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SOLUBILITIES
OF
INORGANIC AND ORGANIC
SUBSTANCES
A HANDBOOK OF THE MOST RELIABLE
QUANTITATIVE SOLUBILITY
DETERMINA TIONS
RECALCULATED AND COMPILED BY
ATHERTON SEIDELL, PH.D. (J.H.U.)
Chemist, Division of Pharmacology, Hygienic Laboratory of the U. .S,
Public Health and Marine-Hospital Service, Washington, D. C.
Formerly Assistant Chemist, Bureau of Chemistry
U. S. Department of Agriculture
Second Printing with Corrections
NEW YORK:
D. VAN NOSTRAND COMPANY
LONDON :
CROSBY LOCKWOOD & SON,
7 STATIONERS' HALL COURT, LUDGATE HILL
1911
m/
PHYSICS DPT
COPYRIGHT, 1907 AND 1911 BY
D. VAN NOSTRAND COMPANY
Stanbope
H 01 LSO N COM PAHT
BOSTON. U. S. A.
PREFACE
DURING the years which have elapsed since Professor Arthur M.
Comey's admirable "Dictionary of Chemical Solubilities" went
to press (March, 1894), the literature upon solubilities has grown
to such an extent that it has appeared desirable to make a new
compilation of it. Soon after beginning work upon this volume the
author realized that it would not be possible to prepare a com-
pilation of solubility results which would fulfill completely the
various requirements of theoretical, technical, analytical, and
other classes of chemists, and he has therefore endeavored to meet
some of the needs of all chemists rather than provide information
especially arranged for any particular class.
The following features have been considered of chief impor-
tance in preparing the present compilation: completeness of the
data, reliability of the determinations, uniformity in expression
of results, convenience of arrangement of material, and the index-
ing of the cross-references to tables.
The material has been collected almost entirely from the origi-
nal sources, and not from text-books or works of reference.
The plan followed has been to search diligently the tables of con-
tents or indices of twenty -five of the principal chemical journals
issued since 1875, and to consult all articles in these as well as in
other journals to which references could be obtained. In this
connection, however, it should be stated that indexed references
to work on solubility usually appear under the name of the sub-
stance employed, and not under the heading "solubility." Fur-
thermore, solubility determinations are often incidental to other
investigations, and consequently are not indicated in the title
of the article or included in the index of the journal. Consid-
ering these difficulties there can be little hope of making such
a compilation complete in every detail, and in the present case
the best that can be said is that an earnest effort has been made
to omit nothing of importance. This has been done not only
for the author's personal satisfaction in perfecting the work,
but also to give the reader a reasonable assurance that the ab-
sence from these pages of results upon a particular substance is
good evidence that such determinations of satisfactory reliability
iii
222563
PREFACE
are not readily obtainable from the usually accessible chemical
journals.
Although at the time Professor Comey compiled his book it
appeared inadvisable to attempt, in the majority of cases, to
select the most reliable determinations of the solubility of the
same substance reported by different investigators, the present
author believes that this can now be done with advantage. The
selections have been made in all cases by calculating the avail-
able determinations to a common basis and drawing curves
through the points plotted on cross-section paper. A comparison
of the curves, together with a study of the details of the methods
by which the determinations were made in the several cases, has
usually furnished clear evidence for a reliable selection. For
some substances, however, this plan could not be followed, and
it has therefore been necessary to present two or more sets of
disagreeing results.
In many instances the calculations and study necessary to
ascertain the most reliable figures have required much labor,
and perhaps in some cases the author has not succeeded in
selecting the ones nearest the truth; but it is believed that the
economy of space required to present the material, and the saving
of the time of the reader in making the necessary selections him-
self, will far overbalance the disadvantage resulting from the
accidental inaccuracies introduced through extended computa-
tions.
An additional advantage resulting from the recalculation of
different determinations to a common basis is the increased
uniformity in the expression of results throughout the volume.
On this account it has been possible to give the solubility of most
substances for regular intervals of temperature and in terms of
weight of dissolved substance per given weight of solvent or of
solution.
Quantitative results alone have been included in this com-
pilation, since it is assumed that qualitative determinations, if
desired, can be readily made by simple tests in the laboratory,
and therefore the effort necessary to collect such observations
from the literature is out of proportion to the value of the inform-
ation obtained.
In regard to the names and formulas of the compounds in-
cluded, the author wishes to say that they are, for the most part,
given as found in the original papers from which they were taken ;
and in some cases a lack of uniformity in the manner of their
iv
PREFACE
expression will be noted. This is especially true of the molecules
of water of crystallization in the formulas given in connection
with the guide names placed in heavy type at the head of the
tables for all substances considered. As is well known, many
compounds, besides gaming or losing water in air, also crystal-
lize with different numbers of molecules of water even at the
ordinary temperature, and it was therefore thought best to include
such information at the proper place in the tables under the
heading "Solid Phase" rather than to select in doubtful cases
the number of molecules of water which the particular substance
was considered to carry under ordinary conditions.
Although the arrangement of the material is alphabetical accord-
ing to the customary English names, an index has been added
which also provides for those cases where there appears a doubt
as to which name is preferable, and furnishes cross-references to
those tables which contain results upon more than one substance.
A glance through the pages of this book will show the incom-
pleteness of the data for many of the most common chemical
compounds. Furthermore many of the results given are of
doubtful accuracy, although the best available. It is hoped,
therefore, that a realization of the present incomplete state of our
information concerning solubilities as evidenced in these pages
will stimulate investigations of many of those substances which
have hitherto been studied incompletely or not at all.
This volume went to press January ist, 1907, and the subject
matter is brought up to November, 1906.
In conclusion, the author begs all indulgence for errors and
omissions, and will thank any one for calling them to his attention
or making suggestions such as would improve a possible future
edition of this "Handbook."
A. S.
WASHINGTON, D.C., Feb. 22, 1907.
ABBREVIATIONS
Abs. Absolute.
Abs. Coef . Absorption Coefficient.
Aq. or aq. Aqueous.
At. Atmosphere.
b. pt. Boiling Point.
cc. Cubic Centimeter.
cone. Concentrated.
d. Dextro.
dj. Density.
f . pt. Freezing Point.
G., g., or gm. Gram.
Gms. or gms. Grams.
G.M. or Gm. Mol. Gram Molecule.
/. Laevo.
m. Meta.
Mg. or mg. Milligram.
Mgs. or mgs. Milligrams.
Mg. Mol. Milligram Molecule.
Millimols. Milligram Molecules.
Mol. Molecule.
m. pt. Melting Point.
N. or n. Normal.
o. Ortho.
ord. Ordinary.
p. Para.
ppt. Precipitate.
pptd. Precipitated.
pt. Part.
sat. Saturated.
sol. Solution.
Sp. Gr. Specific Gravity.
t. Temperature in degrees C.
temp. Temperature.
vol. Volume.
wt. Weight.
vii
ABBREVIATIONS OF TITLES OF JOURNALS
Am. Ch. J. The American Chemical Journal, Baltimore.
Am. J. Sci. American Journal of Science and Arts, New Haven.
Analyst. The Analyst, London.
Ann. See Liebig's Ann.
Ann. chim. anal. appl. Annales de chimie analytique applique"e, Paris.
Ann. chim. phys. Annales de chimie et de physique, Paris.
Ann. Physik. Annalen der Physik und Chemie, Leipzig. See also Pogg.
Ann. and Wied. Ann.
Apoth.-Ztg. Apotheker Zeitung, Berlin.
Arch. Pharm. Archiv der Pharmacie, Halle.
Ber. Berichte der deutschen chemischen Gesellschaft, Berlin.
Biedermann's Centr. Biedermann's Centralblatt fiir Agrikulturchemie,
u. s. w., Leipzig.
Bull. soc. chim. Bulletin de la societe chimique de Paris.
Chem. Centralbl. Chemisches Centralblatt, Berlin.
Chem. Ind. Die Chemische Industrie, Berlin.
Chem. News. The Chemical News, London.
Chem.-Ztg. Chemiker Zeitung, Cothen.
Compt. rend. Comptes rendus hebdomadaires des Seances de FAcademie
des Sciences, Paris.
Dingier pol. J. Dingier' s polytechnisches Journal, Stuttgart.
Gazz. chim. ital. Gazzeta chimica italiana, Palermo.
ahresber. Chem. Jahresbericht iiber die Fortschritte der Chemie, Giessen.
. Am. Chem. Soc. Journal of the American Chemical Society, Easton.
. Anal. Chem. The Journal of Analytical and Applied Chemistry, Easton.
. Chem. Soc. Journal of the Chemical Society of London.
. pharm. chim. Journal de pharmacie et de chimie, Paris.
. Physic. Chem. Journal of Physical Chemistry, Cornell.
. pr. Chem. Journal fiir praktische chemie, Leipzig.
. russ. phys. chem. Ges. Journal of the Russian Chemical Society, St.
Petersburg.
J. Soc. Chem. Ind. Journal of the Society of Chemical Industry, London.
Landw. Vers-Stat. Landwirthschaftlichen Versuchs-Stationen, Berlin.
Liebig's Annalen. Justus Liebig's Annalen der Chemie, Leipzig.
Monatsh. Ch. Monatshefte fiir Chemie, u. s. w., Vienna.
Mon. Sci. Le Moniteur Scientifique, Paris.
Mulder. Scheikundige Verhandelingen en Onderzoekingen, Vol. 3, Pt. 3.
Bijdragen tot de Geschiedenis van Het Scheikungig Gebonden Water by
G. J. Mulder, Rotterdam, 1864.
Pharm. J. Pharmaceutical Journal and Transactions, London.
Phil. Mag. The Philosophical Magazine, London.
Physic. Rev. Physical Review, Cornell.
Pogg. Ann. Annalen der Physik und Chemie, edited by Poggendorf. SP
also Ann. Physik and Wied. Ann.
Proc. Am. Acad. Proceedings of the American Academy of Art
Sciences, Boston.
Proc. Roy. Soc. Proceedings of the Royal Society of London.
Rec. trav. chim. Recueil des travaux chimiques des Pays-Bas, Leid
Sitzber. Akad. Wiss. Berlin. Sitzungsberichte der koniglichen pn
Akademie der Wissenschaften zu Berlin.
Sitzber. Akad. Wiss. Wien. Sitzungsberichte der mathematische na
schaftlichen classe der kaiserlichen Akademie der Wissensc
Wien.
U. S. P. Pharmacopoeia of the United States, 8th Revision, 1900
ix
ABBREVIATIONS OF TITLES OF JOURNALS
Wied. Ann. Annalen der Physik und Chemie, edited by Wiederman. See
also Pogg. Ann. and Ann. Physik.
Wiss. Abh. p. t. Reichanstalt. Wissenschaftlichen Abhandlung der physik-
alische technische Reichstalt, Charlottenburg.
Z. anal. Chem. Zeitschrift fiir analytische Chemie, Wiesbaden.
Z. angew. Chem. Zeitschrift fiir angewandte Chemie, Berlin.
Z. anorg. Chem. Zeitschrift fiir anorganische Chemie, Hamburg and Leipzig.
Z. Elektrochem. Zeitschrift fiir Elektrochemie, Halle.
Z. Krystallogr. Zeitschrift fiir Krystallographie und Mineralogie, Leipzig.
Z. physik. Chem. Zeitschrift fiir physikalische Chemie, Leipzig.
Z. Ver. Zuckerind. Zeitschrift fiir Rubenzucker-Industrie, Berlin.
The above abbreviations with a few necessary exceptions are taken from
the list adopted by the editor of the Journal of the American Chemical Society
for the new abstract journal, "Chemical Abstracts," and will in general be
familiar to many of those who use this volume. In a large number of in-
stances Chem. has been contracted to Ch., but with this exception, and possibly a
few inaccuracies which have slipped in, the abbreviations of journal titles used
in this book conform to the above list.
AOENAPHTHENE C 12 H 10 .
SOLUBILITY IN SEVERAL ORGANIC SOLVENTS.
(Speyers Am. J. Sci. [4] 14, 294, 1902.)
NOTE. In the original paper the results are given in terms of gram
molecules of acenaphthene, acetamide, acetaniiide, etc., per 100 gram
molecules of solvent, at temperatures which varied with each solvent and
with each weighing of the solutions. The tabulated results here given
were obtained by recalculating and reading the figures from curves plotted
on cross section paper.
In Methyl Alcohol.
In Ethyl Alcohol.
In Propyl Alcohol.
t .
(o)*
81-33
(6)* (c)*
1. 80 0.39
(a)
81.1
(V
1.9
(c) '
o-57
(a)
82.3
(*)
2.26
0.88
10
80.40
I
.70 0.38
80.3
2
.8
0.84
8l.8
2.40
i .00
20
79.60
2
.25 o
. 4 8
79.6
4
.0
i .20
81.4
3-40
i .35
30
79-00
3
.50 o
.72
79.1
5
.6
1.70
80.9
4-75
i .90
40
78.45
6
.00 I
.20
78.7
8
4
2 .60
80.6
7.10
2 .90
50
78.15
9
.00 I
77
78.8
I 3
.2
3-90
80.7
ii .10
4.40
60
78.30
ii
.70 2
35
79-4
23
.2
7-00
8l. 5
19.60
8.20
70
78.60
14.30 2
.90
80.75
40
5
12.50
83-9
37.00
16.20
In Chloroform.
In Toluene.
t .
()
(&)
(cY
(a)
W
(c)
143-8
16.
4 12.7
90.7
I3.I8
7-9
10
I40.I
20.
6 16.0
90.8
18.0
10.7
2O
I3 6 -3
27.
o 19.5
91 .0
24-5
i4-5
30
132.4
34-
o 25 .0
91.8
33-5
20.5
40
128.0
42.
5 3 2 -o
92.7
47.0
28.0
50
123.4
5 1 -
5 40-0
94-0
60.5
35-7
60
II9-3
62.
5 5o-o
95-5
74-0
43-5
70
97.2
89.0
5 2 -5
ACETAMIDE CH 3 CO.NH 2 .
SOLUBILITY IN WATER AND IN ALCOHOL.
(Speyers.)
In Water.
t.
(fl)
(6)
(c)
o
105-5
70.8
29.6
10
104.9
81.0
34-o
20
104.3
97-5
40.8
30
103.7
114.0
47-7
40
103.0
i33-o
55-5
50
102.3
154.0
64.0
60
101 .6
177-5
74.0
In Ethyl Alcohol.
(a)
(ft)
(c)
85.62
17-3
18.5
86.2
24.0
26.0
87-3
31 .5
33-8
88.8
40-5
43-o
90-7
50.0
53-5
93-o
61 .0
64-5
95-5
72.0
76.5
ACETANILIDE C 6 H 5 NH.COCH 3 .
100 grams H 2 O dissolve 0.55 gram at 25, and 5.55 grams at b. pt.
* (a) Weight of 100 cc. solution in grams. * (b) Grams dissolved substance per 100 grains solvent.
* (c) Gram molecules of dissolved substance pe: ioc- gram molecules of solvent.
AOETANILIDE a
SOLUBILITY OF ACETANILIDE IN ORGANIC SOLVENTS.
In Methyl Alcohol.
(Speyers.)
In Ethyl Alcohol.
In Chloroform.
t.
(a)
(6)
(c)
'<)
<*)
(c) '
(a)
0)
(c) '
O
86.0
22-7
5-4
84.2
14.7
5-o
J 50
3
3
.66
3-24
10
86.4
30.0
7.0
84.4
20. o
6.6
147
5
7
.80
7.00
20
87-5
41 -O
9.8
85-0
27.0
9.0
144
.0
12
.00
10.50
30
89.2
54-o
13.2
86.0
36.0
12.2
139
.8
17
.0
15.0
40
gz.z
75-5
18.0
87.4
49.0
16.2
J 35
4
23
.0
20- 4
50
93-2
107.0
25.2
89-5
65.0
22 .O
131
4
31
.0
27.6
60
95-7
145.0
34-o
92.0
87.0
30.0
127
.2
41
.0
36.0
SOLUBILITY IN MIXTURES OF ETHYL ALCOHOL AND WATER AT 25.
(Holleman and Antusch Rec. trav. chim 13, 293, 1894.)
Vol. % Cms. C 8 H 9 NO per o n p r
Alcohol, ioo Cms. Solvent. S P' Gr "
Vol. % Gms. C 8 H 9 NO per
Alcohol, ioo Gms. Solvent.
Sp. Gr.
IOO
32
93
0.8512
55
13
13
O
9335
95
0.8737
5o
9
74
9396
93
38
.04
0.8813
45
7
25
9449
90
38
.20
0.8896
40
5
.10
.9508
87
37
.80
0.8959
35
3
58
9567
85
36
-83
0.8996
3 1
2
56
.9617
80
33
.62
0.9072
25
I
73
o
.9683
75
29
25
0.9133
20
I
3o
o
9736
7o
24
73
0.9185
15
I
03
9795
65
20
.42
0.9185
10
O
94
-9845
60
16
5i
0.9287
O
54
9970
ACETIC ACID
CH 3 COOH.
SOLUBILITY IN WATER.
(Dahms Ann. Phys.
[4] 60,
122, '97.)
t.
Gms. CHgCOOH per
ioo Gms. Solution.
Solid
Phase.
t.
Gms. CH 3 COOH per
ioo Gms. Solution.
Solid
Phase.
- 5
15 .1
Ice
20
66. 3
CH 3 COOH
IO
28.2
a
io
76-
7
"
15
39-5
u
o
87.0
2O
49-5
(t
+ 10
90.
8
"
-25
57-o
a
16.
5 100.0 tr. pt.
tt
-26
.6 c8.o
Ice-
h CH,COOH
DISTRIBUTION OF ACETIC ACID BETWEEN:
Water and Amyl Alcohol at 20. Water and Benzene at 25.
(Herz and Fischer Ber. 37, 4747, '04) (H. and F. Ber. 38, 1140, '05.)
Gms. CH 3 COOH
G. M. CH 3 COOH
Gms. CH 3 COOH
G. M. CH 3 COOH
per
IOO CC.
per
IOO
cc.
per
IOO CC.
per
IOO CC.
H 2
Alcoholic
'H 2
Alcoholic
H 2
C 6 H 6 '
H 2 O
CeHe
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
I
0.923
O-OI
0095
5
0.130
0.05
O.OOI4
2
1.847
0.03
O
.0280
10
0.417
O.IO
0.0005
3
2-741
0-05
.0460
20
-55
O-2O
0.0030
4
3 694
O.O7
O
.0645
30
3-03
0.30
O.O29O
5
4-587
O.O9
o
0830
40
4-95
0.50
0-051
6
5-475
O.II
.1010
0.70
0.090
7
6-434
0.13
o
1190
8
7.328
- ,
ACETIC AGIO
DISTRIBUTION OF ACETIC ACID BETWEEN WATER AND BENZENE.
(Waddell J. Phys. Ch. 2, 237, 1898.)
Results in terms of grams per 100 grams solution.
Upper Layer.
Lower Layer.
t.
CHaCOOH.
C 6 H 6 .
H 2 0.
25
0.46
99-5 2
O-O2
25
3.10
9^-75
0.15
25
5-20
94-55
0.25
25
8.7
90.88
0.42
25
16.3
82.91
0-79
25
30-5
67 .37
2.13
25
52-5
39.60
7-6o
35
I .2
98.68
0.08
35
5-7
93-97
o-33
35
9.0
90.42
0.58
35
45 -
49.00
6.0
35
52.2
39-4
8.4
CHaCOOH
. C 6 H 6 .
H 2 0.
9-4
0.18
90.42
28.2
o-53
71.27
37-7
0.84
61 .46
48-3
1.82
49-88
61 .4
6.1
32-5
66.0
13-8
20.2
52-8
39-6
7.6
16.4
0.62
89.98
36.8
1.42
62.78
49.0
2.10
48.90
61.3
25-5
13.2
52.2
39-4
8.4
DISTRIBUTION OF ACETIC ACID BETWEEN WATER AND CHLOROFORM:
At Room Temperature. At 25.
(Wright, Thomson and Leon Proc. Roy. (Herz and Lewy, Rothmund and Wilsmore.)
800.49,185,1891.)
Results in parts per 100 parts of solution.
Upper Layer. Lower Layer.
Cms. CHaCOOH
per 100 cc.
G. M. CHaCOOH
per 100 cc.
CHaCOOH. CHC1 3 .
H 2 O. CHaCOOH
. CHC1 8 .
H 2 0.
H 2
Layer.
CHCU
Layer.
H 2
Layer.
CHCI;
Layer.
O
0.84
99-
16
o
99.01
0.99
2
0.
089
0.05
0.0032
6. 4 6
0.92
92.
62
1.04
98.24
0.72
4
0.
3 J 3
0.075
0.0062
17.69
0.79
8l.
52
3-83
94.98
1.19
6
0.
596
0.100
0.0100
25.10
I. 21
73-
69
6.77
91.85
1.38
8
o.
974
0.150
0.0198
33-71
2-97
63.
32
1 1 . 05
87.82
I-I3
10
I.
43
0-175
0.026O
44.12
7-30
48.
58
17.72
80.00
2.28
12
I.
982
0.200
0.0325
50.18
15.11
34-
71
25-75
70.13
4.12
20
5-
10
0.30
0.070
30
10.
2
0.50
0.170
40
15-
3
O.7O
0.275
50
21.
9
0.80
0-335
5 2 -3
39-
54
0.87
0.659
The figures in the table for 25 were read from the curve plotted
from the results of H. and L., Z. electro. Ch. u, 818, 1905, and of R.
and W., Z. phys. Ch. 40, 623, 1902.
The influence of electrolytes upon the distribution of acetic acid
between the aqueous and chloroform layers was investigated by
Rothmund and Wilsmore, and the following results expressed in gram
molecules per liter at 25 were obtained:
Cone, of Cone, of CHaCOOH Cone*
ectro-
lyte.
Cl
NO,
Electrolyte
Aq.
Layer.
0.463
0.463
0.926
0.926
0.316
0.316
0-633
0.633
in
CHaCOOH Electro- Electrolyte
in
C
HaCOOI
H 2
Layer.
I.I68
1.787
I.I68
2.053
I.OOO
1-737
Aq.
Layer.
0.876
I-538
0.8! 3
1.586
0.936
1.694
0.965
1.631
CHCla ' H 2 O
Layer. Layer.
0.0907 0.946
0.2435 1. 680
0.0938 0.966
0.2902 1.858
0.0927 0.958
0.2537 1.720
0.0981 0.988
0.2486 1.702
* Calculated
lyte- Aq.
Layer.
i H 2 SO 4 0.514
1.029
NH 4 N0 8 i.o
I.O
LiNO 3 i.o
I.O
from table above.
Aq.
Layer.
1.099
1-555
1.136
1.991
0.892
1.513
CHCla
Layer.
O.I3I5
0.2714
O.I3I3
0.3481
0.1005
0.2581
ACETIC ACID 4
DISTRIBUTION OF ACETIC ACID AT 25 BETWEEN:
Water and Carbon Bisulphide. Water and Carbon Tetrachloride.
(Herz and Lewy.) (Herz and Lewy.)
Gms. CHaCOOH G. M. CH 3 COOH Cms. CH 3 COOH G. M. CH 3 COOH
per ipo cc. per 100 cc. per 100 cc. per ipo cc.
'H 2 CST 'H 2 CS 2 H 2 CC1 4 H 2 O CClT
Layer. Layer. Layer. Layer. Layer. Layer, Layer. Layer.
65 2.64 i.i 0.45 3 *& -5 -3
70 3.0 1.2 0.55 40 3-0 o-7 0-055
75 3.3 i-2 0.80 50 4.8 0.9 0.095
80 5.4 i-35 0.97 60 5.8 i.i 0.155
85 6.4 1.4 i-3 7o 12.0 1.2 0.235
76.2 25.2 1.27 0.420
DISTRIBUTION OF ACETIC ACID AT 25 BETWEEN:
Water and Bromoform. Water and Toluene.
(H. and L. Z. electro. Ch. n, 818, '05.) (H. and F. Ber. 38, 1140, '05.)
Gms. CHaCOOH G. M. CHaCOOH Gms. CH 3 COOH G. M. CH 3 COOH
per IPO cc. per 100 cc. per ipo cc. per 100 cc.
1^0 ' CHBr 3 ' ' H 2 O CHBr 3 'H 2 O C 6 H 5 CH 3 ' H 2 O C 6 H 6 CH 3
Layer. Layer. Layer. Layer. Layer. Layer. Layer. Layer.
20 1.5 0.4 0-035 5 0.119 o.i 0.0025
30 3.0 0.6 0.070 10 0.328 0.2 0.0075
40 4.8 0.8 0.120 20 1.132 0.4 0.0260
50 7.8 i.o 0.20 30 2.265 -6 0.0530
60 12.0 i.i 0.28 40 3.725 0.8 0-090
65 15.6 1.15 0.395 50 5.841 i.o 0.140
70 27.0 ... 60 8.344
DISTRIBUTION OF ACETIC ACID AT 25 BETWEEN:
Water and o or p Xylene. Water and m Xylene.
(Herz and Fischer.) (Herz and Fischer.)
Gms. CH 3 COOH
G. M. CH 3 COOH
Gms. CHaCOOH
G.M.
CHgCOOH
per
100 CC.
per
100 CC.
per
100 CC.
per 100 cc.
H 2
Layer.
o or p
Xylene
Layer.
H 2 O
Layer.
o or p
Xylene
Layer.
H 2
Layer.
Xylene
Layer.
H 2
Layer.
m
Xylene
Layer.
5
O.24
O.I
O.OO4
5
O-O6
O.I
0.0015
10
0.48
O.2
O-OIO
10
0.30
0-2
0.007
20
I-I3
0-4
0.025
20
o-95
0-4
0.022
30
2.15
0.6
0.047
30
1.91
0.6
O.O42
40
3-40
0.8
0.079
40
3-04
0.8
0.072
50
5.10
I.O
0.122
50
4-65
i.o
O.III
60
7.27
I .2
0.230
60
6.65
I .2
70
12.52
NOTE. The distribution results as presented in the original
papers to which references are given in the above tables, are reported
in millimolecules per 10 cc. portions of each layer in the several cases.
To obtain the figures given in the above tables, the original results be-
fore and after calculating to gram quantities were plotted on cross-
section paper, and from the curves thus obtained, readings for regular
intervals of concentration of acetic acid in the aqueous layer were
selected.
Chlor ACETIC ACID
Chlor ACETIC ACID CH 2 C1COOH.
DISTRIBUTION OF CHLORACETIC ACID BETWEEN:
(Herz and Fischer.)
Water and Benzene at 25'
Water and Toluene at 25.
Gms. CH 2 C1COOH
G. M. CH 2 C1COOH
Gms. CH 2 C1COOH
G. M. CH 2 C1COOH
per ioo cc.
per ioo cc.
per ioo cc.
per ioo cc.
H 2 O C 6 H 6
H 2 O C(jHe
Jtl 2 vJ CensLrls
H 2 O C 6 H 5 CH 3
Layer. Layer.
Layer. Layer.
Layer. Layer.
Layer. Layer.
0.25* 8.69
0.0025 0-090
o.i* 5.22
o.ooi 0.055
o-5 15-59
0.005 0.155
0-5 20.31
O.005 O-2O
i.o 27.87
o.oio 0-28
i.o 34.87
o.oio 0.36
1.5 41.10
0-015 0.415
1-5 49.14
O.OI5 0.50
2.0 52.90
O-O2 O-54
2 . 60 46
O-O2 O.62
3.0 68.01
0.03 0.70
3-0 72.28
0-03 0-77
4-o 76.52
O.O4 O-79
4-0 81.72
0-04 0-85
5-O 86.94
0-05 0.90
DISTRIBUTION OF CHLORACETIC ACID BETWEEN:
(Herz and Lewy.)
Water and Chloroform at 25*
Water and Bromoform at 25.
Gms. CH 2 C1COOH
G. M. CH 2 C1COOH
Gms. CH 2 C1COOH
G. M. CH 2 C1COOH
per
IOO CC
per ioo cc.
per ioo cc.
per ioo cc.
H 2
CHC1 3
H 2 O
CHClg '
H 2
CHBr 3
H 2
CHBrs
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
5*
0.283
0-05
O.OO25
40*
0.850
o-45
O.OII
10
0.614
0.10
o 0060
50
1.889
0.50
0-0165
20
1. 088
O.2O
0.0135
60
2.994
0.60
O.O28
40
2.948
0-40
O.O29
70
4.241
0.70
0.040
50
3.684
O-6o
0.045
80
5.620
0.80
0-053
60
4.440
0.70
0.061
90
7.560
0.90
0-067
70
7.086
o-75
0.077
91 .6
11.340
0.97
O.I2O
DISTRIBUTION OF CHLORACETIC ACID BETWEEN:
(Herz and Lewy.)
Water and Carbon Bisulphide
at 25.
Water and Carbon Tetra-
chloride at 25.
Gms. CHzClCOOH
per ioo cc.
G. M. CH 2 C1COOH
per ioo cc.
Gms. CH 2 C1COOH
per ioo cc.
G
. M. CH 2 C1COOH
per ioo cc.
'H2O
CS 2 '
H 2
Cb 2
H 2
ecu
H 2
ecu
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
60*
.426
0.6
O
.OO42
90*
I
.417
95
0.0150
80
.691
0.8
.007
95
2
.031
I
.00
0.0195
90
O
.803
I.O
o
.009
IOO
2
645
I
05
O.O27O
IOO
I
.040
1.05
o
0105
105
4
.26
I
.10
0.0415
105
I
.464
1. 10
o
.015
106.7
5
.19
I
13
0.0550
106.7
I
.890
1-13
o
,020
See Note, page 4-
Chlor ACETIC ACIDS
SOLUBILITY OF MONOCHLOR, DICHLOR, AND OF TRICHLORACETIC ESTER
IN AQUEOUS ALCOHOL AT ROOM TEMPERATURE.
(Bancroft Phys. Rev. 3, 193, 1895-96, from results of Pfeiffer, Z. physik. chena. 9, 469, '92.)
cc. Ethvl
Alcoholin
cc. H 2 O added to cause separation of a second phase
in mixtures of the given amis, of Alcohol and 3 cc. of :
Mixtures.
CHaClCOOC 2 H 5 .
CHC1 2 COOC 2 H 5
CC1 3 COOC 2 H 5 .
3
1.32
O.QO
0.65
6
4-OI
2-45
1. 80
9
7-30
4-33
3.02
12
10.78
6.60
4.50
15
i6.!6
9. 2O
6.50
18
22.16
. . .
21
28.74
a AOETNAPHTHALIDE C 2 H ( ONH(C 10 H 7 ).
SOLUBILITY IN MIXTURES OF ALCOHOL AND WATER AT 25.
(Holleman and Antusch Rec. trav. chim. 13, 289, 1894.)
Vol.%
Alcohol.
Gms. per
100 Gms.
Solvent.
Sp. Gr. of
Solutions.
Vol.%
Alcohol.
Gms. per
100 Gms.
Solvent.
Sp. Gr. of
Solutions.
100
4-02
0.7916
65
I. 7 8
0.8977
95
4-3 1
0.8150
60
1-44
0.9091
90
4-II
0.8344
55
1.02
0.9201
85
3-69
0.8485
5
0.71
0.9290
80
3-18
0.8624
35
0.25
0-9537
75
2-73
0-8761
20
O.O9
0.9717
70
2.31
0.8798
10
0.04
0.9841
ACETONE (CH 3 ) 2 CO.
SOLUBILITY OF ACETONE AT 25 IN AQUEOUS SOLUTIONS OF:
Electrolytes. Non-Electrolytes.
(Bell J. Phys. Ch. 9, 544, 1905; Linebarger Am. Ch. J. 14, 380, 1892.)
Gms. Electro-
lyte per
Gms. (CH 3 ) 2 CO per 100 Gms.
Solvent in Solutions of:
Gms. Non- Gms. (CH 3 ) 2 CO per 100 Gms.
Electrolyte Solvent in Solutions of:
Solution.
K 2 C0 3
Na 2 CO 3 (NH4) 2 CO 3 MgCO 3 Aq. Solution. doH 8 *
Anethol.* (C 6 H 5 ) 2 CO.
I
25
.
. . .
83-
5
5
92.5
103.0
90.0
2
50
.
51.0
IIO.O
65-
10
117.0
123.0
108.5
5
CO
65
.0
38.0
73-5
47-
o
20
137.0
144-5
126.0
7
5
46
5
27-5
57-o
38.
O
30
148.5
155-0
i33-o
10
34
5
19-5
44-5
29.
40
J 55-5
162 -O
136.0
12
5
2 5
5
14.0
35-o
50
159-5
166.0
135-5
15
.0
18
.0
9-0
28.0
. .
.
60
160.2
165.0
I3I-5
20
.0
8
.0
2-7
.
70
i55-o
158.0
123.0
25
.0
3
7
.
80
108.5
30
O
i
.6
.
90
82.0
* Anethol = p Propenylanisol CHs.CHiCHUK^OCHs. Naphthalene results at 35.
NOTE. The original results were recalculated and plotted on cross-
section paper. From the curves so obtained the above table was
constructed. See also Note, page 7.
ACETONE
SOLUBILITY OP ACETONE IN AQUEOUS SOLUTIONS OF CARBOHYDRATES.
(Krug and McElroy J. Anal. Ch. 6, 184, '92; Bell J. Phys. Ch. 9, 547, '05.)
Per cent
Sugar.
IO
20
30
35
40
45
5o
55
60
65
70
In Aqueous Solutions of Cane Sugar.
Gms. (CH 3 )2CO per 100 Gms. Sugar Solution at:
15.
20. 25. 30.
35.
\
40.
597-2
581.8
574-8
272.5
250.0
251.8
172.4
150.0
150.6
96.4
92.8
89.8
71.9
68.8
65-7
50.8
48.1
45-9
35-8
33-8
32-5
25.2
24.2
23-4
18.3
17.7
17.0
13.2
12.8
12-5
no
85
62
42
29
In Aqueous Dextrose Solutions.
In Aqueous Maltose Solutions.
Per
cent
Gms
, (CH 3 ) 2 CO
Solvent
per
at:
ioo Gms.
Per
cent
Gms. (CH 3 ) 2 CO per ioo Gms.
Solvent at:
Dextrose.
15.
25-
3S-
Maltose.
i5- 25.
35-'
10
736
7
747
9
7 6l
5
IO
353-6
348.
,i
342.0
2O
255
3
247
7
240
.8
20
185.4
181,
,2
176.9
30
157
5
149
.8
142
5
30
119.9
116
.0
112 .4
40
86
9
79
.6
74'
40
78.4
74
7
70-5
50
36
.2
33
.0
3 1
.2
50
46.2
42
9
39-8
NOTE. The above determinations were made by adding successive
small quantities of acetone to mixtures of known amounts of water
and the carbohydrate, and noting the point at which a clouding due
to the separation of a second phase occurred. This method was also
used for the solubility of acetone in the aqueous electrolyte solutions
(see previous page). In the case of the aqueous non-electrolyte
solutions, however, successive small amounts of water were added to
mixtures of known amounts of acetone and the non-electrolyte.
DISTRIBUTION OF ACETONE BETWEEN WATER AND BENZENE AT 25.
(Herz and Fischer Ber. 38, 1142, '05.)
Gms. (CH 3 ) 2 CO per ioo cc. G. M. (CH 3 ) 2 CO per ioo cc.
C 6 H 6 *
Layer.
0.025
0-047
o-975
0.150
0.215
0.275
Aq.
Layer.
C 6 H 6
Layer.
Aq.
Layer.
I*
I .20
O.O25*
5
4.17
O.O5
10
10.15
O.IO
IS
15 .59
0.15
20
22.50
O-2O
0.25
*
See Note, page 4.
ACET-PHENETIDINE 8
ACET-PHENETIDINE p (PHENACETINE s
SOLUBILITY IN WATER, ALCOHOL, ETC.
(U. S. P.)
Gms. C 8 H4(OC 2 H S )NHCH 3 CO per 100 Gms.
25
b.pt.
H 2 0.
0.108
1-43
C 2 H 5 OH.
8-33
5O.O
(CH 3 ) 2 0.
CHC1,.
ACET-TOLUIDE p CH 3 .C 6 H 4 NH.C 2 H 3 O.
SOLUBILITY IN MIXTURES OF ALCOHOL AND WATER AT 25'
(Holleman and Antusch Rec. trav. chim. 13, 288, '94.)
Alcohol.
Gms. per
loo Gms.
Solvent.
Sp. Gr.
of
Solutions.
IOO
IO.I8
o . 8074
95
10-79
0.8276
90
IO.62
0.8440
85
9.62
0.8576
80
8-43
0.8685
75
7.04
0.8803
70
5.81
o . 8904
65
4-39
0.9021
60
3-59
0.9II5
55
2 .69
0.9207
Vol. %
Alcohol.
Gms. per
TOO Gms.
Solvent.
Sp. Gr,
of
Solutions.
50
1.92
0.9306
45
I.4I
0.9380
40
0.96
0.9460
35
0.66
0.9544
2 5
0.31
0.9668
20
0.23
0-9725
15
0.16
0.9780
5
0.13
0.9903
o
O-I2
0.9979
ACETYLENE C 2 H 2 .
SOLUBILITY IN WATER.
(Winkler ; see Landolt and Bornstein's Tabellen, 3 d ed. p. 604, '05.)
O
5
10
15
20
25
30
1.49
1.03
o-93
0.84
O.20
0.17
0.15
0.13
O-I2
O.II
0.09
a, " Absorption Coefficient," = the volume of gas (reduced to o
and 760 mm. pressure) taken up by one volume of the liquid at the
given temperature when the partial pressure of the gas equals 760 mm.
mercury.
<7, " Solubility," = the amount of gas in grams which is taken up by
loo grams of the pure solvent at the given temperature if the total
pressure, i.e., the partial pressure of the gas plus the vapor pressure of
the liquid at the absorption temperature is 760 mm.
9 ACETYLACETONE
ACETYLACETONE CH 3 COCH 2 COCH,.
SOLUBILITY IN WATER.
(Rothmund Z. phys. Ch. 26, 475, '98.)
Cms. CH 8 COCH,COCH 8 per 100 Cms.
30
40
50
60
70
80
87.7 (crit. temp.) 56.8
NOTE. Weighed amounts of water and acetylacetone were placed in
small glass tubes, which were then sealed and slowly heated until the
contained mixtures became homogeneous. The temperature was then
allowed to fall very gradually and the point noted at which cloudiness
appeared. This point was accurately established for each tube by repeated
trials. The curve plotted from these determinations shows two percentage
amounts of acetylacetone which cause cloudiness at each temperature
below the critical point. Of these two points, for each temperature, one
represents the aqueous layer, i.e., the solubility of acetylacetone in water;
and the other represents the acetylacetone layer, i.e., the solubility of
water in acetylacetone. This method is known as the " Synthetic Method,"
and yields results in harmony with those obtained by the analytical method,
i.e., by analyzing each layer after complete separation occurs.
H 2
Layer.
Acetyl Acetone
Layer.
15.46
I7-58
95-02
93.68
2O.22
23-23
91.90
89.41
27.10
33-92
78.82
AOONITINE (Amorphous) C 34 H 47 NO n .
SOLUBILITY IN SEVERAL SOLVENTS.
(At 25 U.S.P.; at i8- 2 2, Miiller Apoth.-Ztg. 18, 2, '03.)
Gms. C34H 4 jNOi per . Cms. CsJL^NOn per
Solvent. IOQ Gms. Solvent at: Solvent. 100 Gms. Solvent at:
i8-22. 25. i8-22. ' IpT
Water . . . 0.054 0.031 Benzene ....... J 7-85
Alcohol ..... 4.54 Carbon Tetrachloride 1.99
Ether ... 1.44 2.27 Petroleum Ether . . 0.023 0.028
ADIPIO ACID (Normal) (CH 2 ) 4 (COOH) 2 .
100 grams H 2 O dissolve 1.44 grams adipic acid at 15.
(Henry Compt. rend. 99, 1157, '84; Lamouroux Ibid. 128, 998, '90-)
AIR.
10
AIR
SOLUBILITY IN WATER.
(Wiakler Her. 34, 1409, '01; see also Peterson and Sondern Ber. 22, 1439, '89.)
cc.* of atmospheric O and N per liter of:
Dist. H 2 O (at 760 mm.). Sea Water (at 760 mm.).
t".
a.
& .
Oxygen.
Nitrogen.
Oxygen.
Nitrogen.
0.02881
0.02864
10.19
18.45
7-77
14.85
5
02543
.02521
8.91
16.30
6-93
J3-32
10
.02264
.02237
7.87
14.50
6.29
12 .06
J 5
.02045
.O2OII
7-04
13.07
5-7o
II .05
20
.01869
.01826
6-35
II .91
IO.25
2 5
.01724
.01671
5-75
10.96
9.62
30
.01606
01539
5-24
IO.I5
40
.01418
CI3IS
4-48
8.67
5o
.01297
.01140
3.85
7-55
60
.01216
.00978
3-25
6.50
80
.01126
.00600
1.97
4-03
00
.01105
. ooooo
o.oo
0-00
B = " Coefficient of Absorption," i.e., the amount of gas dissolved
by the liquid when the pressure of the gas itself without the tension
of the liquid amounts to 760 mm.
B f = " Solubility," i.e., the amount of gas, reduced to o and 760
mm., which is absorbed by one volume of the liquid when the barometer
indicates 760 mm. pressure.
* Reduced to o and 760 mm.
SOLUBILITY OF AIR IN AQUEOUS SULPHURIC ACID AT 18 AND 760 MM.
(Tower Z. anorg. Ch. 50, 382, '06.)
Wt. % H 2 SO 4 98 90 80 70 60 50
Solubility Coef. 0.0173 0.0107 0.0069 0.0055 0.0059 0.0076
SOLUBILITY OF AIR IN ALCOHOL, ETC.
(Robinet Compt. rend. 58, 608, '64.)
Solvent.
Oil of Lavender . .
Oil of Turpentine .
14.0
Solvent.
Vols. Air per 100
Vols. Solvent.
Alcohol (95 . i%) . . 14.1
Petroleum 6.8
Benzene .
Vols. Air per 100
Vols. Solvent.
. . 6. 9
. . 24.2
ALANINE ( Aminopropionic Acid) CH 3 CH(NH 2 )COOH.
SOLUBILITY IN MIXTURES OF ALCOHOL AND WATER AT 25.
(Holleman and Antusch Rec. trav. chim. 13, 297, '94.)
Vol.%
Alcohol.
Gms. per
100 Gms.
Solvent.
Sp. Gr. of
Solutions.
16.47
I .0421
5
14-37
I.03II
IO
12.43
I -O2OO
15
10.49
I .0101
20
8.48
0.9984
25
7.11
0-9886
31
5-53
0.9761
Vol. %
Gms. per
Sp. Gr. of
Alcohol.
100 Gms.
Solvent.
Solutions.
35
4.91
0.9670
40
3-89
0-9577
50
2.38
0-9355
60
i-57
0.9102
70
0.85
0.8836
80
o-37
o 8556
ii ALDEHYDE
ALDEHYDE.
SOLUBILITY OF p FORMALDEHYDE (TRIOXYMETHYLENE) IN AQUEOUS
SODIUM SULPHITE SOLUTIONS AT 20.
(Lumiere and Seyewetz Bull. soc. chim. [3] 27, 1213, '02.)
Grams Sodium Sulphite per 100 cc. H 2 O 5 10 20 28
Gms. Trioxymethylene per 100 cc. solution 22 24 26 27
100 gms. H 2 O dissolve 12.5 paraldehyde at 25, and 6.6 gms. at b. pt.
ALCOHOLS.
SOLUBILITY OF AMYL ALCOHOL IN WATER AT 22.
(Herz Ber. 31, 2671, '98.)
ioo cc. water dissolve 3.284 cc. amyl alcohol. Sp. Gr. of solu-
tion = 0.9949, Volume = 102.99 cc.
ioo cc. amyl alcohol dissolve 2.214 cc. water. Sp. Gr. of solu-
tion = 0.8248, Volume = 101.28 cc.
Sp. Gr. of H 2 O at 22 = 0.9980 ; Sp. Gr. of amyl alcohol at 22= 0.8133.
SOLUBILITY OF AMYL ALCOHOL IN WATER AT DIFFERENT TEMPERA-
TURES, " SYNTHETIC METHOD" (see Note, page 9).
(Alexejew Ann. phys. Chem. 28, 305, '86.)
Gms. CsHnOH per ioo Gms. Gms. CcHnOH per ioo Gms.
t o ' Aqueous Alcoholic ' t o ' Aqueous Alcoholic"
Layer. Layer. Layer. Layer.
08 97 ioo 2.0 80
20 6 94 120 4.0 77
40 4 90 140 7-o 73
60 2 87 150 9.0 72
80 1.5 83
SOLUBILITY OF AMYL ALCOHOL IN AQ. ETHYL ALCOHOL SOLUTIONS.
(Bancroft Phys. Rev. 3, 193, '95-96.)
~r Fthvl cc.H 2 O added to cause Separation of a
4i u 1 Second Phase in Mixtures of the given
Alcohol Amounts of Ethyl Alcohol and 3 cc.
in Mixture. Portions of Amvl Alcohol at:
9.1. 19.2.
3 !3- 21 3-5o
6 !o-3S 10. 80
9 18.34 19-10
12 27.47 29-15
15 4I-25 43-15
NOTE. The effect of various amounts of a large number of salts
upon the temperature (39.8) at which a mixture of 20 cc. of amyl
alcohol + 20 cc. of ethyl alcohol + 32.9 cc. of water becomes homo-
geneous has been investigated by Pfeiffer (Z. phys. Ch. 9, 444, '92).
The results are no doubt of interest from a solubility standpoint, but
their recalculation to terms suitable for presentation in the present
compilation has not been attempted.
SOLUBILITY OF ISOAMYL ALCOHOL IN WATER.
Gms. Iso Amyl Alcohol per ioo Gms. Q,
H2O Layer. Alcoholic Layer.
13.7 2.0 ... Balbrano Ber. 9, 1437, '76
16.5 2.5 92.9 Wittstein Jahrb. 408, '62
22 2.61 97.36 Herz Ber. 31, 2669, '98
to
Aqueous
Alcoholic
.
Layer.
Layer.
20
27
66
10
28
60
27-5
56
10
26.O
57
20
22-5
60
30
18
63-5
40
16
65-5
60
I 3
67
80
i5
63
100
20
52
loycrit.
temp. 33
120
130
133 crit
. temp.
ALCOHOLS 12
SOLUBILITY OF BUTYJ^ ALCOHOLS IN WATER, " SYNTHETIC METHOD "
(see Note, page 9).
(Alexejew Ann. phys. Chem. 28, 305, '86.)
Secondary Butyl Alcohol I so Butyl Alcohol
and Water. and Water.
Cms. Secondary Butyl Alcohol per 100 Gms. Cms. Iso Butyl Alcohol per 100 Cms.
Aqueous Alcoholic
Layer. Layer.
13 85
9 84
7-5 83
7 82
7 77-5
8 72
16 62
28 50
40
DISTRIBUTION OF ETHYL ALCOHOL BETWEEN WATER AND BENZENE
AT 25.
(Taylor J. Phys. Ch. I, 468, '97.)
Composition of 10 cc. of Upper Layer. Composition of 10 cc. Lower Layer.
CflHa. HaCT C 2 H 5 OH. 'CeH 6 . H^O C 2 H 6 OH.
5.92 0.60 3.48 4.37 1.07 4.56
6.43 0.48 3-09 3.54 I.4I 5.05
7.40 0.29 2.31 2.04 2.27 5.69
8.13 0.17 1.70 I. 08 3.22 8.70
8.65 o.io 1.25 0.59 4-06 5.35
9.05 0.06 0.89 0.28 4.99 4.73
ALUMINIUM CHLORIDE A1C1 3 - 6 H 2 O.
SOLUBILITY IN WATER.
(Gerlach Z. anal. Ch. 8, 250, '69.)
ioo gms. saturated solution contain 41.13 gms. A1C1 3 at 15, Sp. Gr
of solution = 1.354.
ALUMINIUM SULPHATE A1 2 (SO 4 ) 3 18 H 2 O.
SOLUBILITY IN WATER.
(Poggiale Ann. chim. phys. [3] 8, 467, '43.)
Gttn. A1 2 (SO 4 )3 per ioo Gms. Gms. A1 2 (SO 4 ) 3 per ioo Gms.
t. Water. Solution. t. Water. Solution/
o 31.3 23.8 60 59.1 37.2
10 33.5 25.1 70 66.2 39.8
20 36.1 26.7 80 73-1 42.2 y
30 40.4 28.8 90 80.8 44.7
40 45.7 31.4 ioo 89.1 47.1
So 5 2 - 1 34-3
ioo gms. of a saturated solution of aluminium sulphate in glycol con-
tain 14.4 gms. A1 2 (SO 4 ) 3 . (de Coninck Bull. acad. roy. Belgique, 359, '05.)
ALUMS
ALUMS.
SOLUBILITY OP AMMONIUM ALUM AND OP POTASSIUM ALUM
IN WATER.
(Mulder ; Poggiale Ann. chim. phys. [3] 8, 467, '43; Locke Am. Ch. J 26, 174, '01; Marino
Gazz. chim. ital. 35, II, 351, '05; Berkeley Trans. Roy. Soc. 203 A, 214, '04.)
Ammonium Alum.
Potassium Alum.
t.
Gms. (NHJt
A1 2 (S0 4 ) 4
Gms. (NH 4 ) 2
A1 2 (S0 4 ) 424 H 2
G.M.(NH 4 ) 2
A1 2 (S0 4 ) 4
Gms. K 2
A1 2 (S0 4 ) 4
Gms. K 2 G. M. K 2
A1 2 (S0 4 ) 424 H 2 A1 2 (S0 4 ) 4
per 100 g.
per 100 g.
per 100 g.
per 100 g.
per 100 ST.
per 100 fir.
H 2 0.
H 2 0.
H 2 0.
H 2 0.
H 2 O.
H 2 O.
o
2.10
3-90
O.OO44
3-
5-65
0-0058
5
3-50
6.91
O.OO74
3-5
6.62
0.0068
10
4-99
9-52
O.OI05
4-0
7.60
0.0077
15
6.25
12.66
0.0132
5-
9-59
0.0097
20
7-74
I 5- I 3
0.0163
5-9
ii .40
O.OII4
25
9.19
19.19
O.OI94
7-23
14.14
O.OI4O
30
10.94
22 -OI
0.0231
8-39
16.58
O.OI62
40
14.88
30.92
0-0314
11.70
23-83
0.0227
5o
20. IO
44-10
0.0424
17.00
36.40
0.0329
60
26.70
66.65
0-0569
24-75
57-35
0.0479
70
40.0
110.5
0.0774
80
71.0
321-3
0-1374
90
109.0
2275.0
0.2IIO
92 5
119.0
00
0-2313
95
109.7
00
0.2312
NOTE. The potassium alum figures in the preceding table were
taken from a curve plotted from the closely agreeing determinations of
Mulder, Locke, Berkeley, and Marino. For the higher temperatures
(above 60), however, the results of Marino are lower than those of
the other investigators, and are omitted from the average curve.
Locke called attention in his paper to the fact that Poggiale 's results
upon ammonium and potassium alum had evidently become inter-
changed through some mistake. This explanation is entirely sub-
stantiated, not only by Locke's determinations, but also by those of
Mulder and Berkeley. The ammonium alum figures given above were
therefore read from Poggiale's potassium alum curve, with which
Locke's determination of the solubility of ammonium alum at 25 is in
entire harmony.
SOLUBILITY OF AMMONIUM ALUM IN PRESENCE OF AMMONIUM SUL-
PHATE AND IN PRESENCE OF ALUMINIUM SULPHATE IN WATER.
Mixture Used.
(Riidorff Ber. 18, 1160, '85.)
100 Gms. Saturated Solution Contain:
Grams (NH 4 ) 2 SO 4 + Grams
Saturated Ammonium Alum at 18.5 1.42 3.69
20 cc. above sol. + 6 gms. cryst. A1 2 (SO 4 ) 3 . . . 0.45 16.09
20 cc. above sol. + 4 gms. cryst. (NH 4 ) 2 SO 4 . .. 20.81 0.29
ALUMS 14
SOLUBILITY OF MIXTURES OF POTASSIUM ALUM AND ALUMINIUM SUL-
PHATE AND OF POTASSIUM ALUM AND POTASSIUM SULPHATE
IN WATER.
(Marino Gazz. chim. ital. 35, II, 351, '05.)
to
Gms. per 1000 Gms. H 2 O.
Gm. Mols. per i ooo Mols. H 2 O.
Al 2 (S0 4 ) 3 .i8H 2 0.
K 2 SO 4 .
Al 2 (SO 4 ) 3 -i8H 2 O.
K 2 S0 4 .'
o
243-73
23-45
6.1
2-3
20
824.25
30.85
15.1
3.1
35
911 .02
35-29
24.1
3-6
1243-21
59-55
33-5
6.1
65
1598.00
ii9-43
43.1
12.6
77
1872 .11
183.80
5o-5
18.9
5.06
75 -83
O.I
7-8
-5
8.66
75 I 8
O.2
7-7
5-
16.07
85.78
0-4
8.8
10
18.52
96.50
o-5
99
15
20.56
109.30
o-55
II. 2
39.60
147-8
I .0
15.2
40
73-88
163.1
1.9
16.8
50
126.0
195-4
3-4
20.1
60
249.7
238.8
6.7
24.6
7o
529.0
323.7
14.2
3^-6
80
1044.0
517-27
28.1
S3 -4
Solid
Phase.
K 2 A1 2 (S0 4 ) 2 . 24 H 2
+ A1 2 (S0 4 ) 3
K 2 A1 2 (S0 4 ) 2 . 24 H 2
+ K 2 S0 4
SOLUBILITY OF MIXTURES OF POTASSIUM ALUM AND OF THALLIUM
ALUM IN WATER AT 25.
(Fock Z. Kryst. Min. 28, 397, '97.)
K 2 A1 2 (SO 4 ) 4 . 24 H 2 O ; T1 2 A1 2 (SO 4 ) 4 .2 4 H 2 O.
Con
iposition of ;
A_ . ._
solution.
Solid Phase
KAl(SO 4 ) 2 J>er Liter.
T1A1(SO 4 ) 2 per Liter.
Mol.% Sp. Gr. of
Mol. % of
Potassium
Grams.
Mg. Mols.
Grams.
Mg. Mols.
KA1(S0 4 ) 2 . Solutions.
Alum.
69.90
270.5
o.oo
o.oo
100 1-0591
IOO-O
74-56
288.2
0.48
I-I3
99.61
.0601
99-32
67.90
262.8
1.72
4.07
98.48
.0598
96.84
65-30
252.7
4-52
10.67
95-95
.0603
90.84
64-95
251.4
9.60
22 .67
9i-73
.0605
82.94
53-23
205-9
18.44
43-56
82.54
.0609
68.24
45-3 2
175-4
24.60
58.10
75-12
.0609
58.23
38.02
147.2
32.48
76.75
65-73
.0611
46.72
34-54
J 33-6
35-59
84.10
61.36
.0611
44-23
28-35
109.7
42.99
101 .60
5 r -93
.0623
32-07
10.94
42.4
66.12
156.2
21-34
.0654
7-94
o.oo
o.o
75-46
178.3
o.oo
.0674
O-OO
ALUMS
SOLUBILITY OP SODIUM ALUM IN WATER.
100 gms. H 2 O dissolve 51.0 gms. (?anhy.) Al 2 Na 2 (SO 4 ) 4 .24H 2 O at 16.
(Auge Compt. rend, no, 1139, '90.)
ioo gms. H 2 O dissolve no.o gms. Al 2 Na 2 (SO 4 ) 4 .24H 2 O at o.
(Tilden J. Ch. Soc. (Lond.) 45, 269, '84.)
SOLUBILITY OF CAESIUM ALUM, RUBIDIUM ALUM, AND OF THALLIUM
ALUM IN WATER.
(Setterburg Liebig's Annalen, ail, 104, '82; Locke Am. Ch. J. 26, 183, '01; Berkeley Trans.
Roy. Soc. 203 A, 215, '04.)
Caesium Alum.
Gms. per ioo Gms. H 2 O.
Rubidium Alum.
Gms. per ioo Gms. H 2 O.
fc .
Al 2 Cs 2 (S0 4 ) 4 .
Al 2 Cs 2 (S0 4 ) 4
. 24 H 2 0.
Al 2 Rb 2 (S0 4 ) 4 .
Al a Rb2(S0 4 ) 4
.2 4 H 2 0.
O.2I
o-34
0.72
I .21
5
0.25
0.40
0.86
1.48
10
0.30
0.49
1.05
1.81
20
O.4O
0.65
1.50
2-59
25
0.50
0.81
i. 80
3.12
30
O-6o
o-97
2.20
3-82
40
0.85
1.38
3-25
5- 6 9
50
1.30
2. II
4-8o
8.50
60
2-00
3-27
7-40
I3-36
70
3-20
5-27
12.40
23-25
80
5-40
9-OI
21 .60
43-25
90
10.50
i8.ii
IOO
22.70
42-54
Thallium Alum.
Gms. per ioo Gms. H 2 O.
A. 2 T. 2 (S0 4 ), AlaT^SO,),
3-15 4-84
5.86
7-12
10-00
3.80
4.60
6.40
7.60
14.40
22 .50
14-89
23-57
38.41
65.19
NOTE. Curves were plotted from the closely agreeing determina-
tions recorded by the above named investigators and the table con-
structed from the curves.
AMINES.
METHYL AMINE AND TRI METHYL AMINE, DISTRIBUTION BETWEEN
Water and Benzene.
(Herz and Fischer Ber. 38, 1143, '05.)
Gms. N(CHa)3 Millimols N(CH 3 ) 3
per ioo cc. per^io cc.
Aq. CgHg
Layer. Layer.
0.584 0.295
1.377 0.670
1.819 O.92I
2.474 1.237
3.619 1.823
4.663 2.328
5.568 2.847
6.760 3-474
11.135 5-86i
Water and Amyl Alcohol.
(Herz and Fischer Ber. 37, 4751, '04.)
Gms. NH 2 (CH3) Millimols NH 2 (CH 3 )
per ioo cc. per 10 cc.
Aq.
Layer.
o-37
0.94
i-57
1.89
2.00
2-53
3-30
Alcoholic
Layer.
0.12
o-33
0-54
0.69
0.72
0.92
1.24
Aq.
Layer.
I - I 5S
3-036
5-054
6.083
6.429
8.126
10.613
Alcoholic
Layer.
0-3804
1.070
1-759
2 .219
2-3J5
2.981
3-974
Aq.
CeHe
Layer.
Layer.
o-345
0.174
0.812
0.396
1-075
o-545
i .462
0-73 1
2.139
1.077
2-757
1.376
3.292
1.683
3-996
2-053
6.582
3-465
AMINES
16
SOLUBILITIES OP Di ETHYL
AMINE AND WATER.*
(Lattey Phil. Mag. [6] 10, 398. '05-)
Cms. NH(C2H 6 ) 2
per 100 Gms.
t.
Aqueous
Layer.
Amine
Layer.
J 55
21-7
59-o
!5<>
23-6
55-5
148
24-8
53-5
146
26.3
51.0
J 45
28.0
49.0
144
31.0
4S-o
DISTRIBUTION OF TRI ETHYL AMINE
BETWEEN WATER AND AMYL
ALCOHOL AT 25.
(Herz and Fischer Ber. 37, 4751, '04.)
Cms. N(C 2 H 5 ) 3
per ipo cc.
Millimols N(C 2 H 6 ).,
per 10 cc.
Aqueous
Layer.
Alcoholic
Layer.
Aqueous
Layer.
Alcoholic
Layer.
0-0885
0,1683
0-1866
0.2502
2.299
4-457
4.922
6.491
0-0875
0.1664
0.1846
0.2474
2.273
4.408
4-868
6.418
143.5 ( crit - t-) 37-4
Tri Ethyl AMINE
N(C 2 H 5 ) 3 .
SOLUBILITY IN WATER.
(Rothmund Z. phys. Ch. 26, 433, '98.)
Gms. N(C 2 H B ) 3 per 100 Gms.
Gms. N(C 2 H 6 ) 3 per 100 Gms.
Aq. Layer.
Amine Layer.
Aq. Layer.
Amine Layei
18
.6 (crit. temp.)
51-9
40
3-65
96.48
20
14.24
72.0
5
2.8 7
96.4
25
7-30
95.18
55
2-57
96-3
30
5.80
96.60
60
2.23
9 6 -3
35
4-58
9 6 -5
65
1.97
96-3
SOLUBILITY OF TRI ETHYL AMINE IN MIXTURES OF WATER AND ETHYL
ALCOHOL AT DIFFERENT TEMPERATURES.*
(Meerburg Z. phys. Ch. 40, 647, '02.)
o% Alcohol. 13.33% Alcohol. 28.98% Alcohol. 38.84% Alcohol. 60.16% Alcohol
G. N(C 2 H 5 ]
t . per 100
t.
G. N(C 2 H 5 ) 3 G. N(C 2 H 5 ) 3 G. N(Cfa
per 100 t. per too t. per too
" G.N(C 2 H 6 ) 3
t . per 100
g. sol.
g.
sol.
g. sol.
g. sol.
g. sol.
69.2
1-7
38-3
8
.2
54
5
22.8
73
4
31.2
76-77 71.2
30.8
5-6
13
9
45
.0
29.8
65
4
33-3
74-75 75-o
23.1
8-5
28.0
21
.6
33
4
51 .1
51
.6
40.6
72-73 80.0
I8. 7
25-8
26.4
30
.6
31
4
63-7
42
.1
50.6
I8. 7
37-2
24.9
40
5
30
3
68.5
40
9
54-7
19.5
51.8
24.2
49
.8
28
5
82.2
34
.2
70.6
20.5
68.6
24.1
60
7
35
.0
91.8
33
77-5
20.5
84.0
24.0
69
7
34
7
88.0
20.5
89.7
23-5
73
.6
40
5
9*-3
21.4
92.4
24.0
81
5
25-8
95-5
24.2
87
4
26.5
96.1
25.0
92
o
NOTE. Results for Tri Ethyl Amine, Water and Ethyl Ether, and for
Tri Ethyl Amine, Water and Phenol are also given by Meerburg.
100 gms. abs. methyl alcohol dissolve 57.5 grams NH(C 6 H S ) 2 at 19.5.
100 gms. abs. ethyl alcohol dissolve 56.0 grams NH(C 6 H 5 ) 2 at 19.5.
(de Bruyn Z. phys. Ch. 10, 784, 1892.)
* Determinations made by " Synthetic Method," see Note, page 9.
i; AMINES
SOLUBILITY OF Di PHENYL AMINE AND ALSO OF TRI PHENYL AMINE IN
CARBON BISULPHIDE.
(Arctowski Com pt. rend. 121, 123, '95.)
NH(C 6 H 5 ) 2 in CS 2 . N(C 6 H 6 ) 3 in CS 2 .
AO Gms. per 100 . Gms per 100
Gms. Solution. Gms. Solution.
-88J 0.87 -83 1.91
-117 0.37 -91 1.56
102 1.24
0.98
SOLUBILITY OF Di PHENYL AMINE IN HEXANE AND IN CARBON
BISULPHIDE.
(Etard Ann. chim. phys. [7] 2, 570, '94.)
Gms. NH(C 6 H 5 ) 2 Gms. NH(C 6 H 6 ) 2
per IPO Gms. Sol, in ; per 100 Gms. Sol. in;
Hexane. CS 2 . Hexane. CSj.^
60 ... 1.3 o 2.6 33.7
50 ... 2.2 +IO 3-8 46.8
40 ... 3-8 20 6.7 60.9
-30 0.5 7-2 30 13.8 76.0'
20 0.8 12.5 40 47-o
10 1.4 21.6 50 94-0 ...
AMMONIA NH 3 .
SOLUBILITY OF AMMONIA IN WATER.
(Roscoe and Dittmar Liebig's Annalen, 112, 334, '59; Raoult Ann. chim. [5] I, 262, '74; Mallet
Am. Ch. J. 19, 807, '97.)
At 760 mm. Pressure. At 760 mm. Pressure.
G. NH 3 Vol. NH 3 G.NH 3 Vol. NHa
t. per 100 g. per i g. t. per 100 g. per i g.
H 2 0. H 2 0. H 2 0. H 2
40 294.6 ... 2O 52.6 710
30 278.1 ... 25 46.0 635
20 176.8 30 40.3 595 (28)
~io 111.5 35 35.5
o 87.5 1299 40 30.7
5 77-5 1019 45 2 7-o
10 67.9 910 50 22.9 ...
15 60.0 802 56 18.5
SOLUBILITY OF AMMONIA IN AQUEOUS SALT SOLUTIONS.
(Raoult.)
In Calcium Nitrate Solutions In Potassium Hydroxide Solutions
Gms. NH 3 per 100 Gms. NH 3 per 100
Gms. Solvent in: Gms. Solvent in:
t. ' 28.38% In 59-03% 11-25% 25.25%
Ca(N03) 2 . Ca(N0 3 ) 2 . KOH. KOH.
o 96-25 104.5 7 2 - 49-5
8 78.50 84.75 57-o 37-5
16 65.00 70.5 46-0 28.5
24 37-3 2I - 8
AMMONIA 18
MUTUAL SOLUBILITY OF AQUEOUS AMMONIA AND POTASSIUM CARBON-
ATE SOLUTIONS.
(Newth J. Chem. Soc. 77, 776, 1900.)
The solutions used were: Potassium Carbonate saturated at 15
(contained 57.2 grams K 2 CO 3 per 100 cc.). Aqueous Ammonia of
0.885 Sp. Gr. (contained about 33 per cent ammonia). The determina-
tions were made by adding successive small quantities of one of the
solutions to a measured volume of the other, and observing the point
at which opalescence appeared.
Saturated KgCOg in Aq. Ammonia. Aq. Ammonia in Saturated
t. cc. KaCOs per %KyO 3 Solution f cc. Ammonia %K2CO 3 Solution
100 cc. Ammonia. in Mixture. in 100 cc. KjCOa. in Mixture.
I 2.0 2.0 37-5 72.7
6 3.0 3.0 47-5 6 7-6
ii 5.0 4-7 52-5 6 5-o
16 6.5 6.1 60.0 63.0
21 8.5 8.0 77.5 56.3
26 10.5 9.5 105.0 49.0
31 12.5 ii. i 152.5 39.0
38 20.0 16.6 195-0 33-0
39 21.0 17-0 220.0 31.0
42 25.0 20- o 250.0 28.5
43 35.0 26.0 285.0 26.5
Above 43 the solutions are completely miscible. If 10 per cent of
water is added to each solution the temperature of complete miscibility
is lowered to 25. The mutual solubilities are:
Per cent K 2 CO 3 Solution in:
t.
Ammonia
K 2 C0 3 Sol.
Layer.
Layer.
8
62
10
ii
52
20
15
38
25 (crit. pt.)
25
With the addition of 12.9 per cent of water to each solution the
temperature of complete miscibility (crit. pt.) is lowered to 10. With
the addition of 18.1 per cent water this temperature becomes o.
SOLUBILITY OF AMMONIA IN ABSOLUTE ETHYL ALCOHOL.
(Delepine J. pharm. chim. [5] 25, 496, 1892; de Bruyn Rec. trav. chim. ii, 112, '92.)
to
.
Cms. NH 3
Gms. NH 3 per 100 Gms. Solution.
Gms. NH 3 per TOO Gms. Alcohol
.
Density.
per 100 cc.
Solution.
(Delepine.)
(de Bruyn.)
(Delepine.)
(de Bruyn.)
0.782
I3-05
20-95
19.7
26.5
24-5
5
0.784
12 .00
19.00
!7-5
23.0
21 .2
10
0.787
10.85
16.43
15.0
19.6
I 7 .8
15
0.789
9-20
13.00
13.2
15.0
15.2
20
0.791
7-50
10.66
"5
II. 9
13.2
25
o-794
6.00
IO.O
IO.O
II .0
II .2
30
0.798
5-15
9-7
8.8
10-7
9-5
AMMONIA
SOLUBILITY OF AMMONIA IN AQUEOUS ETHYL ALCOHOL.
(Delepine.)
In 96% Alcohol.
In 90% Alcohol.
In 8o%j\lcohol.
t.
Sp. Gr.
Solution.
G. NH 3 per
zoo Gms. Sol.
Sp. Gr. G. NH 3 per
Solution. 100 Gms. Sol.
Sp. Gr. G. NH 3 per
Solution. 100 Gms. Sol.
O
0.783
24-5
O.8OO 30.25
0.808 39 -o
10
0.803
18.6
0.794 28.8
0.800 28.8
20
0.788
14.8
0-795 IS' 8
O.82I 19.1
30
0.791
10.7
0.796 II-4
0.826 12.2
In 60% Alcohol.
t.
Sp. Gr.
Solution.
G. NH 3 per
100 Gms. Sol.
o
0.830
50-45
10
0.831
37-3
20
0.842
26.1
30
0.846
21 .2
In 50% Alcohol.
Sp. Gr.
Solution.
0.835
0-850
0.869
0.88 3
G. NH 3 per
100 Gms. Sol.
69.77
43-86
33-8
25.2
SOLUBILITY OF AMMONIA IN ABSOLUTE METHYL ALCOHOL.
(de Bruyn Rec. trav. chim. n, 112, '92.)
G. NH 3 per 100 Grams.
O
5
10
15
G. NH 3 per 100 Grams.
Solution. Alcohol.
29-3
26.5
24.2
21 .6
41-5
3 6 -4
31.8
27.8
20
25
30
Solution. Alcohol.
19.2 23.8
20.
16.0
I6. 5
I4.O
DISTRIBUTION OF AMMONIA BETWEEN:
Water and Amyl Alcohol at 20. Water and Chloroform at 20.
(Herz and Fischer Ber. 37,
4747, '04.)
(Dawson and McCrae J. Ch. Soc. 79, 496, '01; see
also Hantsch and Sebaldt Z.phys.Ch.so, 258, '99.)
Gms . NH 3 per TOO cc.
G.M.NH 3 per IQOCC.
Gms.NHsper TOO cc.
G. M. NH 3 per too cc.
Aq. ^
Alcoholic
Aq.
Alcoholic
Aq.
Crici 3
Aq.
CrtU 3
Layer
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
o-5
.072
O
25
O
0035
O
.2
O.OO7
O.OI
0-00038
I -0
.147
O
50
.0073
O
4
O.OI5
O-02
0.00073
2 -C
.272
I
OO
.0148
.6
0.023
0-03
O.OOII4
3-o
438
2
OO
0295
O
.8
0.031
O-O4
0.00152
4.0
595
3
.00
.0460
I
.0
0-039
0-05
0.00193
5-
756
I
.2
0-046
O-o6
O.OO232
.
I
4
0-055
0.08
o . 003 i i
I
.6
0-063
O-IO
0-00396
NOTE. The influence of a large number of electrolytes upon the
distribution of ammonia between water and chloroform was also
investigated. For calculations of above distribution results, see Note,
page 4.
AMMONIUM ARSENATES 20
SOLUBILITY OF AMMONIUM CALCIUM ARSENATE AND AMMONIUM
MAGNESIUM ARSENATE IN WATER, ETC.
(Field J. Ch. Soc. II, 6, '73-)
Grams per ioo Grams Solvent.
Solvent.
Water 0.02 o 014
Aq. Ammonia 10% (Sp. Gr. 0.88) o.ooi 0.007
Aq. NH 4 C1 5% . . , 0.415
Aq. NH 4 C1 10% 0.095
AMMONIUM BENZOATE NH 4 C 7 H 6 O 2 .
SOLUBILITY IN WATER AND IN ALCOHOL.
Cms. NH4C7H 5 O2 per 100 Gms. Solvent in :
t. 'Water. Alcohol."
25 9-5 2 4-o
b. pt. 83.33 13.2
AMMONIUM BROMO PLATINATE (NH 4 ) 2 PtBr 6 .
100 gms. sat. aq. solution contain 0.59 gm. (NH 4 ) 2 PtBr 6 at 20.
(Halberstadt Ber. 17, 2965, '84.)
AMMONIUM BROMIDE NH 4 Br.
SOLUBILITY IN WATER.
(Eder Abh. K. Akad. Wiss. (Berlin) 82 ii, 1284, '80.)
Gms. NIL^Br. per 100 Grams. Gms. NH 4 Br. per 100 Grams.
t. 'Solution. Water.' t. Solution. Water.
10 39.8 66.2 50 48-5 94-3
20 42.5 74 -o 60 50-2 101.0
30 44.8 81.3 80 53.5 115-0
40 46.7 87.5 100 56.1 128.2
SOLUBILITY OF AMMONIUM BROMIDE IN ABSOLUTE ETHYL ALCOHOL,
METHYL ALCOHOL, AND IN ETHER.
(Eder; de Bruyn Z. phys. Ch. 10, 783, '92.)
In Ethyl Alcohol. In Methyl Alcohol. In Ether (0.729 Sp. Gr.).
Gms. NH4Br Gms. NH4Br Gms. NILJBr
per IPO prams. per 100 Grams. per 100 Grams.
t. Solution. Alcohol. Solution. Alcohol. Ether.
15 2 -97 3- 6 o- I2 3
19 3.12 3.22 ii. i 12.5
78 9.50 10.50 ....
Solubility of Tetra Ethyl AMMONIUM BROMIDE N(C 2 H 6 ) 4 Br, and
of Tetra Methyl Ammonium Bromide N(CH 3 ) 4 Br in Acetonitril.
(Walden Z. phys. Ch. 55, 712, '06.)
ioo cc. sat. solution in CH 3 CN contain 9.59 gms. N(C 2 H 6 ) 4 Br at 25.
100 cc. sat. solution in CH 3 CN contain 0.17 gm. N(CH 3 ) 4 Br at 25.
AMMONIUM CADMIUM BROMIDE NH 4 Br.CdBr 2 .|H 2 O.
ioo parts of water dissolve 137.0 parts NH 4 Br.CdBr 2 .$H 2 O.
ioo parts of alcohol dissolve 18.8 parts NH 4 Br.CdBr 2 .$H 2 O.
ioo parts of ether dissolve 0.36 part NH 4 Br.CdBr 2 .JH 2 O.
(Eder Dingier polyt. J. 221, 89, '76.)
21 AMMONIUM CARBONATE
AMMONIUM CARBONATE (NH 4 ) 2 CO 3 .
100 grams H 2 O dissolve 100 grams (NH 4 ) 2 CO 3 H 2 O at 15.
100 grams glycerine dissolve 20 grams (NH 4 ) 2 CO 3 at 15.
(Divers J. Ch. Soc. 23, 171, '70.)
AMMONIUM BICARBONATE NH 4 HCO 3 .
SOLUBILITY IN WATER.
(Dibbits J. pr. Ch. [2] 10, 417, '74.)
Gms. NILJICOa per 100 Grams.
Solution. Water.
10.6
o
5
10
15
13.7
iS-5
11.9
T 3-7
15.8
l8 -3
Grams NHjNCOa per 100 Grams.
Solution. Water.
20 17-4 21. o
25 19-3 23.9
3 2I -3 27.0
SOLUBILITY OF AMMONIUM BICARBONATE IN AQUEOUS SOLUTIONS OF
AMMONIUM CHLORIDE SATURATED WITH CO 2 .
(Fedotieff Z. phys. Ch. 49, 168, '04.)
Per 1000 cc. Solution.
4. W I . Ol
1 i cc. Sol.
G.M.
G.M.
Gms.
Gms.
G. M.
G. M.
Gms
NH4C1.
NILJICOs. NH 4 C1.
NHiHCOjj.
NH4C1.
OQ
NH 4 HC0 3 . NH 4 C1.
1.22 ^ ^
NH 4 HCOa.
T T f\ ^v
. .
o 1.077
4.41
o-37
235
9
2 9
.2
\J
5-42
0.46
290.8
i iy . o
36.0
15 1.064
O-O
2 .12
o
I6 7
.2
o.o
2.36
o.o
186.4
15 1.063 0-5
1.84
26
.8
145
.2
0.56
2.06
29.9
162.9
15 1.062
1.0
i-59
53
5
125
5
1 .13
1. 80
60.6
142.2
15 1.062
1.41
1.42
75
4
112
.2
i-59
I .60
85.1
126.9
IS
.065
1,89
4.28
100
.8
101
.1
2.18
1.48
116.8
II6.8
15
.069
2.87
0.99
153
3
78
.2
3-42
1.18
183.0
93-3
IS
.076
3- 8 4
0.79
205
.2
62
5
5-03
0.98
269.3
77-3
.085
4.82
0.65
257
9
5 1
4
6.21
0.84
332.5
66.4
15
.085
4-95
0.62
264
.8
48
9
6.40
0.81
343-5
64.2
30
o.o
3-42
o.o
270.0
7O
*7 .A
T . TC
20*7 .n
nr .r
SOLUBILITY OF AMMONIUM BICARBONATE IN AQUEOUS SOLUTIONS OF
SODIUM BICARBONATE SATURATED WITH CO 2 .
(Fedotieff.)
o
o
15
15
Per 1000 cc. Solution.
Wt.of ' r M
i cc. Sol. N G H M 6g
G.M.
Gms.
i. NaHCO 3 .
Gms.
' I
.072
53
1.28
44.6
IOI
4
I
.064
.0
2 .12
o.o
I6 7
.2
I
090
o
63
1.92
5 2 -5
I5 !
3
Per looo Grams
G.M.
NaHCOjj.
O.O
0.58
0.0
0.71
o.o
0.83
G.M.
1.51
i-39
2.36
2.16
3-42
2.91
Gms.
aHC0 3 .
0-0
48.2
o.o
59-2
o.o
70.0
Gms.
119.0
109.4
186.4
170.6
270.0
230.0
AMMONIUM BICARBONATE 22
SOLUBILITY OF MIXTURES OF AMMONIUM BICARBONATE, SODIUM
BICARBONATE, AND AMMONIUM CHLORIDE IN WATER
SATURATED WITH CO 2 .
(Fedotieff.)
t o Wt. of
Gram Mols. per 1000
Gms. H 2 O.
Gms. per 1000 Gms. H2O.
Solid
Phase
i cc. Sol
" NaHCO 3 .
NaCl.
NH4C1.
NaHCO 3 .
NaCl.
NI^Cl.
iruasc.
o
.114
o-59
0.96
4
.92
49.61
56
.16
263
4
a+b + c
O
.187
0-12
4-83
2
74
IO.O9
282
.6
146
7
"
15
.116
o-93
0.51
6
.28
78.18
29
.84
336
.2
u
15
. I7 8
0.18
4.44
3
73
15.13
259
.8
199
.6
14
15
0.30
3-09
4
56
25.22
180
.8
244
.1
a + c
15
.128
0.51
1.68
5
45
42.87
98
.28
291
7
"
15 1. 112
0.99
o-35
5
65
83.22
20
47
302
4
a + b
15 I.IOS
1.07
O.2O
5
.21
89.95
II
.70
2 7 8
9
a
15 1.106
I .12
o.n
4
.92
94.14
6
44
263
4
a
15 i.ioi
1.16
0.14
4
.00
97-52
8
.19
214
.i
(i
15 1.090
o-93
o-95
2
03
78.18
55
58
108
.6
((
a =
NaHCO 3
,
b =
NH 4 HCO 3 ,
c
=
NH 4 C1.
AMMONIUM URANYL CARBONATE 2(NH 4 ) 2 CO 3 UO 2 CO 3 .
(Ebelmen.)
100 grams H 2 O dissolve 5 grams of the salt at 15.
AMMONIUM LEAD COBALTICYANIDE NH 4 PbCo(CN) 6 . 3 H 2 O.
(Schuler Sitz. Ber. K. Akad. W. (Berlin) 79, 302.)
ioo grams H 2 O dissolve 12.0 grams of the salt at 18.
AMMONIUM CHLORIDE NH 4 C1.
SOLUBILITY IN WATER.
(Mulder; below o, Meerburg Z. anorg. Ch. 37, 203, 1903.)
Gms. NH 4 C1 per ioo Gms. Gms. NH 4 C1 per ioo Gms.
Solution. Water." Solution. Water".
-15 19.7 24.5 40 31.4 45-8
-10.9 20.3 25.5 50 33.5 50.4
-5.7 21.7 27.7 60 35.6 55.2
o 22.7 29.4 70 37.6 60.2
+ 5 23.8 31.2 80 39.6 65.6
10 24.9 33.3 90 41.6 71.3
15 26.0 35.2 ioo 43 - 6 77-3
20 27.1 37-2 no 45-6 83.8
25 28.2 39.3 115.6 46.6 87.3
30 29.3 41.4
Density of saturated solution at o = 1.088, at 15 = 1.077, at I 9
- 1-075-
AMMONIUM CHLORIDE
SOLUBILITY OF AMMONIUM CHLORIDE IN AQUEOUS AMMONIUM BI-
CARBONATE SOLUTIONS SATURATED WITH CO 2 .
(Fedotieff Z. phys. Ch. 49, 169, 1904.)
Per 1000 cc. Solution.
Per 1000 Cms. H 2 O.
t.
VV I . Ol
i cc. Sol.
G.M.
G. M.
Gms.
Gms.
G.
M.
G. M.
Gms.
Gms.
NH 4 HCO 3 . NH 4 C1. NH.HCC
3 . NKiCl.
NH.HCG-3. NH/C1.
NH4HC1. NH4C1.
1 .069
O-O
4.60
O-O
246
.1
O
O
5-57
o.o
298.0
1.077
o-37
4.41
29.2
235
9
O
.46
5-42
36-0
290.8
15
1.077
o.o
5-29
o.o
283
.1
O
6.64
o.o
355-o
1.085
0.62
4-95
48.9
264
.8
O
.8l
6.40
64.2
343-5
30
O
O
7.78
o.o
416.4
70
I
7 .A.Q
OT .0
70*7 .0
SOLUBILITY OF AMMONIUM CHLORIDE IN AQUEOUS SOLUTIONS OF
SODIUM CHLORIDE SATURATED WITH CO 2 .
(Fedotieff.)
Per 1000 cc. Solution.
Per 1000 Gms. H 2 O.
t.
Wt.of
G.
M.
G. M.
Gms.
Gms.
G. M.
G. M.
Gms.
Gms.
i cc. Sol.
NaCl.
NH 4 C1.
NaCl.
NH 4 C1.
NaCl.
NH 4 C1.
NaCl.
NH 4 C1.
I .069
O
.0
4.60
O
.0
246.1
0-0
5-57
o.o
2Q8.0
O
1.085
4
.04
2.26
236
.5
121 -O
4.89
2-73
286.4
146.1
15
1.077
.0
5-29
O
o
283-1
O-O
6.64
o.o
355-o
15
1.097
o
.81
4.71
47
5
252.1
I .02
5-91
59-8
316.4
15
I .I2O
I
.68
4-13
98
o
221 .7
2.09
5.18
122 .4
277.0
15
I-I53
2
-87
3-38
168
o
180.7
3-57
4.20
208.9
224.7
15
I-I75
3
65
2.98
213
5
159-4
4-55
3-72
266.8
198.8
30
o-o
7.78
0-0
416.4
30
1.166
3
30
3-70
J 93
o
198.0
4.26
4-77
249-0
255-4
45
O-O
9-03
0-0
483.7
AC
A.O
6.02
277 .0
722.1
SOLUBILITY OF AMMONIUM CHLORIDE IN AQUEOUS SOLUTIONS OF
HYDROCHLORIC ACID AT o.
(Engel Ann. chim. phys. [6] 13, 379, '88.)
Sp. Gr. of
Solutions.
076
.069
.070
.071
073
.078
I
I
I
I
I
I
I .100
1.114
Milligram Molecules per Grams per 100 cc.
10 cc. Solution. Solution.
HCl.
NH 4 C1.
HCl.
NH 4 C1.
O-O
46.12
o.o
24.61
2. 9
43 - 6
1.05
23 -16
5-5
41 -o
1.99
21.78
7-85
39-15
2.84
20.79
10.85
3 6 -45
3-93
19.36
21.4
27-37
7-74
14-54
53-o
10.87
19.18
5-78
61 .0
8.8
22 .07
4.67
Sat. HCl at 1 2
3 -7 at
17
AMMONIUM CHLORIDE
24
SOLUBILITY IN AQUEOUS AMMONIA SOLUTIONS
(Engel Bull. soc. chim. [3] 6, 17, 1891.)
AT 0.
Sp. Gr. of
Milligram
per 10 cc.
Molecules
Solution.
Grams per 100 cc.
Solution.
Solutions.
'NH 3 .
NI^Cl.
NH 4 OH.
NH 4 C1.
1.067
5-37
45-8
0.92
24.52
1.054
12. 02
45-5
2.05
24-35
I.03I
38.0
44-5
6.48
23-82
I .025
47-o
44.0
8.02
2 3-5 6
I.OI7
54-5
43- 6 3
9-30
23-35
o-993
80.0
43.12
13.66
23.09
0.992
90.0
44.0
I5-36
23-56
0.983
95-5
44-37
16.29
23-75
o-953
130.0
49-75
22.18
26.63
0.931
169-75
60-0
28.97
32.14
SOLUBILITIES OF MIXTURES OF AMMONIUM CHLORIDE AND OTHER SALTS
IN WATER.
(Riidorff, Karsten, Mulder.)
Both salts present in solid phase.
4, 0> Grams per 100 Grams H 2 O.
b.pt. 67.7NH 4 Cl+2i. 9 KCl M
t e .
19.
21.
20.
18.
15-
22.
5
5
o
5
(
jrams ]
Der K
30 (Jl
an
is tiz^J
R
R
R
K
R
R
29.
26.
33-
39-
28.
30-
2
8
8
2
9
4
NH 4 Cl+i74.o
" + 46-5
" + ii. 6
" + 17.0
" + 16.9
" 4- 19.1
NH 4 NO 3
(NH 4 ) 2 S0 4
BaCl 2
Ba(N0 3 ) 2
KC1
KC1
14.8 38.8
18-5 39-8
14.0 36.8
18.7 37.9
18.7 22.9
+ 34 .2KN0 3 K
+ 38.6KNO 3 K
+ 14.1 K 2 SO 4 R
+ i 3 . 3 K 2 S0 4 K
R
SOLUBILITY OF AMMONIUM CHLORIDE IN ABSOLUTE ETHYL AND METHYL
ALCOHOL AT 19 AND IN AQUEOUS ETHYL ALCOHOL
SOLUTIONS.
100 grams absolute ethyl alcohol dissolve 0.62 grams NH 4 C1.
100 grams absolute methyl alcohol dissolve 3.35 grams NH 4 C1.
(de Bruyn Rec. trav chim. n, 156, '92.)
In Aqueous Alcohol at 30.
(Bathrick J. Physic. Chem. i, 159, '96.)
Wt. per cent
Alcohol.
per 100 g.
Alcohol.
Wt. per cent
Alcohol.
G. NH 4 C1
per 100 g.
Alcohol.
O
40.4
45-9
17.0
8-3
35-3
54-3
I4.O
l6.9
31.8
65 -o
9 .6
25-9
27-5
75-6
6. 4
34-4
21.7
87.9
2-9
In Aq. Alcohol of 45 Wt. %.
(Gerardin Ann. chim. phys. [4] 5, 147, '65.)
'
G. NH 4 C1
t.
per 100 g.
Alcohol.
4
II -2
8
12.6
27
38
56
19.4
2 3 .6
30.1
25 AMMONIUM CHLORIDE
SOLUBILITY OF AMMONIUM CHLORIDE IN AQUEOUS GLYCERINE SOLU-
TIONS AND IN AQUEOUS ACETONE SOLUTIONS AT 25.
(Herz and Knoch Z. anorg. Chem. 45, 263, 267, '05.)
In Aqueous Glycerine.
(Sp. Gr. of Glycerine 1.255, Impurity about 1.5%.)
In Aqueous Acetone.
Wt.%
NH4C1 per 100 cc. Sp. Gr.
Solution. , 2s Vol.%
NH 4 C1 per 100 cc.
Solution.
Sp. Gr.
Glycerine*
Millimols.
Grams. 4
Millimolb
Grams. ""* 4
.
585
.1
3I-32
0793
585
I
31
32
1.0793
13
.28
544
.6
29.16
.0947
10
534
I
28
59
I. O6l8
25
.98
502
9
26.93
.1127
20
464
6
24
.87
I.045I
45
36
434
4
23 .26
.1452
30
396
7
21
2 3
1.0263
54
23
403
5
21 .60
.1606
40
328
5
17
59
o . 9998
83
.84
291
4
15.60
.2225
^46.5
L 283
7
o . 9800
100
.00
228
4
12.23
.2617
^85-7
U 18
9
I
.01
0.8390
90
9
4
O
5o
0-8274
*
Between these two concentrations of acetone, the
solution
separates into
two layers.
L indicates
lower layer, U indicates "upper layer.
Solubility of Tetra Ethyl AMMONIUM CHLORIDE N(C 2 H 6 ) 4 C1, and
also of Tetra Methyl Ammonium Chloride N(CH 3 ) 4 C1 in Acetonitril.
100 cc. sat. solution in CH 3 CN contain 29.31 gms. N(C 2 H 6 ) 4 C1 at 25.
100 cc. sat. solution in CH 3 CN contain 0.265 g ms - N(CH 3 ) 4 C1 at 25.
(Walden Z. physik. Chem. 55, 712, '06.)
AMMONIUM
CHROMATES.
SOLUBILITY IN WATER
AT 30'
(Schreinemaker Z. physic. Chem. 55, 89, '06.)
Composition in Wt. per cent of:
Solid Phase.
The Solution.
The Residue.
% Cr0 3 .
% NH 3 .
% Cr0 3 .
% NH 3 .
6-933
22.23
. . .
9.966
16.53
47-59
20-44
16.973
8.20
22-53
6-37
38-03
12.15
27.09
6.87
48 .02
12 .01
26.19
5-7o
47 -38
8.81
25-99
5.10
41.56
7-58
30.16
3-5o
38.89
3.10
61.08
8.80
42.44
3-i5
59-72
6-75
44-08
2.27
54-90
4.14
52.91
i .11
60.88
3-09
54-56
1.03
63.07
3-9
56-57
0.97
65.70
2-95
58-87
0.65
69.74
3-24
62.48
0.46
71-93
3.10
63.60
o .40
73-68
1.18
63.66
0.41
71 .47
2.07
62.94
0-21
62.28
o.o
. . .
(NH 4 ) 2 CrO<
(NH 4 ) 2 Cr0 4 +(NH 4 ) 2 Cr 2 7
(NH 4 ) 2 Cr 2 7
(NH 4 ) 2 Cr 2 7 +(NH 4 ) 2 Cr 3 1( ,
(NH 4 ) 2 Cr 3 O 10
(NH 4 ) 2 Cr 3 10 + (NH 4 ) 2 Cr 4 13
(NH 4 ) 2 Cr 4 3
(NH 4 ) 2 Cr 4 O 13 +CrO 3
U
Cr0 3
CrOs
100 gms. of the sat. aq. solution contain 28.80 gms.(NH 4 ) 2 CrO 4 at 30
100 gms. of the sat. aq. solution contain 3 2. 05 gms. (NH 4 ) 2 Cr 2 O 7 at 30
AMMONIUM FLUOBORIDE
26
AMMONIUM FLUOBORIDE NH 43 BF 3 ,
100 parts of water dissolve 25 parts salt at 16, and about 97 parts
at b. pt. (Stolba Chem. Techn. Cent. Anz. 7, 459->
AMMONIUM FORMATE
Formate.
HCOONH 4 , and also Ammonium Acid
SOLUBILITY IN WATER.
(Groschuff Ber. 36, 4351, '03.)
Solid.
20
o
20
40
60
80
Gms. HCOONH 4
per 100 Gms.
Solution. Water.
41.9 72 HCOONH,
50.5 102
58.9
6 7 .I
75-7
84.2
116 f. pt.
143
204
3"
Gms. per 100 Gms.
t. Solution.
Solid.
PV.OCO
HCOONH 2 + HCOOH. * ""~"
6-5
46.7
34-1
HCOONH 4 .HCOOH
i-5
49.6
36.2
M
6.0
5 J -3
37-4
11
8-5
5 2 - 1
38.0
M
7
49.6
36.2
HCOONH 4 labil.
i3
53-
38.6
" stabil.
29
55-8
40.7
39
57-8
42.2
H 2 O free solution.
SOLUBILITY OF AMMONIUM FORMATE IN FORMIC ACID SOLUTIONS.
(Groschuff.)
30 grams of HCOONH 4 dissolved in weighed amounts of formic acid
and cooled to the point at which a solid phase separated.
G. M.
COONI
per
Gms.
G. M.
Gms.
HCOONH* HCOONH 4 qni;H
HCOONH,
t.
per
100 Gms.
per
100 G.M.
Phase.
t.
per
100 Gms
Solution.
HCOOH.
Solution
- 3
35-3
39-9
HCOONH
v "
50.0
HCOOH
39
57.8
+ 8.5
40.6
49.9
11
78
73-i
21.5
50.0
73-
"
116 m.pt.
, IOO.O
Solid
Phase.
73.0 HCOONH, labil.
loo.o stabil.
199.0
00
AMMONIUM IODATE NH 4 IO 3 .
100 parts H 2 O dissolve 2.6 parts salt at 15 and 14.5 parts at 100.
(Rammelsberg Pogg. Ann. 44, 555, 1838.)
Tetra Methyl AMMONIUM IODIDE N(CH 3 )J.
SOLUBILITY IN SEVERAL SOLVENTS.
(Walden Z. physik. Chem. 55, 708, '06.)
SD
Gr. of
Gms. N(CH 3 ) 4 I per 100.
Solvent.
Formula.
t .
'
Gi
us.
cc
, Solution.
Solution.
Water
H 2
O
I
-Ol88
2
OI
I
97
Water
H 2 O
25
I
.0155
5
.31-5 .89
>5
.22
Methyl Alcohol
CH 3 OH
o
O
.8025
o
.l8-0.22
o
.22
Methyl Alcohol
CH 3 OH
25
-7920
0.38-0.42
o
.48
Ethyl Alcohol
C 2 H 5 OH
25
.7894
o
.09
Glycol
(CH 2 OH)
2
o
J
.OI4
Glycol
(CH 2 OH)
3
25
I
.0678
.240
.224
Acetonitril
CH 3 CN
25
. . .
o
.650
Nitro Methane
CH 3 N0 2
o
I
1387
o
.25-0-32
o
.22
Nitro Methane
CH 3 NO 2
25
I
.1285
o
.34-0.38
.21
Acetone
(CH 3 ) 2 CO
,118
. .
Acetone
(CH 3 ) 2 CO
25
o
.187
Salicyl Aldehyde
C 6 H 4 .OH.
COH
o
I
.1492
o
.302
o
.263
Salicyl Aldehyde
CJL.OH.
COH
25
I
1379
o
.510
o
,484
27 AMMONIUM IODIDE
Tetra Ethyl AMMONIUM IODIDE N(C 2 H 6 )J.
SOLUBILITY IN SEVERAL SOLVENTS.
(Walden Z. physik. Chem. 55, 6gS, '06.)
SD Gr of
Gms. N(C 2 H 5 )4 I per 100.
Solvent.
Formula.
t.
Solution.
cc. Solution. Sohitkm
Water
H 2 O
o
I .0470
16.31
I5-58
Water
H 2 O
2 5
I .IO2I
36.33(35
5) J 3-44
Methyl Alcohol
CH 3 OH
o
0.8326
3-7-4-3
4-44
Methyl Alcohol
CHsOH
25
o . 8463
10.5 (10
.7) 12.29
Ethyl Alcohol
C 2 H 5 OH
0.7928
0.348
0-439
Ethyl Alcohol
C 2 H 5 OH
25
0.7844
0.98 (o
.88) 1.249
Glycol
(CH 2 OH) 2
I . 1039
3-27
2-97
Glycol
(CH 2 OH) 2
25
I . 0904
7-63 (7
55) 7-oo
Acetonitril
CH 3 CN
0.8163
2.24
2.74
Acetonitril
CH 3 CN
25
0.7929
3-o4(3
54) 3-83
Propionitril
CH 3 CH 2 CN
0.8059
0.618
0.767
Propionitril
CH 3 CH 2 CN
25
0.7830
0.81-1.
01 1.29
Benzonitril
C 6 H 5 CN
25
. . .
0.467
. . .
Methyl Sulphocyanide
CH 3 SCN
25
1.0828
4.40
4.06
Ethyl Sulphocyanide
C,H 5 SCN
25
I .0012
0-475
0-47
Nitro Methane
CH 3 NO 2
o
1.1658
3-59
3.004
Nitro Methane
CH 3 N0 2
25
I.I476
5.61-6.
27 5-6i
Nitroso Dimethylin
(CH 3 ) 2 N.NO
25
I .OO59
2.67
2.66
Acetyl Acetone
CH 3 COCH 2 COOCH 3
25
0.268
Furfurol
C 4 H 3 O.COH
o
I.I738
3-9 1
3-33
Furfurol
C 4 H 3 O.COH
25
I .1692
5-33
4-55
Benzaldehyde
C H 5 COH
25
o-43
Salicylaldehyde
C 6 H 4 .OH.COH
25
change-
able-i7
.7
Anisaldehyde
C 6 H 4 .OCH 3 .COH
25
o-59
Acetone
(CH 3 ) 2 CO
0.7991
0.174
0.218
Acetone
(CH 3 ) 3 CO
25
0.249
0.218
Ethyl Acetate
CH 3 COOC 2 H 5
25
0.00039
Ethyl Nitrate
C 2 H 5 ON0 2
25
I .0984
0.062
0.056
Benzoyl Ethyl Acetate
C 6 H 5 COCH 2 COOC 2 H 5 25
I I3C3
0.321
0.284
Di-Methyl Malonate
CH,(COOCH 3 ) 2
25
I . 1335
0.040
0-035
Methyl Cyan Acetate
CH 2 CNCOOCH 3
o
I .1341
1.82
1.605
Methyl Cyan Acetate
CH 2 CNCOOCH 3
25
2-83
Ethyl Cyan Acetate
CH 2 CNCOOC 2 H 5
1.0760
i-o57
0.981
Ethyl Cyan Acetate
CH 2 CNCOOC 2 H 6
25
I .0607
1.71
1.41
AMMONIUM IODIDE
28
Tetra Propyl AMMONIUM IODIDE N(C 3 H 7 ) 4 I.
SOLUBILITY IN SEVERAL SOLVENTS.
(Walden Z. phyaik. Chem. 55. 700. '06.)
Gms. N(C 3 H 7 )4 I per 100.
cc. Solution.
Solvent.
Formula.
Sp. Gr. of
Solution.
Gms.
Solution.
Methyl Alcohol
CH 3 OH
o
9756
40
.92
41
94
Methyl Alcohol
CH 3 OH
25
I
.0187
56
.42
55
37
Ethyl Alcohol
C 2 H 8 OH
o
8349
6
.5-6.8
8
.14
Ethyl Alcohol
C 2 H 5 OH
25
.8716
19
.88-20.29
23
.28
Acetonitril
CH 3 CN
o
8553
13
03
15
.24
Acetonitril
CH 3 CN
25
.8584
18
.69
21
77
Propionitril
C 2 H 6 CN
o
o
.8280
6
37
7
.66
Propionitril
C-jHjsCN
25
.8191
9
65
ii
.76
Benzonitril
C 6 H 6 CN
25
.0199
8
44
8
35
Nitro Methane
CH 3 NO a
o
.181
14
79
12
52
Nitro Methane
CH 3 N0 2
25
.158
22
.24
19
.21
Nitro Benzol
C 6 H 6 N0 2
25
' 5
.71
4
79
Benzaldehyde
C 6 H 6 COH
o
.0581
7
.06
6
.67
Benzaldehyde
CeHsCOH
25
0549
9
.87
9
35
Anisaldehyde
C 6 H fi .OCH 3 .COH
.1114
5
.60
5
.04
Anisaldehyde
C 6 H 6 .OCH 3 .COH
25
I
.1004
6
75
6
.14
Salicylaldehyde
C 6 H 5 .OH.COH
52
. . .
39
.28
Ethylnitrite
C 6 H 6 ONO 8
o
I
.1207
522
o
.466
Ethylnitrite
C 6 H 5 ON0 2
25
I
.1025
o
653
o
592
Di-Methyl Malonate
CH 2 (COOCH 3 ) 2
o
I
I 53 2
o
.298
o
259
Di-Methyl Malonate
CH 2 (COOCH 3 ) 2
25
I
1345
o
.320
o
.282
Acetone
(CH 3 ) 2 C
o
o
.8259
2
.692
3
.26
Acetone
(CH 3 ) 2 CO
25
.8049
3
944
4
.90
Ethyl Acetate
CHaCOOCA
25
8975
o
.0063
o
.007
AMMONIUM NITRATE NH 4 NO 3 .
SOLUBILITY IN WATER.
(Schwarz Ostwald's Lehrbuch, ad ed. p. 425; Muller and Kaufmann Z. physik. Chem.
42, 497, 'oi-'oz.)
t
Sp. Gr.
Solution.
G. Mols.
NH 4 NO 3 per
too Mols. H 2 C
Gms. NH4NO 3 per
)ioo Gms.
Solid
Phase.
Solution.
Water.
o
. . .
26
63
54
.19
118
3
NH 4 NO 3 rhomb, ft
12
.2
2945
34
5o
60
53
J 53
4
20
.2
.3116
43
30
65
.80
192
4
it
25
O
3*97
48
19
68
i7
214
.2
H
30
.O
3299
54
40
70
73
241
.8
tc
32
. j
3344
57
.60
7i
97
256
9
NH 4 NO 3
rhomb, ft + rhomb, a
35
.0
3394
59
.80
72
.64
265
.8
NH 4 N0 3
rhomb, a
40
.0
3464
66
.80
74
.82
297
.0
50
.0
77
.41
77
49
344
.0
M
60
.0
94
73
80
.81
421
.0
((
70
.0
112
30
83-32
499
.0
80
.0
130
50
85
25
580
.0
It
90
.0 ...
166
5o
88
.08
740
.0
NH 4 NO 3
rhombohedral ?
100
.0
196
.00
89
7i
871
.0
a 9 AMMONIUM NITRATE
SOLUBILITIES OF MIXTURES OF AMMONIUM NITRATE AND OTHER
SALTS.
(Riidorff Mulder.)
ioo gms. H 2 O dissolve 162.9 gms. NH 4 NO 3 + 77.1 gms. NaNO, at
i6R.
ioo gms. H 2 O dissolve 88.8 gms. NH 4 NO 3 + 40.6 gms. KNO, at
9 M.
ioo gms. H 2 O dissolve 101.3 gms. NH 4 NO 3 + 6.2 gms. Ba(NO 8 ) 2 at
9 M.
SOLUBILITY OF AMMONIUM NITRATE IN AMMONIA.
(Kuriloff Z. physik. Chem. 25, 109, '98.)
Mols. NH4NO8
Gms. Gms. per ioo Mols. Gms.
NH 4 NO 3 t.
+ NH 3 .
o.o 33.3
6-25 35-9
1.2457 13.9 68.8
0.3700 32.3 94.0
o-35 J 5 3 6 -9 J 9o-8
0.2607 38.3 168.0
-80
-60
-44-5
-30
-10.5
o
Gms.
NH 3 .
IOO
I.39I8
0.9526
0.8308
0.9675
o - 7600
0-9358
0.7746
4.2615
0.6439
0.7578
Mols.
Gms. per ioo
NH 3 . N^NOs
+ NHs?
0.2352
0.1857
0-7747
0.0665
0.0588
45-9
47-o
53-8
67-3
74.2
100.0
t = temperature of equilibrium between solution and solid phase.
SOLUBILITY OF AMMONIUM NITRATE IN NITRIC ACID.
(Groschuff Ber. 37, 1488, '04.)
Determinations by the " Synthetic Method," see Note, page 9.
Gms. Mols. Gms. Mols.
t o NHiNOa NHiNOs Solid t o NH 4 NO 3 NH 4 NO 3 Solid
' per ioo per ioo Phase. per ioo per ioo Phase.
Gms. Sol. Mols. HNO 3 . Gms. Sol. Mols. HNO 3 .
8
21. I
21
.1
N^NOs-aHNOg
II
.0
51-7
84-
3 NH.NOs.HNOs
23
28.7
3 1
.6
a
12
.0
54.7
95-
I
" labil.
29
.5m.pt.
3 8.8
5o
.0
"
II
5
57-6
108.0
b
27
5
44.6
63
.4
b
II
5
54-0
92.
4 N
r^NOs labil.
23
5
49-4
76
.8
"
17
.0
54-7
95-
I
44 stahU.
17
5
54-o
92
4
"
27
.0
56.2
IOI.
44
16
4
5
.0
54-3
45-8
93
66
5
7
NH 4 NO 3 .HN0 3
labil
49
79
.0
.0
60.4
68.1
120.0
168.0
a= solution in HNO 3 , b = solution in NH,NOj
SOLUBILITY OF AMMONIUM TRI-NITRATE IN WATER.
(Groschuff.)
Gms. NH 4 NO 3
Gms. HNO 3
Mols. NH4NO8* Mols.
t.
per ioo
Gms.
per ioo
Gms.
per ioo
Mols.
pel
total
Solution.
Solution.
H 2 O.
Solt
-8
34-2
53-9
64.3
22
-2.5
34-8
54-8
75-1
23
35-4
55-8
9O.O
24
i'-s
36.6
5 6 -9
113 .O
25
19-5
37-4
58.9
225.0
29
25.0
38.1
60.0
450.0
31
29.5 m. pt.
38.8
61.2
o.o
O
Solid
Mols. Phase
tion.
o NHJSTOs^HNO,
i
3
7
.o
.o
or NH*NO 8 .2HNO 8 .
AMMONIUM NITRATE 30
SOLUBILITY OF AMMONIUM NITRATE IN AQUEOUS ETHYL ALCOHOL.
(Fleckenstein Physic. Z. 6, 419, '05.)
Grams of NH 4 NO 3 Dissolved per 100 Grams Aq. Alcohol of (Wt.%).
f~.
100%.
86.77%.
76.12%.
51-65%.
25.81%.
0%.
20
2-5
II .0
23.0
70-0
140
J 95
30
4.0
14.0
32 .0
90.0
165
230
40
5-o
18.0
43-o
115 .0
196
277
50
6.0
24.0
55-o
144.0
244
365
60
7-5
30.0
70.0
183.0
320
70
9.0
41 .0
93-o
230.0
80
10.5
56.0
NOTE. The figures in the preceding table were read from curves
shown in the abridged report of the work, and are therefore only
approximately correct. Determinations of the solubility in methyl
alcohol solutions were also made but not quoted in the abstract. The
" Synthetic Method" (see Note, page 9) was used.
100 grams absolute ethyl alcohol dissolve 4.6 grams NH 4 NO 3 at
14 and 3.8 grams at 20.5.
100 grams absolute methyl alcohol dissolve 14.6 grams NH 4 NO 3 at
14 and 17.1 grams at 20.5.
(Schiff and Monsacchi Z. physik. Chem. 21, 277, '96; at 2o.sde Bruyn Ibid., 10, 783, '92.)
AMMONIUM MAGNESIUM NITRATE 2NH 4 NO 3 .Mg(NO 3 ) 2 .
100 parts water dissolve 10 parts salt at 12.5.
(Foucroy.)
AMMONIUM MANGANIC MOLYBDATE 5(NH 4 ) 2 MoO 4 .Mn 2 (Mo 2 O 7 ) 8 .
i 2 H 2 O.
100 parts water dissolve 0.98 Darts salt at 17.
(Struve J. pr. Chem. 61, 460, '54.)
AMMONIUM OXALATE (NH 4 ) 2 C 2 O 4 .
100 grams H 2 O dissolve 2.215 grams (NH 4 ) 2 C 2 O 4 at o Sp. Gr. of
solution = 1.0105.
(Engel Ann. chim. phys. [6] 13, 359, '88.)
SOLUBILITY OP NEUTRAL AMMONIUM . OXALATE IN AQUEOUS SOLU
TIONS OF ACID AMMONIUM OXALATE.
(Engel.)
J Milligram Mols. per 10 Grams per too cc.
cc. Solution. Solution.
(NH 4 ) 2 C 2 4
3.54 o-o 2.19 o.o
2-65 1.45 1.63 0-77
2 -475 2 -5 2 5 i-52 1-34
2.38 2.90 1.47 1.54*
* Both salts present in solid phase
3 i AMMONIUM OXALATE
SOLUBILITY OP AMMONIUM OXALATE AND OXALIC ACID IN WATER AT 25.
(Walden Am. Ch. J. 34, M9, '05-)
Mixtures of the two substances were dissolved in warm water and
the solutions allowed to cool in a thermostadt held at 25.
Composition of Solution.
Grams per 100 Gms.
Solution.
Mols. per 100 Mols.
H 2 0.
Solid Phase.
(NH,)
2 C 2 O 4
H 2 C
(NH 4 ) 2 C 2 4
. H 2 C 2 4 .
.28
IO
2O
0.045
2
.281
H 2 C 2 O 4 .2H 2 O and (NH 4 ) 2 C 2 O 4 . 3 H 2 C 2 O 4 . 4 I
O
.46
7
24
0.072
I
570'
2
3
44
65
2
2
59
.80
0.372
0.566
546
599
Double salt, (NH 4 ) 2 C 2 O 4 .3H 2 C 2 O 4 . 4 H 2 O
4
5
99
.20
3
3
55
0.791
0.824
745 J
.781
(NH 4 ) 2 C 2 O 4 . 3 H 2 C 2 4 . 4 H 2 O and
(NH 4 ) 2 C 2 4 .H 2 C 2 4 .H 2
5
36
3
38
0.853
741
|
6
.27
3
.04
I -OO
.671 1
> Double salt, (NH 4 ) 2 .C 2 O 4 .H 2 C 2 O 4 .H 2 O
7
03
2
.90
I-I3
O
645 '
1
7
.08
2
.70
I.I4
599
(NH 4 ) 2 C 2 4 .H 2 C 2 4 .H 2 and (NH 4 ) 2 C 2 O 4
6
.92
0-775
(NH 4 ) 2 C 2 4
AMMONIUM HYDROGEN PHOSPHITE (NH 4 H)HPO 3 .
100 grams water dissolve 171 grams (NH 4 H)HPO 3 at o, 190 grams
at 14.5 and 260 grams at 31.
(Amat. Compt. rend. 105, 809, '87.'
AMMONIUM PERMANGANATE NH 4 MnO 4 .
100 parts water dissolve approximately 8 parts of NH 4 MnO 4 at 15.
(Aschoff.)
AMMONIUM FLUO SILICATE (NH 4 ) 2 SiF 6 .
100 parts water dissolve 18.5 parts (NH 4 ) 2 SiF,5 at 17.5, Sp. Gr. 1.096.
(Stolba Chem. Centr. 418, 1877.)
AMMONIUM SALICYLATE C 6 H 4 (OH)COONH 4 .
100 parts H 2 O dissolve m.i parts C 6 H 4 (OH)COONH 4 at 25; 100
parts alcohol dissolve 43.5 parts at 25 and 100 parts at the b. pt.
(U. S. P.)
AMMONIUM SULPHATE (NH 4 ) 2 SO 4 .
SOLUBILITY IN WATER.
(Mulder.)
^ Grams (NH4) 2 SO 4 per 100 Grams. ft0 Grams (NH 4 ) 2 SO 4 per 100 Grams.
Water. Solution/
78.0 43-8
81.0 44-8
88.0 46.8
95-3 48.8
103.3 5 8
107.5 S 1 - 8
Sp. Gr. of saturated solution at 15 - 1.248; at 19 = 1.241.
t .
Water.
Solution.
i
O
70.6
41.4
30
5
7 1.8
41.8
40
10
73-o
42.2
60
15
74-2
42.6
80
20
75-4
43-o
100
25
76.7
43-4
108.9
AMMONIUM SULPHATE 32
SOLUBILITY OF MIXTURES OF AMMONIUM SULPHATE AND COPPER
SULPHATE AT 16, AND OF AMMONIUM SULPHATE AND
POTASSIUM SULPHATE AT 19.1.
(Rudorff Ber. 6, 482, '73-)
(NH^jsSO, + CuS0 4 . (NH 4 ) 2 S0 4
G. per 100 g. Solution. . , . G.per loog.Solution
Preparation of Solution. ,__--_ Preparation of Solution. __-*__
Both salts in excess 8.55 7.12 Both salts in excess 39.3 37.97
1 5 cc. sat. sol. + 3 gms. 1 5 cc. sat. sol. + 4 g.
(NH 4 ) 2 SO 4 1.77 18.16 K 2 SO 4 4-94 33-26
15 cc. sat. soL + 3 gms. 15 cc. sat. sol. + 4 g.
CuSO 4 .5H 2 O 15-85 5.65 (NH 4 ) 2 SO 4 2.05 40.80
SOLUBILITY OF AMMONIUM SULPHATE IN AQUEOUS ETHYL ALCOHOL
SOLUTIONS.
(Traube and Neuberg Z. physik. Chem. i, 510, '87; Bodlander Ibid. ^, 318, '91; Schreinemaker
Ibid. 23, 657, '97 ; de Bruyn Ibid. 32, 68, 'oo; Linebarger Am. Ch. J. 14, 380, '92.)
Upper Layer Results. Lower Layer Results.
Grams per 100 Gms. Solu- Qms C 2 H,OH Gms - (NH 4 ) 2 SO 4 per 100 g.
tion at io-4o. per 100 Gms. Solution at:
C 2 H 6 OH. '(NH 4 ) 2 S0 4 .
100 0-0
80 o.i
70 0.3
60 1-4
So 3-2
45 4-8
40 6.6
35 9-2
30 12.2
25 14-6
NOTE. When ammonium sulphate is added to aqueous solutions
of alcohol, it is found that for certain concentrations and temperatures
the solutions separate into two liquid layers, the upper of which con-
tains the larger percentage of alcohol.
Most of the determinations which have been made upon this system,
as contained in the papers referred to above, are given in terms of
grams of ammonium sulphate, of alcohol and of water per 100 grams
of these three components taken together. Those results which are
given in other terms can be readily calculated to this basis, and it is
therefore possible to make a comparison of the several sets of de-
terminations by plotting on cross-section paper and drawing curves
through the points. In the present case the grams of alcohol per 100
grams of solution were taken as ordinates, and the grams of ammo-
nium sulphate in the same quantity of each solution taken as abscissae.
It was found that a single curve could be drawn through practi-
cally all the points representing the upper layer solutions at the
several temperatures, but the points for the solutions containing the
larger amounts of water gave curves which diverged with increase of
temperature. The results given for 33 in the above table are not
to be accepted as correct until further work has been done.
Solution.
'6.5.
15.
33.
O
42.0
42 .6
44
2-5
39-o
36.2
40.2
37-2
?
7-5
33-2
34-5
42
IO.O
12.5
15.0
30.0
27.2
24.6
31.0
28.0
25.2
35
17 5
22 .O
22 .4
?
20. o
20. o
20.0
?
33 AMMONIUM SULPHATE
SOLUBILITY OF AMMONIUM SULPHATE IN AQUEOUS PROPYL ALCOHOL
SOLUTIONS AT 20.
(Linebarger Am. Ch. J. 14, 380, '92.)
Gms. per 100 Gms.
Gms. per 100 Gms.
Solution.
Solution .
CjjHrOH. (NH 4 ) 2 S0 4 :
C 3 H 7 OH. (NH 4 ) 2 SCv
70 0-4
40 3.2
60 i.o
30 4-8
50 2.0
20 6.7
AMMONIUM OADIIITTM SULPHATE (NH 4 ) 2 Cd(SO 4 ) 2 6H 2 O.
100 cc. H 2 U dissolve 72.3 grams (NH 4 ) 2 Cd(SO 4 ) 2 at 25.
(Locke Am. Ch. J. 27, 459, 'ot.)
AMMONIUM CHROMIUM SULPHATE (Alum) (NH 4 ) 2 Cr 2 (SO 4 ) 4 .
24 H 2 O.
100 cc. H 2 O dissolve 10.78 grams anhydrous or 21.21 grams hydrated
salt at 25.
(Locke Am. Ch. J. 26, 174, '01.)
AMMONIUM COBALT SULPHATE (NH 4 ) 2 Co(SO 4 ) 2 .6H 2 O.
SOLUBILITY IN WATER.
(Tobler Liebig's
t.
O
10
2O
2 5
30
Annalengs, 193, '55; v. Hauer J. pr.
Ch. J. 27. 459. '01.)
Gms. (NH4) 2 Co(SO 4 ) 2
per TOO Gms. t.
Chem. 74. 433. '58; at 25, Locke Am.
Gms. (NH 4 ) 2 Co(SO 4 ) 2
per 100 Gms.
Water. Solution.
6.0 5.7
9-5 8.7
13.0 11.5
14.72 12.8
17.0 14-5
40
50
60
70
80
Water. Solution.
22. l8.O
27-0 21-3
33-5 25.1
40.0 28.6
49.0 32.9
NOTE. The determinations reported by the above named inves-
tigators were plotted on cross-section paper and although considerable
variations were noted, an average curve which probably represents
very nearly the true conditions was drawn through them, and the above
table made from this curve.
AMMONIUM COPPER SULPHATE (NH 4 ) 2 Cu(SO 4 ) 2 .6H 2 O.
100 grams H 2 O dissolve 26.6 grams salt at 19, Sp. Gr. of sol. = 1.1336
(Schiff Liebig's Ann. 109, 326, '59.)
AMMONIUM IRON SULPHATE (Alum) (NH 4 ) 2 Fe 2 (SO 4 ) 4 .2 4 H 2 O.
100 cc. H 2 O dissolve 44.15 gms. anhydrous or 124.40 gms. hydrated
salt at 25. Sp. Gr. of saturated solution at 15 = 1.203.
(Locke Am. Ch. J. 26, 174, '01.)
AMMONIUM IRON SULPHATE (ferrous) (NH 4 ) 2 Fe(SO 4 ) 2 .6H 2 O.
SOLUBILITY IN WATER.
(Tobler; at 25, Locke Am. Ch. J. 27, 459, '01.)
ft o G. (NH 4 ) 2 Fe(S0 4 ) 2 t o G. (NH 4 ) 2 Fe(SO 4 ) 2 t) C 6 H 5 N 2 .C 6 H 4 .OC 2 H 5 .
SOLUBILITY IN 100 PER CENT ACETIC ACID.
(Dreyer and Rotarski Chem. Centr. 76, II, 1016, '05.)
t= 89.2 91 93 95.6 97.2 99.6
Mols. per liter. 0-153 0.176 0.185 0.209 0.232 0.252
A knick at 94.7 corresponds to the transition temperature of the
a modification into the /3 modification.
BARIUM ACETATE Ba(CH 3 COO) 2 .
SOLUBILITY IN WATER.
(Walker and Fyffe J. Ch. Soc. 83, 179. '03; Krasnicki Monatsh. Chem. 8, 597, '87.)
Gms. Ba(CH 3 COO) 2 Gms. Ba(CH 3 COO) 2
t. per IPO Gms. Solid Phase. t. per TOO Gms. Solid Phase.
Water. Solution. Water. Solution.
0.3 58.8 37.0 Ba(C 2 H 3 2 ) 2 . 3 H 2 40.5 79.0 44.1 Ba(C 2 H 3 O 2 ) 2
7-9 61 6 38.1 41.5 78.7 44.0
17.5 69.2 40.9 44.5 77.9 43.8
21.6 72.8 42.1 51.8 76.5 43.4
24.1 78.1 43.9 " 63.0 74.6 42.7
26.2 76.4 43-3 Ba(C 2 Hp 2 ) 2 .H 2 73.0 73.5 42.4
30.6 75.1 42.9 84.0 74.0 42.5
35-o 75- 8 43-i 99-2 74-8 42-8
39-6 77-9 43-8
Transition temperatures 24.7 and 41'
BARIUM ARSENATE Ba 3 (AsO 4 ) 2 .
100 gms. H 2 O dissolve 0.055 m - Ba 3 (AsO 4 ) 2 ; 100 gms. 5% NH 4 C1
dissolve 0.195 g m -> an d IO gms. 10% NH 4 OH dissolve 0.003 g m -
Ba 3 (AsO 4 ) 2
(Field J. Ch. Soc. u 6, 1859-)
BARIUM BROMATE 44
BARIUM BROMATE BaBrO 3 .H 2 O.
SOLUBILITY IN WATER.
(Trantz and Anschiitz Z. physik. Chem. 56, 238, '06; Rammelsberg Pogg. Ann. 52, 81, '41.)
Gms. Ba(BrO 3 ) 2 Cms. Ba(BrO 3 ) 2 Gms. Ba(BrO 3 )j
t per 100 Gms. t. per 100 Gms. t. per 100 Gms.
Solution. Solution. Solution.
0.034 0.28 30 0-95 70 2.922
o 0.286 40 1.31 80 3.521
-f-io 0-439 5 I -7 2 9 4-26
20 0.652 60 2.271 98.7 5- 2 56
25 0.788 99.65 5.39
BARIUM BROMIDE BaBr 2 . 2 H 2 O.
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 99, 47, '56; Etard Ann. chim. phys.[7]2, 540, '94.)
Gms. BaBrg per I0 Grams. Gms. BaBrg per TOO Grams.
t. 'Water. Solution. t. ' Water. Solution.
(Kremers.) (Kremers.) (Etard.) (Kremers.) (Kremers.) (Etard.)
20 45-6 4o 114 53- 2 5*-5
o 98 49.5 47-5 5o n8 54-1 52-5
10 101 50.2 48.5 60 123 55.1 53.5
20 104 51.0 49.5 70 128 56.1 54.5
25 106 51.4 50.0 80 135 57.4 55-5
30 109 52.1 50-6 100 149 60.0 57-8
140 59.4
Sp. Gr. of saturated solution at 19.5 = 1.710.
The results of Kremers and Etard are both given, since it is uncer-
tain which is the more correct.
SOLUBILITY OF MIXTURES OF BARIUM BROMIDE AND BARIUM IODIDE
IN WATER AT DIFFERENT TEMPERATURES.
(Etard.)
Grams per 100 Gms. Solution. Grams per 100 Gms. Solution.
BaBr 2 . BaI 2 . BaBr 2 . * Bal^.
16 4.8 58.4 170 ii. o 67.4
-f6o 5.5 66.0 210 14.9 67.7
135 9.2 67 .2 Both sahs present in solid phase.
SOLUBILITY OF BARIUM BROMIDE IN METHYL AND ETHYL ALCOHOLS.
(de Bruyn Z. physik. Chem. 10, 783, 92 ; Richards Z. anorg. Chem. 3, 455, '93 ; Rohland Ibid.
15 412, '97.)
Parts BaBr 2 per 100 Parts BaBr 2 .2H 2 O per 100
t o parts Aq. C 2 H 6 OH of: parts of Aq. CH 3 OH of:
100%. 97%- 87%. 100%. 93-5%. 50%.
15.0 .. 0.48 (BaBr 2 .2H 2 O) .. 45.9 27.3 4-O
22.5 3 6 56.1
BARIUM BUTYRATE Ba(C 4 H 7 O 2 ) 2 . 2 H 2 O.
SOLUBILITY IN WATER.
(Deszathy Monatsh. Chem. 14, 249, '93.)
Gms. Ba(C 4 H 7 O 2 ) 2 per 100 Gms. Gms. Ba(C 4 H 7 O 2 ) 2 per TOO Gms.
Water. Solution. Water. Solution.
o 37.42 27.24 50 36.44 26.77
10 36-65 26.82 60 37-68 27.36
20 36.12 26.55 70 39-58 28.36
30 35-85 26.38 80 42-13 29.64
40 35-82 26.37
45
BARIUM CAPROATB
BARIUM CAPROATE AND BARIUM ISO CAPROATE.
SOLUBILITY IN WATER.
(Kulisch Monatsh. Chem. 14, 567, '93.) (Konig Monatsh. Chem. 15, 23, '94.)
Barium Caproate (Methyl 3 Pentan.) Barium Iso Caproate (Methyl 2 Pentan.)
Ba(CH 3 .CH 2 CH(CH 3 )CH 2 COO) 2 . Ba(CH 3 CH(CH 3 )CH 2 .CH 2 COO) 2 .
Gms,Ba(C 6 H u 2 ) 2
t<\ per 100 Gms.
Solid Phase.
Water. Solution.
11.71
10
.49
Ba(C 6 H u 2 ) 2 . 3 iH 2
10
8.38
7
73
44
20
6.89
6
45
"
30
5-87
5
55
"
40
5-79
5
47
"
50
6.63
6
.21
"
60
8-39
7
74
"
70
ii .09
9
.98
"
80
14. 71
12
.82
"
90
19.28
16
.16
"
per 100 Gms.
Solid Phase.
Water.
Solution.
14-34
12.54
Ba(C 6 H u O 2 ) 2 . 4 H 3 O
13-33
11.77
"
12 .67
II .26
"
12.37
II .01
"
12 .42
II .05
"
12.83
11.38
11
I3-63
11.99
"
14-68
12. 80
"
16.24
*3-97
"
17-95
15-23
**
BARIUM CARBONATE BaCO 3 .
SOLUBILITY IN WATER.
(Holleman, Kohlrausch and Rose Z. physik. Chem. 12, 129, 241, '93.)
Electrolytic conductivity method used.
i liter H 2 O dissolves 0.016 g. BaCO 3 at 8.8, 0.022 g. at 18, and
0.024 g. at 24.2.
SOLUBILITY OF BARIUM CARBONATE IN WATER CONTAINING CO 2 .
The average of several determinations at about 10, by Bineau,
Lassaigne, Foucroy and Bergmann'is i.io gms. BaCO 3 per liter water.
Wagner (Z. anal. Ch. 6, 167, '67) gives 7.25 gms. BaCO 3 per liter of
water saturated with CO 2 at 4-6 atmospheres pressure.
BARIUM CHLORATE BaClO 3 .H 2 O.
SOLUBILITY IN WATER.
(Trantz and Anschiitz Z. physik. Chem 56, 238, '06; Kremers Pogg. Ann. 99, 43. '56; Tilden and
Shenstone Trans. Roy. Soc. 34, '84.)
Gms. Ba(C10 3 ) 2
t. ]
aer 100 Gms.
Solution.
- 2-75
15.28
16.90
-f 10
21.23
20
25.26
25
27-53
Gms. Ba(ClO 3 ) 2
t. per TOO Gms.
Solution
30
29 43
40
50
60
33 -16
36.69
40.05
70
80
43-04
45-90
90
99
105
116
146
Gms. Ba(ClO3>a
per zoo Gms.
Solution.
48.70
: 5 1 '- 1 ?
52.62
66.0
78.0
BARIUM CHLORIDE 46
BARIUM CHLORIDE BaCl 2 .2H 2 O.
SOLUBILITY IN WATER.
(Mulder; Engel Ann. chim. phys. [6] 13, 372, '88; Etard Ibid. [7] 2, 535, '94.)
AO Gms. BaCb per 100 Gms.
t *
Gms. BaCl 2
per 100 Gms.
t
Water.
Solution.
Water.
Solution.
o
3 1.6
24.0
60
46.4
31-3
10
33-3
25.0
70
49-4
33-i
20
35-7
26.3
80
52-4
34-4
25
37-o
27.0
100
58.8
37-o
30
38.2
27.7
130
59-5
37-3
40
40-7
28.9
160
63.6
38-9
50
43-6
30-4
2I 5
75-9
43 - 1
Sp. Gr. of solution saturated at o = 1.25; at 20 = 1.27.
SOLUBILITY OF MIXTURES OF BARIUM CHLORIDE AND BARIUM NITRATE
IN WATER.
Both salts present in solid phase.
(Etard.)
Grams per 100^ Gms. Solution. Grams per loo^Gms. Solution.
BaCl 2 . Ba(N0 3 ) 2 . BaCl 2 . * Ba(NO 3 ) 2 .
o 22.5 4.3 ioo 31 14
20 24.5 6.0 140 32 20
40 26.5 7.5 180 33 26
60 28.5 9.5 210 32 32
SOLUBILITY OF MIXTURES OF BARIUM CHLORIDE AND MERCURIC
CHLORIDE IN WATER.
(Foote and Bristol Am. Ch. J. 32, 248, '04.)
Gms. per too Gms. . Gms. per ioo Gms.
t Solution. Solid t0 Solution. Solid
BaCl 2 . ' HgU 2 : BaCl 2 . ' Hgd,.
10.4 23-58 50-54 { Ba SS + 10.4 22.10 51-66
10.4 23.44 50-74 (DoubleSalt IO '4 21.64 5 1-74
I0. 4 22.58 51.23 BaCl 2 .3HgCl 2 . 2 5 2 3 .02 54>83
10.4 22.48 51.41 (
SOLUBILITY OF MIXTURES OF BARIUM CHLORIDE AND POTASSIUM
CHLORIDE IN WATER.
(Foote Am. Ch. J. 32, 253, '04.)
ioo grams saturated solution contain 13.83 grams BaCl 2 + 18.97
grams KC1 at 25.
SOLUBILITY OF MIXTURES OF BARIUM CHLORIDE AND SODIUM
CHLORIDE IN WATER.
(Precht and Wittgen Ber. 14, 1667, '81; Rudorff Ber. 18, 1161, '85.)
Gms. per ioo Gms. H 2 O. Gms. per ioo Gms. Solution.
'BaCl 2 . NaCl. BaCl 2 . NaCf.
20 4-1 33.8 2-9 25.0
40 6.3 33.6 4.5 23.0
60 9.7 33.5 6.8 23.4
80 13.9 33.6 9.4 22.8
IOO 17.9 33.6 II. 8 22.2
47 BARIUM CHLORIDE
SOLUBILITY OF BARIUM CHLORIDE IN AQUEOUS SOLUTIONS OP
HYDROCHLORIC ACID AT o.
(Engel Ann. chim. phys. [6] 13, 371, '88.)
'HCl.
iBaC! 2 .
HCl.
BaCl 2 .
HCl. BaCl 2 .
O
28
-90
O
30
.10
O
24.07
I
.1
27
.80
O
.40
28
95
32
2 3
31
2
.8
26
.07
I
.02
27
15
o
83
22
.11
5
.0
23
40
I
.82
24
36
I
5 1
2O
.14
14
4
14.00
5
.24
14
57
4
58
12
.76
18
.8
IO
-20
6
.84
10
47
6
J 3
9
37
22
7
6
.67
8
99
6
95
h
55
6
33
32
.0
2
74
ii
.66
2
85
IO
.81
2
.64
50-5
.29
18
.41
O
3o
16.92
O
.28
Sp. Gr. of TO cc Sol " Gms - I** ioo cc. Sol. Gms. per ,00 g. Sol.
Solutions.
1.250
1.242
1.228
.2IO
143
.Il8
.099
.079
.088
Less than i part of BaCl 2 is soluble in 20,000 parts of concentrated
HC1 and in 120,000 parts of cone. HC1 containing volume of ether.
(Mar Am. J. Sci.[ 3 ] 43, 521, '92-)
SOLUBILITY OF BARIUM CHLORIDE IN ABSOLUTE METHYL ALCOHOL
AND IN GLYCERINE.
(In Alcohol, de Bruyn Z. physik. Chem. 10, 783, '92.)
ioo parts of CH 3 OH dissolve 2.18 parts BaCl 2 at 15.5, and 7.3 parts
BaCl 2 . 2 H 2 at 6.
ioo parts by weight of glycerine dissolve 10 parts of BaCl 2 at 15.5.
SOLUBILITY OF BARIUM CHLORIDE IN AQUEOUS ETHYL ALCOHOL AT 15.
(Schiff Liebig's Ann. 118, 365, '61; Rohland Z. anorg. Ch. 15, 412, '97.)
Wt. per cent alcohol 10 20 30 40 60 80 97
Gms. BaCl 2 .2H 2 Oper
ioo g. aq. alcohol 31-1 21.9 14.7 10.2 3.5 0.5 0.014
BARIUM CHROMATE BaCrO 4 .
SOLUBILITY IN WATER AND IN SALT SOLUTIONS.
f. Solvent.
( (Kohlrausch & Rose
18 Water 0.0038 { z. physic. Ch. 12, 241,
( '93-)
ord. temp. o . 0062 (ignited BaCrO 4 ) ( (Schweitzer - z. anal.
ord. temp. o.oioo (not ignited) jch. 20, 4 i 4 , '90.)
K n f " 0^/1-7 ( (Mescherzerski Z.
D - P L o .043 j anah ch 2I> 39Q7 , 82 }
Ord. temp. I .5% Am. Acetate 0.020 ( (Fresenius - Z. anal.
ord. temp. 0.5% Am. Nitrate 0.022 jch.ag, 4 i8, 'oo-)
BARIUM CITRATE Ba 3 (C 6 H 5 O 7 ) 2 .7H 2 O.
SOLUBILITY IN WATER AND IN ALCOHOL.
TOO grams water dissolve 0.0406 gram Ba 3 (C G H 5 O 7 ) 2 .7H 2 O at 18,
and 0.0572 gm. at 25.
ioo grams 95% alcohol dissolve 0.0044 gram Ba 3 (C 6 H 5 O 7 ) 2 .7H 2 O at
18, and 0.0058 gm. at 25.
(Partheil and Hiibner Archiv. Pharm. 241, 413, '03.)
BARIUM CYANIDE 48
BARIUM CYANIDE Ba(CN) 2 .
SOLUBILITY IN WATER AND IN ALCOHOL AT 14.
(Joannis Ann. chim. phys. [5] 26, 489, '82.)
ioo parts water dissolve 80 parts Ba(CN) 2 .
100 parts 70% alcohol dissolve 18 parts Ba(CN) 2 .
BARIUM FERROGYANIDE AND BARIUM POTASSIUM FERRO-
CYANIDE.
(Wyrouboff Ann. chim. phys. [4] 16, 292, '69.)
ioo parts water dissolve o.i part Ba 2 Fe(CN) 6 .6H 2 O at 15, and i.o
part at 75.
ioo parts water dissolve 0.33 part BaK 2 Fe(CN) 6 .5H 2 O at ord. temp.
BARIUM FLUORIDE BaF 2 .
(Kohlrausch Z. physik. Chem. 50, 365, 'o4-'o5.)
i liter of water dissolves 1.63 gms. BaF 2 at 18. Electrolytic conduc-
tivity method.
BARIUM FORMATE Ba(HCOO) 2 . 2 H 2 O.
SOLUBILITY IN WATER.
