossoms; of this 1.18 per cent was alumina. Way, J. T., and G. H. Ogston (Jour. Roy. Agr. Soc., n, pt. 2, p. 497; Jahresb. Chem., 1850, p. 666, Table A, p. 660) note 1.90 per cent ash in rye (dry material). Of this 0.50 per cent was alumina. Weber, R., and E. Ebermayer ("Lehre der Waldstreu," Berlin, 1876. Cited by Wolff in "Aschen Analysen," Berlin, 1880, pt. 2, pp. 87, 130) determined the A1 2 O 3 in fir litter, i.e. needles, etc., under fir trees. The pure ash in eleven analyses ranged from 1.07 to 2.00 per cent. From 1.09 to 9.98 per cent of the total pure ash was found to be A1 2 O 3 . Weber and Ebermayer ("Lehre der Waldstreu," Berlin, 1876. Cited by Wolff in "Aschen Analysen," Berlin, 1880, pp. 100, 131) also give figures showing that the pure ash of white pine 4O ALUMINIUM IN VEGETABLE PRODUCTS. litter ranges from 1.99 to 5.27 per cent. Of this 1.44 to 7.02 per cent was found to be A1 2 O 3 . Wefers-Bettink, H. (Rev. Trav. Chim. Pays-Bas, 2, p. 126; Jahresb. Chem., 1883, p. 1496), analyzed "Legen," a Japanese drug, which has been said to consist largely of the excrement of an insect, " Dendang." He concluded that it was of vegetable origin and probably prepared from the seed of some strychnin- yielding plant. Legen contained 16.88 per cent ash, of which A1 2 O 3 was one of the constituents. Weigelt, C. H. (Jour. Prakt. Chem., 106 (1869), p. 193), reports 10.5 per cent pure ash in one specimen of Parmelia scruposa; of this 28.171 per cent was found to be A1 2 O 3 . Wellborn, G. (Pharm. Jour. Trans., 3d ser., 9, p. 181; Jour. Chem. Soc/London, 1878, II, p. 1009), in a paper on the detec- tion of alum in flour states that too much allowance has been made for alumina in wheat, as it is not an invariable constituent. Wheeler, C. Gilbert (Erdman's Journal, 94, p. 385; Jahresb. Agr. Chem., 1865, p. 114), reports traces of A1 2 O 3 in the ash of nine varieties of Bavarian hops. Will and Fresenius (Chevallier et Baudrimont, " Dictionnaire des alterations," Paris, 1878, p. 1131) note the occurrence of alumina in the ash of Hungarian tobacco. Winternitz (Vierteljahressch. Prakt. Pharm., 4, p. 542; Pharm. Centbl., 1855, p. 820; Jahresb. Chem., 1855, p. 722) found 8.88 per cent ash in dandelion (Leontodon taraxacum) (whole plant without root, dried at moderate temperature). Of this 0.402 per cent was A1 2 O 3 . Witting (Keller and Tiedemann's Nord. American Monats- ber. Pharm. Chem., 1851, p. 404; Jahresb. Chem., 1851, p. 712, Table C, p. 708) reports in ash of birch "No. 76 " 1.38 per cent alumina and in "No. 74" 0.42 per cent, and in ash of beech " No. 75 " 0.05 per cent. The amount of total ash is not stated. Wittstein (Repert. Pharm., 2d ser., 46, p. 329 ; Pharm. Centbl., 1847, p. 739; Jahresb. Chem., 1847-48, p. 1082; and Table A, p. 1074) reports 1.56 per cent ash in green leaves of Virginia creeper (Vitis hederacea) ; of this 0.07 per cent was alumina. Wittstein (Vierteljahressch. Prakt. Pharm., 3, p. 10; Pharm. Centbl., 1854, p. 12; Jahresb. Chem., 1853, p. 579) reports 1.13, 1.98, and 2.92 per cent ash in the bark of pine trees (Scotch ALUMINIUM IN VEGETABLE PRODUCTS. pine) (Pinus silvestris), 220, 172, and 135 years old, respectively, which grew on the sandy soil of the "Hauptmoor, " near Bam- berg, the ash containing respectively 10.12, 4.49, and 3.08 per cent A1 2 O 3 . The wood from the trunks of these trees contained 0.45, 0.58, and 0.42 per cent ash with respectively 0.92, 0.72, and 0.26 per cent A1 2 O 3 . Wittstein (Vierteljahressch. Prakt. Pharm., 4, p. 525; Jahresb. Chem., 1855, p. 722) reports two analyses (the first by Nut- zinger; the second by Thielau) of the ash of heather (Calluna vulgaris) (whole plant, without root, in bloom): sample "a," grown on moorland, contained, air-dry, 2.876 per cent ash with 0.844 per cent A1 2 O 3 , and sample "b," grown on sandstone, contained, air-dry, 3.324 per cent ash with 0.513 per cent A1 2 O 8 . Wittstein, G. C. (Arch. Pharm., 2d ser., in, p. 14; Jahresb. Chem., 1862, p. 509), reports the following: ALUMINA IN CERTAIN PLANTS. Kind of Plant. Reindeer moss (Cladonia rangiferina) dried at 1 60; from Riefs, near Passau Reindeer moss (C. rangiferina) from Frauen- berge Reindeer moss (C. rangiferina) from neighbor- hood of Sterz Lichen (Variolaria dealbatd) from Barenstein- leithe, near Grafenau; not well cleaned Old man's beard ( Usnea barbatd) from Grafenau . . Lichen (Gyrophora pustulatd) from Veitsberge. . . . Iceland moss (Cetraria islandica) from Bavarian forest Sphagnum moss (Sphagnum cuspiaatum) Irom Upper Bavaria White birch (Betula alba) from Bavarian forest; wood dried at 1 00 White birch (Betula alba) from Bavarian forest; leaves dried at 100 Beech (Fagus sylvaticd) from Bavarian forest; wood Beech (Fagus sylvatica) from Bavarian forest; leaves Dwarf pine (Pinus pumilid) from Bavarian forest; wooa Dwarf pine (Pinus pumilid} from Bavarian forest; bark. . Total Ash. A1 2 O 3 in Ash. Per* Cent. I.I8 1.325 0.905 18.20 1 .49.6 3.00 o.S 2 .OI4 0.864 0.74 4-3 0.284 1-375 Per Cent. I .805 1.694 1.948 7-495 i-653 4.069 4.348 2.834 0.663 0.287 0.508 o . 162 0.124 o .240 These plants are discussed in relation to the material (rock or soil) on which they grew. ALUMINIUM IN VEGETABLE PRODUCTS. Wittstein (Vierteljahressch. Prakt. Pharm., 13, p. 364; Jahresb. Agr. Chem., 1865, p. 108) quotes an analysis showing that fresh fig leaves from plants grown on calcareous soil con- tain 0.286 per cent ash, 0.03 per cent of this being A1 2 O 3 . Wittstein, G. C. (Ann. Chem. u. Pharm., 108, p. 203; Chem. Centbl., 1858; Jahresb. Agr. Chem., 1858-59, p. 121), reports the ash content of the different parts of a primrose (Primula farinosd). The following figures are quoted, being for material dried at 100: Root, 1.617; leaves, 0.955; stem, 0.539; flower heads, 1.145; and entire plant, 0.832 per cent A1 2 O 3 respectively; or, dif- ferently stated : Of the 0.832 per cent A1 2 O 3 in the entire plant, 0.175 P er cent was in the root, 0.198 per cent was in the leaves, 0.294 per cent was in the stem, and 0.165 P er ceirt was i n the flower head. Wittstein, G. C. (Vierteljahressch. Prakt. Pharm., 16, p. 81; Jahresb. Chem., 1867, p. 769), reports alumina as follows in leaves and flowers of lilac (Syringa vulgaris), all dried at 110. ALUMINA IN DIFFERENT PARTS OF LILAC. Part of Plant. Ash. A1 2 O 3 . Leaves (variety with white blossoms) Per Cent. 4 380 Per Cent. O I Q ? Leaves (variety with purple blossoms) 4 . 022 188 Flowers (without calyx, variety with white blossoms) * 76 I ? C Flowers (without calyx, variety with purple blossoms) 4 286 24O Wittstein, G. C. (Arch. Pharm. 3d ser., 8, p. 341; Jahresb. Agr. Chem., 1875-76, p. 139; Jour. Chem. Soc. London, 1877, I, p. 487), reports 5.936 per cent total ash in a spurge (Euphorbia amygdoloides) (whole plant) grown on soil rich in silicate and 4.85 per cent in another sample from similar soil. The ash of the first contained 1.057 and of the latter 1.325 per cent A1 2 O 3 . Wittstein, G. C. (Arch. Pharm., 3d ser., 7 (1875), P- 3945 Jour. Chem. Soc. London, 1876, I, p. 736), finds that the ash of the elder tree (Sambucus nigra) contains 0.250 per cent A1,O 3 . Wittstein also reports (Arch. Pharm., 3d ser., 8 (1876), p. 229; Jahresb. Agr. Chem., 1875-76, pp. 132, 138) 94 per cent total dry ALUMINIUM IN VEGETABLE PRODUCTS. 43 matter in sunflower seeds (Helianthus annuus), the ash con- taining 0.23 per cent A1 2 O 3 and 1.9 per cent ash, with 0.28 per cent A1 2 O 3 in the whole plant. Wittstein, G. C. (Arch. Pharm., 3d ser., 8 (1876), p. 342; Jahresb. Agr. Chem., 1875-76, p. 139), reports 7.132 per cent ash in Herniaria glabra (dry plant) grown in silicious soil and 6.622 per cent in plants grown on dolomite soil. The former contained 1.321 and the latter 1.755 P er cent A1 2 O 3 . Wolff, E. (Aschen Analysen, pt. 2, p. 128), cites figures showing that heather contains 2.08 per cent pure ash. It is stated that on an average 0.33 per cent of the total ash is A1 2 O 3 , the range in eleven analyses being from o to 2.3 per cent. Wolff asfo states (Aschen Analysen, p. 128) that in moss (the variety not given) the pure ash constituent is equal to 2.74 per cent on an average. Of this A1 2 O 3 constitutes 2.35 per cent, the range in eleven analyses being from only o to 7.99 per cent. Wolff also states (Aschen Analysen, p. 128) tnat the pure ash content of lycopodium is 5.10 per cent, 39.17 per cent of this being A1 2 O 3 , the range of this constituent in six analyses being from 22.2 to 57.36 per cent. Some of the data cited by Wolff were undoubtedly from early analyses, interesting chiefly from an historical standpoint. Wolff, J. (Vierteljahressch. Prakt. Pharm., 3, p. i; Jahresb. Chem., 1853, p. 562), found 1.2 per cent ash in air-dry birch fungus (Birken schwamms). Of this 3.14 per cent was A1 2 O 3 . The plant analyzed was without doubt the rough boletus (Bo- Ictus scaber), sometimes called Birken-pilz. Wypf el, M. (23 Jahresb. Niederoster. Landes Realgym. Wald- hofen, 1892, p. 22; Just's Jahresb. Bot., 20 (1892), I, i, p. 425), studied the effect of chlorids on plant growth. Seedlings of corn (Zed), bean (Phaseolus), pea (Pisum), cucurbit (Cucur- bita), sunflower (Helianthus), beet (Beta), onions, and Hart- wegia comosa w^ere watered daily with 0.5 to 2.0 per cent solu- tions of different chlorids. Among the conclusions drawn were the following: Chlorids which are widely distributed and which contain important material for plant growth (mag- nesium, calcium, potassium, and aluminium chlorid) at first had a favorable effect. Later, when they became more con- centrated in the soil, they hindered growth and finally killed 44 ALUMINIUM IN VEGETABLE PRODUCTS. the plants. Magnesium chlorid was the least harmful, potas- sium and aluminium chlorids most harmful. Yardley, H. B. (Chem. News, 79 (1899), p. 122; Jour. Chem. Soc. London, 76 (1899), II, p. 793), found 4.19 per cent ash in cardamon seeds and husks. Of this 1.53 per cent was A1 2 O 3 . Yoshida, H. (Jour. Chem. Soc. London, 43 (1883), p. 472), reports a chemical study of lacquer (Uritshi), the milky secretion of lac (Rhus vernicefera) . Gum constitutes from 3 to 8 per cent of the original juice. A sample weighing 0.5267 gm. gave 0.0267 m - asn - The asn was found to contain in addition to -other constituents 7.85 per cent A1 2 O 3 . Yoshida (Jour. Chem. Soc. London, 51 (1887), pp. 748-750) takes exception to the idea that alumina is not a normal con- stituent of flowering plants, as stated by Allen (Commercial Organic Analysis, vol.. i, p. 38). In the Japanese lacquer tree (Rhus vernicefera) alumina is present, apparently as an arabate. According to the author the soil of the plain of Musashi, on which Tokyo is situated, is of volcanic origin and is remark- able for the large proportion of alumina in it which is soluble in hydrochloric acid. This gave promise that here, if any- where, aluminium should certainly be found in flowering plants. He therefore examined a number of plants and flowers grown on the farm lands of the Imperial College of Agriculture at Komaba, near Tokyo. Each one was carefully picked over and all imperfect and soaked grains rejected. Great care was taken to clean the grains and parts so as to remove all dirt. They were ground and incinerated, care being taken to avoid all possible contamination with clay or charcoal. The materials examined included soy bean (Soja hispida) (which the author calls "pea"), whole seed, cotyledons, and hull or skin, red bean (Adzuki) (Phaseolus radiat-us), hill and paddy rice, wheat, barley, two sorts of millet, and buck- wheat. The analytical methods are described in detail. The table beyond reports the results of. the analyses. Of this work the author says : "It will be seen that I have found alumina in every case except that of the pea [soja], while in the hull or skin of the pea, one of the largest amounts of alumina occurs. The results here recorded may at least serve to indicate the propriety of reconsidering the accuracy of the ALUMINIUM IN VEGETABLE PRODUCTS. 45 dictum that aluminium is not a constituent of flowering plants." ASH CONSTITUENTS OF A NUMBER OF PLANTS. Kind of Plant Ash in In Ash. Sample. Alumina. Phosph. Acid. Silica, etc. "Pea" (whole) (Sojahispida) "Pea" (cotyledons) (Sojahispida) " Pea" (hull or skin) (Soja hispida) Red bean (Adzuki) (Phaseolus ra- diatus) Per Cent. 4.22 4-31 2 60 Per Cent. 0.053 .000 .268 006 Per Cent. 33-48 5-66 -20 80 Per Cent, o .50 3.60 Rice (hill) o 87 161 6^ v Rice (paddy) o tc6 180 D x 6 6 JV Wheat 2 62 j-* 7v 10.99 Barley I OO 140 U J OO 1 -3 1 Millet (Awd) (Panicum italicum). . Millet (Hiye) (P. cruscorvi) Buckwheat 1.68 0.94 i 72 .272 .185 112 66 x y 40.43 39.87 I OA i .19 8.91 8.62 o 81 Young, W. C. (Analyst, 2 (1878), p. 13), in an article on the estimation of alum in bread, reported that from bread containing no added alum he obtained 0.07 grain A1.PO 4 per 1000 grains. Young, W. C., also reports (Analyst, 12 (1887), p. 29), in an article on "Sour Bread and the Logwood Test," that he found aluminium phosphate equivalent to 7.8 grains of alum in 4 pounds of bread which he subsequently learned contained no added alum. A second sample of the same bread yielded alu- minium phosphate equivalent to 8 grains of alum in 4 pounds of bread. In his investigation he found that the logwood test as applied by him indicated the presence of aluminium in the sam- ples of flour or bread examined which were known to contain no added alum, provided the sample underwent acid fermentation or was acidulated with acetic acid. In a discussion of his paper, W. Blythe states that all bread contains more or less alumina. Young, W. C. (Analyst, 12 (1887), p. 145), reports later a con- tinuation of his investigation. He found that the aluminium normally present in the flours he examined was contained in the gluten of the wheat and not in the starch, and was present 46 ALUMINIUM IN VEGETABLE PRODUCTS. in the form of aluminium phosphate. The following quotation is of interest in this connection: " Another conclusion which may be fairly drawn from my results is that the alumina naturally present in flour is com- bined with the gluten. This being so, I thought it would be interesting to see if gluten would absorb alumina from a solu- tion of alum. With this object I prepared some gluten, thoroughly dried it, and found the ash equal to 1.28 per cent. A portion of this gluten finely powdered was placed in a 2 per cent solution of alum and kept for some hours at a temperature of about 1 80 F. ; it was then thrown on to a filter, thoroughly washed, and dried. The ash then amounted to 1.32 per cent. Taking into consideration the great difficulty of washing the gluten free from excess of alum, I do not think this slight in- crease of ash is due to absorption of alumina. Although the gluten does not appear to have the property of absorbing alumina from a solution of alum, yet its properties are affected in a marked degree by contact with such a solution, as it may then be kept moist in a warm place without giving any indica- tion of decomposition, whilst ordinary gluten, as is well known, darkens in color, swells, and rapidly decomposes under similar circumstances." Young, W. C. (Analyst, 13 (1888), p. 5), reports the deter- mination of alumina in the best quality of Vienna flour, con- taining 0.7 per cent ash and about 8 per cent gluten. From 100 gms. of flour he obtained 0.0075 g m - f phosphate of alumina. Of his experiment he says: "The gluten was separated by washing in a muslin bag in the usual way, and when dried contained 1.26 per cent ash; 20 gms. of this dried gluten, finely powdered, was then treated with about 250 cc. of a mixture of equal volumes of acetic acid and water and heated in the water -bath for about twenty- eight hours. By this time the mass had become quite liquid, the gluten having lost its firmness in the same way that gelatin does under similar circumstances. After standing a short time the liquid was poured off and the sediment further treated with weak acetic acid twice, and the three portions of liquid evaporated to dryness, the sediment being rejected. In this way I think that any extraneous earthy matter present in the ALUMINIUM IN VEGETABLE PRODUCTS. 47 gluten was separated, and, therefore, only the natural alumina retained. "The dried residue was* then burnt to a perfect ash, the ash dissolved in dilute hydrochloric acid and filtered, the insoluble matter being well washed and weighed. The insoluble matter thus obtained weighed only 0.009 g m -> an d of this .0075 was silica. "The insoluble matter was then fused with about twice its bulk of mixed alkaline carbonates, dissolved in dilute hydro- chloric acid, and filtered. This filtrate was added to the acid solution of the ash, evaporated to dryness, redissolved in a small quantity of dilute hydrochloric acid, and filtered. The filtrate was then boiled and cautiously added to 25 cc. of a saturated solution of pure caustic soda, also boiling, and the whole kept boiling for a few minutes. It was then filtered, and the precipitate washed, the filtrate made slightly acid with hydrochloric acid, about 5 cc. of a saturated solution of sodium phosphate added, and finally a slight excess of ammonia. After boiling for about ten minutes, the precipitate of phos- phate of alumina was collected and weighed. . . . "In this way I obtained .0185 gm. of phosphate of alumina from 20 gms. of gluten. Now, as the flour contained 8 per cent of gluten, and gave originally .0075 per cent of phos- phate of alumina, 20 gms. of gluten would be equivalent to 250 of the flour, which would yield .01875 f phosphate of alumina. So that practically I obtained the whole of the alumina of the flour in the gluten. As in the process of wash- ing the starch from the gluten a large proportion of any foreign earthy matter that may have been present must have been separated, and any remaining eliminated by dissolving the gluten in acetic acid, there can be no doubt that the alumina obtained in this experiment was present as a natural constituent of the flour, and I think further that the interesting fact is established that the bulk of it is associated with the gluten." Young, W. C. (Analyst, 15 (1890), p. 83), in a report of an investigation of the solubility of phosphate of alumina in acetic acid undertaken with special reference to the estimation of alumina in flour, bread, etc., makes the following statement: "I may mention that rye bread, of which I frequently have 48 ALUMINIUM IN VEGETABLE PRODUCTS. samples for analysis from the east end of London, invariably gives a strong reaction with a logwood test, although I have never found more than .008 gm. phosphate of alumina in 100 gms." Yvon, M. (Jour. Pharm. et Chim., 4th ser., 25 (1877), p. 588), reports the ash analyses of Thapsia garganica from Hegeria and T. sylphium * from Asia, the former with 7.52 per cent and the latter with 5.746 per cent in the fresh plant. Of this 0.3 and 0.433 P er cen t respectively was said to be A1 2 O 3 . Zeyer, N. (Vierteljahressch. Prakt. Pharm., 10, p. 504; Jahresb. Chem., 1861, p. 769), found 4.05 per cent ash in the bark of Atherosperma moschatum dried at 100. Of this 0.191 per cent was A1 2 O 3 . * There is an evident error in the names of the plants in the original tables as published. The names as quoted above have been corrected. ALUMINIUM IN ANIMAL PRODUCTS. Dieterich, E. (Vierteljahressch. Prakt. Pharm., 16, p. 56; Chem. Centbl., 1867, p. 287; Jahresb. Chem., 1867, P- 822), reports 3.2 per cent ash in cochineal (silver-gray Honduras variety); of this 1.390 was A1 2 O 3 . Harrison and Kinnicutt, according to Rotch (Pediatrics, Philadelphia, 1896, p. 175), found 0.40 per cent iron oxid and alumina in the ash of woman's milk, the total ash ranging from o.i to 0.2 per cent. From the data at hand, the propor- tion of the ash constituents was recalculated, the value for iron oxid and alumina being given as 0.37 per cent. Silica was also found, and it is stated that this and alumina have not been noted in any previous analysis. Data are also quoted by Rotch (loc. cit., p. 218) regarding the ash of cow's milk which it is said were reported by Konig, Forster, and others. The value given for total ash is 0.70 per cent, of which 0.44 per cent was iron oxid and alumina. Heyl (Ann. Chem. Pharm., 62, p. 87, Repert. Pharm., 2d ser., 47, p. 231; Pharm. Centbl., 1847, p. 591: Jahresb. Chem., 184748, p. 938) notes 29.18 per cent aluminium silicate in a sample of officinal burned sponge (Schwammkohle). Liebermann, C. (Ber. Deut. Chem. Gesellsch., 1885, p. 1969; Jahresb. Chem., 1885, p. 1847), estimates that cochineal yields 9 to 10 per cent pure coloring matter. In good cochineal carmine, he found 7 per cent ash. This contained a trace of A1 2 O 3 . Carmine is regarded as an aluminium-calcium- protein compound of the coloring matter present. Mayrhofer, J. (Chem. Centbl., 1891, I, p. 175; Jahresb. Chem., 1891, p. 2820), notes a trace of alumina in the ash of that portion of an abnormal leather which was soluble in cold water. 49 $0 ALUMINIUM IN ANIMAL PRODUCTS. McMurtrie, W. (American Chemist, 4, p. 339; Watts' Dictionary, 1879, vol. 8, pt. i, p. 765), finds in the excrements of the common bat 19.88 per cent of alumina. Miintz, A. (Ann. Chim., 4th ser., 20, p. 309; Compt. Rend. Acad. Sci., Paris, 69, p. 1309; Bui. Soc. Chim., 2d ser., p. 379; Dingler's Polytech. Jour., 195, p. 466; Jahresb. Chem., 1869, p. 1149), in a study of the chemical changes in tanning, reports 0.6693 an d 0.4670 per cent ash respectively in fresh, rather thin hide from a young cow, and very thick ox hide. The ash contained respectively 0.0930 and 0.0704 per cent Al 2 3 .Fe 2 O 3 . Schutze, R. (Chem. Centbl., 1889, II, p. 588; Jahresb. Chem., 1889, p. 2156), found in the ash of the mantle of Phal- lusia mammillaris (after extraction with ether) 9.52 per cent A1 2 O 3 . The amount of ash is not stated. Staffel (Arch. Pharm., 2d ser., 64 (1850), p. 148; Pharm. Centbl., 1851, p: 162; Jahresb. Chem., 1850, p. 573) found in veal (breast) free from fat and skin 77.64 per cent water, and in the dry material 3.1 per cent ash. This contained according to his analysis a trace of alumina. He also found a trace in the ash of beef. The fresh material contained 72.63 per cent water; the dry 2.2 per cent ash. Theile, R. (Jenaische. Ztschr. Med., 3, p. 147; Ztschr. Chem. y 1868, p. 125; Chem. Centbl., 1867, p. 296, 305; Vierteljahressch. Prakt. Pharm., 17, p. 197; Bui. Soc. Chim., 2d ser., 10, p. 153; Jahresb. Chem., 1867, p. 772), reports 2.3 per cent ash in egg albumen, 15.04 per cent of this being A1 2 O 3 .PO 5 . Thezard (Compt. Rend. Acad. Sci.. Paris, 120 (1895), p. 1126; Jour. Chem. Soc., London, 68 (1895), H P- 45*5) analyzed a very white, porous, and very brittle tibia from an adult human mummy from an Egyptian tomb of unknown age. In addition to other constituents, he reports 0.534 per cent A1 2 O 3 . Walter, G. (Ztschr. Physiol. Chem., 13, p. 464; Jahresb. Chem., 1889, p. 2156), reports 28.165 P er cerrt asn m the shell- like, outer covering of Protopterus annectens (air-dry). This contained 5.491 per cent A1 2 O S . ALUMINIUM IN NATURAL WATERS. Abb6ne (Jour. Pharm., 3d ser., 12, p. 412; Pharm. Centbl., 1848, p. 47; Jahresb. Chem., 1847-48, p. 1009) notes traces of alumina in the water of the Pre Saint Didier upper and lower mineral springs at Courmayeur. Adams, F. D. (Geol. and Nat. Hist. Survey, Canada, 1885. Chemical Contributions, p. 15, M), reports 0.0005 parts alumina per 1000 in water from a spring at Halowell Grant, near Antigonish, Nova Scotia. This water is used for medicinal purposes. Adams, F. D. (Geol. and Nat. Hist. Canada, 1888-9. Chem- ical Contributions, p. 17, R.), in an analysis of water from a boring in the west half of Lot 26, in the fourth range of Otanabee, Peterborough County, Ontario, reports 0.0008 part alumina per 1000. Agrestini, A. (Gaz. Chem. Ital. ; Jour. Chem. Soc. London, 64 (1893), II, p. 175), found in the hepatic mineral spring water of the Valle del Gallo, near Urbino, 0.0005 A1PO 4 per 1000 gms. Aillaud (Compt. Rend. Acad. Sci., Paris, 95, p. 104; Jahresb. Chem., 1882, p. 1627) reports 0.007 g m - A1 2 S 3 O 12 per 1000 cc. in high water from the Rio Grande which was used for the water supply of Panama. Aillaud (Compt. Rend. Acad. Sci. Paris, 95, p. 104; Jahresb. Chem., 1882, p. 1637) reports 0.020 gm. A1 2 O 3 per 1000 cc. in well-water from Emperador, Panama, and o.on gm. A1 2 O 3 in water from a second well in the same locality. 51 $2 ALUMINIUM IN NATURAL WATERS. Allemann, H. (Wiener Akad. Ber., 56 (2. Abt.), p. 47 ; Wiener Akad. Anz., 1867, p. 135; Jour. Prakt. Chem., 101, p. 317; Chem. Centbl., 1867, p. 423; Inst. 1867, p. 341; Jahresb. Chem. 1867, p. 1039), in an analysis of the Sauerbrunn at Ebriach in Karnthen, reports 0.034 part A1 2 O 3 and 0.015 parts aluminium phosphate per 10,000. Andouard (Jour. Chim. Med., 3d ser., 5, p. 466; Jahresb. Chem., 1849, p. 617) found 0.003 gm. aluminium phosphate and 0.006 gm. alumina per 1000 cc. in mineral water from Villecelle, near Lamalou (Herault). Andouard, A. (Jour. Pharm., 4th ser., 9, p. 336; Jahresb. Chem., 1869, p. 1291), reports two analyses of Beaupreau spring-water from Dep. Maine-et-Loire. It contained 0.022 and o.oio gm. A1 2 O 3 per 10,000 gms. The second analysis was made with a sample taken after heavy rain. Ashley, J. M., E. T. Bennett, and T. J. Herapath are quoted (Jahresber. Chem., 1849, p. 620) as reporting traces of alu- minium in Thames water near London Bridge, Thames water at Greenwich, and mineral water from Kingswood, near Bristol, respectively. Avequin (Jour. Pharm., 3d ser., 32, p. 288; Jahresb. Chem., 1857, p. 729) notes 1.753 grains alumina per gallon (=58,372 grains) in Mississippi River water taken at Carrollton, a few miles above New Orleans, Louisiana. Bailey, E. H. S., in an extended treatise entitled "Special Report on Mineral Waters" (University Geol. Survey of Kansas, vol. 7), gives analytical data regarding the composition of a large number of waters in Kansas. The following table sum- marizes the data concerning alumina in these waters. ALUMINIUM IN NATURAL WATERS. $3 ALUMINA IN KANSAS MINERAL WATERS. Analyst. Page. Alumina per Liter. The Chlorid Group. Arkansas City Well E H S Bailey I3T Grams. Eureka Mineral Well . . . . E H S Bailey I 37 Geuda Spring No 4 . . . . Bailey and Franklin 1 4.7 01 c8 Bromo-magnesium Well E. H. S. Bailey I ^O trace Geyser Mineral Well The Sulphate Group. Burr Oak \ E. H. S. Bailey G. H. Failyer and 157 I T 6o .0178 'Capioma Mineral Well C. M. Breese E. H. S. Bailey r iuy I 7O ZI 75 Carbondale Spring E. H. S. Bailey 172 Centralia Gypsum Well Conway E. B. Knerr Failyer and Breese J 73 .OOyO Chlor-Sulphate Group. Merrill Spring A. Merrill A to I 06 Great Bend Mineral Well Great Spirit Spring, No. 2 Lincoln Springs No i . . E. H. S. Bailey Bailey and Rice Bailey and Franklin 197 205 2O7 trace .0166 Lincoln Springs No 2 Bailey and Franklin 208 Lincoln Springs, No. 3 Bailey and Franklin 2OQ Carbonate Group. Dixon Spring . ... E. B Knerr 2 I O Kickapoo Springs E. H. S. Bailey 237 Sulfid Group. Cherokee City Well Bailey and Hull 260 Columbus Well Failyer and Willard 262 trace Fort Scott Sulfo-magnesian Well . Moss Springs Well E. H. S. Bailey G. H. Failyer 266 268 .0144 O24.I Wakefield Sulfur Well Bailey and Porter 271 O ^ 3O Chalybeate (Iron) Group. Atchison Electric Light Well McDuff's Spring E. B. Knerr E. B. Knerr 280 28l .0567 OI2O Special Group. Lithium Sprino" Omio Failyer and Willard 307 IO4O Providence Mineral Well Soft-water Group. Atchison Parker's Spring J. H. Banks E. B. Knerr 308 311 trace 0032 Bailey quotes analyses of a number of waters for purposes of comparison, but does not cite the original place of publication. The following table shows data regarding the occurrence of alumina in such as have not been noted from other sources. 54 ALUMINIUM IN NATURAL WATERS. ALUMINA IN A NUMBER OF WATERS. Analyst. Page. Alu- minium Chlorid per Gallon. Alu- minium Phos- phate per Gallon. Alumina per Gallon. Alu- minium Sul- phate per Gallon. Oranien Quelle, Kreuznach, Rhen- ish Prussia Liebig 160 Grains. Grains. 760 Grains. Grains. Dead Sea 161 2J 37 Carabana, Spain A. Proust 192 .020 Friedrichshall, Saxe- Meiningen, Germany Apollinaris Germany Bauer Bischoff 2I 5 246 .56 I . 2O Sulphur Spring, Aix- les-Bains France . . Bonjeau 273 T. . 2OO Excelsior Sp'gs Mo \ Woodward r 3OI 207 Sparta Artesian Well, \Visconsin andRob'tson J M Hirsch ) 6 7QI 048 Bailey, E. H. S., and Mary A. Rice (Trans. Kansas Acad. Sci., 14 (1896), p. 40; Jour. Chem. Soc. London, 72 (1897), II, p. 109) report 1.66 parts A1 2 O 3 per 100,000 in water from a mineral spring in Mitchell County, Kansas, near Cawker City. Baker, W*. H. (Dingler's Polytech. Jour., 218, p. 267; Jour. Chem. Soc. London, 1876, I, p. 890), notes 55.128 grains A1 2 (SO 4 ) 3 per gallon in the water of a swallet in the Empire mine of the Luzerne Company. Ballo, M. (Ber. Deut. Chem. Gesellsch., 1878, p. 1900; Jahresb. Chem., 1878, p. 1306), notes 0.0017 A1 2 O 3 (with a trace of P 2 O 5 ) per 1000 in a thermal spring at the foot of the Blocksberg. Ballo, M. (Ber. Deut. Chem. Gesellsch., 1878, p. 1902 ; Jahresb. Chem., 1878, p. 1305), in two samples of Ofener Bitter Wasser reports 0.229 and 0.089 parts A1 2 O 3 (with P 2 O 5 ) per 10,000, respectively. Ballo, M. (Russ. Ztschr. Pharm., 22, p. 68; Jahresb. Chem., 1883, p. 1945), notes 0.0229 part A1 2 O 3 per 1000 parts in the bitter water of the Victoria well at Of en, Hungary. Ballo, M. (Ber. Deut. Chem. Gesellsch., 1884, p. 673; Jahresb. Chem., 1884, p. 2035), reports 0.00952 gm. A1 2 O 3 per 1000 cc. in Borhegyer Sauerwasser from Bibarczfalva, Austria-Hungary. Barth, L. v., and R. Wegscheider (Wiener. Klin. Wochensch., 1891, No. 8; Jahresb. Chem., 1891, p. 2620) report 0.3575 gm. ALUMINIUM IN NATURAL WATERS. 