&, UC-NRLF B H 17S 7Sfl M01J& OJ! 1 TMJfi GEOLOGICAL SURTET ENGLAND AND WALES. THE FELSITIC LAVAS OF ENGLAND AND WALES, WITH AN INTRODUCTORY DESCRIPTION OP THE CHIEF CHARACTERS OE THIS GROUP OP ROCKS. BY FRANK RTJTLEY, F.G.S., LECTURER ON MINERALOGY, ROYAL SCHOOL OF MINES. PUBLISHED BY OBDER OP THE LORDS COMMISSIONERS OF HEB MAJESTY'S TBHAIUBY. LONDON: PRINTED FOR HER MAJESTY'S STATIONERY OFFICE j AND SOLD BY LONGMANS & Co., Paternoster Row; TRUBNER & Co., Ludgate Hill; LE i v Co., Limited, 33, King William Street, E.C. ; E. STANFORD, 55, Charing Cross; WYLD, 12, Charing Cross; and B. QUARITCII, 15, Piccadilly. Manchester : T. J. DAY, 53, Market Street; Edinburgh : W. and A. K. JOHNSTON. 4, St. Andrew Square ; Dublin : HODGES, FIGGIS, & Co., 104, Grafton Street ; and A. THOM & Co., Limited, Abbey Street. 1885. Price JS'inepence. /^BERKELEY LIBRARY UNIVERSITY OF V CALIFORNIA EARTH SCIENCES LIBRARY EXCHANGE MEMOIRS OF THE GEOLOGICAL SURYET. ENGLAND AND WALES. THE FELSITIC LAVAS OF ENGLAND AND WALES, WITH AN INTRODUCTORY DESCRIPTION OF THE CHIEF CHARACTERS OF THIS GROUP OF ROCKS. BY FRANK RUTLEY, F.G.S., LECTURER ON MINERALOGY, ROYAL SCHOOL OF MINES. PUBL1SFIED BT ORDER OP THE LORDS COMMISSIONERS OF HER MAJESTY'S TREASURY. LONDON: PRINTED FOE HER MAJESTY'S STATIONERY OFFICE: AND SOLD BY LONGMANS & Co., Paternoster Jiow; TRUBNER & Co., Ludgate Hill ; LETTS, SON, & Co., Limited. 33, King William Street, E.C. ; E. STANFORD, 55, Charing Cross; WYLD, 12, Charing Cross ; and B. QUARITCH, 15, Piccadilly. Manchester : T. J. DAY, 53, Market Street; Edinburgh : W. and A. K. JOHNSTON. 4, St. Andrew Square ; Dublin : HODGES, FIGGIS, Co., 104, Grafton Street ; and A. THOM & Co., Limited, Atbey Street. 1885. Price Ninepence. EARTH SCIENCES LIBRARY *** CONTENTS. Page. Preface. By the Director-General. Introduction ........ i Felsitic Lavas of Shropshire, &c. - - -11 ,, ftie English Lake District - 12 North Wales - -15 .. Skomer Island - 18 ,, ., Pembrokeshire - - 20 Post-Silurian Felsitic Lavas - - - - 22 Felsites of Doubtful Origin - - - Tabular Statement - ^ - 2o v -. Alphabetical List of Localities - - -27 Explanation of the Plates (I. to IT.) - - - 28 u 18642. Wt. 8917. A 2 313025 PREFACE. IN the following pages a summary is given of all that is at pre- sent known regarding the distribution of that interesting group of rocks, the Felsitic Lavas, in England and Wales. Mr. Rutley has incorporated the published observations of other petrographers with those made by himself in the Collections of the Geological Survey. As the number of instances of devitrified rocks is con- stantly being increased in the British Islands and abroad, and a& the subject of devitrification is one on which much light still requires to be thrown, both by observations on ancient rocks and by laboratory experiments, it is believed that the publication of this Memoir will be of service. ARCH. GEIKIE, Director-G eneral. Geological Survey Office, 28, Jermyn Street, S.W., 21st November 1885. THE FELSITIC LAVAS OF ENGLAND AND WALES, WITH AN INTRODUCTORY DESCRIPTION OP THE CHIEF CHARACTERS OP THIS GROUP OP ROCKS. INTRODUCTION. Ten years ago the former occurrence of vitreous rocks in England and Wales was not demonstrated, even if suspected. The terms felstone, felsite, petrosilex, hornstone, eurite, &c., had 'for many years been applied to rocks of more or less compact texture, often with conchoidal fracture, having approximately the hardness and fusibility of felspars, and believed to be intimate admixtures of felspar and quartz. Such rocks frequently exhibited, especially upon weathered surfaces, a finely banded structure, closely resembling the lamination of sedimentary rocks, and where, as sometimes happened, they were found to be inter- bedded with ancient stratified deposits, occasionally fossiliferous, it is not surprising that they were now and then described as " altered flags " and slates, to which, when in advanced stages of metamorphism, these felsitic rocks certainly bear a somewhat close resemblance. Their mineralogical affinity to the groundmass of quartz-porphyries or quartz-fel sites and also to trachytes was recognised. Many of them were mapped by the Geological Survey as lavas, and more than twenty years ago, the banding in one of the Welsh felsites was stated by Sir Andrew Ramsay to have " probably originated in the same cause that produced the lamination in the lava of Ascension." Although a very large proportion of the English and W r elsh felsites are now known to be true lavas, it should also be remem bered that many rocks of quite different origin exist which, from their mineral constitution and structure, may also be termed felsites or felstones. To describe all the rocks which might be included in the group of felstones would be a somewhat difficult and arduous 2 > * . .. ... ,., . .INTRODUCTION. task, even if the needful information were at hand ; although it may, perhaps, be useful to give, in conclusion, a few selected examples of felstones which have apparently had an origin different from that of the lavas which specially constitute the subject of these pages.