(Krasnicki Monatsh. Chem. 8, 597, '87.)
t o Gms.Ba(HCOO) 2 periooGms. t o Gms. Ba(HCOO) 2 per ioo Gms.
Water. Solution. Water. Solution.
o 27.76 21.72 40 34-8i 25.82
10 28.46 21.15 5 37 I 4 27.10
20 30.11 23.15 60 38.97 28.03
25 31.20 23.80 70 39.95 28.54
30 3 2 -34 24.45 80 39 .71 28.42
BARIUM HYDROXIDE Ba(OH) 2 .
SOLUBILITY IN WATER. SOLID PHASE Ba(OH) 2 .8H 2 O.
(Rosenthiel and Riihlmann Jahresber. Chem. 314, '70.)
t o Gms. Ba(OH} 2 per ioo Gms. t o Gms. Ba(OH) 2 per ioo Gms.
Water. Solution. Water. Solution.
o 1.67 1.65 30 5.59 5.29
5 1.95 1.92 40 8.22 7.60
10 2.48 2.42 50 13-12 ii. 61
15 3.23 3.13 60 20.94 17.32
20 3.89 3.74 75 63.51 38.85
25 4.68 4.47 80 101.40 50.35
SOLUBILITY OF BARIUM HYDROXIDE IN AQUEOUS ACETONE AT 25.
(Herz and Knoch Z. anorg. Chem. 41, 321, '04.)
_ , . Ba(OH) 2 per too cc. Sat. Gms. Ba(OH) 2
Sp. Gr. of Vol.% Solution. per
Solutions. Acetone. , ioo Gms.
Millimols. Grams. Solution.
1.0479 55-8 4-722 4-506
i. 0168 10 31-84 2.730 2.686
0.9927 20 17.79 i-5 2 5 J -536
-97 6 3 3 9- J o o-779 0.798
0.9561 40 4.75 0.407 0.426
0-9398 50 1.54 0.132 0.141
0.9179 60 0.48 0.041 0-045
0.8956 70 0.08 0.007 0.018
49 BARIUM IODATE
BARIUM IODATE Ba(IO 3 ) 2 .H 2 O.
SOLUBILITY IN WATER.
(Trantz and Anschiitz Z. physik. Chem. 56, 238, '06.)
t o Gms Ba(lp 3 ) 2 per t Gms. Ba(IO 3 ) per te Cms. Ba(IO s ) 2 per
100 Gms. Solution, 100 Gms. Solution. 100 Gms. Solution
0-046 O.OOS 30 O-O3I 7O 0-093
+ 10 0.014 40 0.041 80 0.115
2O O-O22 50 0-056 QO O.I4I
25 0.028 60 0-074 ioo 0.197
BARIUM IODIDE BaI 2 .
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 103, 66, 1858; Etard Ann. chim. phys. [7] 2, 544, '94.)
Gms. BaI 2 per ioo Gms. Gms. BaI 2 per ioo Gms.
Water. Solution. Solld Phase ' * Water, 'solution. *** ^^
-20 143-9 59-o BaI 2 .6H 2 O 40 231.9 69.8 BaI 2 .2 H 2 O
o 170.2 63.0 60 247.3 7 1 - 2 "
4-10 185.7 65.0 80 261.0 72.3 "
20 203.1 67.0 ioo 271.7 73.1 "
25 212.5 68.0 120 281.7 73-8 "
30 219.6 68.7 160 294.8 74.6 "
Sp. Gr. of saturated solution at 19. 5 = 2.24.
For method of interpolating above results, see Note, page 33.
ioo grams 97% Ethyl Alcohol dissolve 1.07 g. BaI 2 .2H 2 O at 15.
(Rohland Z. anorg. Chem. 15, 417, 1897.)
BARIUM MALATE BaC 4 H 4 O 6 .
SOLUBILITY IN WATER.
(Cantoni and Basadonna Bull. soc. chim. [3] 35, 731, '06.)
t o Gms.BaQHiOg . Gms.BaC 4 H 4 O 5 - Gms.EaC^O s
per ioo cc. Sol. per ioo cc. Sol. per ioo cc. SoL
20 0.883 35 0.895 60 i. oi i
25 0.901 40 0.8 70 1.041
30 0.903 50 0.942 80 1.044
SOLUBILITY IN WATER AND IN ALCOHOL.
(Rartheil and Hiibner Archiv. Pharm. 241, 413, '03.)
ioo grams water dissolve 1.24 gms. BaC 4 H 4 O 6 at 18, and 1.3631
gms. at 25.
too grams 95% alcohol dissolve 0.0038 gms. BaC 4 H 4 O 6 at 18, and
0.0039 S m - at 25.
BARIUM MALONATE BaC 3 H 2 O 4 .N 2 O.
SOLUBILITY IN WATER.
(Miczynski Monatsh. Chem. 7, 263, '86.)
Gms.BaC3H 2 O 4 per looGms. Gms. BaC3H 2 O 4 per ioo Gms.
Water. Solution. Water. Solution.
o 0.143 0.143 50 0.287 0.285
10 0.179 0.179 60 0.304 0.303
2O O-2I2 O-2II 7O 0.317 0.316
30 0.241 0.240 80 0.326 0-325
40 o - 266 o . 265
BARIUM MOJ.YBDATE BaMoO 4 .
ioo parts water dissolve 0.0058 part BaMoO 4 at 23.
(Smith and Bradbury Ber. 24* 2930, '91. ^
BARIUM NITRATE 50
BARIUM NITRATE Ba(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Mulder; Gay Lussac; Etard Ann. chim. phys. [7] 2, 528, 94; Euler Z. physik. Chem
Gms. Ba(NO 3 ) 2
jo per 100 Gms. t.
Gms. Ba(N0 3 ) 2
per loo Gms.
Water.
Solution.
'Water.
Solution.
O
5-o
4 .8
80
27.0
21.3
10
7-o
6-5
100
34-2
25-5
20
9.2
8.4
120
42.0
29.6
25
10.4
9-4
I4O
5O-O
33-3
30
ii. 6
10.6
160
58.0
36-7
40
14.2
12.4
180
67.0
40.1
5
17.1
14.6
200
76.0
43-2
60
20.3
16.9
215
84-5
45-8
Sp. Gr. of saturated solution at 19.5 = 1.072.
SOLUBILITY OF MIXTURES OF BARIUM NITRATE AND LEAD NITRATE
IN WATER AT 25.
(Fock. Z. Kryst. Min. 28, 365, '97; at 17, Euler Z. phyisk. Chem. 49, 315, '04.)
J.I1 OOIUUOU.
In Solid Phase.
3. Gr. of
>olution.
Gms.
per Liter.
Mg. Mols.
per Liter.
Mol. %
Mol.%
Ba(NfV)o
Ba(N0 3 ) 2 .
Pb(N0 3 ) 2 .
Ba(N0 3 ) 2 .
Pb(N0 3 ) 2
Ba(N0 3 ) 2 .
r>
of Acetic
Acid.
per 50 cc.
Sol.
CHsCOOH.
Ba Oxalate
O
O
.0077
o.oo
0.0154
3-
85
O
.0564
23'
12
O.II27
o-5 6 5
0423
3-39
o . 0845
5-
79
.O5II
34
76
0-I02I
1.425
o
.0520
8-55
o . 1039
i7-
3o
O
.0048
103
.90
0-0096
2.85
0556
17.11
O-IIII
* Dried at 70.
BARIUM ACID OXALATE 52
BARIUM ACID OXALATE BaC 2 O 4 .H 2 C 2 O 4 . 2 H 2 O.
SOLUBILITY IN WATER.
(Groschuff.)
A0 Gms. per 100 Gms. Solution.
Mols. per 100 Mols. H 2 O.
Mols. H 2 C
V *
H 2 C 2 4 .
BaC 2 O 4 .
H 2 C 2 4 .
BaC 2 O 4 . Per i MoLBa
0.27
0.030
0.054
0.0024
22
18
0.66
O.O7O
0.130
0.0056
24
20.5
0.76
0.076
0.15
0.0061
25
38
1.61
0.16
o-33
0.013
25
4i
1.82
0.18
0.37
0.015
25
S3
2.92
0.31
0.60
O.O26
24
60
3.60
0.40
o-75
0.033
22-5
80
6.21
0.81
i-34
0.070
J 9
90
7.96
i .11
i-7S
0-098
18
99
10.50
i-55
2-39
O.I4I
J 7
BARIUM PROPIONATE Ba(C 3 H 5 O 2 ) 2 .H 2 O. also 6H 2 O.
SOLUBILITY IN WATER.
(Krasnicki Monatsh. Chem. 8, 597, '87.)
t.
Gms.]
per
ioo Gms.
Water.
Solution.
o
47-98
32.41
10
51 .56
34-02
20
54-82
35-42
30
57-77
36-65
40
60.41
37.66
Gms. Ba(C 3 H 3 O 2 ) 2
t. per lop Gms.
50
60
70
80
Water.
62.74
64.76
66.46
67.85
Solution.
38.57
39 -3 1
39-93
40.42
BARIUM SULPHATE BaSO 4 .
SOLUBILITY IN WATER.
Electrolytic Conductivity Method.
(Holleman; Kohlrausch and Rose Z. physik. Chem. 12, 131, 241, '93.)
t
io v
26
34 C
37-7'
Gm. BaSO 4 per liter 0.0017 0.0020 0.0023 0.0026 0.0029 0.0031
SOLUBILITY OF BARIUM SULPHATE IN AQUEOUS SOLUTIONS OF HYDRO-
CHLORIC AND OF NITRIC ACIDS.
(Banthisch J. pr. Chem. 29, 54, 1884.)
In Hydrochloric Acid. In Nitric Acid.
, * x , * N
cc. containing Mgs. BaSO 4 Gms per 100 cc. C c. containing Mgs. BaSO 4 Gms. per 100 cc.
i Mg.Equiv. per i Mg. Equiv. Solution. i Mg.Equiv. per i Mg.Equiv. Solution.
ofHCl. ofHCl. gel BaS0 4 : of HNO 3 . of HNO 3 . HNO 3 . BaSO 4 .
2.0 0.133 1.82 0.0067 2.0 0.140 3- I 5 0.0070
i.o 0.089 3-65 0.0089 i.o 0.107 6.31 0.0107
0.5 0.056 7-29 o.oioi 0.5 0.085 12. 61 0.0170
0.2 0.017 18.23 0.0086 0.2 0.048 3I-52 0.0241
TOO cc. HBr dissolve 0.04 gms. BaSO 4 ; 100 cc. HI dissolve 0.0016
gms. BaSO 4 at the boiling point.
(Haslam Chem. News 53, 87, '86.)
53 BARIUM SULPHATE
SOLUBILITY OF BARIUM SULPHATE IN AQUEOUS SOLUTIONS OF IRON,
ALUMINUM AND MAGNESIUM CHLORIDES AT 20 25.
(Fraps. Am. Ch. J. 27, 290, '01.)
Gms. Milligrams BaSO4 per Liter in: Gms. Mgs. BaSO4 per Liter in:
Chloride , * s Chloride
per Liter. Aq. FeCl 8 . Aq. A1C1 3 . Aq. MgCl 2 . per Liter. Aq. FeCl 3 . Aq. A1C1 3 . Aq.MgCl 2 .
i 5 8 33 30 25 150 116 50
2\ 72 43 30 50 160 170 50
5 IJ 5 6o 33 ioo 170 175 50
10 123 94 33
BARIUM PerSULPHATE BaS 2 O 8 . 4 H 2 O.
100 parts water dissolve 39.1 parts BaS 2 O 8 or 52.2 parts BaS 2 O 8 .
4H 2 O at o.
(Marshall J. Ch. Soc. 59, 771, '91.
BARIUM SULPHITE BaSO 3 .
SOLUBILITY IN WATER AND IN AQUEOUS SUGAR SOLUTIONS.
(Rogowicz Z. Ver Zuckerind. 938, 1905.)
Cone, of
Gm. BaSU,
i per 100 cc. bol.
Cone, of
Gm. BaSO 4 per
100 cc. Sol.
Sugar Sol.
at 20.
at 80.
Sugar Sol.
at 20.
at 80.
oBx
0.0197
0.00177
40 Bx
o . 0048
0.00158
10 "
O-OIO4
0-00335
50 "
0.0030
O.OOI49
20 "
0.0097
0-00289
60 " (sat.)
0.0022
O-OOII2
30 "
O.OO78
o .00223
BARIUM SUCCINATE AND BARIUM ISO SUCCINATE
Ba.CH 2 CH 2 (COO) 2 . Ba.CH 3 CH 2 (COO) 2 .
SOLUBILITY OF EACH IN WATER.
(Miczynski Monatsh. Chem. 7, 263, 1886.)
Gms. Ba. Succinate Gms. Ba. Iso Succinate
t. per 100 Gms. per 100 Gms.
Water. Solution. Water. Solution.
o 0.421 0.420 1.884 1-849
10 0.432 0.430 2.852 2.774
20 0.418 0.417 3-6i8 3-493
30 0.393 0.392 4.181 4.014
40 0.366 0.365 4-542 4-346
50 0.337 0.336 4.700 4-594
60 0.306 0.305 4-656 4-450
70 0.273 0.272 4.410 4.224
80 0.237 0.237 3-9 62 3- 8l
100 gms. H 2 O dissolve 0.396 gms. Ba Succinate at 18 and 0.410
gms. at 25.
100 gms. 95% alcohol dissolve 0.0015 gms. Ba Succinate at 18 and
0.00 1 6 gms. at 25. (Partheil and Hiibner Archiv. Pharm. 241, 413. '03-)
BARIUM TARTRATE Ba(C 2 H 2 O 3 ) 2 .
SOLUBILITY IN WATER.
(Cantoai and Zachoder Bull. soc. chim. [3] 33, 751, '05; see also Partheil and Hiibner.)
Gms. Ba(C 2 H 2 O 3 ) 2
t. per 100 cc. t.
Gms. Ba(C 2 H 2 O 3 ) 2
per 100 cc.
t\
Gms. Ba(C 2 H 2
per 100 cc.
Solution.
Solution.
Solution.
O.O2O5
30
0.0315
70
o . 0480
10
0.0242
40
0.0352
80
0.0527
2O
O.O279
50
0-0389
9
0.0541
25
0.0297
60
0.0440
BARIUM TARTRATE 54
SOLUBILITY OF BARIUM TARTRATE IN AQUEOUS ACETIC ACID
SOLUTIONS at 26-27.
(Herz and Muhs Ber. 36, 3715, '03.)
Normality Gms. residue* G ms. per loocc. Solution. Normality. Cms. residue* Gms. per icocc. Solution
f Acfd tiC ^Vol." CHaCOOH.'Ba tartrate; ^ IC ^f. CC ' CH 3 COOH: Ba tartrate'.
o 0.0328 o.o 0.0655 3-77 0.1866 22.62 0.3728
0.565 0.1151 3.39 0.2300 5.65 0.1865 33.90 0.3726
1.425 0.1559 8.55 0.3115 16.85 0.0218 101.10 0.0436
2.85 0.1739 17.11 0.3475
* Dried at 70.
ioo grams 95% alcohol dissolve 0.032 gm. Ba tartrate at 18 and
0-035 6 S m - at 2 5- (Partheil and Hiibner.)
BENZALDEHYDE C 6 H 5 COH.
ioo gms. H 2 O dissolve 0.3 gm. benzaldehyde at room temperature.
(Fluckiger Arch. Pharm. [3] 7, 103, '75.)
BENZAMIDE C 6 H 6 CONH 2 .
SOLUBILITY IN ETHYL ALCOHOL.
(Speyers Am. J. Sci. [4] 14, 295, '02.)
G.M. Gms.
t o Sp. Gr. of C 6 H 6 CONH 2 C 6 H 8 CONH 2 t o
' Solutions, per ioo G.M. per ioo Gms.
CjjHsOH. C 2 HsOH.
Sp. Gr. of
Solutions.
G.M.
C 6 H 6 CONH 2
per ioo G.M.
C 2 H 6 OH.
Gms.
C 6 H S CONH 2
per ioo Gms.
CgHsOH.
O
3.833
3
,i
8
J 5
40
0.848
II .
O
28
.92
10
0.832
4
2
ii
.04
5o
0.862
14.
2
37
34
2O
0.833
D
9
I 5
52
60
0.881
17
2
45
.22
25
0.835
6
.8
*7
.87
70
0.913
20.
4
63
30
0.838
8
.2
21
56
. .
.
. .
SOLUBILITY OF BENZAMIDE IN MIXTURES OP ALCOHOL AND WATER
AT 25
(Holleman and Antusch Rec. trav. chim. 13, 294, '94.)
Vol.
A
Gms.
Gms.
C B H 6 CONH 2
per ioo Gms.
Sp. Gr. of
Solutions.
Vol.%
Alcohol.
QjHeCONHa
per ioo Gms.
Sp. Gr. of
Solutions.
Solvent.
Solvent.
17.03
0.830
70
23.87
0.925
21 .12
0.856
60
18.98
0-939
24.50
0.878
5
13-74
0-949
26.15
0-895
40
8.62
0.958
26.63
O.9OO
31
5-33
0.967
26.43
0.907
15
2.28
0.912
25.41
0.917
O
J-35
0.999
IOO
95
90
85
83
80
75
BENZENE C 6 H 6 .
SOLUBILITY IN WATER AT 22.
(Herz Ber. 31, 2671, '98.)
ioo cc. water dissolve 0.082 cc. C 6 H 6 , Vol. of Sol. = 100.082,
Sp. Gr. = 0.9979.
ioo cc. C 6 H 6 dissolve 0.211 cc. H 2 O, Vol. of sol. = 100.135,
Sp. Gr. = 0.8768.
55
BENZENE
BENZENE, ACETIC ACID, WATER MIXTURES.
(Lincoln J. Physic. Chem. 8, 2<;i, '04.)
NOTE. To mixtures of known amounts of acetic acid and benzene,
water was gradually added until clouding occurred. The same degree
of clouding did not represent the end point in all cases, as was assumed
by Waddel. (J. Physic. Chem. 4, 161, 'oo.)
At 25.
cc.
cc.
cc.
:oo
H. C 6 H C .
H 2 O.
5
10- 06
o-45
5
8.04
o-55
5
6.03
0.64
5
3.02
0.98
5
2 -OI
1.28
5
I .01
1.89
5
O.6o
2.80
5
o-35
4-54
5
0.17
9-53
At 35.
cc.
cc.
cc.
CH 3 COOH.
C 6 H.
H 2 0.
IOO
iS.IO
I.I4
IOO
16.09
I .22
IOO
10. 06
I .55
IOO
6.03
2.17
IOO
4-02
2-77
IOO
3-oi
3.26
IOO
I .00
7.01
IOO
0.65
10.10
IOO
0.47
13.64
BENZENE, AQ. ALCOHOL MIXTURES; BENZENE, AQ. ACETONE MIX-
TURES AT 20.
H 2 O added to mixtures of known amounts of the other two and
appearance of clouding noted.
(Bancroft Phys. Rev. 3, 31, 1895. g6.)
C 6 H 6 ,C 2 H 5 OH and H 2 O C 6 H 6 ,CH 3 OH and H 2 O C 6 H 5 ,(CH 3 ) 2 CO and H 2 O
Per 5 cc. C 2 H 5 OH. Per 5 cc. CH 3 OH. Per 5 cc. (CH 3 ) 2 CO.
cc. H 2 0.
cc. C 6 H fi .
cc. H 2 O.
cc. C 6 H 6 .
cc. H 2 O.
cc. C 6 H ."
2O
0.03
5-o
O.I5
8.0
O-IO
8
o J 3
3-o
O.2I5
3-o
o-395
4
o-39
2 .0
o-59
2 .O
0.69
2
1.17
1.4
I -0
i-3
I .0
I -S
1.87
I .0
1.9
0.51
2 -O
I .0
3-57
0.8
3-o
0.295
3-o
0.605
8.0
0.69
4-0
0.2
4-0
o-34
20. o
0.49
8.0
o . 15
5-o
MUTUAL SOLUBILITY OF BENZENE AND NAPHTHALENE PICRATE
C 6 H 2 (NO 2 ) 3 OH.C 10 H 7 OH.
" Synthetic Method " used see Note, p. 9.
(Kuriloff Z. physik. Chem. 24, 442, '97.)
t .
in .6
102.0
29-5
4-6
5-02
a = Mols. /3 Naphthalene Picrate per 100 Mols. of /3 Napthalene
Picrate plus Benzene.
Determinations for a large number of isothermes are also given.
t.
Cms.
Picrate.
Cms.
Benzene
a
157
100.0
IOO.O
148.4
2.128
O.II5
79-3
J 37-4
1.274
0.170
61.1
134.2
1.384
0.297
49-3
126.8
I .019
0-343
38.3
Gms.
Picrate.
Gms.
Benzene.
a
I-I73
1.087
1.037
1.780
19.2
II .2
0.390
1.329
8.430
21. 80
o-95
0.48
IOO-O
BENZENE 56
SOLUBILITY OF BENZENE IN SULPHUR.
By " Synthetic Method, " see Note, p. 9.
(Alexejew Ann. Physik. Chem. 28, 305, '86.)
t o Gms. C 6 H 6 per 100 Gms. t o Gms. C 6 H 6 ^per 100 Gms.
S Layer. C 6 H 6 Layer! S Layer. CH 6 Layer."
ioo 6 75 140 16 61
no 8 72.5 150 19 55
120 10 70 160 25 45
130 12 66 164 (crit. temp.) 35
Di Brom BENZENE (p) C 6 H 4 Br 2 .
SOLUBILITY IN ETHYL, PROPYL, Iso BUTYL ALCOHOLS, ETC.
(Schroder Z. physik. Chem. n, 456, '93.)
Determinations by " Synthetic Method" see Note, p. 9.
Grams C 6 H 4 Br 2 (p) per ioo Grams Sat. Solution in:
t .
C 2 H 6 OH.
CgHyOH.
(CH 3 )CH.CH 2 OH.
(C 2 H 6 ) 2 0.
CS 2 .
C 6 H 6 .
C 6 HsBr.
27
10
30
34
34
22
20
. . .
38
43
43
2 9
30
14
. .
15
47
53
53
36
40
19
20
57
62
62
45
50
26
2,7
30
67
72
7i
54
60
38
40
44
77
81
80
67
70
57-6
67
65
87
90
88
79
75
80.5
85
77
84
80
94-4
95
94.6
90
Chlor BENZENE C 6 H 5 C1.
SOLUBILITY OF CHLOR BENZENE IN SULPHUR.
" Synthetic Method, " see page 9.
(Alexejew.)
Grams C fi HsCl^per ioo Grams.
t. Sulphur Chlor Beii-
Layer. zene Layer.
90 13 70
ioo 18.5 63
no 27 53
116 (crit. temp.) 38
For the solubility of Mixtures of di Chlor Benzene and di Brom
Benzene in aqueous Ethyl Alcohol solutions see Thiel.
(Z. physik. Chem. 43, 656, 1003.)
Di Nitro BENZENE (m) C 6 H 4 (NO 2 ) 2 .
SOLUBILITY IN BENZENE, BROM BENZENE AND IN CHLOROFORM.
" Synthetic Method."
(Schroder.)
Gms. C 6 H 4 (NO 2 ) 2 per ioo Gms. C 6 H 4 (NO2) 2 per
t<\ Gms. Sol, in: t. ioo Gms. Sol, in:
C 6 H 6 . C 6 H 5 Br. CHCla. C 6 H 6 . C 6 H 5 Br. CHC1 3 .
15 17.5 ... 22.2 40 52.O 38.0 42.O
20 26.0 18.5 25.0 50 62.5 47.5 52.5
2 5 33-o 2 3-7 2 9-o 60 71.0 57.0 65.0
30 40.0 28.7 33.0 ...........
57
BENZENES
Solubilities of Di-Nitro BENZENES and of Tri-Nitro BENZENES in
Several Solvents.
(de Bruyn Rec. trav. chim. 13, 116, 150, '94.)
Grams per too Grams Solvent.
Solvent.
Methyl Alcohol
Ethyl Alcohol
20
20.
5
5
3-3
1.9
(N 675'
3-5
(/OC 6 H 4 .
(N0 2 ) 2 .
o. 69
0.4
(s)C H
4-9 (i 6) 16.2 (15.5)
1.9 (16) 5- 45 (15.5)
Propyl Alcohol
20.5
i
.09
2
.4
o
298
Carbon Bi-Sulphide
17-
6
.236
I
35
I 4 8
o
2 5
Chloroform
17-
6
27
. I
3 2
4
I.
82
6
i
Benzene
18.
2
5
.66
39
45
2.
56
6
2 (16)
Ether
17-
5
.
i
-5
t
Ethyl Acetate
18.
2
12
.96
36
.27
3-
56
t
Toluene
16.
2
3
.62
3
.66
2.
36
t
Carbon Tetra Chloride
16.
2
143
i
.18
0.
12
. . .
f
Water
(ord.)
.014
0.0525
0.
008
.
Symmetrical Tri-Nitro BENZENE.
SOLUBILITY IN AQUEOUS ALCOHOL AT 25.
(Holleman and Antusch Rec. trav. chim. 13, 296, '94.)
Vol.%
Alcohol.
r. C 6 H 3 (N0 3 ) 3 (*)
per 100 g.
Solvent.
Sp. Gr. of
Solutions. .
Vol. %
Alcohol.
G. C 6 H 3 (N0 3 ) 3 (*)
per loo g.
Solvent.
Sp. Gr. of
Solutions.
100
2-34
0-7957
80
o-57
0.8582
95
1-57
0.8131
75
0.47
0-8708
90
I .12
0.8288
7o
0.37
0.88o8
85
o-79
0.8436
60
0.23
0.9064
BENZOYL PHENYL HYDRAZINE C 6 H 6 .NH.NH.C 7 H 6 O.
SOLUBILITY IN AQUEOUS ALCOHOL.
(Holleman and Antusch Rec. trav. chim. 13, 291, '94.)
Vol.%
Alcohol
Gms. Hydrazine
per loo g.
Solvent.
Sp. Gr.
Solutions.
100
2-39
0-793
95
2-43
0.814
93
3.00
0.822
90
2.26
0.831
Vol. %
Alcohol.
Gms. Hydrazine
per 100 g.
Solvent.
Sp. Gr.
Solutions.
80
70
i 59
i. 08
0.859
0-884
55
40
0.51
0.16
0.917
0.946
BENZO SULPHONIC ACIDS.
SOLUBILITY IN WATER.
(Bahlman Liebig's Ann. 186, 309, '77.)
Name of Acid.
0-Amido benzo sulphonic acid.
Amido brom benzo sulphonic acid.
Mono brom amido benzo sulphonic acid.
Barium di-brom benzo sulphonic acid.
Barium nitro brom benzo sulphonic acid
(hydra ted).
Barium nitro brom benzo sulphonic acid
(anhydrous).
* At 18 = i .201.
Gms. Sulphonic Add per 100 Gms.
Solution at:
11 = 1.301
8 = 0.737
12 = 0.431
14 = 1.713
15= 1-436
16 = 1.131*
15 = 0.463
9 = i ,098
16 = 0.527 30 = 0.914
8 = 0.156
BENZINE 58
BENZINE (Petroleum) C 5 H 12 C 6 H 14 .
ioo parts of alcohol dissolve about 16 parts benzine of 0.638
0.660 Sp. Gr., at 25.
BENZOIO ACID C 6 H 6 COOH.
SOLUBILITY IN WATER.
(Bourgoin Ann. chim. phys. [5] 15, 171, '78.)
Grams. C 6 H 6 COOH Grams. C fl H 8 COOH
^o^ per ioo Gms. t. per ioo Gms.
Water. Solution. Water. Solution.
o 0.170 0.170 40 0.555 0.551
10 0.210 0.209 50 0-775 0.768
20 0.290 0.289 60 I - I 55 1.142
25 0.345 0.343 80 2.715 2.643
30 0.410 0.408 ioo 5.875 5.549
ioo grams saturated aqueous solution contains 0.340 gram
C 6 H 5 COOH at 25; 0.353 gram at 26.4; 0.667 gram at 45-
(Paul Z. physik. Ch. 14, in, '94; Noyes and Chapin Ibid. 27, 443. '98
Ibid. 51, 393, '05; Philip J. Ch. Soc. 87, 992, '05 ; see also Alexeje\v
305, '86; Ost J.pr. Ch.[ 2 ] 17, 232, '78; Vaubel Ibid. la]
SOLUBILITY OF MIXTURES OF LIQUID BENZOIC ACID AND WATER.
(Alexejew.)
Determinations by" Synthetic Method," see Note, p. 9. Figures
read from curve.
Gms. CfiH 5 COOH per ioo Gms. Gms. C 6 H 5 COOH per ioo Gms.
Aq. Layer. Benzoic Ac. Layer. Aq. Layer. Benzoic Ac. Layer.
70 6 83 ioo 12.0 69.0
80 7.5 79.5 no 18.0 59.0
90 8.5 76 116 (crit. temp.) 35
SOLUBILITY OF BENZOIC ACID IN AQUEOUS SOLUTIONS OF:
(Hoffman and Langbeck.)
Potassium Chloride at 25. Potassium Nitrate at 25.
es and Chapin Ibid. 27, 443, '98; Hoffman and Langbeck
see also Alexejew Ann. Phys. Ch. 28,
52, 73, '95.)
Nor-
mality
Gms.
KC1.
Dissolved QHsCOOH. ^JJ" ^gg;
Dissolved C 6 H 5 COOH.
of Aq.
KC1.
Liter.
Mol . Cone . Wt . per cent . -j^J
Liter.
Mol. Cone. Wt. per cent.
O.O2
1.49
5
0254-10-*
0.
339
0.02
2
.02
5
.0326-IO~~ 4
0.340
0.05
3-73
4
.9801 "
o.
333
O.O5
5
.06
r
.0421 "
0.341
O.2O
14.92
4
7639 "
o.
322
0.20
20.
24
5
02 97
0.340
0.50
37-3
4.
3632 "
o.
295
0.50
5
59
4
.9400
o-334
1. 00
101 .
19
4
.7646 "
0.322
SOLUBILITY OF BENZOIC ACID IN AQUEOUS SOLUTIONS OF:
(Hoffmann and Langbeck.)
Nor-
mality
nf An
Sodium Chloride.
Gms. Gms. CfiH 5 COOH
NaCl per ioo Gms. Sol.
Sodium Nitrate.
^r T ~ J^ Gms - C 6 H 5 COOH
mahty NaNO 3 pe r I00 Gms . g^
OI AC].
NaCl.
JT
Cl
at
2S-
at 45-
oi AQ.
NaN0 3 .
JJC1
Liter.
at 25.'
at 45-
o.oo
o
OO
O
340
O
.667
.02
1.70
0-340
0.666
O-O2
I
.17
O
339
.663
O
05
8. 5 I
o-339
0.663
O.O5
2
93
335
654
O
2O
17 .02
0-333
0.647
O-2O
II
.70
o
336
.617
O
50
42-54
0.319
0.613
0.50
2 9
2 5
o
.282
546
I
.00
85.09
0.294
1. 00
58
50
o
449
59
BENZOIC AOID
SOLUBILITY OF BENZOIC ACID IN AQUEOUS SOLUTIONS OF SODIUM
ACETATE, FORMATE, BUTYRATE, AND SALICYLATE.
(Noyes and Chapin Z. physik. Chem. 27, 443, '98; Philip J. Ch. Soc. 87, 992, '05.)
Grams
Gram;
3 CeH 5 COOH
per Liter of S<
>lution in:
Sodium
Salt per
CHgCOONa.
HCOONa.
CaHyCOONa. Qj^OH.COONa.
Liter.
At 25.
At 26. 4 6 .
At 25.
At 26.4.
At 26.4.
At 26.4.
O
3-4i
3-53
3-41
3-53
3-53
3-53
I
4-65
4-75
4-25
4-35
4-50
3-62
2
5-7o
5-85
4-75
4-85
5-40
3 7o
3
6.70
6.90
5-20
5-30
6.15
3 80
4
7.60
7-85
5-6o
5-70
6.90
3-87
6
8.40
4.00
8
. . .
. . .
. . .
. . .
. . .
4.10
Sodium Salt
CH 3 COONa.
HCOONa.
C 3 H 7 COONa. CeH^OH.COONa
per Liter.
At 25.
At 26.4.
At 25.
At 26.4'.
At 26.4. At 26.4.
O
.00
O
.0279
O
.0289
0.0279
0.0289
O
.0289
0.0289
O
.01
O
.0362
.0370
0.0330
0-0336
0.0376
0-0300
O
.02
O
.0440
.0448
0.0364
0.0372
O
455
0.0312
03
O
.0508
.0518
0.0392
0.0398
o
0525
0.0321
O
.04
O
.0572
.0586
O.O4l6
0-0423
.0596
0.0328
O
.06
o . 0460
o . 0466
0.0342
SOLUBILITY OF BENZOIC ACID IN ABSOLUTE ALCOHOLS.
(Tiirofeiew Compt. rend. 112, 1137, '91; at 15, Bourgoin Ann. chim. phys., [5] 13, 406, '78.)
In Ethyl Alcohol.
In Methyl Alcohol.
G. C 6 H 5 COOH
per loo Gms.
G. C 6 H 5 COOH
per 100 Gms.
In Propyl Alcohol.
G. CeHeCOOH
per 100 Gms.
3
15
21
CH 3 OH.
50.l6
Solution.
33-39
69.29 40.93
C 2 H 5 OH.
4O.l6
46.70
54-09
Solution.
28.65
31.80
35 ^o
C 3 Jti 7 OH.
29.88
Solution.
23.00
40 .64 28 . 90
SOLUBILITY OF BENZOIC ACID IN 90% ALCOHOL, IN ETHER AND IN
CHLOROFORM.
(Bourgoin.)
Solvent.
Gms. C 6 H 5 COOH per TOO Grams.
90% Alcohol
Ether
Chloroform
15
15
25
Solvent.
41 .62
3 r -35
14.30
Solution.
29-39
23.86
12 .50
SOLUBILITY OF BENZOIC ACID IN AQUEOUS SOLUTIONS OF DEXTROSE.
Normality of
Aq. Dextrose.
Gms. CeHi2(
per Liter.
0.02
3-67
O.O5
O.2O4
0-533
1. 068
9-OO
36.73
96.15
192.30
(Hoffman and Langbeck.)
Dissolved CeHsCOOH at 25.
Mol. Cone.
Weight
Per Cent.
5-0322.IO" 4
o-34
5-0403 "
o-34
5-0303 "
o-34
5-032I '
o-34
5-0443 "
0-341
Dissolved CeHsCOOH at 4<.
Mol. Cone.
Weight "
Per Cent.
9. 9088. io~ 4
0.674
9.9328 "
0.669
9.9323 "
0.669
IO-OIOI *'
0-674
10-0,369 "
0.676
BENZOIO AOID 60
SOLUBILITY OP BENZOIC ACID IN AQUEOUS SOLUTIONS OF UREA AND
OF THIO UREA.
(Hoffman and Langbeck.)
Normality Cms. CaHsCOOH Dissolved at 25.
of Solution. per Liter. M ol. Cone. Wt. per cent.
In Aqueous Urea o.io 6.01 CO(NH 2 ) 2 5-i876.io~ 4 0.350
In Aqueous Thio Urea 0.20 15.23 CS(NH 2 ) 2 5-4994 " 0.372
Amido BENZOIO ACIDS C 6 H 4 .NH 2 .COOH (m).
SOLUBILITY IN WATER AND IN OTHER SOLVENTS.
(de Coninck Compt. rend. 116, 758, "93.)
In Water. In Organic Solvents.
Gms. Gms.
t. CflH4.NH 2 .COOH(m) Solvent. t. CeH4.NH 2 .COOH(m)
per 100 cc. H 2 O. per 100 cc. Solvent.
o 0.43 Ethyl Alcohol (95%) 12.5 2.92
10 0.52 Methyl Alcohol (pure) 10.5 4.05
20 0.67 Acetone 11.3 6.22
30 0.87 Methyl Iodide 10.0 0.04
40 1.15 Ethyl Iodide o.o 0.02
50 1.50 Chloroform 12.0 0.07
60 2.15 Bromoform 8.0 trace
7o 3-iS
SOLUBILITY OF THE THREE ISOMERIC AMIDO NITRO BENZOIC ACIDS.
In Ether. In Ethyl Alcohol (90%).
Gms. C6H 3 .NO 3 .NH 2 .COOH Gms. QjH3NO 3 .NH 2 .COOH
. o per 100 cc. Ether. f per 100 cc. Alcohol.
Ortho. Meta. Para. Ortho. Meta. Para.
2.7 10.84 1.70 6.41 3 8.13 1.79 8.4
5.8 16.05 (6.8) 1.81 8.21 9.6 10.70 2.20 11.3
SOLUBILITY IN WATER OF THE THREE ISOMERIC:
(Vaubel J. pr. Chem. [2] 52, 72, '95-)
Amido Benzo Sulphonic Acids. Amido Phenols.
G. C8H4.NH 2 .SO 2 H per 100 g. Aq. Sol. o G. C6H 4 (OH).NH 2 per 100 g. Aq. Sol.
Ortho. Meta. Para. Ortho. Meta. Para.
7 i. 06 1.276 0.592 (6) o 1.7 2.6(20) i.i
Brom, Chlor, and lodo BENZOIG ACIDS.
SOLUBILITY IN WATER AT 25.
(Paul Z. hysik. Chem. 14, in, '94; Lowenherz Ibid. 25, 401, '98; Vaubel.)
Per 1000 cc. Aqueous Solution.
Compound. Formula. / *
Grams. Gram Mol.
Brom benzoic acid. C e H 4 Br.COOH (ortho). 1-856 0.00924
Brom benzoic acid. C c H 4 Br.COOH (meta). 0.402 0-00200
Brom benzoic acid. C 6 H 4 Br.COOH (para). 0.056 0-00028
Chlor benzoic acid. C 6 H 4 C1.COOH (ortho). 2.087 0.01333
lodo benzoic acid. C fl H 4 I.COOH (ortho). 0.95
lodo benzoic acid. C e H 4 I.COOH (meta). 0.12
6i
BENZOIO ACIDS
SOLUBILITY OF ORTHO HYDROXY BENZOIC ACID (SALICYLIC ACID), META
HYDROXY BENZOIC ACID, AND PARA HYDROXY BENZOIC ACID (ANISIC
ACID) IN WATER, BENZENE, ETC. (See also pp. 38 and 274.)
(Walker and Wood J. Ch. Soc. 73, 622, '98; Vaubel J. pr. Chem. [2] 52, 73, '95.)
ioo gms. aq. solution contain 0.225 gm. C 6 H 4 .OH.COOH (o) at
15 (Vaubel).
ioo gms. aq. solution contains 0.794 gm. C 6 H 4 .OH.COOH (p) at
15 (Vaubel).
Gms. C H 4 .OH.COOH
to^ per ioo Gms. H2O.
10
Meta.
o-55
Para.
0.25
20
25
30
35
0.90
i. 08
i-34
i .64
0.50
0.65
0.81
I -01
40
2 .IO
1.24
50
60
3.10
2.12
80
. . .
In Acetone.
G. CeH4.OH.COOH
per loo^cc. Sol.
Meta. Para!
26.O 22-7
Gms. C6H4.OH.COOH
per ioo Gms.CeHa.
Meta.
Para.
O.OOlS
O.OO8
0.0027
0-010
0.0035
0-012
O.OI5
0.017
0.028
o - 0045
o . 0060
0.0082
0.0162
0-047
O.O28
O.O66
In Ether.
G. QH4.OH.COOH
per ioo cc. Sol.
Meta. Para'.
9-73 9-43
Methyl BENZOIO ACIDS C 6 H 4 COOH.CH 3 . o, m, and p.
SOLUBILITY IN WATER.
(Vaubel.)
Gms. CaHiCOOH.CHa per 1000 Gms. Sat. Solution.
Ortho.
1.18
Meta.
0.98
Para.
0-35
Nitro BENZOIO ACIDS C 6 H 4 .NO 2 .COOH. o, m, and p.
SOLUBILITY IN SEVERAL SOLVENTS.
(de Coninck Compt. rend. 118, 471
and Gold
tfor solubility in H 2 O, see also Paul, Vaubel, Lowenherz,
Z. physik. Chem. 25, 95, '96.)
Gms. C 6 H4.NO2.COOH per ioo cc. Solvent.
ouiveui.
v
Ortho.
Meta.
Para.
Water
20
0.682 (0.654G.)
0.3IS
0.039
Water
25
0-743-0-779
0.341
O.O28
Water
30
0.922
. . .
Methyl Alcohol
10
42.72
47-34
9 .6
Ethyl Alcohol
10
28.2
33-i(ii.7 )
0-9
Ethyl "(3 3 Vol.%)
15
0.64(11.8)
0.52
0-055
Acetone
10
41-5
4i-5
4-54
Benzene
10
0.294
o-795
0.017(12.5)
Carbon Bi-Sulphide
10
O-OI2
0-10(8.5)
0.007
Chloroform
10
0.455 C 11 - )
5 -678
0.066
Ethei
10
21.58
25-I75
2 .26
Ligroin
10
trace
0-013
0-00
BENZOIO ACIDS 62
SOLUBILITY OF PARA NITRO BENZOIC ACID IN AQUEOUS SOLUTIONS
OF ANILIN AND OF PARA TOLUIDIN AT 25.
(Lowenherz Z. physik. Chem. 25, 395, '98.)
In Anilin. In ^-Toluidin.
G. Mols. per Liter. Gms. per Liter. G. Mols. per Liter. Gms. per Liter.
'
aHcNHa
C 6 H 4 .N0 2 .
COOH.
C 6 H 5 NH 2
C0 4 OH 2 '
c gg ra - *
C 6 H 4 NH 2 -
CH 3 .
CH 4 N0 2 .
COOH.
O-O
0-00164
0-0
.274
o
.0
.00164
O
.0
0-274
O-OI
0.00841
0.91
I
.406
o
.01
OIOO
I
.071
I .671
O-O2
0.01379
1.82
2
304
.02
.0174
2
.142
2 .902
O.O4
0.02172
3-64
3
.629
o
03
.0245
3
.213
4-097
0.08
0.0347
7.29
5
.798
SOLUBILITY OF ORTHO NITRO BENZOIC ACID IN AQUEOUS SOLU-
TIONS OF SODIUM BUTYRATE, ACETATE, FORMATE, AND
SALICYLATE AT 26.4.
(Philip J. Chem. Soc. 87, 992, '05.)
. Mols. ,.
Original results in terms of per liter.
Gms. Na Salt
Urns. Ur
tno U 8 ii 4 UUUJl..
NU 2 per .Liter o
t solution in:
per Liter.
C 3 H 7 COONa.
CH 3 COONa.
HCOONa.
C 6 H 4 .OH.COONa.
7-85
7-85
7-85
7-85
o-5
8-35
8.50
8.60
8-35
I.O
8.90
9-15
9-50
8.70
2
IO-O
I0.8o
"-5
9-4
3
II .2
12-55
13 .5
II .0
4
12-4
14-5
15-6
JI -5
6
15.2
SOLUBILITY OF ORTHO NITRO BENZOIC ACID IN AQUEOUS SOLUTIONS
OF DEXTROSE, SODIUM CHLORIDE, AND OF SODIUM NITRATE.
Original results in molecular quantities.
(Hoffman and Langbeck Z. physik. Chem. 51, 412, '05.)
In Dextrose. In NaCl. In NaNO 3 .
G. C 6 H 12 Oa
per loo cc.
Solution.
o.o
0.36
1. 80
9-50
2O.OO
G.(o)C 6 H 4
per 100
N0 2 .COOH
g. Solvent.
G. NaCl.
per 100 cc
Solution.
O.II7
0.195
0.585
2.425
5-80
G.(o)C 6 H 4 N0 2 .COO
per 100 g. Solvent.
H G.NaNO 3
per 100 cc.
Solution.
O.I7O
0.284
0-851
4-255
8.510
v
G.(o)C 6 H 4 N0 2 .COOH
per TOO g. Solvent.
At 25.
0.736
0.736
0.732
O.722
0.703
At
I .
I .
I .
I .
I .
35.
063
064
061
051
030
At 25.
o-743
0.746
0.749
0.688
o-597
At 35.
I .072
1-075
I .O7O
0-967
0.831
At 25.
0.746
o-754
0.767
0.774
0.748
At 35 6 -
1.074
I.OSO
I .096
1.097
1.047
BENZOIO SULPHINIDE (Saccharine) C 6 H 4 <^J 2 >NH.
100 parts water dissolve 0.4 part at 25 and 4.17 parts at 100.
100 parts alcohol dissolve 4 parts at 25 (U. S. P.).
BENZOPHENONE
BENZOPHENONE (C 6 H 5 ) 2 CO.
SOLUBILITY IN AQUEOUS ALCOHOL AND IN OTHER SOLVENTS.
(Derrien Compt. rend. 130, 722, 'oo; Bell J. Physic. Chem. 9, 550, '05.)
In Aqueous Alcohol at 40.
(Bell.)
Wt. % Gms. (C 6 H 5 ) 2 CO
Alcohol P 61 " I0 Gms.
>olven
t- Solvent.
Solution.
40
2
I.Q
45
5
4-8
50
8
8-3
55
ii
9.9
60
16
13-8
65
28
22.6
Wt.%
Gms. (C 6 H 5 ) 2 CO
Alcohol
per 100 Gms.
in Solvent.
Solvent. Solution.
67.5
39 28.1
70
5 6 35-9
71
67 39.2
72
90 47.4
72-5
105 51.2
73
156 61.0
In Aqueous Alcohol and other Solvents.
(Derrien.)
Solvent.
97% Ethyl Alcohol 17
85 cc. 97% Alcohol + iscc. H 2 O "
80 " " + 20 "
75" " +26"
Methyl Alcohol (pure) 9.8
15.0
Acetic Ether (pure) 9.6
Carbon B isulphide 1 6 . i
Gms.
(C 6 H 5 ) 2 CO
per 100 g.
Solvent.
Solvent.
13-5
3-8
2 .2
*-3
II .O
14-3
19.2
66.6
Benzene
Xylene
Nitro Benzene
Chloroform (com.)
Bromoform
Toluene
Ligroine
15-8
16.5
!7-3
17.2
14.6
Gms.
(C 6 H 5 ) 2 CO
per
100 g.
Solvent.
76.9
38-4
5 8.8
55-5
33-3
55-5
6.7
BERYLLIUM HYDROXIDE Be(OH) 2 (See also Glucinium, page 140).
SOLUBILITY IN AQUEOUS SOLUTIONS OF SODIUM HYDROXIDE.
(Rubenbauer Z. anorg. Chem. 30 334, '02.)
Moist Be(OH) 2 used, solutions shaken 5 hours, temperature prob-
ably about 20.
Gms. per 100 cc. Solution.
'NaOH. Be(OH) 2 .'
Per 20 cc. Solution.
Molecular
Dilution
Gms. Na.
Gms. Be.
of the
NaOH.
Q-335 8
0.0358
1.37
0-6716
0.0882
0.68
0.8725
0-II75
o-53
I-7346
0-2847
0.27
2.917
5.840
18.310
BERYLLIUM SULPHATE BeSO,.
SOLUBILITY IN WATER.
(Levi, Malvano Z. anorg. Chem. 48, 446, '06.)
0.850
2.094
2.789
6.760
31
50
72
77
30
40
68
85
Mols. H 2 O
per i Mol.
BeS0 4 .
II. 18
9.62
.2 7.79
4 7-!3
13-33
12.49
9.42
7-65
Gms. BeSO 4 per
100 Gms.
Solid
Phase.
BeS0 4 .6H 2 O
BeSO 4 . 4 H 2 O
95-
107.
in
80
91.
119
Mols. H 2 O
per i Mol.
BeS0 4 .
4 6.44
2 5.06
4-55
6.89
4 5-97
4-93
3-9 1
Gms. BeSO 4 per
100 Gms.
Solid
Phase.
BeSO 4 . 4 H O
BeSO 4 .aH,O
Water.
60-67
74-94
81.87
43-78
46.74
61.95
76.30
Solution .
34-3 2
37-77
42.85
45.01
3-45
38.27
43.28
Water.
90.63
II5-3
128.3
8 4 . 7 6
97-77
118.4
149-3
Solution.
47-55
53.58
56.19
45-87
49.42
54-21
59-88
BISMUTH
64
BISMUTH Bi.
MUTUAL SOLUBILITY OF BISMUTH AND ZINC.
(Spring and Romanoff Z. anorg. Chem. 13, 34, '96.)
Upper Layer. Lower Layer.
'%Bi. %Zn." %Bi. %Zn.
266 86 14
419 3 97
475 8 4 16 5 95
Upper Layer. Lower Layer.
%Bi. %Zn. %Bi. %Zn.
584 80 20 10 QO
650 77 23 15 85
750 70 30 27 73
810-820 (crit. temp.)
BISMUTH CHLORIDE BiCl 3 .
100 grains absolute acetone dissolve 17.9 grams BiCl 3 at 18.
(Naumann Ber. 37, 4332, 1004.)
BISMUTH IODIDE BiI 3 .
100 grams absolute alcohol dissolve 3.5 grams BiI 3 at 20.
(Gott and Muir J. Chem. Soc. 57, 138, '90.)
ioo grams methylene iodide CH 2 I 2 dissolve 0.15 gram BiI 3 at 12.
(Retgers Z. anorg. Chem. 3, 343, '93.)
BISMUTH NITRATE Bi(NO 3 ) 3 .sH 2 O.
ioo grams acetone dissolve 48.66 grams Bi(NO 3 ) 3 .5H 2 O at o, and
41.7 grams at 19.
(von Laszczynski Ber. 27, 2285, '94.)
BISMUTH OXIDE Bi 2 O 3 .
SOLUBILITY OF BISMUTH OXIDE IN AQUEOUS NITRIC ACID AT 20.
(Rutten and van Bemmelen Z. anorg. Chem. 30, 386, '02.)
Present in Shaker
Flask.
Gms. per ioo Gms.
Solution.
Mols. per ioo Mols. H 2 O.
Solid
Per i part Bi 2 O 3 .
3N 2 O 5 .ioH 2 O.
Bi 2 3
N 2 5
Bi 2 3
N 2 6 Ra ! i B c J > 2 3
: JN 2 <->5.
Phase.
24.4 parts H 2 O
3 . 2 partsH 2 O
0.321
0.963
7.17
o 126
2.844
I
.61
.82
i
12
4
.8
.8
Bi 2 O 3 .N 2 6 .2H 2 O
Dilute HNO 3
Dilute HNO 3
l8' 37
3148
15-9
2 3-7
10.50
27.2
$
83
65
.8
i
3
3
.6
.0)
Bi 2 O 8 N 2 5 .HjO
Dilute HNO 3 =
6.13% N 2 5
32-93
24.83
97
97
i
3
.2
(Bi 2 O v N 2 5 .H 2 Oand
Bi 2 3 . 3 N 2 O 6 .ioH 2
6.816% N 2 5
32.67
24.70
29.70
96.57
i
3
2 1
24.0% N 2 O 6
51.0% N 2 O 6
24.16
11.66
28.25
46.62
19.65
10.81
98
186
.76
2 3
i
i
r
.0
.2
>-Bi 2 O 3 .3N 2 O 5 .ioH 2 O
70.0% N 2 O 6
20.76
53-75
33-5 1
355
.87
i
io.6j
Anyhdrous HNO
Bi 2 O 3 + "
27.85
38.56
4.05
51.02
68.28
74.90
51.0
14-35
7-45
403.0
492.0
592.9
i
i
I
7-9
34-3
79-5 J
Bi 2 3 . 3 N 2 5 .ioH 2 O
Bi 2 3 .3N 2 5 . 3 H 2
Bi a 8 . 3 N a 6 . 3 H a O
and
Results are also given for 9, 30, and 65.
65 BORIC ACID
BORIC ACID (Ortho) H 3 BO 3 .
SOLUBILITY IN WATER.
(Ditte Compt. rend. 85, 1069, 77; Herz and Knoch Z. anorg. Chem. 41, 319, '04.)
Gms. H 3 BO 3 per
f^ ioo Gms.
Gms. B 2 O 3
per ioo Gms. t.
Gms. HsBO 3 per
ioo Gms.
Gms. EyO 3
per ioo Gms.
\Y
ater.
Solution.
H 2 0.
'Water.
Solution.
O
I
95
I
.91
I
.1
40
7-0
6-54
3
95
10
2
.70
2
63
I
5
5o
8.8
8.09
5
.08
20
4
.0
3
85
2
25
60
II .0
9.91
6
.2
25
4
7
4
49
2
65
80
16.8
14-38
9
5
30
5
4
5
.12
3
05
IOO
27-5
2i-57
15
52
The above results of Ditte are probably low.
Herz and Knoch find for 13, 3.845 grams H 3 BO 3 per 100 cc. solution,
for 20, 4-909, 25, 5.593, and 26, 5.637.
Bogdan finds 5.753 grams H 3 BO 3 per 100 grams H 2 O at 25.
SOLUBILITY OF BORIC ACID IN AQUEOUS SOLUTIONS OF HYDROCHLORIC,
SULPHURIC, AND NITRIC ACIDS AT 26.
(Herz Z. anorg. Chem. 33, 355, 34, 205, '03.)
Normality of Normality of
the H 2 S0 4 , HC1 Dissolved
or HN0 3 . B(OH) 3 .
o 0.91
0-5 0.78
i .o 0.71
2.0 0.58
3.0 0-49
4-0 0.41
5-o 0.35
6.0 0.26
The determinations given in the original tables in terms of normal
solutions when plotted together lay close to an average curve drawn
through them. The figures in the tables here shown were read (and
calculated) from the average curve.
SOLUBILITY OF BORIC ACID IN AQUEOUS SOLUTIONS OF ELECTROLYTES
Gms. Strong Acid Gms. B(OH) 3 per ioo cc
. Solution.
Solution.
In HC1.
In H 2 SO 4 .
In HNO 3 .
5- 6 4
5- 6 4
5.64
5
4.0
4-25
4-5
10
3-2
3-6
3-9
I 5
2-45
3-o
3-35
20
1.8
2-5
2.9
25
2.0
2-55
30
!-55
2 .1
35
J -75
AT 25
(Bogdan Ann. Scient. Univ. Jassy, 2, 47, 'o2-'o3.)
Gms. Electro-
Grams H 3 BO 3 per 100 Gms. H 2 O in Aq. Solutions of:
lytc per 100
Gms. H 2 O.
NaCl.
KCl.
NaNO 3 .
KNO 3 .
Na 2 S0 4 .
K 2 S0 4 .
O
5-75
5-75
5-75
5-75
5-75
5-75
10
5-75
5.80
5-78
5.81
5.88
5-92
20
5-74
5.86
5.81
5-88
6.00
6.10
40
5-72
5-98
5-87
6.04
6-33
6.50
60
5-72
6.12
5-95
6. 20
6.70
6.92
80
5-71
6.29
6. 02
6.37
7.10
7.40
Interpolated from the original.
100 parts alcohol dissolve 6.5 parts H 3 BO 3 at 25 and 23 parts at
b. pt. (U. S. P.).
BORIO ACID
66
SOLUBILITY OF BORIC ACID IN AQUEOUS SOLUTIONS OF UREA, ACE-
TONE, AND OF PROPYL ALCOHOL AT 25.
(Bogdan.)
Grams of
CO(NH 2 ) 2 ,(CH 3 )2CO
or of CaHyOH per
100 Cms. H 2 O.
O
10
20
40
60
Cms. H 3 BO 3 per 100 g. H 2 O in Aq.
Solutions of:
CO(NH 2 ) 2
(CH 3 ) 2 CO.
CsH 7 OH.
5-75
5-75
5-75
5-84
S-84
5-80
5-93
5-93
5-85
6.13
6.12
5-94
6-31
6.29
6.03
SOLUBILITY OF BORIC ACID IN AQUEOUS SOLUTIONS OF :
Acetic Acid at 26.
(Herz Z. anorg. Chem. 34, 205, '03.)
Normality of Solutions. Cms. per 100 cc. Solution.
CW 3 COOH.
B(OH) 3 .
CH 3 COOH.
B(OH) 3 .
O
0.91
5.64
I
0.82
5
4-7
2
0.65
10
4.2
4
0.42
20
3-
6
0.25
30
2.O
Acetone at 20.
(Herz and Knoch Ibid. 41, 319, '04.)
cc. Acetone
per 100 cc.
Solvent.
B(OH) 3 per
TOO cc. Solutioi
Millimols.
Grams.
79-15
4.91
20
81.71
5-07
30
83-35
5-17
40
82.72
5-*3
50
81.62
5.06
60
76.40
4-74
70
67.62
4.19
80
55-05
3-4i
100
8.06
0.50
Pure Glycerine (Sp.Gr. =1.260
at 15.5).
(Hooper Pharm. J. Trans. [3] 13, 258, '82.)
SOLUBILITY OF BORIC ACID IN:
Aq. Solutions of Glycerine
at 25.
(Herz and Knoch Z. anorg. Chem. 45, 268, '05.)
Gms. B 2 O 3
t o 3H 2 O per
100 CC.
Glycerine
- Gms. B(OH) 3 per 100
Gms.
Wt. % Millimols
Glycerine B(OH) 3 per
in Solvent. 100 cc. Sol.
Sp. Gr.
25
Gms. B(OH)a
per 100
Glycerine. Solution.
a <4'
cc. Solution
Gms.So-
* lution.
O
20
I5-87
!3
17
O
90.1
I .OI7
5
59
5-50
IO
24
19.04
16
.00
7
15
90.1
1.038
5
59
5-38
2O
28
22 .22
18
.21
20
44
90.6
1.063
5
.62
5.28
30
33
26.19
20
75
3 1
55
92.9
I .090
5
.76
5- 2 9
40
38
30.16
23
17
40
95
97-0
I.II 3
6
.02
5 -41
50
44
34-92
25
95
48
7
103.0
I - I 33
6
39
5-64
60
50
39-68
28
.41
69
.2
140.2
1.187
8
.69
7-32
70
56
44-65
30
72
100
O
390-3
1.272
24
.20
19.02
80
61
48.41
32
.61
90
67
53-18
34
.70
100
72
57-14
36
36
67 BORIC ACID
DISTRIBUTION OF BORIC ACID BETWEEN WATER AND AMYL ALCOHOL
AT 25.
(Fox Z. anorg. Chem. 35, 130, '03.)
Millimols B(OH) 3 in Cms. B(OH) 3 in 100 cc. Millimols B(OH) 3 in Cms. B(OH) 3 in 100 cc
'Aq.
Alcoholic
Aq.
Alcoholic
Aq.
Alcoholic
Aq.
Alcoholic
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
265.8
76.6
I
.648
475
87
9
33
.2
Q-545
O.206
196.5
59-5
I
.219
o
369
75
.2
22
7
0.466
o. 141
159.6
47-5
O
.990
o
,294
64
.6
J 9
.76
0.400
0.123
I26.O
37-i
o
. 7 8l
,230
BORIC ACID (Tetra) H 2 B 4 O 7 .
100 grams water dissolve 2.69 grams H 2 B 4 O 7 at 15, Sp. Gr. = 1.015.
(Gerlach Z. anal. Chem. 28, 473, '89.)
BORON TRI-FLUORIDE BF 3 .
i cc. H 2 O absorbs 1.057 cc - BF 3 at o and 762 mm., i cc. cone.
H 2 SO 4 (Sp. Gr. 1.85) absorbs 50 cc. BF 3 .
BROMINE Br.
SOLUBILITY IN WATER.
(Winkler Chem. Ztg. 23, 687, '99; Roozeboom Rec. trav. chim. 3, 29, 59, 73, 84, '84; Dancer
J. Chem. Soc. 15, 477, '62; at 15, Dietze Pharm. Ztg. 43, 200, '98.)
Grams Bromine per 100 Grams. "Absorption
Coefficient."* Solubility. *
a. q.
60.5 43-1
45.8 32.4
35-1 24.8
27.0 19.0
21-3 14.8
17.0 II.7
I 3 .8 9.4
9.4 6.2
6.5 4-0
4.9 2.8
3-0 I.I
* For " Absorption Coefficient " a and "Solubility" q, of Bromine Vapor in water, see Acetylene,
page 9-
t.
t
Water.
Solution .
(W.)
(R. D. & D.)
(W.)
(R. D. & D.)
4.17
4-22
3-98
4-05
5
3-92
3-7
3-77
3-57
10
3-74
3-4
3.61
3-29
15
3-65
3-25
3-52
3-!5
20
3-58
3.20
3-46
3.10
25
3-48
3-17
3-36
3-o7
30
3-44
3-!3
3-32
3-03
40
3-45
3-33
50
3-52
3-40
60
80
. . .
. . .
BROMINE
68
SOLUBILITY OF BROMINE IN AQUEOUS SOLUTIONS OF POTASSIUM Sui/-
PHATE, SODIUM SULPHATE, AND OF SODIUM NITRATE AT 25.
(Jakowkin Z. physik. Chem. 20, 38, '96.)
Normality of Gms. per Liter.
n I*. Q-1-. *:,-._. *^ *-
In Na 2 SO 4
Gms. per Liter.
In NaNO 8
Gms. per Liter.
KabO 4 .
Br.
Na 2 S0 4 .
Br.
NaN0 3 .
Br.
i 9 I.l8
25.14
63.55
25.07
85.09
28.80
i 45-59
29.44
31*77
29.20
42-54
31-35
i 22.79
31.46
15.88
3* -33
21.27
32.62
i n-39
32.70
7-94
32-94
10.63
33-33
iV 5-69
33 - I0
3-97
32.26
5-3 1
33-74
SOLUBILITY OF BROMIN IN NORMAL AQUEOUS SALT SOLUTIONS
AT 25.
(McLauchlan Z. physik. Chem. 44, 617, '03.)
Gms.
Normality
Gms.
Gms.
Normality
Gms.
Salt.
Salt
per
of
Dis-
Br. per
Salt.
Salt
per
of
Dis-
Br. per
Liter.
solved Br.
Liter.
Liter.
solved Br.
Liter
Water
O .
O
0.
424
33-95
NH 4 NO 3
80.
II
0.
688
55-15
Na 2 SO 4
63-
55
0.
286
23-9
NaCl
58-
50
O .
701
55-90
K 2 S0 4
91.
18
0.
3 IO
24.8
KC1
74-
60
o.
718
57-40
(NH 4 ) 2 S0 4
70.
04
o.
971
77-7
NH 4 C1
53-
5 2
I .
028
82.2
NaNO 3
85-
09
O.
3495
28.0
CH 3 COONH 4
77-
9
4-
26
340-5
KN0 3
101.
19
0.
362
28=95
H 2 S0 4 *
49.
3
0.
366
29.26
* Wildeman.
SOLUBILITY OF BROMINE IN AQUEOUS POTASSIUM BROMIDE SOLUTIONS.
(Worley J. Chem. Soc. 87, 1107, '05; see also Wildeman Z. physik. Chem. II, 421, '93.)
Gram Mols. KBr Gms. KBr
Br. per Liter Dissolved at 26.5.
Br. per Liter Djssolved at 18.5.
per Liter.
per Liter.
G. Mols.
Grams.
G. Mols.
Grams.
O-OO
o.oo
0.4282
34-23
o . 4448
35-56
O-O2
2.18
0-4671
37-35
0.4823
38.56
O.O4
4-38
0.5IOI
40.79
0.5243
41.91
0-06
6-55
0-5530
44.21
0.5668
45 -3 1
0.08
8.76
0.5920
47-33
o . 6059
48.44
o.io
10.91
0.6488
5I-87
0-6533
52-23
O.2O
21.82
0.8591
68.69
0-8718
69.69
O.4O
43.82
1.2704
101.60
I.3I24
104 . 90
0.6o
65.46
1.6717
I33-70
I.77I2
141 .60
0.80
87.64
2.1029
168.10
2.2354
178.70
0.90
98.19
2-3349
186.20
2.4851
198.70
ioo grams saturated solution of Bromine in Carbon Bisulphide con-
tain 45.4 grams Br at 95, 39.0 grams at 110.5, and 3 6 -9 grams
at - 116.
(Arctowski Z. anorg. Chem. n, 274, *95-'96.)
BROMINE
DISTRIBUTION OF BROMINE AT 25 BETWEEN WATER AND:
(Jakowkin Z. physik. Chem. 18, 588, '95.)
Carbon Bisulphide.
Bromoform.
Carbon Tetra Chloride.
Cms. Br.
per Liter of:
Cms. Br.
per Liter of:
Gms. Br.
per Liter of:
Aq. Layer.
CS 2 Layer.
Aq. Layer.
CHBr 3 Layer.
Aq. Layer.
CC1 Layer.
o-5
36
o-5
33
o-S
15
i
80
i
66
i
28
2
I6 3
2
136
2
60
3
240
3
206
3
90
4
330
4
276
4
123
5
420
5
346
5
156
6
5*5
6
415
6
190
7
620
8
260
10
340
12
43
14
520
BRUCINE C 21 H 20 (OCH 3 ) 2 N 2 O 2 . 4 H 2 O.
SOLUBILITY IN SEVERAL SOLVENTS AT i8-22.
(Muller Apoth. Ztg. 18, 232, '03.)
Solvent.
Water
Ether
Acetic Ether
Benzene
Gms. Brucine
per 100 Gms.
Solution.
0.0563
0-749
4-255
I. II
Solvent.
Gms. Brucine
per loo Gms.
Solution.
Petroleum Ether 0.088
Carbon Tetra Chloride 0.078
Carbon Tetra Chloride* 1.937
Glycerine 2 . 2
* Schindelmeiser Chem. Ztg. 25, 129, '01.
BUTANE C 4 H J0 .
SOLUBILITY IN WATER AT t. AND 760 MM.
t. o 4 10 15 20
Vols. C 4 H 10
per 100 vols. H/) 3.147 2.77 2.355 2.147 2.065
Iso BUTYL ACETATE, etc.
SOLUBILITY IN WATER.
(Traube Ber. 17, 2304, '84; at 20, Vaubel J. pr. Chem. 59, 30, '99.)
Compound.
Grams Com-
pound per 100
Grams HzO.
22
22
2O
20
Iso Butyl Acetate 0.5
Iso Butyl Formate i . o
Normal Butyric Aldehyde 3.6
Iso Butyric Aldehyde 10.0
BUTYL ACETATE 70
SOLUBILITY OF BUTYL ACETATE AND OF BUTYL FORMATE IN MIXTURES
OF ALCOHOL AND WATER.
(Bancroft Calc. from Pfeiffer Phys. Rev. 3, 205, 'ps-'jtf.)
cc. H-jO added to cause separation of a
AI u i second phase in mixtures of the given
in Mbrture. quantity of alcohol and 3 cc. portions of:
Butyl Formate.
Butyl Acetate.
3
3-45
2.08
6
8.83
6.08
9
14-75
10.46
12
21.45
15-37
11
29.65
39-o
20-42
25 .60
21
51.8
3 J -49
24
00
37-48
2 7
43-75
30
50-74
33
59-97
ioo cc. H 2 O dissolve 0.7 cc. iso butyl acetate at 25 (Bancroft).
Iso BUTYRIC ACID (CH 3 ) 2 CH.COOH.
SOLUBILITY IN WATER.
(Rothmund Z. physik. Chem. 26, 475, '98.)
Synthetic Method used, see Note, p. 9.
Gms. Iso Butyric Acid per ioo Gms.
b .
Aq. Layer.
Iso Butyric Ac. Layer.
5
16.4
73-4
10
17-5
68.5
15
19-4
62.5
20
22.6
53-9
22
25 .8
49.6
24.7 (crit. temp.) 36.3
CADMIUM BROMIDE CdBr 2 .
SOLUBILITY IN WATER.
(Dietz Ber. 32, 95, '99; Z. anorg. Chem. 20, 260, '99; Wiss. Abh. p.t. Reichanstalt, 3, 433, 'oo; see also
Eder Dingier polyt. J.22I, 189, '76; Etard Ann. chim. phys. [7] 2, 536, '94.)
Gms.CdBr 2 Mols. CdBr 2 Gms. CdBr 2 Mols. CdBr 2
t . per ioo Gms. per ioo Solid Phase. t. per ioo Gms. per ioo Solid Phase.
Solution. Mols. H 2 O. Solution. Mols. H 2 O.
o 37.92 4.04 CdBr 2 .4H 2 O 40 60.65 10.20 CdBr 2 .H 3 O
18 48.90 6.21 45 60.75 10.24
30 56.90 8.73 " 60 61.10 10.39 "
38 61.84 10.73 80 62.29 J o-4 8
35 60.29 10.05 CdBr 2 .H 2 O ioo 61.63 IO - 6 3 "
Density of saturated solution at 18= 1.683.
7i
CADMIUM BROMIDE
SOLUBILITY OF CADMIUM BROMIDE IN ALCOHOL, ETHER, AND
IN ACETONE.
100 gms. sat. solution of CdBr 2 .4H 2 O in abs. alcohol contain 20.93
gms. CdBr 2 at 15 (Eder).
100 gms. sat. solution of CdBr 2 .4H 2 O in abs. ether contain 0.4 gm.
CdBr 2 at 15 (Eder).
100 gms. absolute acetone dissolve 1.559 g ms - CdBr 2 at 18.
(Naumann Ber.37, 4332, '04.)
CADMIUM (Mono) AMMONIUM BROMIDE CdBr 2 .NH 4 Br.
SOLUBILITY IN WATER.
(Rimbach Ber. 38, 1553, '05; Eder.)
AO ioo Grams Solution contain Gms.
Atomic Relation . G . CdBrs.NH^r
'Cd.
Br.
NH 4 .
Cd
: Br :
; NH 4 .
|^tl l\J\J VJlllD.
Solution.
I -O
16.33
34-87
2.63
I
3
I
53-82
14-8
17.40
37-15
2.80
I
3
I
58.01
52.2
19-79
42.38
3.21
I
3
I
65-31
IIO.I
22.99
49.17
3-72
I
3
I
75-98
ioo gms. sat. solution of CdBr 2 .NH 4 Br in abs. alcohol contain 15.8
gms. double salt at 15 (Eder).
ioo gms. sat. solution of CdBr 2 .NH 4 Br in abs. ether contain 0.36
gm. double salt at 15 (Eder).
CADMIUM (Tetra) AMMONIUM BROMIDE CdBr 2 .4NH 4 Br.
SOLUBILITY IN WATER.
(Rimbach.)
The double salt is decomposed by water at temperatures below 160*
ioo Gms. Solution contain Gms. Atomic Relation in Sol. Atomic Relation in Solid.
I .
' Cd.
Br.
NH4.
Cd
: Br :
NH4.
Cd
: Br :
NH 4 .
0.8
14.72
50
.46
6.67
I
4.82
2.82
I
10
.02
8.02
13.0
*4-95
5 1
.48
6.85
I
4-85
2.8 5
I
II
57
9-57
44-o
15 .01
53
85
7-35
I
5-04
3-04
I
6
.84
4.84
76.4
14.6
54
.28
7.80
I
5-32
3-32
I
6
63
4-63
I2 3-5
J 5-5
59
5o
8-45
I
5-38
3-38
I
7
.40
5-4o
160.0
14.7
62
.67
9-43
I
5-99
3-99
I
6
03
4-03
CADMIUM (Mono) POTASSIUM BROMIDE CdBr 2 .KBr.H 2 O.
SOLUBILITY IN WATER.
(Rimbach; see also Eder.)
t.
0-4
50.0
112. 5
ioo Gms. Solution contain Gms.
Cd.
Br.
K.
*5-4i 33-o 5-42
16.85 35-96 5-86
19.58 41.86 6.85
22.24 48.28 8.14
Atomic Relation in Sol.
Gms.CdBr 2 .KBr
'Cd :
Br
: K.
Solution.
I
3
I
53 -63
I
3
I
58.61
I
3
I
67.87
0.98
3
1.03
78.11
CADMIUM BROMIDE 72
CADMIUM Tetra POTASSIUM BROMIDE is decomposed by water at
ordinary temperatures.
CADMIUM (Mono) RHUBIDIUM BROMIDE CdBr 2 .RbBr.
SOLUBILITY IN WATER.
(Rimbach.)
too Gms.
Solution contain Gms.
Atomic Relation in Sol . Gms. CdBr 2 .RbBr
t.
per 100 Gms.
Cd.
Br.
Rb.
Cd :
Br
Rb.'
Solution.
0.4
8.37
!7-93
6-43
I
3
I .01
32.65
14-5
10.72
23.02
8.30
o-99
3
1. 01
41-87
49.2
15.01
32.I3
11.51
i
3
I
58-54
107-5
19.65
41.12
14.06
1.02
3
0.96
75-77
CADMIUM (Tetra) RHUBIDIUM BROMIDE CdBr 2 . 4 RbBr.
SOLUBILITY IN WATER.
(Rimbach.)
too Gms. Solution contain Gms. Atomic Relation in Sol. Gms.CdBr 2 .4RbBr
13-5
114-5
CADMIUM (Mono) SODIUM BROMIDE CdBr 2 .NaBr2iH 3 O.
SOLUBILITY IN WATER, ETC., AT 15.
(Eder Ding, polyt. J. 221, 189, '76.)
Gms. CdBr 2 .NaBr per 100 Gms. Solid
VCn ' 'Solution. Solvent.' Phase.
Cd
Br
Rb.
Cd :
Br
: Rb.'
per 100 jm
Solution.
5-70
24.94
17.97
0.98
6
4-05
47-95
6-55
28.74
20-74
o-97
6
4-05
55-J7
8.25
35 -5 1
25-39
0.99
6
4-02
68.82
9-5
40.67
29.00
1. 00
6
4.0
79-04
Water 49.0 96.1 CdBr 2 .NaBr.2^H 2 O
Absolute Alcohol 21.2 27.0
Absolute Ether 0.52 0.53
CADMIUM CHLORATE Cd(ClO 3 ) 2 .2H 2 O.
SOLUBILITY IN WATER.
(Meusser Ber. 35, 1422, '02.)
Gms. Mols. Gms. Mols.
t Cd(C10 3 ) 2 Cd(C10 3 )2 Solid Phase f Cd< a <> Cd(ClO 3 ) 2 Solid Phase.
per 100 Gms. per 100 Mols. ruasc. * 'periooGms. per 100
Solution. H 2 O. Solution. Mols.H 2 O.
-20 72.18 22.47 Cd(ClO 3 ) 2 .2H 2 O 18 76.36 27.98Cd(ClO 3 ) 2 .2H 2 O
-15 72.53 22.87 49 80-08 34-82
o 74-95 25.92 65 82.95 42-14
Density of the saturated solution at 18 = 2.284.
73
CADMIUM CHLORIDE
SOLUBILITY IN WATER.
(Dietz W. Abh. p. t. Reichanstalt 3, 433, 'oo; above 100, Etard Ann. chim.phys.t?] 2, 536, '94.)
t .
G. CdCl 2 perMols.CdC! 2 Soiid
100 Gms. per 100 p , t .
Solution. Mols.H 2 O.
G.CdCl,per
100 Gms.
Solution.
Mols.CdCl, s^
iffi/Sb. *5.
- 9
43-58
7-5]
+ 10
57-47
*3-3
49-39
9.6
PHri TT O 2O
57-35
13.2
+ 10
55-58
12.3
40
57-5 1
13-3
I 5
59.12
14- 2J
60
57-7i
13-4
10
44-35
7-8^
80
58.41
13.8
o
47-37
9.0
100
59-52
14-4.
+ 18
52-53
10.9
^CdCl 2 .2iH 2 150
64.8
3
56.91
12.8
(monoclinic) 2OO
72.0
36
57-91
13-5.
270
77-7
Density of saturated solution at 18 = 1.741.
100 gms. abs. ethyl alcohol dissolve 1.52 gms. CdCl 2 at 15. 5.
100 gms. abs. methyl alcohol dissolve 1.71 gms. CdCl 2 at 15. 5.
(de Bruyn Z. physik. Chem. 10, 783, '92.)
CADMIUM AMMONIUM CHLORIDE CdCl 2 .NH 4 Cl.
SOLUBILITY IN WATER.
(Rimbach Ber. 30, 3075, 1897.)
100 Gms. Solution contain Gms. Gms. CdC^.NHiCl per 100 Gms.
i> .
Cd.
Cl.
NH .
Solution.
Water. '
2.4
14.26
13-44
2 .24
29-94
42.74
16.0
15.82
15-07
2.56
33-45
50.26
41.2
18.61
17.46
2.89
38.96
63 -83
63.8
20.92
19-73
3-34
43-99
78.54
105.9
24.70
23-52
4.01
5 2 -23
109.33
CADMIUM (Tetra) AMMONIUM CHLORIDE CdCl 2 .4NH 4 Cl.
IN CONTACT WITH WATER.
The salt is decomposed in aqueous solution.
(Rimbach.)
. o 100 Gms. Solution contain Gms. Atomic Relation in Solution.
*
' Cd.
Cl.
NH4. C
d : Cl :
NIL;
3-9
5-75
18.17
7-37
9-96
7.96
16.1
6.96
20.26
7-97
9-2O
7-13
40.2
9.91
23.84
8.92
7 .6i
5.61
58-5
12.50
26.53
9-35
6. 7 i
4.66
112 .9
16.66
3 J -79
10.78
6. 02
4.02
i J 3-9
16.51
32.71
11.30
6.26
4.26
SOLUBILITY OF MIXTURES OF CADMIUM TETRA AMMONIUM CHLORIDE
AND CADMIUM AMMONIUM CHLORIDE IN WATER.
(Rimbach Ber. 35 t 1300, '02.)
100 Gms. Solution contain Gms.
Atomic Relation.
Solid Phase,
Mol. per cent of:
Cd.
Cl.
NH 4 .
Cd
: Cl :
NH*.
CdCli.
NHCL
CdClj.
4 NH 4 C1.
I .1
5-34
17.62
7.27
i
10-47
8.50
49.6
50-4
14.0
7.12
19.86
7.84
i
8.84
6.87
47-0
53-o
40-7
10.24
23 .82
8.85
i
7-37
5-37
77.0
23 o
58.5
12.50
26-53
9-35
i
6. 7 I
4.66
CADMIUM CHLORIDE
74
SOLUBILITY OP MIXTURES OF CADMIUM TETRA AMMONIUM CHLORIDE
AND AMMONIUM CHLORIDE IN WATER.
(Rimbach.)
ioo Gms. Solution
40 contain Gms.
Atomic
Relation .
Solid Phase,
Mol. per cent of:
Cd.
Cl.
NH.
Cd
: Cl :
NH 4 .
NH 4 C1. CdCl 2 . 4 NH 4 Ci.
I -0
2.82
17.11
7
.82
I
19
.21
17.28
59-o
41
.0
I 3 .2
2.76
18.84
8
.71
I
21
.62
19.62
74-0
26
.0
4O.I
3.16
22 .56
10
49
I
22
65
20-74
71.0
29
.0
58-2
3-5 1
25.21
II
.72
I
22
79
20.89
69.0
31
.0
CADMIUM BARIUM CHLORIDE 2 (CdCl 2 ).BaCl 2 .sH 2 O.
SOLUBILITY IN WATER.
(Rimbach Ber. 30, 3083, '97.)
ioo Gms. Solution
Gms. 2 (CdCl 2 ).BaCl 2
t.
contain Gms.
per ioo Gms.
Cd.
Cl.
Ba.
Solution.
Water.
22 .6
17.71
16.89
II .0
45-60
83.82
41-3
19.22
18.15
11-77
49.14
96.62
53-9
19.85
18-75
12.41
51.04
104.25
62.2
20-59
19.66
12.83
53-08
"3-13
69 5
21 .20
20. 18
13.09
54-47
119.64
107.2
24.25
23-23
14.90
62.38
165-85
CADMIUM BARIUM CHLORIDE CdCl 2 .BaCl 2 .4H 2 O.
SOLUBILITY IN WATER.
(Rimbach.)
ioo Gms. Solution
Gms. CdCl 2 .BaCl2
t.
contain Gms.
per ioo Gms.
Cd.
Cl.
Ba.
Solution. Water.
22.5
11.98
15.19
14.71
41.88 72.06
32-9
12 .40
16.18
16.09
44.67 80.73
41.4
I3-05
16.95
16.81
46.81 88.01
S3 -4
13.96
18.21
18.13
50.30 101.21
62 .0
J 4-73
18.81
18.74
52.28 109.56
97-8
17-57
22.48
22.00
62.05 l6 3-^o
108.3
18-53
23-51
22.79
64.83 184.33
109.2
18.67
23.69
29-95
65.31 188.27
CADMIUM MAGNESIUM CHLORIDE 2 (CdCl 2 )MgCl 2 .i2H 2 O.
SOLUBILITY IN WATER.
(Rimbach.)
ioo Gms.
Solution
Gms. 2(CdC
l 2 ).MgCl 2
1;*. contain Gms.
per ioo l
jms.
Cd.
Cl.
Mg.
Solution.
Water.
2
4
22
,14
21 .
06
2
.41
45
,6l
83.86
2O
.8
24
30
22 .
80
2
55
49
,6 9
98.77
45
5
26
.24
24-
55
2
.72
53
51
115.10
67
.2
28
45
26.
7i
2
.98
58
,14
138.90
121
.8
3 1
.84
30
20
3
44
65
, 4 8
189 69
75 CADMIUM CHLORIDE
CADMIUM (Mono) RHUBIDIUM CHLORIDE CdCl 2 .RbCl.
SOLUBILITY OF CADMIUM MONO RHUBIDIUM CHLORIDE IN WATER.
(Rimbach Ber. 35, 1303, '02.)
100 Gms. Solution ontain Gms. Gms. CdCl 2 .RbCl per 100 Cms.
I/ .
Cd.
Cl.
Rb.
Solution.
Water.
I .2
4.80
4-53
3-63
12-97
14.90
14-5
6.20
5.88
4-75
16.80
2O.I9
41.4
9-34
8.86
7.14
25-3 1
33 89
57-6
ii .40
10.78
8.63
30-83
44 -5 8
103.9
17.14
16.37
13-39
46.62
87.36
CADMIUM (Tetra) RHUBIDIUM CHLORIDE CdCl 2 .4RbCl.
IN CONTACT WITH WATER.
(Rimbach.)
The double salt decomposes to CdCl 2 .RbCl and RbCl.
t
100 Gms.
Solution contain Gms.
Atomic Relation.
Solid Phase,
Mol. per cent of:
Cd.
Cl.
Rb.
Cd : Cl
: Rb.
CdCl 2 .
RbCl.
Cdc;i 2 .
4 RbCl.
o-7
0.65
6. 5 2
J 4-73
I 31.88
29.88
30
70
8.8
1.07
7-37
16.13
I 21.89
19.89
24
7 6
13.8
1.32
7.86
16.93
I 18.88
16.83
16
8 4
42.4
3-21
n-35
22.45
I II .21
9.21
14
86
59-o
4.61
13 .41
25-3 1
I 9.23
7-23
33
67
108.4
8.94
18-57
3 I - I 5
I 6.57
4-59
SOLUBILITY OF MIXTURES OF CdCl 2 .4RbCl AND RbCl IN WATER.
(Rimbach.)
100 Gms. Solution contain Gms. Atomic Relation. Mo?per cent'of :
Cd! CL~ Rb!" Cd !~C1 : Rb. CdCl 2 .4Rbcl RbCl.
0.4 12.86 30.97 ..ii 55 45
14.8 13.62 32.81 .. i i 67 33
17.9 14.0 33.71 .. i i 80 20
THE EFFECT OF THE PRESENCE OF HC1, CaCl 2 AND OF LiCl UPON
THE DECOMPOSITION OF CADMIUM TETRA RHUBIDIUM
CHLORIDE BY WATER AT 16.
(Rimbach Ber. 38, 1570, '05.)
100 Gms. Solution contain Gms. Mols IQQ Mds HZ Q Mo i eC ular Ratio.
Total Cl.
Cl.
HCl.
Cd.
Rb.
CdCl 2 .
RbCl.
HCl. CdCla
: RbCl.
36-44
0-84
36.61
0.41
I
39
O
109
0-483
29.76
I
4-43
28.45
0.8o
28.44
o-35
I
38
o
.082
0.422
20-35
I
5^5
12 .09
3-24
9.11
0.69
6
74
I 39
1.772
5 .60
I
12-75
Ca.
CaCl 2 .
CaCl 2 .
14.98
7-56
20.91
o-73
2
.80
o
159
0-799
4-59
I
5-04
12.70
5-77
15.96
0.77
4
.87
o
.163
i-353
3-4i
I
8.31
10.85
3-78
14.47
i .00
8
5 1
.211
2-3 6 5
2.24
I
II .22
9-o8
1.84
5.10
1.24
12
.14
o
.262
3-385
1.09
I
12.92
Li.
LiCl.
LiCl.
26.49
4-87
29.40
0.56
3-
871
o
139
i .271
19.40
I
9- J 3
20-37
3-33
2O II
0-52
7-
84
.122
2-433
12.54
I
19.88
See Note on next page.
CADMIUM CHLORIDE 76
CADMIUM (Mono) POTASSIUM CHLORIDE CdCl 2 .KCl.H 2 O.
SOLUBILITY IN WATER.
(Rimbach Ber. 30, 3079, '97; see also Croft Phil. Mag. [3] 21, 356, '42.)
100 Cms. Solution Cms. CdCl 2 .KCl
^o_ contain Gms. per 100 Gms.
Cd. Cl . Solution. Water.
2.6 9.53 9.03 3.31 21.87 27.99
15.9 11-63 10-98 3.99 26.60 36-24
41.5 15.47 14-73 5-45 35 - 66 55-34
60.6 17.68 16.80 6.20 40.67 68.55
105.1 22.46 21.34 7.87 5 J -67 106.91
CADMIUM (Tetra) POTASSIUM CHLORIDE CdCl 2 . 4 KCl.
IN CONTACT WITH WATER.
(Rimbach.)
The double salt is decomposed when dissolved in water at ordinary
temperature.
TOO Grams Solution contain Gms.
l< .
Cd.
Cl.
K.
4
3- 6 4
9.84
8. 3 I
23.6
5.66
14.02
11.52
50.2
9.10
18.09
13.60
108.9
11.94
23.11
17 .16
NOTE. The effect of the presence of certain chlorides upon the
decomposition of cadmium tetra potassium chloride by water at 16
was investigated by Rimbach in a manner similar to that used in the
case of cadmium tetra rhubidium chloride (see preceding page). The
results, which show the extent to which increasing amounts of the
several chlorides force back the decomposition of the double salt, were
plotted on cross-section paper, and the points at which the decom-
position was prevented, were determined by interpolation. These
values which show the minimum amount of the added chlorides which
must be present to insure the crystallization of the pure double salt are
shown in the following table.
Added
Mols.
per
ioo Mols
. H 2 0.
Density of
Mols.
per
Liter of
Solution.
Chloride.
CdCl 2 .
KC1.
Added
Chloride.
Solutions.
CdCl 2 .
KC1.
Added*
Chloride.
HC1
0.074
.296
19
.80
I
.1403
0-033
.132
8.828
LiCl
0-344
I
376
9
30
I
.1380
0.166
.663
4.483
CaCIg
0-544
2
.I 7 6
3
.80
I
2333
0.270
I
.808
1.887
KC1
1.034
6
.514*
2
378
I
.214
0.507
3
.195*
I .167
* Total.
CADMIUM CYANIDE Cd(CN) 2 .
ioo gms. H 2 O dissolve 1.7 gms. Cd(CN) 2 at 15.
(Joannis Ann. chim. phys. [5] 26, 489, '82.)
77
CADMIUM FLUORIDE
CADMIUM FLUORIDE CdF 2 .
SOLUBILITY IN WATER.
100 cc. saturated aqueous solution contain 4.36 gms. CdF 2 at 25.
(Jager Z. anorg. Chem. 27, 34, 'ox.)
CADMIUM HYDROXIDE Cd(OH) 2 .
SOLUBILITY IN WATER.
i liter of aqueous solution contains 0.0026 gm. Cd(OH) 2 at 25.
(Bodlander Z. physik. Chem. 27, 66, '98.)
CADMIUM IODIDE CdI 2 .
SOLUBILITY IN WATER.
(Dietz W. Abh. p. t. Reichanstalt 3, 433, 'oo; see also Kremers Pogg. Ann. 103, 57, '58; Eder
Dingl. polyt.' J. 221, 189, '76; Etard Ann. chim. phys. [7] 2, 536, '94.)
A0 Gms. CdI 2 per 100 Gms.
Mols. CdI 2
Gms. CdI 2 per 100 Gms.
Mols. CdI 2
Solution.
Water.
MoTs!H 2 O.
Solution.
Water.
per 100
Mols. H 2 O.
44.4
79-8
3-9
30
47-3
89.7
4-43
10
45-4
83.2
4.1
40
48.4
93-8
4.6
15
45-8
84-5
4.17
50
49-35
97-4
4.8
18
46.02
85.2
4.2
75
5 2 - 6 5
III .2
5-4
20
46-3
86.2
4.26
100
56.08
127.6
6-3
2 5
46.8
87.9
4-34
Density of saturated solution at 18 = 1.590.
SOLUBILITY OF CADMIUM IODIDE IN ORGANIC SOLVENTS.
Observer.
(Eder.)
(Timofeiew Compt. rend. 112, 1224, '91.)
(Timofeiew Compt. rend. 112, 1224, '91.)
(Timofeiew Compt. rend. 112, 1224, '91.)
(Eder.)
(Naumann Ber. 37, 4332, '04.)
Gms. CdI 2 per
Solvent.
t.
TOO
Gms.
Solution.
Solvent.
Absolute Alcohol
15
50-5
102.0
Ethyl Alcohol
20
42 .6
74.27
Methyl Alcohol
20
59-o
*43-7
Propyl Alcohol
2O
28.9
40.67
Absolute Ether
15
21.7
27.7
Absolute Acetone
18
20-0
25.0
CADMIUM AMMONIUM IODIDES (Mono and Di) .
SOLUBILITY IN WATER, ETC.
(Rimbach Ber. 38, 1557. '05; at 15 Eder Dingl. polyt. J. 221, 189, '76.)
Solvent.
Water
Abs. Alcohol
Abs. Ether
Cd. Mono
Ammonium Iodide.
Gms. CdI 2 .NH 4 I per
t 100 Gms.
15
Solution. Solvent.
52.6 ni.o
53 JI 3
29.4 41-7
Cd. Di
Ammonium Iodide.
Gms. CdI 2 . 2 NHJ per
t. 100 Gms.
Solution.
Solvent.
14-5
85-97
6II.6
15
59
143
IS
10
II
CADMIUM IODIDES 78
CADMIUM POTASSIUM IODIDES, Mono = CdI 2 .KI.H 2 O,
Di= CdI 2 .2KI.2H 2 O.
CADMIUM Di SODIUM IODIDE CdI 2 . 2 NaI.6H 2 O.
SOLUBILITY IN WATER, ETC., AT 15.
(Eder.)
Gms. CdI 2 .KI
Solvent. *** I0 ? Gms "
Gms. CdI 2 .2KI
per 100 Gms.
Gms. CdI 2 .2NaI
per 100 Gms.
Solution.
Solvent.
Solution.
Solvent.
Solution.
Solvent.
Water 51.5
Abs. Alcohol
Abs. Ether
1 06
57-8
41.7
3-9
137
71
4.1
6l. 3
53-7
9.0
158.8
116.2
9-9
CADMIUM NITRATE Cd(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt 3 440, 'oo.)
Gms. Cd(N0 3 ) 2
t o_ per 100 Gms.
Solution.
Water.
-13
37-37
59-67
I
47-33
89.86
+ I
5 2 -73
III-5
5 2 -37
109.7
+ 18
55-9
126.8
30
58-4
140.4
40
61 .42
159.2
59-5
76-54
3 2 6-3
25.0
Density of saturated solution at 18 = 1.776.
Mols. Cd(NO 3 ) 2
Solid
per 100 Mols. H 2 O.
Phase.
4-55
Cd(N0 3 ) 2 . 9 H 2
6.85
"
8.50
"
8-37
Cd(NO s ) 2 . 4 H 2
9.61
"
10-7
"
12 .1
tt
K
CADMIUM OXALATE CdC 2 O 4 .3H 2 O.
i liter of sat. aqueous solution contains 0.033 g m - CdC 2 O 4 at 18.
(Kohlrausch Z. physik. Chem. 44, 197, '03.)
CADMIUM SULPHATE CdSO 4 .
SOLUBILITY IN WATER.
(Mylius and Funk W. Abh. p. t. Reichanstalt 3, 444, 'oo; see also Kohnstamm and Cohn Wied
Ann. 65, 344, '98; Steinwehr Ann. der Phys. (Drude) [4] Q, 1050, '02; Etard Ann. chim. phys
[7] 2 536, '94.)
Solid
Gms. CdSO 4
t . per TOO Gms.
Solution.
Water.
-17
44-5
80.2
10
46. i
85.5
- 5
48.5
94-2
-18
43-35
76.52
10
43- 2 7
76.28
43.01
76.48
+ 10
43.18
76.00
20
43-37
76.60
CdS0 4 .7H 2
CdSO 4 .|H 2 O
40
60
73-5
74-5
77
85
90
100
Gms. CdSO 4
per 100 Gms.
Solid
CdSO 4 .fH 2 O.
tt
CdS0 4 .H 2 O
it
it
it
tt
Solution. Water.
43-99 78.54
44.99 83.68
46.6 87.28
46.7 87.62
42.2 73.02
39-6 65.57
38.7 63.13
37.8 60.77
79
CADMIUM SULPHATE
SOLUBILITY OF CADMIUM SULPHATE IN AQUEOUS SOLUTIONS OF SUL-
PHURIC ACID AT o.
(Engel Compt. rend. 104, 507, '87.)
Equivalents per 10 Gms. H2O.
H 2 S0 4 .
CdSO 4 .
o.
7 1.6
3-87
70.9
12.6
62 .4
28.1
50.6
43-3
40.8
47.6
37-o
53-8
3 2 -7
7i-5
23.0
Density
of Solutions.
I .609
Grams per 100 Grams H2O.
545
476
435
421
407
379
H 2 S0 4 .
CdSO 4 .
O-OO
74.6l
I .90
73-87
6.18
6 5-3
I3-78
52-73
21.23
42.52
23-34
38-56
26.38
34-07
35-0 6
23.96
SOLUBILITY OF MIXED CRYSTALS OF CADMIUM SULPHATE AND FERROUS
SULPHATE IN WATER AT 25.
(Stortenbecker Z. physik. Chem. 34, 109, 'oo.)
Composition of Solution.
Gms. per
100 Gms. H 2 O.
Mols. per :
too Mols. H 2 O.
Mol. % Cd.
CdSO 4 .
FeSO 4 .
Cd.
Fe. '
in Sol.
Crystals with 2 Mols. H 2 O.
76.02
o.o
6-57
o.o
100
57-6i
10.63
4-98
1.26
79-8
Crystals with 7
Mols. H 2 0.
57-6i
10.63
4.98
1.26
79-8
78.5
44-6
24.4
0-0
26.60
o.o
3-I65
o.o
Mol. per cent Cd in
Crystals of
Solid Phase.
100
99-o
36.6
34-6
ii .1
4-8
o.o
CADMIUM POTASSIUM SULPHATE CdK 2 (SO 4 ) 2 .
SOLUBILITY IN WATER.
(Wyrouboff Bull. soc. chim. [3] 25, 121, '01.)
to
G. CdK 2 (S0 4 ) :
i per
Solid
to
G. CdK 2 (SO 4 ) 2
,
100 Gms. H 2 (
)
Phase.
.
per 100 Gms. H 2 O.
16
42.89
CdK 2
(S0 4 ) 2 . 2 H 2
26
42.50 C
3 1
46.82
"
3 1
42.80
40
47-40
a
40
43-45
64
44.90
Solid
Phase.
CdK 2 (S0 4 ) 2 .iiH 2
CADMIUM SODIUM
SULPHATE
80
CADMIUM SODIUM SULPHATE CdNa 2 (SO 4 ) 2 .2H 2 O.
SOLUBILITY IN WATER, ALSO WITH THE ADDITION OF CADMIUM SUL-
PHATE AND OF SODIUM SULPHATE.
(Koppel, Gumpery Z. physik. Chem. 52, 413, '05.)
Solid Phase.
CdNa 2 (S0 4 ) 2 . 2 H 2
CdNa 2 (SO 4 ) 2 . 2 H 2 O
+ CdSO|.|H 2
CdNa 2 (SO 4 ) 2 . 2 H 2 O
+ Na 2 S0 4 .ioH 2
CdNa 2 (SO 4 ) 2 . 2 H 2 O
+Na 2 SO 4
Gms. per 100 Gms.
40. Solution.
Gms. per 100 Gms.
H 2 0.
Mols. per 100 Mols.
H 2 0.
24
30
CdS0 4 .
22.25
22-55
Na 2 SO 4 .
I5-07
15.29
CdSO 4 .
35-49
36.28
Na 2 S0 4 .
24.04
24.60
CdS0 4 . Na 2 S0 4 .
3-07 3-05)
3- J 4 3-12 Y
40
22.89
15 .65
37-24
25-45
3.22 3-28;
O
40.32
4-85
73-54
8.85
6.36
1
10
39 -9 1
5-24
72.77
9-55
6.30
.21 1
20
40.26
5-16
73 -81
9-45
6-39
.20
40
39 - 8 9
7 .l8
75-38
I3-56
6.52
72
14.8 40.18
4.60
72.68
8-32
6.29
/
37-30
6-53
66.32
ii .62
5-74
47]
10
32-53
8.69
55-34
14-78
4-79
.84 I
20
22 .69
14.71
36-25
23-52
3.14 2.98 1
25
16-33
19.82
25.60
31.06
2.21 3.94'
30
9-21
27.80
14.62
44.14
1.26 4.59]
35
8.26
29-35
13.26
47-06
i .15 5.96 [-
40
9.98
28.27
16.24
46.27
1.41 5 .86j
CAESIUM ALUMS
SOLUBILITY OF CAESIUM CHROMIUM ALUM, CAESIUM IRON ALUM,
CAESIUM INDIUM ALUM, AND OF CAESIUM VANADIUM ALUM IN
WATER.
(Locke Am. Ch. J. 27, 174, '01.)
Formula of Alum.
Cs 2 Cr 2 (S0 4 ) 4 .2 4 H 2
a.
a
Cs - Fe 2 (SO 4 ) 4 .24H 2 O
Cs 2 V 2 (S0 4 ) 2 . 24 H 2
25
30
35
40
25
30
35
40
25
25
Gms. per 100 cc. H 2 O.
Anhydrous
Salt.
Hydrated
Salt.
0-57
0.96
I. 206
o-94
1.52
x -53
2-43
1.71
2.72
2 -52
3-75
6.04
4.01
6.01
9.80
7-57
n-73
0.771
I-3 1
Gram Mols. Salt per
100 cc. H 2 O.
O.OOI5I
O.OO25
0.0032
o . 00405
O.OO45
O.OO66
O.OO99
0.0156
0.0172
O-OO2O4
8i CAESIUM CHLORAURATE
CAESIUM OHLORAURATE CsAuCl 4 .
SOLUBILITY IN WATER.
(Rosenbladt Ber. 19, 2537, '86.)
t.
Gms. CsAuCl 4
per ioo Gms.
Solution.
to.
Gms. CsAuCU
per ioo Gms. t .
Solution.
Gms. CsAuCU
per ioo Gms.
Solution.
10
o-5
40
3-2 80
I6. 3
20
0.8
50
5-4 90
21.7
30
I -7
60
8.2 IOO
27-5
70
12 -O
CAESIUM FLUOBORIDE CsBFl 4 .
100 grams water dissolve 0.92 gram CsBFl 4 at 20, and 0.04 gram
at 100. (Godeffroy Ber. 9, 1367, '76.)
CAESIUM MERCURIC BROMIDE CsBr. 2 HgBr 2 .
100 grams saturated aqueous solution contain 0.807 gram CsBr.
2HgBr 2 at l6. (Wells - Am. J. Sci. [3} 44, 221, '92.)
CAESIUM CARBONATE Cs 2 CO 3 .
100 grams absolute alcohol dissolve n.i grams Cs 2 CO at 19, and
20.1 grams at b. pt. (Bunsen.)
CAESIUM CHLORIDE CsCl.
SOLUBILITY IN WATER.
(Berkeley Trans. Roy. Soc. (Lond.) 203 A, 208, '04; see also Hinrichsen and Sachsel Z. physik.
Chem. 50, 99, '04- '05; at 25, Foote.)
to
G. CsCl per IPO Gms.
G.Mol.CsCl
G. CsCl per ioo Gms.
G. Mol. CsCl
.
Solution.
Water.
per Liter.
'
Solution
. Water.
per
Liter.
O
61-7
161
4
6
74
60
6 9
7
229.7
8
.28
10
6 3 .6
174
7
fj
.11
70
70
.6
239-5
8
. 4 6
20
6 5 .I
186
5
>j
38
80
71
4
250-0
8
-6 4
3
66.4
197
3
7
63
90
72
.2
26o.I
8
.80
40
67-5
208
.0
h
.86
IOO
73
.0
270.5
8
, 9 6
So
68.6
218
5
8
.07
119.4
74
4
290.0
9
.22
SOLUBILITY OF MIXTURES OF CAESIUM CHLORIDE AND MERCURIC
CHLORIDE IN WATER AT 25.
(Foote Am. Ch. J. 30, 340, '03.)
Gms. per ioo Gms. Gms. per ioo Gms.
Solution. Solid Phase. Solution. Solid Phase.
CsClI HgCl 2 . CsCl 2 . HgCl 2 .
65.61 o.o CsCl 38.63 1.32
65.78 0.215 CsCl + CssHgCl 5 17.03 0.51
62.36 0.32 ) Double Salt I 'S3 '4 2
57.01 0.64 I CssHgClg 0.6l 2.64 CsHg + CsHg,Cl 6
52.35 1.23 ) -65-1% CsCl . 49 2>9I ) DoubleSalt
J
51.08 1.44 Cs 3 HgCl fi + CsjHgCl* 0.40 3-78 J CsHg 2 Cl 5 = 23.7%CsCl
40.30 1.49 ) DoubleSalt 0.44 4.63 CsHg a Cl B + CsHg 8 Cl u
45.95 1.6 9 f Cs i HgCl 4 =5S.4%C S Cl 0.41 4-68 ) Doub i e salt
45- 2 3 J -73 Cs,HgCU + CsHgCl, 0.25 5.65 ) CsHg 8 Cl n =ii.i%C 6 Cl
o.i 8 7.09 CsH g6 Cl u + HgCl,
0.0 6.90 HgCl,
CAESIUM CHLORTELLURATE 82
CAESIUM CHLORTELLURATE CsTeCl 6 .
SOLUBILITY IN AQUEOUS HYDROCHLORIC ACID.
(Wheeler Am. J. Sci. [3] 45, 267, '93.)
ioo parts HC1 (Sp. Gr. 1.2) dissolve 0.05 part CsTeCl 6 at 22.
ioo parts HC1 (Sp. Gr. 1.05) dissolve 0.78 part CsTeCl 6 at 22.
CAESIUM THALLIC CHLORIDE 3 CsCl.TlCl 3 .2H 2 O.
ioo parts H 2 O dissolve 2.76 parts 3CsCl.TlCl 3 .2H 2 O at 17, and 33.3
parts at I00. (Godeffroy Z. Osterr. Apoth. Ver. No. 9, 1886).
CAESIUM IODATE CsIO 3 .
ioo parts H 2 O dissolve 2.6 parts CsIO 3 at 24, and 2.5 parts 2CsIO 3 .
I 2 O 6 at 2 1. (Wheeler Am. J. Sci. [3] 44, 123, '92.)
CAESIUM IODIDE Csl.
SOLUBILITY OF MIXTURES OF CAESIUM IODIDE AND IODINE IN WATER.
(Foote Am. Ch. J. 29, 210, '03.)
t .
-4
-4
4
O-2
Gms. per ioo Gms.
Solution. t.
Gms. per ioo Gms.
Solution.
Solid Phase at
Csl
Csl and CsI 3
CsI 3 and CsI 5
CsI 5 and I
Csl.
27.68
27.52
3 .l8
0.85
I.
O-O
0.09
0.31
0-34
35-6
35-6
35-6
35-6
Csl.
51.48
51.66
10.72
3-74
i.
o.o
0.71
1.78
1. 60
Gms. per ioo Gms.
t Solution.
In Separated Heavy Solution
Gms. per ioo Gms. Solution.
Solid
Phase
Csl.
i.
Csl.
]
5 2
.2
16
75
4-52
CsI 3
and
CsI 6
52
.2
6
,69
.
.
CsI 5
and
I
52
.2
6
.72
3-32
22
94
73
72
CsI 5
5 2
.2
6
65
3-45
22
.80
.63
I
73
26
.98
I5-07
CsI 3
and
CsI 6
73
16
.66
10.50
27.56
68
.40
CsI 5
73
6
,27
4.08
*7
.68
80
.02
I
CAESIUM (Tri) IODIDE CsI 3 .
ioo cc. saturated aqueous caesium iodide (about 17 per cent Csl)
solution contain 0.97 gram CsI 3 at 20, density of solution = 1.154.
(Wells Am. J. Sci. [3] 44, 221, '92.)
CAESIUM NITRATE CsNO 3 .
SOLUBILITY IN WATER.
(Berkeley Trans. Roy. Soc. (Lond ) 203 A, 213, '04.)
Gms. CsNO 3 per
t . ioo Gms.
G. Mols.
CsN0 3
Gms. CsNO 3 per
t o. ioo Gms.
G. Mols CsNO 3
Solution .
Water.
per Liter.
Solution.
Water'.
per loiter.
O
8-54
9-33
0.476
60
45-6
83.8
3-41
10
12.97
14.9
0,725
70
51 .7
107.0
4.10
20
18.7
23.0
I .11
80
57-3
134.0
4.81
30
25-3
33-9
1.58
90
62 .0
163 .O
5-50
40
32.1
47-2
2.12
IOO
66-3
197.0
6.19
50
39-2
64.4
2-73
106
.2 68.8
220-3
6.58
CAESIUM OXALATE
CAESIUM OXALATE Cs 2 C 2 O 4 .H 2 O.
SOLUBILITY OF MIXTURES OF CAESIUM OXALATE AND OXALIC ACID IN
WATER AT 25.
(Foote and Andrew Am. Ch. J. 34 156, '05.)
Varying amounts of the two substances were dissolved in hot water
and the solutions allowed to cool in a thermostadt held at 25.
Solid
Phase.
H 2 C 2 O 4 . 2 H 2 O
H 2 C 2 4 . 2 H 9 + H 3 Cs(C 2 4 ) 2 . 2 H 2
Double Salt
H 3 Cs(C 2 4 ) 2 . 2 H 2
H 3 Cs(C 2 4 ) 2 2H 2 + H 4 Cs 2 (C 2 4 ) 3
Double Salt.
H 4 Cs 2 (C 2 4 ) 3
H 4 Cs 2 (C 2 4 ) 3 +HCsC 2 4
Double Salt.
HCsC 2 O 4
HCsC 2 4 +H 6 Cs 8 (C 2 4 ) 7
Double Salt.
H 6 Cs 8 (C 2 4 ) 7
H 6 Cs 8 (C 2 4 ) 7 +Cs 2 C 2 4 .H 2
Cs 2 C 2 4 .H 2
Gms. per 100
G. Mols.
per 100
Gms.
Solution.
G. Mols
H 2 0.
H 2 C 2 4
Cs 2 C 2 4 . H 2 C 2 4 .
Cs 2 C 2 O 4 .
10. 2O
2.274
10.29
o
.61 2.314
0-035
7 -9Q
9
.92 i
[-924
O.6l4 (
4.11
25
.12 I.l62
1.81 J
4-32
27
55
[.279
2 .06
4-2-7
28
30
[ .267
2.14 {
4.40
35
.90 3
.476
3-07 *
4.82
40
. 10
[ .752
3 -7 1
4-45
42
.32 ]
.672
4-05 )
3-05
48
.80
.268
5-i6
i .04
68
.69 0.688
11.56 J
0.91
7 1
.24 0.648
13.06
0.77
73
45 0.598
J4-5 1 (
o-75
74
.04 0.596
14-96 *
0.74
75
.20 0.625
J 5-93
o.o
75
.82 o.o
I 5-97
CAESIUM PERMANGANATE CsMnO 4 .
100 cc. sat. aqueous solution contain 0.097 gm. CsMnO 4 at i'
gtn. at 19, and 1.25 gms. at 59.
0.23
(Patterson J. Am. Chem. Soc. 28, 1735, ! o6.)
CAESIUM SELENATE Cs 2 SeO 4 .
100 grams H 2 O dissolve 245 grams Cs 2 SeO 4 at 12.
(Tutton J. Chem. Soc. 71, 850, '97.)
CAESIUM SULPHATE Cs 2 SO 4 .
SOLUBILITY IN WATER.
(Berkeley Trans. Roy. Soc. (Lond.) 203 A, 210, '04.)
Gms. Cs 2 SO 4 per
t o . 100 Gms.
G. Mols.
Cs 2 S0 4
Solution.
Water.
per Liter.
O
62.6
167 .1
3-42
IO
63-4
I73-I
3-49
20
64.1
178.7
3-56
30
64.8
184.1
3 -62
40
65-5
189.9
3.68
50
66.1
194.9
3-73
Gms. Cs 2 SO 4 per
t. 100 Gms.
G. Mols.
Cs 2 S0 4
Solution.
Water.
per Liter.
60
66
7
199
9
3
.78
7
67
.2
205
.0
3
83
80
67
.8
210
3
3
.88
9
68
.3
214
9
3
.92
100
68
.8
2 2O
3
3
97
108.6
69
.2
224
5
4
.00
CAESIUM DOUBLE 84
SULPHATES
SOLUBILITY OF CAESIUM DOUBLE SULPHATES IN WATER AT 25.
(Locke Am. Ch. J. 27, 459, '01.)
Cms. Anhydrous Salt Gm. Mols.
Name. Formula. per 100 Gms. Salt per 100
Solution. Water. Gms.H 2 O.
Caesium Cadmium Sulphate Cs 2 cd(SO 4 ) 2 .6H 2 o 58.16 139.9 0.2455
Caesium Cobalt Sulphate Cs2Co(so 4 )2.6H 2 o 29.52 41.9 0.081
Caesium Copper Sulphate Cs,Cu(SO 4 ) 2 .6H 2 o 31-49 46.0 0.0882
Caesium Iron Sulphate Cs 2 Fe(so 4 ) 2 .6H 2 o 50.29 101.1 0.1967
Caesium Magnesium Sulphate Cs 2 M g (so 4 ) 2 .6H 2 o 34-77 53-3 0.1106
Caesium Manganese Sulphate Cs2Mn(so 4 ) 2 .6H 2 o 44.58 80.4 0.157
Caesium Nickel Sulphate Cs 2 Ni(so 4 ) 2 .6H 2 o 20.37 25.6 0.0495
Caesium Zinc Sulphate Cs2Zn(so 4 )2.6H 2 o 27.87 38.6 0.0738
CAFFEINE C 6 H(CH 3 ) 3 N 4 O 2 .H 2 O.
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P. ; Gockel J. Chem. Soc. 74. 327, '98; Commaille Compt. rend. 81, 819, '75.)
Grams Caffeine per 100 Grams Solvent at:
Solvent.
25.
80.
18.
b.pt.
17
b. Dt. ^
U.S.
P.
Gockel.
Commaille.
Water
2
.19
I 9
23
.
, . .
I.
3it
45-54
Alcohol
I
.88
f
.85*
.
. .
, . .
o.
6il
Ether
O
.267
O
.119
O
295
o.
c-44 J
O .^6J
Chloroform
12
5
.
II
77
15
63
12 .
97t
19.02!
Benzene
.
.
.911
5
.29
.
Carbon Tetra
Chloride
.
. .
,
. .
o
.089
o
.702
.
Carbon Bisulphide
.
.
0.0585!
o-454t
* 60. t 6 S .
t Gms
. anhydrous caffeine.
Abs. alcohol and abs.
ether.
CALCIUM ACETATE Ca(CH 3 COO) 2 .2H 2 O.
SOLUBILITY IN WATER.
(Lumsden J. Chem. Soc. 81, 355, '02; Krasnicki Monatsh. Chem. 8, 597, '87.)
Gms. Ca(CH 3 COO) 2 Gms. Ca(CH 3 COO) 2
t . per TOO Gms. Solid Phase. t. per 100 Gms. Solid Phase.
Solution. \Vater. Solution. Water.
O 27.2 37.4 Ca(CH 3 COO) 2 . 2 H 2 60 24.6 32.7 C a (CH 3 COO) 2 . 2 H 2 O
10 26.5 36-0 Ca(CH 3 COO) 2 . 2 H 2 O 80 25.! 33.5 Ca(CH 3 COO) 2 .2H 2 O
20 25.8 34.7 Ca(CH 3 COO) 2 .2H 2 O 84 25.3 33.8 Ca(CH 3 COO) 2 .2H 2 O
2 5 2 5 '5 34 - 2 Ca(CH 3 COO) 2 .2H 2 O 85 24.7 32.9 Ca(CH 3 COO) 2 .H 2 O
3 2 5-3 33-8 Ca(CH 3 COO) 2 . 2 H 2 90 23.7 31.1 Ca(CH 3 COO) 2 .H 2
40 24.9 33.2 Ca(CH 3 COO) 2 .2H 2 IOO 22.9 29.7 Ca(CH3COO) 2 .H 2 O
SOLUBILITY OF CALCIUM ACETATE IN AN AQUEOUS SATURATED SOLU-
TION OF SUGAR AT 31.25.
(Kohler Z. Ver. Zuckerind. 47, 447, *97.)
TOO gms. solution contain 8.29 gms. Ca(CH 3 COO) 2 + 60.12 gms. sugar,
loo gms. water dissolve 26.3 gms. Ca(CH 3 COO) 2 + 190.3 gms sugar.
85 CALCIUM ACETATES
CALCIUM (Tri) Methyl ACETATE Ca[(CH 3 ) 3 CCOO] a .
CALCIUM (Di) Ethyl ACETATE Ca[(C 2 H 6 ) 2 CHCOO] 2 .
CALCIUM Methyl Ethyl ACETATE Ca[CH 3 (C 2 H 6 ).CHCOO] 2 .
SOLUBILITY OF EACH IN WATER.
(Landau Monatsh. Chem. 14, 717, '93; Keppish Ibid, g, 600, '88; Sedlitzki Ibid. 8, 573, '87.>
Ca. Tri Methyl Acetate.
Ca. Di Ethyl Acetate. Ca. Methyl Ethyl.
Acetate.
Gms. Ca(C 5 H 9 O 2 )2
Gms.
Ca(CeHiiO 2 ) 2 Gms. Ca(C5H fi O 2 ) 2
t .
per 100 Gms.
per
100 Gms.
per
ioo Gms.
Water. Solution.
Water
. Solution.
Water.
Solution.
7.30 6.81
30-3
23.22
28.78
22-35
10
6.84 6.40
27.8
31 .71
24.07
20
6.54 6.14
25.6
20.38
33-76
25-23
30
6.40 6.01
23-7
19.16
34-92
25.89
40
6 . 44 6 . 05
22 .1
I8.IO
35-20
26-04
50
6.64 6.22
20.8
17.22
34.60
25 .71
60
6.86 6.42
19-9
16.60
33-n
24.89
70
7.11 6 . 64
19.2
16.11
30-74
23.41
80
7.38 6.87
27.49
21 .56
CALCIUM Methyl Propyl ACETATE Ca[CH 3 (C 3 H 7 ).CHCOO] : .
CALCIUM (Di) Propyl ACETATE Ca[(C 3 H 7 ) 2 CHCOO] 2 .
CALCIUM (Iso) Butyl ACETATE Ca[(CH 3 ) 2 CH(CH 2 ) 2 COO] 2 .
SOLUBILITY OF EACH IN WATER.
(Stiassny Monatsh. Chem. 12, 596, '91; Furth Ibid. 9, 313, '88; Konig Ibid. 15, 22, '94.)
Ca. Methyl Propyl Acetate. Ca. Di Propyl Acetate. Ca. Iso Butyl
Acetate.
Gms. Ca(C 6 H n O 2 ) 2 Gms. Ca(C 8 H 15 O 2 ) 2 Gms. Ca(C 6 H u O 2 ) 2
t o^ per ioo Gms. per ioo Gms. per ioo Gms.
Water. Solution. Water. Solution. Water. Solution.
o 16.58 14.22 9.57 8.73 7.48 6.96
10 15.80 13.65 8.35 7.71 6.38 5.99
20 15-14 I 3- I 5 7- I 9 6.71 5-66 5-36
30 14.61 12.75 6 - I3: 5-77 5-3 1 5-04
40 14.21 12.45 5-9 4-84 5-3 1 5-4
50 13.94 12.24 4-i4 3-98 5- 68 5-37
60 13-79 12.13 3-25 3-15 6 -4i 6.02
70 13.78 12.12 2.44 2.38 7.51 6.98
80 13-89 12.20 1-65 1.62 8.97 8.23
90 10.79 9-74
CALCIUM BROMIDE CaBr 2 .
SOLUBILITY IN WATER.
(Kremers Pogg
yield
22
O
10
20
2 5
;. Ann. 103, 65, '58; Etard ^
in irregular curve and are evid<
ims. CaBr 2 per ioo Gms.
\nn. chim. phys. [
;ntly less accurate
34-2
40
60
80
?! 2, 532, *94. gives results which
than those of Kremers.)
tns. CaBr 2 per ioo Gms.
Water.
101
I2 5
I 3 2
153
Solution.
50-5
55-5
57-o
58.8
60.5
Water.
213
2 7 8
295
312
Solution.
65
68.1
73-5
74-7
75-7
Density of saturated solution at 20 = 1.82.
CALCIUM BUTYRATE
86
CALCIUM (Normal) BUTYRATE Ca[CH 3 (CH 2 ) 2 COO] 2 .H 2 O.
CALCIUM (Iso) BUTYRATE Ca[(CH 3 ) 2 CH.COO] 2 .sH 2 O.
SOLUBILITY OF EACH IN WATER.
(Lumsden J. Chem. Soc. 81, 355, '02; see also Chancel and Parmentier Com pt. rend. 104, 474,
'87; Deszathy Monatsh. Chem. 14, 251, '93, and also Hecht Liebig's Annalen 213, 72, '82, give
results for the normal salt which are somewhat below those of Lumsden for the lower temperatures.
SedJitzki Monatsh. Chem. 8, 566, '87, gives slightly different results for the iso salt.)
Calcium Iso Butyrate.
Calcium Normal Butyrate.
Gms. Ca(C 4 H 7 O 2 ) 2
t
per ]
too Gms.
t.
Water.
Solution.
20.31
16.89
o
10
J 9-i5
16.08 '
20
20
18.20
J 5-39
30
25
17.72
!5-5
40
30
17.25
14.71
60
40
16.40
14.09
62
60
15.15
13.16
65
80
14-95
13 .01
80
100
15-85
13.69
100
Gms. Ca(C 4 H 7 2 ) 2
per 100 Gms.
Water. Solution.
Solid
Phase.
20 .10 16 . 78 Ca(C 4 H 7 2 ) 2 . 5 H 2
22.40 18.30
23.80 19.23
25.28 20.65
28.40 22.12
28.70 22.30
28.25 22.O3
27.00 21.26
26.IO 20.69
CALCIUM CAPROATE Ca[CH 3 (CH 2 ) 4 COO] 2 .H 2 O.
CALCIUM 3 Methyl PENTANATE Ca[CH 3 .CH 2 .CH(CH 3 )CH 2 .
COO] 2 . 3 H 2 0.
CALCIUM CAPRYLATE Ca[CH 3 (CH 2 ) 6 COO] 2 .H 2 O.
SOLUBILITY OF EACH IN WATER.
(Lumsden; the Pentanate, Kulish Monatsh. Chem. 14, 566, '93; see also Keppish Ibid, g, 594,
'88, and Altschul Ibid. 17, 571, '96, for results on the Caproate.)
Ca. Caproate.
Gms. Ca(CaH u Oa) 2
t . per 100 Gms.
H 2 0.
O
20
2.23
2.18
40
2.15
50
60
80
2 .IO
2.15
2.30
100
2-57
Ca.
3 Methyl Pentanate.
Ca. Caprylate.
Gms. Ca(C6HnO2)2
per 100 Gms,
Gms. Ca(C 8 H 15 O 2 )s
per zoo Gms.
H 2 0.
o-33
0.31
0.28
O.26
Water. Solution.
12.33 IO -98
I7.l8 14.66
18.99 *5-97
18.73 I5-78
17.71 15.04
13.37 ii -80
0.24
0.32
9-94 9-04
0.50
CALCIUM CARBONATE CaCO 3 .
SOLUBILITY IN WATER, AS DETERMINED BY THE ELECTROLYTIC
CONDUCTIVITY METHOD.
(Holleman, Kohlrausch, and Rose Z. physik. Chem. 12, 129, 241, '93.)
i liter solution contains o.oi gram CaCO 3 at 8.7, and 0.012 gram
at 20.
8 7 CALCIUM BICARBONATE
CALCIUM BICARBONATE Ca(HCO 3 ) 2 .
SOLUBILITY IN WATER AT 15.
Calcium carbonate in presence of water, free from and containing
carbon dioxide, dissolves as the hydrogen carbonate.
(Among the investigators who have reported results upon the solubility of calcium bicarbonate may be
mentioned, Cossa Z. anal. Chem. 8, 145, '69; Schloesing Com pt. rend. 74, 1522, '72; Caro Arch.
Pharm. [3] 4, 145, '74; Reid Proc. Roy. Soc. (Edin.) 15, 151, '87-'88; Irving and Young J. Chem.
Soc. 56, 344, '88; Anderson Proc. Roy. Soc. (Edin.) 16, 319, '88- '89 ; Engel Ann. chim. phys.
[6] I 3> 348, '88; Lubavin J. russ. phys. chem. Ges. 24, 389, '92; Pollacci L'Orosi 19, 217, '96,
etc. The results, however, which appear of most interest and reliability are the following by Tread-
well and Reuter Z. anorg. Chem. 67, 185, '96.)
cc. CC2 per 100 cc. Partial Pres- Gms. per 100 cc. Saturated Solution.
Gaseous Phase sure of CC>2
(o and 760 mm.). in mm. Hg.
8.94 67.9
6.04 45-9
5-45 4i-4
2.18 16.6
1.89 14.4
1.72 13.1
0.79 6.0
0.41 3- 1
0.25 1.9
o . 08 o 6
Therefore i liter sat. solution at 15 and o partial pressure of CO 2
contains 0.385 gram Ca(HCO 3 ) 2 .
SOLUBILITY OF CALCIUM BICARBONATE IN AQUEOUS SODIUM CHLORIDE
SOLUTION AT 15.
(Tread well and Reuter.)
The NaCl solution contained about 5 grams per liter, and was there-
fore approximately T V normal.
cc. CC>2 per I0 cc. Partial Pres- Grams per 100 cc. Saturated Solution.
(1 aseous Phase sure of CO 2
(o and 760 mm.). in mm. Hg.
16.95 I28 ' 8
11.47 8 7-2
6.07 46.1
3.16 24.0
0.50 3-8
4i 3-4
Free CO 2 .
Ca(HC0 3 ) 2 .
Ca.
0.1574
0.1872
0.0462
0-0863
0-1755
0-0433
0.0528
0-1597
0.0394
0.0485
O.I54O
0-0380
0.0347
O.I492
0.0368
0-0243
Q-I33 1
0.0329
O.OI45
0.1249
0.0308
o . 0047
0.0821
O.O2O3
O.OO29
0-0595
O.OI47
0.0402
0.0099
0.0385
0.0095
Free CO 2 .
Ca(HC0 3 ) 2 .
Ca.
0.1325
0.2184
0-0539
O-IIOI
0.0235
0.0135
0.0027
0.2143
0.1492
0-1183
0-0739
0-0529
0.0368
0.0292
O.Ol82
0.0003
o . 0490
0-0349
0.0332
O.OI2I
0.0086
0.0082
CALCIUM BICARBONATE
88
SOLUBILITY OF CALCIUM BICARBONATE IN AQUEOUS SOLUTIONS OT
AMMONIUM NITRATE, SODIUM CHLORIDE AND OF SODIUM SULPHATE.
(Cameron and Seidell J. Physic. Chem. 6, 50, '02; Berju and Kosminiko Landw. Vers. Stat. 60,
422, '04.)
In NI^NOa Solutions at 18. In NaCl Solutions at 25.
Grams per Liter Solution. Grams per Liter Solution.
In Na 2 SO 4 Solutions at 24
Grams per Liter Solution.
rH4NO 8
. Ca(HC0 3 ) 2 .
NaCl.
Ca(HC0 3 ) 2 .
Na 2 S0 4 .
Ca(HCO 3 ) 2 total.
Ca(HC0 3 ) 2 .
o
O.2IO
o . 1046
O
0.092
0.092
5
10
20
0.340
0.415
0-547
5
10
20
0.150
O.lSo
O.2IO
5
IO
20
0-175
0.232
0.277
0.22O
O.262
40
80
0.744
0.940
40
80
O.225
O.22O
40
80
o-33 2
0.400
0.307
o-347
IOO
150
2OO
0.215
0.192
0.170
IOO
200
0.432
0.510
0.600
o-355
0.382
0.400
250
0.137
250
0.725
o-435
CALCIUM CHLORATE Ca(ClO 3 ) 2 .2H 2 O.
100 grains saturated aqueous solution contain 64.0 grams Ca(ClO 3 X
at 1 8. Density of solution is 1.729.
(Mylius and Funk Ber. 30, 1718, '97.)
CALCIUM CHLORIDE CaCl 2 .
SOLUBILITY IN WATER.
(Roozeboom Z. physik. Chem. 4, 42, '80; see also Mulder; Ditte
Ann. chim. physic. [6Ji3, 381, '88; Etard Ibid
Com pt. rend. 92, 242, '81; Eng"*
[?] 2, 532, '94.)
Gms. CaCl 2 per
100 Gms.
Solid
Phase.
Water. Solution.
29.8 Ice + CaCl 2 .6H 2 O
33.3 CaCl 2 .6H 2 O
37.3 CaCl 2 .6H 2 O
39.4 CaCl 2 .6H 2 O
42 . 7 CaCl 2 .6H 2 O
50.7 CaCl 2 .6H 2 O
47 . 6 CaCl 2 .4H 2 Oa
50.1 .4H 2 Oa+.6H 2 O
53-4 -4H 2 Oa
5I.I CaCl 2 . 4 H 2 OB
53 .O . per 100 Mols.
O
18
31
38
50
60
100
o
18
3i
50
60
70
100
Densities of the saturated solutions of the above several hydrates
at 18 are: a CaCrO 4 .2H 2 O, 1.149; ft CaCrO 4 .2H 2 O, 1.105; CaCrO 4 .H 2 O,
1.096; CaCrO 4 .iH 2 O, 1.044; CaCrO 4 , 1.023.
100 cc. 29% alcohol dissolve 1.206 grams CaCrO 4 .
100 cc. 53% alcohol dissolve 0.88 gram CaCrO 4 .
(Fresenius Z. anal. Chem. 30, 672, '91.)
CALCIUM POTASSIUM FERROCYANIDE CaK 2 Fe(CN) 6 . 3 H 2 O.
100 parts H 2 O dissolve 0.125 part salt at 15, and 0.69 part at b. pt.
(Kunheim and Zimmerman Dingt. polyt. J. 252, 478, '84.)
CALCIUM FLUORIDE CaF 2 .
i liter of saturated aqueous solution contains 0.016 gram CaF 2 at
1 8. Determined by the electrolytic method.
(Kohlrausch Z. physik. Chem. 44, 197, '03.)
Water. Solution.
UC1 imj -i.Vl.LMa.
H 2 0.
Solid Phase, a CaCrO 4 .2H 2 O.
(Monoclinic.)
O
17-3 J 4-75
2 .O
18
16.68 14.3
1.93
20
16.6 14.22
I .93
30
16.5 13.89
1.8 5
45
14-3 I2 -53
1.6 5
Solid
Phase, ft CaCrO 4 . 2 H 2 (Rhombic.)
10.9 9.8
1-25
18
11.5 10.3
40
n. 6 10.4
i-34
Solid Phase, CaCrO 4 .H 2 O
13.0 II-5
1.50
18
10.6 9.6
I .22
25
10. o 9.1
I .15
40
8-5 7-8
0.98
60
6.1 5.7
0.70
75
4.8 4.6
0.56
100
1 2 ^ .1
O O
o-37
CALCIUM FORMATE Ca(HCOO) 2 .
SOLUBILITY IN WATER.
(Lumsden J. Chem. Soc. 81, 355, '02; see also Krasnicki Monatsh. Chem. 8, 597, '87.)
Gms.Ca(HCOO) 2
t. per 100 Gms. 4
Gms.Ca(HCOO) 2
per TOO Gms.
O
20
40
Water.
16.15
16.60
I7-05
Solution.
13.90
14.22
14.56
60
80
100
Water.
17.50
17-95
18.40
Solution.
14-89
15 .22
15-53
9 i CALCIUM HEPTOATE
CALCIUM HEPTOATE (Oenanthate) Ca[CH 3 (CH 2 ) 6 COO] 2 .H 2 O.
SOLUBILITY IN WATER.
(Lumsden J. Chem. Soc. 81, 355, '02; see also Landau Monatsh. Chem. 14, 712, '03; Altschul
Ibid. 17, 575, '96.)
t. o. 20. 40. 60. 80. 100.
G. Ca(C 7 H 13 2 ) 2 per
100 gms. solution 0.94 0.85 0.81 0.81 0.97 1.24
CALCIUM HYDROXIDE Ca(OH) ? .
SOLUBILITY IN WATER,
(Average curve from the results of Lamy Ann. chim. phys. [5] 14, 145, '78; Mahen Pharm. J. Trans
[3] 14. 55, '83-84; Herzfeld Z. Ver Zuckerind. 34, 820, '97, and Guthrie J. Soc. Chem. Ind. 20,
224, *oi.)
Grams per 100 Grams H 2 O. Grams, per TOO Grams H 2 O.
Ca(OH) 2 . CaO. Ca(OH) 2 . CaO. "
o 0.185 0.140 50 0.128 0.097
10 0.176 0.133 60 0.116 0.088
20 0.165 0.125 70 0.106 0.080
25 0.159 0.120 80 0.094 0.071
30 0.153 0.116 90 0.085 0.064
40 0.141 o. 107 100 0.077 0.058
SOLUBILITY QF CALCIUM HYDROXIDE IN AQUEOUS SOLUTIONS OP
AMMONIUM CHLORIDE AT 25.
(Noyes and Chapin Z. physik. Chem. 28, 520, 'oo.)
Millimols per Liter. Grams per Liter of Saturated Solution.
NEUCl Ca(OH) 2 . NtUCl c(OH) 2 = CaO.
o.oo 20.22 o.oo 1-50 1.13
21.76 29.08 I-l65 2.l6 1.63
43.52 39 .23 2-33 2.91 2 -20
8 3-7 59 - 68 4-447 4-42 3-45
SOLUBILITY OF CALCIUM HYDROXIDE IN AQUEOUS SOLUTIONS OF
CALCIUM CHLORIDE.
(Zahorsky Z. anorg. Chem. 3, 41, '93; Lunge J. Soc. Chem. Ind. u, 882, '92.)
Concentration Grams CaO Dissolved per 100 cc. Solvent at:
ofCaCl 2 Solutions,Wt.%. - ~^~ ~T ^ ~^
o 0.1374 0.1162 0.1026 0.0845 0.0664
5 0.1370 0.1160 0.1020 0.0936 0.0906
10 0.1661 0.1419 0.1313 0.1328 0.1389
15 0.1993 0.1781 0.1706 0.1736 0.1842
20 0.1857* 0.2249 0.2204 0.2295 0.2325
25 0.1661* 0.3020* 0.2989 0.3261 0.3710
30 0.1630* 0.3680* 0-3664 0.4122 0.4922
* Indicates cases in which a precipitate of calcium oxychloride
separated and thus removed some of the CaCl 2 from solution. ^
The results in o% CaCl 2 solutions, i.e., in pure water, are high when
compared with the average results given above.
CALCIUM HYDROXIDE
92
SOLUBILITY OF CALCIUM HYDROXIDE IN AQUEOUS SOLUTIONS OP
POTASSIUM CHLORIDE AND OF SODIUM CHLORIDE.
(Cabot J. Soc. Chem. Ind. 16, 417, '97.)
Cms. of the
Chloride
per Liter.
O
30
60
1 2O
240
3 20
In KC1 Solutions. In NaCl Solutions.
Gms. CaO per Liter at: Cms. CaO per Liter at:
b.
1.36
I.70I
I-725
I.7l8
1.248
15.
I-3I
1.658
1.674
I. 606
I.IQ9
99 & .
o- 6 35
0.788
0.876
0.894
0.617
o.
36
.813
.86
37
054
15.
i-3i
1.703
1.824
i .722
1.274
0.929
99.
- 6 35
0.969
1 .004
1 .015
0.771
0.583
SOLUBILITY OF LIME IN AQUEOUS SOLUTIONS OF SODIUM CHLORIDE
ALONE AND CONTAINING SODIUM HYDROXIDE.
(Margiet Bull. soc. chim. [3] 33, 631, '05.)
Gms. CaO per Liter of Solution.
per liter. Without 0.89 .NaOH 4 .09 .NaOH
NaOH. per Liter. per Liter.
O.22
J-3 <
5.8
5
1.4 <
3.9
10
1.6
.0
25
i-7
.1
50
1.8
25
75
i .9
4
100
1.85
4
G. NaCl.
per Liter.
150
182
225
250
300
Gms. CaO per Liter of Solution.
Without
NaOH.
o.89.NaOH 4.o 9 .NapH
per Liter. per Liter.
I .2
I .2
I .0
0.9
0-7
0-44
O.22
SOLUBILITY OF CALCIUM HYDROXIDE IN AQUEOUS SOLUTIONS OF
SODIUM HYDROXIDE.
(d'Anselme Bull. soc. chim. [3] 29, 938, '03.)
Concentration of NaOH:
Grams CaO per Liter Sat. Solution at:
Normality.
Gms. per Liter
O
O
N/ioo
0-4
N/2 5
1.6
N/is
2.66
N/8
5-00
N/5
8.00
N/2
20-00
To.
50.
70.