55 A1 2 O 3 per 10,000 gms. in mineral spring water from Mitterbad, Ultenthale, Tirol. Barzilowski, J. (Ber. Deut. Chem. Gesellsch., 1884, p. 183; Jahresb. Chem., 1884, p. 2037), notes 0.0055 P art A1 2 O 3 per 1000 parts in Tokiew mineral water; and 0.103 P art A1 2 O 3 per 1000 parts in Alexandro-Jermolowski mineral water, both from the Caucasus. Bauck, G. (Analyse der Salzsoolen von Colberg, Inaug. Diss. Gottingen, 1860; Jahresb. Chem., 1860, p. 830), reports alumina (parts per 10,000) in Colberg, Germany, saline mineral water as follows: Salinensoole, o.on; Zillenbergsoole, 0.008, and Marktsoole, 0.006. Bechamp, A. (Compt. Rend. Acad. Sci. Paris, 62, p. 1088; Jour. Pharm., 4th ser., 3, p. 448; Jour. Prakt. Chem., 98, p. 189; Chem. Centbl., 1866, p. 864; Jahresb. Chem., 1866, p. 998), found 0.0052 gm. alumina per 1000 cc. in Therese sulphur spring at Fumades (Arrondissement d'Alais), and (Compt. Rend. Acad. Sci. Paris, 62, p. 1034; Bui. Soc. Chim., 2d ser., 6, p. 9; Inst. 1866, p. 173; Jour. Pharm., 4th ser., 3, p. 444; Jour. Prakt. Chem., 98, p. 190; Chem. Centbl., 1866, p. 864; and Compt. Rend. Acad. Sci. Paris, 63, p. 559; Jahresb. Chem., 1866, p. 998) also reports 0.00106, 0.0008, and o.oon gm. alumina per liter respectively in Dulimbert, Bouillants, and Grander mineral springs at Vergeze, Dep. du Gard. Becker, G. F. (U. S. Geol. Survey Mon. 13, p. 265), quotes an analysis of water from Borax Lake, Cal., by Melville (Geol. Survey Cal., i, p. 98) which showed 0.0029 g m - A1 2 O 3 per liter. Becker (pp. 347 and 349) also gives an analysis of the water of Steamboat Springs, Nevada. The A1 2 O 3 present was 0.0025 gm. per 10 liters. Bell (Chem. News, 21, p. 83, from Amer. Jour. Pharm.; Jahresb. Chem. Naumann, 1870, p. 1392) notes traces of A1 2 O 3 in a mineral spring in New York in the Adirondack region. Bender, R. (Arch. Pharm., 3d ser., n (1877), p. 50; Jour. Chem.- Soc. London, 1878, II, p. 18), notes that Fresenius found 0.00013 parts A1PO 4 per 1000 in Heilbrunnen mineral spring water, a spring situated near Lake Taach, and in the water of the Stahlbrunnen at Wassenach, 0.00045 A1PO 4 . 56 ALUMINIUM IN NATURAL WATERS. Bender, R. (Arch. Pharm., 26. ser., 185 (1868), p. 5; Jahresb. Chem., 1868, p. 1035), reports 0.005, 0-182, and 0.045 A1 2 O 3 per 10,000 parts respectively in the Victoria, Angustus, and Cold Spring III. These waters are all from the thermal springs of Neuenahr. He also reports per 10,000 parts 0.176 A1 2 O 3 in the old or small Sprudel spring No. I and 0.19 Al 2 O 3 +Fe 2 O 3 in the new or large Sprudel No. II. The Marien Sprudel contained 0.06 Al 2 O 3 + Fe 2 O 3 . Bensemann, R. (Chem. Centbl. Ausz., 1882, p. 186; Jahresb. Chem., 1882, p. 1629), reports 0.0026 A1 2 3 per 100 in a Sool- quelle at Kammin, Germany. Berlin, N. J. (Oefversigt. K. Vetenskops. Akad. Forhl., 1863, p. 221; Jahresb. Chem., 1865, p. 939), notes 0.00794 part alumina per 10,000 in Torpasaltkalle at Lilla Edet in Sweden. Bertoni, G. (Gaz. Chem. Ital., 14 (1884), p. 232; Jahresb. Chem., 1884, p. 2035), i n an analysis of the Acquarossa Spring at Biasca, Italy, notes 0.0485 gm. A1 2 O 3 per 1000 cc. Billot, E. (Jour. Chim. Med., 3d ser., p. 569; Jahresb. Chem., J 853, P- y 1 ^), reports alumina (gm. per 1000 cc.) in water from Besancon, France, as follows: Doubs, 0.002; spring-water from the Grand Rue, 0.0094. Bizio (Wiener. Acad. Ber., 41, p. 335, Rep. Chim. Pure. 2, p. 390; Jahresb. Chem., 1860, p. 837) reports (parts per 10,000) 0.0371 A1 2 O 3 in the St. Gothard Spring water from Ceneda, Italy. Bizio, G. (Atti. Imp. Reg. Inst. Venato Sci. Let. ed Arti., 3d ser., n; Jahresb. Chem., 1865, p. 940), notes 7.7507 alumina per 10,000 in mineral water from Civillina. Bizio, G. (Gaz. Chim. Ital., 10 (1880), p. 43; Jahresb. Chem., 1880, p. 1529), reports new analyses of the springs of Civillina, Italy. The old basin contained 1.28414 gms. aluminium sulphate; the new basin, 1.50764 gms. aluminium sulphaV per 1000 gms. Blondeau (Compt. Rend. Acad. Sci. Paris, 30, p. 481: Pharm. Centbl., 1850, p. 910; Jahrb. Chem., 1850, p. 621) notes the occurrence of aluminium salts as among the ordinary constituents of water of brooks, rivers, and springs. Water ALUMINIUM IN N A 7^ URAL WATERS. $? containing 0.4 to 0.5 gm. total mineral matter per liter is re- garded as satisfactory for household purposes. Blondeau (Compt. Rend. Acad. Sci. Paris, 35, p. 147; Inst. 1852, p. 238; Jour. Prakt. Chem., 57, p. 244; Jahresb. Chem., 1852, p. 756) reports 0.0016 gm. alumina (per 1000 gms.?) in water from Salles-la-Source, Aveyron. Bobierre and Moride (Compt. Rend. Acad. Sci. Paris, 32, p. 376; Inst. 1851, p. 90; Jour. Pharm., 3d ser., 20, p. 244; Jahresb. Chem., 1851, p. 666) note 0.401 gm. total solids per 1000 cc. in mineral water from Kirouars, France; this contained a trace of alumina. The same authors (Compt. Rend. Acad. Sci. Paris, 33, p. 322; Inst. 1851, p. 306; Pharm. Centbl., 1851, p. 748; Jahresb. Chem., 1851, p. 666) noted 0.350 gm. total solids per 1000 cc. in mineral water from La Bernerie, France. This contained 0.6 per cent alumina. Bolley, P., and F. Schweizer (Ann. Chem. Pharm., 106, p. 237; Chem. Centbl., 1858, p. 600; Jahresb. Chem., 1858, p. 800) found 0.0103 fe 01 -) alumina per 1000 cc. in the sulphur water from Schinznach, Switzerland. Bolley, P., and Brigel (Schweiz. Polytech. Ztschr., 1865, p. 47; Ztschr. Chem., 1865, p. 639; Jahresb. Chem. 1865, p. 936) report 0.0130 alumina per 1000 parts in the sulphur spring A at Lostorf in the Jura. Bosshard, E. (Chem. Centbl., 1892, II, p. 1039; Jahresb. Chem., 1892, p. 2689), reports 0.00057 m - A1 2 O 3 per 10,000 gms. in the Old Spring water at St. Moritz in the Engadine and 0.00040 gm. A1 2 O 3 per 10,000 gms. in Paracelsus spring water from the same locality. Boussingault (Compt. Rend. Acad. Sci. Paris, 78, pp. 453, 526, 593, Ann. Chim. Phys., 5th ser., 2, p. 76; Arch. Pharm., 3d ser., 5, p. 354; Jahresb. Chem., 1874, p. 1337) reports 0.4028 gm. A1 2 O 3 per liter in the water of the Rio Vinagre, near the falls of San Antonio, Colombia, a volcanic region, and 0.500 gm. per liter in a hot spring at the foot of the Ruiz volcano. Boutel, G. F., examined the mineral waters of Saint Nectaire (Ann. Chim. Phys., 6th ser., 7, p. 536; Jour. Chem. Soc., London, 50 (1886), II, p. 858) and reported per liter 0.0330 gm. A1 2 O 3 in Source Rouge and 0.0239 g m - i n Source du Mont Cornador. Braconnot (Jour. Chim. Med., 3d ser., 7, p. 737; Jahresb, $8 ALUMINIUM IN NATURAL WATERS. Chem., 1851, p. 665) notes 0.0080 gm. silica and alumina per 1000 cc. in the Luxeuil Spring. Brignone, G. (Gaz. Chem. Ital., 14 (1884), p. 42; Jahresb. Chem., 1884, p. 2036), found in water from the island of Pan- telleria (Italy), 0.00245 gm. A1 2 O 3 .P 2 O 5 per 1000 cc. Buchner, A. (Jour. Prak. Chem., 102, p. 209; Neue Repert. Pharm., 16, p. 481; Neue Jahrb. Pharm., 28, p. 292; Jahrb. Chem. Will., 1867, p. 1036), found 0.00104 gm. alumina per liter in potable water from the spring at Neumarkt, Ober- pfalz, Bavaria. Buchner, L. A. (Neue Rep. Pharm., 17, p. 357; Jour. Chem., 104, p. 360; Jahresb. Chem. Will., 1868, p. 1037), reports traces of alumina in the sulphur spring at Oberdorf in Allgau. Buchner, M. (Wiener. Akad. Ber., 2. Abt., 71, p. 309; Jahr- esb. Chem., 1875, p. 1296), notes 0.0274 parts aluminium phosphate per 10,000 in Moriz spring- water from Sauerbrunn, near Rohitsch, Austria. Buchner, M. (Chem. Centbl., 1876, p. 789; Jour. Chem. Soc. London (1877), II, p. 176), in the water of the Tempelbrunnen at Rohitsch, notes 0.0095 parts ( = A1PO 4 ) per 100,000. Buchner, M. (Chem. Centbl., 1881, p. 567; Jahresb. Chem., 1882, p. 1631), found 0.0249 parts A1 2 O 3 .P 2 O 5 per 10,000 in the Lindenbrunnen at Zlatten, Austria-Hungary. Bull (Silliman's Amer. Jour., 2d ser., 4, p. 385; Pharm. Centbl., 1848, p. 319; Jahresb. Chem., 1847-48, p. 999) reports 0.14 gm. alumina per 10,000 gm. in spring- water from Hart- ford, Connecticut. Bunsen (Neue Jahresb. Pharm., 2, pp. 190, 194; Pharm. Centbl., 1854, p. 931; Jahresb. Chem., 1854, p. 758) examined a number of mineral waters, reporting aluminium phosphate (parts per 1000) as follows: Sophienquelle, 0.0033; Peters- quelle, 0.0071, and Salzquelle, 0.0035. a ^ a ^ Petersthal. Bunsen, according to Riegel (Neue Jahresb. Pharm., 9, p. 301 ; Jahresb. Chem., 1858, p. 794), found 0.007 P art alumina per 10,000 parts in water from the Elizabethenquelle at Rothen- fels, Baden. Bunsen (Beitrage zur Statistik der inneren Verwaltung des Grossherzthums Baden, n, Nos. 30, 43, and 56; Jahresb. ALUMINIUM IN NATURAL WATERS. S9 Chem., 1 86 1, p. 1090) in Baden mineral springs notes alumina as follows (parts per 10,000): Ursprung, o.on; Judenquelle, o.on; Bruhquelle, 0.009; Murquelle, trace, and Rothenfelser Mineralquelle, 0.007. Bunsen and Kirchoff (Poggendorf's Ann., 113, p. 358; Phil. Mag., 4th ser., 22, p. 344; Jahresb. Chem., 1861, p. 1092) note o.ooi alumina (parts per 10,000) in the Umgemach thermal spring (Baden-Baden) and note. 0.00020 in saline water from Durkheim. Burrell, B. A. (Jour. Chem. Soc. London, 69 (1896), p. 536), in an analysis of the water of the dropping well at Knaresborough in Yorkshire, notes a trace of alumina. Carius, L. (Ann. Chem. Pharm., 137, p. 106; Jahresb. Chem. Will., 1866, p. 987), notes in the Ottilienquelle, Badequelle, and Marienquelle from the Inselbad near Pader- born, 0.009, 0-009, an d 0.004 grams alumina per 10,000 respectively. Carnelley, T. (Chem. News, 31, p. 27; Jahresb. Chem., 1875, p. 1298), reports in a spring (iron) near Trefriw, Wales, 233.3 parts aluminium per million. An earlier analysis by Hassal (Chem. News, 31, p. 27; Jahresb. Chem., 1875, P- 1298) gives 112.4. These values correspond to 1358.9 aluminium sulphate and 3.2 aluminium phosphate, and 707.7 aluminium sulphate, and o.o aluminium phosphate per million respectively. Carnot, A. (Ann. Mines, 9th ser., 6 (1894), p. 355), reports a series of analyses of French mineral waters made at the 6cole du Mines, containing data for the period from January, 1885, to June, 1894. The following contained alumina (grams per liter): "Sources de Fraysse, No. i," Commune de Cransac, De'partement 1'Aveyron, 0.0016; "Sources de Fraysse, No. 2," 0.0840, which were calculated to be equal to 0.0087 an d 0.2790 gm. A1 2 (SO 4 ) 3 respectively. The "Sources Roques" and "Rou- quette," Cransac, Departement 1'Aveyron, contained respec- tively 0.0093 an d 0.0071 A1 2 O 3 equal to 0.0300 and 0.0230 aluminium sulphate. The "Sources No. 2," Cransac, con- tained 0.1340 Al 2 O 3 = o.4462 aluminium sulphate. Water from the Briscous salt-wells, Commune Briscous, De'partement Basses- Pyrenees, 0.0050 A1 2 O 3 (with traces of Fe 2 O 3 ). (See also Compt. Rend. Acad. Sci. Paris, in, p. 192.) 6O ALUMINIUM IN NATURAL WATERS. Carnot, A. (Ann. Mines, gth ser., 16 (1899), p. 33), reports a later series of analyses of mineral waters made at the laboratory of the ficole Nationale superieure des Mines, July, 1 894-5 une, 1899. In. the following, alumina was reported (grams per liter): "Source Saint-Louis," Departement de la Drome, 0.1650 ( = 0.5505 aluminium sulphate); spring, Canton et Arrond. de Bagneres-de-Bigorre, Departement Hautes-Pyrenees, 0.00060. Casali, A. (Staz. Sper. Agr. Ital., 19, p. 509; Jahresb. Chem., 1890, p. 2658), notes traces of aluminium in potable water from Bologna, Riggio-Emilia, Ferrara, and Ancona. Casselmann, W. (Jahrb. Ver. Naturk. Herzogthum Nassau, No. 15, p. 139; Jour. Prak. Chem., 83, p. 385; Chem. Centbl., 1861, p. 874; Jahresb. Chem., 1861, p. 1094), reports alumina (per cent by weight) as follows in Nassau mineral water : Sool- sprudel, 0.00062; Soolsprudel (sample taken in 1859), 0.00012; No. IV (1857), 0.00054; No. VII (1858), 0.00005; No- I (1^59), 0.00016; No. X (1859), 0.000023; No. Ill (1859), 0.00016; and Neuenhainerquelle (1860), trace. Cassels, J. L. (Amer. Chem., 4 (1873), p. 169; Jahresb. Chem., Naumann, 1873, p. 1246), reports 0.333 m - A1 2 3 per 10,000 cc. in spring- water from Castalia, Ohio. Chandler, C. F., F. A. Cairns, and S. P. Sharpless (Ann. Chem., 2d ser., 3, pp. 93, 164, and 202; Jahresb. Chem., Nau- mann, 1872, p. 1189) found in the Saratoga waters "Glacier Spouting," "Empire," and "Triton," 0.08 gm., 0.07 gm., and a trace of alumina per 10 liters. Chandler, C. F., and F. A. Cairns (Amer. Chem., 4 (1873), p. 86; Jahresb. Chem., Naumann, 1873, p. 1246) note 0.055 gm. A1 2 O 3 per 10 liters in Saratoga union spring-water (0.324 grains per gallon). Chandler, C. F., and F. A. Cairns (Amer. Chem., 6, p. 241; Jahresb. Chem., 1876, p. 1309) report 0.1002 gm. A1 2 O, per 10,000 cc. in St. Leon water from Canada, and (Amer. Chem., 6, p- 37; Jahresb. Chem., 1876, p. 1309) 0.0220 gm. A1 2 O 3 per 10,000 cc. in artesian water from Sheboygan, Wisconsin. Chatard, T. M. (U. S. Geol. Survey, Bui. 9, p. 23), found in water from Humboldt River, Nevada, 0.3615 gm. total solids per liter, of which 0.0013 IT 01 - or -37 P er cent was A1 2 O 3 . Chatard, T. M. (U. S. Geol. Survey, Bui. 9, p. 24), in water ALUMINIUM IN NATURAL WATERS. 6 1 from Hot Springs, Hot Springs Station, Nevada, found 2.4924 gms. total solids per liter, o.ooio gm. or 0.04 per cent being aluminium. Chatard, T. M. (U. S. Geological Survey, Bui. 9, p. 27), found in warm spring-water, Mono Basin, California, 2.0850 gms. total solids, containing 0.0018 gm. or 0.09 per cent A1 2 O 3 . Chatard, T. M. (U. S. Geological Survey, Bui. 9, p. 29), found in water from City Creek, Utah (collected above reservoir which supplied Salt Lake City), 0.2400 gm. total solids per liter, o.ooio gm. or 0.041 per cent being A1 2 O 3 . Chatard, T. M. (U. S. Geol. Survey, Bui. 55, p. 93), found in water from Owens Lake, California, 0.023 g m - A1 2 O 3 per kilo. Chatard, T. M. (U. S. Geological Survey, Bui. 64, pp. 59, 60), notes 0.0005 and 0.0012 gm. A1 2 O 3 per liter respectively in artesian wells A and B, St. Augustine, Florida; also 0.0077 gm. A1 2 O 3 per liter in water from a well four miles northwest of Clinton, Miss. Chevallier, A. (Jour. Chem. Med., 3d ser., 7, p. 193; Jahresb. Chem., 1851, p. 666), found 0.125 g m - alumina and silica per liter in mineral water from Wattweiler. Clark (Chem. Soc. Quar. Jour., i, p. 155; Pharm. Centbl., 1848, p. 650; Jahresb. Chem., 1847-48, p. 998) notes a trace of alumina in the Thames water at Twickenham. Clark, F. W. (U. S. Geol. Survey, Bui. 55, p. 92; Jahresb. Chem., 1891, p. 2622), reports 0.0020 gm. A1 2 O 3 per 1000 cc. in Potash Sulphur Spring water from Garland County, eight miles southeast from Hot Springs. Cloez, C. (Compt. Rend. Acad. Sci. Paris, 98, p. 1282; Jahresb. Chem., 1884, p. 2036), found 0.0710 gm. Al 2 O 3 ,SiO 2 per 1000 c.c. in a mineral spring near Brucourt, in the neighborhood of Dives, France. Crawfurd (Vierteljahressch. Prakt. Pharm., 6, p. 161; Chem. Centbl., 1875, p. 267; Jahresb. Chem., 1857, p. 722) notes 0.023421 Al 2 O 3 .SiO 3 per 1000 parts in mineral water from Kellberg near Passau, Germany. Crook, J. K. (Mineral Waters of the United States and their Therapeutic Uses, Philadelphia, 1899), made an exten- sive compilation of analyses of mineral waters of the United States which was based, the author says, on treatises on 62 ALUMINIUM IN NATURAL WATERS. mineral waters, issued by the various States, National Geological reports, railroad guides, etc., as well as information received in reply to inquiries addressed to all spring resorts and com- mercial springs of the United States which could be reached. Personal visits were also paid to many of the more important localities. In quoting analytical data he has expressed the results in grains per United States gallon. The whole subject is discussed with special reference to the use of mineral waters in the treatment of disease. It has been the author's purpose to include all the springs of the United States whose waters are actually used at the present time. The following state- ments are made regarding aluminium in discussing the value of the different constituents of mineral waters: "This substance is found in springs in the form of the oxide, or alumina, and of the sulphate. It occurs in variable quan- tities, ranging from a mere trace to sixty or eighty grains per gallon, as seen in some of the Virginia alum springs. The sulphate is almost always present in the sulphureted chalyb- eate waters, and, as stated above, in the acid springs. The internal use of alum waters is generally governed by these associated ingredients. Some of the alum springs have acquired a considerable reputation in scrofulous diseases and in chronic diarrhoea and dysentery. The iron-alum waters are beneficial in passive hemorrhages and in exhausting night -sweats. Locally their astringent action calls them into service in much the same class of cases as are benefited by the acid waters. They have produced valuable results in conjunctivitis, stomatitis, chronic vaginitis, and other relaxed or inflammatory states of those portions of the mucous surfaces accessible to local treatment. They have also been found to act as a useful auxiliary in the treatment of ulcerated surfaces, abrasions, etc. In large quantities the alum waters have a laxative influence, but they are seldom used in virtue of this action." The following table summarizes the data quoted from Dr. Crook's report: ALUMINIUM IN NATURAL WATERS. 63 ALUMINIUM IN SPRING-WATERS OF THE UNITED STATES. Spring. Analyst. Page. Aluminium Sulphate per U. S. Gallon. Alumina iTs. Gallon. Alabama. Matchless Mineral Wells. . . f E. A. Smith, oi Grains. Grains. > 6C Arkansas. Arkansas Lithia Springs. . . \ J. B. Little Muehler 08 3 U 3 O O2 California. Agua de Vida Lower Spring Anderson I IO 37 Agua de Vida Upper Spring Anderson I IO 4.O Alum Rock Alkaline Saline Spring Alum Rock Chalybeate Sp'g Anderson Hatch 112 112 6-45 Anderson Iron Spring G E. Colby I 14 X J O3 Anderson Sour Spring G. E. Colby lie 1 II Blodgett's Springs Anderson I2O 41 3 Calistoga Springs Anderson 126 Calistoga Swimming Pool. . . El Paso de Robles, Main Sulphur Spring Anderson Anderson 126 I 70 4/ .27 2 ? El Paso de Robles, Soda Spring Anderson I 31 ^0 8c Eureka Springs W. D. Johnson I 31 ^j i 30 Felt's Mineral Springs 1^2 d California Geysers, Lemon- ade Spring T. Price I^S 32 02 California Geysers, Witches' Caldron T. Price 178 2 04 2 7 California Geysers, Acid Sp'g CaliforniaGeysers,Alum Sp'g California Geysers, Iron Gey- ser Creek .... T. Price T. Price T. Price N> Go Oo C X 00 00 20 .62 63.82 80 California Geysers, Spring on hill T. Price 138 . 2O California Geysers Iron Sp'g T Price 138 I 7 California Geysers, Indian Spring California Geysers, Mud In- dian Spring T. Price T. Price 138 138 22.78 .18 California Geysers, Spring little above Indian Spring California Geysers, hot sul- phur-water, above bath- house T. Price T. Price 138 138 118.78 2 . 3O California Geysers, Devil's Teakettle T Price 138 3i 16 Glen Alpine Springs Anderson 142 I 43 Gordon Springs Anderson 142 7 C IT Harbin Hot Sulphur Spring 144 I 6O Harbin Chalybeate Spring. . 144 7 3 a. Amount not stated. Qualitative analysis. 64 ALUMINIUM IN NATURAL WATERS. ALUMINIUM IN SPRING-WATERS. Continued. Spring. Analyst. Page. Aluminium Sulphate per U. S. Gallon. Alumina Gallon. Highland Seltzer W Anderson 146 Grains. Grains. 17^ Highland Dutch or Ems "W^ Anderson 146 I 2 Hot Borate 147 2 Od. Howard Springs, Excelsior, No i W T Wenzell 148 O O ^ Howard Springs, The Twins, No 2 W T Wenzell 148 O I 5 Howard Springs, Eureka, No 7 W T Wenzell 148 O IO Howard Springs, Neptune, No 4 W T Wenzell 148 O IO Howard Springs Soda No. ^ W T Wenzell 148 O I 7. Lane Mineral Springs \ San Francisco Re- finin " and Analyti- I. i en 2 OI cal Association Litton Seltzer Springs W Anderson I CI 6 81 Mark West Springs 1^2 a Mono Lake "W Anderson I C. 7 26 67. Pagoda Spring (Napa Soda) "^T Anderson ICC c 7 Newsom's Arroyo Grande Springs . . "W Anderson 1^,6 7 7 Pacific Conress Springs "W^ Anderson *.3~' 1*8 4CQ Great Paraiso Hot Soda Springs . . . 160 c,6 Piedmont White Sulphur "Iron Springs " "W^ Anderson 161 A Santa Barbara Hot Springs. . Santa Rosa White Sulphur Springs W. Anderson "W Anderson 162 161 2 .90 *+J Ql Santa Ysabel Sulphur Springs " Main "W^arm " TV" Anderson 164. 7 Santa Ysabel Sulphur Springs Cold Sulphur No I "W Anderson l6A to 8* Santa Ysabel Sulphur Springs Cold Sulphur No 2 "W^ Anderson l64. 84. Santa Ysabel Warm Sulphur Mud W Anderson i6<; 6? Summit Soda Springs "W \nderson 168 I 17 Thermal Acid (Caso Range) 160 7404 .41 ? A " o Tolenas Springs . . W Anderson 170 I IO Tuscan (or Lick) Springs F W Hatch 170 & TVilbur Springs W Anderson m' 3Q7 \\ 7 itter's Mineral Springs 174 i 6? Young's Natural-gas Well and Mineral Springs W Anderson I7 1 ? c !8 Colorado . Manitou Soda Springs, Manitou E. Waller 187 .07 a. Qualitative analyses. Amount not reported. ALUMINIUM IN NATURAL WATERS. 65 ALUMINIUM IN SPRING-WATERS. Continued. Spring. Analyst. Page. Aluminium Sulphate per U. S. Gallon. Alumina per U.S. Gallon. Manitou Soda Springs, Na.va.jo E Waller 187 Grains. Grains. I O Poncho Hot Springs I QO 5 20 Connecticut, Stafford. Spring L Norton IQ7 ^ w J J Georgia. Bowden Lithia Upper Spring Bowden Lithia Lower Spring Bowden Lithia Lower Spring Franklin Spring Pratt Pratt Doremus 206 206 206 212 i-33 2.61 -53 a Hughes' Mineral Well Trentham Spring H. C. White 214 218 I .02 a Meriweather County Warm Sorin ' H C White 210 A.6 Idaho. Indan-Ha Spring C F Chandler 222 o ? Illinois. Kane County Magnesia Sorin^ W S Hains 226 oo Indiana. Indian Alkaline Saline Sprin " E. T. Cox 2"?I .82 Magnetic Mineral Spring. . . . Iowa. Fry's Mineral Spring W. A.Noyes W S Hains 234 2 3Q - J 7 066 Lineville Mineral Springs A E Woodward 2 T.Q 28 Kansas. Geuda Spring No i Bailey 244 06 Geuda Spring No. 2 Bailey 244 .01 Geuda Sprin" No 4 Bailey 24. 4 OI Geuda Spring No. 5 Geuda Spring No 7 Bailey Bailey 244 244 .01 OI Topeka Mineral ^Vells Barnes and Sims 2 47 4.O Kentucky. ~Q\cr Bone Springs 2 Co a Maine. Keystone Spring R. C. Stanley 261; 8c.c Maryland. Mardela Spring P. B. Wilson 272 3A a. Qualitative analyses. Amount not given. b. Heinrichs, in an analysis of this water, reports .29 grains "Silica Alumina" per U. S. gallon. c. With silica. 66 ALUMINIUM IN NATURAL WATERS. ALUMINIUM IN SPRING-WATERS. Continued. Spring. Analyst. Page. Aluminium Sulphate per U. S. Gallon. Alumina Gallon. Michigan. Clark's Riverside Mineral Springs S P Duffield 286 Grains. Grains. 13 41 Eastman's Springs, King David 286 1 1 Eastman's Springs, Bimini . . 287 O 3 Eastman's Springs, Golden Fountain 288 OI Owosso Mineral Water St. Clair Mineral Spring S. P. Duffield 206 830 oo Minesota. Indian Medical Spring C. W. Drew 200 03 White Mineral Spring W. A. Noyes 2QO Mississippi. Brown's Wells, Spring No. i. Brown's Wells, Spring No. 2. Castilian Mineral Spring, No i J .R. Chilton G. Little E W Hilgard 302 302 8. ii b b Missouri. B B. Mineral Water P Schweitzer 18 31 Blue Lick Springs P Schweitzer 3 IO b Blue Lick Springs 311 IO 2 ? 0.23 Excelsior Springs 312 Nevada. Walley's Hot Springs J. W. Phillips 32 "? .02 New Hampshire. j Jackson, also ) 327 b Londonderry Lithia Spring. . New Mexico. Las Vegas Hot Spring, No. 6 "j Richards J H. Halvorson W. S. Hains 328 5-05 .IO New York. Geneva Lithia Water Deer Lick Spring A. A. Cunningham C F Chandler 350 3 ^4. 8-75 North Carolina. Thompson's Bromine- ar- senic Spring H Froehling 374. c a With silica. b. Amount not given. Qualitative analyses. c. Contains .12 grain aluminium phosphate per U. S. gallon. ALUMINIUM IN NATURAL WATERS. 6 7 ALUMINIUM IN SPRING-WATERS. Continued. Spring. Analyst. Page. Aluminium Sulphate per U. S. Gallon. Alumina ifs. Gallon. North Carolina Hot Springs . Park's Springs . . . j Chandler and 1 Pellew A. R. Ledoux V. G. Bloede V. G. Bloede F. A. Genth C. M. Cresson W. A. Middleton? C. B. Gibson? C. B. Gibson? J. W. Slocum /. T. Anderson . M. Safford and } J. C. Wharton W. H. Johnson E. Everhart E. Everhart A. Meacham S. F. Baird E. T. Fristoe H. Froehling 376 378 400 400 406 409 416 430 43 1 435 444 446 449 45 2 45 2 460 461 476 480 482 485 489 497 Grains. Grains. .04 3-5 . II .09 . I2& C .27 .02 30 . 12 be 25 .166 d e f Pennsylvania. Bedford Magnesia Spring. . . Bedford Bowling Alley Spring Gaylord & Gulick Mineral Springs . . 6.580 Minnequa Springs Tuscarora Lithia Spring. . . . South Dakota. South Dakota Hot Springs, Mammoth Mineral Spring . Lakatah Springs Tennessee. Dixie Mineral Water Red Boiling Springs, No. 2 . . Upper Red Boiling Spring . . Texas. Burdett Mineral Wells Overall Mineral Well No. i. . Overall Mineral Well No. 2 . Utah. Midway Warm Springs Utah Hot Springs IS 81.71 4.99 .56 Virginia. Harris An ti dyspeptic and Tonic Springs No i Blue Ridge Springs . . Cold Sulphur Springs 2 .46 Crocket's Arsenic - Lithia Springs H. Froehling M. B. Hardin W. H. Taylor Glenola (Wayland) Spring . . Hunter's Pulaski Alum Springs 1 6 .40 a. Practically the same analyses as quoted by Peale (U. S. Geological Survey Bulletin 32, page 49) for Blassburg (Pa.) springs. b. The value given refers to aluminium. c. Qualitative analyses. Amount not reported. d. Contains .02 grain aluminium phosphate and .15 grain aluminium silicate per U. S. gallon. e. Contains trace of aluminium phosphate and .12 grains aluminium silicate per U. S. gallon. f. Contains .04 grain aluminium phosphate and .20 grain aluminium silicate per U. S. gallon. 68 ALUMINIUM IN NATURAL WATERS. ALUMINIUM IN SPRING-WATERS. Continued. Spring. Analyst. Page. Aluminium Sulphate per U. S. Gallon. Alumina per US. Gallon. Iron Lithia Springs H Froehling 4-07 Grains. 8 CK Grains. a Massanetta Springs J W Mallet 4-00 O I "\ Milboro Sulphur Spring Roanoke Red Sulphur Cha- lybeate Spring G. B. M. Zerr H Froehling 500 r 06 b o ? .26 c West Virginia. Hart Well S C Wells r ? i W d Wisconsin. Allouez Mineral Water W. W. Daniels cor 17 Fort Crawford Mineral Water G Bode r -2 7 66 Wyoming. Fountain Geyser, Yellow- stone National Park r c 2 06^ a. With . 1 1 grain aluminium phosphate per U. S. gallon in addition. b. With trace of aluminium phosphate in addition. c. With .02 grain aluminium phosphate per U. S. gallon in addition. d. Contains .03 grain aluminium phosphate and .09 grain aluminium and iron car- "bonate per J. S. gallon. See also analyses quoted by Peale, U. S. Geological Survey Bulletin 32, page 73. e. Chemical combinations calculated by E. E. Smith from analytical data. Dambergis, A. K. (Ber. Dent. Chem. Gesellsch., 20, p. 3328; in Jour. Chem. Soc. London, 54 (1888), II, p. 238), in the water of one of the sulphur springs of the peninsula of Methana on the east side of the Chelona range near the village of Wromolimni, reports 0.019 parts A1 2 O 3 per 10,000. Dambergis (Ber. Deut. Chem. Gesellsch., 19, p. 2538; Jour. Chem. Soc. London, 52 (1887), II, p. 23) reports 0.0200 alumina in water from ^Egina Springs and 0.06000 in water from Andros, grams per 10,000 cc. in both cases. Davis, R. H. (Jour. Chem. Soc. London, 39, p. 19; Jahresb. Chem., 1881, p. 1449), notes 12.78 gms. A1 2 O 3 per 10,000 cc. in the Harrowgate, England, "Old Alum Well." Darton, N. H. (U. S. Geological Survey Bui. 138), in his report on artesian well prospects on the Atlantic coastal plain region, quotes a number of analyses of water in which iron and alumina are reported together. ALUMINIUM IN NATURAL WATERS. 69 De Luca (Compt. Rend. Acad. Sci. Paris, 67, p. 909; Inst. 1868, p. 354; Jahresb. Chem. Will., 1868, p. 1040) reports traces of alumina in the "Solfatare" of Puzzuoli. De Luca, S. (Compt. Rend. Acad. Sci. Paris, 70, p. 408; Jour. Pharm., 4thser., 12, p. 33; Inst. 1870, p. 49; Chem. Centbl., 1870, p. 1 80; Chem. News, 21, p. 119; Jahresb. Chem., Naumann, 1870, p. 1389), reports 0.335 gm. A1 2 O 3 per 1000 cc. in the "Solfatare" water from Pozzuoli. De Negri, A. and E. (Gaz. Chim. Ital., 8 (1878), p. 120; Jour. Chem. Soc. London (1878), II, p. 715), note 0.000417 gm. aluminium phosphate per liter in mineral water from Casteggio, Italy. Devarda, A. (Chem. Centbl., 1891, II, p. 365; Jahresb. Chem., 1891, p. 2619), in mineral water from Costalta (Southern Tyrol), notes 0.01614 gm. Al 2 O 3 .3SiO 2 per 1000 cc. Deville (Ann. Chim. Pharm., 3d ser., 23, p. 32 ; Arch. Pharm., 2d ser., 55, p. 301; Jahresb. Chem., 1847-48, p. 996) analyzed a number of waters, finding alumina as follows (grams per 100,000 cc.): Seine River at Bercy, 0.0005; Rhine at Stras- burg, 0.0025; Loire at Orleans, 0.0071; Rhone at Geneva, 0.0039; Doubs at Rivotte, 0.0021; Mouillere spring- water, 0.0043; Billecul Spring, 0.0043 ; Arcier Spring, 0.0090; Bregille Spring at Besan9on, 0.0065; Suzon Spring at Dijon, o.ooio; Arcueil at Paris, 0.0053; well in the Grand Rue, 0.0094; well Rue de la Prefecture, 0.0062; and at the Facultd des Sciences at BesanQon, 0.0039. Dewar, J. (Chem. News, 24, p. 171; Jour. Chem. Soc. London, 25 (1872), p. 60), found 1.8 grains A1 2 O 3 per gallon in the acidulous chalybeate water from Melrose. Dietrich, H. (Min. Petr. Mitth., 2d ser., 3, p. 439; Jahresb. Chem., 1880, p. 1527), reports 0.005, 0.006, and 0.005 m - A1 2 O 3 per 10,000 gms., respectively, in three mineral springs at Krynica, Austria-Hungary. Dietrich, H. (Jahrb. K. K. Geol. Reichsanst., 43 (1893), p. 275; Jour. Chem. Soc. London, 70 (1896), II, p. 435), found 0.00335 A1,O 3 per 1000 parts in the water of the Klebelsberg Spring, Ischl, Austria. Dormoy (Ann. Min., 6th ser., 12, p. 461 ; Jahrb. Chem. Will.. 1867, p. 1040) reports alumina with iron oxid or iron and 70 ALUMINIUM IN NATURAL WATERS. manganese oxid in fourteen waters from Luxeuil, the amount ranging from 0.00157 to 0.01486 gm. per liter. Drown, T. M. (State Board Health Mass. Rpt., 24 (1892), p. 345), reported analyses of a number of waters from Massa- chusetts. The data regarding alumina follow: ALUMINIUM IN MASSACHUSETTS WATERS. Kind of Water. Alumina. Parts per 100,000. Mansfield, well 0.0173 Framingham, Spring northeast of sewage fields 0444 Stoughton, well 047 5 Everett, Spring 0325 Maiden, tubular wells -0125 Framingham, Spring northwest of sewage field .0250 Hyde Park, Neponset River .0062 Hyde Park, tubular wells near river . 0440 Hyde Park, starch-factory well near river 0175 Woburn, Horn Pond 0409 Woburn, filter-gallery 0143 Wayland, reservoir .0360 Wayland, filter-gallery -475 Westborough, Insane Hospital tubular wells - 02 5o Reading, filter-gallery .0493 Bradford, Well No. 7 0250 Bradford, Well No. 12 oioo Marblehead Water Co., Swampscott, large wells and tubular wells 0125 Marblehead, town supply, large well and tubular wells .0110 Lawrence, sewage filtered through filter-paper -385 Lawrence, effluent from intermittent filtration of sewage. Tank No. 4 0266 Lawrence, effluent from intermittent filtration of sewage. Tank No. 9 0457 Du Menil (Arch. Pharm., 2d ser., 69 (1852), p. i; Pharrru Centbl., 1852, p. 229; Jahresb. Chem., 1852, p. 754) found 0.500 grain alumina (with silica) per 3 pounds in sulphur- water from Seebruch near Vlotho. Du Ponteil (Ann. Chem. Pharm., 96, p. 193: Jour. Prakt, Chem., 67, p. 249; Chem. 'Centbl., 1856, p. 4: Ann. Chim. Phys., 3d ser., 46, p. 233; Jahresb. Chem., 1855, p. 831) found 0.3546 A1 2 O 3 -3SO 3 per 100 parts in the clear yellow very acid water of a hot lake on the volcanic White Island, Plenty Bay, New Zealand. ALUMINIUM IN NATURAL WATERS. 