* It has already been stated that felsites are believed to consist of felspar and quartz. The constituent grains of these minerals are very minute in rocks of this class, but when we examine thin sections of felsite under the microscope, polarised light being employed, we notice that there is a considerable difference in the size of the crystalline grains in different kinds of felsite ; we also see that there is sometimes a marked difference in the distinctness with which the boundaries of the grains are visible, for while in some cases their outlines are quite sharply defined, so that the eye can clearly recognise the exact area occupied by each grain in the section, as in the groundmass of an ordinary quartz-felsite or elvan, in others the grains seem to shade off one into another, so that no distinct boundary can be assigned to any particular grain, in which case the section presents a hazy or blotchy appearance, while, furthermore, we may in some instances meet with so fine a texture that the field of the microscope seems merely to be studded with minute points of light even under moderately high powers. It is evident, then, that we may have very different " polarisation pictures " resulting from different varieties of felsite. The first of the structures just mentioned, in which the con- stituent grains are distinctly marked and the several quartz and felspar grains are capable of recognition under the microscope, is termed a " micro- crystalline structure." The second and third, in which the boundaries of the crystalline grains are inappreciable and the different mineral characters of the grains cannot be determined, is known acq. Quart. Journ. Geol. Soc., Vol. XLL, 1885; Presidential Address by Prof. Bonney. ; j Herman & Kutley, Proc. Koyal Soc., Vol. XXXIX, 1S85. " Zirkt'l, Mik. Beschaff, d. Min. u. Gest, p. 274. ** Rutley, Monthly Microscopical Journ., April 1870. 8 SPHERULITIC STRUCT DKE. in polarised light, and, like other radiating crystalline aggregates, they show a dark interference-cross when viewed between crossed nicols (Figs. 3b, and 9, PL 1). This is the most common type of spherulite. Less common, and usually of considerably larger size, are those which show no indication of a radiate structure, but appear under tolerably high powers to be made up of minute granules (Fig. 5, PL 1). Sometimes spherules exhibit irregular, or denticulate, or serrated boundaries (Fig. 4, PI. 1), as in some of the devitrified lavas of the Glyders in North Wales. These have always a radiating crystalline structure, and it appears as though their peripheral development had been influenced irregularly by the crystallisation of the surrounding matter.* Occasionally elongated spherules are met with, which Zirkel has termed axiolites, (Fig. 13, PL 1). Axiolitic structure has not hitherto been seen in British rocks. The largest spherulitic bodies often present quite a nodular character. These are the " lithophysen " of Von Richthofen,f who considered them to have resulted from the inflation of siliceous segregations by imprisoned steam. They are frequently cavernous. Professor Bonney, who, among others, has investigated the nature of these bodies, has arrived at the following conclusions : J :WY HILLS on the opposite side of the Conway Estuary, and described by him in his paper, " On some Nodular Felsites in the Bala Group of'. North Wales."* In the same paper other nodular fel sites have been noted between CONWAY FALLS and PANDY MILL, in the LEDR VALLEY, about half a mile above the new viaduct, where nodules from one to one and a half inches, and sometimes nearly three inches in diameter occur, and iii the upper part, and at the western end, of Conway Moun- tain. In the last-named locality Professor Bonney states that he believes the rock still retains a glassy residuum, a point of interest in rocks of such great antiquity. In addition to the spherulitic structures occurring in the lavas of ESGAIR-FELEN a distinctly perlitic one has been described by the author, thus leaving no doubt that the rock was once vitreous. In one section from this locality the perlitic structure is very curiously restricted to certain definite areas, Fig. 1, PI. IV., the boundaries of which follow the contours of mosaic-like aggregates of quartz, which may be regarded as filled-up vesicles. This phenomenon is probably due to an originally different state of tension in the glass immediately surrounding the vesicles. Another felsitic lava, which crops out about 100 feet from the base of the Giyder Fawr,f shows a small spherulitic structure under * Quart. Journ. Geol. Soc., Vol. XXXVJIL, p. 289. t /&., Vol. XXXV., p. 508. 