100.
i . 170
0.94
0.880
0.65
o-75
o-53
o-54
o-35
o-57
o-35
0.225
0.14
o-39
0.18
O-2O
0.06
O.II
0.04
0.05
o.oi
O.II
O-O2
O-OI
trace
0.02
trace
o.oo
o.oo
For results upon mixtures of calcium hydroxide and alkali carbonates
and hydroxides, see Bodlander Z. angew. Chem. 18, 1138, '05.
93 CALCIUM HYDROXIDE
SOLUBILITY OF CALCIUM HYDROXIDE IN AQUEOUS SOLUTIONS OP
GLYCERINE AT 25.
(Herz andKnoch Z. anorg. Chem. 46, 193, '05; for older determinations, see Berthelot Ann. chim.
phys. [3] 46, 176; and Carles Arch. Pharm. [3] 4, 558, '74.)
Density of
Solutions
Wt. per cent
Glycerine
in Solution.
Millimols
*Ca(OH) 2 per
100 cc. Solution.
Gms. per
100 cc. Solution.
Ca(OH) 2
= CaO/
1.0003
o.o
4-3
0-1593
o.i 206
1.0244
7-*S
8.13
0.3013
O.228l
1-0537
20.44
14.9
0.5522
0.4180
I .0842
3i-55
22.5
0-8339
0.6313
I.II37
40.95
40.1
1.486
I.I25
i -i35 6
48.7
44-o
1.631
1.234
1.2072
69.2
95-8
3-550
2.687
SOLUBILITY OF LIME IN AQUEOUS SOLUTIONS OF SUGAR.
(Weisberg Bull. soc. chim. [3] 21, 775, '99.)
The original results were plotted on cross-section paper and the
following table constructed from the curves.
ist series, t = i6 / -i7.
>ms. p
Sr 100 Gms.
Sc
ution.
G. CaO per 100
Gms. Sugar in Sol.
Sugar.
CaO.
I
0.30
35-o
2
0.56
28.7
3
0.85
28.0
4
I .12
27.7
5
I .40
27-5
6
1.65
27-5
8
2 .22
27-5
10
2-77
27-5
12
3-27
27-5
14
3-85
27-5
2d, series t =
= i er
Gms. pe
:r 100 Gms.
Sc
lution.
G. CaO per 100
Sugar.
CaO.
VJITIS. oiigur in ool.
I
0.50
62.5
2
o-75
36.0
3
i .02
32.5
4
I .22
30.2
5
i-45
28.5
6
1.67
27.7
8
2 .22
27-5
10
2-77
27-5
12
3-27
27-5
14
3-85
27-5
In the second series a very much larger excess of lime was used than
in the first series. The author gives results in a subsequent paper,
Bull. soc. chim. [3] 23, 740, 'oo, which show that the solubility is also
affected by the condition of the calcium compound used, i.e., whether
the oxide, hydrate, or milk of lime is added to the sugar solutions.
CALCIUM IODATE
94
CALCIUM IODATE Ca(IO 3 ) 2 .6H 2 O.
SOLUBILITY IN WATER.
(Mylius and Funk Ber. 30, 1724, '97; W. Abh. p. t. Reichanstalt 3, 448, 'oo.)
t .
Gms.
Ca(I0 3 ) 2
per ioo
Gms. Sol.
Mols.
Ca(I0 3 ) 2
per ioo
Mols.H 2 O.
Solid
Phase.
t.
Gms.
Ca(I0 3 ) 2
per ioo
Gms. Sol.
Mols.
Ca(I0 3 ) 2
per ioo
Mols. H 2 O.
Solid
Phase.
O
.10
0.0044 Ca(IO 3 ) .611,0 21
O
37
O
.016 Ca(IO 3 ) 2 .H 2 O
10
O
17
0.0075
f
35
O
.48
.021
14
18
O
2 5
O.OII
40
52
O
.023
(I
30
O
.42
0.019
tt
45
O
54
O
.024
11
40
O
.6l
0.027
5o
o
59
O
.026
(I
5
O
.8 9
0.040
60
o
-65
.029
11
54
j
.04
0.046
80
79
O
034
60
j
36
0.063
n
IOO
94
O
.042
Density of solution saturated at 18 = i.oo.
CALCIUM IODIDE CaI 2 .
SOLUBILITY IN WATER.
(Average curve from the results of Kremers Pogg. Ann. 103, 65, '58; Etard Ann. chim. phys. [7]
2. 532, '94-)
O
10
2O
Gms. CaI 2 per 100
Gms. Solution.
64.6
66.0
67.6
30
40
60
Gms. CaI 2 per 100
Gms. Solution.
6 9
70.8
74
t .
80
100
Gms. CaI 2 per 100
Gms. Solution.
78
81
Density of solution saturated at 20 2.125.
CALCIUM (Neutral) MALATE Ca(C 4 H 4 O 5 ).3H 2 O.
CALCIUM (Acid) MALATE Ca(C 4 H 5 O 5 ) 2 .6H 2 O.
CALCIUM MALONATE Ca(C 3 H 2 O 4 ). 4 H 2 O.
SOLUBILITY OF EACH IN WATER.
(Iwig and Hecht Liebig's Ann. 233, 167, '86; Cantoni and Basadonna Bull. soc. chim. [3] 35
731, '06; the malonate, Miczynski Monatsh. Chem. 7, 261, '86.)
Ca. Neutral Malate. Ca. Acid Malate. Ca. Malonate.
Gms. Ca(C 4 H 4 5 )
per ioo.
Gms. Ca(C 4 H 5 O 5 ) 2
Gms. Ca(C 3 H 2 O 4 )
t .
Gms.
Gms.
cc. Sol.
per ioo Gms.
per ioo
H 2 0.
Sol.
(C and B).
Water.
Solution.
Gms. H 2 O.
0.290
10
0.85
0.84
1.8
1-77
0-330
20
0.82
0.81
0.907
I .5
1.48
o-3 6 5
30
0.78
o-77
0.835
2.0
I .96
0.396
40
0-74
o-73
0.816
5-2
4-94
0.422
50
0.66
0.65
0.809
15.0
13.09
0-443
57
o-57
0.56
32.24
24.29
60
0.58
0.58
0.804
26.0
20.64
0.460
70
0.63
0.63
0-795
II .O
9.91
0.472
80
0.71
0.70
o-754
6.8
6-37
0.479
90
0.740
SOLUBILITY OF CALCIUM MALATE IN WATER AND IN ALCOHOL.
(Partheil and Hiibner Archiv. Pharm.24i, 413, '03.)
ioo grams H 2 O dissolve 0.9214 gram CaC 4 H 4 O 5 .H 2 O at 18, and
0.8552 gram at 25.
ioo grams 95% alcohol dissolve 0.0049 gram CaC 4 H 4 O 6 .H 2 O at 18,
and 0.00586 gram at 25.
95 CALCIUM NITRATE
CALCIUM NITRATE Ca(NO 3 ) 2 .2H 2 O.
SOLUBILITY IN WATER AT 18.
(Mylius and Funk Ber. 30, 1718, '97.)
ioo grams saturated solution contain 54.8 grams Ca(NO 3 ) 2 . Density
of solution, 1.548.
CALCIUM OXALATE Ca(COO) 2 .H 2 O.
SOLUBILITY IN WATER, BY ELECTROLYTIC CONDUCTIVITY METHOD.
(Holleman, Kohlrausch, and Rose Z. physik. Chem. 12, 129, 241, '93; Richards, McCaffrey,
and Bisbee Z. anorg. Chem. 28, 85, '01.)
-o Cms. CaC 2 O 4 per t o Cms. CaC 2 O 4 per
Liter of Solution. Liter of Solution.
13 0.0067 (H) 25 0.0068 (R, McC and B)
18 0.0056 (K and R) 50 0.0095
24 0.0080 (H) 95 0.0140 "
SOLUBILITY OF CALCIUM OXALATE IN AQUEOUS SOLUTIONS OF ACETIC
ACID AT 26-27.
(Herz and Muhs Ber. 36, 3715, '03.)
Normality of G. CH 3 COOH Residue from 50.052
Acetic Acid. per ioo cc. Sol. cc. Solution.
o o.oo 0.0017
0.58 3-48 0-0048
2.89 17-34 0-0058
5-79 34-74 0.0064
The residues were dried at 70 C.
CALCIUM OXIDE. See Calcium Hydroxide, p. 91.
CALCIUM PHOSPHATE (Tribasic) Ca 3 (PO 4 ) 2 .
SOLUBILITY IN WATER.
The determinations of the solubility of this salt in water, as stated
in the literature, are found to vary within rather wide limits, due, no
doubt, to the fact that so-called tribasic calcium phosphate is apparently
a solid solution of the dibasic salt and calcium oxide, and therefore
analyses of individual samples may show an excess of either lime or
phosphoric acid. When placed in contact with water, more PO 4 ions
enter solution than Ca ions, the resulting solution being acid in reaction
and the solid phase richer in lime than it was, previous to being added
to the water. For material having a composition approximating
closely that represented by the formula Ca 3 (PO 4 ) 2 the amount which
is dissolved by CO 2 free water at the ordinary temperature, as cal-
culated from the calcium determination, is o.oi to o.io gram per liter,
depending upon the conditions of the experiment. Water saturated
with CO 2 dissolves 0.15 to 0.30 gram per liter.
A list of references to papers on this subject is given by Cameron
and Hurst J. Am. Chem. Soc. 26, 903, '04; see also Cameron and
Bell, Ibid. 27, 1512, '05.
CALCIUM PHOSPHATE
CALCIUM
96
PHOSPHATE (Dibasic) CaHPO 4 .2H a O.
SOLUBILITY IN WATER.
(Cameron and Seidell J. Am. Chem. Soc. 26, 1460, '04; see also Rindell Compt. rend. 134, 112, 'oa;
Magnanini Gazz. chim. ital. 31, II, 544, '01.)
i liter of CO 2 free water dissolves 0.136 gram CaHPO 4 at 25.
i liter of water sat. with CO 2 dissolves 0.561 gram CaHPO 4 at 25.
SOLUBILITY OF Di CALCIUM PHOSPHATE AND OF MONO CALCIUM PHOS-
PHATE IN AQUEOUS SOLUTIONS OF PHOSPHORIC ACID AT 25.
(Cameron and Seidell J. Am. Chem. Soc. 27, 1508, '05; Causse Compt. rend. 114, 414, '92.)
2 O 5
in Excess of
that combined
with Ca.
2.53 CaHP0 4 . 2 H 2
21.5
46.45
89.0
128.0
159-4
Gram, .per Liter of ^ ^ ^.per Liter
Solution.
CaO.
P 2 O 5 .
I.7I
4.69
n-57
36.14
23-3I
75-95
39.81
139.6
49.76
191 .0
59-40
234.6
70.31
279.7
77.00
317.0
72.30
35 J -9
69-33
361.1
59.98
419.7
53-59
451 .7
44-52
505-8
39-89
538.3
Calc. from
Found.
CaHPO.
c r . T>,
Sohd Phase '
190.7
tt
226.0
122.2
169.0
CaHP0 4 . 2 H 2 0+
CaH 4 (PO ) 2 .H 2
CaH 4 (P0 4 ) 2 .H 2
I86.I
tt
267.9
a
3I6.I
"
393-1
tt
437-4
"
4-i5
28.05
56-53
97.01
120.7
144.1
170.6
(174.2 CaHPO 4 or
I 3 2i. 3 CaH 4 (P0 4 ) 2
301.6 CaH 4 (P0 4 ) 2
289.3
250.2
223.7
185.8
166.4
Density of the solution in contact with both salts at 25 = 1.29.
SOLUBILITY OF Di CALCIUM PHOSPHATE IN AQUEOUS N/2oo SOLUTION
OF ACID POTASSIUM TARTRATE AT 25.
(Magnanini .)
i liter of the solution contains 0.08 gram Ca = 0.235 gram CaHPO 4 .
CALCIUM PHOSPHATE (Monobasic) CaH 4 (PO 4 ) 2 ,H 2 O.
SOLUBILITY IN WATER.
This salt is stable in contact with the aqueous solution only when
there is present free phosphoric acid to the extent indicated by the
above table.
CALCIUM PELARGONATE (Nonate) Ca[CH 3 (CH 2 ) 7 COO] 2 .H 2 O.
CALCIUM PROPIONATE Ca(CH 3 .CH 2 COO) 2 .H 2 O.
SOLUBILITY OF EACH IN WATER.
(Lumsden J. Chem. Soc. 81, 355, '02; Krasnicki Monatsh. Chem. 8, 597, '87.)
Calcium Pelargonate.
Grams
t. Ca[CH 3 (CH 2 ) 7 COO]2
per 100 Grams H 2 O.
o 0.16
20 0.14
40 0.13
60 O.I2
80 0.15
90 0.18
ioo 0.26
Calcium Propionate.
Grams Ca(CH 3 .CH 2 COO) 2 per 100 Grams.
Water. Solution.
42.80 29.97
39.85 28. 4 8
38.45 27.76
38.25 27.67
39.85 28.48
42.15 29.66
48.44 3 2 - 6 3
97 CALCIUM SELENATE
CALCIUM SELENATE CaSeO 4 .
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 532, '94.)
t. -i. +5. 20. 37. 67.
Cms. per ioo gms. sol. 7.4 7.3 7.6 6.8 5.1
The accuracy of these results appears questionable.
CALCIUM SILICATE CaSiO 3 .
SOLUBILITY IN WATER AND IN AQUEOUS SUGAR SOLUTIONS AT 17.
(Weisberg Bull. soc. chim. [3] 15, 1097, '96.)
The sample of calcium silicate was air dried.
Grams per ioo cc. Saturated Solution.
Solvent.
Water
10% sugar sol.
20% sugar sol.
A
L I7 -
After Boiling and Filtering Hot.
CaO(det.) CaSiO.,(calc.)
0.0094 0.0195
O-OI2O O.O249
CaO(det.)
o . 0046
0.0065
0.0076
CaSiO 3 (calc.)
0.0095
0-0135
0.0157
CALCIUM SUCCINATE Ca(C 2 H 2 O 2 ) 2 .
CALCIUM (Iso) SUCCINATE CaCH 3 .CHC 2 O 4 .H 2 O.
SOLUBILITY OF EACH IN WATER.
(Miczynski Monatsh. Chem. 7, 261, '86.)
Calcium Succinate. Calcium Iso Succinate.
t e .
Gms.
Ca(C 2 H 2 2 ) 2
per ioo Gms.
Gms.
t o Ca(C 2 H 2 2 ) 2
' per ioo Gms.
Gms.
t o Ca(C 2 H 2 2 ) 2
' per ioo Gms.
Gms.
t o Ca(C 2 H 2 O 2 ) 2
' per ioo Gms.
H 2 O.
H 2 O.
H 2
H 2 0.
I .127
50
1.029
O
0.522
50
0.440
10
1.220
60
0.894
IO
0.524
60
0.396
20
1.276
70
0-770
20
o-s 1 ;
70
0.342
40
I.I77
80
0.657
40
o-475
80
0.279
ioo cc. H 2 O dissolve 1.424 grams succinate (CaC 4 H 4 O 4 .H 2 O) at 18,
and 1.436 grams at 25.
ioo cc. 95% alcohol dissolve 0.00136 gram succinate (CaC 4 H 4 O 4 .
H 2 O) at 18, and 0.00136 gram at 25.
(Partheil and Hiibner Archiv. Pharm. 241, 413, '03.)
CALCIUM SULPHATE CaSO 4 . 2 H 2 O.
SOLUBILITY IN WATER.
(Hulett and Allen J. Am. Chem. Soc. 24, 674, '02; for references to other determinations see Hulett
and Allen, also Euler Z. physik. Chem. 49, 313, '04. Determinations by the electrolytic conductivity
method Holleman, Kohlrausch and Rose Z. physik. Chem. 12, 129, 241, '93.)
Gms. CaSO 4
Millimols.
Density of >
Gms. CaSO 4
Millimols
Density of
t .
per ioo cc.
Solution.
per
Liter.
Solutions.
per ioo cc.
Solution.
per Liter.
Solutions.
0-1759
12
.926
I
.00197
40
O
.2097
I5-4I3
C
99439
10
0-1928
14
.177
I
00173
55
O
.2009
I4-7 6 5
.98796
18
0.2016
14
.817
I
.00059
65
3
.1932
I4.2OO
.98256
25
o . 2080
15
295
.99911
75
.1847
J 3-575
.97772
30
o . 2090
15
.361
.99789
IOO
o
.1619
ii .900
35
o . 2096
15
405
O
.99789
107
n-390
...
CALCIUM SULPHATE 98
SOLUBILITY OP CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF HYDRO-
CHLORIC, NITRIC, CHLOR ACETIC, AND FORMIC ACIDS.
(Banthisch J. pr. Chem. 29, 52, '84; Lunge J. Soc. Chem. Ind. 4, 32, '85.)
In Hydrochloric. In Nitric. In Chlor Acetic. In Formic.
Grams Acid
per 100 cc.
Grams CaSO 4 per
100 cc. Sol.
Gms. CaSO 4 per
100 cc. Solution
Gms. CaSO 4 per
100 CC. Sol.
Gms. CaSO 4 per
loo cc. Sol.
Solution.
at 25.
at io2 6 .
at 25.
at 25.
at 25.
O
0.208
0.160
O.2O8
O.2O8
0.208
I
0-72
1.38
0.56
2
I .02
2.38
0.82
3
1.25
3.20
I .02
4
1.42
3- 6 4
I .20
O.22
0.24
6
1.6 5
4-65
1.48
8
i-74
1.70
10
. . .
1.84
0.25
12
I. 9 8
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF PHOS-
PHORIC ACID AT 25.
(Taber page 61, Bull. 33, Bureau of Soils U. S. Dept. Agr., 1906.)
Gms.
per
Liter.
Sp. Gr. of
Gms. per Liter. g p Q T o f
P 2 4 .
CaSO 4 .
Solutions at f .
P 2 5 .
CaSO 4 - Solutions at ff .
.0
2
126
O
.9991
145
.1
7
.920
.106
5
O
3
143
I
OO2
205
.0
8
383
145
10
5
3
734
I
.007
3 11
5
7
965
.221
21
4
4
45 6
I
Ol6
395
.8
6
.848
.280
4 6
3
r
760
I
035
494
.6
5
572
344
05
3
H
318
I
075
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF SUL-
PHURIC ACID.
(Cameron and Breazeale J. Physic. Chem. 7, 574, '03.)
Grams H 2 SO 4
Resul
Its at 25.
Results at 35,
, Results at 43 ,
per Liter of
Solution.
Gms. CaSO 4
per Liter.
wt. of i cc :
Sol.
Gms. CaSO 4
per Liter.
Gms. CaSO 4
per Liter.
O-OO
2 .126
0.9991 grams
. . .
2.145
0.48
2.128
1.0025 "
2.209
2.236
4-87
2.144
1.0026 "
2.451
2.456
8. ii
2.203
1.0051 "
2.760
16.22
2.382
1.0098 "
3.II6
48.67
2.727
i .0302 "
3-397
3-843
75.00
2.841
I-Q435 "
. . .
4.146
97-35
2-779
1.0756 "
3.606
146.01
2-571
u
3- J 5o
4-139
194.70
2-3*3
1.1134 "
3-55 1
2 43-35
i .901
1.1418 "
2 -959
292.02
i-54i
1.1681 "
, . .
2.481
99
CALCIUM SULPHATE
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF
AMMONIUM SALTS.
(In NH4C1 and NH 4 NO 3 , Cameron and Brown J. Physic. Chem. 9, 210, '05 ; In (NH 4 ) 2 SO 4 at 25*,
Sullivan J. Am. Chem. Soc. 27, 529, '05; In (NH 4 ) 2 SO 4 at 50, Bell and Tabor J. Physic. Chem. 10,
119, '06.)
In NH 4 C1 In NH 4 NO 3 In NH 4 C1
at 25. at 25. at 25.
Gms. Ammo- G.CaSO 4 G. CaSO 4 Gms. Ammo- G. CaSO 4
nium Salt Dissolved Dissolved nium Salt Dissolved
per Liter. per Liter. per Liter- per Liter. per Liter.
o 2.08 2.08 300 10.10
20 5.00 3.70 375 7.40
40 7 .00 5 .10 400
60 8 . oo 6 . 05 600
80 8.50 7.00 800
100 9.10 7 .65 1000
150 10.30 8.88 1400
200 10-85 9-85 sat.
In (NH 4 ) 2 SO 4 at 25. In (NH 4 )^SO 4
Grams per Liter Sol. \vt. of 100 cc. Grams per Liter Sol.
In NH 4 N
at 25.
G. CaSO 4
Dissolved
per Liter.
I0.8o
II -40
12.15
12 .IO
II. 8l
IO.02
7-55
at 50.
Sp. Gr.
(NH 4 ) 2 SO 4 .
CaSO 4 .
Sat,
Sol.
'(NH 4 ) 2 S0 4 .
CaSO 4 .
of Solutions.
O-OO
.208
99
.91
O
.OO
2
.168
0.129
.204
99
.91
15
65
I
.609
I .0026
0.258
.199
99
.92
30
67
I
750
I.OII3
0.821
.181
99
95
9 1
.6
2
542
I .0440
1.643
.166
99
99
160
4
3
.402
I -0819
3.287
154
IOO
.10
221
.6
4
.068
1.1108
6-575
.144
IOO
34
340
.6
5
.084
i .1653
13 .15
.146
IOO
.82
4 l6
5
5
354
i . 1964
26.30
o
.162
101
.76
428
4
4
.632
i . 2043
84-9
233
105
34
530
.8
2
.152
1-2437
169.8
333
no
32
566
,o
I
.08
1.2508
339-6
45
119
,15 566.7
.00
i .2510
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF
CALCIUM SALTS AT 25.
(Cameron and Seidell J. Physic. Chem. 5, 643, '01; Seldell and Smith Ibid. 8, 493, '04; Cameron
and Bell J. Am. Chem. Soc. 28, 1220, '06.)
In Calcium In Calcium In Calcium Hydroxide and
Chloride. Nitrate. vice versa.
Grams per Liter Sol.
Gms. per Liter Sol.
Wt. of
Gms. per Liter Sol.
Solid
CaCl 2 .
CaSO 4 . '
Ca(N0 3 ) 2 .
CaS0 4 .
i
cc. Sol.
CaO.
CaSO 4 .
Phase.
0-00
2
.06
0-0
2.08
.998
O
O
2
.126
CaSO^HjO
7-49
I
.24
2 5
1.24
I
.014
O
.062
2
030
u
II .96
I
.18
50
I .20
I
.032
.I 7 6
I
.918
tt
25-77
I
. IO
IOO
I-I3
I
.067
349
I
853
32-05
I
.08
2OO
o-93
I
137
O
.61
j
.722
it
S I -S3
I
.02
300
0.7-6
I
.204
939
I .
634
a
97.02
.8 4
4OO
o-57
I
.265
I
.222
j
.588
\ CaS0 4 . 2 H 2 0+
! Ca(OH) 2
192.71
47
500
0.40
I
.328
I
.242
I
.214
Ca(OH) 2
280.30
.20
544
o-35
I
352
I
150
.666
a
367-85
03
I
.166
.00
it
CALCIUM SULPHATE
100
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS op
MAGNESIUM CHLORIDE AND OF MAGNESIUM NITRATE AT 25.
(Cameron, Seidell, and Smith.)
In Magnesium Chloride. In Magnesium Nitrate.
Grams per Liter of Sat. Solution.
MgCl 2 .
CaSO 4 .
H 2 Oo
O-O
2.08
997-9
8.50
4.26
99 6 -5
19.18
5- 6 9
994-5
46.64
7-59
989.1
121 .38
8.62
972.2
206.98
6-57
949-9
337-o
2.77
908.7
441.1
i-39
878.6
Gms. per
Liter Sol.
Wt. of i cc.
Solution.
0.9981
Mg(N0 3 ) 2 -
o.o
CaSO 4 .
2.08
25
50
100
200
5-77
7.88
9.92
13-34
I .0205
1.0398
1.0786
I .1498
300
40O
14.00
14.68
I.2I90
I .2821
5*4
15.04
!-3553
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF MAG-
NESIUM SULPHATE AT 25.
(Cameron and Bell J. Physic. Chem. 10, 210, '06.)
Grams per Liter Solution. 5
>p. Gr. of
itions at if
MgS0 4 .
CaS0 4 .
o.o
2.046 1.0032
3-20
1.620 I-0055
6-39
I-507
.0090
10.64
I.47I
-OIl8
21.36
1.478
.0226
42.68
I-558
.0419
64.14
I. 608
.0626
85.67
I .617
0833
128.28
1.627 ]
.II9O
Grams per Liter Solution.
MgS0 4 .
149.67
I65-7
CaS0 4 .
597
549
171 .2
198.8
474
.422
232.1 ]
265.6 ]
298.0 <
254
070
>.86o
330.6 <
5.647
355-o <
5.501
Sp. Gr. of
Solutions at j|f .
J 377
.1479
1537
.1813
.2095
.2382
.2624
.2877
3023
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF POTAS-
SIUM CHLORIDE, BROMIDE, AND IODIDE AT 21.
(Ditte Ann. chim. phys. [7] 14, 294, '08.)
In KC1 Solutions. In KBr Solutions. In KI Solutions.
Grams of the
Potassium Salt
per Liter.
Cms. CaSO 4
per Liter.
O
10
2.05
3-6
2O
40
60
4-5
5-8
6.6
80
7-2
100
I2 5
7-5
double salt
200
250
300
Cms. CaSO 4
per Liter.
2.O5
3-i
3-6
4-5
5-2
5-9
6-3
6.7
7-o
7-3
double salt
Gms. CaSO 4
per Liter.
2.05
2.8
3-2
3-9
4-5
4-85
5-45
5-8
5-95
6-00
double salt
ioi CALCIUM SULPHATE
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF POTAS-
SIUM NITRATE AND OF POTASSIUM SULPHATE AT 25.
(Seidell and Smith J. Physic. Chem. 8, 493, '04; Cameron and Breazeale Ibid.S, 335, '04.)
In Potassium Nitrate. In Potassium Sulphate.
Cms. per Liter Cms. per Liter
Solution. Wt.oficc. Solution. Wt. of i cc.
Solution. ^r ' . Solution.
KNO 3 - CaSO 4 . K 2 SO 4 . CaSO 4 .
o.o 2.08 0.9981 o.o 2.08 0.9981
12-5 3-28 I.OoSl 4.88 I. 60 1.0036
25.0 4.08 I.OI54 5.09 1.56 1.0038
50.0 5.26 I.032I 9.85 1.45 1.0075
loo-o 6.86 1.0625 I 9-57 *-49 1.0151
150 7.91 1.0924 28.35 1.55 1.0229
200 8.69 1.1224 30.66 1.57 1.0236
260 syngenite 1-1539 3 2 -47 1-58*
* Solid phase syngenite. Results for the solubility of syngenite in solutions of potassium sulphate are
also given in the original paper.
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF
SODIUM CHLORIDE AT 26.
(Cameron J. Physic. Chem. 5, 556, '01; see this paper for references toother work, also Orloff T.russ-
phys. chem. Ges. 37, 949, '02; Cloez Bull. soc. chim. [3] 29, 167, '03; d'Anselme Ibid. [3] 2Q
372, '03.)
Grams per 100 cc. Solution. \vt. of i cc. Grams per 100 cc. Solution. \yt of i cc.
'NaCl. CaS0 4 . ' Solution. ' NaCl. CaSO 4 . ' Solution.'
0-00 0.2I2I 0.9998 I7-650 0.712 1.1196
9.115 0.666 1.0644 22.876 0.679 1.1488
14.399 0.718 1.0981 26.417 0.650 1.1707
14.834 0.716 I.IOI2 32.049 0.572 I-2034
SOLUBILITY OF MIXTURES OF CALCIUM SULPHATE AND CALCIUM CAR-
BONATE IN AQUEOUS SOLUTIONS OF SODIUM CHLORIDE AT 23.
(Cameron and Seidell J. Physic. Chem. 5, 643, '01.)
Grams per Liter Solution. Grams per Liter Solution.
NaCl. CXHC0 3 ) 2 . CaSC 4 . "~ NaCl. Ca(HCO 3 ) 2 . CaSO 4 7
o.oo 0.060 J -93o 79 -52 0.060 6.424
3.63 0.072 2.720 121.90 0.056 5-272
11.49 0-089 3-446 193.80 0.048 4.786
39.62 o-ioi S^S^ 267.60 0.040 4.462
SOLUBILITY OF MIXTURES OF CALCIUM SULPHATE AND SILVER SUL-
PHATE IN WATER.
(Euler Z. physik. Chem. 49, 313, '04.)
...
Per Liter
of Solution.
Total Salt r _ .
1JS2"- %&*
' Gms. Salt.
Gms. Equiv.
Salt.
17 o|CaSO<
2. SI
7-235
0-034
0-0464
0-9473 1-0083
39 146.61 2.23 1.1427
655 7.24 i-394 257.10 2.65 i. 2120
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS AND ALCOHOLIC
MONO POTASSIUM TARTRATE SOLUTIONS AT 20.
(Magnanini Gazz. chim. ital. 31, II, 544, '01.)
Gms. CaSO 4 Cms. CaSO. 4
Solvent. per 100 Gms. Solvent. per 100 Gms.
Solution. Solution
Water 0.2238 10% alcoholic N/ 2 oo KHC 2 H 4 O 6 0.0866
Aq. N/200 KHC 4 H 4 O 6 0.2323 Aq. N/ 2 oo KHC 2 H 4 O 6 + 5%
10 per cent alcohol 0.0970 tartaric ac. 0.2566
10% ale. NAoo KHC 2 H 4 6 + 5%
tartaric ac. o . 1086
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SUGAR SOLUTIONS.
(Stolle Z. Ver. Zuckerind. 50, 331, 'oo.)
Per cent Concen- Grams CaSO 4 Dissolved by i Liter of the Sugar Solutions at:
tration of Sugar
Solutions.
O
IO
20
27
35
42
49
55
CALCIUM SULPHIDE CaS.
SOLUBILITY IN AQUEOUS SUGAR SOLUTIONS.
2
I
I
I
30.
.041
.808
.263
.030
2
I
I
I
I
40.
T 57
730
.652
438
050
5 6 4
.486
i
i
i
i
50.
730
730
.419
.088
777
739
505
i
i
i
i
i
60.
730
574
.380
.283
.108
.816
5 6 4
.486
i
i
i
i
o
70.
.652
574
.419
283
.914
855
.603
369
i
i
i
80.
.710
.613
263
.972
729
.486
.330
Per cent Concen-
tration of Sugar /
(Stolle.)
Grams CaS Dissolved per Liter of the Sugar Solutions at:
Solutions.
30.
40.
50.
60.
70.
80.
90:
O
i
.982
2
.123
I
235
1.390
I .696
2
.032
2.496
10
i
.866
I
. 3 l6
I
.441
1.673
I .560
I
634
1-544
20
2
.187
I
.696
I
.802
1.905
1.879
I
.892
1.930
27
2
.522
2
.097
2
059
2 .226
2.342
2
304
2-357
35
2
.689
2
.265
2
.304
2.406
2-342
2
857
2-947
42
2
342
2
-I 3 6
2
.226
2.522
2-574
2
509
2.689
49
2
445
2
.290
2
458
2.6 3 8
2.728
2
.8l8
3-063
55
2
509
2
.226
2
340
2.882
2.766
2
972
3.616
103 CALCIUM SULPHITE
CALCIUM SULPHITE CaSO 3 .
SOLUBILITY IN WATER AND IN AQUEOUS SUGAR SOLUTIONS AT 18.
(Weisberg Bull. soc. chim. [3] 15, 1097, '96.)
Grams CaSOa per 100 cc. Solution.
Solvent. ' A R o After Boiling
Solution 2 Hours.
Water o . 0043
10 Per cent Sugar 0-0083 0.0066
30 Per cent Sugar 0.0080 0-0069
CALCIUM TARTRATE CaC 4 H 4 O 6 .4H 2 O.
SOLUBILITY IN WATER.
(Cantoni and Zachoder Bull. soc. chim. [3] 33, 747, '05.)
-o Cms. CaC 4 H 4 O 6 .4H 2 O Gms.CaC 4 H 4 O 6 .4H 2 O . Gms.CaC 4 H 4 O 6 .4H 2 O
per 100 cc. Sol. per 100 cc. Sol. per 100 cc. Sol.
o 0-0365 30 0-0631 70 0.1430
10 0-0401 40 0-0875 80 0-1798
20 0-0475 5 o-iioo 85 0.2190
25 0-0525 60 O.I262
ioo gms. aq. Ca. tartrate solution contain 0.0185 g. CaC 4 H 4 O 6 .4H 2 O
at 18, and 0.029489 at 25.
ioo gms. 95% alcohol solution contain 0.0187 g. CaC 4 H 4 O 6 .4H 2 O at
l8, and 0.02352 at 25. (Partheil and Hiibner Archiv. Pharm. 241, 413, '03.)
ioo gms. aq. Ca. tartrate solution contain 0.0364 g. CaC 4 H 4 O 6 at 20.
ioo gms. 10% alcohol solution contain 0.0160 g. CaC 4 H 4 O c at 20.
ioo gms. 10% alcohol + 5% tartaric acid solution contain 0.1632 g.
CaC 4 H 4 O 6 at 20 . (Magnanini Gazz. chim. ital. 31, II, 544, ? oi.)
SOLUBILITY OF CALCIUM TARTRATE IN AQUEOUS ACETIC ACID
SOLUTIONS AT 26-27.
(Herz and Muhs Ber. 36, 3715, '03; see also Enell Pharm. Centrallh. 38, 181; Z.anal. Chem. 38,
368, '99-)
Normality of Gms.CH 3 COOH Residue from Normality of Gms.CH 3 COOH Residue from
Acetic Acid. per ioo cc. Sol. 50.052 cc. Sol. Acetic Acid, per ioo cc. Sol. 50.052 cc. Sol.
o o 0-0217 3 .80 22.80 0.2042
0.57 3.42 0-1082 5.70 34-20 0-1844
1.425 8.55 0-1635 10.09 60.54 0-1160
2.85 17.10 0.1970 16.505 93 .03 0.0337
The residue was dried at 70 C.
CALCIUM BITARTRATE CaH 2 (C 4 H 4 O 6 ) 2 .
SOLUBILITY IN WATER AND IN AQUEOUS SOLUTIONS OF ACIDS AND
OF SALTS.
(Warington J. Chem. Soc. 28, 946, '75.)
In Hydrochloric Acid. In other Acids and in Salt Solutions at 14.
<^* a g^J!:glS& AcidorS au. ^^S.
ioo Gms. Sol. At 22. At 80.
o 0.600 4.027 Acetic Acid 0-81 0.422
0.68 3.01 5.35 Tartaric Acid 1.03 0.322
2.15 6.88 n-35 Citric Acid 0.84 0.546
4.26 11.19 20.23 Sulphuric Acid 0-685 1.701
8.36 22.75 40-93 Hydrochloric Acid 0.504 1-947
16.13 48.31 80.12 Nitric Acid 0.845 1.969
Potassium Acetate 1-387 0.744
ITO bhartrlt?aff 0olveo ' 422gms ' Potassium Citrate 1.397 0.843
CALCIUM VALERATE 104
CALCIUM VALERATE Ca[CH 3 (CH 2 ) 3 COO] 2 .H 2 O.
CALCIUM (Iso) VALERATE Ca[(CH 3 ) 2 .CH.CH 2 .COO] 2 . 3 H 2 O.
SOLUBILITY OP EACH IN WATER.
(Lumsden J. Chem. Soc. 81, 355, '02; see also Furth Monatsh. Chem. 9, 313, '88; Sedlitzky
Ibid, 8, 566, '87.)
Calcium Valerate. Calcium Iso Valerate.
Solid
Phase.
Ca(C 5 H 9 2 ) 2 . 5 H 2
Gms. Ca((
:5H B O2)2 Gms. Ca(C 5 H 9 O 2 ) 2
t, per TOO Gms. t .
per 100 Gms.
Water. Solution.
Water.
Solution.
O
9.82
8.94
o
26.05
2O-66
10
9-25
8-47
10
22.70
18.50
20
8.80
8.09
20
21. 80
17.90
30
8-40
7-75
30
21.68
17.82
40
8.05
7-45
40
22 .OO
18.18
50
7-85
7.28
45-5
22-35
18.42
57
7-75
7.19
J 9-95
16.63
60
7.78
7.22
60
18.38
I5-52
70
7-80
7.24
70
17.40
14.82
80
7-95
7-36
80
16.88
14.44
90
8.20
7-58
90
16.65
14.28
100
8.78
8.07
100
l6 -55
14 . 20
CAOUTCHOUC.
Ca(C 5 H 9 2 ) 2 .H 2
SOLUBILITY IN ORGANIC SOLVENTS.
(Hanausek J. pharm. chim. [5] 15, 509, '87.)
Grams. Caoutchouc Dissolved per 100 Gms. Solvent.
Solvent. , ; ^ ,
Gear a. Tete Noire. Sierra Leone.
Ether 2.5 3.6 4.5
Turpentine 4.5 5.0 4.6
Chloroform 3.0 3.7 3.0
Petroleum 1.5 4.5 4.0
Benzene 4.4 5.0 4.7
Carbon Bisulphide 0.4 o.o o.o
CAMPHORIC ACID C 8 H 14 (COOH) 2 .
100 grams of water dissolve 0.8 gram C 8 H 14 (COOH) 2 at 25, and 10
grams at the b. pt. (U.S. P.)
CARBAZOLE (Di Phenylene imid) (C 6 H 4 ) 2 NH.
100 grams abs. alcohol dissolve 0.92 gms. (C 6 H 4 ) 2 NH at 14, and
3.88 grams at b. pt.
100 grams toluene dissolve 0.55 gm. (C 6 H 4 ) 2 NH at 16.5, and 5.46
grams at b. pt.
CARBAMIDES.
SOLUBILITY IN SEVERAL SOLVENTS.
as Methyl Phenyl Carbamide (m. pt. 82), Benzyl Carbamide (m. pt.
149)- o Tolyl Carbamide(m.pt. 185) and p Tolyl Carbamide (m.pt. 173).
(Walker and Wood J. Chem. Soc. 73, 626, '98.)
Grams Carbamide per 100 cc. Sat. Solution.
v
as
Methyl
Phenyl.
Benzyl.
P Tolyl.
Tolyl.
Water
45
74
I.7I
0.307
.251
Acetone
23
29.
4
3-10
2.66
O
.462
Ether
22
5
2 .
28
0-053
O.O62
O
.Ol62
Benzene
44
2
12 .
4
0.0597
0.043
o
0155
CARBON DIOXIDE
CARBON DIOXIDE CO 2 .
SOLUBILITY IN WATER AND IN AQUEOUS SODIUM CHLORIDE SOLUTIONS.
(Bohr Wied. Ann. Physik. [3] 68, 503, '99; Geffcken Z.physik.Chem. 49, 271, '04; Just Ibid.
37, 354i 'i.)
Solubility in Water.
b .
0.
ft.
/.
o
o-335
i-7 J 3
5
0.277
1.424
10
0.231
1.194
15
0.197
1.019
1.070
20
0.169
0.878
2 5
0.145
0-759
0.826
30
0.126
0.665
40
0.097
0-530
50
0.076
0.436
60
0.058
0-359
Nac1 %
In 17.62%
Nad.
1.234
0.675
I .024
0-875
o-577
0-503
o-755
0.664
0-583
0.442
o-393
0-5*7
0.414
0.319
0.263
0.370
0-305
0-235
0.183
q = wt. of gas dissolved by 100 grams of solvent at a total pressure of 760 mm.
= the Bunsen Absorption Coefficient which signifies the volume (v) of
the gas (reduced to o and 760 mm.) taken up by unit volume (F) of the liquid
when the pressure of the gas itself minus the vapor tension of the solvent is
760 mm. _ v
~ V(i + 0.00367 /) '
/ = the Ostwald Solubility Expression which represents the ratio of the
volume (v) of gas absorbed at any pressure and temperature, to the volume
(V) of the absorbing liquid, i.e. I =
This expression differs from the
Bunsen Absorption Coefficient, /3, in that the volume (v) of the dissolved gas
is not reduced to o and 760 mm. The solubility / is therefore the volume
of gas dissolved by unit volume of the solvent at the temperature of the
experiment. The two expressions are related thus:
+0.0036 7 I),
SOLUBILITY IN WATER AT PRESSURES ABOVE ONE ATMOSPHERE.
(Wroblewski Compt. rend. 94, 1335, '82.)
.Pressure Coefficient of Saturation * at :
in Atmos- . - * - .
pheres. I2 -4
Pressure* Coefficient of Saturation * at:
in Atmos- / - * - >
pheres.
i
5
10
1-797
8.65
16.03
I2 -4
i. 086
5.15
9- 6 5
20
25
30
21.65
30.55
33-74
17.11
20.31
23.25
* Coefficient of Absorption is no doubt intended.
SOLUBILITY OF CO 2 IN AQUEOUS SOLUTIONS OF ACIDS AND SALTS
(Geffcken.)
Aq.
Gms. Acid
CO 2 Dissolved, / at:
Aq.
Gms.
Salt
C(
D 2 Diss
olved, I at
Solvent.
per Liter.
15.
25 '
Solvent.
per Liter.
15.
25-'
HC1
18.23
I
043
.806
CsCl
8 4
17
i
006
0.781
ti
36.46
I
.028
799
KC1
37
30
o
.976
0-759
tt
72.92
I
.000
795
KC1
74
.60
o
.897
0.700
HNO 3
3I-52
I
.078
.840
KI
83
.06
o
992
o-775
6 3-05
I
.086
853
KI
166
.12
923
0.727
tt
126.10
I
.100
.877
KBr
59
55
o
.986
0.768
H,so 4
24.52
I
.018
794
KBr
119
.11
o
.914
0.713
49.04
O
.978
.770
KNO 3
5o
59
I
005
0.784
tt
98.08
O
.917
730
KN0 3
101
.19
.946
0-749
ti
I47-II
.870
.698
RbCl
60
47
o
.989
0.769
tt
196.15
o
.828
.667
RbCl
1 20
95
o
.921
0.788
CARBON DIOXIDE
106
SOLUBILITY IN AQUEOUS
SOLUTIONS OP SALTS.
(Mackenzie Wied. Ann. Physik.[2] i, 450, '77.)
Salt in
Solution.
Gms. Salt per Density of
loo Gms. Solution. Solution 15.
Absorption Coefficient a at:
8. 15. 22?
KC1
6.05 I. 021
0.988 0.777 0.670
"
8.646 1.053
0.918 0.777 0.649
"
11-974 I.oSo
0.864 0.720 0.597
"
22.506 1-549
0.688 0.571 0.480
NaCl
7.062 1-038
0.899(6.4) 0.735
tt
12.995 1-080
0.633(6.4) 0.557 0.482
tt
17.42 1.123
0.518(6.4) 0.431 0.389
tt
26.00
195
0-347(6-4) 0.297 0.263
NH 4 C1
6.465
.021
1.023 0-825 0.718
tt
8.723
047
i.ooo 0-79 1 0.702
"
12.727
053
0.922 0.798 0.684
''
24-233
.072
0.813 (10) 0.738 0.600
8. l6.5. 22. 3 0.
BaCLj
7.316
.068
0.969 0-744 0.680 0.566
i(
9-753
.092
1. 02 1 0.645 0-607 0.543
tt
14.030
137
0.618 0.524 0.467
11
25-215
273
0.495 0.618 0.383 0.315
SrC^
9-5 11
.087
0.779 0.663 0.581 0.508
tt
12-325
1159
0.737 0.586 0.507 0.539
tt
I7-7I3
.173
0.606 0.473 0.444 0-367
11
31 .194
343
0.285 0.245 0.247 0.223
CaCl,
4-365
.036
0.942 0.759 0.673 0.596
1C
5-739
.049
0-855 0.726 0.616 0.527
tt
8.045
.068
0-838 0.674 0.581 0.500
It
15-793 i-i39
0-632 0.520 0.471 0.400
SOLUBILITY OP CARBON DIOXIDE IN ALCOHOL.
(Bohr Wied. Ann. Physik [4] i, 247, J oo.)
In 99 per cent Alcohol. In 98.7 per cent Alcohol.
t0 cc. CO 2 (at o and 760 mm.) per i cc. cc. CO 2 (at o and 760 mm.) per i cc.
Alcohol. Sat. Solution.
Alcohol. Sat. Solution.
-65
38.41
35-93
39.89
37-22
20
7-5i
7.41
7-25
7.16
10
5-75
5-69
5-43
5-38
O
4-44
4.40
4-35
4-31
+ 10
3-57
3-55
20
2.98
2.96
. . .
25
2 .76
2-74
. . .
30
2-57
2.56
40
2 .20
2 .19
45
2.OI
2.00
icy
CARBON DIOXIDE
SOLUBILITY IN AQUEOUS ALCOHOL AT 20.
(Miiller Wied. Ann. Physik. [2] 37, 39. '89; Lubarsch Ibid. [2] 37. 525, '89.)
Density of
Per cent Alec
Alcohol.
By Wt.
0.998
1.07
0.969
22.76
0-960 (22
4)
28.46
0-956
3 I - I 7
tt>s. Coef.
Density of Per cent Alcohol Abs. Coef.
)f CO 2 , a.
Alcohol.
By Wt.
Of C0 2 , a.
0.861
0.922
49-o
0.982
0.841
0.870(18.8)
71.1
1.293
0.792
0.835(16)
85-3
1.974
O.Sol
o-795 to )
99-7
2.719
0.877
42.15
SOLUBILITY OF CARBON DIOXIDE IN ORGANIC SOLVENTS.
(Just Z. physik. Chem. 37, 354. '01.)
Solvent.
Sol. of CO 2 , Ostwald Expression."
CS 2
C.H.NH,
C 5 H n OH
C 6 H 5 Br
CC1 4
C.H.CH,
CXN0 2
0.870
1.324
1.831
1.842
2.294
2-305
2.425
2.456
0.889
1-434
1.941
1.964
2.502
2 .426
2.540
2-655
Q-945
i-53i
2.058
2 .092
2.603
2-557
2.716
2.845
Solvent.
C 3 H 7 OH
C 2 H 5 OH( 95 %)
C 6 H 5 COH
CHC1 3
CH 3 OH
CH 3 COOH
(CH 3 CO) 2
(CH 3 ) 2 CO
Sol. of CO 2 , Ostwald Expression*
fee-
2.498
2.706
2.841
3-430
4.691
5 .206
6.295
ho.
2.923
3-057
3.681
4.205
5.129
5.720
6.921
3-130
3-304
4.606
5.614
6.18
* See p. 105.
Determinations are also given for the solubility in glycerine, iod
benzene, o and m toluidine, eugenol, benzene tri chloride, cumol,
carvene, di chlor hydrine, iso butyl alcohol, benzyl chloride, meta xylol,
ethylene bromide, chlor benzene, propylene bromide, amyl bromide,
carvol, amyl chloride, iso butyl chloride, butyric acid, ethylene chloride,
pyridine, amyl formate, propionic acid, amyl acetate, iso butyl
acetate, and in methyl acetate.
See Woukoloff Compt. rend. 108, 674; 109, 62, '89, for the solubility
of CO 2 in CS 2 and CHC1 3 at different pressures.
CARBON MONOXIDE CO.
SOLUBILITY IN WATER.
(Winkler Ber. 34, 1416, *oi.)
to
|3, "Absorp
1
3', " Solu-
o
/3, "Absorp.
/
V, "Solu-
.
Coef."
bility."
Q-
I
Coef."
bility."
'
o
03537
O
03516
.0044
40
0.01775
O
.01647
O-OO2I
5
03149
O
.O3I22
O
0039
50
O.Ol6l5
O
.OI42O
O-OOlS
10
.028l6
o
.02782
o
0035
60
0.01488
-OII97
O.OOI5
15
02543
o
.02501
o
.0031
70
O.OI44O
o
.00998
O.OOI3
20
o
.02319
o
.O2266
o
.0028
80
O.OI43O
o
.00762
O-OOIO
25
.O2I42
o
.02076
.OO26
90
O.OI42O
o
. 00438
0.0006
.01998
o
.01915
o
.OO24
100
O.OI4IO
.00000
o-oooo
/8 = vol. of CO absorbed by i volume of the liquid at a partial pres-
sure of 760 mm. See page 105.
ft' = vol. of CO (reduced to o and 760 mm.) absorbed by i volume
of the liquid under a total pressure of 760 mm.
q = grams of CO dissolved by 100 grams H 2 O at a total pressure of
760 mm.
CARBON MONOXIDE
1 08
SOLUBILITY OF CARBON MONOXIDE IN AQUEOUS ALCOHOL SOLUTIONS
AT 20 AND 760 MM. PRESSURE.
(Lubarsch Wied. Annalen Physik. [2] 37, 525. '89-)
Wt.% Alcohol. Vol.% Absorbed CO. Wt. % Alcohol. Vol. % Absorbed CO.
o.oo 2.41 28.57 1.50
9-09 J - 8 7 33-33 !-94
16.67 J -7S 50.00 3.20
23.08 1.68
SOLUBILITY OF CARBON MONOXIDE IN ORGANIC SOLVENTS.
(Just Z. physik. Chem. 37, 361, *oi.)
Results in terms of the Ostwald Solubility Expression, see p. 105.
Solvent.
Water
Anilin
Carbon Bisulphide
Nitro Benzene
Benzene
Acetic Acid
Amyl Alcohol
Xylene
loo volumes of petroleum absorb 12.3 vols. CO at 20, and 13.4 vols
at 10.
(Guiewaszr and Walfisz Z. physik. Chem. i, 70, '87.)
/25.
O.O24O4
0.08314
0.09366
0.1707
O.I7I4
O.I7I4
O.I78I
0.02586
0.05055
o. 08112
0.09105
o. 1645
o. 1689
o. 1706
0.1744
Solvent.
Toluene
Ethyl Alcohol
Chloroform
Methyl Alcohol
Amylacetate
Acetone
Iso Butyl Acetate
Ethyl Acetate
te.
0.1808
o. 1921
0.1954
0.2140
0.2225
0.2365
0.2516
0.1742
o. 1901
0.1897
o. 1830
0.2108
0.2128
0.2314
0.2419
SOLUBILITY OF CARBON MONOXIDE IN MIXTURES OF ACETIC ACID AND
OTHER SOLVENTS AT 25.
(Skirrow Z. physik. Chem. 41, 148, '02.)
Results in terms of the Ostwald Solubility Expression, see p. 105.
Mixture of
Acetic Ac. and:
% CHgCOOH
in Mixture.
CO.
By Wt.
By Vol.
Anilin
IOO.O
IOO.O
0.173
"
86.5
90.8
O.I 10
58.3
68-5
0.070
"
13-8
25.1
0.058
tt
O-O
o.o
0-053
Benzene
67-5
63-4
0.199
"
33-6
29.6
0.198
"
19.2
16.5
0.190
n
o.o
o.o
0.174
Mixture of
Acetic Ac. and :
Chloroform
tt
Nitro Benzene
tt
Toluene
ft
% CH 3 COOH
in Mixture.
CO.
/25-
0.196
0.206
0.156
0.130
0.093
0.191
0.195
0.190
0.182
ByWt. By Vof.
56.4 64.5
0-0 0-0
88.4 84.8
49.0 66.3
o-o o-o
74.7 71.0
56.9 52.6
20.5 17.8
o.o o-o
109
CARBON MONOXIDE
SOLUBILITY OF CARBON MONOXIDE IN MIXTURES OF ACETONE AND
OTHER SOLVENTS AT 25.
(Skirrow.)
Mixture of %(CH 3 ) 2
CO in Mixture. CO.
Mixture of
%(CH 3 ) 2 CO in
Mixture.
CO.
Acetone and:
By Wt.
By Vol.
Acetone and:
By Wt.
By Vol.
IK-
Anilin
IOO.
IOO.O
0.
238
Chloroform
66.
6
78.
9
0.226
"
79-
2
85-9
0.
179
"
26.
5
40.
4
0.212
"
44-
9
56.7
0.
no
"
0.
o
O.
o
0.207
" 0.0
0.0
0.
053
8 Naphthol
86.
93-
9
o. 190
Carbon Bisulphide
82.
83.8
0.
236
ti
73-
I
87-
i
o. 169
"
50.
5
61.8
0.
227
Nitro Benzene
78-
4
88.
5
0.207
it
26.
o
35-7
o.
187
"
46.
8
69.
5
0-157
ft
14-
5
21.2
0.
144
(I
0.
0.
o
0.090
"
o.
o
O.O
o.
096
Phenanthrene
87-
2
95-
4
o. 205
Naphthalene
86.
7
93-5
0.
199
"
75-
90.
2
0.183
"
72.
6
85-4
o.
187
SOLUBILITY OF CARBON MONOXIDE IN MIXTURES OF BENZENE AND
OTHER SOLVENTS AT 25.
(Skirrow Z. physik. Chem. 41, 144, '02.)
The solubility of the CO given in terms of the Ostwald Expression,
see p. 105.
Mixture of
Benzene and:
Naphthalene
Phenanthrene
a Naphthalene
Ethyl Alcohol
%CeH 6 in
Mixture.
By Wt.
IOO.O
88. 5
66.2
89.2
72.6
96.5
87.9
47-7
o.o
By Vol.
IOO.O
92.6
76.3
95-i
85.8
98.1
93-i
44-9
o.o
CO.
/25-
0.174
o. 164
o. 141
0.144
0.127
0.149
0.139
0.181
0.192
Mixture of
Benzene and:
Anilin
Nitro Benzene
%C 6 H 6 in
Mixture.
'ByWt.'~
87.3
71. 7
42.6
21. 2
0.0
7 1.8
45-1
o.o
By Vol.
8 9 .I
75-2
47.0
24.3
o.o
80. 1
5 6 -4
o.o
CO.
/25.
o. 156
0.131
0.095
0.068
-53
o. 152
o. 127
0.093
SOLUBILITY OF CARBON MONOXIDE IN MIXTURES OF TOLUENE AND
OTHER SOLVENTS AT
(Skirrow.)
25
Mixture of
Toluene and:
%QH5CH 3 in
Mixture.
CO.
/25-
Mixture of
Toluene and:
%C 6 H 5 CH 3 in
Mixture.
CO.
126-
B'y Wt.
By Vol.
By Wt.
By Vol.
Anilin
IOO
.0
IOO.O
.182
a Naphthol
95-5
97
.1
O.I7I
94
4
93
5
169
a
91.2
94
.2
O.l62
tl
80
.1
80
3
o
,148
Nitro Benzene
81.7
85
-7
0.160
tl
55
4
55
.6
"5
tt
50.8
58
.1
0.131
tt
25
4
25
.6
o
,077
((
23-7
29-3
0.108
tl
.0
.0
o
053
ti
O-O
o
.0
0.093
Naphthalene
92
9
94
.8
o
.169
Phenanthrene
94-4
97
.0
0.170
tt
84
9
88
7
.161
it
88.8
93
9
o. 161
tt
77
3
82
5
153
it
78.4
87
5
0.147
CARBON MONOXIDE no
SOLUBILITY OF CARBON MONOXIDE IN MIXTURES OF ORGANIC
SOLVENTS AT 25.
(Skirrow.)
% of Latter in Mixture. CO
Mixture Composed of: By Wt. ' By Vol. fa. '
Chloroform and Methyl Alcohol o.o o . 207
" 13.0 0.202
" " 100 0.196
Carbon Bisulphide and Ethyl Di Chloride 100 0.147
75 0.157
51 0.160
" 18.4 0.140
o.o 0.083
Methyl Alcohol and Glycerine o.o o.o 0.196
39.6 30.1 0.096
60.5 50.1 0.052
77.1 68.9 0.025
" " 100.0 100.0 very small
NOTE. From the results shown in the preceding five tables, it is
concluded that the solubility of carbon monoxide in various mixtures
of organic solvents is, in general, an additive function.
CARBON BISULPHIDE CS 2 .
SOLUBILITY IN WATER.
(Chancel and Parmentier Compt. rend. loo, 773, 85; Rex Z. physik. Chem. 55, 355, '06.)
Grams CS 2 per 100 Grams CS2 pe' 100
*- cc. Solu- Cms. H 2 O' t . cc. Solu- Gms. H 2 O
tion. (Rex). tion. (Rex).
o 0.204 0.258 30 0.155 0.195
5 0.199 35 0.137
10 0.194 0.239 40 o.i ii
15 0.187 45 0.070
20 0.179 o.ioi 49 0.014
25 0.169
100 cc. H 2 O dissolve o.i 74 cc. CS 2 at 22; Vol. of solution= 100.208,
Sp. Gr. = 0.9981.
100 cc. CS 2 dissolve 0.961 cc. H 2 O at 22; Vol. of solution= 100.961,
Sp. Gr. = 1.253. (Herz Ber. 31, 2670, '98.)
SOLUBILITY OF CARBON BISULPHIDE IN:
Aq. Solutions of Ethyl Alcohol at 17. Methyl Alcohol.
(Tuchschmidt and Folleuins Ber. 4, 583, '71.) (Rothmund Z. physik. Chem. 26, 475, '08.)
Wt. per Gms. CS 2 Wt. per Gms. CS 2 Wt. per cent CS 2 in:
cent per 100 cc. cent per 100 cc. t . pij,OH pc '
Alcohol. Solvent. Alcohol. Solvent. " Layer.
ioo oo 9!-37 5o 10 45.1 98.3
98-5 l82 84.12 30 20 50.8 97.2
98.15 132 76.02 20 25 54.2 96.4
96.95 IOO 48.40 2 30 58.4 95.5
93-54 7o 47-90 o 35 64.0 93.5
40 . 5 (crit. temp. ) 80 . 5
Ill
CARBON OXYSULPHIDE
SOLUBILITY OF CARBON OXYSULPHIDE IN WATER.
(Winkler; see Landolt and Bernstein's Tabellen, ad ed. p. 602, 1906.)
o
5
IO
I 5
1-333
1-056
0.835
0.677
t.
20
25
3O
8.
o-5 6 i
0.468
0.403
0.356
0.28l
O.22I
0.179
For ft and q see Carbon Dioxide, page 105.
CARBON TETRACHLORIDE. Seep. 201.
CARVOXIME C 10 H 4 :NOH.
SOLUBILITY IN r LIMONENE.
(Goldschmidt and Cooper Z. physik. Chem. 26, 714, '98.)
q.
0.147
0.122
O.IO4
Gms. C 10 H 4 :NOH
Gms. C 10 H 4 :NOI
I
t. per 100 Gms. Solid Phase.
t . per 100 Gms.
Solid Phase.
r Limonene.
r Limonene.
24.6 44-6 / Carvoxime
48 198.7
/ Carvoxime
30.0 59.2 / Carvoxime
49-4 199-7
r Carvoxime
30.3 3-3 r Carvoxime
55-4 325-1
/ Carvoxime
38.4 104.3 /Carvoxime
55-9 346.6
r Carvoxime
39 . 4 103 . i r Carvoxime
58.8 560.0
r Carvoxime
43.1 130.8 /Carvoxime
63.2 126.93
r Carvoxime
CERIUM ACETATE, BUTYRATE, FORMATE, etc.
SOLUBILITY IN WATER.
(Wolff Z. anorg. Chem. 45, 102, '05.)
Grams Anhydrous Salt per 100 Gms. Solution at:
Salt.
Acetate
Butyrate
Iso Butyrate
Formate
Propionate
Formula.
Ce(C 2 H 3 2 ) 3 .iiH 2
Ce(C 4 H 7 2 ) 3 , and 3 H 2
Ce(C 4 H 7 2 ) 3 . 3 H 2
Ce(CH0 2 ) 8
Ce(C 3 H 5 2 ) 3 .H 2 0, and 3 H 2 O
3-544
15-
19.61
3.406
6.603(20.4)
0.398(13)
18.99
76.
12.97
1.984
3-39
o.374(75-3 )
15-93
CERIUM AMMONIUM NITRATE (Ceri) Ce(NO 3 ) 4 . 2 NH 4 NO 3 .
SOLUBILITY IN WATER.
(Wolff.)
t e .
Gms. per 100 Gms.
Solution.
Atomic
Relation.
Gms. Ce(N0 3 )4-2NH 4 N0 3
per 100 Gms.
25
4
NHU.
.065
15
Ce.
16
NH*
2.08
: Ce.
I
Solution.
Water.
140.9
35-2
4
273
16
10
2
.06
I
61.79
161 .7
45-3
4
.489
16
6 9
2
.08
I
64.51
174.9
64-5
4
.625
(IS
40 Ce
03 Ce
IV
2
2
.06
39
i Ce
iCe
IV
66.84
201 .6
85.6
4
.778
|x8.
Us-
i6Ce
79 Ce
IV
2
2
04
34
iCe
i Ce
IV
69.40
226.8
(22.
82 Ce
2
08
iCe
112
.117
|i6.
22 Ce
IV
2
95
iCe
IV
88.03
735-4
CERIUM AMMONIUM NITRATE 112
CERIUM AMMONIUM NITRATE (Cero) Ce(NO 3 ) 3 .2NH 4 NO 3 .4H 2 O.
SOLUBILITY IN WATER.
(Wolff.)
Gms. per 100 Gms.
to Solution.
Atomic Relation.
per 100 Gms.
NH4.
Ce. "
NH4
Solution.
Water.'
8
75
4
.787
18
56
I
999
I
70
.2
235-5
25
o
5
.09
19
.80
I
995
I
74
.8
296.8
45
o
5
53
21
.06
2
037
I
80
4
410-2
60
6
.01
22
77
2
054
I
87
.2
681.2
65
06
6
.11
23
.42
2
.022
I
89
.1
817.4
CERIUM AMMONIUM SULPHATE Ce 2 (SO 4 ) 3 .(NH 4 ) 2 SO 4 .8H 2 O.
SOLUBILITY IN WATER.
(Wolff.)
t. c
Gms.
per 100 G
I4) 2 SO 4 Solid
ms - Phase.
Gms.
. Ce 2 (S0 4 ) 3 .(NH 4 ) 2 S0 4
1 per 100 Gms.
Solid
Phase.
Solution.
Water".
Solution.
Water.
22.3
5
.06
5
33 -8H 2
45
.0
2
-91
2
99
Anhydride
35 - 1
4
93
5
.18
55
25
2
.16
2
.21
ii
45-2
4
.76
4
99
75
4
I
.46
j
, 4 8
11
85
.2
I
17
j
.18
"
CERIUM SULPHATE Ce 2 (SO 4 ) 3 .
SOLUBILITY OP THE SEVERAL HYDRATES IN WATER.
(Koppel Z. anorg. Chem. 41, 377, '04; the previous determinations by Muthman and Rolig Z.
anorg. Chem. 16, 455, '98, and by Wyrouboff Bull. soc. chim. [3] 25, 121, '01, are shown by Koppel
to be inaccurate.)
Gms.
Solution.
o
14.20
0-525
18.8
14.91
o-555
19.2
15.04
0.561
o
17 .35
0.665
IS
10.61
0-376
21
8.863
0.308
3 1.6
6.686
0.227
45-6
4.910
0.164
5
4-465
0.148
60
3-73
0.123
65
3-47
0.114
o
*5-95
0.605
15
9-95
o-35o
Solid Phase.
Ce 2 (SO 4 ) 3 .i2H 2 O
Ce 2 (SO 4 ) 3 .gH 2 O
Ce 2 (S0 4 ) 3 .8H 2
Gms.
Mols
Gms.
wo
Solution.
2 '
20.5
8.69
0.302
40
5-6I3
0.188
60
3 .88
0.129
45
8.II6
0.280
60
3-145
0-103
80
I.I9
0.0382
100.5
0.46
0.0149
35
7-8
0.27
40
5-7i
0.19
5
3-3i
O.II
65
1-85
0.06
82
0.98
0.032
100.5
0.42
0.014
Solid Phase.
Ce 2 (S0 4 ) 3 .8H 2
Ce 2 (S0 4 ) 3 . 5 H20
Ce 2 (S0 4 ) 3 . 4 H 2 O
H3 CHLORAL HYDRATE
CHLORAL HYDRATE C 2 HC1 3 O.H 2 O.
SOLUBILITY IN WATER, ETHYL ALCOHOL, CHLOROFORM, AND IN
TOLUENE.
(Speyers Am. J. Sci. [4] I4t 294, '02.)
Calculated from the original results, which are given in terms of
gram molecules of chloral hydrate per 100 gram mols. of solvent.
In Water.
In Alcohol.
In Chloroform.
In Toluene.
W. S.
'W. S. '
W. S.
w. s:
o 1.433 l8 9-7
I. 11 123.3 I
530 3-7
0.898 3.2
5 1.460 233.0
1.16 130.0 i
5*5 4-o
0.900 4-O
10 1-485 275.0
.23 140.0 i
.510 5.0
0.910 7.0
15 1.510 330.0
.30 160.0 i
.505 9.0
0.915 ii. o
20 1-535 383.0
.36 185.0 i
.510 19.0
0-94 21.0
25 1-555 433-o
.42 215.0 i
.520 34.0
o-97 3 6 -
30 1.580 480.0
49 245.0 i
.540 56.0
i. 02 56.0
35 1.59 516.0
.55 280.0 i
.570 80.0
1.13 80.0
40 i . 605
i. 60 320.0 i
.590 no.o
1.40 no.o
45 i .620
...
W = wt. of i cc
. saturated solution
, S = Gms. C 2
HC1 3 .H 2 O per 100
grams solvent.
CHLORINE Cl.
SOLUBILITY IN
WATER.
(Winkler Landolt and Bernstein's Tabellen, sd ed. p.
532, 60 1, '06; Roozeboom Rec. trav. chlm,
3*
59, '84; 4, 69, '85; Z. physik.
Chem. 2, 452, '88.)
to or
n *
Gms. Cl per
Solid
P
q. c .
loo Gms. H 2 O.
Phase.
o 4.610
1.46 O.24
0.492
Ice+C1.8aq.
3 3-947
1.25 o
0.507-0.560
C1.8 aq.
6 3.411
1. 08 2
0.644
it
9 3-031
0.96 4
0.732
9.6 2 . 980
0.94 6
0-823
12. O 2.778
0.88 8
0.917
10 3.095
0.997 9
o . 965-0 . 908
K
15 2 - 6 35
0.849 20
i.8 S
it
2O 2.26o
0.729 28.7
3-69
25 -985
0.641
30 .769
0.572
40 .414
0-459
50 .204
o-393
60 . 006
0.329
70 0.848
0.279
80 0.672
0.223
90 0.380
0.127
IOO O-OOO
0-000
p' = vol. of Cl (red. to o and 760 mm.) absorbed by i vol. H 2 O at
total pressure of 760 mm.
q = Gms. Cl per 100 gms. H 2 O at a total pressure of 760 mm.
CHLORINE 114
SOLUBILITY IN WATER.
(Goodwin Ber. 15, 3039, '82.)
The saturated aqueous solution of the chlorine was cooled until
chlorhydrate separated; the temperature was then gradually raised
and portions withdrawn for analysis at intervals. Slightly different
results were obtained for solutions in contact with much, little, or no
chlorhydrate. The following results are taken from an average
curve.
.o Solubility f0 Solubility + Solubility
Coefficient. Coefficient. Coefficient.
2-5 1.76 II 3-0 25 2.06
5.0 2.00 12.5 2.75 30 1.8
7.5 2.25 15 2.6 40 1.35
10 2.7 20 2.3 50 i.o
SOLUBILITY OF CHLORINE IN AQUEOUS SOLUTIONS OF HYDROCHLORIC
ACID AND OF POTASSIUM CHLORIDE.
(Goodwin.)
Coefficient of Solubility in:
t.
HC1
HC1
HCl
KCl
(1.046 Sp. Gr.).
(1.08 Sp. Gr.).
(1.125 Sp. Gr.).
(20 g. per loo cc.).
4-1
6. 4
7-3
1.5
5
5- 1
5-2
6.7
2.0
10
4.1
4-5
6.1
2.2
15
3-5
3-9
5-5
1.6
20
3-o
3-4
4-7
1.2
25
2-5
3-o
4.0
1.0
30
2.0
2.4
0-9
40
1.25
1.6
Goodwin also gives results for solutions of NaCl, CaCl 2 , MgCl 2 , SrCl 2 ,
Fe 2 Cl 2 , CoCl 2 , NiCl 2 , MnCl 2 , CdCl 2 , LiCl, and in mixtures of some of
these, but the concentrations of the salt solutions are not stated.
SOLUBILITY OF CHLORINE IN AQUEOUS SOLUTIONS OF SODIUM
CHLORIDE.
(Kumpf Wied. Ann. Beibl. 6, 276, '82; Kohn and O'Brien J. Soc. Chem. Ind. 17, 100, '08.)
Coefficient of Solubility in:
b
9-97% NaCl.
i6.oi%NaCl.
19.66% NaCl.
26.39% *
2-3
I. 9
J -7
o-5
5
2.0
1.6
1.4
0.44
10
i-7
i-3
I-IS
0.4
i5
1.4
i. 06
o-95
0.36
20
1.2
0.9
0.8
0-34
2 5
0-94
o-75
0.65
o-3
50
0.2
80
. . .
. . .
0.05
TOO cc. of 6.2 per cent CaCl 2 solution dissolve 0.245 gram Cl at 12.
100 cc. of 6.2 per cent MgCl 2 solution dissolve 0.233 gram Cl at 12.
100 cc. of 6.2 per cent MnCl 2 solution dissolve 0.200 gram Cl at 12.
For coefficient of solubility see page 105.
ii5 CHLORINE MONOXIDE
CHLORINE MONOXIDE C1 2 O.
100 volumes of water at o absorb 200 volumes of C1 2 O gas.
CHLORINE TRIOXIDE C1 2 O 3 .
SOLUBILITY IN WATER AT APPROX. 760 MM. PRESSURE.
(Brandan Liebig's Ann. 151, 340, "69.)
t. 8.5. 14.0. 21. 93.
Gms. C1 2 O 3 per ioo gms. H 2 O 4-7 6 5 5 -012 5-445 5-651
Garzarolli and Thurnbalk Liebig's Ann. 209, 184, '81, say that
C1 2 O 3 does not exist, and above figures are for mixtures of C1 2 O and Cl.
CHLOROFORM CHC1 3 .
SOLUBILITY IN WATER.
(Chancel and Parmentier Compt. rend, ioo, 473, 85; Rex Z. physik. Chem. 55, 355, '06.)
. o Gms. CHCla per
ioo Gms. H 2 fcex).
o 1.062
10 0.895
2O O.822
3 0.776
ioo cc. H 2 O dissolve 0.42 cc. CHC1 3 at 22; Vol. of sol. = 100.39 cc -
Sp. Gr. = 1.0002.
ioo cc. CHC1 3 dissolve 0.152 cc. H 2 O at 22; Vol. of sol. = 99.62 cc.,
Sp. Gr. = 1.4831.
(Herz Ber. 31, 2670, '98.)
t.
Gms. CHC1 3 per
Liter of Solution.
Density
of Solutions.
o
9.87
1.00378
3-2
8.90
17.4
7.12
I .00284
29.4
7-05
1.00280
41.6
7.12
I .00284
54-9
7-75
1.00309
SOLUBILITY OF CHLOROFORM IN AQUEOUS ETHYL ALCOHOL, METHYL
ALCOHOL, AND ACETONE MIXTURES AT 20.
(Bancroft Phys. Rev. 3, 29, '95, '96.)
:n Ethyl
Alcohol.
In Methyl Alcohol.
In Acetone.
Per 5 cc.
C 2 H 5 OH.
Per 5 cc.
CH 3 OH.
Per 5 cc.
(CH 3 ) 2 CO
cc. H 2 0.
cc. CHC1 3 .
cc. H 2 O.
cc. CHC1 3 '.
cc. H 2 O.
cc. CHC1 3 .
10
O.2O
10
O-IO
5-o
0.16
8
o-3
5
0.48
4-0
0-22
6
0-515
4
0.8o
3-o
o-33
4
1-13
2
4-0
2 -O
0.58
2
2.51
1.49
7-0
I -O
o-955
I
4.60
i-35
8.0
o-79
I .12
0.91
5-o
I .12
IO.O
0-505
I. 60
0.76
6.0
0.30
2.50
o-55
8.0
O-2I
3-50
0.425
IO -O
0.19
4-0
0.2O
20. o
0.16
5-o
0.125
30.24
0.12
IO.O
CHROMIUM ALUMS 116
SOLUBILITY OF CHROMIUM ALUMS IN WATER AT 25.
(Locke Am. Ch. J. 26, 174, 'ox.)
Per IPO cc. Water.
Alum Formula. ' Grams Grams Gram '
Anhdyrous. Hydrated. Mols.
Potassium Chromium Alum KjCr^SO^^HjO 12.51 24.39 0.0441
Tellurium Chromium Alum TejCr^SO^^HjO 10.41 16.38 0.0212
CHROMIUM CHLORIDE (ic) CrCl 3 .6|H 2 O.
100 grains H 2 O dissolve 130 grams (green modification) at 15.
(Recoura Compt. rend. 102, 518, '86.)
CHROMIUM DOUBLE SALTS.
SOLUBILITY IN WATER.
(Jorgensen J. pr. Chem. [2] 20, 105, '79; [2] 30, i, '84; [2] 42, 208, '90; Struve Ibid. [2] 61, 457,
'990
Gms. per
Name of Salt. Formula. t . 100 Gms.
H 2 0.
Chloro Tetra Amine Chromium
Chloride CrCl(NH 3 ) 4 (OH 2 )Cl 2 15 6.3
Chloro Purpureo Chromium Chloride CrCl(NH 3 ) 5 Cl 2 16 0.65
Luteo Chromium Nitrate Cr(NH 3 ) 6 (NO 3 ) 3 . ? 2.6
Chloro Purpureo Chromium Nitrate CrCl(NH 3 ) 6 (NO 3 ) 2 17.5 1.4
Chromic Potassium Molybdate 3K 2 O.Cr 2 O 3 .i2MoO 3 .2oH 2 O 17 2.5
CHROMIUM TRIOXIDE CrO 3 .
SOLUBILITY IN WATER.
(Mylius and Funk Wiss. Abh. p. t. Reichanstalt, 3, 451, 'oo.)
li
Gms. CrO 3 per 100
g. Solution.
Mols. CrO 3 per
100 Mols. H 2 O.
Solid Phase.
62.08
29.4
CrO a
62.38
29.8
(t
62.45
29.91
"
64.55
32-7
u
50
99 67.39 37 - 1
Density of solution saturated at 18 = 1.705.
CHROMIUM SULPHATES (ous and ic).
SOLUBILITY IN WATER (ous at o).
Salt. G ^ 5 ' Pfjf ^ Solid Phase. Authority.
Lrins. Jri2vJ.
ChromOUS 12 .35 CrSO 4 .7H 2 O (Moissan Bull. soc. chim. [2] 37, 296, '82)
Chromic 1 2O . O Cr 2 (SOJ 3 . l8H 2 O (Etard Compt. rend. 84, 1090, '77.)
CHRYSAROBIN C 30 H 26 O 7 .
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.)
Solvent Gms. per 100 Gms. Solvent at; Solvent Gms. per 100 Gms.
Water 0.021 0-046 Chloroform 5.55
Alcohol 0.324, 0.363 (60) Ether 0.873
Benzene 4.0 ... Amyl Alcohol 3.33
Carbon Disulphide o . 43
ii7 GHRT8EN
OHRYSEN C 18 H 12 .
SOLUBILITY IN TOLUENE AND IN ABS. ALCOHOL.
(v. Becchi.)
ioo gms. toluene dissolve 0.24 gm. C 18 H, 2 at 18, and 5.39 gms. at
100.
ioo gms. abs. alcohol dissolve 0.097 gm. C 18 H 12 at 16, and 0.170 gm.
at b. pt.
CINCHONA ALKALOIDS. (See also Quinine, p. 269.)
SOLUBILITY or CINCHONLNE, CINCHONIDINE, QUININE, AND QUINIDINE
IN SEVERAL SOLVENTS AT i8-22.
(Miiller Apoth.-Ztg. 18, 233, '03; see also Prunier J. pharm. chim. [4] 29, 136, '79.)
Grams of the Alkaloid per ioo Grams Solution.
Solvent.
Cinchonine
Cinchonidine
CTJ XT /"
Quinine
C 20 H 24 N 2 0,.
Quinidine
r H M O
1 22 2
1<
pU.g^A.^gVX*
Hydrate.
Anhydride.
1^20^* 24 2^2
Ether
O.IO
.211
I
619
.876
o
.776
Ether sat. with I^O
0.123
5 2 3
5
-6l8
2
794
I
.629
H 2 O sat. with Ether
0.025
.0306
o
.0667
.0847
o
031
Benzene
0-0545
.099
o
.2054
I
.700
2
451
Chloroform
0.6979
9
.301
1 00 +
100 +
IOO +
Acetic Ether
0.0719
3003
4
65
2
.469
I
.761
Petroleum Ether
0-0335
0475
o
.0103
.0211
.0241
Carbon Tetra Chloride o .0361
.0508
o
.203
529
o
565
Water
0.0239
0255
574
.0506
o
.0202
Glycerine (15 .5)
0.50
o.
50
ioo grams chloroform dissolve 0.565 gm. cinchonine at 50.
100 grams abs. ether dissolve 0.264 gm. cinchonidine at 32.
(Kohler Z. anal. Ch. 18, 242, '79.)
SOLUBILITY or CINCHONINE AND CINCHOTINE SULPHATE, TARTRATE,
BlTARTRATE, OXALATE, AND HYDROCHLORIDE IN WATER.
(Forst and Bohringer Ber. 14, 1266, '81.)
Cinchonine Salts.
Formula.
2(C 19 H 22 N 2 0)S0 4 H 2 . 2 H 2 13
2 (C 19 H 22 N 2 O) C 4 H 6 O 6 _._2 H 2 O 1 6
v^ioiioalN o^-' *^
2 (C 19 H 02 N 2 O) .C 2 H 4 O 4 .H 2 O
C 19 H 22 N 2 O.HC1. 2 H 2 O
20
10
Gms. per
ioo Gms.
H 2 O.
Cinchotine Salts.
Formula. 1
1.52
3.0
2 (C 19 H 24 N 2 0)S0 4 H 2 .2H 2 13
2(C 19 H 24 N 2 0)C 4 H 6 6 . 2 H 2 16
C 19 H 24 N 2 O.C 4 H 6 O 6 . 4 H 2 O 1 6
0.96 2 (C, 9 H 24 N 2 O) .C 2 H 2 O 4 .H 2 O 10
4.16 C 19 H 24 N 2 O.HC1. 2 H 2 O 10
Gms. per
ioo Gms.
H 2 O.
3.28
I. 7 6
1.28
1.16
2.12
SOLUBILITY OF CINCHONINE SULPHATE AND OF CINCHONIDINE SUL-
PHATE IN SEVERAL SOLVENTS.
Solvent.
(U. S. P.)
Gms. (C 1
per ioo Gms. Solvent.
At 25.
At 80.
Water
1.72
3- 1
Alcohol
IO-O
19.2(60)
Ether
0.04
. . .
Chloroform
i-45
. . .
Glycerine
.6-7 (15)
Gms. (C,H 22 N 2 0),.H 2 S0 4 .3H 2
per ioo Gms. Solvent.
At 25.
1. 60
1-4
O-O2
O.II
At 80
(60)
CINNAMIC ACID 118
CINNAMIC ACID C 6 H 5 CH:CH.COOH.
SOLUBILITY OF CINNAMIC ACID IN AQUEOUS SOLUTIONS OF SODIUM
ACETATE, BUTYRATE, FORMATE, AND SALICYLATE AT 26.4.
(Philip J. Chem. Soc. 87, 992, '05.)
Calculated from the original results, which are given in terms of
molecular quantities per liter.
Cms. Na Salt
Gms. L
6ii 5 UH:(JH.tJUUJtl ]
>er Later in bolu
-A.
tions of:
per Liter.
CH 3 COONa.
C 3 H 7 COONa.
HCOONa.
C 6 H 4 .OH.COO1
0.56
0.56
0.56
0.56
I
1.50
I. 3
0.92
O.62
2
2.12
I.8S
I .12
0.70
3
2.52
2 .25
1.27
o-73
4
2.8 5
2.60
I .40
0.77
5
3-05
2-90
1-47
0.80
8
0.90
i liter of aqueous solution contains 0.491 gm. C 6 H 5 CH:CH.COOH
at 25 (Paul).
SOLUBILITY OF CINNAMIC ACID IN AQUEOUS SOLUTIONS OF ANILIN
AND OF PARA TOLUIDIN AT 25.
(Lowenherz Z. physik. Chem. 25, 394, '98.)
Original results in terms of molecular quantities per liter.
In Aqueous Anilin. In Aqueous p Toluidin.
Grams per Liter. Grams per Liter.
C 6 H 5 CH :CHCOOH. CeH^CHsNHa. C 6 H 5 CH : CHCOOH.
0.49 o 0.49
1 1. 2O I 1.52
2 1.65 2 2. 2O
3 2.02 3 2.83
4 2.35 4 3-35
6 2.92 5 3.80
SOLUBILITY OF CINNAMIC ACID IN METHYL, ETHYL, AND PROPYL
ALCOHOLS.
(Timofeiew Compt. rend. 112, 1137, '91.)
Grams C 6 H 5 CH:CH.COOH per 100 Grams of:
CH 3 OH. C 2 H 5 OH. C 3 H 7 OJL
o 20.65 15-61 10.63
19.5 28.91 22.03 I S-4 I
SOLUBILITY OF BROM CINNAMIC ACIDS.
a Brom and ft Brom Cinnamic Acid a Brom Cinnamic Acid in Aq.
in Water at 25. Solutions of Oxalic Acid at 25.
(Paul Z. physik. Chem. 14, in, '94.) (Noyes Z. physik. Chem. 6, 245, '90.)
Per loop cc. Solution. Normality^ of Solutions. Grams per Liter.
Aci d- Grams. Millimols. ' (COOH) 2 . C 6 H 5 CH: (COOH) 2 . C 6 H 5 CH:
CBr:COOH. CBrCOOH.
a, C 6 H 5 CH: CBrCOOH 3.9325 17.32 o 0.0176 o.o 3.995
/3, C 6 H 6 CBr: CHCOOH 0.5255 2.315 0.0275 0.0140 2.448 3.178
0.0524 0.0129 4.716 2.928
H9 CITRIC ACID
CITRIC ACID C 3 H 4 (OH)(COOH) 3 .H 2 O.
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; Bourgoin Ann. chim. phys. [5] 13, 406, '78.)
Cms. C 3 H 4 (OH)(COOH) 3 .H 2 per TOO Cms.
solvent . t . ,.
Solution. Solvent.
Water 25 64.8 185
Water b. pt. 70.3 250
Alcohol (90%) 25 34.6 75.9
Alcohol (U.S.P.) 39.2 64.5
Alcohol (Abs.) " 43.2 52.8
Ether " 2.21 2.26
Ether (U.S.P.) 5.2 5.55
COBALT BROMIDE CoBr 2 .
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 537, '94.)
t. 59. 75.
Gms. CoBr 2 per 100 gms. solution 66.7 66.8
COBALT DOUBLE SALTS.
SOLUBILITY IN WATER.
(Jorgensen J.pr. Chem. [2] 18, 205, '78; 19, 49, '79; Kurnakoff J. russ. phys.
'92.)
Name. Formula.
Chloro purpureo cobaltic bromide CoCl(NH 3 ) 5 Br 2
Bromo purpureo cobaltic bromide CoBr(NH 3 ) 5 Br.,
Chloro tetra amine cobaltic chloride CoCl(NH 3 ) 4 (OH 8 )Cl 9
97.
68.1 (blue)
chem. Ges. 24, 629,
Gms. Salt
t. per 100
Gms. H 2 O.
14.3 0.467
16 0.19
2.50
Chloro purpureo cobaltic
chloride
CoCl(NH 3 ) 5 Cl 2
0.232
Chloro purpureo cobaltic
chloride
CoCl(NH 3 ) 5 Cl 2
15
5
o
.41
Chloro purpureo cobaltic
chloride
CoCl(NH 8 ) 6 CI 2
46
6
I
03
Luteo cobaltic chloride
Co(NH 3 ) 6 Cl 3
o
4
.26
Luteo cobaltic chloride
Co(NH 3 ) 6 Cl 3
46
.6
12
74
Roseo cobaltic chloride
Co(NH 3 ) 5 (OH 2 )Cl 3
o
16
.12
Roseo cobaltic chloride
Co(NH 3 ) 5 (OH 2 )Cl 3
16
.2
24
.87
Chloro purpureo cobaltic
Chloro purpureo cobaltic
iodide
nitrate
CoCl(NH 3 ) 5 I 2
CoCl(NH 3 ) 5 (N0 3 ) 2
J 9
15
.2
2
I
O
25
Chloro purpureo cobaltic
sulphate
CoCl(NH 3 ) 5 SO 4 . 2 H 2 O
17
3
75
Nitrato purpureo cobaltic nitrate
Co(N0 3 )(NH 3 )(N0 3 ) 2
16
36
COBALT CHLORATE Co(ClO 3 ) 2 .
SOLUBILITY IN WATER.
(Meusser Ber. 35, 1419, '02.)
Gms. Mols.
t o Co(ClO 3 ) 2 Co(ClO 3 ) 2 Solid
per too Gms. per 100 Phase.
Gms.
t o Co(C10 3 ) 2
' per loo Gms
Mols.
Co(C10 3 ) 2 Solid
per loo Phase.
Solution.
Mols. H 2 0.
Solution.
Mols.
H 2 0.
12
29
97
o
.41
Ice
18
6 4
.19
14.
28
Co(C10 3 ) 2 . 4 H 2 0.
21
53
3
9
.08
Co(ClO 3 ) 2 .6H 2
. 21
64
39
14-
5 1
"
19
53
.61
9
.20
"
35
6 7 ,
09
16.
10
"
O
57
45
10
75
"
47
6 9 ,
66
18.
29
"
10.5
61
12
.90
44
61
7 6
.12
25-
39
44
Density
of solution saturated at
18 =
I.86I.
COBALT CHLORIDE 120
COBALT CHLORIDE CoCl 2 .
SOLUBILITY IN WATER.
(Etard Compt. rend. 113, 699, '91; Ann. chim. phys. [7] 2, 537, '94.)
Gms. Gms.
. CoCl 2 per Solid f0 CoCl 2 per Solid
* ' 100 Gms. Phase. 100 Gms. Phase.
Solution. Solution.
-io 27.0 CoCl2.6H 2 O (red) 35 38.0 CoCl 2 .H 2 O (violet)
o 29.5 40 41.0
H-io 31.5 50 47-o
20 33-5 60 47.5 CoCl 2 .H 2 (blue)
25 34-5 8o 49-5
30 35-5 I0 5!-
SOLUBILITY OP COBALT AMMONIUM CHLORIDES IN WATER.
(Kurnakoff J. russ. phys. chem. Ges. 24, 629, '93; J, Chem. Soc. 64, ii, 509, '93.)
. Grams per 100 Grams H2O at:
o^ 16.9. 46.6'.
CoCl 3 .5NH 3 0.232 ... 1.031
CoCl^NHg-EL/) 16.12 24.87 ...
CoCl 3 .6NH 3 4.26 ... 12.74
SOLUBILITY OF COBALT CHLORIDE IN AQUEOUS HYDROCHLORIC
ACID SOLUTIONS AT o.
(Engel Ann. chim. phys. [6] 7, 355, '89.)
Milligram Mols.
per io cc. Sol. fp.J3r.rf
Gms
. per 100 Gms.
Solution.
Gms. per 100 cc.
Solution.
&CoCl 2 . HCl.
CoCl 2 .
HCl.
CoCl 2 .
HCl.
62
-4
343
30
i7
O
.00
40-5
58
52
3
7
-328
28
.62
.102
38.0
135
50
.8
ii
45
.299
25
39
.321
33-o
.417
37
25
25
.2
.248
19
43
.738
24.2
.919
12
O
.167
7-15
I
.718
8-34
2
.00
4
75
74
75
.150
2
.68
2
369
3-o8
2
72
12
.0
104
5
.229
6
34
3
.099
7-79
3
.81
25
.0
139
o
323
12
27
3
.829
16.24
5
.07
SOLUBILITY OF COBALT CHLORIDE IN AQUEOUS ALCOHOL
AT 11.5.
(Bodtker Z. physik. Chem. 22, 509, '97.)
io gms. of CoCl 2 .6H 2 O were added to 20 cc. of alcohol and in addition
the amounts of CoCl 2 shown in the second column. The solutions were
shaken 2 hours, 5 cc. withdrawn, and the amount of dissolved CoCl 2
determined by evaporation and weighing.
Vol. % Gms. CoCl 2 Gms. per 5 cc. Solution. Vol. % Gms. CoCl 2 Gms. per 5 cc. Sol.
Alcohol. Added. H 2 O. CoCl 2 . Alcohol. Added. H 2 O. CoCl 2 .
91.3 o.o 1.325 1.168 99.3 0.612 0.764 1-459
98.3 o.o 1-134 1-214 99.3 0.813 0.688 1.568
98.3 0.0 1. 068 I.lSl 99-3 1-022 0.634 L7I3
99.3 o.o 1.045 I - I 99 99-3 I - 2 4Q 0.553 i 831
99.3 0.194 0.899 1.204 99-3 I-446 0.483 1.943
99.3 0.400 0.829 1.325 99.3 1-650 0.500 2.183
100 gms. sat. solution in alcohol (0.792 Sp. Gr.) contain 23.66 gms.
CoCl a , Sp. Gr. = I.OI07. (Winkler J.pr.Chem.pi, 207, '6 4 J
121
COBALT CHLORIDE
SOLUBILITY OF COBALT CHLORIDE IN ORGANIC SOLVENTS.
Gms. per 100 Gms. Solvent.
Solvent. t.
Acetone o
" 22.5
25
18
Ethyl Acetate 14
79
Ether
Glycol
COBALT IODATE Co(IO 3 ) 2 .
SOLUBILITY IN WATER.
(Meusser Ber. 34, 2435, '01.)
Solid Phase :
t. Co(I0 3 >.4H 2 0. Co(I0 3 ) 2 .2H 2 0.
CoCl 2 .
9-II
9.28
8.62
2-75
0.08
0.26
0.021
CoCl 2 . 2 H 2 o7 Authority.
17.16 (St. von Laszczynski Ber. 27, 2285, '94.)
1 7 06 (St. von Laszczynski Ber. 27, 2285, '94.)
. . . (Krug and McElroy J. Anal. Ch. 6, 184/92.)
(Naumann Ber. 37, 4332, '04.)
... (St. von Lasczczynski.)
O . 0291 (Bodtker Z. physik. Chem. 22, 509, '97.)
10 7 (per 100 g.Sol.) (de Coninck Bull.acad.roy.Belglque, 359, 'o S J
G.
M.
O
o-54
0.028
18
0.83
0.038
30
1.03
0-046
So
i .46
0.065
60
1.86
0-084
65
2.17
0-098
Co(I0 3 ) 2 .
G.
M.
G.
M.
0.32
O.OI4
. . .
o-45
O.O2O
1.0 3
0.046
0.52
O.O23
0.89
O.O4O
0.67
0.030
0.85
0.030
0.84
1-02
per 100 gms.
0.038
0.045
solution.
o-75
0.69
75
100
G = Gms. Co(IO 3 ) 2
per 100 Mols. H 2 O.
COBALT IODIDE CoI 2 .
SOLUBILITY IN WATER.
(Etard Compt. rend. 113, 699, '91; Ann. chim. phys. [7] 2, 537, '94.)
The accuracy of these results is doubtful.
Gms. CoI 2
t. per 100 Gms. Solid Phase.
Solution.
Co(N0 3 ) 2 .
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt 3, 439, 'oo.)
Solid Phase.
Co(N0 3 ) 2 .9H 2
Co(NO 3 ) 2 .6H 2 O
Density of solution saturated at 18 = 1.575.
0-033
0.031
M = Mols. Co(IO 3 ) a
10
55-5
Lol 2 .
58.0
10
61.5
15
63-2
20
65.2
25
67
COBALT NITRATE (
(Funk -
Gms.
Mols.
t
Co(N0 3 ) 2
Co(N0 3 ) 2
per 100 Gms.
Solution.
per 100
MoIs.H 2 0.
-26
39-45
6.40
20-5
42.77
7-35
21
41-55
6.98
10
43-69
7.64
- 4
44-^5
7-99
45-66
8.26
+ 18
49-73
9.71
Gms. CoI 2
t.
per 100 Gms.
Solid Phase.
Solution.
25
67-5 <
^OlyHjC
> (olive)
30
7O.O
"
40
75-o C
(yellow)
50
79.0
It
80
80.0
no
81.0
It
Gms.
Mols.
t o Co(N0 3 ) 2
' per TOO Gms.
Co(N0 3 ;
^ Solid Phase
Solution.
MdJ.nTo.
4 1 55-96
12-5
Co(N0 3 ) 2 .6H 2
56 62.88
I6. 7
M
55 61.74
I 5 .8
Co(N0 3 ) 2 . 3 H 2
62 62.88
I6. 7
"
70 64 . 89
18.2
M
84 68.84
21.7
"
91 77.21
33-3
**
COBALT NITRATE
122
SOLUBILITY OF COBALT NITRATE IN GLYCOL.
(de Coninck Bull. acad. roy. Belgique, 359, '05.)
TOO grams saturated solution contain 80 gms. Cobalt Nitrate.
COBALT RUBIDIUM NITRITE Rb 3 Co(NO 2 ) 6 .H 2 O.
100 grams H 2 O dissolve 0.005 gram of the salt.
(Rosenbladt Ber. 19, 2531, '86.
COBALT SULPHATE CoSO 4 .7H 2 O.
SOLUBILITY IN WATER.
(Mulder; Tobler Liebig's Ann. 95, 193, '55; Koppel Wetzel Z. physik. Chem. 52, 395, '05.)
Gms. CoSO 4
t <\ per 100 Gms.
Mols. CoSO 4
per 100 t .
Gms. CoSO 4 Mols. CoSO 4
per 100 Gms. p^ IOO
Solution. Water. Mols. 1 2 U. Solution. Water. Mols. H 2 O.
o 20.35 25.55 2.958 35 31.40 45-80 5.31
5 21.90 28.03 3-251 4o 32-81 48.85 5.664
10 23.40 30.55 3.540 50 35-56 55-2
15 24.83 33.05 3.831 60 37.65 60.4
20 26.58 36.21 4-199 7 39-66 65.7
25 28.24 39.37 4.560 80 41.18 70.0
30 29.70 42.26 4-903 I0 45-35 83.0
SOLUBILITY OF MIXTURES OF CoSO 4 .7H 2 O AND Na 2 SO 4 .ioH 2 O
IN WATER.
(Koppel; Wetzel.)
Gms. per Gms. per Mols. per
t. 100 Gms. Solution. 100 Gms. H 2 O. 100 Mols. H 2 O. Solid Phase.
CoS0 4 .
N a2 S0 4 .
'CoSO 4 .
Na 2 SO 4 .
CoSO 4 .
Na 2 S0 4 .'
O
5
16.56
17.46
h
9
63
59
21
23
85
94
10.07
2
2
54
77
I
I
27
.67
CoSO 4 .7H 2 O -f
Na 2 SO 4 .ioH 2 O
10
17.90
ii
73
25
.41
16.67
2
94
2
.11
.
20
17-59
16
43
26
65
24.91
3
.09
3
.15
CoNa 2 (SO 4 ) 2 . 4 H 2 O
25
17.06
15
7
25
36
23-32
2
95
2
97
"
30
15-94
14
93
23
.15
21 .6l
2
7o
2
74
"
35
15-73
14
5 2
22
54
20.85
2
.62
2
.64
"
40
14.87
14
22
2O
.98
20.05
2
.46
2
53
"
18.5
18.75
I 5
,61
28
.61
23.82
3
32
3
.02
CoNa 2 (S0 4 ) 2 . 4 H 2 O
20
19.30
15
10
29
.42
23.01
3
.41
2
.92
+ CoS0 4 . 7 H 2 O
2 5
20.30
13
.60
30
74
20-58
3
56
2
.61
"
30
21.67
12
05
32
.70
18.17
3
79
2
30
M
35
22 .76
IO
43
34
.06
15.61
3
95
I
.98
"
40
24.05
9
.16
35
.01
I3-72
4
.8!
I
74
"
18.5
16.87
16
97
25
.50
2
.96
3
25
CoNa 2 (S0 4 ) 2 . 4 H 2
20
15.41
18
.12
23
.18
27 .26
2
.69
3
45
+Na 2 SO 4 .ioH 2 O
25
10.63
23
.26
16
07
35-17
I
.86
4
.46
30
6.01
28
.67
9
.20
43-74
I
.07
5
54
35
4-56
32
.14
7
.19
50-79
835
6
44
CoNa 2 (S0 4 ) 2 . 4 H 2
40
4-72
.78
7
45
50.10
o
.864
6
34
-f- Na 2 SO 4
I2 3
COBALT SULPHATE
SOLUBILITY OF COBALT SULPHATE IN METHYL AND ETHYL ALCOHOL
AND IN GLYCOL.
Solvent.
Cms. per 100 Gms.
Solvent.
Observer.
Methyl Alcohol (abs.)
CoSO 4 .7H 2 O.
42 . 8 (de Bruyn Z. physik. Ch. 10, 784, '92.)
50.9
54-5
13-3
1.8
CoS0 4 .
3 .
15 ...
18 1.04
(93-5%) 3
(5o%) 3 ...
Ethyl Alcohol (abs.) 3 ... 2.5
GI y CQl -(periOOgmS. (deConinck-Bull.acad.
solution) 3 . i 359, '05.)
COCAINE C 17 H 21 N0 4 .
COCAINE HYDROCHLORIDE C 17 H 21 NO 4 .HC1.
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; at i8-22; Muller Apoth.-Ztg. 18, 248, '03.)
Gms. per 100 Gms. Solvent.
roy.Belgique,
Gms.
C 17 H 21 N0 4 . C l7 H 21 N0 4 .HCi:
per 100 Gms.
Solvent.
Water
2 5
0.17
250
Ether+H 2 O
18-22
34-o
Water
80
0.38
IOOO
H 2 + Ether
18-22
0.254
Alcohol
25
20. o
38
Benzene
1 8-2 2
100
Ether (U.S.P.)
25
26.3
CC1 4
J 7
18.5
Ether
18-22
ii. 6
. . .
Acetic Ether
18-22
58-99
Chloroform
18-22
IOO +
Petroleum Ether 1 8-2 2
2-37
CODEINE C 18 H 21 NO 3 .H 2 O, also the Phosphate and Sulphate.
COLCHICINE C 22 H 25 NO 6 .
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; at i8-22 , Muller.)
Grams, per 100 Grams Solvent.
Solvent.
Water
Water
Water
Alcohol
Alcohol
Ether
Ether
Ether sat. with H 2 O
H 2 O sat. with Ether
Benzene
Benzene
Chloroform
Carbon Tetra Chloride 17
Acetic Ether
Petroleum Ether
t .
r ~
Codeine
Codeine
~**
(
-isH2iNO3 H 2 O.
HaPO 4 .2 Aq.
H 2 S0 4 . 5 Aq.
C 22 H 25 NO 6 .
1 8-2 2
9.616
25
I-I3
44-9
3-3
4-5
80
1.70
217.0
16.0
5-o
25
62.5
0-383
o 096
60
108.7
1.03
0.27
25
8.0
0.075
0.64
18-22
. . .
0.126
1 8-2 2
. . .
. . .
. . .
0.18
1 8-2 2
12.05
18-22
o-939
25
i-iS
25
151 .5
0.015
100 +
17
1.328
O-I2I
18-22
.
1-342
1 8-2 2
0-058
COLLIDINE 124
COLLIDINE (2, 4, 6, Tri Methyl Pyridine) C 6 H 2 N(CH 3 ) 3 .
SOLUBILITY IN WATER.
(Rothmund Z. physik. Chem. 26, 433, '98.)
Gms. Collidin per 100 Gms. Gms. Collidin per 100 Gms.
Aq. Layer. Collidin Layer. Aq. Layer. Collidin Layer.
5.7 (crit. t.) 17.20
10 7.82 41.66 80 1.73 86.12
20 3.42 54-92 loo 1.78 88.07
30 2.51 62.80 I2O 1.82 88.98
40 1.93 70-03 140 2.19 89.10
60 1.76 80.19 160 2.93 87.2
180 3.67
COPPER ACETATE Cu(C 2 H 3 O 2 ) 2 .H 2 O.
loo grams of glycerine dissolve 10 grams of copper a.cetate at 15.5.
COPPER BROMIDE (ous) Cu 2 Br 2 .
SOLUBILITY OF CUPROUS BROMIDE IN AQUEOUS SOLUTIONS OF POTAS-
SIUM BROMIDE AT i8-2o.
(Bodlander and Storbeck Z. anorg. Chem. 31, 460, '02.)
Millimols per Liter. Grams, per Liter.
KBr.
Total Cu.
Total Br. Cu (ic).
Cu (ous).
KBr.
Total Cu.
Cu (ic).
Cu (ous).
O
0.3157
0.4320 o.
2096
.1061
0.0201
.0133
0.0067
2 5
O.II9
0.
012
.107
2
.98
0.0076
.0007
O.OO68
40
O.2OO
0.
013
.187
4
.76
0.0127
.0007
O.OII9
60
0.310
0.
025
.285
7
0.0197
.0015
O.OlSl
80
0.423
0.
012
.411
9
.53
0.0266
.0007
0.026l
IOO
0.584
... .
.584
ii
.91
0.0371
0.0371
120
0.693
...
.693
14
.29
O.O44I
0.0441
500
8.719
...
8
.719
59
55
0.5540
0.5540
COPPER CHLORATE (ic) Cu(ClO 3 ) 2 . 4 H 2 O.
SOLUBILITY IN WATER.
(Meusser Ber. 35, 1420, '02.)
Gms.
Mols.
Gms.
Mols,
t o Cu(ClO 3 ) 2 Cu(ClO 3 ) 2 Solid
per loo Gms. per 100 Mols. Phase.
Solution. H 2 O.
t
Cu(ClO 3 ) 2 Cu(ClO 3 ) 2 Solid
per loo Gms. per loo Mols. Phase.
Solution. H 2 O.
12
30-53
3-43
Ice
18
62.17
12
.84
Cu(C10 3 ) 2 . 4 H 2
31
54-59
9-39
Cu(ClO 3 ) 2 .4H 2 O
45
66.17
15
.28
"
21
57-12
10.41
"
59-6
69.42
17
73
M
+ 0.8
58-51
ii .02
"
76.9
2 5
57
.
Density of
solution
saturated at
18 =
1.695.
COPPER CHLORIDE (ic) CuCl 2 .
SOLUBILITY IN WATER.
(Reicher and Deventer Z. physik. Chem. 5, 560, '90; see also Etard Ann. chim. phys. [7] 2, 528, '94.)
Gms. CuCl 2 Gms. CuCl 2 Gms. CuCl 2
t. per loo Gms. t. per 100 Gms. t. per 100 Gms.
Solution. Solution. Solution.
o 41.4 25 44.0 50 46.65
10 42.45 30 44-55 60 47-7
20 43.5 40 45.6 80 49.8
loo 51.9
Density of solution saturated at o = 1.511, at 17.5 = 1.579.
COPPER CHLORIDE
SOLUBILITY OF CUPRIC CHLORIDE IN AQUEOUS SOLUTIONS OF HYDRO-
CHLORIC ACID AT o.
(Engel Ann. chim. phys. [6] 17, 351, '89.)
Milligram Mols. per 10 cc. Sol. Sp Gr. of Gms. per 100 cc. Sol. Gms. per 100 Gms. Sol.
fcCuCl 2 . HCI. Solutions.
CuCl 2 .
HCI.
CuCl 2 .
HCI."
91
75
o
49
61
.70
O-O
41
41
o
86
.8
4
5
475
58
37
I .64
39
58
I
ii
83
.2
7
.8
458
55
95
2.84
38
37
I
95
79
35
10
5
435
53
37
3 -83
37
19
2
.67
68
4
20
25
389
46
.01
7-38
33
.11
5
3i
5
o
37
5
319
33
.62
13 .67
25
5
10
37
22
.8
70
25
.231
15
33
25.61
12
.46
20
.80
23
5
IO2
5
.288
IS
.81
37 -36
12
27
29
.00
26
7
128
.0 1.323
17
.96
46.66
I 3
57
35
.26
29
o
Sat. HCI
SOLUBILITY OF CUPROUS CHLORIDE IN AQUEOUS SOLUTIONS OF HYDRO-
CHLORIC ACID.
(Engel Ibid, [6] 17, 372, '89; Compt. rend. 121, 529, '95.)
illigram Mols. per 10 cc. Sol. g D Q r> o { Gn
is. per 100 cc. Sol.
Gms. per 100 Gms. So
iCu 2 Cl 2 .
HCI. Solutions.
Cu 2 Cl 2 .
HCI:
C U2 C1 2 .
HCI
Results at
0.
o-475
8
975 1-05
o
.471
327
O
.448
.312
I .5
17
5
.049
I
.486
.638
I
.418
.608
2.9
26
o
.065
2
.872
.948
2
.697
932
4-5
34
5
.080
4
457
I
257
4
.127
I
.164
8-25
47
.8
135
8
.172
I
743
7
.199
I
535
J 5-5
68
5
.261
IS
7
2
497
12
.46
I
.980
33-o
104
o
345
32
.68
3
.827
24
.30
2
845
Results at
I5-I<
).
7-4
54
.4 1.19
7
33
i
983
6
159
I
.666
10.8
68
.9 1.27
10
.69
2
5"
8
.422
I
977
12.8
75
.0 1.29
12
.68
2
734
9
.826
2
.119
16 o
92.0 1.38
15
.84
3
346
ii
.48
2
.424
COPPER CHLORIDE, AMMONIUM CHLORIDE MIXTURES IN AQUEOUS
SOLUTION AT 30.
(Meerburg Z. anorg. Chem. 45, 3, '05.)
Grams per 100
Gms. Sat. Solution.
CuCl 2 .
O
1.9
3-6
10.5
NH4C1.
29-5
28.6
25-9
I6. 5
19.9
9.4
29.4
4.9
41.4
2 I
43-2
2 .O
43-9
Grams per 100
Gms. Solid Phase.
CuCl 2 .
6.0
37-o
21.7
28.5
35-i
43 i
5* -9
NH^Cl.
48-2
34-9
23.1
18.4
Solid Phase
NH4C1 + CuCl 2 2NH4C1.2H2O
CuCl 2 .2NH4C1.2H 2 O
13 3
6 . 6 CuCl 2 .2NH 4 C1.2H 2 + CuCl 2 .2H 2 O
CuCl 2 . 2 H 2
COPPER AMMONIUM 126
CHLORIDE
COPPER AMMONIUM CHLORIDE CuCl 2 .2NH 4 C1.2H a O.
SOLUBILITY IN WATER.
(Meerburg.)
Gms.
. e CuCl 2 .2NH 4 Cl Solid
r ' per 100 Gms. Phase,
Gms.
t o CuCl 2 . 2 NH 4 Cl Solid
per 100 Gms. Phase.
Solution.
Solution.
-10.5
3-87
Ice
30
27.70
CuCl 2 .2NH 4 Cl.
2 H 2 O
-10.8
20.12
Ice
40
3-47
a
II
20.3
Ice + CuCl 2 .2NH 4 C1.2H 2 O
5
33-24
u
10
20.46
CuCl 2 .2NH 4 Cl. 2 H 2
60
36.13
11
o
12
22.02
24.26
!!
39-35
43.36
u
tt
20
25-95
a
SOLUBILITY OF CUPROUS CHLORIDE IN AQUEOUS SOLUTIONS OF CUPRIC
SULPHATE AT ABOUT 20.
(Bodlander and Storbeck Z. anorg. Chem. 31, 22, '02.)
Millimols per Liter.
Grams per Liter.
CuS0 4 .
Total Cu.
Total Cl.
Cu(ic).
Cu(ous).
CuS0 4 .
Total Cu.
Total Cl.
Cu(ic).
Cu(ous).
2.
880
5-312
2.258
0.
622
0.0
0.183
0.188
0-143
0.040
0.987
3-
602
4.908
3 -145
O,
457
0.158
o. 229
0.174
O. 2OO
0.029
i-975
4-
553
4.68 7
4.131
0,
,422
0.315
0.290
0.166
0.263
0.027
2.962
5-
193
4.256
4.625
o.
509
0-473
0.330
0.151
0.292
0.032
4-937
7-
276
4.329
6.546
0.
73
0.788
0.463
o.i54
0.4l6
0.046
SOLUBILITY OF CUPROUS CHLORIDE IN AQUEOUS SOLUTIONS OF POTASSIUM
CHLORIDE AT i8-2o EXCEPT DETERMINATIONS IN 3RD, 7, STH, AND
LAST LINE, WHICH ARE AT 1 6.
(Bodlander and Storbeck.)
Millimols per Liter.
Grams per Liter.
KC1.
Total Cu.
Total Cl.
Cu(ic).
Cu(ous).
kci.
Total Cu.
Total Cl.
Cu(ic),
Cu(ous)
2.851
5-43 6
2.222
0.629
o.o
O.
181
0.193
0.
141
0.040
2.5 i-955
6.015
I.42I
0-534
0.186
0.
124
0.213
0.
090
0.034
5
1.522
7.525
I. 008
0.514
0.373
0.
097
0.267
o.
069
0.033
10
1.236
11-735
0-475
0.761
0.746
0.
079
0.416
0.
030
0.048
20
1.446
21.356
0.324
I. 122
1.492
o.
092
0-759
o.
02 1
0.071
5
2.411
not det.
0.1088 2.302
3.730
0.
J 53
not det.
0.
007
o. 146
100
4.702
a
o.ooo
4.702
7.460
o.
2 99
o.
000
0.299
2OO
9.485
tt
0.000
9.485
14.920
0.
603
(I
0.
opo
0.603
1000
97-o
n
o.ooo
97.0
74.60
6.
170
(4
o.
000
6.170
2OOO
384.0
n
0.000
384.0
149.2
24.
42
(1
0.
000
24.420
SOLUBILITY OF COPPER CHLORIDE IN AQUEOUS SOLUTIONS OF SODIUM
CHLORIDE.
(Hunt Am. J. Sci. [2] 49, 154, '70.)
Grams CuCl 2 per 100 cc. Solution of:
II
40
90
Sat. NaCl.
8-9
11.9
16. 9
15% NaCl. 5% NaCl.
3-6
6.0 i.i
10.3 2.6
127 COPPER CHLORIDE
SOLUBILITY OF COPPER CHLORIDE AND POTASSIUM CHLORIDE DOUBLE
SALTS AND MIXTURES IN WATER.
(Meyerhoffer Z. physik. Chem. 5, 102, '90.)
Cl per i Gram Solution. Mols.per iooMols.H2O.
*- 'Present as Present as' r r . JjJJ
CuCl 2 . KC1. CuCl2 ' KCL
39.4 0.120 0.107 5.56 9.93 CuCl 2 . 2 KCl. 2 H 2 + KC1
49.9 0.129 O.II5 6.39 II-4
60.4 O.I42 O.I25 7.71 I3-6
79.1 0.168 0.142 ii. i 18.8
90.5 0.188 0.154 14.9 24.4
93-7 0.194 0-156 l6.2 26.0 CuCl 2 .KCl + KCl
98.8 0.197 O.l62 17.5 28.7
O 0.214 O.O2I 9-84 1-94 CuCl 2 .2KC1.2H 2 O + CuCl 2 .aH 2 O
39.6 0.232 0.049 I2 -9 5-44
50.1 0.233 0.059 13.7 6.90
52.9 0-241 0.062 14.8 7.63
60.2 0.246 0.066 15.8 8.49 CuCl 2 .KCl + CuCI 2 .2H 2
72.6 0.255 0.063 16.8 8.35
64 . 2 ... 14.9 1 1 . 6 CuCl 2 .2KC1.2H 2 -f CuCl 2 .KCl
72.5 ... ... 14.8 15.0 CuCl 2 .KCl
SOLUBILITY OF CUPRIC CHLORIDE IN SEVERAL SOLVENTS.
(Etard Ann. chim. phys. [7] 2, 564, '94; de Bruyn Z. physik. Chem. 10, 783, '92; de Coninck
Compt.rend. 131, 59, 'oo; St. von Laszczynski Ber. 27, 2285, '94.)
Grams CuCl 2 per 100 Grams Sat. Solution at:
ouiveiu.
Methyl Alcohol
Ethyl Alcohol
0.
36
32
15.
40.5 (deB.)
35.0 (deB.)
20.
36.5
35-7
4 o. 80.
37.0 ...
39.0
Propyl Alcohol
29
30
5
30
5
Iso Propyl Alcohol
. . .
16
.0 30
.0
n Butyl Alcohol
15
15
3
16
.0 16
5
Allyl Alcohol
23
. . .
23
-0
Ethyl Formate
IO
. . .
9
.0
8
o
Ethyl Acetate
. . .
O
.0
2
5 i
3 (72)
Acetone (abs.)
8.86*
8. 9 2f
2
.88
(18) ..
i
40 (56;
Acetone (80%)
18
9*
.
Ether
0.043 ( II0 )
o.
ii
.
* (CuCl 2 .2
Aq.)
t (CuCl 2 .2 Aq.)
$ (23 CuCl 2 .2 Aq.)
For the solubility of cupric chloride in mixtures of a number of
organic solvents, see de Coninck.
COPPER CHLORIDE
128
IN AQUEOUS ALCOHOL AT 11.5.
Chem. 22, 507, '97.)
indicated amounts of CuCl 2 were
The solutions shaken two hours,
SOLUBILITY OF CUPRIC CHLORIDE
(Bodtker Z. physik.
10 gms. of CuCl 2 2H 2 O and the
added to 20 cc. portions of alcohol.
5 cc. portions withdrawn.
Vol. % Gms. CuCl 2 Gms. per 5 cc. Solution.
Alcohol. Added. H 2 O. CuCl 2 .'
89.3 o.o 0.794 1.137
92.0 o.o 0.648 1.090
96.3 o.o 0.478 1.116
99.3 o.o 0.369 i. 208
COPPER NITRATE (ic) Cu(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt, 3, 440, 'oo.)
Vol. % Gms. CuCl 2
Gms. per 5 cc. Solution.
Alcohol. Added.
H 2 O. CuCl 2 .
99-3 0.223
0.330 1.295
99.3 0.887
0.247 1.639
99.3 1-540
O.I9I 2.o86
99-3 i-957
0.164 2.400
Gms.
Mols.
t.
Cu(N0 3 ) 2
per 100 Gms.
Cu(N0 3 ) 2
per 100
Solid Phase.
Solution.
Mols. H 2
,
-23
36.08
5-42
Cu(NO 3 ) 2 .9H 2
20
40.92
6.65
"
21
39-5 2
6.27
Cu(NO 3 ) 2 .6H 2 O
O
45-00
7.87
"
+ 10
48.79
9- T 5
"
18
53-86
ii .20
u
20
26.4
25
40
60
86
ii4-5
Gms. Mols.
Cu(N0 3 ) 2 Cu(N0 3 ) 2
per 100 Gms. per 100 Solid Phase.
Solution. Mols. H 2 O.
55.58 I2.O Cu(NO 3 ) 2 .6H 2 O
I6. 7
14.4
15-2
17.2
20.0
63-39
60. 01
61 .51
64.17
67-5 1
77-59
Cu(N0 3 ) 2 . 3 H 2
33-3
Density of solution saturated at 18 = 1.681.
COPPER SULPHATE CuSO 4 .5H 2 O.
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 528, '94; Patrick and Aubert Trans. Kansas Acad. Sci. 19, '74 ; at
Z. E!ec
[5, Cohen
lectrochem. 9, 433, '03; at 25, Trevor Z. physik. Chem. 7, 470, '91.)
Gms. CuSO 4 per 100 Gms.
1 .
O
10
Solution.
12-5
14.8
Water.'
14-3
17.4
20
25
17.2
I8. S
20-7
22-7
30
40
20. o
22.5
25.0
28.5
50
25.0
33-3
i .
Solution.
Water. "
60
28-5
40.0
80
35-5
55-o
100
43-o
75-4
120
44-o
78.6
I4O
44-5
80.2
1 60
44-o
78.6
180
43-o
75-4
SOLUBILITY OP COPPER SULPHATE IN AQUEOUS SOLUTIONS OF SUL-
PHURIC ACID AT o.
(Engel Compt. rend. 104, 507, '87.)
Milligram Equiv, per 10
Gms. H 2 O.
H 2 S0 4 .
CuSO 4 .
o.o
18.6
4.14
17.9
14.6
19.6
31.0
12.4
54-2
8.06
56-25
7-75
71.8
5-o
Sp. Gr. of
Solutions.
I.I44
Grams per TOO Grams
H 2 0.
H 2 S0 4 .
o.oo
CuSO 4 .
14.85
I -143
I.I58
2.03
7 .l6
14.29
J 5-65
I .170
I-I95
I .211
15.20
26.57
27-57
9.90
6-43
6.19
1.224
35-2
3-99
i2 9 COPPER SULPHATE
SOLUBILITY OF COPPER SULPHATE IN AQUEOUS SOLUTIONS OF AMMO-
NIUM SULPHATE AT o.
(Engel Com pt. rend. 102, 114, '86.)
Milligram Equiv. per
10 cc. Solution.
Sp. Gr. of
o utions.
Grams per
loo cc. Solution.
(NH4) 2 S0 4 .
CuSO 4 .
(NH 4 ) 2 S0 4 .
CuS0 4 .
o.o
18.52
I.I44
0.0
14.79
5-45
20.15
I .190
3 .6l
16.09
7-o
10-5
I.IOS
4-63
8.38
7-4
9-1
1.099
4.90
7.26
8.45
6.425
1.0815
5-59
5-13
II .35
3-7
I .071
7 -5 1
2 95
18.6
1.178
1.082
12.31
o-94
31.2
i .0
I .Il6
20.65
0.80
MIXTURES OF COPPER AMMONIUM SULPHATE AND NICKEL AMMONIUM
SULPHATE IN WATER AT i3-i4.
(Fock Z. Kryst. Min. 28, 394, '97.)
CuSO 4 .(NH 4 ) 2 SO 4 .6H 2 O NiSO 4 .(NH 4 ) 2 SO 4 .6H 2 O.
Mol. % in Solution. Mols. per 100 Mols. H 2 O. Mol. % in Solid Phase.
Cu.
Salt.
Ni Salt.
Cu Salt.
Ni Salt. '
Cu.
Salt.
Ni Salt."
O
OO
IOO
.00
.00
0.521
OO
IOO
.00
33
34
66
.66
.1476
O
295
10
.29
89
71
43
95
O
.2664
.2089
30
59
6 9
.41
73
^89
26
.20
.4165
.1449
52
23
47
77
79
.92
20-08
O
4785
.1202
78
.80
21
.20
IOO
.00
o
.00
I
0350
o
OO
IOO
.0
.00
MIXTURES OF COPPER AMMONIUM SULPHATE AND ZINC AMMONIUM
SULPHATE IN WATER AT 13 14.
(Fock.)
CuSO 4 .(NH 4 ) 2 SO 4 .6H 2 O ZnSO 4 .(NH 4 ) 2 SO 4 .6H 2 O.
Mol. % in Solution. Mols. per 100 Mols. H 2 O. Mol. % in Solid Phase.
Cu. Salt.
Zn Salt.
Cu Salt..
Zn Salt.
Cu. Salt.
Zn Salt.
4-97
95-03
O.O422
o . 8069
2-39
97.6l
10.65
89-35
o 0666
0-5638
4-52
95-48
19.24
80.76
0.1218
O.S"5
9-03
90.97
30.19
69.81
0.2130
0.4924
14.67
85-33
44.44
55-56
0.3216
O.4O22
22 .62
77-38
100.00
o.oo
1-035
O-OOO
IOO
0-000
SOLUBILITY OF COPPER SULPHATE IN AQUEOUS SOLUTIONS OF
MAGNESIUM SULPHATE AT o.
(Diacon Jahresber. Chem. 61, '66.)
Grams per TOO Gms.H 2 O. Solid Grams per 100 Gms. H 2 O. Solid
CuS0 4 . "MgS0 4 . ' CuSCv MgS0 4 .
O 26.37 MgSO 4 .6H 2 O 12.03 I 5 67
2.64 25.91 *3-6i 8.64
4-75 25.30 " 14-99 o.oo
9-01 23 . 30 MgSO 4 .6H2O + CuSCVsHzO
COPPER SULPHATE
130
COPPER SULPHATE, MANGANESE SULPHATE, MIXED CRYSTALS AT 25'
(Stortenbecker Z. physik. Chem. 34, 112, *oo.)
Mols. per 100 Mols. H2O.
Gms. per ioq Gms. H2O.
CuSO 4 . MnSO 4 .
Triclinic Crystals with sH 2 O.
20-2 O
19.76 3.69
13.65 3 I -5 2
ii. 61 39.41
9-39 46.77
6-47 53-39
3-o J 58-93
o.o 61.83
Monoclinic Crystals with ?H 2 O.
Mol. % Cu Mol. % Cu
Cu.
Mn. '
in Solution.
in Crystal:
2.282
O
100
100
90-5
99-3
2.23
0-44
83.5
74-1
97-3
57-7
95 - 1
31.0
81.3
i-54
3 -76
29.0
26.1
70.4
i .31
4.70
21.8
21 .2
42 .6
20.0
34-4
i. 06
5-59
15-9
22 .9
13-45*
I 5 .2*
o-73
6-37
10.27
10-5
5-o
4-9
0-34
7-03
4.6
2.31
2.15
o.o
7-375
o.o
100.
9-39
6.47
o.o
46.77
53-39
i .06
o-73
o.o
5-58
6.37
8*
20-0
IS-9
!3-45
10.27
4.6*
o.o
28.2
23-5
20.8
16.0
5 .8*
100
* Indicates points of labil equilibrium.
COPPER SULPHATE, ZINC SULPHATE, MIXED CRYSTALS IN WATER.
(Stortenbecker Z. physik. Chem. 22, 62, '97.)
Triclinic Crystals with sH 2 O.
Monoclinic Crystals with 7H 2 O.
Rhombic Crystals with 7H 2 O.
ols. per too
Mols. H 2 O.
Mol. % Cu
Mol. % Cu
Cu.
Zn.
in Solution.
in Crystals.
2.28
O
100
100
1.8 3
2-o8
46.8
94-9
I.4I
3-60
28.1
86.4
I.I 9
5-01
19.2
77-9
1.86
3-36
36.2
40.4
1.22
4-45
21-5
29-5-31-9
1. 01
4-72
17.6
24 . 1-28 .
0.82
5-03
14.0
19.0-22.
0.51
5-59
8.36
12.4-14.9
0.30
5-56
4.87
7.02
o.o
6.42
o.o
1.19
5.01
19-2
5.01
0.51
5-59
8.36
1.97
0.267
5-77
4.42
*?$
o.o
5-94
o.o
0-00
131 COPPER SULPHATE
SOLUBILITY OF COPPER SULPHATE, SODIUM SULPHATE MIXTURES IN
WATER.
(Koppel Z. physik. Chem. 42, 8, 'oi-'o2; Massol and Maldes Compt. rend. 133, 287, '01.)
O
10
15
17.7
23.0
40.15
17.7
23
40.15
18
20
25
30
33-9
37-2
30
30.1
30
Gms. per 100 Gms.
Solution.
CuSO 4 .
Na 2 S0 4 .
13.40
6.23
14-90
9.46
I5.I8
11.64
14-34
I 3-34
14.36
12 .76
J 3-73
12.26
14.99
13.48
16.41
II .35
20.56
8.0
13-53
13.84
u-34
15 .70
6.28
21 .20
2 .607
28.38
J -475
32-30
1.494
31.96
5-38
22.17
3-69
25-37
J -57
32.09
Mols. per 100 Mols.
Na 2 SO 4 .'
0.98
I. 5 6
2.02
2-34
2.21
2.10
2-39
1.99
1.47
2.41
2-73
3-70
5-21
6.18
6.08
CuSO 4
1.88
2.23
2.23
2.24
2.23
2.10
2-37
2-57
3-25
2 .IO
I. 7 6
0.98
o-43
0.25
0.25
Solid Phase.
CuS0 4 . 5 H 2 + Na 2 S0 4 .ioH 2
CuS0 4 .Na 2 S0 4 .6H2O
CuS0 4 .Na 2 S0 4 .6H 2 + CuSO 4 . 5 H 2 O
CuSO 4 .Na 2 SO 4 .6H 2 O + Na 2 SO 4 .ioH 2 O
}
CuSO 4 .Na 2 SO 4 .6H 2 O + increasing
amts. of Na 2 SO 4 .ioH 2 O
SOLUBILITY OF COPPER POTASSIUM SULPHATE CuK 2 (SO 4 ) 2 .6H 2 O in
WATER AT 25.
100 gms. H 2 O dissolve 11.14 gms. CuK 2 (SO 4 ) 2 .
(Trevor Z. physik. Chem. 7, 470, '91.
SOLUBILITY OF COPPER SULPHATE IN METHYL AND ETHYL ALCOHOL,
ETC.
(de Bruyn Z. physik. Chem. 10, 786, '92; de Coninck Bull. acad. roy. Belgique, 257, '05.)
Solvent.
Methyl Alcohol Abs.
93-5%
50%
Abs.
Ethyl Alcohol Abs.
Glycol
Glycerine
Gms. per 100 Gms. Solvent. SOLUBILITY IN AQUEOUS
Gms. CuSO 4 .5H 2 O
per 100 g. Solvent.
15-3
3-2
0.25
CuSO 4 .
CuS0 4 . 5 H 2 0.
ALCOI
18 1.05
I 5 .6
(Schiff Liebij
18
18
o-93
0.40
Wt.%
Alcohol.
3
13-4
10
3
i .1
20
14.6
7.6*
40
15 .5
3-o
* Per 100 g. sol.
COPPER SULPHIDE CuS.
SOLUBILITY IN AQUEOUS SUGAR SOLUTIONS.
(Stolle Z. Ver. Zuckerind. 50, 340, *oo.)
Gms. CuS per Liter of Aq. Sugar Solution at:
% Sugar
in Solvent.
10
30
50
0.5672
0-8632
0-9076
45-
0.3659
0.7220
1.0589
75.
I-I345
1.2033
I . 2809
COPPER TARTRATE 132
COPPER TARTRATE CuC 4 O 6 H 4 . 3 H 2 O.
SOLUBILITY IN WATER.
(Cantoni and Zachoder Bull. soc. chim. [3] 33, 751, '05.)
Gms.
Gms.
Gms.
t
CuC 4 OeH 4 .3H2O
t '
:uC 4 6 H 4 . 3 H 2 O
t .
CuC 4 6 H 4 . 3 H20
*
per 100 cc.
per 100 cc.
per 100 cc.
Solution.
Solution.
Solution.
15
0.0197
40
O.I42O
65
0.1767
20
0.0420
45
0.1708
70
0.1640
25
o . 0690
50
0.1920
75
0.1566
30
o . 0890
55
0.2124
80
0.1440
35
0.1205
60
0.1970
85
0.1370
CRESOL C 6 H 4 (OH).CH 3 o, m and p.
SOLUBILITY IN WATER AT 20.
(Vaubel J. pr. Chem. [2] 52, 72, '95.)
TOO grams of the saturated aqueous solution contain :
f. A.
2.45 grams o cresol, 2.18 grams m cresol, 1.94 grams p cresol.
DISTRIBUTION OF CRESOL BETWEEN WATER AND ETHER,
(Vaubel J. pr. Chem. [2] 67, 472, '03.)
Composition of Solvent. Gms. Cresol in H^O Layer. In Ether Layer.
200 cc. H 2 O+ioo cc. Ether 0-0570 i .0760
200 cc. H 2 O + 2oo c.c. Ether 0.0190 i -1144
CUMINIC ACID C 3 H 7 C 6 H 4 .COOH (p Iso Propyl Benzoic Acid).
SOLUBILITY IN WATER AT 25.
(Paul Z. physik. Chem. 14, in, '94.)
1000 cc. sat. solution contain 0.1519 gm. or 0.926 millimol Cuminic
Acid.
PseudoCUMIDINE (CH 3 ) 3 .C 6 H 2 .NH 2 (sym. 5 Amino, i, 2, 4, Trimethyl
benzene).
SOLUBILITY IN WATER.
(Ljwenh.-rz Z. physik. Ch. 25, 412, '98.)
|
t. 19-4. 23.7. 28.7.
Gms. $ Cumidine per liter H,O i . 198 i . 330 i .498
CYANOGEN CN.
SOLUBILITY IN SEVERAL SOLVENTS AT 20.
(Gay Lussac.)
Solvent. Vols. CN per i Vol. Solvent.
Water 4.5
Alcohol 23 .o
Ether 5 . o
Oil of Turpentine 5.0
133 DIDYMIUM SULPHATE
DIDYMIUM SULPHATE Di 2 (SO 4 ) 3 .
SOLUBILITY IN WATER.
(Marigr ac Ann. chim. phys. [3] 38, 170, '53.)
Gms.Di 2 (SO 4 ) 3 Solid Gms.Di 2 (SO 4 ) 3
t. per ioo pT; 1 " t. per ioo
Gms.H-jO. Gms.HzO. Phase -
12 43.1 Di 2 (S0 4 ) 3 ? 34.0 Di,(S0 4 ) 3 .6H 2
18 25.8 19 n. 7 Di 2 (S0 4 ) 3 .8H 2
25 20.6 40 8.8 "
38 13.0 50 6.5
50 ii. o ioo 1.8 "
DIDYMIUM POTASSIUM SULPHATE K 2 SO 4 .Di 2 (SO 4 ) 3 . 2 H 2 O.
(Marignac.)
ioo gins. H 2 O dissolve 1.6 grains double salt at 18.
ERBIUM SULPHATE Er 2 (SO 4 ) 3 .
SOLUBILITY IN WATER.
(Hoglund.)
ioo gms. H 2 O dissolve 43.0 gms. Er 2 (SO 4 ) 3 at o.
ioo gms. H 2 O dissolve 23.0 gms. Er 2 (SO 4 ) 3 .8H 2 O at 20.
ERYTHRITE CH 2 OH(CHOH) 2 CH 2 OH.
ioo grams saturated solution in pyridine contain 250 gms. at 26.
(Holty J. Physic. Chem. 9, 764, \>5.J
ETHANE C 2 H 8 .
SOLUBILITY IN WATER.
(Winkler Ber. 34, 1421, '01.)
t. /9. /3'. q. t. ft. 0'. q.
o 0.0987 0.0982 0.0132 40 0.0292 o 0271 0.0037
5 0.0803 0.0796 0.0107 50 0.0246 0.0216 0.0029
10 0.0656 0.0648 0.0087 60 0.0218 0.0175 0.0024
J 5 -55 0.0541 0.0073 7 0-0195 0-0135 0.0018
20 0.0472 0.0462 0.0062 80 0.0183 0.0097 0.0013
25 0.0410 0.0398 0.0054 90 0.0176 0.0054 0.0007
30 0.0362 0.0347 0.0049 Io 0.0172 o.oooo o.oooo
ft = Absorption coefficient, i.e., the volume of gas (reduced to o
and 760 mm.) absorbed by i volume of the liquid when the pressure
of the gas itself without the tension of the liquid amounts to 760 mm.
/?' = Solubility, i.e., the volume of gas (reduced to o and 760 mm.)
which is absorbed by one volume of the liquid when the barometer
indicates 760 mm. pressure.
q = the weight of gas in grams which is taken up by TOO grams of
the pure solvent at the indicated temperature and a total pressure
(that is, the partial pressure of the gas plus the vapor pressure of the
liquid at the absorption temperature) of 760 mm.
ETHER
134
ETHER (C 2 H 6 ) 2 O.
RECIPROCAL SOLUBILITY OF ETHER
AND WATER.
(Klobbie Z.physik.Chem. 24, 619, '97; Schuncke Ibid. 14, 334, '94; St.Tolloczko Ibid. 20, 407,
'96.)
Solubility of Ether in Water.
Lower Layer Aqueous.
, Gms. (C 2 H 5 ) 2 O per 100 Cms.
Solubility of Water in Ether.
Upper Layer Ethereal.
Gms. H 2 O per 100 Gms.
Water.
Solution.
o
13.12
ii. 6
5
II-4
10.2
10
9-5
8.7
15
8.2
7.6
20
6 -95
6-5
25
6.05
5-7
30
5-4
5 - 1
*4o
4-7
4-5
*5o
4-3
4.1
*6o
3-8
3-7
* 7 o
3-3
3-2
*8o
2.9
2.8
Ether.
I .01
Solution
I .0
1. 06
1.05
1. 12
I .12
(2.6,8.)
.16
1 - r 5
.20
1.20
(2.65,8.)
.26
1.26
33
1.32
52
1-50
73
I .7
1.83
1.8
2 .04
2 -O
2.25
2 .2
* Indicates determinations made by Synthetic Method, for which see page 9.
ioo cc. H 2 O dissolve 8.11 cc. ether at 22; Vol. of solution 107.145 cc.,
Sp. Gr. 0.9853.
ioo cc. ether dissolve 2.93 cc. H 2 O at 22; Vol. of solution 103.282,
Sp. Gr. 0.7164. (Herz Ber. 31, 2671, '98.)
For recent determinations of the density of ether, see Christomanos
Z. anorg. Chem. 45, 136, '05.
SOLUBILITY OF ETHER IN AQUEOUS SOLUTIONS OF HYDROCHLORIC
ACID.
(Schuncke Z. physik. Chem. 14, 334, '94; in 38.52% HC1, Draper Chem. News, 35, 87, '77.)
In 3 8. 5 2%HCl.
In 3 i.6i%HCl.
HC1.
cc. Ether
cc.
Ether Gms. per i Gram H 2 O.
cc. Ether Gms. per
i g. H 2 0.
t.
per ioo cc.
Solvent.
per ioo cc.
Solvent. HC1.
(C 2 Hs) 2 O. Solvent.
' HCl.
(C 2 H 6 ) 2 0.
-6
181
149
0.4622
I
387
67.2
253
0.5637
o
177
5
142
0.4622
I
58.3
o . 4863
+ 6
172
5
I 3 I
5
0.4622
I
.2075
5I-I
253
0.4231
i5
163
121
7(i4)
0.4622
I
I o75
40-5
o
253
0.3299
20
158
116
.9(20.8)
0.4622
I
.0005
33-i
253
0.2688
26
J 35
104.
2
0.4622
.9360
27-5
253
O-222I
In i2. 5 8%HCl.