71 Eakins, L. G. (U. S. Geol. Survey Bui. 60, p. 172), found in water from a zooo-foot well in Lebanon, Missouri, 0.0032 gm. A1 2 O 3 per liter. Effenberger, A. (Wiener Akad. Ber. 51, 2. Abt., p. 252; Chem. CentbL, 1865, p. 848; Jahresber. Chem. Will... 1865, p. 934), notes per 10,000 parts, 0.006 part alumina in the medicinal springs at Mullaken in Upper Austria. Egger, E. (Chem. CentbL, 1881, p. 664; Jahresb. Chem., 1 88 1, p. 1443), reports an analysis of the Adelheidquelle at Heilbrunn, Germany. This water contained o.ooio gm. A1 2 O 3 per 1000 cc. Egger, E. (Chem. CentbL, 1882, p. 187; Jahresb. Chem., 1882, p. 1629), in a sulphur spring at Seon, Germany, reports 0.0018 gm. aluminium phosphate per 1000 cc. Emerson, B. K. (U. S. Geol. Survey Mon. 29, p. 750), quotes an analysis made by S. D. Hayes of the water of Mount Mineral Spring, Shutesbury, Massachusetts. A trace of alumina is reported. Emerson, B. K. (U. S. Geol. Survey Bui. 159, p. 91), reports 12.80 A1 2 O 3 parts per 1,000,000 in water from an artesian well in Dalton, Massachusetts. Emmons, S. F. (U. S. Geol. Survey Rpt., 17 (1895-96), pt. II, p. 411), in an article on the mines of Custer County, Colorado, reports a number of analyses by Hillebrant. Vadose water from the Geyser mine, 5oo-foot level, contained 0.8 A1 2 O 3 -P 2 O 5 parts per 1,000,000 (p. 461); deep water from the Geyser mine, 20oo-foot level, 1.06 A1 2 O 3 parts per 1,000,000 (p. 462). These values refer to the theoretical composition of the water before sediment was deposited. Essner, J. C. (Bui. Soc. Chim., 3d ser., 6, p. 148; Jahresb. Chem.. 1891, p. 2615), reports 0.240 gm. aluminium sulphate ( + i8H 2 O) per 1000 cc. in a subterranean water from the neigh- borhood of Port Vendres. Essner, J. C. (Bui. Soc. Chim., 3d ser., 7, p. 480; Jahresb. Chem., 1892, p. 2688). reports 0.0240 gm. (?) A1 ? O 3 per 1000 cc. in water from the iron sulphur spring at Roufaque. Fehling (Wiirttemberg. Naturwissensch. Jahreshefte, 13, p. 113, Jahresb. Chem., 1857, p. 720) found traces of alumina ?2 ALUMINIUM IN NATURAL WATERS. in the following artesian mineral water from the Stuttgart bath near Berg: Haupt-Trinkquelle and Westliche Quelle. Fehling (Wurttemberg. Naturw. Jahreshefte, 16, pp. 106, 129; Neues Jahrb. Pharm., 14, pp. 286, 295; Jahresb. Chem., 1860, pp. 833, 834) reports alumina as follows (grams per 100,000) in Wurttemberg mineral waters: Wildbad Warm Springs; Trinkquelle No. 10, Trinkhalle, 0.055; Quelle No. 19, Katherienbad, 0.059; mixture of water from ten springs, 0.070; Teinach mineral springs, Hirschquelle, 0.126; Bachquelle, trace ; and Dintenquelle, 0.071. Fehling, H. (Wurttemb. Naturw. Jahresb., 22, pp. 129, 147, 159; Jahresb. Chem. Will., 1867, p. 1035), notes an average of 0.055 parts of alumina per 100,000 in waters from Wildbad; 0.038 in water from Liebenzell; traces in Bachquelle from Teinach, and 0.126 in Hirschquelle from Teinach. Feliciani, G. (Gaz. Chim. Ital., 26 (1896), I, p. 281; Jour. Chem. Soc. London, 70 (1896), II, p. 615), notes a trace of alumina in the water of the acid spring at Ponte Molle near Rome. Fellenberg reports (Untersuchung d. Schwefelwasser d. Gurnigelbades, Bern, 1849; Jahresber. Chem. Will., 1850, p. 623) 0.0051 part aluminium silicate per 10,000 gms. in one water analyzed, designated No. A. Further, 0.08 alumina and iron oxid in another, designated No. B. The author also analyzed the water from two other sulphur springs from the same neighborhood. No aluminium was reported in either. In the sediment of the Stockquelle (1. c., p. 624) he found 14.47 P er cent alumina (with calcium phosphate). The Stockquelle water was one of those mentioned which contained no alumina. Ferstl (Jahrb. K. K. Geol. Reichsanstalt, 1853, No. 4, p. 683; Jahresb. Chem., 1853, p. 712) reports in the Luhatschowitz (Austria) mineral water, Vincenzbrunnen, Amandbrunnen, Johannisbrunnen, and Luisenquelle, aluminium phosphate (parts per 1000) as follows: 0.0047, 0.0048, 0.0041, and 0.0086, respectively. Figuier and Mialhe (Jour. Pharm., 3d ser., 13, p. 401; Jour. Chim. Med., 3d ser., 4, p. 635; Pharm. Centbl., 1848, p. 662; Jahresb. Chem., 1847-48, p. 1005) note a trace of alumina in Niederbronn (Alsace) and alumina (grams per 1000 cc.) ALUMINIUM IN NATURAL WATERS. 73 as follows in mineral water from Bourbonne: Source de la Place, 0.030; Source de 1'inte'rieur de 1'etablissement, 0.029. They also note (Jour. Pharm., 3d ser., n, p. 338; Jour. Prakt. Chem., 42, p. 465; Pharm. Centbl., 1847, p. 431; Jahresb. Chem., 1847-48, p. 1006) a trace of aluminium in mineral water from Rieumajou near Salvetat, Dept. de I'Hdrault. Filhol (Jour. Pharm., 3d ser., 20, p. 81; Jahresb. Chem., 1851, p. 664) reports aluminium silicate (gms. per 1000 cc.) in Bagtteres-de-Luchon springs as follows: Bayen, a trace; Azemar, 0.0237; Richard (upper spring), 0.0292; Grotte supe- rieure, 0.0109; Blanche, o.oioi ; Ferras (upper spring No. 2), trace; Pre No. i and Bordeu No. 4, each 0.0073; Grotte infe- rieure, 0.0141, and La Reine, 0.0274. Ferras also contained 0.0022 gm. alumina per 1000 cc., and La Reine a trace. Filippuzzi (Wiener. Acad. Ber. 21, p. 561; Chem. Centbl., 1856, p. 937; Jahresb. Chem., 1856, p. 773) reports 0.01927 aluminium phosphate and 0.36004 aluminium sulphate per 10,000 parts in mineral water from Valdagno, Italy. Finckh, C. (Neue. Jahrb. Pharm., 34, p. 13; Chem. Centbl., 1870, p. 615; Jahresb. Chem. Naumann, 1870, p. 1382), notes traces of aluminium in Ochsenhausen mineral water from Bieberach, Germany. Fluckiger, F. A. (Mittheil. Naturf. Gesellsch. Bern, 1862, p. 17; Arch. Pharm., 2d ser., in (1862), p. in ; Vierteljahressch. Prakt. Pharm., n, p. 342; Jahresb. Chem., 1862, p. 820), analyzed a sample of acid water taken by Stohr and Zollinger in 1858 at the first waterfall of the brook Sungi Pa'it flowing from the lake in the crater of Idjen volcano in Java. It con- tained per 100 gms. 0.150 A1 2 O 3 . Folberth (Verhandl. und Mittheil. Siebenburg. Vereins Naturwissensch., 1855, No. 7; Jahresb. Chem., 1855, p. 844) reports 0.0222 basic aluminium phosphate per 1000 parts in the saline water from the Felsenquelle near Bassen, Hungary. Folberth, F. (Verhandl. u. Mittheil. Siebenburg. Vereins Naturw. Hermannstadt, n, p. 78; Jahresb. Chem., "1861, p. 1102), notes A1 2 O 3 (grams per 10,000) as follows in mineral water: Pokolsdr, 0.142, and Czifra-viz, 0.402. Fresenius (Untersuchungen d. Mineralwasser d. Herzog- thums Nassau, I, Wiesbaden, 1850; Jahresb. Chem., 1850, OF THE 74 ALUMINIUM IN NATURAL WATERS. p. 622) notes 0.0051 gm. aluminium silicate per 10,000 gms. in the Wiesbaden Kochbrunnen water. Fresenius (Jahrb. Vereins. Naturk. Herzogthum Nassau, 7, pt. p. 145; Untersuchungen der Mineralwasser des Herzog- thums Nassau, II, Wiesbaden, 1851; see also Ann. Chem. Pharm., 82, p. 249; Jahresb. Chem., 1851, p. 652) examined the mineral waters of Ems, reporting per 1000 parts aluminium phosphate as follows : Kesselbrunnen, 0.00125 part; Krahnchen, 0.00042 part; Ftirstenbrunnen, 0.00044 part; Neue Quelle, 0.00142 part. Fresenius (Chem. Unters. Mineralwasser. Herzogth. Nassau, III, Ann. Chem. Pharm., 83, p. 252; Pharm. Centbl., 1853, p. 45; Jahresb. Chem., 1852, p. 753) notes a trace of alumina in the warmest Schlangenbad mineral water. Fresenius (Jour. Prakt. Chem., 58, p. 156; Arch. Pharm., 2d ser., 75, p. 301; Pharm. Centbl., 1853, p. 405; Jahresb. Chem., 1853, p. 709) in the Bernhard spring and the Johann- Georgen spring at Krankenheil-Tolz, Bavaria, found 0.002034 and 0.002782 gm. aluminium silicate per 1000 gms. respect- ively. Fresenius (Jahrb. Ver. Naturk. Herzogthums Nassau, No. ii ; Jour. Prakt. Chem., 70, p. i; Neue. Jahrb. Pharm., 7, p. 7; Chem. Centbl., 1857, p. 49; Jahresb. Chem., 1856, p. 770) found 0.000133 gm. aluminium phosphate per 1000 gms. in water from the sulphur spring at Weilbach, Nassau, Germany. Fresenius (Jour. Prakt. Chem., 72, p. i; Chem. Centbl., 1857, p. 913; Jahresb. Chem., 1857, p. 720) notes a trace of alumina in the mineral spring at Geilnau in Nassau, Germany. Fresenius, R. (Jour. Prakt. Chem., 98, p. 321; Jahresb. Chem. Will., 1866, p. 989), reports 0.000254 aluminium phos- phate per 1000 parts in the potable spring-water (Trinkquelle) of Driburg and 0.000335 aluminium phosphate in the Herster mineral spring near the same place. Fresenius, R. (Jour. Prakt. Chem., 95, p. 151 ; Chem. Centbl., 1865, p. 728; Vierteljahresschr. Prakt. Pharm., 15, p. 208; Jariresber. Chem. Will., 1865, p. 929), notes aluminium phos- phate per 1000 parts in three springs at Pyrmont as follows: Stahlbrunnen, 0.000084; Brodelbrunnen, 0.000295; and Klos- ALUMINIUM IN NATURAL WATERS. 7$ teralleequelle, 0.000091. The water of the first is used for drinking, the second for bathing. Fresenius, R. (Jour. Prakt. Chem., 97, p. i; Chem. Centbl., 1866, p. 335; Jahresb. Chem. Will., 1866, p. 990), reports 0.000102 part aluminium phosphate per 1000 in Felsenquelle No. 2 at Ems (Bad Ems). Fresenius, R. (Jahrb. nassau. Verein Naturkunde, pt. 19, 20 (1864), pp. 453. 488; Jour. Prakt. Chem., 103, pp. 321, 425; Chem. Centbl, 1868, pp. 703, 800; Jahrb. Min., 1868, p. 629; Jahrb. Chem. Will., 1867, p. 1034), reports 0.000430 aluminium phosphate per 1000 parts in a mineral water from Niederselters. Fresenius, R. (Jour. Prakt. Chem., 106, pp. 193, 206; Chem. News, 20, p. 213; Jahresb. Chem. Will., 1869, p. 1281), found in Tonnisteiner Heilbrunnen, Tonnisteiner Stahlbrunnen, and Lamscheider Mineralbrunnen, 0.00013, 0.00045, and 0.000460 part A1 2 O 3 P 2 (X per 1000 respectively. In the latter 0.000034 part alumina united with silica is also reported. Fresenius, R. (Jahrbiicher nassau. Ver. Naturkunde, 25 and 26, pp. 347, 361; Jahresb. Chem., 1871, p. 1226), notes 0.000134 part aluminium phosphate per 1000 in Victoria and 0.000120 part in Romerquelle water from Ems. Fresenius, R. (Jour. Prakt. Chem., 2d ser., 9, p. 368; Jour. Chem. Soc. London, 27 (1874), p. 968), notes 0.000193 part aluminium phosphate per 1000 in water from the warm mineral spring in the bath-house of the Royal William Medical Estab- lishment at Wiesbaden. Fresenius, R. (Jour. Prakt. Chem., 2d ser., 6, p. 53; Jahresb. Chem. Naumann, 1872, p. 1181), reports new analyses of the mineral springs at Ems. These were Kranchen, Ftirsten- brunnen, Kesselbrunnen, and Neue Badequelle. They con- tained respectively, per 1000 parts, o. 000116, 0.000117,0.000200, and 0.000209 part aluminium phosphate. Fresenius, R. (Jour. Prakt. Chem., 2d ser., 7, p. 191 ; Jahresb. Chem. Naumann, 1873, p. 1238), notes 0.000021 part aluminium phosphate per i ooo parts in Carlsquelle water from Bad Helmstedt . Fresenius, R. (Jour. Prakt. Chem., 2d ser., 9, p. 368; Jahresb. Chem., 1874, p. 1325), reports 0.000193 part aluminium phos- phate per 1000 parts in the mineral water of Wilhelmsheilanstalt, Wiesbaden. 76 ALUMINIUM IN NATURAL WATERS. Fresenius, R. (Jour. Prakt. Chem., 2dser., 25, p. 310; Jahresb. Chem., 1882, p. 1628; Jour. Chem. Soc. London, 40 (1882), p. 1178), notes traces of aluminium in the Oberbrunnen at Salzbrunn, Germany. In this same water Valentiner in 1866 noted 0.0005 g m - alumina and phosphoric acid per 1000. Fresenius, R. (Jour. Prakt. Chem., 2d ser., 45, p. 287; Jah- resb. Chem., 1892, p. 2684; Jour. Chem. Soc. London, 62 (1892), p. 796), reports per 1000 gms. in Julianenbrunnen and Georgen- brunnen water from Bad Eilsen 0.000126 and 0.000136 alumina respectively, in addition to 0.000155 an d 0.000060 aluminium phosphate. Fresenius, C. R. (Jahrb. nassau. Ver., 46 (1893), p. i; Jour. Chem. Soc. London, 70 (1896), II, p. 315), notes a trace of alumina in the water of the Victoria Spring at Oberlahnstein. Fresenius, H. (Jour. Prakt. Chem., 2d ser., 35, p. 237; Jah- resb. Chem., 1887, p. 2532), found 0.000334 gm. aluminium phosphate and 0.000401 gm. aluminium silicate per 1000 gms. Schutzenhofquelle water, Wiesbaden, Germany. Fresenius, H. (Jahrb. nassau. Ver. Naturk., 51 (1898), p. i; abs. Jour. Chem. Soc. London, 76 (1899), II, p. 114), finds in water from a new boring at Selters near Weilburg on the Lahn a trace of alumina. Garrigau (Compt. Rend. Acad. Sci. Paris, 84, p. 963; Jah- resb. Chem., 1877, p. 1387) notes 0.0096 part A1 2 O 3 per 1000 in the Cliff Spring at Saint- Nectaire le Haut, France. Genth (Keller and Tiedemann's Nord. Amer. Monats- ber., 1852, June, p. 246; Pharm. Centbl., 1852, p. 588; Jahresb. Chem., 1852, p. 758) notes a trace of alumina in mineral water from Bristol near Philadelphia, Pennsylvania. Giles (Pharm. Jour. Trans., 7, p. 75; Jahresb. Chem., 1847 48, p. 998) notes 0.260 gm. alumina per 10,000 gms. in spring- water from Wolverton. Gintl, W. F. (Jour. Prakt. Pharm., 2d ser., 20, p. 356; Jah- resb. Chem., 1879, p. 1264), in Ferdinand Spring, Marienbad, Bohemia, reports 0.06334 gm. basic aluminium phosphate per 10,000 gms. Gintl, W. F. (Jour. Prakt. Chem., 2d ser., 24, p. 25; Jahresb. Chem., 1881, p. 1445), notes 0.05256 A1 2 P 2 O 8 per 10,000 parts in Ambrosius water from Marienbad, Bohemia. ALUMINIUM IN NATURAL WATERS. 77 Gintl, W. F. (Separate; abstracted in Jahresb. Chem., 1882, p. 1632), notes 0.0744 part basic aluminium phosphate in the West spring and 0.1019 part in the East spring at Langen- bruck near Franzensbad, Austria-Hungary. Girardin (Jour. Chim. Med., 3d ser., 4, p. 643; Jour. Pharm., 3d ser., 15, p. 113; Jahresb. Chem., 1847-48, p. 1006) found a trace of aluminium sulphate in St. Paul spring-water from Rouen. Glasel, E. (Jahrb. Geol. Reichsanst., 19, p. 295; Chem. News, 20, p. 190; Jahresb. Chem. Will., 1869, p. 1290), reports 0.0028 gm. aluminium per 1000 in mineral water from Rajec-Toplitz. Glaser, M., and W. Kalmann (Ber. Deutsch. Chem. Gesellsch., 21 (1637); Jour. Chem. Soc. London, 54 (1888), p. 796), in the Roncegno (South Tyrol) water, report 0.4343 gm. A1 2 O 3 per liter. Godeffroy, R. (Sep. from Ztschr. Allgm. Oesterr. Apothe- kervereins; Jahresb. Chem., 1882, p. 1623), found in water from the middle of Gmunden Lake o.ioo part A1 2 O 3 per 100,000. Gooch, F. A., and J. E. Whitfield (U. S. Geol. Survey Bui. 47 1 PP- 36-81, and table facing page 82) report, in analyses of waters of the Yellowstone National Park, the following, the quantities in every case being grams per kilogram of water. In every case the author gives the calculated amount of the aluminium compound present, as well as the amount of alumina determined : Cleopatra Spring, 0.0049 Fe.Al calculated = 0.0093 A1 2 O 3 ; Hot River, 0.0051 Fe.Al = 0.009 7 A1 2 O 3 ; Gardiner River, sample taken Oct. 12, 1883, above Hot River, 0.0042 Fe.Al = 0.0079 A1 2 O 3 ; Gardiner River, sample taken Sept. 26, 1884, at Mammoth Hot Springs, o.ooio Fe.Al = 0.0019 A1 2 O 3 ; Water- supply at Mammoth Hot Springs, o.oon Fe.Al =0.0021 A1 2 O 3 ; Soda Spring, 0.0004 Al = 0.0008 A1 2 O 3 ; Fearless Geyser, 0.0002 Al=* 0.0004 A1 2 O 3 ; Pearl Geyser, 0.0031 Al= 0.0059 A1 2 O 3 ; Constant Geyser, 0.0048=0.0304 A1 2 (SO 4 ) 3 ; Coral Spring, sample taken Aug. 20, 1884, 0.0029 Al = 0.0143 A1 2 C1 6 ; Coral Spring, sample taken Oct. n, 1886, 0.0077 Al = o.oi39 A1 2 O 3 ; Echinus Spring, 0.0027 Al = 0.0171 A1 2 (SO 4 ) 3 ; Schlammkessel, 0.0081 Fe.Al = o.o5i3 Al 2 (SO 4 ) 3 ".Fe 2 (SO 4 ) 3 ; Fountain Geyser, ?8 ALUMINIUM IN NATURAL WATERS. 0.0057 Al = o.oio8 A1 2 O 3 ; Great Fountain Geyser, 0.0021 Al = 0.0040 A1 2 O 3 ; Hygeia Spring, 0.0036 Al = 0.0068 A1 3 O 3 ; Firehole River, 0.0031 Al = 0.0059 A1 2 O 3 ; Excelsior Geyser, 0.0012 Al = 0.0023 Al^Ogj Old Faithful Geyser, 0.0009 Al = 0.0017 A1 2 O 3 ; Splendid Geyser, sample taken Sept. 10, 1885, 0.0027 Al =0.0051 A1 2 O 3 ; Splendid Geyser, sample taken Aug. 28, 1884, 0.0034 Al = 0.0064 A1 2 O 3 ; Giantess Geyser, 0.0049 Al = 0.0093 A1 2 O 3 ; Beehive Geyser, 0.0029 ^1 = 0.0055 A1 2 O 3 ; Grotto Geyser, 0.0036 Al = o.oo68 A1 2 O 3 ; Turban and Grand Geysers, 0.0032 Al = 0.0061 A1 2 O 3 ; Artemisia Geyser, 0.0079 Al = 0.0150 A1 2 O 3 ; Taurus Geyser, 0.0040 Al = 0.0075 A1 2 O 3 ; Asta Spring, 0.0059 Fe.Al = 0.0112 A1 2 O 3 ; Bench Spring, 0.0145 Fe.Al = 0.0066 A1 2 (SO 4 ) 3 + 0.0263 A1 2 O 3 ; Firehole River, 0.0029 Al = o.oo55 A1 2 O 3 ; Yellowstone Lake, 0.0021 Al = 0.0040 A1 2 O 3 ; Alum Creek, 0.0025 Al = o.oi58 A1 2 (SO 4 ) 3 ; Chrome Spring, 0.0043 Fe.Al=o.oo82 A1 2 O 3 ; Mush Pot Spring, 0.0045 Al= 0.0285 A1 2 (S0 4 ) 3 ; Devil's Ink Pot, 0.0037 Al = 0.0234 A1 2 (SO 4 ) 3 ; Soda Butte Spring, 0.0069 Fe.Al = o.oi3i A1 2 O 3 . Gorup-Besanez (Ann. Chem. Pharm., 79, p. 50; Pharm. Centbl., 1851, p. 718; Jahresb. Chem., 1851, p. 653) found alumina (unweighable amount) in mineral water from Stebin, Bavaria. Gossart (Jour. Pharm., 4th ser., u, p. 292; Chem. News, 21, p. 214; Jahresb. Chem. Naumann, 1870, p. 1389) notes traces of A1 2 O 3 in a sulphur spring near Meurchin, Pas-de-Calais. Gottl (Oester. Ztschr. Pharm., 1853, pp. 253, 266; Jahresb. Chem., 1853, p. 711) found 0.0040 gm. alumina per 1000 gms. in the Karlsbad Schlossbrunnen. Gb'ttl (Vierteljahressch. Prakt. Pharm., 4, p. 192; Arch. Pharm., 2d ser., 84, p. 179; Pharm. Centbl., 1855, p. 286; Jah- resb. Chem., 1855, p. 841) notes 0.022 alumina per 10,000 parts in Giesshubler water from the Rodisfort (Germany) acid spring. Gottl (Vierteljahressch. Prakt. Pharm., 5, p. 161; Jahresb. Chem., 1856, p. 772) notes 0.028 alumina per 1000 parts in the Karlsbad Sprudel water. Gottlieb (Wiener. Acad. Ber., 30, p. 191; Chem. Centbl.. 1858, p. 612; Jahresb. Chem., 1858, p. 796) notes 0.019 basic aluminium phosphate per 10,000 parts in Marienbrunnen water from Gabernegg, Austria-Hungary. ALUMINIUM IN NATURAL WATERS. 79 Gotfieb (Wiener. Akad. Ber., 56, 2. Abt., p. 836; Jour. Prakt. Chem., 102, p. 472; Jahresb. Chem. Will., 1867, p. 1038) reports 0.0147 aluminium phosphate per 10,000 parts in water from Emmaquelle at Gliechenberg in Steiermark. Gottlieb, J. (Wiener. Akad. Ber., 60, 2. Abt., pp. 349, 357; Jahresb. Chem. Will., 1869, p. 1287), found in "old" and "new" Johannes water, and Hauptquelle from Neuhaus (all in Steier- mark), 0.0233, 0.0481, and 0.0026 part aluminium phosphate per 10,000 respectively. Gottlieb, J. (Wiener Akad. Ber., 62 2. Abt., p. 780; Jahresb. Chem. Naumann, 1870, p. 1386), notes in the Konigsbrunnen from Kostreinitz in Steiermark 0.0213 P art aluminium phos- phate per 10,000. Graham, T., W. A. Miller, and A. W. Hofmann (Rpt. Govt. Commission on the Chemical Quality of the Supply of Water to the Metropolis, London, 1851; Quart Jour. Chem. Soc., 4, P- 375 J Jahresb. Chem., 1851, p. 656) note traces of alumina in water supplied by New River Water Co., East London Water Co., Kent Water Co., and Hampstead Water Co. In the second the alumina reported equals 0.47 grains per gallon with iron and phosphoric acid salts. The waters were not from the Thames. Thames water and five spring-waters from the Hindhead (Surrey) district, Farnham and Gravesend, were also found to contain alumina with iron and phosphate. Grandeau, L. (Ann. Chim. Phys., 3d ser., 60, p. 479; Jahresb. Chem., 1860, p. 839), reports 0.0408 alumina per 1000 cc. in mineral water from Pont-a-Mousson, Dept. Meurthe, France. Grange (Ann. Chim. Phys., 3d ser., 24, p. 496; Jahresb. Chem., 1847-48, p. 996) reports in the Isere water at Grenoble 0.0035 gm. alumina per 100,000 cc. Grange (Jahresber. Chem., 1850, p. 622) studied the water of the Iserethal. He regarded the earthy taste of some spring- water as due to alumina held in solution by CO 2 . Griffin, M. L. (unpublished data), found 0.718 gm. aluminium sulphate per liter in water from a spring running through the new engine-pit of the Boston and Maine Car-shops in Mechanics- ville, New York. von Gumbel, C. W. (Chem. Centbl., 1891, II. p. 566. Jahresb, 80 ALUMINIUM IN NATURAL WATERS. Chem., 1891, p. 2618), notes analyses by A. Schwagerof Plinius- quelle and Ostgothenquelle thermal water from Bormio and the Ortler region. The former contained 0.0137 gm. A1 2 O 3 per 1000 cc. ; the latter 0.0042 gm. Giinsberg, R. (Wiener. Acad. Ber., 43, 2. Abt., p. 197; Jahresb. Chem., 1861, p. 1103), reports 0.0012 gm. aluminium phosphate per 1000 gms. in Siegwasser from the Bronislaw spring at Truskawice, Galicia. Guyot, P. (Compt. Rend. Acad. Sci. Paris, 77, p. 1384; Jahresb. Chem. Naumann, 1873, p. 1242), notes o.oio gm. SiO 2 .Al 2 O 3 per liter in Saint-Thiebaut water from Nancy. Hamberg, N. P. (Jour. Prakt. Chem., 80, p. 385: Chem. Centbl., 1860, p. 955; Ztschr. Ges. Naturw., 17, p. 71; Jahresb. Chem., 1860, p. 842), reports aluminium sulphate (parts per 10,000) in the water of medicinal springs at Ronneby, Swe- den, as follows: Eckholzquelle, 15.038230, and Alte Quelle, 3.834603. Hardin, M. B. (Amer. Chemist, 4, p. 247, Arch. Pharm., 3dser., 5 (1874), p. 180; Jahresb. Chem. ; 1874, p. 1336), made analyses of four alum springs in Rockbndge County, Virginia, and reports 5-359 6l 7-3 8 5 6 > 7-53946, 12.41395. and 3.25892 gms. alumina per 1000 cc. The water was collected under different conditions as regards rainfall. The residue obtained by evap- orating the water contained 9.490 per cent alumina. von Hauer (Jahrb. K. K. Geol. Reichsanstalt, 1853, p. 154; Jahrsb. Chem., 1853, p. 712) found in mineral water from Rog- gendorff, Hungary, 0.033 parts aluminium sulphate per 1000 parts. von Hauer (Jahrb. K. K. Geol. Reichsanstalt, 1858, p. 165; Jahresb. Chem., 1858, p. 798) notes 0.0013 alumina per 1000 parts in the thermal sulphur- water from Warasdin-Toplitz, Croatia. von Hauer (Jahrb. K, K. Geol. Reichsanstalt, 1861, p. 57: Jahresb. Chem., 1861, p. TIOO) notes 0.023 grains alumina P er pound ( = 7680 grains) in acid water from Suliguli near Visco in Marmarosch. Hehner, O. (Chem. News, 38, p. 249; Jahresb. Chem., 1878. p 1 3 T 4) , in brown water from a spring 3 2 kilometers from Cape Town notes 525.19 parts A1 2 S 3 O 12 per 100,000. ALUMINIUM IN NATURAL WATERS. 8 1 Heller, F. (Wiener. Acad. Ber., 19, p. 363; Jahresb. Chem., 1856, p. 772), notes 0.030 alumina per 10,000 parts in water from the Franz Joseph Quelle at Fured on the Plattensee. Henry (Jour. Pharm., 3d ser., 13, p. 5; Pharm. Centbl., 1848, p. 264; Jahresb. Chem., 1847-48, p. 1007) reports aluminium silicate (grams per 1000 cc.) as follows: in Source Grande Grille, 0.230; Source nouvelle, 0.233; Source Pre Sale, 0.070 (Vichy); Source de 1'Hopital, 0.120, and Source du Puits at Cusset, 0.080. Henry, O. (Jour. Chim. Med., 3d ser., 6, p. 314; Jahresb. Chem., 1850, p. 628), notes 0.368 parts alumina per 1000 parts in the Fraysse mineral water from Cransac, Dept. Aveyron. Poumerede (Jahresb. Chem., 1850, p. 628) found in the same water 0.369 part alumina per 1000 parts. Henry (Jour. Pharm., 3d ser., 17, p. 161; Jahresb. Chem., 1850, p. 628) also notes aluminium sulphate and aluminium ammonium sulphate in Source-haute (Richard) and Source-basse (Richard) mineral water from Cransac. Henry, O. (Jour. Pharm., 3d ser., 19, p. 104; Jahresb. Chem., 1851, p. 663), notes aluminium silicate and lithium silicate in mineral water from Sail-les Chateaumorand as follows: Hamel or Saule, d'Urfe, Roman, Sulphur and Iron Sulphur springs: also alumina with calcium sulphate and silica in the Bellety (steel) spring from the same place. Henry, 0. (Jour. Pharm., 3d ser., 20, p. 161 ; Pharm. Centbl., 1851, p. 748; Jahresb. Chem., 1851, p. 664), reports alumina and silica (parts per 1000) as follows: in spring-water from Saint- Denis near Blois, Dept. Loire and Cher, Medicis, 0.007; Renaulme, 0.007; and Saint-Denis, 0.044. Henry, 0. (Jour. Pharm., 3d ser., 21, p. 401; Jahresb. Chem., 1852, p. 757), in mineral water from Saint-Honord, Dept. Nievre, notes 0.023 part aluminium silicate per 1000 parts. Henry, O. (Jour. Pharm., 3d ser., 30, pp. 172, 246; Jahresb. Chem., 1856, p. 774), reports 0.050 gm. alumina and silica per 1000 cc. in mineral water from Saxon, Canton Wallis, Switzerland. Henry, 0., Sr. according to Grasset (Compt. Rend. Acad, Sci. Paris, 46, p. 182; Inst., 1858, p. 37; Jahresb. Chem., 1858. p. 802), found 0.128 gm. alumina and silica per 1000 cc. in water from Bondonneau, Dept. Drome, France. 82 ALUMINIUM IN NATURAL WATERS. Henry, O., and L'He*ritier (Jour. Pharm., 3d ser., 28, pp. 333, 408; Jahresb. Chem., 1855, p. 834) found alumina (grams per 1000 cc.) in mineral water from Plombieres as follows: Source du Crucifix, 0.0120; Sources des Dames, o.oioo; Source de Sainte-Catherine, o.ono; Bain Romain, 0.0130; Bain tempere, o.ono; Source du Savonneuse, 0.01400; and Source ferru- gineuse de Bourdeille, 0.00750. Hessert, J. (Ann. Chem., 176, p. 241; Neue. Repert. Pharm., 24, p. 541 (see under J. Volhard) : Jahresb. Chem., 1875, p. 1302), reports 0.0024 part alumina per 1000 parts in sulphur- water from Spring Bir Keraui, after removal of the sediment which separated on standing. Including sediment there was 0.0236 alumina. Hidegh, C. (Wiener Akad. Ber., 53 (2. Abt.), p. 395; Jahresb. Chem. Will., 1866, p. 993), reports in the spring at Johannisbad near Vienna 0.008 part alumina (and P 2 O 5 ) per 10,000 parts. Hillebrand, W. F. (U. S. Geol. Survey Bui. 113, p. 50), found 2.5 parts A1 2 (SO 4 ) 3 per 1,000,000 in East Spring, and 3.2 in West Spring at Joplin, Missouri, both zinc-bearing springs. Hillebrand, W. F. (U. S. Geol. Survey Bui. 113, p. 114), found in water from Ojo Calient e, a thermal spring near Taos, N. M., 0.5 part A1 2 O 3 per million parts. Hoffmann, J. (Analysen der beiden Bohrquellen zu Hom- burg, Homburg, 1856; Neue Jahrb. Pharm., 7, p. 52; Chem. Centbl., 1856, p. 821; Jahresb. Chem., 1856, p. 770), notes traces of alumina in the water from two bored wells at Hom- burg, Germany. Hruschauer (Ann. Chem. Pharm., 63, p. 229; Jour. Prakt. Pharm., 42, p. 466; Pharm. Centbl., 1847, p. 829; Jour. Pharm., 3d ser., 13, p. 49; Jahresb. Chem., 1847-48, p. 1002) reports 0.163 ^ rn - basic aluminium phosphate per 10,000 gms. in Ko- streiniz (Steiermark) mineral water. Hiibener (Chem. Ztg., 14, p. 1410; Chem. Centbl., 1890. II, p. 846) notes 0.002500 gm. alumina (with a trace of phosphoric acid per liter in water from a bored well in Westerland. The well from which this water was obtained had been recently bored. The water contained a much larger propor- tion of iron than many of the longer-known steel-wells. Westerland is on the Island of Sylt, Prussia. ALUMINIUM IN NATURAL WATERS. 83 Huppert (Chem. Centbl., 1877, p. 137; Jour. Chem. Soc. London, 1878, II, p. 209) reported analyses of the water of the new spring and Josefsquelle at Bilin; they contained respectively 0.0056, and 0.0057 A1 2 O 3 .P 2 O 5 , presumably parts per 10,000. He quotes an analysis of the Josefsquelle water made in 1845 by Redtenbacher, reporting 0.084 A1 2 O 3 .P 2 O 5 . Hunt, T. S. (Silliman's Amer. Jour., 26. ser., 8, p. 364; Jahresb. Chem., 1849, p. 621), reports 0.4681 part alumina per 1000 parts in Tuscarora Sour spring-water from the neighborhood of Brantford, Canada. Hunt, T. S. (Silliman's Amer. Jour., 2d ser., n, p. 174; Jahresb. Chem., 1851, p. 669), reports a trace of alumina and phosphate in water from the "outer spring" at Varennes; a trace of alumina in the "inner spring" water from Varennes; 0.014500 part alumina per 1000 parts in St. Leon and 0.00500 in Caxton water; all mineral springs in Canada. Hunt, T. S. (Phil. Mag., 4th ser., 13, p. 239; Chem. Centbl., 1857, p. 683; Jahresb. Chem., 1857, p. 728), found a trace of alumina in Ottawa River water taken at St. Anne Lock, near Montreal, and St. Lawrence River water, taken on the south side of the Pointe-des-Cascades near Vaudreuil. Husemann, A. (Neue Jahrb. Pharm., 33, p. 197; Chem. Centbl., 1870, p. 392; Amer. Chemist, 2dser., i, p. 119; Jahresb. Chem., Naumann, 1870, p. 1383), notes traces of aluminium in the Belvedra Spring near Chur. Husemann, A. (Neue Jahrb. Pharm., 38, p. 257; Jahresb. Chem., Naumann, 1872, p. 1184), reports 0.0022, 0.0021, 0.0018, and 0.0018 part alumina per 10,000 parts in four samples of mineral water from Tarasp. Husemann, A. (Jahrb. Pharm., 39, p. 200, 315; Jahresb. Chem., Naumann, 1873, p. 1240), reports o.oon part alumina per 10,000 parts in Neue Belvedraquelle, and traces in three other springs, all near Chur, Switzerland. Husemann, A. (Arch. Pharm., 3d ser., 6, pp. 97, 395; 7, p. 204; Jahresb. Chem., 1875, p. 1291), reports respectively in the "old" and "new" St. Moritz (Switzerland) Eisen Sauerling, 0.00050 and 0.00030 part alumina per 10,000 parts. Three Tarasp (Lower Engadine) mineral springs contained per 10,000 parts respectively 0.0025, 0.0019, and 0.0021 part alumina. 84 ALUMINIUM IN NATURAL WATERS. Two Val Sinestra springs (Lower Engadine) contained per 10,000 parts respectively 0.0020 and 0.0021 part alumina. Jackson, D. D., says in unpublished data regarding the natural occurrence of aluminium sulphate in waters: "Many of our driven wells along the southern shore of Long Island contain aluminium sulphate, but in no case does an entire well- plant contain it. "Alum is noticeable in amount in individual wells at Oconee, Clear Stream, Wantagh, Merrick, and Matowa. One of the wells recently analyzed at Merrick contained 268 parts per million of aluminium sulphate. This is equivalent to 15.6 grains per gallon. In other words, the water would remove the color and impurities from fifteen to twenty times its volume of impure water. "This analysis was made after the water had been actively drawn upon for two weeks, and at this time the taste was strong of alum. During periods of rest the alum is considerably greater in amount. "At the same time the examination of the entire Merrick plant revealed the fact that no alum was present, but that the water was milky with aluminium hydrate which had been precipitated by the carbonate in the adjoining wells. The alkalinity of the entire supply from the plant was only 3 parts per million. This shows that the carbonate had been used up in the precipitation of the alum. "The driven wells at Oconee gave 2.0 parts per million of A1 2 O 3 , and those at Clear Stream gave 1.6 parts per million. This refers to the entire plant during active operation in each case." Janecek, G. (Chem. Centbl., 1887, p. 172; (Ausz.) Jahresb. Chem., 1887, p. 2535), reports 0.00272 gm. A1 2 O 3 per 1000 gms. in the Jamnicer-alkalisch-muriatischen Sauerlings water. John, C. v. (Verhandl. Geol. Reichsanst., 1876, p. 114; Jah- resb. Chem., 1876, p. 1302), notes 0.1490 part A1 2 O 3 per 10,000 parts in well-water from Locendol, Steiermark. John, C. v. (Jahrb. Geol. Reichsanst., 31, p. 509; Jahresb. Chem., 1881, p. 1447), reports in spring-water from Locendol, Austria-Hungary, 0.1490 part A1 2 O 3 per 10,000 parts. John, C. v. (Chem. Centbl., 1891, II, p. 881; Jahresb. ALUMINIUM IN NATURAL WATERS. &5 Chem., 1891, p. 2621), found 0.0139 gm. alumina per 10,000 gms. in Friedrichsquelle water from Zeidelweid, Bohemia. John, C. v. (Jahrb. Geol. Reichsanst. Wien, 48, 375; Chem. Centbl., 70 (1899), II, p. 1047), reported analyses of mineral waters from a number of localities in Eastern Bohemia. The data regarding A1 2 O 3 follow: ALUMINIUM IN SOME MINERAL WATERS FROM EASTERN BOHEMIA. Kind of Water. Dry Matter per Liter at i 80 C. A1 2 O 3 in Dry Matter. Lukorna Grams.