16 NORTH WALES. the microscope,, the spherules, or rather radiating crystallisations which appear to constitute the entire rock, having usually very jagged boundaries (see Fig. 4, PI. II.). In connexion \vith the larger spheroidal or nodular bodies it is worth noting that a thin section through a concretion or spheroid, about an inch in diameter, from one of the felsites of Skomer Island, off the west coast of Pembrokeshire, is traversed by slightly- flexed, approximately-parallel bands, some of them extremely narrow and charged with nearly opaque ferruginous matter, while other bands show a fine crypto-crystalline structure. The matter lying between these bands is coarsely crystalline, this texture contrasting strongly with that of the more delicate belts. These spheroids, evidently of secondary origin, may be compared with those occurring in the Magnesian Limestone of Durham, which, in a similar manner, are traversed by the planes of lamination in the limestone, while this Skomer Island concretion is traversed by the bands common in viscous lavas. Close to the GLYDERS and on the right-hand side of the road ascending from PONT-Y-GROMLECH to GORPIIWYSFA a dark-grey felsite occurs which has a fissile, platy structure, and a splintery fracture. When examined microscopically it shows great numbers of irregularly-shaped shreds and strings, (PI. II. Fig. 6). In polarised light the rock is seen to be felsitic throughout, but the crystalline texture of the shreds differs somewhat from that of the groundmass of the section. A striking similarity is seen between the microscopic structure of this rock and that of a Hungarian Obsidian, from Tolcsva. A rhyolite from Gardiner's River, Montana, U.S., also exhibits a similar structure.* It may be worthy of note that the forms of these shreds, as seen in section, bear a certain resemblance to the forms of shreds of glass met with in some volcanic ejectamenta. There seems, however, but little doubt that the Pont-y-Gromlech rock is a devitrified obsidian or rhyolite, similar to the Tolcsva or to the Gardiner's River rocks.f The structure is not by any means common, and appears to be due to the extremely convoluted bands being cut through in a given direction, so that only portions of the bands are in- cluded between the planes of section. What appears to be a similar structure, but on a much larger scale, occurring in a felsite on the Minnesota shore, is figured by Mr. R. D. Irving in his treatise " On the Copper-bearing Rocks of Lake Superior," where he attributes it to tl flowing in a viscid condition.''^ * Quart. Journ. Geol. Soc. Vol. XXX VII., p. 400. f Professor Ch. de la Vallee Poussin figures and describes a precisely similar rock, which occurs in beds approximately of Bala age at Grand -Manil, near Gem- bloux, in Brabant. " Les Anciennes Khyolites, dites Euritcs, de Grand-Manil." Bull. Acad. royalc de Bolg.. 3 mc serie, t. x., No. 8, 1885. J Third Annual Kepoit, U.S. Gcol. Survey, p. 129. NORTH AVALE?. 17 A specimen of felsitic lava from CONWAY MOUNTAIN* shows a well-marked banded structure. Under the microscope it presents a very uniform felsitic appearance and shows some pseudomorphs of exceedingly fine-grained felsitic matter, after felspar crystals. Thess crystals or pseudomorphs lie with their longest axes parallel with the banding of the rock (Fig. 5. : PI. III.). At CLOGWYN DTJR AEDDU, a ridge about a mile to the N.W. of the summit of Sxowpox, a well -banded devitrified obsidian occurs (PI. IL, Fig. 5), showing faint, though unmistakeable traces of perlitic structure, which on account of iis faintness renders this section especially worthy of study.f It indicates, indeed, that perlitic structure may become completely effaced by devitrification, and that we may, therefore, often be justified in the assumption that many felsites which now show no trace of perlitic structure may once have been vitreous. Although we may look for this structure as a trustworthy test of the former vitreous character of a rock, yet we must not lose sight of the fact that there are vast numbers of specimens of recent obsidians and other glassy rocks which show no trace of perlitic structure, and it would therefore be not merely injudicious, but erroneous, to exclude all felsites, in which this structure is absent, from the category of vitreous rocks. On this account some examples of what ara provisionally termed " doubtful felsitic lavas " are appended to this monograph. In connexion with this doubtful series it is interesting to note the close resemblance between some of the claystone porphyries (Thonsteinpo?phi/r) and certain devitrified rhyolitic rocks. Apart from the devitrification which has taken place in the Clogwyn dur Arddu lava, there is no structural distinction to be found between it and ordinary banded obsidians. The structure of rocks of this class may, however, be somewhat difficult to interpret at times. In a section of a banded felsitic lava, similar to that from Clogwyn dur Arddu, but derived from Vicart Point, on the north coast of Jersey, the banding has been greatly disturbed by crushing and displacement, no less than a dozen minute faults occurring in one band within a space of less than an inch, while fragments of gome bands abut against others at angles of about 45 degrees. The resemblance of the lavas of Clogwyn dur