In 3.65 % HC1.
AO cc. Ether per
Gms. per i Gram H 2 O.
cc. Ether per
Gms. per i Gram H 2 O.
ioo cc. Solvent.
HCl.
(C 2 H 5 ) 2 0.
ioo cc. Solvent.
HCl.
(C 2 H 5 ) 2 0.
-6
26
45
O
.144
.2106
19
23
0-0308
1454
22
.19
O
.144
.1748
4-6
19
.18
O
.144
!503
14
3i
0.0308
O
.1070
15
IS
.61
O
.144
.I2IO
II
83
0-0308
O
.0868
20
13
76
.144
O
.1059
10
52
0-0308
O
.0769
26
12
.70
O
.144
o
.0970
9
.24
0-0308
.0673
i 3 5 ETHEK
SOLUBILITY OF ETHER IN AQUEOUS SALT, ETC., SOLUTIONS AT 18.
(Euler Z. physik. Chem. 49, 306, '04.)
Aq. Solu-
tion of:
Gms. per
Liter Added
Salt.
Gms. (C 2 H C )20
per TOO cc.
Solvent.
Aq. Solu-
tion of:
Gms. per
Liter Added
Salt.
Gms. (C 2 H
per TOO c
Solvent.
Water
0-0
7-8
Na 2 S0 4
59-54
3-7
KNO 3
ioi .19
5-4
Mannite
91.06
6. 7
KC1
73-6
4-7
H 2 S0 4
49.0
6.6
Lid
42.48
5-2
u
122.5
5-65
NaCl
58-5
4-5
11
245.0
4-55
SOLUBILITY OF ETHER IN AQUEOUS ETHYL ALCOHOL AND IN AQUEOUS
METHYL ALCOHOL MIXTURES AT 20.
(Bancroft Phys. Rev. 3, 122, *95-'96.)
In Ethyl Alcohol. In Methyl Alcohol.
Per 5 cc. Alcohol. Per 5 cc. Alcohol. Per i cc. CH 3 OH. Per i cc CH 3 OH.
cc.H 2
.* cc.(C 2 H 5 ) 2 O.t cc.H 2 O.* cc.(C 2 H 5 ) 2 O.t
cc.H 2 O.
cc.(C 2 H 5 ) 2 O. cc.H 2 O.
cc.(C 2 H 5 -) 2 0:
50
1.30 4.45 7-o
10
I.I3 0.83
1. 80
25
1.70 4-0 7.8
7
0-85 0.64
3-00
IO
2.41 3.87 8.0
4
O-6o 0.52
5-o
8
3.35 3.10 10. o
2-5
0.56 O-44
IO-O
6
5.10 2.08 15.0
1.8
0.63 0.45
15.0
5-
21 6.00 1.77 17.5
I .0
1.23
* Saturated with ether.
t
Saturated with water.
ETHYL ACETATE CH 3 COOC 2 H 6 .
SOLUBILITY IN WATER AND IN AQUEOUS SALT SOLUTIONS AT 28.
(Euler Z. physik. Chem. 31, 365, '99; 49, 306, '04.)
Cone, of Salt
Solution.
CH 3 COOC 2 Hs
per Liter.
Solvent f
Cone, of Salt
Solution.
CH 3 COOC 2 H 6
per Liter.
Solvent.
Nor- Gms per
mality. Liter.
Gram
Mols.
Grams.
Nor- Gms. per Gram
mality. Liter. Mols.
Grams.
Water
0.825
75-
02
NaCl(at 18)
\ 14.62
0.
76
67.0
KN0 3
50-59
0.77
67.
81
it
i 29.25
0.
67
59-
a
I
ioi. 19
0.72
63-
40
(t it
I 58.5
O.
51
45-
o
it
2
202.38
0.625
55-
04
Na 2 S0 4
I 71.08
0.
465
40.
96
KC1
\
18.4
0.747
65-
79
" (at 18)
i 35-54
O.
61
54-
it
\
36.8
0.685
65-
33
tt ti
i 71.08
O.
42
37-
it
I
73-6
0-575
50-
64
MgS0 4
J 16.30
O.
733
64.
55
t(
2
147.2
0.41
36.
ii
tt
i 32-6
o.
655
57-
68
NaCl
I
14.62
0-745
65-
61
tt
i 65.21
0-505
44.
47
29.25
0.677
59.62
ZnSO 4
\ 20. l8
o.
733
64-
55
ti
I
58.5
0-545
47-
99
.
i 40.36
0.
653
57-
5
2
117.0
0.315
27.
74
"
i 80.73
0.
500
44.
03
In Methyl Alcohol.
In
Acetone.
Per i cc. CH 3 OH.
Per i
cc. (CH 3 ) 2 CO.
cc. HzO. CHaCOOCzHs.
cc. H 2 O.
CH 3 COOC 2 H 8 .
10 I. 08
IO
1. 01
3 0.68
5
O.6o
1-5 1.69
2
o-43
1.29 2.50
i-5
0.47
i.o 4.9
I.O
0.63
0.98 7.0
0.8
0.74
i.o 8.0
0.51
1. 00
1.03 10. o
0.25
2 .OO
0.29
5-oo
1 acetate. t Saturated
with water
'.
ETHYL ACETATE 136
SOLUBILITY OF ETHYL ACETATE IN AQUEOUS ETHYL ALCOHOL, METHYL
ALCOHOL, AND ACETONE MIXTURES AT 20.
(Bancroft Phys. Rev. 3, 122, 131, '95-' 96.)
In Ethyl Alcohol.
Per i cc..C 2 H 5 OH.
_ TT S\ Or CC.
cc. i^u.* CH 3 COOC 2 He.t
10 0.25
8 0.27
4 0.35
2 I -O2
I .06 2 . 50
0.65 5-0
0-54 7-0
0.44 10.0
ioo cc. H 2 O dissolve 7.26 g. ethyl acetate at 28.
(Euler Z. physik. Chem. 31, 360, '99.)
ioo cc. H 2 O dissolve 9.26 cc. ethyl acetate at 20.
ioo cc. ethyl acetate dissolve 2.94 cc. water at 20.
ETHYL BUTYRATE C 3 H 7 COOC 2 H 5 .
SOLUBILITY IN WATER AND IN AQUEOUS ETHYL ALCOHOL MIXTURES
AT 20.
ioo g. H 2 O dissolve 0.5 g. ethyl butyrate at 22.
(Traube Ber. 17, 2304, '84-)
ioo cc. H 2 O dissolve 0.8 cc. ethyl butyrate at 20. (Bancroft.)
ioo cc. ethyl butyrate dissolve 0.4 0.5 cc. H 2 O at 20.
Per 5 cc. ( cc. H 2 O 10 6 4 2.96 2.10
Ethyl Alcohol ( cc. C 3 H 7 COOC 2 H 5 0.34 0.96 2.47 4.00 6.0
ETHYL FORMATE HCOOC 2 H 6 .
ioo grams water dissolve 10 grams ethyl formate at 22. (Traube.)
ETHYL PROPIONATE C 2 H 5 COOC 2 H 5 .
SOLUBILITY IN WATER AND IN AQUEOUS ETHYL ALCOHOL MIXTURES.
(Bancroft.)
ioo grams H 2 O dissolve 1.7 grams ethyl propionate at 22. (Traube.)
.1.1 cc. H 2 O to cause separation of a second phase in
cc. rticoi ixtures of the given amounts of Alcohol and 3 cc.
in Mature. portions of Ethyl Propionate.
3 2.32
6 6.87
9 J 2-35
12 19.17
15 27.12
18 36.84
21 50.42
24 oo
3
1.42
39
53-13
9
7.18
45
63.60
i5
14-13
57
90-53
21
22.40
72
131.0
27
31.62
81
180.0
33
41 .62
i 3 7 ETHYL VALERATE
ETHYL VALERATE C 4 H 8 COOC 2 H fi ,
ETHYL (Iso) VALERATE (CH 3 ) 2 .CH.CH 2 COOC 2 H 6 .
SOLUBILITY OF EACH IN WATER AND IN AQUEOUS ALCOHOL
MIXTURES AT 20.
(Bancroft.)
ioo cc. water dissolve 0.3 cc. ethyl valerate at 25.
100 cc. water dissolve 0.2 cc. ethyl iso valerate at 20.
ioo cc. ethyl iso valerate dissolve 0.4+ cc. water at 20.
Mixtures of Ethyl Alcohol, Mixtures of Ethyl Alcohol,
Ethyl Valerate and Water. Ethyl Iso Valerate and Water.
Per 5 cc. Ethyl Alcohol.
ec. Alcohol* cc.H 2 O.t cc. Alcohol* cc.H 2 O.f ~~* cc Ethyl '
cc.H 2 0. IsoVal / rate .
10 0.15
8 0.23
6 o .46
5 0.72
4 1-23
* cc. Alcohol in mixture.
t cc. H 2 O added to cause the separation of a second phase in mixtures of the given amounts of alcohol
nd 3 cc. portions of ethyl valerate.
Di ETHYL KETONE (3 Pentanon) (C 2 H 5 ) 2 CO.
SOLUBILITY IN WATER.
(Rothmund Z. physik. Ch. 26, 433, '98 )
Determinations made by Synthetic Method, see page 9.
Cms. Di Ethyl Ketone Cms. Di Ethyl Ketone
t. per ioo Gms. t. per 700 Gms.
Aq. Layer. Ketone Layer. Aq. Layer. Ketone Layer.
20 4.60 ... ioo 3-68 93 .10
40 3-43 97-42 120 4.05 90.18
60 3.08 96.18 140 4.76 87.01
80 3.20 94-92 160 6.10 83.33
ETHYL BROMIDE C 2 H 5 Br.
SOLUBILITY IN ETHER.
(Parmentier Com pt. rend. 114, 1002, '92.)
t. 13- o- I2 - 22.5. 32.
G. C 2 H 5 Br per ioo gms. Ether 632 561 462 302 253
SOLUBILITY OF ETHYL BROMIDE, ETC., IN WATER.
(Rex Z. physik. Chem. 55, 355, '06.)
Grams per ioo Grams H 2 O at:
Dissolved Substance. , * *
o. 10. 20. 30.
Ethyl Bromide 1.067 0.965 0.914 0.896
Ethyl Iodide 0.441 0.414 0.403 0.415
Ethylene Chloride 0.922 o . 885 o . 869 o . 894
Ethylidene Chloride o . 656 o . 595 o . 550 o . 540
ETHYL CARBAMATE 138
ETHYL CARBAMATE CO(OC 2 H 5 )NH,. (See also Urethane, p. 347.)
SOLUBILITY IN SEVERAL SOLVENTS AT 25.
(U. S. P.)
Solvent: Water. Alcohol. Ether. Chloroform. Glycerine.
Cms. CO(OC 2 H 5 )NH 2 66
per 100 gms. solvent Ioo + 77 33
ETHYLENE C 2 H 4 .
SOLUBILITY IN WATER AND IN ALCOHOL.
(Bunsen and Carius; Winkler Landolt and Bornstein, Tabellen, 3d ed. p. 604, '06.)
o
P.
O.226
Q-
O.O28l
Solubility in Alec
. o Vols. C 2 H 4 per
5
O.I9I
0.0237
L
ioo Vols. Alcohol.
10
O.l62
O-O2OO
O
359-5
15
0.139
O.OI7I
4
337-5
20
O.I22
0.0150
10
308.6
25
0.108
O.OI3I
15
288.2
30
0.098
O.OIlS
20
271.3
For ft and q see Ethane, page 133.
SOLUBILITY OF ETHYLENE IN METHYL ALCOHOL AND IN ACETONE.
(Levi Gazz. chim. ital. 31, II, 513, '01.)
Results in terms of the Ostwald Solubility Expression /. See p. 105.
t. In Methyl Alcohol. In Acetone. t. In Methyl Alcohol. In Acetone.
o 3-39 2 4 4-0652 30 1-8585 i. 8680
10 2.8831 3-35 8 40 1-3432 1.0852
20 2.3718 2.6278 50 0.8259 0.2772
25 2. ,1154 2.2500 60 0.3506
The formulas from which the above figures were calculated are:
In Methyl Alcohol, / = 3 .3924 0.05083 t o.ooooi / 2 .
In Acetone, / = 4.0652 0.06946 / 0.000126 t 2 .
PATS.
SOLUBILITY OP THE FATTY ACIDS OBTAINED FROM SEVERAL SOURCES
IN ALCOHOL AND IN BENZENE.
(Dubois and Fade Bull. soc. chim. [2] 44, '85.)
Crude
Fatty
A *J t
Gms.
Fat per ioo (
Alcohol at:
Jms. Abs.
Gms. Fats
per ioo Gms.
T> C
Acid of:
o.
10.
26.
Benzene at 12 ,
Mutton
2.48
5-02
67.96
14.70
Beef
2.51
6.05
82.23
15.89
Veal
5.00
I3-78
137.10
26.08
Pork
5-6 3
11.23
118.98
27.30
Butter
10.61
24.81
158.2
69.61
Margarine
2.37
4-94
47-06
J 3-53
139 FUMARIO ACID
FUMARIC ACID COOH.CH:CH.COOH.
MALEIC ACID (CH) 2 (COOH) 2 .
SOLUBILITY IN WATER.
(Vaubel J. pr. Chem. [2] 59, 30, '99.)
ioo gms. water dissolve 0.672 gram fumaric acid at 165.
ioo gms. water dissolve 50.0 grams maleic acid at 100.
FURFUROL C 4 H 3 OCHO.
SOLUBILITY IN WATER.
(Rothmund Z. physik. Chem. 26, 475, '98.)
Determinations by Synthetic Method, for which see page 9.
Gms. CH 3 OCHO per ioo Gms. Gms. C 4 H 3 OCHO per ioo Gms.
Aq. Layer. Furfurol Layer. Aq. Layer. Furfurol Layer.
40 8.2 93.7 ioo 18.9 83.5
50 8.6 93.0 no 24.0 78.5
60 9.2 92.0 115 28.0 74.6
70 10.8 90.7 120 34.4 68.1
80 13.0 89.0 122.7 (crit. t.) 5 1 -
90 15.5 86.6
GADOLINIUM SULPHATE Gd 2 (SO 4 ) 3 .8H 2 O.
SOLUBILITY IN WATER.
(Benedicks Z. anorg. Chem. 22, 409, 'oo.)
t o Gms. Gd 2 (S0 4 )s per ioo g Hd ph
Gms H 2 L).
o 3.98 Gd 2 (SO 4 ) 3 .8H 2 O
10 3-3
14 2.8
25 2.4
34.4 2.26
GALACTOSE C 6 H 12 O 6 .
ioo grams saturated solution in pyridine contain 5.45 grams C 6 Hi 2 O,
at 26, density of solution 1.0065.
(Holty J. Physic. Chem. 9, 764, '05 )
GALLIC ACID CeH^OHa) (3, 4, 5) COOH +H 2 O.
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; Bourgoin Ann. chim. phys. [5] 13, 406, '78.)
Gms. CvHeOs.J^O per ioo Gms.
doivem.
i> .
Solvent.
Solution.
Water
25
I .20
1.18
Water
IOO
33-3
25.0
Alcohol (Abs.)
23-3
18.1
Alcohol (U.S.P.)
25
24.1
19-3
Alcohol 90%
38.8
18.9
Ether
2 5
2.56
2.50
Glycerine
25
8-3
7.66
GERMANIUM DIOXIDE 140
GERMANIUM DIOXIDE GeO 2 .
100 gms. H 2 O dissolve 0.405 gm. GeO 2 at 20, and 1.07 gms. at
100.
(Winkler J. pr. Chem. [2] 34, 177. '86; 36. i?7, '87.)
GERMANIUM (Mono) SULPHIDE GeS and GERMANIUM (Di)
SULPHIDE GeS 2 .
100 gms. H 2 O dissolve 0.24 GeS and 0.45 gm. GeS 2 .
(Winkler.)
GLASS.
For data on the solubility of glass in water and other solvents, see :
(Cowper J. Chem. Soc. 41, 254, '82; Emmerling Liebig's Annalen, 150, 257, '69; Bohling Z.
anal Chem. 23, 518, '84; Kreusler and Herzhold Ber. 17, 34, '84; Kohlrausch Ber. 24, 3561, '91;
Wied Ann. 44, 577, '91; Forster Ber. 25, '92; Mylius and Forster Ber. 22, noo, '89; Ber. 25, 70,
'92; Wartha Z. anal. Chem. 24, 220, '85, etc.)
GLYCOLIC ACID CH 2 OH.COOH.
SOLUBILITY IN WATER.
(Emich Monatsh. Chem. 3, 336, '84.)
t. 20. 60. 80. 100.
Gms. CH 2 OH(COOH)
per too gms. H 2 '33 0.235 0.850
GLUCINIUM SALTS. (See also Beryllium p. 63).
SOLUBILITY IN WATER AND IN ACETIC ACID SOLUTIONS.
(Marignac; Sestini Gazz. chim. ital. 20, 313, '90.)
Gms. Anhydrous Salt
Salt. Formula. Solvent. ^perioo Gms. Solvent.^
At 20. At 100.
Glucinium potassium fluoride G1F 2 .KF Water 2.0 52
sodium " GlF 2 .NaF 1.4 2.8
Glucinium hydroxide G1(OH) 2 Water + CO 2 sat. 0.0185 (G1O) ...
phosphate G1 3 (PO 4 ) 2 .6H 2 O 2% CH 3 COOH 0.055
10% 0.1725
GLUTARIO ACID (Pyrotartaric) (CH 2 ) 3 (COOH) 2 .
SOLUBILITY IN WATER.
(Lamouroux Compt. rend. 128, 998, '99.)
t. o. 15. 20. 35. 50. 65.
Gms. (CH 2 ) 3 (COOH) 2
per loo cc solution 42-9 5-7 63.9 79.7 95.7 111.8
GOLD Au.
SOLUBILITY OF GOLD IN POTASSIUM CYANIDE SOLUTIONS.
(Maclaurin J. Chem. Soc. 63, 729, '93.)
Gold disks placed in Nestler tubes with KCN solutions.
Grams Au Dissolved in 24 Hours in Nessler Tubes :
l 1*1 fciGUl
KCN.
Full.
iFull.
Oxygen
Passed in.
Oxygen -f
Agitation.
O.I
O.OOI95
0.00331
1.0
0.00162
O.OO4I8
0.00845
0.0l87
S-o
0.0032
0-0046
0-01355
0.0472
20.0
O.OOI2
0.00305
O.OH5
0.0314
50. o
0-00043
0.00026
0.00505
Q.OIOS
141 GOLD CHLORIDE
GOLD CHLORIDE (Auric) AuCl 3 .
SOLUBILITY IN WATER, ETC.
100 gms. H 2 O dissolve 68 grams AuCl 3 .
AsCl 3 and SbCl 3 each dissolve about 2.5% AuCl 3 at 15, and 22% at
1 60.
SnCl 4 dissolves about 4% AuCl 3 at 160, and a trace at o.
(Lindet Bull. soc. chim. [2] 43, 149. '86.)
GOLD PHOSPHORUS TRI CHLORIDE (Aurous) AuClPCl 3 .
100 gms. PC1 3 dissolve i gram at 15, and about 12.5 grams at 120.
(Lindet Compt. rend. 101, 1492, '85.)
GOLD ALKALI DOUBLE CHLORIDES.
SOLUBILITY OF SODIUM GOLD CHLORIDE, LITHIUM GOLD CHLORIDE,
POTASSIUM GOLD CHLORIDE, RHUBIDIUM GOLD CHLORIDE, AND
CAESIUM GOLD CHLORIDE IN WATER.
(Rosenbladt Ber. 19, 2537, '86.)
Grams Anhydrous Salt per 100 Grams Solution.
Il .
NaAuCLi.
LiAuCU.
KAuCU.
RbAuCU-
CsAuCU-
10
5 8.2
53- 1
27.7
4-6
o-5
20
60.2
57-7
3 8.2
9-0
0.8
30
64.0
62.5
48.7
13-4
i-7
40
69.4
67-3
59-2
17.7
3-2
50
77-5
72.0
70.0
22 .2
54
60
90.0
76.4
80.2
26.6
8.2
70
81.0
31.0
12.0
80
85-7
35-3
I6. 3
90
39-7
21-7
100
44-2
27-5
GUAIACOL C 6 H 4 (OH)OCH 3 1:2. GUAIACOL CARBONATE C 6 H 4
(OCH 3 )O 2 .CO.
SOLUBILITY IN WATER, ALCOHOL, ETC.
(U. S. P.)
Gms. per 100 Gms. Solvent.
Guaiacol. Guaiacol Carbonate.
Water 25 i .89
Alcohol 25 ... 2.08
Chloroform 25 ... 66.6
Ether 25 ... 7-69
Glycerine 25 100
aTriPhenyl GUANIDINE C 6 H 6 N:C(NHC 6 H 6 ) 2 .
SOLUBILITY IN MIXTURES OF ALCOHOL AND WATER AT 25.
(Holleman and Antusch Rec. trav. chim. 13, 292, '94.)
Gms. Gms.
Vol. % (
Alcohol.
100
95
90
85
[^jHsN :C( NHCfjHfi}
per 100 Gms.
Solvent.
6.23
3-75
2.38
1.58
(2 Density
of Solutions.
0-8021
0.8158
0.8309
0.8433
Vol.%
Alcohol.
80
75
70
60
per 100 Gms.
Solvent.
1. 06
0-67
0.48
0-22
5)2 Density
of Solutions.
0.8572
0.8704
0.8828
o . 9048
HELIUM
142
HELIUM He.
SOLUBILITY IN WATER.
(Estreicher Z. physik. Chem. 31, 184, '99.)
Absorption Coefficient.
r.Barometic Vol. of
Pressure. Water.
Vol. of
He. '
.
. .
.000270
764
.0
73
584
I
.093
758
.0
73
578
I
.062
.000260
758
.0
73
597
I
.046
0.000255
757
.8
73
.641
I
.008
o
.000246
758
4
73
.707
.996
.000242
762
3
73
793
983
.000238
764
4
73
.897
985
.000238
764
5
74
.0167
.972
.000234
762
.0
74
.147
957
.000232
76!
7
74
.294
947
.000229
760
9
74
.461
.920
.000223
o
o-5
5
10
15
20
25
30
35
40
45
5
For q and also Absorption Coefficient, see Ethane, page 133.
At Bar. Pressure
Minus H 2 O
Vapor Tension.
At 760 mm.
Pressure.
O.OI5O
O.OI49
0.0144
O.OI49
0.0146
0.0142
0.0144
0.0137
0.0140
0-0135
0.0139
0.0133
0.0133
O.OI3I
0.0137
0-0138
0-0138
0.0129
0.0139
O.OI27
O.OI4O
O.OI24
O.OI4O
HEXANE C 6 H 14 .
SOLUBILITY IN METHYL ALCOHOL.
(Rothmund Z. physik. Chem. 26, 475, '98.)
Determined by Synthetic Method, see page 9.
Gms. Hexane per 100 Gms. Gms. Hexane per TOO Gms.
10
20
30
Alcoholic
Layer.
26.5
31-6
38-3
Hexane
Layer.
96.8
95-9
93-7
Hexane
Layer.
t Alcoholic
Layer.
35 43 - 6 91-2
40 52-7 85.5
42.6(crit. t.) 68.9
: Solutions.
C 9 H 9 N0 3 .
KC 9 H 8 N0 3 .
I .002
O.Ol82
O
1.003
0.0163
O-OII
I.OOS
0.0183
0-071
I -O22
0.0234
0.254
I .114
0.064
I. 3 6
I.I82
O.I3I
2.21
I . 192
0.147
2.32
i . 195*
0-153
2.40
i .201
0-133
2.50
1.239
0.084
3-oi
1.282
0.068
3-57
1.282
0-065
3-58
i . 276
0.031
3-56
1.277
p. oi i
3-55
I -m
.O.OO
3-56
Solid
Phase.
HIPPURIO ACID C 6 H 6 CONH.CH 2 COOH.
SOLUBILITY IN AQ. POTASSIUM HIPPURATE SOLUTIONS AT 20.
(Hoitsema Z. physik. Chem. 27, 317, '98.)
Grams per Liter Solution.
C 9 H 9 NO 3 . KCgHgNOs.
3.276 o.o
2.919 2.39
3.278 15.43
4.I9I 55.18
11-47 295.4
23.46 480-1
26.32 504.1
27.40 521.4
23.82 543.1
15.04 654.0
12. 18 775.7
II. 60 777.8
5-55 773-4
1.917 771.3
773-4
C 9 H 9 N0 3 +
C 9 H 9 N0 3 .KC 9 H8N0 3 .H 2 O
+ KC 9 H 8 N0 3
143 HOMATROPINE HYDRO-
BROMIDE
HOMATROPINE HYDROBROMIDE C 16 H 21 NO 3 .HBr.
SOLUBILITY IN WATER, ETC.
(U. S. P.)
100 grains water dissolve 17.5 grams salt at 25.
100 grams alcohol dissolve 3.08 grams salt at 25, and 11.5 grams
at 60.
100 grams chloroform dissolve 0.16 gram salt at 25.
HYDRASTINE C 21 H 21 NO 6 . HYDRASTINE HYDROCHLORIDE
C U H U NO,.HC1.
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; Muller Apoth.-Ztg. 18, 249, '03.)
Gms. C2iH2iNC>6 per 100 Gms. Gms. per 100 Gms.
Solvent. Solution. Solvent. Solution at i8-22.
' At i8-2 2 . *~ At 80. C 2l H 2l NO 6 . C 11 H 11 NO 2 .HCr.
Water 0.0033 - 02 5 Ether 0.51 0.078 (25)
Alcohol 0.74(25) 5.9(60) Ether + H 2 O 0.80
Benzene 8.89 ... Chloroform 100+ 0-35(25)
Acetic Ether 4.05 ... CC1 4 o. 123
Petroleum Ether 0.073
HYDRAZINE SULPHATE N 2 H 4 .H 2 SO 4 .
100 grams water dissolve 3.055 grams N 2 H 4 .H 2 SO 4 at 22.
(Curtius and Jay J. pr. Chem. [2] 39, 39, '89.)
HYDROBROMIC ACID HBr.
SOLUBILITY IN WATER.
(Roozeboom Z. physik. Chem. 2, 454, '88; Rec. trav. chim. 4, 107, '85; 5, 358, '86; see also Pickering
Phil. Mag. [5] 36, 119, '93-)
Gms.HBr KffiolvedjCat 760-7651^.) Gms HBr Dissolved at
/3. Lower Pressures per 100
Gms. H 2 O.
175.0 (10 mm.)
611.6
581 .4 108.5 (5 mm.)
532-1
468.6
406.7
344.6
t.
per 100 L
rms.
' Water.
Solution.
- 2.5
255-0
7I-83
15
239.0
70.50
o
221 .2
68.85
+ 10
210-3
67.76
15
204-0
67.10
25
193.0
65.88
5
171 .5
63.16
75
ISO'S
60.08
100
130.0
56-52
For /3 see
Ethane, page
!33-
HYDROCHLORIC AGID 144
HYDROCHLORIC ACID HC1.
SOLUBILITY IN WATER AT DIFFERENT TEMPERATURES AND
PRESSURES.
(Deicke; Roscoe and Dittmar Liebig's Ann. 112, 334, '59; below o, Roozeboom Rec. trav.
chim. 3, 104, '84.)
At Different Temperatures and 760 mm. Pressure. At Different Pressures and o.
t.
cc. HC1 per
ioocc.H 2 O.
Density.
Cms. HC1 per Gms. HC1 per
100 g. Sol. 100 g. H 2 O.
Pressures.*
Gms. HClper
100 g. H 2 O.
5 2 5- 2
1.2257
45-15
82.31
60
6l. 3
4
497-7
I .2265
44 -3 6
79-73
100
65-7
8
480.3
1.2185
43-83
78.03
150
68.6
12
471-3
I .2148
43-28
76.30
200
70.7
14
462.4
1.2074
42.83
74-92
300
73-8
18
451.2
I . 2064
42-34
73-41
4OO
76-3
23
435-o
I.20I4
41-54
71.03
500
78.2
30
40.23
67-3
600
80.0
40
, 38-68
63-3
750
82.4
So
37-34
59-6
IOOO
85.6
60
35-94
56.1
1300
89-5
* Pressures in mm. Hg minus tension of H 2 O vapor.
At a pressure of 760 mm. At pressures below and above 760 mm.
t. q. t. q. t. mm. Pressure. q.
-24 IOI.2 -15 93.3 -23.8 ... 84.2
21 98.3 io 89.8 2i 334 86.8
18.3 96.0 5 86.8 19 580 92.6
18 95.7 o 84.2 18 900 98.4
-17.7 1073 101.4
For value of q, see Ethane, page 133.
SOLUBILITY OF HYDROCHLORIC ACID GAS IN METHYL ALCOHOL, ETHYL
ALCOHOL, AND IN ETHER AT 760 MM. PRESSURE.
(de Bruyn Rec. trav. chim. u, 129, '92; Schuncke Z. physik. Chem. 14, 336, '94.)
Grams HC1 gas per 100 Grams Solution in:
)H. C 2 H 6 OH. (C 2
-10 e 4 .6 ... 37.51 (-9.2)
- 5
o
+ 5
io
15
20
25
30
CH 3 OH.
C 2 H 6 OH.
(C 2 H 6 ) 2 0.
^4.6
37-5 1 (
37-o
5 J -3
45-4
35-6
44-2 (6.5)
33-i
42.7(11-5)
30.35
27 .62
47 -0 (18)
41 .0
24.9
43-0(31-7)
40.2 (23.5)
38.1 (32)
22.18
19.47
145 HYDROFLUORIC ACID
HYDROFLUORIC ACID HF.
100 grams H 2 O dissolve in grams HF at 35.
(Metzner Compt. rend. 119, 683, '94.)
HYDRIODIO ACID HI. IODIO ACID HIO 3 .
For determinations of the freezing points of aqueous solutions of HI,
and isolation of the several hydrates at temperatures below o, see
Pickering Ber. 26, 2307, '93.
SOLUBILITY OF IODIC ACID AND ITS MODIFICATIONS IN WATER.
(Groschuff Z. anorg. Chem. 47, 343, '05.)
Grams per 100
Gms. Solution.
Gram Mols. I 2 O B
per 100 Gm. Mols.
Solid
HIO 3 .
I 2 8 .
H 2 0.
Solution.
Phase.
-14
7 2.8
69.1
12. 1
10.8
Ice + HIO a
74-1
70-3
12.8
"3
HI0 3
16
75- 1
71.7
13-7
12.0
u
40
77-7
73-7
IS- 1
13.2
a
60
80.0
75-9
17.0
14-5
a
80
82.5
78-3
19.4
I6. 3
85
83.0
78.7
20-0
I6. 7
IOI
85.2
80.8
22.8
18.6
no
86.5
82.1
24.7
19.8
HIO, + HL.O,
125
87.2
82.7
25-9
20. 6
HI 3 8
140
88.3
83.8
27.9
21.8
n
1 60
9o-5
85-9
3 2.8
24-7
tl
f
Aq.
Solution.
27.73% HN0 3
Solution.
40.88% HNOa
Solution.
74-1
18.0
9-0
75-8
21 .0
IO-O
77-7
27.0
14.0
80.0
38.0
18.0
SOLUBILITY OF IODIC ACID IN NITRIC ACID.
(Groschuff.)
Grams HIOs per 100 Grams.
O
2O
40
60
HYDROGEN H. SOLUBILITY IN WATER.
(Winkler Ber. 24, 99, '91; Bohr and Bock Wied. Ann. 44, 318, '91; Timofejew Z. physik.
Chem. 6, 147, '90.)
t. ft'. _ L _ ^ ft. q.
o 0.0214 0.0214 0.000193
5 0.0203 0.0209 0.0241 0.0204 0.000184
10 0.0193 0-0204 0.0229 0.0195 0.000176
15 0.0185 0.0200 0.0217 0.0188 0.000169
20 0.0178 0-0196 - 0.0205 0.0182 0.000162
25 0.0171 0.0193 0.0191 0.0175 0.000156
30 0.0163 ... ... 0.0170 0.000147
40 0.0153 ... ... 0-0164 0.000139
50 0.0141 ... ... 0.0161 0.000129
60 0.0129 ... ... 0.0160 0.000119
80 0.0085 ... 0.0160 0.000079
100 o.oooo ... ... 0.0160 o-oooooo
/ = Ostwald Solubility Expression, see page 105. For /?', ft, and q>
see Ethane, page 133.
HYDROGEN
146
SOLUBILITY OP HYDROGEN IN AQUEOUS SOLUTIONS OF ACIDS AND
BASES AT 25.
(Geffcken Z. physik. Chem. 49, 268, '04.)
Gram Equiv.
Acids and
Solubility of H
Ostwald Expression) in Solutions of:
per Liter. HC1 '
o.o 0.0193
0.5 0.0186
i.o 0.0179
2 .O O .Ol68
3.0 0.0159
4.0
HN0 3 .
0.0193
0.0188
0-0183
0.0174
0-0167
0.0160
iH 2 S0 4 . CHgCOOH. CH 2 C1COOH. KOH. NaOH.
0.0193 0.0193
O.OI92 0-0189
0.0193
0.0185
0.0177
0.0163
0.0150
O.OI4I
O.OI9I
0.0188
0.0186
0.0186
0.0186
0.0180
0.0193
0.0167
0.0142
0.0193
0.0165
0.0139
0.0097
0.0072
0.0055
The above figures for the concentrations of acids and bases were
calculated to grams per liter, and these values with the corresponding
/ 25 values for the solubility of hydrogen plotted on cross-section paper.
From the resulting curves the following table was read.
Grams Acids
and Bases
per Liter.
20
40
60
80
IOO
150
2OO
250
Solubility of H
(fe6 =
Ostwald Expression) in Solutions of:
HC1.
.0193
.0185
.0179
.0173
.0167
.0160
HN0 3 .
0.0193
0-0189
0.0186
0.0183
0.0180
0.0179
0.0171
0.0165
0.0160
*H 2 S0 4 .
0.0193
0.0186
0.0180
0.0174
0.0168
0.0162
0.0148
0.0140
CH 3 COOH.
0.0193
O.OI92
O.OI9I
O.OI9O
0.0189
0.0189
0.0188
0.0186
0.0184
CH 2 C1COOH
0.0193
0.0191
0.0190
0.0188
0.0187
0.0185
0.0182
0.0179
KOH.
.0193
.0172
0153
o^S
NaOH.
0.0193
0.0l65
O.OI4O
O.OII7
O.OO97
0.0082
0.0058
For Ostwald Solubility Expression, see page 105.
SOLUBILITY OF HYDROGEN IN AQUEOUS SOLUTIONS OF AMMONIUM
NITRATE AT 20.
(Knopp Z. physik. Chem. 43, 103, '04.)
p-
Normality
(per 1000 Gms.)
H 2 O.
Molecular
Concentra-
tion.
Absorption
Coefficient
of Hydrogen.
Density
of Solutions.
o.oo
O-OO
o.oo
0.0188
1.037
o . 1308
0.002352
0.01872
1.0027
2 .167
0.2765
0.004956
0.01845
1.0072
3-378
0.4363
0.007799
0.01823
I -OI22
4-823
0-6333
0.011280
0.01773
I.OI82
6-773
o . 9069
0.016447
0.01744
1.0262
1.550
1.6308
0.028525
0.01647
1.04652
147
HYDROGEN
SOLUBILITY OP HYDROGEN IN AQUEOUS SOLUTIONS OF
CHLORIDE.
(Braun Z. physik. Chem. 33, 735, 'oo.)
BARIUM
Cms. BaCl 2
Coefficient of Absorption of Hydrogen at :
A
per 100 Gms.
Solution.
5.
10.
IS-
20.
25.
O-OO
0.0237
O-022I
0.0206
0.0191
0.0175
3- 2 9
O-02II
0-0198
0.0185
0.0172
0.0157
3-6
0.02O9
O.OI97
0.0184
0.0170
0.0156
6-45
0-0196
0.0186
0.0173
0.0161
0.0147
7.00
O.OI94
0.0183
0.0172
0.0159
0.0146
SOLUBILITY OF HYDROGEN IN AQUEOUS SOLUTIONS OF CALCIUM CHLOR-
IDE, MAGNESIUM SULPHATE, AND LITHIUM CHLORIDE AT 15.
(Gordon Z. physik. Chem. 18, 14, '95.)
Coefficient of Absorption of hydrogen in water at 15 = 0.01883.
In Calcium In Magnesium In Lithium
Chloride.
Sulphate.
Chloride.
Gms.
CaCl 2
G.M.
CaCl 2
Absorption
Coefficient
Gms.
MgS0 4
G.M.
MgS0 4
Absorption
Coefficient
Gms.
LiCl
G.M.
LiCl
Absorption
Coefficient
per
too g. Sol.
per
Liter.
of H.
per
zoo g. Sol.
per
Liter.
of H.
per
100 g. Sol.
per
Liter.
of H.
3-47
0.321
0.01619
4-97
o-433
0.01501
3-48
0-835
0.01619
6. 10
0.578
0.01450
10.19
0.936
0.01159
7-34
1.800
0.01370
"33
I. 122
0.01138
23.76
2.501
0.00499
14.63
3-734
0.0099
i7-5 2
I.I827
0.00839
26.34
2.962
0.00519
For definition of Coefficient of Absorption, see page 105.
SOLUBILITY OF HYDROGEN IN AQUEOUS SOLUTIONS OF POTASSIUM
CARBONATE, CHLORIDE, AND NITRATE AT 15.
(Gordon.)
In Potassium
In Potassium
In Potassium
Carbonate.
Chloride.
Nitrate.
Gms.
K 2 C0 3
G.M.
K 2 C0 3
Absorption
Coefficient
Gms.
KC1
G.M.
KC1
Absorption
Coefficient
Gms.
KN0 3
G. M.
KN0 3
Absorption
Coefficient
per
100 g. Sol.
per
Liter.
of H.
per
100 g. Sol.
per
Liter.
of H.
per
100 g.Sol.
Liter.
of H.
2.82
0.209
0.01628
3.83
0.526
0.01667
4-73
0.482
0.01683
8-83
0.690
0.01183
7.48
1.051
0.01489
8.44
0.879
0-01559
16.47
1.376
0.00761
12.13
i-755
0.01279
16.59
1.820
0.01311
24.13
2.156
0.00462
19.21
2.909
O.OIOI2
21.46
2.430
O.OIlSo
4I.8l
4.35 2
O.OOl6o
22.92
3-554
0.00892
SOLUBILITY OF HYDROGEN IN AQUEOUS SOLUTIONS OF POTASSIUM
CHLORIDE AND NITRATE AT 20.
(Knopp Z. physik. Chem. 43, 103, '04.)
In Potassium Chloride.
In Potassium Nitrate.
p>
Normality
(per looo
g. H 2 0).
Absorption
Coefficient.
Density
of
Solutions.
P-
Normality
(per looo
g. H 2 0).
Absorption De " sit y
Coefficient. Solutions
1.089
1475
0-01823
I
.0052
I
224
O
.1245
0.01835
.0059
2 .123
.2907
0.01757
I
.OIl8
2
094
.2114
o. 01818
.0113
4.070
.5687
o. 01661
I
.0243
4
OIO
.4127
0-01785
.0236
6-375
.9127
O.OI53I
I
0394
5
925
.6225
0.01743
0359
7.380
I
.0682
0.01472
I
.0460
7
742
.8293
0-01667
.0477
13.612
2
.1222
0.01255
I
.0875
13
.510
I
5436
0.01436
.0865
HYDROGEN
148
SOLUBILITY OP HYDROGEN IN AQUEOUS SODIUM CARBONATE AND
SULPHATE SOLUTIONS AT 15.
(Gordon.)
In Sodium Carbonate. In Sodium Sulphate.
Gms. NaizCOs G.M.
per 100 Gms. Na2COa
Absorption
Coefficient
Gms. Na 2 SO 4 G. M.
per 100 Gms. Na2SO4
Absorption
Coefficient
Solution. per Liter.
of H.
Solution. per Liter.
of H.
2.15 O.2O7
0-01639
4-5 8 Q-33S
O.OI5I9
8.64 0.438
0.01385
8.42 0.638
0.0154
11.53 1.218
0.00839
16.69 1.364
0.00775
SOLUBILITY OF HYDROGEN IN AQUEOUS SOLUTIONS OF SODIUM
CHLORIDE.
(Braun; Gordon.)
Gms.NaCl
Coefficient of Absorption of Hydrogen at:
per 100 Gms.
Solution.
5-
10.
15.
20.
25.
1.25
0.0218
O.O2O5
O.OI9I
0.0177
0.0162
3.80
0.0198
0.0188
O.OI76
O.0l62
0.0148
4.48
0.0192
0.0l82
O.OI7I
O.OI59
0.0143
6.00
0.0184
0.0175
0.0164
0.0153
0.0138
14-78
0.0093
23.84
0.00595
SOLUBILITY OF HYDROGEN IN AQUEOUS SOLUTIONS OF SODIUM
NITRATE.
In Sodium Nitrate at 20. In Sodium Nitrate at 15.
(Knopp.) (Gordon.)
r ~
Normality
Absorption
\
Density
Gms.NaNOa
G.M.
Absorption
p-
(per 1000
Coefficient
of
per loo Gms.
NaNO 3
Coefficient
Gms. H 2 0).
of H. S
qlutions.
Solution.
per Liter.
of H.
1.041
0.1236
0.01839
.0052
5-57
0.679
0.01603
2 .192
0.2634
0.01774
.0130
II .16
I-4I3
0.0137
4-405
0.5416
0.01694
.0282
19.77
2.656
O.OIO52
6.702
o . 8442
O.OI5l8
.O44II
37-43
5-7II
0.00578
12.637
1-7354
O.OI3O
.08667
SOLUBILITY OF HYDROGEN IN ALCOHOL.
(Timofejew Z. physik. Chem. 6, 147, '90.)
o
6.2
13-4
18.8
Coefficient of Abs. in
08.8% Alcohol.
0.0676
0.0693
0.0705
O.O74O
4
18.8
Coefficient of Abs. in
99-7% Alcohol.
0.0749
0.0740
SOLUBILITY IN AQUEOUS ALCOHOL SOLUTIONS AT 20 AND 760 MM.
PRESSURE.
(Lubarsch Wied. Ann. [2] 37, 525, '89.)
Wt. % Alcohol.
o.oo
Vol. % Absorbed H.
i-93
Wt. % Alcohol.
28.57
Vol. % Absorbed H.
1.04
9.09
16.67
23.08
i-43
i .29
1.17
33-33
50.0
66.67
I.I7
2.02
2-55
149
HYDROGEN
SOLUBILITY OF HYDROGEN IN AQUEOUS SUGAR SOLUTIONS AT 15.
(Gordon Z. physik. Chem. 18, 14, '95.)
Gms. Sugar per
zoo Gms. Solution.
16.67
30.08
47 - 6 5
Gm. Mols. Sugar
per Liter.
0.520
0-993
1.699
Absorption
Coefficient of H.
0-01561
0.01284
0.00892
SOLUBILITY OF HYDROGEN IN WATER AND IN ORGANIC SOLVENTS.
Results in terms of the Ostwald Expression, see page 105.
(Just Z. physik. Chem. 37, 359, '01.)
Solvent. /2s- /so-
Amyl Acetate 0.0774 0.0743
Xylene 0.0819 0.0783
Ethyl Acetate 0.0852 0.0788
Toluene 0.0874 0.0838
Ethyl Alcohol (98.8%) o. 0894 o. 0862
Methyl Alcohol 0.0945 0.0902
Iso Butyl Alcohol 0.0976 0.0929
Solvent.
Water
Anilin
Amyl Alcohol
Nitro Benzene
Carbon Bisulphide
Acetic Acid
Benzene
Acetone
0.
o.
0.
0.
0.
0.
0.
0.
fa.
0199
0285
0301
0371
0375
0633
0756
0764
0.
o.
0.
o.
0.
0.
0.
0.
feo-
0200
0303
0353
0353
0336
0617
0707
0703
SOLUBILITY OF HYDROGEN IN CHLORAL HYDRATE SOLUTIONS
AT 20".
(Knopp.)
p-
Normality (per
1000 Gms. H 2 O).
Molecular
Concentration.
Absorption
Coefficient of H.
Density
of Solutions.
4.91
0.310
0.005594.
0-01839
I .O2O2
7.69
0.504
0-008992
0.01802
I .0320
14.56
1.030
0.0l8223
O.OI7I2
I .0669
29.50
2-530
0.04360!
O.OI542
1.1466
38.42
3-770
0.063647
0.01440
1.1982
49-79
6.000
0.097493
0.01353
1.2724
63.90
10.700
o. 161660
0.01307
1-3743
SOLUBILITY OF HYDROGEN IN PROPIONIC ACID SOLUTIONS.
(Braun.)
G. CaHsCOOH
Coefficient of Absorption of Hydrogen at:
per 100 Oms.
Solution.
5-
10.
15.
20.
25.
2 .63
0.02245
0.0214
O-O2OO
0.0188
0.0172
3-37
0.0222
0.0212
O.OI99
0.0187
0.0171
5-27
O.O224
O-02I2
0.0198
0.0184
0.0171
6.50
0.0218
O.O2O9
0.0193
0.0183
0.0169
9.91
0.0213
0.0203
O.OI9I
0.0178
0.0160
SOLUBILITY OF HYDROGEN IN PETROLEUM.
(Griewasz and Walfisz Z. physik. Chem. i, 70, '87.7
Coefficient of absorption at 20 = 0.0582, at 10 = 0.0652.
HYDROGEN SULPHIDE 150
HYDROGEN SULPHIDE H 2 S.
SOLUBILITY IN WATER AND IN ALCOHOL AT t AND 760 MM. PRESSURE.
(Bunsen and Carius; Fauser Math, u Natur. W. Ber. (Ungarn.) 6, 154, '88.)
In Water.
/
t .
i Vol
. H 2 Absorbs
ft.
3-
o
5
4
3
37
97
Vols. H 2 S(ato and
U
760 mm.) 4
4
.686
.063
.710
.615
10
J 5
20
2 5
3
3
2
2
59
2 3
.91
.61
U
3
3
2
.520
.056
.672
530
458
398
30
35
40
2
2
L
33
.08
.86
:
In Alcohol.
i Vol. Alcohol Absorbs
17.89 Vols. H 2 S(at o and 760 mm .)
14-78
11-99
9-54
7.42
5-96 (24)
For ft and q see Ethane, page 133.
SOLUBILITY OF HYDROGEN SULPHIDE IN AQUEOUS SALT SOLUTIONS
AT 25.
(McLauchlan Z. physik. Chem. 44 6cs, '03.)
NOTE. The original results are given in terms of -r which is the
LO
iodine titer (I) of the H 2 S dissolved in the salt solution divided by the
titer (/ ) of the H 2 S dissolved in pure water. These figures were multi-
plied by 2. 6 1 (see 25 results in preceding table) and the products
recorded in the following table as volumes of H 2 S absorbed by i vol.
of aqueous solution.
Solution.
Grams Salt
per Liter.
I Vols. H 2 S
lo. per i Vol. Sol
. Solution. G-.S.U
I Vols. H 2 S
/ . per i Vol. So*
n NH 4 Br
9 8,
,o
I.OO
2.61
n
KBr
119
.0
0.
945
2-47
n NH 4 C1
53-
4
0.96
2.40
n
KC1
74
5
O.
853
2. 22
n NH 4 NO 3
80
,o
0.99
2.58
n
KN0 3
101
.0
0.
913
2.38
Jn (NH 4 ) 2 S0 4
33
0.82
2.14
in
K 2 SO 4
43
5
0.
78
2.O4
in (NH 4 ) 2 S0 4
16.
5
o. 91
2.37
In
K 2 S0 4
21
7
o.
89
2.32
n NH 4 C 2 H 3 O 2
77.
j
1.09
2.84
n
KI
166
.0
0.
98
2. 5 6
n (NH 2 ) 2 CO
60,
, i
1.02
2.66
n
NaBr
103
.0
o.
935
2.44
\n HC1
18.
22
0-975
2-54
n
NaCl
58
5
0.
847
2.21
in H 2 SO 4
24.
5 2
0.905
2.36
in
NaCl
29
.2
o.
93
2.42
n C 4 H 6 6
150-
0.944
2.46
n
NaNO 3
85
.0
0.
893
2.32
3 n C 4 H 6 6
45o.
o
0.858
2. 24
in
Na 2 S0 4
35
5
0.
73
1.90
Pure C 3 H 5 (OH) 3
1000.
0.863
2.26
in
Na 2 S0 4
i7
.8
0.
89
2.32
HYDROQUINONE C 6 H 4 (OH) 2 i : 4 , also Resorcin C 6 H 4 (OH) 2 i : 3 and
Pyrocatechin C 6 H 4 (OH) 2 1:2.
SOLUBILIT.Y IN WATER.
(Vaubel J. pr. Chem. [2] 59, 30, '99.)
TOO grams solution contain 6.7 grams hydroquinone at 20. Sp. Gr.
of sol. = 1.012.
100 grams solution contain 63.7 grams resorcin at 20.
TOO grams solution contain 31.1 grams pyrocatechin at 20.
I5i HYDROQUINONE
SOLUBILITY OF HYDROQUINONE IN SULPHUR DIOXIDE IN THE
CRITICAL VICINITY.
(Centnerswer and Teletow Z. Electrochem. 9, 799, '03.)
Determinations made by the Synthetic Method, for which see Note,
page 9.
^o Gms. Hydroquinone ^ Gms. Hydroquinone t o Gms.Hydroquinone
per IOQ Gms. Sol. per 100 Gms. Sol. ' per 100 Gms. Solution.
63 0.89 117.6 4.46 136.7 10.31
73.5 1.22 123.3 5 - 66 141-4 13-3
89.2 2.l8 134.2 8.31 145-0 14-9
HYDROXYLAMINE NH 2 (OH). HYDROXYLAMINE HYDRO-
CHLORIDE NH 2 (OH).HC1.
SOLUBILITY IN SEVERAL SOLVENTS.
(de Bjxiyn Rec. trav. chim. n, 18, '92; Z. physik. Chem. 10, 783, '92.)
Grams NH 2 OH Grams NH 2 (OH).HC1
Solvent. t. per 100 Gms. t. per 100 Gms.
Solution. Solvent.
Methyl Alcohol (abs.) 5 35-o T 9-75 16.4
Ethyl Alcohol (abs.) 15 15.0 19-75 4-43
Ether (dry) (b. pt.) 1.2
Ethyl Acetate (b. pt.) 1.6
For densities of NH 2 (OH).HC1 solutions, see Schiff and Monsacchi
Z. physik. Ch. 21, 277, '96.
HYOSCYAMINE C 17 H 21 NO 3 .
SOLUBILITY IN SEVERAL SOLVENTS AT i8-22.
(Miiller Apoth.-Ztg. 18, 249, '03.)
Gms. C, 7 H 21 NO 3 Gms.Ci7H 2 iN
Solvent. per 100 Gms. Solvent. pe r I0 Gms.
Solution. Solution.
Water -355 Chloroform 100+
Ether 2.02 Acetic Ether 4-903
Ether sat. with H 2 O 3.913 Petroleum Ether 0.098
Water sat. with Ether 3 .125 Carbon Tetra Chloride 0.059
Benzene o . 769
HYOSCINE HYDROBROMIDE, etc.
SOLUBILITY IN SEVE.RAL SOLVENTS AT 25.
(U. S. P.)
. Grams per 100 Grams Solvent.
Solvent. Hyoscine
Hydrobromide
C, 7 H 21 N04.HBr.3H 2 0.
Hyoscyamine
Hydrobromide
C,7H23N0 3 .HBr.
Hyoscyamine
Sulphate
(C 17 H 23 N0 3 ) 2 .H 2 S04.
Water 66.6
very soluble
very soluble
Alcohol 6 . 2
50
15.6
Ether
0.062
0.04
Chloroform 0.133
40.0
0.043
IODINE
IODINE I.
*- e
Gms.
I per Liter
.
Solution.
15 O.272-O.283
25
0.279
25
0.304
25
0-339
25
0.340
30
0-457
152
SOLUBILITY IN WATER.
Authority.
(Dietz Pharm. Ztg. 43, 290, '98.)
(McLauchlan Z. physik. Chem. 44, 617, '03.)
(Herz and Knoch Z. anorg. Chem. 45, 269, '05.)
(Jakowkin Z. physik. Chem. 18, 590, '95.)
(Noyes and Seidensticker Z. physik. Chem. 27, 359, '98.)
(Dietz.)
SOLUBILITY OF IODINE IN AQUEOUS POTASSIUM IODIDE
SOLUTIONS AT 25.
(Noyes and Seidensticker; Bruner Z. physik. Chem. 26, 147, '98.)
Millimols^per Liter.
KI.
(I 2 ).
o.ooo
1.342
0.830
1.814
1.661
2-235
3-322
3-052
6.643
4.667
13.29
8.003
26.57
14.68
53-15
28.03
106.3
55-28
Gms. per Liter.
KI.
I.
O-OO
0.340
i-37
0.461
2-75
0.568
5'S 1
0-775
11.03
1.185
22 .07
2.032
44-I5
3.728
88.3
7.II9
176.6
14.04
Results by Bruner.
Gms. KI per Gms. I
1000 g. Sol. per Liter.
10 0.78*
20 1. 60
40 3- 2 5
60 5 04
80 6 . 94
100 8 . 96
* There is some uncertainty in regard to the position of the decimal point in this column,
lation from the original it should be one place further to the right.
By caku
SOLUBILITY OF IODINE IN AQUEOUS SALT SOLUTIONS AT 25.
(McLauchlan.)
Gms. Salt Gms. Dissolved I
per Liter. per Liter.
Salt.
Gms. Salt Gms. Dissolved I
per Liter. per Liter.
Na,S0 4
29.77
0.160
K 2 SO 4
43-5
0.238
(NH 4 ) 2 S0 4
33-o
0.246
NaNO 3
85.0
0.257
KN0 3
IOI .2
0.266
NH 4 NO 3
8o.O
o-375
NaCI
58-5
0-575
KC1
73-6
0.658
Salt.
NH 4 C1
NaBr
KBr
NH 4 Br
NH 4 C 2 H 3 2 77-1
(NH 4 ) 2 C 2 H 4 86.9
H 3 B0 3 55.8
53-4
103.0
119.0
08.0
o-735
3-29
3.801
4.003
0.440
0.980
0.300
SOLUBILITY OF IODINE IN ARSENIC TRI CHLORIDE.
(Sloan and Mallet Chem. News, 46, 194, '82.)
t. o. 15 . 96.
Gms. I per 100 gms. AsCl 3 8.42 n.88 36.89
153 IODINE
SOLUBILITY OF IODINE IN AQUEOUS ETHYL AND NORMAL PROPYL
ALCOHOL SOLUTIONS AT 15.
(Bruner Z. physik. Chem. 26, 147, '98.)
In Aq. Ethyl Alcohol. In Aq. Propyl Alcohol.
Gms. Gms.
Gms.
Gms.
Gms.
Gms.
Gms.
Gms
C 2 H6OH I per
per 100 Gms. 100 cc.
Solvent. Solution.
C 2 H 5 OH
per 100 Gms.
Solvent.
I per
100 CC.
Sol.
CaHyOH
per loo Gms.
Solvent .
I per
100 CC.
Sol.
C 3 H 7 OH
per loo Gms.
Solvent.
I per
loo cc.
Sol.
10 0.05
60
I.I4
10
0-05
60
2.71
2O O-o6
70
2-33
20
O.II
70
4-10
30 o.io
80
4.20
30
0.40
80
6.05
40 0.26
90
7-47
40
0.94
90
9.17
50 0.88
100
i5- 6 7
50
1.64
100
M-93
SOLUBILITY OF IODINE IN BENZENE, CHLOROFORM, AND IN ETHER.
(Arctowski Z. anorg. Chem. n, 276, '95-'Q6.)
In Benzene.
In Chloroform.
In Ether.
t.
Gms. I per 100
Gms. Solution.
A o Gms. I per 100 .
Gms. Solution.
Gms. I per ioo
Gms. Solution.
4-7
8.08
-49
0.188
-83
15-39
6.6
8.6 3
-55i
0.144
-90
14-58
10.5
9.60
-60
0.129
-108
15.09
13-7
10-44
-6 9 i
0.089
16.3
11.23
-73i
0.080
+ 10
i . 76 pe
r ioo gms. C
:HCL
SOLUBILITY OF IODINE IN BROMOFORM, CARBON TETRA CHLORIDE, AND
IN CARBON BISULPHIDE AT 25.
(Jakowkin Z. physik. Chem. 18, 590, '95.)
i liter of saturated solution in CHBr 3 contains 189.55 g ms - I
i liter of saturated solution in CC1 4 contains 30.33 gms. I.
i liter of saturated solution in CS 2 contains 230.0 gms. I.
SOLUBILITY OF IODINE IN CARBON BISULPHIDE SOLUTIONS.
(Arctowski Z. anorg. Chem. 6, 404, '94.)
+ o Gms. I per ioo
Gms. Solution.
t .
Gms. I per ioo
Gms. Solution.
t.
Gms. I per ioo
Gms. Solution.
ioo
0.32
o
7.89
30
19.26
-80
0.51
IO
10.51
36
22 .67
63
1 .26
15
12-35
40
25.22
-2O
4.14
20
14.62
42
26.75
10
5-52
2 5
16.92
IODINE 154
SOLUBILITY OF IODINE IN MIXTURES OF CHLOROFORM AND ETHYL
ALCOHOL, CHLOROFORM AND NORMAL PROPYL ALCOHOL, CHLOROFORM
AND BENZENE, AND CHLOROFORM AND CARBON BISULPHIDE AT 15.
(Bruner.)
Cms. CHC1 3
Grams I Dissolved per
A
ioo cc. of Mixtures of:
of Mixtures. CHCl3 + C 2 H 5 OH. CH 3 C1 + C 3 H 7 OH
. CH 3 C1 + C 6 H 6 .
CH 3 C1 + CS 2 .
O
15.67
14-93
IO.4O
17.63
IO
9-43
13.16
9.84
J 5-93
20
8.69
ii .20
8.78
14.20
30
7.80
8.98
7-74
12. 16
40
7.09
8.09
6.96
IO.2O
50
6.62 .
7.82
6. 20
Q.OS
60
6.24
7.09
5-34
7.72
70
5-77
6.42
4.89
6.42
80
5 -06
5-54
4-53
S- 2 7
QO
4-34
4-52
4.07
4-32
100
3.62
3.62
3-62
3 .62
SOLUBILITY OF IODINE IN MIXTURES OF CARBON TETRA CHLORIDE AND
BENZENE AND IN MIXTURES OF CARBON TETRA CHLORIDE
AND CARBON BISULPHIDE AT 15.
(Bruner.)
Cms. CCU per Cms. I per ioo cc. of Mixture of: Gms. CCUper Gms. I per ioo cc. of Mixture
' CC1 4 + CS 2 . 'SffctSw. CC1 4 + C 6 H 6 . ' CC1 4 +CS 2 .'
o 10.40 17.6 60 4.90 5.55
10 9.44 14-44 7 4-09 4-50
20 8.53 12.33 8 o 3-4i 3-37
30 7.77 10.34 90 2.74 2.60
40 6.63 8.60 ioo 2.06 2.06
50 5.70 6.83
SOLUBILITY OF IODINE IN AQUEOUS GLYCERINE SOLUTIONS
AT 25.
(Herz and Knoch Z. anorg. Chem. 45, 269, '05.)
Density of glycerine at 25/4 = I - 2 555I impurities about 1.5%
Wt.% Glycerine Millimols I Grams I per Density of
inSolvent. per ioo cc. Solution. loocc. Solution. Solutions at 25/ 4.
o 0.24 0.0304 Q-9979
7.15 0.27 0.0342 .0198
20.44 0-38 o'.o482 -0471
31.55 0.49, 0.0621 -0750
40.95 0.69 0.0875 -995
48.7 1.07 0.135 .1207
69.2 2.20 0-278 I 7 6 S
100.0 9.70 1-223 .2646
155
IODINE
DISTRIBUTION OF IODINE BETWEEN CARBON BISULPHIDE AND
AQ. POTASSIUM OXALATE.
(Dawson Z. physik. Chem. 56, 610, '06; Dawson and McRae J. Chem. Soc. 81, 1086, '02.)
Cms. I per Liter of
Concentration
of
Aq. K 2 C 2 4 .
i .o Equiv.
1.0 "
1.0 "
Aq. Layer.
2.408
3-555
5.766
6.861
CS 2 Layer.
10.82
16.32
27.91
34-Qi
17.07
Vol. of Solution
which Contains
i Mol. I.
105-3
71-37
43-99
36.98
71.97
Fraction of I
Uncombined
in Solution.
0.005495
o 005915
l.o", 6. SOI 34-01 30 .98 0.006055
1.2 3.525 17.07 71.97 0.005645
DISTRIBUTION OF IODINE BETWEEN AMYL ALCOHOL AND WATER AND
BETWEEN AMYL ALCOHOL AND AQUEOUS POTASSIUM IODIDE
SOLUTIONS AT 25.
(Herz and Fischer Ber. 37, 4752, '04.)
The original results were plotted on cross-section paper, and the
following tables made from the curves.
Millimols I per 10 cc
JxUlUUKUo J. p
cr 10 uc. u
i n 2 w aiiu oi /v
4. rv.i x^ayen
5.
Amyl Alcohol Layer
'""
N
2N
jj
4N
N "*
in Each Case.
HaO.
K.I.
KI
K 1 .
KI
JfT
10
10
10
10
IO
2-5
0.012
0-135
0.160
O.I7O
0.170
3-o
O.OI4
0.150
0.185
O-2OO
O.2OO
0.160
4-0
O-Ol8
0.180
0-235
0-255
0.270
0.240
5
0-021
O.2IO
0.280
o-3 J 5
0-340
0-315
6
O.O25
0.230
0.330
0-375
O.4IO
0.390
7
0.029
0.250
o-375
0.430
0.480
0.470
8
0.260
0.420
0.490
0-550
o-555
9
0.270
0.450
o-55o
O.62O
0.640
10
O.28o
0.470
0.605
0.690
0.720
12
0.490
0.700
0-830
0.900
14
0.510
0.790
0.980
I .200
20
0-575
Gms.I per 100 cc.
Amyl Alcohol Layer
Gms. I per
100 CC. Of
H 2 O and of KI
Layers.
N
N
N
N
N ^
in Each Case.
H 2 0.
K. I
'KL
KI
KI
KI.
IO
IO
JO
10
IO
3
O.OI4
0.164
O.2O
O.2I
O.2I
4
0.016
0.196
O.24
O.26
O.26
0.21
6
0.026
0.252
0-34
0.38
O.40
o-37
8
0-033
0.297
o-43
0-49
o-54
0.51
10
0-040
0.328
0.51
0.61
0.67
0.69
12
0.341
0-58
o-73
0-81
0.84
H
. . .
0.60
0.83
o-95
i .00
16
0.63
0.91
1.09
i .20
18
0.64
25
0.71
The original figures for sN/io and loN/io KI solutions give prac-
tically identical curves.
Results for the distribution of Iodine between N/io KI solutions on
the one hand, and mixtures in various proportions of C 6 H + CS 2 ,
C 6 H 5 CH 3 + CS 2 , C 6 H 6 + C 6 H 5 CH 3 , C 6 H 6 + light petroleum, CS 2 + light
petroleum, CS 2 +CHC1 3 , CHC1 3 + C 6 H 6 , CC1 4 + CS 2 and CC1 4 + C 6 H 8 CH 3
on the other hand, are given by Dawson J. Chem. Soc., 81, 1086, '02.
IODINE 156
DISTRIBUTION OF IODINE BETWEEN WATER AND BROMOFORM, WATER
AND CARBON BISULPHIDE, AND WATER AND CARBON
TETRA CHLORIDE AT 25.
(Jakowkin Z. physik. Chem. 18, 590, '95.)
Original results plotted on cross-section paper and table made from curves. Jakowkin points out that
the results of Berthelot and Jungfleisch Ann. chini. phys. [4] 26, 400, '72, are incorrect on account of
the presence of HI.
Grams I per Liter of Grams I per Liter of:
H 2 Layer in Each Case. CRBr3 ^ C S 2 Layer. CCU Layer.
0.0$ 20 30 4-0
o.io 45 60 8 -5
0.15 71 9 1 J3-0
0.20 100 126 17.5
0.25 130 l6o 22.0
IODOFORM CHI 3 , IODOL C 4 I 4 NH (Tetra lodo Pyrrol).
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P. ; Vulpius Pharm. Centrh. 34, 117, '93.)
,. t * o Grams per loo^Grams Solvent.
CHjjL CJ 4 NH.
Water 25 0.0106 0.0204
Alcohol 25 2.14 (1.43 gms. (V.)) n.i
Alcohol b. pt. (10.0 gms. (V.)) . . .
Ether 25 19.2 (16.6 gms. (V.)) 66.6
Chloroform 25 ... 0.95
IRIDIUM DOUBLE SALTS.
SOLUBILITY IN WATER.
(Palmaer Ber. 23, 3817; 24, 2000, '91.)
Double Salt. Formula. f. G g^
Irido Pentamine Bromide Ir(NH 3 ) 5 Br 3 12.5 0.284
Bromonitrate Ir(NH 3 ) 5 Br(NO 3 ) 2 18 5.58
" '* Trichloride Ir(NH 3 ) 5 Cl 3 15.1 6.53
" " Chloro Bromide Ir(NH 3 ) 5 ClBr 2 15 0.47
Chloro Iodide Ir(NH 3 ) 5 ClI 2 15 0.95
Chloro Nitrate Ir(NH 3 ) 5 Cl(NO 3 ) 2 15.4 1.94
Chloro Sulphate Ir(NH 3 ) 5 ClSO 4 . 2 H 2 O 15.0 0.74
Nitrate Ir(NH 3 ) 5 (NO 3 ) 3 16 0.28
" Aquo Pentamine Bromide Ir(NH 3 ) 5 (OH 2 )Br 3 ord. temp. 25 . o
" " Chloride Ir(NH 3 ) 5 (OH 2 )Cl 3 ord. temp. 74.7
" " " Nitrate Ir(NH 3 ) 5 (OH 2 )(NO 3 ) 3 17 10.0
IRON BROMIDE (Ferrous) FeBr 2 .6H 2 O.
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 537, '94.)
t<>.
Gms. FeBr 2
per 100 Gms. Sol.
t.
Gms. FeBr 2
per loo Gms. Sol.
t.
Gms. FeBr 2
per too Gms. Sol.
20
47-0
3o
55-o
60
S9-
5o-5
40
56.2
80
6i. S
20
53-5
IOO
64.0
IRON CARBONATE (Ferrous) FeCO 3 .
100 gms. H 2 O saturated with CO 2 at 6-8 atmospheres dissolve 0.073
gram FeCO 3 . (Wagner Jahresber. Chem. 135, '67.)
157
IRON CHLORIDE
IRON CHLORIDE
(Ferrous) FeCl 2 .4H 2 O.
(Etard.)
SOLUBILITY IN WATER.
t.
Gms. FeCl 2
per loo Gms
Solution.
Solid Phase.
10
39-2
FeCl 2 . 4 H 2
15
40.0
"
25
4i-5
u
30
42.2
(t
40
43-6
11
50
45-2
u
60
80
87
90
IOO
120
Gms. FeCl 2
per loo Gms.
Solution.
47-o
50.0
51.2
51-4
5 1.8
SoHd Phase.
FeCl 2 .4H 2 O
FeCl 2 . 4 H 2 + FeCl 2
FeCl 2
SOLUBILITY OF IRON CHLORIDE
(Roozeboom Z. physik.
Mols.Fe 2 Cl 6 Gms - Feds per 100
t. per loo Mols, Gms.
H 2 0. H 2 0. Solution.
Solid Phase, Fe 2 Cl 6 .i2H 2 O.
2-75 49-52 33' 12
2-98 53-6o 34-93
4-i3 74-39
91.85
106.8
150.0
201 .7
23I.I
246.7
-55
-27
o
+ 20
30
37
42.66
47.88
51-64
60. 01
66.85
69.79
71.15
5-10
5-93
8-33
30 11.20
2O 12.83
8 13-7
Solid Phase, Fe 2 Cl 6 .7H 2 O.
20 11-35 204.4 67.14
32 13-55 244.0 70.92
30 15.12 272.4 73- J 3
25 15.54 280.0 73.69
Solid Phase, Fe 2 Cl.5H 2 O.
12 12.87 231.8 69.87
27 14.85 267.5 72.78
(FERRIC) Fe 2 Cl 6 IN WATER.
Chem. 10, 477, '92.)
Mols. Fe 2 Cle Gms - FeQ 3 per 100
t. per loo Mols. Gms.
HzO. R 2 0. Solution.
Solid Phase, Fe 2 Cl 6 .sH 2 O (con.).
35 J 5- 6 4 281.6 73.79
50 17-50 3*5-2 75-9 1
55 19-iS 344-8 77.52
55 20.32 365.9 78.54
Solid Phase, Fe 2 Cl6.4H 2 O.
So 19-96 359-3 78-23
55 20.32 365.9 78.54
60 20.70 372.8 78.86
69 21.53 387.7 79.50
73.5 25.0 450-2 81.81
70 27.9 502.4 83.41
66 29.2 525.9 84.03
Solid Phase, Fe 2 Cl & .
66 29.2 525.9 84.03
75 28.42 511.4 83.66
80 29.20 525.9 84.03
loo 29.75 535-8 84.26
SOLUBILITY OF FERRIC CHLORIDE IN AQUEOUS SOLUTIONS OF
AMMONIUM CHLORIDE AT 25, 35, AND 45.
(Mohr Z. physik. Chem. 27, 197, '98.)
Results at 25. Results at 35. Results at 45.
Solid Phase
in Each Case.
Fe 2 Clfl.i2H 2 0(sB 2 Oat4S )
Hydrate + Double Salt
Double Salt
Double Salt + Mixed Crystals
Mixed Crystals
NH4C1
Mols. per
loo Mols. H 2 O.
Mols. per
loo Mols. H 2 0.
Mols. per
loo Mols. H 2 O.
NH 4 C1.
Fe 2 Cl 6 .
10.98
NH4C1.
Fe 2 Cl. 6 .
I3-36
NH 4 C1.
o.o
Fe 2 Cl 6 .
33-4
i-S7
10-74
1.41
J 3-o5
2.48
9-O2
3.08
9.28
4.08
9-58
5-28
7-73
6.98
7.64
9-59
6-77
10.76
6.70
13.09
6.31
9-83
6.70
II .60
6.52
13-54
6.28
9-65
6.07
12.28
6.08
12.91
5-49
9-93
5-23
n-57
3-98
J 3-49
4.84
9.92
3-97
11.89
3-38
13.46
4.99
10.31
2.05
13-23
1 38
13-30
0-0
14.79
o.o
16.28
o.o
IRON CHLORIDE
158
SOLUBILITY OF
Mols.per TOO Mols.HgO
NBUCl.
Fed*.
'NH 4 C1.
FeCl 3 .
o.o
9-30
o.o
83.88
1.09
9-57
3-24
86.32
I. 3 6
9-93
4-03
91 .6l
2 .OO
9.27
5-92
83.64
2.79
8.71
8.31
78.77
4-05
8.09
12.08
73-20
6.41
7.18
19.12
64-83
10.78
6.21
32.04
56.00
7-82
6-75
23.21
60.83
7.62
5-94
22 .63
53-47
7.70
5-03
22 .90
45-42
7 .8l
4-34
23-23
39-13
8-52
2.82
25-33
25-43
10-95
0.68
32-55
6.15
11.88
o.o
35-30
o.o
Solid
Phase.
Fe 2 Cl 6 .i2H 2 O
FERRIC CHLORIDE IN AQUEOUS SOLUTIONS OP
AMMONIUM CHLORIDE AT 15.
(Roozeboom Z. physik. Ch. 10, 148, '92.)
Grams per TOO Gms. H 2 O .
Fe 2 Cl 6 .i2H 2 O -f Double Salt
Double Salt
Mixed Crystals containing 7.29% FeCla
5 -55 "
4-4 "
3-8
. 3I
NH4C1
SOLUBILITY OF FERRIC CHLORIDE IN AQUEOUS HYDROCHLORIC ACID
SOLUTIONS AT DIFFERENT TEMPERATURES.
(Roozeboom and Schreinemaker Z. physik. Chem. 15, 633, '94;)
,0.
Gms. per 100 Gms.
H 2 0. Solid
Mols. per 100 Mols. Gms. per 100 Gms.
H 2 0. H 2 0. Solid
' HC1.
FeCl 3 .
HCl.
FeCl 3 . Ph ase-
HCl.
FeCl 3 .
HCl.
FeCl 3 .
Phase.
Results at o.
Results at
25 (con.).
O
8.25
74-
3'
O
.0
29.00
0.0
261.!'
7-52
6. 5 I
15.22
58-
62
7
5
29-75
15.18
267.9
Fe 2 Cle
cHoO
13-37
6-33
27.06
57-
01
19
5
35-25
39.46
3 J 7-4>
5 n y^
16.80
8.70
33-99
78.
34
19
.5
35-25
39.46
3 I 7-4l
18.45
10.23
37-34
92-
10
.Fe 2 Cl 6
20
.6
35-34
41.68
318.3
20.40
15.40
41.28
138.
7
.i2H 2 O
31
34
41.58
63.42
374-4
e2 . 4 H2O
20.10
16.00
40.67
144.
i
33
.00
43.00
66. 77
387.3
19-95
17.70
40.37
159-
4
34
-65
44.80
70.11
403. 4 >
19.00
18.05
22.75
23.41
38.45
36.53
204.
2IO.
8
8 ,
40
39
.41
-03
40. 25
41.38
81.77
78. 9 8
362.4-]
372.7
- F ^HC,
18.05
23.40
36.53
210.8 JFeaClfl
35
-74
45-24
72.33
407. 4J
+ 4 H 2
I9-50
25-93
39-55
233.5 ) - 7H2
Results at 40.
24. 12
26.00
26.00
34.60
37-27
34.60
30.04
32. 16
32.16
38.11
36.60
38.11
48.81
52.60
52.60
70.01
75-4i
70.01
270.
289.
289.
343-
329-
343-
5
6
6
2
6
2
"*&(>
F -?3&
13-4
13-4
27.0
32.4
37-45
37-45
50.80
58.0
50.8
0.0
27. II
27.11
54.64
0.0
291.7
337-3
337-3
457-5.
522. 3'
Fc *%>
**%>
Results at 25.
42
.01
48.64
85.00
438-0,
0.0
2-33
10.90
23-72
o.o
4.715
98.
213.
6 5 } F Sao
42
42
50
.01
47-52
48.64
86.72
85.00
fir c *Hc>
438.0) + 4 H 2
0.0
24-5
0.0
220
7 J
0.0
23-5
0.0
211.
6 ]
Results for other temperatures
2.33
23-72
4.715
213-
4 lFe 2 Cl6
are
also given in
the original
7-50
29-75
15.18
267.
9 j .?H 2 O
paper.
o.o
3i-5o
o.o
283.
6 }
159
IRON CHLORIDE
SOLUBILITY OF THE SALT PAIR FeCl a .NaCl. IN WATER AT 21.
(Hinrichsen and Sachsel Z. physik. Chem. 50, 94, 'o4-'os.)
Grams Used.
Gms. per 100
Gms. Solution.
G. Mols. per
iooMols.H 2 O. Solid
FeCl a . NaCl.
FeCl 3 . NaCl.
FeCl 3 . NaCl.
o 3.6
o 36-10
O 1 1 . 2 NaCl
1.8 3.0
24.27 9.10
2 . 69 2.8 Mix Crystals
3-6 2.5
25.40 8.45
2.8l 2.6
5-5 2.0
26.40 5 .25
2-93 2.54
7-2 1-5
38-15 3-9o
4.23 1.22
9.0 i.o
45 -3 8 2.45
5-03 0.75
10.8 0.5
46.75 2. ii
5.18 0-65
10.8 o.o
83.39 o-o
9.3 0.0 FeCla
SOLUBILITY OF
THE SALT PAIR FeCl a
,.KC1 IN WATER AT 21.
(H. and S.)
Grams Used.
Gms. per 100
Gms. Solution.
Gm . Mols. per 100
Mols. H 2 0. Solid
FeCl 3 . KC1/
FeCl 3 . KC1. '
-FeCl 3 . ' KCi: PhaSe '
35
o 34-97
8.45 KCI
13 28
13.44 24.45
I . 49 5-9O Mix Crystals
18 21
23.18 16.54
2-57 3-99
23 18.5
28.05 11-69
3-II 2.82
28 16
35.72 11.68
3.96 2.82
3i 10.5
36-62 11.19
4 . 06 2 . 70 Double Salt
36.2 9
37-35 13-67
4-i4 3-3
46.5 6
5^69 7-54
5.73 1.82
J 5"5 o
83.89 o.o
9-3 0.0 FeCl 3
SOLUBILITY OF
THE SALT PAIR FeCl 3 .
CsCl IN WATER AT 21.
(H. and S.)
Grams Used.
Gms. per 100
Gms. Solution.
Gm. Mols. per 100
Mols. H 2 0. Solid
FeC] 3 . CsCl.
FeC] 3 . CsCl.
'Fed,. ' CsCL
o 65
o.o 65.0
O.O 6.95 CsCl
O.6 II .6
o-45 55 - l8
'5 5-9 FeCls-CsCLHaO
1-4 10.2
2.1 52.38
0.23 5.6
2.2 8.8
5.24 51.44
o-57 5-5
2.0 7.4
7.8 47.70
0.86 5.1 FeCl 3 .2CsCl.H 2 O
3.8 6.0
8.93 41.15
0.99 4.4
4-6 4.6
J 5-34 25.25
1.70 2.7
5-4 2.8
21.65 14.96
2 . 40 1.6
6.2 1.4
27.96 8.42
3.10 0.9
35-0 0.2
48.71 0-94
5-40 o.i
35.0 o.o
83.89 o.o
9.3 o.o FeCi 3
100 gms. abs. acetone dissolve 62.9 gms. FeCl 3 at 18.
(Naumann Ber.37, 4332, '04.)
IRON NITRATE 160
IRON NITRATE (Ferrous) Fe(NO 3 ) 5
Solid
Phase.
-27 35-66 5.54 Fe(N0 3 ) 2 . 9 H 2 ~9 39-68 6.57 Fe(NO 3 ) 2 .6H 2 O
-21-5
-15-5
Density of solution saturated at 18 = 1.497.
IRON OXIDES, HYDROXIDE and SULPHIDE.
SOLUBILITY IN AQUEOUS SUGAR SOLUTIONS.
(Stolle Z. Ver Zuckerind. 50, 340, 'oo.)
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt 3, 438, 'oo.)
Cms.
Mols.
Gms.
Mols.
Fe(NO 3 ) 2
Fe(N0 3 ) 2 S()lid
Fe(N0 3 ) 2
Fe(N0 3 ) 2
per loo
Gms.
^ r ois~ -
t .
per 100
Gms.
per 100
Mols.
Sol.
H 2 O.
Sol.
H 2 0.
35-66
5 54 Fe(N0 3 ) 2 .9H 2
-9
39.68
6-57
36.10
5 64
41 .53
7-10
36-56
5.76
18
45-14
37-17
5.91
24
46.51
8.70
60.5
62.50
16.67
7 Sugar One Liter of Sugar Solutions Dissolves Milligrams of:
in Sol- Fe 2 (OH) 6 at: Fe 2 O 3 at: Fe 3 O 4 at:
FeS at:
vent.
17-4.
45
75.
17-5.
45.
17-5.
45-
75.
17-5.
45.
75. '
10
3-4
3-4
6.1
1.4
2 .O
10-3
10-3
12-4
3-8
3-8
5-3
30
2-3
2.7
3-8
1.4
12-4
10-3
12-4
7-i
9.1
7-2
50
2-3
1.9
3-4
0.8
I.I
14-5
10-3
14-5
9-9
19.8
9.1
IRON PHOSPHATE Fe 2 (PO 4 ) 3 .
THE ACTION OF WATER AND OF AQUEOUS SALT SOLUTIONS UPON
FERRIC PHOSPHATE.
(Lachowicz Monatsh. Chem. 13, 357, '92; Cameron and Hurst J. Am. Chem. Soc. 26, 888, '04.)
The experiments show that the ordinary precipitation methods for
the production of ferric phosphate give products which do not conform
to the formula Fe 2 (PO 4 ) 3 . By digesting such samples with water
very little is dissolved, but the material is decomposed to an extent
depending upon the relative amounts of solid and solvent used. The
amount of PO 4 dissolved per gram of Fe 2 (PO 4 ) 3 varies from about
0.0026 gram removed by 5 cc. H 2 O to 0.0182 gram removed by 800 cc.
H 2 O at the ordinary temperature.
IRON SULPHATE (Ferrous) FeSO 4 .7H 2 O.
SOLUBILITY IN WATER.
(Franckel Heidelberg '05, Landolt and Bernstein's Tabellen, 3d ed. p. 537, '06.)
Cms. FeSO 4 -,.. Cms. FeSO 4 ,,..
t. per 100 ? lld t. per TOO lld
Gms.H 2 0. Phase " Gms.H 2 0. Phase '
I . 82 14 . 98 Ice+FeSO 4 .7H 2 O 56.6 54 . 58 FeSO 4 -7H 2 O -f- FeSO 4 .4H 2 O
O I5-62 FeSO 4 -7H 2 O 60 55 - 2 FeSO 4 -4H 2 O
10 20.85 " 70 56.04
20 26.42 75.8 56.8 FeS0 4 . 4 H 2 + FeS0 4 .H 2
30 33-00 " 80 50.6 FeS0 4 .H 2 O
40 40.20 90 43.0
50 48.55
ioo grams sat. solution in Glycol contain 6.0 grams FeSO 4 at ordi-
nary temperature. (de Coninck.)
161 IRON POTASSIUM SULPHATE
IRON POTASSIUM SULPHATE (Ferrous) FeSO 4 .K 2 SO 4 .6H 2 O.
SOLUBILITY IN WATER.
(Tobler Liebig's Ann. 95, 193, '55.)
t.
Cms. K 2 Fe(S0 4 )2
per 100 Grams
H 2 0.
o
19.6
10
24-5
14.5
16
25
29.1
30-9
36.5
t.
Cms. K2Fe(S0 4 ) 2
per loo Grams
H-jO.
35
41-0
40
45 -o
55
56.0
65
57-3
70
64.2
SOLUBILITY OF MIXTURES OF FERROUS SULPHATE FeSO 4 .7H 2 O AND
SODIUM SULPHATE Na 2 SO 4 .ioH 2 O IN WATER.
(Koppel Z. physik. Chem. 52, 405, '05.)
Gms. per 100 Gms.
t. Solution.
Gms. per TOO Gms.
H 2 0.
FeS0 4 .
Na 2 SO 4 .
FeSO 4 .
Na 2 SO 4 .
O
14.
54
4-93
18
.06
6
.11
15-5
i7-
76
ii
32
25
05
I 5
97
21.8
16.
57
15
32
24
34
22
5 1
24.92
16.
21
15
13
23
.62
22
.04
35
16.
35
14
.98
23
.91
21
83
40
16.
37
15
.42
24
.01
22
.62
18.8
18.
13
.8
26
63
20
.28
23
19.
58
12
5
28
.82
18
4
27
20.
97
II
3
30
95
16
.64
3 1
22 .
91
9
.71
33
99
14
.41
35
23-
85
9
.26
35
.61
13
85
40
26.
3 2
7
85
39
.98
II
.92
18.8
18.
23
14
83
27
2 3
22
.16
23
13 .
83
18
.04
20
.31
26
.48
28
7-
66
24
.41
ii
.28
35
94
31
4-
58
29
5
6
95
44
75
35
4-
04
30
49
6
.16
46
-58
40
4-
10
30
.60
6
27
46
99
Solid Phase.
FeSO 4 .7H 2 O + Na 2 SO 4 .ioH 2 O
FeNa 2 (S0 4 ) 2 . 4 H20
FeNa 2 (SO 4 ) 2 .4H 2 + FeSO 4 .7H 2 O
FeNa 2 (SO 4 ) 2 . 4 H 2 O + Na 2 SO 4 .ioH 2 O
FeNa 2 SO 4 4H 2 + Na a SO 4
(Marignac.)
LANTHANUM BROMATE 162
LANTHANUM BROMATE La(BrO 3 ) 3 .9H 2 O.
100 gms. H 2 O dissolve 28.5 gms. lanthanum bromate at 15.
LANTHANUM SULPHATE La 2 (SO 4 ) 3 .
SOLUBILITY IN WATER.
(Muthmann and Rolig Ber. 31, 1723, '98.)
Gms. La 2 (SO 4 ^3 per 100 Gms. Gms.La 2 (SO 4 ) 3 per looGi
Solution. Water.' Solution. Water.'
o 2.91 3.0 50 1.47 1.5
14 2.53 2.6 75 0.95 0.96
30 1.86 1.9 100 0.68 0.69
LEAD Pb.
MUTUAL SOLUBILITY OF LEAD AND ZINC.
(Spring and Romanoff Z. anorg. Chem. 13, 34, '96.)
Upper Layer. Lower JLayer. Upper Layer. Lower Layer.
2-J/1
%pb.
98 8
%Zn.
I 2
%pb.
C7
Zn.
6^0
%p
82
b. %Z
OT*7
n.
7f)
%Zn/
GOT"
419
Q2 -O
8.0
i-5
9 8
5
740
800
6
79-
*7
21
O 2 C
O
Q
.0
IO-O
14 o
93 -
90.0
86 o
475
584
91 .0
86.0
9.0
14.0
2.0
5-o
9 8
95
O
.0
900
910-920
59-
(crit.
u ^5
o 41
temp.
.0
)
25-5
74-5
LEAD ACETATE Pb(C 2 H 3 O 2 ) 2 . 3 H 2 O.
SOLUBILITY IN SEVERAL SOLVENTS.
Solvent.
(U. S. P.)
Grams Pb(C 2 H 3 O 2 ) 2 per 100 Grams Solvent at:
25. b. pt.
Water 50 200
Alcohol 3.3 ioo
Alcohol (0.941 Sp. Gr.) 12.5 (per ioo cc. at 15 .5)
Glycerine 20.0 (15)
LEAD BENZOATE Pb(C 7 H 6 O 2 ) 2 .H 2 O.
SOLUBILITY IN WATER.
(Paietta Gazz. chim. ital. 36, II, 67, '06.)
t. 18. 40.6. 49.5.
Gms. Pb(C 7 H 5 O 2 ) 2 .H 2 O
per ioo gms. sat. solution 0.149 0.249 0.310
LEAD BROMATE Pb(BrO 3 ) 2 .H 2 O.
ioo gms. cold water dissolve 1.33 gms. lead bromate.
(Rammelsberg Pogg. Annalen. 52, 96, '41; Bottger Z. physik. Chem. 46, 602, '03.)
LEAD BROMIDE
163
PbBr 2 .
SOLUBILITY IN WATER.
(Lichty J. Am. Chem. Soc. 25, 474, '03.)
LEAD BROMIDE
Density
t of Solutions
Gms. PbBr2 per 100
Milligram Mols. PbBf2 per too
H 2 O at o.'
cc. Solution.
Gms. H 2 O.
cc. Solution.
Gms. H 2 O.
o 1-0043
Q-4554
0-4554
I .242
I .242
15
0053
0.7285
0.7305
1.987
1.989
25
.0061
0.9701
0-9744
2 .646
2-655
35 ^
.0060
1.3124
i .3220
3-577
3-603
45
.0059
J -7 2 59
I -7457
4-705
4-760
55
.0046
2 .IO24
2.1376
5-73i
5-827
65
.0028
2.516
2-574
6.859
7.0l6
80
.0000
3-235
3-343
8.819
9-II3
95 0.9995
4.1767
4-3613
11.386
I I . 890
IOO
4-550
4-75 1
12.40
12.94
SOLUBILITY OF LEAD BROMIDE IN AQUEOUS HYDROBROMIC ACID
AT 10.
loo grams H 2 O containing 72.0 grams HBr dissolve 55.0 grams
PbBr 2 per 100 gms. solvent, and solution has Sp. Gr. 2.06.
(Ditte Compt. rend. 92, 719, '81.)
LEAD CARBONATE PbCO 3 .
SOLUBILITY IN WATER BY ELECTRICAL CONDUCTIVITY METHOD.
(Kohlrausch and Rose Z. physik. Chem. 12, 241, '93; Bottger Ibid. 46, 602, '03.)
i liter of water dissolves o.oon 0.0017 gram PbCO 3 at 20.
LEAD CHLORATE Pb(ClO 3 ) 2 .
loo grams H 2 O dissolve 151.3 grams Pb(ClO 3 ) 2 , or 100 grams sat.
solution contain 60.2 gms. Pb(ClO 3 ) 2 at 18. Density of solution, 1.947.
(Mylius and Funk Ber. 30, 1718, '97.)
LEAD CHLORIDE PbCl 2 .
SOLUBILITY IN WATER.
(Lichty; see also Formanek Chem. Centrb. 18, 270, '87; Bell Chem. News, 16, 69, '67; Ditte
Compt. rend. 92, 718, '81.)
t.
Density
Gms. PbCl 2 per 100
Milligram Mols^. PbCl 2 per TOO
H 2 a/ o!'
cc. Solution.
Gms. H 2 O,
cc. Solution.
Grams H 2 O.
I .0066
0.6728
0.6728
2 .421
2 .421
J 5
I . 0069
0.9070
o . 9090
3-265
3.272
25
I .0072
1.0786
I .0842
3 .882
3-903
35
I 0060
I-3I50
1.3244
4-733
4.767
45
I . OO42
1.5498
!-5 6 73
5-579
5-644
55
I . OO2O
I .8019
1.8263
6.486
6-573
65
0.9993
2-o8lO
2 .1265
7.490
7-651
80
0-9947
2.5420
2 .6224
9.150
9-439
95
0.9894
3-035 8
3-I654
10.926
n-394
IOO
3.208
3-342
11.52
12 -OI
LEAD CHLORIDE
164
SOLUBILITY OF LEAD CHLORIDE IN AQUEOUS SOLUTIONS OF HYDRO-
CHLORIC ACID.
(At o, Engel Ann. chim. phys. [6] 17, 359, '89; at 25, Noyes Z. physik. Chem. 9, 623,
ent temperatures, Ditte Compt. rend. 92, 718, '81; see also Bell J. Chem. Soc. 21,
'92; at differ-
350, '68.)
Gms. HCl Gms. PbCl 2 per
per loo
Gms. PbCl 2 per 100 Gms. Solution at:
Liter.
0.
25.
Gms. H 2 0.
0.
20. 40.
55.
' 80.
O
5
83
IO
79
O
8
O
ii. 8 17.0
21 .
3 I.O
O-5
4
5
9
.0
IOO
i
.2
i-4 3-2
5
5.
12.0
1.0
3
.6
7
.6
150
i
5
2 .0 5 .0
7'
q
16.0
2-O
2
.2
6
.0
200
3
5
5.0 8.2
ii .
fj
21.5
3-0
I
.6
5
o
250
6
5
8.0 13.0
16,
2
28.5
6
I
4
3
.1
300
10
7
12-5 I7-S
22.
O
35-o
10
I
.2
i
.8
4OO
21
5
24.0
.
IOO
I
.2
.
2OO
5
.2
.
250
IO
5
.
300
17
5
.
400
40
.0
.
SOLUBILITY OF LEAD CHLORIDE IN AQUEOUS SALT SOLUTIONS
AT 25.
(Noyes; in HgQ 2 solutions at 20, Formanek Chem. Centralb. 270, '87.)
In Aqueous Solutions of:
HCl, KC1, MgCl 2 , CaCl 2 , MnCl 2 In CaCl 2
and ZnCl 2 Gram Equivalents Gram Equiv.
per Liter of: per Liter.
In HgCl 2
Gram Equiv.
per Liter.
In Pb(N0 3 ) 2
Gram Equiv.
per Liter.
'Salt. PbCl 2 . CdCl 2 . PbCl 2 .
o.o 0.0777 - 0.0777
0.05 0.050 0.05 0.0601
o.io 0.035 o.io 0.0481
O.2O O-O2I O-2O O.O355
HgCl 2 . PbCl 2 .
o.o 0.0777
o.i 0.0992
Pb(N0 3 ) 2 . PbCl 2 .
o.o 0.0777
O.2 0.0832
The above results were calculated to grams per liter plotted on cross-
section paper, and the figures in the following table read from the
curves.
Gms. Salt
Grams PbCl 2 per Liter in Aqueous Solutions of:
per
Jter,
HCl.
KC1.
MgCl 2 .
CaCl 2 .
MnCl 2 .
ZnCl 2 . CdCl 2 .
HgCl 2 .
Pb(N0 3 ) 2
O
10.79
10.79
10.79
10.79
10.79
10.79 10
79
io.79(
N) 9
7i(F)
10.79
I
8-5
9-3
7-7
8. 7
9-5
IO
.2
ii .0
9
.8
10.8
2
6-5
8.2
6-5
7 .6
8-3
9
7
11.4
IO
.0
10.85
3
S- 2
7-2
5-7
6. 7
7-3
9
.2
11.7
IO
3
10.87
4
4-3
6.5
5-2
6.0
6-3
8
.6
12.0
10
5
10.90
6
3-2
5-3
4.4
4.8
5-o
7
7
12.7
II
o
10.95
8
2-5
4-5
3-9
4.1
7
.0
13-3
II,
6
ii .00
IO
2. I
3-9
3-3
3-5
6
3
14.0
12.
2
ii .05
14
. . .
3- 1
. . .
. . .
2.8
3-o 5
4
. . .
*3
2
11.15
20
T A
8
ii . 20
40
10
,0
11.70
165 LEAD CHLORIDE
SOLUBILITY OF LEAD CHLORIDE IN GLYCERINE.
(Presse Ber. 7, 599, '74.)
i part glycerine + 7 parts H 2 O dissolve 0.91 per cent PbCl 2 .
i part glycerine + 3 parts H 2 O dissolve 1.04 per cent PbCl 2 .
i part glycerine + i part H 2 O dissolves 1.32 per cent PbCl 2 .
Pure glycerine dissolves 2.00 per cent PbCl 2 .
LEAD CHROMATE PbCrO 4 .
One liter of water dissolves 0.0002 gram PbCrO 4 at 18 (conductivity
method). (Kohlrausch Z. physik. Chem. 50, 365, 'o 4 -'os.)
SOLUBILITY OF LEAD CHROMATE IN AQUEOUS POTASSIUM HYDROXIDE
SOLUTIONS.
(Lacland and Lepierre Bull. soc. chim. [3] 6, 230, '91.)
t . Grams KOH per 100 cc. Grams PbCrO 4 per 100 cc.
15 2.308 I.I9
60 2.308 1.62
80 2.308 2.61
102 2.308 3.85
LEAD CITRATE Pb(C 6 H 5 O 7 ) 2 .H 2 O.
SOLUBILITY IN WATER AND IN ALCOHOL.
100 gins. H 2 O dissolve 0.04201 gm. Pb(C 6 H 5 O 7 ) 2 .H 2 O at 18, and
0.05344 gm. at 25.
100 gms. alcohol (95%) dissolve 0.0156 gm. Pb(C 6 H 6 O 7 ) 2 .H 2 O at
l8, and 0.0167 g m - at 2 5- (Partheil and Hubner Archiv. Pharm. 241, 413, '03.)
LEAD DOUBLE CYANIDES.
SOLUBILITY IN WATER.
(Schuler Sitzber. Akad. Wiss. Wien, 79, 302, '79.)
Double Salt. Formula. t. G ^ S ^ 2 Q
Lead Cobalticyanide Pbg[Co(CN) 6 ] 2 .7H 2 O 18 56. 5*'
Lead Cobalticyanide PbJCo(CN) 6 ] 2 .7H 2 O 19 61.3
Lead Potassium Cobalticyanide PbKCo(CN) 6 .3H 2 O 18 14.8
Lead Cobalticyanide Nitrate Pb3[Co(CN) 6 ] 2 .Pb(NO 3 ) 2 .i2H 2 O 18 5.9
Lead Ferricyanide Nitrate PblFe(CN) 6 ] 2 .Pb(NO 3 ) 2 .i2H 2 O 16 7.5
Lead Potassium Ferricyanide PbKFe(CN) 6 .3H 2 O 16 21.0
LEAD FLUORIDE PbF 2 .
One liter of water dissolves 0.64 gram PbF 2 at 18 (conductivity
method) . (Kohlrausch Z. physik. Chem. 50, 365, 'o 4 -'o5.)
LEAD FORMATE Pb(HCOO) 2 .
SOLUBILITY OF LEAD FORMATE IN AQUEOUS SOLUTIONS OF BARIUM
FORMATE AT 25.
(Fock Z. Kryst. Min. 28, 383, "97-)
Mol. % in Solution.
Grams per Liter. gp. Gr. of
In Solid Phase Mol.% of
Pb(HC0 2 ) 2 .
Ba(HC0 2 ) 2 '.
Pb(HC0 2 ) 2 .
Ba(HCO 2 ) 2 . Solutions.
Pb(HC0 2 ) 2 .
Ba(HC0 2 ) 2 .
o.oo
100.
28.54
.2204
0-0
100
0.29
99.71
I.I04
28.65
.2213
1.72
98.28
0-74
99.26
2.803
28.90
.2251
5' 2 9
94.71
1.24
98.76
5-309
32.24
.2529
11-94
88.06
2.91
97.09
II .42
29.29
.2341
24.81
75 - J 9
5-92
94.08
23.11
28.13 1.2355
56.54
43-46
100.00
o.o
28.35
I.09II
100.
0-0
LEAD HYDROXIDE
166
LEAD HYDROXIDE Pb(OH) 2 .
SOLUBILITY OF LEAD HYDROXIDE IN AQUEOUS SOLUTIONS OF SODIUM
HYDROXIDE. (Moist Lead Hydroxide used, temperature not given.)
(Rubenbauer Z. anorg. Chem. 30, 336, '02.)
Grams per 100 cc. Solution.
Amt. of Na
in 20 cc.
Amt. of Pb.
in 20 cc.
Mol. Dilution
of NaOH.
O.2O24
O-IOI2
2 .27
0-3196
0.1736
1.44
0.5866
0-3532
0-785
0.9476
0.4071
0.485
1.7802
0.5170-
0.258
NaOH.
i-759
2.778
5.10
8-235
I5-470
Pb(OH) 2 .
0.590
I -OIO
2.056
2.370
3-Qio
LEAD IODATE Pb(IO 3 ) 2 .
One liter of water dissolves 0.019 gm. Pb(IO 3 ) 2 at 18.
(Kohlrausch; Bottgero
LEAD IODIDE PbI 2 .
SOLUBILITY IN WATER.
(Lichty J. Am. Chem. Soc. 25, 471, '03.)
t.
Density.
Grams PbI 2 per 100
Millimols PbI 2 per 100
(H 2 O at'o.)
cc. Solution.
Grams H 2 O.
cc. Solution.
Grams H 2 O.
o
I . OOO6
O.O442
o . 0442
0-096
0-096
J 5
o . 9998
0-0613
0.0613
0-133
0-133
25
o . 9980
0-0762
0.0764
0.165
0.166
35
0.9951
0-1035
o . 1042
0.224
0.226
45
0.9915
o . 1440
0-1453
0.312
0-3*5
55
0.9872
0.1726
0-1755
o-374
0.381
65
0.9827
O.2I4O
0.2183
0.464
o-473
80
0-9745
0-2937
0.3023
0.637
0.656
95
0.9671
0-3814
0.3960
0.828
0.859
100
O.42O
0.436
0.895
0.927
SOLUBILITY OF LEAD IODIDE IN ACETONE, ANILIN AND AMYL ALCOHOL.
(von Laszczynski Ber. 27, 2285, '94.)
Grams PbI 2 per 100 Grams Solvent.
O.02
0.50
Solvent.
(CH 3 ) 2 CO
C 6 H 5 NH 2
C 6 H 5 NH 2
C 5 H 7 OH
t
59
13
184
i .10
0.02
i6 7
LEAD IODIDE
SOLUBILITY OF MIXTURES OF LEAD IODIDE AND POTASSIUM IODIDE
IN WATER.
(Ditte Ann. chim. phys. [5] 24, 226, '81; Schreinemaker Z. physik. Chem. 9, 65, '92.)
/ .
PbI 2 .
KI.
Pbi 2 .
K 2 I 2 .
Phase.
5
I6 3
8.8
Double Salt + PbI 2
2O
9
260
o-3
14.1
..
28
25
325
0.9
17.6
..
39
45
449
1.8
24-3
"
67
255
75 1
9-9
40.7
i>
80
731
1186
28.5
64-3
80
519.9
976.4
22 .2
5 2 -9
4. It
104.5
1411
1521
55 .1
82.5
.
120
2151
1812
83-9
98.2
"
137
2874
2097
112 .2
113.8
.1
175
5603
2947
218.7
159-9
189
3339
181.0
I.
9
96.6
1352
3-77
73-3
Double Salt + KI
13
114.3
1384
4.46
75-05
23
186.3
1510
7.27
81.08
" "
5o
526.7
1906
20.56
103-3
it it
64
789.3
2161
30.8
117.2
ti i.
83-5
1108.6
2434
43-2
I3I-9
it u
92
1273
2566
49-7
139-3
u
137
2382
3278
93-o
117.7
"
165
4187
4227
163.4
229.1
,
218
10303
402.3
. . .
u
241
12803
7998
499-9
433 - 6
t,
242
12749
497-8
.<
250
15264
596.0
I,
t.
Gms. PbI 2 .2KI per
1000 Gms. H 2 O.
Mols. PbI 2 .2KI per
1000 Mols. H 2 O.
157
5218
141.07
172
6489
I7S-S
186
7903
213-7
194
9266
250.6
2OI
II320
306.0
Solid Phase.
PbI 2 .2KI.2}H,O
LEAD MALATE Pb.C 4 H 4 O 5 . 3 H 2 O.
SOLUBILITY IN WATER AND ALCOHOL.
(Partheil and Hiibner Archiv. Pharm. 241, 413, '03.)
ioo gms. H 2 O dissolve 0.0288 gm. PbC 4 H 4 O 5 .3H 2 O at 18, and
0.06504 gm. at 25.
ioo gms. 95% alcohol dissolve 0.0048 gm. PbC 4 H 4 O 6 .3H 2 O at 18-
25-
Density of alcohol employed = 0.8092.
LEAD NITRATE 168
LEAD NITRATE Pb(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Mulder;
Kremers Pogg. Ann. 92, 497, '54; at 15, Michel and Kraft Ann. chim
471, '54; at 17, Euler Z. physik. Chem. 49, 314, '04.)
Grams Pb(NO g ) 2 per 100 Gms. i0 Grams Pb(NO 3 ) 2 per
.Phys. [3],
TOO Gms.
* ' ' Water.
Solution.
27-33
31.6
34-2
35-2
3 6 -9
38.8
*
(3)
Euler
40
SO
60
80
IOO
17
Water.
Solution.
41-9
45-o
47.8
52-7
34-54"
O
10
17
20
25
30
36
44
So
52
56
60
4
.0
3
4
7
: 3 8
48
54
56
60
66
.8< 2 )
3
.0
5
.6
.0
69
78
88
107
127
5 2
4 75
7 85
o 95
.6 115
o 138
,76*
.0
.0
.0
.0
.8
(i) Mulder, (2) Kremers, (3) Average of M and K.
Density of saturated solution at 17 = 1.405. (Euler.)
SOLUBILITY OF LEAD NITRATE IN ETHYL AND METHYL ALCOHOL.
Gms. Pb(NO 3 ) 2 per 100 Grams Solvent at:
Solvent. , ^ p
Aq. C 2 H 5 OH (Sp. Gr. .9282) 4.96 5.82 8*77 xs.8 14*9 (G)
Abs. C 2 H 5 OH o. 04 (20.5) (de B)
Abs. CH 3 OH 1.37 "
(Gerardin Ann. chim. phys. [4] 5, 129, '65; de Bruyn Z. physik. Chem. 10, 783, 'p 2 -)
SOLUBILITY OF MIXED CRYSTALS OF LEAD NITRATE AND STRONTIUM
NITRATE IN WATER AT 25.
(Fock Z. Kryst. Min. 28, 372, '97.)
Mol. per cent in Solution.
Gms. per 100 cc. Solution.
Sp. Gr. of
Mol. per cent in Solid Phase.
Pb(N0 3 ) 2 .
Sr(N0 3 ) 2 .
Pb(N0 3 ) 2 .
Sr(N0 3 ) 2 .
Solutions.
Pb(N0 3 ) 2 .
Sr(N0 3 ) 2 .
IOO
O
.0
46.31
o.o
I
4472
IOO
O
.0
87
.41
12
39
50-47
4-5 6
I
4336
99
05
O
95
78
.68
21
32
53-92
8.14
I
.4288
98
.11
I
.89
56
39
43
.61
45-34
17.81
I
.4263
97
.02
2
.98
60
.29
39
7i
44.48
18.74
I
4245
96
.06
3
94
33
.70
66
30
25-23
35-03
I
.4468
83
.8 4
16
.16
24
58
75
.42
I9-I3
37-54
I
.4867
32
.88
67
.12
o
o
IOO
o
o.o
71.04
I
SMi
.0
IOO
.00
LEAD OXALATE PbC 2 O 4 .
One liter of water dissolves 0.0015 g m - PbC 2 O 4 at 18 (conductivity
method). (Bottger Z. physik. Chem. 46, 602, '03; Kohlrausch Ibid 50, 356, 'o4-'os.>
LEAD OXIDES. SOLUBILITY IN WATER.
(Bottger; Ruer Z. anorg. Chem. 50, 273, '06.)
No. Description of Oxide. ^rfltt' pe?Lher.
1. Yellow Oxide, by boiling Pb hydroxide with 10% NaOH i . 03 X io~ 4 o. 023
2. Red Oxide, by boiling Pb hydroxide with cone. NaOH 0.56X10"* 0.012
3. Yellow Oxide, by heating No. i to 630 1.05X10"* 0.023
4. Yellow Oxide, by heating No. 2 to 740 i.ooXio" 4 0.022
5. Yellow Oxide, by heating com. yellow brown oxide to 620 i . 09 X io~ 4 o. 024
6. Yellow Brown Oxide commercially pure 1.10X10"* 0.024
7. Yellow Brown Oxide, by long rubbing of No. 5. 1.12X10"* 0.025
Bottger gives for three samples of lead oxide, 0.017, 0.021, and 0.013
gm. per liter respectively.
i6(> LEAD PALMITATE
LEAD PALMITATE, LEAD STEARATE.
100 cc. absolute ether dissolve 0.0138 gm. palmitate and 0.0148
gm. stearate.
(Lidoff Bull. soc. chim. [3] 10, 356, '93.)
LEAD PHOSPHATE (Ortho) Pb 3 (PO 4 ) 2 .
One liter of 4.97 per cent aqueous acetic acid solution dissolves 1.27
gms. Pb 3 (P0 4 ) 2 .
(Bertrand Monit. Scient. [3] 10, 477, '68.)
LEAD SUCCINATE PbC 4 H 4 O 4 .
SOLUBILITY IN WATER AND IN ALCOHOL.
(Partheil and Hubner Archiv. Pharm. 241, 413, '03.)
ioo gms. H 2 O dissolve 0.0253 g m - PbC 4 H 4 O 4 at 18, and 0.0285
gm. at 25.
ioo gms. 95% alcohol dissolve 0.00275 gm. PbC 4 H 4 O 4 at 18, and
0.003 g m - a t 2 5-
Density of alcohol used = 0.8092.
LEAD SULPHATE PbSO 4 .
One liter of water dissolves 0.041 gm. PbSO 4 , by conductivity
method.
(Kohlrausch; Bottger. Dibbits Z. anal. Chem. 13, 1.39, '74, finds 0.038 gram by gravimetric method.)
SOLUBILITY OF LEAD SULPHATE IN AQUEOUS SOLUTIONS OF STRONG
ACIDS.
(Schultz Pogg. Ann. 113, 137, '61; Rodwell J. Chem. Soc. 15, 59, '62.)
In Aq. H 2 SO 4 . In Aq. HC1. In Aq. HNO 3 .
(a). (6). (c). (a). (6). (c). (a). (6). (c).
1.540 63.4 0.003 1.05 10.6 0.14 i. 08 i i. 6 0.33
1-793 85.7 o-o 11 I -o 8 l6 -3 -35 J - 12 J 7-5 -59
1.841 97.0 0.039 i. ii 22. o 0.95 1.25 34-0 0.78
1.14 27.5 2. ii 1.42 60.0 i.oi
1.16 31.6 2.86
(a) Sp. Gr. of Aq. Acid, (i) Gms. Acid per ioo Gms. Solution, (c) Gms.PbSO* per ioo Gms. Solvent.
SOLUBILITY OF LEAD SULPHATE IN AQUEOUS SOLUTIONS OF AMMO-
NIUM ACETATE AND OF SODIUM ACETATE.
(Noyes and Whitcomb J. Am. Chem. Soc. 27, 756, '05; Dunnington and Long Am. Ch. J. 22,
217, '99; Dibbits Z. anal. Chem. 13, 139, '74.)
In Ammonium Acetate. In Sodium Acetate.
At 25 (N. and W.). At 100 (D. and L.). (D.).
1
Millimols
per Liter.
Grams per Liter. G.
NH 4 C 2 H 3 2 G.PbSO 4
Gms. per ioo Gms. H 2 O.
NH 4 C 2 H 3 2 . PbS0 4 . NH^HsOa.
PbSO, ^solution.
Solution.
NaC 2 H 3 O 2 . PbSO 4 .
O-O
0.134
O-O
O.O4I
28
7-12
2.05
0.054
I03.S
2.10
7.98
0.636
32
9.88
8.2
0.853
207.1
4-55
I5-96
1.38
37
10.58
41.0
II .23
4I4.I
10. IO
31.92
3-02
45
II .IO
LEAD (Hypo) SULPHATE 170
SOLUBILITY OF MIXTURES OF LEAD HYPOSULPHATE AND STRONTIUM
HYPOSULPHATE AT 25.
(Fock Z. Kryst. Min. 28. 389, '97.)
il. per cent in Solution.
Grams per Liter.
Sp. Gr. of
Mol. per cent in Solid Phase
PbS^o SrSaOa PbS2Oe. SrS 2 Oe-
Solutions. PbS^Oe
SrS 2 6
-4H 2 O.
.4H
-4H 2 0.
. 4 H 2 0.
0-0
IOO
.0
O
.0
145
6
I
.1126
.0
IOO.O
1.05
98
95
2
97
.2
I
.1184
O
30
99 7
84
.69
40
.82
152
5
I
.1503
3
.87
96.13
46.80
53
.20
149
.2
114
5
I
.2147
9
.84
90.16
62.30
37
.70
256
.1
85
.0
I
.2889
19
.26
80.74
75-75
24
25
3 IO
3
67
.0
I
3252
23
73
76.27
78.09
21
.91
373
7
70
.8
I
.3726
32
.24
67.76
88.29
II
7 1
509
5
45
.6
I
.4671
49
97
50.13
IOO.O
O
.00
374
3
.0
I
.6817
.00
o.oo
LEAD TARTRATE PbC 4 O 6 H 4 .
SOLUBILITY IN WATER.
(Cantoni and Zachoder Bull. soc. chim. [3] 33, 751, '05; Partheil and Hiibner Archiv. Pharm. 241,
413, '03-)
t o Cms. PbCiOeHi Per 1 Cms. PbC 4 O 6 H 4 per Gms. PbC 4 O 6 H 4 per
100 cc. Solution. ioo cc. Solution. 100 cc. Solution.
l8 O-OIO (P. andH.) 50 O-OO225 70 0.0032
25 0.0108 " 55 0.00295 75 0.0033
35 0.00105 60 0.00305 80 0.0038
40 0.0015 65 0.00315 85 0-0054
NOTE. The positions of the decimal points here shown are just
as given in the original communications.
100 gms. alcohol of 0.8092 Sp. Gr. (about 95%) dissolve 0.0028 gm.
PbC 4 O 6 H 4 at 1 8, and 0.003 1 5 g m - at 2 5- (P. and H.)
LEVULOSE C 6 H 12 O 6 .
100 gms. saturated solution in pyridine contain 18.49 g ms - C 6 H 12 O a
at 26, Sp. Gr. 1.0521. (Holty J. Physic. Chem. g, 764, '05.)
LIGROIN.
ioo cc. H 2 O dissolve 0.341 cc. ligroin at 22 Vol. of solution = 100.34,
Sp. Gr. 0.9969.
ioo cc. ligroin dissolve 0.335 cc. H 2 O at 22 Vol. of solution = 100:60,
Sp. Gr. 0.6640. (Herz Ber.3i, 2671, '98.)
LITHIUM BENZOATE C 6 H 5 COOLi.
ioo gms. H 2 O dissolve 33.3 gms. at 25, and 40.0 gms. at b. pt.
ioo gms. alcohol dissolve 7.7 gms. at 25, and 10.0 gms. at b. pt.
(U. S. P.)
LITHIUM BORATE Li 2 OB 2 O 3 .
SOLUBILITY IN WATER.
t o 10 20 30 40 45
Gms. Li 2 OB 2 O 3 per ioo Gms. H 2 O 0.7 1.4 2.6 4.9 11.12 20
(Le Chatelier Compt. rend. 124, 1094, *97-)
iyi LITHIUM BROMATE
LITHIUM BROMATE LiBrO 3 .
100 gms. H 2 O dissolve 153.7 gms. LiBrO 3 at 18, or 100 gms. saturated
solution contain 60.4 gms. Sp. Gr. of sol. = 1.833.
(Mylius and Funk Ber. 30, 1718, '97.)
LITHIUM BROMIDE LiBr.
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 104, 133, '58.)
Gms. LiBr per 100 Gms. Gms. LiBr per 100 Gms.
Water. Solution. Water. Solution.
O 143 58.8 40 202 66.9
10 161 61.7 50 214 68.2
2O 177 63.9 60 224 69.1
25 184 64.8 80 245 71.0
30 190 65.5 ioo 266 72.7
ioo gms. saturated solution in glycol, C 2 H 4 (OH) 2 .H 2 O, contain 37.5
gms. LiBr at 14.7. (de Coninck Chem. Centr. 76, II, 883, '05.)
LITHIUM CARBONATE Li 2 CO 3 .
SOLUBILITY IN WATER.
(Bevade J. russ. phys. chem. Ges. 16, 591, 84; Bull. soc. chim. [2] 43, 123, '85; Fliickiger Arch.
Pharm.[3]25, 542, '87; Draper Chem. News, 55, 169, '87.)
An average curve was constructed from the available results and
the following table read from it.
Gms. Li 2 CO3 per ioo Gms. Gms.Li 2 CO3 per looGms.
Water. Solution. Water. Solution.
o .54 1.52 40 1.17 1.16
10 .43 1.41 50 i. 08 1.07
20 .33 1.31 60 I. 01 I. 00
25 .29 1.28 80 0.85 0.84
30 .25 1.24 ioo 0.72 0.71
Density of saturated solution at o = 1.017; at 15 = 1.014.
SOLUBILITY OF LITHIUM CARBONATE IN AQUEOUS SOLUTIONS OP
ALKALI SALTS AT 25.
(Geffcken Z. anorg. Chem. 43, 197, '05.)
The original results were calculated to gram quantities and plotted
on cross-section paper. The figures in the following table were read
from the curves.
Gms. Salt Grams Li 2 CO 3 per Liter in Aqueous Solutions of:
per Liter.
KC
KNOg.
KC1.
NaCl.
K 2 S0 4 .
Na 2 S0 4 .
NH 4 C1.
(NH 4 ) 2 S0 4 .
O
12
63
12.63
12 .63
12
.63
12 .63
12
.63
12.63
12.63
10
12
95
I 3 O'N
13 .IO
13
4
13-9
14
o
16.0
20-7
2O
I 3
.10
13-3
13-5
*3
9
14.7
15
o
19.2
25.0
30
13
2 5
13-6
I 3 .8
14
3
IS-4
16
.0
21.5
28.2
40
13
.40
I 3 .8
14.0
14
.6
16.0
16
.6
2 3-3
30.8
60
I 3 .8
14-2
14
5
16.9
i?
.8
. 26.0
35- 2
80
.
13-6
14.0
14
4
17.7
18
.6
27.6
38-5
IOO
.
J 3-5
J 3-9
14
. 2
18.2
19
4
28.4
41.0
120
.
13-3
13-7
14
O
19
9
28.7
42.6
140
.
13.0
13-3
.
20
4
28.8
43-5
170
.
12.6
28.9
2OO
12 .2
20 .0
ioo gms. aq. alcohol of 0.941 Sp. Gr. dissolve 0.056 gm. Li 2 CO 3 at
LITHIUM (Bi) CARBONATE 172
LITHIUM (Bi) CARBONATE LiHCO 3 .
100 grams H 2 O dissolve 5.501 grams LiHCO 3 at 13.
(Bevade Ber. 17, R 406, '84.)
LITHIUM CHLORATE LiClO 3 .
100 grams H 2 O dissolve 213.5 grams LiClO 3 at 18, or 100 grams sat.
solution contain 75.8 grams. Sp. Gr. of sol. = 1.815.
(Mylius and Funk Ber. 30, 1718, '97.)
LITHIUM CHLORAURATE LiAuCl 4 .
SOLUBILITY IN WATER.
(Rosenbladt Ber. 19, 2538, '86.)
A o Gms. LiAuCU per + Gms. LiAuCU per
TOO Gms. Solution. 100 Gms. Solution
I o Gms. LiAuCU per
100 Gms. Solution.
10
53-i
40
67-3
60
7 6.4
20
57-7
50
72.0
70
81.0
30
62 .5
80
85.7
LITHIUM CHLORIDE LiCl.
SOLUBILITY IN WATER.
(Average curve from results of Gerlach Z. anal. Chem. 8, 281, '69.)
Gms. LiCl per 100 Gms. ^ Gms. LiCl yr 100 Gms.
Water. Solution." Water. Solution.
o 67 40.1 40 90.5 47.5
10 72 41.9 50 97.0 49.2
20 78.5 44 -o 60 103.0 5 z -9
25 81.5 49.9 80 115.0 53.5
30 84.5 45.8 100 127.5 5 6 -
Density of saturated solution at o, 1.255; at I 5 I - 2 75-
SOLUBILITY OF LITHIUM CHLORIDE IN AQUEOUS SOLUTIONS OF HYDRO-
CHLORIC ACID AT o.
(Engel Ann. chim. phys. [6] 13, 385, '88.)
Milligram Mols. per
10 cc. Solution.
Gms. per 10 cc.
Solution.
Sp. Gr. of
LiCl.
HCl.
LiCl.
HCl.'
Solutions.
1 2O
o.o
5 I.O
0-0
1-255
97-5
22 .5
41.4
8.2
1.243
67.0
66.0
28.5
24.1
1.249
58.0
81.0
24.6
29-5
I .251
SOLUBILITY OF LITHIUM CHLORIDE IN SEVERAL SOLVENTS.
(von Laszczynski Ber. 27, 2285, '94; de Coninck Chem. Centrh. 76, II, 883, '05.)
Gms. LiCl
t . per 100 Gms.
(CH 3 ) 2 CO.
o 4.60
12 4.41
2$ 4-II
etoi
L.)
ne.
In Pyridine.
(von L.)
In Glycol.
(de C.)
Gms. LiCl
Gms. LiCl
Gms. LiCl
t .
per 100 Gms.
t . per 100 Gms.
t. per 100 Gms.
(CH 3 ) 2 CO.
C 6 H 6 N.
Sat. Sol.
4 6
3.76
15 7-78
15 ii. o
53
3-12
100 14.26
58
2.14
173
LITHIUM CHROMATE Li 2 CrO 4 .2H 2 O.
LITHIUM CHROMATE
LITHIUM BICHROMATE Li 2 Cr 2 O 7 . 2 H 2 O.
SOLUBILITY IN WATER AT 30.
(Schreinemaker Z. physik. Chem. 55, 79, '06; at 1 8, Mylius and Funk Ber. 30, 1718, '97.)
Composition in Weight per cent:
Solid
Phase.
LiOH.H 2 O
LiOH.H 2 + Li 2 Cr0 4 . 2 H2O
Of Solution.
Of Residue.
%Cr0 3 .
%Li 2 0.
%Cr0 3 .
%Li 2 0.
o.o
7.09
6.986
7-744
4.322
18.538
16.564
8.888
10-089
I9-556
25.811
10.611
15-479
21 .106
33-6l8
12.886
24-365
19.398
37-4H
14.306
44-555
17.411
37-588
14.381
36-331
18.552
37-495
13-3"
5i-o75
16.384
40 . 280
10.858
43.404
i i . 809
53-793
14.070
45 -13
9-5*5
56.085
10.190
47-945
7-95 1
58.029
9.238
57-Q3 1
6.432
65.560
8-733
67.731
5-7I3
71.687
8-5I3
67.814
5-689
80.452
3.780
65 . 200
4.661
. . .
63-257
2.141
85.914
0.758
62.28
Li 2 CrO 4 .2H 2 O
Li 2 Cr 2 O 4 .2
Li 2 Cr 2 07.2H 2 O
Li 2 Cr 2 07.2H 2 + Cr0 3
Cr0 3
A saturated aqueous solution contains :
49.985 per cent Li 2 CrO 4 , or 100 grams H 2 O dissolve 99.94 grams
Li 2 CrO 4 at 30 (S.).
56.6 per cent Li 2 Cr 2 O 7 , or 100 grams H 2 O dissolve 130.4 grams
Li 2 Cr 2 O 7 at 30 (S.).
52.6 per cent Li 2 CrO 4 , or 100 grams H 2 O dissolve 110.9
LiCrO 4 at 18 (M. and F.).
Sp. Gr. of sat. solution at 18 = 1.5 74.
LITHIUM CITRATE C 3 H 4 (OH)(COOLi) 3 .
100 gms. H 2 O dissolve 50 gms. citrate at 25, and 66.6 gms.at b. pt.
100 gms. alcohol of 0.941 Sp. Gr. dissolve 4 gms. citrate at 15.5.
(U. S. P.)
LITHIUM FLUORIDE LiF.
100 grams H 2 O dissolve 0.27 gram LiF at 18. Sp. Gr. of sol.
1.003.
(Mylius and Funk.)
LITHIUM FORMATE
174
LITHIUM FORMATE HCOOLi.
SOLUBILITY IN WATER.
(Groschuff Ber. 36, 179, '03.)
Gms.
Mols.
Gms.
Mols.
HCOOLi
HCOOLi
Solid
HCOOLi
HCOOLi
Solid
per ioo
per ioo
Phase.
t .
per ioo
per ioo
Phase.
Gms.
Mols.
Gms.
Mols.
Solution.
H 2 0.
H 2 0.
H 2 0.
21 .14
9.28
HCOOLi .H 2
9 1
54.16
40.90
HCOOLi .H 2
24.42
II. l8
"
98
57-05
45-99
HCOOLi
27.85
13-36
"
104
57 -4
47.11
"
35 -60
19.14
11
120
59-63
51 .13
"
44.91
28.22
"
20
O
18
49-5
74
Sp. Gr. sat. sol. at 18 = 1.142.
SOLUBILITY OF NEUTRAL LITHIUM FORMATE IN ANHYDROUS
FORMIC ACID.
Gms. per 100 Gms. Solution.
Mols. per TOO Mols. H 2 O.
V .
HCOOLi.
HCOOH.
HCOOLi.
HCOOH.
O
25-4
47-02
II.So
39-27
18
25-9
46.92
12. 1 1
39- 11
39
26.4
46.92
12 .42
39 -13
60
26.9
46.94
12-74
39-13
79
27.8
47-02
I3-36
39.26
HCOOLi
LITHIUM HYDROXIDE LiOH.
SOLUBILITY IN WATER.
(Dittmar J. Soc. Ch. Ind. 7, 730, '88; Pickering J. Chem. Soc. 63, 909, '93.)
Gms. per
ioo Gms.
Gms. LiOH
Gms. per ioo Gms.
Gms. LiOH.
t
Solution.
per ioo Gms.
t. Solution.
per ioo Gms
Li 2 0.
LiOH.
H 2 O.
Li 2 O.
LiOH.
H 2 0.
O
6.67
10.64
12-7
40
7.29
11.68
I 3 .0
IO
6.74
I0.8o
12-7
50
7-56
12.12
20
6.86
10-99
12.8
60
7.96
12.76
13 :1
25
6-95
II .14
12-9
80
8.87
14.21
15-3
30 7-05
11.27
12.9
IOO 10. O2
16.05 17-5
LITHIUM IODATE Li(IO 3 ).
ioo grams H 2 O dissolve 80.3 grams LiIO 3 at 18, or ioo grams solu-
tion contain 44.6 grams. Sp. Gr. of sol. = 1.568.
(Mylius and Funk Ber. 30, 1718, '97.)
Water.
Solution.
\> *
Water.
Solution.
151
60.2
40
179
64.2
J 57
61.1
50
I8 7
65-2
62 .2
60
202
66.9
167
62.6
70
230
69.7
171
6 3 .I
75
263
72-5
175 LITHIUM IODIDE
LITHIUM IODIDE Lil.
SOLUBILITY IN WATER.
(Kremefs Pogg. Ann. 104, 133, '58; in, 60, '60.)
Gms. Lil per ioo Gms. ^ Grams Lil per ioo Gms.
O
10
2O
25
30
ioo grams sat. solution in Glycol (C 2 H 4 (OH) 2 .H 2 O) contain 28.0
grams Lil at 15.3. (de Coninck Chem. Centrb. 76, II, 883, '05.)
ioo cc. saturated solution in Furfurol (C 4 H 3 O.COH) contain 45.86
gms. Lil at 25.
ioo cc. saturated solution in Nitro Methane (CH 3 NO 2 ) contain
1.219 g ms - Lil at o, and 2.519 gms. at 25.
(Walden Z. physik. Ch. 55, 713, 718, '06.)
LITHIUM NITRATE LiNO 3 .
SOLUBILITY IN WATER.
(Donnan and Burt J. Chem. Soc. 83, 335, '03.)
t o Gms.LiNOaper Solid t o Gms. LiNO 3 per Solid
ioo Gms. Solution. Phase. ioo Gms. Solution. Phase.
O.I 34-8 LiN0 3 . 3 H 2 O 29.87 56.42 LiN0 3 .3H 2
10-5 37.9 " 29.86 56.68
12. I 38.2 " 29.64 57-48
13-75 39-3 " 29.55 58-03
19.05 40.4 43-6 60.8 LiN0 3 .*H 2 O
21- 1 42-9 " 5-5 61.3
27-55 47-3 " 55-o 63.0
29-47 53- 6 7 " 6o - 6 3- 6
29-7 8 55-09 " 6 4-2 64.9
70.9 66.1
Cryohydrate point of the trihydrate, 17.8. Transition points, 29.6
and 61.1.
LITHIUM OXALATE Li 2 C 2 O 4 .
SOLUBILITY OF MIXTURES OF LITHIUM OXALATE AND OXALIC
ACID IN WATER AT 25.
(Foote and Andrew Am. Ch. J. 34, 153, '05.)
Mixtures of the two substances were dissolved in water, and the
solutions cooled in a thermostadt to 25.
Gms. per ioo Gms. Solution. Mols. per ioo Mols. H 2 O. Soli( j
H 2 C 2 4 . Li 2 C 2 4 . H 2 C 2 4 . Li 2 C 2 4 .' Phase.
10 . 20 ... 2 . 274 H 2 C 2 4 . 2 H 2 O
10 .66 2 .06 s
2.457 0.622 H 2 C 2 4 .H 2 and HLiC 2 O 4 .H 2 O
8.08 3-18 1.823 0.633) Double Salt
2.60 5.03 0.563 0. 9 62J H =3f 2 4 H 4 2 ? 2 4 and 44-7 Li 2 C 2 0,
2 12 I 'III 0.469 1-273 HLiC 2 4 .H 2 and U 2 C 2 4
5.87 ... I.90I Li 2 C 2 4
LITHIUM PHOSPHATE 176
LITHIUM PHOSPHATE Li 3 PO 4 .
100 grams H 2 O dissolve 0.04 gram L1 3 PO 4 . (Mayer Liebig's Ann. 98, 193, '56.)
LITHIUM (Hypo) PHOSPHATE Li 4 P 2 O 6 .7H 2 O.
100 grams H 2 O dissolve 0.83 gram hypophosphate at ord. temp.
(Rammelsberg J. pr. Ch. [2] 45, 153, '92.)
LITHIUM PERMANGANATE LiMnO 4 .3H 2 O.
100 grams water dissolve 71.4 grams permanganate at 16.
(Ashoff.)
LITHIUM SALTS of Fatty Acids.
SOLUBILITY IN WATER AND IN ALCOHOL OF 0.797 SP. GR. AT 18
AND AT 25.
(Partheil and Ferie Archiv. Pharm. 241, 554, '03.)
Grams Salt per 100 cc. Sat. Solution in:
Salt.
Stearate
Palmitate
Myristate
Laurinate
Oleate
Formula.
C 17 H 35 COOLi
C 15 H 31 COOLi
C 13 H 27 COOLi
C n H 23 COOLi
C^HggCOOLi
Water at
Alcohol at
18.
OIO
.Oil
.0232
.158
.0674
o
o
o
25.
Oil
.018
.0234
.1726
.1320
' 18.
O.O4I
0.0796
0.184
0.418
0.9084
O
O
I
25.
0532
.0956
.2IOO
.4424
OIO
LITHIUM SULPHATE Li 2 SO 4 .
SOLUBILITY IN WATER.
(Average curve from Kremers Pogg. Ann. 95, 468, '55; Etard Ann. chim. phys. [7] 2, 547, '94.)
j.o Gms. Li 2 SO4 per
100 Gms. Solution
j.o Gms. Li 2 SO 4 per
100 Gms. Solution
4.0 Gms. Li 2 SO 4 per
. 100 Gms. Solution.
20
18.4
20
25-5
50
24-5
10
24.2
2 5
25-3
60
24.2
O
26.1
30
25-1
80
23-5
10
25-9
40
24.7
100
23.0
NOTE. For equilibrium between lithium sulphate ammonia and
water, see Schreinemaker and Cochert Chem. Weekblad. 2, 771; 3,
157, '06.
EQUILIBRIUM BETWEEN LITHIUM SULPHATE, ALUMINUM SULPHATE,
AND WATER AT 30.
(Schreinemaker and De Waal Chem. Weekblad. 3, 539, '06.)
Composition in Weight per cent:
Of Solution.
Of
Residue.
Solid
Phase.
% Li 2 SO 4 . %
A1 2 (S0 4 ) 3 .
% Li 2 SO 4
, % A1 2 (S0 4 ) 3 .
25.1
O
Li 2 SO 4 .H 2 O
21-93
5-34
"
16.10
14.89
63.70
4-O2
13-63
20.76
14.72
3I-I7
( Li 2 S0 4 .H 2 +
1 Al 2 (SO 4 ) 3 .i8H 2 O
13.24
21.71
61 .24
7-22
Li 2 S0 4 . 4 H 2 O
ii .73
22 .08
6.92
33-54
Al 2 (SO 4 ) 3 .i8H 2 O
6-75
24-34
3-77
37.06
M
3-44
26.12
o.o
28.0
. . .
1.
NOTE. For solubility of lithium sulphate in mixtures of alcohol
and water at 30, see Schreinemaker and Van Dorp, Jr. Chem. Week-
blad. 3, 557, '06.
177 MAGNESIUM BROMATE
MAGNESIUM BROMATE Mg(BrO 3 ) 2 .6H 2 O.
100 cc. sat. solution contain 42 grams Mg(BrO 3 ) 2 , or 0.15 grammols.
at 1 8.
(Kohlrausch Sitzb. K. Akad. Wiss. (Berlin), i, 90, '07.)
MAGNESIUM BROMIDE MgBr 2 .6H 2 O.
SOLUBILITY IN WATER.
(Menschutkin Chem. Centrb. 77, I, 646, '06; at 18, Mylius and Fu.ik Ber. 30, 1718, '97.)
Grams MgBij per 100 Gms. Grams MgBr 2 per 100 Grams.
Solution. Water. Solution. Water.
io 47.2 89.4 40 50.4 101.6
o 47-9 9 1 -9 50 51-0 104.1
io 48.6 94.5 60 51.8 107.5
18 49-0 96.1 80 53-2 JI 3-7
18 50.8 103 .4 (M. and F.) 100 54-6 120.2
20 49.1 96.5 120 56.0 127.5
25 49.4 97.6 140 58.0 138.1
30 49-8 99-2 160 62.0 163.1
Density of saturated solution at 18 = 1.655 (M. and F.)
Etard Ann. chim. phys. [7] 2, 541, '94, gives solubility results
which are evidently too high.
SOLUBILITY OF MAGNESIUM BROMIDE ALCOHOL COMPOUNDS IN THE
CORRESPONDING ALCOHOLS.
(Menschutkin Chem. Centrb. 77, I, 334, 647, '06.)
In the Corresponding Alcohols.
Results Expressed in Mols. per cent.
t<>.
MgBr 2 .6CH 3 OH
in CH 3 OH.
MgBr 2 .6C 2 H 5 OH
in C 2 H 6 OH.
6.0
2.O
20
6. 4
4-6
40
6. 9
8. 4
50
7 .2
IO-9
60
7-5
I4-I
80
8.25
22.1
100
9.6
38.6
150
16.7
100.0 (108.
5)
i go
IOO.O
Determinations are also given for the solubility of MgBr 2 .6C 3 H 7 OH
in C 3 H 7 OH, of MgBr 2 .6(CH 3 ) 2 C 2 H 3 OH in (CH 3 ) 2 C 2 H 3 .OH, and of MgBr 2 .
6(CH 3 ) 2 C 2 H 3 OH in (CH 3 ) 2 C 2 H 3 OH, also of MgBr 2 . 4 (CH 3 ) 2 .CHOH in
iso propyl alcohol and in tri methyl carbinol.
For the solubility magnesium bromide mono etherate (MgBr 2 .
(C 2 H 6 ) 2 O) in ethyl ether, see Menschutkin Chem. Centrb. 77, 1, 1868,
'06; also Z. anorg. Ch. 49, 208, '06. For magnesium bromide di
etherate (MgBr 2 .2C 4 H 10 O) in ethyl ether, see Menschutkin Z. anorg.