* 62 .4400 Grams, o .0040 Micknovka 60 6400 OOQ3 Tavurka . . . 6 64^0 002 ^ Enema. 3 1002 .0040 Straschov ^ 0840 .0400 Bohdanec Kapelle i .8080 .0020 Bohdanec, St. George 3 .4720 .0050 * Probably grams per liter not stated in the abstract cited. John, C. v., and H. B. v. Foullon (Chem. Centbl., 1890, II, p. 772; Jahresb. Chem., 1890, p. 2657) report analyses of four potable springs at Luhatschowitz, namely, Vincenzbrunnen, Amandbrunnen, Johannbrunnen, and Louisenquelle. These contained respectively, 0.004, 0.005, 0.004, and o.ooi alumina (probably parts per 1000). John, C., and C. v. Hauer (Verh. Geol. Reichsanst., 1876, P- 35 5 i Jahresb. Chem., 1876, p. 1302) report 0.0415 part A1 2 O 3 per 10,000 parts in Ranigsdorf Sauerling. Johnstone, W. (Chem. News, 31, p. 15; Jahresb. Chem., 1875, p. 1300), reports 0.1970 gm. A1 2 S 3 O 12 per 1000 cc. in Hertfell Spring near Moffat, Scotland. Johnstone, W. (Chem. News, 39, p. 259; Jahresb. Chem., 1879, p. 1269), reports in St. Dunstan's Well, Melrose, Scotland, 0.019503 gm. aluminium phosphate per 1000 cc. Johnstone, J. W. (Analyst, 12, p. 90; Jour. Chem. Soc. Lon- don, 52 (1887), II, p. 1087), notes in Flitwick water, rising through a ferruginous peat-bed in Flitwick Moor, per 1000 parts, 0.0044 part alumina. 86 ALUMINIUM IN NATURAL WATERS. Jolles, A. (Ztschr. Nahrungsmittel u. Hyg., 1892, p. 373; Jahresb. Chem., 1892, p. 2684), found 0.064 gm. alumina per 10,000 gms. in water from the Kartner Romerquelle in Prevail near Gutenstein. Jones, W. Black (British Med. Jour., 1903, p. 1055), quotes from the Lancet, 1894, an analysis of Llangammarch mineral water, reporting 3.340 grain alumina and silica per gallon. Kachler, J. (Wiener. Akad. Ber. (2. Abt.), 70, p. 654; Jahresb. Chem., 1875, P- I2 96)> reports respectively 0.0743 and 0.0042 part alumina per 10,000 parts in two sour springs near Poschitz, Bohemia. Kalecsinszky, A. (Ungar. Naturw. Ber., i, p. 370; Jahresb. Chem., 1886, p. 2321), reports 0.0052 part H 6 A1 2 O 6 per 10,000 parts in iron-water from Rosenau, Comitat Gomor, Hungary. Kemper (Arch. Pharm., 2d ser., 108, p. 163; Jahresb. Chem., 1 86 1, p. 1096) found a trace of alumina in artesian water from Gosling's Garden at Osnabruck. Kenrick, E. B. (Geol. and Nat. Hist. Survey, Canada, Chemical Contributions, 1886, p. 13 T), reports "a very small quantity" of alumina in a qualitative analysis of water from Dougherty's so-called carbonic acid spring located in the mountains between Clinton and Carguiles, British Columbia. The total solid matter per 1000 parts in the filtered water was 1.442 parts. In the same publication (p. 14 T) the author reports a similar analysis of water from a spring at the foot-hills of Western Butte, Sweet Grass Hills, District of Alberta, Northwest Ter- ritory. The total solids in the filtered water amounted to 0.857 part per 1000 parts. According to a qualitative analysis it contained a "very small quantity" of alumina. Kersting (Ann. Chem. Pharm., 90, p. 158; Jour. Prakt. Chem., 63, p. 125; Pharm. Centbl., 1854, p. 589; Jahresb. Chem., 1854, p. 771), in a sulphur-spring water from Schoneck near Segewold, Russia, notes 0.0017 part alumina per 1000 parts. Knerr, E. B. (Trans. Kansas Acad. Sci., 15 (1895-96), p. 88), notes a trace of alumina in a spring- water from Atchison, reputed to possess medicinal virtues. In the water from a well two and a half miles north of Centralia he notes 3.7 parts alumina per 1,000,000. ALUMINIUM IN NATURAL WATERS. 8/ Kofler, L. (Vierteljahressch. Prakt. Pharm., 15, p. 161; Jahresb. Chem. Will., 1866, p. 992), reports in the Voralberg springs, Rothenbrunnen, Eisenquelle von Uebersaxen, Eisen- wasser des Bad Reuthe, Eisenwasser Bad Andelsbtich, Schwefelwasser Bades Hopfreben, and Quelle zu Raggal, 0.0322, 0.031, 0.0081, 0.0476, 0.0514, and 0.0107 grain A1 2 O 3 per pound respectively. Konya, S. (Wiener Akad. Ber., 61, 2. Abt., p. 7; Viertel- jahresb. Prakt. Pharm., 19, p. 373; Chem. Centbl., 1870, p. 132; Inst., 1870, p. 88; Jahresb. Chem., Naumann, 1870, p. 1387), notes 0.008 part alumina per 10,000 parts in the Bitterwasser from Weilutza near Jassy. Kosmann (Jour. Pharm., 3d ser., 17, p. 43; Jour. Prakt. Chem., 50, p. 49; Pharm. Centbl., 1850, p. 141; Jahresb. Chem., 1850, p. 627) notes a trace of alumina in mineral water from Niederbronn, Germany. Kyle, J. J. J. (Chem. News, 38, p. 28; Jahresb. Chem., 1878, p. 1295), reports in Rio de la Plata water taken 8 kilometers above Buenos Ayres 0.0060 part A1 2 O 3 per 1000 ccm., and in the Parana water 8 kilometers above its union with the La Plata 0.0030 part A1 2 O 3 per 1000 parts. Lahache, E. (Jour. Pharm. et. Chim., 6th ser., 9 (1899), p. 477), reports "alumina, silica, etc.," as follows, in a number of potable waters from new wells, and old wells recently cleaned, in the region of Tougourt-Ouargla in the Sahara: Tougourt, 0.080; Bled et Amax, 0.088; El Fetir, 0.043; H. Mes- saoud, 0.035; El-Hadjira, 0.068; H. Dahane, 0.058; H. Debiche et Strifigi, 0.034; Donionidi, 0.049; N'Gonca, 0.005; an d Ouargla, 0.008 gm. per liter. Lane, A. C. (U. S. Geol. Survey, Water-supply and Irriga- tion Papers, 31, pp. 18-93), * n a study of the mineral water of Lower Michigan, cites a number of analyses. The data relating to aluminium are quoted below.* In every case the values are parts per 1000 unless otherwise stated. In Detroit River water (p. 18) S. H. Douglas (Biennial Rpt. Mich. State Geologist, 1861, p. 204) reports 0.0105 A1 2 O 3 . The Dearborn Drug and Chemical Works, Chicago (p. 18), * Some of the analyses given were cited by Peale (U. S. Geol. Survey Bulletin 32, see p. 103); all such are omitted. 88 ALUMINIUM IN NATURAL WATERS. analyzed water from Muskegon Lake, Manistee Lake, Traverse Bay, and Detroit River, finding in the first o.ooi (FeAl) 2 O 3 , and in the others traces of (FeAl) 2 O 3 . In Lake Superior water (p. c6) W. F. Jackman (Proc. Mich. Pharm. Assoc., 5th year, p. no) found 0.90 part A1 2 O ? per 1,000,000 parts. In Shiawassee River water at Owasso, the Dearborn Drug and Chemical Works (p. 27) found o.ooi (AlFe) 2 O 3 and traces in Battle Creek city water, usually taken from Lake Goguac, Grand River water at Jackson, and water from the creek at Ann Arbor (Huron River?). G. A. Kirchmaier (p. 27) (An. Rpt. Saginaw Board Water Com., 1892, Sup., pp. 31-33) reports (AlFe) 2 O 3 as follows: Shiawassee River, 0.0061; Cass River, 0.0070; West Side Pumping Station, Saginaw, 0.007 \ East Side Pumping Station, 0.0611; and Tittabawassee River, 0.0843. J- E. Graves (p. 27) notes in Chippewa River water (Midland Water Supply) 0.0094 (AlFe) 2 O 3 . A number of waters from wells and springs in the uncon- solidated deposit (Pleistocene) follow (pp. 31-33). Welcome Island lithia water taken three miles north of Pontiac in the center of Lake Angelus, analyzed by J. E. Clark, 0.0014 A1 2 O 3 ; King David Spring, Benton Harbor, analyzed by W. S. Haines, 0.0020 A1 2 O 3 ; Nochemo Spring, Reed City, analyzed by R. Fischer and A. B. Prescott, o.ooi A1 2 O 3 ; and well, 18 feet deep, Ypsilanti, analyzed by Dearborn Drugand Chemical Co., trace A1 2 O 3 . In the wells included under the group "Miscellaneous Analyses" (p. 57) are the following: Owasso City supply- wells, analyzed by Dearborn Drug and Chemical Works, trace of A1 2 O 3 , and Hudson Zauberwasser, analyzed by A. B. Prescott, 0.00043 A1 2 O 3 . In water of the Midland Mineral Spring (p. 60), said to be 400 feet deep, 0.0247 A1 2 (P 2 O 5 ) 3 is reported by S. P. Duffield. The analysis is probably the same as that quoted by Peale (U. S. Geol. Survey Bui. 32, see p. 103). S. P. Duffield (p. 65) reports an analysis of Butterworth's Grand Rapids Magnetic Spring, 261-274 feet deep, with 0.007 A1 2 3 . ALUMINIUM IN NATURAL WATERS. 89 Chilton (p. 66) (Biennial Rpt. State Geologist, Michigan, 1860, pp. 171, 1 86) notes 0.245 Al 2 O 3 +SiO 2 in an East Saginaw well 649 feet deep. In the group entitled ' ' Water from Devonian or Silurian Limestones" (pp. 72-85) are the following: S. P. Duffield found in wells at Clark's Riverside Bath-house, Detroit, 0.230 A1 2 O 3 . J. H. Long noted 0.005 A1 2 O 3 in water from Excelsior Well, 1400 feet deep, Benton Harbor. In water from Coldwater Prescdtt notes 0.643 aluminium sulphates. In water from the St. Clair Spring, Oakland House Well, 1250 feet deep, S. P. Duffield reports 12.00 A1 2 O 3 , and also reports 0.421 A1 2 O 3 in the Mount Clemens Original Well, which has also been known as the Avery and Soolbad. T. Tonnele found 0.044 A1 2 O 3 in the water of the Mount Clemens Clemen- tine Well, 1060 feet deep. S. P. Duffield reports 0.601 A1 2 O 3 in the Mount Clemens Media Well. C. F. Chandler and C. E. Pellew (Geol. Survey Michigan, 5, pt. 2, p. 46) in Alma wells Nos. i, 2, and 3, report 5.0325, 3.905, and 4.0823 grains A1 2 O 3 per gallon (?), respectively. A number of miscellaneous analyses are included in the appendix (pp. 91, 93). H. F. Northrup and G. W. Rafter (Special Water-supply Committee of the City Council, Travers City, Rpt., p. 20), note a trace of A1 2 O 3 in Lake Michigan water at Chicago. C. G. Wheeler notes a trace of A1 2 O 3 in water of the Mount Clemens Pagoda Spring. In water from the Ypsilanti Sanitarium J. E. Clark found 0.15 A1 2 3 . Lang, E. E. (Verhandl. Ver. Naturkunde Presburg, 2, 1857, pt. 2, p. i; Jahresb. Chem., 1858, p. 798), reports alumina (parts per 1000) in water from Trentschin Toplitzer Bad, Hun- gary, as follows: Briinnlein (Urquelle), 0.009 an d Spiegelbad, No. i, 0.017. Langer, T. (Arch. Pharm., 3d ser., 2, p. 304; Jahresb. Chem., Naumann, 1872, p. 1186), notes traces of alumina in a mineral spring at Mattigbad, Austria. Lambert, E. G. (Ann. Chim. et Phys., 4th ser., 12, p. 309; Jahrb. Chem. Will., 1867, p. 1043), notes in the sulphur spring of Monterey (Mexico) 0.027 g m - aluminium silicate per liter. The water is used internally and for baths. The occurrence 9O ALUMINIUM IN NATURAL WATERS. of aluminium is also noted in potable water, sulphur- water, etc., of Maria Island. Laminne (Jour. Pharm., 3d ser., 13, p. 354; Jour. Chim.Med., 3d ser., 4, p. 461 ; Pharm. CentbL, 1848, p. 512; Jahresb. Chem., 1847, 1848, p. 1009) found 0.0020 part alumina per 1000 parts in mineral water from Tongern, Belgium. De Launay (Ann. Mines, gth ser., 5 (1894), p. 139) quotes an analysis of the mineral waters of Pfaefers-Ragatz, Canton St. Gall, Switzerland, made by Planta-Reichenau. In this water 0.00091 gm. aluminium phosphate per liter is reported, which was calculated to be equivalent to 0.00038 A1 2 3 . Leber (Pharm. Centbl., 1849, p. 791; Jahresb. Chem., 1849, p. 614) found 0.1157 alumina per 1000 parts in the "new" mineral spring-water from Salzschlirf near Fulda. Lefort (Jour. Pharm., 3d ser., 16, p. 14; Jahresb. Chem., 1849, p. 617) notes 0.017 g m - aluminium silicate per 1000 cc. in Enclos des Celestins mineral water from Vichy. Lefort, J. (Jour. Pharm., 3d ser, 21, p. 340; Jahresb. Chem., 1852, p. 757), notes 0.009, 0.008, and 0.005 S m - alumina per 1000 gms. in the "right," "left," and "middle" mineral springs, respectively, at Jenzat, Dept. Allier. Lefort, J. (Jour. Pharm., 3d ser., 31, p. 84; Jahresb. Chem., 1857, p. 725), found traces of alumina in the following mineral waters from Royat and Chamalieres, Dept. Puy-de-D6me, France; Royat Spring, Casarbad, Saint-Mart, and Roches (Beaurepaire) Spring. Lefort, J. (Jour. Pharm., 3d ser., 32, p. 264; Jahresb. Chem., 1857, p. 726), notes a trace of alumina in mineral water from Neyrac, Dept. d'Ardeche, France. Legrip (Jour. Chim. Med., 3d ser., 4, p. 83; Pharm. Centbl., 1848, p. 431; Jahresb. Chem., 1847-48, p. 1006) found 0.0074 gm. alumina per 1000 cc. in mineral water from Doulaux, Dept. Creuse. Le Grip (Jour. Chim. Med., 3d ser., 5, p. 514; Jahresb. Chem., 1849, p. 6 1 8) notes 1.75 per cent alumina in total solids of mineral water from Chaumaix, Dept. Creuse, the total solids being equal to 5.80 gms. per 10,000 cc. Leverett, F. (U. S. Geol. Survey Rpt., 17 (1895-96), pt. II, ALUMINIUM IN NATURAL WATERS. pp. 701-828), in an article on the water resources of Illinois, gives a number of analyses of water from springs, shallow wells, artesian wells, etc., a number of which, it is stated, were quoted from D. W. Mead's "Hydrography of Illinois." Some of these have been noted from Peale's compilation (U. S. Geol. Survey Bui. 32); others follow. G. H. Ellis (p. 824) reported 0.13 gm. A1 2 O 3 per U. S. gallon in Bushnell Railroad Well; W. S. Haines (p. 824) notes 0.08 grains per U. S. gallon in Wood- stock "drift" well. In "St. Peter's" water from Macomb, 111., G. Steiger (p. 826) reports 0.0013 gm. A1 2 O 3 per 1000 cc. The alumina (grains per U. S. gallon) found in a number of artesian-well waters by different analysts (pp. 827, 828) follows: ALUMINA IN CERTAIN ARTESIAN WATERS. Artesian Wells. Analyst. A1 2 O 3 per U.S. Gal. Auditorium Chicago, 111 E. G. Smith Grams. O7 Munger's laundrv, Chicago, 111 E. G. Smith O 3 Davenport Iowa glucose factory E Guteman l6 Dekalb 111 water-works G M Davidson 6^ 60 Dixon 111 water-works E G Smith I 2 Galena 111 water-works W. Simpson 06 Geneseo 111 water-works D M Stanner 8 cc lerseyville 111 water-works E G Smith oo 06 La or ran or e Mo Wyaconda well ? OQ Macomb 111 water-works G Steiger O7 C Monmouth 111 , water-works E. G. Smith IO Montezuma Ind W A Noyes O7 Peru 111 water-works . . E G Smith w / Od. Rockford 111 ... E G Smith I 3 Rockford 111 water- works E G Smith 06 Sterling 111 E G Smith O C W J In several others a trace of alumina is noted. Lengyel, B. v. (Foldtani Kozlony, 23 (1893), p. 293; Jahrb. Min., 1895, I, Ref. 66; Jour. Chem. Soc. London, 68 (1895), II, p. 1 1 8), finds that the Kolop Sulphur Spring, situated near Tisza Silly in the great Hungarian plain, contains o.oioi gm. A1 2 3 per kilogram. Lepsius, B. (Ber. Deut. Chem. Gesellsch., 21, p. 552; Jour. Chem. Soc. London, 54 (1888), p. 435), notes 0.00017 gm. A1 2 (P0 4 ) 3 per liter in the water of the Tonnissteiner medicinal 92 ALUMINIUM IN NATURAL WATERS. spring and quotes an earlier analysis by Fresenius, reporting 0.00013 gm. Lewy (Compt. Rend. Acad. Sci. Paris, 24, p. 449; Jahresb. Chem., 1847-48, p. ion) reports 1.66 aluminium sulphate per 1000 parts in thermal-spring water from Paramo de Ruiz, New Granada. See also Boussingault (Compt. Rend. Acad. Sci. Paris, 24, p. 397; Ann. Chim. Phys., 3. ser., 20, p. 109; lour. Pharm., 3. ser., n, p. 487; Jour. Prakt. Chem., 40, p. 438; Ann. Chem. Pharm., 64, p. 292; Poggendorf's Ann., 71, p. 444; Pharm. Centbl., 1847, p. 414). L'Hote, L. (Chem. Centbl., 1891, I, p. 207; Jahresb. Chem., 1891, p. 2620), found 0.0012 gm. alumina in the 2.216 gms. total solids obtained from 1000 cc. of mineral water from Penon de los Banos, Mexico. Liebig (Ann. Chem. Pharm., 63, p. 127; Jour. Prakt. Chem., 42, p. 463; Pharm. Centbl., 1847, p. 828; Jour. Pharm., 3d ser., 13, p. 65; Jahresb. Chem., 1847-48, p. 1002) notes a trace of aluminium oxid in bitter water from Friedrichshall at Hild- burghausen. Liebig (Ann. Chem. Pharm., 79, p. 94; Pharm. Centbl., 1851, p. 916; Vierteljahressch. Prakt. Pharm., i, p. 218; Jour. Pharm., 3d ser., 20, p. 315; Jahresb. Chem., 1851, p. 650) examined the sulphur waters of Aachen, reporting traces of aluminium phosphate in Kaiserquelle, Corneliusquelle, Rosen- quelle, and Quirinusquelle. Liebig (Ann. Chem. Pharm., 98, p. 145; Vierteljahressch. Prakt. Pharm., 5, p. 547; Jour. Prakt. Chem., 69, p. 28; Chem. Centbl., 1856, p. 390; Jahresb. Chem., 1856, p. 765) notes the occurrences of traces of aluminium phosphate in the follow- ing Kissingen mineral waters: Racoczy, Pandur, and Max- brunnen. Liebig (Ann. Chem. Pharm., 98, p. 350; Jour. Prakt. Chem., 69, p. 331; Chem. Centbl., 1856, p. 350; Jahresb. Chem., 1856, p. 766) notes the occurrence of traces of aluminium phosphate in the following mineral waters : Bitter water from Mergentheim, Bonifaciusquelle, Marienquelle, Elizabethenquelle, and Her- mannsquelle, the last four at Neuhaus near Neustadt, Germany. Limouzm-Lamothe (Jour. Chim. Med., 3d ser., 9, pp. 716, 763; Jahresb. Chem., 1853, p. 716) in mineral water from the ALUMINIUM IN NATURAL WATERS. 93 Dept. Aveyron, viz., from Prugnes and from Cayla (Princess Spring, Magdalen Spring, and Rose Spring), found alumina as follows: 0.035, 0.050, 0.055, an d 0.050 gm. per 1000 cc. respectively. Liversidge, A. (Chem. News, 42, p. 324; Jahresb. Chem., 1880, p. 1536; Jour. Chem. Soc., London, 40 (1881), p. 564), notes 12.86 parts aluminium chlorid per 100,000 in addition to 4.17 alumina with a trace of ferric oxid in a spring on Kan- tavu, one of the Fiji Islands. Liversidge, A. (Chem. News, 62, p. 264; Jour. Chem. Soc. London, 60 (1891), p. 280), in water from a hot spring in Savo Island, notes the occurrence of aluminium. Liversidge, A. W. Skey, and G. Gray (Rpt. Assoc. Adv. Sci. Australasia, 7 (1898), p. 87) have collected analyses of the mineral waters of Australasia. The data regarding aluminium are given on page 94. In addition to the above traces of alumina are reported by W. Skey (p. 105) in eighteen Te Aroha mineral waters, Queensland. Aluminium and iron are reported together in a number of other waters. Lord (Geol. Survey Ohio, 6(1888); U. S. Geol. Survey Rpt. 8, pt. II, p. 621) analyzed a brine from a well drilled at Lorain, Lorain County, Ohio, which contained 0.040 part alumina per 1000 parts. Losanitsch, S. M. (Ber. Deutsch. Chem. Gesellsch. 20, p. 1114; Jour. Chem. Soc. London, 52 (1887), p. 648), re- ports in mineral waters from Servia A1 2 O 3 (parts per 1000) as follows: Wrnjacka banja, 0.00105; Bukowik, 0.00271; Palanka, 0.00199; Alexinacka banja, 0.00279; Ribarska banja, o.ooio; Wranjska banja, 0.0005, an< i Brestowacka banja, 0.00140. Lowe, J. (Jahresb. Phys. Ver. Frankfurt a. M., 1853-54, p. 55; Jahresb. Chem., 1854, p. 759), notes in the Kronthal, Germany, Salzquelle, 0.000550 part aluminium silicate per 1000 parts. Lowe, J. (Jahresb. Phys. Ver. Frankfurt a. M., 1854-55, p. 58; Jahresb. Chem., 1856, p. 770), notes 0.001269 m - alu- minium silicate per 1000 gms. in the Kronthal, Nassau, Ger- many, Stahlquelle water. 94 ALUMINIUM IN NATURAL WATERS. ALUMINIUM IN AUSTRALASIAN MINERAL WATERS. Analyst. Page. Alu- minium Sul- phate per Gallon. Alu- mina per Gallon. Alu- minium Phos- phate per Gallon. Alu- minium Chlo- ride per Gallon. Alu- minium Silicate per Gallon. New Zealand. Alkaline water, Auck- land W Skey 88 Grains. Grains. 30 Grains. Grains. Grains. Springs Hanmer, J v Haast 89 trace Chlorinated water, W Skey 89 45 Chlorinated water, W Skey 37 1 6 42 Acid alum water, Mo- tuhora (Whale Isl- and, Bay of Plenty . Acid aluminous water, Ohaeawai, Auckland Alum water Onetapu, Desert Auckland. . . Otira Gorge, sulphur- etted and siliceous J. A. Pond J. Hector W. Skey G. Gray 90 92 92 48.48 a b . 21 P a h u a Wairarapa, chlorinated water. . Chlorinated water, Tologo Bay W. Skey W. Skey 93 2. I5C .64 Chlorinated water, No. i , Waimate Block. . Chlorinated water, No. 2, Waimate Block. . Chlorinated water, No. 3, Waimate Block. . Weak chalybeate Wai- rongoa, North Taiera Otoga W. Skey W. Skey W. Skey A G Kidson- 95 95 95 trace 2.86 trace 2 5 Alkaline saline water, Waiwera, Auckland. Chlorinated water, A, Hunter W. Skey W Skey 96 06 trace . 91 Chlorinated water, B W Skey O6 I . 22 Chlorinated water, C W Skey 96 . 21 Carbonated alkaline water Whangarei J A Pond traces Acid water, Lake White Island or Whakaari J Hector go 5 1703 . id New South Wales. Alkaline water, Balli- more Water Milparinka Queensland. Te Pupunitanga Priets's Bath, Ro- turua District. . . . J. C. H. Mingaye A. H. Jackson W. Skey 98 98 IOO 21 . 67 trace little a. Temperature 6o-ii6 F. Deposits alum and sulphur (amount not stated) on cooling. Total solids, 134.4 grains per gallon. b. Total solids, 456 grains per gallon, mainly potash, alum and magnesia, and ferrous chlorides. c. With trace of iron. d. Sesquichloride. ALUMINIUM IN NATURAL WATERS. 95 ALUMINIUM IN AUSTRALASIAN MINERAL WATERS. Continued. Analyst. Page. Alu- minium Sul- phate per Gallon. Alu- mina per Gallon. Alu- minium Phos- phate per Gallon. Alu- minium Chlo- ride per Gallon. Alu- minium Silicate per Gallon. Waikupapapa Saddler's Bath, Roturua Dis- trict W. Skey TOO Grains. Grains. Grains. Grains. Grains. Waikirihou V a u x ' s Bath, Roturua Dis- trict Toko Postmasters' Bath, Roturua Dis- trict Arikikapakapa, Ro- turua District Te Mimi Okakahi, Ro- turua District Ti Kute Great Spring, Roturua District. . . Sulphur Bay Spring, Rotorua District. . . Perekari, Rotorua District South Australia. Wyly's Well Farina W. Skey W. Skey W. Skey W. Skey W. Skey W. Skey W. Skey G A Goyder 100 100 too 100 100 100 too 33-22 1-34 .68 trace 11.22 trace trace Spring The Peake G A Goyder 26 G A Goyder Spring, Andrawilla, G A Goyder 4 2 Healy Springs, Indul- G A. Goyder . I O Oolarinna Soak age Well Billa-kalina Springs, G. A! Goyder G A Goyder 107 25 45 Sulphur Spring.Strang- G A Goyder 75 G A. Goyder 107 32 Weedina Spring G. A. Goyder G A Goyder 107 15 3 Spring Alton Downs, Herbert River, North G A Goyder 68 Ludwig, E. (Wiener Akad. Ber., 52, 2. Abt., p. 264; Jah- resber. Chem. Will., 1865, p. 934), notes 0.005 aluminium phosphate per 10,000 parts in the thermal spring at Tobelbad, near Gratz, in Steiermark. Ludwig, E. (Wiener. Akad. Ber., 50, 2. Abt., p. 247; Chem. Centbl., 1865, p. 702; Jahresber. Chem. Will., 1865, p. 935), notes traces of aluminium phosphate in three mineral springs at Mahren, viz., Johannisbrunnen, Neue Quelle, and Paula- quelle. Ludwig, E. (Min. Petr. Mittheil., 2d ser., 4, p. 519; Jahresb. Chem., 1881, p. 1447), found 0.0053 A1 2 O 3 per 10,000 parts in the Sauerquelle from Apatovac, Austria-Hungary. 96 ALUMINIUM IN NATURAL WATERS. Ludwig, E. (Min. Petr. Mittheil. 6. p. 150; Jahrseb. Chem., 1884, p. 2035), notes o.ooio A1 2 O 3 per 10,000 parts in Maria Theresia Quelle at Andersdorf, Austria-Hungary. Ludwig, E. (Die Mineralquellen Bosniens, abs. Chem. Centbl., 1889, II, p. 264; Jahresb. Chem., 1889, p. 2633), reports in the following mineral waters from Bosnia: (i) Ther- mal spring at Ilidze near Sarajewo; (2) Sauerling from Kisel- jack; (30) Sauerling from Bistrica; (30) Sauerling from Ljes- kovica (Giftquelle) ; (4) Rjecicaquelle at Maglaj ; (6) Sauerling at Dragunje; (7) Sauerling at Kiseljack near D. Tuzla; and (8) iodine spring at Navioci near Han Sibosica; A1 2 O 3 as follows: 0.012, 0.002, 0.006, 0.004, 0.0017, -5> o.ooi, and 0.021 (probably parts per 10,000). Ludwig, E. (Tschermak's Mineral. Mittheil. 1890, Jahresb. Chem., 1890, p. 2662), reports 1.319 aluminium sulphate in Cervena-Rjeka-Quelle and 0.146 aluminium sulphate in the Quelle an der Strasse (presumably parts per 10,000 cc.). Both these "vitriol" springs are at Srebrenica, Bosnia. He also reports (Tschermak's Mineral. Mittheil., 1890; Jahresb. Chem., 1890, p. 2663) 13.468 gms. aluminium sulphate per 10,000 cc. in a mineral spring at Biidos (Balvanyos) in Sieben- biirgen, 0.007 gm. alumina per 10,000 cc. in Karlsquelle; 0.0025 gm. aluminium per 10,000 cc. in Fidelisquelle ; and 0.961 part aluminium sulphate per 10,000 parts in the alum spring, all on the Biidos (Stinkberg). Ludwig, E. (Die Mineralquellen Bosniens, abs. Chem. Centbl., 1890, II, pp. 468. 846; Jahresb. Chem., 1890, p. 2666), reports analyses of mineral-spring waters from Bosnia. The following waters contained alumina (grams per 10,000 in every case): No. ia, saline, Dolnj-Tuzla, 0.005; No. 16, saline, Dolnj-Tuzla, 0.009; No. 2, thermal spring at Gradacac, 0.007; No. 5, sulphur spring, Raso, o.ooi ; No. 6, Sauerling at Jasenica, 0.006; No. 7, Sauerling at Dubnica, 0.002; No. 8, Sauerling at Tesanj, 0.019; No. 9, thermal spring, Vrucica, 0.008; No. 10, thermal spring, Kulasi, 0.007 ' No. n, sulphur spring, Smodelac, 0.003; No. 12, thermal spring, Gorni Sehar, o.ooi; No. 13, thermal spring, Slatina Ilidze, 0.003; No. 14, Sauerling spring, Slatina Ilidze, 0.005; No. 15, thermal spring at Gata, 0.002; ALUMINIUM IN NATURAL WATERS. 9/ No. 16, thermal spring at Fojnica, o.ooi; and No. 17, thermal spring at Banja Visegrad, o.ooi. Other springs contained aluminium sulphate as follows (grams per 10,000) : Waters from Srebrenica (Haldenwasser), No. 4a, arsenic vitriol Crni Guber, 2.227; No. 46, arsenic vitriol Mala Kiselica, 1.482; and No. 4C, arsenic vitriol Velika Kiselica, 0.384. Ludwig, E. (Tsch. Min. Mittheil., 16 (1896), p. 133; Jour. Chem. Soc. London, 72 (1897), II, p. no), notes in a car- bonated water from a spring at Seifersdorf , Austrian Silesia, o.ooi parts A1 2 O 3 per 10,000, and also notes (Tsch. Min. Mittheil., 16 (1896), p. 140; Jour. Chem. Soc. London, 72 (1897), II, p. no) 0.002 part A1 2 O 3 per 10,000 parts in water from the Constantine Spring in Gleichenberg, Styria. Ludwig, E. (Wien. Klin. Wochensch., 10 (1897), P- 56; Chem. Centbl., 1897, I, p. 718; Jour. Chem. Soc. London, 74 (1898), II, p. 392), reports 0.004 A1 2 O 3 parts per 10,000 in water from the iodine spring at Wels, Upper Austria. Ludwig, E., and V. Ludwig (Wien. Klin. Wochensch., n (1898), 207) studied the composition of the acid iron springs at Johannisbrunn in Silicia, reporting per 10,000 parts by weight o.ooi part alumina in Marienquelle and 0.002 part in Paula- quelle. Ludwig, E., and J. Mauthner (Min. Petr. Mittheil., 2d ser., 2, p. 269; Jahresb. Chem., 1880, p. 1524) report analyses of the Carlsbad thermal springs. These contained A1 2 O 3 per 10,000 cc. as follows: Sprudel, 0.004 g m - i Marktbrunnen, 0.007 gm.; Schlossbrunnen, 0.005 g m - 1 Miihlbrunnen, 0.005 gni- ' Neubrunnen, 0.006 gm. ; Theresienbrunnen, 0.005 g m - 1 Eliz- abethquelle, 0.006 gm. ; Felsenquelle, 0.003 g m - 1 Kaiser- brunnen, 0.005 gm. The article (loc. cit., p. 1526) contains a reference to Lerch's analyses made in 1847. He reported 0.005 gm. A1 2 O 3 per 10,000 cc. in Orchesterquelle, and 0.006 gm. in Elizabethquelle. Ludwig, E., and T. Panzer (Wiener Klin. Wochensch., 13 (1900), p. 617) note a trace of alumina in the water of the Gastein, Austria, Hauptquelle or Elizabethquelle. They also quote data obtained by earlier analysts. Thus Hiine- feld reported 0.016 A1 2 O 3 in 1828; Saltmann, 0.027 i n 98 ALUMINIUM IN NATURAL WATERS. Wolff, 0.022 in 1845; an d Ullik, 0.003 in 1845, parts per 10,000 in every case. Ludwig, H. (Arch. Pharm., 26. ser., 93 (1858), pp. 129, 257; Jahresb. Chem., 1858, p. 795), notes 0.0054 Al 2 O 3 .SiO 3 per 1000 parts in the cold sulphur-water from Tennstadt, Thu- ringia. Ludwig, H. (Arch. Pharm., 2. ser., 133 (1868), p. i; Jahresb. Chem. Will., 1868, p. 1037), reports per 1000 cc. 0.0033 Al 2 O 3 ,2SiO 2 in Friedensquelle from Rostenberg in Sachsen- Weimer-Eisenach. Lunge, G., and L. Landolt (Sep. from Corresp. Schweizer- Aerzt.; Jahresber. Chem., 1885, p. 2317) report 0.0259 gm. A1 2 C1 6 per 1000 gms. in the Schweizerhalle saline spring at Basel. Lunge, G., and R. E. Schmidt (Zeit. Analyt. Chem., 25, p. 309; Jour. Chem. Soc. London, 50 (1886), p, 996), in water of the St. Lorenz hot spring at Leuk, note per kilogram 0.00051 gm. alumina. Magerstein, V. T. (Verhandl. Geol. Reichsanst., 1879, p. 191; Jahresb. Chem., 1879, p. 1265), reports a trace of A1 2 O 3 in two mineral waters from Zuckmantel and Einsiedel, Austria. Maier, P. J. (Naturk. Tijdschrift. Nederland Indie, 21, p. i; 22, p. 44; 23, pp. 46, 378; Jahresb. Chem , 1861, p. 1113), found A1 2 O 3 (grams per 100) in mineral water from Dutch East India as follows: Spring at Koeningan near the river Tjisangarong, 0.01730; Sissipan Spring, near the river Tjisan- garong, 0.01050; spring northeast from the Palimang mountain, 0.00039; Prajan Spring at Res. Madioen, trace; hot spring at the foot of Kaba mountain, 0.00059; and thermal spring on Pengalengen plateau, 0.00038. Mangini, F. (Gaz. Chim. Ital., 17 (1887). p. 517; Jour. Chem. Soc. London, 54 (1888), p. 1261), in an analysis of the chalybeate water of Raffanelo in the commune of Canale Mon- terano, reports 0.1350 gm. A1 2 O 3 per liter. Marchand, E., and E. Leudet (Jour. Pharm., 37, p. 328; Jahresb. Chem., 1860, p. 838) report aluminium salts as follows (grams per 1000 gm.) in mineral water from Bleville, France: 0.0031 A1 2 O 3 3SO 3 ; 0.0151 A1 2 O 3 .NH 4 O.4SO 3 -. 0.0145 A1 2 O 3 .KO.4SO 3 ; 0.0022 A1 2 O 3 PO 5 ; and 0.0493 CaO.Al 2 O 3 .4SiO 3 . ALUMINIUM IN NATURAL WATERS. 