Arddu to the obsidian of Ascension was long ago noted by Sir Andrew Ramsay.J On the south side of the Oapel Curig Road, about a quarter of a mile from BEDDGELERT, Mr. G. G. Butler collected specimens of a devitrified spherulitic obsidian or pitchstone. The rock is dark greenish-grey, spotted with pale greenish-grey spherules, some isolated and over J inch in diameter (PL II., Fig 3.), while others have coalesced, forming bands ^ to J inch in breadth. First quarry past the turnpike on the road to Penmaen Mawr. f This structure is not indicated in Fig. 5, PI. II. It occurs in another part of the section, and could only be properly rendered by a more delicate style of engraving. J "Descriptive Catalogue of Rock Specimens," 3rd Edition, 18fi2,Vlus. Piact. GeoL Quart. Journ. Geol. Soc., Vol. XXXVII., p. 404. 18 SKOMER ISLAND. Under the microscope the spherules are seen to have narrow but clear and colourless, borders, very sharply defined, while similar sharply-defined lines traverse the matrix in which the. spherules lie. Some of these lines are straight, while others describe curves which indicate a rude perlitic or spheroidal structure. Perlitic markings on a smaller scale are also visible in some parts of the section. Figures illustrative of these structures are appended to the paper already cited. On the eastern side of the EIFL RANGE, in Caernarvonshire, a rhyolite occurs which has been described by Professor Bonney.* SKOMER ISLAND. The felsitic lavas of Skomer Island off the West Coast of Pembrokeshire and south of St. Bride's Bay, must be regarded as of Lower Silurian age, as indicated by Sir Roderick Murchison.f Specimens from this locality, collected by Sir Andrew Ramsay, are deposited in the Rock Collection in the Museum of Practical Geology, and it is from sections taken from some of them that the following notes have been made. The felsitic lavas of this island are probably the (i quartzose cornean, mostly striped," of Sir Henry Dela Beche,J who also mentions the occurrence of a i( fine-grained compact greenstone sometimes approaching to cornean." A. section made from one of these (< greenstones " in the Jermyn Street collection shows that it is a basalt. These rocks are considered to belong to the Llandeilo or to the Bala series. Their microscopic characters were first described in 1881. They show, as a rule, a well-marked banding ; while occasionally they contain spherules an inch or more in diameter. Under the microscope both spherulitic and perlitic structures are beautifully defined. The microscopic spherules generally have a radiating crystalline structure, but in the larger ones this is either imperfectly developed, so that they show no dark cross between crossed nicols, or else it is absent. These larger bodies sometimes interrupt the bands composed of the smaller spherules. In the section from which Fig. 1. PI. Ill,, was drawn, by ordinary trans- mitted light, the finely-banded, perlitic and spherulitic structure of the rock is admirably seen. The spherules appear colourless, but the section is pervaded by clear brownish-green serpentine, seemingly quite structureless, which lies between the perlitic cracks and com- monly occupies the central area of each perlitic section, so that we can only conclude that in most cases the nuclear portion of each * Quart. Journ. Geol. Soc., Vol. XXXV., p. 305. t " Siluria" 4th Edition, p. 144. i Trans. Geol. Soc., 2nd Scries, Vol. II., p. 8. Quart. Journ. Geol. Soc., Vol. XXXVII., p. 409. SKQMER ISLAND. 19 perlitic body was more readily soluble than the rest of the rock, and that after its removal serpentinous matter refilled the cavity and that similar infiltrations in percolating along the minute planes of perlitic and laminar, or banded, structure formed irregular deposits of serpentine, which substance represents, in- deed, a large proportion of the rock in its present state. There is not the slightest indication that this material has resulted from the alteration of any magnesia-bearing mineral, so that we can only assume that it has been brought in solution from some other source. It may possibly be derived from basalt, which also occurs in the island. The curious way in which this green matter follows the minute structure of the rock, especially the perlitic, picking it out in a manner which renders the structure unusually striking, is a sufficient proof, if any be needed, of the secondary origin of this substance. The rock is throughout highly spherulitic, in fact spherules occur wherever serpentine does not occur. These are generally very small, having a radiating crystalline structure and showing dark crosses between crossed nicols. They appear massed together in somewhat irregular belts of variable width, and it is interesting to note that there is a very delicate banded structure passing through them ; just such as one sees in modern vitreous lavas, which is perfectly distinct, in spite of the immense antiquity of the rock and the great changes which it has undergone. There are, in addition to the