Ch. 49, 35, '06. For magnesium bromide hexa formic acid and mag-
nesium bromide hexa acetic acid compounds in anhydrous solutions of
the corresponding acids, see Iswietja d. Petersburger, Polytechn. Inst.
6, 293, '06; Chem. Centrb. 77, II, 1482, '06.
MAGNESIUM CARBONATE 178
MAGNESIUM CARBONATE MgCO 3 .
SOLUBILITY IN WATER IN PRESENCE OF CARBON DIOXIDE AT 15*
(Tread well and Reuter Z. anorg. Ch. 17, 200, '98.)
cc CO2 t>er TOO cc-
Gas Phase (at o
Partial
Pressure of COs
Grams per
ioo cc. Solution.
and 760 mm.)-
in mm. Hg.
Free CO 2 .
MgCO 3 .
Mg(HC0 3 ) 2 .
Total Mg.
18.86
143-3
O.II90
. . .
I .2IO5
0.2016
5-47
41 .6
0.0866
I .2IO5
0.2016
4-47
33-8
0.0035
I.2I05
0.2016
i-54
11.7
0.0773
I .0766
0.2016
J -35
10.3
0.0765
0.7629
0.1492
1.07
8.2
0.0807
0-5952
0.1224
0.62
4-7
O.O7OI
0.3663
0.0865
0.60
4.6
0.0758
0.3417
0.0788
o-33
2-5
0.0748
0.2632
0.0655
0.21
1.6
0.0771
O.2229
0.0594
O.I4
i .1
O.O7IO
0.2169
0.0566
O.O3
o-3
O.O7II
0-2036
0-0545
0.0685
0.2033
0-0536
O.O7O2
0.1960
0.0529
0.0625
0.2036
0.0520
0.0616
0.1954
0.0511
0.0641
0.1954
0.0518
Therefore at o partial pressure of CO 2 and at 1 5 and mean barometric
pressure, one liter of saturated aqueous solution contains 0.641 gram
of MgCO 3 plus 1.954 grams Mg(HCO 3 ) 2 .
SOLUBILITY OF MAGNESIUM CARBONATE IN WATER CHARGED WITH CAR-
BON DIOXIDE AT PRESSURES GREATER THAN ONE ATMOSPHERE.
(Engel and Ville Compt. rend. 93, 340. '81; Engel Ann. chim. phys. [6] 13, 349, '88.)
Pressure of
CC>2 in
G. MsCOa^
per Liter.
Pressure of
f~*O in
G. MRCO 3 * per Liter.
Atmospheres.
At
12.
At 19.
LxV_/2 1"
Atmospheres
At 12.
At 19.
0-5
20.
5
4
.0
42.8
I .0
26.
5
25
.8
4
7
43-5
2-0
34-
2
33
.1(2,
i At.)
6
.0
5O.6
48-5
(6.2
At.)
3-o
39-
O
37
2(3
.2 At.)
9
.0
56.6
SOLUBILITY IN WATER SATURATED WITH CO 2 AT ONE ATMOSPHERE.
(Engel.)
t o Cms. MgCO 3 * f0 Gms.MgCOa* ..<, Cms. MgCO 3 *
per Liter. per Liter. per Liter.
5 36 30 21 60 ii
10 31 40 17 80 5
20 26 ioo o
* Dissolved as Mg(HCO 3 ) 2 .
179 MAGNESIUM CARBONATE
SOLUBILITY OP MAGNESIUM CARBONATE IN AQUEOUS SOLUTIONS OP
SODIUM CARBONATE AT 25. The solutions being in equilibrium
with an atmosphere free from CO 2 .
(Cameron and Seidell J. Physic. Ch. 7, 588, '03.)
Wt. of i Liter Grams per Liter. Reacting Weights per Liter.
of Solution. Na 2 C0 3 . MgCO 3 . Na 2 CO 3 . MgCO 3 '.
996.8 o.oo 0.223 o.ooo 0.00266
1019.9
23.12
0.288
O-22O
0.00344
1047.7
50-75
0.510
0.482
O.O062O
1082.5
86.42
0.879
O.82O
O.OI027
1118.9
127.3
i -3*4
I .209
O.OI57O
1147.7
160.8
1.636
I .526
0.01955
1166.1
181.9
1.972
1.727
0.02357
1189.4 213.2 2.317 2.024 0.02770
SOLUBILITY OF MAGNESIUM Bi CARBONATE AND OF MAGNESIUM CAR-
BONATE IN AQUEOUS SOLUTIONS OF SODIUM CHLORIDE AT 23. The
solutions being in equilibrium with an atmosphere of CO 2 in the
one case, and in equilibrium with air free from CO 2 in the other.
(C. and S.)
In Presence of CO 2 as Gas Phase.
Gms. NaCl
per Liter.
Gms, Mg(HC0 3 ) 2
per Liter.
Wt. of i
Liter.
Gms. NaCl
per Liter.
Gms. MgCO 3
per Liter.
7-0
30.64
996.9
0.0
0.176
56.5
30.18
IOI6.8
28.0
0.418
119.7
27.88
IO4I .1
59-5
0.527
163.9
24.96
1070.5
106.3
0.585
224.8
20.78
1094-5
147-4
0-544
306.6
10-75
1142.5
23I.I
0.460
II7O.I
272.9
o-393
II99-3
331-4
0.293
SOLUBILITY OF MAGNESIUM CARBONATE IN AQUEOUS SOLUTIONS OF
SODIUM SULPHATE AT 24 AND AT 35.5. The solutions being in
equilibrium with an atmosphere free from CO 2 .
(Cameron and Seidell.)
Results at 24. Results at 35.5.
Wt. of
Gms. Na 2 SO 4
Gms. MgCO 3
Wt. of
Gms. Na 2 SO<
Gms. MgCO 3
i Liter.
per Liter.
per Liter.
i Liter.
per Liter.
per Liter.
997-5
o.oo
0.216
995 - 1
0-32
O.I3I
IO2I .2
25.12
0.586
1032.9
41.84
o-577
1047.6
54 76
0.828
1067.2
81.84
0.753
1080.9
95.68
I .020
1094.8
116.56
0.904
1133 .8
160.8
1.230
1120.4
148.56
0.962
"57-3
191.9
1.280
1151 .7
186.7
1.047
1206.0
254.6
I-338
1179.8
224.0
i. 088
1242.0
305-1
I. 3 88
1236-5
299.2
1.130
MAGNESIUM CHLORATE
1 80
MAGNESIUM CHLORATE Mg(ClO 3 ) 5
i8
18
29
35
Gms.
Mg(C10 3 ) 2
per 100 Gms,
Solution.
51.64
53-27
60.23
Mols.
Mg(C10 3 ) 2
, per 100
Mols. H 2 O.
IO.O5
10-73
12.22
14.25
16.48
SOLUBILITY
(Meusser Ber.
Solid
Phase.
Mg(C10 3 ) 2 .6H 2
ii
IN
35.
t
42
65
39
61
68
93
WATER.
1416, '02 .)
Gms.
o Mg(C10 3 ) 2
per loo Gms.
Solution.
63.82
5 69.12
5 65.37
O 69 . 46
70.69
(73-71)
Mols.
Mg(C10 3 ) 2
per 100
Mols.H 2 O.
16.16
20.08
17.76
21.40
22 .69
(26.38)
Solid.
Phase.
Mg(C10 3 ) 2 .4H 2
Mg(C10 3 ) a . 2 H 2
Sp. Gr. of saturated sol. at + 18 = 1.564.
MAGNESIUM CHLORIDE MgCl 2 .
SOLUBILITY IN WATER.
(van 't Hoff and Meyerhoffer Z. physik. Chem. 27, 75, '98; Engel; Lowenherz. Results quoted
from Landolt and Bornstein Tabellen, sd, ed. p. 549, '06.)
to Gms.MgCl?
per TOO Gms
Solid
40 Gms. MgC^perioo
Gm s' Solid
Solution.
Water.
Phase.
Solution
. Water.
Phase.
IO
ii
.1
12
5
Ice
34
5
5 2
.8
MgCl 2 .6H 2 O
20
16
.0
19.0
10
34
9
53
5
"
30
19
4
24.O
2O
35
3
54
5
33-6
20
.6
26
.0
Ice + MgCl 2 .i 2 H 2 O
22
35
.6
55
.2
"
12
26
7
36
5
MgCl 2 .i 2 H 2 O
25
36
.2
56
7
41
16.4
3
.6
44
.O4f.pt.
40
36
5
57
5
"
16.8
17.4
19=4
9.6
3-4
3 1
32
33
33
34
.6
-3
3
9
4
46
47
49
5 1
S 2
2
6
9
3
3 j
MgCl 2 .i2H 2 O +
MgCl 2 .8H 2 O a
MgCl 2 .i 2 H 2 +
MgCl 2 .8H 2 0/3
MgCl 2 .i2H 2 +
MgCl 2 .6H 2 O
MgCl 2 .8H 2 ft
+ MgCl 2 .6H 2
MgClo.8H 2 O a +
MgCl 2 .6H 2 about
60
80
100
Il6.7
152.6
181.5
37
39
42
46
49
55
9
.8
.2
.2
.1
.8
61
66
73
85
96
126
.0
.0
.0
5
4
.0
( MgCl 2 .6H 2 -f
1 MgCl 2 . 4 H 2 G
MgCl 2 . 4 H 2
{ MgCl 2 . 4 H 2 +
\ MgCl 2 . 2 H 2
186
56
.1
128
.0
MgCl 2 .2H 2
SOLUBILITY OF MAGNESIUM CHLORIDE IN AQUEOUS SOLUTIONS
HYDROCHLORIC ACID AT o.
(Engel Compt. rend. 104, 433, '87.)
gram Mols. p^r 10 cc. Solution, gp. Gr. of
Grams per Liter of Solution.
HC1.
iMgC! 2 . bolutions.
HC1.
MgCl a .
O-O
99-55 1-362
o.o
474.2
4-095
95-5
354
14-93
454-8
9-5
90.0
344
34-63
428.6
17.0
82.5
.300
61.97
393-o
20.5
79.0
297
74-74
376.2
28.5
71.0
.281
103.9
338.3
42.0
60.125
J 53-i
286.4
58.75
46.25
214.2
220.3
76.0
32.0
277.1
152.0
sat. HC1 (Ditte)
6-S
181 MAGNESIUM CHLORIDE
SOLUBILITY OF MIXTURES OF MAGNESIUM CHLORIDE AND OTHER
SALTS IN WATER AT 25.
(LSwenherz Z. physik. Chem. 13, 479, '94.)
Mixture, Gram Mols. per 1000 Mols. H 2 O. Gms. per Liter of Solution.
MgCl 2 .6H 2 O + MgSO 4 .6H 2 O 104 MgCl 2 + 14 MgSO 4 25.0 C1 + 4.4 SO 4
MgCl 2 . 7 H 2 + MgS0 4 .6H 2 73 +15 19.5 "+5.3 "
MgCl 2 .6H 2 O + MgCl 2 .KC1.6H 2 O 106 Cl+i K 2 + 105 Mg 26.9 C1+ 0.3 K+ 45.7 SO 4
Results for the remaining possible combinations of magnesium
sulphate and potassium chloride are also given.
MAGNESIUM GHROMATE MgCrO 4 .7H 2 O.
100 grams H 2 O dissolve 72.3 grams MgCrO 4 at 18, or 100 grams
solution contain 42.0 grams. Sp. Gr. = 1.422.
(Mylius and Funk Ber. 30, 1718, '97.)
MAGNESIUM POTASSIUM CHROMATE MgCrO 4 .K 2 CrO 4 .2H 2 O.
100 grams H 2 O dissolve 28.2 grams at 20, and 34.3 grams at 60.
(Schweitzer.)
MAGNESIUM PLATINIC CYANIDE MgPt(CN) 4 .
SOLUBILITY IN WATER.
(Buxhoevden and Tamman Z. anorg. Ch. 15, 319, '97.)
Gms.MgPt(CN) 4
Gms. MgPt(CN) 4
t .
per 100 Gms.
Solid Phase.
t.
per 100 Gms.
Solid Phase.
Solution.
Solution .
-4-12
24.90
MgPt(CN) 4 .6.8-8.iH 2 O
48.7
40.89
MgPt(CN) 4 . 4 H 2
o-5
26.9
" (Red)
55
41-33
"
5-5
28.65
"
58.1
42.15
"
18.0
32.46
"
69.0
43-49
'
36.6
39-53
"
77.8
44.90
"
45 -
4i-33
87.4
45-5 2
"
46.2
42 .0
90.0
45- 6 5
42.2
40.21
MgPt(CN) 4 . 4 H 2 O
93-o
45-04
46-3
39.85
" (Bright Green)
96.4
44-33
MgPt(CN) 4 . 2 H 2 O
100.
44-o
(White)
MAGNESIUM FLUORIDE MgF 2 .
One liter of water dissolves 0.076 gram MgF 2 at 18 by conductivity
method. (Kohlrausch Z. physik. Ch. 50, 356,' 04- '05.
MAGNESIUM HYDROXIDE Mg(OH) 2 .
One liter of water dissolves 0.008 0.009 g m - Mg(OH) 2 at 18 by
Conductivity method. (Dupre and Brutus Z. angew. Ch. 16, 55, '03.)
SOLUBILITY OF MAGNESIUM OXIDE IN AQUEOUS SOLUTIONS CONTAINING
SODIUM CHLORIDE AND SODIUM HYDROXIDE.
(Maigret Bull. soc. chim. 33, 631, '05.)
Grams MgO per Liter Solution with Added:
Gms. NaCl
per Liter.
125
I4O
160
0.8 g. NaOH
per Liter.
O.O7
0.045
none
4.0 g. NaOH
per Liter.
0.03
none
MAGNESIUM HYDROXIDE 182
SOLUBILITY OF MAGNESIUM HYDROXIDE IN AQUEOUS SOLUTIONS OP
AMMONIUM CHLORIDE AND OF AMMONIUM NITRATE AT 29.
(Herz and Muhs Z. anorg. Ch. 38, 140, '04.)
NOTE. Pure Mg(OH) 2 was prepared and an excess shaken with
solutions of ammonium chloride and of ammonium nitrate of different
concentrations.
Concentration of
Acm Kequirea
for Liberated
Normality of:
Grams per Liter.
(Normal.)
(Normal.) CC<
'Mg(OH) 2 . NH4C1'.
Mg(OH) 2 . NH4C1.
. 7 (NH4C1)
0.09835
0.156 0.388
4.55 20.86
o . 466
O.IIOS
0-loS 0.250
3-!5 *3-39
o-35
0.09835
0.089 0.172
2.60 9.21
0-233
O.IIOS
0.0638 0.106
1.86 5.67
O.IIOS
0.049 0.0771
i-43 4-i3
0.35 (NH 4 N0 3 )
O.IIOS
0.0833 O.l834(NH4NO3)2 .43 14.69
0.175
O.IIOS
0.0495 0.076
" i-45 6.09
MAGNESIUM IODATE Mg(IO 3 ) 2 .
SOLUBILITY IN WATER.
(Mylius and Funk Ber. 30, 1722, '97; Wiss. Abh. p. t. Reichanstalt 3, 446, 'oo.)
Gms.
Mols.
Gms.
Mols.
t o Mg(I0 3 ) 2
per TOO
Mg(I0 3 ) 2 Solid
per loo Mols. Phase.
t
Mg(I0 3 ) 2 Mg(I0 3 ) 2 Solid
per 100 per too Mols. Phase.
Gms. Solution.
H 2 0.
Gms. Solution.
H 2 0.
3
.1
O
.15 Mg(I0 3 ) 2 .ioH 2
6
.8
o-34
Mg(I0 3 ) 2 . 4 H 2
20
10
.2
O
55
10
6
4
0.30
"
30
17
4
I
.01
18
7
.6
0.40
35
21
9
I
35
20
7
7
0.40
"
67.
5
10
.0
35
8
9
0.47
"
63
12
.6
0.69
"
100
J 9
3
i .13
"
Sp. Gr. of solution sat. at 18= 1.078.
MAGNESIUM IODIDE MgI 2 .
SOLUBILITY IN WATER.
(Menschutkin Chem. Centrb. 77, I, 646, '06; at 18, Mylius and Funk Ber. 30, 1718, '97.)
O
10
18
20
25
30
40
45
Solid
Phase.
MgI 2 .8H 2 O
Gms. MgI 2 per
100 Grams Solution.
5O.O
53.0 (59.7 M.andF.)
53-4
54-4
55-4
57-8
59-9
Density of saturated solution at 18= 1.909. (M.andF.)
t o Grams MgI 2 per Solid
' 100 Grams Solution. Phase.
50
6l.6
MgI 2 .6H 2
70
61.85
"
90
62 . I
M
110
62.25
"
I4O
62-5
"
1 60
63.0
"
200
64.1
"
183 MAGNESIUM IODIDE
SOLUBILITY OF MAGNESIUM IODIDE ALCOHOL COMPOUNDS IN THE
CORRESPONDING ALCOHOLS.
(Menschutkin Chem. Centrb. 77, I, 335, '06.)
Results expressed in molecular per cent.
. MgI 2 .6CH 3 OH MgI 2 .6C 2 H 5 OH . MgI 2 .6CH 3 OH MgI 2 .6C 2 H 8 OH '
* inCH 3 OH. in C 2 H 6 OH. *' in CH 3 OH. inC 2 H fi OH.
o 6.3 2.3 ioo 10.5 19.7
10 6.6 3.1 120 ii. 8 28.2
20 7.0 4.0 140 13.4 53-6
40 7.8 6.2 160 15.7 80.3(145)
60 8.6 9.3 180 18.7 100.0(146.5)
80 9.5 13.5 200 23.1
SOLUBILITY OF MAGNESIUM IODIDE Di ETHERATE (MgI 2 .2C 4 Hi O) IN
ETHYL ETHER.
(Menschutkin Z. anorg. Ch. 49, 46, '06.)
Synthetic Method used, see Results in the Critical
page 9. Vicinity.
Grams per ioo Gms. Solution. Gms. per ioo Cms. ScJution.
MgI 2 . MgI 2 .2C4H 10 O. ' MgI 2 . MgI 2 .2C 4 H, O.
5-4 i-45 2.2 37-3 *9-4 29.3
ii. 8 2.43 3.7 38.5 22.45 34-4
J 5- 6 3-46 5.3 3 8 -5 26.07 39-9
18.1 5.4 8.3 38.5 29.8 45.7
20.4 7.55 ii. 6 38 32.8 50.3
22.2 11.28 17.3
Two liquid phases appear near the melting point of the magnesium
iodide di etherate. The lower may be considered as a solution of ether
in di etherate, and the upper as a solution of the lower layer in ether.
The critical temperature is 38.5.
Lower Layer. Upper Layer.
Gms. per ioo Gms. Solution. Gms. per ioo Gms. Solution
MgI 2 . MgI 2 .2C 4 H 10 0. ' ' MgI 2 . MgI 2 .2C 4 H 10 0. "
14-8 35.5 54.4 18.6 13.57 20.8
20.0 35.8 54.8 23.2 14.4 22.1
28.4 35.5 54.4 24.4 14-6 22-4
33 35-7 54-7 3 2 -4 i5- 82 24.2
35 35-3 54-i
The solubility of double compounds of magnesium iodide and
alkyl esters in the corresponding acetates is given by Menschutkin
Chem. Centrb. 77, I, 647, '06. For the solubility of magnesium iodide
hexa acetic acid compound in anhydrous acetic acid solutions, see Chem.
Centrb. 77, II, 1482, '06.
MAGNESIUM NITRATE 184
MAGNESIUM NITEATE Mg(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt 3, 437, *oo.)
Gms. Mols. Gms. Mols.
Mg(NO 3 ) 2 Mg(NO 3 ) 2 Solid Mg(NO 3 ) 2 Mg(NO 3 ) 2 Solid
t. per ioo Gms. per ioo Mols. Phase. t. per ioo Gms. per ioo Mols. Phase.
Solution. H 2 O. Solution. H 2 O.
2 3 35-44 6.6 Mg(N0 3 ) 2 . 9 H 2 40 45-87 10.3 Mg(NO 3 ) 2 .6H 2 O
20 36.19 7-0 80 53-69 14.6
18 38.03 7.4 90 57.81 16.7
18 38.03 7.37 Mg(N0 3 ) 2 .6H 2 89 63.14 20-9J
-4-539-50 7-92 " 77-5 6 5- 6 7 23.2 V*
o 39-96 8.08 67 67.55 25- 1 )
-f-l8 4 2 -33 8.9 * Reverse curve-
Sp. Gr. of solution saturated at 18 = 1.384.
MAGNESIUM OXALATE Mg.C 2 O 4 .2H 2 O.
One liter of water dissolves 0.3 gram MgC 2 O 4 at 18 (conductivity
method). (Kohlrausch Z. physik. Ch. 50, 356, '05.)
MAGNESIUM (Hypo) PHOSPHATE Mg 2 P 2 O 6 .i 2 H 2 O.
One liter of water dissolves 0.066 gram hypophosphate.
(Salzer Liebig's Ann. 232, 114, '86.)
One liter of water dissolves 5.0 grams magnesium hydrogen
hypophosphate MgH 2 P 2 O 6 .4H 2 O. (Salzer.)
MAGNESIUM SALICYLATE Mg(C 7 H 5 O 3 ) 2 . 4 H 2 O.
One liter of saturated solution contains 8.015 grams of the salt.
(Barthe Bull. soc. chim. [3] n, 519, '94.)
MAGNESIUM FLUOSILICATE MgSiF 6 .6H 2 O.
One liter of water dissolves 652 grams of the salt at 17.5. Sp. Gr.
Of Solution = 1.235. (Stolba Chem. Centrb. 578, '77 )
MAGNESIUM SULPHATE MgSO 4 .
SOLUBILITY IN WATER.
(Mulder; Tilden J. Ch. Soc. 45, 409, '84; Etard Com pt. rend, 106, 741, '88.)
Etard' s results for the lower temperatures are somewhat low.
Mulder's and Til den's results agree very well.
t o Gms. MgSOj per ioo Gms. Solid t o Gms. MgSO 4 per ioo Gms. Solid
Solution. Water. Phase. Solution. Water. Phase.
O 21.2 26.9 MgSO 4 .7H 2 O 50 33-5 50-3
10 24.0 31.5 60 35.5 55.0
20 26.5 36.2 70 37.5 59.6
25 28.2 38.5 80 39.1 64.2
30 29-0 40.9 " 90 40.7 68.9
40 31.2 45.6 " ioo 42.5 73.8
no 45-5 83.6
For temperatures between 123 and 190, grams MgSO 4 per ioo grams
solution = 48.5 -0.4403 t. (Etard).
For densities of aqueous solutions of MgSO,, see Barnes and Scott
J. Physic. Ch. 2, 542, '98.
185 MAGNESIUM SULPHATE
SOLUBILITY OF MAGNESIUM SULPHATE IN METHYL AND ETHYL
ALCOHOLS.
(de Bruyn Rec. trav. chim. n, 112, '92.)
Solvent. t. Per 100 Gms. Solvent. Solvent. t. Per 100 Cms. Solvent.
Abs. CH 3 OH 18 1.18 gms. MgS0 4 93% Methyl Ale. 17 9.7 gms.MgSO 4 .7H 2 O
17 41-0 " MgS0 4 . 7 H 2 50% " 3-4 4.1
" 3-4 29.0 " Abs. C 2 H 5 OH 3 1.3 " "
SOLUBILITY IN AQUEOUS ETHYL ALCOHOL.
(Schiff Liebig's Ann. 118, 365, '61.)
Wt. per cent Alcohol 10 20 40
G. MgSO 4 .yH 2 O per 100 gms. solvent 64.7 27 .1 i .65
SOLUBILITY OF MAGNESIUM SULPHATE IN SATURATED SUGAR SOLUTION
AT 31.25.
(Kohler Z. Ver. Zuckerind. 47, 447, '97.)
ioo grams saturated aqueous solution contain 46.52 grams sugar -f
14.0 grams MgSO 4 .
ioo grams water dissolve 119.6 grams sugar + 36.0 grams MgSO 4 .
MAGNESIUM POTASSIUM SULPHATE MgK 2 (SO 4 ) 2 .6H 2 O.
SOLUBILITY IN WATER.
(Tobler Liebig's Ann. 95, 193, '55.)
t.-o 20 30 45 60 75
Gms. MgK 2 (S0 4 ) 2
per ioo gms. H 2 O 14.1 25.0 30.4 40.5 50.2 59.8
MAGNESIUM SULPHITE MgSO 3 .6H 2 O.
ioo grams cold water dissolve 1.25 grams sulphite; ioo grams boil-
ing water dissolve 0.83 gram.
(Hager Chem. Centrb. 135, '75.)
MALONIC ACID CH 2 (COOH) 2 .
SOLUBILITY IN WATER.
(Klobbie Z. physik. Chem. 24, 622, '97; Miczynski Monatsh. Ch. 7, 259, '86; Henry Compt. rend
99, 1157, '84; Lamouroux Ibid. 128, '998, '99.)
Grams CH 2 (COOH) 2 per ioo Grams CH 2 (COOH) 2 per ioo
I .
Gms. Solution.*
cc. Solution (L.).
Gms. Solution.*
cc. Solution (L.;
o
52.0
61 .0
So
71.0
93-o
10
56.5
67.0
60
74-5
100.0
20
60.5
73-o
70
106.0
25
62 .2
7 6 -3
80
82.0
30
64.0
80.0
IOO
89.0
40
68.0
86.5
132
(m. pt.) loo-o
* Average curve from results of K., M., and H.
MALONIC ACID
186
SOLUBILITY OF MALONIC ACID IN ETHER.
(Klobbie.)
k.
Gms. CH 2 (COOH) 2
per ioo Gms.
Solution.
f.
Gms. CH 2 (COOH) 2
per ioo Gms.
Solution.
o
10
7-74
30
80
10-5
33-o
20
9.00
90
39-o
25
9-7
Gms. CH 2 (COOH) 2
t . per ioo Gms.
Solution.
IOO 46.0
no 56-0
120 70.0
132 (m. pt.) 100.0
ioo grams saturated solution of malonic acid in pyridine contain
14.6 grams at 26.
(Holty J. Physic. Ch. 9, 764, '05.)
SOLUBILITY OF SUBSTITUTED MALONIC ACIDS IN WATER.
(Lamouroux.)
Grams per ioo cc. Saturated Aqueous Solution.
t.
r
Methyl
Ethyl
n Propyl
n Butyl
Iso Amyl
Malonic
Malonic
Malonic
Malonic
Malonic
Malonic
Acid.
Acid.
Acid.
Acid.
Acid.
Acid.
61.1
44-3
5 2.8
45-6
ii. 6
38.5
15
70.2
58-5
6 3 .6
60. 1
30-4
51-8
25
76.3
67.9
71.2
70.0
43-8
79-3
30
92.6
9 r -5
90.8
94.4
79-3
83-4
MANGANESE BORATE MnH 4 (BO 3 ) 2 H 2 O.
SOLUBILITY IN WATER AND IN AQUEOUS SALT SOLUTIONS.
(Hartley and Ramage J. Ch. Soc. 63, 137, '93.)
Grams MnH4(BO 3 ) 2 per Liter in Solutions of:
t.
H 2 O +
Na 2 S0 4
Na 2 S0 4
NaCl
CaCl 2
trace
(0.2 Gms
(20 Gms.
(20 Gms.
(20 Gms.
Na 2 SO 4 .
per Liter). per Liter).
per Liter).
per Liter).
14
0-94
I .7
18
0-77
I-3I
2 .91
40
0.50
0.69
(52) 0.65
2.44
60
0.36
O-6o
2.25
80
0.08
0.12
0.29
MANGANESE BROMIDE MnBr 2 . 4 H 2 O.
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 537, '94.)
t.
Gms. MnBr 2
per ioo Gms.
Solution.
Solid
Phase.
t.
Gms. MnBr 2
per-ioo Gms.
Solution.
Solid
Phase.
20
52-3
MnBr 2 . 4 H 2 O
40
62.8
MnBr 2 .4H 2 O
10
54-2
u
50
64-5
"
56.0
"
60
66.3
10
57-6
"
70
68.0
20
59-5
(1
80
69.2
MnBr.2H 2 O
2$
60.2
II
90
69-3
.
30
61.1
M
IOO
69-5
i8 7
MANGANESE CHLORIDE
MANGANESE CHLORIDE MnCl 2 .4H 2 O.
SOLUBILITY IN WATER.
(Etard; Dawson and Williams Z. physik. Chem. 31, 63, '99-)
Mols. MnCJ 2
per 100 Mols. H 2 O.
,. o Sp. Gr. of G
rams MnCJ 2 per 100 Gram
Solutions.
Water
Solution.
20
53-8
35-o
10
58-7
37-o
O
63-4
38-8
+ 10
68.1
40-5
20
73-9
42-5
25
.4991
77.18
43-55
30
5049
80.71
44-68
40
5348
88.59
46.96
50
5744
98.15
49-53
57-65
.6097
105.4
5J-33
60
.6108
108.6
52.06
70
.6134
no. 6
52-52
80
112.7
52.98
90
114.1
53-2
100
ii5-3
53-5
1 20
118.8
54-3
140
iiQ-5
55-o
II.OS
IJ -55
12 .69
14.05
15 .IO
J5-55
15-85
16.14
Solid
Phase.
MnCl 2 . 2 H 2 O
One liter of water dissolves 87.0 grams MnCl 2 . One liter of sat. HC1
dissolves 19.0 grams MnCl 2 at 12
(Ditte Compt. rend. 92, 242, '81.)
MANGANESE FLUO SILICATE MnSiF 6 .6H 2 O.
100 grams H 2 O dissolve 140 grams salt at 17.5. Sp. Gr. of solution
= 1.448. (Stolba Chem. Centrb. 292, '83.)
MANGANESE NITRATE Mn(NO 3 ) 2 .6H 2 O.
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt 3, 438, 'oo.)
Gms.
Mn(NO 3 ) 2
Mols.
Mn(NO 3 ) 2 Solid
t .
Gms.
Mn(N0 3 ) 2
Mols.
Mn(N0 3 ) 2 Solid
par 100
Gms. Sol.
per 100 Phase.
Mols. H 2 O.
per TOO
Gms. Sol.
per TOO Phase.
Mo]s.H 2 O.
-29
42.29
7
.37 Mn(NO 3 ) 2 .6H 2 O.
18
57
33
13
.5
Mn(NO 3 ) 2 .6H 2 O.
-26
43-15
7
63
25
62
37
16
7
21
44-3
8
O
27
65
.66
J 9
.2
Mn(NO 3 ) 2 -3H 2 O.
-16
45-52
8
4
29
66
99
2O
4
"
- 5
48.88
9
.61
67
38
20-7
o
50-49
10
.2
34
7 1
3 1
24
9
"
+ 11
54-50
12
.0
35-5
76
.82
33
3
Sp. Gr. of solution saturated at 18 = 1.624.
MANGANESE (Hypo) PHOSPHITE Mn(PH 2 O 2 ) 2 H 2 O.
100 grams H 2 O dissolve 15.15 grams salt at 25, and 16.6 grams at
b. pt.
MANGANESE SULPHATE
188
MANGANESE SULPHATE MnSO 4> 5H 2 O.
SOLUBILITY IN WATER.
(Cottrell J. Physic. Ch. 4, 651, '01; Richards and Fraprie Am. Ch. J. 26, 77, '01. The results
of Linebarger Am. Ch. J. 15, 225, '93, were shown to be incorrect by Cottrell, and this conclusion
was confirmed by R. and F.)
Grams MnSO 4 per
4. loo Gms.
' Water.
Solution.
10
47
.96
32
.40
O
53
23
34
73
5
56
.24
35
99
9
59
33
37
.24
12
61
77
38
.19
14-3
63
93
39
.00
5
58
.06
36
.69
9
59
.19
37
.18
15
61
.08
37
.91
2 5
64
78
39
67
76
40
38
35-5
7 1
.61
4i
74
Solid Phase.
MnSO 4 .7H 2 O
MnSO 4 .sH 2 O
Grams MnSO 4 per
t. 100 Gms.
Water.
Solution.
16
63.94
38-99
18.5
64.19
39.10
25
65 -3 2
39-53
30
66.44
39-93
39-9
68.81
40.77
49-9
72.63
42.08
41.4
60.87
37-84
5
58.17
36.76
60
55-o
35-49
70
52.0
34-22
80
48.0
32-43
90
42-5
29.83
100
32.0
24.24
Solid Phase
MnSO 4 . 4 H 2 O
MnSO 4 .H 2 O
SOLUBILITY OF MANGANESE SULPHATE, COPPER SULPHATE MIXED
CRYSTALS IN WATER AT 18.
(Stortenbecker Z. physik. Chem. 34, 112, 'oo.)
Mols. per 100 Mols. Mol. per cent
H 8 O. Cu in :
'Cu. Mn. Solution. Crystals.
Solid Phase, CuMnSO 4 .sH 2 O, Triclinic.
2.282 o
2.23 0-44
i-54 3-76
4.70
[I .06 5.58
Mols. per 100 Mols.
H 2 0.
Mol. per cent
Cu in:
100
100
[0
73
6-37
90
5
.
.
83
5
.
O
34
7-
03
74
.1
97
3
.
.
57
7
95
.1
.
7-
37
3 1
.0
81
3
Solid
Phase
. Cu
2 9
.0
26
21
.1
.8
70
4
[i-
,06
5'.
58
21
2O
.2
O
42
34
.6
4
[a.
73
6.
37
15
I 3
9
9
22
15
9]
.2*
8
Cu. Mn. Solution. Crystals.
Solid Phase, CuMnSO 4 .sH 2 O. Triclinic.
10.27 10.5]
5.0 4-9
4 . 60
2.31
o.o
2.15
O-O
20-4 28.2*
15-9
12 .45
10.27
o.o
23.5]
20.8
16.0]
5.8*
o.o
* Indicates meta stabil points.
CuMnSO 4 .5H 2 O = 100-90.8 and 2.11-0 mol. percent Cu.
CuMnSO 4> 7H 2 O = 37.8-4.92 mol. per cent Cu.
SOLUBILITY OP MANGANESE SULPHATE IN GLYCOL.
100 grams saturated solution contain 0.5 gram MnSO 4 .
fde Coninck Bui. acad roy. Belgique, 359, '05.)
i8 9 MANGANESE SULPHATE
SOLUBILITY OF MANGANESE SULPHATE IN AQUEOUS ETHYL AND
PROPYL ALCOHOL SOLUTIONS AT 20.
(Linebarger Am. Ch. J. 14, 380, '92; Snell J. Physic. Ch. 2, 474, '98.)
Cone, of Alcohol Cms. MnSO 4 per 100 Cms. Aq. Cone, of Alcohol Gms.MnSO 4 per looGms. Aq.
in Wt. per cent. Ethyl Ale. Propyl Ale! in Wt. per cent. Ethyl Ale. ' Propyl Ale.'
34 9-5 6.0 44 3-3 *-9
36 7-2 4.6 48 2.2 1.4
38 S- 8 3-5 5 2 i-4 LI
40 4.7 2.8
MANGANESE POTASSIUM VANADATE MnKV 5 O 14 .8H 2 O.
100 grains H 2 O dissolve 1.7 grams salt at 18.
(Radan Liebig's Ann. 251, 129, '89.)
MANNITE C 6 H 8 (OH) 6 .
SOLUBILITY IN WATER.
(Campetti Abs. in Z. physik. Chem. 41, 109, '02.)
Grams CeHgCOH^ per 100 Grams.
' Water. Solution. '
10 T 3-94 12.78
15 16.18 14.63
20 18.98 16.86
100 grams of saturated solution of mannite in Pyridine contain 0.47
gram C 6 H 8 (OH) 6 at 26. (Hoity j. Physic. Ch. 9, 764, '05.)
MANNITOL C 6 H 8 (OH) 6 .
SOLUBILITY IN WATER.
(Findlay J. Ch. Soc. 81, 1219, '02.)
Gms. G.M. Gms. G. M.
+ o Wt. of i cc. Mannitol Mannitol . Wt. of i cc. Mannitol Mannitol
in Grams. perioo per 100 ' in Grams. per 100 per 100
Gms.H 2 O. G.M.H 2 O. Gms.H 2 O. G.M.H 2 O.
o 1.044 7-59 o-75 50 1-099 (47-7) 47-Qi 4-65
10 ... 11-63 I *2
2.98
1.89
7.71
7.64
8.40
8.38
91.24
91.78
1RbCl. S HgCl 2
Calc. Composition
1.50
7-55
8-30
91.81
8. 20% RbCl, 9 i.8%HgCl 2
I .10
7.21
8.07
91.58
. '
0.79
7.16
6.91
93-15
j RbC1.5HgCl 2 and HgCl-,
0.84
7.42
2.27
97.09
... j
none
6.90
none
IOO.O
HgCl 2
193 MERCURIC CHLORIDE
SOLUBILITY OF MERCURIC CHLORIDE IN METHYL, ETHYL PROPYL,
n BUTYL, Iso BUTYL AND ALLYL ALCOHOLS.
(Etard Ann. chim. phys. [7] 2, 563, '94.)
NOTE. For the solubility in Me, Et, and propyl alcohols at room
temperature, see Rohland Z. anorg. Ch. 18, 328, '98; at 8.5, 20 and
38.2, see Timofejew Compt. rend. 112, 1224, '91; in Me and Et
alcohols at 25, see de Bruyn Z. physik. Ch. 10, 783, '92. The deter-
minations of these investigators agree well with those of Etard, which
are given below.
Grams HgG 2 per 100 Grams Saturated Solution in:
I .
CHgOH.
C 2 H 5 OH.
C 3 H 7 OH. CH 3 (CH 2 j 3 OH. (CH 3 ) 2 CHCH 2 OH.
CH 2 .CH.CHj,OH.
-30
14-5
15.0
20
20.1
J 5-7
J 3-5
21 .O
10
I 5 .2
26.5
I6. S
13-7
. . .
25-5
2O. I
29.8
17.4
14.0
5-2
30.0
+ 10
26.3
30.6
18.0
14-3
6.0
37-5
20
34-o
32.0
18.8
14.6
6.8
46-5
25
40.0
32-5
19-5
J 5-5
7-2
30
44-4
33-7
20.0
16.5
7-5
40
58.6
35-6
23.0
19.6
9-7
60
62.5
41.2
29.8
26.5
17.0
. . .
80
66.0
47-5
36.8
33-o
24.9
100
70.1
54-3
43-8
31 .7
1 20
73-5
61.5
50.6
39-2
78.5
SOLUBILITY OF MERCURIC CHLORIDE IN ACETIC ACID.
(Etard.)
t.
Gms.
HgCl 2 per
100 Gms.
f.
Gms.
HgCl 2 per
loo Gms.
t<>.
Gms.
HgCU per
loo Gms.
Solution.
Solution.
Solution.
20
2-5
70
8-5
no
I 3 .6
30
3-5
80
9-7
1 20
16.5
40
4-7
90
II .0
130
20.7
50
6.0
IOO
12.4
140
25.2
60
7-2
160
34-8
SOLUBILITY OF MERCURIC CHLORIDE AND SODIUM CHLORIDE IN ETHYL
ACETATE AT 40.
(Linebarger Am. Ch. ]. 16, 214, '94.)
Mols.
per loo Mols.
Gms. .
per 100 Gms.
Gms. per
loo Gms.
Acetate.
Acetate
Solution.
Solid
Phase.
NaCl.
HgCl 2 .
NaCl.
HgCl 2 .
NaCl.
HgCl 2 :
0.8
12-9
0.53
39-7
o-53
28.4
HgCl 2
2-3
12-4
i-53
38-15
27.61
it
4-3
l6-4
2-85
5 -44
2.78
33-54
"
9.1
22.85
6.05
86.14
5.60
46.28
M
18.5
34-9
12.29
107.4
10.95
51.76
II
20. o
40.0
13.29
123.0
n-73
55- 18
HgCl 2 + NaCl
The double salt (HgCl 2 ) 2 .NaCl is formed under proper conditions.
MERCURIC CHLORIDE
194
SOLUBILITY OF MERCURIC
CHLORIDE IN
ACETONE.
ETHYL ACETATE AND IN
(Etard; von Laszcynski Ber. 27, 2285, '94; Krug and McElroy J. Anal. Ch. 6, 186, '92; Linebar-
ger Am. Ch. J. 16, 214, 94; Aten Z. physik. Ch. 54, 121, '05.)
NOTE. The results obtained by the above named investigators
were calculated to a common basis and plotted on cross-section paper.
The variations which were noted could not be satisfactorily harmonized,
and therefore all the results are included in the following table.
SOLUBILITY.
In Ethyl Acetate.
In Acetone.
Grams HgCl 2 per TOO Grams Solution.
Gms.
per TOO Gms. Solution.
tl . t
Laszcynski.
Aten. Linebarger.
N 1
Etard. K and McE. Laszcynski. Aten.
Etard.
10
.
23-
O
40
44-0*
57
.0
O
22
O
23-
2
32
.0
40
49-7
43-o*
61
7
+ 10
22
.2
23-
5
32
5
40
52.0
51.0^-58.9!
6!
7
20
22
5
23-
4
32
7
40
54
58- st
61
7
25
22
7
23
5
33
.0
40
37-4 55- 2
5 8. 2 f
61
-7
30
23
.0
.
33
.2
40
... ...
61
7
40
23
5
.
33
5
40
61
-7
50
24
.0
33
5
41
61
7
60
24
7
.
.
42-5
... ...
61
7
80
26
.0
45-2
61
7
IOO
.
48.0
1 20
.
.
50.8
...
.
150
.
.
.
55-o
...
(*)
Solid
phase HgCl 2 (CH 3 ) 2 CO.
(t) Solid
Phase HgCl 2 .
loo grams absolute acetone dissolve 143 grams HgCl 2 at 18.
(Naumann Ber. 37, 4332, '04.)
SOLUBILITY OF MERCURIC CHLORIDE IN SEVERAL SOLVENTS.
(Arctowski Z. anorg. Ch. 6, 267, '94; von Laszcynski; Sulc. Z. anorg. Ch. 25, 401, 'oo.)
In Carbon Bisul-
phide (A.).
...
Gms. HgCl 2
per 100 Gms.
Solution.
10
O-OIO
O.OlS
10
O.O26
15
0.032
20
0.042
25
30
0-053
0.063
In Benzene
(von L.).
In Several Solvents
at 18-20 (S.).
Gms. HgCl 2
Gms. HgCl 2
t .
per 100 Gms.
Solvent.
per 100 Gms.
Solution.
Solvent.
IS
o-537
CHBr 3
0.486
41
0.616
CHC1 3
0.106
55
0.843
CC1 4
O.OO2
84
1.769
C 2 H 5 Br
2 .OIO
C 2 H 4 Br 2
1-530
I 9 5 MERCURIC CHLORIDE
SOLUBILITY OF MERCURIC CHLORIDE IN ABSOLUTE ETHYL ETHER.
(Etard; Laszcynski ; Kohler Z. anal. Ch. 18, 242, '79.)
t o Cms. HgCl 2 per t3.CeH 5o NH 2
71.6 71.7 49- 1
71.2 76.3 55.1
70.6 78.3 57.9
71.6 82.1 63. 5 CH(CjH 5 )3 monoclinic
74.3 84.9 68.2
82.1 91.7 80.9
87.3 96.1 90.2
Tri Phenyl METHANE
202
SOLUBILITY OF TRI PHENYL METHANE IN BENZENE.
(Linebarger Am. Ch. J. 15, 45, '93.) (Hartley and Thomas.)
Gms. Gms. , ,
f. C "
,Jtnuti5>3 PC
'^QHe" 13
Solid Phase. t. ViooGt
Solution.
per cent Solid Phase.
' CH(C 6 H 6 ) 3 .
3-9
3 90
C 6 H 6 +CH(C 6 H 5 ) 3 .C 6 H 8 33
12 .6
4-4
CH(C 6 H 6 ) 3 .C 6 H 8
rhombs
4-0
4.06
CH(C6H 6 )3-C6H 6 49 . 4
24.0
8.8
12-5
5-i8
65.6
38-9
17 .2
"
16.1
6.83
73-8
57-5
30.2
"
19.4
7.24
77.1
67.4
39-7
"
23.1
8-95
77-9
76-3
5 -7
"
37-5
42 .0
10.48
19.61
(C6H 5 ) 3 CH.C 6 H 8 7? ,-
+ CH(C 6 H S ) 3 1 7'5
CH(C6H 6 ) 3 70-2
80.2
84.1
5 6 -4
62.8
::
44.6
22 .64
74-6
87-5
69.1
CH(C 6 H 5 ) 3 .
monoclinic
50.1
30.64
76.0
89.0
72.2
"
55-5
40.51
78.8
9o-5
75-3
"
71 .0
I4O.OO
82.3
93-i
81.3
11
76.2
319.67
86.6
95-7
87.8
"
NOTE. Hartley and Thomas call attention to the inaccuracy of Linebarger 's results and the cor-
rectness of Kuriloff 's determinations (Z. physik. Chem. 22, 547, '97).
SOLUBILITY OF TRI PHENYL METHANE IN CARBON BISULPHIDE.
(Etard Ann. chim. phys. [7] 2, 570, '94; below 80, Arctowski Z. anorg. Ch. n, 273, '95.)
Gms. CH(C 6 H 5
t .
per 100 Gms.
Solution.
113
-5 0.98
102
1.24
- 91
1.56
- 8 3
1.91
- 60
3-4
Gms. CH(C 6 H 5 ) 3
t. per 100 Gms.
Solution.
-40
7-5
2O
13 . 7
O
+ 10
25.8
38.7
2O
43-2
30
52-9
40
5
60
70
80
Gms. CH(C 6 H 6 ) 3
per 100 Gms.
Solution.
63
7 2
78.6
85.6
92 . 2
SOLUBILITY OF TRI PHENYL METHANE IN HEXANE AND IN
CHLOROFORM.
(Etard.)
Gms. CH(C6H 5 ) 3 per 100 Gms.
Solution in:
Hexane .
Chloroform.
-5o
10-5
-30
I .2
15.2
20
1.6
I9.O
10
2 .2
23-5
3-5
28.9
+ 10
5-6
35-o
20
8-3
4i-5
Gms. CH(C 6 H5) 3 per 100 Gms.
Solution in:
Hexane.
Chloroform.
30
12-5
48.8
40
2O-
5 6.1
50
2 5 .8
6 3 .8
60
45-7
71.7
70
62 .0
79-8
80
78-5
87.2
90
97.0
203
Tri Phenyl METHANE
SOLUBILITY OF TRI PHENYL METHANE IN PYRIDINE.
(Hartley and Thomas J. Ch. Soc. 89, 1028, '06.)
Synthetic method used, see note, page 9.
Cms. Mol.
CH(QjH 5 )3 per Solid
penooGms. cent Phase.
Solution. CH(C6H 5 ) 3 .
22.8
3 1 '?
37-9
48.7
46.2
53-3
57-6
66.6
70.1
22.0
27.2
30-7
39-5
43-5
CH(C 6 H 6 ) 3
monoclinic
Gms. Mol.
CH(CH 6 ) 3 per Solid
penooGms. cent. Phase.
Solution. CH(C 6 H 6 ) 3 .
59-3
67.8
7 2.8
80.6
86.8
75-6
81.9
85-7
9*-S
95-8
CH(QH 5 ) 3
59 7
66.4
77-2
88.1
SOLUBILITY OF TRI PHENYL METHANE
(Hartley and Thomas.)
IN:
Gms.
Pyrrole.
Mol.
Gms.
Thiophene.
Mol.
t o CH(C 6 H 6 ) 3 per Solid
' per i oo Gms. cent Phase.
Sol. CH(C 6 H 5 ) 3 .
t o CH(C6H 5 ) 3 per Solid
' per ioo Gms. cent Phase.
Solution. CH(C6H 5 ) 3 .
24
.6
24
3
8
. I CH(C 6 H 5 ) 3 .C 4 H 4 NH
rhombs
25
7
26.O
10
.8 CH(C6H 5 )3
i
29
.0
29
.8
10
4
33
5
3 1 - 1
*3
5
3 1
5
33
4
12
.1
44
.0
43-6
21
.1
36.8
42.7
40
49
.6
.1
2O
.8 CH(C6H 6 ) 3
monoclinic
47
53
.6
5
48.4
58.7
24
32
4
9
4 6
9
56
.0
2 5
9
57
4
70.2
44
7
53
.2
63
9
32
.8
57
.6
74-8
50
.6
60
O
72
3
41
.8
62
7
78.7
56
.0 CH(C6H 5 ) 3
63
9
76
7
47
4
67
.0
81.9
60.8
68
5
81
9
55
.6
67
.2
82.1
61
3
7 1
.1
84
4
59
74
.2
87.4
70
5
80
.0
9 1
5
74-8
79.0
90-3
76
3
89
.2
97
.6
9 1
.8
87
.2
96.2
89
9
rhoml
METHYL ACETATE, Butyrate and Propionate.
SOLUBILITY IN WATER AT 22.
(Traube Ber. 17, 2304, '84.)
ioo grams H 2 O dissolve 25.0 grams CH 3 COOCH 3 ; 1.7 grams C 3 H 7
COOCH 3 ; 5.0 grams C 2 H 5 COOCH 3 .
METHYL IODIDE, Methylene Chloride and Methylene Bromide.
SOLUBILITY OF EACH IN WATER.
(Rex Z. physik. Chem. 55, 355, '06.)
Grams per ioo Grams H2O.
O
10
20
30
CH 3 I.
CH 2 C1 2 .
CH 2 Br 2 .
i-5 6 5
2-363
I - I 73
1.446
2 .122
I .146
1.419
2 .OOO
I.I48
1.429
1.969
I.I76
METHYL BUTYRATE, 204
METHYL BUTYRATE, METHYL VALERATE.
SOLUBILITY OF EACH IN AQUEOUS ALCOHOL MIXTURES.
(Bancroft Phys. Rev. 3, 193, '95.)
ioo cc. H 2 O dissolve 1.15 cc. methyl butyrate at 20.
cc. Alcohol cc - H 2 Added * cc . Alcohol cc. H 2 O Added *
in Mixture. Butyrate. Valerate. "* Mixture. Valerate.
3 2.34 1-66 27 41.15
6 - 6.96 5.06 30 52.37
9 12.62 9.03 33 62.25
12 19-45 J 3-4o 36 74.15
15 28.13 18.41 39 91.45
18 33-8o 24.00 42 oo
21 55-64 3-9
24 oo 36,72
* cc. H2O added to cause the separation of a second phase in mixtures of the given amounts of ethyl
alcohol and 3 cc. portions of methyl butyrate and of methyl valerate respectively.
METHYL ETHYL KETONE CH 3 .CO.C 2 H S .
SOLUBILITY IN WATER.
(Rothmund Z. physik. Chem. 26, 475, '08.)
By synthetic method, see Note, page 9.
Gms. Ketone per ioo Cms. Cms. Ketone per ioo Gms.
Aq. Layer. Ketone Layer. Aq. Layer. Ketone Layer,
io 34.5 89.7 90 16.1 84.8
-f-io 26.1 90.0 no 17.7 80.0
30 21.9 89.9 130 21.8 71.9
50 17.5 89.0 140 26.0 64-0
70 16.2 85.7 151.8 (crit. temp.)44-2
MOLYBDENUM TRIOXIDE MoO 3 .
ioo gms. cold H 2 O dissolve 0.187 g m - MoO 3 .
(Dumas; Buchlolz.)
ioo gms. hot H 2 O dissolve 0.104 gm. MoO 3 .
(Hatchett.)
MORPHINE C 17 H 19 NO 3 .H 2 O.
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; Mviller Apoth.-Ztg. 18, 257, '03.)
Gms. Morphine per ioo Gms.
Solvent. Gms. Morphine per ioo Gms. Solution. Solvent. Solution.
At i8-22. At 25. At 8o 6 . 'At i8-22. At 25.
Water 0.0283 0.030 0.0961 Chloroform 0.0655 -555
Alcohol ... 0.600 1.31(60) Amyl Alcohol ... 0.8810
Ether 0.0131 0.0224 ... Ethyl Acetate 0.1861 0.1905
Ether sat. with Petroleum
H 2 O 0.0094 ... ... Ether 0.0854
H 2 O sat. with Carbon Tetra
Ether 0.0447 Chloride 0.0156 0.032(17)
Benzene 0.0625 Glycerine 0.45 (15.5)
205 MORPHINE
SOLUBILITY OP MORPHINE IN AQUEOUS SOLUTIONS OF SALTS AND
BASES AT ROOM TEMPERATURE, SHAKEN EIGHT DAYS.
(Dieterich Pharm. Centrh. 31, 395, '90.)
In N/io Salt or Base. In N/i Salt or Base.
Grams per Liter. Grams per Liter.
|. csau or case. <
Salt or Base.
Morphine.
Salt or Base.
Morphine.
NH 4 OH
3-SI
O.2O
35-08
0-505
(NH 4 ) 2 C0 3
4.80
0.031
48.03
O.O4O
KOH
4.62
2.78
46.16
. . .
K 2 C0 3
6.92
O-2O
69.15
o-379
KHCO 3
IO.O2
O.O24
100.16
0.040
NaOH
4-00
3-33
40.05
. . .
Na 2 CO 3
5-30
0.09
53-03
0.14
NaHCO 3
8.41
0.032
84.06
0.044
Ca(OH) 2 (sat.)
I .00 (2 5 )
MORPHINE ACETATE CH 3 COOH.C 17 H 19 NO 3 . 3 H 2 O, Morphine
Hydrochloride HC1.C 17 H 19 NO 3 .3H 2 O, Morphine Sulphate H 2 SO 4 .
(C 17 H 19 NO 3 ) 2 .5H 2 O, and Apo Morphine Hydrochloride HC1.C 17
H 17 N0 2 .
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.)
Grams per 100 Grams of Solvent.
Solvent.
Acetate.
Hydrochloride.
Sulphate.
Apo M. Hydrochloride.
'25
80.
25.
80,
25.
80
25-
80.'
Water
44-
9
50.0
5-8l
200.
6-53
166.
6
2 -53
6.25
Alcohol
4-
6
40.0*
2.4
2.
8*
0.22
0.
53*
2.62
3-33
Chloroform
o.
21
. .
. . .
. .
.
.
.
0.026
Ether
. . ,
. . .
. . .
. .
.
. . .
. .
-53
Glycerine
19.
2
20. Of
. .
* 60. 1 15.5.
ioo gms. H 2 O dissolve 1.69 gms. apo morphine hydrochloride at
15.5, and 2.04 gms. at 25.
ioo gms. 90% alcohol dissolve 1.96 gms. apo morphine hydro
Chlorde at 2 5. (Dolt Pharm. J. [4] 22, 345, '75-)
ioo gms. H 2 O dissolve 4.17 gms. morphine sulphate at 15.
(Power Am. J. Pharm. March, '82.)
MUSTARD OIL Allyl Isosulphocyanic Ester CS:NC 3 H 5
SOLUBILITY IN SULPHUR BY SYNTHETIC METHOD. See Note, p. 9.
(Alexejew Ann. Physik. Chem. 28, 305, '86.)
Grams Mustard Oil per ioo grams.
Sulphur Layer. Mustard Oil Layer.
90 10 72
IOO 12 67
no 15 62
120 23 51
124 (crit. temp.) 35
a NAPHTHYLAMINE
206
a NAPHTHYLAMINE p Sulphonic Acid (Naphtion Acid), i : 4
C 10 H 6 NH 2 .SO 2 H and a Naphthalamine o Sulphonic Acid, i : 2
a C 10 H 6 NH 2 .S0 2 H.
SOLUBILITY OF EACH IN WATER.
(Dolinski Ber. 38, 1836, '05.)
O
10
20
30
40
Gms. per 100
Gms. H 2 O.
Gms. per loojGms. H 2 O.
p Sulphonic
o Sulphonic
t .
p Sulphonic
o Sulphonic
Ac.
Ac.
Ac.
Ac.
0.027
O.24
50
0.059
0.81
0.029
0.32
60
0.075
I .OI
0.031
0.41
70
0.097
I .37
0.037
0.52
80
0.130
I. 80
0-048
0.65
90
0.175
2 .40
IOO
o .228
3 -19
NAPHTHALENE C 10 H 8 .
SOLUBILITY IN METHYL, ETHYL, AND PROPYL ALCOHOLS. .
(Speyers Am. J. Sci. [4] 14, 294, '02 ; at 19.5, de Bruyn Z. physik. Chem. 10, 784, '92 ; at n, Timo
feiew Compt. rend. 112, 1137, '91.)
The original results were calculated to a common basis, plotted on
cross-section paper, and the following table read from the curves.
In Methyl Alcohol.
Wt. of i ci
Gms. C 10 H 8
Solution.
CH^OH"'
O
0.8194
3-48
10
0.812
5-6
2O
0.807
8.2
25
0.805
9.6
30
0.804
II .2
40
0.805
16.2
50
0.813
26.O
60
0.837
5O.O
65
0.870
70
0.9023
(68) .'.'.'
In Ethyl Alcohol.
In P-opyl Alcohol.
Wt. of i cc.
Solution.
Gms. C 10 H 8
per zoo Gms
C 2 H 6 OH.
0.8175
5-o
0.814
7-o
O.SlO
9 .8
0.809
"3
0-809
13-4
0.812
19.5
0.822
35-o
0.855
67.0
0.890
96.0
0.930
179.0
Wt. of i cc.
Solution.
0.8285
0.824
0.821
0.82O
O.82O
0.823
0-837
0.867
0.897
0-933
Gms. Cjo-hs
per 100 Gms.
C 3 H 7 OH.
4-45
5-6
8.2
9.6
xx .4
16.4
26.0
50.0
80.0
'34-1 (68.5)
SOLUBILITY OF NAPHTHALENE IN AQUEOUS ACETONE.
(Cady J. Physic. Ch. 2, 168, '98.)
Grams per 100 Grams Solution.
1
Acetone.
Water.
Naphthalene.
IO.O
89.92
0.05
19.91
80.0
O.O9
29.92
69.67
O.4I
40.8l
58.22
0-97
48.67
48.68
2 -65
57-43
36.64
5-93
60.43
25-75
13.82
65-5
55-3
45
38
32.2
28.5
28.2
The isotherms for intervals of 10 lie so close together that they
are practically indistinguishable for the greater part of their length.
207
NAPHTHALENE
SOLUBILITY OF NAPHTHALENE IN:
Chloroform.
Carbon Tetra
Chloride.
Carbon Di
Sulphide.
(Speyers; Etard.)
(Schroder Z. physik. (Arctowski Compt.
Ch. n, 457, '93.) rend, 121, 123, '95; Etard.)
Wt. of i cc.
Solution.
Gms. CioHg per
100 Grams
CHC1 3 .
Gms. CioHg per
100 Gms. Sat.
Solution .
Gms. CioHg per
100 Gms. Sat.
Solution .
. . .
O.62
I. 3 8
2-3
. . .
8.8
. . .
6.6
15.6
14.1
1-393
19-5
9-0
19.9
1-355
25-5
14-0
27-5
1.300
31.8
20. o
36-3
1.280
35-5
23.0
41 .0
1-255
40.1
26.5
46.0
i .205
49-5
35-5
57-2
i .150
60.3
47-5
67.6
i .090
73-i
62.5
79-2
i .040
87.2
80.0
9o-3
-108
- 82
- 5
- 30
10
o
+ 10
20
25
3
40
5
60
70
NOTE. Speyers' results upon the solubility of C 10 H 8 in CHQ 3 ,
when calculated to grams per 100 grams of solvent, agree quite well
with Etard's (Ann. chim. phys. [7] 2 570, '94 figures, reported on the
basis of grams C 10 H 8 per 100 grams saturated solution.
Benzene.
SOLUBILITY OF NAPHTHALENE IN:
(Schroder; Etard; Speyers.)
Chlor Benzene. Hexane. Toluene.
t.
Gms. CioHg
per zoo Gms.
Solution.
Gms. CioHs
per 100 Gms.
Solution.
Gms. CioHg
per 100 Gms.
Solution.
Wt. of i cc.
Solution.
Gms. CioHg
per 100 Gms.
C 6 H 5 .CH3.
-50
o-3
20
1.9
O
5-5
0.9124
+ 10
27-5
24.0
9.0
0.9126
15.0
20
36.0
31.0
14.0
0-9*35
28.0
25
40-5
35-o
J 7-5
0-9I55
36.0
30
45-5
39-o
21 .O
0.9180
42 -O
40
54-o
48.0
30.8
0.9250
56.0
50
65.0
57-5
43-7
0-935
6 9-5
60
77-5
7o-5
60.6
0-9475
83.0
70
88.0
85.0
78.8
o . 9640
97-5
80
0.9770
in .0
NAPHTHOIC ACID C 10 H 7 COOH.
One liter of aqueous solution contains 0.058 gram C 10 H 7 COOH at
J. (Paul Z. physik. Ch. 14, m, '94.)
/3 NAPHTHOL 208
/3 NAPHTHOL C 10 H 7 OH.
100 grams H 2 O dissolve 0.105 gram at 25, and 1.33 grams at b. pt.;
100 grams alcohol dissolve 164.0 grams at 25.
NARCEINE.
100 grams pure carbon tetra chloride dissolve o.on gram narceine
at 17. (Schindelmeiser Chem.-Ztg. 25, 129, '01.)
NEODYMIUM CHLORIDE NdCl 3 .
100 grams H 2 O dissolve 98.7 grams NdCl 3 at 13, and 140. 4 grams at
I OO. (Matignon Compt. rend. 133, 289, '01 )
NEODYMIUM SULPHATE Nd 2 (SO 4 ) 3 .
SOLUBILITY IN WATER.
(Muthmann and Rolig Ber. 31, 1728, '98.)
Gms. Nd 2 (SO 4 ) 3 per 100 Gms. Gms. Nd 2 (SOj) 3 per 100 Gms.
Solution. * Water. Solution. Water.
o 8.7 9.5 50 3.5 3.7
16 6.6 7.1 80 2.6 2.7
30 4-7 5-o Io8 2 - 2 2 -3
NICKEL BROMATE Ni(BrO 3 ) 2 .6H 2 O.
100 grams cold water dissolve 27.6 grams nickel bromate.
NICKEL BROMIDE NiBr,.
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 539, '94-)
t o Gms. NiBr 2 per
100 Gms. Solution,
80 60.6
100 60 . 8
120 60.9
140 61 .o
NICKEL CHLORATE Ni(ClO 3 ) 2 .
SOLUBILITY IN WATER.
(Meusser Ber. 35, 1419, '02.)
Gms. Mols. Gms. Mols.
+ o Ni(ClO 3 ) 2 Ni(ClO 3 ) 2 Solid t o Ni(ClO 3 ) 2 Ni(ClO 3 ) 2 Solid
' per too Gms. per 100 Phase. penooGms. per 100 Phase.
Solution. Mols.H 2 O. Solution. Mols.H 2 O.
18 49-55 7^4 Ni(ClO 3 ) 2 .6H 2 O 48 67.60 16.65 Ni(ClO 3 ) 2 .4H 2 O
- 8 51.52 8.49 " 55 68.78 17.59
o 52.66 8.88 " 65 69.05 18.01
+ 18 56.74 10.47 " 79-5 75-5 2 4-68
40 64.47 15-35 " -13-5 3 I - 8 5 3-73 Ice
9 26.62 2.90
Sp. Gr. of solution saturated at + 18 = 1.661.
-o G ms.NiBr 2 per f0 Gms. NiBr 2 per
1 * 100 Gms. Solution. 100 Gms. Solution.
20
10
47-7
50-5
2 5
30
57-3
58.0
O
+ 10
2O
53-o
55-o
56.7
40
60
60.0
60.4
20Q
NICKEL CHLORIDE
NICKEL CHLORIDE NiCl 2 .
SOLUBILITY IN WATER.
(Etard; at 12, Ditte Compt. rend. 92, 242, '81.)
t.
Gms. NiCl 2 per
100 Gms. Solution.
t .
Gms. NiCI 2 per
100 Gms. Solution.
t.
Gms. NiCl 2 per
loo Gms. Solution.
-17
29.7
2 5
4O.O
60
45-i
o
35-o
30
40.8
70
46.0
+ 10
37-3
40
42-3
78
46.6
20
39-i
So
43-9
100
46.7
1000 cc. sat. HC1 solution dissolve 4.0 grams NiCl 2 at 12.
100 grams abs. alcohol dissolve 53.71 grams NiCl 2 .6H 2 O at room
temperature.
100 grams abs. alcohol dissolve 10.05 grams NiCl 2 at room temperature.
(Bodtkcr Z. physik. Chem. 22, 511, '97.)
ioo grams abs. alcohol dissolve 2.16 grams NiCl 2 .7H 2 O at 17, and
1.4 grams at 3
(de Bruyn Rec. trav. chim. n, 156, '92.)
ioo grams saturated solution in glycol contain 16.2 grams NiCl 2 at
room temperature. (de Coninck Bui. acad. roy. Belgique, 359, '05.)
NICKEL IODATE
Gms.
Mols.
t.
Ni(I0 3 ) 2
per ioo Gms.
Ni(I0 3 ) 2
per ioo Mols.
Solution.
H 2 O.
O
o-73
0-033
18
1 .01
0-045
30
1.41
0.063
o-53
0.023
18
0.68
0.030
30
0.86
0-039
50
1.78
O-o8o
8
0.52
0.023
Ni(I0 3 ) 2 .
SOLUBILITY IN WATER.
(Meusser Ber. 34, 2440, '01.)
Solid
Phase.
Ni(I0 3 ) 2 4H 2
Ni(IO 3 ) 2 .2H 2 O (i)
Ni(I0 3 ) 2 . 2 H 2 (2)
(i) a Dihydrate.
Gms.
t o Ni(I0 3 ) 2
' per ioo Gms
Solution.
Mols.
Ni(IO 3 ) 2 Solid
. per ioo Mols. Phase.
H 2 0.
18
5o
o-55
0.81
. 0245 Ni(IO3) 2 .2H 2 O (2)
0-035
75
80
1.03
I .12
0-045
0.049
30
I-I35
1.07
. 050 Ni(IO 3 ) 2
o - 046
75
I .02
0-045
90
0.988
0-044
(2) Dihydrate.
NICKEL IODIDE
20
o
10
20
Gms. NiI 2 per
ioo Gms. Solution.
52.0
55-4
57-5
59-7
NiI 2 .
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 546, '94.)
ioo Vjms. aoiuuon.
60
70
80
90
2 5
30
40
Gms. NiI 2 per
ioo Gms. Solution.
60. 7
6l. 7
63-5
64.7
Gms. NiI 2 per
ioo Gms. Solution.
64.8
65.0
65.2
65-3
KICKEL NITRATE
210
NICKEL NITRATE Ni(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt, 3, 439, 'oo.)
Gms. Mols.
t o Ni(N0 3 ) 2 Ni(N0 3 ) 2
per 100 Gms. per 100 Mols.
Solid
Phase.
Solution.
H 2 0.
-23
39-02
6.31
21
39-48
6-43
-10-5
44-13
7-79
21
39-94
6-55
-12.5
41-59
7.01
10
42.11
7.16
- 6
43.00
7-44
44 -3 2
7.86
+ 18
48-59
9-3
Ni(N0 3 ) 2 .9H 2
Ni(NO 3 ) 2 .6H 2 O
Gms. Mols.
t o Ni(N0 3 ) 2 Ni(N0 3 ) 2 Solid
' per 100 Gms. per 100 Mols. Phase.
Solution. H 2 O.
Ni(N0 3 ) 2 .6H 2 O
Ni(N0 3 ) 3 . 3 H 2
20
49-06
9-49
4i
55-22
12 .1
56-7
62.76
I6. 7
58
61.61
15-9
60
61.99
16.0
64
62.76
16.6
70
63-95
17.6
90
70.16
23.1
95
77.12
33-3
100 grams sat. solution in glycol contain 7.5 grams Ni(NO 3 ) at
room temperature. (de Co ninck.)
NICKEL SULPHATE NiSO 4 .
SOLUBILITY IN WATER.
(Steele and Johnson J. Ch. Soc. 85, 116, '04; see also Etard and Mulder.)
Grams NiSO 4 per Grams NiSO 4 per
t. 100 Gms. 5j t o TOO Gms.
Solid
T>U ~
Solution. Water. Solution. Water."
.rnase*
5 20-47 25.74 NiS0 4 . 7 H 2 33.0 30.25 43.35
NiSO 4 .6H 2 O
o 21.40 27.22 35.6 30.45 43-79
' (blue)
9 23.99 31.55 44.7 32.45 48.05
"
22.6 27.48 37.90 50.0 33.39 50.15
"
30 29.99 42.46 53.0 34.38 52.34
"
32-3 30-57 44-02 54.5 34.43 52.50
NiSO 4 .6H 2
33 3 J -38 45-74 " 57 -o 34-8i 53.40
" (green)
34 31-20 45-5 60 35.43 54.80
"
32-3 30-35 43-57 Niso 4 .6H 2 o 70 37.29 59.44
M
33-o 30-25 43-35 " < blue > 80 38.71 63.17
H
34-o 30.49 43-83 99 43-42 76-71
"
Transition points, hepta hydrate <= hexa hydrate =31
Hexa hydrate (blue) => hexa hydrate (green) = 53.3.
5.
211
NICKEL SULPHATE
SOLUBILITY OF MIXTURES OF NICKEL SULPHATE AND COPPER SULPHATE.
Results at 35.
(Fock Z. Kryst. Min. 28, 387, '9?-)
Gms. per 100 Gms. H;jO.
Hol. per cent in Solution. I
dol. per cent in Solid P
hase. Crystal
CuSO 4 . NiSO 4 .
'CuS0 4 . NiS0 4 ."
CuSO 4 . NiSO 4 . ' Form.
9.62 583.9
i-57 98.43
-35 99-65 Rhombic
41.66 484.4
7.69 92.31
2.12 97.8
3
75-39 553-5
11.66 88.34
4-77 95-23 Tetragonal
106.40 506.5
16.92 83.08
6.52 93.48
172.0 483-8
25-63 74-37
13.88 86.17
186.9 468.0
27.90 72.10
l8 .77 8l . 23 Tetragonal
94.91 5-O9 Triclinic
Results at 67.
20.04 729-3
2-65 97-35
0.93 99.07 Monoclinic
66.01 706.2
8.31 91.69
2.86 97.14
88.08 501.6
13-55 86.45
3.92 96.08
47-94 675.0
16.39 83.61
6.66 93.34
249.9 747-8
24-46 75-54
?? 29 Ti f\R /Monoclinic
"3-^ 77 >uc (Triclinic
SOLUBILITY OF MIXTURES OF NICKEL
SULPHATE AND SODIUM SUL-
PHATE, ETC
.
(Koppel; Wetzel Z. physik. Chem. 52, 401, '05.)
Gms. per 100
Gms. per 100
Mols. per 100
t. Gms. Solution.
Gms. H 2 O.
Mols. H 2 0.
Solid
NiSO 4 . Na 2 SO 4 .
NiSO 4 . Na 2 SO 4 .
NiSO 4 . Na 2 SO 4 . "
Phase .
o 16.94 7.61
22.46 IO.O9
2.61 1.28 '
5 17.99 10.85
25.28 15-24
2-94 i-93
NiSO 4 .7H 2 O +
Na 2 SO 4 .ioH 2 O
10 18.97 13.85
28.26 20.64
3.29 2.61
20 18.76 17.21
29.31 26.87
3.410 3.404
NiNa 2 (SO 4 ) 2 . 4 H 2
25 17.85 16.54
27-33 25.33
3.181 3.208
30 16.74 15.34
24.64 22.58
2.868 2.861
35 16.28 14.91
23.66 21.67
2-753 2.744
4o 15-35 J 4-49
21.88 20.65
2.546 2.616
18.5 19.61 16.49
30.70 25.80
3-56 3-27 *
20 20.13 16.15
3 J -59 25.35
3.67 3.21
25 21.20 14.77
33.11 23.06
3.85 2.92
NiNa 2 (SO 4 ) 2 . 4 H 2 -f
30 22.60 I 2. 80
34.98 19.82
4.07 2.59
NiSO 4 -7H 2 O
35 23.62 10.78
36.01 16.43
4.19 2.08
40 24.92 9.39
37.93 14-29
4.41 1.81 -
18.5 16.80 18.93
26.14 29.45
3.04 3-72 '
20 15.48 20. l8
25 10.92 24.12
24.06 31.37
16.81 37.13
2.80 3.97
1.96 4.70
NiNa 2 (S0 4 ) 2 . 4 H 2 O 4
' N a2 S0 4 .ioH 2
30 6.40 28.71
9.87 44.25
1.15 5.60 J
35 4-54 31-65
7-i3 49-59
0.838 6.28
NiNa 2 (S0 4 ) 2 . 4 H 2 +
40 4-63 31.37
7.24 49.03
o . 843 6.21
Na 2 SO4
NICKEL SULPHATE 212
SOLUBILITY OF NICKEL POTASSIUM SULPHATE NiK 2 (SO 4 ) 2 .6H 2 O IN
WATER.
(Tobler Liebig's Ann. 95. 193. 'SSJ v. Hauer J. pr. Ch. 74, 433, '58.)
Grams NiK 2 (SO 4 ) 2 Grams NiK 2 (SO 4 ) 2
*o per TOO Gms. H 2 O. ^ per 100 Gms. H^.
' (Tobler.) (v. Hauer.)" ' (Tobler.) (v. Hauer.)'
05-3 50 30
10 8.9 ... 60 35.4 20.47
20 13.8 9.53 70 42.0
30 18.6 ... 80 46.0 28.2
40 24-0 I4-03
SOLUBILITY OF NICKEL SULPHATE IN METHYL AND ETHYL ALCOHOLS.
(de Bruyn Z. physik. Ch. 10, 783, '92.)
ioo grams abs. ethyl alcohol dissolve 1.3 grains NiSO 4 .7H 2 O at 17.
100 grams abs. methyl alcohol dissolve 46.0 grams NiSO 4 .7H 2 O at
17, and 24.7 grams at 4.
ioo grams abs. methyl alcohol dissolve 0.5 gram NiSO 4 at 18.
ioo grams abs. methyl alcohol dissolve 31.6 grams NiSO 4 .6H 2 O at 17.
ioo grams 93.5% methyl alcohol dissolve 10.1 grams NiSO 4> 7H 2 O at
4, and 7.8 grams NiSO 4 .6H 2 O at 18.
ioo grams 50.0% methyl alcohol dissolve 2.0 grams NiSO 4 .7H 2 O at
4, and 1.9 grams NiSO 4 .6H 2 O at 18.
ioo grams sat. solution in glycol contain 9.7 grams NiSO 4 at room
temperature.
(de Coninck Bull. acad. roy. Belgique 359, '05.)
NICOTINE C 10 H 14 N 2 .
SOLUBILITY IN WATER.
(Hudson Z. physik. Chem. 47, 114, '04.)
Determinations made by Synthetic Method, for which see Note, page
9. Below 60 and above 210 both liquids are miscible in all propor-
tions; likewise with percentages of nicotine less than 6.8 and above 82
per cent the liquid does not show two layers at any temperature.
Below 94 the upper layer is water. Above 94 the upper layer is
nicotine. The curve plotted from the following results makes a com-
plete circle.
in
6.8 94 95
7-8 89 155
10. o 75
14.8 65 200
32.2 61 210
49-0 64 205
66.8 72 190
80.2 87 170.
82,0 129 130
213 NITROGEN
NITROGEN N.
SOLUBILITY IN WATER.
(Winkler Ber. 24, 3606, '91; Braun Z. physik. Chem. 33, 732, 'oo; Bohr and Bock Wied. Ann.
44, 318, '0i.)
O
0.0235*
o.o2 39 t
...J
0.0233*
0.00239*
5
0-0208
0.0215
0.0217
0.0206
0.00259
10
0.0186
0.0196
0-0200
0.0183
0.00230
15
0.0168
0.0179
0.0179
0.0165
0.00208
20
0.0154
0-0164
0.0162
0.0151
0.00189
25
0.0143
0.0150
0.0143
0.0139
0.00174
30
0.0134
0.0138
0.0128
o. 00161
35
0-0125
0.0127
0.0118
0.00148
40
0.0118
0.0118
O-OIIO
0.00139
5
0.0109
0.0106
. . .
0.0096
O.OOI2I
60
O-OIO2
o.oioo
0.0082
0.00105
80
0.0096
0.0051
0.00069
IOO
0.0095
o.oioo
o.oooo
o.ooooo
*W. fB.andB. $ B.
For values of ft, ft', and q, see Ethane, page 133.
SOLUBILITY OF NITROGEN IN AQUEOUS SALT SOLUTIONS.
(Braun.)
Coefficient of Absorption of N in Barium Chloride Solutions of:
t.
13-83
11.92
6.90
3-87
3-33
per cent.
per cent.
per cent.
per cent.
per cent.
5
0.0127
0.0137
0.0160
O-OlSo
0-0183
10
O.OII7
0.0125
O.OI47
0.0166
o.oies
15
O-OIO4
O-OII4
0.0132
0.0148
0.0150
20
0.0092
0.0098
0.0118
0.0132
0.0135
25
0.0078
0.0086
0.0104
O.OII4
O.OII9
Coefficient of Absorption of N in Sodium Chloride Solutions of:
t.
11-73
8.14
6.4
2.12
0.67
per cent.
per cent.
per cent.
per cent.
per cent.
5
O-OIO2
O.OI27
0-0138
O.OI79
0-02OO
10
0.0093
O.OII3
O.OI26
0.0164
0.0185
i.S
O.OoSl
O-OIOI
O.OII3
O.OI47
0.0164
20
O.O066
0.0087
0-0098
O.OI3I
0-0148
25
0-0047
0.0075
0.0083
O.OH3
O.OI3O
SOLUBILITY OF NITROGEN IN ALCOHOL.
(Bunsen.)
t 5 10 15 20 24
Vols. N * 0.1263 0.1244 0.1228 0.1214 0.1204 0.1198
dissolved by i Vol. Alcohol.
* At o and 760 mm.
NITROGEN
214
SOLUBILITY OF NITROGEN IN MIXTURES OP ALCOHOL AND WATER
AT 25.
(Just Z. physik. Ch. 37, 361, '01.)
Results in terms of the Ostwald solubility expression, see page 105.
Vol. H 2 O in Mixture. Vol. Alcohol in Mixture. Dissolved N (/2s).
ioo o 0.01634
80 20 0-01536
67 33 0.01719
o ioo (99 . 8 % Alcohol) o . 1 43 2
SOLUBILITY OF NITROGEN IN SEVERAL SOLVENTS AT 20 AND 25.
(Just.)
Solvent. / 25 . ISQ.
Toluene 0.1235 0.1186
Chloroform 0.1348 0.1282
Methyl Alcohol o. 1415 o. 1348
Ethyl Alcohol (99.8%) o. 1432 o. 1400
Acetone o. 1460 o. 1383
Amyl Acetate o. 1542 o. 1512
Ethyl Acetate 0.1727 0.1678
Iso Butyl Acetate 0.1734 0.1701
Solvent.
I 2b .
feo.
Water
0.01634
0.01705
Aniline
0.03074
0.02992
Sulphur Dioxide
0.05860
0.05290
Nitro Benzene
0.06255
0.06082
Benzene
0.1159
o. 1114
Acetic Acid
o. 1190
o. 1172
Xylene
0.1217
0.1185
Amyl Alcohol
o. 1225
o. 1208
SOLUBILITY OF NITROGEN IN PETROLEUM. COEFFICIENT OF ABSORP-
TION AT 10 = 0.135, AT 20 = O.II7.
(Gniewasz and Walfisz Z. physik. Ch. i, 70, '87 )
SOLUBILITY OF NITROGEN IN AQUEOUS PROPIONIC ACID AND UREA
SOLUTIONS.
(Braun.)
Coefficient of Absorption of N in C 2 H 5 COOH Solutions of:
tl .
11.22 per cent.
9.54 per cent.
6.07 per cent.
4.08 per cent.
3.82 per cent.
5
10
IS
20
0.0195
0.0178
0.0159
0.0146
0.0204
0.0l82
0.0163
0.0147
0.0208
0.0186
0-0164
0-0148
O.O2IO
0.0192
0.0169
O.OI54
O.0209
O.OI9I
0.0l67
0.0155
25
O.OI3O
0.0134
0.0134
0.0137
0.0137
Coefficient of Absorption of N in CO(NH 2 ) 2 Solutions of:
V .
15.65 percent.
1 1. 9 per cent.
9.42 percent.
6.90 per cent.
5.15 per cent.
2. 28 per cent.
5
10
TS
20
0.0175
O.Ol62
O.OI5O
O.OI4O
0.0179
0.0167
0-OI49
0.0139
O.OI9O
0.0176
0.0158
O.OI46
0.0198
0-0183
0.0165
O.OI5I
O.OI97
0.0l82
0.0165
O.OI5I
O.OI99
0.0184
O.OI7I
0.0155
2 5
O.OI3O
O.OI30
0.0133
0.0137
0.0135
0.0139
215 NITROUS OXIDE
NITROUS OXIDE N 2 O.
SOLUBILITY IN WATER.
(Bunsen; Gordon Z. physik. Ch. 18, 9, '95; Roth Ibid. 24,123, '97; Knopp Ibid. 48,106, '04
Geffcken Ibid. 49, 276, '04.)
*.
(B.)
(G.)
(R)
(K.)
q
'(R.)
5
1.0950
1-0955
i . 1403
o .205
i . 161
10
0.9196
o .9200
0.9479
o . 171
0.9815
15
0.7778
0.7787
0.7896
0.143
-8315
20
0.6700
o .6700
0.6654
o .6270
0. 121
o 7131
25
0.5961
0-5752
o. 104
0.6281
Coefficient of Absorption /3. */-^ U M^ y m te - rms / ( N
of Ostwald Expression (/).*
K-.) (0?
I .067
. . o .9101
0.7784
739 0-6756
0.5992
* Calculated by Geffcken.
NOTE. Knopp and also Geffcken call attention to the fact that
Roth in making his determinations used a rubber tube between the
gas burette and the shaking flask, and give this as an explanation of
the high results which he obtained.
SOLUBILITY OF NITROUS OXIDE IN AQUEOUS SULPHURIC ACID.
(Lunge Ber. 14, 2188, '81; see also Geffcken 's results.)
Sp. Gr. of H 2 SO 4 1.84 i. 80 I -7o5 i-45 1-25
Vols. N 2 O dissolved
by 100 vols. H 2 SO 4 75.7 66.0 39.1 41.6 33.0
100 vols. of KOH solution of 1.12 Sp. Gr. absorb 18.7 vols. N 2 O.
100 vols. of NaOH solution of i.io Sp. Gr. absorb 23.1 vols. N 2 O.
SOLUBILITY OF NITROUS OXIDE IN AQUEOUS SOLUTIONS OF ACIDS.
(Geffcken.)
Results in terms of the Ostwald Solubility Expression (/). See p. 105,
In Hydrochloric Acid. In Nitric Acid. In Sulphuric Acid.
Cms. HCl
per Liter.
l8.22
3 6 -45
72.90
SOLUBILITY OF NITROUS OXIDE IN AQUEOUS SOLUTIONS OF:
(Roth.)
Phosphoric Acid. Oxalic Acid.
N 2 O Dissolved
Gms.HNOa N 2 Dissolved
Gms. H 2 SO 4 1
ST 2 O Dissolved
/
/25-
per Liter.
la-
/ 25 -
per Liter.
/15-
ks-
'-755
0.
577
36.
52
0.777
0-597
24.52
o.
734
O.
566
'.738
o.
568
63-
05
0.777
0.602
49-04
0.
699
543
). 716
o,
557
126.
IO
0-775
0.611
98.08
o.
645
509
147.12
0.
602
o.
482
196. 16
0.
562
0.
463
t
5
10
15
20
25
Coefficient of Abs. in H 3 PO 4 Solutions of:
-*
Coefficient of Abs. in
(COOH) 2 Solutions of:
3-38%.
1-057
0.8827
0-7388
0.6253
0.5427
4-72%.
I -0365
0.8665
0.7258
0.6147
0-5329
8.84%.
0.9883
0-8296
0.6977
0.5926
0.5143
9.89%.
o-9 6 35
0.8101
0.6826
0.5810
0-5054
13-35%.
0.9171
0.7711
0.6505
o-5555
o . 4860
0.812%.
I.I450
0.9526
0.7940
0.6694
0.5784
3-70%.
I.I094
0.9264
0-7745
0.6538
0-5643
NITROUS OXIDE
216
SOLUBILITY OF NITROUS OXIDE IN AQUEOUS SOLUTIONS OF PROPIONIC
ACID AT 20.
(Knopp.)
Gms. C 2 H 5 COOH
per liter ^S-^S 60.42 158.4 176.6 344-
Coef. of Absorp-
tion of N 2 O 0.6323 0.6369 0.6504 0.6534 0.7219
SOLUBILITY OF NITROUS OXIDE IN AQUEOUS SALT SOLUTIONS.
Results by Geffcken in terms
page 105.
Salt.
Ammonium Chloride
Ammonium Chloride
Caesium Chloride
Lithium Chloride
Lithium Chloride
Potassium Bromide
Potassium Bromide
Potassium Chloride
Potassium Chloride
Potassium Iodide
Potassium Iodide
Potassium Hydroxide
Potassium Hydroxide
Rubidium Chloride
Rubidium Chloride
of the Ostwald expression (/). See
Cone, of
Salt per Liter.
Solubility
of N 2 O.
Formula,,
Gram Equ
iv. Grams.
*i*.
'*.
NH 4 C1
o-5
26.76
0.730
o-557
NH 4 C1
I .0
53-5 2
0.691
0.529
CsCl
o-5
84.17
O.7IO
0-544
LiCl
o-5
21 .24
0.697
o-535
LiCl
I .0
42.48
0.623
0.483
KBr
o-5
59-55
0.697
0-536
KBr
I .0
119.11
0.627
0.485
KC1
o-5
37-3
0.686
0.527
KC1
I .0
74-6
0.616
o-475
KI
o-5,
83.06
0.702
0.541
KI
I .0
166.12
0-633
0.492
KOH
o-5
28.08
0.668
0.514
KOH
i .0
56.16
o-559
0.436
RbCl
o-5
60.47
0.695
0-533
RbCl
I .0
120.95
0.625
0.483
Results by Knopp, in terms of the coefficient of absorption,, See
page 105.
Salt.
Formula.
Potassium Nitrate KNO q
Sodium Nitrate
NaNO q
Cone, of S;
lit per Liter.
Coef. of Absorption
Normality.
Grams.
of N 2 at 20.
0.1061
10-74
0-6173
0.2764
27.94
o . 6002
0.5630
56-97
0-57*3
1.1683
118.2
0:5196
0.1336
"37
o . 6089
0.3052
25-97
0.5876
0.6286
53-5o
0-5465
i .1200
95-30
0.4926
Results by Roth, in terms of the coefficient of absorption.
Grams NaCl per
100 Grams
Solution.
0.99
1. 808
7.886
5-865
Coefficient of Absorption of N 2 O at:
5.
I .0609
I OO32
0-9131
0.8428
10. 15. 20.
0.8812 0.7339 0.6191
0.8383 0.7026 0.5962
0.7699 0.6495 0.5520
0.7090 0.5976 0.5088
25.
0.5363
0.5190
0.4475
0.4224
217 NITROUS OXIDE
SOLUBILITY OF NITROUS OXIDE IN AQUEOUS SALT SOLUTIONS.
Results by Gordon in terms of coefficient of absorption. See p. 105.
Concentration of Salt. Coefficient of Absorption of N 2 O at:
Salt. Grams per Gram
100 Grams Mols. 5.
Solution. per Liter.
10.
15.
20
Calcium Chloride 5 . 79
o-547
0.819
0.697
0.591
0.500
9.86
0.964-
0.668
0.586
0.509
435
13-99
i .416
0.510
0.441
0-380
.328
Lithium Chloride 1.35 .
0.319
0.986
0.831
O.7OO
594
3 -.85
0.928
0.878
0-743
O.O29
536
11.48
2.883
0.606
0.512
o-437
.382
Lithium Sulphate 2.37
0.219
0-934
0.792
0.670
5 6 9
5-46
0.521
o-795
0.665
o-557
474
8.56
0.836
0.646
o-555
o-477
415
Magnesium Sulphate 5 . 90
0.521
0.766
0.664
0.561
.471
7.66
0.687
0.708
0.586
0.488
.414
10.78
o-997
0.569
0.491
0.417
346
Potassium Chloride 4-90
0.676
0.879
0-751
0.643
555
7.64
1.037
0-799
0-693
0.591
494
14-58
2.147
0-654
o-574
0.500
430
22.08
3-4I4
Q-544
0-459
0-390
339
Potassium Sulphate 2 . 62
0.154
0.986
0-831
0.701
.605
4-78
0.285
0.918
0.763
0-637
542
Sodium Chloride 6 . 20
i .107
0.800
0.682
0-585
509
8.88
i .614
0.713
0.603
0.510
434
12.78
2.391
0.634
o-532
0-449
.386
Sodium Sulphate 5 . 76
0.427
0.808
0.677
0.584
495
8-53
0.646
0.692
o-574
0.482
.416
12.44
Q-974
0-559
0-486
0.417
o
354
Strontium Chloride 3.31
0.215
0.928
0.788
0.671
578
5-73
0.380
0.848
0.709
0.610
550
13-24
o-939
0.644
0-547
0.463
.390
SOLUBILITY OF NITROUS OXIDE IN ALCOHOL AND IN AQUEOUS CHLORAL
HYDRATE
SOLUTIONS
AT 20
.
(Bunsen; Knopp
Z. physik. Ch.
48, 1 06, '04.)
In Alcohol (B.).
In Aq
. Chloral Hydrate (K.).
Vols. N 2 O
Normality
Gms.
r*~~t ~t
t . (it o and 760 mm.)
of C 2 HC1 3 O.H 2 AI^'M.^
per i Vol . Alcohol . C 2 HC1 3 O .H 2 O .
per Liter.
2 v -'
o 4-178
0.184
30-43
0.618
5 3-844
0-445
73.60
0.613
10 3.541
0.942
155-8
0.596
I 5 3.268
I .165
192.7
0-589
20 3- 02 5
1-474
243-8
o-579
24 2.853
I .911
316.4
0.567
SOLUBILITY OF NITROUS OXIDE IN PETROLEUM. COEFFICIENT OF
ABSORPTION AT 10 = 2.49, AT 20 = 2.11.
(Gniewasz and Walfisz Z. physik. Ch. i, 70, '87.)
NITROUS OXIDE
218
SOLUBILITY OF NITROUS OXIDE IN AQUEOUS SOLUTIONS OF GLYCERINE
AND OF UREA.
(Roth.)
Coefficient of Absorption of N2O in Glycerine Solutions of:
346 per cent
6.73 per cent. 12
.1 2
per cent. 16.24 per cent.
5
i
.097
i
055
999
959
10
.917
.887
o
.841
.810
15
767
745
.710
.686
20
o
647
0-630
.605
585
25
0-556
542
527
-508
Coefficient of Absorption of N 2 O in
Urea Solutions of:
3^31
per cent
4-97
per cent.
6.37 per cent.
7.30 per cent.
9.97 per cent.
I
.IO4
I
.096
i .
088
I .101
I .069
.921
O
.920
o.
909
0.921
0.901
.771
o
773
o.
76!
0.772
0.761
0-653
.656
o.
644
0-655
0-651
O
569
o
567
o.
559
0.570
0-569
Q.
t.
ft.
ft'.
9.
o . 00984
40
0.0351
0.0325
0.00440
o . 00860
50
0.0315
0.0277
0.00376
0.00757
60
0.0295
0.0237
0.00324
o . 00680
70
0.0281
0.0195
0.00267
0.00618
80
0.0270
0.0144
0.00199
0-00564
90
0-0265
0.0082
o .00114
0.00517
100
0.0263
o.oooo
o . ooooo
t.
5
10
15
20
25
NITRIC OXIDE NO.
SOLUBILITY IN WATER.
(Winkler Ber. 34, 14*4, '01.)
t. ft. ft'.
o 0.0738 0.0734
5 0.0646 0.0641
10 0.0571 0-0564
15 0-0515 0.0506
2O O.O47I 0.0460
25 O.O43O 0-0419
30 0.0400 0.0384
For values of ft, ft' and q, see Ethane, page 133.
SOLUBILITY OF NITRIC OXIDE IN AQUEOUS SULPHURIC ACID
SOLUTIONS AT 18.
(Lunge Ber. 18, 1391, '85; Tower Z. anorg. Ch. 50, 382, '06.)
Wt. per cent H 2 SO 4 Sp. Gr.
in Solution. at 15.
98 1.84
90 1.82
80 1.733
70 1.616
60 1.503
5 r -399
* Volume of NO (at 760 mm.) per i volume of aqueous H 2 SO 4 .
SOLUBILITY OF NITRIC OXIDE IN ALCOHOL.
(Bunsen.)
t o 5 10 15 20
Vols. NO* 0.316 0.300 0.286 0.275 0.266
absorbed by i vol. Ale.
* At o and 760 mm.
Tension of
H 2 O Vapor.
Solubility Coefficient *
of NO at 18.
0.0227 (0.035, L.)
o.i mm.
0-4 ||
0-0193
O.OII7
6.2 "
O.OII3
O.OIlS
O.OI2O
(0.017, L.
24"
0.261
2I 9 OXALIC AOID
OXALIC ACID (COOH) 2 . 2 H 2 O.
SOLUBILITY IN WATER.
(Average curve from results of Alluard; Miczynski Monatsh. Ch. 7, 2158, '86; Henry Com pt. rend.
99, US?. '84; Lamouroux Ibid. 128, 998, 'oo; at 25, Foote and Andrew
Am. Ch. J. 34, 154, '05.)
Grams (COOH) 2 per roo Grams Grams (COOH)^ per 100 Grams
H 2 O. Solution. H 2 O. Solution.
o 3-45 3-33 40 21.15 17.46
10 5-55 5-26 50 31-53 2 3-97
20 8.78 8.07 60 45.55 3*-37
25 11.36 10.21 70 63.82 38.95
30 13.77 11.91
SOLUBILITY OF OXALIC ACID IN ALCOHOLS.
(Timofeiew Compt. rend. 112, 1137, '91; Bourgoin Ann. chim. phys. [5] 13, 406, '78).
Grams (COOH) 2 per 100 Grams of:
t. , ^- ,
Methyl Alcohol. Ethyl Alcohol. Propyl Alcohol.
- i 3 6 -26 20.25 9.73
+ 20 47-24 26.23 I5-I4
SOLUBILITY OF OXALIC ACID IN ABSOLUTE AND IN AQ. ETHER AT 25.
(Bodtker Z. physik. Ch. 22, 512, '97; Bourgoin.)
ioo grams absolute ether dissolve 1.47 grams (COOH) 2 .2H 2 O.
100 grams absolute ether dissolve 23.59 grams (COOH) 2 .
In Aqueous Ether Solutions.
Gms. Solid Acid Added per ioo cc. Ether Solution. Grams per ioo cc. Ether Solution.
(COOH) 2 .2H 2 O. (COOH) 2 . H 2 0. (COOH) 2 .
(1) 5.0 o.o I - 2 5o 0.742
(2) 5.0 o.o 0.788 0.720
5.0 o.o 0.418 1.044
5.0 2.44 0.360 3.388
5-0 4.82 0.484 6.038
5-0 7.14 0.558 8.538
5-0 9.42 0.632 10.996
5.0 11.63 0.676 i3-3 l6
5.0 J 3-79 0.761 15.684
5.0 18.18 0.816 17.818
5.0 22.73 0.816 17.818
(i) Ether saturated with water. (2) Ether containing 0.694 per cent water.
ioo grams glycerine dissolve 15 grams oxalic acid at 15.5.
DISTRIBUTION OF OXALIC ACID BETWEEN WATER AND AMYL ALCOHOL
AT 20.
(Herz and Fischer Ber. 37, 4748, '04.)
Millimols i(COOH) 2 per 10 cc. Grams (COOH) 2 per ioo cc.
Aq. Layer.
\
Alcoholic Layer.
Aq. Layer.
Alcoholic Layer.
o.68c6
O.I45I
0.306
0-0653
2.364
0.7233
I .064
0.320
6.699
2-550
3-015
I.I48
10.029
4.300
4-5 11
1-934
OXYGEN 220
OXYGEN O. SOLUBILITY IN WATER.
(Winkler Ber. 24, 3609, '91; Bohr and Bock Wied. Ann. [2] 44, 318, '91.)
t. Coef. of Absorption ft. q.
cc. O per +o
Liter H*O.
Coef. of Absorption ft. q .
O
O.
0489*
0.0496!
0.00695
10.
187
40
0.
0231*
0.0233t
0.00308
5
0.
0429
0.0439
0.00607
8.
907
5
O.
O2O9
0.0207
0.00266
10
o.
0380
0.0390
0.00537
7-
873
60
0.
0195
O.OlSg
0.00227
15
0.
0342
0.0350
0.00480
7.
038
70
o.
0183
0.0178
0.00186
20
o.
0310
0.0317
0.00434
6.
356
80
0.
0176
0.0172
0.00138
25
0.
0283
0.0290
0.00393
5-
776
90
o.
0172
0.0l69
0.00079
30
o.
0261
0.0268
0.00359
5-
255
100
0.
0170
0.0168
o.ooooo
* w.
t B. and
B.
For values of /? and q see Ethane, page 133.
SOLUBILITY OF THE OXYGEN OF AIR IN WATER.
t. 5.2 5.65 14.78 24.8
Solubility * 8 . 856 8 . 744 7 . 08 5.762
* cc. Oxygen per 1000 cc. H 2 O saturated with air at 760 mm.
SOLUBILITY OF OXYGEN IN WATER AND IN AQUEOUS SOLUTIONS OF
ACIDS, BASES AND SALTS.
(Geffcken Z. physik. Ch. 49, 269, '04.)
Aq. Solution of: Concentration per Liter. Solubility of Oxygen*
Water alone
Hydrochloric Acid
Nitric Acid
a
((
Sulphuric Acid
Potassium Hydroxide
a
Sodium Hydroxide
u
Potassium Sulphate
u
Sodium Chloride
u
SOLUBILITY OF OXYGEN IN AQ. POTASSIUM CYANIDE SOLUTIONS AT 20.
(Maclaurin J. Ch. Soc. 63, 737, '93.)
Cms. KCN per 100 gms. sol. i 10 20 30 50
Coefficient of absorption of O 0.029 0.018 0.013 0.008 0.003
Gram Equiv,
, Grams.
' /16.
125.
0.0363
o . 0308
0.5
18.22
0.0344
0.0296
I .0
36-45
0.0327
0.0287
2 .O
72.90
O.O299
0.0267
o-S
36-5 2
0.0348
0.0302
I .0
63-05
0.0336
0.0295
2 .O
126.10
0-0315
0.0284
o-5
24.52
0-0338
0.0288
i.o
49.04
0.0319
0.0275
2.0
98.08
0-0335
0.0251
3.0
147-12
0.0256
0.0229
4.0
196.16
0.0233
0.0209
5-o
245.20
0.0231
0.0194
o-5
28.08
0.0291
0.0252
I .0
56.16
0.0234
0.0206
o-S
2O.O3
0.0288
0.0250
I .0
40.06
0.0231
0.0204
2.0
80. 12
O.OI52
0.0133
o-5
43-59
0.0294
0*0253
1 .0
87.18
0.0237
0.0207
o-5
29.25
0.0308
0.0262
I .0
58-5
O.O26o
0.0223
2 .O
119.0
O.Ol82
0.0158
Dstwald Solubi
lity Expressions
. See page
105.
221 OXYGEN
SOLUBILITY OF OXYGEN IN ETHYL ALCOHOL, METHYL ALCOHOL AND
IN ACETONE.
(Timofejew Z. physik. Ch. 6, 151, '90; Levi Gazz. chim. ital. 31, II, 513, '01.)
In Ethyl Alcohol of 99.7% (T.).
In Methyl
Alcohol (L.)
In Acetone (L.)
/3.
0'.
0-2337
0.2297
0.31864
0-2997
5
O.230I
0.2247
0.30506
0.2835
IO
o .2266
0.2194
o . 29005
0.2667
15
0.2232
0.2137
0.27361
o . 2493
20
O.22OI
0.2073
0.25574
0.2313
25
0.2177 (24)
0.2017 (24)
0.23642
0.2127
30
0.21569
0.1935
40
0.16990
0-1533
5
0.11840
0.1057
For values of and /3', see Ethane, page 133. / = Ostwald Solu-
bility Expression. Seepage 105.
The formulae expressing the solubility of oxygen in methyl alcohol
and in acetone as shown in the above table are as follows:
In Methyl Alcohol / = 0.31864 0.002572 t o 00002866 t 2 .
In Acetone / = 0.2997 ~~ 0-00318 t 0.000012 t 2 .
SOLUBILITY OF OXYGEN IN AQUEOUS ALCOHOL AT 20 AND 760 MM.
(Lubarsch Wied. Ann. [2] 37, 525, '89.)
Wt. per cent
Alcohol.
Vol. per cent
Absorbed O.
Wt. per cent
Alcohol.
Vol. per cent
Absorbed O.
Wt. per cent
Alcohol.
Vol. per cent
Absorbed O.
o.oo
9.09
16.67
2.98
2. 7 8
2.6 3
23-08
28.57
33-33
2.52
2.49
2 .67
50.O
66.67
8o.O
3-50
4-95
5.66
SOLUBILITY OF OXYGEN IN PETROLEUM. COEFFICIENT OF ABSORP-
TION AT 10 = 0.229, AT 20 = 0.202.
(Gniewasz and Walfisz Z. physik. Ch. i, 70, '87.)
OZONE O,.
SOLUBILITY IN WATER.
(von Mailfert Compt. rend. 119, 951, '94; Carius; Schone Ber. 6, 1224, '73.)
t. W. G. R. t. W. G, R.
o 39.4 61.5 0.641 27 13.9 51.4 0.270
6 34.3 61.0 0.562 33 7.7 39.5 0.195
1 1. 8 29.9 59.6 0.500 40 4-2 37-6 o.i 12
13.0 28.0 58.1 0.482 47 2.4 31.2 0.077
15-0 25.9 56.8 0.456 55 o- 6 J 9-3 0-031
19.0 21 .o 55.2 0.381 60 o.o 12.3 o.ooo
W = Milligrams Ozone dissolved per liter water. G = Milligrams
Ozone in one liter of the gas phase above the solutions. R = Ratio
of the dissolved to undissolved Ozone (W * G) .
PARAFFINE
222
SOLUBILITY OP OZOKERITE PARAFFINE OF MELTING POINT 64-65
AND SP. GR. AT 20 = 0.917 IN SEVERAL SOLVENTS AT 2O.
(Pawlewski and Filemonowicz Ber. 21, 2973, '88.)
Gms. Paraffine per 100
Solvent.
Carbon Bisulphide
Benzine, boiling below 75
Turpentine, b.pt. i58-i66
Cumol, com. b.pt. 160
" frac. 150-! 60
Xylene, com.b.pt. 135-
" frac. i35-i38
Toluene, com.b.pt.io8-iio
" frac. io8-io9
Chloroform
Benzene
Ethyl Ether
Iso Butyl Alcohol, com.
Gms. Paraffine per 100
Gms.
Solvent.
12.99
cc.
Solvent.
Solvent.
Acetone
Gms.
Solvent.
O. 262
cc.
Solvent.
o. 209
' n-73 8.48
Ethyl Acetate
0.238
. . .
3
6.06
5- 21
" Alcohol
o. 219
4.26
3-7 2
Amyl Alcohol
0. 202
o. 164
3-99
3-39
Propionic Acid
o. 165
o
3-95
3-43
Propyl Alcohol
o. 141
. .
4-39
3-77
Methyl Alcohol
o. 071
0.056
[0
3.88
3-34
Methyl Formate
o. 060
. . .
3-9 2
Acetic Acid
o. 060
0.063
2.42
3.1i
" Anhydride
o. 025
1.99
Formic Acid
0.013
0.015
Ethyl Alcohol 75%
o. 0003
0.285 0.228
PAPAVERINE C 20 H 21 NO 4 .
100 grams pure carbon tetra chloride dissolve 0.203 gram at 17.
(Schindelmeiser Chem.-Ztg. 25, 129, J oi.)
PHENANTHRENE C 14 H 10 .
SOLUBILITY IN ALCOHOL AND IN TOLUENE.*
(Speyers Am. J. Sci. [4] 14, 295, '02.)
In Alcohol. In Toluene.
t.
Gms. CuHio per
100 Grams
Sp. Gr. of
Solutions
Gms. Ci4Hjo per
100 Grams
Sp. Gr. of
Solutions
C 2 H S OH.
(H20 at 4.)
C 6 H 5 .CH 3
(H 2 at 4.]
3-65
0.814
23.0
0.925
10
3.80
0.807
30.0
0.929
20
4-6
O.Soi
42.0
0-934
25
5-5
o-799
50-0
0-939
30
6.4
o-797
58.0
Q-943
40
8.2
o-795
76.0
0-955
5
10.6
0-794
95-o
0.971
60
IS -6
o-797
115.0
0.989
7o
33 -
0.815
135 .0
1.007
80
0.865 (76.4)
155.0
i .027
* Calculated from the original results which are given in terms of gram molecules of Phenanthrene
per 100 gram molecules of solvent, and for irregular intervals of temperature.
Behrend Z. physik. Ch. 10, 265, '92, finds 2.77 grams phenan-
threne per 100 grams alcohol at 12.3, and 3.09 grams at 14.8.
223 PHENANTHRENE
SOLUBILITY OF PHENANTHRENE PICRATE IN ABSOLUTE ALCOHOL.
(Behrend Z. physik. Ch. 10, 205, '92.)
Grams per 100 Grams Saturated Solution.
Picric Acid + Phenanthrene = Phenanthrene Pi crate.
12-3 O.pl 0.71 1.62
14.3 i.oo 0.78 1.78
17.5 I.O5 O.82 1.87
SOLUBILITY OF PHENANTHRENE PICRATE IN ALCOHOLIC SOLUTIONS
CONTAINING PICRIC ACID AND ALSO PHENANTHRENE.
(Behrend.)
Grams Added to 62 cc. Abs. Alcohol. Cms. per 100 Cms. Sat. Solution.
P. Picrate + Picric Ac. + Phenanthrene.
t
Picric Ac. -f- Phenanthrene
= P. Picrate.
12-3
1-4
o-5
0-534
1-413
1-947
12-3
1-4
o
0.9
0.409
2.141
2-550
12-3
0.8
o
2 .1
0-354
2.77
3-124
I2. 3
0.8
o
4.0
0-139
5 .626
5-765
17-5
1-4
O.I
I-I59
o-75
I.9I
17-5
1.4
0.2
o
1.285
0.68
1-97
17-5
1.4
I .0
o
2-45
o-37
2.82
17-5
1.4
4.0
6.15
o-i95
6-345
17-5
1.4
o.o
2.2
0.423
3.276
3-699
PHENOL C 6 H 5 OH.
SOLUBILITY IN WATER.
(Alexejew Wied. Ann. 28, 305, '86; Schreinemaker Z. physik. Ch. 33, 79, 'oo; Rothmund Ibid
26, 474, 98.)
Determinations were made by the " Synthetic Method," for which
see Note, page 9.
Grams Phenol per 100 Grams
Aqu
10
20
30
40
50
55
60
65
68.3 (crit. temp.) 33.4
Vaubel J. pr. Ch. [2] 52, 73, '95, states that 100 grams sat. aque-
rus solution contain 6.1 grams phenol at 20. Sp. Gr. of solution =
1.0057.
SOLUBILITY OF PHENIC ACID (PHENOL, C 6 H 5 OH) IN PARAFFINE
AND IN BENZENE.
(Schweissinger Pharm. Ztg. '84- '85.)
Grams CeHsOH per 100 Grams Solvent at:
Solvent. r- J
16. 21. 25 . 43
Paraffine 1.66 5.0
Benzene 2.5 8.33 10.0 100.0
Aqueous Layer.
Phenol
Layer.
7-5
75
.0
8-3
72
.1
8.8
6 9
.8
9.6
66
9
12 .0
62
7
14-1
59
5
16.7
55
4
21.9
49
.2
PHENOL
224
SOLUBILITY OF PHENOL IN AQUEOUS ACETONE SOLUTIONS.
(Schreinemafcer .)
In 4.24 %
Acetone.
Grams Phenol per
In 12.2%
Acetone.
Gms. Phenol per
In 24.4%
Acetone.
Gms. Phenol per
In 59.9%
Acetone.
Gms. Phenol per
t
ioo Gms.
ioo Gms.
ioo Gms.
ioo Gms.
L .
Aq . Acetone
Layer.
Phenol
Layer.
Aq . Acetone
Layer.
Phenol
Layer.
Aq . Acetone
Layer.
Phenol
Layer.
Aq. Acetone
Layer.
Phenol
Layer
2O
. . .
. . .
26.
60.5
3
5.0
74.0
4.0
71.0
6^0
6 9-5
28.5
57-0
40
5-5
70.0
32.0
52.0
5
5-7
67. o
5-
67.0
8.0
64.0
34- 5
49- c
60
6-5
61.0
36.511
46.511
70
9.0
51.0
7-5
57-5
19. o
57.0 (49-5) 41-5
80
14 o
34-o
10.5
49-5
14.0
52-5
(8 4 ) 22.
5
20.4*
30-5*
23. ol
47. ot
(90- 3) 25
c
26. si
44. oi
(90- 5) 35-
90
t8 5
?87.S
45
!l47-S
The figures in the above table were read from curves plotted from
the original results.
SOLUBILITY OF PHENOL IN AQUEOUS SOLUTIONS d TARTARIC ACID.
(Schreinemaker.)
In 5.093% Acid.
In 19.34% Acid.
In 40.9% Acid.
Gms. Phenol per ioo Gms.
Gms. Phenol per ioo Gms.
Gms.PhenoIper ioo Gms.
t.
Aq. Acid
Phenol
t .
Aq. Acid
Phenol
t .
Aq. Acid
Phenol
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
30
7-5
72-5
5
10.
77.0
70
I 3 .0
50
10.5
65.5
60
12.5
72.0
80
I6. 5
77.0
60
14-5
58.0
70
19.0
64.0
85
2O. O
74-o
65
19-5
53-0
75
29.0
56.0
90
26.5
71.0
67.5
25.0
48.5
77
47.
,o
95
63.5
6 9
47-5
97
54.
o
DISTRIBUTION OF PHENOL BETWEEN:
AMYL ALCOHOL AND WATER AT 25.
(Herz and Fischer Ber. 37, 4747, '04.)
Millimols Phenol
per 10 cc.
Gms. Phenol
per ioo cc.
Alcoholic Aqueous
Layer. Layer.
o. 75 o. 047
0.9 0.05
i.i 0.07
2.6 o. 16
54-1 3.83
56.3 3-9
Alcoholic Aqueous
Layer. Layer.
o. 705 o. 0441
o. 846 o. 047
1.035 0.066
2.445 0.150
50.88 3.601
52.93 3.667
BENZENE AND WATER AT 20,
(Vaubel J. pr. Ch. [2] 67, 476. 'cj-)
Volumes of Solvents
used per
i Gm. Phenol
5occ.H 2 O + 5occ.C 6 H 6
" +IOOCC. "
+ I50CC. "
+ 200CC. "
Gms. Phenol in-
Layer
H 2
Layer.
o. 286 o. 714
o. 1188 0.8212
0.0893 0.9107
0.0893 0.9107
225
PHENOL
DISTRIBUTION OF PHENOL BETWEEN WATER AND BENZENE AND
BETWEEN AQUEOUS K 2 SO 4 SOLUTIONS AND BENZENE AT 25.
(Rothmund and Wilsmore Z. physik. Ch. 40, 623, '02.)
NOTE. The original results, which are given in terms of gram
mols. per liter, were calculated to grams per liter, and plotted on cross-
section paper. The following figures were read from the curves
obtained.
Between H 2 O and
Effect of K 2 SO 4 upon the Distribution.
Grams C 8 H 5 OH
Cms. K 2 SO 4
(i) Gms.
C 6 H 5 OH
(2)Gms. C 6 H 5 OH
per Liter of:
per Liter
per Liter of:
per Liter of:
H 2
Layer.
C 6 H 6
Layer.
Aq.
Solution.
Aq.
Layer.
C 6 H 8
Layer.
Aq.
Layer.
C 6 H 8
Layer.
5
10
I. 3 6
17.08
59-96
9-52
26.28
10
28
2.72
16.92
60-63
9-5
26.38
15
52
5-44
16.85
60.92
9-46
26-55
20
8 4
10.89
16.44
62.73
9-35
27 .06
25
128
21.79
15.89
65.19
9.09
28.27
30
2OO
43-59
I4-85
69.71
8.68
30.21
35
300
87.18
12 .92
78.00
7-79
34.38
40
4IO
45
520
50
610
(i) First series.
(2)
Second series.
DISTRIBUTION OF PHENOL AT 25 BETWEEN:
(Herz and Fischer Ber. 38, 1143, '05.)
Water and Toluene.
Millimols
C b H 6 OH
Grams C 6 H 5 OII
per 10 cc.
per 100
cc.
C 6 H 5 CH 3
Layer.
H 2 O
Layer.
C 6 H 5 CH 3
Layer.
H 2 6
Layer.
1.244
0.724
1.169
0.681
3-47
1.469
2.865
1.381
4.667
2 .200
4-389
2.068
6.446
2.861
6.o6l
2 .691
14.960
4-75
14.07
4.467
17.725
5-346
16.69
5.027
47.003
7.706
44-20
7.246
53-783
8.087
50.58
7.604
90.287
9.651
84.89
9.074
Water and
Millimols C 6 H 5 OH
per 10 cc.
m Xylene.
Grams C 6 H 6 OH
per 100 cc.
' mC 6 H 4 (CH 3 ) 2 H 2 * '
Layer. Layer.
1.610 1.071
4.787 2.726
12.210 5-i68
22.718 6.994
34.827 8.124
5I-352 9-123
77.703 10.050
C 6 H 4 (CH 3 ) 2 H 2 0"
Layer. Layer.
1.514 1.007
4.501 2.563
11.22 4.860
21.36 6.577
32.75 7.640
48.28 8.578
73-07 9-450
DISTRIBUTION OF PHENOL BETWEEN WATER AND CARBON TETRA
CHLORIDE AT 20.
(Vaubel J. pr. Ch. [2] 67, 476, '03.)
Grams Phenol in:
Cms. Phenol
Used.
Volumes of Solvents.
i 50 cc. H 2 O+ 10 cc. CC1 4
I " ' + 20 CC. "
+ 30 cc. "
+ 50 cc. "
" +IOOCC. "
+ i5occ. "
-f200CC. "
H 2 Layer.
CC1 4 Layer.
0.8605
0.1285
0.7990
o . 1900
0.7275
O.26l5
0-6435
0-3455
o . 4680
0.5210
0.3645
0.6245
0.3240
0-6650
PHENOLATE 226
PHENOLATE of Phenyl Ammonium.
SOLUBILITY IN WATER.
Figures read from Curve. (Alexejew Wied. Ann. 28, 305, '86.)
By Synthetic Method, See page 9.
Gms. Phenolate per 100 Gms. Gms. Phenolate per 100 Gms.
Aq. Layer. Phenolate Layer. Aq. Layer. Phenolate Layer.
10 3 94 no 9 76
30 4 93 I2 I2 6 9
50 5 91 130 17.5 60
70 6 87.5 140 (crit. temp.) 40
90 7 83
PHENYL (Di) AMINES C 6 H 4 (NH 2 ) 2 .
SOLUBILITY IN WATER AT 20.
(Vaubel J. pr. Ch. [2] 52, 73, '95-)
A _ Gms. per ioo Sp. Gr. of
Gms. Solution. Solution.
m Phenyl di Amine 23 .8 1-0317
P 3-7 1-0038
Nitro PHENOLS C 6 H 4 .OH.NO 2 .
ioo grams saturated aqueous solution contain: 0.208 gram ortho,
2.14 grams meta, 1.32 grams para nitro phenol at 20.
(Vaubel.)
Di Nitro PHENOL C 6 H 3 .OH.(NO 2 ) 2 .
SOLUBILITY IN ALCOHOLS AT 19.5.
(de Bruyn Z. physik. Ch. 10, 784, '92.)
ioo grams abs. methyl alcohol dissolve 6.3 grams C 6 H 3 .OH.(NO 2 ) 2 .
ioo grams abs. ethyl alcohol dissolve 3^9 grams C 6 H 3 .OH.(NO 2 ) 2 .
SOLUBILITY OF MIXTURES OF 5 TRI BROM PHENOL AND 5 TRI CHLOR
PHENOL IN METHYL ALCOHOL AT 25.
(Thiel Z. physik. Ch. 43, 667, '03; from Wurfel Dissertation Marburg, '96.)
Molecular per cent C 6 H 2 .OH.Br3 n Solubility of
' In Solid.
In Solution.
CeH 2 .OH.Cl 3 .
C 6 H 2 .OH.Br 3 .
i oiai.
O
O.204
O
0.204
4-49
3-59
0-194
0.007
0.201
10.13
7-58
O.I9I
0.016
O.2O6
16.28
12.15
0.172
O.O24
0.196
62.44
13.07
O.2O4
O.O3I
0-235
69.88
15.86
0.150
0.028
0.178
81.76
19.01
0.096
0.023
O.IlS
84.66
24.05
0-069
O.O22
O.O9I
87-53
32.46
0.043
0-021
0.063
93.62
47-87
O-O2I
0.019
O.O4O
IOO.O
IOO.O
0-0
O.OI9
O.OI9
227 PHENYL SALIC YL ATE
PHENYL SALICYLATE (Salol) C 6 H 4 (OH).COOC 6 H 6 i: 2 .
100 grams H 2 O dissolve 0.043 S Tarn - salicylate at 25. 100 grams
alcohol dissolve 20.0 grams at 25.
(u. s. P.)
Di PHENYL C 6 H 5 .C 6 H 6 .
100 grams absolute methyl alcohol dissolve 6.57 grams at 19.5.
100 grams abs. ethyl alcohol dissolve 9.98 grams at 19.5.
(de Bruyn Z. physik. Ch. 10, 784, '92.)
PHOSPHO MOLYBDIC ACID P 2 O 5 .2oMoO 3 .52H 2 O.
SOLUBILITY IN ETHER.
(Parmentier Com pt. rend. 104, 686, '87.)
t o 8.1 19.3 27.4 32- 9 C
Gms. Acid per 100 gms. Ether 80.6 84.7 96.7 103.9 107.9
PHOSPHORUS P. (yellow)
SOLUBILITY IN BENZENE.
(Christomanos Z. anorg. Ch. 45, 136, '05.)
. o Gms. P pel
i oo Gms. C 6 1
50 6.80
55 7-32
60 7 . 90
65 8.40
70 8.90
75 9-4o
81 10.03
Gms. P per
t . 100 Gms.
(C 2 H 6 ) 2 0.
28 1. 60
30 i-75
33 i -80
35 2.00
100 grams CS 2 dissolve about 1750 grams yellow P at room temper-
ature. (Vogel Jahresber. Chem. 149, '68.)
ioo grams alcohol of 0.799 Sp. Gr. dissolve 0.312 gram P cold and
0.416 gram hot. (Buchner)
-o Gms. P per
' iooGms.C 6 H 6 .
Sp. Gr. of]
Solution.
-o Gms. P per
" 100 Gms. CeHe.
Sp. Gr. of
Solution.
O
1.513
. . .
23
3-399
0-8875
5
1.99
25
0.8861
8
2.31
o . 8990
30
4.60
10
2.4
0.8985
35
5 I 7
15
2-7
0-894
40
5-75
18
3 - 1
0.892
45
6. ii
20
3-2
0.890
SOLUBILITY
OF PHOSPHORUS
IN ETHER.
(Christomanos.)
...
Gms. P per
loo Gms.
(C 2 H 6 ) 2 0.
Sp. Gr. of
Solutions.
f.
Gms. P per
100 Gms.
(C 2 H 5 ) 2 0.
Sp. Gr. of
Solutions.
0-434
15
0.90
0.723
5
O.62
. . .
18
I .01
0-719
8
0-79
0.732
20
I -04
0.718
10
0.85
0.729
23
I .12
0.722
25
i-39
0.728
PHOSPHORUS 228
SOLUBILITY OF YELLOW PHOSPHORUS IN SEVERAL SOLVENTS AT 15.
(Stich Pharm. Ztg. 48, 343. '03-)
Solvent. Gms. P per 100 Gms. Solution.
Almond Oil i .25
Oleic Acid i .06
Paraffine i . 45
Water 0.0003
Acetic Acid o . 105
PHTHALIC ACIDS C 6 H 4 (COOH) 2 .
SOLUBILITY IN WATER.
(Vaubel J. pr. Ch. [2] 52, 73, '95; 59, 30, '99-)
Acid. t . Gms. per 100 Gms. Solution.
o Phthalic Acid 14 0.54
Iso Phthalic Acid 25 0.013
Tere Phthalic Acid . . almost insoluble
SOLUBILITY OF o PHTHALIC ACID IN ALCOHOL AND IN ETHER AT
(Bourgoin Ann. chim. phys. [5] 13, 406, '78.)
Grams CeH^COOETte o per TOO Grams
Solution. Solvent.
Absolute Alcohol 9 . 1 56 1 1 . 70
90 per cent Alcohol 10.478 10.08
Ether 0.679 0.684
TO
PHTHALIC ANHYDRIDE C 6 H 4 O-
SOLUBILITY IN WATER.
(van der Stadt Z. physik. Ch. 41, 358, '02.)
All determinations, except first three, made by the Synthetic Method.
See page 9.
t.
irams CgKjOa per 100 Gms. Mol. i
>er cent
Grams Cg^Os per 100 Gms. M l.
^ r*r -oTif
Water.
Solution. Q^Os-
Water.
Solution.
C 8 H 4 3
O,
,002 9 5
0.
00295
. 00036
189.5
1076
91.
66
56.73
25
0.
6194
O.
6150
o
754
188.8
1265
9 2.
68
60.63
50
I,
630
I.
604
.198
187.1
1474
93-
65
64. 22
135-9
94.
3
4 8.
54
10
30
181.8
2332
95-
88
73-95
165.4
210,
o
6 7 .
75
20
36
176.2
3334
97-
07
80.23
179.4
319
3
7 6.
13
27
.98
169.4
5745
98.
28
87.49
186.2
449.
6
81.
81
35
37
130.9
37570
99-
72
97.89
189.6
546.
i
84.
5
39
93
131.0
83010
99-
86
99.02
191.0
821.
5
89.
19
5o
.00
131.2
oo
100.
00
100. OO
190.4
863.4 89.
62
.24
On page 362 of the original paper the solubility of C 8 H 4 O 3 at o is
given as 0.2722 gram per 100 grams of solution.
229 PHTHALIO ANHYDRIDE
SOLUBILITY OF PHTHALIC ANHYDRIDE IN CARBON BISULPHIDE.
(Arctowski Compt. rend. 121, 123, '95; Etard Ann. chim. phys. [7] 2, 570, '94.)
Gms. CgH 4 O 3
Gms. C 8 H 4 O 3
Gms. C 8 H 4 O 3
f.
per loo Gms.
Solution.
t. per 100 Gms. t.
Solution.
per loo Gms.
Solution.
112.5
0.013
+ 10
-3
70
2-3
93
0.013
2O
0.7
90
3-7
77-5
0.016
30
0.8
IOO
5-o
40
0.03
40
I .2
I2O
8.0
20
O.O6
50
I .3
I4O
13-3
10
o.io
60
I .7
1 60
20.7
O.2O
180
30.2
PHYSOSTIGMINE SALICYLATE C 6 H 4 (OH)COOH.C 16 H 21 N 3 O 2 and
Physostigmine Sulphate H 2 SO 4 (C 15 H 21 N 3 O 2 ) 2 .
SOLUBILITY IN WATER, ALCOHOL, ETC.
(U. S. P.)
Gms. per 100 Gms. Solvent.
Solvent. t. - -i-
bahcylate. Sulphate.
Water 25 1.38 very soluble
Water 80 6.66
Alcohol 25 7.87
Alcohol 60 25.00
Chloroform 25 n.6 "
Ether 25 -57 0.083
PICRIC ACID C 6 H 2 .OH.(NO 2 ) 3 .
SOLUBILITY IN WATER.
(Dolinski Ber. 38, 1836, '05; Findlay J. Ch. Soc. 81, 1219, '02.)
Gms. CeHaNgOy per 100 Grams Gms. CeHaNsOr per 100 Grams
Solution. Water. Solution. Water.
o 0.67 (D.) 0.68 (D.) 1.05 (F.) 60 2.77(0.) 2.81(0.) 3-i7
10 .80 0.81 1. 10 70 3.35 3.47 3- 8 9
2O I. 10 I. II 1-22 80 4-22 4.41 4.66
30 1.38 1.40 1.55 90 5.44 5-7 2 5-49
40 1.75 1.78 1.98 loo 6.75 7.24 6.33
50 2.15 2.19 2.53
Dolinski does not refer to the previous determinations of Findlay
PICKIO ACID
230
SOLUBILITY OF PICRIC ACID IN WATER AND IN AQUEOUS SALT
SOLUTIONS AT 25.
(Levin Z. physik. Ch. 55, 520, '06.)
One liter of aqueous solution contains 0.05328 gram mols. = 12.20
grams C 6 H 2 .OH(NO 2 ) 3 at 25.
Gm Mols Salt Gram Mols. Picric Acid per Liter in Aq. Solutions of:
per Liter.
NaCl.
NaNO 3 .
Na 2 S0 4 .
LiCl.
Li 2 S0 4 .
NH 4 C1.
.01
05524
0.05529
0-05604
0.05480
O
.05661
0.05487
.02
05559
0-05872
0-05872
0-05558
.06053
0.05540
O
05
.05729
0.06632
o .06632
0.05703
.06691
0.05771
.07
.05862
0.07093
0.07093
0.05878
o
07013
0.05865
.10
.05902
0.07670
0.07670
0.06132
o
07437
O
50
.0790
.123
I
.00
.Il8o
.149
Gm.
Mols.
Grams Picric Acid per
Liter in Aq. Solutions of:
Salt per Liter.
NaCl.
NaN0 3 .
Na 2 S0 4 ,
LiCl.
Li 2 S0 4 .
NH 4 C1.
O
.01
12 .66
12.67
12.83
I2 -55
12.97
12-57
O
O2
12.74
13-45
*3-45
12-74
13-87
12 .69
O
05
13.12
I5-J9
15 -19
13.06
15-33
13.22
.07
13-43
16.25
16.25
13-47
16.06
13-44
O
.10
J 3-5 2
17-57
17-57
14.05
17.04
O
50
18.09
28.18
I
.00
26.98
34-14
Solubility in Aq. Cane Sugar.
Solubility in Aq. Grape Sugar.
Jm. Mols.
Sugar
per Liter.
Picric Ac. per L
iter Solution.
Sp. Gr.
Solution.
Gm. Mols.
Grape Sugar
per Liter.
Picric Acid rxr Liter Sol.
Gm. Mols.
Gms.
G. Mols.
Gms.
O.IO
O.O52O2
II .92
I -OI22
O.IO
0.0530
12 .14
0.25
0.04978
II 40
1.0319
0.25
0.0521
11 -93
0.50
0.0482
II .04
I .0654
0.50
0.0509
11.66
I .00
0.0443
IO.I5
I.I294
I .00
0-0474
10.86
SOLUBILITY OF PICRIC ACID IN ABSOLUTE ALCOHOL.
(Behrend Z. physik. Ch. 10, 265, '92.)
ioo gms. sat. solution contain 5.53 grams CgHg
5.92 grams at 14.8. Sp. Gr. of the latter solution
y at 12.3, and
0.8255.
5
10
20
25
?6. 5
35
SOLUBILITY OF PICRIC ACID IN BENZENE.
(Findlay.)
Gms.
Mols.
Gms.
Mols.
C 6 H 3 N 3 7
C 6 H 3 N 3 7
t.
C 6 H 3 N 3 7
per ioo
per ioo
per ioo
per ioo
Gms. C 6 H 6 .
Mols. C 6 H 6 .
Gms. C 6 H 6 .
Mols.C 6 H
3-70
1.26
38.4
26.15
8.88
5-37
I-8 3
45
33-57
II .40
7.29
2. 4 8
55
50-65
17 .21
9.56
3-25
58-7
58.42
19.83
12.66
4-3
65
71 .31
24.2O
13 .51
4.60
75
96.77
32.92
21.38
7.26
2 3 I
PICRIC ACID
SOLUBILITY OP PICRIC ACID IN ETHER.
(Bougault J. pharm. chim. [6] 18, 116, '03; Apoth.-Ztg. 21, 74, '06.)
Solvent. t.
Ether of Sp. Gr. 0.721 13
Ether of Sp. Gr. 0.725 (0.8 pt. H 2 O per 100) 13
Ether of Sp. Gr. 0.726 (i.o pt. H 2 O per 100) i^
Ether saturated with H 2 O 15
H 2 O saturated with Ether 15
Cms. CH 3 N 3 O7 per Liter.
10.8 (B.)
36.8
40.0
5*-2
13-8
DISTRIBUTION OF PICRIC ACID AT 25 BETWEEN:
Water and Amyl Alcohol.
(Herz and Fischer Ber. 37, 4747, '04.)
Water and Toluene,
(H. and F. Ber. 38, 1142, '05.)
Millimols CsHsNsCv
Cms. C 6 H 3 N 3 O 7
Millimols
C 6 H 3 N,0 7
Cms.
C6H 3 N 3 7
per
10 CC.
per loo cc.
per
10 CC.
per
100 CC.
Aq.
Alcohol
Aq.
Alcohol
Aq.
Toluene
Aq.
Toluene
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
0-0553
o . 0930
O.I27
0-2I3
0.075
O.I26
0.172
0.289
O.092O
0.1850
O.2II
0.424
O.IO9
0.230
o 250
0.527
O.l6l3
0.4127
0-369
0.946
0.163
0.482
o-374
I .104
0.1869
0.5182
0.428
1.188
0.244
I .026
o-559
2-35 1
0.3161
1.079
0.724
2-473
0.389
2-347
0.891
5-38o
0.4471
1.638
I .024
3-753
0.496
3-747
1 .137
8.586
0.5624
2.189
1.288
5-oi7
0-583
5- I 35
1 .336
11.770
0.6423
2-549
1.472
5-839
DISTRIBUTION OF PICRIC ACID AT 25 BETWEEN:
Water and Bromoform.
(Herz and Lewy Z. Electrochem. u, 820, '05.)
Water and Chloroform.
(H. and L.)
Millimols CeHsN 3 O 7
per 10 cc.
Cms. C 6 H 8 N 3 7
per 100 cc.
Millimols C e H 3 N 3 7
per 10 cc.
Gms. Cgri 3 N 3 O 7
per loo cc.
Aq. Bromoform
Layer. Layer.
0.321 0.365
O.4OI 0.515
o-475 0.655
o-575 0.871
0.674 1.14
Aq. Bromoform
Layer. Layer.
0.736 0.836
0.919 I.lSo
I. 088 I.50I
i-3i7 1-995
1.545 2.612
Aq. Chloroform
Layer. Layer.
0.2O7 0.254
0-329 0-547
0.488 1.09
0.561 1.41
0.588 1.53
Aq . Chloroform
Layer. Layer.
0-474 0.582
0-754 1-253
1.118 2.498
1.285 3.230
I-348 3.505
PILOCARPINE HYDROCHLORIDE C n H 16 N 2 O 2 .HCl, Pilocarpine Ni-
trate C U H 16 NA.HNO 3 , and Piperine C 17 H 19 NO 3 in Several Solvents.
Solvent.
Water
Alcohol
Alcohol
Chloroform
Ether
2 5
2$
60
25
25
(U. S. P.)
Grams per 100 Grams Solvent.
Ci,H 16 N 2 2 .HCl. CiiH 16 N 2 2 .HN03. C, 7 H 19 NO 3 .
333 25 insoluble
4.35 1.66 6.66
9.09 6.2 22.7
0.18 ... 58.8
2.8
PLATINUM ALLOYS 232
SOLUBILITY OF PLATINUM ALLOYS IN NITRIC ACID.
(Winkler Z. anal. Ch. 13, 369, '74.)
Approx. Grams Alloy Dissolved per 100 Grams HNOs Solution oi
Alloy * per cent / ~"
Pt in Alloy.
i-398Sp.Gr.
i.298Sp.Gr.
x.igoSp-Gr.
i.2g8Sp.Gr.:
Pt and Silver
10
57
44
69
37
"
5
69
57
5 1
35
tt
2-5
62
61
69
11
i
75
70
76
Pt and Copper
IO
46
27
II
5 1
"
5
36
34
14
"
2-5
51
40
30
"
i
5 2
41
37
Pt and Lead
10
7
9
8
. .
"
5
8
9
10
"
2-5
22
i7
ii
"
21
18
23
. .
Pt and Bismuth
10
14
19
4
3
tt
5
21
20
6
18
ti
2-5
25
42
8
. .
11
i
49
6 4
10
. .
Pt and Zinc
10
10
II
19
5
"
5
16
12
6
ii
2-5
16
24
19
. .
tt
i
20
32
37
PLATINUM BROMIDE PtBr 4 .
100 grams sat. aqueous solution contain 0.41 gram PtBr4 at 20
(Halberstadt Ber. 17, 2962, '84.)
PLATINIC POTASSIUM BROMIDE K 2 PtBr 6 .
100 grams sat. aqueous solution contain 2.02 grams K 2 PtBr 6 at 20.
(Halberstadt.)
PLATINIC DOUBLE CHLORIDES of Ammonium, Caesium, Potas-
sium, Rubidium and Thallium.
SOLUBILITY IN WATER.
(Crookes Chem. News 9, 37, 205, '64; Bunsen Pogg. Ann. 113, 337, *6i.)
Grams per 100 Grams Water.
i/ .
o
10
(NH^PtCle. Cs 2 PtCl 6 .
O.O24
0.666 (15) 0.050
K 2 PtClfi.
0-74
0.90
Rb 2 PtCl.
0.184
0.154
Tl 2 PtCl6.
0.0064 (15)
20
25
0.079
0.095
I .12
I .26
O.I4I
0.143
. . .
30
40
O.IIO
0.142
I.4I
I. 7 6
0.145
0.166
. . .
So
60
0.177
0.213
2.17
2.64
0.203
0-253
.