99 Mason, W. P. (Chem. News, 61, p. 123; Jour. Chem. Soc., London, 58 (1890), p. 854), reports an analysis of the water of Excelsior Springs near Kansas City, Missouri, which showed 2.10 parts A1 2 O 3 per 1,000,000. Maumene* (Compt. Rend. Acad. Sci., Paris, 31, p. 270; Pharm. Centbl., 1850, p. 754; Jahresb. Chem., 1850, p. 626) notes 0.00112, 0.00119, 0.00140, and 0.00197 g m - alumina per 1000 cc., respectively, in water from the Vesle taken on January 23, 1849, at Chateau-d'Eau; Vesle water taken at the same place June 18, 1849; Vesle water taken June 18, 1849, at Saint-Brice, and water from the Suippe. Meyer, R. (Ber. Deut. Chem. Gesell., n (1878), p. 1521; Jour. Chem. Soc. London, 36 (1879), H> P- 33), in water from the mineral spring at Tenninger Bad, Somvirex Tobel, Ori- sons, notes 0.0008 part A1 2 O 3 and H 3 PO 4 per 10,000. Mingaye, J. C. H. (Jour. Proc. Roy. Soc. New South Wales, 26 (1892), p. 73), reports a number of analyses in a study of some of the well, spring, mineral, and artesian waters of New South Wales and their probable value for irrigation. A potable water from Yarrangobilly caves and one from Jenolan caves each contained a trace of alumina. Other waters contained alumina (parts per 1000) as follows: Water from Jenkins's quarry, 0.0082; from Kidwell's quarry, 0.0104; from Marden's quarry, 0.0126; from Walsh's quarry, 0.0096; water from brewery, Broken Hill, 0.0044; Silverthorne's well, Broken Hill, 0.0030; water from Portion 86, taken from a bore in a lime- stone quarry, Broken Hill, 0.0004; Wilcannia, water from Tarella, 0.0064; water from Barragan, near Mudgee, trace; Belabula River, Clifden Run, trace; artesian water from Cutta- bura, Bourke private bore, and Bourke Corrella Station, trace; and mineral water from Jarvisville, near Picton, Ballinore, Tarbragar River, near Dubbo (artesian), and Rock-Flat Spring, near Cooma, Monara District, each a trace. In one or two other cases alumina with iron is noted. Mingaye, J. C. (Rpt. Australian Assoc. Adv. Science, 6 (1895), P- 2 65)' i n a second paper, which deals with analyses of the artesian waters of New South Wales and their value for irrigation and other purposes, reports alumina as follows (parts per thousand) : Kelly's Camp bore, 0.0028 (with a trace of IOO ALUMINIUM IN NATURAL WATERS. Fe 2 O 3 ), water from Barringun bore, 0.0036 (with a trace of Fe 2 3 ); Corella bore No. i (private), trace; Waroo Springs bore, 0.0036 (with a trace of Fe 2 O 3 ); Cuttaburra bore and Dungle Ridge bore, each a trace. In several other waters alumina and ferric oxid are reported together. Miteregger, J. (Jahrb. Naturhist. Landesmuseums Karnthen, 1861, No. 5, p. i; Jahresb. Chem., 1861, p. 1099), notes alu- minium (parts per 10,000 cc.) as follows, in water from Radlbad, near Gmiind, 0.820; Sauerling Bades Vellach in Vella- thale Hauptquelle No. IV, 0.130; Sauerling Bades Vellach in Vellathale Quelle No. II, 0.189; Sauerling Bades Vellach in Vellathale Quelle No. Ill, 0.080; Sauerling, Bades Vellach in Vellathale Quelle No. V, o.ioo, and Sauerling from Ebriach, near Eisenkappel, 0.130. Mitteregger, J. (Jahrb. Naturhist. Landesmuseums Karn- then, 1862, p. 109; Jahresb. Chem., 1862, p. 813), notes alumina per 10,000 gms. in Karnthen medicinal waters as follows: Katharien-Bad at Klein-Kirchheim, 0.050; Preblauer Sauerbrunnen, 0.040; Sauerbrunnen at Weissenbach in the Lavantthale, 0.140; and Kleininger Sauerbrunnen in the Lavantthale, 0.240. Moissenet (Ann. Min., 5th ser., 17, p. 7; Jahresb. Chem., 1860, p. 839) reports A1 2 O 3 (grams per 1000 cc.) in French mineral waters as follows: Water from Sylvanes, Dept. Aveyron, Source des Moines, 0.0300; Source des Petites Baignoires, 0.0750; Source des Petites-Eaux, 0.0200; Source des Bains Nouveaux, 0.0200; water from Plombieres, Sources des Dames, 0.0075, and Source ferrugineuse, 0.1433; an d a trace of A1 2 O 3 in water from Vittel, near Contrexeville, Dept. Vosges, Source Marie, Source des Demoiselles, and Grand Source. Moitessier, A. (Compt. Rend. Acad. Sci. Paris, 51. p. 636; Jahresb. Chem., 1860, p. 839), notes 0.0030 gm. alumina per 1000 in the water of the warm spring about 2 km. north of Montpellier, France. Morelli (Chem. Ztg., 1881, p. 815; Jahresb. Chem., 1881, p. 1448) found 0.0299 part aluminium sulphate per 1000 in one spring and 0.0326 part aluminium sulphate in another at Ceresole Reale, Italy. Morin, P. (Jour. Pharm., 3d ser., 21, p. 5; Arch. Phil. Nat., ALUMINIUM IN NATURAL WATERS. IOI 18, p. 224; Jahresb. Chem., 1851, p. 667), found 0.0162 gm. aluminium silicate per 1000 gms. in mineral water from Coese (Savoy). Morin, P. (Jour. Pharm., 3d ser., 40, p. 183; Jahresb. 'Chem., 1861, p. 1106), found 0.0027 g m - alumina per 1000 gms. in mineral water from the Guillot spring at Evian, Savoy. Muck, F. (Jour. Prakt. Chem., 96, p. 459; Chem. Centbl., 1866, p. 384; Jahresb. Chem., 1865, p. 931), reports in 1000 parts Natronsauerling from Nassau 0.00060 gram alumina. Miigge, 0. (Jahrb. Min., Beilageband. 4, p. 576. Jahresb. Chem., 1886, p. 2324), reports an analysis by C. Pieper of a hot spring south of Naiwaschasee, Massailand, East Africa. This contained 0.779 g m - A1 2 S 3 O 12 per 1000 cc. Miiller, E. (Arch. Pharm., 2dser., 186 (1868), p. 16; Jahresb. Chem,, 1868, p. 1038), reports per 500 gms. 0.0027 A1 2 O 3 PO 5 and 0.0150 A1 2 O 3 .3HO in the water of the sulphur spring at Seebruch. Miiller, G. (Neue. Jahrb. Pharm., 3, p. 205; Pharm. Centbl., 1855, p. 526; Jahresb. Chem., 1855, p. 840), reports 0.0340 alumina per 1000 gms. in the Bergstrasse Stahlquelle water from Weinheim. Mtiller, G. (Wiener. Akad. Ber., 2. Abt., 58, p. 101 ; Inst., 1868, p. 384; Jahresb. Chem., 1868, p. 1035), reports traces of A1 2 O 3 in the Ida spring at Biloves in Bohemia. Muspratt, J. S. (Pharm. Jour. Trans., n, p. 151; Jahresb. Chem., 1851, p. 653), notes traces of alumina in the water of the principal spring at Baden-Baden. Nasini, R., and F. Anderlini (Gaz. Chim. Ital., 24 (1894), I, p. 327; Jour. Chem. Soc., London, 66 (1894), II, p. 422) report 0.0015 A1 2 O 3 part per 10,000 by weight in the water of Hot Springs at Monte Irone, Albane. Netwald (Unters. des Mineralwasser zu Hall bei Krems- miinster, Linz, 1853; Jahresb. Chem., 1853, p. 711) notes in mineral water from Hall near Kremsmunster, Austria, 0.0038 gm. aluminium silicate per 1000 gms. Northcote, A. B. (Phil. Mag., 4th ser., 14, p. 457; Jahresb. Chem., 1857, p. 727), notes a trace of alumina in the following IO2 ALUMINIUM IN NATURAL WATERS. saline waters from Cheshire, England: Anderton, Marston, Winsford, and Wheelock. Nuricsan, J. (Foldtani Kozlony, 23 (1893), p. 296; Jahrtx Min., 1891, I, Ref. 67; Jour. Chem. Soc. London, 68 (1895), H p. 118), notes 0.0017 ? m - A1 2 O 3 per kilogram in the water of the Roman brine spring and 0.0064 in the Shaft spring at Torda, Hungary. Nuricsany and Spangler (Wiener Acad. Ber., 14, p. 121; Pharm. Centbl., 1855, p. 78; Jahresb. Chem., 1854, p. 771) note in mineral water from Roggendorff (Hungary) 0.019 gm. alumina per 1000 gms. Ochsenius, C. (Ztschr. Geol. Ges., 34, p. 357; Jahresb, Chem., 1882, p. 1626), notes traces of A1 2 O 3 in water from the Great Salt Lake, Utah. Oppermann (Mem. Mus. Strassburg, 4, 1853, p. 21; Jahrb. Min., 1854, p. 184; Jahresb. Chem., 1853, p. 717) notes 0.006250 gm. alumina per 1000 cc. in mineral water from Sulzbach, Alsace. Orlow, N. A. (Farmaz. Jour., 40, 1901, pp. 2, 26; Ztschr. Untersuch. Nahr. u. GenussmtL, 5 (1902), p. 133), reports 0.0022 gm. A1 2 O 3 per 1000 cc. in the Director spring water from Staraja-Russa. Orlowsky, A. (Ber. Deut. Chem. Gesell., 1883, p. 978 (cor- resp.); Jahresb. Chem., 1883, p. 1947), notes 0.001904 part A1 2 O 3 per 1000 parts in Bolschoi water (used for baths) and 0.001784 part A1 2 O 3 per 1000 parts in Kasimer water (used for drinking), both springs in Slawinsk, Poland. Orosi (Gaz. Toscana, 1847, P- 99 I Pharm. Centbl., 1847, p. 413; Jour. Prakt. Chem., 42, p. 468; Jahresb. Chem., 1847 48, p. 1009) found 0.0049 part alumina per 1000 in Mofetta di S. Quirico, water from Tuscany. Osnaghi (Wien. Acad. Ber., 17, p. 443; Chem. Centbl., 1856, p. 40; Jahresb. Chem., 1855, p. 842) notes o.oio part alumina per 1000 parts in mineral water from Galdhof, near Seelowitz, Austria. Otto, R., and H. Beckurts (Arch. Pharm., 3d ser., 18, p. 115; Jahresb. Chem., 1881, p. 1444) report 0.0030000 part A1 2 O 3 per 1000 parts in Hroswitha water and 0.0035000 part A1 2 O 3 in ALUMINIUM IN NATURAL WATERS. 103 Wilhelmsquelle ; both waters from Herzogludolfsbad, near Gan- dersheim, Germany. Parmentier, F. (Compt. Rend. Acad. Sci. Paris, 115, p. 125; Jahresb. Chem., 1892, p. 2687), writing of the occurrence of alumina in mineral water, reports the following in springs at Vichy, Saint-Yorre (Allier) Frobert, 0.008; Saint-Louis No. i, 0.007; Precieuse, 0.006; Jeanne d'Arc, 0.004; Sevigne, 0.003. In Vichy (Allier) springs: Dubois, 0.015; Vincent, o.oio. In springs at Hauterive (Allier): Bayard, 0.006; Amelie d'Haute- reve, o.ooi. In Pougues-les-Eaux (Nievre) springs: Grande Source, 0.014; Jeanne d'Arc, 0.006; Saint-Leon, 0.002; and in the Chatelguyon (Puy-de-D6me) spring, Yvonne, 0.009 g m - per 1000 cc. Parmentier, F. (Compt. Rend. Acad. Sci. Paris, 132, 1901, p. 1332; Ztschr. Untersuch. Nahr. u. Genussmtl., 5 (1902), p. 138), states that aluminium occurs in most of the spring- waters previously analyzed by him (for instance, Vichy), al- though it was not reported. In Puits Chomel he reports 0.0117 gm. per 1000 cc., and in Grande Grille he reports 0.0075 g m - P er I00 cc - These waters contained flocculent particles of aluminium hydrate. Parmentier, F. (Compt. Rend. Acad. Sci. Paris, 121 (1895), p. 644; Jour. Chem. Soc. London, 70 (1896), II, p. 195), in a bituminous water from the Grassion spring at Clermont, France, found 0.004 gm. A1 2 O 3 per liter. Passy, A. (Compt. Rend. Acad. Sci. Paris, 68, p. 171; Jahresb. Chem., 1869, p. 1290), notes 0.002 and o.oio gm. A1 2 O 3 per liter, respectively, in spring-water and Aube water from Etufs, France. The analyses were made by H. Magnon. Paterno, E., and G. Mazzara (Gaz. Chim. Ital., 9 (1879), p. 71; Jahresb. Chem., 1879, p. 1266) note a trace of A1 2 O 3 in Termini-Imerese water from Palermo, Sicily. Paterno, E, (Gaz. Chim. Ital., 21 (1891), II, p. 40; Jahresb. Chem., 1891, p. 2619), notes traces of aluminium phosphate in thermal-spring water from Sclafani. Peale, A. C., of the United States Geological Survey (U. S. Geol. Survey Bulletin No. 32, p. 235), published some years ago a very extended compilation of analyses of waters of IO4 ALUMINIUM IN NATURAL WATERS. mineral springs in the United States. The author states that the information was derived primarily from various State Geo- logical Reports, State guide-books and handbooks, government geological reports, etc., and various other scientific publications. Much additional material was obtained from members of the Geological Survey, and in answer to a special set of inquiries sent throughout the United States. Efforts were made by the compiler to verify in each instance the matter presented in regard to the various localities by direct correspondence. Some eight thousand springs are included in the list, of which about eight hundred had been analyzed. The tables, with a few exceptions, do not include brine springs and wells which are used in the production and manufacture of salt, since such waters are not applied to the ordinary uses of mineral springs. The results are arranged by States and Territories, and the analytical data are in the main incorporated in the tables as given in the sources from which they were taken, except that where originally expressed in grains per fraction of a gallon they were recalculated to grains per gallon. Unless otherwise stated the gallon mentioned is the standard United States gallon or wine gallon of 231 cubic inches. In a number of cases the iron and aluminium were reported together. Such figures have been omitted in preparing the data here given, nor is reference made to those spring-waters in which a trace of alumina was reported. The pages of Dr. Peale's report on which the analyses occur, from which the data regarding alu- minium are quoted, are given, as well as the name of the analyst when it was stated. References to the original place of publi- cation are not given, as they were not quoted by Dr. Peale. The following table records the data regarding the occurrence of alumina (A1X3 3 ): A L U MINIUM IN NA T URA L WA TERS. 10$ AMOUNT OF ALUMINA IN THE WATER OF A NUMBER OF MINERAL SPRINGS IN THE UNITED STATES. Name of Spring. Analyst. Page. Alumina per Gallon. Maine. Poland Star Spring F L Bartlett Grains. Roscicrucian Spring S Dana Hayes 16 6 Z u Hartford Cold Springs 16 u o New Hampshire. Iron Spring Milford G E Sewell I 7 Birchdale Springs, Concord Sprino'S . . C F Chandler 18 Unity Springs, Iron Spring Vermont. Middletown Springs No i . . . . S. Dana Hayes Peter Collier 18 .04 fi*r r New York. Artesian Lithia Spring, Ball- Eton Spa C F Chandler .07 C O o Franklin Artesian Well, Balls- ton Spa C F Chandler 66 o/S Washington Lithia Well (old Conde Dentonian), Ballston, Spa C F Chandler 66 3 -7 White Sulphur, Chittenango Springs C F Chandler n o Cave Spring, Chittenango Springs C F Chandler 66 Cherry Valley Phosphate Spring. . Lebanon Thermal Spring. Richfield Sulphur Spring .... . . Saratoga Champion Spouting Spring C. F. Chandler H. Dussance T. Deecke C F Chandler 66 34 35 37 ?s .14 45 . 10 A6 Saratoga Crystal Springs Saratoga Congress Spring Saratoga Empire Spring Saratoga Eureka Spring . . . C. F. Chandler T. R. Chilton C. F. Chandler Allen o Co Co Co C D CO 00 00 C 31 32 .42 Saratoga Flat Rock Spring. . . . C F Chandler oy 7Q -*6 Saratoga Hathorn Spring C F Chandler 7Q Saratoga High Rock Springs Saratoga Pavilion Spring C. F. Chandler C F Chandler 39 AQ L 6 I .22 3 -2 Saratoga Pavilion Spring J R Chilton Saratoga Putnam Spring J R Chilton c6 Saratoga New Putnam Spring. . . . Saratoga A or Alum Spring Saratoga Seltzer Spring C. F. Chandler J. G. Pohle C F Chandler 40 40 A.O i) u .22 .38 ? 7 Saratoga Union Spring Saratoga United States Spring. . . Saratoga Vichy Spring New Jersey. Schooley's Mountain Spring Warwick Spring C. F. Chandler C. F. Chandler C. F. Chandler C. Mclntyre, Jr. C F Chandler 4i 41 4i 43 A -1 32 .09 .48 14 7O / u a. With iron. b. With soda. c. Grains per cubic foot. 106 ALUMINIUM IN NATURAL WATERS. ALUMINA IN MINERAL SPRINGS Continued, Name of Spring. Analyst. Page. Alumina per Gallon. Pennsylvania . Cresson Magnesia Spring F. A Genth 47 Grains. O I Gettysburg Lithia Spring F. A. Genth 4.8 O2 Mineral Springs Hanover Hollenbush 48 Kane Sulphur Spring Maryland. Strontia Mineral Spring F. A. Genth W Simon 49 p ? 03 i 86 a Virginia. Bath Alum Spring No i Hayes DO c8 Bath Alum Spring No 3 Haves 5 eg 12 20 b Clifton Spring No i J L Ca'mpbell e,8 O7 C Blue Ridge Spring F A Genth CQ 14 Farmville Lithia Springs, No. 2. . Mineral Springs, near Farmwell Station No i E. T. Fristoe R B Riees 60 6O 2.52 Mineral Springs, near Farmwell Station No 3 R B Riggs 60 Boiler Bath (Old Ladies' Boiler Bath Hot Spring) F W Clarke 61 Hot Spout Bath F W Clarke 61 Octagon Bath F W Clarke 61 New Hot Spring F W Clarke 61 Sulphur Bath or Ladies' Sulphur Bath F W Clarke 61 Jordan Alum Chalybeate Spring. . Jordan White Sulphur Springs. . . Massanetta Mineral Springs. ..... Rawley Springs, Main Fountain . . Rockbridge Alum Springs, Chaly- beate Spring Rockbridge Alum Spring, No. i . . Rockbridge Alum Spring, No. 2. . Rockbridge Alum Spring, No. 3. . Rockbridge Alum Spring, No. 4. . Rock Enon Springs J. W. Mallet T. Antisell J. W. Mallet J. W. Mallet J. W. Mallet A. A. Hayes A. A. Hayes M. B. Hardin A. A. Hayes Gale and Mew 62 63 63 63 64 64 65 65 65 67 5 .OI .16 .05 c .06 14.76 17.91 43-95 24.09 80 Roanoke Red Sulphur Springs . . . Shenandoafr Alum Springs M. B. Hardin J. W. Mallet 67 67 .01 12 3Q C West Virginia. Capon Main Spring J. W. Mallet 71 02 c Capon Beauty Spring J. W. Mallet 71 02 c Greenbrier White Sulphur Sour Spring W B Rogers 72 1 6 20 f Salt Sulphur Iodine Spring D. Stewart 73 .18 a. Parts per 100,000. 6. Also aluminium phosphate. See p. 113. c. Grains per imperial gallon. d. Grams per liter. e. Grains in 100 cubic inches. ALUMINIUM IN NATURAL WATERS. ALUMINA IN MINERAL SPRINGS. Continued. ID/ Name of Spring. Analyst. Page. Alumina per Gallon. North Carolina. Greensborough Spring Panacea Spring, near Littleton. . . Park's Alkaline Mineral Spring Georgia. Helicon Springs W. C. Kerr, a W. C. Kerr, a A. R. Ledoux H. C. White W. C. Stubbs W. C. Stubbs L. Harper A. Dove J. M. Safford W. A. Noyes J. M. Safford J. B. Mitchell J. M. Safford Troost R. Peter R. Peter R. Peter J. P. Barnum E. H. Larkin Wright and Merrill A. Merrill C. F. Chandler W. M. Mew W. M. Mew O. N. Stoddard E. S. Wayne A. Fennel E. T. Cox 77 78 78 85 93 93 97 103 103 104 104 106 in 116 116 118 122 122 127 128 128 128 133 134 134 138 Grains. .18 32 3-5 .05 b 12.41 i. 45 .00005 G 2 .OO .06 .04 .29 5 .06 .08 .02 d. e .0006 / .0021 /,g I .20 / 45 49 i . 54 I . 22 3-46 .98 . 12 .22 .19 b Alabama. Johnson's Wells Talladega Spring Mississippi. Lauderdale Springs . Tennessee. Austin's Springs Crisp Springs Galbraith's Springs Hurricane Springs Montvale Springs Tilford's Mineral Well White Cliff Springs Kentucky. Estill Springs, White Sulphur Spring Olympian Salt Sulphur Spring. . . Olympian White Sulphur Spring . Kuttawa Mineral Springs Arkansas. Hot Springs Warm Springs . . . Texas. Palo Pinto Well Wootan Well No i Wootan Well No 2 Wootan Well, No. 4: Ohio. Green Mineral Spring Ohio Magnetic Spring Cedar Springs, Washington Sprin CT Indiana. Greencastle, North or Daggy Spring \ a. Reported in Geol. North Carolina, i (1875). b. Grains per imperial gallon. c. Parts per 100. d. Grains per 1000. e. With trace of phosphates. f. Parts per 1000. g. With iron and manganese carbonates. 108 ALUMINIUM IN NATURAL WATERS. ALUMINA IN MINERAL SPRINGS. Continued. Name of Spring. Analyst. Page. Alumina per Gallon. Indiana. Greencastle, Middle or Dewdrop Spring Marion Artesian Well E. T. Cox 138 I 3Q Grains. .09 a 3C a West Saratoga Spring, No. i West Saratoga Spring, No. 2 Illinois. Alcyone Mineral Springs Glen Flora Springs E. T. Cox E. T. Cox Wheeler and Blaney J V Z Blaney 140 140 144 1 4-4. . 22 a 43 a 1.99 a I r Versailles Mineral Spring, No. i. . Rockford Artesian Well, No. i. . . Michigan. Riverside Magnetic Spring No 2 J. V. Z. Blaney E. G. Smith 144 144 14-7 730, b . 0009 c ci d Butterworth's Magnetic Spring, Grand Haven Mineral Spring. . . . Mount Clemens Mineral Well. . . . Mount Clemens Media Spring. . . . Mount Clemens Soolbad Spring. . "W^arner's Spring S. P. Duffield C. G. Wheeler S. P. Duffield S. P. Duffield S. P. Duffield 147 148 148 148 148 I ">O 49 a 30 29.47 29 .00 II . 21 2 ? Wisconsin. Arctic Spring W. W. Daniels I C 7 I ~ Bethesda Springs, Waukesha .... Black Earth Mineral Springs C. F. Chandler A C Barry 153 1C? . 12 I OO Buckhert's Fountain G. Bode I C T. 16 Eureka Springs G. Bode I CA . 19 c Fountain Springs J. V. Z. Blaney 154 9 Gibson Springs G. Bode i CA I 3 c Glen Springs F C Chandler i C4 o=c Gomber's Well i C4 i T. Hacket's Spring . . . G. Bode i 54 . 1 1 Horeb Springs G. Bode i =54 2 T, Hy^eia Springs A. Thiel i P- 3 2 55 Jahresb. Chem., 1853, p. 714) found 0.0005 P art alumina per 1000 parts in the same water. Heidepriem and Poselger (Jour. Prakt. Chem., 58, p. 473; Pharm. Centbl., 1853, p. 324; Jahresb. Chem., 1853, p. 714) also note a trace of alumina in this water, as did Braun in two analyses reported by Rivier and Fellenberg (Jour. Prakt. Chem., 59, p. 303; Jahresb. Chem., 1853, p. 715). Robinson, A. E., and C. F. Mabery (Jour. Amer. Chem. Soc. 18 (1896), p. 915; Jour. Chem. Soc. London, 72 (1897), II, p. 510), report in bittern water from a boring 2667 feet deep at Conneautsville, Crawford County, Pennsylvania, 31.1 parts A1C1 3 per 100,000. Roux (Compt. Rend. Acad. Sci. Paris, 73, p. 910; Jour. Chem. Soc. London, 24 (1871), p. n8i) 2 reports 0.00720 gm. aluminium silicate per liter in the water of an artesian well at Rochefort. Rupp, G. (Ztschr. Ang. Chem., 1891, p. 448; Jahresb. Chem., 1891, p. 2618), in a steel spring at Bad Griesbach found 0.003 gm. alumina per 1000 cc. Russell, I. C. (U. S. Geol. Survey Bui. 108, p. 93,, notes that T. M. Chatard found in Owens Lake (California) 0.023 part A1 2 O 3 per 1000 parts. Russell, I. C. (U. S. Geol. Survey Bui. 52, p. 38), quotes an analysis of James River, Va., water reported by W. H. Taylor ALUMINIUM IN NATURAL WATERS. IIQ (An. Rpt., Richmond (Va.) Board of Health, 1876). The .account of AL,O 3 noted is 0.00041 part per 1000 parts. Russell, I. C. (U. S. Geol. Survey Mon. n, Tables, p. 176), quotes a number of analyses of American rivers, inclosed lakes and springs. Some of these have been noted already from other publications. Others follow, the values given in every case representing parts per 1000. Hydrant (river) water from Los Angeles, California, according to W. J. Jones (Rpt. Cal. State Board Health, 1878) contains 0.00171 part A1 2 O 3 and hydrant (river) water from Sacramento, California, 0.00120 part A1 2 O 3 . E. R. Horsford (Geol. of New Jersey, 1868, p. 703) notes 0.01342 part A1 2 O 3 in Pasaic River water taken four miles above Newark. T. M. Chatard reports 0.0013 A1 2 O 3 in Humboldt River water taken at Battle Mountain, Nevada (see also Mon. n, p. 41). Of the analyses of American springs,, two, which should be noted, contained alumina. These are the following: artesian well, "Glacier Spouting Spring," Saratoga, N. Y., analyzed by F. A. Cairns and C. F. Chandler (Amer. Chemist, 1872, Nov., p. 164), containing 0.00770 part A1 2 O 3 , and artesian well, Sheboygan, Wis., analyzed by C. F. Chandler (Amer. Chemist, 1876, p. 370), containing 0.0022 part per 1000 parts in both cases. Russell states also that O. Loew (Ann. Rpt. Chief En- gineers, 1876, Appendix JJ, p. 410) reports an analysis of the water of Owens Lake, California, noting a trace of alu- minium. According to data quoted by Russell (loc. cit.) Terreil (Larted, Geological Explorations of Dead Sea, p. 278) found that the Dead Sea water contains traces of alumina. Say, M. (Wien. Acad. Ber., 13, pp. 298 and 457; Pharm. Centbl., 1854, p. 923; Jahresb. Chem , 1854, p. 771), reports (grams per 1000 gms.) in Hildegarde spring-water from Of en 0.047, and in mineral water from Lippa 0.0157, both towns in Hungary. Scherer (Ann. Chem. Pharm., 99, p. 257; Vierteljahressch. Prakt. Pharm., 6, p. 81; Jour. Prakt. Chem., 70, p. 151; Chem. Centbl., 1856, p. 810; Jahresb. Chem., 1856, p. 767) found c.0002 gm. alumina per 1000 cc. in Wernarzer mineral water, 120 ALUMINIUM IN NATURAL WATERS. and a trace in the sweet potable water near the Sinnberger- quelle, both waters from Bruckenau, Germany. Scherer (Neue. Jahrb. Pharm., 7, p. 309; Tahresb. Chem. 1857, p. 721) notes a trace of alumina in the saline water from Philippsquelle at Orb, Germany. Scherfel, A. (Ungar. Naturw. Ber., i, p. 195; Jahresb. Chem., 1886, p. 2321), notes 0.002349 part A1P0 4 and 0.019317 part A1 2 O 3 per 1000 parts in water from a spring at Kirchdrauf in der Zips, Szepesvaralja, Hungary. Scherfel, A. (Ungar. Naturw. Ber., i, p. 230; Jahresb. Chem., 1886, p. 2322), notes 0.014722 part A1PO 4 and 0.017778 part Al 2 O 3 per 10,000 parts in mineral water from Czemete near Eperies, Hungary. Schmidt, C. (Arch. Naturk. Liv. Esth. Kurlands., ist ser., i, p. 293; Jahresb. Chem., 1854, p. 771), notes a trace of alumina in the bored saline-spring water from Staraja-Russa, Russia. Schmidt, C. (Melanges Phys. et. Chim. tirees Bui. Akad. Imp. Sci. St. Petersburg 7, p. 427; Petersburg Acad. Bui. 12, p. i; Jahresb. Chem., 1867, p. 1042), notes 0.021 part alu- mina per 10,000 parts in iron water from Stolypin, Russia. Alumina was not noted in the deposit from the water. Schneider, F. C. (Wiener. Akad. Ber., 2. Abt., 69, p. 55; Jahresb. Chem., 1874, p. 1330), reports o.oio, 0.006, 0.015, and o.on part alumina per 10,000 parts, respectively, in four St. Helena thermal springs at Battaglia, Italy. Schrockinger (Verhandl. Geol. Reichsans., 1878, p. 89; Jahresb. Chem., 1878, p. 1301), reports 0.0044 part aluminium phosphate per 10,000 parts in water from a bored well 127 meters deep, near Briix, Bohemia. The analysis was made by Gintl. Schoeller, R. (Ber. Deut. Chem. Gesellsch., 20 (1887), p. 1784; Jahresb. Chem., 1887, p. 2537), reports analyses of streams affecting the Rio de la Plata water. That designated Uruguay water contained 0.0018 gm. alumina per 1000 gm. Schwarz, E. (Wiener Akad. Ber., 55, 2. Abt., p. 35; Wiener Akad. Anz., 1867, p. 7; Chem. Centbl., 1867, p. 558, Inst., 1867, p. 151; Jahresb. Chem., 1867, p. 1037), notes 0.007 part aluminium phosphate per 10,000 parts in mineral water from Modling near Vienna. ALUMINIUM IN NATURAL WATERS. 121 Schweissinger (Chem. Centbl., 1890, I, p. 875; Jahresb. Chem., 1890, p. 2662) notes a trace of alumina in the Bad Marienborn iron-sulphur water. Shepard, C. U. (Silliman's Amer Jour., 26. ser., 47, p. 357; Jahresb. Chem., 1869, p. 1293), reports 0.0000093 P ar t calcium, iron, and aluminium phosphate per 100 parts in artesian water from Charleston, South Carolina. Siegmund, H., and P. Juhasz (Wiener Akad. Ber., 54, 2. Abt., p. 216; Wiener Akad. Anz., 1866, p. 162; Inst., 1866, p. 400; Jahresb. Chem., 1866, p. 996) found 0.002 part alumi- nium phosphate per 10,000 parts in the Voslau mineral water. Simmler, T. (Jour. Prakt. Chem., 71, p. i; Chem. Centbl., 1857, p. 498; Jahresb. Chem., 1857, p. 723), found 0.0046 gm. alumina with phosphoric acid per 1000 gm. in sulphur-water from Stachelberg, Canton Glarus, Switzerland. Smith (Jour. Chem. Soc. London, 15 (1862), p. 57; Jour. Prakt. Chem., 89, p. 186; Chem. News, 5, p. 96; Rep. Chim. Appliquee, 4, p. 216; Jahresb. Chem., 1862, p. 822) found in the water of the Te Tarata hot spring on the coast of Rotomahana, north New Zealand, 0.32 grain alumina per gallon. Smith (Jour. Prakt. Chem., 89 (1863), p. 186; U. S. Geol. Survey Rpt. 9, p. 655) notes 0.005 m - alumina per kilogram in White Terrace Geyser water from New Zealand. Smith, L. (Silliman's Amer. Jour., 2d ser., 12, p. 10; Jah- resb. Chem., 1851, p. 668), reports aluminium sulphate in mineral water from Brusa (Asia Minor) as follows: Kukurtlu 0.0043 and Bademli Baghtsche 0.0020 gm. per 1000 cc., and Gueuzayasma a trace. He reports further (Silliman's Amer. Jour., 2d ser., 12, p. 366; Jour. Prakt. Chem., 55, p. no; Jah- resb. Chem., 1851, p. 668) a trace of aluminium sulphate in the Yalova hot spring, and 0.0221 gm. aluminium sulphate per 1000 cc. in the Touzla Spring water. Smoot, L. E. (Amer. Chem. Jour., 19 (1897), p. 234; Jour. Chem. Soc. London, 72 (1897), II, p. 329), notes 0.891 gm. A1 2 O 3 per liter in an alum-water from Lee County, Virginia. Soubeiran, E. (Jour. Pharm., 3d ser., 32, p. 19; Jahresb. 122 ALUMINIUM IN NATURAL WATERS. Chem., 1857, p. 726), found 0.054 gm. alumina and silica per 1000 cc. in Vic-sur-Cere mineral water, Cantal, France. Spath, E. (Chem. Centbl., 1889, II, p. 896; Jahresb. Chem., 1889, p. 2636), notes traces of A1/) 3 ,P 2 O 5 in Temple and Wiesen Spring water from Bad Steben at Oberfranken. Spengler quotes F. Mohr's analysis of the Felsenquelle of Ems (Arch. Balneologie, 3 (1864), p. 136; Viertelj. Prakt. Pharm., 14, p. 234; Chem. Centbl., 1865, p. 608; Jahresber. Chem., 1865, p. 931). A pound (7680 grains) contained 0.0960 grain alumina. Spica, P. (Gaz. Chim. Ital., 12 (1882), p. 555; Jahresb. Chem., 1882, p. 1623), noted traces of A1 2 O 3 in two samples of water from Lake Derkol near Constantinople. Spica, P. (Gaz. Chim. Ital., 22 (1892), I, p. 354; Jahresb. Chem., 1892, p. 2686), notes 0.001999 gm. aluminium phosphate per 1000 cc. in mineral water from Burge Malo. Spurr, J. E. (U. S. Geol. Survey Mon. 31, p. 212), quotes an analysis by C. F. Chandler of water from Yampa Spring, Glenwood Springs, Colorado. This contained a trace of alumina. Stackmann, A. (Russ. Ztschr. Pharm., 24, pp. 129, 145, 161, 209, 225, 273, 289, 321, 337; Jahresb. Chem., 1885, p. 2319), reports analyses of mineral water from Psekoup or Gorjatschy Kljutsch. Data are quoted for (i) Alexanderquelle, (2) Olga- quelle, (3) Marienquelle, (4) Karmalinquelle, (5) Michail- quelle, (6) Kamenewquelle, (7) Sudliche Drainagequelle, (8) spring without particular name, and (9) mixture of above eight waters. These contained respectively o.ooio, 0.0005 0.0005, 0.0005, 0.0007, 0.0009, o.ooio, 0.0005, an d 0.0012 A1 2 O 3 (presumably grams per 1000 cc.). The author also reports 0.0050 gm. A1 2 O 3 per 1000 cc. in a sulphur spring and 0.0390 gm. A1 2 O 3 per 1000 cc. in a saline spring analyzed by him. Steiger, G. (U. S. Geol. Survey Bui. 113, p. 113), in water from American Carlsbad Spring, Nashville, Illinois, found 3.60 parts A1 2 O 3 per 1,000,000. Stein, W. (Schmidt's Jahrb Ges. Med.. 70. p 142; Jahresb. Chem., 1851, p. 654), notes traces of alumina in the medicinal waters of Elster. Saxony, as follows: Gasquelle, Salzquelle or Augenquelle, and Trinkquelle or Stahlbrunnen. ALUMINIUM IN NATURAL WATERS. 123 Steinbrtick (Arch. Pharm., 2d ser., 145 (1871), p. 97; Jah- resb. Chem., 1871, p. 1228) reports 0.0212 and 0.0134 gm. A1 2 O 3 per liter in two springs at Neuragoczi near Halle. Stieren, E. (Vierteljahressch. Prakt. Pharm., 10, p. 365; Jahresb. Chem., 1861, p. 1112), notes 0.040830 part alumina per 1000 parts in artesian water from Peterson's saline water, Tarentum, Pennsylvania. Strecker, A. and H. (Chem. Lab. Univ. Christiana, 1854, p. 67, Ann. Chem. Pharm., 95, p. 177; Jahresb. Chem., 1854, p. 770), in the sulphur-water of Sandefjord found 0.0068 part alumina per 1000 parts, and 0.0033 parts in near-by sea- water. Streit, S., and W. Holecek (Wiener Akad. Ber:, 53, 2. Abt., p. 371; Jahresb. Chem., 1866, p. 995) note 0.021 and 0.0067 part aluminium phosphate per 10,000 parts, respectively, in Toplitz and Someraubad mineral water from Mahren. Thresh, j. C. (Chem. News, 46, p. 226; Jahresb. Chem., 1882, p. 1635), found 10.416 gms. A1 2 S 3 O 12 and 0.065 g m - A1PO 4 per 10,000 cc. in the Orchard Alum Spring water, England. Thresh, J. C. (Jour. Chem. Soc. London, 41 (1882), p. 117), in Buxton thermal water reports 0.000683 Al 2 O 3 .Ca 3 (PO 4 ) 2 per 10,000 gms. He notes that in 1852 Playfair reported 0.034 part Al 2 O 3 .Fe 2 O 3 per 10,000 parts in the same water. Thorner, W. (Repert. Analyt. Chem., 3, p. 22; Jahresb. Chem., 1883, p. 1944), reports in a bored well (Soolquelle) at Melle, Germany, 0.000102 part A1 2 O 3 per 1000 parts. Thorner, W. (Ztschr. Angew. Chem., 1889, p. 309; Jahresb. Chem.. 1889, p. 2631), reports 0.0020 gm. alumina per 1000 cc. in water from the Germania Spring at Schwalheim, Germany. Thorner, W. (Chem. Ztg., 17, p. 1411; Jour. Chem. Soc. London, 66 (1894), II, p. 195), reports A1 2 O 3 as follows in some German mineral-spring waters: Stahl 0.0132, Angelika at Tonnisstein 0.0056, Wilhelms 0.0679, New Spring at Melle 0.0045, an d Sulphur Spring at Levern 0.0020 gm. per liter. Thorpe, T. E. (Jour. Chem. Soc. London, 65 (1894), p. 772), reported analyses of a number of mineral waters from Chelten- 124 ALUMINIUM IN NATURAL WATERS. ham, England. The Chadnor Villa well contained 0.00015 part aluminium phosphate per 1000 parts, and the Lansdowne well and the Pittville wells, Nos. i, 2, and 3, each traces. Tissandier, G. (Compt. Rend. Acad. Sci. Paris, 80, p. 58; Jahresb. Chem., 1875, P- I28 4), reports a trace of A1 2 O 3 in melted snow collected in Paris and in the country. Tournaire (Ann. Minn., 5th ser., 17, p. 65; Jahresb. Chem., 1860, p. 841), reported 0.165 m - Al 2 O 3 .SiO 2 in mineral water from Roddes (France), near Ambert. Tournaire (Ann. Minn., 5th ser., 17, p. 66; Jahresb. Chem., 1860, p. 841) found 0.055 g m - Al 2 O 3 .Si0 3 per 1000 cc. in a mineral water from Ceyssat, Dept. Puy-de-D6me, France. Treadwell, F. P. (Arch. Pharm., 231 (1893), p. 579; Jour. Chem. Soc. London, 66 (1894), II, p. 323), in the upper spring of Gyrenbad, Canton Zurich, found 0.000200 part A1PO 4 per 10,000 parts. Trillion, H. (Chem. Ztg. II. Rept., p. 211; Chem. Centbl., 1887, p. 1239; Jahresb. Chem., 1887, p. 2534), notes 0.00109 gm. aluminium phosphate per 1000 gms. in the sulphur-water of Bad Wemding at Ries. Trillich, H. (Chemische Analyse des Hauptbrunnens zu Munster a. Stein, Munich; Chem. Centbl., 1889, II, p. 896; Ausz.; Jahresb. Chem., 1889, p. 2631), notes 0.00168 part A1 2 O 3 per 1000 parts in water from the Hauptbrunnen at Munster, Germany. Tschermak (Jahrb. K. K. Geol. Reichsanstalt, 1858, p. 297; Jahresb. Chem., 1858, p. 796) found 0.0092 part aluminium phosphate per 1000 parts in mineral water from Kondran near Regensburg, Germany. Tschermak, T. (Min. Petr. Mitth., 2d ser., 3, p. 315; Jahresb. Chem., 1880, p. 1528), quotes analyses made by P. Schnell and Stenner in 1855 of water from an iron spring at Slanik, Roumania. This contained o.o^ gm. A1 2 O 3 per 10,000 gms. Turner, T. (Chem. News, 49, p. 186; Jahresb. Chem., 1884, p. 2036), reports 0.0740 gm. A1 2 O 3 (with some Fe 2 O 3 ) per 1000 cc. in water from the salt wells of Dudley, England. Valentiner, W. (Jour. Prakt. Chem., 99, p. 91; Jahresb. Chem., 1866, p. 994), in Oberbrunnen and Miihlbrunnen ALUMINIUM IN N 'A 7 'URAL WATERS. 