little spherules which constitute so great a portion of the rock, some much larger ones. These often interrupt the bands, composed of the little spherules, quite abruptly. They show a tendency towards a radiate crystal- line structure, but the crystallisation in these larger spherules is very irregular, and they show no interference-cross between crossed nicols. This is one of the most beautiful examples of a devitrified lava to be met with in rocks of Lower Silurian age. Another specimen from the same locality presents somewhat different microscopic characters, no perlitic structure being visible ; but, by ordinary transmitted light, the section is seen to" be traversed by irregular bands, which look like segregations of brownish or greenish-brown dust (Fig. 3, PI. III.), with numerous circular or oval spots, which, under a power of about 250 diameters, appear to be segregations of very fine chloritic scales. It is evident, when the section is viewed between crossed nicols, that these spots mark the position of spherules, which in many cases have been obliterated ; and we may regard these dusty-looking belts as spherulitic bands, while in some instances we may see unaltered bands composed of spherules, the chlcritic matter having segregated only along the margins of these bands. The broader intermediate belts consist of crypto-erystalline matter with a few included spherules and irregularly-shaped pale green or greenish- brown plates of a chloritic mineral. An additional example of what appears to be an altered spheru- litic structure is afforded by the section shown in Fig. 2, PI. III. 20 PEMBROKESHIRE. Here, by ordinary transmitted light, we find the rock traversed by approximately clear and colourless bands, irregularly moniliform, often with adherent circular patches of similarly clear, colourless matter ; while like circular areas, doubtless representing spherules, lie scattered between these clear bands. The intercalated bands consist of greenish-brown chloritic matter in intimate admixture with fine doubly-refracting particle-. When the section is rotated between crossed nicols it is evident that if the clear bands and circular areas be sections through spherulitic belts and isolated spherules, they have, at all events, parted with their radiating- crystalline structure ; and in the case of certain narrow moniliform belts, a strong jointed structure may be traced across them ap- proximately at right-angles to the axis of the belt, the spaces between each pair of joints being occupied by perfectly distinct crystalline bundles, (Figs. 3 and 4, PI. IV.). This structure has evidently been superinduced since the formation of the spherules, and is precisely analogous to that met with in the devitrification of thin, parallel-sided plates of artificially formed glass*. That we have in this, and the preceding rock, examples of devitrified spherulitic obsidians there can be little doubt. PEMBROKESHIRE. NEAR FISHGUARD and at STRUMBLE HEAD, on the north coast of Pembrokeshire, certain felsitic rocks occur which have been mapped by the Geological Survey as "altered Llandeilo flags." Specimens so labelled, which have long been in the Rock Collection in the Museum of Practical Geology, seemed to bear so close a resemblance to devitrified lavas that sections of them were cut, and subsequent microscopic examination indicates that the rock from LLANWNDA, near Fishguard, is of a rhyolitic type. It is crypto -crystal line, has a banded structure, and contains 4 small lath-shaped felspar crystals, ranged with their longest axes approximately parallel to the banding (Fig. 6, PL III.). In the spcimen from STRUMBLE HEAD, collected between the Camp and the North Coast, the banding is absent, at all events in the section examined, yet although there is no proof that it is a rhyolitic rock, its microscopic character is not incompatible with such a supposition, while its occurrence on approximately the same horizon as the Llanwncla felsite lends support to the view that it may be an extension of it. Under the microscope it is seen to consist of a mesh-work or felting of delicate crystalline spiculae, with apparently a little isotropic matter. It is a bluish-grey flint- like rock or hornstone. A specimen, also in the Jerm^n Street collection, labelled, " Altered Llandeilo Flags from Carneddu, near Builth,'* presents a somewhat similar appearance under the micro- -y-Gromlech rock (p. 16). Irregular spots of green matter are present, which, from their form, may be pumice fragments, filled with chlorite*, but there is no good proof of this. No doubt an examination of more specimens from the same beds might give a clue one way or the other. The felsite of MYNTDD NODOL, 5 miles W.N.W. of Bala, is a rock of much the same microscopic character as the preceding, but has rather more the aspect of a lava. There seem to be indications of fluxion structure, but they are very obscure. A felsite which, under the microscope, shows a considerable number of porphyritic quartz crystals around which sweep