7o
80
0.251
0.291
3-79
0.329
0.417
:::
90
100
0.332
1.25 0.377
4-45
0.521
0-634
0.050
233 PLATINIO CHLORIDES
SOLUBILITY OF AMMONIUM PLATINIC CHLORIDE AND OF POTASSIUM
PLATINIC CHLORIDE IN ALCOHOL AT i5-2o.
(Fresenius; Peligot Z. aaal. Ch. 36, 322, '97.)
o, L Gms. per Liter Solution. Cms, per Liter Solution. '
(NH4) 2 PtCl 6 . K 2 PtCl 6 . '
55% Alcohol 0.150 ... 95% Alcohol 0.0037 0.030
76 0.067 0.026 Abs. " ... 0.0082-0.002?
85 ... 0.180 80 Vol.% Alcohol + 20
Vol. % Ether ... 0.027
90 o. loo Abs. Methyl Alcohol . . . 0.072
PLATING AMINES.
SOLUBILITY IN WATER.
(Cleve.)
Amine. Formula.
/ATTT \ pi Gms. per TOO Gms. H2O.
Platino Semi Di Amine Chloride Pt < gj "> 0.26 at o '3.4 at 100
Chloro Platin Amine Chloride * C1 2 Pt< NHCl ' 14 " 3 ' "
Chloro Platin Semi Diamine Chloride Cl 3 Pt(NH 3 ) 2 Cl o. 33 " i . 54 "
POTASSIUM ACETATE CH 3 COOK.
SOLUBILITY IN WATER.
100 gms. sat. aq. solution contain 73.65 gms. CH 3 COOK, or 100
gms. H 2 O dissolve 286.3 gms. at 31.25.
(Kohler Z. Ver. Zuckerind. 47, 447, '97.)
ioo gms. H 2 O dissolve 188 gms. CH 3 COOK at 5, 229 gms. at 13.9,
492 gms. at 62.
(Osann.)
ioo gms. 99 per cent ethyl alcohol dissolve 33.3 gms. CH 3 COOK at
15, and 50.0 gms. at 80.
POTASSIUM (Di Hydrogen) ABSENATE KH 2 AsO 4 .
ioo gms. sat. aq. solution contain 15.9 gms. KH 2 AsO 4 , or ioo gms.
H,O dissolve 18.86 gms. at 6. Sp. Gr. of solution = 1.1134.
(Field J. Ch. Soc. n, 6, '59.)
POTASSIUM BENZOATE KC 7 H 5 O 2 .3H 2 O.
SOLUBILITY IN WATER.
(Paietta Gazz. chim. ital. 36, II, 67, '06.)
t- 17-5 2 5 33.3 5
Gms. KC 7 H 5 O 2 per ioo Gms. 41.4 42.4 44.0 46.6
Solution.
POTASSIUM BORATES
234
SOLUBILITY OF POTASSIUM BORATES IN WATER AT 30.
(Dukelski Z. anorg. Chem. 50, 42, '06, complete references given.)
Gms. per 100 Gms. Solution. Gms. per 100 Gms. Residue.
K 2 0.
B 2 3 .
K 2 0.
B 2 3 .
47-50
46.36
0.91
46.13
9-O2
40.51
1-25
41 .62
9.71
36.82
1. 80
39-90
32-74
3-51
37-22
14.58
29.63
6.98
35-05
17.92
24-84
17.63
30.02
21 .70
23-30
18.19
26.84
31-49
16.21
13.10
2 5 >I2
33-18
11.78
9.82
20-57
26.43
9.18
8.00
22.38
3I-30
6.22
9.13
20.87
31.06
7-73
13-37
22.21
36.24
7.8!
13.28
I7-50
34.18
7.71
13.21
11-49
34-81
7-63
13.28
I2-5I
40.52
3 42
7-59
10-77
37-35
i. 80
4-i5
5 .88
20 oo
0.51
3- J 9
I0.8l
40.89
o-33
4.58
7-72
34-21
0.31
4.46
3-91
30.68
3-54
Solid
Phase.
KOH. 2 H 2 O
K 2 O.B 2 3 .2iH 2 O
K 2 O.2B 2 O 3 . 4 H 2 O +K 2 O.sB 2 3 .8H 2 O
K 2 O.5B 2 3 .8H 2 O
K 2 O.sB 2 O 3 .8H 2 O+ B(OH) 3
POTASSIUM (Fluo) BORIDE KBF 4 .
100 gms. H 2 O dissolve 0.44 gm. KBF 4 at 20, and 6.27 gms. at 100
(Stolba Chem. techn. Centr. Anz. 7, 459, '89.)
POTASSIUM BROMATE KBrO,.
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 97, 5, '56; Rammelsberg Ibid. 55, 79, '42; Pohl Sitzber. Akad. Wiss
Wien. 6, 595, '51.)
Gms. KBrO 3 per 100 Gms.
Gms. KBrO 3 per 100 Gms.
ll .
Water.
Solution.
t .
Water.
Solution.
3 !
3-o
40
I 3 .2
ii. 7
10
4 .8
4.6
50
17-5
14.9
20
6. 9
6-5
60
22 .7
18.5
25
8.0
7-4
80
34 o
25 4
30
95
8.7
100
50-0
33-3
Sp. Gr. of solution saturated at 19.5 = 1.05.
235 POTASSIUM BROMATE
SOLUBILITY OF POTASSIUM BROMATE IN AQUEOUS SOLUTIONS OF
SODIUM NITRATE AND OF SODIUM CHLORIDE.
(Geffcken Z. physik. Chem. 49, 296, '04.)
In Sodium Nitrate. In Sodium Chloride.
Grams per Liter. Mols. KBrO 3 Grams per Liter. Mols. KBrO 3
NaNO 3 . KBrO 3 . Per Liter - NaCl. KBrO 3 . Per Liter.
o.o 78-79 0.4715 - 7 8 79 0.4715
42.54 96.01 0.5745 29 25 82.24 0.5220
85.09 108.6 0.6497 5 8 -5o 93 .87 0.5616
170.18 128.3 0.7680 117.0 100.9 0.6042
255.27 150-9 0.9026 I 75-5 IO 4 3 0.6244
340.36 1/2.3 1-031 234.0 106.9 0.6400
POTASSIUM BROMIDE KBr.
SOLUBILITY IN WATER.
(Average curve from results of Meusser Z. anorg. Chem. 44, 79, '05; Etard Compt. rend. 98, 1432,
'84; Ann. chim. phys. [?J 2, 526, '94; de Coppet Ibid. [5] 30, 416, '83; Tilden and
Shenstone Phil. Trans. 175, 23, '84.)
Grams KBr per 100 Grams Grams KBr per 100 Grams
Solution.
Water.
Solution.
Water.
6
5
20.
25.0
30
41.4
70.6
8,
c
26.
5
35
7
40
43-o
75-5
10
5
29.
e
41
.8
50
44-5
80.2
n
3 1
2
45-3
60
46.1
85-5
IO
3 1 -
8
46
7
70
47-4
90.0
5
33-
3
5o
.0
80
48.7
95-o
o
34-
9
53
5
90
49-8
99-2
5
36-
i
56
5
IOO
51.0
104.0
10
37-
3
59
5
no
52-3
109 . 5
15
38-
5
62
5
140
54-7
120.9
20
39-
5
65
.2
181
59-3
145.6
25
40.
4
67
7
SOLUBILITY OF
MIXTURES OF POTASSIUM BROMIDE AND
AMMONIUM
BROMIDE IN
WATER AT 25
(Fock
Z. Kryst. Min.
28, 357. '97-)
Grams per Liter Solution.
Mol. per cent in Solution.
Sp. Gr. of
Mol. per cent
in Solid Phase
NH 4
Br.
KBr
NH 4 Br.
KBr.
Solutions.
NH 4 Br.
KBr.
o.
OO
558-
i
o.o
IOO
I-3756
.00
IOO
6.
4
554-
2
1.38
9 8.
62
1-3745
O
.26
99-74
24.
64
536.
5
5-29
94-
7 1
1-3733
I
.27
98.73
SI'
34
516-
8
10-77
89.
23
1.3721
2
.02
96.98
152 .
9
441.
2
29.63
70-
37
i .3711
8
.42
9I-58
262 .
2
347-
3
47.84
52-
16
* -37*5
17
.20
82.80
347-
6
262 .
3
61 .69
38.
3 1
1-3753
27
. 9 8
72.02
4
260.
3
64.03
35-
97
1-3753
32
53
67.47
417 .
8
232.
2
68. 61
3 1 -
39
1.3766
39
45
60-55
432-
5
222.3
70.27
29.
73
1-3777
variable
variable
480.
8
179.
9
76.47
23-
53
1.3766
98
53
i-47
577-
3
o.
o
IOO.O
o.
o
1-3763
IOO
.0
o.oo
POTASSIUM BROMIDE
236
SOLUBILITY OF POTASSIUM BROMIDE IN AQUEOUS SOLUTIONS OP
POTASSIUM HYDROXIDE.
(Ditte Compt. rend. 124, 30, '97.)
Grams per 1000 Grams H2O.
KOH. KBr. '
36.4 558.4
IJ 3-5 433- 6
177.2 358.1
231.1 281.2
Grams per 1000 Grams HgO.
KBr.
248.1
KOH.
277.6
434-7
579.6
806.9
64.8
33.4
VOLUBILITY OP MIXTURES OF POTASSIUM BROMIDE AND CHLORIDE AND
OF MIXTURES OF POTASSIUM BROMIDE AND IODIDE IN WATER.
(Etard Ann. chim. phys. [7] 3, 275, '97.)
Mixtures of KBr and KC1. Mixtures of KBr and KI.
Grams per TOO Gms. Solution. Grams per 100 Grams Solution.
v *
KBr.
KCL
20
17-5
10.5
O
21-5
10.8
10
23.2
II .0
20
24.8
II .2
25
25-5
"3
30
26.3
11.4
40
28.0
"5
60
30.6
ii. 8
80
33-4
12 .1
100
35-7
12.6
1 20
38.0
12-9
150
40.6
I3'4
KBr.
9 .2
Kl.
42-5
9.9
IO.2
45-3
46.6
10.5
10-7
10-9
II .2
47-5
48.0
48.6
49.6
ii. 9
12.6
5*-3
52-7
13.2
53-8
14.0
54-8
14.9
55-5
SOLUBILITY OP POTASSIUM BROMIDE IN AQUEOUS SOLUTIONS OF
POTASSIUM CHLORIDE, AND OF POTASSIUM CHLORIDE IN AQUEOUS
SOLUTIONS OF POTASSIUM BROMIDE, AT 25.2.
(Touren Compt. rend. 130, 1252, 'oo.)
KBr in Aq. KCl Solutions.
Mols. per Liter. Grams per Liter.
KCl in Aq.
Mols. per Liter.
KBr Solutions.
Grams per Liter.
KCl.
KBr.
KCl.
KBr.
KBr.
KCl.
KBr.
KCl.
0.0
4
, 7 6l
O-O
567
.0
.0
4.18
.00
3II.8
0.67
4
.22
50.0
502
5
O
49
3.85
58
4
287.2
0.81
4
.15
60.4
494
.2
85
3-58
101
3
267.1
I .35
.70
100.7
440
7
I
31
3-19
156
.1
238.0
1.48
3
54
110.4
421
.6
I
.78
2 .91
211
9
217 .1
1.61
o
,42
I2O.O
407
.2
2
25
2.58
268
.0
192.4
1.70
o
34
126.8
397
7
2
.69
2-33
320
4
173-8
2.46
2
50
183.5
297
7
3-775
525
28J.6
625
3
237
POTASSIUM BROMIDE
SOLUBILITY OF POTASSIUM BROMIDE IN AQUEOUS SOLUTIONS OF
POTASSIUM NITRATE, AND OF POTASSIUM NITRATE IN AQUEOUS
SOLUTIONS OF POTASSIUM BROMIDE, AT 14.5 AND AT 25.2.
(Touren Compt. rend. ^30, 908, 'oo.)
KBr in Aqueous KNO 3 Solutions. KNO 3 in Aq. KBr Solutions.
Mols. per Liter. Grams per Liter. Mols. per Liter. Grams per Liter.
KN0 3 .
KBr.
KN0 3 .
KBr.
KBr.
KN0 3 .
KBr.
KN0 3 .
Results at
14-2.
Results at 14.20.
O-O
4
332
.0
5I5-9
.0
2.228
O
O
225.4
0-362
4
.156
36
.6
494-9
-356
2 .026
42
4
205 .0
0.706
4
093
71
4
487.4
.784
I-835
93
4
185-7
1-235
3
939
124.9
469.1
I
.092
1.730
130
-0
J 75-o
I
577
I-587
I8 7
.8
160.6
Results at
25-2.
2
542
I .406
302
7
142.2
0-0
4
.761
O
.0
566.2
3
536
1.308
421
.1
132-3
O.I3I
4
72
13
3
561 .0
Results at 25.2.
0-527
4
.61
53
3
549-1
O
3.217
.0
325-5
0.721
4
54
72
9
540.8
38
3.026
45-3
306.2
1.09
4
475
no
3
533-o
93
2.689
no
.8
272.0
I .170
4
44
118
4
528.8
I
37
2.492
163
. i
252 .2
1.504
4
375
J 5 2
.2
521.1
I
.208
2 -2l6
J 43
.8
224.3
2
.87
1.958
34i
.8
198.1
3
55
1.807
422
.8
182.8
SOLUBILITY OF POTASSIUM BROMIDE IN ALCOHOLS AT 25.
(de Bruyn Z. physik. Chem. 10, 783, '92; Rohland Z. anorg. Chem. 18, 327, '98.)
Grams KBr Dissolved by 100 Gms. Alcohol at:
Alcohol.
Methyl Alcohol
Ethyl Alcohol
Propyl Alcohol
Room Temp. (R.).
I .92
0.28 (Sp. Gr. 0.81)
0-055
25 (de B.).
1.51 Abs. Alcohol
SOLUBILITY OF POTASSIUM BROMIDE IN AQUEOUS ALCOHOL.
(Taylor J. Physic. Ch. I, 724, '96-'97-)
Results
at 30.
Results
at 40.
Wt. per cent Alcohol
Gms. KBr per 100 Gms.
Gms. KBr per
100 Gms.
in Solution.
'Sat. Solution.
Solvent.
Sat. Solution.
Solvent.
O
41 .62
71.30
43-40
76.65
5
38.98
67.25
40-85
72.70
10
3 6 '33
63.40
38-37
69.00
20
31.09
56-40
33-27
62.30
30
25.98
50-I5
28.32
5 6 -45
40
21 .24
44-95
23 .22
50.46
50
16.27
38-85
l8.II
44-25
60
II .50
32-50
13 -O2
37-40
70
6.90
24.70
7.98
28.90
80
3-9
15-95
3-65
18.95
90
0.87
8.80
1.03
10.45
100 gm. acetone dissolve 0.023 gm. KBr at 25*
(Krug and McElroy
J. anal. Chem. 6, 184, '92.)
POTASSIUM BROMIDE
238
Aqueous Acetone.
cc. Acetone
I0 cc - Sat. Solution.
per ioo cc.
Millimols
Gms.
Gms.
Solvent.
KBr.
KBr.
H 2 0.
O
481.3
57-3
80.6
2O
366.7
43-67
69-5
30
3*0-5
36.98
62.97
40
259.0
30.85
55-60
50
2O2 .9
24.16
47-60
60
144.9
17 .22
39-15
70
95-3
n-35
29.78
80
46-5
5-54
2O. IO
90
IO.I
I .20
IO.I5
PASSIUM
Z. anorg.
BROMIDE AT 25 IN:
Chem. 45, 262, '05.)
Aqueous Glycerine.
Wt
. % KBr per 100 cc
.Sol.
Sp. Gr.
Solutions.
Glyc
in Sc
Srine
vent.
Millimols.
Gms.
1-3793
481
3
57
32
1.2688
13
.28
444
3
S 2
.91
i. 2118
2 5
.98
404
.0
48
IT
i .1558
45
36
340
5
40
55
i .0918
54
23
310
4
36
.98
1.0275
83
.84
219
25
26
.11
0.9591
100
OO
172
65
20
56
0.8942
0.8340
Sp. Gr.
Solutions
1-3793
1-3704
1-3594
1.3603
1.3691
100 cc. sat. solution of potassium bromide in furfurol (C 4 H 3 O.COH)
Contain 0.139 gm. KBr at 25. (Walden Z. physik. Chem. 55, 713, '06.)
POTASSIUM BUTYRATE C 3 H 7 COOK.
100 grams water dissolve 296.8 grams C 3 H 7 COOK, or 100 grams
sat. solution contain 74.8 grams at 31.25.
100 grams of an aq. solution saturated with sugar and C 3 H 7 COOK
contain 49.19 grams sugar + 34.78 grams C 3 H 7 COOK + 16.03 grams
H 2 O at 31.25. (Kohler Z. Ver. Zuckerind. 47, 447, '97.)
POTASSIUM CARBONATE K 2 CO 3 .
POTASSIUM (Bi) CARBONATE KHCO 3 .
SOLUBILITY OF EACH IN WATER.
(Mulder; Dibbits J. pr. Chem. [2] 10, 439, '74.)
Grams K 2 CO 3 per 100 Grams
1 .
Solution.
47-2
Water.
89.4
IO
20
5 2 -2
5 2.8
IO9.O
112 .O
30
53-3
II4.O
40
60
IOO
54-o
56.0
60.9
II7.0
127.0
156.0
Grams KHCO 3 per ioo Grams
Solution. Water.
21-7
24.9
28.1
31.2
37-5
22-4
27-7
33-2
39-o
45-3
60.0
Kohler (loc. cit.) gives for the solubility of K 2 CO 3 in water, 48.91
grams K 2 CO 3 per 100 grams solution, or 95.9 grams per 100 grams
H 2 O at 31.25. In saturated sugar solution at the same temperature
he finds 56.0 grams sugar + 22.24 grams K 2 CO 3 + 21.76 grams H 2 O
per loo grams sat. solution. Engel (Ann. chim. phys. [6] 13, 366, '88)
finds 1 1 i.o grams K 2 CO 3 per 100 grams H 2 O or 52.6 grams per 100 grams
sat. solution at o. Sp. Gr. of solution = 1.542. For potassium bi car-
bonate he finds 23 grams KHCO 3 per 100 grams H 2 O, or 18.7 grams
per loo grams solution. Sp. Gr. of solution = 1.127.
239 POTASSIUM CARBONATE
SOLUBILITY OF POTASSIUM Bi CARBONATE IN AQUEOUS SOLUTIONS OF
POTASSIUM CARBONATE AT o.
(Engel.)
Milligram Mols. rjer 10 cc. Solution. p. Gr. of Grams per 100 cc. Solution.
' *K 2 C0 3 . KHC0 3 Solutions. ' K 2 CO 3 . KHCO 3 ."
o.o 21.15 I - I 33 o.o 21.2
17.14 15-28 1.182 ii. 8 15.3
24.10 12.65 I - 2 3 16.7 12.6
34.50 10.25 1.241 23.8 10.3
49-20 7.55 1.298 34.0 7.6
62.14 5.86 i-35 43- 5-9
74.60 4.90 i-39 8 5 1 - 6 4-9
87.50 3.75 1.448 60.5 3.8
117.75 - I -54 2 81.4 o.o
SOLUBILITY OF POTASSIUM CARBONATE IN AQUEOUS SOLUTIONS OF
ETHYL AND PROPYL ALCOHOLS AT 20.
(Linebarger Am. Ch. J. 14, 380, '92; de Bruyn Rec. trav. chim. 18, 87, '99.)
In Aq. Ethyl Alcohol. In Aq. Propyl Alcohol.
Wt. per cent
C 2 H 5 OH in
Solvent.
Gms. K 2 CO 3
per 100 Gms.
Sat. Solution.
Wt. per cent
C 2 H 5 OH in
Solvent.
Gms. K 2 CO 3
per 100 Gms.
Sat. Solution.
Wt. per cent
C 3 H 7 OH in
Solvent.
Gms. K 2 CO 3 per
100 Gms.
Sat. Solution.
10
24
50
2 -5
40
4-3
20
16
55
1.8
45
3-o
30
10
60
i .1
50
2 -O
40
5-6
65
0.8
55
i-3
45
4
69
0.4
60
0.8
65
o-5
TOO grams glycerine of 1.225 Sp. Gr. dissolve 7.4 grams K 2 CO 3 .
(Vogel N. Rep. Pharm. 16, 557, '67.)
POTASSIUM SODIUM CARBONATE KNaCO 3 .6H 2 O.
100 gms. H 2 O dissolve 184 gms. salt at 15. Sp. Gr. of sol. = 1366.
(Stolba J. pr. Chem. 94, 406, '65.)
POTASSIUM URANYL CARBONATE 2 K 2 CO 3 .(UO 2 )CO 3 .
100 gms. H 2 O dissolve 7.4 gms. salt at 15.
(Ebelmen Liebig's Ann. [3] 5, 189, '52.)
POTASSIUM CHLORATE KC1O 3 .
SOLUBILITY IN WATER.
(Gay-Lussac Ann. chim. phys. n, 314, 1819; Pawlewski Ber. 32, io4o, r> 99; above 100, Tilden
and Shenstone Proc. Roy. Soc. 35, 345, '81; see also Blarez Compt. rend. 112, 1213, '91;
Etard Ann. chim. phys. [7] 2, 526, 94; at 99, Kohler Z. anal. Chem. 18, 242, '79.)
Gms. KClOg per 100 Gms. Gms. KClO.-< per TOO Gms.
c .
Solution.
Water.
Solution.
Water.
O
3-04
3.14
3-3*
70
22-55
29.16
32-5*
IO
4.27
4-45
5-o
80
26.97
36.93
39-6
2O
6.76
7 .22
90
31-36
46.11
47-5
25
7.56
8.1 7
8.6
100
35-83
55-54
56.0
30
8.46
9.26
IO.I
120
42.4
73-7
73-7
40
n-75
I3-3 1
14-5
I 3 6
49-7
98-5
99.0
50
15.18
17-95
19.7
I9O
64.6
183.0
183.0
60
18.97
23.42
26.0
330
96.7
2930-00
*
Gay Lussac.
POTASSIUM CHLORATE
240
SOLUBILITY OF POTASSIUM CHLORATE IN AQUEOUS SOLUTIONS OP
POTASSIUM BROMIDE AT 13.
(Blarez Com pt. rend. 112, 1213, '91.)
Cms. per 100 Cms.
Solution.
Gms. per 100 Gms.
Solution.
Gms. per 100 Gms.
Solution.
'KBr.
KC1O 3 .
KBr.
KC1O 3 .
KBr.
KC10 3 .
O.2O
5 .l8
I .0
5-04
6.0
3-46
O-6o
5.20
2 -O
4.60
8.0
2.8o
0.8
5.06
3-o
4.2
10.
2.40
4-0
4.0
SOLUBILITY OF POTASSIUM CHLORATE IN AQUEOUS SOLUTIONS OF
OTHER POTASSIUM SALTS AT 14-! 5.
(Blarez.)
Salt.
KOH
KC1
KBr
KI
u
Gms. per 100 Gms. Solution.
K Salt.
KC1O 3 .
4-47
I.9I
3-82
4-45
3-58
3-05
6.10
4-49
3.60
4-25
8.51
4-59
3-65
Gms. per 100 Gms. Solution,
oau. <-
K Salt.
KC10 3 .
KNO 3
2-59
4-5 1
u
5.18
3.88
K^SO,
2.23
4.71
U
4.46
3-9 8
K 2 C 2 O 4
2.42
4-72
"
4-85
3-93
SOLUBILITY OF POTASSIUM CHLORATE IN AQUEOUS SOLUTIONS OP
POTASSIUM CHLORIDE AT 20.
(Winteler Z. Electrochem. % 360, 'oo.>
p. Gr. of
Grar
ns per Liter.
Sp Gr. of
Gran
is per Liter.
olutions.
KC1.
KC10 3 .
Solutions.
KC1-
KC1O 3 .
.050
7I.I
I .098
120
24-5
050
10
58.0
I.IOS
I4O
22 .5
.050
20
49-0
I.II9
1 60
21 .O
054
40
39-5
I.I30
180
20. o
.064
60
34-o
I .140
200
20. o
075
80
30.0
1.168
250
20. o
.086
100
27.0
SOLUBILITY OF POTASSIUM CHLORATE IN AQUEOUS SOLUTIONS OF
POTASSIUM NITRATE.
(Arrhenius Z. physik. Chem. n, 397, '93.)
Results at 19.85'
Results at 23.87'
Mols. per Liter.
Grams per Liter. Mols. per Liter.
Grams per Liter.
KN0 3 . KC10 3 . "
KNO 3 .
KC1O 3 ' KNO 3 . KC1O 3 '
KN0 3 . KC10 3 .
o.o 0.570
o.o
69.88 o.o 0.645
o.o 79-09
0.125 0.529
12.65
64.86 0.5 0.515
50.59 63.14
0.25 0.492
25.29
60.33
i.o 0.374
ioi .19
45 .85
2.O 0.328
202.38
40.22
241
POTASSIUM CHLORATE
SOLUBILITY OF POTASSIUM CHLORATE:
(Taylor J. Physic. Chem. i, 720, '96- '97; see also Gerardin Ann. chim. phys. [4] 5, 148, '65.)
In Aqueous Alcohol.
In Aqueous Acetone.
Wt. percent A ^3O-
Alcohol or Gms. KC1O 3 per
of Acetone *> Gms.
At 40.
Gms. KC1O 3 per
TOO Gms.
At 30.
Gms. KC1O 3 per
100 Gms.
At 40.
Gms. KC1O 3 per
100 Gms.
insolvent. Solution
. Water.
Solution.
Water.
Solution.
Water.
Solution.
Water.
9- 2 3
IO.I7
12.23
13-93
9-23
IO.I7
11.23
*3-93
5
7.72
8.80
10.48
12-33
8. 3 2
9-5 6
II .10
13.11
10
6-44
7-65
8.84
10-77
7.63*
9.09
10.28*
12 .60
20
4-5 1
5-90
6.40
8.56
6.09
8.10
8.2 7
II .26
30
3.21
4-74
4.67
7-00
4-93
7.40
6.69
10.24
40
2-35
4.00
3-41
5.88
3-90
6.76
5-36
9-45
50
i .64
3-33
2.41
4-94
2.90
5-98
4-03
8.40
60
I .01
2-53
I.4I
3-69
2.03
5-i7
2.86
7-35
70
o-54
1.82
0.78
2.63
1.24
4.18
1.68
5.68
80
0.24
I .22
0-34
i-73
o-57
2.88
0.79
3-97
90
0.06
O.62
O-I2
1.17
0.18
1.82
0.24
2-45
* Solvent, 9.09 Wt. per cent Acetone.
ioo grams glycerine dissolve 3.5 grams KC1O 3 at 15.5.
100 grams sat. solution of KC1O 3 in glycol contain 0.9 gram KC1O 3 .
(de Coninck Bui. acad. roy. Belgique, 359, '05.)
POTASSIUM (Per) CHLORATE KC1O 4 .
SOLUBILITY IN WATER AND IN ALCOHOL.
(Muir Chem. News, 33, 15, '76; Wenze Z. angew. Ch. 5, 691, '91.)
In Water. (M.)
In Alcohol. (W.)
t.
Gms.KClO 4 per
ioo Gms. H2O.
Sp. Gr. of
Solutions.
Wt. per cent Gms.KClO 4 per
Alcohol. ioo Gms. Alcohol.
6
0-7
I .OOO5
97-2
0.0156
25
oo
1-9
6-45
20.
I.OI23
I -Ol8l
I . 0660
95-8
90.0
O-020
0-036
POTASSIUM CHLORIDE KC1.
SOLUBILITY IN WATER.
Ver. Zuckerind. 47, 447, '97; Andrae J. pr. Chem. [2] 29,
[4] 5, i37, '65; de Coppet Ibid. [5] 3<>, 4". '83; Etard Ibid. [7]
and Shenstone Proc. Roy. Soc. (Lond.) 35, 345, '83.)
A0 Gms. KC1 per ioo Gms. ^ Gms.KCl per ioo Gms.
456, '84; Gerardin Ann. chim. phys.
2,526, '94; Mulder; above 100, Tilden
i0 Gms.KCl per ioo Gms.
Solution.
Water.
Solution.
Water.
Solution.
Water.
-9
19
3
23-9
40
28,
6
40
.0
147
41-5
70.8
-4-5
20
.6
25-9
So
29
9
42
.6
180
43-7
77-5
21
.6
27-6
60
31
3
45
5
Solid Phase
Ice
5
22
7
29-3
70
32
,6
4 8
3
-9
19-3
23-9
10
23
7
31.0
80
33
,8
5 1
.i
-8
. 17.7
21-5
15
24
5
32-4
90
35
.1
54
.0
-8
16.7
20.
20
2 5
4
34-o
IOO
36
.2
56
7
-7
14.9
J 7-5
25
26
.2
35-5
130
39
.8
66
.0
-6
13.6
J 5-7
30
27
.1
37-o
-5
5 I2 -5
14-3
Sp. Gr. of solution sat. at o = i.iso;- at 15 = 1.172,
POTASSIUM CHLORIDE
242
SOLUBILITY OF MIXTURES OF POTASSIUM CHLORIDE AND AMMONIUM
CHLORIDE IN WATER AT 25.
(Fock Z. Kryst. Min. 28, 353, '97.)
Grams per Liter
Solution.
Mol. per cent
in Solution.
Sp. Gr. of
oolutions*
Mol. per cent in
Solid Phase.
' NH 4 C1.
KCl.
NH 4 C1.
KCl.
NH 4 C1.
KCl.
o.oo
311 .3
o.oo
100.
1.1807
o.o
100
22. Si
293-3
9.41
90.59
i .1716
I .21
98.79
35-39
278.7
15.04
84.96
1.1678
2 -II
97.89
89.17
273.2
34.26
65-74
i .1591
6.18
93.82
127.8
234.6
46 59
53-44
1-1493
8.90
91.10
147.2
204.2
5!- 6 3
48.37
i .1461
10-53
89.47
197-3
157-7
63-56
36-44
i .1391
17.86
82.14
232-5
116.8
73-49
26.51
1.1326
6o.20
39.80
244-5
123.0
73-48
26.52
1.1329
76.88
23.12
261 .9
in .0
79.10
20.90
1.1245
97-5 1
2-49
259.0
102 .2
82.14
17.86
I .1212
97-79
2 .21
278.6
53-16
87.96
12 .04
I IOO9
98.85
I .15
320.7
3 x -24
93-45
6-55
I .0912
99-33
0.67
273-5
o.oo
100.00
o.oo
1.0768
IOO-0
o.oo
SOLUBILITY OF MIXTURES OF POTASSIUM CHLORIDE AND POTASSIUM
BROMIDE AT 25.
(Fock.) .
Grams per Liter
Solution.
Milligram Mols.
per Liter.
Mol. per cent o r* ^f
KPl i'n "P - "JP.OI
1 m cAi*;x^
Mol. per cent
KCl in
KBr.
KCl.
KBr.
KCl.
Solution.
Solid Phase.
558.I
O-OO
4686.2
o.o
o.o
1-3756
O.OO
531-5
23-44
4462 . 7
314.2
6.16
1.3700
o.oo
503- 6
46.57
4228.5
624.3
12.86
1.3648
8.2 3
454-6
82.62
3817.8
1108.0
22.49
1-3544
15.68
379-6
136.6
3188.1
1830.7
36.48
i-332o
33-66
324-8
166.9
2727.6
2237.4
45.06
1.3119
63-5 1
218.0
213.9
1830.2
2868.0
60.30
1.2689
82.29
140.7
250.9
1181.1
3363-9
74-oi
1-2455
88.04
47-5
291.7
398.8
39 IJ -4
85.22
1.1977
96.98
o-o
3*1-3
o.o
4173 - 1
100.00
1.1756
100 . oo
SOLUBILITY OF POTASSIUM CHLORIDE IN
HYDROCHLORIC ACID
(Jeannel Compt. rend. 103, 381, '86; Engel Ann
AQUEOUS SOLUTIONS OF
AT 0.
. chim. phys. [6] 13, 377, '88.)
Milligram Mols.
per 10 cc. Grams per 100 cc. Solution. Sp. Gr. o
KCl.
HC1.
KCl.
HCl. Solutions
34-5
o.o
25-73
O-O
159
30.41
3-9
22 .69
1.42
^
27-95
6.6
20-84
2-41 ]
.150
27-5
7- 1
20.51
2-59 3
147
23-75
II .1
17.71
4-05
137
16.0
23.0
n-93
8.39 I. Ill
10.0
34-o
7.46
12.40 I-IO5
7-5
41 .0
5 -60
14.95 I-I05
2 .0
65-5
1.49
23.88 I. 121
2-4
148.8 (sat.)
i-52
54.26 1.224
ioo cc. saturated HCl solution dissolve 1.9 grams; KCl at 17.
(Ditte Compt. rend. 92, 42, '86.)
243 POTASSIUM CHLORIDE
SOLUBILITY OF POTASSIUM CHLORIDE IN AQUEOUS POTASSIUM
HYDROXIDE SOLUTIONS.
(Engel Bull. soc. chim. [3] 6, 16, '91; Winteler Z. Electrochem. 7, 360, 'oo.)
Results at o. Results at 20.
(Engel.) (Winteler.)
Mg. Mols. per
10 cc. Solution Sp. Gr. of
Gms. per 100 cc.
Solution.
Gms. per 100 cc.
Solution.
Sp. Gr. of
Solution.
KCl.
KOH.
KCl.
KOH.
kci.
KOH.
35-5
O
i
159
26.83
o
.0
29
3
I -O
1.185
3 I.O
2
375
i
.146
23-44
I
33
21
.1
10.
i .210
28.3
4
7
i
153
21.39
2
.64
14
.8
2O-O
1.245
23.0
9
9
i
.172
*7-39
5
56
10
4
30.0
1.295
18-38
15
.1
i
.195
13.89
8.46
6
.8
4O.O
I -345
14-43
20
o
i
.2l6
10.91
ii
2 3
4
.0
5O.O
1-397
"43
24
63
i
239
8.64
13
83
2
.2
6o.O
1.450
8.98
29
2 5
i
.26l
6.78
16
43
I
4
7O.O
i .500
6.28
35
.13
L
.294
4-74
19
72
1
.1
8o.O
i .550
O
9
8 5 .0
1.580
SOLUBILITY OF MIXTURES OF POTASSIUM CHLORIDE AND POTASSIUM
IODIDE IN WATER.
(Etard Ann. chim. phys. [7] 3, 275, '94.)
Grams per 100 Gms. Solution. Grams per 100 Gms. Solution.
I/ B
KCl.
Kl.
(/
KCl.
KI.
3-7
50-5
100
6.2
61 .0
20
4.2
53-o
140
7-3
63-7
40
4-7
55-3
180
8-3
65-5
60
5- 2
57-5
220
9-4
66 3
80
5-7
59-4
245
10.
66.5
SOLUBILITY OF POTASSIUM CHLORIDE IN AQUEOUS MAGNESIUM
CHLORIDE SOLUTIONS.
(Precht and Wittgen Ber. 14, 1667, *8i.)
Grams KCl per 100 Grams Sat. Solution in:
f.
M II%
15%
MgCl 2 .
21-2%
MgCl*.
30%
MgCl 2 -
20% M K C1
10
14-3
9-9
5
3
1-9
4
.2
KC1+5
7
NaCl
20
*5-9
6
5
2.6
6
.0
" +5
9
"
30
17 .5
12.7
7
.6
3-4
6
9
" +6
.0
"
40
19.0
14.2
8
.8
4.2
7
-9
" +6
.1
"
50
20.5
15.6
10
.0
5.0
8
9
" +6
3
11
60
21.9
17.0
ii
.2
5-8
9
9
" +6
4
"
80
24-5
19-5
13
.6
7-3
10
9
" +6
.6
tt
90
25-8
20.8
14
7
8.1
ii
9
" +6
7
"
100
27.1
22.1
15
9
8.9
13.0
" +6
9
a
POTASSIUM CHLORIDE
244
SOLUBILITY OF POTASSIUM CHLORIDE IN AQUEOUS SOLUTIONS OF
POTASSIUM NITRATE, AND OF POTASSIUM NITRATE IN AQUEOUS
SOLUTIONS OF POTASSIUM CHLORIDE, AT SEVERAL TEMPERATURES.
(Touren Compt. rend. 130, 908
1. 130, 908, 'oo; Bodlander Z. physik. Ch. 7, 360, '91; Nicol Phil. Mag.
(Lond.) 31, 369, '91; Soch J. Physic. Ch. 2, 46, '98.)
KC1 in Aq. KNO 3 Solutions at:
14-5 (T.).
17-5 (B.).
25.2 (T.). 20, etc. (N.).
Gms. per Liter <- p_
Senior, <*.
Gms. per Liter.
Gms. per Liter.
Gms. per 1000 Gms.
H 2 0.
KN0 3 .
KCl.
'KN0 3 .
KCI:
KN0 3 .
KCI:
KNO 3l KCI.
288
3
173
0.
293-9
0.
311
.8
o.oo 345.2
20.64
284
.2
.198
65.
8
275.0
13-
7 6
306
.6
56.18 342.15
32.18
282
. I
. 2IO
88.
3
273-4
32.
18
303
.6
168.54 334.39
62. 23
276
.8
.225
124.
8
265-3
91.
26
293
.2
at 25
82.77
273
5
.236
148.
3
259.8
122.
7
287
.2
oor* & *J AT *)
JI 5-9
270
7
239
152.
2
259.6
141.
4
284
. 2
*^5- 64 L *6
119.1
268
3
239
i54.
9
259-5
182.
7
276
.0
at 80
123.4
267
.2
.241
153.
3
262.4
1175.0 402.0
KNO 3 in Aq. KCl Solutions at :
25-2.
Grams per Liter Solution. Grams per Liter Solution. Grams per 1000 Gms.
KCl.
0.0
I3-58
3!- 6 3
65.64
132.6
164.4
196.5
236.9
KN0 3 .
225.4
219.8
208.2
185.2
I S9-S
J 53-3
144.0
KCl.
0.0
19-39
49.22
IOO-7
155-2
207.3
226.8
KN0 3 .
3 2 5-5
3*2-3
288.7
254.0
224.4
203.9
196.9
KCL
o.o
82.9
165.8
248.7
310.8
KNO 3 . '
311.1
256.8
221-7
202. O
501.6
KNO 3 in Aq. KCl at 20.5 (B.). KCl in Aq. KNO 3 at 20.5 (B.).
Gms. per 100 Gms.
Solution.
Sp.Gr.of
O 1 i*
KCl. KN0 3 .
Solutions.
o.o 27.68
1.1625
4.72 24.39
I .1700
7-74 22.44
1.1765
12.23 20 - 2 3
1.1895
15.15 18.96
I.I 9 83
I9.6l 17.67
I .2150
22.17 I7.II
I .2265
24.96 16 79
I . 2400
Gms. per 100 Gms.
Solution.
Sp. Gr. of
O1 A*
KNO 3 .
KCl.
bolutions.
o.o
29-39
1.1730
6. 5 8
27.50
i . 1980
8.88
27-34
I. 2100
12.48
26.53
1.2250
14.83
25.98
1.2360
15.22
25,96
1.2390
15-49
25-95
1.2388
15-33
26.24
I.24IO
245 POTASSIUM CHLORIDE
SOLUBILITY OF MIXTURES OF POTASSIUM CHLORIDE AND POTASSIUM
SULPHATE IN WATER.
Gms. per 100 Gms, Gms. per TOO Gms.
t. H 2 0. Observer. t. H 2 O. Observer.
KC1. + K 2 SO 4 . KC1 + K 2 SO 4 .
10 30.9 I 32 (Precht and Wittgen.) 40 38.7 1.68 (P. and W.)
15.8 28.0 2.3 (Kopp.) 50 41.3 1.82
20 33-4 1-43 ( p andW.) 6 O 43.8 1.94
2 5 34 -?6 2> 93 (Van'tHoffand Meyerhoffer.) 80 49-2 2.21 "
30 36.1 1-57 (P.andW.) 100 54.5 2.53
SOLUBILITY OF MIXTURES OF POTASSIUM CHLORIDE AND SODIUM
CHLORIDE IN WATER,
( (i) Precht and Wittgen Ber. 14, 1667, '81; at 25 and at 80, (3) Soch J. Physic. Ch. 2, 46, '98;
(2) Etard Ann. chim. phys. [7] 3, 275, '97.)
Grams per 100 Grams H2O. Grams per 100 Grams H2O.
KCl Nad. ' 'KC1. NaCl. '
o 11.2(1)11.2(2) 30.0(030.0(2) 50 22.0(1)19.0(2) 27.7(1)32.3(2)
10 12.5 12.3 29.7 30.5 60 24.6 20.6 27.2 32.8
20 14-7 *3- 8 2 9- 2 3 I -o 7o 2 7-3 3 2 -5 26 -8 34-1
25 15.8(3)14.5 29.0(3)31.3 80 30.0(3)25.2(3) 26.4(3)34.0
30 17.2 15.4 28.7 31.5 90 32.9 28.4 26.1 32.3
40 19.5 17.0 28.2 31.9 100 34.7 32.3 25.8 30.6
NOTE. Page and Keightly, Rudorff and also Nicol, give single
determinations which lie nearer the results of Precht and Wittgen
than to those of Etard.
SOLUBILITY OF POTASSIUM CHLORIDE IN AQUEOUS SOLUTIONS OF
SODIUM CHLORIDE, AND OF SODIUM CHLORIDE IN AQUEOUS SOLU-
TIONS OF POTASSIUM CHLORIDE, AT 20.
(Nicol Phil. Mag. (Lond.) 31. 369, '91-)
KC1 in Aq. NaCl Solutions. NaCl in Aq. KC1 Solutions.
Grams per 100 Grams H 2 O. Grams per 100 Grams HaO.
' NaCl. KC1. ' KC1. NaCl.
o.o 34-5 2 - 35-9 1
6-5 29.37 4-H 34-39
13.0 4-71 8 - 2 9 3 2 -7!
19.5 .42 12.42 3 I -3
100 gms. 40 per cent by wt. alcohol dissolve 5.87 gms. KC1 + 12.25
gms. NaCl at 25.
100 gms. 40 per cent by wt. alcohol dissolve 5.29 gms. KNO 3 + 10.06
gms. KC1 at 2 5. (Soch J. Physic. Ch. 2, 46, '98.)
100 eras r' s. ethyl alcohol dissolve 0.034 gm. KC1 at 18.5.
100 'gins. aos. methyl alcohol dissolve 0.5 gm. KC1 at 18.5.
(de Bruyn Z. physik. Ch. 10, 783, '92; Rohland Z. anorg. Ch. 18, 327, '98.)
POTASSIUM CHLORIDE
246
SOLUBILITY OP POTASSIUM CHLORIDE IN AQUEOUS ALCOHOL.
(Gerardin Ann. chim. phys. [4] 5, 140, '65.)
Interpolated from the original results.
Grams KC1 per 100 Gms. Aq. Alcohol of Sp. Gr.:
t.
0.9904
0.9848
0.9793
0.9726
0-9573
0-939
0.8967
0.8244
= 5-5
= 9-35
= 13.6
= 19.1
= 30
= 40
= 60
= 90
Wt.%.
Wt.%.
Wt.%.
Wt.%.
Wt.%.
Wt.%.
Wt.%.
Wt.%.
o
23-4
19-5
15-5
-S
7-0
4.0
i-7
o.o
5
25.0
21 .O
j6.8
12.8
8.0
4-8
2.2
o.o
10
26.4
22-5
18.0
14.0
9.0
5-6
2-7
o.o
15
26.8
24.0
19.2
15.2
IO.O
6.4
3-i
0.04
20
29.1
25-3
20.3
16.1
10.8
7.2
3-5
0.06
2 5
30-4
26.8
21.5
17.1
ii. 6
7-9
3-9
0.08
30
3 1 -?
28.0
22 .6
18.2
12.5
8-5
4.2
O-IO
40
34-3
30-8
24.8
20. o
14.0
9-9
4.8
0.20
50
37-o
33-5
27.0
21.8
15-5
10.8
5- 2
0.30
60
16.8
ii. 8
5-5
0.40
SOLUBILITY OF POTASSIUM CHLORIDE IN AQUEOUS ALCOHOL AT:
(Schiff Liebig's Ann. 118, 365, *6i.)
14-5
(Bodlander Z. physik. Ch. 7, 316, '91.)
Sp. Gr. Wt. G. KCl per
of per cent 100 s. Aq.
Sp. Gr.
of Sat.
Grams per TOO cc. Solution.
Alcohol. Alcohol. Alcohol.
Solutions.
C 2 H 5 OH.
H 2 0.
KCl.
0.984 10
19.
8
I
.1720
.
88
.10
2 9 .
10
0.972 20
14.
7
I
.1542
2
79
85
.78
26.
85
0.958 30
10.
7
I
1365
4
.98
84
.00
24.
67
o . 940 40
7-
7
I
.IO75
10
56
79
.63
20.
56
0.918 50
5-
o
I
.1085
15
57
75
.24
17-
24
0.896 60
2 .
8
I
0545
20
.66
70
52
14.
27
0.848 80
o.
45
I
0455
24
2 5
67
05
13-
2 5
Gerardin's results at 15
agree
9 6 95
40
.42
5
.18
6.
35
well with the
above deter-
9315
48
73
40
.60
3-
82
minations.
.8448
68
63
15
55
o.
3o
30
and 40.
(Bathrick J. Physic. Chem. i,
1 60,
' 9 6.)
Wt.
Gms. KCl .
per 100 Gms.
Wt.
Gms.
KCl per 100 Gms.
per cent
Aq. Alcohol.
per cent
Aq. Alcohol.
Alcohol.
At 30.
At 40.
Alcohol.
At 30.
At
40.
38.9
41.8
43
.1
II
.1
13
.1
5-28
33-9
35-9
55
9
6
.8
8
.2
9-43
30.2
33-3
65
9
3
.6
4
.1
16.9
24.9
27 .6
78
.1
i
3
I
.0
25.1
19.2
21.8
86
.2
4
5
34-i
15-6
17.2
247
POTASSIUM CHLORIDE
SOLUBILITY OF POTASSIUM CHLORIDE IN AQUEOUS ACETONE
SOLUTIONS.
(Snell J. Physic. Ch. 2, 484. '98; at 20, Herz and Knoch Z. anorg. Ch. 41, 317, '04.)
Per cent
At 20.
At 30.
At 40.
At 50.
Acetone
in
KC1 per 100 cc.
Solution.
Gms. per 100 Gms.
Solution.
Gms. per 100 Gms.
Solution .
Gms. per 100 Gms.
Solution.
Solvent.
Millimols. Grams.
Acetone. KC1.
Acetone. KC1.
Acetone. KC1.
O
410.5 30.62
o. o 27.27
o.o 28.69
o.o 30.0
9.1
351.7 26.23
6.96 23.42
6-79 25.33
...
2O
286.6 21.38
l6.22 18.90
15.75 ~21.28
... ...
30
223.7 16.69
25.45 15.06
two layers
25.67 14.42
40
166.5 12.42
35-52 II-3I
it
36.03 9.93
50
115.4 8.61
45.98 8.04
d
46.46 7.07
60
71-2 5-3i
56.91 5.12
(i
57-37 4-38
7
38.5 2.87
68.18 2.60
(t
68.56 2.22
80
12.9 0.96
78.43 0.76
79-34 0.58
79.25 0.94
9
2.O O.I5
89.88 0.13
89.84 0.16
8i + sat.sol.
100
0.0 0.0
100. 0.00
100.00 0.00
NOTE. For the 20 results the per cent acetone in the solvent is
stated in terms of volume per cent, and the concentration of the second
solution is 10 per cent instead of 9.1 which is the concentration of the
solvent for the corresponding results at the other temperatures.
AT THE TEMPERATURE 40 AND FOR CONCENTRATIONS OF ACETONE
BETWEEN 20 AND 80 PER CENT THE SATURATED SOLUTION SEPAR-
ATES INTO Two LAYERS HAVING THE FOLLOWING COMPOSITIONS:
Upper Layer.
Grams per 100 Grams Solution.
HjjO.
(CH 3 ) 2 CO.
KCl.
55- 2
31.82
12.99
53-27
35-44
ii .29
5*- 2 3
48.50
10.27
50-3 +
39.88
9-77
48.02
43.18
8.79
46.49
45-34
8.17
5 8 -99
25.24
15-77
Lower Layer.
Grams per 100 Grams Solution.
H 2 O.
(CH 3 ) 2 CO.
KCl.
28.14
69.42
2-44
30.96
6 5-97
3-07
32.64
63-79
3-56
34-07
62 .01
3-92
37-44
57-67
4.89
38.68
56-I7
5-25
23.66
74.91
i-43
TOO cc. sat. solution of potassium chloride in furfurol (C 4 H 3 O.COH)
contain 0.085 g m - KCl at 25.
(Walden Z. physik. Ch. 55, 713, '06.)
POTASSIUM CHLORIDE
248
SOLUBILITY OF POTASSIUM CHLORIDE IN AQUEOUS SOLUTIONS OP
GLYCERINE AT 25.
(Herz and Knoch Z. anorg. Ch. 45, 267, '05.)
Sp. Gr. of Glycerine at 2 5 /4 = 1.2555. Impurity about 1.5%.
Wt. per cent
Glycerine in
Solvent.
13.28
25.98
4S-36
KC1 per 100 cc.
Solution.
Sp. Gr. of
Solutions.
I.lSo
1.185
I.I94
I. 211
Wt. per cent K.C1 per 100 cc.
Glycerine in Solution
Sp. Gr. of
Solutions.
I .219
1.259
1.286
Millimols. Grams.
424.5 31.66
383.4 28.61
339-3 25.31
271.4 20-24
Solvent. Millimols. Grams.
54.23 238.5 17.79
83.84 149.0 I I. I I
100.00 no. 6 8.25
ioo grams H 2 O dissolve 246.5 grams sugar + 44.8 grams KC1 at
31.25, or ioo grams of the sat. solution contain 62.28 grams sugar
+ 11.33 grams KC1.
(Kohler Z. Ver, Zuckerind. 47, 447, '97.)
POTASSIUM CHROMATE K 2 CrO 4 .
POTASSIUM (Di) CHEOMATE K 2 Cr 2 O 7 .
SOLUBILITY OF EACH IN WATER.
(Alluard Compt. rend. 59, 500, '64; Nordenskjold and Lindstrom Pogg. Ann. 136, 314, '69;
Etard Ann. chim. phys. [7] 2, 527, '94; Kremers Pogg. Ann. 92, 497, '54; Tilden and Shenstone
Phil. Trans. 23, 1884.)
Potassium Chromate.
Grams per ioo Grams Water.
Potassium Di Chromate.
o
58.2*
10
60.0
20
61 .7
25
62.5
30
63 .4
40
65.2
50
66.8
60
68.6
70
70.4
80
72.1
90
73-9
IOO
75-6
I2 5
79.0
150
83.0
S9-3t
60.2*
61 .2
62.5
63.2
64-5
64.2
64-5
65.2
66.5
67.0
68.6
69.0
70.6
71.0
72.7
73-o
74-8
75-o
76.9
77.0
79.0
79.0
82.2
Grams per ioo Grams Water.
5*
5
7
7
12
12
16
16
20
20 .
26
27
34
37
43
47
52
58
61
70
70
82
80
97
no
145
143
205
Etard,
t Alluard.
t N. and L.
A., K., T. and S.
249
POTASSIUM CHKOMATE
SOLUBILITY OF POTASSIUM CHROMATES IN WATER AT 30.
(Schreinemaker Z. physik. Ch. 55, 83, '06.)
Composition in Wt. per cent of:
The Solution.
The Residue.
Per cent CrO 3 .
Per cent K 2 O.
Per cent CrO 3 .
Per cent K 2 O.
O
47
o.o
47.16
12.59
47-54
0-1775
34.602
10-93
37-47
I-35 1
26.602
16.482
32-532
20.584
37-I3I
39.922
I5-407
19.225
27.966
29.377
20.67
19.17
19.096
17.30
37-64
22 .6l
ii .35
7.88
17-93
3.412
25-85
7/82
43 -5 1
3.01
49-45
9.91
44.46
3-245
53-94
12.40
46.368
2.823
60.314
12-935
49-357
2-353
63.044
11.684
53-215
1.360
62.958
8.002
62-55
0.796
67.944
6.731
62.997
0.621
70.0
4.0
62.28
o.o
. . .
Solid
Phase.
KOH.2H20
KaCrO,
K 2 Cr0 4 +K 2 Cr 2 07
K 2 Cr 2 07
K 2 C r2 7 + KaCraOjo
K 2 Cr 3 10
K 2 Cr 4 O l3 +Cr0 3
CrOa
ioo gms. sat. solution in glycol C 2 H 4 (OH) 2 .H 2 O contain 1.7 gms.
K 2 CrO 4 at 15.4.
ioo gms. sat. solution in glycol C 2 H 4 (OH) 2 .H 2 O contain 6.0 gms.
7 at 14-6
(d e Coninck Bull. acad. roy. Belgique, 257, '05.)
POTASSIUM CITRATE C 3 H 4 (OH)(COOK) 3 .H 2 O.
SOLUBILITY IN WATER AND IN SATURATED SUGAR SOLUTION AT 31.25.
(Ko'hler Z. Ver. Zuckerind. 47, 447, '97.)
ioo gms. H 2 O dissolve 169.7 gms. C 6 H 5 O 7 K 3 , or ioo gms. sat. solu-
tion contain 6 1 . 1 1 gms.
ioo gms. H 2 O dissolve 198.3 gms. C C H 5 O 7 K 3 -f 303.9 gms. sugar,
or ioo gms. sat. solution contain 32.83 gms. C 6 H 5 O 7 K 3 4- 50.3 gms.
sugar.
POTASSIUM CYANATE KCNO.
SOLUBJLITY IN ALCOHOLIC MIXTURES.
(Erdmann Ber. 26, 2439, '93.)
Solvent.
80 per cent Alcohol +20 per cent Water
80 per cent Alcohol + 20 per cent Methyl Alcohol
80 per cent Alcohol + 10 per cent Acetone
Grams KCNO per
Liter Solvent at b. pt.
62
7 6
82
POTASSIUM CYANIDE KCN.
ioo gms. H 2 O dissolve 122.2 gms. KCN, or ioo gms. sat. solution
contain 55.0 gms. KCN at 103.3. (Griffiths.)
ioo gms. abs. ethyl alcohol dissolve 0.87 gm. KCN at 19.5.
ioo gms. abs. methyl alcohol dissolve 4.91 gms. KCN at 19.5.
(de Bruyn Z. physik, Ch. 10, 783, '92.)
ioo gms. glycerine dissolve 32 gms. KCN at 15.5.
POTASSIUM CYANIDES 250
POTASSIUM CHEOMOCYANIDE K 3 Cr(CN) 6 .
100 gms. H 2 O dissolve 32.33 gms. K 3 Cr(CN) 6 at 20.
(Moissan Ann. chim. phys. [6] 4, 136, '85; Christensen J. pr. Ch. [2] 31, 166/85.)
POTASSIUM CHEOMISULPHOCYANIDE K 2 Cr(SCN) 6 . 4 H 2 O.
100 gms. H 2 O dissolve 139 gms. salt.
(Karsten Ann. Suppl. 3, 170.)
POTASSIUM CARBONYL FERROOYANIDE K 3 FeCO(CN) 5 . 3 iH 2 O.
100 gms. H 2 O dissolve 148 gms. salt at 16.
(Miiller Compt. rend. 104, 992, '87.)
POTASSIUM FEKBICYANIDE K 3 Fe(CN) 6 .
POTASSIUM FEBROCYANIDE K 4 Fe(CN) 6 . 3 H 2 O.
SOLUBILITY OF EACH IN WATER.
(Wallace J. Ch. Soc. 7, 8, '85 ; Etard Ann. chim. phys. [7] 2, 526, '94; Schiff Liebig's Ann.
H3 35, '60; Michel and Krafft Ann. chim. phys. [3] 41, 478, '58; Thomsen.)
NOTE. The available determinations fall very irregularly when
plotted on cross- section paper, and the following figures, which are
averages, are therefore hardly more than rough approximations to the
true amounts. The figures under K 4 Fe(CN) 6 show the limits between
which the correct values probably lie.
Grams per 100 Gms. H 2 O. Grams per TOO Gms. H 2 O.
t .
o
10
20
25
10
K#e(CN) a . K 4 Fe(CN) 6 .
t".
40
60
80
100
IQA.d
K3Fe(CN) 6 . K4Fe(CN) G .
3 1
36
43
46
<0
r 3
20
25
28
32
2O
40
48
S7
60
66
82.6
38
S 2
66
76
70
83
89
9i
POTASSIUM FLUORIDE KF. 2 H 2 O.
100 gms. H 2 O dissolve 92.3 gms. KF, or 100 gms. sat. solution
contain 48 gms. KF at 18. Sp. Gr. of solution = 1.502.
(Mylius and Funk Ber. 30, 1718, '97.)
SOLUBILITY OP POTASSIUM FLUORIDE IN HYDROFLUORIC ACID AT 21.
(Ditte Compt. rend. 123, 1282, '96.)
Gms. per 100 Gms. H 2 O. Gms. per 100 Gms. H 2 O. Gms. per 100 Gms. H2O.
HF.
KF.
HF.
KF.
HF.
KF.'
o.o
96-3
9- 2 S
29.9
20.68
38.4
I .21
72.0
II .36
29.6
28.60
46.9
1.61
61 .0
12.50
30-5
41.98
6l.8
3-73
40.4
J 3-95
31-4
53-71
74-8
4-03
32-5
15.98
33-4
74-20
105.0
6.05
30-4
17.69
35-62
119.20
169.5
POTASSIUM FORMATE
POTASSIUM FORMATE HCOOK.
SOLUBILITY OF POTASSIUM FORMATE AND OF THE ACID SALT
IN WATER.
(Groschuff Ber. 36, 1785, 1903.)
Solid Phase : HCOOK
Solid Phase : HCOOK. HCOOH.
Gms.
HCOOK
t . per ioo
Gms.
Mols.
HCOOK
per ioo
Mols.
Gms. HCOOK Gms.
.HCOOH HCOOK
t . per ioo per ioo t.
Gms. Gms.
Gms.
HCOOK
per ioo
Gms
Mols.
HCOOH
Mol. 1
Solution.
H 2 0.
Solution.
Solution.
Solution
. HCOOK.
20
72
.8
57
4
60
4
39-o
o
36-3
3-21
4- 18
7 6
.8
7i
.0
25
6 9
.8
45- 1
19-5
38.2
2 .96
50
80
7
89
.8
50
79
.2
51.2
39-3
40.8
2.6 5
90
86
.8
141
.0
80
90
7
58.6
60
44.0
2-33
120
92
.0
247
.0
70
45-9
2.16
I4O
96
.0
511
90
52-1
1.68
157
IOO
.0
00
Sp. Gr. of sat. sol. at 18= 1.573.
NOTE. Since the acid salt is less soluble at ordinary temperatures
than the neutral salt, it can be precipitated from the solution of the
neutral salt by addition of aqueous formic acid. Proceeding in this
way an impure product is obtained, giving solubility values (expressed
in HCOOK) as shown in the last three columns above.
POTASSIUM FLUOGERMANATE K 2 GeF 6 .
SOLUBILITY IN WATER.
(Winkler; Kruss and Nilson Ber. 20, 1696, '87.)
ioo gms. H 2 O dissolve 173.98 gms.K 2 GeF 6 at 18, and 34-07 gms.
at 100 (W. ).
ioo gms. H 2 O dissolve 184.61 gms. K 2 GeF 6 at 18, and 38.76 gms. at
100 (K. andN.).
POTASSIUM HYDROXIDE KOH.
SOLUBILITY IN WATER.
(Pickering J. Ch. Soc. 63, 908, '93; at 15, Ferchland Z. anorg. Ch. 30, 133, '02.)
Gms. KOH
t . per ioo Gms.
Solid
Til
t.
Gms
per
. KOH
TOO Gms.
Solid
Phase.
Water.
Solution.
Water. Solution.
22
7
3-
6
Ice
15
107
5 1 -
7
KOH. 2 H 2
20
7
22
5
18.
4
2O
112
S 2 -
8
"
65
.2
44 -5 30 -
8
"
30
126
55-
76
"
-36
.2
36-2
26.
6
KOH. 4 H 2 O
32-5
135
57-
44
KOH. 2 H 2 +
KOH.H 2
32
7
77
94
43-8
50
140
58.
33
KOH.H 2 O
-33
80
44-
4 KOH
, 4 H 2 0+KOH
. 2 H 2 IOO
I 7 8
64-
03
41
-23
.2
85
45-
9
KOH. 2 H 2
I2 5
2I 3
68,
06
M
o
97
49 . 2
143
3 11
7 75
73
10
103
50
7
"
Sp. Gr. of sat. solution at 15 = 1.5355.
POTASSIUM IODATE 252
POTASSIUM IODATE KIO 3 .
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 97t 5. '56; at 30, Meerburg Ch. Weekbl. I, 474, '04.)
t 20 3 40 60 80 100
Gms. KIO 3 per
100 gms. H 2 O 4.73 8.13 11.73 I2 -8 J 8-5 24.8 32.2
100 gms. H 2 O dissolve 1.3 gms. potassium hydrogen iodate(KH(IO 3 ) 2
at 15, and 5.4 gms. at 17. (Serullas Ann. chim. phys. 22, 118.)
ioo gms. H 2 O dissolve 4.0 gms. potassium di hydrogen iodate
KH 2 (IO 3 ) 2 at 1 5. (Meineke Liebig's Ann. 261, 360, '91)
POTASSIUM IODIDE KI.
SOLUBILITY IN WATER.
(Mulder; de Coppet^Ann. chim. phys. [5] 30, 417, '83; Etard Ibid. [7] 2, 526, '94; Meusser
Z. anorg. Ch. 44, 80, 05; see also lilden and Shenstone Phil. Trans. 23, '84; Schreinemaker
Z. physik. Chem. 9, 71, '92.)
Gms, KI per ioo Gms.
Gms.
KI per ioo Gms.
t ,
Water.
Solution. r
Water.
Solution.
10
II5.I
53
5
80
192
6 5 .8
- 5
II9.8
54
5
90
2OO
66.7
i
122 .2
55
.0
IOO
208
67 5
o
127-5
56
.0
no
215
68 3
10
I 3 6
57
.6
120
223
69 o
20
25
144
148
59
59
.0
7
Ice Curve
30
152
60
3
- 5
25
7
22 5
40
1 60
61
5
- 7
42
.6
29.9
50
1 68
62
7
- 9
5 5 1
5
34-o
60
176
63
7
ii
5 6 4
7
39-3
70
184
64.8
-14
75
.8
427
SOLUBILITY OF POTASSIUM IODIDE IN ABSOLUTE ALCOHOLS,
(de Bruyn Z. physik. Ch. 10, 783, '92; Rohland Z anorg. Ch. 18, 327, '98.)
ioo gms. methyl alcohol dissolve 16.5 gms. KI at 20.5.
ioo gms. ethyl alcohol dissolve 1.75 gms. KI at 20.5.
ioo gms. propyl alcohol dissolve 0.46 gm. KI at i5-2o (R.).
SOLUBILITY OF POTASSIUM IODIDE IN:
Ethyl Alcohol
of 0.9496 Sp. Gr.
Aqueous Ethyl Alcohol at 18.
*""
Gms. KI per
Sp. Gr.
Weight
Gms. KI
Sp. Gr.
Weight
Gms. KI
t.
IOO
of
per cent
per ioo Gms.
of
per cent
per ioo Gms
Gms. Alcohol
Alcohol.
Alcohol.
Alcohol.
Alcohol.
Alcohol.
Alcohol.
8
6 7 . 4
0.9904
S- 2
I30-5
0.9390
45
66.4
I 3
69.2
0.9851
9 .8
119.4
0.9088
59
48.2
25
75- 1
0.9726
23.0
IOO. I
0.8464
86
II-4
46
847
0.9665
29.0
89.9
0.8322
9i
6.2
55
87-5
0.9528
38.0
76.9
62
90.2
(Gerardin
Ann. chim. phys. [4] 5, 155, '65.)
253 POTASSIUM IODIDE
SOLUBILITY OF POTASSIUM IODIDE IN ACETONE AND IN PYRIDINE.
(von Laszcynski Ber, 27, 2285, '94; at 25, Krug and McElroy J. Anal. Ch. 6, 184, '92.)
Gms. KI per 100 Gms. Solvent at:
Solvent. ,
-2.5. 10. 22. 2 5 . S 6.
Acetone 3 .08 ... 2.38 2.93 1.21
Pyridine ... 0.26
100 gins, glycerine dissolve 40 gms. KI at 15.5.
SOLUBILITY OF POTASSIUM IODIDE IN SEVERAL SOLVENTS.
(Walden Z. physik. Ch. 55, 714, '06.)
Solvent.
Formula.
t.
Sp. Gr. of
Gms. KI per TOO
Solution.
cc. Solution.
Gms. Solution.
Water
H 2 O
o
I . 6699
94-05
5 6 -32
Water
H 2
25
I-7254
102. 70
59-54
Methyl Alcohol
CH 3 OH
o
o. 8964
II. 6l
12.95
Methyl Alcohol
CH 3 OH
25
0.9003
I3-5-I4.
3 J 4-97
Ethyl Alcohol
C 2 H 5 OH
o
0.8085
I.I97
1.479
Ethyl Alcohol
C 2 H 5 OH
25
o. 7908
1.520
1.922
Glycol
(CH,OH) 2
1-3954
43.28
31-03
Glycol
(CH 2 OH) a
25
1.3888
47-23
33-oi
Acetonitril
CH 3 CN
0.8198
1.852
2.259
Acetonitril
CH 3 CN
25
o. 7938
i-57
2.003
Propionitril
C,H 5 CN
0.8005
0.34-0.
41 0.0429
Propionitril
C,H 5 CN
25
0.7821
0.32-0.
36 0.0404
Benzonitril
C 6 H 5 CN
25
i . 0076
0.051
0.0506
Nitro Methane
CH 3 NO 2
i. 1627
0.314-0
.366 0.315
Nitro Methane
CH 3 N0 2
25
1.1367
0.289-0.349 0.307
Nitro Benzene
C 6 H 5 N0 2
25
0.0019
Acetone
(CH 3 ) 2 CO
o
0.8227
1.732
2. 105
Acetone
(CH 3 ) 2 CO
25
o. 7968
1.038
1.302
Furfurol
C 4 H 3 O.COH
. . .
15. 10
. . .
Furfurol
C 4 H 3 O.COH
25
i. 2014
5-93
4*94
Benzaldehyde
C 6 H 5 COH
25
i . 0446
o-343
0.328
Salicyl aldehyde
C 6 H 4 .OH.COH
o
i. 1501
1-257
1.093
Salicyl aldehyde
C 6 H 4 .OH.COH
25
I-I373
0-549
0.483
Anis aldehyde
C 6 H 4 .OCH 3 .COH
1.1223
1.520
1-355
Anis aldehyde
C 6 H 4 .OCH 3 .COH
25
1.1180
0.720
0.644
Ethyl Acetate
CH 3 COOC 2 H 5
25
0.0013
Methyl Cyan Acetate
CH 2 CNCOOCH 3
o
i. 1521
3-256
2.827
Methyl Cyan Acetate
CH,CNCOOCH 3
25
I-I358
2-459
2.165
Ethyl Cyan Acetate
CH 2 ~CNCOOC 2 H 5
25
1.0628
0.989
0.930
POTASSIUM NITRITE 254
POTASSIUM NITRITE KNO 2 .
100 gms. H 2 O dissolve about 300 gms. KNO 2 at 15.5.
(Divers J. Ch. Soc. 75, 86, '99.)
POTASSIUM NITRATE KNO 3 .
SOLUBILITY IN WATER.
(Mulder; Andrae J. pr. Ch. [2] 29, 456, '84; Gerardin Ann. chim. phys. [4] 5, 150, '65; Etard
Ibid. [7] 2, 526, '04; Ost J.pr. Ch.[>]i7, 233, '78; at 31-25. Kphler Z. Ver. Zuckerind. 47, 447,
'97; Euler Z. physik. Ch-49, 315, '04; Tilden and Shenstone Phil. Trans. 23, '84;Berkeley Trans.
Roy. Soc. 203 A, 213, '04.)
Average Curve.
Gms.KNO 3 per 100 Gms. Gms.KNO 3 per TOO Gms.
Water. Solution. Water. Solution.
o 13.3 11.7 70 138 58.0
10 20.9 17.3 80 169 62.8
2O 3-1 6 24.0 90 202 66.9
25 37.3 27.2 ioo 246 71.1
30 45.8 31.4 no 300 75.0
40 63.9 39.0 120 394 79.8
50 85.5 44.0 125 493 83.1
60 no.o 52.0
SOLUBILITY OF MIXTURES OF POTASSIUM NITRATE AND BARIUM
NITRATE IN WATER.
(Euler Z. physik. Ch. 49, 313, '04.)
t. Sp. Gr. of Sat. Solution. Grams per ioo Grams H 2 O.
17 1. 120 13.26 KNO 3 + 6.31 Ba(NO 3 ) 2
21.5 17.00 " + 7-58
30 1.191 24.04 + 9.99
50 49-34 +18.09
SOLUBILITY OF POTASSIUM NITRATE IN AQUEOUS SOLUTIONS OF NITRIC
ACID AT o.
(Engel Compt. rend. 104, 913, '87.)
p. Gr. of
Equivalents per 10 cc. Solution.
x
Grams per ioo cc. Solution.
1.079
12
5
KN0 3
o
HN0 3
12
65
KNO 3
O
.00
HN0 3
9
9
tt
5
.87 " '
10
.02
"
3
7i
tt
1.093
8
.28 "
13
.2
8
38
"
8
38
"
.117
7
4
ii
21
55 "
7
49
"
13
58
tt
.144
7
4
n
3 I.I 7.49
a
19
47
ii
2O2
7
.6
tt
4 8
o
7
.68
u
30
.04
n
.289
10
3
ii
68
.0 "
10
.42
tt
42
86
n
- 49 8
28
3
tt
120
5
28
.64
u
75
95
tt
255
POTASSIUM NITRATE
SOLUBILITY OF POTASSIUM NITRATE AND OF ACID POTASSIUM NITRATES
IN NITRIC ACID.
(Groschuff Ber. 37, 1490, '04.)
NOTE. Determinations made by the so-called thermometric
method, i.e., by observing the temperature of the disappearance of
the separated, finely divided solid from solutions of known concen-
tration.
t.
Grams
per 100 Gms.
Solution. Solid
Gms. per i
t . Soluti
oo Gms.
on.
Solid
TJU,.,..
KNO 3 .
HN0 3 .
KN0 3 .
HN0 3 . iliasc '
- 6
24
4
75-
41 KNO 3 .2HNO 3 (i)
22-5
47-2
5 2 -93
KNO 3 .HNO 3
+ 14
3 2.6
67.
42 " (stabil)
23-5
47-8
S 2
.11
(stabil)
17
34
8
65-
04
25-5
48.6
5 1
.46
"
19
5 37'
2
62.
90
27.0
49-4
So
.78
"
22
44-
5
55-
4 6
29.0
50.1
49
94
KN0 3 .HN0 3
21
5 47-
8
5 2 -
1 1 KN0 3 . 2 HN0 3 (2)
30-5
50-9
49
!5
(labil)
21
5 48.
6
S 1 -
46 " (labil)
21 -O
49-4
50
78
KN0 3 (labil)
20
50.
9
49-
I S
39-o
50-9
49
J 5
(stabil)
- 4
37-
2
62.
8 1 KN0 3 .HN0 3
50
51.7 48.32
-16
5 44-5
55-
46 " (labil)
C 1 )
Solution in HNO 3 .
(2) Solution
in
KN0 3 .
CONDUCT
OF
ACID POTASSIUM
NITRATE TOWARDS
WATER.
Gms. per 100 Gms.
t . Solution. .Sohd t o.
Gms. per 100 Gms.
Solution.
Solid
Phase.
KNO 3 .
HN0 3 .
KNO 3 .
HNO 3 .
22
44-
5
55-
5 KN0 3 . 2 HN0 3
5o
38.
7
48.
3
KNOg
2O
5 44-
i
55-
o
61
36.
44-
8
"
18
43-
8
54-
5
63
34-
5
43 -
12
43-
53-
6
60.5
30-
9
39-5
6
42.
3
5 2
7
56
27.
6
34-
4
"
41.
6
S 1 -
8
43
20.
8
25-
9
"
12
41.
3
S 1 -
4 KN0 3
17
ii .
7
16.
6
"
22
40.
9
S 1 -
o
-5
5-
54
6.
9 1
"
40
39-
9
49-
8
SOLUBILITY OF MIXTURES OF POTASSIUM NITRATE AND POTASSIUM
CHLORIDE IN WATER.
(Etard Ann. chim. phys. [7] 3, 283, '94; at 20, Rudorff Ber. 6, 482, '73; Nicol Phil. Mag. [5]
3it 385. '91-)
Gms. per 100 Gms.
t. Solution.
Gms. per 100 Gms.
t_ Solution.
Gms. per 100 Gm:
^o Solution.
KN0 3 . KC1.
o 5.0 20.0
10 8.0 20.8
2O 12-6 21.2
25 14.0 21-3
KN0 3 . KC1.
30 l6-O 21.2
4O 21.0 2 1 - O
50 27.0 20. o
60 33-5 19-0
KNO 3 . KC1.
7o 39-5 : 7-5
80 45-5 x 5-8
100 57.5 i i -6
120 69.0 7-7
POTASSIUM NITRATE 256
SOLUBILITY OF POTASSIUM NITRATE IN AQUEOUS SOLUTIONS OF:
(Touren Compt. rend. 131, 259, 'oo.)
Potassium Carbonate. Potassium Bi Carbonate.
Results at 14.5. Results at 14.5.
Mols. per Liter
Cms
. per Liter.
Mols. per Liter.
Grams per Liter.
K 2 C0 3
KNU 3 .
K 2 C0 3 .
KN0 3 .
KHC0 3 .
KN0 3 . KHC0 3 .
KN0 3 .
o.o
2
.228
O
O
225
O
o
2
33
o.o
236
0.48
I
85
66
4
188
O
39
2
17
39-0
2 2O
1.25
I
39
172
9
141
O
.76
2
03
76.0
205
2. 5 8
.86
356
9
87
I
.16
I
.92
116
194
3-94
.64
544
9
65
I
55
I
.81
155
183
Results at
25.
Results at
25.
o.o
3
.217
O
.0
326
.0
3
.28
o.o
332
o-59
2
.62
81
.6
265
.89
2
.84
8 9
287
i-35
I
97
186
7
199
I
33
2
65
133
268
2.IO
I
.46
290
5
148
I
.91
2
45
191
249
2.70
I
.14
373
.6
"5
3-58
79
495
.1
80
SOLUBILITY OF MIXTURES OF POTASSIUM NITRATE AND POTASSIUM
SULPHATE IN WATER.
(Euler Z. physik. Ch. 49, 313, '04.)
t. Sp. Gr. of Sat. Solution. Grams per 100 Grams Water.
15 1.165 24/12 KNO 3 " 5.65 K 2 SO 4
20 30.10 " 5.58 "
25 i. 210 36.12 5.58
SOLUBILITY OF MIXTURES OF POTASSIUM NITRATE AND SODIUM
CHLORIDE IN WATER.
(Etard Ann. chim. phys. [7] 3, 283, '94; the older determinations of Rudorff, Karsten, Mulder, etc.,
agree well with those of Etard.)
Gms. per 100 Gms.
* Solution .
t.
Gms. per 100 Gms.
Solution. t.
Gms. per 100 Gms.
Solution.
KN0 3 .
NaCl.
KN0 3 -
NaCl."
13
24
40
30.5
19
10
16
23
50
36
20
20
22
60
42-5
15
25
23
21-5
80
,55
12
30
25
20-5
IOO
67
9-5
KNO 3 . NaCl.
120 73 8.0
140 77 7.0
i 60 79.5 6.0
170 80.5 5.5
SOLUBILITY OF POTASSIUM NITRATE IN AQUEOUS SOLUTIONS OF SODIUM
NITRATE AND VICE VERSA AT 20.
(Carnelly and Thomson J. Ch. Soc. 53, 782, '88; Nicol Phil. Mag. 31, 369, '91.)
KNO 3 in Aq. NaNO 3 Solutions. NaNO 3 in Aq. KNO 3 Solutions.
Grams per 100 Grams H2O. Grams per TOO Grams H 2 O.
NaN0 3 . KN0 3 KNO 3 . ' NaNO 3 . '
o 31.6 o 88
10 30.5 10 90
20 31.0 20 92
40 33-0 25 93
6 o 35-5 30 94
80 41.0 35 96
257 POTASSIUM NITRATE
SOLUBILITY OF MIXTURES OF POTASSIUM NITRATE AND SILVER NITRATE
IN WATER.
(Etard Ann. chim. phys. [7] 3, 283, '94.)
Gms. per 100 Gms. Sol.
^ Gms. per 100 Gms. Sol.
Gms. per 100 Gms.Sol.
'
KN0 3 .
AgN0 3 .
KN0 3 .
AgNU 3 .
'
KN0 3 .
O
13-5
43
o
30
26
.8
49-4
80
36.2
55
.1
10
19.0
44
7
40
2 9
.6
51 .5
IOO
38.3
55
3
20
23.0
47
.0
50
32
.0
54-o
120
4O.O
55
.6
25
25.0
48
.0
60
33
5
54-8
140
41-5
55
.8
SOLUBILITY OF MIXED CRYSTALS OF POTASSIUM NITRATE AND SILVER
NITRATE IN WATER AT 25.
(Herz Inaug. Diss. (Berlin) '05; Calc. by Fock Z. Kryst. Min. 28, 405, '97.)
Grams
per Liter.
Mg. Mols.
per Liter.
Mol. per cent
AgN0 3 in
Solution.
Mol. per cent
AgN0 3 in
Solid Phase.
AgNOg.
KN0 3 .
AgN0 3 .
KN0 3 .
45-9
321.8
270
3 l8o
7-83
0-2896
110.7
322 .6
651 .3
3^4
16.96
o . 6006
176.8
333-7
1040
3298
23-97
o . 9040
259.6
364.0
1528
3597
29.81
1.054
365 .6
456-4
2151
4511
32.28
I .604
57-9
387.2
2988
3816
43.85
2-439
745-9
398.6
4388
3960
52.70
8.294
SOLUBILITY OF MIXED CRYSTALS OF POTASSIUM NITRATE AND THAL-
LIUM NITRATE IN WATER AT 25.
(Fock.)
Grams per Liter.
Mg. Mols.
per Liter.
Mol. per cent
TINOa
Sp. Gr.
of
Mol. per cent
T1NO 3
T1NO 3 .
KN0 3 .
T1N0 3 .
KN0 3 .
in Solution.
Solutions.
in Solid Ph;sj.
0-00
35 J -o
o.o
3468.2
o.oo
I .2632
O-OO
2-37
329.0
8.9
325I-5
o-43
I.I903
0.08
6-15
332-4
23.1
3285.1
0.70
I.I956
0-20
17.64
333-7
66.3
3298.1
1.97
I .2050
o-57
49-74
333-3
186.9
3294.4
5-37
I .2196
1.78
63.60
321.0
239.0
3*72-4
7.01
1.2436
2 .19
86.18
330-5
323-8
3265-8
9.02
I .2617
2-77
123.8
428.3
465.2
4232.6
9.90
1.2950
| 6.00
1 27.04
101.3
245.1
380.6
2423-3
I3-58
I .2050
93-33
116.1
o.o
463.1
o.o
100.00
I .0964
100-00
SOLUBILITY OF POTASSIUM NITRATE IN AQUEOUS ALCOHOL SOLUTIONS.
(Gerardin Ann. chim. phys. [4] 5, 151, '65.)
Grams KNO 3 per 100 Grams Aqueous Alcohol of Sp. Gr.:
t o
1
0.9904
0.9843
0.9793
0.9726
09571
0.939
0.8967
0.8429
wt s %.
= 13-6
Wt.%.
= 19.1
Wt.%.
=30
Wt.%.
=40
Wt.%.
= 60
Wt.%.
=90
Wt.%.
10
17
13
10
7
4-5
3
I
0-2
18
22-5
i8. 5
14.5
10
6.2
4-5
1.6
o-3
20
24
20
16
ii
7-o
5
2
o-3
25
29
24-5
20
13.5
9.0
6-5
2-5
0.4
30
36
30
25
17
ii .5
8
3-o
o-5
40
S 2
43
36
27
16.5
ii
4
0.6
50
72
61
50
38
23.0
16
6
0.7
60
93
79
69
52
31-0
21
8
i .1
POTASSIUM NITRATE 258
SOLUBILITY OF POTASSIUM NITRATE IN AQUEOUS ALCOHOL AT 18.
(Bodlander Z. physik. Ch. 7, 316, '91.)
Sp. Gr. of Gms. per 100 cc. Solution. gp. Gr. of Gms. per IOQ^CC. Solution.
Solution. C 2 H 6 OH. iSx KNO 3 . Solution. C 2 H 6 OH. ScT KNO 3 .
.1480 ... 89.80 25.0 I.OI2O 23.33 69.81 8.06
.1085 3.30 87.44 20.11 0.9935 28.11 64.74 6.50
.1010 5.24 86.26 18.60 0.9585 37.53 54-21 4.11
.0805 8.69 83.18 16.18 0.9450 42.98 48.15 3.37
0755 9- 6 8 3- J o 15-39 0.9050 51.23 27.32 1.95
.0655 14.08 77.93 14-54 0.8722 61.65 24.74 0.83
1.0490 16.27 76-36 12.27 0.8375 69.60 13-95 0-20
!-o375 J 9-97 72-93 !o-85
SOLUBILITY OF POTASSIUM NITRATE IN AQUEOUS ALCOHOL AND IN
AQUEOUS ACETONE.
(Bathrick J. Physic. Ch. i, 160, '96.)
In Aqueous Alcohol. In Aqueous Acetone at 40.
W, Percent G-f-^O-
Wt. per cent
jms. JsJNUa per 100 ^r
,x_.
ms. AQ. Aiconoi
Alcohol. '
At "*
45-6
64-5
8.2 5
32-3
47.1
17.0
22.4
33-3
25-7
^S- 1
24.1
35-o
11.4 (34-4)
16.7
44-9
7.0
11-6(44:
54-3
4-5
7-2(55:
65.0
2-7
4-4
75-6
i-3
2.0 (76.
88.0
0.4
0.6 (88.
o 64.5
8.5 51.3
16.8 38.9
25 .2 22 .8
34.3 24.7
44-i 17-0
53-9 "-9
64.8 7.2
76.0 3.0
.5) 87.6 0.7
100 grams H 2 O saturated with sugar and KNO 3 dissolve 224.7 g ms -
sugar + 41 . 9 gms. KNO 3 , or 100 gms. of the saturated solution contain
61.36 gms. sugar + 11.45 g ms - KNO 3 at 31.25.
(Kohler Z. Ver Zuckerind. 47, 447, '97.)
POTASSIUM OXALATE K 2 C 2 O 4 .4H 2 O.
SOLUBILITY OF MIXTURES OF POTASSIUM OXALATE AND OXALIC ACID
IN WATER AT 25.
(Foote and Andrew Am. Ch. J. 34, 155, '05.)
Gms. per 100 Gms. Solution. Mols. per 100 Mols. H 2 O.
'H 2 C 2 4 . * K 2 C 20 ;. 'H 2 C 2 4 . ' K 2 C 2 4 : Solid Phase.
10-2 ... 2.274 ... Hj!C 2 O 4 .2H 2 O
10.31 O.O4 2.302 O-CO 1 ? H 2 C 2 O 4 .2H 2 O + H3K(C 2 O 4 )2-2H 2 O
2.046 0.016 DoublesaltH3 K(C 2 4 ) 2 . 2 H 2
3-39 - 6 3 0.707 0.071
2.o6 4.26 O - 440 O . 49 5 H 3 K(C 2 O 4 ) -2H 2 O + HKC 2 O 4
I.I6 11.50 0.266 1.42 7 { DoublesaltH KC 2 0,
0.99 io-93 0.240 2.235 *
0.85 2 1. 08 0.221 2.928 HKC 2 4 + H 2 K 4 (C 2 04) 3 .2H 2
0.82 21-49 0.2II 2.998 "]
0.64 23.52 O.I 69 3-3^1 [ Double salt H 2 K4(C 2 O 4 )3.2H 2 O
0.57 24.88 0.153 3.617 j
-43 2 7'5 2 0.122 4.14 H 2 K 4 (C 2 4 ) 3 .2
27.40 ... 4.09 K 2 C 2 4 .H 2
259
POTASSIUM OXALATE
SOLUBILITY OF POTASSIUM OXALATE AND ACID POTASSIUM OXALATE IN
WATER.
(Alluard; results at o, Engel Ann. chim. phys. [6] 13, 362, '88.)
ioo gms. H 2 O dissolve 25.24 gms. K 2 C 2 O 4 , or 100 gms. of sat. solu-
tion contain 20.62 gms. K 2 C 2 O 4 at o. Sp. Gr. of solution = 1.161.
Acid Oxalate in Solutions of Neutral Oxalate at o.
Acid Oxalate in Water
H 2 SO 4 Corre-
sponding to K
in 10 cc. Sol.
n KOH Corre-
sponding to Free
Acid in 10 cc.
Sp. Gr. of
Solutions.
Gms.
TOO CC
per
t .
Gms. KHC 2 4
per ioo Gms.
K 2 C 2 4 .
H 2 C 2 6 4 . n2U -
28.
5
0-4
I .
164
23
53
o,
18
O
2
.2
10.
8
0.925
8
.91
O
,41
10
3
.1
6,
8
1-075
I
042
5
.61
O
,48
20
5
.2
4-
78
1.25
I ,
031
3
94
O
56
40
10
5
3-
83
i-45
I
025
3
.16
O
65
60
20
5
3-
35
I
,022
2
.76
.68
80
34
7
2 .
6(1)
1-85
I
.Ol8
2
83
IOO
5 1
5
2.
o (2)
2.25
I
.007
I
65
I
.00
o.
45(3)
1.25
I
004
O
37
O
56
(i) Sat. with acid potassium oxalate.
(2) Sat. with both acid oxalate and tetroxalate.
(3) Sat. with tetroxalate.
POTASSIUM PERMANGANATE KMnO 4 .
SOLUBILITY IN WATER.
(Baxter, Boylston, and Hubbard J. Am. Ch. Soc. 28, 1343, '06 ; Patterson Ibid. 28, 1735, '06.)
Grams KMnO 4 per ioo :
Grams KMnO 4 per ioo :
Gms. Solution
. Gms. H 2 O
. cc. Solution (P).
Gms. Solution.
Gms. H 2 0.
O
2-75
2.83
2.84
34-8
9.64
10.67
9-8
4-13
4.31
. . .
40
II .l6
12.56
15.0
5.22
45
12-73
14.58
19.8
S-9 6
6-34
50
14-45
16.89
24.8
7 .06
7 59
. . .
55
16.20
19-33
29.8
8.28
9-03
8.69
65
20.02
25-03
Sp. Gr. of saturated solution at 15 = 1-035.
SOLUBILITY OF POTASSIUM PERMANGANATE IN:
Water. Aqueous Acetone Solutions at 13
(Voerman Chem. Centrb. 77, I, 125, '06.)
(Herz and Knoch Z. anorg. Ch. 41, 317 '04.)
t.
Gms. KMnO 4 per
ioo Gms. Solid
cc. Acetone KMnO 4 per ioo cc.
oer ioo cc. Solution.
Solution.
Water.
Solvent.
Millimols.
Grams.
0.18
0-58
0.58 Ice
148.5
4.70
- 0.27
o-99
1. 01
10
l62 .2
S'*3
- 0.48
1.98
2.02
2O
177-3
5.61
- 0.58
2 .91
3 OO Ice + KMnO 4
30
208.2
6-59
+ 10- O
4.01
4-22 KMnO 4
40
257-4
8.14
15
4-95
5-20
50
289.7
9.16
25
7.00
7-53
60
316.8
IO-O2
40
10.40
ii. 61
70
328.0
10.38
50
14-35
16.75
80
3 I2 -5
9.89
9
227 .0
7.18
IOO
67.0
fl.14
POTASSIUM PERMAN- 260
6ANATE
SOLUBILITY OF MIXED CRYSTALS OP POTASSIUM PERMANGANATE AND
POTASSIUM PERCHLORATE AT 7.
(Muthmann and Kuntze Z. Kryst. Min. 23, 368, '94; recalculated by Fock Ibid. 28, 402, '97.)
Mol. per cent
Milligram Mols. per Liter. Grams per Liter. KMnO 4 in
KMnO 4 . KC1O 3 . ' KMnO 4 . KC1O 4 . " Crystals of Solid
o.o 63.91 o.oo 8.86 o.oo
29-37 54-48 4.65 7.55 2.84
67.73 42-75 10.71 5.93 9-78
79-04 39-59 12-50 5-49 J o-8i
99.81 38.63 15.79 5.36 15.96
122.24 34-39 19-34 4-77 23.56 -
119.21 38-91 18.84 5-39 24.28
128.08 33-77 20.26 4.68 26.40
144.46 33.14 22.86 4.59 34.32
167.81 29.53 26.55 4-09 44-42
183.09 25.19 28.97 3.49 67.33
197.82 20.16 3 I -3 2.80 77-95
233.75 28.26 36.98 3.92 94.37
264.27 o.oo 41.81 o.oo 100.00
SOLUBILITY OF MIXED CRYSTALS OF POTASSIUM PERMANGANATE AND
RUBIDIUM PERMANGANATE AT 7.
(Muthmann and Kuntze, calc. by Fock.)
Milligram Mols. per Liter. Grams rjer Liter. KMnO 4 in
KMn0 4 . RbMn0 4 . KMnO 4 - RbMnO 4 '. Crystals of Solid
Phase.
27.04 22.69 4.28 4.64 3.50
75-00 22.22 11.84 4-54 13-75
120.26 31-29 J 9-o3 6.40 34-29
188.30 38.98 29-80 7.97 71.45
198.36 41.29 31.39 8.44 92.50
205.76 42-50 32 .56 8.69 99-47
225.12 26.00 35.61 5.32 99-3 2
264.27 o.oo 41.81 o.oo 100.00
POTASSIUM PHOSPHATE KH 2 PO 4 (Monobasic).
One liter aqueous solution contains 249.9 grams at 7.
(Muthmann and Kuntze.)
POTASSIUM HYPOPHOSPHATE, etc.
SOLUBILITY IN WATER.
(Salzer Liebig's Ann. 211, i, 82.)
Gms. Salt per 100
. Salt. Formula. Gms. H 2 O.
Cold! Hot.
Potassium Hypophosphate K 4 P 2 O 6 .8H 2 O 400
Hydrogen Hypophosphate K 3 HP 2 O 6 .3H 2 O 200
Di Hydrogen Hypophosphate K 2 H 2 P 2 O 6 .3H 2 O 33 100
Tri Hydrogen Hypophosphate KH 3 P 2 O 6 66.6 200
Penta Hydrogen Hypophosphate K 3 H 5 (P 2 O 6 ) 2 . 2H 2 O 40 125
Hydrogen Phosphite KH 2 PO 3 172 (20) . . .
Hypophosphite KH 2 PO 2 200 (25) 333
Hypophosphite KH 2 PO 2 * 14.3(25) 28
* Solvent alcohol.
2 6i POTASSIUM PHOSPHO-
MOLYBDATE
POTASSIUM PHOSPHOMOLYBDATE K 3 PO 4 .nMoO 3 .iiH 2 O.
100 gms. H 2 O dissolve 0.007 g ms - at 30.
100 gms. aqueous 10 % HNO 3 dissolve 0.204 gms. at 30.
(Donk Proc. Assoc. Official Agrl. Chemists Bull. No. 90, Bureau of Chemistry,
U. S. Dept. of Agr., '05.)
POTASSIUM SELINATE K 2 SeO 4 .
SOLUBILITY IN WATER.
t. -20. -5. +5. 18. 97.
Gms. K 2 SeO 4 per 100 gms. solution 51-5 51-7 52.0 52.6 54.9
(Etard Ann. Chim. phys. [7] 2, 550, '94.)
POTASSIUM STANNATE K 2 SnO 3 .3H 2 O.
100 gms. H 2 O dissolve 106.6 gms. at 10, and 110.5 g ms - a "t 20.
Sp. Gr. at 10 = 1.618 at 20 = 1.627.
(Ordway Am. J. Sci. [2] 40, 173, '65.)
POTASSIUM SULPHATE K 2 SO 4 .
SOLUBILITY IN WATER.
(Mulder; Andrae J. pr. Ch. 29,456, '84; Trevor Z. physik. Ch. 7, 468, 91; Tildenand Shenstone
- Phil. Trans. 31, '84; Berkeley Trans. Roy. Soc. 203 A, 209, '04; see also Etard Ann. chim. phys.
17J 2, 549. '94-)
Gms.K 2 SO 4 per looGms. A0 Gms. K 2 SO 4 per TOO Gms.
Gms. K 2 SO 4 per loo Gms.
'
Water.
Solution.
Water.
Solution.
'
Water.
Solution.
O
7-35
6
85
40
14
.76
12
.86
90
22.8
18.57
10
9-22
8
44
5
16
50
14
16
IOO
24.1
19.42
20
II .11
10
.00
60
18
17
15
38
I2O
26.5
20-94
25
12 .04
10
75
70
19
75
16
49
143
28.8
22.36
30
12-97
ii
.48
80
21
4
i7
6 3
170
32-9
24.76
Sp. Gr. of solution saturated at 18 = 1.083.
SOLUBILITY OF POTASSIUM SULPHATE IN AQUEOUS AMMONIA
SOLUTIONS AT 20.
(Girard Bull. soc. chim. [2] 43, 552, '85.)
Gms. NH 3 per zoo cc. solution o 6.086 15.37 24.69 31.02
Gms. K 2 SO 4 per loo cc. solution 10.80 4.10 0.83 0.14 0.04
SOLUBILITY OF MIXED CRYSTALS OF POTASSIUM SULPHATE AND
AMMONIUM SULPHATE AT 25.
(Fock Z. Kryst. Man. 28, 375, '97.)
Grams per Liter.
Milligram Mols. per Liter.
Mol. per cent
K 2 S0 4 in
Solution.
Sp. Gr.
of
Solution.
Mol. per cent
K 2 SO 4 in
Solid Phase.
K 2 SO 4 .
(NH 4 ) 2 S0 4 .
K 2 S0 4 .
(NH 4 ) 2 S0 4 .
127.9
O-O
734
o.o
IOO
1. 086
IOO
135-7
115-7
778.5
874-6
47-1
I.I49
91.28
84.20
281.1
483
2126
18.5
I .2OO
80.05
59.28
355-o
340
2685
11.13
I .226
68.63
40.27
482-7
2 3 I
3650
5-98
I .246
27-53
o.oo
542-3
O-O
4100
o.oo
1.245
o.oo
Results are also given for 14, 15, 16, 30, 46, and 47.
POTASSIUM SULPHATE 262
SOLUBILITY OF MIXED CRYSTALS OF POTASSIUM COPPER SULPHATE
AND AMMONIUM COPPER SULPHATE IN WATER.
CuSO 4 .K 2 SO 4 .6H 2 O and CuSO 4 (NH 4 ) 2 SO 4 .6H 2 O at i3-i4.
(Fock.)
Mols. per 100 Mols. H 2 O Mol. per cent K Salt Mols. per icy Mols. H 2 O Mol. per cent K Salt
K. Salt. NH 4 Salt, in Solution, in Solid. K Salt. NH 4 Salt, in Solution. in Solid.
o-oo 1-035 o- 00 - 0.2946 0.5096 36.63 58.20
0.0897 0.8618 5.06 10.34 0.3339 0.3319 50.15 75.34
0.2269 0.6490 16.76 33-05 0.4560 0.1961 69.93 83.86
0.2570 0.5887 30.40 46.22 0.4374 o.oo 100.00 100.00
SOLUBILITY OF SOME POTASSIUM DOUBLE SULPHATES IN
WATER AT 25.
(Locke Am. Ch. J. 27, 459, '01.)
Double Salt. Formula. p^T^Gms? 1
Potassium Cobalt Sulphate K 2 CO(SO 4 ) 2 .6H 2 O ' 12.88
Copper " K 2 Cu(SO 4 ) 2 .6H 2 O 11.69
Nickel " K 2 Ni(SO 4 ),.6H 2 O 6.88
" Zinc " K 2 Zn(SO 4 ) 2 .6H 2 O 13.19
SOLUBILITY OF POTASSIUM NICKEL SULPHATE AND ALSO OF POTASSIUM
ZINC SULPHATE IN WATER AT DIFFERENT TEMPERATURES.
Grams per 100 Gms. H 2 O. Grams per 100 Grams H^.
*- ' K 2 Ni(SO 4 ) 2 K 2 Zn(SO 4 ) 2 * t0 - 'K 2 Ni(SO 4 ) 2 K 2 Zn(SO 4 ) 2
.6H 2 O. .6H 2 O. .6H 2 O. .6HO 2 .
o 6 13 40 23 45
10 9 19 50 28 56
20 14 26 60 35 72
25 16 30 70 43 88
3o 18 35
SOLUBILITY OF THE THREE HYDRATES OF POTASSIUM FERRO SULPHATE
IN WATER AT DIFFERENT TEMPERATURES.
(Kuster and Thiel Z. anorg. Ch. 21, 116, '99.)
K 2 S04.FeSp 4 .6H 2 0. K 2 SO 4 .FeSO 4 .4H 2 O. K 2 SO4.FeSO 4 .2H 2 O.
t. cc.N/ioKMnO 4 Gms. K 2 SO 4 cc.N/ioKMnO 4 Gms.K 2 SO 4 cc.N/io KMnO 4 Gms. K 2 SO'
per 2cc.
Solution.
-FeSO 4 per
100 cc. Sol.
per 2 cc.
Solution.
.FeSO 4 per
100 cc. Sol.
per 2 cc.
Solution.
.FeS0 4 per
100 cc. Sol.
o-5
12-4
18.36
*5-5
22.94
15-4
22-79
17.2
17.0
25 .16
18.1
26.79
21 .6
31.98
40.1
24-8
36.72
21 .9
32.41
2 7 .6
40.86
60
29.0
42-93
24.1
35-68
28.8
42.63
80
30.6
45-29
27-3
40.46
28.6
42-34
90
29.6
43-82
28.9
42-73
95
29.8
44.11
27.7
41 .01
263
POTASSIUM SULPHATE
SOLUBILITY OF POTASSIUM SULPHATE IN AQUEOUS SOLUTIONS OP
POTASSIUM CHLORIDE, BROMIDE, AND IODIDE.
(Blarez Com pt. rend. 112, 939, '91.)
Interpolated from the original results.
Grams Halogen
Salt per 100
cc. Solution.
O
2
4
6
8
10
12
Grams K.2SO4 per 100 cc. in Aq.
Solutions of:
KC1
KBr
KI
at 12.5.
at 14.
at 12.5.
9-9
10. 16
9-9
8-3
9.1
9.2
7.0
8.2
8.4
5-7
7-4
7-7
4.6
6.6
7.2
3-5
6.0
6.6
5-5
6.0
SOLUBILITY OF MIXED CRYSTALS OF POTASSIUM SULPHATE AND
POTASSIUM CHROMATE AT 25.
(Fock Z. Kryst. Min. 28, 379, '97.)
Milligram Mols. per Liter
Grams per Liter.
Mol. pe
K 2 SC
r cent Sp. Gr. Mol. per
~>. in of TC^O.
cent
in
' K2S0 4 . K 2 Cr0 4 .
K 2 S0 4 .
K 2 CrO 4 .
Solution. Solution. Solid P
iase.
618.1
o
.0
107
7
O
.00
100
.O 1-083
IOO
O
608.4
103
106
.0
2O
.02
85
5 1 i
.092
99
65
341.0
691
.8
59
.46
134
5
33
.01 I
.141
97
30
174-8
1496
.0
30
47
290
5
10
.50 I
.231
9 1
97
110.7
2523
19
30
490
5
4
2i i-35 6
28
43
100-6
2687
17
54
522
3
3
.60 1.377
2
.41
o.o
2847
o
o
553
5
.00 1.398
O
.00
734-o
o
.0
127.9
o
.0
100
.0 1.0863
IOO
o
617.0
103
4
107
.6
20
.1
85
.65 1-0934
99
.78
463
452
7
80
.72
88
.0
55
55
I2 35
98
49
279
948
.2
48
.64
184
4
22
.72
.1700
96
.07
153
1469
26
.68
285
.6
9
.41
2255
85
77
296
2681
5 1
.61
521
.2
21
.09
.3688
25
73
o.o
2715
o
.00
527
.8
O
.00
378i
o
.00
SOLUBILITY OF POTASSIUM SODIUM SULPHATES IN WATER.
Double Salt.
3 K 2 S0 4 .Na 2 S0 4
5K 2 SO 4 .Na 2 SO 4
4.4
12.7
IOO.O
Cms. per 100
Cms. H 2 O.
40.8
9 .2
10. 1
25.0
Authority.
(Penny Phil. Mag. [4] 10, 401, '55.)
(Gladstone J. Ch. Soc. 6, n, '54-)
POTASSIUM SULPHATE 264
SOLUBILITY OF POTASSIUM SULPHATE IN AQUEOUS ALCOHOL.
(Gerardin Ann. chim. phys. [4] 5, 147. '65; Schiff Liebig's Ann. 118, 362, '61.)
In Aq. Alcohol of 0.939 I n Alcohol of Different
Sp. Gr.= 4o Wt. %. Strengths at 15.
Cms. K 2 SO 4 Weight Cms. K 2 SO 4
t. per 100 Gms. per cent per 100 Gms.
Alcohol. Alcohol. Sat. Sol.
40 0.16 10 3.90
80 O.2I 2O 1.46
60 0.92 30 0.56
40 O.2I
ioo gms. glycerine of 1.255 Sp. Gr. dissolve 1.316 gms. K 2 SO 4 at ord.
temp. (Vogel Neues Report, Pharm. 16, 557 '67.)
SOLUBILITY OF POTASSIUM SULPHATE. IN AQUEOUS ACETIC ACID AND
IN AQUEOUS PHENOL SOLUTIONS AT 25.
(Rothmund and Wilsmore Z. physik. Ch. 40, 619, '02.)
In Aq. Acetic Acid.
Mols. p^er Liter. Grams per Liter.
In Aq. Phenol.
Mols. per Liter. Grams per Liter.
CH 3 COOH.
K 2 S0 4 .
CHgCOOH
. K 2 S0 4 .
CeHsOH.
K 2 S0 4 .
C H 5 OH.
K 2 S0 4 .
o.
0-6714
O
.0
117.0
O
O
O
.6714
0.0
II7.0
o.
07
0.6619
4
.2
115.4
O
.032
.6598
3-01
II5.0
o.
137
0-6559
8
.22
114.4
O
.064
.6502
6. 02
IJ 3-3
o.
328
0.6350
J 9
.68
no. 8
.127
o
.6310
11.94
no.o
o.
578
0.6097
34
.68
106.3
.236
o
.6042
22.19
J 5-3
I.
151
o-SSS 6
69
.06
96.87
o
.308
5834
28.97
101 .7
2 .
183
0-4743
128
58
82.70
.409
o
5572
38.46
97.2
o.
464
o
.5480
43-63
95-5
0.498 (sat.) 0.5377 46.82 93.8
ioo grams water dissolve 10.4 grams K 2 SO 4 + 219.0 grams sugar at
31.25, or ioo grams sat. solution contain 3.18 grams K 2 SO 4 4- 66.74
grams SUgar. (Kohler Z. Ver. Zuckerind. 47, 447, '97.)
POTASSIUM ACID SULPHATE KHSO 4 .
SOLUBILITY IN WATER.
(Kremers Liebig's Ann. 92, 497, '54.)
t 20 40 100
Gms. KHSO 4 per ioo gms. H 2 O 36.3 51.4 67.3 121.6
POTASSIUM PERSULPHATE K 2 S 2 O 8 .
ioo gms. H 2 O dissolve 1.77 gms. K 2 S 2 O 8 at o.
(Marshall J. Ch. Soc. 59, 77 1, '91.)
POTASSIUM SODIUM THIOSULPHATE KNaS 2 O 3 .2H 2 O.
POTASSIUM SODIUM HYDROGEN SULPHITE KNa 2 H(SO 3 ) 2 .
4 H 2 0.
ioo grams H 2 O dissolve 213.7 grams KNaS 2 O 3 .2H 2 O (a) at 15.
ioo grams H 2 O dissolve 205.3 g rams KNaS 2 O 3 .2H 2 O (6) at 15.
ioo grams H 2 O dissolve 69.0 grams KNa 2 H(SO 3 ) 2 .4H 2 O at 15.
(Schwicker Ber. 22, i73i '89.)
20
265 POTASSIUM SULPHO-
CYANIDE.
POTASSIUM SULPHOCYANIDE KSCN.
100 grams H 2 O dissolve 177.2 grams K*SCN at o, and 217.0 grams at
(Rudorff Ber. 2, 68, '69.)
SOLUBILITY OF POTASSIUM SULPHOCYANIDE IN ACETONE, AMYL
ALCOHOL, ETC.
(von Laszcynski Ber. 27, 2285, '94.)
In Acetone. In Amyl Alcohol. In Ethyl Acetate. In Pyridine.
Gms. KSCN per Gms. KSCN per Gms. KSCN per Gms. KSCN per
t. 100 Gms. t. 100 Gms. t. 100 Gms. t. 100 Gms.
(CH3) 2 CO.
CeHnOH.
CH 3 COOC 2 H 6 .
C&HsN.
22
20-75
13
0.18
O
0.44
6-75
58
20-40
65
i-34
14
0.40
20
6.15
100
2.14
79
0.20
58
4-97
133-5
3-15
97
3.88
"5
3.21
POTASSIUM (Bi) TARTBATE (Mono) KHC 4 H 4 O 6 Cream of Tartar.
SOLUBILITY OF MONO POTASSIUM TARTRATE IN WATER.
(Alluard Liebig's Ann. 133, 292, '65; Roelofsen Am. Ch. J. 16, 466, '94; Blarez Compt. rend.
112, 434, '91; at 20, Magnanini Gazz. chim. ital. 31, II, 542, 'or; at 25, Noyes
Z. physik. Ch. 13, 413, '94.)
and Clement
Gms. KHCJ^Ofl
Gms.
KH
C4H 4 O
per
ioo Gms. Solution.
t.
per ioo
Gms. Solution.
o. 3 o(R.
) o
32 (A.)
o-35(B.)
40
0.96
I.
3 I-
29
10
0.37
O
.40
0.42
5
1.25
I.
8 I.
80
20
0.49
53 (M.)
0.60
60
2.
4
25
0.58
.654(N. andC.)
0.74
80
....
4-
4
30
0.69
o
.9 (A.)
0.89
IOO
6.
5
SOLUBILITY OF POTASSIUM ACID TARTRATE (KHC 4 H 4 O 6 ) IN NORMAL
SOLUTIONS OF ACIDS AT 20.
(Ostwald; Huecke J. pr. Ch. [2] 29, 49. '84-)
Purified tartrate was added in excess to normal solutions of the acids,
and after shaking clear i cc. portions of each solution were withdrawn
and titrated with approximately N/io Ba(OH) 2 solution; i cc.
normal acid requiring 10.63 cc - f the Ba(OH) 2 solution.
Acid.
Gms.
Acid
cc. N/io
Ba(OH) 2
Gms.
KHC,H 4 6 A ^
Gms. cc. N/io Gms
Acid Ba(OH) 2 KHC 4 H 4 O
per roo cc.
Solvent.
per i cc.
Solution.
per IOQCC.
Solution.
per loo cc.
Solvent.
per i cc. per ico cc
Solution. Solution'
HN0 3
6.
3 1
5
.77*
10
.21
C 2 H 5 S0 3 H
II
.0
5.01*
8.87
HC1
3.
65
5-
3 2
9
42
HO.(CH 2 ) 2 S0 3 H
12.
61
5-33
9-43
HBr
8.
10
5-
38
9-
75
C 6 H 5 S0 3 H
15-
81
5-25
9.29
HI
12.
80
5-
43
9-
61
HCOOH
4-
60
0-45
0.80
H 2 S0 4
4-
90
3-
97
7-
03
CH 3 COOH
6
00
0.27
0.48
HCH 3 SO 4
ii.
21
5-
58
12.
44
CH 2 C1COOH
9-
45
I. 01
1.79
HC 2 H 5 S0 4
12.
61
5-
4i
9-
58
C 2 H 5 COOH
7
40
o. 24
0.42
HC 3 H 7 S0 4
14-
01
5-
21
9-
22
C 3 H 7 COOH
8.
81
0.23
0.41
* The figures in this column show the amount of the Ba(OH) 2 solution in excess of that which would
have been required by the normal acid solution alone in each case, viz., 10.63 cc. They, therefore, corre-
spond to the amount of KHC^Oo dissolved in i cc. of each saturated solution, and when multiplied
by i-77give the grams of KHC^Oo per 100 cc. solution.
POTASSIUM TARTRATE.
266
SOLUBILITY OF MONO POTASSIUM TARTRATE (KHC 4 H 4 O 6 ) IN AQUEOUS
SOLUTIONS OF ELECTROLYTES AT 25.
(Noyes and Clement Z. physik. Ch. 13, 413, '94; Magnanini Gazz. chim. ital. 31, II, 542, f oi.)
Cms.
Equiv.
Cms.
per
Gm.
Equiv .
Grams
per
Electro-
per
Liter.
100 CC.
Electro-
per Liter.
100 CC.
lyte.
Electro- KHC 4
Electro-
KHC*
lyte.
Electro- KHC 4 "
Electro-
KHC 4 '
lyte.
H 4 6 .
lyte.
H40 6 .
lyte.
H40 6 .
lyte.
H40 6 .
KC1
0.025
0.0254
1.86
0.4788
CH 3 COOK
0.05
0.0410
4.91
0.7718
0.05
0.0196
3-73
0.3680
O.IO
0.0504
9.82
0.9486
O.IO
0.0133
7.46
0.2509
u
O.2O
0.0634
19.63
1.1930
0.20
0.0087
14.92
0.1636
KHSO 4 (20)
O.OI
0-0375
1.36
0.706
KC1O 3
0.025
0.0256
3.06
0.4821
u
0-02
0.0500
2.72
0-941
"
O.O5
0.0197
6.13
0.3716
O.IO
0-1597
13.62
3.006
"
O.IO
0.0138
12.26
0.2601
KHC 2 O 4 * (20) o.oi
0.0369
1.28
0.694
"
O.2O
0.0092
24.52
0.1728
0.02
0.0424
2. 5 6
0.798
KBr
O.O5
0.0197
5-95
0.3699
O.IO
0.1132
12.82
2.130
O.IO
0.0134
11.91
0.2517
HC1
0.013
0.0367
0-45
0.690
O.2O
0.0087
23.82
0.1629
"
0.025
0.0428
0.91
0.806
KI
0.05
0.0196
8.30
0-3687
0.050
0.0589
1.82
1.109
O.IO
0.0132
16.61
0.2492
NaCl
0.05
0.0376
2.92
0.708
tt
O.2O
0.0086
33- 22
0.1619
"
O.IO
0.0397
5-85
0.748
KNO 3
O.05
0.0195
5.06
0.3676
O.2O
0.0428
11.70
0.805
O.IO
0.0136
IO.I2
0-2551
NaCIO,
O.O5
0.0382
5-32
0.718
O.2O
0.0090
20.24
0.1696
O.IO
0.0405
10.65
0.763
K 2 S0 4
0.05
0.0208
4-3 6
0.3921
u
O.2O
0.0446
21.30
0.840
O.IO
0.0147
8.72
0.2769
* Acid potassium oxalate.
O.2O
O.OIOO
17.44
0.1881
SOLUBILITY OF MONO POTASSIUM TARTRATE IN AQUEOUS ALCOHOL
SOLUTIONS.
(Roelofsen Am. Ch. J. 16, 466, '94; Wenger Ibid. 14, 624, '92.)
NOTE. The original results were plotted on cross-section paper and
the following figures read from the curves.
o
10
20
25
30
40
50
Milligrams KHC 4 H 4 O6 per 10 cc. of Aq. Alcohol of;
10
20
3
40
60
so
per cent.
per cent.
per cent.
per cent.
per cent.
per cent.
17
II
7
6
6
6
22
14
8
7
6
6
29
18
ii
8
6
6
34
21
12
9-5
6-5
5-5
40
2 5
13
ii
7
5-5
55
36
19
14
7-5
5
87
55
2 9
19
8
5
POTASSIUM FLUO TITANATE K 2 TiF 6 .H 2 O.
SOLUBILITY IN WATER.
(Marignac Ann. chim. phys. [4] 8, 65, '66.)
t o 3 6 10 14 20
Cms. K 2 TiF 6 per 100 gms. H 2 O 0.55 0.67 0.77 O.QI 1.04 1.28
267 POTASSIUM VANADATB
POTASSIUM VANADATE K 3 V 5 O 14 .5H 2 O.
100 grams H 2 O dissolve 19.2 grains at 17.5.
(Radan Liebig's Ann. 251, 120, '89.)
POTASSIUM ZINC VANADATE KZnV 6 O 14 .8H 2 O.
100 grams H 2 O dissolve 0.41 gram of the salt (Radan).
PRASEODYMIUM SULPHATE Pr 2 (SO 4 ) 3 .
SOLUBILITY IN WATER.
(Muthmann and Rolig Ber. 31, 1727, '98.)
Gms. Pr 2 (SO 4 ) 3
t . per 100 Gms.
Solid
Phase. '
Gms. Pr 2 (SO 4 ) 3
per loo Gms.
Solid
DU
Solution.
Water.
Solution.
Water.
> .rnase.
I6. 5
19.8
Pr 2 (S0 4 ) 3 .8H 2 75
4-0
4.2
Pr 2 (SO 4 ) 3 .8H 2 O
18
12-3
I4-I
8 5
1-5
J -55
Pr 2 (S0 4 ) 3 .8H 2 +
35
9-4
IO-4
"
Pr 2 (S0 4 ) 3 . 5 H 2
55
6.6
7- 1
95
I .0
I .01
Pr 2 (S0 4 )3.5H20
PROPIONIO ALDEHYDE C 2 H 5 COH.
100 grams H 2 O dissolve 16 grams aldehyde at 20.
(Vaubel J. pr. Ch. 59, 30, '09.)
PROPIONITRIL C 2 H 5 CN.
SOLUBILITY IN WATER.
Synthetic method used. See Note, page 9.
(Rothmund Z. physik. Ch. 26, 474, '98.)
Wt. per cent C 2 H S CN in; Wt. per cent C 2 H 5 CN in:
* ' Aq. C 2 H 5 CN ** A^ C 2 H 5 CN
Layer. Layer. Layer. Layer.
40 10.7 92.1 95 19.6 78.0
50 ii. 6 90.5 ioo 22.4 75.5
60 12.7 88.5 105 26.0 72.1
70 13.2 86.1 no 32.0 66.5
80 14-9 83.4 113 .1 (crit. temp.) 48.3
90 17.6 80.2
PROPYL ACETATE, Butyrate and Propionate.
SOLUBILITY OF EACH IN AQUEOUS ALCOHOL MIXTURES.
(Bancroft Phys. Rev. 3, 205, '95, calc. from Pfeiffer.)
cc. H 2 O Add
ed to Cause S<
JL.
jparation * in :
cc. H 2 O Added to cause Separation* i
hoi in P. Ace-
Mixture, tate.
P. Buty-
rate.
P. Propio-
nate.
cc. Alco-
hol in
Mixture.
P. Ace- P.Buty-
tate. rate.
P, Propio-
nate.
3
4-5o
I.I9
1.58
21
58.71 19.68
27.83
6
10.48
3-55
4-70
24
00 23.72
33-75
9
17.80
6.13
8-35
30
32 .10
47-15
12
26 .00
12.54
36
41-55
63.18
15
35-63
12.31
17-15
42
51 .60
83-05
18
47-50
15.90
22.27
4 8
62 .40
107.46
54
73 85
* cc. H 2 O added to cause the separation of a second phase in mixtures of the Riven amounts of alcohol
and 3 cc. portions of propyl acetate, butyrate and propionate,
PROPYL ACETATE 268
SOLUBILITY OF PROPYL ACETATE, FORMATE, AND PROPIONATE
IN WATER.
100 cc. H 2 O dissolve 1.7 gms. propyl acetate at 22.
100 cc. H 2 O dissolve 2.1 gms. propyl formate at 22.
(Traube Her. 17, 2304, '84.)
ioo cc. H 2 O dissolve 0.6 cc. propyl propionate at 25. (Bancroft.)
PROPYL CHLORIDE, Bromide, etc.
SOLUBILITY IN WATER.
(Rex Z. physik. Ch. 55, 355, '06.)
Grams P. Compound per ioo Gms. H 2 O at:
Propyl Compound.
O . 10 . 20 . 30 .
CH 3 CH 2 CH 2 C1 (normal) 0.376 0.323 0.272 0.277
CHgCHLjCKjBr " 0.298 0.263 0.245 0.247
CH 3 CH 2 CH 2 I 0.114 0.103 0.107 0.103
(CH 3 ) 2 CHC1 (iso) o . 440 o . 363 o . 305 o . 304
(CH 3 ) 2 CHBr " 0.418 0.365 0.318 0.318
(CH 3 ) 2 CHI " 0.167 0.143 0.140 0.134
PROPYLENE C 3 H 6 . SOLUBILITY IN WATER.
(Than Liebig's Ann. 123, 187, '62.)
t. ft. q.
o 0.4465 0.0834
5 0.3493 0.06504
10 0.2796 0.0519
15 0.2366 0.0437
2O O.22O5 0-0405
For values of (3 and q, see Ethane, page 133.
PYRENE C 16 H 10
SOLUBILITY IN TOLUENE AND IN ABSOLUTE ALCOHOL.
ioo gms. toluene dissolve 16.54 gms. pyrene at 18.
ioo gms. absolute alcohol dissolve 1.37 gms. pyrene at 10 and 3.08
gms. at b. pt.
PYROGALLOL C 6 H 3 (OH) 3 i, 2, 3.
SOLUBILITY IN
(u. s
ioo gms. water dissolve 62.5 gms. C 6 H 3 (OH) 3 at 25.
SOLUBILITY IN WATER, ETC.
(u. s. P.)
ioo gms. alcohol dissolve 100.0 gms. C 6 H 3 (OH) 3 at 25.
ioo gms. ether dissolve 90.9 gms. C 6 H 3 (OH) 3 at 25.
269
QUININE
QUININE C 20 H 24 N 2 O 2 . (See also Cinchona alkaloids, p. 117.)
SOLUBILITY OF QUININE AND OF QUININE SALTS IN WATER AND
OTHER SOLVENTS.
(U. S. P.)
Grams. Quinine Compound per 100 Grams Solvent in:
Compound.
C 20 H 24 N 2 2
C 20 H 24 N 2 2 . 3 H 2
C 20 H 24 N 2 2 HC1.H 2
C 20 H, 4 .N 2 2 . 2 C 6 H 4 (OH).
COOH.H 2 O
(C 20 H 24 N 2 2 ) 2 .H 2 S0 4 . 7 H 2
C 20 H 24 N 2 2 .H 2 S0 4 . 7 H 2
C 20 H 24 N 2 2 .HBr.H 2
Water.
Alcohol.
At 25.
166.6
166.6
166.6
9.09
1.16
5-55
149.2
Ether. Chloroform.
At 25. At 25.
22.2 52.6
76.9 62.5
0.417 122. O
0.91 2.70
... 0.25
0.056 o. 109
6.2
Glycerine.
At 25.
0.633
0.472
12. 2
6.2 5
2. 7 8
5-55
12.5
At
0.
0.
5-
i.
0.
II.
2.
25-
057
06 5
55
30
i39
77
5
At 80.
0.123
o. 129
250.0
2.86
2. 22
II7.7
33-3
SOLUBILITY OF QUININE IN AQUEOUS SOLUTIONS OF CAUSTIC ALKALIES.
(Doumer and Deraux J. pharm. chim. [6] i, 50, '95.)
METHOD. A one per cent solution of quinine sulphate containing
a very small amount of HC1 was gradually added to 200 cc. portions
of the caustic alkali solutions of the various concentrations stated,
and the point noted at which a precipitate of the appearance cor-
responding to that of i cc. of milk in 100 cc. of water, remained
undissolved.
In Aq. Ammonia. In Aq. Sodium Hydrate. In Aq. Pot. Hydrate.
Gms.KOH Gms. Anhydrous
Gms.NH 3
Gms. Anhydrous
per 200 cc.
Solution.
Quinine
Dissolved.
0.52
0-084
0.65
0.084
4-59
0-096
13.08
O-I22
18.88
0.144
25.19
0.174
35-79
0.184
Gms.NaOH
per 200 cc.
Solution.
Gms. Anhydrous
Quinine
Dissolved.
0.007
O.O92
O-OI2
O.O9I
0-740
2 .l6o
3.188
6.172
8-537
0.090
0.079
0-056
O.O44
0-021
17.074
O.OI5
per 200 cc.
Solution.
0.612
1.512
10.944
44 74
Quinine
Dissolved.
0.088
O.O82
0.068
0.039
O.OO6
Salt.
Brom Hydrate (basic)
(neutral)
Chlor Hydrate (basic)
Lactate
SOLUBILITY OF QUININE SALTS IN WATER.
(Regnault and Willejean Chem. Centralb. 18, 252, '87.)
-o Gms. Salt per <; u t o
* ' iooGms.H 2 0.
2.06 Salicy late (basic) 15
Sulphate " 14
16
18
" (neutral) 15
14
12
14
16
15
12
14
15
37
12-33
13-19
14.79
14.20
3.80
4.14
4-25
10.03
16.18
18
Gms. Salt per
loo Gms. H 2 O
O.II4
0.139
o . 153
0.160
8.50
8.90
9.62
Valerate (basic) 12-162.59
RESORGINOL.
270
RESORCINOL C 6 H 4 (OH) 2 i, 3.
SOLUBILITY IN:
Water. Ethyl Alcohol.
(Speyers Am. J. Sci. [4] 14, 294, '02.) (Speyers.)
O
10
20
25
30
40
50
60
70
80
NOTE. The original results of Speyers are given in terms of
mols. per ioo mols. H 2 O.
According to Vaubel, ioo gms. H 2 O dissolve 175.5 g ms - C 6 H 4 (OH) 2
or ioo gms. sat. solution contain 63.7 gms. at 20. Sp. Gr. of sol.
= I - I 335- (J. pr. Ch. [ 2 ] 52, 73. '95-)
SOLUBILITY OF RESORCINOL IN BENZENE.
(Rothmund Z. physik. Ch. 26, 475, '98.)
Synthetic method used. See Note, p. 9.
Gms. C 6 H 4 (OH) 2 per ioo Gms.
Sp.Gr.of C
Solutions.
rms.C 6 H 4 (OH) 2 per ioo Gms.
Water.
Solution.
I .IOI
60
37-5
1.118
8l
44.8
I-I34
103
5 -7
I .142
117
53-9
1.148
56-7
I - I 57
161
58.9
1.165
198
66.5
1.172
246
71.1
i .176
320
76.2
1.179
487
82.9
Sp.Gr.of <
Solutions.
jms. CsH 4 (OH) 2 per ioo Gms.
Alcohol.
Solution.
1-033
2IO
67.8
1.036
223
69.0
I .041
236
70-3
1.045
243
70.8
I .048
250
71.4
I .056
266
72.7
1.065
286
74-1
I .075
3 11
75-7
1.087
34i
77-3
I .104
375
78.9
C 6 H 6 Layer. C 6 H 4 (OH) 2 Layer.
60 4-8 79.4
7o 6.6 77.5
80 9.2 75.0
Gms. C 6 H 4 (OH)2 per 100 Gms.
C 6 H 6 Layer. C 6 H4(OH) 2 Layer
90 13.0 71.3
ioo 19.5 65.7
105 24.6 60.7
109.3 ( cr ft- temp.) 42.4
DISTRIBUTION OF RESORCINOL BETWEEN WATER AND ORGANIC
SOLVENTS AT ORDINARY TEMPERATURE.
(Vaubel J. pr. Ch. [2] 67, 478, '03.)
Gms.
C 6 H4(OH) 2 Solvents.
Used.
i .191 60 cc. H 2 O+ 30 cc. Ether
i .191 60 cc. H 2 O+ 60 cc. Ether
0-800 40 cc. H 2 O+ 40 cc. Benzene
0.800 40 cc. H 2 O+ 80 cc. Benzene
0.500 50 cc. H 2 O+ 50 cc. CC1 4
0.500 50 cc. H 2 O+ioo cc. CC1 4
0.500 50 cc. H 2 O+i5o cc. CC1 4
Gms. C fl ]
EI 4 (OH) in:
H 2 O Layer.
0.2014
Organic
Solvent Layer.
0.9896
0.2475
0-5 8 73
0-9525
0.2127
o-5773
0.4885
0.4880
0.4880
O.2227
O.OII5
O-OI2O
O.OI2O
RHODIUM SALTS. SOLUBILITY IN WATER.
(Jorgensen J. pr. Ch. [2] 27, 433. '83; 34. 394. '86; 44, SL '91 )
Salt. Formula. t.
Chloro Purpureo Rhodium Chloride ClRh(NH 3 ) 5 Cl 2 17
Luteo Rhodium Chloride Rh(NH 3 ) 6 Cl 3 8
Luteo Rhodium Nitrate Rh(NH 3 ) 6 (NO 3 ) 3 ord. t.
Luteo Rhodium Sulphate
[Rh(NH 3 ) 6 ] 2 (S0 4 ) 3 . 5 H 2 20
Gms. per ioo
Gms. H 2 O
0.56
13-3
2. I
2-3
271 RUBIDIUM ALUM
RUBIDIUM ALUMS.
SOLUBILITY IN WATER.
(Locke Am. Ch. J. 27, 174, *oi.)
Gms. Alum oer ioo Gms. H*O.
p _ __i
t
^
Anhydrous.
Hydrated.
G. Mols.
Rb. Aluminum Alum
RbAl(SO 4 ) 2 .i2H 2 O
2 5
1.81
3-15
0.0059
.
"
3
2.19
0.0072
11
"
35
2.66
0.0087
11
"
40
3.22
0.0106
Rb. Chromium Alum
RbCr(S0 4 ) 2 .i 2 H 2
25
2 -57
4-34
o. 0079
"
"
3
. . .
o. 0096
"
"
35
4- IJ
.
0.0128
"
"
40
5-97
.
0.0181
Rb. Vanadium Alum
Rb. Iron Alum
RbV(SO 4 ) 2 .i2H 2 O
RbFe(SO 4 ) 2 .i2H 2 O
2 5
25
5-79
9-74
9-93
16.98
0.0177
0.0294
"
U
3
20. 24
0.0617
Biltz and Wilke (Z. anorg. Ch. 48, 299, '06) find for the solubility of
rubidium iron alum in water, at 6.6, 4.55 gms. per 100 cc. solution;
at 25, 29.0 gms.; and at 40, 52.6 gms.
RUBIDIUM FLUOBORIDE RbBF 4 .
100 gms. H 2 O dissolve 0.55 gm. RbBF 4 at 20, and i.o gram at 100.
(Godeffroy Ber. 9, 1337, '76.)
RUBIDIUM BROMIDE RbBr.
SOLUBILITY IN WATER.
(Rimbach Ber. 38, 1557, '05.)
Gms. RbBr per ioo Gms. Gms. RbBr per TOO Gms.
' Water. Solution. Water. Solution.
0-5 89.6 47.26 39.7 I3I-85 56.87
5.0 98.0 49-50 57-5 J 5 2 -47 60.39
16.0 104.8 S 1 - 1 ? I][ 3-5 205.21 67.24
RUBIDIUM CARBONATE Rb 2 CO 3 .
100 gms. absolute alcohol dissolve 0.74 gm. Rb 2 CO 3 .
(Bunsen.)
RUBIDIUM CHLORATE RbClO 3 .
SOLUBILITY IN WATER.
(Reissig Liebig's Ann. 127, 33, '63.)
t. 4.7. 13.0. 18.2. 19-0.
Gms. RbClO 3 per ioo grams H 2 O 2.8 3.9 4.9 5.1
RUBIDIUM (Per) CHLORATE RbClO 4 .
ioo grams H 2 O dissolve 1.08 grams RbClO 4 at 21.3.
(Longuimine Liebig's Ann. 121, 123, '62.)
RUBIDIUM CHLORIDE 272
RUBIDIUM CHLORIDE RbCl.
SOLUBILITY IN WATER.
(Rimbach Ber. 35, 1304, '02; Berkeley Trans. Roy. Soc. (Lond.) 203 A, 207, '04.)
t o Mols. RbCl Gms. RbCl per 100 Gms. Mols. RbCl Gms. RbCl per 100 Gms.
per Liter. Water. Solution. per Liter. Water. Solution.
o 5.17 77.0 43-5 60 6.90 115.5 53.6
10 5.55 84.4 45.8 70 7.12 121.4 54-8
20 5.88 91.1 47.7 80 7.33 127.2 56.0
33 6.17 97.6 49.4 90 7.52 133.1 57.1
40 6.43 103.5 5-9 I0 7-7 1 J 3 8 -9 5 8 -9
50 6.67 109.3 5 2 - 2 112.9 7.95 146.6 59.5
RUBIDIUM TELLURIUM CHLORIDE Rb 2 TeCl 6 .
100 gms. Aq. HC1 of 1.2 Sp. Gr. dissolve 0.34 gm. Rb 2 TeCl 6 at 23.
100 gms. Aq. HC1 of 1.05 Sp. Gr. dissolve 13.09 gms. Rb 2 TeCl 6 at 23.
(Wheeler Am. J. Sci. [3] 45, 267, '93-)
RUBIDIUM THALLIUM CHLORIDE 3 RbClTlCl 3 .2H 2 O.
100 gms. H 2 O dissolve 13.3 gms. at 18, and 62.5 gms. at 100.
(Godeffroy Zeit. allgem. Oster. Apoth. No. 9, '80.)
RUBIDIUM CHROMATE (Mono) Rb 2 CrO 4 .
SOLUBILITY IN WATER.
(Schreinemaker and Filippo Chem. Centralb. 77, I, 1321, '06.)
Gms. RbCrO 4
t. per loo
Gms. RbCrO 4
t. per 100
Gms. RbCrO 4
t . per too
Gms. Solution.
Gms. Solution.
Gms. Solution.
- 7
36-65
50 47-44
2 .40
I5-58
o
38-27
60 . 4 48 . 90
3 .25
20.03
10
40.23
Solid Phase, Ice
-4-14
24.28
20
42.42
0.6 6.95
-5-55
30-15
30
44.11
i.i 7 .22
-6.71
34-3 1
40
46-13
-1.57 9.87
about 7
36-65
RUBIDIUM (Di) CHROMATE Rb 2 Cr 2 O 7 .
zoo grams saturated aqueous solution contain 9.47 grams Rb 2 Cr 2 O 7
at 30.
(Schreinemaker and Filippo.)
RUBIDIUM HYDROXIDE RbOH.
loo grams sat. aqueous solution contain 63.39 grams RbOH at 30.
(Schreinemaker and Filippo.)
RUBIDIUM IODATE RbIO 3 .
loo grams H 2 O dissolve 2.1 grams RbIO 3 at 23.
(Wheeler Am. J. Sci. [3] 44, 123, '92.)
RUBIDIUM IODIDE Rbl.
loo grams H 2 O dissolve 137.5 grams Rbl at 6.9, and 152.0 grams at
J 7-4 (Reissig Liebig's Ann. 127, 33. '63.)
273 RUBIDIUM IODIDE
SOLUBILITY OF RUBIDIUM IODIDE IN ORGANIC SOLVENTS.
(Walden Z. physik. Ch. 55, 713, 718, '06.)
Solvent. Formula. Grams Rbl per TOO cc. Solution.
Acetonitril CH 3 CN 1.478 at o 1.350 at 25
Propionitril C 2 H 5 CN 0.274 " 0-305 "
Nitromethane CH 3 NO 2 0.567 " 0.518 "
Acetone (CH 3 ) 2 CO 0.960 " 0.674 "
Furfurol C 4 H 3 O.COH 4.930 "
RUBIDIUM BROM IODIDE RbBrJ.
100 gms. sat. aq. solution contain about 44.0 gms. RbBr 2 I, and
the Sp. Gr. of the solution is 3.84.
(Wells and Wheeler Am. J. Sci. [3] 43, 475, '92.)
RUBIDIUM NITRATE RbNO 3 . SOLUBILITY IN WATER.
(Berkeley Trans. Roy. Soc. (Lond.) 203 A, 207, '04.)
..
Mols.
RbN0 3 -
Per Liter.
Grams RbNOs per ioo Gms. ^
Mols. C
RbN0 3
Per Liter.
1ms. RbNOs per ioo Gms
Water.
Solution.
Water
Solution .
o
1.27
19-5
I6. 3
60
7-99
200
66.7
10
2 .04
33-o
2 4 .8
70
9.02
25 1
71-5
20
3.10
53-3
34-6
80
9-93
309
75-6
30
4-34
81.3
44.8
90
10.77
375
78.9
40
5.68
116.7
53-9
IOO
n-54
452
81.9
5
6.88
155-6
60.9
118.3
12 .76
6l 7
86.1
RUBIDIUM PERMANGANATE RbMnO 4 .
One liter of aqueous solution contains 6.03 grams RbMnO 4 at 7.
(Muthmann and Kuntze Z. Kryst. Min. 23, 3771 '94.)
ioo cc. sat. aq. solution contain 0.46 gm. RbMnO 4 at 2, 1.06 gms. at
19 and 4.68 gms. at 60. (Patterson J. Am. Ch. Soc. 28, 1735, '06.)
RUBIDIUM SELENATE Rb 2 SeO 4 .
ioo grams H 2 O dissolve 158.9 grams Rb 2 SeO 4 at 12.
(Tutton J. Ch. Soc. 71, 850, '97.)
RUBIDIUM FLUO SILICATE Rb 2 SiF 6 .
ioo gms. H 2 O dissolve 0.16 gm. Rb 2 SiF 6 at o, and 1.36 gms. at 100.
(Stolba J. pr. Ch. 101, i, '67.)