12$ mineral waters from Ober-Salzbrunn reports per 1000 parts, 0.005 an d 0.0003 P ar t aluminium with phosphoric acid, respectively. Vierthaler, A. (Wiener Akad. Ber., 56, 2. Abt., p. 463; Wiener Akad. Anz., 1867, p. 220; Jour. Pharm. Chem., 102, p. 381; Jahrb. Chem., 1867, p. 1040), reports traces of alu- mina in the Cattani No. 2 and San Francesco springs of Spalato. Vohl, H. (Dingler's Polytech. Jour., 199, p. 311; Chem. Centbl., 1871, p. 269; Arch. Pharm., 2d ser., 146 (1871), p. 199; Jahresber. Chem., 1871, p. 1223), reports 0.0008 gm. Al 2 O 3 per 10,000 cc. in one sample and o.oio gm. in five samples of Rhine water taken under different circumstances near Cologne. Vohl, H. (Ber. Deut. Chem. Gesellsch., 1875, P- 611; Arch. Pharm., 3d ser., 7, p. 134 (see under R. Bender); Jahresb. Chem., 1875, p. 1290), notes 0.0556 gm. alumina per 10,000 cc. in Birresborn mineral water. Vohl, H. (Ber. Deut. Chem. Gesellsch., 1876, p. 20; Jahresb. Chem., 1876, p. 1298), reports 0.3925 gm. alumina per 10,000 cc. in Birresborn mineral water taken after the spring had been cleaned. Vohl, H. (Ber. Deut. Chem. Gesellsch., n (1878), pp. 605, 877: Jahresb. Chem., 1878, p. 1299; Jour. Chem. Soc. London, 34 (1878), II, p. 714), notes in Gerolsteiner Schlossbrunnen, located near Pelm, Germany, 0.0002 part A1 2 O 3 per 1000 parts, and in Birresborn spring-water from the same locality traces of alumina. Vohl, H. (Ber. Deut. Chem. Gesell., n (1878), p. 1678; Jahresb. Chem., 1878, p. 1304), reports 0.3067 part A1 2 O 3 per 10,000 parts in Ofener Rakoczy Bitterwasser. He quotes C. R. C. Tichborn's analysis, which gave 0.27 part A1 2 O 3 per 10,000 parts, and J. Molnar's, which gave 0.4840 part A1 2 O 3 per 10,000 parts. The water varies in composition at different seasons, etc. von der Marck, W. (Arch. Pharm., 2d ser., 102 (1860), p. i; Vierteljahressch. Prakt. Pharm., 9, p. 161; Chem. Centbl., 1860, p 485; Ztschr. Chem. Pharm., 1860, p. 170; Jahresb. Chem., 1860, p. 831), reports 0.00676 gm. alumina per 1000 126 ALUMINIUM IN NATURAL WATERS in the Stahlbrunnen, one of the Hermannsborn mineral springs near Pombsen, Germany. Wait, F. G. (Rpt. Section of Chem. and Mineral., Geol. Survey Canada, 1898, p. 48 R), reports 0.345 part alumina per 1000 in the filtered water from Lake Goodenough, a soda lake in British Columbia. It was calculated that this repre- sented 0.825 part aluminium phosphate or 64.016 grains per imperial gallon. Wait (Geol. Survey Canada, Chem. Contributions, 1892-93, p. 78 R) notes 0.0002 part alumina with a little ferrous oxide per 1000 parts in water from a bored well 1943 feet deep near Deloraine, Manitoba. Wallace (Analyst, 1880, p. 79; Jahresb. Chem., 1880, p. 1535) notes 8.0 parts A1 2 O 3 per 1,000,000 in an English artesian water. Wallace (Rept. British Assoc., 1862, Notices and Abstracts, p. 94; Jahresb. Chem., 1862, p. 818) found alumina and phos- phate as follows: Loch Katrine water (thirty-five miles from Glasgow) o.io, and the same water at Glasgow 0.16 grain per gallon. Walton, G. E., in his volume on mineral waters of this country and Canada (The Mineral Springs of the United States and Canada, New York, 1883) quotes a number of analyses in which alumina was reported. Such data (unless noted from other sources) are included in the table on the next page. Walz, G. F. (Neue. Jahrb. Pharm., 6, p. 265; Jahresb. Chem., 1856, p. 769), found o.ooio gm. alumina per 1000 gm. in sulphur-spring water from Weisloch, Baden, the sample being taken at the spring-house. In a sample taken after flowing one-eighth mile through a pipe the water contained 0.0009 gm. alumina per 1000 gms. Wandesleben (Neue Jahrb. Pharm., 3, p. 123; Pharm. Centbl., 18^5, p. 361; Jahresb. Chem., 1855, p. 840) notes 0.0013 gm. alumina per 1000 gms. in Oestringer sulphur-water from Langenbriicken, Baden. Weed, W. H., and L. V. Pirsson (U. S. Geol. Survey Bui. 139, p. 150) quote an analysis of White Sulphur Springs, Montana, which records a trace of alumina. ALUMINIUM IN NATURAL WATERS. 12/ MINERAL WATERS OF THE UNITED STATES AND CANADA. Spring. Analyst. Page. A1 2 O 3 per Pint. Aluminium Sulphate per Pint. California Seltzers Spring Versailles, 111., Curry Spring. . . Caledonia, Ontario, Gas Spring Caledonia, Ontario, Saline Sorinsf H. G. Hanks J. V. Z. Blaney T. Sterry Hunt T Sterry Hunt I 4 8 149 164 164 Grains. 75 .091 a .032 trace Grains. Caledonia, Ontario, Inter- mittent Spring T. Sterry Hunt 164 trace Caledonia, Ontario, sulphur- water T. Sterry Hunt 183 019 Big Bone Kentucky springs . . . Berkshire, Mass., Soda spring. Caxton, Quebec, spring Slaters ville, N. Y., spring Excelsior Mo springs T.' Sterry 'Hunt B. Hitchcock 193 335 3 8 9 399 418 " b" .036 h> b b South Park, Col., spring G. E. Patrick 450 .047 a. With trace of iron. b. Qualitative analysis amount not stated. Weidel, H., and G. Goldschmiedt (Wiener Acad. Ber., 2. Abt., 74, p. 391; Jahresb. Chem., 1877, p. 1386) report 0.0063 part A1 2 O 3 per 10,000 parts in O Tura Sauerling water from Hungary. Wertheim, T. (Wiener Acad. Ber., 42, p. 479; Rep. Chim. pure, 3, p. 131; Jahresb. Chem., 1860, p. 836) notes 0.02899 part alumina per 10,000 parts in Franz- Joseph-Bad water from Tiiffer, Austria. Weselsky, P., and A. Bauer (Wiener Acad. Ber., 29, p. 585; Chem. Centbl., 1858, p. 652; Jahresb. Chem., 1858, p. 797) note 0.00227 part alumina (with phosphoric acid?) per 1000 parts in water from the Konig Ferdinand Eisenbad, Weidritz- thal near Presburg, Hungary. Wiggers (Bal. Ztg. i, p. 4; Pharm. Centbl., 1854, p. 934; Jahresb. Chem., 1854, p. 762) notes that a potable water from a spring at Hofgeismar, Hesse-Nassau, Germany, contained a trace of alumina too small to weigh. Wiggers (Arch. Pharm., 2d ser., 102, p. 215; Jahresb. Chem., 1860, p. 832) found 0.001920 grain alumina per pound ( = 7680 grains) in the Driburg, Germany, mineral water. 128 ALUMINIUM IN NATURAL WATERS. Wildenstein, R. (Jour. Prakt. Chem., 85, p. 100; Chem. CentbL, 1862, p. 200; Jahresb. Chem., 1862, p. 810), notes 0.00180 part aluminium phosphate per 10,000 parts in water from a hot mineral spring a Burtscheid, Germany. Will (Ann. Chem. Pharm., 61, p. 181; Pharm. CentbL, 1847, p. 507; Jahresb. Chem., 1847-48, p. 1002) eports in water from Rippoldsau as follows: Josephsquelle 0.0953, Wenzelsquelle 0.0840, and Leopoldsquelle 0.0822 gm. alu- mina per 10,000 gms. Will (Ann. Chem. Pharm., 81, p. 73; Pharm. CentbL, 1852, p. 237; Jahresb. Chem., 1851, p. 650) found 0.00119 part aluminium phosphate per 1000 parts in sulphur-water from Weilbach. Willm, E. (Compt. Rend. Acad. Sci. Paris, 86, p. 543; Bui. Soc. Chim., 2d ser., 29, p. 291; Jahresb. Chem., 1878, p. 1309), notes in Aix-les-Bains (Savoy) sulphur spring 0.001,3 gm. aluminium per liter, and in the alum-spring water o 0003 gm. A1 2 S 3 O 12 per liter. Willm, E. (Compt. Rend. Acad. Sci. Paris, 86, p. 613; Jour. Chem. Soc. London, 34 (1878), II, p. 560), analyzed mineral water from Challes, Savoy, reporting 1.21851 and 0.3306 gm. per liter soluble matter in Source principale and Petite Source, the former containing 0.0059 gm. alumina and the latter 0.0232 gm. alumina and sand together. Willm, E. (Compt. Rend. Acad. Sci. Paris, 90, p. 547; Jahresb. Chem., 1880, p. 1534), reports an analysis of the Richard spring at Cransac, France. April 15, 1879, the water contained 0.02800 gm. A1 2 S 3 O 12 , and July 14, 1879, 0.1760 gm. per 1000 cc. Willm, E. (Bui. Soc. Chem., 2d ser., 31, p. 3; Jahresb. Chem., 1879, p. 1266), reports 0.0027, 0.0024, and 0.0012 gm. alumina per 10,000 cc., respectively, in three Auvergne mineral waters, and traces in three others. Willm, E. (Compt. Rend. Aead. Sci. Paris, 90, p, 630; Jahresb. Chem., 1880, p. 1533), analyzed the Bussang springs in the Vosges. Salmade contained 0.0012, Ober Quelle o.on, and Quelle Marie o.ooio gm. A1 2 O 3 , respectively, per 1000 cc. Willm, E. (Compt. Rend. Acad. Sci. Paris, 103, p. 416, ALUMINIUM IN NATURAL WATERS. 1 29 Jour. Chem. Soc. London, 50 (1886), p. 997, notes 0.0003 g m - alumina per liter in the Bosquet water of Bagneres de Luchon, Haute Garonne. Willm, E. (Compt. Rend. Acad. Sci. Paris, 1 13, p. 87 ; Jahresb. Chem., 1891, p. 2617), notes per 1000 cc. in Madeleine water No. i 0.0644, i n Madeleine water No. 2 0.0248, in Cercle water 0.0154, in Damont water 0.0963, and in Des demoiselles spring 0.0399 aluminium sulphate. These springs are at Rennes-les-Bains (Aude). The first three belong to a com- pany; the last two to the town. Wittstein (Vierteljahressch. Prakt. Pharm., 10, p. 342; Jahresb. Chem., 1861, p. 1097) reports A1 2 O 3 in water as follows: Ohe River 0.00017, Hohenbrunnerfilz 0.00076, Schliessheimer moor water 0.00029, I sar River 0.00030, and Brunnthaler water 0.00013 gm. per 1000 gms. Wolff, J. (Wiener Akad. Ber., 56, 2. Abt., p. 55; Wiener Akad. Anz., 1867, p. 137; Jour. Prakt. Chem., 101, p. 318; Chem. Centbl., 1867, p. 424; Inst., 1867, p. 391; Jahrb. Chem., 1867, p. 1039), reports 0.0064 part alumina and phosphoric acid per 10,000 parts in water from the mineral spring at Siebenbiirg. Wreden, F., and A. Fuchs (Ber. Deut. Chem. Gesellsch., 1874, p. 1147; Jahresb. Chem., 1874, p. 1335) note in "5 per cent Soljanka" mineral water and water from an artesian well, both at Ciechocinek, Poland, 0.0035 an( ^ o.oioi part A1 2 (HO) 6 per 1000 parts, respectively. A salt obtained from the " 5 per cent Soljanka" water was analyzed and found to contain 0.0314 per cent A1 2 O 3 . Dried at 110 the salt contained 1.005 per cent material which was not soluble in water. Wroblewsky, E. (Bui. Soc. Chim., 2d ser., 30, p. 436; Ber. Deut. Chem. Gesell., 1878, p. 1848 (corresp.); Jahresb. Chem., 1878, p. 1314), reports 0.02119 part A1 2 O 3 per 1000 parts in a spring near Ekaterinodar in the Caucasus. Wurtz, H. (Silliman's Amer. Jour., 2d ser., 22, pp. 124, 301; Jahresb. Chem., 1857, p. 729), notes a trace of alu- mina in Delaware River water taken near Trenton, New Jersey. Zaleski, S. S. (Chem. Ztg., 1892, p. 594; Jahresb. Chem., ISO ALUMINIUM IN NATURAL WATERS. 1892, p. 2683), notes 0.0018 part A1 2 O 3 per 1000 parts in Ingol Lake water, Gouv. Jenissejsk. Zaugerle, M. (Neue. Repter. Pharm., 14, p. 9; Chem. Centbl., 1865, p. 798; Jahresber. Chem., 1865, p. 933), reports traces of alumina in the Schillingsforst spring, Bavaria. ALUMINIUM IN MISCELLANEOUS MATERIALS. Corney, B. G., D. Guthrie, and F. B. Guthrie (Jour, and Proc. Roy. Soc. New South Wales, 33 (1900), p. 224; Jour. Chem. Soc. London, 78X1900), II, p. 569) note the presence of 41.53 per cent A1 2 O 3 in an edible earth from Fiji. The earth is regarded as a silicate with the formula Al 2 O 3 (SiO 2 ) 2 (H 2 O) 2 , with Fe 2 O 3 present as an impurity. Hebberling, M. (Vierteljahressch. Prakt. Pharm., 18, p. 558; Dingler's Poly. Jour., 194, p. 88; Chem. News, 20, p. 249; Jahresb. Chem., 1869, p. 1119), analyzed earth from Berbek, Java, which is eaten by the natives. He found 25.939 per cent alumina. Love, E. G. (Chem. News, 41, p. 187; Jahresber. Chem., 1880, p. 1118), reports the analysis of a Japanese edible earth. This contained 13.61 per cent alumina. Muir, M. M. P. (Chem. News, 36, p. 202; Jour. Chem. Soc., London, 34 (1878), II, p. 120), notes 17.97 P er cent A1 2 O 3 in an edible clay from Mackenzie County (South Island), New Zea- land. He states that this clay is largely eaten by sheep. Schmidt, C. (Ann. Chim. Phys., 4th ser., 26, p. 535; Jour. Chem. Soc. London, 26 (1873), p. 151), in an article on Eat- able Earths of Lapland and Southern Persia, notes 40.797 per cent alumina in earth eaten in Lapland. The specimen came from the village of Ponoi. Alumina was not reported in the earth from Kirman (called G'hel i G'iveh) in Southern Persia. Stark, J. F. (Chem. News, 23, p. 199; Jour. Chem. Soc. Lon- don, 24 (1871), p. 425), reports 4.17 per cent A1 2 O 3 in an earth- ball from a horse. The ball weighed over two pounds. 131 132 ALUMINIUM IN MISCELLANEOUS MATERIALS. The principal constituent of the earth-ball was ammonium- magnesium phosphate, which amounted to 83.2 per cent. Thompson, W. Oilman (Practical Dietetics, New York, 1902, p. 281), notes the occasional use of alum and aluminium chloride as preservatives. This use of aluminium compounds has also been noted by other writers. INDEX. Abies ex eels a, 21. Acer negundo, 1 1. Achyranthus aspera, 39. Aconite roots, 23, 39. Aconitum heterophyllum, 39. Aconitumjaponicum, 39. Acquarossa Spring, Biasca, Italy, 56. Adder's tongue, 10. Adelheidquelle. Heilbrunn, Germany. 71, 114. Adirondacks, New York, spring, 55. ^Egina Springs, Greece, 68. Agnesquelle, Lobenstein, Germany, 117. Agrostemma githago, 12. Agua de Vida Lower Spring, Cal., 63. Agua de Vida Upper Spring, Cal., 63. Aix-les-Bains, France, alum spring, 128. Aix-les-Bains, France, sulphur spring, 54, 128. Albany, Ga., artesian well. 118. Alcyone Mineral Springs, Illinois, 108. Alexanderquelle, Psekoup, 122. Alexandro-Jermolowski, Caucasus, spring, 55. Alexinaka banja, Servia, spring, 93. Alfalfa soil, 1 6. Alfalfa roots, 7. Alga, 1 6. Alleghany Springs, Virginia, 113, 114. Allouez Mineral Spring, Wisconsin, 68. Alma, Mich., wells, 89. Almond shells, 30. Almonds, 30. Alsophila australis, n. Alte Quelle, Ronneby, Sweden, 80. Alum Creek, Yellowstone National Park, 78. Alum Rock Alkaline Saline Spring, California, 63. Alum Rock Chalybeate Spring, California, 63. 133 134 INDEX. Alum Spring, Saratoga, N. Y., 105. Alveneu Sulphur Spring, 115. Amandbrunnen, Luhatschowitz, Austria-Hungary, 72, 85. Amazon River, 117. Ambrosia artemisiafolia, 14. Ambrosius Spring, Marienbad. Austria-Hungary, 76. Ameliaquelle, Iwoniez, Austria-Hungary, 116. Amelie d'Hautereve, Hautereve, France, spring, 103. American Carlsbad Spring, Nashville, 111., 122. Americus, Ga., artesian well, 118. Anatto, 20. Anatto seeds, 15. Ancona, Italy, spring, 60. Andansonia digitata, 19. Anderson Iron Spring, California, 63. Anderson Sour Spring, California, 63. Anderton, England, spring, 102. Andropogon scoparius, 14. Angelika, TOnnisstein, Germany, spring, 124. Angustus Spring, Neuenahr, 56. Ann Arbor (Huron River ?), creek, 88. Apollinaris Spring, Germany, 54. Apples, ripe, 8. Araliarhizomes, 27. Aralia californica, 27. Arcier Spring, Besancon, France, 69. Arctic Spring, Wisconsin, 108. Arcueil Spring, Paris, France, 69. Arenaria media, 16, 17. Arenaria r libra, 16. Arkansas City Well, Kans., 53. Arkansas Lithia Springs, 63. Armeria maritima, 38. Artemisia Geyser, Yellowstone National Park, 78. Artemisia maritima, 16. Artesian Lithia Spring, Ballston Spa, New York, 105. Artesian Mineral Well, Prairie du Chien, Wis., 109. Artesian Well, Aberdeen, S. D., 109. Artesian Well, England, 126. Artesian Well, Louisville, Ky., 112. Artesian Well, No. I, Rockford, 111., 108. Arum (Colocasia) esculentum, 18. Arum maculatum, 31. Aspidium filix femina, 36. Aspidium filix mas, 36. Asta Spring, Yellowstone National Park, 78. Atchison Electric Light Well, Kans., 53. INDEX. 135 Atchison, Kans., spring, 86. Atchison Parker's Spring, Kansas, 53. Atherosperma moschatum, 48. Atlantic coastal plain, United States, artesian wells, 68. Atropa belladonna, 27. Aube River, Etufs, France, 103. Auditorium, Chicago, 111., artesian well, 91. Augenquelle, Elster, Germany, 122. Austin's Springs, Tennessee, 107. Australasian mineral waters, 94, 95. Auvergne, France, springs, 128. Azemar Spring, Bagneres-de-Luchon, France, 73. Bachquelle, Teinach, Germany, 72. Bad Griesbach, Germany, spring, 118. Bad Jeni-Kaplidja, Anatolia, Asia Minor, spring, 118. Bad Marienborn, spring, 12 1. Bad Wendig, Ries, spring, 124. Bademli Baghtsche, Brusa, Asia Minor, spring, 121. Baden-Baden, Germany, spring, 101. Badequelle, Paderborn, Germany, 59. B. B. Mineral Spring, Mo., 66. Bagneres-de-Bigorre, spring, France, 60. Bain Romain, Plombieres, France, 82. Bain tempere, Plombieres, France, 82. Banana-tree sap, 18. Banja Visegrad, Bosnia, 97. Baobab fibers, 19. Barley, 45. Barley sprouts, 23. Barragan, New South Wales, spring, 99. Barringun, New South Wales, artesian well, IOO. Bat manure, 50. Bath Alum Spring, No. i, Virginia, 106. Bath Alum Spring, No. 2, Virginia, 106, no. Bath Alum Spring, No. 3, Virginia, 113. Bayard, Hauterive (Allier), France, spring, 103. Bayen Spring, Bagneres-de-Luchon, France, 73. Beans, 34. Bear River Hot Springs, Utah, 109. Beaupreau Spring, France, 52. Beck's Hot Spring, Salt Lake City, Utah, iiS. Bed straw, 38. Bedford Bowling Alley Spring. Pennsylvania, 67. Bedford Iron and Alum Springs, Virginia, HO. Bedford Magnesia Spring, Pennsylvania, 67. Beech, 40, 41. UNIVERSITY I OF J ^&SS0S INDEX. Beef. 50. Beehive Geyser, Yellowstone National Park, 78. Beet sugar, 25. Beets, 14. Belabula River, New South Wales, 99. Belladonna leaves, 23, 27. Bellety Steel Spring, Sail-les Chateaumorand, France, 81. Belvedra Spring, Chur, Switzerland, 83. Bench Spring, Yellowstone National Park, 78. Bergstrasse Stahlquelle, Weinheim, Germany, 101. Bermuda-grass roots, 7. Bernhard Spring, Krankenheil-Tolz, Germany, 74. Bethesda Springs, Waukesha, Wis., 108. Betula alba, 41. Big Bone Springs, Kentucky, 65, 127. Billecul Spring, Besan9on, France, 69. Bimbia, Africa, spring, 116. Birch, 40. Birch fungus, 43. Birch sap, 26. Birchdale Spring (Concord Spring), New Hampshire, 105. Birken schwamms, 1 6, 43. Birresborn. Pelm, Germany, spring, 125. Bitter Wasser, Ofen, Germany, 54. Bitterwasser, Weilutza, Roumania, 87. Bixa orellana, 15. Black Earth Mineral Springs, Wisconsin, 108. Black thorn, 32, Black truffle, 29. Blanche, Bagneres-de-Luchon, France, spring, 73. Bled et Amax, Sahara, Africa, well, 87. Bleville, France, spring, 98. Blocksberg Mountains, Germany, spring, 54. Blodgett's Springs, California, 63. Bloodroot rhizome, 23. Blossburg Spring, Pennsylvania, no. Blueberries, dried, 21. Blue Lick Springs, Mo., 66. Blue Ridge Springs, Virginia, 67, 106. Blue thistle, 14. Boiler Bath (Old Ladies' Boiler Bath Hot Spring), Virginia, 106. Boletus edulis, 15. Bologna, Italy, spring, 60. Bolschoi, Slawinsk, Poland, spring, 102. Bondonneau, France, spring, 81. Bonifaciusquelle, Neuhaus, Germany, 92. Bouillants Spring, Vergeze, France, 58. INDEX. 137 Borax Lake, California, 55. Bordeu No. 4 Spring, Bagnereres-de-Luchon, France, 73. " Borhegyer Sauervvasser," Austria-Hungary, 54. Borland Mineral Well, West Virginia, 113. Bormio, Italy, spring, 114. Bosquet, Bagneres-de-Luchon, France, spring, 129. Bourke Corrella Station, New South Wales, artesian well, 99. Botirke, New South Wales, artesian well, 99. Bovista gigantiza, 27. Bowden Lithia Springs, Georgia, 65. Bowsher Mineral Spring, Missouri, 109. Box elder leaves, n. Bradford Mineral Spring, New Hampshire, 66. Bradford, Mass., wells, 70. Bratton Spring, Missouri, 113. Bray era anthelmintica, 17- Bread, 3, 4, 5, 39, 45- Bregille Spring, Besancon, France, 69. Brestowacka banja, Servia, 93. Briscous Salt Wells, France, 59. Bristol, Pa., spring, 76. Bromus seca/inus, 29. Broom sedge, 14. Brucourt, France, spring, 61. Bryony root, 18. Brodelbrunnen, Pyrmont, Germany, 74. Broken Hill Brewery, New South Wales, well, 99. Broken Hill Quarry, New South Wales, artesian well, 99. Bromo-magnesium Well, Kansas, 53. Bronislaw Spring, Truskawice, Galicia, 80. Brown's Wells, Springs, Mississippi, 66. Briihquelle, Baden. Germany, 59. Briinnlein (Urquelle), Trentschin Toplitzer Bad. Austria-Hungary, 89. Brunthaler, 129. Briix. Austria-Hungary, artesian well, 120. Buckhert's Fountain, Wisconsin, 108. Buckwheat, 45. Budos (Balvanyos). Siebenbiirgen, spring, 96. Biidos (Stinkberg), Bosnia, spring, 96. Buffalo Lithia Springs, Virginia, no. Bukowik, Servia, spring, 93. Bullicame, Viterbo, Italy, springs, 116. Burdett Mineral Wells, Texas, 67. Burge Malo, spring, 122. Burr Oak Spring, Kansas, 53. Burtscheid, Germany, spring, 128. Bushnell Railroad Well, Illinois, 91. INDEX. Butterworth's Magnetic Spring, Grand Rapids, Mich., 88, 108. Buxton, England, spring, 123. Cacao. 9. Caledonia Springs, Ontario, 127. California Geysers, Acid Spring, 63. California Geysers, Alum Spring, 63. California Geysers, Devil's Teakettle, 63. California Geysers, Hot Sulphur Springs, 63. California Geysers, Indian Spring, 63. California Geysers, Iron Spring, 63. California Geysers, Iron Spring, Geyser Creek, 63. California Geysers, Lemonade Spring, 63. California Geysers, near Indian Spring, 63. California Geysers, Mud Indian Spring, 63. California Geyser Spring, near river, 63. California Geysers, Witches' Caldron, 63. California Geysers, Seltzer Spring, 127. Calisaya bark, 23. Calistoga Springs, California, 63. Calistoga Swimming Pool, California, 63. Calluna vulgar is, 41. Calumba roots, 23. Camborne, Cornwall, England, spring, 114. Cane sugar, 25, 38. Cape Town, Africa, spring, 80. Capon Beauty Spring. West Virginia, 106. Capon Main Spring, West Virginia, 106. Capioma Mineral Well, Kansas, 53. Capsella burs a past or is. 13. Capsicum, 7. Carabana, Spain, spring, 54. Carbondale Spring, Kansas, 53. Cardamon, 17. Cardamon seeds and husks, 44. Carica papaya, 28. Carlsquelle, Bad Helmstedt. Germany, 75. Carlsquelle, Iwoniez, Austria-Hungary, 116. Casarbad, France, spring, 90. Cascara bark, 23. Cass River, Michigan, 88. Castalia, Ohio, spring, 60. Castanea leaves, 23. Casteggio, Italy, spring, 69. Castilian Mineral Spring, Mississippi, 66. Catoosa Springs, Georgia, in, 112. Cave Springs, Virginia, no. INDEX. 139 Cawker City, Kans., spring, 54. Caxton, Canada, springs, 83, 127. Ceanothus americanus, 9. Cedar Springs, Washington Spring, Ohio, 107. Centralia Gypsum Well, Kansas, 53. Centralia, Kans., well, 86. Ceratonia siliqtia, 30. Cercle, Rennes-les-Bains, France, spring, 129. Ceresole Reale, Italy, spring, 100. Cervena-Rjeka-Quelle, Srebrenica, Bosnia, 96. Cetraria islandica, 41. Cetrarid, 16. Ceyssat, France, spring, 124. Chadnor Villa, Cheltenham, England, well, 124. Chalybeate Springs, Georgia, 112. Champion Spouting Spring, Saratoga, N. Y., 105. Charleston, S. C., artesian well, 121. Chatelguyon, Puy-de-D6me, France, spring, 103. Chaumaix, France, spring, 90. Cheken leaves, 19. Cherokee City Well, Kans., 53. Cherokee Magnetic Mineral Spring, Iowa, 109. Cherries, 21. Cherry Valley Phosphate Spring, New York, 105. Cheshire, England, springs, 102. Chestnuts, 13. Chickweed, 16, 17. Chimaphila leaves, 23. China flava fibrosa, 30. China huanuco, 30. China regia cum epid., 30. China regia sine epid. , 30. China rubra, 30. "Chine," 17. Chippewa River, Michigan, 88. Chittenango Cave Spring, New York, 105. Chittenango White Sulphur Springs, New York, 105. Chlorangium jussuffii, 16, 22, 29. Choke-cherry bark, 23. Chrome Spring, Yellowstone National Park, 78. Chur, Switzerland, springs, 83. Church Hill Alum Springs, Virginia, in. Cicuta maculata, 1 6. Cider vinegar, 14. Ciechpcinek, Poland, artesian well, 129. Cinchona, 19, 23. Cinchona bark, 25. 140 INDEX. Cinchona offidnali, 19. Cinchona succirubra, 19. Cinnamon bark, 32. City Creek, Utah, 61. Civillina, Italy, spring, 56. Cladonia, 16. Cladonia rangiferina, 41. Cladophora glomerata, 1 6, 29. Clark's Riverside Mineral Springs, Detroit, Mich., 66, 89. Clay, edible, from New Zealand, 131. Cleopatra Spring, Yellowstone National Park, 77. Cliff Spring, Saint-Nectaire le Haut, France, 76. Clifton Spring, No. I. Virginia, 106. Climax Springs, Missouri, 109. Clinton, Miss., well, 61. Club moss, i, 10, 12, 23, 31. Cochineal, 49. Cockle-burr, 17. Cocoa shells, 9. Coe'se, France, spring, 101. Coffee beans, 25. Coffee tree, 25. Colchicum, 30. Cohhicum autumnale, 30. Cold Spring III, Neuenahr, 56. Cold Sulphur Springs, Virginia, 67, in. Coldwater, Mich., well, 89. Columbus Well, Kansas, 53. Coltsfoot, leaves, 8. Columbia Chalybeate Spring, Missouri, 109. Conferva glomerata, 27. Congress Spring, Saratoga, N. Y., 105. Conneautville, Pa., artesian well, 118. Constant Geyser, Yellowstone National Park, 77. Constantine Spring, Gleichenberg, Austria-Hungary, 97. Convolvulus batatas, 1 8. Convolvulus roots, 7. Conway Springs, Kans., 53. Cooper's Well, Mississippi, 112. Coral Spring, Yellowstone National Park, 77. Corella, New South Wales, artesian well, 100. Corncobs, 2. Corn cockle, 12. Corn kernels, 33. Corneliusquelle, Aachen, Germany, 92. Corydalis, 16. Corydalis bulbosa, 16 INDEX. 141 Costalta, Southern Tyrol, spring, 69. Cattani Spring, No. 2, Spolato, 125. Cow's milk, 49. Crenothrix manganifera, 20. Crenothrix kuJmiana, 2O. Crenothrix ochracea, 20. Cresson Alum Spring, Pennsylvania, no. Cresson Iron Spring, Pennsylvania, no. Cresson Magnesia Spring, Pennsylvania, 106. Crisp Springs, Tennessee, 107. Crni Guber, Srebrenica, Bosnia, spring, 97. Crocket's Arsenic-Lithia Springs, Virginia, 67. Crocus, autumn. (See Colchicum.) Crystal Springs, Saratoga, N. Y., 105. Cuckoo-pint leaves, 31. Cullum's Ferruginous Spring, Alabama, 114. Curry Spring, Versailles, 111., 127. Cuttaburra, New South Wales, artesian well, 99, 100. Cuyahoga Lithia and Magnesium Springs, Ohio, 112, 114. Cyathea serra, 10. Cynanchum monspehacum, 20. Czemete, Austria-Hungary, spring, 120. Czifra-viz, spring, 73. Dalton, Mass., artesian well, 71. Damont, Rennes-les-Bains, France, spring, 129. Dandelion, 32, 33, 40. Davenport, la., glucose factory, artesian well, 91. Davis Mineral Well, Kentucky, 112. Dead Sea, 54, 119. Deer Lick Spring, New York, 66. Dekalb, 111., water-works, artesian well, 91. Delaware River, New Jersey, 129. Deloraine, Manitoba, artesian well, 126. Des demoiselles, Rennes-les-Bains, France, spring, 129. Detroit River, Michigan, 87, 88. Devil's Ink Pot, Yellowstone National Park, 78. Dianthns caryophyllus, I. Dicksonia squarrosa, 1 1. Digitalis leaves, 23. Dintenquelle, Teinach, Germany, 72. Director Spring, Starja-Russa, 102. Dixie Mineral Spring, Tennessee, 67. Dixon, 111., water- works, artesian well, 91. Dixon Spring, Kansas, 53. Dock, 14. Dog-bane, 20. M 2 INDEX. Dolnj-Tuzla, Bosnia, springs, 96. Donatusquelle, Albulathale, 115. Donionidi, Sahara, Africa, well, 87. Dorna-Sara Arsenic Spring, Roumania, 116. Doubs River, France, 56. 69. Doulaux, France, spring, 90. Dougherty's Carbonic Acid Spring, British Columbia, 86. Driburg, Germany, spring, 127. Dropping Well, Knaresborough, England, 59. Dubois (Allier), Vichy, France, spring, 103. Dudley, England, wells, 124. Dulimbert Spring, Vergeze, France, 55. Diingle Ridge, New South Wales, artesian well, 100, Durkheim, Germany, spring, 59. Dwarf pine, 41. Earth ball from a horse, 131. Earth, edible, from Berbek. Java, 131. . Earth, edible, from Fiji, 131. Earth, edible, from Japan, 131. Earth, edible, from Ponoi, Lapland, 131. Eastern Bohemia, mineral waters, 85. Eastman's Springs, Michigan, 66. East Saginaw, Mich., well, 89. East Spring, Joplin, Mo., 82. East Spring, Langenbruck, Austria-Hungary, 77. Echium vulgar e, 14. Echinus Spring, Yellowstone National Park, 77. Eckholzquelle, Ronneby, Sweden, 80. Eddoes. (See Taro.) Eel grass, 2, 16. Egg albumen, 50. Einsiedel, Austria-Hungary, spring, 98. Eisenquelle von Uebersaxen, Voralberg, Austria-Hungary, 8 C ; Eisenwasser Bad Andelsbuch, Voralberg, Austria-Hungary, 87. Eisenwasser des Bad Reuthe, Voralberg, Austria-Hungary, 87. Ekaterinoder, in the Caucasus, spring, 129. Elder, 19, 42. Eleusine indica, 14. El Feter, Sahara, Africa, well, 87. El-Hadjira, Sahara, Africa, well, 87. Elizabethquelle, Carlsbad, Austria-Hungary, 97. Elizabethenquelle, Neuhaus, Germany, 92. Elizabethenquelle, Rothenfels, Germany, 58. Elm bark, 23. El Paso de Robles Hot Sulphur Spring. California, no. El Paso de Robles Main Sulphur Spring, California, 63. INDEX. 143 El Paso de Robles Soda Spring, California, 63. Emmaquelle, Gliechenberg, Austria-Hungary, 79. Emperador, Panama, well, 51. Empire Mine, swallet, 54. Empire Spring, Saratoga, N. Y., 60, 105. Enclos des Celestins, Vichy, France, spring, 90. English ivy, 7. English walnut bark, 35. Equisetum maximum, IO. Equisetum telmateja, 26. Ergot, 18, 29, 37. Erica vulgar is, 1 6. Estill Springs, Black Sulphur Spring, Kentucky, 112. Estill Springs, White Sulphur Springs, Kentucky, 107. Etufs, France, spring, 103. Eucalyptus, 34. Eiicalyptus globulus, 34. Eucalyptus ro strata, 34. Euphorbia amygdoloides, 42. Eureka Mineral Well, Kansas, 53. Eureka Springs, California, 63. Eureka Spring, Saratoga, N. Y., 105. Eureka Springs, Wisconsin, 108. Everett Spring. Massachusetts, 70. Excelsior Geyser, Yellowstone National Park, 78. Excelsior Springs, Missouri, 54, 66, 99, 127. Excelsior Well, Benton Harbor, Mich., 89. Faculte des Sciences, Besan9on, France, well, 69. Fagus sylvatica, \\. Fairview Springs, Texas, 112. Farmville Lithia Springs, No. 2, Virginia, 106. Farmwell Station, Va., springs, 118. Farnham, England, spring, 79. Fearless Geyser, Yellowstone National Park, 77. Felsenquelle, Bad Ems. Germany, 75, 122. Felsenquelle, Carlsbad, Austria-Hungary, 97. Felsenquelle, near Bassen, Austria-Hungary, 73. Felt's Mineral Springs, California, 63. Ferdinand Spring, Marienbad, Austria- Hungary, 76. Fern root-stalks, 34. Fern roots, 36. Ferrara, Italy, spring, 60. Ferras Spring, Bagneres-de-Luchon, France, 73. Fidelisquelle, Bosnia, 96. Fig leaves. 42. Fir bark, dry, 22. 144 INDEX. . Fir cones, dry, 22. Fir moss, 22. Fir needle litter, 22, 39. Fir needles, 21, 22. Fir twigs, 22. Firehole River, Yellowstone National Park, 78. Fitzpatrick, Ala., artesian well, 118. Flat Rock Spring, Saratoga, N. Y., 105. Flax stems, 20. Flit wick Moor, spring, 85. Floating buttercup, 32. Flour, 2, 3, 14, 28. 38, 46. Flowing Spring, Kansas, 109. Fojnica. Bosnia, spring, 97. Fontinalis antipyretica, 10, 36. Fort Crawford Mineral Spring, Wisconsin, 68. Fort Scott Sulpho-magnesian Well, Kansas, 53. Fountain Geyser, Yellowstone National Park. 68, 78. Fountain Springs, Wisconsin, 108. Framingham, Massachusetts, springs, 70. Frangula bark, 23. Franklin Artesian Well, Ballston Spa, N. Y., 105. Franklin Spring, Georgia, 65. Franz-Joseph-Bad, Tiiffer, Austria-Hungary, 127. Franz Joseph Quelle, Fiired, Austria-Hungary, 81. Fraysse, Cransac, France, spring, 81. French Lick Springs. Pluto's Well, Indiana, 112. Friedensquelle, Rostenberg, Germany, 98. Friedrichshall, Germany, spring, 54. Friedrichshall, Germany, spring. 92. Friedrichsquelle, Zeidelweid, Austria-Hungary, 85. Fry's Mineral Spring, Iowa, 65. Fulbrunnen, Wiesbaden, Germany, spring, 114. Fungus, edible, 27. Furstenbrunnen, Ems, Germany, 74, 75. Galbraith's Spring, Tennessee, 107. Galdhof, Seelowitz, Austria-Hungary, spring, 102. Galena, 111., water- works, artesian well, 91. Galium mollugo, 38. Garden pink, I. Garden rose, I. Gardiner River, Yellowstone National Park, 77. Gasquelle, Elster, Germany, 122. Gastrolobium bilobwn. 