films of a chloritic or sericitic mineral, occurs at Y-GARN, neat Llanrhaidr-yn-Mochnant. It may be a quartz-rhyolite. Between TAX- Y- GUIS IAN and CWM ORTHIN, near FFESTINIOG, and at CAREGLWYD, LLANFECHELL, ANGLESEY, felsites of doubtful origin, so far as microscopic evidence goes, also occur. Many other felsites might be mentioned concerning which it is difficult or impossible to give any decided opinion from their microscopic characters. Some may be lavas, and some altered tuffs ; while others may be porcellanites, or less metamorphosed slates and shales, and, at times, even fine-grained felspathic grits which have undergone more or less change may, from their mineral constitution, be included in the somewhat elastic group of felstone?. A very good example of the obliteration of structural pecu- liarities in rocks of this class is seen in a microscopic section of a little felsitic vein, a friction-breccia about five inches broad, passing through fine-grained Silurian grits in Smooth Beck, N.E. of ESTHTVAITE WATER, in Westmorland, in which by ordinary trans- mitted light the forms of angular and rounded fragments are shown only by pale brown, nearly washed-out-looking patches, which, between crossed nicols, are scarcely to be distinguished from their felstic cement. Similar effacement of fragmental * See description of pumice fragment by Sorby. Presidential Address, Quart. Journ. Geol. Soc., Vol. XXXVI., p. 80. 1880. 24 structure may also be noted in highly altered volcanic agglo- merates. So deceptive, sometimes, is the aspect of altered clastic rocks, that it is scarcely possible to distinguish by the eye alone between them and felsitic lavas, especially when the specimens possess well-marked lamination and the surfaces have been somewhat weathered. The foregoing pages probably give only a few of the English and Welsh localities where felsitic lavas occur, although it is hoped that most of the spots where they are at present known have here been recorded. No doubt, by following along the strike of felsitic beds now known to be lavas, the list of localities might be added to considerably ; while further examination of felsites of doubtful origin in the field may lead to the recognition of many old lava-flows which have hitherto passed unnoticed. In doubtful cases the evidence gathered in the field is quite as valuable as, or more so than, that derived from microscopic investigation. 25 TABULAR STATEMENT OF PETROLOGICAL AFFINITIES. The subjoined table shows the relation which the rocks mentioned in this Memoir bear to one another. Crystalline. A glassy resi- duum, rare. More or less completely vitreous ; but crystallites, as a rule, abundant. Felsitic Lavas = Devitrified (i.e. t crystalline) conditions of Obsidia or Pitclistone. Obsidian = The most perfectly glassy condition into which the same moken matter which produces quartz - trachyte or quartzless trachytes can pass. Contains little or no water. Silica = 60 to 80 / . Pitchstone A less perfectly glassy condition of tra- chytic matter. Con- tains a variable amount of water up to 10 %. Silica = 63 to 73%. Crystalline. Commonly with more or less glassy matter. Qua rtz- Trachyte. Rhyolite of Richthofen. Liparite of Roth. Silica = 75 to 77 %. i Sanidine- Trachyte. .....Sanidine-Rhyolite Silica = 74 to 78 %. .... Quartz-Pornhvru. Trachyte. ....Quartzless-Trachyte. Uomite. Silica = 62 to 68 %. Crystalline. Elvan. ! j Granite. The following brief statement of the lithological characters of the rocks mentioned may help to render the preceding table more generally intelligible : Felslte. Micro-crystalline, crypto-crystalline, micro-felsitic. Seldom any true Obsidian. Glass containing crystallites and occasionally crystals. Banded, perlitic, and spherulitic structures common. Pitchstone. Glass with vast quantities of crystallites and often many porphyritic crystals. Banded, perlitic, and spherulitic structures common. Quartz-Trachyte > Rhyolite, or Liparite. Micro-crystalline or aphanitic ground- mass, occasionally micro-granitic. Porphyritic crystals of quartz and sanidine, also triclinic felspars, hornblende and biotite. Sanidine- Trachyte, Sanidine-Rhyolite. Micro-crystalline or aphanitic ground- mass, chiefly composed of felspars. Porphyritic felspars and biotite. Tridy- mite often present. 26 Trachyte, QuartzJess Trachyte, Domite. Crystalline groundinass generally, consisting chiefly of felspar microliths with a very small quantity of glass. Porphyritic sanidine, and often some tricliuic felspars, hornblende, and Hotite. High per-centage of silica usually regarded as due to tridymite. Quartz-Porphyry, Quarlz-Felsite, Elnan, Micro-crystalline (felsitic) matrix. Porphyritic crystals of .quartz and orthoclase. Mica seldom present, and then only in small quantity. Granite. Crystalline (completely). Essentially composed of crystals of quartz, felspar (chiefly orthoclase) and mica. Obsidians and pitchstones occur both as lava flows and as dykes. The trachytes occur chiefly as lava flows. The quartz-porphyries form dykes. Granite occurs in large intrusive masses and in veins. 