RUBIDIUM SILICO TUNGSTATE Rb 8 SiW 12 O 42 .
ioo gms. H 2 O dissolve 0.65 gm. Rb 8 SiW 12 O 42 at 20, and 5.1 gms. at
I OO. (Godeffroy Ber. 9, 1363, '76.)
RUBIDIUM SULPHATE Rb 2 SO 4 . SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 550, '94; Berkeley Trans. Roy. Soc. (Lond.) 203 A, 207, '04.)
t .
Mols. r
Rb 2 S0 4 <-
per Liter.
rms. Rb 2 SO 4
j>er ioo Gms
t.
Mols. o
Rb2SO 4 /
per Liter.
ms. Rb2SO 4 per ioo Gms.
Water.
Solution.
Water.
Solution.
o
1.27
3 6 -4
27-3
60
2-15
67.4
40-3
10
I .46
42 .6
29.9
70
2.25
71.4
41-7
20
I .64
48.2
32-5
80
2-34
75-o
42-9
30
1-79
53-5
34-9
90
2.42
78.7
44.0
40
I .92
58.5
3 6 -9
IOO
2.49
81.8
45-o
50
2.04
63.1
38-7
102.4
2.50
82.6
45-2
RUBIDIUM SULPHATE 274
SOLUBILITY OF RUBIDIUM DOUBLE SULPHATES IN WATER AT 25.
(Locke Am. Ch. J. 27, 459, '01.)
Per IPO cc. H 2 O. Per 100 cc. H 2 O.
Formula. Cms. Mols. " Formula. Cms. ' Mols. '
Anh. Salt. Salt. Anh. Salt. Salt.
Rb 2 Cd(SO 4 ) 2 .6H 2 O 76.7 0.1615 Rb 2 Mn(SO 4 ) 2 .6H 2 O 35.7 0.0857
Rb 2 Co(SO 4 ) 2 .6H 2 O 9.28 0.022 Rb 2 Mg(SO 4 ) 2 .6H 2 O 20.2 0.0521
Rb 2 Cu(SO 4 ) 2 .6H 2 O 10.28 0.0241 Rb 2 Ni(SO 4 ) 2 .6H 2 O 5.98 0.0142
Rb 2 Fe(SO 4 ) 2 .6H 2 O 24.28 0.0579 Rb 2 Zn(SO 4 ) 2 .6H 2 O 10.10 0.0236
SALICYLIC ACID C 6 H 4 .OH.COOH i :2.
SOLUBILITY IN WATER. (See also p. 61.)
Ibid. 27, 315, '98; Hoffmann and Langbeck Ibid. 51, 400, '05. For determinations not in good agreement
with the following, see Alexejew Ann. Physik. Chem. 28, 305, '86; Bourgion Ann. chim. phys. [5]
iSs 165, '78; Ost. J. pr. Ch. [2] 17, 232, '78.)
Gms.
h o CeH^OHCOOH
per
Gms.
t o C 6 H 4 OH.COOH
per
Gms.
fc0 C 6 H 4 OH.COOH
oer
Liter Solution.
Liter Solution.
Liter Solution.
0.8
25
2 .2
60
8.2
10
I .2
3
2-7
70
I 3 .2
20
1.8
40
3-7
80
20-5
5o
5-4
SOLUBILITY OF SALICYLIC ACID (LIQUID) IN WATER.
(Alexejew.)
Determinations by Synthetic Method. See Note, page 9. Figures
read from curve.
Gms. C H 4 OHCOOH
per 100 Gms.
t. Aqueous Salicylic Acid
Layer. Layer.
60 7 68
70 8 64
80 12 58
90 19 49
95 (crit. temp.) 32
SOLUBILITY OF SALICYLIC ACID IN AQUEOUS SALT SOLUTIONS AT 25
AND AT 35.
(Hoffmann and Langbeck Z. physik. Ch. 51, 407, '05.)
Normalit
Salt.
KC1
tt
KN0 3
a
it
tt
NaCl
a
u
It
Normality
of Salt
Gms.
Salt per
V^fVL-L^Vyi-lV-V/W 11 *
dissolved at 25.
dissolved' at 35.
Solution.
Liter.
Gms. per 1000 G. Molecular Gms. p
er 1000
G. Molecular
gms. Sat. Sol.
percentage, gms. S
iat. Sol.
percentage.
0.0
O.O
2
.206
2
8851
3
.197
O.O2O
1.49
2
.24
2
.9216.
io~ 4
3
23
4
.22o6.I<
_-
o.ioo
7.46
2
25
2
9377
it
3
23
4
.2203
"
0.492
36.73
2
.02
2
.6321
a
3
.01
3
.9268
a
1 .004
74-92
I
.89
2
4759
tt
2
.68
3
5003
tt
O.02O
2 .02
2
25
3
935 1
tt
3
25
4
2499
it
o .100
IO-I2
2
30
3
0103
it
3
32
4
3334
"
0.504
51.10
2
38
3
.1061
a
3
38
4
.4123
it
I .004
101 .60
2
39
3
.1249
n
3
36
4
3848
tt
O.020
I.I9
2
23
2
.9110
tt
3
.22
4
.2062
it
O.IOO
5-95
2
.22
2
.9027
tt
3
.20
4
.1806
tt
0-497
29.50
2
OO
2
.6128
tt
2
85
3
.7171
"
0.988
58.80
I
.72
2
.2487
n
2
43
3
.1596
"
275
SALICYLIC ACID
SOLUBILITY OF SALICYLIC ACID IN AQUEOUS SOLUTIONS OF SODIUM
FORMATE, ACETATE, AND BUTYRATE AT 26.4.
(Philip J. Ch. Soc. 87, 992, '05.)
Mols - Na SaIt ^^C 6 H 4 .OH.COOH per Liter in: Cms Na Cms. Ce^OHCOOH per Liter in:
ioo
perLiter -
ioo - -
HCOONa. CH 3 COONa. C
I.7I 1.71
1.71
2-35 2.47
3-05 3-35
2.50
3-48
3-7 4-2
4-35
4-3 5- 1
4.8 6.1
5-3
6-3
'HCOONa. CH 3 COONa. C 3 H 7 COONa
2.36 2.36 2.36
3-7 3-6
5-o 5-2
6.2 6.75
7-2 8.3
3-3
45
5-65
6.85
8.1
SOLUBILITY OF SALICYLIC ACID IN AQUEOUS SOLUTIONS OF SODIUM
SALICYLATE AT 20.1.
(Hoitsema Z. physik. Ch. 27, 315, '98.)
Solid
Phase.
C^OHCOOH
Gram Mols
. per Liter.
Sp. Gr.
Grams
per Liter.
C 6 H 4 OH
COOH.
C 6 H 4 OH
COONa.
of
Solutions.
C 6 H 4 OH
COOH.
CeH 4 OH
COONa.
0.0132
O
I .OO2
1.823
O-O
O-OII2
0.017
1.003
i-55
2.705
0-0124
O.II3
I .009
1.71
17.98
0-0143
0.226
I .Ol6
1.97
35-96
O.Ol64
0-344
I .024
2 .26
54-74
O.O2O3
0.500
I .034
2.80
79 -5 6
0.062
1.70
1.098
8.56
270.5
0-095
2 .11
I-I37
13.11
335-7 {
0.091
2 .19
I.I44
12-56
348-4
0.086
3-41
I .215
11.88
542.6
O.oSl
4-23
1.263
ii .19
673 -o{ C
O.O48
4-l8 J
1.259
6.63
665.1
O-02I
4-12
1.258
2 .90
665-5
O-OO
4-15
1-257
O-O
660.3
( C 6 H4OHCOOH.C 6 H 4 OHCOONa
+ C 6 H 4 OHCOOH
C 6 H 4 OHCOOH.C 6 H 4 OHCOONa
C 6 H 4 OHCOOH.C 6 H 4 OHCOONa
+ C 6 H 4 OHCOONa
Ce^QHCOONa
SOLUBILITY OF SALICYLIC ACID IN ALCOHOLS IN ETHER AND IN
ACETONE.
(Timofeiew Compt. rend. 112. 1137, '91; at 15. Bourgoin Ann. chim. phys. [5] 13, 405, '?8;
at 17 and 23, Walker and Wood J. Ch. Soc. 73, 620, '98.)
Solvent.
t .
Gms. CH 4 OHCOOH
per ioo Gms.
Solvent.
Gms. CCR.OHCOOH
t _ per ioo Gms.
Solvent.
Solution.
Solvent. Solution.
CH 3 OH
-3
40.
67
28.
9 1
C 3 H 7 OH()
~3
26
. 12
20
7i
CH 3 OH
+ 21
62.
48
38.
46
C 3 H 7 OH()
+ 21
37-
69
27.
36
C 2 H 5 OH
~3
36.
12
26.
29
(CH 3 ) 2
15
5-
47
33
55
C 2 H 5 OH
63
33-
17
(CH,) 2
17
23
4*
C 2 H 5 OH
21
53-
53
34.87
(CH 3 ) 2 CO
23
3 1
3*
C,H,OH 90%
IS
42.
09
29.
62
* Per
ioo cc. Sat
. Solution.
SALICYLIC ACID 276
SOLUBILITY OF SALICYLIC ACID IN AQUEOUS SOLUTIONS OF ETHYL
ALCOHOL, .Iso BUTYL ALCOHOL, DEXTROSE, CANE SUGAR, AND OF
LEVULOSE AT 25 AND AT 35.
Aq. Solvent.
H 2 O
C 4 H 9 OH (iso)
C 6 H 12 6
C 6 .H 12 6
(Hoffmann and Langbeck Z. physik. Ch. 51, 400, '05.)
C a H 4 OHCOOH dis- CH 4 OHCOOH dis-
Conc. of Solvent. solved at 25. solved at 35.
Normality.
O.O
Gms. per
Liter.
O.O
Grams Grams Grams
molecular per ioo gms. molecular
percentage. sat. solution, percentage.
2.8851 0.22064.1844
Grams
per ioo gms.
sat. solution.
0.3197
O.
0249
I.
146
2.8966.10"^
1 o.
222
4-
2044. io~ 4
0.322
0.
0560
2.
578
2.9150 "
0.
223
4-
2348
tt
.324
o.
1747
8.
04
2.9901
o.
229
0.
2399
II.
05
4-
434i
1C
O
.339
I.
03
47-
4
3.5279 "
0.
270
5-
2816
tt
.404
I.
638
75-44
3.9253
0.
300
0.
020
i.
496
2.909
0.
223
4-
229
11
.324
o.
051
3-
74
2-955 "
o.
226
4-
289
(I
329
0.
IOO
7.48
3-033 ;;
0.
232
4-
435
11
339
o.
521
38.
60
o.
285
5-
624
It
0-43 1
0.
02
3-6
2.886 "
0.
221
4-
184
tt
o
.321
0.
10
18.
o
2.898 "
0.
222
4-
202
(I
.322
0.
5
89-
6
2-954 "
o.
226
4-
263
It
o
.326
I.
00
180.
3- OI 5
0.
231
4-
3 60
11
334
o.
02
6.
88
2.885 "
o.
221
4-
206
(I
322
0.
10
34-
97
2.964 "
0.
227
4-
287
11
.328
0.
5
172.
o
3-239
0.
248
4-
697
tt
.360
I.
10
376.
3
3-633 "
o,
2 7 8
5-
236
tt
.401
0.
02
3-
6
2.888 "
0.
221
0.
06
10.
8
2.895 "
o.
221
0.
25
45-
2.944
c.
225
SOLUBILITY OF SALICYLIC ACID IN BENZENE.
(Walker and Wood J. Ch. Soc. 73 620, '98.)
Gms. Gms. Gms.
Ce^OHCOOH t o CeH 4 OHCOOH t o C^OHCOOH
per ioo Gms. per ioo Gms. per ioo Gms.
CeHs- CeHg. CeHe-
11-7 0.460 30.5 0.991 49.4 2.380
18.2 -579 34-6 1.261 64.2 4-40
36.6 1.430
SELENIUM Se.
SOLUBILITY IN CARBON BISULPHIDE.
(Marc Z. anorg. Ch. 48, 425, '06.)
ioo cc. CS 2 dissolve 0.065 g m - amorphous Se at room temperature.
Se which is heated to 180 for 6-7 hours is insoluble in CS 2 . Se crystal-
lized from the melt at 200 is insoluble in CS 2 . Se heated once quickly
to 140 is very slightly soluble in CS 2 .
ioo gms. methylene iodide (CH 2 I 2 ) dissolve 1.3 gms. Se at 12.
(Retgers Z. anorg. Ch. 3, 346, '93.)
277 SELENIOUS ACID
SELENIOUS ACID H 2 SeO 3 .
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 551, '94.)
t o Cms. H 2 SeO 3 per
100 Gms. Solution.
t o Gms. H 2 SeO 3 per
100 Gms. Solution
t o Gms. H 2 SeO 3 per
* loo Gms. Solution.
10
42.2
25
67.0
60
79-3
47-4
30
70.2
70
79-3
+ 10
55-o
40
77-5
80
79-3
20
62.5
5
79.2
90
79-4
SILICON Si.
SOLUBILITY IN LEAD AND IN ZINC.
(Moissan and Siemens Ber. 37, 2088, '04.)
In Lead. In Zinc.
, o Gms. Si per 100 t o Gms. Si per too
Gms. Solution. Gms. Solution.
1250 0-024 600 0.06
1330 0.070 650 0.15
1400 0.150 730 0-57
I45O O-2IO 8OO 0.92
1550 0.780 850 1.62
SILICON IODIDES Si 2 I 6 , SiI 4 .
SOLUBILITY IN CARBON BISULPHIDE.
(Friedel and Lachburg Bull. soc. chim. [2] 12, 92, '69; Friedel Liebig's Ann. 149, 96, '69)
ioo gms. CS 2 dissolve 19 gms. Si 2 I 6 at 19.
100 gms. CS 2 dissolve 26 gms. Si 2 I 6 at 27.
ioo gms. CS 2 dissolve 2.2 gms. SiI 4 at 27.
SILICO TUNGSTIC ACID H 8 SiW 12 O 42 .
ioo gms. H 2 O dissolve 961.5 crystallized silico tungstic acid at 18,
and solution has Sp. Gr. 2.843.
SILVER 278
For equilibrium between metallic Silver and mercury (Silver amal
gam) and mixed aqueous solutions of their nitrates, determined foe
mixtures of the two metals in all proportions, see Reinders Z. physik.
Ch. 54, 609, '06.
SILVER ACETATE CH 3 COOAg.
SOLUBILITY IN WATER.
(Nernst Z. physik. Ch. 4,379/89; Arrhenius Ibid, n, 396, '93; Goldschmidt Ibid. 25, 93, '98,
Nauman and Rucker Ber. 38, 2293, '05; Raupenstrauch Monatsh. Ch. 6, 585, '85; Wright and
Thompson Phil. Mag. [5] I7t 288, '84; 19, i, '85.)
t o Gms.Ag(C 2 H 3 O 2 )
per Liter.
o 7.22
10 8.75
15 9-4
20 10.4
SOLUBILITY OF SILVER ACETATE IN AQUEOUS SOLUTIONS OF:
Silver Nitrate. Sodium Acetate.
t o Gms.Ag(C 2 H 3 O2)
per Liter.
t.
Cms. Ag(C 2 H 3 O 2 )
per Liter.
25 II. 2
50
16.4
30 12. I
60
18.9
40 I4.I
70
21.8
80
25.2
AgNOa
per Liter.
Gms. CH 3 COOAg per Liter at:
Gms.
CHgCOONa
per Liter.
Gms.CHsCOOHg per Liter at:
16 (Nernst).
1 9 .8 (Arrhenius) .
1 6 (N.,N.andR.).
i8.6(A.).
O
10.05
9-85
O
10.05
9.9
5
8.2
7-9
5
6-3
6.6
10
7-o
6.6
10
4.6
4-9
15
6. 4
5-5
15
3-8
4.1
2O
5-7
4-5
20
3-3
3-5
30
4-4
30
2.8
40
3-2
40
2.4
SILVER Mono Chlor ACETATE CH 2 ClCOOAg.
One liter aqueous solution contains 12.97 grams CH 2 ClCOOAg at
16.9. (Arrhenius.)
SOLUBILITY OF SILVER MONO CHLOR ACETATE AT 16.9 IN
AQUEOUS SOLUTIONS OF:
Silver Nitrate. Sodium Chlor Acetate.
Gms.
Gms.
Gms.
Gms.
AgNOs
per Liter.
CH 2 ClCOOAg
per Liter.
CH 2 ClCOONa
per Liter.
CH 2 ClCOOAg
per Liter.
O-O
12.97
o.o
12.97
9 .6
IO.O5
3 .88
10.05
17.0
7-55
7-77
8.16
15-53
6. 02
31.07
4.19
58.26
3-26
SILVER Di Propyl ACETATE AgC 8 H 16 O 2 .
TOO gms. H 2 O dissolve 0.123 gm. AgC 8 H 15 O 2 at 11.7, and 0.190 gm.
at 72.
(Furth Monatsh. Ch. g, 311, '88.)
279 SILVER ACETATES
SILVER Methyl Ethyl ACETATE Ag.CH 3 .CH 2 .CH(CH 3 )COO.
SILVER Di Ethyl ACETATE Ag.[(C 2 H 5 ) 2 CH.COOJ.
SILVER Tri Methyl ACETATE Ag.(CH 3 ) 3 CCOO.*
SOLUBILITY OF EACH WATER.
(Sedlitzky Monatsh. Ch. 8, 563, '87; Keppish Ibid. 9, 589, '88; Stiassny Ibid. 12, 601, '91.)
Gms. per 100 Gms. H2O. Gms. per 100 Gms. H2O.
I .
Ag.C 5 H 9 O 2 .
AgC6H u 2 .
AgC 6 H 9 2 *
i .
AgC 6 H 9 2 .
AgC 6 HnO 2 .
AgC6H 9 2 *
I .112
0.402
I .10
50
I .602
0-536
1.47
10
I .126
0.413
I .15
60
1.827
0.585
20
I.I82
0.432
I .22
70
2.093
0.643
1.68
30
1.280
0.458
I .22
80
2.402
1. 80
40
I .420
0-494
i-37
SILVER BENZOATE C (i H 6 COOAg.
One liter of aqueous solution contains 1.763 gms. C 6 H 5 COOAg at
14.5, and 2.607 gms. at 25.
(Holleman Z. physik. Ch. 12, 129, '93; Noyes and Schwartz Ibid. 27, 287, '98.)
SOLUBILITY OF SILVER BENZOATE AT 25 IN AQUEOUS SOLUTIONS OF:
Nitric Acid (N. and S.). Chlor Acetic Acid (N. and S.).
Millimols per Liter. Grams per Liter. Millimols per Liter. Grams per Liter.
HNO 3 .
0.0
0.004435
0-00887
0-00892
0.01774
0-02674
C 6 H 5
COOAg.
O.OII44
0.01395
0.01698
0.01715
0.02324
0.03071
HNO 3 .
O-O
0.28o
o-559
0.562
1.118
1.686
C 6 H 5
COOAg.
2 .607
3- J 95
3.889
3.926
5-3 21
7.031
CH 2
C1COOH.
o.o
0.00394
0-00787
0.01574
C 6 H 5
COOAg.
O.OII44
0.01385
o 01612
0.02093
CH 2
C1COOH.
o.o
0-371
0.744
1.487
C 6 H 5
COOAg.
2.607
3.172
3.691
4.792
One liter of cold alcohol dissolves 0.169 gm. C 6 H 5 COOAg; one liter
Of boiling alcohol dissolves 0.465 gram. (Liebermann Ber. 35, 1094, '02.)
SILVER BORATE AgBO 2 .
One liter of aqueous solution contains about 9.05 gms. AgBO 2 at 25.
(Abegg and Cox Z. physik. Ch. 46, n, '03.)
SILVER BROMATE AgBrO 3 .
SOLUBILITY IN WATER.
t. Gms. AgBrO 3 per Liter. Authority.
2Q I .586 (Bottger Z. physik. 01.46, 602, '03.)
24.5 1.911 (Noyes Z. physik. Ch. 6, 246, '90.)
25 I . 68 (Longi Gazz. chim. ital. 13, 87, '83.)
SOLUBILITY OF SILVER BROMATE IN AQUEOUS AMMONIA AND NITRIC
ACID SOLUTIONS AT 25.
(Longi.)
Grams AgBrOa per
1000 cc. Sol. 1000 Gms. Sol.
Ammonia Sp. Gr. 0.998=5% 35.10 35.54
Ammonia Sp. Gr. 0.96 =10% 443-6 462.5
Nitric Acid Sp. Gr. i .21 =35% 3.81 3.12
SILVER BROMATE 280
SOLUBILITY OF SILVER BROMATE AT 24.5 IN AQUEOUS
SOLUTIONS OF:
Silver Nitrate (Noyes). Potassium Bromate (N.).
Normal Content. Gms. per Liter. Normal Content. Gms. per Liter.
AgN0 3 .
AgBrO 3 .
AgN0 3 -
AgBrO 3 .
KBrO 3 .
AgBrO 3 .
KBrOs.
AgBrOa.
O-O
o
,0o8l
o
.0
I .911
O
.0
O
.0081
O-O
I.QII
0-0085
o
.0051
I
445
1.203
o
.0085
.00519
1.42
1.225
0.0346
o
.0022
5
.882
0.510
o
.0346
.00227
5-78
O-SS^
SILVER BROMIDE AgBr.
SOLUBILITY .IN WATER.
t . Gms. AgBr per Liter. Authority.
2O O .000084 (Bottger Z. physik. Ch. 46, 602, '03.)
25 O .OOOI37 (Abegg and Cox Z. physik. Ch. 46, n, '03.)
IOO O.OO37O (Bottger Z. physik. Ch. 56, 93, '06.)
(See alsoHolleman Z. physik. Ch. 12, 129, '93; Kohlrausch Ibid. 50, 365, '05.)
SOLUBILITY OF SILVER BROMIDE IN AQUEOUS AMMONIA SOLUTIONS.
(Longi Gazz. chim. ital. 13, 87, '83; at 80, Pohl Sitzber. Akad. Wiss. Wien, 41, 267, '60.)
Gms. AgBr at 12 per Gms . AgBr at 8o o ^
Solvent. I000 cc . Iooo Gms. * Gms.
Solvent. Solvent. Solvent.
Ammonia Sp. Gr. 0.998 = 5% 0.114 0.114
Ammonia Sp. Gr. 0.96 =10% 3 -33-4.0 3-47
Ammonia Sp. Gr. o . 986 ... ... 0.51* i.ot
* Dried AgBr. t Freshly pptd.
SOLUBILITY OF SILVER BROMIDE IN AQUEOUS SOLUTIONS OF:
Ammonia at o. Mono Methyl Amine at 11.5.
(Jarry Ann. chim. phys. [7] i? 363. '99-) (Jarry.)
Grams per 100 cc. Solution. Gms. per 100 cc. Solution.
, ^ t * N
NHs Gas. AgBr. NH 3 Gas. AgBr. NH 2 CH 3 . AgBr.
3.07 0.080 26.27 1.067 ii. oi 0-07
4-88 0.096 3I-26 I-568 I3-I7 0.12
6.69 0.172 33 .89 1.987 15.13 0.16
8.29 0.212 36-52 2.669 J]C 7-97 0.28
11.51 0.349 37-22 2.888 32.58 0.55
I5-32 0.557 37-70 2.930 35.62 0.73
18.09 0.722 39-26 2.892 43-n 1-27
J 9-53 o-74i 39-95 2.852 48-44 2.89
SOLUBILITY OF SILVER BROMIDE IN AQUEOUS SOLUTIONS OF
SODIUM THIO SULPHATE AT 35.
(Richards and Faber Am. Ch. J. 21, 186, '99.)
Gms. Cryst. Na Thio Sulphate Gms. AgBr Dissolved Mols. AgBr Dissolved
per Liter. per Gram of Thio Sulphate. per Mol. of
loo 0.376 0-496
200 0.390 0.515
300 0-397 0-524
400 0-427 0.564
28i SILVER BROMIDE
SOLUBILITY OF SILVER BROMIDE IN AQUEOUS SALT SOLUTIONS.
(Valenta Monatsh. Ch. 15, 250, '94; see also Cohn Z. physik. Ch. 18, 61, '95.)
Gms.AgBr per 100 Cms. Aq. Solution of Concentration:
Salt Solution. t. , x
1:100. 5:100. 10: 100. 15:100. 20:100.
Sodium Thio Sulphate 20 0.35 1.90 3.50 4.20 5.80
" Calc. by Cohn 20 0.50 2.40 4.59 6.58 8.40
Sodium Sulphite 25 0.04 ... 0.08
Potassium Cyanide 25 ... 6.55
" Calc. by Cohn 25 ... 6.85
Potassium Sulphocyanide 25 ... ... o . 73
Ammonium Sulphocyanide 20 ... 0.21 2.04 5.30
Calcium Sulphocyanide 25 ... ... 0.53
Barium Sulphocyanide 25 ... . .. 0.35
Aluminum Sulphocyanide 25 ... ... 4.50
Thio Carbamide 25 i .87
Thio Cyanime 25 0.08 0.35 0.72
NOTE. Cohn shows that the lower results obtained by Valenta
are due to the excess of solid AgBr used and the consequent formation
of the less soluble di salt 3(AgS 2 O 3 Na) 2 instead of the more soluble
salt (AgS 2 O 3 Na) 2 Na 2 S 2 3 .
100 cc. H 2 O containing 10 per cent of normal mercuric acetate,
Hg(C 2 H 3 O 2 ) 2 + Aq., dissolve 0.0122 gram AgBr at 20.
100 gms. NaCl in cone. aq. solution dissolve 0.474 gm. AgBr at 15.
100 gms. NaCl in 21 per cent solution dissolve 0.182 gm. AgBr at 15.
100 gms. KBr in cone, solution dissolve 3.019 gms. AgBr at 15.
95 gms. NaCl -f 10 gms. KBr in cone. aq. solution dissolve 0.075
gm. AgBr at 15.
(Schierholz Sitzber. K. Akad. Wiss. (Vienna) 101, 2b, 4, '90-)
SILVER BUTYRATE C 3 H 7 COOAg.
SILVER (Iso) BUTYRATE (CH 3 ) 2 CHCOOAg.
SOLUBILITY OF EACH IN WATER.
Ch. 25, 93, '98; Arrhenius Ibid. 11, 396, '93; R
Ch. 6, 589, '85-)
Gms. per 100 Grams H 2 O. Grams per 100 Gms. H 2 O.
(Goldschmidt Z. physik. Ch. 25, 93, '98; Arrhenius Ibid, n, 396, '93; Raupenstrauch Monatsh
Ch. 6, 589, '85-)
Butyrate. Iso Butyrate. Butyrate. Iso Butyrate.
o 0.363 0.796 30 0.561(1.1020.) i. 060
10 0.419 0.874 40 0.647 .
17.8 0.432 (A.) ... 50 0.742 i-3 I 3
18.8 0.445 (A.) 60 0.848
20 0.484(0.9990.) 0.961 70 0.901 1.670
25 ... (1.0440.) ... 80 1. 14 1-898
SILVER BUTYRATE
282
SOLUBILITY OF SILVER BUTYRATE IN AQ. SOLUTIONS OF SILVER
ACETATE, SILVER NITRATE AND OF SODIUM BUTYRATE.
(Arrhenius Z. physik. Ch. n, 396, '93.)
In Silver Acetate at 17.8.
G. Mols. per Liter. Grams per Liter.
CH 3
COOAg.
C 3 H 7
COOAg.
CH 3
COOAg.
C 3 H 7
COOAg.
o.o
0-0221
o.o
4-32
O.O27O
0-0506
0.0139
O.OIO3
4-5 1
8-45
2.71
2-01
In Silver Nitrate at 18.8.
G. Mols. per Liter. Grams per Liter.
C 3 H.
COO
AgNO 3 .
C 3 H 7
COOAg.
o.o 0.0228
0.0667 0-0078
o.ioo 0.0062
In Sodium Butyrate at 18.2.
Ag.
o.o 4.445
n-33 1-521
17.00 1.209
G. Mols. per Liter. Grams per Liter. G. Mols. per Liter. Grams per Liter.
' CsH 7
COONa.
o.o
O.OO66
0-0164
0-0329
C 3 H 7
COOAg.
O.O224
O.OI99
0.0169
O.OI3I
C 3 H 7
COONa.
o.o
o-73
1.81
3-62
COOAg.
4-3 6 3
3.881
3.296
2-555
C 3 H 7
COONa.
0.0658
0-I3I5
0.263
0-493
C 3 H 7
COOAg.
O.OO9I
o . 0060
o . 0040
0.0027
' C 3 H 7
COONa.
7-24
14-47
28.96
54-28
C 3 H 7
COOAg.
i-774
1.170
0.780
0.526
SILVER CAPROATES Ag(C 6 H u O 2 ).
SOLUBILITY IN WATER.
(Keppish Monatsh. Ch. 9, 589, '88; Stiassny Ibid. 12, 596, '91; Kulisch Ibid. 14, 570, '93; Konig
Ibid. 15, 26, '94; Altschul Ibid. 17, 568, '96.)
Results in terms of grams salt per 100 grams H 2 O.
Methyl 3 Pentan 4 Methyl Pentan
Acid 4 4 Acid
CH 3 .CH 2 CH 3 (CH 2 )2CH(CH 3 )
:H 3 CH 2 COOAg. .COOAg.
O . 076 (A.) O . 078(Keppisch) o l68 (Konig) o . 880 (Kulish) 0.510 (Stiassny)
Normal Caproate
I 2 ) 4 COOAg.
CHg(CH 2
2 Methyl Pentan
4 Acid
CH 3 .CH.CH 3
.(CH 2 ) 2 COOAg. .CHCH
O
0.076 (A.)
0.078
10
0.085
0.089
20
O-IOO
0-107
30
0.123
0.131
40
0.154
0.161
50
0.193
0.198
60
0.240
0.243
70
0.295
0.288
80
o-354
90
0.162
0.163
0.170
0.183
0.203
0.229
0.263
0.300
0-347
0.858
0.849
0.854
0.871
0.902
0.946
1.003
1.073
0.528
o-55o
o-574
0.602
0.632
0.666
0.702
0.742
SILVER CARBONATE Ag 2 CO 3 .
SOLUBILITY IN WATER.
t. Gms. Ag 2 CO 3 per Liter. Authority.
15 .031 (Kremers Pogg. Ann. 85, 248, '52.)
25 O -033 (0.00012 gm. atoms Ag.) (Abegg and Cox Z. physik. Ch. 46, n, '03.)
IOO .50 (Joulin Ann. chim. phys. [4] 30, 260, '73.)
J 5 0.85 (inH 2 Osat.withCO 2 ) (Johnson Ch. News, 54, 75, *86.)
SILVER CHLORATE AgClO 3 .
loo grams cold water dissolve 10 grams AgClO 3 (Vauquelin) ; 20
gms. AgClO 3 (Wachter).
283 SILVER CHLORIDE
SILVER CHLORIDE AgCl.
SOLUBILITY IN WATER.
(A large number of determinations are quoted by Abegg and Cox Z. physik. Ch. 46, u, '03; see also
Kohlrausch Ibid. 50, 356, 04- '05; Bottger Ibid. 46, 602, '03, 56, 93, '06.)
t. I4- 20. 2 5 . 4 2. 100.
Cms. AgCl per liter 0.0014 0.0016 0.0020 0.0040 0.0218
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS SOLUTIONS OF:
Ammonia at o. Mono Methyl Amine at 11.5.
(Jarry Ann. chim. phys. [7] 17, 342, '99.) (Jarry.)
Grams per 100 Grams Solution. Gms. per 100 Gms. Solution.
NH 3 Gas.
AgCl.
NH 3 Gas.
AgCl.
NH 2 CH 3 .
AgCl.
i-45
0-49
28.16
6-59
I. 7 8
0.16
1.94
I. 3 6
29.80
7.09
4-44
0.62
5.60
3-44
30.19
7-25
5-51
0.83
6.24
4.00
3 2 -43
5-87
7.66
1.32
11.77
4.68
34 -5 6
4-77
13.70
3-29
16.36
5.18
37-48
3-90
18.69
5-43
36.69
9-93
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS SOLUTIONS OF
AMMONIA.
(Longi Gazz, chim. ital. 13. 87, '83; at 25, Valenta Monatsh. Ch: 15, 250, '94; at 80, Pohl
Sitzber. Akad. Wiss, Wien, 41, 627, '60.)
Gms. AgCl per
100
vent.
o , * o Gms. AgCl
Solvent - * ' Gms. Sol
Aq. Ammonia of o . 998 Sp. Gr. = 5 % 12 o . 233
0.96 Sp. Gr, = 10% 18 7.84
" o-986Sp. Gr. 80 1.49
" = 3% 25 1.40
= 15% 25 7.58
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS SOLUTIONS OF
AMMONIUM CHLORIDE.
(Schierholz Sitzber. K. Akad. Wiss. (Vienna) 101, 2b, 8, '90; see also Vogel N. Rep. Pharm. 23,
335, '74. Hahn Wyandotte Silver Smelting Wks., 1877.)
Solubility at 1 5. Solubility at Different Temperatures.
Grams per 100 Gms. Solution. t 0> Gms. per 100 Gms. Solution.
NflUCl.
AgCl.
NH4C1. AgCl.
10.00
O.005O
15
26.31 0-276
14.29
0-0143
40
0.329
17.70
0-0354
60
0-421
19.23
0-0577
80
0-592
21.98
o.no
90
0.7II
25-3 1
0.228
IOO
0.856
28.45
0-340 (24-5)
no
1-053
Sat. at ord. temp.
0.157
Sp. Gr. of
26.31 % NH 4 C1 solution at
iS = i.o8.
SILVER CHLORIDE 284
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS SOLUTIONS OP
ALUMINUM AND AMMONIUM SALTS.
(Valenta; see also Cohn Z. physik. Ch. 18, 61, '95.)
Cms. AgCl per 100 Cms. Solvent of Concentration:
Aq. Salt Solution. t. , - * - s
i : 100. 5 : 100. 10 : 100.
Aluminum Sutphocyanide 25 ... ... 2.02
Ammonium Carbonate 25 ... ... 0-05
Sulphocyanide 20 ... 0.08 0.54
" Thio Sulphate 20 0.57 1.32 3.92
" Cak. by Cohn* 0.64 3.07 5.86
* See Note, p. 281.
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS HYDROCHLORIC
ACID SOLUTIONS AT ORDINARY TEMPERATURE.
(Pierre J. pharm. chim. [3] 12, 237, '47; Vogel.)
Cone. HC1 + Aq. 5.0 100 vol. sat. HC1 -f 10 vol. H 2 O 0.56
i vol. Cone. HC1+ i vol. H 2 O 1.6 " + ?o " " 0.18
Sat.HCl. Sp. Gr.i.i6s 2.98 " +30 " " 0.09
" (atb.pt.) 5.60 " +50 " " 0.035
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS SALT SOLUTIONS.
(Vogel; Hahn; Valenta )
Salt Solution. Cone, of Salt. t . fooGmfsofudon.
Barium Chloride 27.32% 24.5 0.057 (H.)
Barium Chloride saturated ord. temp. 0.014 (Vg.)
Barium Sulphocyanide 10 : 100 25 0.20 (VI.)
Calcium Sulphocyanide 10:100 25 0.15 (VI.)
Calcium Chloride 41.26% 24.5 0.571 (H.)
Calcium Chloride saturated ord. temp. 0.093 (Vg.)
Copper Chloride " 24.5 0.053 (H.)
Ferrous Chloride " " 0.169 (H.)
Ferric Chloride " " 0.006 (H.)
Manganese Chloride 0.013 (H.)
Magnesium Chloride 50:100 25 0.50 (VI.)
Magnesium Chloride 36.35% 24.5 0-53 1 (H.)
Magnesium Chloride saturated ord. temp. 0.171 (Vg.)
Strontium Chloride " 0.088 (Vg.)
Zinc Chloride 24.5 0.0134 (H.)
Potassium Chloride " ord. temp. 0.0475 (Vg.)
Potassium Chloride 24.95% I 9-^ 0-0776 (H.)
Potassium Cyanide 5:100 25 2.75 (VI.)
Potassium Cyanide 5 ; ioo 25 5-24 (Cohn*)
Potassium Sulphocyanide 10: 100 25 o.n (VI.)
Sodium Chloride saturated ord, temp. 0-095 (Vg.)
Sodium Chloride 25.95% 19-6 0105 (H.)
* See Note, page 281.
285 SILVER CHLORIDE
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS SOLUTIONS OF
POTASSIUM CHLORIDE AT 15.
(Schierholz Sitzber. K. Akad. Wiss. (Vienna) 101, ab, 8, '90-)
Grams per ioo Grams Grams per ioo Grams
Solution. Solution.
KC1 AgCl. KC1. A^CL
lo.o o-ooo 22.47 0-045
14.29 O.004 24.0 O.072
16.66 0.008 25.0 0.084
20.00 0.020 Sp. Gr. of 25% KC1 sol.,= 1.179
MIXTURES OF SILVER CHLORIDE AND SILVER HYDROXIDE IN EQUI-
LIBRIUM WITH AQ. POTASSIUM HYDROXIDE SOLUTIONS AT 25.
(Noyes and Kohr J. Am, Ch. Soc. 24, 1144, '02 )
Normality Millimols per Liter Grams per Liter.
of KOH. KC1. KOH. KcT~ KOH. ~~AgCl.
0-333 3-4I4 347-8 0.255 10.05 0.4896
0-065 0.598 65.0 0.0446 2-00 0-0828
SOLUBILITY OF SILVER CHLORIDE IN AQ. SOL. OF SODIUM CHLORIDE.
(Schierholz; Vogel; Hahn.)
Solubility Solubility at Different
at 15. Temperatures.
Gms. per ioo Gms, . Gms. AgCl per ioo Gms.
Solution. Solution in:
NaCl. AgCl. 14% NaCl 26.3% NaCl.
lo.o 0.0025 15 0.007 0.128
14.29 0.0071 30 0-OIT O.I32
18.18 0-0182 40 0.014 0.158
21.98 0-0439 50 0-023 0.184
23.53 0.0706 70 0.042 0.263
25.64 0.103 80 0.054 0.315
26.31 0.127 90 0.069 0.368
ioo 0-090 0.460
Sp.Gr. of 26. 31% NaCl sol. = 1.207. 109 0.107(104) 0.571
SOLUBILITY AT 20, 50, AND 90 (CALC. FROM ORIGINAL).
(Barlow J. Am. Chem. Soc 28, 1446, '06 )
Gms. NaCl Gms. AgCl dissolved per too cc. Gms NaCl Gms. AgCl dissolved per ioo cc.
per ioo cc. Solution at: per ioo cc, Solution at:
Solution. ' 2 o. 50. 90. Solution. 2 o". 50". 90",
3.43 0.00018 0.0016 0-0067 11.5 0-0031 0.0124 0.0436
4.60 0-00025 0.0025 o.oioo 15.3 0-0090 0.0191 0.0732
5-75 0.00047 0.0034 0.0135 23.0 0-0313 0.0889 0.1706
7.67 0.00125 0-0058 0-0236
Results are also given for the solubility of silver chloride in aqueous
sodium chloride solutions containing hydrochloric acid.
SOLUBILITY OF SILVER CHLORIDE IN AQ. SODIUM NITRATE SOLUTIONS.
j. o Gms. per ioo Gms. H2O. * o Gms. per TOO Gms. H2O.
NaN0 3 . AgCl. ' NaN0 3 - AgCl. '
5 0.787 0.00086 15-20 0.393 0.00096
18 0.787 0.00146 o 787 0.00133
30 0.787 0.00233 2.787 0.00253
45-55 -787 0-00399 (Mulder )
SILVER CHLORIDE 286
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS SOLUTIONS OP
SODIUM THIO SULPHATE, ETC.
(Valenta ; Cohn; Richards and Faber Am. Ch. J. 21, 168, '99.)
Gms. AgCl per 100 Gms. Aq. Solutions of Concentration:
Salt Solution. t. , ^
i . 100. 5 ; loo. 10 : 100. 15 : 100, 20 : 100.
Sodium Sulphite 25 ... ... 0.44 ... 0.95
Sodium Thio Sulphate 20 0.40 2.00 4.10 5 .50 6.10
" Calc. by Cohn* 0.38 1.83 3.50 5.02 6.41
Sodium Thio Sulphate 35 9 .08 t
Thio Carbamide 25 0.83
Thio Cyanime 25 0.40 1.90 3-90
* See Note, page 281. t Gms. per 100 cc. solution (R. and F.).
SILVER CHROMATE Ag 2 CrO 4 .
One liter of water dissolves 0.026 grn. Ag 2 CrO 4 at 18, and 0.020
gm. at 25. (Abegg and Cox Z.physik.iCh. 46,11, '03, Kohlrausch y^^ so s 356, '04-^5)
SOLUBILITY OF SILVER CHROMATE IN AQUEOUS SOLUTIONS OF
NITRATES AT 100.
(Carpenter J. Soc. Chem. Ind. 5, 286, '86.)
o_ lwr Gms. Salt Gms. Ap 2 CrO 4
per 100 cc. H 2 O . per 100 cc Solution.
Water o o . 064
Sodium Nitrate 50 0.064
Potassium Nitrate 50 0.192
Ammonium Nitrate 50 0.320
Magnesium Nitrate 50 0.256
SILVER (Di) CHROMATE Ag 2 Cr 2 O 7 .
One liter of aqueous solution contains 0.00019 gram mols. or 0.083
gram Ag 2 Cr 2 O 7 at 15. (Mayer Ber. 36, 1741, '03 )
SILVER CITRATE C 6 H 5 O 7 Ag 3 .
100 gms. H 2 O dissolve 0.0277 gm. C 6 H 6 O 7 Ag 3 at 18, and 0.0284
grn. at 25. (Partheil and Htibner Archiv. Pharm. 241, 413, ; o 3 .)
SILVER CYANIDE AgCN.
One liter of aqueous solution contains 0.000043 grn. AgCN at 17.5
and 0.00022 gm. at 20 (by Conductivity Method).
(Abegg and Cox Bottger Z. physik. Ch. 46, 602, '03.)
SOLUBILITY OF SILVER CYANIDE IN AQUEOUS AMMONIA SOLUTIONS.
(Longi Gazz. chem. ital. I3 S 87, '83.)
ioo gms. aq. ammonia of 0.998 Sp. Gr_ = 5% dissolve 0.232 gm.
AgCN at 12.
ioo gms. aq. ammonia of 0.96 Sp. Gr. = 10% dissolve 0.542 gm.
AgCN at 1 8.
SILVER SODIUM CYANIDE AgCN.NaCN.
ioo gms. H 2 O dissolve 20 gms. at 20, and more at a higher tem-
perature, ioo gms. 85% alcohol dissolve 4.1 gms. at 20.
(Baup Ann. chim. phys [3] 53> 468, '58.)
SILVER THALLOUS CYANIDE AgCN.TlCN.
ioo gms. H 2 O dissolve 4.7 gms. at o, and 7.4 gms. at 16.
(Fronmiller Ber i j, 92, '78.)
287 SILVER FLUORIDE
SILVER FLUORIDE AgF.
100 gms. H 2 O dissolve 181.8 gms. at 15.8. Sp. Gr. of sol. = 2.61.
(Gore Proc. Roy. Soc. 18, 158, '70.)
SILVER FULMINATE CAg 2 (NO 2 )CN.
One liter of aqueous solution contains 0.075 g m - C 2 Ag 2 N 2 O 2 a ^ T 3
and O.lSo gm. at 30. (Holleman Rec. trav. chim. 15, 159, '96.)
SILVER HEPTOATE (Onanthylate) AgC 7 H 13 O 2 .
SOLUBILITY IN WATER.
(Laudau Monatsh. Ch. 14, 709, '93; Altschul Ibid. 17, 568, '96.)
f0 Gms. AgC 7 H l3 O2 per too Gms. H 2 O. ^o Gms. AgC 7 H 13 O 2 per ioo Gms. HzO.
O 0-0635 (Landau) 0.0436 (Altschul) 50 O . 1652 (Landau) o .0858 (Altschul)
10 0.0817 0-0494 60 0.1906 0.1036
20 0.1007 -555 7 0.2185 0.1351
30 o.i 206 . 0.0617 80 0.2495 0.1688
40 0.1420 0.0714
SILVER IODATE AgIO 3 .
One liter of aqueous solution contains 0.04 gram or 0.00014 g
mols. at i8-2o, and 0.05334 gm. or 0.000189 g. rnols. at 25.
(Longi; Bottger; Kohlrausch; Noyes and Kohr J. Am. Ch. Soc. 24, 1141, '02.)
SOLUBILITY OF SILVER IODATE IN AQUEOUS SOLUTIONS OF
AMMONIA AND OF NITRIC ACID AT 25.
(Longi Gazz. chim. ital. 13, 87, '83.)
ioo gms. aq. ammonia of 0.998 Sp. Gr. = 5% dissolve 2.36 gms. AgIO 3 .
100 gms. aq. ammonia of 0.96 Sp. Gr. = 10% dissolve 45.41 gms.
AgI0 3 .
ioo gms. aq. nitric acid of 1.21 Sp. Gr. = 35% dissolve 0.096 gm.
AgI0 3 .
SILVER IODIDE Agl.
One liter of aqueous solution contains 0.0000028 gm. Agl at 2o-25.
(Average of several determinations by Kohlrausch, Abcgg and Cox, etc. Holleman gives higher figures.)
i liter of aq. ammonia of 0.96 Sp. Gr. = 10% dissolve 0.035 S rn -
Agl at 12. (Longi.)
SOLUBILITY OF SILVER IODIDE IN AQUEOUS SALT SOLUTIONS.
(Valenta Monatsh. Chem. 15, 250, '94; Cohn Z. physik. Ch. 18, 61, '95.)
Gms. Agl per ioo Gms. Aq. Solution of Concentration:
Aq. Salt Solution. t. , -- ^
i : ioo. 5 : ioo. 10 : ioo. 15 : ioo. 20 : ioo.
Sodium Thio Sulphate 20 0.03 0.15 0.30 0.40 0.60
" Calc. by Cohn* 0.623 2.996 5.726 8.218 10.493
Potassium Cyanide 25 ... 8.28 ......
11 Calc. by Cohn* ... 8.568 ...
Sodium Sulphite 25 ... o.oi 0.02
Ammonium Sulphocyanide 20 ... 0-02 0.08 0.13
Calcium 25 ... 0.03
Barium " 25 ... 0.02
Aluminum 25 ... 0-02
Thio Carbamide 25 ... 0.79
Thio Cyan ime 25 0.008 0.05 0.09
* See Note, page 281.
SILVER IODIDE 288
SOLUBILITY OF SILVER IODIDE IN AQUEOUS SOLUTIONS OF SODIUM
CHLORIDE, POTASSIUM BROMIDE AND OF POTASSIUM IODIDE AT 15.
(Schierholz Sitzb. K. Akad. Wiss. (Vienna) 101, 20, 10, '90.)
In Sodium Chloride. In Potassium Iodide.
Gms. per 100 Gms. Solution. Gms. per 100 Gms. Solution.
NaCl. AgL KI. Agl.
26.31 0.0244 59 .16 53.13
25.00 0.00072 57 .15 40.0
50.0 25.0
40.0 13.0
In Potassium Bromide. ^3 ' \'^
Gms. per 100 Gms. Solution. 2 5 >o 2 '75
KBr Agl 21-74 1.576
30.77 0.132 20. o 0.80
TOO gms. sat. silver nitrate solution dissolve 2.3 gms. Agl at 11,
and 12.3 gms. at b. pt.
100 gms. pyridine dissolve o.io gm. Agl at 10, and 8.60 gms. at
121 . (von Laszcynski Ber. 27, 2285, '94.)
SILVER MALATE C 4 H 4 O 5 Ag 2 .
100 gms. H 2 O dissolve 0.0119 gm. at 18, and 0.1216 gm. at 25.
(Partheil and Hiibner Archiv. Pharm. 241, 413, '03.)
SILVER NITRATE AgNO 3 .
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 526, '94; Kramers
Phil. Trans
Pogg. Ann. 92, 497, '54; Tilden and Shenstone
23, '84.)
to
Grams AgNOg per
100 Gms.
to
Grams AgNOg per
100 Gms.
.
Solution.
Water".
*
Solution.
Water.
-5
48 (Etard) . .
50
79 (Etard) 82
455
53 55
122
60
81.5 84
525
10
62 6 3
170
80
85-5 87
669
20
68 69
222
100
88.5 9 oi
952
25
70.5 72
257
120
9i 95
1900
30
72-5 75
300
I4O
Q3 . "\
Vo
AO
76. S 7O
176
1 60
24.68
16.41
7-77
3 -02
23.86
16.07
7-36
2.90
Solid
Phase.
KSCN
KSCN + 2 KSCN.AgSCN
Double Salt.
aKSCN.AgSCN =
53- 92% KSCN
2 KSCN.AgSCN+
KSCN-AgSCN
Double Salt.
KSCN.AgSCN =
36.9% KSCN
KSCN.AgSCN+ AgSCN
SILVER TARTRATE C 4 H 4 O 6 Ag 2 .
100 gms. H 2 O dissolve 0.2012 gm. C 4 H 4 O 6 Ag 2 at 18, and 0.2031
gm. at 25.
SILVER VALERATES
(Partheil and Hiibner Archiv. Pharm. 241, 413, '03.)
AgC 5 H 9 2 .
SOLUBILITY IN WATER.
Normal Valerate I so Valerate
CH 3 (CH 2 ) 3 .COOAg.
(Furth Monatsh. Ch. 9, 311,
Gms. per 100 Gms. HaO.
CH 3 .CH(CH 3 ) 2 CH 2 COOAg.
Sedlitzky Ibid. 8, 563, '87.)
Gms. per 100 Gms. H 2 O.
*
Normal V.
Iso V.
o
0.229
0.177
10
0.259
0-2II
20
0-300
0-246
30
0-349
0.283
40
0.408
0.321
t .
Normal V.
Iso V.
50
0-474
0.360
60
o-55 2
0.4OI
70
0.636
0-443
80
0.486
100 gms. H 2 O dissolve 0.73 gm. silver valerate at 20.
(Markwald Her. 32, 1089, '99-)
SILVER VALERATE 292
SOLUBILITY OF SILVER VALERATE IN AQUEOUS SOLUTIONS OP
SILVER ACETATE, SILVER NITRATE AND OF SODIUM
VALERATE.
(Arrhenius Z. physik. Ch. n 396, '93.)
In Silver Acetate at 17.8. In Silver Nitrate at. 16.5.
Mols. per Liter. Gms. per Liter. Mols. per Liter. Gms. per Liter.
C 2 HsO 2 Ag.
C 5 H 9 O 2 Ag. C 2 H 3 O 2 Ag. CgHgO^
.g. AgNO 3 . C6HyO 2 Ag. AgNO 3 . (
o.o
o . 0094 o.o i . 96
o.o 0.0094 o.o
i .96
0.0067
0.0070 I.I3 1.46
0-0067 0.0068 I.I4
1.42
o -0135
0.0057 2.27 1.19
0.0133 0.0051 2.29
1.07
0.0270
0.0037 4.54 0-77
0-0267 O.003I 4-58
0.65
0.0505
0-00265 8.48 O-55
O-IOOO O-OOI2 17.00
0,25
In Sodium
Valerate at 18.6.
Mols. per Liter.
Grams, per Liter.
'CjjHsOjjNa. C s H 9 2 Ag:
C 2 H 3 2 Na. CsH 9 2 Ag.
o.o 0-0095
o.o 1.986
O.OI75 O-OO47
2.17 0-982
0-0349 0.0030
4.32 0.627
0-0698 O-OOlS
8.65 0.376
O.I395 O.OOI5
I7-3 1 0.313
SILVER VANADATE Ag 6 V 4 O 13 .
One liter of aqueous solution contains 0.047 gram at 14, and 0.073
gm. at 100. (Carnelly Liebig's Ann. 166, 155, '73.)
SODIUM ACETATE CH 3 COONa. 3 H 2 O.
SOLUBILITY IN WATER.
Interpolated from original.
(Schiavor Gazz. chim. ital. 32, II, 532, '02.)
Gms. CH 3 COONa Gms. CH 3 COONa
A o per TOO Gms. + o per ioo Gms.
Water. Solution. Water. Solution.
o 34 25.4 25 53 34-7
10 41 29.1 30 57 36.3
20 49 32.9 40 65 39.4
ioo gms. H 2 O dissolve 46.9 gms. CH 3 COONa at 31.5.
(Kohler Z. Ver. Zuckerind. 47, 447, '97.)
ioo cc. aqueous solution contain 41.11 gms. CH 3 COONa at 10.
(Enklaar.)
SOLUBILITY OF SODIUM ACETATE IN AQUEOUS SOLUTIONS OF
ACETIC ACID.
(Enklaar Rec. trav. chim. 20, 183, } oi.)
Gram Mols. per Liter. Grams per Liter.
CH 3 COOH." CHgCOON'a. CH 3 COOH. CHgCOONa.
o 5.0 o.o 411.1
0-085 5.0 5-1 410.3
0.12 5.0 7.2 410.4
SOLUBILITY OF SODIUM ACETATE IN ABSOLUTE ALCOHOL AT
ROOM TEMPERATURE.
(Bodtker Z. physik. Ch. 22, 510, '97.)
ioo gms. alcohol dissolve 1.81 gms. CH 3 COONa or 7.49 gms. CH 3
COONa. 3 H 2 O.
293
SODIUM ACETATE
SOLUBILITY OF SODIUM ACETATE IN AQUEOUS ALCOHOL:
At 1 8,
(Gerardin Ann. chim. phys. [4] 5, 158, '65.)
Wt. Gms.CHgCOONa
per 100 Gms.
Alcohol.
Aq. Alcohol.
S- 2
38.0
9 .8
35-9
23.0
29.8
29.0
38.0
27-5
23-5
45 -
59-o
86.0
20.4
14.6
39
91 .0
2 -I
At Different Temperatures.
(Schiavor.)
Degree Gms. per 100 Gms. Alcohol.
of A
Alcohol.
CH 3 COONa.
CH 3 COONa.3H 2 0.
8
98.4
2.08
3-45
12
98.4
2 .12
3-5 1
19
98.4
2-33
3.86
II
90
2.07
3-42
13
90
2.1 3
3-52
15
63
13.46
22.32
18
63
13.88
23-03
21
63
14.65
24.30
23
40
28.50
47.27
ioo gms. H 2 O dissolve 237.6 gms. sugar +57.3 grams CH 3 COONa,
or ioo gms. of the saturated solution contain 58.93 gms. sugar +
14.44 gms. CH 3 COONa at 31 . 25. (Kohier.)
SODIUM ARSENATE Na 3 AsO 4 .i2H 2 O.
ioo grams aqueous solution contain 21.1 grams Na 3 AsO 4 .i2H 2 O.
(=10.4 gms. Na 3 AsO 4 ) at 17. Sp. Gr. of solution = 1.1186.
(Schiff Liebig's Ann. 113, 350, '60.)
ioo grams glycerine dissolve 50 gms. sodium arsenate at 15.5.
(Pharm. Centralh. No. 30, '81.)
SODIUM HYDROGEN ARSENATE Na 2 HAsO 4 .i2H 2 O.
ioo gms. H 2 O dissolve 17.2 gms. Na 2 HAsO 4 .i2H 2 O (= 7.3 gms.
anhydrous) at o. 56.0 gms. (= 19.89 gms. anhydrous) at 14. Sp. Gr.
1.1722, 37.0 gms. anhydrous at 21, and 140.7 gms. hydrated at 30.
(Schiff Liebig's Ann. 113, 350, '60; Tilden J. Ch. Soc. 45, 409, '84.)
SODIUM BENZOATE C 6 H 5 .COONa.
ioo gms. H 2 O dissolve 62 gms. at 25, and 77 gms. at b. pt.
ioo gms. alcohol dissolve 2.3 gms. at 25, and 8.3 gms. at b. pt.
(U. s. P.)
SODIUM (Tetra) BORATE Na 2 B 4 O 7 .ioH 2 O (Borax).
SOLUBILITY IN WATER.
(Horn and Van Wagener Am. Ch. J. 30, 347, '03.)
Gms. Na 2 B 4 O 7
Gms. Na 2 B 4 O 7
t.
per ioo Gms.
t .
per ioo Gms.
t.
HO.
H 2 0.
5
i-3
5o
10-5
60
10
1.6
54
13-3
62
21.5
2.8
55
14.2
65
30
3-9
56
15.0
70
37-5
5-6
57
16.0
80
45
8.1
90
IOO
Gms.
per ioo Gms.
H 2 0.
2O
Transition
imately 62.
19.4
22. 2O-7
22. 21-9
24.4
31-5
41 .o
52-5
temperature Na 2 B 4 O 7 .ioH 2 O > Na 2 B 4 O 7 .5H 2 O approx-
Sp. Gr. of saturated solution at 15 = 1.032. (Geriach.)
SODIUM BORATES 294
SOLUBILITY OF SODIUM BORATES IN WATER AT 30.
(Dukelski Z. anorg. Ch. 50, 42, '06, complete references given.)
Gms. per ioo Gms. Solution.
Gms. per 100^
Gms. Residu<
; - Solid
Phase.
K 2 0.
B 2 3 .
K 2 O.
B 2 3 .
42.O
NaOH.H 2 O
41-37
5.10
43-54
4.19
"
38-85
5-55
37-20
ii. 18
Na 2 O.B 2 O 3 .4H 2 O
34-44
3-73
33-52
10.80
"
29-39
2.51
29.63
10. II
"
26.13
2-75
27-85
15.21
"
23.00
3.82
24.91
ii .60
"
16.61
13.69
21 .29
20.64
"
21.58
4-63
24.52
19.04
Na 2 O.B 2 3 . 4 H 2 O +!Na 2 O.B 2 O 3 .8H 2 O
20.58
4.69
21. 6l
16.59
Na 2 O.B 2 O 3 .8H 2 O
I5-32
6.21
19.70
17.84
"
12-39
9.12
18.05
18.17
"
8.85
10.49
II .72
20.62
Na 2 O.2B 2 O 3 .ioH 2 O
5.81
6.94
10.82
21.31
1.88
2.41
7-31
I5-50
1-38
5 .16
7 .l6
17.44
2. 02
7-79
6.24
16.38
4.08
17.20
8.96
29.20
Na 2 O.2B 2 O 3 .ioH 2 O + Na 2 O.5B 2 O 3 .io!
3-79
15.84
5 .68
28.19
Na 2 O.sB 2 O 3 .ioH 2 O
2.26
12.14
5-21
29.19
H
1.99
11.84
5-74
39.66
Na 2 O.2B 2 O 3 . IO H 2 O + B(OH) 3
1.86
11.18
i. 06
28.78
B(OH) 3
0.64
6. ii
0.31
3 I - I 9
"
3-54
ioo gms. alcohol of 0.941 Sp. Gr. dissolve 2.48 gms. sodium borate
at 15.5.
ioo gms. glycerine dissolve 60.3 gms. at i5.5> and ioo gms. at 80.
(U.S.P.)
Gaudolphe J. pharm. chim. [4] 22, 366, '75 says that glycerine
dissolves its weight of sodium borate at ordinary temperatures.
SODIUM BROMATE NaBrO 3 .
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 94, 271, 55; 97, 5, '56.)
t. o 20 40 60 80 100
Gms. NaBrO 3 per ioo
Gms. H 2 O 27.5 34.5 50.2 62.5 75.7 90.9
Sp. Gr. of saturated solution at 19.5= 1.231. (Geriach.)
295
SODIUM BROMIDE
SODIUM BROMIDE NaBr. 2 H 2 O.
SOLUBILITY IN WATER.
(Etard Compt. rend. 98, 1432, '84; de Coppet Ann. chim. phys. [5] 30, 411, '83.)
L.O Grams NaBr per 100
Gms. H 2 O.
20
57-5*
7i -4t
O
66
79-5
IO
72
84-5
20
77
90-3
30
82.5
97-3
40
88.0
105.8
t o. Grams NaBr per 100
Gms. H 2 O.
5
95-112*
n6f
60
112
117
80
113
119
IOO
114
121
120
116
124
140
118
. . .
* Etard.
t de Coppet.
Transition temperature for NaBr.2H 2 O NaBr is approximately
50. Kremers Pogg. Ann. 97, 14, '56 gives results which fall near
those of de Coppet for the NaBr.2H 2 O, and near those of Etard for
the NaBr section of the curve.
SOLUBILITY OF SODIUM BROMIDE IN AQUEOUS SOLUTIONS OP
SODIUM HYDROXIDE AT 17.
(Ditte Compt. rend. 124, 30, '97.)
Gms. per 100 Gms. H 2 O. Gms. per 100 Gms. H2O. Gms. per 100 Gms. H->O.
NaOH.
NaBr.
NaOH.
NaBr.
NaOH.
NaBr.
0-0
91 .38
17.17
63.06
28.43
48.00
3.26
79.86
19.12
62 .51
36.61
38.41
9.24
68.85
22-35
59.60
46.96
29-37
13-43
64.90
24.74
55-03
54-52
24.76
SOLUBILITY OF SODIUM BROMIDE IN ALCOHOLIC SOLUTIONS.
(Rohland Z. anorg. Ch. 18 327, '98; Z. anal. Ch. 44, 252, '05; de Bruyn Z. physik. Ch. 10, 783
'92; Eder Dingl. polyt. 221, 89, '75.)
Alcohol.
Methyl Alcohol
Ethyl
Propyl
Ethyl
Methyl
Ethyl
Ethyl Ether
Concentration .
of Aq. Alcohol.
^15 ~- 799 room temp.
90% by vol.
Absolute
J 5
Gms. NaBr
per 100 Gms.
Alcohol.
(R.)
21.7
7.14
2 .OI
4 . o (hydrated NaBr)
17.35 (de Bruyn.)
6.3 (NaBr 2 H 2 0) (Eder.)
0.08
SODIUM CARBONATE
296
SODIUM CARBONATE Na 2 CO 3 .ioH 2 O.
SOLUBILITY IN WATER.
(Mulder; Lowel Ann. chim. phys. [3] 33, 382, '51; at 15, Reich Monatsh. Ch. 12, 464, '91; at
32-34.5 Na 2 COa.7H 2 O b, Ketner Z. physik. Ch. 39, 646, 'oi-'o2.)
Solid Phase:
Na 2 CO 3 .ioH 2 O. Na 2 CO 3 .7H 2 O (6). Na 2 CO 3 .7H 2 O (a),
Gms. Na 2 COs Gms. Na 2 CO3 Gms. Na 2 COa
AO per 100 Gms. per 100 Gms. per 100 Gms.
Water.
Solution.
Water.
Solution.
Water.
Solution.
O
7
.0
6
5
20-4
16
9
32.0
24.2
5
9
5
6
9
23-2
18
.8
35-o
25-9
10
12
5
ii
.1
26.2
20
.8
37-8
27-4
15
16
4
14
.1
29-5
22
.8
41.2
29.2
20
21
5
17
7
33-5
2 5
.1
45-5
31 -3
25
28
.2 (29
.8*)
22 .O
38.0
27
5
30
37
.8(40
9*)
27
4
43-5
30
3
32-5
46
.2
3 1
.6 (32.1
)46.6
31
.8
35
40
46
46
.2
.1 (49
7*)
3 1
.6
(33-3
(34-5
) 48.6
32
33
7
9
60
46
.0 (46
.4*)
31
.5
Solid
Phase Na 2 CO 3 .H 2 O
80
45
8(45
.2*)
3 1
4
IOO
45
5
31
.3
105
45
.2
3 1
.1
* Epple Dissertation, Heidelberg, p. 26, 1899.
Sp. Gr. of solution saturated at 17.5, 1.165 (Hager) ; at 18, 1.172
(Kohlrausch) ; at 23, 1.222 (Schiff) ; at 30, 1.342 (Lunge). See also
Wegschroeder and Waller Monatsh. Chem. 26, 685, '05, for Sp. Gr.
determinations at other temperatures.
SOLUBILITY OF SODIUM CARBONATE IN AQUEOUS SOLUTIONS
OF SODIUM CHLORIDE AT 15.
(Reich.)
Gms. per too
Gms. H 2 O.
Gms. NaCl
per loo
Gms. Na 2 CO 3
per loo Gms.
Gms. per loo Gms. NaCl Gms. Na 2 CO 3
Gms. H 2 O. per IOO pe r IOO Q m s.
NaCl.
Na 2 CO,
,ioH 2
Gms.
Solution.
NaCl
Solution.
NaCl.
Na 2 C03
.ioH 2 O.
Gms.
Solution.
NaCl
Solution .
o.o
61.42
O
.0
16
.42
23.70
39
.06
15
.96
9-76
4-03
53-86
2
.92
14
47
27-93
39
73
18
.26
9.62
8.02
48.00
5
.80
12
.87
3I-65
41
44
20
.06
9-73
12 .02
43-78
8
.61
II
.62
35-46
43
77
21
75
7-95
l6.05
40.96
ii
3i
IO
.70
37-23
45
.27*
22
.46
10.13
19.82
39-46
13
7i
10
.11
* Both salts in solid phase.
SOLUBILITY OF SODIUM CARBONATE IN AQUEOUS SOLUTIONS
OF ETHYL AND OF PROPYL ALCOHOL AT 20.
(Linebarger Am. Ch. J. 14, 380, '92.)
Gms. Na 2 CO 3
Gms. Na 2 CO 3
Wt. per cent
Alcohol.
per loo Gms. Sol.
Wt. per cent
Alcohol.
per loo Gms. Sol.
In Ethyl. In Propyi'.
In EthyL In Propyi.
28
4.4
48
0.9 1.3
38
2.7
50
84 1.2
44
1.7 1-7
54
O-8o O-9
46
62
0-4
C 2 H 5 OH.
Na 2 C0 3 .
H 2 0.
C 2 H 5 OH.
Na 2 CO 3 .
H 2 O.
35
62.9
o-3
3 6.8
I .0
32-4
66.6
40
61 .0
0-4
3 8.6
I .2
31-9
66.9
49
61 .0
0-4
3 8.6
I .2
31-5
67-3
68
55-8
0-9
43-3
2-3
28.8
68.9
31-2
52-4
0.8
46.8
29-3
3 r -9
54-8
o-7
44-5
i-7
29.8
68.5
32-3
56.1
0.6
43-3
i-5
30.2
68.3
33-2
58.1.
o-5
42.4
1.4
31.0
67.6
297 SODIUM CARBONATE
SOLUBILITY OF SODIUM CARBONATE IN AQUEOUS SOLUTIONS OF
ETHYL ALCOHOL.
(Ketner Z. physik. Ch. 39, 646, 'oi-'o 2 .)
NOTE. The mixtures were so made that an alcoholic and an
aqueous layer were formed, and these were brought into equilibrium
with the solid phase.
Cms. per 100 Cms. Alcoholic Layer. Cms. per 100 Cms. Aq. Layer.
> * . *
Phase.
N a2 C0 3 .H 2
Na 2 C0 3 .7H 2 O (b)
27.7 Crit.sol.i 4 % C 2 H 5 OHi 3 % Na 2 CO 3 73 % H 2 O
28.2 23.5 7.3 69.2 7.9 18.6 73.5 Na 2 C0 3 .ioH 2
29.0 32.7 3.8 63.5 4.3 22.7 73.0
29.7 40-0 2.1 57.9 2.9 25.5 71.6
30.6 47.8 1.2 51.0 2.3 27.8 69.9
SOLUBILITY OF Na 2 CO 3 .ioH 2 O IN DILUTE ALCOHOL AT 21.
(Ketner.)
Grams per loo^Grams Solution. Grams per 100 Grams Solution.
Na 2 CO 3 . C 2 H 6 OH. HbO. Na 2 CO 3 . C 2 H 5 OH. H^O.
18.5 o.o 81.5 1.2 39-2 59-6
12.7 6.2 81.1 0.2 58.2 41.6
6-9 J 5-3 77-8 o.i 67.1 32.8
3.2 26.1 70.7 0.06 73.3 26.64
100 gms. saturated solution in glycol contain 3.28-3.4 gms. sodium
Carbonate. (d e Coninck Bull. acad. roy. Belgique, 359, '05.)
ioo gms. H 2 O dissolve 229.2 gms. sugar + 24.4 gms. Na 2 CO 3 , or
100 gms. sat. aq. solution contain 64.73 g ms - sugar + 6.89 gms. Na 2 CO 3 .
(Kohler Z. Ver. Zuckerind. 47, 447, '97.)
SODIUM (Bi) CARBONATE NaHCO 3 .
SOLUBILITY IN WATER.
(Dibbits J. pr. Ch. [2] 10, 439, '74.)
Gms. NaHCO 3 per ioo Gms Gms. NaHCO per ioo Gms.
i
Water.
Solution.
Water.
Solution
o
6. 9
6-5
30
II .1
IO.O
10
8.1 5
7-5
40
12-7
"3
20
9 .6
8.8
5
14-45
12.6
25
9-4
60
l6-4
13-8
Sp. Gr. of sat. solution at 16 = 1.069. (Stoiba.)
ioo gms. alcohol of 0.941 Sp. Gr. dissolve 1.2 gms. NaHCO 3 at 15.5.
ioo gms. glycerine dissolve 8 gms. NaHCO 3 at 15.5.
SODIUM (Bi) CARBONATE 298
SOLUBILITY OF SODIUM BICARBONATE IN AQUEOUS AMMONIUM
BICARBONATE SOLUTIONS SATURATED WITH CO 2 .
(Fedotieff Z. physik. Ch. 49, 169, '04.)
Wt. of i cc. Mols.per lopo Gms.H2O. Grams per 1000 Gms. H2O.
alution.
' NHiHCOs.
NaHCO 3 .
NH,HC0 3 .
NaHC0 3 .
1.072
i-39
0.58
109.4
48.2
o.o
0.82
o.o
69.0
056
o.o
1.05
o.o
88.0
O6l
0.29
o-95
23.0
80.0
.065
0.56
0.89
44-o
74-6
073
1. 08
0.79
85-7
66.7
090
2.16
0.71
170.6
59-2
o.o
1.65
o.o
138.6
2.91
0.83
23.0
70.0
30
SOLUBILITY OF SODIUM BICARBONATE IN AQUEOUS SOLUTIONS
OF SODIUM CHLORIDE SATURATED WITH CO 2 .
(Fedotieff; see also Reich Monatsh. Ch. 12, 464, '91.)
ft o Wt. Of I CC.
Mols.per io<
x) Gms.HaO. Grams per 1000 Gms. H2
Solution.
NaCl.
NaHCO 3 .
NaCl.
NaHC0 3 . '
o
o.o
0.82
o.o
69.0
.208
6.0
O.O9
350 - 1
7-7
15
.056
o.o
1.05
o.o
88.0
.063
0.52
0.82
30.2
68.6
073
1.03
0.64
60. 1
53-6
tt
.096
2 .11
0.41
123.1
34-8
ii
.127
3-20
0.28
187.2
23.0
tt
.158
4-39
0.19
256-9
16.1
11
.203
6.06
O-I2
354-6
10.0
30
.066
o.o
I .31
o.o
IIO. 2
.079
I .02
0.87
59-9
72.8
u
.100
2.08
0.56
121 .9
47-3
u
.127
3 .l8
0.38
186.3
32.0
"
.156
0.27
256.0
22.3
tt
.199
6.12
0.17
358.1
13-9
45
.077
o.o
1.6 5
o.o
138.6
n
.086
1.04
I .12
60.7
94-o
11
.115
2 -65
0.62
155-2
52-0
(i
.127
3-24
0.52
189.4
43-4
"
155
4.38
o-37
256.1
30-7
.198
6.18
0.23
361-5
19.5
loo grams alcohol of 0.941 Sp. Gr. dissolve 5.55 grams sodium
sulpho carbonate at 15.5.
SODIUM CHLORATE NaClO 3 .
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 97, 4, '56.)
A o Grams per 100 Grams . Grams per 100 Grams
Water. Solution. Water. Solution.
o 81.9 45 .o 60 147 .1 59.5
12 89.3 47-2 80 175.6 63.7
20 99-0 49-7 IOO 232.6 69.9
40 123.5 55.3 120 333.3 76.9
299 SODIUM CHLORATE
SOLUBILITY OF SODIUM CHLORATE IN AQUEOUS SODIUM CHLORIDE
SOLUTIONS AT 20.
(Winteler Z. Electrochem. 7, 360, 'oo.)
Volume Wt. Grams per Liter. Volume Wt. Grams per Liter.
of Solutions. NaCL NaClOa. of Solutions. NjJcT NaClOa-
1.426 5 668 1.365 175 393
1.419 25 638 1.345 200 338
1.412 50 599 1.319 225 271
1.405 75 559 1.289 250 197
1.398 loo 522 1.256 275 120
1.389 125 484 1.235 290 78
1.379 150 442 1.217 300 55
loo gms. H 2 O dissolve 24.4 gms. NaCl + 50.75 gms. NaClO, at 12.
loo gms. H 2 O dissolve 11.5 gms. NaClH- 249.6 gms. NaClO 3 at 122.
(Schlosing Compt. rend. 73 1273. *7i-)
loo gms. alcohol of 77 Wt. per cent dissolve 2.9 gms. NaClO 3 at 16.
(Wittstein.)
loo gms. alcohol dissolve i gm. NaClO 3 at 25, and 2.5 gms. at b. pt.
loo gms. glycerine dissolve 20 gms. NaClO 8 at 15.5.
SODIUM CHLORIDE NaCl.
SOLUBILITY IN WATER.
(Mulder ; de Coppet Ann. chim. phys. [5] 30, 411, '83; Andrae J. pr. Ch. [2] 29, 456, '84; above
100, Tilden and Shenstone Phil. Trans. 23, '84; Berkeley Trans. Roy. Soc. (Lond.) 203 A, 206,
'04; Etard Ann. chim. phys. [7] 2, 527, '94, gives irregular results.)
t o Gms. NaCl per Gms^NaCl Gms. NaCl per Gms-Naa
iooGms,H 2 0. joo ^ Sol IPO Gms. H 2 O. ^^
o 35-7* 35- 6 3t 26.28! 70 37-3* 37-5 1 ! 27^
10 35 - 8 35-69 26.29 80 38.4 38.00 27.54
20 36.0 35.82 26.37 90 39.0 38.52^ 27.80
25 36-12 35.92 26.43 zoo 39.8 39-12! 28.12
30 36.3 36.03 26.49 II8 39-8 28.46
40 36.6 36.32 26.65 I 4 42.1 29.63
50 37-o 36-67 26.83 160 43-6 30.37
60 37-3 37-o6 27.04 180 44.9 30-98
* M.; de C. t A. t B.
SOLUBILITY OF SODIUM CHLORIDE IN AQUEOUS SOLUTIONS OP
AMMONIUM CHLORIDE.
(Fedotieff Z. physik. Ch. 49, 170, '04.)
o Wt. of i cc. Mols. per 1000 Gms. H2O. Grams per 1000 Gms. H2O.
Solution. ' NH 4 C1. NaCl! NH 4 C1. NaCl'.
o ... o.o 6.09 o.o 356.3
" 1-185 2-73 4.89 I46.I 286.4
15 1.200 o.o 6.12 o.o 357-6
1.191 1.07 5.58 57.3 326.4
" I-l83 2.22 5.13 Il8-9 3OO.O
" I.I76 3-48 4-64 186.4 271.6
" I.I75 3.72 4.55 198.8 266.8
30 ... o.o 6.16 o.o 360.3
1.166 4.77 4-26 255.4 249.0
45 ... o.o 6.24 o.o 365-0
" ... 6.02 4.0 322.1 233.9
SODIUM CHLORIDE
300
SOLUBILITY OF SODIUM CHLORIDE IN AQUEOUS SOLUTIONS OF
HYDROCHLORIC ACID.
(Engel Ann. chim. phys. [6] 13, 374, '88; Enklaar Rec. trav. chim. 20, 183, 'or.)
At . .(Engel.) At io-io.5. (Enklaar.)
Mg. Mols. per 10 cc. Sp. Gr. of Gms. per Liter. Mols. per Liter. Grams per Liter.
HC1.
NaCl.
Solution.
HCl.
NaCl.
HCl.
NaCl.'
HCl.
NaCl.
o.o
54-7
I
.207
O
O
32.0
o.o
6. ii
o
O
35-77
I .0
53-5
j
204
365
31-3
0.27
5-77
9
.84
33-76
1.85
52.2
j
2O2
O
.674
30-5
o-35
5-67
12
>7 6
33-19
5- 1
48-5
I
.196
I
859
28.4
o-43
5-59
15
.68
32.71
9.28
44.0
I
.185
3
38
25-7
o-57
5-43
20
.78
31-77
J5-05
37-9
I
173
5
49
22.2
0.72
5-28
26
.06
30.89
30-75
23-5
I
.141
ii
.20
13-7
2 .60
3-42
94
77
20. 01
5 6 -35
6.1
I
.119
20
54
3-6
2.8o
3.18
IO2
.1
19.04
3-31
2.74
120
.6
16.03
SOLUBILITY OF MIXTURES OF SODIUM CHLORIDE AND OTHER
SALTS IN WATER, ETC.
Gms. per 100 Gms. Solvent. Authority.
(Karsten.)
(Soch J. Physic. Ch. 2, 46, '98.)
(Quoted by Euler Z. physik. Ch.
49, 3i5. '04.)
* Sp. Gr. of solution at 17 = 1.179.
SOLUBILITY OF MIXTURES OF SODIUM CHLORIDE AND POTASSIUM
SULPHATE IN WATER AT VARIOUS TEMPERATURES.
(Precht and Wittgen Ber. 15, 1666, '82.)
Solvent.
t .
Water
17
u
17
u
p
It
25
(I
80
Alcohol (40%)
25
Water
20
Of*
17
t
26
4
NaCl+22.iNH 4 Cl*
17
34
5
u
+ 4.iBaCl 2
?
38
3
Cl
+ 2 9 . 5 KN0 3
25
38
5
(t
+ 41-14 " .
80
39
,81
(t
+ 168.8 "
25
J 5
.78
(t
+ 13-74 "
20
30
54
(I
+ I3-95KC1 j,
25
28
.90
(I
+ 16.12 " J
^o Grams per ipo
Grams H 2 O. t o
Grams per 100 Grams H 2 O.
' NaCl
K 2 S0 4
KU
NaCl
K 2 S0 4
KCt
10
33-4
8
.1
3
.2
60
36
4
II
9
2-7
20
34-o
8
9
3
.1
70
36
.6
12
.8
3-2
30
34-6
9
.6
2
9
80
36
.0
12
3
5.1
40
35-2
10
4
2
.8
9o
35
9
12
4
7-o
50
35-8
ii
.1
2
.8
IOO
35
.6
12
.6
8.8
SOLUBILITY OF SODIUM CHLORIDE IN AQUEOUS SOLUTIONS OF
SODIUM BICARBONATE SATURATED WITH CO 2 .
(Fedotieff.)
Grams per 10000 Gms. H2O.
.o Wt. Of I CC.
Mols. per 1000
Gms. Hj
Solution.
NaHC0 3 .
NaCl.
O-O
6.09
81
79-8 27.1
3* -5
47-05
9.90
93
81.19 29.6 Na 2 Cr 2 O7
36
47.98
10-2
98
81.25 29.8
40
48.97
10.6
/
Sodium Tri Chromate.
A
so .20
ii .6 "
"J
Gms. Na 2 Mols. Na 2
49-5
50-93
11.5
to
Cr 3 O, per Cr 3 Oi per Solid
54-5
52.28
12.2 "
100 Gms. 100 Mols. Phase.
Solution. H 2 O
59-5
53-39
12-7
80.03 *9 9 Na 2 Cr 3 O l0 .H 2 O.
65
55-23
13-7 Na 2 Cr0 4
I5t
80 . 44 20.4
7o
55-J5
I 3 .6
18
80-60 20.56
80
55-53
I 3 .8
55
82.68 23.7
100
55-74
I4.O
99
85.78 29.9
*Sp. Gr. of sat. sol. at 18 = 1.432. tSp. Gr. of sat. sol. at 18 = 2.059.
jSp. Gr. of sat. solution at 18 = 1.745.
SODIUM CHROMATES 3
Sodium Tetra Chromate.
tv
Gms.
per ioo Gms.
Solution.
Mols.
Na 2 Cr 4 O J3
per ioo
Mols.H 2 0.
Solid
Phase.
o
16
18*
22
72.96
74.19
74.60
76.01
10-5
II .2
II .27
I2. 3
Na 2 Cr 4 0, 3 . 4 H 2
M
34
Tetra Sodium Chromate.
Gms. Mols.
Na 4 CrO 5 Na 4 CrO 6
per ioo Gms. per ioo
10
i8f
27.7
37
Solution.
35-58
37-50
40.09
45 :i 3
Viols. H 2 O.
4-II
4.42
4.8l
5-38
6.62
Solid
Phase.
* Sp. Gr. of sat. solution at 18= 1.926.
t Sp. Gr. of sat. solution at 18 = 1.446.
SOLUBILITY OF SODIUM CHROMATES IN WATER AT 30.
(Schreinemaker Z. physik. Ch. 55, 91, '06.)
Composition in weight per cent :
Of Solution. Of Residue.
%Cr0 3 -
%Na 2 0.
%Cr0 3 .
%Na 2 0.
Solid Phase.
O
42
. . .
NaOH.H 2 O
2 .OO
41.44
5*8 3
42.64
NaOH.H 2 O + Na 2 CrO 4
2.04
40-89
. . .
Na 2 Cr0 4
4-23
35-5 1
27.52
36.57
"
6.64
32-34
27.72
34.60
"
IS -!9
27.06
37-07
32.20
"
IO.22
29-39
I5-48
28.41
Na 2 CrO 4 + Na 4 CrO 6 .i3H 2 O
8-93
28.49
18.09
26.89
Na 4 CrO 6 .i 3 H 2
8.62
26.91
"
13.12
23.91
18.57
25.92
18.44
22.86
. . .
it
19.26
22.98
21.54
25-3I
N^CrOs.isH-zO + Na 2 CrO 4 . 4 H 2 O
17.84
24.21
26.24
24-98
N a2 Cr0 4 . 4 H 2 O
28.82
17.88
31-97
23-47
"
38.93
16.30
40.70
20-83
"
48.70
16.49
47-49
19-75
Na 2 CrO 4 . 4 H 2 O + Na 2 Cr 2 O7. 2 H 2 O
50.68
15-72
Na 2 Cr 2 7 .2H 2 O
58.08
13.89
62.76
I7-38
"
66.13
13.70
69.48
16.06
Na 2 Cr 2 O 7 .2H 2 O + Na 2 Cr3Oio.H 2 O
65.98
J4-I5
69.46
I5-I5
Na 2 Cr3O 10 .H 2
68.46
10.95
73-88
I3-38
Na 2 Cr 3 Oio.H 2 O + Na 2 Cr 4 Q l3 -4H 2 O
66.88
9-85
71.27
10.67
Na 2 Cr 3 O, 3 .4H 2 O
70.06
11.85
83-95
9-57
" (?)
69.04
ii .04
81.80
6-43
CrOa
67.84
9.81
82.85
5-42
64.48
4-5i
79-49
2.71
62.28
o.o
100.00
"
ioo gms. of a saturated aqueous solution contain at 30:
46.627 gms. Na 2 CrO 4 , or ioo gms. H 2 O dissolve 87.36 gms. Na-jCrO,.
66.4 gms. Na 2 Cr 2 O 7 , or ioo gms. H 2 O dissolve 197.6 gms. Na 2 Cr 2 O 7 .
ioo gms. absolute methyl alcohol dissolve 0.345 gm. Na 2 CrO 4 at 25.
(de Bruyn Z. physik. Ch. 10, 783, '93.)
305 SODIUM CITRATE
SODIUM CITRATE 2C 3 H 4 (OH)(COONa) 3 .nH 2 O.
100 gms. H 2 O dissolve 90.9 gms. citrate at 25, and 250 gms. at b. pt.
(U-S.P.)
SODIUM (Ferro) CYANIDE Na 4 Fe(CN) 6 .
SOLUBILITY IN WATER.
(Conroy J. Soc. Chem. Ind. 17, 104, '98.)
t 20. 4 2. 80. 98.5.
Gms. Na 4 Fe(CN) 6 per ioo gms. H 2 O 17.9 30.2 59.2 63.0
SODIUM FORMATE HCOONa, SOLUBILITY IN WATER.
(Groschuff Ber. 36, 1788, '03.)
Gms. Mols. Gms. Mols.
t o HCOONa HCOONa Solid t o HCOONa HCOONa Solid
' per ioo Gms. per ioo Mols. Phase. periooGms per ioo Mols. Phase.
Solution. H 2 O. Solution. H 2 O.
20 22.8o 7.82 HCOONa.sH 2 O 25.5 50.53 27.0 HCOONa.aH 2 O
O 30.47 II. 6 " l8 49.22 25 65 HCOONa
+ 15 41.88 19.1 29 50.44 26.9
18 44.92 21.6 " 54 53.80 30.8
l8 44-73 21-4 HCOONa. 2 H 2 O 74.5 56.82 34.8
21 46.86 23.3 100.5 6l -54 42-35
23 48.22 24.65 123 66.20 51-8
Sp. Gr. of the saturated solution of the dihydrate at 18 = 1.317.
SOLUBILITY OF SODIUM ACID FORMATE (EXPRESSED AS NEUTRAL
SALT) IN AQUEOUS SOLUTIONS OF FORMIC ACID.
(Groschuff.)
Gms. Mols. Gms. Mols.
t o HCOONa HCOONa Solid t o HCOONa HCOONa Solid
' per ioo Gms. per ioo Mols. Phase. * per ioo Gms. per ioo Mols. Phase.
Solution. H 2 O. Solution. H 2 O.
O 22.35 19.5 HCOONa-HCOOH 45.5 38.85 43.1 HCOONa
25.5 29.62 28.45 7 41-27 47-5
66.5 41.08 47.1 85 43 .09 51.2
SODIUM FLUORIDE NaF.
ioo gms. sat. aq. solution contain 4.3 gms. NaF at 18. Sp. Gr. of
Solution = 1.044. (Mylius and Funk Ber. 30, 1718, '97.)
SOLUBILITY OF SODIUM FLUORIDE IN AQUEOUS SOLUTIONS OF
HYDROFLUORIC ACID AT 21.
(Ditte Compt. rend. 123, 1282, '96.)
Grams per 1000 Grams H^. Grams per 1000 Grams HgO.
o.oHF~ 41. 7 NaF 83.8 HF 22.9 NaF
io. o " 4i-4 " 129.7 " 23.8 "
45.8 " 22.5 " 596.4 " 48-8 "
56.5 " 22.7 " 777-4 " 8i-7 "
SODIUM FLUO SILICATE Na 2 SiF 6 .
ioo gms. H 2 O dissolve 0.65 gin. at 17.5, and 2.45 gms. at 100.
(Stolba Z. anal. Ch. n, 199, '72.)
SODIUM HYDROXIDE
306
SODIUM HYDROXIDE NaOH.
SOLUBILITY IN WATER.
(Pickering J. Ch. Soc. 63, 890, '93; Mylius and Funk (Dietz) Wiss. Abh. p. t. Reichamstalt 3, 450, 'oo.)
Gms. NaOH
to per ioo Gms.
Solution.
Water.
- 7.8
8.0
8. 7
20
16.0
19.1
-28
19.0
23-5
24
22.2
28-5
-17.7
24-5
32-5
29.6
42 .O
+ 5
32.2
47-5
10
34-o
51 .5
15-5
38-9
6 3-53
5
45-5
83-5
12
50.7
103.0
Solid
Phase.
Ice
Ice + NaOH. 7 H 2 O
NaOH. 7 H 2 + NaOH. S H 2 O
NaOH. 5 H 2 + NaOH^HijO a
NaOH. 4 H 2 a
NaOH. 4 H 2 a+ NaOH 3 iH 2 O
NaOH. 3 iH 2 O
f. pt.
NaOH.aiHjsO + NaOH.2H.zO
NaOH. 2 H 2 + NaOH.H 2
20
30
40
50
60
80
no
192
Gms. NaOH
per ioo Gms.
Solid
Phase.
NaOH.H 2 O
Solution.
52.2
Water.
109
54-3
56.3
119
129
59-2
63-5
i74
M
69.0
74.2
222.3
288
NaOH^H 2
+ NaOH
75-8
78.5
313
365
NaOH (?)
83 -9
521
Sp. Gr. of sat. solution at 18 = 1.539.
For determinations of the Sp. Gr. of sodium hydroxide solution, see
Kohlrausch Wied. Ann. i, 1879; Wegschnider and Waller
Monatsh. Chem. 26, 685, '05.
SODIUM IODATE NaIO 3 .
SOLUBILITY IN WATER.
(Gay-Lussac; Kremers Pogg. Ann. 97, 5, '56.)
t. o. 20. 40. 60 80. 100.
Gms. NaIO 3 per ioo gms. H 2 O 2.5 9 15 21 27 34
SODIUM IODIDE NaI. 2 H 2 O.
SOLUBILITY IN WATER.
(de Copper Ann. chim. phys. [5] 30, 411, '83; see also Etard Compt. rend. 98, 1434, '84; and Kremers
Pogg. Ann. 97, 14, '56.)
t
Grams Nal
per ioo Gms. Solid
t
Grams Na!
[ per ioo Gm
's- Solid
Water.
Solution. Phase.
Water.
Solution.
Phase.
20
148.0
59 . 7 NaI.2H 2 O
60
256.8
72.0
NaI. 2 H 2 O
O
158.7
61.4
65
278.4
73-6
"
10
168.6
62.8
6 7
293
74.6
Nal
2O
178.7
64 . 1
70
294
74.6
"
25
184.2
64.8
80
296
74-7
"
30
190.3
65.6
IOO
302
75 .1
"
40
205.0
67.2
at
Absolute Ethyl Alcohol
d, 5 0.8 10 Ethyl Alcohol
Absolute Methyl Alcohol
d 15 o. 799 Methyl Alcohol
d ls 0.816 Propyl Alcohol
VJIHS. ouiveiu
22.5 43.1
ord. temp. 58.8
22.5 77.7
ord. temp. 83.3
ord. temp. 26.3
Acetonitril
Propionitril
Nitro Methane
Acetone
Furfurol
at o. at 25.
22.09 18.43
9.09 6.23
0.34 0.48
very soluble
25.10
SODIUM MOLYBDATE
SODIUM MOLYBDATE Na 2 MoO 4 .
SOLUBILITY IN WATER.
4
6
9
10
Cms.
Na 2 MoO 4
per 100
Cms.
Solution.
35-58
38.16
39.28
Mols.
Na 2 MoO 4
per 100
Mols.
H 2 0.
(Funk Ber. 33, 3697, 'oo.)
Solid
Phase.
3.86Na 2 Mo0 4 .ioH 2 15.5
4-47 18
4-83 32
5-39 5i-5
5 .65 Na 2 MoO 4 .2H 2 O IOO
Cms.
Na 2 Mo0 4
per loo
Cms.
Solution.
Mols.
Na 2 MoO 4
per TOO
Mols.
H 2 0.
Solid
Phase.
39-27
5 .65 Na 2 Mo0 4 .2ll2O
39-40
39.82
41.27
5-70
5-78
6.14
45-57
7-32
11
zoo gms. H 2 O dissolve 3.878 gms. sodium tri molybdate Na 2 Mo 3 O 10
at 20, and 13.7 gms. at 100.
(Ullik Liebig's Ann. 144, 244, '67.)
SODIUM NITRATE NaNO 3 .
SOLUBILITY IN WATER.
(Mulder; Berkeley Trans. Roy. Soc. (Lond.) 203 A, 211, '04; see also Ditte Compt. rend. 80, 1164,
'75; Maumee Ibid. 58, 81, '64; Etard Ann. chim. phys. [7] 2, 527, '94.)
Gms. NaNO 3 per 100 Gms. Mols. per
to
Gms. NaNO 3 per 100 Gms.
Mols. per
t
Solution.
Water.
Liter.
42.2
72.9- 73.0*
6.71*
80
IO
44-7
80.8- 80.5
7 .l6
IOO
20
46.7
87.5- 88.0
7 .6o
120
2 5
47.6
91.0- 92.0
7 .8o
180
30
48.7
94.9- 96.2
8.06
220
40
50-5
102.0-104.9
8.51
225
50
52.8
112.0-114.0
8.97
313
60
54-9
122.0124.0
9.42
Solution. Water. Liter.
7 148.0-148.0* 10.35*
3 180.0-175.8 11.30
68.6 2l8. 0-208. 8t I2.22f
i 35 6 -7
5 5o 6 -o
5 1076.0
00
59-
64.
78.
83.
pt. 100.0
* Berkeley.
t "9
SOLUBILITY OF SODIUM NITRATE IN AQUEOUS SOLUTIONS OF
NITRIC ACID AT o.
(Engel Compt. rend. 104, 911, '87; see also Schultz Zeit. Ch. [2] 5, 531, '62.)
Equivalents per 10 cc. Solution,
NaN0 3 .
HNO 3 .
66.4
O
63-7
2 .65
60.5
5-7
5 6 -9
8.8
52-75
12-57
48-7
16.9
39-5
27.0
35- 1
32-25
3 1 - 1
37-25
23-5
48.0
18.0
57-25
12.9
71.0
p. Gr. of
Grams per i
oo cc. Solution.
olutions.
NaNO 3 .
HN0 3 .
I-34I
56.5
O-OO
I-338
54-2
1.6 7
51.48
3-59
324
48.42
5-55
.312
44-88
7-92
.308
41.44
10.65
.291
33 - 6l
17.02
.285
29.86
20-33
.282
26.46
23-48
I .276
20. o
30.26
I .276
I5-32
36.09
I .291
10.97
44.76
SODIUM NITRATE 308
SOLUBILITY OF MIXTURES OF SODIUM NITRATE AND POTASSIUM
NITRATE IN WATER AT 20.
(Carnelly and Thomson J. Ch. Soc. 53, 709, '88.)
NaNC^n Gms ' *F ' Gms ' NaNcSn Gms " P ' Gms '
Mixtures H2 - t Mixtures Hz P- _
Used. NaNO 3 . KNO 3 . Used. NaNO 3 . KNOa.
ioo 86.8 o 45-7 53-3 34-7
90 96.4 13.2 40 45-6 35-5
80 98.0 38.5 20 20.8 33.3
60 90.0 47.6 10 9.4 31.5
50 66. o 40.0 o o.o 33-6
ioo gms. H 2 O dissolve 24.9 gms. NaCl + 53.6 gms. NaNO 3 at 20.
(Rxidorff Ber. 6, 484, '73; Karsten; Nicol Phil. Mag. [5] 31, 386, '91.)
SOLUBILITY OF SODIUM NITRATE IN AQUEOUS SOLUTIONS OF
SODIUM HYDROXIDE AT o.
(Engel Bull. soc. chim. [3] 6, 16, '91.)
Milligram Mols. per 10 Sp. Gr. Grams per ioo cc.
cc. Solution. o f . Solution.
Na 2 O. NaNOjj," Solutions. NaOH. NaNO 3 '.
o.o 66.4 1-341 o.o 56-50
2.875 62.5 1.338 2.30 53.19
6.1 57-15 1-333. 4-89 48-63
12.75 47-5 J -3 2 7 10-21 40-42
26.0 29.5 1.326 20.83 25.10
39-o 17-5 x -33 2 3 I - 2 5 J 4.89
45.88 13.19 1.356 36.76 11.22
60.88 6.05 1.401 48-75 5-15
SOLUBILITY OF SODIUM NITRATE IN ALCOHOLS.
ioo gms. abs. methyl alcohol dissolve 0.41 gm. NaNO 3 at 25.
ioo gms. abs. ethyl alcohol dissolve 0.036 gm. NaNO 3 at 25.
(de Bruyn Z. physik. Ch. 10, 783, '92.)
SOLUBILITY OF SODIUM NITRATE IN AQUEOUS ETHYL ALCOHOL
AT DIFFERENT TEMPERATURES.
(Bodlander Z. physik. Ch. 7, 317, '91; Taylor J. Physic. Ch. i, 723, '97; Bathrick Ibid. I, i62,"'96,)
Results at 13 (B.).
Sn Gr of Gms. per ioo cc. Solution.
Results at 16.5 (B.).
So Gr.of Gms. per ioo cc. Solution.
Solutions.
C 6 H 6 OH.
H 2 0.
NaN0 3 .
Solutions.
C 6 H 5 OH.
H 2 0.
NaNO 3 .
1.3700
.0
75-34
61
.66
I
3745
o.o
75
25
62 -2O
1-3395
3
.08
73-53
57
34
I
.3162
6.16
70
.82
54-64
1.3120
6
.01
71.81
53
39
I
.2576
II .60
68
.10
46.06
1.2845
8
30
70.85
49
30
I
.2140
16.49
65
.04
39-87
i .2580
10
.91
69.47
45
.42
I
.1615
22.17
61
.67
32-3 1
1-2325
13
77
67.12
42
36
I
0855
32.22
52
.92
23-4I
i .2010
16
.46
66.16
37
.48
I
0558
37-23
48
50
19.85
I
.0050
43-98
42
.78
13-74
O
.9420
52.60
32
13
9-47
O
.9030
6o.OO
2 5
65
4-65
.8610
63.16
21
31
1.63
39
SODIUM NITRATE
Results at 30 (T.).
Wt. per cent
Alcohol in
Gms. NaNO 3
per ioo Gms.
Solvent.
Solution.
Water-
O
49-10
96-4S
5
46.41
9 I - I 5
10
43-50
85-55
20
37-42
74-75
30
3I-3I
65.10
40
25.14
55-95
50
18.94
46.75
60
12-97
37-25
70
7 .8l
28.25
90
I .21
12 .25
Results
at 40.
(Bathrick.)
Wt.
per cent
Alcohol.
Cms. NaNOa
per ioo Gms.
Aq. Alcohol.
O
104-5
8.22
90-8
17.4
73-3
26.O
6l.6
36.0
48.4
42.8
4O.6
55-3
27.1
65.1
18.1
77.0
9-4
87.2
4.2
SOLUBILITY OF SODIUM NITRATE IN AQUEOUS SOLUTIONS OF
ACETONE.
Results at 30.
(Taylor.)
Results at 40.
(Bathrick.)
Wt. per cent
Acetone in
Gms. NaNO 3
per ioo Gms.
Solvent.
Solution.
Water.
49-10
96.45
5
46.96
93-20
9.09
45 - 11
90.40
2O
40.10
83.70
30
35-o8
77-20
40
29.80
70-75
50
24-34
64.40
60
18.55
59-95
70
13 .15
50-50
80
7.10
38-20
90
1.98
20.20
Wt.
per cent
Acetone.
O-O
8.47
16.8
25.2
34-3
44-i
53-9
64.8
76.0
87.6
Gms. NaNOa
per ioo Gms.
Aq. Acetone.
91
78.
66.4
57-9
46.2
32.8
23.0
10.8
3-2
SODIUM NITRITE NaNCX.
ioo gms. H 2 O dissolve 83.3 gms. at 15.
(Divers J- Ch. Soc. 75, 86- '00}
ioo gms. abs. methyl alcohol dissolve 4.43 gms. NaNO 2 at 19.5.
ioo gms. abs. ethyl alcohol dissolve 0.31 gm. NaNO 2 at 19.5.
(de Bruyn Z. physik. Ch. 10, 783, 92.)
SODIUM RHODO NITRITE Na 6 Rh 2 (NO 2 ) 12 .
ioo gms. H 2 O dissolve 40 gms. at 17, and ioo gms. at 100.
(Leidie Compt. rend. HI, 107, '90.)
SODIUM OXALATE C 2 O 4 Na 2 .
SOLUBILITY IN WATER.
(Souchay and Leussen Liebig's Ann. 99, 33, '56; Pohl J. pr. Ch. 56, 216, '52.)
t. 15.5. 21 3. 100.
Gms. Na 2 C 2 O 4 per ioo gms. H 2 O 3.22 3 . 74 6 .33
SODIUM OXALATE 310
SOLUBILITY OF MIXTURES OP SODIUM OXALATE AND OXALIC
ACID IN WATER AT 25.
(Foote and Andrew Am. Ch. J. 34, 154. 'S-)
Gms. per 100 Gms. Mols. per too Mols.
Solution. H 2 Q.
Na 2 C 2 4 . H 2 C 2 4 . Na 2 C 2 O 4 .
IO-2O ... 2 .274 . . . H 2 C 2 O 4 .2H2O
10.50 0.83 2.370 0.130 H 2 C 2 O 4 . 2 H 2 0+HNaC 2 O 4 .H2O
9.15 0.71 2.032
0.47 3. 20 0.098
0.42 3.85 0-090 0.541 HNaC 2 O 4 .H 2 O + N a2 C 2 O 4
3 . 60 ... O 502 Na 2 C 2 O 4
SODIUM p NITRO PHENOL C 6 H 4 .ONa(i).NO 2 (4).
SOLUBILITY IN WATER AND IN AQUEOUS NORMAL SOLUTIONS OP
NON ELECTROLYTES.
(Goldschmidt Z. physik. Ch. 17, 154, '95.)
Gms. C 6 H 4 .ONa(i).NO 2 (4) per 100 Gms. Solution in:
23-7
28.6
70 6
Water.
5-597
6.721
7 2
Sp. Gr. of
Mols. per 1000 Mols. H 2 O.
.
*
Solutions.
S0 4
K 2
Na 2
C1 2
Solid Pha.sc.
*4-
4
5-
42
14.
39
51-
83
60.
8
K 3 Na(S0 4 )2+Na 2 SO 4 .ioH 2 O+
KCl-}-NaCl
0.
2
3-
35
12.
78
5
93
60.
36
Na 2 S0 4 .ioH 2 0+KCl+NaCl
o.
4
3-
59
16.
38
40.
75
53-54
Na 2 SO 4 .ioH 2 O+KCl+K 3 Na(SO 4 ) 2
16.
3
4-
72
17-
58
50.
56
63-
42
K 3 Na(SO 4 )2+KCl+NaCl
24.
8
I . 2484
4-
37
20.
00
4 8.
36
64.
01
K 3 Na(SO 4 )d-KCl+NaCl
*i6.
3
16.
29
9-
16
61.
06
53-
93
K 3 Na(S0 4 ) 2 +NaCl+Na 2 SO 4 .ioH 2 O+
24.
5
1.2625
14.
45
9-
90
58.
46
53-
9i
K 3 Na(S0 4 ) 2 4-NaCl+Na 2 S0 4
0.
3
2.
75
25-
77
17.
93
40.95
K 3 Na(S0 4 ) 2 +KCl+K 2 S0 4
25-
I . 2034
2.
94
36.
20
14.
80
48.
06
K 3 Na(S0 4 )2+KCl+K 2 SO 4
*i 7 :
9
1.2474
13.84
0.
62.57
48.
70
Na 2 S0 4 .ioH 2 O+Na 2 SO 4 +NaCl
*3o.
i
I . 2890
50-
4i
10.
08
40.
33
0.
K 3 Na(SO 4 ) 2 +Na 2 S0 4 .ioH 2 O+Na 2 SO 4
21.
4
.
.
46.
61
46.
36
NaCl .2H 2 O+Na 2 SO 4 .ioH 2 O
-23-
7
.
10.
51
39-
58
50.
09
NaC1.2H 2 O+KCl
10.
9
I.
45
30.
68
29.
23
KC1+K 2 SO 4
- 3
16.
25
10.
03
6.
21
K3Na(SO 4 ) 2 +Na 2 SO 4 .ioH 2 O
- 3
16.
24
IO.
03
6.
21
.
K3Na(S0 4 )2-r-K 2 S0 4
-14
i.
39
25-
59
8.
78
32-
94
K 3 Na(SO 4 ) 2 +Na 2 SO 4 .1 oH 2 O+KCl
-14
i.
39
25-
59
8.
78
32-
94
K 3 Na(SO 4 ) 2 +K 2 SO 4 +KCl
-23-
3
0.
15-
44-
20
58.
97
Na 2 SO 4 .ioH 2 O+KCl+NaC1.2H2O
* Indicates transition points.
3*3
SODIUM SULPHATE
SOLUBILITY OF SODIUM SULPHATE IN AQUEOUS SOLUTIONS OP
SULPHURIC ACID.
(D'Ans, Shepherd and Giinther Z. anorg. Chem. 49, 356-61, '06.)
Cms. per 1000 Cms. Solution. Mols. per 1000 gms. Solution
H,S0 4
Na 2 S0 4
H 2 SO 4
Na 2 S0 4
0.0
2IQ.O
0.0
I.54I
28.1
237-4
0.286
1.671
33-2
247-5
0.338
1.742
86.7
320.7
0.884
2.256
154.6
335-8
1.576
2.363
163.5
346.4
1.666
2-437
256.3 297.4
Solid Phase.
Na 2 SO 4 10 H 2
Na 2 S0 4 10 H 2 O + Na 2 S0 4
Na 3 H(S0 4 ) -H 2 + Na 2 SOi
Na 3 H(SO 4 ) 2 +Na 2 S0 4
2.611 2.091 Na 3 H(SO 4 ) 2 + Na 3 H(S0 4 ) 2 - H 2 O
SOLUBILITY OF SODIUM SULPHATE IN AQUEOUS SOLUTIONS OF
SODIUM CHLORIDE AT DIFFERENT TEMPERATURES.
(Seidell Am. Ch. J. 27, 52, '02.)
Results at 10.
Results at 21.5'
Results at 27.
Sp. Gr. Gms. per 100 Gms.
of H 2 O.
Sp. Gr. Gms. per 100 Gms.
of H 2 0.
Sp. Gr. Gms. per 100 Gms.
of HaO-
Solutions. NaCl. Na 2 SO 4 ."
Solutions. Nad. Na 2 SO 4 .'
Solutions. Nad. NaabCv
.080 o.o 9.14
1.164 o.o 21.33
1.228 o.o 31-10
.083 4.28 6.42
1.169 9-05 x 5-48
1.230 2.66 28.73
.IO2 9.60 4-76
1.199 17.48 13.73
.230 5.29 27.17
150 J 5-65 3-99
1.214 20.41 13-62
.235 7 .90 26.02
.164 21.82 3.97
1.243 26-01 15.05
.259 16.13 24.83
1.192 28.13 4-i5
1.244 26.53 14.44
.253 18.91 21.39
1.207 3 - 11 4-34
1.244 27.74 13.39
.249 19.64 20. i i
1.217 32.27 4.59
1.244 3*-25 10.64
.245 20.77 *9-29
1.223 33.76 4.75
1.243 31.80 10.28
238 32-33 9-53
1.245 32.10 8.43
1.219 33.69 4.73
I. 212 34.08 2.77
1.197 35-46 o.oo
Results at 30.
Results at 33.
Results at 35.
Sp. Gr. Gms. per TOO Gms.
of H 2 O.
So Gr Gms. per 100 Gms.
of ' HzO.
Sp. Gr. Gms. per 100 Gms.
of H 2p-
Solutions. NaCl. Na 2 SO 4 .
Solutions. NaCl. Na 2 SO 4 .
Solutions. Nad. Na 2 SO
1.281 o.o 39-7o
1.329 o.o 48.48
.324 o.o 47-94
1.282 2.45 38.25
1.323 1.22 46.49
.314 2.14 43.75
1.284 5.61 36.50
1.318 1.99 45 .16
.256 13-57 26.26
1.290 7.91 35.96
1.315 2.64 44-09
.238 18.78 19.74
1.276 10.61 31-64
1-309 3-47 42-6i
.231 31.91 8.28
1.270 12.36 29.87
1.265 12.14 2 9-32
193 35-63 o.oo
1.258 15.65 25.02
1.237 21.87 l6 -83
1.249 18.44 21.30
1.234 32.84 8.76
1.244 20.66 19.06
1-217 33-99 4-63
1.236 32.43 9.06
1.208 34.77 2.75
SODIUM SULPHATE
SOLUBILITY OF SODIUM SULPHATE IN AQUEOUS ETHYL ALCOHOL.
(de Bruyn Z. physik. Chem. 32, 101, *oo.)
Content Gms. Na 2 SO 4
t. of per 100 Gms.
Alcohol. Aq. Alcohol.
Gms.
per 100 Gms. Solution.
Solid
Phase.
'H 2 O.
C 2 H 6 OH. Na 2 SO 4 .
IS
0.7
12.7
88.7
o.o
"3
Na 2 SO 4 .ioH2O
tt
9.2
6.7
8 5 .I
8.6
6-3
"
a
19.4
2.6
78.6
18.9
2.9
"
(i
39-7
0.5
00.0
39-5
0.5
"
n
58-9
O.I
4I.I
58.8
O.I
"
tt
72.0
o.o
28.0
72.0
o.o
"
it
o.o
37-4
72.8
o.o
27.2
Na 2 S0 4 . 7 H 2
tt
II .2
16.3
76.5
9-5
14.0
"
tt
20. 6
7.0
74-3
19.2
6-5
"
cc
30.2
2 .O
68.4
29.6
2 .O
"
25
o.o
28.2
78.1
o.o
21-9
Na 2 SO 4 .ioH 2 O
tt
10.6
13-9
78.5
9-3
12 .2
"
(t
24.0
4-5
72.8
22 .9
4-3
"
(I
54-o
0.4
45-6
54-o
0.4
"
36
o.o
49-3
67.0
o.o
33-o
Na 2 S0 4
tt
8.8
29.2
70.6
6.8
22.6
tt
12.8
22.4
71.2
10.5
I8. 3
tt
17.9
15-4
71.1
13-4
ft
18.1
15-3
71.0
J 5-7
13-3
It
28.9
5-4
66.5
28.4
5- 1
tt
48.7
0.8
50-9
48.3
0.8
45
o.o
47-9
67.6
o.o
32-4
tt
9.0
27-5
71 .3
7- 1
21.6
tt
14-5
19.2
71.8
12. 1
16.1
tt
20. 6
12.3
70.6
18.4
10- O
tt
31.0
65.6
29-5
4-9
*
Between certain concentrations
of the aqueous
alcohol the liquid
separates into two layers at
25, 36
and 45.
o
Upper Layer.
Lower Layer.
Gms.HaO.
Gms.CuHgOH.
Gms.Na 2 SO 4 . Gms.H 2 O. Gms,C 2 H 5 OH. Gms.Na 2 SO 4
25
66. 5
27-3
6.2
67.4
5- 1 27.5
"
68.1
23-9
8.0
68.5
6.0 25.5
tt
68.3
23.1
8.6
68.3
6.7 25.0
36
. . .
. . .
66.6
4.1 29.3
tt
57-7
38.4
3-9
n
65.0
28.3
6.7
68.8
5-9 25.3
tt
68.1
21 .2
10.7
68.9
9.4 21.7
45
61.8
32-9
5-3
. . .
... ...
tt
65.8
25-3
8.9
68.4
8.8 22.8
"
66.0
24-0
IO-O
68.6
10. i 21.3
3i5 SODIUM SULPHATE
SOLUBILITY OF SODIUM SULPHATE IN AQUEOUS PROPYL ALCOHOL
AT 20.
(Linebarger Am. Ch. J. 14, 380, '92.)
Gms. CgHyOH
Gms. Na 2 SO 4
Gms. C 3 H 7 OH
Gms. Na2S
per ioo Gms.
Alcohol-Water
per ioo
Gms. Sat.
per ioo Gms.
Alcohol-Water
per ioo
Gms. Sat.
Mixture.
Solution.
Mixture.
Solution.
42.20
1.09
56-57
o-55
49-77
I .15
60.64
0.44
55-65
0.72
62.81
0.38
ioo gms. H 2 O dissolve 183.7 gms. sugar + 30.5 gms. Na 2 SO 4 at
31.25, or ioo gms. sat. solution contain 52.2 gms. sugar + 9.6 gms.
Na 2 SO 4 . (Kohler Z. Ver. Zuckerind. 47, 447, '97.)
SODIUM (Bi) SULPHATE NaHSO 4 .
ioo gms. H 2 O dissolve 28.6 gms. at 25, and 50.0 gms. at 100.
ioo gms. alcohol dissolve 1.4 gms. at 25. os. Solution.
5 30.60 2.70 Na 2 WO 4 .ioH 2 O 3.5 41.67 4.37 Na 2 WO 4 ,2H 2 O
-4 31.87 2.86 " +5 41-73 4-39
~3-5 3 2 -9 8 3-0 1 18 42-0 4-40
-2 34.52 3.23 21 42.27 4.48
o 3 6 -54 3-5 2 43-5 43'98 4-8i
+ 3 39-20 3.95 " 80.5 47-65 5-57
5 41.02 4.26 100 49.31 5.95
Sp. Gr. of sat. solution at 18 = 1.573. For Sp. Gr. determinations
of aqueous solutions at 20, see Pawlewski Ber. 33, 1223, 'oo.
SODIUM Fluo ZIRCONATE 5 NaF.ZrF 4 .
100 gms. H 2 O dissolve 0.387 gm. at 18, and 1.67 gms. at 100.
(Marignac J. pr. Chem. 83, 202, *6i.)
STRONTIUM BENZOATE Sr(C 7 H 6 O 2 ) 2 .H 2 O.
SOLUBILITY IN WATER.
(Paietta Gazz. chim. ital 36, II, 67, '06.)
t 15-7 24.7 31.4 40.9
Gms. Sr (C 7 H 5 O 2 ) 2 per 100 gms. solution 5 .31 5.4 5 .56 5 .77
STRONTIUM BROMATE Sr(BrO 3 ) 2 .
One liter of aqueous solution contains 0.9 gram molecules or 309
gms. Sr(BrO 3 ) 2 at l8. (Kohlrausch Sitzb. K. Akad. Wiss. (Berlin) 90, '97.)
STRONTIUM BROMIDE SrBr 2 .6H 2 O.
SOLUBILITY IN WATER.
(Average curve from results of Kremers Pogg. Ann. 103, 65, '58; and Etard Ann. chim.
phys. [7] 2, 540, '94.)
t o Gms. SrBr 2 per 100 Gms. t Gms. SrCl 2 per ioo Gms. Solid
Solution
Water. Phase.
2O 26.O
35-1 SrCl 2 .6H 2 O
60
o 30-3
43-5
70
10 32.3
47-7
80
20 34.6
52.9
IOO
25 35-8
55-8
120
30 37-o
58-7
I4O
40 39-5
65-3
1 60
50 42.0
72.4
1 80
Transition
temperature about
62.5.
= 1.334; at 15 = 1.36.
Gms. SrCl 2 per 100 Gms.
Solution.
Water
60
45-o
8l.8
70
46.2
85 -9
80
47-5
9o-5
IOO
50.2
100.8
120
53-o
112. 8
I4O
55-6
125 .2
1 60
58-5
I4I.O
1 80
62 .0
163.1
Solid
Phase.
SrCl 2 .6H 2
Sp. Gr. of sat. solution at o
SOLUBILITY OF STRONTIUM CHLORIDE IN AQUEOUS SOLUTIONS OF
HYDROCHLORIC ACID AT o.
(Engel Ann. chim. phys. [6] 13, 376, '88.)
Mg. Mols. per
10 cc. Solution.
51 .6
44-8
HC1.
O
6.1
37-85
12.75
27.2
22 .O
23-3
28.38
14.0
37-25
4-25
52-75
Sp. Gr. of
Solution.
334
34
.269
.220
.201
.167
Grams per ioo cc. Solution.
SrCl 2 .
40-9
35-5
30-0
21 .56
17.44
II .09
3-37
HCl.
O.O
2 .22
4-65
8-49
!o.35
13-58
19.23
100 gms. abs. methyl alcohol dissolve 63.3 gms. SrCl 2 .6H 2 O at 6.
100 gms. abs. ethyl alcohol dissolve 3.8 gms. SrQ 2 .6H 2 O at 6.
(de Bruyn Z. physik. Chem. 10, 787, '93.)
SOLUBILITY OF STRONTIUM CHLORIDE IN AQUEOUS ETHYL
ALCOHOL SOLUTIONS AT 18.
(Gerardin Ann. chim. phys. [4] 5, 156, '65.)
Sp. Gr, of
Aq. Alcohol
ato.
Wt.
per cent
Alcohol.
Gms. SrCl 2
per loo Gms.
Alcohol.
Sp. Gr. of
Aq. Alcohol
ato.
Wt.
per cent
Alcohol.
Gms. SrClj
per too Gms.
Alcohol.
O.QQO
6
49-8l
o-939
45
26.8
0.985 -
10
47-0
0.909
59
19.2
o-973
23
39-6
0-846
86
4-9
0.966
30
35-9
0.832
9*
3-2
o-953
38
3-4
STRONTIUM CHROMATE 318
STRONTIUM CHROMATE SrCrO 4 .
SOLUBILITY IN WATER, ETC., AT 15.
(Fresenius Z. anal. Chem. 29, 419, '90; 30, 672, '91.)
Cms. SrCrO 4 Cms. SrCrO 4
Solvent. per i oo Solvent. per 100
Gms. Solvent. Gms. Solvent.
Water 0.12 Aq. Ethyl Alcohol (29%) 0-0132
Aq. NH 4 C1 (5 %) o . 195 Aq. Ethyl Alcohol (53 %) o .002
Aq. CH 3 COOH(i%) 1.57
STRONTIUM FLUORIDE SrF 2 .
One liter of water dissolves 1.87 rng. equiv. or 0.117 gm. SrF 2 at
l8, by conductivity method. (Kohlrausch Z. physik. Chem. 50, 356, '04-05-)
STRONTIUM HYDROXIDE Sr(OH) 2 .
SOLUBILITY IN WATER.
(Scheibler N. Z. Rubenzuckerind. 7, 257 ; abstract in J. pharm. chim. [5] 8, 540, '83.)
Grams per looprams Solution. Grams per TOO cc. Solution.
SrO. Sr(OH) 2 .8H 2 O." SrO. Sr(OH) 2 .8H 2 O. "
o 0.35 0.90 0.35 0.90
10 0.48 1.23 0.48 1.23
20 0.68 i-74 0.68 i-74
30 i. oo 2.57 i. 01 2.59
40 1.48 3.80 1.51 3.87
50 2.13 5.46 2.18 5.59
60 3.03 7.77 3.12 8.00
70 4-35 IX - 16 4-55 XI - 6 7
80 6.56 16.83 7- 2 18.01
90 12.0 30-78 i3- 6 4 34-99
100 18.6 47-7 1 22.85 58-61
STRONTIUM IODATE Sr(IO 3 ) 2 .
100 gms. H 2 O dissolve 0.026 gm. at 15, and 0.72-0.91 gm. at
IOO . (Gay-Lussac; Rammelsberg Pogg. Ann. 44, 575, '38.)
STRONTIUM IODIDE SrI 2 .6H 2 O.
SOLUBILITY IN WATER.
(Average curve from the results of Kremers Pogg. Ann. 103, 65, '58; and Etard Ann. chim. phys.
[?] 2, 528, '74-)
Gms. SrI 2 per 100 Gms Solid t o Gms. SrI 2 per 100 Gms. Solid
Solution. Water. Phase. Solution. Water. Phase.
O 62.3 165.3 SrI 2 .6H 2 O 90 78.5 365-2 SrI 2 .2H 2 O
20 64.0 177.8 " IOO 79.3 383.1
40 65.7 I9I-5 " 120 80.7 4l8.I
60 68.5 217.5 " I 4 82.5 471-5
80 73.0 270.4 " 175 85.6 594-4
Transition temperature about 90. Sp. Gr. of sat. solution at 20 =
2.15.
loo gms. saturated solution of strontium iodide in absolute alcohol
contain 2.6 gms. SrI 2 at 20, 3.1 gms. at + 4, 4.3 gms. at 39, and 4.7
gms. at 82. (Etard.)
319 STRONTIUM MALATB
STRONTIUM MALATE SrC 4 H 4 O 6 .
SOLUBILITY IN WATER.
(Cantoni and Basadonna Bull. soc. chim. 35, 731, '06.)
Gms. per 100
Gms. per 100
Gms. per 100
*
cc. Solution.
.
cc. Solution.
*
cc. Solution.
20
0.448
40
I-385
55
2.460
25
0-550
45
1-743
60
2.821
30
0.752
5
2.098
65
3.148
35
1.036
3.360
STRONTIUM MOLYBDATE SrMoO 4 .
100 gms. H 2 O dissolve 0.0104 gm. SrMoO 4 at 17.
(Smith and Bradbury Ber. 24, 2930, '91.)
STRONTIUM NITRATE Sr(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Mulder; see also Etard for slightly lower results.)
-o Gms. Sr(NO 3 ) 2 per 100 Gms. Solid t o Gms. Sr(NO 3 )7 per 100 Gms. Solid
' Solution. Water. Phase. Solution. Water. Phase.
O 28.3 39.5 Sr(N0 3 ) 2 . 4 H 2 40 47.7 91.3 Sr(N0 3 )
10 35-5 54-9 5 48 -i 92.6
20 41.5 70.8 60 48.5 94.0
25 44.1 79.0 80 49.3 97.2
30 46.7 87.6 " 100 50.3 loi.i
Transition temperature about 31. Sp. Gr. of sat. solution at 20 =
1.44.
100 gms. absolute alcohol dissolve 0.024 gm. Sr(NO 3 ) 2 .
100 gms. rectified spirit dissolve 0.50 gm. Sr(NO 3 ) 2 .
(Hill Pharm. J. Trans. [3] 19, 420, '88.)
STRONTIUM OXALATE SrC 2 O 4 .H 2 O.
One liter of aqueous solution contains 0.52 mg. equivalent SrC 2 O 4
or 0.046 gm. at 18, conductivity method.
(Kohlrausch Z. physik. Chem. 50, 356, '04- '05.)
SOLUBILITY OF STRONTIUM OXALATE IN AQUEOUS ACETIC ACID
SOLUTIONS AT 26-27.
(Herz and Muhs Ber, 36, 3715, '03.)
Normality
Gms. per 100 cc. Solution.
Normality
Gms. per 100 cc. Solution.
of
Acetic Acid.
CHsCOOH.
Residue
SrC 2 4 .H 2 0.
of
Acetic Acid.
CKaCOOH.
Residue
SrC 2 O 4 .H 2 O.
o.o
O-O
0.009
3.86
23.16
0-0898
0.58
3-48
0.0526
5-79
34-74
0.0496
i-45
8.70
O.O622
16.26
97-5 6
o . 0060
2.89
J 7-34
0-0642
STRONTIUM SALICYLATE Sr(C 6 H 4 OH.COO) 2 .2H 2 O.
100 gms. H 2 O dissolve 5.55 gms. at 25, and 28.6 gms. at b. pt.
(u. s. P.)
100 cc. aqueous solution contain 1.830 gms. anhydrous salt. (Banhe.)
100 gms. alcohol dissolve 1.5 gms. at 25, and 9.52 gms. at b. pt.
(U. S. P. ; Barthe Bull. soc. chim. [3] u, 519, '94.)
STRONTIUM SULPHATE 320
STRONTIUM SULPHATE SrSO 4 .
One liter of aqueous solution contains 1.24 mg. equivalents or 0.114
gm. SrSO 4 at 18, by conductivity method.
(Kohlrausch Z. physik. Chem. 50, 356, '04- '05; Holleman Ibid. 12, 129, '93; Wolfmann Oster.
Ung. Z. Zuckerind. 25, 997, '97.)
SOLUBILITY OF STRONTIUM SULPHATE IN AQUEOUS SOLUTIONS OF
HYDROCHLORIC, NITRIC, CHLORACETIC AND FORMIC ACIDS.
(Banthisch J. pr. Chem. [2] 29, 52, '84.)
cc. of Aq.
Acid con-
In Aq. HC1
Gms. per 100 cc.
In Aq. HNO 3
Gms. per 100 cc.
In Aq. CH 2 C1COOH In Aq. HCOOH
Gms. per 100 cc. Sol. Gms. per 100 cc.
taining i
Mg. Equr
in each caa
so
so
I.
' CH 2 C1
COOH.
>! ' HC1.
SrS0 4 .
HNO 3 .
SrS0 4 .
SrSO 4 . HCOOH .
SrS0 4 .
0.2
18.
23
0.161
31
S 2
.381
... ...
. . .
0.5
>j
.29
0.207
12
-6l
307
... ...
. . .
I .0
3
6 5
0.188
6
30
.217
94
47
O.O26 46.02
O.O24
2 .O
j
.82
0.126
3
.138
47
23
O.O22
10.
o.
36
0.048
o
63
049
...
SOLUBILITY OF STRONTIUM SULPHATE IN SULPHURIC ACID
SOLUTIONS.
r, f Gms. SrSO 4
t. HCO I** 100 Authority.
H2SO <- Gms. Acid.
Ord. Concentrated 5 . 68 (Struve Z. anal. Chem. 9, 34, 1870.)
" fuming 9.77
91 % O .08 (Varenne and Paulean Compt. rend. 93, 1016, ? 8i.)
70 Sp. Gr. 1 .843 = 99 / 14-0 (Garside Chem. News, 31, 245, '75.)
SOLUBILITY OF STRONTIUM SULPHATE IN AQUEOUS SALT
SOLUTIONS.
(Virck Chem. Centralb. 402, '62.)
In Aq. NaCl. In Aq. KC1. In Aq. MgCl 2 . In Aq. CaCl 2 .
(a.) (b.)
8.44 0.165
15.54 0.219
22.17 0-lSl
(a.) (b.)
8.22 0.193
12-54 0.193
18.08 0.251
(.) (&.)'
1.59 0.199
4.03 0.206
13.63 0.242
(a.) (b.)
8.67 0.176
16.51 0.185
33.70 O.I7I
(a) = Gms. salt per 100 gms. aq. solution. (6) = Gms. SrSO 4 per
100 gms. solvent.
STRONTIUM TARTRATE SrC 4 H 4 O 6 . 3 H 2 O.
SOLUBILITY IN WATER.
(Cantoni and Zachoder Bull. soc. chim. [3] 33, 751, '05.)
t.
Gms.
SrC 4 H 4 6
. 3 H 2 per
100 CC.
t<>.
Gms.
SrC.
Gms:
per 100 cc.
Solution.
Solution.
Solution.
O.II2
25
0.224
60
0.480
10
0.149
30
0.252
70
0.580
15
0.174
40
0-328
80
0.680
20
0.200
50
0.407
85
o-755
:H 3 COOH.
SrC 4 H 4 O .3H 2 6.
Acetic Acid.
CH 3 COOH.
SrC 4 H 4 O 6 .3H 2 C
o.o
O.227
3-77
21.85
I .051
3-39
0.678
5-65
33-90
0.982
8.15
0.864
16.89
101.34
0.184
17 .10
0.996
321 STRONTIUM TARTRATE
SOLUBILITY OF STRONTIUM TARTRATE IN AQUEOUS SOLUTIONS OF
ACETIC ACID AT 26-27.
(Herz and Muhs Ber. 36, 3715, '03.)
Gms. per ioo cc. Solution.
kid. CH 3 COOH. SrC 4 H 4 O .3H 2 6. Acetic Acid." c
0-0
1.425
STRONTIUM (Di) TUNGSTATE SrW 2 O 7 . 3 H 2 O.
100 cc. H 2 O dissolve 0.35 gm. at 15.
(Lefort Ann. chim. phys. [5] 15, 326, '78.)
STRYCHNINE C 21 H 22 N 2 O 2 .
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; at 20, Muller Apoth.-Ztg. 18 258, '03; Schindelmeiser.)
Gms. C 21 H 22 N 2 O 2 Gms. C 2 H 22 N 2 O 2
per 100 Gms. per 100 Gms.
Solvent. < r~ " Solvent. .
Solution Solvent Solution Solvent
at 20. at 25. at 20*. at 25.
Water 0.021 0.016 Petroleum Ether 0.0093
Water Sat. with Ether 0.0166 ... Acetic Ether 0.1972 ...
Ether 0.0432 0.0182 Carbon Tetra Chloride 0.158 o.645(i7)(S.)
Ether Sat. with H 2 O 0.0513 ... Alcohol ... 0.909
Benzene o. 770 o. 666 Amyl Alcohol ... o. 555
Chloroform 100+ 16. 6 Glycerine ... 0.25 (15)
ioo gms. pyridine dissolve 1.24 gm. C 21 H 22 N 2 O 2 at 26.
(Holty J. Physic. Chem. 9, 764, '05.)
SOLUBILITY OF STRYCHNINE NITRATE AND SULPHATE IN SEVERAL
SOLVENTS.
(U. S.P.)
Strychnine Nitrate. Strychnine Sulphate.
Gms. per TOO Gms. Solvent at: Gms. per ioo Gms. Solvent at:
Solvent. ' * 7-3 > < 3 " r~s
25 . 80 . 25 . 80 .
Water 2.38 12.5 3.23 16.6
Alcohol o . 83 i . 66 (60) 1.54 5-o (60)
Chloroform 0.64 0.31
Glycerine 1.66 4-0(15) 22.5(15)
SUBERIC ACID C e H 12 (COOH) 2 .
SOLUBILITY IN WATER.
(Lamouroux Compt. rend. 128, 998, '99.)
t. o. 15. 20. 35. S r - 65
Gms. C 6 H 12 (COOH) 2
per ioo cc. solution 0.08 0.13 0.16 0.45 0.98 2.22
SUCCINIC ACID 322
SUCCINIC ACID (CH 2 ) 2 (COOH) 2 .
SOLUBILITY IN WATER.
(Miczynski Monatsh. Chem. 7, 263, '86; Van der Stadt Z. physik. Chem. 41, 355, '02; Lamouroux
Compt. rend. 128, 998, '99; for other concordant results, see Bourgoin Bull. soc. chim. [2] 21, no
'74; Henry Compt. rend. 99. H57 '84.)
Gms. Succinic
o Gms. (CH 2 ) 2 (COOH)2 per 100 / r ^p^o O Mol. per cent.
'Gms. H 2 0. cc. Solution." ( 2) ^ r H 2 O. (CH 2 ) 2 COCOO".
100 Gms. H 2 O.
o 2.80 2-78(L.) 2.34 99-58 0.42
10 4-51 4-o 3-80 99-32 0.68
20 6.89 5.8 5.77 98.97 1.03
25 8.06 7-0 6.74 98.80 1.20
30 10.58 8.5 8.79 98.44 1-56
40 16.21 12.5 13.42 97-64 2.36
50 24.42 18.0 19.95 96-53 3-47
60 35.83 24.5 28.77 95-07 4-93
70 51-07 40.11 93-26 6.74
80 70-79 54-oS 91.12 8.88
89.4 95-45 70.62 88.71 11.29
104-8 146.3 ... 101.2 84.57 15.43
115.1 188.5 ... 126.8 81.4 18.6
134-2 335-4 187-8 74-72 25.28
159-5 748.2 ... 295.2 65.27 34.73
180.6 1839-0 ... 408.5 57.6 42.4
182.8 oo ... 542-3 50-0 50-0
174.4 808.5 40.7 59.3
153.3 ... 2239.0 19.86 80.14
128.0 ... ... 8865.0 5.89 94.11
118.8-119 o-oo 100.00
SOLUBILITY OF SUCCINIC ACID IN ALCOHOLS AND IN ETHER.
(Timofeiew Compt. rend. 112, 1137, '91; at 15, Bourgoin Ann. chim. phys. [5] 13, 405, '78.)
Gms. (CH 2 ) 2 (COOH) 2 per 100 Gms.
Solvent. t Solv f nt at:
-i. +i5- +21.5.
Abs. Methyl Alcohol 10.51 19 . 40
Abs. Ethyl 5 .06 I2 -59 9-49
90% " 7-5 1
Abs. Propyl " 2.11 ... 4-79
Abs. Ether 1.265
DISTRIBUTION OF SUCCINIC ACID BETWEEN WATER AND AMYL
ALCOHOL AT 20.
(Herz and Fischer Ber. 37, 4748, '04.)
Millimols C 4 H 6 O 4 Gms. C 4 HeO 4 per Millimols $C 4 H 6 O 4 Gms. C 4 H 6 O 4
per 10 cc. loo cc. per 10 cc. per 100 cc.
Alcohol
Aq. Alcohol
Aq.
Alcohol
Aa.
Alcohol
Aq. "
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
0.1888
O
.2684
O
.1114
0-1584
3
.899
6
0795
2.302
3.588
0.3643
5252
O
.215
0-310
5
.199
8
099
3.069
4-779
0.7077
I
0373
.418
0.612
6
334
10
.170
3-739
6.000
1-440
2
.1266
.850
J -255
7
.119
ii
555
4.202
6.821
2.7I5
4
0495
I
.603
2.391
323 SUCCINIC ACI1S
SOLUBILITY OF SUCCINIC ACID IN AQUEOUS ACETONE AT 20.
(Herz and Knoch Z. anorg. Chem. 41, 320, '04.)
cc. Acetone per C 4 H 6 O 4 per ioo cc. Solution. cc. Acetone per C 4 H 6 O 4 per ioo cc. Solution
100 cc. Solution. Millimols. Grams. ' 100 cc. Solution. Millimols. Grams. '
o 107.8 6.363 60 275.7 16.27
J o 127.4 7-5*9 7o 278.5 16.44
20 155.8 9 J 94 80 265.3 15.66
30 186.7 11-02 90 201-9 11.91
40 225.4 13-30 ioo 51.5 3.04
50 254.3 15.01
SOLUBILITY OF SUCCINIC ACID IN AQUEOUS GLYCERINE
SOLUTIONS AT 25.
(Herz and Knoch Z. anorg. Chem. 45, 268, '05.)
Wt.%
Glycerine
CaHeO-i per ioo cc.
Solution.
Sp. Gr.
of
Wt.%
Glycerine
C 4 HeO 4 per ioo cc.
Solution.
Sp. Gr.
of
in Solvent
Millimols.
Grams.
Solutions.
in Solvent.
Millimols.
Grams.
Solutions.
O
133-4
7
.874
I
.0213
40
95
105.8
6.244
I
. II2Q
7-15
128.2
7
.566
I
-0407
4 8
.70
99-9
5 -896
I
.I208
20-44
II8-3
6
.982
I
-0644
6 9
.20
88-5
5-223
I
.1804
3 I -55
109.7
6
.476
I
.0897
IOO
.00*
74.6
4.440
I
2530
* Sp. Gr. of Glycerine i -2555. Impurity about i .5 per cent.
SUCCINIMID C 2 H 4 <>NH.
SOLUBILITY IN WATER AND IN ETHYL ALCOHOL.