15. Gata, Bosnia, spring, 96. Gaylord and Gulick's Mineral Spring. Pennsylvania, 67, no. Geilnau, Nassau, Germany, spring, 74. INDEX. H5 Gelsemium root, 23. Geneseo, 111., water-works, artesian well, 91. Geneva Lithia Spring, New York, 66. Georgenbrunnen, Bad Eilsen. Germany, 76. Geranium rhizome, 23. Gerlosteiner Schlossbrunnen, Pelm, Germany, 125. Germania Spring, Schwalheim, Germany, 123. Gettysburg Lithia Spring, Pennsylvania, 106. Geuda Springs, Kansas, 53, 65. Geyser Mine, Custer County, Colorado, 71. Geyser Mineral Well, Kansas, 53. Giantess Geyser. Yellowstone National Park, 78. Gibson Springs, Wisconsin, 108. Giesshiibler, Rodisfort, Germany, spring, 78. Glacier Spouting Spring, Saratoga, N. Y., 60, 119. Glen Alpine Springs, California, 63. Glen Flora Springs, Illinois, 108. Glen Springs, Wisconsin, 108. Glenola (Wayland) Spring, Virginia, 67. Glycyrrhiza root, 23. Gmunden Lake, Austria-Hungary, 77. Golden seal root, 16. Gombert's Well, Wisconsin, 108. Gordon Springs, California, 63. Gorni Sehar, Bosnia, spring, 96. Gosling's Garden, Osnabriick, artesian well, 86. Gradacac, Bosnia, spring, 96. Grand Haven Mineral Spring, Michigan, 108. Grand River, Jackson, Mich., 88. Grand Rue Spring, Besangon, France, 56, 69. Grande Grille, Vichy, France, spring, 103. Grande Source, Pougues-les-Eaux, Nievre, France, 103. Grande Source, Vittel, France, 100. Granier Spring, Vergeze, France, 55. Grape branches, 31. Grape juice, 6, 27. Grape leaves, 31, 38. Grape must, 31. Grape seeds, 16. Grape wood, 27. Grapes, 24, 26. Grapevines, 17, 30, 38. Grassion Spring, Clermont, France, 103. Gravesend, England, spring, 79. Great Bend Mineral Well, Kansas, 53. Great Fountain Geyser, Yellowstone National Park, 78. Great Paraiso Hot Soda Springs, California, 64. 146 INDEX. Great Salt Lake, Utah, 102. Great Spirit Spring, No. 2, Kansas, 53. Greenbrier White Sulphur Springs, West Virginia, 106, in, Green Mineral Spring, Ohio, 107. Greensborough Spring, North Carolina, 107. Greuillea robust a, 26. Grossluder Spring, Salzschlirf, Germany, 117. Grotte inferieure, Bagneres-de-Luchon, France, spring, 73. Grotte superieure, Bagneres-de-Luchon, France, spring, 73. Grotts Geyser, Yellowstone National Park, 78. Guarana paste, 28. Guarana seed, 23, 28. Guarana shells, 28. Gueuzayasma, Brusa, Asia Minor, spring, 121. Guillot Spring, Evian, France, 101. Gyrenbad, Switzerland, spring, 124. Gyrophora, 16 Gyrophora pustulata, 22, 41. Racket's Spring, Wisconsin, 108. Haddon Mineral Well, Kansas, 109. Hall, Austria-Hungary, spring, 101. Halowell Grant Spring, Nova Scotia, 51. Harbin Chalybeate Spring, California, 63. Harbin Hot Sulphur Spring, California, 63. Hart Well, West Virginia, 68, 113. Hartford Cold Springs, Maine, 105. Hartford, Conn., spring, 58. Harris Antidyspeptic and Tonic Springs, Virginia, 67. Hartsel Hot Mineral Springs, Colorado, 109. Hartivegia comosa, 43. Hathorn Spring. Saratoga, N. Y., 105. Hauptbrunnen, Miinster, Germany, 124. Hauptquelle, Gastein, Austria-Hungary, 97. Hauptquelle, Neuhaus, Austria-Hungary, 79. Haupt-Trinkquelle, Stuttgart, Germany, 72. H. Dahne, Sahara, Africa, well, 87. H. Debiche et Strifigi, Sahara, Africa, well, 87. Heather, 16, 41, 43. Heilbrunnen, near Lake Taach, 55. Helianthus annuus, 43. Helicon Springs, Georgia, 107. Hellibore rhizome rootlets, 23. Hemlock bark, 2. Hemp, refuse, 8. Hermannsquelle, Neuhaus, Germany, 92. Herniaria glabra, 43. INDEX. 147 Herster, Driburg, Germany, spring, 74. Hertfell Spring, Scotland, 85. Hickman's Springs, Kentucky, 112. Hides, 50. High Rock Spring, Saratoga, N. Y., 105. Highland Dutch or Ems Spring, California, 64, no, Highland Magic Spring, California, no. Highland Seltzer Spring, California, 64, no. Hildegarde Spring, Ofen, Austria-Hungary, 119. Hindhead, England, springs, 79. Hirschquelle, Teinach, Germany, 72. H. Messaoud, Sahara, Africa, well, 87. Hohenbrunnerfilz. 129. Holly leaves, 30. Homburg, Germany, artesian well, 82. Honey, 9. Honeysuckle berries, 15. Hop blossoms, 39. Hops, 9, 23, 40. Horeb Springs, Wisconsin, 108. Horse bean, 18. Horse chestnut, 35. Horsetail, 10, 26. Hosea Saline Sulphur Spring, Indiana, 113. Hot Borate Spring, California, 64. Hot River. Yellowstone National Park, 77. Hot Spout Bath, Virginia, 106. Hot Spring, Savo Island, 93. Hot Springs, Arkansas, 107. Hot Springs, Hot Springs Station, Nevada, 61, 113. Hot Springs, Monte Irone, Albane, Italy, 101. Howard Springs, California, 64. Hroswithaj Herzogludolfsbad, Germany, spring, IO2. Hughes' Mineral Well, Georgia, 65. Human milk, 49. Humboldt River, Nevada, 60, 119. Humboldt's Salt Well, Minnesota, 109. Hunter's Hot Spring, Montana, 109. Hunter's (Pulaski) Alum Springs, Virginia, 67. Hurricane Springs, Tennessee, 107. Hyacinth, 38. Plyacinthus orientalis, 38. Hyde Park, Mass., artesian wells, 70. Hyde Park, Mass., wells, 70. Hydrangea. 8, 23. Hydrangea arborescens, 8. Hydras Us canadensis, 1 6. INDEX. Hydrastis rhizome, 23. Hygeia Springs, Wisconsin, 108. Hygeia Spring, Yellowstone National Park, 78. Hyoscyamus leaves, 23. Iceland moss, 41. Ida Spring, Biloves, Austria- Hungary, 101. Idjen volcano, Java, lake, 73. Ilex aquifolium, 30. Ilidze, Bosnia, spring, 96. Illicium anisatum, 32. Indian fig. (See Prickly pear.) Indan-Ha Spring, Idaho, 65. Indian Medical Spring, Minnesota, 66. Indian Spring, Indiana, 65, 113. Ingol, Lake, Russia, 130. Iodine Donatus, Solis, 115. lodo-Magnesian Springs, Wisconsin, 108. Iowa Acid Spring, 109. Irondale Springs, West Virginia, in. Iron Lithia Springs, Virginia, 68. Iron Spring, Milford, N. H., 105. Iron-Sulphur Spring, Sail-les-Chateaumorand, France, 81. Isar River, Germany, 36. Isere River, France, 79. Jacob's Artesian Well, Wisconsin, 108. Jalap, 23. James River, Richmond, Va., 118. Jamnicer-alkalisch-muriatischen Sauerlings, 84. Jarvisville, New South Wales, spring, 99. Jeanne d'Arc, Pougues-les-Eaux, Nievre, France, spring, 103. Jeanne d'Arc (Allier), Vichy, France, spring, 103. Jenkins's Quarry, New South Wales, spring, 99. Jenolan Caves, New South Wales, spring, 99. Jenzat, France, springs, 90. Jerseyville, 111., waterworks, artesian well, 91. Johann-Georgen Spring, Krankenheil-Tolz, Germany, 74. Johannis Spring, Stainz, Austria-Hungary, 117. Johannes Springs, Steiermark, Austria-Hungary. 79. Johannesbad, Vienna, Austria-Hungary, spring, 82. Johannbrunnen, Luhatschowitz, Austria- Hungary, 72, 85. Johannisbrunnen, Mahren, Germany, 95. Johnson's Wells, Alabama, 107. Jordan Alum Springs, Virginia, 106, in. Jordan White Sulphur Springs, Virginia, 106. Jordan's Mineral Well, Wisconsin, 108. INDEX. 149 Josefsquelle, Bilin, Austria-Hungary, 83. Josephsquelle, Rippoldsau, 128. Judenquelle, Baden. Germany, 59. Julianenbrunnen, Bad Eilsen, Germany, 76. Jute fiber, 7. Kaba Mountain, East India, spring, 98. Kaiserbrunnen, Carlsbad, Austria-Hungary, 97. Kaiserquelle, Aachen, Germany, 92. Kalmia latifolia, 26. Kamenewquelle, Psekoup, 122. Kane County Magnesia Spring, Illinois, 65. Kane Sulphur Spring, Pennsylvania, 106. Kantavu, Fiji Islands, spring, 93. Karlsbad Sprudel, Austria-Hungary, 78. Karlsquelle, Bosnia, 96. Karmalinquelle. Psekoup, 122. KaTtner Romerquelle, Prevail, Austria-Hungary, 86. Kasimer Slawinsk, Poland, spring, 102. Katharien-Bad, Karnthen, Austria-Hungary, 100. Kava root, 17. Kellberg, Germany, spring, 61. Kelly's Camp, New South Wales, artesian well, 99. Kentucky Alum Springs, 112. Kesselbrunnen, Ems, Germany, 74, 75. Keystone Spring, Maine, 65. Kickapoo Springs, Kansas, 53. Kidwell's Quarry, New South Wales, spring, 99. King David Spring, Ben ton Harbor, Mich., 88. Kingswood, England, spring, 52. Kirchdrauf in der Zips, Austria-Hungary, spring, 120. Kirouars, France, spring, 57. Kittanning Mineral Spring, Pennsylvania, no. Klebelsberg Spring, Ischl, Austria- Hungary, 69. Kleininger Sauerbrunnen, Karnthen, Austria Hungary, 100. Klosteralleequelle, Pyrmont, Germany, 75. Kochbrunnen, Wiesbaden, Germany, 74. Koeningan, East India, spring, 98. Kola-nut, 23. Kolop Sulphur Spring, Austria-Hungary, 91. Kondran, Germany, spring, 124. Konig Ferdinand Eisenbad, Weidritzthal, Austria-Hungary, 127. Konigsbrunnen, Krostreinitz. Austria-Hungary, 79. Kostreiniz, Steiermark, Austria-Hungary, spring, 82. Kousso, 17. Krahnchen, Ems, Germany, 74. 75. Kronenquelle, Salzbrunn, Germany, 116. * 50 INDEX. Krynica, Austria-Hungary, spring, 69. Kukurtlu, Brusa, Asia Minor, spring, 121. Kulasi, Bosnia, spring, 96. Kuttawa Mineral Springs, kentucky, 107. La Bernerie, France, spring, 57. La Reine Spring, Bagneres-de-Luchon, France, 73. Labrador tea, 2. Lacquer (Uruski), 44. Lagrange, Mo., Wyaconda, artesian well, 91. Lakatah Springs, South Dakota, 67. Lake Derkol, Turkey, 122. Lake Goguac, Michigan, 88. Lake Goodenough, British Columbia, 126. Lake Michigan, Chicago, 111., 89. Lake Superior, Michigan, 88. Lamscheider, Mineralbrunnen, Germany, 75. Landreth's Mineral Well, Missouri, 109. Lane Mineral Springs, California, 64. Lansdowne Well, Cheltenham, England, 124. Larch needles, 20. Las Vegas Hot Spring, New Mexico, 66. Lauderdale Springs, Mississippi, 107. Laurel root, 26. Lawrence, Mass., sewage, 70. Leather, 49. Lebanon, Mo., artesian well, 71. Lebanon Thermal Spring, New York, 105. Ledum palustre, 2. Lee County, Virginia, spring, 121. <( Legen," 40. Leontodon taraxacum, 40. Leopoldsquelle, Rippoldsau, 128. Lichen, 41. Liebenzell, Wilrttemberg, Germany, 72. Lilac flowers and leaves, 42. Linden leaves, 7. Lindenbrunnen, Zlatten, Austria-Hungary, 58. Lincoln Springs, Kansas, 53. Lineville Mineral. Springs, Iowa, 65. Lippa, Austria -Hungary, spring, 119. Lithium Spring, Omio, Kans., 53. Litton Seltzer Springs, California, 64. Llangammarch. spring, 86. Loc'endol, Austria-Hungary, well and spring, 84. Loch Katrine, Scotland, 126. Loire River, Orleans, France, 69. INDEX. 1 5 I London, England, water supply, 79. Londonderry Lithia Spring, New Hampshire, 66. Long Island, southern shore, wells, 84. Lonicera xylosteum, 15. Lorain, Ohio, artesian well, 93. Los Angeles, Cal., river, 119. Louisenquelle, Luhatschowitz, Austria-Hungary, 72, 85. Lupine leaves, 7. Luxeuil Springs, France, 58, 70. Lycopodium, 43. Lycopodium powder, 23. Lycopodium alpinum, 10, 29. Lycopodium annotinum, 12. Lycopodium billardieri, 10. Lycopodium cernuum, 10. Lycopodium c^hamaecyparissus, I, 16, 29, 31. Lycopodium clavatum, I, 10, 16, 23, 31. Lycopodium complanatum, 26, 31. Lycopodium denticulatum, 34. Lye opodinm phlegmaria, 10, 29. Lycopodium selago, 10. Macomb, 111., water-works, artesian well, 91. Madeleine Spring, No. I, Rennes-les-Bains, France, 129. Madeleine Spring, No. 2, Rennes-les-Bains, France, 129. Maes a picta, I. Magdalen Spring, Cayla, France, 93. Magnetic Mineral Spring, Indiana, 65. Magnetic Spring No. 2, Riverside, Mich . , 108. Mala Kiselica, Srebrenica, Bosnia, spring, 97. Maiden, Mass., tubular wells, 70. Mammoth Hot Springs, Yellowstone National Park, 77. Mandarin orange, 30, 31. Manistee Lake, Michigan, 88. Manitou Soda Springs, Colorado, 64, 65. Mansfield, Mass., well, 70. Marblehead, Mass., wells, 70. Marblehead, Water Company, Swampscott, Mass., wells, Mardela Spring, Maryland, 65. Marden's quarry, New South Wales, spring, 99. Maria Island, spring, 90. Maria Theresia Quelle, Andersdorf, Austria-Hungary, 96. Marien Sprudel Spring, 56. Marienbrunnen, Gabernegg, Austria-Hungary, 78. Marienquelle, Johannisbrunn, Austria-Hungary, 97. Marienquelle, Neuhaus, Germany, 92. Marienquelle, Paderborn, Germany, 59. IS 2 INDEX. Marienquelle, Psekoup, 122. Marine Algae, 27, 29. Marion Artesian Well, Indiana, 108. Mark West Springs, California, 64. Marktbrunnen, Carlsbad, Austria- Hungary, 97. Marktsoole, Colberg, Germany, 55. Marsilea quadrifoliata, IO. Marston, England, spring, 102. Massanetta Mineral Springs, Virginia, 68, 106. Matchless Mineral Wells, Alabama, 63. Mattigbad, Austria-Hungary, spring, 89. Maxbrunnen, Kissengen, Germany, 92. McDuff 's Spring, Kansas, 53. Mechanicsville, N. Y., spring, 79. Medical Lake, Washington, no. Medicis Spring. Saint-Denis, France, 81. Melle, Germany, artesian well, 123. Melle, Germany, spring, 123, Melrose, Scotland, spring, 69. Mergentheim, Germany, spring, 92. Meriweather County Warm Springs, Georgia, 65. Merrill Spring, Kansas, 53. Meurchin, Pas-de-Calais, France, spring, 78. Michailquelle, Psekoup, 122. Midland Magnetic Well, Michigan, 113. Midland Mineral Spring, Michigan, 88. Middle or Dewdrop Spring, Greencastle, Ind., 108. Middletown Springs, No. I, Vermont, 105. Midway Warm Springs, Utah, 67. Milboro Sulphur Spring, Virginia, 68. Millet, 45. Millingtonia hortensis, 19. Mineral Spring, No. I, Versailles, III., 108. Mineral Springs, Farmwell Station, Va., 106. Mineral Springs, Hanover, Pa., 106. Mineral Well, Pierre, S. Dak., 109. Minnequa Springs, Pennsylvania, 67. Mississippi River water, 52, 116. Mitterbad, Tirol, spring, 55. Modling, Austria-Hungary, spring, 120. Mofetta di S. Quirico, Tuscany, Italy, spring, 102. Monmouth, 111., water-works, artesian well, 91. Mono Basin, California, spring, 61. Mono Basin Warm Springs, California, no. Mono Lake Spring, California, 64. Monterey, Mexico, spring, 89. Montezuma, Ga., artesian well, 118- Montezuma, Ind., artesian well, 91. INDEX. 153 Montpellier, France, spring, 100. Montvale Springs, Tennessee, 107. Morchella esculent a, 1 6, 29. Morel, 16, 29. Moresville Mineral Springs, Missouri, 113. Moriz Spring, Rohitsch, Austria-Hungary, 58. Morphine, 21. Moss, 10, 43. Moss Springs Well, Kansas, 53. Mouillere, Besan9on, France, spring, 69. Mountain raspberry, 7. Mount Clemens Clementine Well, Michigan, 89. Mount Clemens Media Spring, Michigan, 108. Mount Clemens Media Well, Michigan, 89 . Mount Clemens Mineral Well, Michigan, 108. Mount Clemens Original Well, Michigan, 89. Mount Clemens Soolbad Spring, Michigan, 108. Mount Mineral Spring, Shutesbury, Mass., 71. Miihlbrunnen, Carlsbad, Austria-Hungary, 97. Miihlbrunnen, Ober-Salzbrunn, Austria-Hungary, 125. Miillaken, Upper Austria, springs, 71. Mullein, 14. Munger's laundry, Chicago, 111., artesian well, 91. Murquelle, Baden, Germany, 59. Musa paradisica, 18. Mushroom, edible, 15. Muskegon Lake, Michigan, 88. Mush Pot Spring, Yellowstone National Park, 78. Myrtle leaves and stems, 15. Myrtus cheken, 15- N'Gon9a, Sahara, Africa, well, 87. Naiwaschasee, Massailand, East Africa, spring, IOI. NatronsSuerling, Nassau, Germany, 101. Natural soda-water, Passug, 115. Navioci, Bosnia, spring, 96. Neponset River, Hyde Park, Mass., 70. Neubrunnen, Carlsbad, Austria-Hungary, 97. Neubrunnen, Radein, Austria-Hungary, 117. Neue Badequelle, Ems, Germany, 75 . Neue Belvedraquelle, Switzerland, 83. Neuenhainerquelle, Nassau, Germany, 60. Neue Quelle, Ems, Germany, 74. Neue Quelle, Mahren, Germany, 95. Neue Stahlquelle, Lobenstein, Germany, 117. Neumarkt, Germany, spring, 58. Neuragozi, Germany, spring, 123. 154 INDEX. New Baden Spring, Missouri, 109. New Hot Spring, Virginia, 106. New Jersey tea, 9. New Johannes Spring, Neuhaus, Austria-Hungary, 79. New Putnam Spring, Saratoga, N. Y., 105. New Spring, St. Moritz, Switzerland, 83. Newsonis Arroyo Grande Springs, California, 64. Neyrac, France, spring, 90. Niederbronn, Germany, 72, 87. Nieder Langenau, spring, 1 16. Niederselters, Germany, spring, 75. Nochemo Spring, Reed City, Mich., 88. North Carolina Hot Springs, 67. North or Daggy Spring, Greencastle. Ind., 107. O Tura Sauerling, Austria-Hungary, 127. Oak Orchard Acid Springs, New York, no. Oak Orchard Acid Water, New York, no. Oats, 18. Oberbrunnen, Ober-Salzbrunn, Germany, 76, 125. Oberbrunnen, Flinsberg, Silesia, 116. Oberquelle, Bussang, France, 128. Ochsenhausen, Bieberach, Germany, spring, 73. Octagon Bath, Virginia, 106. Oestringer, Langenbrllcken, Germany, spring, 127. Ofener Rakoczy Bitterwasser, 125. Ohe River, 36, 129. Ohio Magnetic Spring, 107. Ojo Caliente, N. M., spring, 82. Old Alum Well, Harrowgate, England, 68. Old Faithful Geyser, Yellowstone National Park, 78. Old Johannes Spring, Neuhaus, Austria-Hungary, 79. Old man's beard, 41. Old Spring, St. Moritz, Switzerland, 57, 83. Olgaquelle, Psekoup, 122. Olympian Salt Sulphur Spring, Kentucky, 107. Olympian White Sulphur Spring, Kentucky, 107. Ophelia chirata, 19. Ophiglossum vulgatum, 10. Opium, 39. Opuntia vulgaris, 25. Orange peel, 25. Oranien Quelle, Kreuznach, Germany, 54. Orchard Alum Spring, England, 123. Orchesterquelle, Carlsbad, Austria-Hungary, 97. Orezza, Island of Corsica, spring, 116. Orites excelsa, 33. INDEX. 155 Orkney Bear Wallow Spring, Virginia, in. Orkney Healing Spring, Virginia, in. Orkney Powder Spring, Virginia, in. Ostgothenquelle, Bormio, Italy, 80. Ottawa River, Montreal, Canada, 83. Ottilienquelle, Paderborn, Germany, 59. Ouargla, Sahara, Africa, well, 87. Overall Mineral Wells, Texas, 67. Owasso City, Mich., well, 88. Owasso Mineral Spring, Michigan, 66. Owatonna Mineral Spring, Minnesota, 109. Owatonna Vichy Spring, Minnesota, 109. Owens Lake, California, 61, 118, 119. Pacific Congress Springs, California, 64. Pagoda Spring, Mount Clemens, Mich., 89. Pagoda (Napa-Soda) Spring, California, 64. Palanka, Servia, spring, 93. Palmyra Springs, Eye Springs, Wisconsin, 108. Palmyra Springs, Zenobia's Fountain, Wisconsin, 108. Palo Pinto Well, Texas, 107. Panacea Spring, Littleton, N. C., 107. Pandur, Kissingen, Germany, spring, 92. Panic grass, 12. Panicum capillare, 12. Panicum cruscorvi, 45. Panicum italicum, 45. Panicum tnonostachyum, 12. Pantelleria Island, Italy, 58. "Paprika," 7. Paracelsus Spring, St. Moritz, Switzerland, 57. Paramo de Ruiz, New Granada, spring, 92. Parana River, above union with Rio de la Plata, 87. Pareira, 31. Paris, France, melted snow, 124. Park Spring, Wisconsin, 109. Park's Springs, North Carolina, 67, 107. Parmelia scruposa, 40. Paroquet Springs, Kentucky, 1 12. Passaic River, New Jersey, 119. Passy, France, artesian well, 115. Paulaquelle, Mahren, Germany, 95. Paulaquelle, Johannisbrunn, Austria-Hungary, 97. Paullina sorbilis, 28. Pavilion Spring, Saratoga, N. Y., 105. Paw-paw, 28. Pearl Geyser, Yellowstone National Park, 77. 156 INDEX. Peas, 8, 34, 45- Pengalengen Plateau, East India, spring, 98. Peninsula of Methana, spring, 68. Penon de los Banos, Mexico, spring, 92. Pepperwort, 38. Perry Spring, No. 3, Lower Sulphur, Illinois, 114. Peru, 111., water- works, artesian well, 91. Petalostigma quadriloculare, 15* Peterborough County, Ontario, artesian well, 51. Petersquelle, Petersthal, Germany, 58. Petite Source, Challes, France, 128. Pfaefers-Ragatz, Switzerland, spring, 90. Pfister's Spring, Kansas, 109. Phallusia mammilaris, 50. Phaseolus radiatus, 44, 45. Philippsquelle, Orb, Germany, 120. Phytolacca decandra, 15. Piedmont White Sulphur Iron Springs, California, 64. Pinus larix, 20. Pinus pumilio, 41. Pinus sylvestris, 21, 22, 41. Piper methysticum, 17. Piscidia erythrina, bark, 23. Pittsville Wells, Cheltenham, England, 124. Plane tree leaves, 38. Plant ago major. 36. Plantago maritima, 17. Plant ago media, 16. Plantain, 16, 36. Plantain seed, 17. Pliniusquelle, Bormio, Italy, 80. Plums, 37. Poison ivy, 21. Poke weed root, 15. Pokolsar, spring, 73. Poland Star Spring, Maine, 105. Polygonum hydropiper, 38. Polysaccum pisocarpium, 16. Pomegranate root bark, 34. Poncho Hot Springs, Colorado, 65. Pont-a-Mousson, France, spring, 79. Ponte Molle, Italy, spring, 72. Poppy petals, 39. Portion, New South Wales, spring, 99. Portulaca oleracea, 14. Port Vendres, France, subterranean, 71. INDEX. 157 Poschitz, Austria. Hungary, spring, 86. Posidonia oceanica, 33. Potash Sulphur Spring, Arkansas, 61. Potato weed, 14. Prajan Spring. Res. Madioen, East India, 98. Pre No. I Spring, Bagneres-de-Luchon, France, 73. Pre Saint Didier Springs, Courmayeur, Italy, 51. Precieuse (Allier), Vichy, France, spring, 103. Preblauer Sauerbrunnen, Karnthen, Austria- Hungary, 100. Preservatives, 132. Prickly ash bark, 23. Prickly chaff flower, 39. Prickly pear, 25, 30. Primrose, 42. Primula farinosa, 42 . Princess Spring, Caylus, France, 93. Protopterus annectus, 50. Providence Mineral Well, Kansas, 53. Prugnes, France, spring, 93. Prunus cerasus, 21. Prunus domestica, 37. Prunus spinosa, 32. Psekoup Springs, 122. Psilotum triquetrum, 10. Puits Chomel, Vichy, France, spring, 103. Pulaski Alum Spring, Virginia, in. Purslane, 14. Putnam Spring, Saratoga, N. Y., 105. Quelle an der Strasse, Srebrenica, Bosnia, 96. Quelle Marie, Bussang, France, 128. Quelle, No. 19, Katherienbad, Wiirttemberg, Germany, 72. Quelle zu Raggel, Voralberg, Austria- Hungary, 87. Quirinusquelle, Aachen, Germany, 92. Racoczy, Kissingen, Germany, spring, 92. Rafifanelo, Italy, spring, 98. Ragaz-Pfaffers, spring, 115. Ragweed, 14. Rajecz-Toplitz, Austria-Hungary, spring, 77. Raleigh's Mineral Spring, Box Springs, Tennessee, 112. Raleigh's Mineral Spring, Marble Springs, Tennessee, 112. Ramalina fraxinea, 22. Ranigsdorf Sauerling, 85. Ranunculus fluitans, 32. Rape seed, 2. 158 INDEX. Rape straw, 2. Raso, Bosnia, spring, 96. Ravenden Spring, Arkansas, 112. Rawley Springs, Main Fountain, Virginia, 106. Reading, Mass., filter gallery, 70. Red bean, 45. Red Boiling Springs, Tennessee, 67. Red clover tops, 23. Red currant juice, 21. Red grape stalks, 24. Red grapes, 24. Red peppers, husk, 7. Reindeer moss, 41. Renaulme Spring, Saint-Denis, France, 81. Rhatany, 17. Rhine River, Germany, 69, 125. Rhododendron, 32. Rhododendron ferrugineum, 32. Rhone River, Geneva, Switzerland, 69. Rhubarb roots, 8. Rhus aromatica, 18. Rhus glabra, 14. Rhus toxicodendron, 21. Rhus vernicefera, 44. Ribarska banja, Servia, 93. Rice, 34, 45- Rice straw, 33. Richard Spring, Bagneres-de-Luchon, France, 73. Richard Spring, Cransac, France, 128. Richfield Sulphur ^Spring, New York, 105. Rieumajou, France, spring, 73. Riggio-Emilia, Italy, spring, 60. Rio de la Plata, 87, 120. Rio Vinagre, San Antonio, Colombia, 57. Rjecicaquelle, Maglaj. Bosnia, 96. Roanoke Red Sulphur Springs, Virginia, 68, 106. Rochefort, France, artesian well, 118. Roches (Beaurepaire), France, spring, 90. Rock Enon Springs, Virginia, 106. Rock Flat Spring, New South Wales, 99. Rockbridge Alum Springs, Virginia, 80, 106, ill. Rockford, 111., artesian well, 91. Rockford, 111., water- works, artesian well, 91. Roddes, France, spring, 124. Roggendorff, Austria-Hungary, spring, 80, 102. Roman Brine Spring, Torda, Austria- Hungary, 102. INDEX. 1 59 Roman Spring, Sail-les-Chateaumorand. France, 81. ROmerbrunnen, Echzell, Wetterau, 114. Romerquelle, Ems, Germany, 75. Roncegno, South Tyrol, spring, 77. Rosa renwntana, I. Rose Spring, Caylus, France, 93. Rosenau, Austria-Hungary, spring, 86. Rosenquelle, Aachen, Germany, 92. Roscicrucian Spring, Maine, 105. Rosheim, France, spring, 116. Rothenbrunnen, Voralberg, Austria-Hungary, 87. Rothenfelser Mineralquelle, Baden, Germany, 59. Roufaque, spring, 71. Royal William Medical Establishment, Wiesbaden, Germany, spring, 75. Royat Spring, France, 90. Rubus articus, 7. Rue de la Prefecture, Besan^on, France, well, 69. Ruiz Volcano Hot Spring, 57. Rumex obtusifolius, 14. Rut a herb a, 23. Rye, 39. Sabadilla seed, 23. Sacramento, Cal., river, 119. Saginaw, Mich., water-supply, 88. Saint-Denis Spring, France, 81. Saint-Honore, France, spring, 81. Saint-Leon, Pougues-les-Eaux, Nievre, France, 103. Saint-Louis No. I (Allier), Vichy, France, spring, 103. Saint-Mart, France, spring, 90. Saint-Thiebaut, France, spring, 80. Saint- Yorre (Allier), Frobert, Vichy, France, spring, 103. Salinensoole, Colberg, Germany, 55. Salix vitellina, 29- Salles-la-Source, Aveyron, France, 57. Salmade, Bussang, France, spring, 128. Salt Sulphur Iodine Spring, Virginia, 106. Salvinia natans, 10. Salzquelle, Kronthal, Germany, 93. Salzquelle, Petersthal, Germany, 58. Salzschlirf, Fulda, Germany, spring, 90. Sambucus nigra, root, 19, 42. San Francesco Spring, Spolato. 125. Sandefjord, Sweden, spring, 123. Santa Barbara Hot Springs, California, 64. Santa Rosa White Sulphur Springs, California, 64. l6o INDEX. Santa Ysabel Sulphur Springs, California, 64. Sarsaparilla, 17, 25. Sassafras, 14. Sassafras officinale, 14. Sauerbrunn, Ebriach, Austria-H angary, 52. Sauerbrunnen, Karnthen. Austria-Hungary, IOO. Sauerbrunnen, Radein, Austria-Hungary, 117. Sauerling Bades Vellach Quelle, No. II. Germany, 100. Sauerling Bades Vellach Quelle, No. Ill, Germany, 100. Sauerling Bades Vellach Quelle, No. IV, Germany, 100. Sauerling Bades Vellach Quelle, No. V, Germany, 100. Sauerling, Bistrica, Bosnia, 96. Sauerling, Ebriach, Germany, 100. Sauerling, Dragunje, Bosnia, 96. Sauerling, Dubnica, Bosnia, 96. Sauerling, Jasenica, Bosnia, 96. Sauerling, Kiseljack, Bosnia, 96. Sauerling, Ljeskovica (Giftquelle), Bosnia, 96. Sauerling, Slatina Ilidze, Bosnia, 96. Sauerling, Tesanj, Bosnia, 96. Sauerquelle, Apatovac, Austria-Hungary, 95. Saule d'Urfe Spring, Sail-les-Chateaumorand, France, 81. Saxon, Switzerland, spring, 81, 118. Schillingsforst Spring, Germany, 130. Schlammkessel, Yellowstone National Park, 77. Schlangenbad, Germany, spring, 74. Schliefheiner, moor, 129. Schlossbrunnen, Carlsbad, Austria-Hungary, 78, 97. Schoneck, Russia, spring, 86. Schooley's Mountain Spring, New Jersey, 105. Schutzenhofquelle, Wiesbaden, Germany, 76. Schwefelwasser Bades Hopfreben, Voralberg, Austria-Hungary, 87. Schweizerhalle, Basel, Switzerland, spring, 98. Sclafani, Italy, spring, 103. Scotch pine, 41. Scotch pine needles, 20. Scotch pine pollen, 22. Sea weed, 28, 33. Secale cereale, 29. Secale cornutum, 18, 29, 37. Seebruch, Austria -Hungary, spring, 70, IOI, Seifersdorf, Austria-Hungary, spring, 97. Seine River, Bercy, France, 69, Selaginella, 29. Selaginella martensii, IO. Selaginella spinulosa, IO INDEX. l6l Sellers, Germany, artesian well, 76. Seltzer Spring, Saratoga, N. Y., 105. Semen cina:, 15. Semlitsch Spring, Radein, Austria-Hungary, 117. Seon, Germany, spring, 71. Serneus, Switzerland, spring, 114. Seven Springs, Abingdon, Va., in. Sevigne (Allier), Vichy, France, spring, 103. Shaft Spring, Torda, Austria-Hungary, 102. Shealtiel Mineral Springs, Wisconsin, 108. Sheboygan Mineral Springs, Wisconsin, 108. Sheboygan, Wis., artesian well, 60, 119. Shenandoah Alum Spring, Virginia, 106. Shepherd's purse, 13. Sheridan Springs, Wisconsin, 108. Shiawassee River, Owasso, Mich., 88. Siebenbiirg, Austria- Hungary, spring, 129. Siloam Springs, Iowa, 109. Silurian Spring, Wisconsin, 108. Silverthorne's Well, Broken Hill, New South Wales, 99 Sinnbergerquelle, Brtickenau, Germany, 120. Sissipan, East India, spring, 98. Skagg's Hot Springs, California, no. Slanik, Roumania, spring, 124. Slatersville, N. Y., spring, 127. Slatina Ilidze, spring, 96. Sloe. ( See Black thorn. ) Smithville, Ga., artesian well, 118. Smodelac, Bosnia, spring, 96. Soda Butte Spring, Yellowstone National Park, 78. Soda Spring, Berkshire, Mass., 127. Soda Spring, Yellowstone National Park, 77. Soja hispida, 45. Solatium carolinense, 14. Solfatare, Puzzuoli, Italy, 69. Soljanka, Ciechocinek, Poland, spring, 129. Someraubad, Mahren, Germany, 123. Soolquelle. Kammin, Germany, 56. Soolsprudel, Nassau, Germany, 60. Soolsprudel I, Nassau, Germany, 60. Soolsprudel III, Nassau, Germany, 60. Soolsprudel IV, Nassau, Germany, 60. Soolsprudel VII, Nassau, Germany, 60. Soolsprudel X, Nassau, Germany, 60. Sophienquelle, Petersthal, Germany, 58. Sour Lake Mineral Springs, Texas, 112. 1 62 INDEX. Sour Springs, Texas, 112. Source de la Place, Bourbonne, France, 73. Source de 1'hdpital, France, 81. Source de 1'interieur de 1'etablissement, Bourbonne, France, 73. Source de Sainte-Catherine, Plombieres, France, 82. Source des Bains Nouveaux, Sylvanes, France, 100. Source des Demoiselles, Vittel, France, 100. Source des Moines, Sylvanes. France, 100. Source des Petites Baignoires, Sylvanes, France, 100. Source des Petites-Eaux, Sylvanes, France, 100. Source du Crucifix, Plombieres, France, 82. Source du ferrugineuse de Bourdeille, Plombieres, France, 82. Source du Mont Cornador, Saint Nectaire, 57. Source du Puits, Cusset, Fran x ce, 81. Source du Savonneuse, Plombieres, France, 82. Source ferrugineuse, Plombieres, France, 100. Source Grande Grille, France, 81. Source Marie, Vittel, France, 100. Source nouvelle, France, 81. Source Pre Sale, Vichy, France, 81. Source principale, Challes, France, 128. Source Roques, France, 59. Source Roquette, France, 59. Source Rouge, Saint Nectaire, 57. Source Saint-Louis, France, 60. Source-basse Richard, Cransac, France, 81. Source-haute Richard, Cransac, France, 81. Sources de Fraysse, France, 59. Sources des Dames, Plombieres, France, 82, 100. South Dakota Hot Springs, Mammoth Mineral Springs, 67. South Park, Col., spring, 127. Spanish moss, 25. Sparta Artesian Well, Wisconsin, 54. Sparta Mineral Magnetic Well, Wisconsin, 1 13. Sphagnum cuspidatum, 41. Sphagnum moss, 41. Spiegelbad No. I, Trentschin Toplitzer Bad, Austria- Hungary, 89. Splendid Geyser, Yellowstone National Park, 78. Sponge, 49. Spring Bir Keraui, 82. Sprudel, Carlsbad, Austria-Hungary, 97. Sprudel Spring I, 56. Sprudel Spring II, 56. Spurge, 42. St. Augustine, Fla., artesian well, 61. St. Clair Mineral Spring, Mich., 66. INDEX. 163 St. Clair Spring, Oakland House Well, Mich., 89. St. Croix Mineral Spring, Wisconsin, 108. St. Dunstan's Well, Melrose, Scotland, 85. St. Gothard Spring, Ceneda, Italy, 56. St. Helena, Battaglia, Italy, springs, 120. St. John's breadfruit, 30. St. Lawrence River, Pointe-des-Cascades. Canada, 83. St. Leon, Canada, spring, 60, 83. St. Lorenz Hot Spring, Leuk, Switzerland, 98. St. Moritz, Switzerland, springs, 115. St. Paul Spring, Rouen, France, 77. St. Peter's, Macomb, 111., spring, 91. St. Petersquelle, Tiefenkasten, 115. Stachelberg. Switzerland, spring, 121. Stafford Spring, Connecticut, 65. Stahl, Germany, spring, 124. Stahlbrunnen (Hermannsborn), Pombsen, Germany, 126. Stahlbrunnen, Pyrmont, Germany, 74. Stahlbrunnen, Wassenach, 55. Stahlquelle, Nassau, Germany, 93. Star anise, 32. Staraja-Russa, Russia, artesian well, 120. Steamboat Springs, Nevada, 55. Steben, Germany, spring, 78, 117. Stereocaulon vesuvianum, 9. Sterling, 111., artesian well, 91. Stickweed, 14. Stolypin, Russia, spring, 120. Stoughton, Mass., well, 70. Strawberry juice, 21. Stribling or Augusta Alum Springs, Virginia, III. Strontia Mineral Spring, Maryland, 106. Sudliche Drainagequelle, Psekoup, 122. Sugar cane, 27. Suippe River, France, 99. Suliguli, spring, 80. Sulphur Bath or Ladies' Sulphur Bath, Virginia, 106. Sulphur Spring A, Lostorf, Switzerland, 57. Sulphur Spring, Livern, Germany, 124. Sulphur Spring, Oberdorf, Germany, 58. Sulphur Spring, Sail-les-Chateaumorand, France, 81. Sulphur Spring, Schinznach, Switzerland, 57. Sulz. Germany, spring, 117. Sulzbach, Germany, spring, 102. Sumach, 14, 18. Summit Soda Springs, California, 64, no. 1 64 INDEX. Sunflower seeds, 43. Suzon Spring, Dijon, France, 69. Sweet potato, 18. Sweet Springs (Akesion), Missouri, 109. Sweet Springs (Sweet), Missouri, 109. Syringa imlgaris, 42. Talladega Spring, Alabama, 107. Tarasp, Switzerland, springs, 83. Tarbragar River, near Dubbo, New South Wales, artesian well, 99. Tarqntum, Pa., artesian well, 123. Taro, 1 8. Tarrella, New South Wales, spring, 99. Taurus Geyser, Yellowstone National Park, 78. Tayuya, 27. Te Aroha, Queensland, springs, 93. Te Tarata Hot Spring, New Zealand, 121. Tea, 32. Tempelbrunnen, Rohitsch, Germany, 58. Temple Spring, Oberfranken, 122. Tenninger Bad, Grisons, Switzerland, 99. Tennstadt, Thuringia, Germany, spring, 98. Termini-Imerese, Palermo, Sicily, 103. Thames River, Greenwich, 52. Thames River, London, 52, 79. Thames River, Twickenham, England, 61. 