27 ALPHABETICAL LIST OF LOCALITIES. Anglesey Appletreeworth Valley - Arenig, E. slope of Beddgelert Bodlondeb Point, Conway Brithdir, near Bangor Broughton Moor - Caerbwdy, St. Davids Caer Caraioc, near Church Stret- ton Careglwyd, Llanfechell, Anglesey Careg-winllan, Anglesey - Charlton Hill, near Church Stret- ton Charnwood Forest Church'School Quarries, St. Davids Church Stretton, Shropshire Clogwyn dur Arddu, Snowdou - Colt Crag, E. side of Coniston Old Man Coniston Lake, N.W. of - Coniston Old Man Conway Falls Conway Mountain Copper-mine, Valley N. of Conis- ton - Cwm Orthin, Ffestiniog - Diganwy, near Conway - Duddon Valley Eifl Range Esgair-felen, Glyders Fishguard, Pembrokeshire Glyders, Llanberis Pass - Gorphwysfa, Llanberis Pass Great Stickle Grizedale Tarn - Knott End Kuott, The, Broughton Moor Page. 12 Lawrence Hill, near Wellington Page. 11 .. 14 Lea Rock, near Wellington 11 _ 23 Llanberis Pass - 8, 15 Llanddeiniolen 12 1 *7 Llanwnda, near Fishguard 20 ; 1 / 15 12 14 Llyn Arenig - - Llyn Padaru Long Sleddale, Westmorland 22 12,21 12 12 Moel-y-menyn - 23 tret- MvnyddNoclol - 23 11 Nun's Chapel, St. Davids 21 lesey 23 _ 12 >tret- Old Man, Coniston 14 _ 11 _ 12 Davids 21 11 Pandy Mill, near Conway P on t-y- Cromlech, Llanberis Pass 15 16 Oil - 17 iston 14 Red Crag, near Stockdale, West- - 13 morland 12 _ 14 _ 15 - 17 St. Davids, Church School Quar- onis- ries - 21 _ 13 23 St. Davids, Xuii's Chapel Seathvraite Church, Duddon Valley 21 13 Shap Wells 14 15 Skomer Island - 16,18 13 Snowdon 17 Stockdale 12 Strumble Head - 20 _ 18 _ 15 Till's Hole, LongSleddale 12 - 20 Treffgarn Rocks - 21 - 8, 15 16 Wellington, Shropshire - 11 . 14 - 13 Y-Garn - 23 Y-Graig, S.W. of Eala - 23 _ 14 r 14 EXPLANATION OF THE PLATES. PLATE I. Illustrative of structures occurring in vitreous and devitrified rocks. The figures in this plale are diagrammatic, and represent thin sections, as seen under various magnifying powers, ranging from 10 to 50 linear. Fig. 1. Spherule, "with radiating crystalline structure and vitreous border. 2. Spherule, with similar structure to No. 1, but with a broad border formed of globulites. 3. Spherules, with radiating crystalline structure, but without borders a. As seen by ordinary transmitted light. b. As seen in polarised light between crossed nicols-prisms. 4. Spherulitic body, with radiating crystalline structure and irregularly in- dented surface. Not a spherule in form, but with the same radiating crystalline structure common in spherules. 5. Spherule, with granular structure. C. Globulites segregating, so as to form what appears to be an incipient spherule. 7. Bands composed of mieroliths, deflected by a larger crystal (fluxion structure). 8. Bands, showing different degrees of fineness in their crystalline structure. Such bands may be micro or crypto-crystalline. 9. Bands composed of small spherules, as seen between crossed nicols. 10. Intricately convoluted bands (damascene structure). 11. Moniliform band, formed by the coalescence of spherules. 12. Parallel-sided band, cylindrical or tabular, formed by the coalescence of spherules. 13. Axiolites. 14. Perlitic structure. PLATE II. 1. Devitrified perlitic obsidian. Till's Hole, N. end of Long Sleddale Valley, Westmorland. Devitrified by spherules, which are only appre- ciable in polarised light. bb. Banding traversed by perlitic cracks. gq. Quartz-veins, x 32. 2. Devitrified perlitic obsidian. Ked Crag, 1^ mile N.E. of Stockdale, Westmorland. Shows perlitic structure, and is devitrified partially by spherules, x 18. 3. Devitrified spherulitic pitchstone or obsidian. Beddgelert, N. Wales. Coarse spherulitic structure. Perlitic structure present, but not shown in drawing, x 18. 4. Spherulitic lava. Glyder Fawr, N. Wales. Made up of irregularly shaped spherulitic bodies, x 77. 5. Devitrified obsidian. Clogwyn di'ir Arddu, Snowdon. Roughly parallel banding. Very faint perlitic structure present, but not "shown in drawing. x 20. ,, 6. Devitrified obsidian or rhyoliie. Between Pont y- Cromlech and Gorph- wysfa, Pass of Llanberis. Sections through convoluted bands, x 77. 29 PLATE III. Fig. 1, 2, and 3. Devitrified perlitic and spherulitic obsidians or pitchstones. Skomer Island, off the West Coast of Pembrokeshire. 1 and 2, x 18 ; 3, x55. 4. Rhyolite or devitrified obsidian ? W. of Llyn Arenig, 6 miles W. of Bala. x!8. 5. Rhyolite or devitrified obsidian. Conway Mountain, N. Wales, x 18. 6. Devitrified obsidian or rhyolite. Near Llanwnda, Fishguard, Pembroke- shire, x 18. PLATE IV. 1. Devitrified perlitic obsidian. Esgair-felen, Y. Glyder Fawr, North Wales, x 10. FF = Felsitic matter like PP between crossed nicols. PP = Areas in which perlitic structure occurs. qq = Aggregates of quartz. 2. String of spherules in devitrified obsidian. Skomer Island. Ordinary iilumination. 3. The same in polarised light, showing transverse joints, separating distinct crystalline bundles. LI 18642. 30 PLATE I. tl 18642, 31 PLATE II. Fig. 1 Fig. 5. Fig. 6. 32 PLATE III. Fig. 2. Fig. 3. Fig. 4. Fig. 5. 33 PLATE IV. . fl. L O N D O*N : Printed by EYRE and S P o i T i s w o o r> F., Printers to the Queen's most Excellent Majesty. For Her Majesty's Stationery Office, [8917. 375. 12/85.] 14 DAY USE RETURN TO DESK FROM WHICH BORROWED EARTH SCIENCES LIBKAKY This book is due on the last date stamped below, or on the date to which renewed. Renewed books are subject to immediate recall. LD 21-40m-10,'65 (F7763slO)476 General Library University of California Berkeley 015 98 NE - 96 NAV, 98 SE - 98 NE - 101 SE 104 SW, 108 SE SHEET MEMOIRS OP THE GEOX.OGXCAX, SURVEY continued. p **. /CT?) 55 (NE) 20. Hetton-le-Hole. 46. Ha^rksley Hill House. . cm 6 / w\ 81 (NW) 89* 88 (SW, NW). 22. Wear Head. 52. Barnard Castle. [jancasnirc, oil vii . ~ct^.* \^, /ivr\x7 p \* 23. Eastiratc. 53. Winston. BB&nS^(^!^*3ifflSBiSR: 24. Stanhope. Northumberland, S. Staffordshire, 54 (N\V ^'^^U r \ 4k Rothburv. 80. Cramlington. 98. Walker. S'lrcwsVjury, 60 (^*-E) 61 'JN \Y s o w / -__* 45 Lonsrframlinc- 81. Earsdon. 101. Whitfield. ?VarwickslSre?62 (NESE),63(NW SW) , 54 (NE), R8 (NW). Yorkshire, 88 (NE, SE), 87 (SW),92 (SE),93 (SW). ton. 82. NE.of Gilsland. 102. Allendale 46. Broomhill. 83. Coadley Gate. Town. 47. Coquet Island. 87. Heddon. 103. Slaley. 54. Longhorsley. 88. Long Benton. 105. Newlands. GEOLOGICAL MAPS. 55. Ulgham. ' 89. Tynemoutb. IOC. Blackpool Br. 56 Druridge Bay. 91. Greenheact. 107. Allendale. Scale, six inches to a mile. The Coal-fields and other mineral districts of the N. of Eneland are published on a scale of six inches to a mile, at S to 67 each. MS. Coloured Copies of other six-inch mapVnoHntendedfo^ nce in the Geological Survey Office, 2b, Jeimyn Street, 63. Nether \vittoh. 92. Haltwhistie. 308. Blanchland. 64. Morpeth. 93. HaydonB ridge. 109. Shotleyfleld. 65. NewbiBjgin. 94. Hexlio.m. 110. Wellhope. 72. Bedlingtou. 95. Corbridge. 111. Allonheads. 73. Blyth. 96. Horsley. 112. 97. Newcastle. London. Cumberland. 55. Searness. 69. Buttermere. Lancashire. 56. Skiddaw. 70. Grange. 63. Thackthwaite. 71. Helvellyn. S 15? Ireleth. ^ *Ormsl:irk, St. Johns, &c. Tllvervtone. 85. Standish,&c. 64. Keswick. 74. Wastwater. 05. Dockrayc. 75. Stonethwaite Eell. I!'. CartmeT 86. Adlin.ton Horwick, Ac. "Westmorland. 22. Aldingham. 87. Boltoi ^e-Moora. 47. Clitheroe. *8. Bury 1 rey wood. 48 Colne, Twiston Moor. 89. Rpchdaie, &c. 2. Tees Head. 12. Patterdale. 25. Grasmere. 6. Dufton Tell. 18. Near Grasmere. 88. Kendal. 49. Laneshaw Bridge. 92. Bickerstaffe. 65. Whalley. 93. Wigan, Up Holland, &c. 66* Hawcate. 94. WestHoughton.Hindley. 67 Winewall. 95. Radcliffe, Peel Swinton. 61* Preston 96. Middleton, Prestwich. 62! Balderstone, &c. 97. Oldham, &c. 6S. Accrington. 100. Knowsley, Rainford, &c. 64. Burnlev. 10L Biltinge, Ashton, &c. 65. Stiperden Moor. 102. Lei-" 1 .*, Lowton. 69. Layland. 103. Ashley, Eccles. 70 Blackburn, &c. 10-*- Manchester, Salford, &c. 71*. Haslingden. 105. Asliton-uiider-Lyne. *2. Cliviger, Bacup, &c. 106. Liverpool, &c. 73. Todmorden. 107. Prescott, Huyton, &c. 77. Chorley. 108. St. Helen's.BurtonWood. Yorkshire. 116. Conistone 260. Honley. 7. Redcar. Moor. 261. Kirkburton. 9 133 Kirkbv i)2 Darton. 12*. Bowes. Malham. 203. Hemsworth. 13. Wvcliffe. 184. Dale End. 204. CampsalL 20. I ivthe. 185. Kildwick. 272. Holmfirth. 24. Kirkbv Ravens- 200. Keighley. 273. Penistone. worth. 201. Bingley. 274. Barnsley. 5. Aldborough. 202. Calverley. 275. Darfield. 32. Whitby. " 203. Seacroft. 276. Brodsworth. 33. 204. Aberford. 281. Langsell. 33. Mr.rske. 215. Peeke Well. 282. Wortley. 39. Richmond. 216. Bradford. 283. Wath upon 78. Bolton-le-Moors. 109. Winwick, &c. 79. Entwistle. 111. Cheedale, Stockport, &c. 80. Tottington. 112. Stockport, &c. 81. Wardle. 113. Part of Liverpool, &c. 47.' Robin Hood's 218. Leeds. 284. Conisborough. B-vv. 219. Kippax. 287. Low Bradford. 53. Downholme. 231. Halifax. 288. Ecclesfield. 68. Levbourne. 232. Birstal. 289. Rotherham. 82. Kidstones. 233. EastArdsley. 290. Braithwell. 84 E. Witton." 234. Castleford. 293. Hallam Moors. Durham. 97. Foxup. 246. Huddersfield. 295. Handsworth. 1. Rvton. 5. Greenside. 9S. Kirk Gill. 247. Dewsbury. 296. Laughton - en 2. Gateshead. 6. Winlaton. 99. Haden Carr. 248. Wakeiiuld. le-Morthen. 3. Jarrow. 7. Washington. 100. Lofthouse. 249. Pontefract. 299. 4. S. Shields. 8. Sunderland 115. Arncliffe. 250. Darrington. 300. Harthill. MINERAL STATISTICS. Embracing the produce of Coals, Metallic Ores, and other Minerals. By R. HUNT. From 1853 to 1857, inclusive Is. 6d. each. 1^8, Part L, Is. Qd.; Part IL, 5s. 1859, Is. 6c/. 1860, 3s. Qd. 1861, 2s.; and Appendix, Is. 1862, 2s. 6d 1S63. 2.9. Qd. 1864,2s. 1865, 2s. 6d. 1866 to 1881, 2s. each. (These Statistics are now published by the Home Office, as parts of the Reports oftht Inspectors of Mines.) THE IRON ORES OF GREAT BRITAIN. Parti. The North and North Midland Counties of England (Ont of print). Part II. South Staffordshire. Price Is, Part 111, South Wales. Price Is. 3d. Part IV. The Shropshire Coal-field and North Staffordshire. 1*. 3d.