7"hapsia garganica, 48. Thapsia sylphium, 48. Therese Sulphur Spring, Fumades, France, 55. Theresienbrunnen, Carlsbad, Austria-Hungary, 97. Thermal Acid Spring, California, 64, 113. Thompson's Bromine-arsenic Spring, North Carolina, 66. Tibia from Egyptian mummy, 50. Tickle grass, 12. Tilford's Mineral Well, Tennessee, 107. Tillandsia dianthoidea, 25. Tittabawassee River, Michigan, 88. Tobacco, 13, 18, 19, 34, 40. Tobacco leaves and screenings, 8, 31. Tobelbad, Steiermark, Austria-Hungary, spring, 95. Tokiew, Caucasus, spring, 55. Tolenas Springs, California, 64, no. Tongern, Belgium, spring, 90. Tonnissteiner Heilbrunnen, Germany, 75, 91. Tonnissteiner Stahlbrunnen, Germany, 75. Topeka Mineral Wells, Kansas. 65. INDEX. 165 Toplitz, Mahren, Germany, spring, 123. Torpasaltkalle, Lilla Edet, Sweden, 56. Tougourt, Sahara, Africa, well, 87. Touzla Spring, Asia Minor, 121. Traverse Bay, Michigan, 88. Tree fern, New Zealand, 10, n. Trefriw, Wales, spring, 59. Trentham Spring, Georgia, 65. 'J rianosperma ficifolia, 27. Trinkquelle, Driburg, Germany, 74. Trinkquelle, Elster, Germany, 122. Trinkquelle No. 10, Trinkhalle, Wurttemberg, Germany, 72. Triton Spring, Saratoga, N. Y., 60. Truffles, 9. Tschehirghe, Anatolia, Asia Minor, spring, 115. Tsuga canadensis, 2. Tuber magnatum, 29. Tiiber melanosporum, 29. Turban and Grand Geysers, Yellowstone National Park, 78. Turf moss, 16. Tuscan (or Lick) Springs, California, 64. Tuscarora Lithia Spring, Pennsylvania, 67. Tuscarora Sour Spring, Brantford, Canada, 83. Tussilago farfara, 8. TJmgemach, Baden-Baden, Germany, spring, 59. Union Spring, Saratoga. N. Y., 60, 105. United States Spring, Saratoga, N. Y., 105. Unity Springs, (Iron Spring), New Hampshire, 105. Ursprung, Baden, Germany, 59. Usnea, 16. Usnea barbata, 41. Utah Hot Springs. 67. Utley Mineral Spring, Wisconsin, 109. Val Sinestra, Switzerland, springs, 84. Valdagno, Italy, spring, 73- Valle del Gallo, near Urbino, spring, 51. Varennes, Canada, springs, 83. Variety Springs, (Alum Spring), Virginia, ill. Variolaria dealbata, 41. Veal breast, 50. Velaine-Saint-Aubin, France, spring, 116. Velika Kiselica, Srebrenica, Bosnia, spring, 97. Verbascum lhapsus, 14. Verbesina siegesbeckia, 14. 1 66 INDEX. Vesle River, France, 99. Vesta Spring, Wisconsin, 108. Vichy Spring, Saratoga, N. Y., 105. Vicia faba, 18. Victoria Spring, Ems, Germany, 75. Victoria Spring, Neuenahr, 56. Victoria Spring, Oberlahnstein. 76. Victoria Well, Ofen, Austria-Hungary, 54. Vienna (Josefstadt), Austria-Hungary, spring, 115. Villecelle, France, spring, 52. Vincenzbrunnen, Luhatschowitz, Austria-Hungary, 72, 85. Vincent (Allier), Vichy, France, spring, 103. Virginia creeper, 40. Vic-sur-Cere, Cantal, France, spring, 122. Vitis hederacea, 40. Vittel, France, spring, 100. Voslau, spring, 121. Vrucica, Bosnia, spring, 96. Wakefield Sulphur Well, Kansas, 53. Wallawhatoola Alum Springs, Virginia, ill. Walley's Hot Springs, Nevada, 66. Walsh's quarry. New South Wales, spring, 99. Warasdin-Toplitz, Austria-Hungary, spring, 80- Warm Springs, Arkansas, 107. Warner's Spring, Michigan, 108. Waroo Springs, New South Wales, artesian well, 100. Warwick Spring, New Jersey, 105. Washington Lithia Well, Ballston Spa, New York, 105. Water hemlock, 16. Wattweiler, Alsace, spring, 61. Wayland, Mass., filter gallery, 70. Way land, Mass., reservoir, 70. Weaver Well, Texas, 112. " Weigmann," 16. Weilbach, Nassau, Germany, spring, 74, 128. Weisloch, Baden, Germany, spring, 126. Welcome Island Lithia Water, 88. Wels, Austria-Hungary, spring, 97. Wenzelsquelle, Rippoldsau, spring, 128. Wernarzer, Brlickenau, Germany, spring, 119. West Baden Spring, No. I, Indiana, 113. West Saratoga Springs, Indiana, 108. West Spring, Joplin, Mo., 82. West Sprins, Langenbruck. Austria-Hungary, 77. Westborough Insane Hospital, Mass.. wells, 70. INDEX. 167 Westerland, Germany, artesian well, 82. Western Butte, Northwest Territory, spring, 86. Westliche Quelle, Stuttgart, Germany, 72. Wheat, i, 18, 28, 34, 36,45. Wheat flour, 8, 14, 36. Wheat, milling products, 5, 36. Wheelock, England, spring, 102. White birch, 41. White Cliff Sulphur Spring, Tennessee, 107. White currant juice, 21. White Island, New Zealand, hot lake, 70. White Mineral Spring, Minnesota, 66. White pine litter, 40. White Rock Springs, Wisconsin, 109. White Sulphur Springs, Montana, 126. White Terrace Geyser, New Zealand, 121. White truffle, 29. W T hite wine, 17. Wiener-Neustadt Sauerbrunn, Austria-Hungary, 117. Wilcannia, Tarella, New South Wales, spring, 99. Wiesen Spring, Oberfranken, 122. Wilbur Springs, California, 64. Wilhelms, Germany, spring, 124. Wilhelmsheilanstalt, Wiesbaden, Germany, 75. Wilhelmsquelle, Herzogludolfsbad, Germany, 103. Willow, 29. Wine, 6, 16, 21, 24, 33. Winsford, England, spring, 102. Wire grass, 14. Witter's Mineral Springs, California, 64. Woburn, Mass., filter gallery, 70. Woburn, Mass., pond. 70. Wolf Trap Lithia Springs, Virginia, 113. Wolverton, England, spring, 76. Woodstock, 111., drift well, 91. Wootan Wells, Texas, 107. Worm seed, 15. Wormwood, 16. Wrnjcka banja, Servia, 93. Wranjaska banja, Servia, 93. Xanthium spinosum, 17. Yalova Hot Spring, Asia Minor, 121. Yampa Spring, Glenwood Springs, Colorado, 122. 1 68 INDEX. Yams. (See Sweet potato.) Yarrangobilly caves, New South Wales, spring, 99. Yeast, 2. Yellow Sulphur Springs, Virginia, in. Yellowstone Lake, Yellowstone National Park, 78. Young's Natural-gas Well and Mineral Springs, California, 64. Ypsilanti, Mich., well, 88. Ypsilanti Sanitarium, Mich., spring, 89. Yvonne, France, spring, 103. Zauberwasser, Hudson, Mich., 88. Zillenbergsoole, Colberg, Germany, 55. Zoster a marina, 2, 1 6. Zuckmantel, Austria- Hungary, spring, 98. SHORT-TITLE CATALOGUE OF THE PUBLICATIONS OP JOHN WILEY & SONS, NEW YORK. LONDON: CHAPMAN & HALL, LIMITED. ARRANGED UNDER SUBJECTS. Descriptive circulars sent on application. 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(Cohn.) 2 vols 8vo, 12 50 Fuertes's Water and Public Health i2mo, i 50 Furman's Manual of Practical Assaying 8vo, 3 oo *Getman's Exercises in Physical Chemistry 12010, 2 oo Gill's Gas and Fuel Analysis for Engineers i2mo, i 25 Grotenfelt's Principles of Modern Dairy Practice. (Woll.) i2mo, 2 oo Hammarsten's Text-book of Physiological Chemistry. (Mandel.} 8vo, 4 oo Helm's Principles of Mathematical Chemistry. (Morgan.) i2mo, i 50 Bering's Ready Reference Tables (Conversion Factors) i6mo, morocco, 2 50 Hinds's Inorganic Chemistry 8vo, 3 oo * Laboratory Manual for Students i2mo, 75 Holleman's Text-book of Inorganic Chemistry. (Cooper.) 8vo, 2 50 Text-book of Organic Chemistry. (Walker and Mott.) 8vo, 2 50 * Laboratory Manual of Organic Chemistry. 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(Tingle.). . i2mo, Miller's Manual of Assaying i2mo, Mixter's Elementary Text-book of Chemistry I2mo, Morgan's Outline of Theory of Solution and its Results i2mo, Elements of Physical Chemistry i2mo, Morse's Calculations used in Cane-sugar Factories i6mo, morocco, Mulliken's General Method for the Identification of Pure Organic Compounds. Vot I Large 8vo, 5 oo Nichols's Water-supply. (Considered mainly from a Chemical and Sanitary Standpoint, 1883.) 8vo, 2 50 O'Brine's Laboratory Guide in Chemical Analysis 8vo, 2 oo O'DriscolTs Notes on the Treatment of Gold Ores 8vo, 2 oo Ost and Kolbeck's Text-book of Chemical Technology. (Lorenz Bozart.) (In preparation,) Ostwald's School of Chemistry. Part One. (Ramsey.) (In press.) * Penfield's Notes on Determinative Mineralogy and Record of Mineral Tests. 8vo, paper, 50 Pictet's The Alkaloids and their Chemical Constitution. (Biddle.) 8vo, 5 oo Pinner's Introduction to Organic Chemistry. 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(Designing and Maintenance.) 8vo, 3 oo Freitag's Architectural Engineering. 2d Edition, Rewritten 8vo, 3 90 French and Ives's Stereotomy 8vo, 2 30 Goodhue's Municipal Improvements I2mo X 75 Goodrich's Economic Disposal of Towns' Refuse 8vo, 3 50 Gore's Elements of Geodesy 8vo, 2 50 Hayford's Text-book of Geodetic Astronomy 8vo, 3 oc Bering's Ready Reference Tables (Conversion Factors) i6mo, morocco, 2 50 Howe's Retaining Walls for Earth I2mo, i 25 Johnson's Theory and Practice of Surveying Small 8vo, 4 oo Statics by Algebraic and Graphic Methods 8vo, * oo 5 Kiersted's Sewage Disposal i2mo, i 35 Laplace's Philosophical Essay on Probabilities. (Truscott and Emory.) i2mo, 2 oo Mahan's Treatise on Civil Engineering. (1873.) 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Beams, and Arches. 8vo, 2 oo * Trantwine's Civil Engineer's Pocket-book i6mo, morocco, 5 oo Wait's Engineering and Architectural Jurisprudence 8vo, 6 oo Sheep, 6 50 Law of Operations Preliminary to Construction in Engineering and Archi- tecture. 8vo, 5 oo Sheep, 5 50 Law of Contracts 8vo, 3 oo Warren's Stereotomy Problems in Stone-cutting 8vo, 2 50 Webb's Problems in the Use and Adjustment of Engineering Instruments. i6mo, morocco, i 25 * Wheeler's Elementary Course of Civil Engineering 8vo, 4 oo Wilson's Topographic Surveying ,,,,,, ,8vo, 3 50 BRIDGES AND ROOFS. Boiler's Practical Treatise on the Construction of Iron Highway Bridges. . 8vo, 2 oo * Thames River Bridge 4to, paper, 5 oo Burr's Course on the Stresses in Bridges and Roof Trusses, Arched Ribs, and Suspension Bridges 8vo, 3 50 Du Bois's Mechanics of Engineering. Vol. II Small 4 to, 10 oo Foster's Treatise on Wooden Trestle Bridges. 4to, 5 oo Fowler's Coffer-dam Process for Piers 8vo, 2 50 Greene's Roof Trusses 8vo, i 25 Bridge Trusses 8vo, 2 50 Arches in Wood, Iron, and Stone 8vo, 2 50 Howe's Treatise on Arches 8vo, 4 oo Design of Simple Roof-trusses in Wood and Steel 8vo, 2 oo Johnson, Bryan, and Turneaure's Theory and Practice in the Designing of Modern Framed Structures Small 4to, 10 oo Merriman and Jacoby's Text-book on Roofs and Bridges: Part I. Stresses in Simple Trusses 8vo, 2 50 Part IL Graphic Statics 8vo, 2 50 Part HI. Bridge Design. 4th Edition, Rewritten 8vo, 2 50 Part TV. Higher Structures 8vo, 2 50 Morison's Memphis Bridge 4to, io oo Waddell's De Pontibus, a Pocket-book for Bridge Engineers. . . i6mo, morocco, 3 oo Specifications for Steel Bridges i2mo, s 25 Wood's Treatise on the Theory of the Construction of Bridges and Roofs.Svo, 2 oo Wright's Designing of Draw-spans: Part L Plate-girder Draws 8vo, 2 50 Part II. Riveted-truss and Pin-connected Long-span Draws 8vo, 2 50 Two parts in one volume 8vo, 3 50 6 HYDRAULICS. Bazin's Experiments upon the Contraction of the Liquid Vein Issuing from an Orifice. (Trautwine.) 8vo, 2 oo Bovey's Treatise on Hydraulics 8vo, 5 oo Church's Mechanics of Engineering 8vo, 6 oo Diagrams of Mean Velocity of Water in Open Channels paper, i 50 Coffin's Graphical Solution of Hydraulic Problems i6mo, morocco, 2 50 Flather's Dynamometers, and the Measurement of Power 12 mo, 3 oo Folwell's Water-supply Engineering 8vo, 4 oo Frizell's Water-power , 8vo, 5 oo Fuertes's Water and Public Health i2mo, i 50 Water-filtration Works i2mo, 2 50 Ganguillet and Kutter's General Formula for the Uniform Flow of Water in Rivers and Other Channels. (Hering and Trautwine.) 8vo, 4 oo Hazen's Filtration of Public Water-supply 8vo, 3 oo Hazle hurst's Towers and Tanks for Water- works 8vo, 2 50 Herschel's 115 Experiments on the Carrying Capacity of Large, Riveted, Metal Conduits 8vo, 2 oo Mason's Water-supply. (Considered Principally from a Sanitary Stand- point.) 3d Edition, Rewritten 8vo, 4 oo Merriman's Treatise on Hydraulics. oth Edition, Rewritten 8vo, 5 oo * Michie's Elements of Analytical Mechanics 8vo, 4 oo Schuyler's Reservoirs for Irrigation, Water-power, and Domestic Water- supply Large 8vo, s oo * Thomas and Watt's Improvement of Riyers. (Post., 44 c. additional), 4to, 6 oo Turneaure and Russell's Public Water-supplies 8vo t 5 oo Wegmann's Desien and Construction of Dams 4to, 5 oo Water-supply of the City of New York from 1658 to'iSgs 4to, 10 oo Weisbach's Hydraulics and Hydraulic Motors. (Du Bois.) 8vo, 5 oo Wilson's Manual of Irrigation Engineering Small 8vo, 4 oo Wolff's Windmill as a Prime Mover 8vo, 3 oo Wood's Turbines 8vo, a 50 Elements of Analytical Mechanics 8vo, 3 oo MATERIALS OF ENGINEERING. Baker's Treatise on Masonry Construction 8vo, 5 oo Roads and Pavements 8vo, 5 oo Black's United States Public Works Oblong 4to, 5 oo Bovey's Strength of Materials and Theory of Structures 8vo, 7 50 Burr's Elasticity and Resistance of the Materials of Engineering. 6th Edi- tion, Rewritten 8vo, 7 50 Byrne's Highway Construction 8vo, 5 oo Inspection of the Materials and Workmanship Employed in Construction. i6mo, 3 oo Church's Mechanics of Engineering 8vo, 6 oo Du Bois's Mechanics of Engineering. VoL I Small 4to, 7 50 Johnson's Materials of Construction Large 8vo, 6 oo Keep's Cast Iron 8vo, 2 50 Lanza's Applied Mechanics 8vo, 7 50 Martens's Handbook on Testing Materials. (Henning.) 2 vols 8vo, 750 Merrill's Stones for Building and Decoration 8vo, 5 oo Merriman's Text-book on the Mechanics of Materials 8vo, 4 oo Strength of Materials i2mo, i oo Metcalf's Steel. A Manual for Steel-users lamo, 2 oo Patton's Practical Treatise on Foundations 8vo, 5 oo 7 Rockwell's Roads and Pavements in France i2mo, i 25 Smith's Materials of Machines i2mo, i oo Snow's Principal Species of Wood 8vo, 3 50 Spalding's Hydraulic Cement 12 mo, 2 oo Text-book on Roads and Pavements 1 2mo, 2 oo Thurston's Materials of Engineering. 3 Parts 8vo, 8 oo Part I. Non-metallic Materials of Engineering and Metallurgy 8vo, 2 oo Part II. Iron and Steel 8vo, 3 50 Part III. A Treatise on Brasses, Bronzes, and Other Alloys and their Constituents 8vo, 2 50 Thurston's Text-book of the Materials of Construction 8vo, 5 oo Tillson's Street Pavements and Paving Materials 8vo, 4 oo Waddell's De Pontibus. (A Pocket-book for Bridge Engineers.) . . i6mo, mor., 3 oo Specifications for Steel Bridges i2mo, i 25 Wood's Treatise on the Resistance of Materials, and an Appendix on the Pres- ervation of Timber 8vo, 2 oo Elements of Analytical Mechanics 8vo, 3 oo Wood's Rustless Coatings: Corrosion and Electrolysis of Iron and Steel. . .8vo, 4 oo RAILWAY ENGINEERING. Andrews's Handbook for Street Railway Engineers. 3X5 inches, morocco, i 25 Berg's Buildings and Structures of American Railroads 4to, 5 oo Brooks's Handbook of Street Railroad Location i6mo. morocco, I 50 Butts's Civil Engineer's Field-book i6mo, morocco, 2 50 Crandall's Transition Curve i6mo, morocco, i 50 Railway and Other Earthwork Tables 8vo, i 50 Dawson's "Engineering" and Electric Traction Pocket-book. i6mo, morocco, 5 oo Dredge's History of the Pennsylvania Railroad: (1879) Paper, 5 oo * Drinker's Tunneling, Explosive Compounds, and Rock Drills, 4to, half mor., 25 oo Fisher's Table of Cubic Yards Cardboard, 25 Godwin's Railroad Engineers' Field-book and Explorers' Guide 1 6mo, mor., 2 50 Howard's Transition Curve Field-book i6mo, morocco, i so Hudson's Tables for Calculating the Cubic Contents of Excavations and Em- bankments 8vo, i oo Molitor and Beard's Manual for Resident Engineers i6mo, i oo Nagle's Field Manual for Railroad Engineers i6mo, morocco. 3 oo Philbrick's Field Manual for Engineers i6mo, morocco, 3 oo Searles's Field Engineering i6mo, morocco, 3 oo Railroad Spiral. i6mo, morocco, i 50 Taylor's Prismoidal Formulae and Earthwork 8vo, i 50 Trautwine's Method of Calculating the Cubic Contents of Excavations and Embankments by the Aid of Diagrams 8vo, 2 oo The Field Practice of [Laying Out Circular Curves for Railroads. 1 2 mo, morocco, 2 50 Cross-section Sheet Paper, 25 Webb's Railroad Construction. 2d Edition, Rewritten i6mo. morocco, 5 oo Wellington's Economic Theory of the Location of Railways Small 8vo, 5 oo DRAWING. Barr's Kinematics of Machinery 8vo, 2 50 * Bartlett's Mechanical Drawing 8vo, 3 oo ' " Abridged Ed 8vo, i 50 Coolidge's Manual of Drawing 8vo, paper, i oo Coolidge and Freeman's Elements of General Drafting for Mechanical Engi- neers. (In press.) Durley's Kinematics of Machines 8vo, 4 oo 8 Hill's Text-book on Shades and Shadows, and Perspective 8vo, 2 oo Jamison's Elements of Mechanical Drawing. (In press.) Jones's Machine Design: Part I. Kinematics of Machinery 8vo, i 50 Part II. Form, Strength, and Proportions of Parts 8vo, 3 oo MacCord's Elements of Descriptive Geometrj , , 8vo, 3 oo Kinematics; or, Practical Mechanism , 8vo, 5 oo Mechanical Drawing , , , 4to, 4 oo Velocity Diagrams 8vo, i 50 * Mahan's Descriptive Geometry and Stone-cutting 8vo, i 50 Industrial Drawing. (Thompson.) 8vo, 3 50 Reed's Topographical Drawing and Sketching 4to, 5 oo Reid's Course in Mechanical Drawing 8vo, 2 oo Text-book of Mechanical Drawing and Elementary Machine Design . . 8vo, 3 oo Robinson's Principles of Mechanism 8vo, 3 oo Smith's Manual of Topographical Drawing. (McMillan.) 8vo, 2 50 Warren's Elements of Plane and Solid Free-hand Geometrical Drawing. . i2mo, i oo Drafting Instruments and Operations I2mo, i 25 Manual of Elementary Projection Drawing I2mo, i 50 Manual of Elementary Problems in the Linear Perspective of Form and Shadow i2mo, i oo Plane Problems in Elementary Geometry I2mo, i 25 Primary Geometry .- . i2mo, 75 Elements of Descriptive Geometry, Shadows, and Perspective 8vo, 3 50 General Problems of Shades and Shadows 8vo, 3 oo Elements of Machine Construction and Drawing 8vo, 7 50 Problems. Theorems, and Examples in Descriptive Geometry 8vo, 2 50 Weisbach's Kinematics and the Power of Transmission. (Hermann and Klein.) 8vo, 5 oo Whelpley's Practical Instruction in the Art of Letter Engraving izmo, 2 oo Wilson's Topographic Surveying 8vo, 3 50 Free-hand Perspective 8vo, 2 50 Free-hand Lettering 8vo, i oo Woolf's Elementary Course in Descriptive Geometry. Large 8vo, 3 oo 'ELECTRICITY AND PHYSICS. Anthony and Brackett's Text-book of Physics. (Magie.). ...... .Small 8vo, 3 oo Anthony's Lecture-notes on the Theory of Electrical Measurements i2mo, i oo Benjamin's History of Electricity 8vo, 3 oo Voltaic Cell 8vo, 3 oo Classen's Quantitative Chemical Analysis by Electrolysis. (Boltwood.). .8vo, 3 oo Crehore and Squier's Polarizing Photo-chronograph 8vo, 3 oo Diwson's "Engineering" and Electric Traction Pocket-book. . i6mo, morocco, 5 oo Dolezalek's Theory of the Lead Accumulator (Storage Battery). (Von Ende.) i2mo, ~2 50 Duhem's Thermodynamics and Chemistry. (Burgess.) 8vo, 4 oo Flather's Dvnamometers, and the Measurement of Power i2mo, 3 oo Gilbert's De Magnete. (Mottelay.) 8vo, 2 50 Hanchett's Alternating Currents Explained i2mo, i oo Bering's Ready Reference Tables (Conversion Factors) i6mo, morocco, 2 50 Holman's Precision of Measurements 8vo, 2 oo Telescopic Mirror-scale Method, Adjustments, and Tests Large 8vo, 75 Landauer's Spectrum Analysis. (Tingle.) 8vo, 3 oo Le Chatelier's High-temperature Measurements. (Boudouard Burgess. )i2mo, 3 oo LoVs Electrolysis and Electrosynthesis of Organic Compounds. (Lorenz.) 12 mo, i oo * Lyons's Treatise on Electromagnetic Phenomena. Vols. I. and n. 8vo, each, 6 oo * Michie. Elements of Wave Motion Relating to Sound and Light 8vo, 4 oo 9 Niaudef 8 Elementary Treatise on Electric Batteries. (Fishoack. ) i2mo, 50 Rosenberg's Electrical Engineering. (Haldane Gee Kinzbrunner.). . . .8vo, 50 Ryan, Norris, and Hoxie's Electrical Machinery. VoL L 8vo, 50 Thurston's Stationary Steam-engines 8vo, 50 Tillman's Elementary Lessons in Heat. 8vo, 50 Tory and Pitcher's Manual of Laboratory Physics Small 8vo, oo Hike's Modern Electrolytic Copper Refining 8vo, 3 oo LAW. * Davis's Elements of Law 8vo, 2 50 * Treatise on the Military Law of United States 8vo, 7 oo * Sheep, 7 50 Manual for Courts-martial i6mo, morocco, i 50 Wait's Engineering and Architectural Jurisprudence 8vo, 6 oo Sheep, 6 50 Law of Operations Preliminary to Construction in Engineering and Archi- tecture 8vo, 5 oo Sheep, 5 50 Law of Contracts 8vo, 3 oo Winthrop's Abridgment of Military Law i2mo, 2 50 MANUFACTURES. Bernadou's Smokeless Powder Nitro-cellulose and Theory of the Cellulose Molecule i2mo, 2 50 Holland's Iron Founder i2mo, 2 50 " The Iron Founder,*' Supplement. i2mo, 2 50 Encyclopedia of Founding and Dictionary of Foundry Terms Used in the Practice of Moulding i2mo, 3 oo Eissler's Modern High Explosives 8vo, 4 oo Eff rent's Enzymes and their Applications. (Prescott.) 8vo, 3 oo Fitzgerald's Boston Machinist i8mo, i oo Ford's Boiler Making for Boiler Makers i8mo, i oo Hopkins's Oil-chemists' Handbook 8vo, 3 oo Keep's Cast Iron. 8vo, a 50 Leach's The Inspection and Analysis of Food with Special Reference to State ControL (In preparation.') Metcalf's Steel. 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(Truscott and Emory.) i2mo, 2 oo * Ludlow and Bass. Elements of Trigonometry and Logarithmic and Other Tables 8vo, 3 oo Trigonometry and Tables published separately Each, 2 oo * Ludlow's Logarithmic and Trigonometric Tables 8vo, i oo Maurer's Technical Mechanics 8vo, 4 oo Merriman and Woodward's Higher Mathematics 8vo, 5 oo Merriman's Method of Least Squares 8vo, 2 oo Rice and Johnson's Elementary Treatise on the Differential Calculus . Sm. f 8vo, 3 oo Differential and Integral Calculus. 2 vols. in one Small 8vo, 2 50 Sabin's Industrial and Artistic Technology of Paints and Varnish. (In press.} Wood's Elements of Co-ordinate Geometry 8vo, 2 oo Trigonometry: Analytical, Plane, and Spherical i2mo, i oo MECHANICAL ENGINEERING. MATERIALS OF ENGINEERING, STEAM-ENGINES AND BOILERS. Baldwin's Steam Heating for Buildings iimo, 2 50 Barr's Kinematics of Machinery 8vo, 2 50 * Bartlett's Mechanical Drawing 8vo, 3 oo * " " " Abridged Ed 8vo, i 50 Benjamin's Wrinkles and Recipes I2mo, 2 oo Carpenter's Experimental Engineering 8vo, 6 oo Heating and Ventilating Buildings 8vo, 4 oo Gary's Smoke Suppression in Plants using Bituminous Coal. (In prep- aration.) Clerk's Gas and Oil Engine Small 8vo, 4 oo Coolidge's Manual of Drawing 8vo, paper, i oo Coolidge and Freeman's Elements of General Drafting for Mechanical En- gineers. (In press.) Cromwell's Treatise on Toothed Gearing 12010, i 50 Treatise on Belts and P'ulieys i2mo, i 50 Durley's Kinematics of Machines 8vo, 4 oo Flather's Dynamometers and the Measurement of Power I2mo, 3 oo Rope Driving I2mo, 2 oo 11 Gill's Gas and Fuel Analysis for Engineers i2mo, i 25 Hall's Car Lubrication I2mo, i oo Bering's Ready Reference Tables (Conversion Factors) i6mo, morocco, 2 50 Button's The Gas Engine 8vo, 5 oo Jones's Machine Design: Part I. Kinematics of Machinery 8vo, i 50 Part n. Form, Strength, and Proportions of Parts 8vo, 3 oo Kent's Mechanical Engineer's Pocket-book i6mo, morocco, 5 oo Kerr's Power and Power Transmission 8vo, 2 oo Mac Cord's Kinematics ; or, Practical Mechanism 8vo, 5 oo Mechanical Drawing 4to, 4 oo Velocity Diagrams 8vo, i 50 Mahan's Industrial Drawing. (Thompson.) 8vo, 3 50 Poole's Calorific Power of Fuels 8vo, 3 oo Reid's Course in Mechanical Drawing 8vo, 2 oo Text-book of Mechanical Drawing and Elementary Machine Design. .8vo, 3 oo Richards's Compressed Air i2mo, i 50 Robinson's Principles of Mechanism 8vo, 3 oo Smith's Press-working of Metals ,8vo, 3 oo Thurston's Treatise on Friction and Lost Work in Machinery and Mill Work 8vo, 3 oo Animal as a Machine and Prime Motor, and the Laws of Energetics . lamo, x oo Warren's Elements of Machine Construction and Drawing 8vx>, 7 50 Weisbach's Kinematics and the Power of Transmission. Herrmann Klein.) 8vo, 5 oo Machinery of Transmission and Governors. (Herrmann Klein.). .8vo, 5 oo Hydraulics and Hydraulic Motors. (Du Bois.) 8vo, 5 oo Wolff's Windmill as a Prime Mover 8vo, 3 oo Wood's Turbines Svo, a 50 MATERIALS OF ENGINEERING. Bovey's Strength of Materials and Theory of Structures 8vo, 7 50 Burr's Elasticity and Resistance of the Materials of Engineering. 6th Edition, Reset Svo, 7 50 Church's Mechanics of Engineering 8vo, 6 oo Johnson's Materials of Construction Large 8vo, 6 oo Keep's Cast Iron 8vo, a 50 Lanza's Applied Mechanics '. 8vo, 7 50 Martens's Handbook on Testing Materials. (Henning.) 8vo, 7 50 Merriman's Text-book on the Mechanic* of Materials 8vo, 4 oo Strength of Materals i2mo, i oo Metcalf's Steel. A Manual for Steel-users i amo, 2 oo Smith's Materials of Machines i2mo i oo Thurston's Materials of Engineering 3 vote., Svo, 8 oo Part n. Iron and Steel Svo, 3 50 Part in. A Treatise on Brasses, Bronzes, and Other Alloys and their Constituents. , Svo 2 50 Text-book of the Materials of Construction Svo, 5 oo Wood's Treatise on the Resistance of Materials and an Appendix on the Preservation of Timber Svo, 2 oo Elements of Analytical Mechanics - Svo, 3 oo Wood's Rustless Coatings: Corrosion and Electrolysis of Iron and Steel. . .Svo, 4 oo STEAM-ENGINES AND BOILERS. Carnot's Reflections on the Motive Power of Heat. (Thurston.) i2mo, x 50 Dawson's "Engineering" and Electric Traction Pocket-book. .i6mo, mor., 5 oo Ford's Boiler Making for Boiler Makers i8mo, i oo 12 Goss's Locomotive Sparks 8vo, a oo Hemenway's Indicator Practice and Steam-engine Economy i2mo, a oo Button's Mechanical Engineering of Power Plants 8vo, 5 oo Heat and Heat-engines 8vo, 5 oo Kent's Steam-bo'ler Economy 8vo, 4 oo Kneass's Practice and Theory of the Injector 8vo i so MacCord's Slide-valves 8vo, a oo Meyer's Modern Locomotive Construction 4 to, 10 oo Peabody's Manual of the Steam-engine Indicator i2mo, i 50 Tables of the Properties of Saturated Steam and Other Vapors. . 8vo, i oo Thermodynamics of the Steam-engine and Other Heat-engines 8vo, 5 oo Valve-gears for Steam-engines 8vo, 2 50 Peabody and Miller's Steam-boilers 8vo, 4 oo Pray's Twenty Years with the Indicator Large 8vo, 2 50 Pupln's Thermodynamics of Reversible Cycles in Gases and Saturated Vapors. (Osterberg.) i2mo, i 25 Reagan's Locomotives : Simple, Compound, and Electric i2mo, 2 50 Rontgen's Principles of Thermodynamics. (Du Bois.) 8vo, 5 oo Sinclair's Locomotive Engine Running and Management i2mo, 2 oo Smart's Handbook of Engineering Laboratory Practice i2mo, 2 50 Snow's Steam-boiler Practice 8vo, 3 oo Spangler's Valve-gears 8vo, 2 50 Notes on Thermodynamics i2mo, i oo Spangler, Greene, and Marshall's Elements of Steam-engineering 8vo, 3 oo Thurston's Handy Tables 8vo. i 50 Manual of the Steam-engine .... 2 vols. 8vo, 10 oo Part I. History, Structuce, and Theory 8vo, 6 oo Part II. Design, Construction, and Operation 8vo, 6 oo Handbook of Engine and Boiler Trials, and the Use of the Indicator and the Prony Brake 8vo 5 o Stationary Steam-engines 8vo, 2 50 Steam-boiler Explosions in Theory and in Practice i2mo i 50 Manual of Steam-boilers , Their Designs, Construction, and Operation . 8vo, 5 oo Weisbach's Heat, Steam, and Steam-engines. (Du Bois.) 8vo, 5 oo Whitham's Steam-engine Design 8vo, 5 oo Wilson's Treatise on Steam-boilers. (Flather.) i6mo, 2 50 Wood's Thermodynamics Heat Motors, and Refrigerating Machines 8vo, 4 oo MECHANICS AND MACHINERY. Barr's Kinematics of Machinery 8vo, 2 50 Bovey's Strength of Materials and Theory of Structures 8vo, 7 50 Chase's The Art of Pattern-making i2mo, 2 50 Chordal. Extracts from Letters i2mo, 2 oo Church's Mechanics of Engineering 8vo, 6 oo Notes and Examples in Mechanics 8vo, oo Compton's First Lessons in Metal- working i2mo, 50 Compton and De Groodt's The Speed Lathe i2mo, 50 Cromwell's Treatise on Toothed Gearing i2mo, 50 Treatise on Belts and Pulleys i2mo, 50 Dana's Text-book of Elementary Mechanics for the Use of Colleges and Schools i2mo, i 50 Dingey's Machinery Pattern Making i2mo, 2 oo Dredge's Record of the Transportation Exhibits Building of the World's Columbian Exposition of 1893 4to, half morocco, 5 oo 13 Du Bois's Elementary Principles of Mechanics: VoL I. Kinematics ; 8vo, 3 50 Vol. n. Statics ." 8vo, 4 oo Vol. ni. Kinetics 8vo, 3 50 Mechanics of Engineering. Vol. I Small 4to, 7 50 VoLIL Small 4to, 10 oo Durley's Kinematics of Machines 8vo, 4 oo Fitzgerald's Boston Machinist i6mo, i oo Flather's Dynamometers, and the Measurement of Power iamo, 3 oo Rope Driving i2mo, 2 oo Goss's Locomotive Sparks 8vo 2 oo Hall's Car Lubrication i2mo, i oo Holly's Art of Saw Filing i8mo, 75 * Johnson's Theoretical Mechanics izmo, 3 oo Statics by Graphic and Algebraic Methods 8vo, 2 oo Jones's Machine Design: Part I. Kinematics of Machinery 8vo, i 50 Part n. Form, Strength, and Proportions of Parts 8vo, 3 oo Kerr's Power and Power Transmission 8vo, a oo Lanza's Applied Mechanics 8vo, 7 50 MacCord's Kinematics; or, Practical Mechanism 8vo, 5 oo Velocity Diagrams 8vo, i 50 Maurer's Technical Mechanics 8vo, 4 oo Merriman's Text-book on the Mechanics of Materials 8vo, 4 oo * Michie's Elements of Analytical Mechanics 8vo, 4 oo Reagan's Locomotives: Simple, Compound, and Electric i2mo, 2 50 Reid's Course in Mechanical Drawing 8vo, 2 oo Text-book of Mechanical Drawing and Elementary Machine Design . ,8vo, 3 oo Richards's Compressed Air i2mo, i 50 Robinson's Principles of Mechanism 8vo, 3 oo Ryan, Norris, and Hoxie's Electrical Machinery. Vol. I. 8vo, 2 50 Sinclair's Locomotive-engine Running and Management". i2mo, 2 oo Smith's Press-working of Metals 8vo, 3 oo Materials of Machines ismo, i oo Spangler, Greene, and Marshall's Elements of Steam-engineering 8vo, 3 oo Thurston's Treatise on Friction and Lost Work in Machinery and Mill Work 8vo, 3 oo Animal as a Machine and Prime Motor, and the Laws of Energetics . 121110, i oo Warren's Elements of Machine Construction and Drawing 8vo, 7 50 Weisbach's Kinematics and the Power of Transmission. (Herrmann-r- Klein. ) 8vo, 5 oo Machinery of Transmission and Governors. (Herrmann Klein.). 8vo, 5 oo Wood's Elements of Analytical Mechanics 8vo, 3 oo Principles of Elementary Mechanics i2mo, i 25 Turbines 8vo, 2 50 The World's Columbian Exposition of 1893 4to, i oo METALLURGY. Egleston's Metallurgy of Silver, Gold, and Mercury: VoL I. Silver 8vo, 7 So VoL IL Gold and Mercury 8vo, 7 So ** Iles's Lead -smelting. 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