Interpolated from original results. ( S peyer S - Am. j. sd. [ 4 ] 14, 294, '02:,
In Water. In Ethyl Alcohol.
t. Wt. of T cc. Mols. per Gms. per ioo Wt.oficc. Mols.penoo Gms. per 10
Solution. ioo Mols. H 2 O. Gms. H 2 O. Solution. Mols. C 2 H 5 OH. Gms. C 2 H 6 OH
o 1.025 1.58 8.69 0.815 0.88 1.89
10 .035 2.4 14.0 0.809 1.35 2.7
2O .052 4-O 23-0 O.8o6 2-OO 4-1
25 -067 5-9 33-0 0-805 2-5 5.3
30 .086 8.0 45.0 ; 0.804 3.1 6.8
40 .120 12.8 70.0 0.809 4.9 10.5
50 .145 17.8 96.0 0.816 7.8 16.0
60 .167 22.6 124.0 0-835 12.3 26.5
70 .189 27.5 152-0 0.873
80 .204 32.8 0.954
SUCCINIC NITRIL (Ethylene Cyanide) CNCH 2 CH 2 CN.
The solubility of succinic nitril in water and also in aqueous sodium
chloride solutions at various temperatures has been determined by
Schreinemaker (Z. physik. Chem. 23, 439, '97), and the results
presented in terms of mols. of nitril per ioo mols. of nitril + H 2 O.
The following calculation of these results to gram quantities was
made by Rothmund. (Landolt and Bornstein, 3 d ed. p. 59^, '06.)
Gms. CNCH 2 CH 2 CN per ioo Gms. Gms. CNCH 2 CH 2 CN per ioo Gms.
t. t s t. , %
Aq. Layer. Nitril Layer. Aq. Layer. Nitril Layer.
18.5 10.2 92.0 53-5 33-2 66.4
20 ii. o 91-5 55 40-3 62.8
39 85 .2 55 .4 (crit. temp.) 51.0
45 22.0
SUGAR 324
SUGAR C 12 H 22 O n (Cane Sugar.)
SOLUBILITY IN WATER.
(Herzfeld Z. Ver. Zuckerind. 181, '92; see also Courtonne Ann. chim. phys. [5] 12, 569, '77.)
Gms. Ci 2 H 22 On per t*. Gms.
ioo Gms. ioo Gms.
Solution. Water. Solution. Water.
o 64.18 179-2 40 70.42 238.1
5 64.87 184.7 45 7 J -3 2 248.7
10 65.58 I 9-5 5 7 2 -25 260.4
15 66.33 !97-o 60 74-18 287.3
20 67.09 203.9 7 76.22 320.4
25 67.89 211.4 80 78-36 362.1
30 68.70 219.5 90 80. 61 4*5-7
35 69.55 228.4 ioo 82.97 487.2
6p. Gr. of sat. solution at 15 = 1.329; at 25 = 1.340.
SOLUBILITY OF SUGAR IN AQUEOUS SALT SOLUTIONS AT 30, 50.
AND '70'
Interpolated from original results.
(Schukow Z. Ver. Zuckerind. 50, 313, 'oo.)
Gms. Ci 2 H 22 O a per ioo grams H 2 O in Aq. Solution of:
* .
unis. oau per
ioo Gms. H 2 O.
KC1.
KBr.
KNO 3 .
NaCl.
CaCl 2 .
30
O
219.5
219.5
219.5
219.5
219.5
10
216
218
217
210
I 97
tt
20
221
22O
216
211
189
ft
30
228
224
216
219
192
"
40
237
228
217
233
2OO
"
50
218
2 5
2X3
tt
60
269
243
50
O
260.4
260.4
260.4
260.4
260.4
tt
IO
261
262
260
255
239
It
20
266
266
261
260
228
li
30
274
272
262
269
228
tt
40
284
276
262
284
236
it
50
296
280
263
302
253
tl
60
276
10
O
320.5
320.5
320.5
320.5
320.5
*t
IO
326
324
321
323
295
20
334
328
324
330
286
(i
30
345
334
327
344
286
ti
40
357
34i
33 1
361
295
tt
50
370
349
334
384
308
tt
60
384
357
337
406
327
325
SUGAR
SOLUBILITY OF CANE SUGAR IN SATURATED AQUEOUS SALT
SOLUTIONS AT 31.25.
(Kohler Z. Ver. Zuckerind. 47, 447, '97.)
Gms. Sugar per 100 Gms.
Salt.
CH 3 COOK
C 3 H 7 COOK
C 3 H 4 .OH.(COOK) 3
K 2 C0 3
KC1
CH 3 COONa
NaCl
SOLUBILITY OF CANE SUGAR IN
(Scheibler Ber. 5, 343, '72;
Results at o.
Gms. Sugar per icoGms-
Solution.
Water.
oaii.
Solution.
Water.
324-8
Na 2 C0 3
64.73
229.2
49.19
306.1
KNO 3
61.36
224.7
50-30
303-9
K 2 S0 4
66.74
219.0
56.0
265.4
CH 3 COOCa
60. 12
190.0
62.28
246.5
Na 2 SO 4
52.20
183-7
59-93
237.6
CaCl 2
42.84
I35-I
62 .17
23 6 -3
MgS0 4
46-52
119.6
AQUEOUS ALCOHOL SOLUTIONS.
correction Ber. 24, 434, '91.)
Results at 14. Results
Per cent
Alcohol
Sp. Gr.
of Solution
Gms. Sugar
per 100 cc.
Sp. Gr.
of Solution
Gms.
per 100 cc. Solution.
- T'
Gms. Su
by Vol.
at 17.5.
Solution.
at 17.5.
Sugar.
C 2 H 6 OH.
H 2 0.'
per TOO
Solutio
I-325
85.8
1.326
87-5
O
45-10
10
1.299
80-7
1.300
8l. 5
3-91
44.82
95-4
20
1.236
74-2
1.266
74-5
8. 5 2
43-83
90.0
30
1.229
65-5
1-233
67.9
*3-74
41.87
82.2
40
I.I82
56.7
I.I85
58.0
20.24
40.38
74-9
50
I .129
45-9
I.I 3 I
47-1
28.13
38.02
63-4
60
1.050
32-9
1.058
33-9
37-64
34-47
49-9
70
0.972
18.2
o-975
18.8
46.28
29-57
3i-4
80
0.893
6.4
0.895
6.6
61 .15
21.95
13-3
90
0.837
0.7
0.838
0.9
71.18
12.83
2-3
97-4
0.8o6
0.08
0.808
0.36
77-39
3.28
o-5
SOLUBILITY OF CANE SUGAR IN AQUEOUS ALCOHOL SOLUTIONS AT 14.
(Schrefeld Z. Ver. Zuckerind. 44, '971 '94.)
Wt.
Wt.
Gms. Sugar per 100
Wt.
Wt.
Gms. Sugar per 100
>er cent
per cent
cc. Alcohol-H 2 O
per cent
per cent
cc. Alcohof-H 2 O
UcohoL
Sugar.
Mixture.
Alcohol.
Sugar.
Mixture.
66.2
195-8
50
38.55
62.7
5
64.25
179.7
60
26.70
3 6 -4
10
62 .20
164.5
70
12.25
13-9
20
58-55
141 .2
80
4-05
4.2
30
54-05
II7.8
90
o-95
0.9
40
47-75
9 I -3
100
o.oo
o.o
100 gins, absolute methyl alcohol dissolve 1.18 gms. sugar at 19.
(de Bruyn Z. physik. Chem. 10, 784, '92.)
SOLUBILITY OF SUGARS IN PYRIDINE AT 26.
(Holty J. Physic. Chera. 9, 764, '04.)
Sugar.
T- i Gms. Sugar per Sp. Gr. of
100 Gms. Solution. Solutions.
Cane Sugar
Milk Sugar
Grape Sugar
C 12 H 22 O n
C 12 H 22 O n .H 2
C 6 H 12 C .H 2
6-45
2.18
762
0.9811
i .0521
SUGAR 326
SOLUBILITY OF CANE SUGAR IN AQUEOUS ACETONE AT 25.
(Herz and Knoch Z. anorg. Chem. 41, 322, '04.)
Sp.Gr.of
Solutions.
cc. Acetone
per loo cc.
Solvent.
Cms. Sugar
per loo cc.
Solution.
Gms.
per 100 cc. Solution.
H 2 0.
(CH 3 ) 2 CO.
Q 2 H 22 O n
3306
.2796
0-0
20-0
8 9 .8
76.7
43-3
42.9
o.o
8. 4
89.8
76.7
.2491
.2OO2
.1613
30.0
4O.O
45-o
72.1
59-3
52-5
39-5
39-8
39-o
13-4
20-9
24.6
72.1
59-3
52-5
Above 45 cc. acetone per 100 cc. solvent the solution begins to
separate into two layers. The lower of these contains 51 gms. sugar
per 100 cc. and has Sp. Gr. 1.1522. The upper layer contains so
little sugar that the amount could not be determined by the method
employed. 100 cc. evaporated in a vacuum desiccator left a residue
of 3.68 gms. Above the concentration of 80 cc. acetone per 100 cc.
solvent the two layers unite. In pure acetone 100 cc. solution give
a residue of 0.18 gram sugar.
SOLUBILITY OF GRAPE SUGAR IN WATER AND IN AQ. ALCOHOL.
100 gms. H 2 O dissolve 81.68 gms. C 6 H 12 O 6 or 97.85 gms. C 6 H 12 O 6 .H 2 O
at 15.
100 gms. aq. alcohol of 0.837 Sp. Gr. = 85 wt. per cent dissolve
1.95 gms. C 6 H 12 O 6 at 17.5.
100 gms. aq. alcohol of 0.880 Sp. Gr. = 66 wt. per cent dissolve
B.io gms. C 6 H 12 O 6 at 17.5.
100 gms. aq. alcohol of 0.910 Sp. Gr. = 53 wt. per cent dissolve
16.01 gms. C 6 H 12 O 6 at 17.5.
100 gms. aq. alcohol of 0.915 Sp. Gr. = 51 wt. per cent dissolve
32.50 gms. C 6 H 12 O 6 at 17.5.
SOLUBILITY OF MILK SUGAR IN WATER AND IN ABSOLUTE METHYL
ALCOHOL.
100 gms. H 2 O dissolve 17.03 gms. Ci 2 H 22 O n .H 2 O at 10, 20.8 gms.
at 25 (U. S. P.), 40 gms. at 100, and 100 gms. at b. pt.
100 gms. abs. methyl alcohol dissolve 0.084 gm- at 19.5.
(de Bruyn Z. physik. Chem. 10, 784, '92.)
SULPHANILIO ACID NH 2 .C 6 H 4 SO 3 H.
SOLUBILITY IN WATER.
(Dolinski Ber. 38, 1836, '05.)
Gms. Acid per 100 Gms. Gms. Acid per 100 Gms.
Solution. Water. " Solution. Water. "
o 0.64 0.64 60 3-01 3-io
10 0.83 0.84 70 3-65 3-78
20 1.07 I. 08 80 4.32 4.51
30 1.47 i-49 90 5-25 5-54
40 1.94 1.97 100 6.26 6.67
50 2.44 2.51
327
SULPHUR
SULPHUR S
SOLUBILITY IN:
Tin Tetra Chloride.
Amyl Alcohol.
(Gerardin
Ann. chim. phys.
[4] 5, 134. '6s )
(Gerardin.)
t.
Cms. S
per 100 Gms.
SnCl 4 .
Solid
Phase.
t.
Gms. S
per loo Gms.
C 5 H U OH.
Solid
Phase.
99
5-8
Solid S
95
I -5
Solid S
101
6.2
no
2 .1-2 .2
no
8.7-9.1
112
2 . 6-2 . 7
Liquid S
112
9.4-9.9
Liquid S
120
3-o
n
121
17.0
i<
131
5-3
SOLUBILITY OF SULPHUR IN ETHYL AND METHYL ALCOHOLS.
15
18.5
b. pt.
18.5
Alcohol.
Abs. Ethyl
Abs. Methyl
Gms.
per too Gms.
Alcohol.
0.051
0-053
0.42
0.028
Authority.
(Pohl.)
(de Bruyn Z. physik. Chem. 10, 781, '92.)
(Payen Compt. rend. 34, 356, '52.)
(de Bruyn.)
SOLUBILITY OF SULPHUR IN AQUEOUS ACETONE AT 25.
(Herz and Knoch Z. anorg. Chem. 45, 263, '05.)
Wt. per cent
Acetone
in Solvent.
IOO
90.62
85-38
Sulphur per 100 cc.
Solution.
Millimols.
Grams.
65.0
2.084
45-o
1-442
33-o
1.058
25-3
O.SlI
Sp. Gr.
of
Solution.
0.7854
0.79II
0.8165
0.8295
SOLUBILITY OF SULPHUR IN BENZENE AND IN ETHYLENE Di
BROMIDE.
(Etard Ann. chim. phys. [7] 2, 571, '94; see also Cossa Ber. i, 139, '68.)
In C 2 H 4 Br 2 .
In
C 6 H 6 .
'
Gms. S
Gms. S
t .
per loo Gms.
t.
per loo Gms.
Solution.
Solution.
I .0
70
8.0
10
I .3
80
10.5
20
1-7
90
13-8
25
2.1
IOO
17-5
30
2-4
no
23.0
40
3-2
120
29.0
50
4-3
130
36.0
60
6.0
'
Gms. S
Gms. S
t.
per loo Gms.
t.
per 100 Gms.
Solution.
Solution.
o
1.2
50
6. 4
IO
i-7
60
8. 4
20
2-3
70
II-4
25
2.8
80
I6. 5
30
3-3
90
24.0
40
4-4
IOO
36.5
TOO gms. sat. solution of S in benzoyl chloride, C 7 H 7 C1, contain
I gram S at o and 55.8 gms. at 134.
(Bogousky J. Soc. Phys. Chim. R. 37, 92, '05.)
SULPHUR 328
SOLUBILITY OF SULPHUR IN CARBON BISULPHIDE.
5s; at 10, Retgers
ii, 274, '95-96.)
(Etard Ann. chim. phys. [7] 2, 571, '94; Cossa Ber. i, 138, '65; at 10, Retgers Z. anorg. Chem
3 347. '93; below 77, Arctowski Ibid, n,
Cms. S per joo Cms. Gms. S per 100 Gms. Gms. S per 100 Gms.
Solution. CS2 Solution. CS 2 . "Solution. CS 2 . '
-no 3.0 3.1 -io 13.5 15.6 50 59.0 143.9
100 3.5 3.6 o 18.0 22. o 60 66. o 194.1
80 4.0 4.2 io 23.0* 29.9 70 72.0 257.1
- 60 3-5 3-6 20 29.5 41.8 80 79.0 376.1
- 40 6.0 6.4 25 33.5 50.4 90 86.0 614.1
20 10.5 ii -7 30 38.0 61.3 100 92.0 1150.0
40 50-0 100.0
* 26.4 R.
Sp. Gr. of solution saturated at 15 containing 26 gms. S per 100
gms. solution = 1.372.
SOLUBILITY OF SULPHUR IN HEXANE (C 6 H 14 ).
(Etard.)
A.O Gms. S per
100 Gms. Solution.
2O O.O7
O O.l6
20 0.25
40 0.55
SOLUBILITY OF SULPHUR IN SEVERAL SOLVENTS.
(Cossa Ber. i, 139, '68; Retgers; Cap and Garot J. pharm. chim. [3] 26, 81 '54; Kleven Chem,
Centralb. 434, '72.)
Gms. S per
100 Gms. Solvent.
1.48
10. (R.)
10.58
O.O5-O.I (C.andG.)
SOLUBILITY OF SULPHUR IN COAL TAR OIL, LINSEED OIL AND
IN OLIVE OIL.
(Pelouze Compt. rend. 68, 1179, '69; 69, 56, '69; Pohl.)
Grams S per 100 Grams Coal Tar Oil of:
t.
Gms. S per
100 Gms. Solution.
t.
Gms. S per
100 Gms. Solution.
60
I .0
130
5- 2
80
i-7
140
6.0
100
2.8
160
7.2
1 20
4-4
180
8.2
Solvent.
j.o Gms. S per
100 Gms. Solvent
Solvent.
]
C 6 H 5 NH 2
CHC1 3
(C 2 H 5 ) 2
C 6 H 5 OH
130
22
23-5
85-3
I .21
0-97
C 6 H 5 CH 3
CH 2 I 2
C 10 H 4 N 2 *
C 5 H 3 (OH) 3
230
10
100
ord. t.
* Nicotine.
A.O Sp.Gr.: 0.87
' b. pt.: 8o-ioo.
0.88
8 5 -I20.
0.882
I20-220
0.885 i -oi
. I50-200. 2IO-300.
1 .02
220-30O.
15
2 .1
2
3
2
5
2
.6
6.
7-
o
30
3-0 4-0
5
3
5
.8
8.
5
8.
5
50
5-2
6
.1
8
3
8
7
io.
12 .
o
80
ii. 8
13
7
15
.2
21
.0
37-
41.
o
100
15.2
18
7
23
O
26
4
S 2 -
5
54-
o
1 10
23
o
26
.2
31
o
105.
115 .
120
27
.0
32
.0
38.0
00
00
130
38
7
43
.8
00
00
G. S per 100 Gms.
Linseed
Olive
Oil of
vu - 0.885 Sp.Gr
0-4 2.3
0.6 4.3
1.2 9-O
2.2 l8.O
3-0 25.0
3-5 3o-o
4.2 37.0
5.0 43-0
(160) io. o
100 gms. oil of turpentine dissolve 1.35 gms. S at i6,and 16.2 gms.
P (Payen Compt. rend. 34, 356, '52.)
329
SULPHUR DIOXIDE
SULPHUR DIOXIDE SO,
SOLUBILITY IN WATER.
(Schonfeld Liebig's Ann. 95, 5, '55; Sims Ibid. 118, 340, '61; Roozcboom Rcc. trav. chim. 3.
46, 84.)
Schonfeld.
Vols. SO 2 (at o and
760 mm.) per i Vol.
Gms. SO 2 per
loo Gms. HjjO
Sims.
SO 2 per i Gm. H 2 O.
Roozeboom.
SO 2 Dissolved
per i pt. HaO
**'
Sat. SO 2
+ Aq.
H 2 0.
at total pressure t .
760 mm.
Gms.
Vols."
* . at 760 mm.
pressure.
O
68.86
79
79
22
83
8
0.168
58.7
O
.236
5
59.82
67
.48
19
.31
10
0.154
53-9
2
O
.218
10
5I-38
56
65
16
.21
14
0.130
45-6
4
O
.201
15
43-5 6
47
.28
13
54
20
0.104
36-4
6
.184
20
36.21
39
37
II
.29
26
0.087
30-5
7
O
.176
25
30-77
32
79
9
.41
30
0-078
27-3
8
O
.168
30
25.82
27
16
7
,81
36
0.065
22.8
10
o
154
35
21.23
22
49
40
0.058
2O-4
40
17 .01
18
77
5
,41
46
0.050
17.4
12
o
.142
5
0.045
I 5 .6
Sp. Gr. of sat. solution at o = 1.061; at 10, 1.055; a ^ 20 = 1.024.
i gm. H 2 O dissolves 0.0909 gm. SO 2 = 34.73 cc. (measured at 25)
at 25 and 748 mm. pressure.
(Walden and Centnerszwer Z. physik. Chem. 42, 462, 'oi-'oa .
SOLUBILITY OF SULPHUR DIOXIDE IN SULPHURIC ACID OF
1.84 SP. GR.
Interpolated from original results.
(Dunn Chem. News, 45, 272, '82.)
Sp. Gr.
Coefficient
Sp. Gr.
Coefficient
of Sat.
Solution.
of Absorp-
tion (760 mm.).
t.
of Sat.
Solution.
of Absorp-
tion (760 mm.)
53-o
5
I. 8l86
9-5
10
I .8232
35-o
60
1.8165
7.0
20
I .8225
25.0
70
1.8140
5-5
25
I.822I
21 .O
80
1.8112
4-5
30
I.82I6
18.0
90
I. 8080
4-0
40
I .8205
13.0
SOLUBILITY OF SULPHUR DIOXIDE IN AQUEOUS SULPHURIC ACID
SOLUTIONS.
(Dunn; see also Kolb Bull. soc. ind. Mulhouse 222, '72.)
Sp. Gr. of
Approximate
Coefficient
Sp. Gr. of
Approximate
Coefficient
t.
H 2 S0 4
Per cent
of
t.
H 2 S0 4
per cent
of
Solution.
H 2 S0 4 .
Absorption.
Solution.
H 2 S0 4 .
Absorption
6.9
139
2O
48.67
15
2
173
25
31.82
6.9
.300
40
45-38
16
.8
^S 1
21
3I-56
8.6
.482
58
39 -9 1
14
.8
277
36
30.41
9.8
703
78
29.03
15
.1
458
56
29.87
5-5
.067
IO
36.78
15
.6
.609
70
25- I 7
6.0
.102
*5
3.408
15
o
739
81
20.83
For Coefficient of Absorption, see Ethane page 133.
SULPHUR DIOXIDE 330
SOLUBILITY OF SULPHUR DIOXIDE
(Fox Z. physik. Che
Results in terms of the Ostwald Solubility Expression. See page 105.
SOLUBILITY OF SULPHUR DIOXIDE IN AQUEOUS SALT SOLUTIONS.
(Fox Z. physik. Chem. 41, 461, '02.)
Salt Solution.
NH 4 C1
0.5 Normal
'25 = 34 58
1.0 N.
1-5
38
N.
.06
2.0 N.
39-76
2.5 N.
41-37
3-0 N.
42.78
NH 4 Br
'25 = 36
.25
39
-46
42
.78
46.06
49.17
5 2
25
NH 4 CNS
'25 = 37
78
42
74
47
.26
52
.26
57-oi
61
.46
NH 4 NO 3
'25 = 33
.96
35
.07
36-28
37
.27
38.01
39
.14
NH 4 NO 3
'35=23
35
24
23
24
78
25
57
26.66
27
43
(NH 4 ) 2 S0 4
'25 = 33
35
33
.82
34
33
34
95
35-47
35
.96
(NH 4 ) 2 S0 4
'35=22
.91
23
.14
23
49
23
93
24.23
24
.60
CdCl 2
' 2 5 = 3 J
.66
30
55
29
.46
28
.16
27.09
26
.06
CdCL,
'35 = 2I
73
21
23
20
55
20
.02
19.23
18
.68
CdBr 2
'25= 3 1
.91
3 1
.01
30
29
27
28.15
27
.46
CdBr 2
'35=21
.88
21
.46
20
.81
20
.60
19.70
19
17
CdI 2
'25=33
27
33
.76
34
.16
34
74
34-98
35
77
CdI 2
'35=22
75
23
.06
23
36
23
.71
23-99
24
30
CdSO 4
'25=3!
.11
29
.71
28
.24
26
58
25.14
23
76
CdS0 4
'35=21
45
20
43
19
.42
18
3 1
17.41
16
2 5
KC1
'25=34
.42
36-05
37
76
39
32
40.96
42
.27
KC1
'35=23
74
25
15
26
54
27
94
28-93
30
.02
KBr
'25=35
94
39
.11
42
.41
44
.96
48.87
52
.26
KBr
'35=24-83
27
49
29
.64
3 1
93
34.12
36
.14
KCNS
'25=37
57
42
38
47
.02
5 1
.81
55-87
61
.26
KCNS
'35=25
-63
28
79
32
03
35
05
38-13
42
94
KI
'25=38
.66
44
76
50-58
56
75
62.63
68
36
KI
'35=26
3
30
25
34
.64
38
.04
41.87
45
43
KN0 3
'25=33
.80
34
79
35
77
36
.66
37-57
38
5 2
KN0 3
'35=23
27
24
03
24
79
25
72.
26.54
27
33
K 2 S0 4
.20
33
.61
NaBr
'25=33
76
34
54
35
.27
36
.26
36-84
37
74
NaCl
'25=32
.46
32
25
.96
.76
3I-5 1
3 1
36
NaCNS
'25=35
44
38
.24
40
78
43
37
45-86
48
34
Na 2 SO 4
'25=31
.96
.14
30
45
29
5 1
28.66
28
44
Na 2 SO 4
'35=21
.88
21
35
20
.81
20
.21
19-75
J 9
.27
SOLUBILITY OF SULPHUR DIOXIDE IN ALCOHOLS AND IN OTHER
SOLVENTS.
(de Bruyn Rec. trav. chim. u, 128, '92; Schulze J. pr. Chem. [2] 24, 168, '81.)
In Ethyl Alcohol In Methyl Alcohol In Several Solvents
at 760 mm. at 760 mm. at o and 725 mm. (S.)
jo Gms. SC>2jper 100 Gms. Gms. SO2 per too Gms. gi * SO2 per i Gm. Solvent.
Solution. C 2 HsOH. Solution. CH 3 OH.' Grams. Vols- '
o 53.5 115.0 71.1 246.0 Camphor 0.880 308
7 45-0 81.0 59.9 149.4 CH 3 COOH 0.961 318
12.3 39.9 66.4 52.2 109.2 HCOOH 0.821 351
18.2 32.8 48.8 (17. 8) 44.0 78.6 (CH 3 ) 2 CO 2.07 589
26.0 24.4 32.3 31.7 46.4 SO 2 C1 2 0.323 189
33 1
SULPHUR DIOXIDE
DISTRIBUTION OF SULPHUR DIOXIDE AT 20 BETWEEN:
(McCrae and Wilson Z. anorg. Chem. 35, n, '03.)
Water and Chloroform.
Aq. HC1 and Chloroform.
Cms. SO 2 per
Liter in:
Gm. Equiv. ^SOj
per Liter in:
Cone.
Gms. SO 2 per
Liter in:
Gm. Equiv. $SO 3
per Liter in:
Aq.
Layer.
CHC1 3
Layer.
Aq.
Layer.
CHC1 3
Layer.
of
HC1.
Aq.
Layer.
CHC1 3
Layer.
Aq.
Layer.
CHC1,
Layer.
I-738
I
.123
O
0543
O
035 1
0-05
1.86
I. 4 6
0-0581
0.0456
i-753
j
.122
0547
0350
3-07
2.8 3
0.0960
0-0884
2.346
j
703
.0732
0532
n
4.28
4-07
0.1336
O.I27I
2.628
I
.897
.0821
.0592
(i
5-34
5-42
0-1667
0.1692
3-058
2
385
0955
0745
0.10
1.25
1.41
0.039
O.O44
3-735
3
.062
.1166
.0956
(I
2.78
3.08
0.0868
0.0962
4.226
3
.626
1319
.1132
n
3-86
4-08
O.II99
0.1275
5.269
4
.7 9 8
.1645
.1498
n
5 .161
5-72
0.1612
0.1784
6.588
6
.183
.2057
.1930
0.2
1.268
i-Si
0.0396
0.0471
31.92
33
.84
. 99 68
I
.056
1,914
2.27
0.0597
0-0710
33-26
37
25
I
.038
I
.163
(t
2.464
3-04
0.0769
0.0949
u
3-967
4.90
0.1239
0.1530
0.4
i .202
1.61
0.038
0.0504
n
1.894
2 .26
0.059
0-0706
TANNIC ACID C 13 H 9 O 7 COOH.
100 gms. H 2 O dissolve about 294 gms. at 25; 100 gms. alcohol
dissolve about 439 gms. at 25. (U.S. P.)
TAETARIO ACID C 2 H 2 (OH) 2 (COOH) 2 .
SOLUBILITY IN WATER.
(Leidie Compt. rend. 95, 87, '82.)
t. Grams Tartaric Acid per 100 Gms. H 2 O. t. Gms. Tartaric Acid per 100 Grns. H 2 O.
'
Dextro
Racemic
Racemic
Dextro
Racemic
Racemic
and Laevo
Ac.
Ac.
and Laevo
Ac.
Ac.
Acids.
Anhydrous.
Hydrated.
Acids.
Anhydrous.
Hydrated
O
115.04
8.16
9-23
50
195.0
5O.O
59-54
10
125.72
12.32
14.00
60
217-55
64.52
78.33
20
139-44
18.0
2O.6o
70
243.66
80.56
99.88
2 5
147.44
21.4
24.61
80
273-33
98.12
124.56
30
156.2
2 5 -2
29.10
90
306.56
117 .20
I52-74
40
176.0
37-o
43-32
100
343-35
I37-80
184.91
SOLUBILITY OF TARTARIC ACID IN ALCOHOL AND IN ETHER
AT 15.
(Bourgoin Ann. chim. phys. [5] 13, 405, '78.)
Gms. Tartaric Acid per 100 Gms.
Solvem - Sat. Solution. Solvent!
Absolute Alcohol 20.385 4i-i35
90 % Alcohol 29 . 1 46 25. 604
Absolute Ether o . 389 o . 40
TELLURIUM Te.
100 gms. methylene iodide CH 2 I 2 dissolve o.i gm. Te at 12.
(Retgers Z. anorg. Chem. 3, 349. '93)
TELLURIC ACID
332
TELLURIC ACID H 2 TeO 4 .2H 2 O.
SOLUBILITY IN WATER.
(Mylius Ber. 34, 2208, '01.)
...
Gms.
H 2 TeO 4
per 100
Gms. Sol.
Mols
H 2 Te0 4 per Solid
100 Mols. Phase.
H 2 0.
to.
Gms.
H 2 TeO 4
per loo
Gms. Sol.
Mols.
H 2 TeO 4 per Solid
loo Mols. Phase.
H 2 0.
o
13.92
1.51 H 2 Te0 4 .6H20
30
33.36
4.67 H 2 TeO 4 .2HjC
5
17.84
2.03
40
36.38
5-33
10
26.21
3-3 1
60
43 -67
7-04
jt-
3 2 -79
4.41
80
$1-53
9-93
10
25.29
3.15 H 2 Te0 4 . 2 H 2
IOO
60.84
14.52
18
28.90
3.82
no
67.0
19.0 M
TELLURIUM DOUBLE SALTS
SOLUBILITY OF TELLURIUM DOUBLE BROMIDES AND CHLORIDES
IN AQUEOUS HYDROCHLORIC AND HYDPOBROMIC ACIDS
AT 22.
(Wheeler Z. anorg. Chem. 3, 432, '93.)
Tellurium Double .Salt.
Formula.
Solvent.
Gms. Double Salt per 100
Gms. Solvent
Te Caesium Bromide TeBr 4 .2CsBr Aq. HBr
Te Potassium. Bromide TeBr 4 .2KBr
Te Rubidium Bromide
Te Caesium Chloride
Te Rubidium Chloride
TeBr 4 . 2 RbBr
TeCl 4 .2CsCl Aq. HC1*
TeCl 4 .2RbCl
of i.4pSp. Gr.
0.02
6-57
0.25
0.05
of i.o8Sp.Gr.
0.13
62.90
3-88
0.78
o-34
13.09
So. Gr. of Aq. HC1 solutions 1.2 and 1.05 respectively.
THALLIUM ALUMS
Alum.
SOLUBILITY IN WATER AT 25
(Locke Am. Ch. J. 26. 174, '01.)
Salt per 100 Grams H 2 O.
Formula.
Tl Aluminum Alum
Tl Vanadium Alum
Tl Chromium Alum
Tl Iron Alum
Gms.
Gms.
Gm.
Anhydrous.
Hydrated.
Mols.
7-5
11.78
0.0177
25-6
43-31
0-0573
IO.48
16.38
0.0212
36-IS
64.6
0.0799
TlAl(SO 4 ) 2 .i2H 2 O
TlV(SO 4 ) 2 .i 2 H 9 O
TlCr(S0 4 ) 2 .i 2 H 2
TlFe(S0 4 ) 2 .i2H 2
THALLIUM BROMATE TlBrO 3
One liter saturated aqueous solution contains 3.463 gms. TlBrO 3 at 19.96
(B.), and 7.355 gms. at 39-75 (N. and A.).
(Bottger Z. physik. Chem. 46, 602, '03; Noyes and Abbott Ibid. 16, 132, 'gs.)
THALLIUM BROMIDE TIBr
One liter saturated aqueous solution contains 0.42 gm. TIBr at 18,
0.476 gm. at 20, 0.57 gm. at 25, and 2.467 gms. at 68.5.
(Kohlrausch Z. physik. Chem. 50, 356, '04; Noyes Ibid. 6, 248, '90; Bottger.)
SOLUBILITY or TIBr IN AQ. SOLUTIONS OF T1NO 3 AT 68.5. (Noyes.)
Gram Molecules per Liter. Grams per Liter.
0.0163 T1NO,
0.0294 ll
0.0955 "
0.00410 TIBr
0.00289 "
0.00148 "
4.336 T1N0 3
7.820 "
25-400 "
i . 164 TIBr
0.821 "
0.420 "
333 THALLIUM CHLORATE
THALLIUM CARBONATE AND THALLIUM (Per) CHLORATE.
THALLIUM CHLORATE T1C1O 3 . ( See P- 338-)
SOLUBILITY IN WATER.
(Muir J. Chem. Soc. 29, 857, '76.)
t 20 5 80 100
Gms. T1C1O 3 per ioo gms. H 2 O 2.80 3.92 12.67 36-65 57 -3 1
SOLUBILITY OF MIXED CRYSTALS OF THALLIUM CHLORATE AND
POTASSIUM CHLORATE IN WATER AT 10.
(Roozeboom Z. physik. Chem. 8, 532, '91.)
NOTE. Solutions of the two salts were mixed in different pro-
portions and allowed to crystallize, such amounts being taken that
not more than one or two grams would separate from one liter.
Grams per 1000 cc.
Solution.
Mg. Mols. per 1000 cc.
Solution.
Sp. Gr.
of
Mol. per cent
KC1O 3 in Mixed
TldlO 3 .
KC10 3 .
T1C10 3 .
KC1O 3 .
Solutions.
Crystals.
25.637
89.14
I .0210
O
19.637
6.884
68.27
56-I5
I .0222
2 .0
12 -OOI
26.IOO
41-73
2 1 2 . 89
I .0278
12 .6l
9.036
40-064
31.42
326.79
I-0338
25.01
7.885
7-935
46.497
46-535
27.42
27 .60
379.26
379-57
I .0360
} 36.30-97-93
6.706
46.410
23.32
378.55
1-0357
99.28
6.729
47-109
23-37
384-25
I .0363
99.60
4.858
47 -3 12
16.89
385-9 1
I -0345
99.62
2.769
47-134
9.63
384.46
I .0330
99.67
49.925
407.22
1.0330
IOO-OO
SOLUBILITY OF MIXED CRYSTALS OF THALLIUM CHLORATE AND
POTASSIUM CHLORATE IN WATER AT DIFFERENT
TEMPERATURES.
(Quoted by Rabe Z. anorg. Chem. 31, 156, '02.)
TOO gms. HoO dissolve 2.8 gms. T1C1O 3 4- 3.3 gms. KC1O 3 at o.
100 gms. H 2 O dissolve 10.0 gms. TICICX -f i . 5 gms. KC1O 3 at 15.
100 gms. H 2 O dissolve 12.67 ms - T1C1O 3 + 16.2 gms. KC1O 3 at 50.
100 gms. H 2 O dissolve 57.3 gms. T1C1O, + 48.2 gms. KClO 8 at 100.
THALLIUM CHLORIDE T1C1.
SOLUBILITY IN WATER.
(Average curve from results of Noyes Z. physik. Chem. 9, 609, '92; Bottger Ibid. 46, 602, '03; Kohl-
rausch Ibid. 50, 350, '04; Hebberling; Crookes; Lamy The results of Berkeley Trans. Roy.
Soc. (Lond.) 203 A, 208, '04 are also given.)
10
2O
Gms. T1C1
Liter.
per t0>
Gms. T1C1 per t <>
Liter.
Gms. T1C1 per
Liter.
2.1 (av.)
2-5
3-3
I
2
3
7
4
4
(B.) 25
30
40
5o
3
4
5
6
.86
.2
.2
3
4-0
4.6
6.0
8.0
60
80
100
8.0
12 -O
18.0
IO-2
16.0
24.1
(99-3)
THALLIUM CHLORIDE 334
THALLIUM CHLORIDE T1C1.
SOLUBILITY IN WATER AND IN AQ. SALT SOLUTIONS AT 25.
(Noyes; Noyes ar\d Abbott; Geffcken Z. physik. Chem. 49, 296, '040
G. Mols. per Liter. Grams per Later.
/\Q. oiiit ooiution*
Ammonixun Nitrate NEUNOs
>i
it
Barium Chloride BaCl 2
Cadmium Sulphate CdSO 4
Hydrochloric Acid HC1
' Salt.
0-0
o-5
I.O
2.0
0-0283
0.1468
0.030
0.0787
0.1574
0.0283
0-0560
TICK
o. 01612
0.02587
0.03I2I
0.03966
0.00857
0-00323
O.O2O6
0.0254
0.0309
0.00836
0-00565
Salt.
o.o
40.02
80.05
160.10
5-895
30-59
6-255
16.41
32.82
1.032
2.043
T1C1.
3.861 (G.)
6.2O9
7-473
9-497
2.052 (N.)
0-773
4-933 (N.)
6.081
7-399
2.002 (N.)
1-353
14
0.1468
0.00316
5-357
o-757
Lithium Nitrate LiNO 3
o-5
O.O2542
34-53
6.o8 5 (G.)
"
i .0
0-03035
69.07
7.266
it
2-O
0-03785
138.14
9.063
"
3-o
0.04438
207.21
10.630
Potassium Chlorate KClOa
o-5
0.0237
61.28
5 674 (G.)
Potassium Nitrate KNO 3
0-015
O.OI7O
i-5i7
4-070 (N.)
"
0-030
0.0179
3-033
4-286
"
0.0787
O.OI92
7-775
4-597
it
o.i574
O.O2I2
15.920
5.076
M
o-5
0.0257
50-55
6.153(0.)
M
i .0
0.0308
IOI.II
7-375
"
2.0
0.0390
202.22
9-340
Sodium Acetate CHaCOONa
0.015
0.0168
1.231
4-023 (N.)
"
0.030
O.OI72
2.462
4.118
"
0-0787
0.0185
6.46
4-430
"
0-1574
0.0196
12.92
4-693
Sodium Nitrate NaNO
o-5
0.02564
42.50
6.139 (G.)
ii
I.O
0.03054
85.01
7-3I3
"
2.O
0-03851
170.02
9.221
ii
3-o
0.04544
255-03
10.88
it
4.0
0.05128
340.12
12.28
Sodium Chlorate NaClOj
o-5
O.O232O
53-25
5-555 (G.)
I.O
0.02687
106.5
6 -433
2.0
0.03060
213.0
7.326
3-o
0-03303
3I9-5
7.909
41
4-0
0.03850
426.0
9.215
Thallium Bromate TIBrOj (at 39.75)
0.01567
0.01959
5 201
4.690 (N.andA.)
Thallium Nitrate T1NO
0.0283
0.0083
7.518
1.987 (N.)
0.0560
O.OO57I
14.89
1.368
"
0.1468
0.00332
39-05
0-795
Thallium Sulphate T1 2 SO4
0.0283
0.00886
14.27
/ SU
2. 121 (N.)
' .
0.0560
0.00624
28.23
1-494
Thallium Sulphocyanide T1SCN
Sat.
O.OII9
Sat.
2.849(N.)
(at 39-75)
0.02149
O.Ol8o7
5-504
4.326 (N.andA.)
335
THALLIUM CHLORIDE
SOLUBILITY OF THALLIUM CHLORIDE IN AQUEOUS SOLUTIONS OP
SALTS AT 25.
(Noyes Z. physik. Chem. 9, 609, '92.)
Aq. Salt Gram. Equiv. per
Liter.
Grams, per Liter.
Grams per Liter.
Solution. Salt.
T1C1.
Salt.
T1C1. '
Salt.
T1C1.
NH 4 C1
o.o
NH4C1 or HC1
0.
Ol6l2
0.00 NH4C1 3
,861
.00
HC1 3
.861
and
also 0.025
"
O.
00873
1.338
2.
101
0.886
2,
o
HC1
0.05
11
0.
00589
2.676
" I
.421
i
772
I
.402
O.IO
" 0.00384 . . ...
3
545
"
.920
o. 20
"
0.
00262
10. 704
0.649
7
.090
44 O
.608
CuCl 2
0.025CuCl 2 or CaCl 2 0.
00902
3.36
CuCl 2 2
.161
3
77
CaClj 2
.161
and
also 0.05
0.
00619
6.72
I
483
7
55
I
.483
CaCl 2
O.IO
"
O.
00419
13-45
I
.003
15
.11
44 I
.003
0.20
"
0.
00287
26.90
" O
.688
3
.22
.687
MgCl 2
. 025MgCl 2 or MnClizO .
CKXJOl
2.381
MgCl 2 2
.158
3
.147
MnCl 2 2
.158
and
also 0.05
O.Oo6l8
4.763
" 1.480
6
295
I
.480
MnCl 2
O. IO
11
0.
00412
9.526
" O
.987
12
59
44 O
.987
0.20
11
0.
00278
19.052
.666
25
.18
.666
KC1
0.025
KC1 or NaCl
0.00871
1.86
KC1 2
.086
I
.46
NaCl 2
.086
and
also 0.05
"
O.
00592
3-73
" I.
,418
2
925
I
.418
NaCl
O. IO
"
0.
00397
7.46
"
95 1
5
85
44
951
0.20
0.00268
14.92
44 o
.642
ii
.70
44 O
.642
T1C1O
3 0.025 TIClOaorTlNOsO . 00889
5.276
T1C1O 3 2
.129
4
-74
T1NO 3 2
.129
and
also 0.05
0.
00626
9
.48
I
.500
T1NO 3 o.io
,00423
...
18
.96
I
.014
ZnCl 2
0.025
ZnCl 2
0.00899
3-41
ZnCl 2 2
153
0.05
0.00627
6.81
44 I
.502
O.IO
0.00412
13-63
" 0. 9 87
0.20
"
o.
0028l
27.26
44
673
CdCl 2
0.025
CdCl 2
0.0104
4-53
CdCl 2 2
.491
0.05
"
o.
0078
9.16
" I
.868
O.IO
'
0.
00578
18.33
I
-385
O.20
" 0.00427
36.66
I
.029
One liter of water dissolves 2.7 gms. thallo thallic chloride jTlCl.TlCl,
at i5-i7, and 35.0 grams at 100.
(Crookes; Lamy; Hebberling.)
THALLOUS CHROMATE Tl 2 CrO 4 .
100 gms. H 2 O dissolve 0.03 gm. Tl 2 CrO 4 at 60, and 0.2 gm. at 100.
(Browning and Hutchins Z. anorg. Chem. 22, 380, *oo.)
One liter of aq. 31 per cent KOH solution dissolves 18 grams Tl 2 CrO 4 .
(Lepierre and Lachand Compt. rend. 113, 196, '91.)
One liter of H 2 O dissolves 0.35 gram Thallous Tri Chromate
Tl 2 Cr 3 10 at 15, and 2.27 grams at 100. (Cro oke,.>
THALLOUS CYANIDE 336
THALLOUS CYANIDE T1CN and Double Cyanides.
SOLUBILITY IN WATER.
(Fronmuller Ber. n, 92, '78.)
Cyanide. Formula. Gms. Salt per zoo Cms. H 3 O.
Tl Cyanide T1CN at 28.5, 16.8
Tl Cobalti Cyanide Tl 3 Co(CN) 6 at o, 3.6 ; at 9.5, 5.86 ; at 19.5, 10.04
Tl Zinc Cyanide 2TlCN.Zn(CN) 2 at o, 8.7 ; at 14, 15.2 ; at 31, 29.6
Tl Ferro Cyanide Tl 4 Fe(CN) 6 .2H 2 O at 18, 0.37 at ioi 5 , 3.93.
(Lamy.)
THALLOUS FLUORIDE TIP.
100 gms. H 2 O dissolve 80 gms. TIP at 15.
(Buchner Sitzb. K. Akad. Wiss. (Wein) 52, 2, 644, '65.)
THALLIUM IODATE T1IO 3 .
One liter aq. solution contains 0.578 gram T1IO 3 at 20.
(Bottger Z. physik. Chem. 46, 602, '03.)
THALLIUM IODIDE Til.
SOLUBILITY IN WATER.
(Average results from Bottger; Kohlrausch; Werther; Crookes; Lamy; Hebberling.)
t . o. 20. 40. 60. 80. 100.
Gms. Til per liter 0.02 0.06 0.15 0.35 0.70 1.20
One liter of z\ per cent aq. ammonia dissolves 0.761 gm. T1C1.
One liter of 6$ per cent aq. ammonia dissolves 0.758 gm. T1C1.
One liter of 90 per cent alcohol dissolves 0.0038 gm. T1C1.
One liter of 50 per cent alcohol dissolves 0.027 gm. T1C1.
(Long J. Anal. Ch. 2, 243, '88.)
THALLIUM NITRATE T1NO 3 .
SOLUBILITY IN WATER.
(Berkeley Trans. Roy. Soc. (Lond.) 203 A, 213, '04; see also Etard Ann. chim. phys. [7] 2,
527, '94; Crookes; Lamy.)
Gms. TlNO 3- per 100 Gms. Gms. T1NO 3 per 100 Gms.
Solution.
Water.
i. .
Solution.
Water.
o
3-76
3-91
60
31-55
46.2
10
5-86
6.22
70
41 .01
69-5
20
8. 7 2
9-55
80
5 2.6
III .O
30
12.51
14-3
90
66.66
2OO-O
40
J 7-33
20.9
100
80.54
4I4-0
5
2 3-33
30-4
105
85-59
594-0
Solid phase. T1NO 3 rhombic.
100 gms. H 2 O dissolve 43.5 gms. T1NO 3 + 104.2 gms. KNO 3 at 58.
(Rabe Z. anorg. Chem. 31, 156, '02.)
THALLIUM OXALATE T1 2 C 2 O 4 .
One liter of saturated aqueous solution contains 15.77 grams
T1 2 C 2 O 4 at 20, and 18.69 m s. at 25.
(Bottger Z. physik. Chem. 46, 602, '03; Abegg and Spencer Z. anorg. Chem. 46, 406, '05.)
337
THALLIUM OXALATE
SOLUBILITY OF THALLIUM OXALATE AT 25 IN AQ. SOLUTIONS OF:
Thallium Nitrate.
(Abegg and Spencer.)
Mol. Concentration. Grams per Liter.
T1N0 3 - T1 2 C 2 4 .~
o-oo 18.69
10-95
21 .26
Potassium Oxalate.
(A. and S.)
Mol. Concentration.
T1N0 3 .
O-O
O.O4II4
0.0799
0-1597
T1 2 C 2 4 .
0-03768
0-0264
0.0195
0.01235
K 2 C 2 4 . T1 2 C 2 4 .
0-0498 0-0351
0-0996 0-03565
0-2467
0.4886
Grams per Liter.
K 2 C 2 4 . T1 2 C 2 4 .
8.28l 17.42
16.57
0.0390
0-04506
41 -02
81.25
17.69
19.36
22-37
27.48
13 .IO
9-68
42.51 6.128
0.9785 0.05536 162.6
THALLOUS PHOSPHATE (ortho) T1 3 PO 4 .
One liter of sat. aqueous solution contains 4.97 gms. T1 3 PO 4 at 15
(Crookes.)
T10C 6 H 2 (N0 2 ) 3 .
and 6.71 gms. at 100.
THALLIUM PICEATE
SOLUBILITY IN WATER.
(Rabe Z. physic. Chem. 38, 179, '01.)
t.
Gms.
T10C 6 H 2 (N0 2 )3 Solid
per joo Phase.
t .
T10C 6 H 2 (N0 2 ) 3 Solid
per TOO Phase.
Gms. H 2 0.
Gms.
H0 2 .
O . 135 Monoclinic Red
45
I
.04
Triclinic Yellow
18
0.36
47
I
.IO
"
30
0-575
50
I
.205
"
40
0.825
60
I
73
"
45
I .01
7o
2
43
"
47
1.14
ioo gms. H 2 O dissolve 0.132 gm.
C 6 H 4 (NO 2 ) 3 OK at o.
ioo gms. H 2 O dissolve 0.352 gm.
C 6 H 4 (N0 2 ) 3 OK at 15.
ioo gms. H 2 O dissolve 0.38 gm.
C 6 H 4 (N0 2 ) 3 OK at 20.
C 6 H 2 (NO 2 ) 3 OT1 + 0.36 gram
C 6 H 2 (NO 2 ) 3 OT1 + 0.44 gram
C 6 H 2 (NO 2 ) 3 OT1 + 0.23
gram
(Rabe.)
SOLUBILITY OF THALLIUM PICRATE IN METHYL ALCOHOL.
(Rabe.)
t.
Gms.
T10C6H 2 (NO 2 ) 3 Solid
Gms.
t. T1OC6H 2 (NO 2 ) 3 Solid
per ioo Phase.
Gms. CH 3 OH.
per 100 Phase.
Gms. CH 3 OH.
O- 39 ^ e ^ Form (monoclinic).
45
i-i95
Yellow Form (triclinic).
18
o-59
48
i. 265
25
o. 70
50
x '3 2 5
"
30
0-795
53
1.41
"
35
0.90
57
1-54
"
40
1.02
60
1-65
u
45
I.I7
65
1.84
"
47
1.265
THALLIUM SULPHATE 338
THALLIUM SULPHATE T1 2 SO 4 .
SOLUBILITY IN WATER.
(Berkeley Trans. Roy. Soc. (Lond.) 203 A 211, '04; see also Crookes; Lamy.)
Gms. T1 2 SO 4
per
IOO
Gms. T1 2 SO 4
per ioo
; e . Gms. t.
Gms
Solution.
Water.
Solution.
Water.
2.63
2.
70
60
9.89
10.92
10
3-57
3-
70
70
11.31
12-74
2O
4.64
4-
87
80
12.77
I4.6l
30
5.80
6.
16
90
14.19
16 -53
50
8.44
9-
21
99-7
15-57
18.45
ioo gms. H 2 O dissolve 4.74 gms. T1 2 SO 4 + 10.3 gms. K 2 SO 4 at 15.
100 gms. H 2 O dissolve 11.5 gms. T1 2 SO 4 + 16.4 gms. K 2 SO 4 at 62.
ioo gms. H 2 O dissolve 18.52 gms. T1 2 SO 4 + 26.2 gms. K 2 SO 4 at 100.
(Rabe Z. anorg. Ch. 31, 156, '02.)
THALLIUM SULPHIDE T1 2 S.
One liter of sat. aqueous solution contains 0.215 gm. T1 2 S at 20.
(Bottger Z. physic. Chem. 46, 602, '03 7
THALLIUM DOUBLE SULPHATES
SOLUBILITY IN WATER AT 25.
(Locke Am. Ch. J. 27, 459, '01.)
Salt per TOO cc. H 2 O.
Double Sulphate. Formula. : - " rr-,
Gms . Anhydrous . Gram Mols .
Tl Copper Sulphate Tl 2 Cu(SO 4 ) 2 .6H 2 O 8.1 0.0122
Tl Nickel Sulphate Tl 2 Ni(SO 4 ) 2 .6H 2 O 4.61 0.007
Tl Zinc Sulphate Tl 2 Zn(SO 4 ) 2 .6H 2 O 8.6 0.0129
THALLIUM SULPHOCYANIDE T1SCN.
SOLUBILITY IN WATER AND IN AQUEOUS SALT SOLUTIONS.
(Bottger; Noyes; Noyes and Abbott.)
One liter sat. aq. solution contains 3.154 gms. T1SCN at 20, 3.905 gms.
at 25, and 7.269 gms. at 39.75.
Aq. Salt Solution. t. ^ M 1S ' "" ^ GBUM *" Uta '
Salt. T1SCN. Salt. T1SCN.
Thallium Chloride T1C1 25 sat. O.OIO7 sat - 2 805 (N.)
Thallium Bromate TIBrO. 39-75 0.014960.0221 4 . 966 5 . 793 (N. and A.)
Thallium Nitrate T1NO 25 O.O227 0.00852 6.04 2.233 (N '>
25 0.0822 0.00406 21.88 1.064
Potassium Sulphocyanide, KSCN 25 O.O227 0.0083 2 . 208 2 . 176 (N.)
THALLIUM CARBONATE T1 2 CO 3 .
SOLUBILITY IN WATER.
(Crookes; Lamy.)
t 15.5 18 62 100 100.8
Gms. T1 2 CO 3 per ioo gms. H 2 O 4.2(0.) 5.23 12.85 27.2(0022.4
THALLIUM (Per) CHLORATE T1C1O 4 .
ioo grams H 3 O dissolve 10 gms. T1C1O 4 at 15, and 166.6 gms. at 100.
(Roscoe J. Chem. Soc. 19, 504, '66.)
339 THALLIUM SULPHITE
THALLIUM SULPHITE T1 2 SO 3 .
100 gms. H 2 O dissolve 3.34 gms. T1 2 SO 3 at 15.5.
(Seubert and Elkeu Z. anorg. Chem. a 434, '92.)
THALLIUM VANADATES.
SOLUBILITY IN WATER.
(Carnelly J. Chem. Soc. [2] n, 323, '73; Laebig's Ann. 116, 155, '60.)
Vanadate. Formula. Gms. Vanadate per TOO Gms. H 2 O.
At 15 . At 100.
Tl. meta Vanadate T1VO 3 0.087(11) 0.21
" ortho Vanadate T1 3 VO 3 i .o 1.74
" pyro Vanadate T1 4 V 2 O 7 0.20(14) 0.26
" Vanadate T1 12 V 8 O 26 0.107 0.29
THEOBROMINE C 5 H 2 (CH 3 ) 2 N 4 O 2 .
100 gms. carbon tetra chloride dissolve 0.0212 gm. at b. pt.
100 gms. ether dissolve 0.032 gm. at b. pt.
(Gockel Chem. Centralb. ii, 401, '97.)
80 cc. H 2 O containing 14.8 gms. tri sodium phosphate dissolve
3.5 gms. theobromine at 15.
(Brisse-Moret J. pharm. chim. [6] 7, 176, '98.)
THORIUM SELENATE Th(SeO 4 ) 4 . 9 H 2 O.
100 gms. H 2 O dissolve 0.498 gm. Th(SeO 4 ) 4 at o and 1.972 gms.
at 100.
(Cleve Bull. Soc. chim. [2] 43, 166, '85.)
THORIUM SULPHATE Th(SO 4 ) 2 .
SOLUBILITY IN WATER.
(Roozeboom Z. physic. Chem. 5, 201, '90; Demarcay Compt. rend. 96, 1860, '83.)
Gms. Th(S0 4 ) 2 per Solid t o Gms. Th(SO 4 ) 2 per Solid
' 100 Gms. H 2 0. ' Phase. 100 Gms. H 2 O. Phase.
O 0-74(R) 0.88(D) Th(S0 4 ) 2 .9H 2 O I-5O(R) Tb(SO 4 ) 2 .6H 2 O
10 0.98 1-02 " 15 1-63
20 1.38 1.25 " 30 2-45
30 1.995 I - & 5 45 3-85
40 2 . 998 2 . 83 60 6 . 64
50 5. 22(51) 4-86 17 9-4i(D)
55 6.76 6-5 " 40 4-Q4(R)4-5(35 D )
O 1-0 ThCSO^-SHa 50 2.54 1.94(55)
15 1.38 60 1.63
25 1.85 " 70 1-09 I-32(75 )
44 3-7i " 95 o-7i
TIN CHLORIDE 340
TIN CHLORIDE (Stannous) SnCl 2 .
100 gms. H 2 O dissolve 83.9 gms. SnCl 2 at o and 269.8 gms. at 15,
Sp. Gr. of Solutions 1.532 and 1.827 respectively.
(Engel Ann. chira. phys. [6] 17, 347, '89; Michel and Krafft Ibid. [3] 41, 478,' 51.)
SOLUBILITY OF STANNOUS CHLORIDE IN AQUEOUS SOLUTIONS OF
HYDROCHLORID ACID AT o.
(Engel.)
Milligram Mols.
Solution
per 10 cc.
Sp. Gr.
of
Grams per ioo cc.
Solution.
HC1.
}SnCl 2 .
Solution.
HC1.
SnCl 2 .
74-o
1-532
o.o
70.26
6.6
66.7
1.489
2.405
63-33
13-54
63-7S
1.472
4-935
60.52
24.8
68.4
1.524
9.04
64-95
34-9
8l.2
I .625
12.72
77.11
40-0
94.2
1.724
14.58
89-45
44.0
II7.6
1.883
16.04
111.7
49-4
147.6
2.II4
18.01
138.6
66.0
156.4
2 .190
24.05
148.5
78.0
J 57-o
2.199
28.43
149-0
100 gms. acetone dissolve 55.6 gms. SnCl 2 at 18.
(Naumann Ber. 37, 4332, '04.)
ioo gms. ether dissolve 11.4 gms. SnCl 2 .2H 2 O at o-35.5.
100 gms. ethyl acetate dissolve 31.2 gms. SnCl 2 .2H 2 O at 2, 35.53
gmS. at +22 and 73.44 gmS. at 82. (von Laszcynski Ber. 27, 2285, '94.)
TIN HYDROXIDE Sn(OH) 2 .
SOLUBILITY IN AQUEOUS SODIUM HYDROXIDE SOLUTIONS. MOIST
TIN HYDROXIDE USED, ORDINARY TEMPERATURE.
(Rubenbauer Z. anorg. Chem. 30, 335, '02.)
Gms. per 20 cc.
Solution. D
ilution of the
NaOH.
1.86
1.25
0.72
Gms. per 20 cc.
Solution. j
Mol.
dilution of the
NaOH.
0.48
0.23
Na.
o . 2480
0.3680
0.6394
Sn.
0.1904
0-2614
0.4304
Na.
0.8326
0.9661
2.1234
Sn.
0.5560
0.7849
1.8934
TIN IODIDE (Stannous) SnI 2 .
SOLUBILITY IN WATER AND IN AQUEOUS HYDRIODIC ACID.
(Young J. Am. Chem. Soc. 19, 851, '97.)
t. Gms. SnI 2 per ioo Gms. Aqueous HI Solutions of:
o% = H 2 0.
5-83%.
9-6o% .
15-2%.
20.44%.
24-8%.
30.4%.
36.82%.
20
0.98
0-20
0.23
0.60
1.81
4. 20
10.86
25-3 1
30
1.16
0.23
0.23
0.64
1.81
4.06
10.28
23.46
40
i .40
o-33
0.28
0.71
1.90
4.12
10. 06
23 -*5
50
i .69
0.46
0.38
0.82
2.12
4-34
J o-35
23.76
60
2.07
0.66
o-55
i .11
2.51
4-78
11.03
24.64
70
2.48
0.91
0.80
i-37
2 .92
5-43
11.97
25-72
80
2 -95
1.23
1-13
1.83
3-70
6.38
I 3-3Q
27.23
90
3-46
1-65
1.52
2.40
4-58
7.82
I5-52
29.84
IOO
4-03
2 .23
2.04
3-63
5-82
9.60
34-05
341 TIN IODIDE
TIN IODIDE (Stannic). SnI 4 .
SOLUBILITY IN CARBON BISULPHIDE.
(Sneider Pogg. Ann. 127. 624, '66; Arctowski Z. anorg. Chem. ix, 274, '95.)
t- -ii4 -S ' -94 -89 -84 -58 ord. temp.
Gms. SnL per ,
ioo gms Solution 9"* 1 10.65 9.68 10.22 16.27 59^(S.)
ioo gms. methylene iodide, CH 2 I 2 , dissolve 22.9 gms. SnI 4 at 10.
Sp. Gr. of Solution 3.481.
(Retgers Z. anorg. Chem. 3, 343, '93.)
TIN SULPHATE (Stannous) SnSO 4 .
ioo gms. H 2 O dissolve 18.8 gms. SnSO 4 at 19 and 18.1 gms. at 100.
(Marignac.)
TOLUENE C.H 5 CH,.
SOLUBILITY IN SULPHUR.
Figures read f-om curve, synthetic method used, see Note, page 9.
(Alexejew Ann. Physik. Ch. 28, 305, '86.)
Gms. C 6 H 5 CH 3 per ioo Gms. Gms. CeHsCHa .per ioo Gms
*' S Toluene * ' S Toluene
Layer. Layer. Layer. Layer.
ioo 3 73 150 12.5 59
no 4 71 160 16 53
'120 5 68 170 22 47
130 7 66 175 25 43
140 9.5 63 178 crit. temp. 34
TOLUIC ACIDS (Monomethyl Benzoic Acids) CH 3 .C C H,.COOH.
SOLUBILITY IN WATER AT 25.
(Paul Z. physik. Chem. 14, in, '94.)
per Liter Solution.
Acid ' Grams. Millimols*.
Meta Toluic Acid 0.9801 7.207
Ortho Toluic Acid i . 1816 8 .683
Para Toluic Acid 0.3454 2 .540
TOLUIDINE C f) H 4 CH 3 .NH 2 .
SOLUBILITY IN WATER.
(Vaubel J. pr. Chem. [2] 52, 72, '95; Lowenherz Z. physik. Chem. 25, 410, '98.)
Gms. Gms.
t o CeKUCHs-NHa Solid t C^CHaNI^ Solid
per 1000 Phase. per 1000 Phase.
Gms. H 2 O. Gms. H 2 O.
2O 16.26 Liquid ortho T. 2O-8 7 '39 ParaT.
2O O.I5 Ortho T. 26.7 9-5
20 6.54 P^T. 31.7 11.42
TOLUIDINE 342
SOLUBILITY OF PARA TOLUIDINE IN ETHYL ALCOHOL.
(Interpolated from original results of Speyers Am. J. Sci. [4] 14, 295, '02.)
Wt.
Mols. per
Gms. per
t
of i cc.
ioo Mols.
ioo Gms.
Solution.
C 2 H 6 OH.
C 2 H 5 OH.
O
0-8885
20.72
48.1
5
0-8982
26.0
6o-O
10
0.9080
32.0
74.0
15
0.9180
38.6
9O.O
...
Wt.
of i cc.
Solution.
Mols. per
ioo Mols.
C 2 H 5 OH.
Gms. per
ioo Gms.
C 2 H 6 OH.
2O
25
30
0.9265
0.9360
0.9460
47-0
56.0
66.0
IIO.O
132.0
156.0
Distribution of para Toluidine between water and carbon tetra
Chloride. (Vaubel J. pr. Chem. [2] 67, 478, '03.)
Gms. p Toluidin
Used.
I .0
1.0
Volumes of Solvents.
200 cc. H 2 O-f ioo cc. CC1 4
200 CC. H 2 O + 200 CC. CC1 4
Gms. CaH 4 (CH3)NH 2 p in:
H 2 Layer. CCU Layer."
0.1406 0.8594
0.0666 0.9334
URANYL CHLORIDE UO 2 C1 2 . 3 H 2 O.
ioo gms. H 2 O dissolve 320 gms. UO 2 C1 2 at 18.
(Mylius and Dietz Ber. 34, 2774, '01.)
URANYL DOUBLE CHLORIDES.
SOLUBILITY OF URANYL AMMONIUM CHLORIDE, U. TETRA METHYL
AMMONIUM CHLORIDE, U. TETRA ETHYL AMMONIUM CHLORIDE,
U. CAESIUM CHLORIDE, U. RUBIDIUM CHLORIDE, AND U. POTAS-
SIUM CHLORIDE IN WATER.
(Rimbach Ber. 37, 463, '04.)
Formula of
Double Salt.
Gms. per ioo Gms. Sat. Solution. Atomic Relation in Sol.
Solid
Phase.
r i i Mol. double salt
3-590 4-o.4Mol.NH4O
29.8
19.85 " -
- io.44O 2 = 41.24*
iUO 2 : 4.020
Double salt
80.7
20.23
- io.52O 2 4.91 *
iU0 2 : 3-98O
"
27.1
15.02
' -
- 7.81 C1 2 =37. I5 t
iU0 2 : 3-97C1
M
80.7
15-12
- 7-780 2 = 37-23 1
iUO 2 :3-94O
"
29-75
24.8
22.11
27.18
- 22.5 Cs = 56.04$
-i 6.6 Rb -f-i3.8Cl
iUO 2 : 2.o7Cs
iUO 2 : i.o6Rb: 3.900
H
80.3
30.66
- 19.1 Rb -
hi 5-80 ||
iUO 2 :i.98Rb:3-95Cl
"
0.8
38.57
- 13.590 -
- 3-86K
iUO 2 :2.69Cl:o.69K
^
14.9
33-71
-13.510 -
- T..K
iUO 2 : 3-o6O :i.o6K
The double salt
17-5
37-36
- 14.500 -
- 5-27K
iU0 2 : 2. 9 6O : o.o6K
J is decomposed
25x5
35-oi
_
- 15.260 -
- ... K
iU0 2 : 3 .33Cl:i.33K
> by water at
35-27
-15.920 -
u 7-39K
iU0 2 : 3 .44Cl :i. 4 4K
temperatures
5
34-iS
-16.560 -
- ... K
iU0 2 : 3 .7iCl :i.7iK
below 60.
60
34-19
- 17.250 -
- 9.1 4K
iU0 2 : 3-850 :i.8 5 K
J
7 1 5
33-55
- 9-28K
iU0 2 : 3.96O :i. 9 6K
Double salt
78-5
35-26 " -
- 18^240 -
- 9-95K
i UO 2 13.950 :i.95K
UOaCl 2 .2N(CH 3 ) 4 O, t UO 2 a 2 .N(C 2 H 6 ) 4 O, i UO 2 Cl 2 . 2 CsCl,
= 57-9 gms. UO 2 Cl 2 .2RbO 2 , || = 65.8 gms. UOxCb
343 URANYL SODIUM
CHROMATE
URANYL SODIUM OHROMATE 2 (UO 2 )CrO 4 .Na 2 CrO 4 .ioH 2 O.
100 gms. sat. aqueous solution contains 52.52 gms. (2UO 2 ).CrO 4 .
Na 2 CrO 4 at 20. (Rimbach.)
URANYL POTASSIUM BUTYRATE UO 2 (C 4 H 7 O 2 ) 2 .KC 4 H 7 O 2 -
The double salt is decomposed by water at ordinary temperatures
and the solution gets richer in uranyl butyrate. The solubility at
29.4 in water containing KC 4 H 7 O 2 is 2.10 gms. UO 2 (C 4 H 7 p 2 ) + 0.38
gms. KC 4 H 7 O 2 per 100 gms. solution. The atomic relation being i : 0.64.
(Rimbach.)
URANYL NITRATE UO 2 (NO 3 ) 2 .6H 2 O.
SOLUBILITY IN WATER, ETC.
(Bucholz; de Coninck Compt. rend. 130, 1304, 'oo.)
ioo gms. cold water dissolve 200 gms. UO 2 (NO 3 ) 2 .6H 2 O.
100 gms. abs. alcohol dissolve 333 gms. UO 2 (NO 3 ) 2 .6H 2 O.
ioo gms. 85% alcohol dissolve 3.3 gms. UO 2 (NO 3 ) 2 .6H 2 O at 12 (de C.)
ioo gms. ether dissolve 25 gms. UO 2 (NO 3 ) 2 .6H 2 O.
ioo gms. abs. acetone dissolve 1.5 gms. UO 2 (NO 3 ) 2 .6H 2 O at 12 (de C.)
For densities of Uranium nitrate solutions in water and other
solvents see de Coninck Compt. rend. 131, 1219, 'oo.)
URANYL DOUBLE NITRATES.
SOLUBILITY OF URANYL AMMONIUM NITRATE, U. CAESIUM
NITRATE, U. POTASSIUM NITRATE, AND U. RUBIDIUM
NITRATE IN WATER.
(Rimbach.)
Gms. per ioo Gms. Sat. Solution.
UO 2 . Total Salt.
29.71 + 2.92NH 4 . . . lUO 2
36.46+ 3.54 " ==68.95 "
44.37+ 2.90 " - ...
44.95+ 2.98 " =78.95
31.39+ 6.59 Cs =55.4
31.98+ 1.72 K :
33.40+ 2.72 "
37.07+4.01 " *= 64.82
42.18+ 5.16 " = ...
41.65+ 6.03 " = ...
43.71 + 6.38 " = . . .
35.41+ 4-65Rbf 59-60
34.66+11.01 " =69.49
* + 23.5NO-3. t + I9.74NG-3.
Formula of 4, o
Salt.
U0 2 (N0 3 ) 2 .NH 4 N0 3 0.5
24.9
59 -
" 80.7
UO 2 (NO 3 ) 2 .CsNO, 16.0
U0 2 (N0 3 ) 2 .KN0 3 0.5
13.0
25.0
80.6
UO 2 .(NO 3 ) 2 .RbNO 3 25.0
80.0
Atomic Relation
in Solution.
i. 47 NH 4 :
3-47N0 3
1.46 " :
3-46 "
0.98 " :
2.98 "
i. oo " :
3.00 "
0.44 Cs
2 . 37 N0 3 :
0.37 K
2-57 " :
0-57 "
1.60 " :
0.76 "
2.84 " :
0.84 "
3.00 " :
1. 00 "
3.01 " :
I.OI "
1.40 " :
o-45Rb
3.00 " :
I.OI "
URANYL AMMONIUM PROPIONATE 2 UO 2 (C 3 H 6 O 2 ) 2 .NH 4 C 3 H 8 O 2 .
2H 2 O and Uranyl Potassium Propionate 2UO 2 (C 3 H 5 O 2 ) 2 .KC 3 H 5 O 2 .
(Rimbach.)
ioo gms. aq. solution contain 16.48 gms. 2UO 2 (C 3 H 5 O2) 2 .NH 4 C 3 H 6 O,
at 29.8.
ioo gms. aq. solution contain 2.362 gms. UO 2 (C 3 H 5 O 2 ) 2 + 0.82 gm.
KC 3 H 6 O 2 at 29.4, atomic relation, 1:1.29.
UBANYL SULPHATE 344
UBANYL SULPHATE (UO) 2 SO 4 . 3 H 2 O.
SOLUBILITY IN WATER, ETC.
(Bucholz; de Coninck Bull. Acad. Roy. Belgique, 350, *oi.)
ioo gms. H 2 O dissolve 16.6 gms. UO 2 (SO 4 ).3H 2 O at 13.2, 17.4 gms.
at 15.5, and 22.2 gms. at b. pt.
ioo gms. abs. alcohol dissolve 4.0 gms. UO 2 (SO 4 ).3H 2 O at 18.2
and 5.0 gms. at b. pt.
ioo gms. 85% alcohol dissolve 2.6 gms. UO 2 (SO 4 ).3H 2 O at 16.
ioo gms. 16.2% alcohol dissolve 12.3 gms. UO 2 (SO 4 ).3H 2 O at 10.
URANYL POTASSIUM SULPHATE UO 2 SO 4 .K 2 SO 4 . 2 H 2 O
ioo gms. sat. aq. solution contain 10.41 gms. UO 2 SO 4 .K 2 SO 4 at 25
and 23.13 gms. at 70.5. (Rimbach.)
SOLUBILITY OF UO 2 SO 4 .2K 2 SO 4 .2H 2 O + UO 2 SO 4 .K 2 SO 4 .2H 2 O IN WATER.
Gms. per ioo Gms. Solution. Atomic Relation in Sol. Mol. % in Solid Phase.
I .
UO 2 .
*
s
3 4 .
UOj
. ]
t.
S0 4 .
Mono Salt.
Di Salt. '
14
0.85
4
.19
5
7i
i
35
75 :
18.88
2 9
71
50
6.70
8
15
12
37
i
5
20 :
8.40
7 6
24
80
14.29
8
54
J 5
53
i
4
I 3 :
3.06
12
88
UREA CO(NH 2 ) 2 .
SOLUBILITY IN WATER AND IN ALCOHOLS.
(Campetti Abstract, Z. physic. Chem. 41, 109, '02; Speyers Am. J. Sci. [4] 14, 259, '02.)
NOTE. Speyer's original results are in terms of Mols. CO(NH 2 ) 2
per ioo Mols. H 2 O at irregular temperatures.
In Water. In Methyl Alcohol. In Ethyl Alcohol.
t o Wt. Of I CC.
Solution.
Gms. CO(NH 2 ) 2 per Wt . o f i cc.
looGms. H 2 O. Solution.
Gms.
CO(NH 2 ) 2
per ioo Gms.
Gms.
Wt. of ice. CO(NH 2 ) 2
Solution, per ioo Gms
CH 3 OH.
.C 2 H 5 OH.
1. 121
55
9
0.861
13.8
0.8213
2 -5
IO
134
66
.0
85.0
(C)
0.863
16.0
O.8l4
3-5
20 j
.146
79
.0
108.2
(C)
0.869
20. o
0.809
5-o
30
.156
93
O
0.876
24.0
0.8o6
6-5
40
.165
106
.0
. . .
0.890
30.0
0.804
8-5
50
173
120
.0
. . .
0.908
37-o
0.803
10.5
60
.!8
I3 2
.0
. . .
0.928
47-o
13 .0
70
.187
145
.0
*7-5
ioo gms. abs. methyl alcohol dissolve 21.8 gms. CO(NH 2 ) 2 at 19.5.
ioo gms. abs. ethyl alcohol dissolve 5.06 gms. CO(NH 2 ) 2 at 19.5.
(de Bruyn Z. physic. Chem. 10, 784, '92.)
ioo gms. glycerine dissolve 50 gms. urea at 15.5.
Phenyl Thio UREA (Phenyl thio carbamide) CS.NH 2 .NHC 6 H 5 .
SOLUBILITY IN WATER.
(Rothmund Z. physic. Ch. 33, 406, 'oo; Biltz Ibid. 43, 42, '03; Holeman and Antusch Rec. trav.
chim. 13, 200, '94; Bogdan Ann. Scien. L'Univ. Jassy 2, 43, '02. '03.)
One liter aq. solution contains 2.12 gms. CS(NH 2 ).NHC 6 H 5 at 20
(B.), (R.) and 2.4 gms. at 25. (H. and A.). Bogdan gives 2.547 gms
at 25.
345
Phenyl Thio UREA
SOLUBILITY OP PHENYL THIO UREA IN AQUEOUS SALT
SOLUTIONS AT 20.
(Biltz; Rothmund.)
Mfflimols and also Cms. CS(NH 2 )NHCftH5 Dissolved per Liter of Aqueous
Salt Solution of Concentration:
Salt
0.125 Normal
0.25 Normal
o.^ Normal
ixs Normal
Solution.
Millimols. Gms.
Millimols.
Gms. Millimols.
Gms.
Millimols.
Gms.
JA1C1 3
12.95
1.97
12
.82
I
.96
12.03
1.8 3
10
.69
1.61
NH 4 NO 3
14.17
2.15
14
4
2
.21
J 4-53
2 .22
14
.91
2.27
i(NH 4 ) 2 S0 4
I3-5 1
2.05
12
.84
I
.96
11.78
1-79
9
.98
1.52
iBaC! 2
13.12
1.99
12
.92
I
97
12 .22
1.86
IO
44
J -59
JBa(N0 3 ) 2
13.98
2.13
13
.98
2
J 3
13.90
2.12
CsN0 3
14-53
2.21
14
.90
2
.27
!5- 2 3
2-33
.
. . .
LiN0 3
13.96
2.13
J 3
.96
2
13
J 3-93
2 .12
J 3
73
2.10
iMgS0 4
13.40
2 .04
12
.78
I
95
n-54
J -75
9
43
i-43
KC 2 H 3 O 2
13.40
2 -04
12
95
I
97
12 .14
1.85
10
74
1.62
KBr
13-50
2.05
J 3
35
2
.04
12. 80
i-95
ii
.76
1.79
KC10 3
13.86
2. II
13
.60
2
.06
13.12
1.99
KC1
13.40
2 .04
12
73
I
94
12 .19
1-85
10
54
i. 60
Kl
14.12
2.15
14
.48
2
.21
I4-3 1
2.18
14
.60
2.23
KN0 3
13.89
2 .12
13
85
2
.11
I3-52
2.05
12
.82
i .96
KNO 2
14.52
2 .21
14
65
2
23
13.80
2 .11
12
5 1
1.92
iK 2 S0 4
13-25
2.03
12
49
I
.91
ii .11
I .69
8
73
i-33
RbN0 3
14.22
2 .l6
14
44
2
.19
14-39
2.18
14
.22
2.17
iNa 2 CO 3
13.29
2 .04
12
5 2
I
. 9 I
ii .05
1.68
8
58
1.32
NaClO 3
13-75
2.09
J 3
65
2
.08
13.07
1.98
12
.21
1.86
NaC10 4
14-15
2.15
14
05
2
.14
I3-58
2.06
12
56
1.92
NaCl
13.28
2.02
12
83
I
95
ii .90
1.81
10
.02
1.52
Nal
13.98
2.13
14
.07
2
.14
14.29
2.18
J 3
.96
2.13
NaNO 3
13-94
2 .12
13
77
2
.10
J 3-32
2 .04
12
57
1.92
NaN0 2
14-34
2.18
J 3
.82
2
.11
13.06
1.98
II
5 2
i-75
iNa 2 S0 4
13 -19
2 -OO
12
35
I
.s?
10.85
1.6 3
8
30
1.27
SOLUBILITY OF PHENYL THIO UREA AT 25 IN AQUEOUS
SOLUTIONS OF.
Potassium Nitrate.
(Bogdan.)
Sodium Nitrate.
(Bogdan.)
Gms. Mols.
KN0 3 per
Gms. per
1000 Gms. H2O.
Gms. Mols.
NaN0 3 per
Gms. per
looo Gms. H2O.
1000 Gms.
HzO.
KNO 3 .
CS(NH 2 )
.NHCeHs.
1000 Gms.
H 2 0.
NaNOa.
CS(NH 2 )
.NHQjHs.
1.045
105-7
2-38
I .024
87.14
2.26
o-5 I2 3
5I-84
2.48
0.5065
43-10
2. 4 6
O.2O26
20.50
2-54
0.2031
17.28
2 5 1
o . 1007
10.19
2-56
0.0986
8-39
2-53
0-0503
5-09
2-55
0-0540
4-59
2.54
0-0333
3-36
2-55
0-0335
2.84
2 54
Phenyl Thio UREA
346
SOLUBILITY OF PHENYL THIO UREA IN MIXTURES OF ETHYL
ALCOHOL AND WATER AT 25.
(Holleman and Antusch Rec. trav. chim. 13, 290, '94.)
Vol.
Gms.
CS(NH 2 )
Sp. Gr.
per cent
NHQjHs
of
Alcohol.
per 100 Gms.
Solutions.
Solvent.
roo
3-59
95
4-44
O.82OO
90
4.69
0.8389
85
4.99
0.8544
80
4-70
0.8679
75
4-45
0.8810
70
3-92
0.8915
Vol.
Cms.
CS(NH 2 )
Sp.Gr.
per cent
Alcohol.
NHCH 5
per zoo Gms.
of
Solutions.
Solvent.
65
3-40
O.QOlS
60
2.80
0.9128
50
1.8 7
0.9317
40
I-I3
o . 9486
25
0.56
0.9679
IS
0.38
0.9788
O
0.24
0.9979
SOLUBILITY OF PHENYL THIO UREA IN AQUEOUS SOLUTIONS OF
PROPYL AND OF ETHYL ALCOHOL AT 25.
(Bagdan.)
In Propyl Alcohol.
In Ethyl Alcohol.
G. Mols.
Gms. per 1000 Gms. H 2 O
G. Mols.
Gms. per 1000 Gms.H 2 O
CaHyOH per
looo Gms.
C 3 H 7 OH.
CS(NH 2 )
NHPcHe
C 2 HsOH per
1000 Gms.
CzHsOH.
CS(NH 2 )
H 2 0.
11 v^6 1-5
H 2 O.
UfttlS-
I-03S
62 .IO
3.587
I .1010
49.60
3.193
0.5448
32.688
3.124
0-5355
24.12
2.931
o 1059
6-354
2.643
o . 1094
4-932
2.629
0-05526
3-3 J 6
2-599
0.05018
2.26
2.589
0-04854
2 .912
2.586
0.03271
1-473
2-577
In Propyl Alcohol at o.
i. ooo 60.06 i. 21
o.ioo 6.01 1-047
SOLUBILITY OF PHENYL THIO UREA IN AQUEOUS
ACETONE, MANNITE, CANE SUGAR, DEXTROSE,
(Bagdan.)
Aqueous
Non Electro-
lyte.
(CR,) 2 CO
C 6 H 8 (OH),
SOLUTIONS OF
AND UREA.
;
Gms
. per 1000 Gms.
H ?
Aqueous
Non Electro-
to
Gms. per 1000 Gms.
H 2 0.
*
Non
Elec-
CS(
NH 2 )
lyte.
Non
Elec-
CS(NH 2 )
trolyte.
NH
-CeHs.
trolyte. NHCeHg.
25
7
-478
2
.667
C.H, 2 0,
25
180-40
3
.042
2
.513
2
579
ft
tt
90
. 4 6
2
83
tt
I
.908
2
573
tl
it
29
.29
2
.69
it
182
II
3
.04
tt
(i
18
OI
2
654
it
9 1
05
2
.78
It
"
9
554
2
.603
25
338
.6
3
457
CO(NH 2 ) 2
it
63
.08
3
.306
tt
170
4
3
015
It
tt
29
93
2
.892
"
34
36
2
634
It
it
6.132
2
.618
ft
18
.28
2
596
tt
it
4
942
L a
605
11
10
.09
2
572
tl
ti
2
.009
2
572
O
342
.18
j
420
tl
O
60
.11
t
.310
tt
34
.22
I
044
11
n
6
.01
i
.048
347
URETHANE
URETHANE CO(NH 2 )OC 2 H 5 . SOLUBILITY IN SEVERAL SOLVENTS.
(Speyers Am. J. Sci. [4] 14, 294, '02.) See also Ethyl Carbamate, p. 138.
Interpolated and calculated from the original results which are
given in terms of molecules Urethane per 100 Mols. solvent.
Solubility in Water.
Solubility in Methyl Alcohol.
f.
Wt r M IS -
i cc? CO(NH 2 )
Cr,!,," OC 2 Hg per
100 Mols.
Gms
CO(NH 2 )
OC 2 H 8 per
100 Gms.
/
Wt. of
I CC.
Solu-
Mols.
CO(NH 2 )
OC 2 H 6 per
100 Mols.
Gms.
CO(NH 2 )
100 Gms
tlon> H 2 0.
H 2 O.
tion.
CH 3 OH.
CH 3 OH.
1.023 3.61
I 7 .8
0.956
3I.I8
86.76
10
1.033 6-0
29.7
0.977
41.0
II4.I
15
1.042 15.0
74-2
0.989
47-5
132 .1
20
1. 060 3I-O
153-3
i .000
54-5
IS 1 -?
25
1.073 5-
247-3
1.013
62.5
J 73-9
30
1.078 65.0
321.4
1.024
72.0
200.3
40
1.065 77.0
380.7
1.045
89.0
247.7
Solubility in Ethyl
Alcohol.
Solubility
in Propyl Alcohol.
to.
Wt nf Mols.
, ' CO(NH 2 )
Solu OC 2 H 5 per
zoo Mols.
Gms.
CO(NH 2 )
OC 2 H 5 per
100 Gms,
Wt. of
I CC.
Solu-
Mols.
CO(NH 2 )
OC 2 H S per
100 Mols.
Gms.
CO(NH 2 )
OC 2 H 6 per
100 Gms.
C 2 H 6 OH.
C 2 H 5 OH.
tion.
C 3 H 7 OH=
O
0.8914 23.91
46.26
0.880
19.48
28.9
IO
0-930 36.0
69.6
0.906
31.0
46.0
15
0.950 43.0
89.2
0.923
40.O
59-3
20
0.968 5O.O
96.7
0.942
51.0
75-7
25
0.985 59.0
II4.I
0.963
6o-0
89.0
30
i .001 70.0
135-4
0.983
68.0
100.9
40
1.035 88 -o
170.2
1.025
85.0
126.1
Solubility in Chloroform.
Solubility in Toluene.
t
Wt. of C 0(NH 2 )
Gms.
CO(NH 2 )
OC 2 H 5 per
Wt. of
I CC.
O_l,,
Mols.
CO(NH 2 )
OC 2 H 6 per
Gms.
CO(NH 2 )
OCsH per
S .? lu ~ xoo 2 Mols.
100 Gms.
oOlU-
100 Mols.
100 Gms.
tion. CHC1 3 .
CHC1 3 .
tion.
C6H 6 CH 3 .
o
1.404 27.56
20. 6
0.887
1.77
I.7I
10
1.340 41
30.6
0.874
4.84
15
"I.3IO 46
34-4
0-875
IO-O
9.68
20
1.280 53
39-6
0-883
16.0
I5. 4 8
25
1.240 60
44.8
0.902
25.0
24.18
30
1.203 6 7
50.0
0.927
44-o
42.58
40
1.125 80
59-7
o-995
85.0
82.24
URIC
ACID C 6 H 4 N 4 8 .
SOLUBILITY IN WATER.
(Blarez and Deniges Compt. rend. 104, 1847, '87; at 15 Magnier
483, '75-)
Bull. Soc.
chim. [2] 23,
Gms. C 5 H 4 N 4 3 .
Gms.
CsHiNtOi
Gms. C 6 H 4 N 4 O
t .
per too Gms.
t. per
TOO Gms.
t.
per 100 Gms.
H 2 0.
H 2 0.
H 2 0.
O
O.OO2
30 o
.0088
70
0-0305
IO
0.0037
40 o
.OI22
80
0.0390
15
0.0053
50 o
.0170
00
o . 0498
20
0.006
60 o
.0230
100
0-0625
VALERIANIO AGID 348
VALERIANIC ACID n CH 3 (CH 2 ) 3 COOH (n Propyl acetic acid
Pentane acid) when shaken with water at 16 two layers are formed.
100 gms. of the aqueous layer contains 3.4 gms. CH 3 (CH 2 ) 3 COOH.
100 gms. of the acid layer contains 90.4 gms. CH 3 (CH 2 ) 3 COOH.
(Lieben and Rossi Liebig's Ann. 159, 60, '71.)
YTTRIUM IODATE Y(IO 3 ) 3 . 3 H 2 O.
100 gms. H 2 O dissolve 0.53 gm. yttrium iodate.
(Berlin.)
YTTRIUM SULPHATE Y 2 (SO 4 ) 3 .
100 gms. H 2 O dissolve 15.2 gms. Y 2 (SO 4 ) 3 at ord. temperature,
9.3 gms. Y 2 (SO 4 ) 3 .8H 2 O at ord. temp, and 4.8 gms. Y 2 (SO 4 ) 3 .8HO 2
at IOO . (Cleve Bull. soc. chim. [2] 21, 344, '74.)
YTTERBIUM SULPHATE Yb 2 (SO 4 ) 3 .8H 2 O.
SOLUBILITY IN WATER.
(Cleve Z. anorg. Chem. 32, 143, '02.)
Gms. Yb 2 (SO 4 )a
Gms. Yb 2 (SO 4 ) 3
Gms. Yb 2 (S0 4 ) 3
per TOO gms.
t .
per loo Gms.
t.
per loo Gms.
H 2 0.
H 2 0.
H 2 0.
44-2
55
"-S
80
6.92
34-6
60
10.4
90
5-83
19.1
70
7.22
IOO
4.67
35
ZINC ACETATE Zn(CH 3 COO) 2 . 2 H 2 O.
loo gms. H 2 O dissolve 40 gms. at 25 and 66.6 gms. at b. pt.
loo gms. alcohol dissolve 2.8 gms. at 25 and 166.0 gms. at b.pt.
(U. S. P.)
ZINC BENZOATE Zn(C 7 H 6 O 2 ) 2 .
SOLUBILITY IN WATER.
(Paietta Gazz. chim. ital. 36, II, 67, '06.)
t. 15-9 17 27.8 31.3 37.5 49.8 59
Gms. Zn(C 7 H 5 O 2 ) 2 per
ico gms. aq. solution 2.55 2.49 2.41 2.05 1.87 1.62 1.45
ZINC BROMIDE ZnBr 2 .
SOLUBILITY IN WATER.
(Dietz Wiss. Abh. p. t. Reizhanstalt 3, 431, 'oo; see also Etard Ann. chim. phys. [7] 2, 536, '94.)
t e .
Gms. ZnBr 2
per loo Gms.
Solution.
Mols. ZnBr 2
per loo
Mols.H 2 O.
Solid
Phase.
to.
Gms. ZnBr 2
per 100 Gms.
Solution.
Mols. ZnBr 2
per loo
Mols.H 2 0.
Solid
Phase.
15
77-13
27.0
ZnBr 2 . 3 H 2 O
25
82.46
37-6
ZnBr 2 .2H 2 O
10
78.45
29.1
"
30
84.08
42-3
"
- 5
80.64
33-3
"
37
86.20
50.0
"
8
79.06
30-2
ZnBr 2 .aH 2 O
35
85 -45
46.9
ZnBr 2
79-55
31 .1
11
40
85-53
47-4
"
+ 13
80.76
33-5
"
60
86.08
49-5
"
18
81.46
"
80
86.57
"
IOO
87-05
53-8
*
349
ZING CARBONATE
ZINC CARBONATE ZnCO,.
One liter H 2 O dissolves o.oi gm. at 15.
One liter aq. 5.85 per cent NaCl solution dissolves 0.0586 gm.
at 14.
One liter aq. 7.45 per cent NaCl solutions dissolves 0.0477 g 111 -
^k J 4 (Cantoni and Passamanik Ann. chim. anal. appl. 10, 258, '05.)
ZINC CHLORATE ZnClO 3 .
SOLUBILITY IN WATER.
(Meusser Ber. 35, 1417, '02; at 18; Mylius and Funk Ber. 30, 1718, '97.)
-18
o
8
15
18
Cms.
Zn(C10 3 ) 2
per loogms.
Solution.
55- 62
59-19
6O.2O
67.32
66.52
Mols.
Zn(C10 3 ) 2
per 100
Mols.H 2 0.
9.70
II.OS
II-72
15.96
15-39
Solid
Phase.
Zn(C10 3 ) 2 .6H 2
Zn(C10 3 ) 2 . 4 H 2
Cms.
t o. Zn(C10 3 ) 2
per jooGms.
Solution.
Mols.
Zn(C10 3 ) 2 Solid
per 100 Phase.
Mols. H 2 0.
3O 76.66
4O 69.06
1 6. 20 Zn(C10 8 ) 2 4H 2 O
17.29
55 75-44
Ice curve
24.00
-13 30.27
- 9 26.54
3.36 Ice
2.8o
Sp. Gr. of solution saturated at 18 = 1.916.
ZINC CHLORIDE ZnCl 2 .
SOLUBILITY IN WATER.
(Mylius and Dietz Z. anorg. Chem. 44, 217, '05; see also Dietz Wiss. Abh. p. t. Reichanstalt 3, 429,
'oo; Etard Ann. chim. phys. [7] 2, 536, *94-)
AO Gms.ZnCbper looGms. Solid
A0 Gms.ZnCl 2 per looGms. Solid
Water.
Solution.
Phase.
" Water.
Solution.
Phase.
5
14
12
3
Ice
9
360
78.3
.2*H 2 + .H 2 O
10
25
2O
.0
"
6
385
79-4
ZnCl 2 .2iH 2
40
83
45-3
6
298
74-9
ZnCla.iiHjjO
-62
IO4
51
.0
I C e + ZnCl 24 H 2
10
330
76.8
"
50
113
53
.0
ZnCl 2 . 4 H 2 O
20
368
78.6
"
40
127
55
9
"
26
423
80.9
i*H 2 0+ZnC! 2 .H 2 O
30
160
61
5
. 4 H 2 + . 3 H 2
26.3
433
81.2
.1 *H 2 -f- ZnCl 2
-10
189
65
4
ZnCl 2 . 3 H 2 O
o
342
77-4
ZnCl 2 .H 2 O
o
208
67
5
"
IO
3 6 4
78.4
"
5
230
69
7
"
20
39 6
79.8
"
6-5
252
4 7 1
.6
28
436
81.3
ZnCl 2 .H 2 + ZnClj
5
282
73
.8
3 1
477
82.7
ZnCI a .H 2
309
75
5
. 3 H 2 + .i*H 2
25
432
81.2
ZnCl a
o
235
70
.1
ZnCb.2iH.jO
40
452
81.9
"
6.5
252
7 1
.6
.2iH 2 O + . 3 H 2 O
60
488
83.0
"
10
272
73
.1
ZnCl 2 .2*H 2
80
543
84-4
ii
12.5
303
75
.2
'<
IOO
615
86.0
"
"5
335
77
O
.2*H 2 + .i*H 2
262
00
100-0
"
ZINC CYANIDE Zn(CN) 2 .
loo cc. concentrated Zn(C 2 H 3 O 2 ) 2 + Aq. dissolve 0.4 gm. Zn(CN),.
loo cc. concentrated ZnSO 4 + Aq. dissolves 0.2 gm. (joannis.)
ZINC CHLORIDE
350
SOLUBILITY OF ZINC CHLORIDE, AMMONIUM CHLORIDE MIXTURES
Isotherm for o.
IN WATER.
(Meerburg Z. anorg. Chem. 37, 212,
Isotherm for 20.
Isotherm for 30.
Gms. per ioo Gms.
Solution. jSplid
Gms. per ioo Gms.
Solution. Solid
T>U
Gms. per ioo
Solution.
Gm<
Solid
-, Phase.
ZnCl 2 .
NH 4 Ci:
' ZnCl 2 .
NH 4 C1.
ZnCl 2 .
NH.C1.
O
22
. 8 NH 4 C1
O
.0
26
. 9 NHiCl
O
.0
29
5
NH4C1
3-5
23
O
5
.1
27
.1 "
9
.2
2 9
4
"
23
5
9
5
27
4
16
O
29.7
IO.2
23
9
12
7
27
5
20
.2
30
.1
"
15 .1
24
7
15
7
27
7
24
7
30
4
18.0
25
3
18
.0
27
9
26
3
30
.8
NH4C1 + a
22 .4
26
.0
23
5
29
.0
27
.2
30
.2
a
24.2
26
. i
26
.0
29
5 NH 4 Cl + a
30
.1
29
.6
"
25-7
26
3 NH 4 Cl+a
29
5
28
.1 a
36
.8
28
.2
"
27-5
26
4 o
32
3
27
7
42
4
27
3
"
30-7
25
7
35
.8
27
.0
43
.8
27
3
a + b
33-9
2 5
3
38
7
26
9
45
o
24
4
b
38.8
24
4
40
.2
26
.6
5 1
.2
17
.6
42 .6
24
6 a + b
41
9
26
3
61
9
10
4
"
44-3
21
3 b
43
.2
26
O a + fr
66
9
9
.2
ZnCl 2 + 6
49-2
15
46
9
21
.0 b
75
.6
6
.1
ZnCl 2
52.6
II
9
53
.2
14
5
70
3
7
.6
55-4
10
.0
58
4
II
.1
78-5
3
.2
59-3
7
5
62
7
8. 7
76
9
3
5
it
62.1
6
.8
66
.6
7
.9
79
.8
i
.6
14
81
.6
.0
M
a = ZnCl 2 .3NHCl 3 ,. b = ZnCl 2 .2NH 4 Cl.
ioo gms. abs. acetone dissolve 43.5 gms. ZnCl 2 at 18.
(Naumann Ber. 37, 4332, '04.)
ioo gms. glycerine dissolve 50 gms. ZnCl 2 at 15.5.
ZINC FLUORIDE ZnF 2 . 4 H 2 O.
One liter of water dissolves 16 gms. at 18.
(Dietz.)
ZINC HYDROXIDE Zn(OH) 2 .
One liter of water dissolves 0.0042 gm. ZnO at 18, conductivity
method. (Dupre and Bratas Z. angew. Chem, 16, 55, '03.)
SOLUBILITY OF ZINC HYDROXIDE IN ONE PER CENT AQUEOUS
SALT SOLUTIONS AT i6-2o.
(Snyder Ber. n, 936, '78.)
^ The CO 2 free Zn(OH) 2 dissolved is calculated as milligrams Zn per
liter of the given salt solution. Additional determinations are also
given.
Aq. Salt Mgs. Zn per
Solution. Liter Solution.
Aq. Salt Mgs. Zn per
Solution. Liter Solution.
Aq. Salt Mgs. Zn per
Solution. Liter Solution.
NaCl
5 1
K 2 S0 4
37-5
K 2 C0 3
KC1
43
MgS0 4
27
NH 4 C1
95
CaCl 2
57-5
KNO 3
J 7-5
NH 4 N0 3
77
MgCl 2
65
Ba(N0 3 ) 2
25
(NH 4 ) 2 S0 4
88
BaCl 2
38
ZINC HYDROXIDE
SOLUBILITY OF ZINC HYDROXIDE IN AQUEOUS SOLUTIONS OF:
Ammonia and Ammonia Bases
at i7-i9.
(Herz Z. anorg. Chem. 30, 281, '02.)
Sodium Hydroxide at
Ord. Temp.
(Rubenbauer Ibid. 30, 333, '02.)
Normality
of
Normality
of Dis-
Gms. ZnO
per 20 cc
Gms. per 20 cc. Solution
Mol.
Dilution of
the Base.
solved Zn.
Solution.
Na.
Zn.
the NaOH.
>NH
3
.0011
.00185
o
.1012
0.0040
4-50
236
O
OIIO
O
.0180
O
,1978
0.0150
2-33
O
707
ti
o
059
o
.0958
o
.4278
0.0442
1. 06
,0944NH 2 CH 3
.0005
O
.0008
.6670
0.1771
0.70
.472
.0081
.0132
0.9660
0.9630
0.48
o
944
u
o
03
o
.0484
I
495 1
0.2481
0.31
o
.068
NH 2 C 2 H 5
o
.0003
o
.0005
2
.9901
0.3700
0.16
o
5 1
.0045
o
.0074
Moist Zn
(OH) , used. So-
.68
.0098
.0161
lutions
shaken 5
hours.
ZINC IODATE Zn(IOs),.
100 gms. H 2 O dissolve 0.87 gm. Zn(IO 3 ) 2 cold and 1.31 gms. hot.
(Rammelsberg Pogg. Ann, 43, 665, '38.)
ZINC IODIDE ZnI 2 .
SOLUBILITY IN WATER.
(Dietz Wiss. Abh. p. t. Reichanstalt 3, 432, 'oo; see also Etard Ann. chim. phys. [7] 2, 526, '94.)
Gms. ZnI 2 Mols. ZnI 2
per 100 Gms. per 100 Mols. Solid Phase.
Gms. ZnI 2 Mols. ZnI 2
per 100 Gms. per 100 Solid Phase.
Mols. H 2 0.
ZnI 2 .2H 2
Solution.
Mols. H 2
10
80.50
23-3
- 5
80-77
23-7
81.16
24-3
+ 10
82.06
25.8
22
83.12
2 7 .8
27
89.52
50-3
Solution.
H 2 0.
O
8i.ii
24.2
18
81.20
24.4
40
81.66
25-1
60
82-37
26.4
80
83-05
27-5
100
83.62
28.7
ZnI 3
Sp. Gr. of sat. solution of the anhydrous salt at 18 = 2.725.
ioo gms. glycerine dissolve 40 gms. ZnI 2 at 15.5.
ZINC NITRATE Zn(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt, 3, 438, 'oo.)
Gms. Mols.
Zn(N0 3 ) 2 per ZnNO 3 per Solid
* ioo Gms. ioo Phase.
Solution. Mols. H 2 O.
6.36 Zn(NO 3 ) 2 . 9 H 2 1 8
-25
40.12
0-30
-22-5
40.75
6-54
20
42-03
6.89
-18
43-59
7-34
-18
44-63
7-67
-15
45.26
7.86
13
45 -5 1
7-94
12
45-75
8.01
O
48.66
9.01
H-12-s
52-0
10.3
Gms.
Mols.
t.
Zn(N0 3 ) 2 per
ioo Gms.
Zn(N0 3 ) 2
IOO
per Solid
Phase.
Solution.
Mols. H 2 0.
18
53-50
IO-9
Zn(NO 3 ) a .6H20
25
55-90
12.0
"
36
4 63.63
I6. 7
"
36
64.63
17.4
"
5 65.83
18.3
"
37
66.38
18.8
Zn(NOa) 3 .3H,0
40
67.42
19.7
"
41
68.21
20.4
"
43
69.26
21.4
"
45
5 77-77
33-3
M
ZING OXALATE 352
ZINC OXALATE ZnC 2 O 4 .2H 2 O.
One liter of water dissolve 0.083 M - equiv. = 0.0064 gm. ZnC 2 O 4
at 1 8.
(Kohlrausch Z. physik. Chem. 50, 356, '04- '05.)
ZINC SULPHATE ZnSO 4 .
SOLUBILITY IN WATER.
(Cohen Z. physik. Chem. 34, 189, 'oo; at 50; Callender and Barnes Proc. Roy. Soc. 62, 149, '97;
Etard Ann. chim. phys. [7] 2, 536, '94; Poggiale Ibid. [3] 8, 467, '43; Mulder.)
1
t .
Gms. ZnSO 4> per 100 Gms. Solid *
Gms. ZnSO 4 per 100
Gms. Solid
Solution.
Water.
Phase.
Solution.
Water.
Phase.
- 5
28
.21
39-30
ZnSO 4 .7H 2 O 25
38
94
63
74
ZnS0 4 .6H 2 O
O.I
29
54
41
93
39
41
.22
70
.06
.6H 2 + .
7H 2
9.1
32
.01
47
.09
50
43
45
7 6
.8 4
ZnS0 4 .6H 2 O
15
33
.81
50
.88
70
47
5
88
7
.6H 2 +
.H 2
25
36
.67
57
.90
80
46
4
86
.6
ZnSCvHzO
35
39
.98
66
.61
90
45
5
83
7
"
39
41
.21
7
05
IOO
44
7
80
.8
"
- 5
32
OO
47
.08
ZnS0 4 .6H 2 120
41
7
71
5
01
33-09
49
.48
I4O
38
.0
61
3
"
160
33-o
49
3
"
zoo gms. abs. methyl alcohol dissolve 0.65 gm. ZnSO 4 at 18, 5.90
gms. ZnSO 4 .7H 2 O at 18.
100 gms. 50 per cent methyl alcohol dissolve 15.7 gms. ZnSO.7H 2 O
at 1 8.
(de Bruyn Z. physik. Chem. 10, 783, '92.)
SOLUBILITY OF ZINC SULPHATE IN AQUEOUS ETHYL ALCOHOL.
(Schiff Liebig's Ann. 118, 365, '61.)
Concentration of Alcohol 10 per cent 20 per cent 40 per cent
Gms. ZnSO 4 .7H 2 O per 100
Gms. Solution 51.1 39 -o 3-45
100 gms. glycerine dissolve 35 gms. zinc sulphate at 15.5.
353
ZINO SULPHAT5
SOLUBILITY OF ZINC SULPHATE SODIUM SULPHATE MIXTURES
IN WATER.
(Koppel Gumpery Z. physik. Chem. 52, 409, '05.)
to
Gms. per ioo
Gms. Solution.
Gms. per ioo
Gms. H 2 O.
Mols. per ioo
Mols. H 2 0. Solid
.
ZnSO 4 .
Na 2 SO 4 .
ZnSO 4
Na 2 S0 4 .
ZnSO 4 .
Na 2 S0 4 :
O
27.19
5-33
40.30
7.90
4-50
1. 01
ZnSO^HzO +
5
6.27
42.28
9-52
4.71
1. 2 1 ) Na 2 S0 4 .ioH 2
25
I7-58
15-63
26.32
23.40
2.94
2.96 ZnNa 2 (S0 4 ) 24 H 2
30
17.66
15-58
26.47
23-44
2-95
2-97
35
J 7-59
15-70
26.36
2 3 -5 2
2.94
2.98
40
17-75
15-72
26.68
23 .63
2.98
2.99
10
29.16
7.16
45-79
ii .24
5-"
1.42 '
15
30.70
6.40
48.81
10.17
5-45
1.29
20
32-5 1
5-36
52-34
8.62
5-84
1.09
ZnNa 2 (SO 4 ) 2 4 H 2 O
25
34.36
4.41
56-15
7.22
6.27
0.91
-fZnSO/.yHzO
30
36.28
3.80
60.55
6-34
6.76
0.81
35
38.18
3-30
65-25
5-64
7.28
0.71 ,
38
38-83
2 .90
66.64
4.98
7-44
0-63 ,
ZnNa 2 (SO 4 ) 2 4 HzO
40
38.26
2.78
64.89
4.71
7.24
0.60
+ZnSO 4 .6H 2 O
10
27.91
7.92
43-50
12.34
4-85
I -5 6 5
15
24.28
10.90
36.92
16.71
4.12
2 . 12
20
19.14
14-58
28.77
21.95
3.21
2-79
ZnNa 2 (S0 4 ) 2 ^H 2
+Na 2 SO 4 .ioH 2 O
25
13 .31
19.94
19.93
29.87
2 .22
3 -785
30
6.96
27-75
10.67
42.51
I .19
5-39 .
35
5-6i
30.03
8.72
46.61
0.971
5.91 ) ZnNa 2 (S0 4 ) 2 . 4 H 2
40
5-96
28.65
9.16
43-83
I .02
5-555 1 +Na2S *
ZINC SULPHITE ZnSO 3 .2H 2 O.
100 gms. H 2 O dissolve 0.16 gm. ZnSO 4 .2H 2 O.
(Houston and Trichborne Brit. Med. Jour. 1063, '90.
ZINC TARTRATE C 4 H 4 O 6 .Zn. 2 H 2 O.
SOLUBILITY IN WATER.
(Cantoni and Zachoder Bull. Soc. chim. [3] 33, 751, '05.)
Gms.
t. CJt.06.Zn.2H2O
per 100 cc. Solution.
15 0.019
2O O-022
25 0.036
30 0.041
35 0.055
Gms.
t. C 4 H 4 O b .Zn. 2 H 2
per 100 cc. Solution.
40 o 060
45 0.073
5O 0-087
55 0.116
60 o . 104
Gms.
t. C 4 H 4 6 .Zn.2H 2 O
per 100 cc. Solution.
65 o . ioo
70 0.088
75 0.078
80 0.050
85 0.041
ZINC VALERATE (C 4 H 9 COO) 2 Zn. 2 H 2 O.
ioo gms. H 2 O dissolve 2 gms. (C 4 H 9 COO) 2 .Zn.2H 2 O at 25.
ioo gms. alcohol dissolve 2.8 gms. at 25.
(U. S. P.)
ADDENDUM
The distribution results shown in the following table were obtained
by agitating together equal volumes of olive oil and aqueous solutions
of the several narcotics, and determining the dissolved substance
present in the aqueous layer before and after the agitation. The sum
of the amount of substance in the oil and aqueous layers, as shown
in the table, is the amount originally in 100 cc. of each aqueous solu-
tion used.
The work was done for the purpose of testing the Overton-Meyer
Theory of Narcosis, that the anesthetic action of certain groups of
narcotics is proportional to their distribution between water and the
fatty material occurring in the nervous system, and olive oil was
selected as the solvent best fulfilling the analytical requirements
and at the same time offering a fair resemblance to the fatty substance
of the nervous system. The results are believed to be of interest
both as solubility studies and on account of their connection with
the Theory of Narcosis.
The author is indebted to Dr. Reid Hunt of the Hygienic Laboratory
for calling his attention to the papers containing the distribution
results here tabulated.
354
355
DISTRIBUTION OF SEVERAL SUBSTANCES BETWEEN WATER AND
OLIVE OIL.
(At ord. temp., Baum Archiv. exp. Pathol- u. Pharmakol, 42, 130, 'go; at 3, 30 and 36; Meyer
Ibid. 46, 344, '01; at 15, Harrass Archh . internal . Pharmacodynamie et Therapie, n, 458, '03.)
Name of Substance.
Formula .
Gms. Substance per
t o 100 CC.
C(f.)
Water
Olive Oil
C(w.)
layer (w.).
layer (f.).
Sulfonal
(CH 3 ) 2 C(S0 2 .C 2 H 6 ) 2
ord.
0.0700
0.0686
o-979
Trional
(CH 3 )(C 2 H 5 )C(S0 2 .C 2 H 6 ) 2
it
o . 0404
o. 1646
4.074
Tetronal
(C 2 H 6 ) 2 C(SO 2 .C2H 5 ) 2
it
0.0462
o. 1446
3.756
Di methyl sulphon
di methyl methane
(CH 3 ) 2 C(S0 2 .CH 3 ) 2
tt
0.6072
0.0622
o. 103
Di ethyl sulphon me-
thane
CH 2 .(S0 2 .C 2 H 6 ) 2
"
0.610
0.092
o. 151
Ethyl urethane
NH 2 .C0 2 .C 2 H 5
tt
4-52
0.6l5
0.136
Methyl urethane
NH 2 .C0 2 .CH 3
"
7-5
0.275
0.037
Tertiary butyl alcohol
(CH 3 ) 2 C(OH)CH 3
it
8.744
J -539
o. 176
Amylene hydrate
(CH 3 ) 2 C(OH)CH 2 .CH 3 .
11
6.605
6.605
I. 000
Mono acetin
CaH 6 (OH) 2 .(OC 2 H 3 0)
ti
4.28
0.254
0.059
"
"
3
2-349
o. 229
0.099
n
"
36
2.417
0.161
0.066
Di acetin
CaH 5 (OH)(OC 2 H 3 0) 2
ord.
3-
-7
o. 234
Tri acetin
C3H 5 (OC 2 H 3 0) 3
2.72
0.80
0.205
Bromal hydrate
CBr 3 CH(OH) 2
9.81
6.52
0.665
Butyl chloral hydrate
C3H 4 C1 3 .CH(OH) 2
2.04
3-24
1.589
Chloral hydrate
CCl3CH(OH) 2
16.31
3.10
o. 190
. "
11
4.12
0.91
0.22
"
'
3
i-34
0.08
0-053
n
"
30
I-I5
0.27
0.237
Salicylamide
OH.C6H 4 .CH 2 NH 2
3
0.056
o. 126
2.25
"
"
36
0.075
0.107
1.40
Benzamide
C 7 H 6 ONH 2
3
1.062
o. 706
0.66
"
"
36
1.235
0.533
0-43
Ethyl alcohol
C 2 H 5 OH
3
2.69
0.09 )
0.026
3
3-90
0.07 <)
"
"
3
2.64
o. 14 t
f /
o. 047
3
3.82
o. 16 S
Acetone
(CH 3 ) 2 CO
3
3-07
-5i
"
3
4.14
0.52 >
0.146
"
3
3-92
0.61 )
"
3
2-73
0-73)
"
3
3.86
0.81 >
0-235
3
0.87)
Valeryl di ethyl amide
CH3(CH 2 ) 3 CON(C3H6)2
15
0.231
1-339
5-797
Valeryl di methyl amide CHa(CH2)3CON(CH a )2 1 5
0.911
0-379
0.416
Valeryl ethyl amide
CH 3 (CH2)3CONH(C2Ha)
15
1.029
0.261
0.254
Valer amide
CHa(CH2)aCONH2
15
0.769
o. 241
0-313
Lactic acid di ethyl
amide
CH 3 .CHOH.CON(C 2 H 6 )2
15
1.256
0.194
0.154
Sodium salicylate
QH4.0H.COONa
15
1.444
o. 156
0.108
INDEX
Acenaphthene, i.
Acetamide, i.
Acetanilide, i.
Acetic acid, 2-4.
in aq. benzene, 55.
Acetnaphthalide, 6.
Acetone, 6-7, 355.
in aq. benzene, 55.
in aq. ethyl acetate, 136.
in aq. potassium chlorate, 241.
in aq. potassium chloride, 247.
in aq. potassium nitrate, 258.
in aq. sugar, 326.
Acetphenetidine, 8.
Acet-toluide, 8.
Acetyl acetone, 9.
Acetylene, 8.
Aconitine, 9.
Adipic acid, 9.
Air, 10.
Alanine, 10.
Aldehyde, n.
propionic, 267.
Alcohols, ii, 355.
Alcohol in aq. benzene, 55.
in aq. ether, 135.
in aq. ethyl acetate, 136.
in aq. ethyl butyrate, 136.
in aq. ethyl propionate, 136.
in aq. ethyl valerate, 137.
in aq. methyl butyrate, 204.
in aq. propyl acetate, 267
in aq. potassium carbonate, 239,
in aq. potassium chlorate, 241.
in aq. potassium nitrate, 258.
in aq. sodium carbonate, 297.
in aq. sodium nitrate, 308-9.
in aq. sodium sulphate, 314.
in aq. sugar, 325.
Allyl isosulphocyanic ester, 205.
Aluminum chloride, 12.
rubidium alum, 271.
sulphate, 12.
sulphate + Lithium sulphate, 176.
tellurium alum, 332.
Alums, ammonium, potassium, etc.,
I 3-
caesium, 80.
chromium, 116.
iron ammonium, 33.
rubidium, 271.
tellurium, 332.
Amalgam, 278.
Amido benzoic acids, 60.
benzo sulphonic acids, 60.
Amido brom benzo sulphonic acid, 57,
nitro benzoic acids, 60.
propionic acid, 10.
phenols, 60.
Amines, methyl, etc., 15-17.
Ammonia, 17-19.
lithium sulphate, water, 176.
Ammonium acid formate, 26.
acid oxalate, 30.
alum, 13.
arsenate, 20.
benzoate, 20.
bicarbonate, 21-22.
bicarbonate -f NaHCO a , 298.
bichromate, 25.
bromide, 20.
bromide + KBr, 235.
bromo platinate, 20.
cadmium bromide, 20, 71.
cadmium chloride, 73.
cadmium iodides, 77.
cadmium sulphate, 33.
carbonate, 21.
carbonate in acetone, 6.
cerium nitrate, 111-112.
cerium sulphate, 112.
chloride, 22-25.
chloride and CuCl 2 , 125-126.
chloride and KC1, 242.
chloride and NaCl, 299-300.
chloride and ZnCl 2 , 350.
chromates, 25.
chromium sulphate, 33.
cobalt chlorides, 120.
cobalt sulphate, 33.
copper sulphate, 33, 129, 262.
fluo boride, 26.
fluo silicate, 31.
formate, 26.
iodate, 26.
iodide, 26-28.
iridium sulphate, 34.
iron sulphate, 33.
lead cobalticyanide, 22.
magnesium nitrate, 30.
magnesium sulphate, 34.
manganese molybdate, 30.
manganese sulphate, 34.
nickel sulphate, 34, 129.
nitrate, 24, 28, 30.
oxalate, 30-31.
permanganate, 31.
persulphate, 35.
phosphite, 31.
platinic chloride, 232-233.
3.S7
INDEX
Ammonium salicylate, 31.
sodium sulphate, 34.
sodium sulphite, 35.
sulphate, 24, 31-33.
sulphate + K 2 SO 4 , 261.
sulphocyanide, 35.
tetra chromate, 25.
tri chromate, 25.
tri nitrate, 29.
uranyl carbonate, 22.
uranyl chlorides, 342.
uranyl nitrate, 343.
uranyl propionate, 343.
vanadium sulphate, 34.
zinc sulphate, 34, 129.
Amyl acetate, 35.
alcohol, ii.
butyrate, 35.
formate, 35.
malonic acid, 186.
propionate, 35.
Amylene hydrate, 355.
Anethol, 35.
in aq. acetone, 6.
Anilin, 36-38.
Anis acid, 38, 61.
Anthracene, 39.
Anthraquinone, 40.
Antimony potassium tartrate, 41.
tri chloride, 40-41.
tri iodide, 41.
Apo morphine hydrochloride, 205.
Argon, 41.
Arsenic iodide, 41. <
pentoxide, 41.
tri iodide, 42.
Asparagine, 42.
Astrakanite, 312.
Atropine, 42.
Aurous, auric, see Gold.
Azelaic acid, 43.
Azo phenetol, 43.
Barium acetate, 43.
acid oxalate, 52.
arsenate, 43.
bromate, 44.
bromide, 44.
butyrate, 44.
cadmium chloride, 74.
caproate, 45.
carbonate, 45.
chlorate, 45.
chloride, 24, 46-47.
chloride -f NaCl, 300.
chromate, 47.
citrate, 47.
cyanide, 48.
dibrom, etc., sulphonic acid, 57.
ferrocyanide, 48.
fluoride, 48.
formate, 48, 165.
hydroxide, 48.
iodate, 49.
Barium iodide, 49.
iodide + BaBr 2 , 44.
iodide + Hg(CN) 2 , 197,
iso caproate, 45.
iso succinate, 53.
malate, 49.
malonate, 49.
molybdate, 49.
nitrate, 24, 29, 5051.
nitrate + BaCl 2 , 46.
nitrate + KNO 3 , 254.
nitrite, 51.
oxalate, 51.
persulphate, 53.
potassium ferrocyanide, 48.
propionate, 52.
succinate, 53.
sulphate, 52-53.
tartrate, 53-54.
Benzamide, 54, 355.
Benzaldehyde, 54.
Benzene, 54-56.
Benzine, 58.
Benzoic acids, 58-62, 341.
Benzoic sulphinide, 62.
Benzophenone, 6, 63.
Benzo sulphonic acids, 57, 60.
Benzoyl phenyl hydrazine, 57.
Benzyl carbamide, 104.
Beryllium, see also Glucinium.
Beryllium hydroxide, 63.
salts, 140.
sulphate, 63.
Beta Naphthol, 208.
Borax, 293.
Boric acid, 65-67, 294.
Boron tri-fluoride, 67,
Bismuth, 64.
and Pt alloys, 232.
chloride, 64.
iodide, 64.
nitrate, 64.
oxide, 64.
Bromal hydrate, 355.
Brom benzene (di), 56.
benzoic acid, 60.
benzo sulphonic acid, 57.
cinnamic acid, 118.
phenols, 226.
Bromine, 67-69.
Brucine, 69.
Butane, 69.
Butyl acetate, 69.
alcohol, 12.
alcohol tertiary, 355.
chloral hydrate, 355.
formate, 69-70.
malonic acid, 186.
Butyric acid (iso), 70.
aldehyde, 69.
Cadmium ammonium bromide, 20, 71.
ammonium chloride, 73.
ammonium iodides, 77.
358
INDEX
Cadmium ammonium sulphate, 33.
barium chloride, 74.
bromide, 70-71.
caesium sulphate, 84.
chlorate, 72.
cyanide, 76.
fluoride, 77.
hydroxide, 77.
iodide, 77.
magnesium chloride, 74.
nitrate, 78.
oxalate, 78.
potassium bromide, 71.
potassium chloride, 76.
potassium iodide, 78.
potassium sulphate, 79.
rubidium bromide, 72.
rubidium chloride, 75.
rubidium sulphate, 274.
sodium bromide, 72.
sodium iodide, 78.
sodium sulphate, 80.
sulphate, 78-79.
Caesium alums, 15, 80.
cadmium sulphate, 84.
carbonate, 81.
chloraurate, Si.
chloride, 81.
chloride + FeCl 3 , 159.
chlor tellurate, 82.
chromium alum, 80.
cobalt sulphate, 84.
copper sulphate, 84.
fluoboride, 81.
gold chloride, 141.
iodate, 82.
iodide, 82.
indium alum, 80.
iron alum, 80.
iron sulphate, 84.
magnesium sulphate, 84.
manganese sulphate, 84.
mercuric bromide, 81.
nickel sulphate, 84.
nitrate, 82.
oxalate, 83.
permanganate, 83.
platinic chloride, 232.
selenate, 83.
sulphate, 83.
tellurium halides, 332.
thallium chloride, 82.
uranyl chloride, 342.
uranyl nitrate, 343.
vanadium alum, 80.
zinc sulphate, 84.
Caffeine, 84.
Calcium acetate, 84-85.
bicarbonate, 87-88.
bitartrate, 103.
bromide, 85.
bromide + Hg(CN) 2 , 197.
butyrate, 86.
Calcium caproate, 86.
caprylate, 86.
carbonate, 86.
chlorate, 88.
chloride, 88- -89.
chromate, 90.
citrate, 89.
di ethyl acetate, 85.
di propyl acetate, 85.
fluoride, 90.
formate, 90.
heptoate, 91.
hydroxide, 91.
hydroxide + CaSO 4 , 99.
iodate, 94.
iodide, 94.
iso butyrate, 86.
iso butyl acetate, 85.
iso succinate, 97.
iso valerate, 104.
malate, 94.
malonate, 94.
methyl ethyl acetate, 85.
methyl pentanate, 86.
methyl propyl acetate, 85.
nitrate, 95.
nonate, 96.
oenanthate, 91.
oxalate, 95.
oxide, 91.
pelargonate, 96.
phosphates, 95-96.
potassium ferrocyanide, 90.
potassium sulphate, 101.
propionate, 96.
selenate, 97.
silicate, 97.
succinate, 97.
sulphate, 97-102.
sulphide, 1 02.
sulphite, 103.
tartrate, 103.
tri methyl acetate, 85.
valerate, 104.
Camphoric acid, 104.
Cane sugar, 324-326.
Caoutchouc, 104.
Carbamides, 104.
Carbazole, 104.
Carbon bisulphide, no.
dioxide, 105-107.
monoxide, 107-110.
oxysulphide, 1 1 1 .
tetra chloride, 201.
Carvoxime, in.
Cerium acetate, in.
ammonium nitrate, iii-iia.
ammonium sulphate, 112.
butyrate, in.
formate, 1 11.
iso butyrate, in.
propionate, in.
sulphate, 112.
Chinin, 117.
350
INDEX
Chiriidin, 117.
Chlor acetic acid, 5.
Chloral hydrate, 113, 355.
hydrate butyl, 355.
Chlor benzene, 56.
benzoic acid, 60.
Chlorine, 113-114.
monoxide, 115.
tri oxide, 115.
Chloroform, 115.
Chlor phenols, 226.
Chromic acid, 25, 116, 304.
Chromium alums, 116.
ammonium sulphate, 33.
caesium alum, 80.
chloride, 116.
double salts, 116.
potassium cyanide, 250.
potassium molybdate, 116.
rubidium alum, 271.
sulphate, 116.
tellurium alum, 332.
tri oxide, 25, 116, 304.
Chrysarobin, 116.
Chrysen, 117.
Cinchona alkaloids, 117.
alkaloids salts, 117.
Cinnamic acid, 118.
Citric acid, 119.
Cobalt ammonium chlorides, 120.
ammonium sulphate, 33.
bromide, 119.
caesium sulphate, 84.
chlorate, 1.1.9.
chloride, 120-121.
double salts, 119.
Cobalticyanide of NH 3 + Pb, 22.
Cobalt iodate, 121.
iodide, 121.
lead cyanide, 165.
lead potassium cyanide, 165.
nitrate, 121-122."
potassium sulphate, 262.
rubidium nitrite, 122.
rubidium sulphate, 274.
sulphate, 122-123.
Cocaine, 123.
hydrochloride , 1 2 3 . .
Codeine, 123.
salts, 123.
Colchicine, 123.
Collidin, 124.
Copper and Pt alloys, 232.
acetate, 124.
ammonium chloride, 125-126.
ammonium sulphate, 33, 129.
bromide, 124.
caesium sulphate, 84.
chlorate, 124.
chloride, 124-128.
nitrate, 128.
potassium chloride, 127.
potassium sulphate, 131, 262.
Copper rubidium sulphate, 274.
sodium sulphate, 131.
sulphate, 32, 128-131.
sulphate + CuCl 2 , 126.
sulphate + MnSO 4 , 188.
sulphate + NiSO 4 , 211.
sulphide, 131.
tartrate, 132.
tellurium sulphate, 334.
Cream of tartar, 265-266.
Cresol, 131.
Cumidin (pseudo), 132.
Cuminic acid, 132.
Cuprous, cupric, see Copper.
Cyanogen, 132.
Dextrose in aq. acetone, 7.
Di acetin, 355.
Di brom benzene, 56.
Di chlor acetic acid, 6.
Didymium potassium sulphate, 133,
sulphate, 133.
Di ethyl amine, 16.
ethyl ketone, 137.
ethyl sulphone, 355.
Di methyl sulphone, 355.
Di nitro benzenes, 5657.
nitro phenols, 226.
Diphenyl, 227.
phenyl amine, 17.
Erbium sulphate, 133.
Erythrite, 133.
Ethane, 133.
Ether, 134-135- .
in anthraquinone, 40.
Ethyl acetate, 135-136.
alcohol, see Alcohol.
amines, 16.
ammonium bromide, 20.
ammonium chloride, 25.
ammonium iodide, 27,
bromide, 137.
butyrate, 136.
carbamate, 138.
Ethylene, 138.
chloride, 137.
cyanide, 323.
Ethyl formate, 136.
Ethylidine chloride, 137.
Ethyl iodide, 137.
iso valerate, 137.
ketone, 137.
malonic acid, 186.
methyl ketone, 204.
propionate, 136.
urethane, 355.
valerate, 137.
Fats, fatty acids, 138.
Ferrous, ferric, see Iron.
Ferri, ferrocyanide of potassium, 250.
Formaldehyde, n.
Fumaric acid, 139.
Furfurol, 139.
Gadolinium sulphate, 139.
360
INDEX
Galactose, 139.
Gallic acid, 139,
Germanium dioxide, 140.
potassium fluoride, 251.
sulphide, 140.
Glass, 140.
Glucinium, see also Beryllium.
Glucinium hydroxide, 63.
salts, 140.
sulphate, 63.
Glutaric acid, 140.
Glycolic acid, 140.
Gold, 140.
alkali chlorides, 140.
caesium chlorides, 81.
chloride, 141.
phosphorus tri chloride, 141.
Grape sugar, 325-326.
Guaicol, 141.
carbonate, 141.
Guanidine, 141.
Helium, 142.
Hexane, 142.
Hippuric acid, 142.
Homatropine, hydrobromide, 143.
Hydrastine, 143.
chloride, 143.
Hydrazine sulphate, 143.
Hydriodic acid, 145.
Hydrobromic acid, 143.
Hydrochloric acid, 144.
Hydrofluoric acid, 145.
Hydrogen, 145149.
sulphide, 150.
Hydroquinone, 150-151.
Hydroxy benzoic acids, 61.
Hydroxylamine, 151.
hydrochloride, 151.
Hyoscyamine, 151.
Hyoscine hydrobromide, 151.
Indium ammonium sulphate, 34.
caesium alum, So.
lodic acid, 145.
Iodine, 152154.
lodo benzoic acid, 60.
Iron ammonium alum, 33.
ammonium sulphate, 33.
caesium alum, So.
caesium sulphate, 84.
chloride, 157159.
chloride mix crystals, 159.
hydroxide, 160.
lead cyanide, 165.
nitrate, 160.
oxide, 1 60.
phosphate, 160.
potassium sulphate, 161, 262.
rubidium alum, 271.
rubidium sulphate, 274.
sulphate, 160.
sulphate + CdSCK, 79.
sulphate + Na 2 SO 4 , 161.
sulphide, 160.
Iron tellurium alum, 332.
amyl acetate, 35.
amyl alcohol, 1 1 .
amyl formate, 35.
amyl malonic acid, 186.
Iso butyric acid, 70.
butyric aldehyde, 69.
butyl acetate, 69-70.
butyl alcohol, 12.
phtnalic acid, 228.
propyl benzoic acid, 132.
Ketone, di ethyl, 137.
methyl ethyl, 204.
Lactic acid di ethyl amide, 355.
Lanthanum bromate, 162.
sulphate, 162.
Lead, 162.
and Pt alloys, 232.
acetate, 162.
ammonium cobalticyanide,
22.
benzoate, 162.
bromate, 162.
bromide, 163.
carbonate, 163.
chlorate, 163.
chloride, 163-165.
chromate, 165.
citrate, 165.
cyanides, 165.
fluoride, 165.
formate, 165.
hydroxide, 166.
hyposulphate, 170.
iodate, 166.
iodide, 166-167.
malate, 167.
nitrate, 168.
nitrate + BaCNO^, 50,
oxalate, 168.
oxides, 1 68.
palmitate, 169.
phosphate, 169.
succinate, 169.
sulphate, 169.
tartrate, 170.
Levulose, 170.
Ligroin, 170.
Lime, see Calcium hydroxide,
Lithium benzoate, 170.
bicarbonate, 172.
bichromate, 173.
borate, 170.
bromate, 171.
bromide, 171.
carbonate, 171.
chlorate, 172.
chloraurate, 172.
chloride, 172.
chromate, 173.
citrate, 173.
fluoride, 173.
formate, 174.
INDEX
Lithium gold chloride, 141.
hydroxide, 174.
hypophosphate, 176.
iodate, 174.
iodide, 175.
laurinate, 176.
myristate, 176.
nitrate, 175.
oleate, 176.
oxalate, 175.
palmitate, 176.
permanganate, 176.
phosphate, 176.
stearate, 176.
sulphate, 176.
Magnesium ammonium nitrate, 30.
ammonium sulphate, 34.
bicarbonate, 178-179.
bromate, 177.
bromide, 177.
bromide alcoholates, 177.
bromide aliphatic compounds,
177.
bromide etherates, 177.
cadmium chloride, 74.
caesium sulphate, 84.
carbonate, 178-179.
carbonate in aq. acetone, 6.
chlorate, 180.
chloride, 180181.
chromate, 181.
fluoride, 181.
fluosilicate, 184.
hydroxide, 181182.
hypophosphate, 184.
iodate, 182.
iodide, 182-183.
iodide alcoholate, 183.
iodide, alkyl esters, 183.
iodide, aliphatic compounds, 183.
iodide etherate, 183.
nitrate, 184.
oxalate, 184.
platinic chloride, 181.
platinic chromate, 181.
potassium sulphate, 185.
salicylate, 184.
sulphate, 184-185.
sulphate + MgCl 2 , 181.
sulphate + Na 2 SO 4 , 312.
sulphite, 185.
Maleic acid, 139.
Malonic acid, 185186.
Maltose in aq. acetone, 7.
Manganese ammonium molybdate,3o.
ammonium sulphate, 34.
borate, 186.
bromide, 186.
caesium sulphate, 84.
chloride, 187.
fluo silicate, 187.
hypophosphate, 187.
nitrate, 187.
Manganese potassium vanadate, 189.
sulphate, 188-189.
sulphate + CuSO 4 , 130.
Mannite, 189.
Mannitol, 189.
Mercury, 278.
bromide, 189190.
caesium bromide, 81.
chloride (ic), 190-196.
chloride (ous), 196.
chloride + BaCl 2 , 46.
chloride + CsCl, 81.
cyanide, 197.
fulminate, 197.
iodide, 197199.
oxide, 200.
sulphate, 200.
tetra methyl amine chloride, 195.
Methane, 200.
Methoxy benzoic acid, 38.
Methyl acetate, 203.
alcohol, 136.
amine, 15.
amine HgCl ? , 195.
ammonium iodide, 26.
benzoic acids, 61, 341.
butyrate, 203204.
Methylene bromide, 203.
chloride, 203.
Methyl ethyl ketone, 204.
iodide, 203.
malonic acid, 186.
phenyl carbamide, 104.
propionate, 203.
urethane, 355.
valerate, 204.
Milk sugar, 325-326.
Molybdenum trioxide, 204.
Monoacetin, 355.
Mono chlor acetic acid, 6.
Morphine, 204-205.
salts, 205.
Mustard oil, 205.
Naphthalene, 206-207.
in aq. acetone, 6.
/S- Naphthalene picrate, 55.
Naphthoic acid, 207.
Naphthol, 208.
Naphthylamine sulphonic acid, 206.
Naphtion acid, 206.
Narceine, 208.
Narcotics, 355.
Neodymium chloride, 208.
sulphate, 208.
Nickel ammonium sulphate, 34, 129.
bromate, 208.
bromide, 208.
caesium sulphate, 84.
chloride, 208-209.
iodate, 209.
iodide, 209.
nitrate, 210.
potassium sulphate, 212, 262.
INDEX
sulphate, 210-212.
tellurium sulphate, 334.
Nicotine, 212.
Nitranilines, o, m, and p, 38.
Nitric oxide, 218.
Nitro benzene, 56-57.
benzoic acids, 61-62.
Nitrogen, 213-214.
Nitrous oxide, 215-218.
Nitro phenols, 226.
Olive oil as solvent, 355.
Ortho boric acid, 65-67.
Oxalic acid, 31, 175, 219, 310.
Oxygen, 220-221.
Ozone, 221.
Papaverine, 222.
Paraffine, 222.
Pentane acid, 348.
Pentanon, 137.
Petroleum benzine, 58.
Phenacetine, 8.
Phenanthrene, 222223.
picrate, 223.
Phenic acid, 223.
Phenol, 223-225.
Phenols (amido), 60.
Phenol anilin mixtures, 38.
Phenolate of phenyl ammonium, 226.
Phenyl ammonium, phenolate, 226.
amines, 17.
di amines, 226.
guanidine (tri), 141.
hydrazine (benzoyl), 57.
methane (tri), 201-203.
salicylate, 227.
thio carbamide, 344-346.
thio urea, 344346.
Philocarpine salts, 231.
Phosphorus, 227-228.
Phosphomolybdic acid, 227.
Phthalic acids, 228.
anhydride, 228229.
Physostigmine salts, 229.
Picric acid, 229-231.
Piperine, 231.
Platino amines, 233.
Platinum alloys, 232.
ammonium bromide, 20.
bromide, 232.
double chlorides, 232.
potassium bromide, 232.
Plumbic, see Lead.
Potassium acetate, 233.
acid formate, 251.
acid nitrate, 257.
acid oxalate, 259.
acid sulphate, 264.
alum, 13-14.
antimony tartrate, 41.
arsenate (di hydrogen), 233.
barium ferrocyanide, 48.
benzoate, 233.
bicarbonate, 238-239.
bitartrate, 265-266.
Potassium berates, 234.
boride (fluo), 234.
bromate, 234-235.
bromide, 2315-238.
bromide and chloride, 242.
bromide + Hg(CN) 2 , 197.
butyrate, 238.
cadmium bromide, 71.
cadmium chloride, 76.
cadmium iodide, 78.
cadmium sulphate, 79.
calcium ferrocyanide, 90.
carbonate, 238-239.
carbonate in aq. acetone, 6.
carbonate in aq. ammonia, 180
carbonyl ferrocyanide, 250.
chlorate, 239-241.
chlorate + T1C1O,
335-
chloride, 24, 241-248.
chloride + BaCl 2 , 46.
chloride + CaCl 2 , 89.
chloride + FeCl 3 , 159.
chloride + HgCl 2 , 191.
chloride + Hg(CN) 2 , 197.
chloride + KBr, 236.
chloride + KNO 3 , 255.
chloride + NaCl, 300.
chloride + Na 2 SO 4 , 312.
chromates, 248-249.
chromates + K 2 SO 4 , 263.
chromium alum, 116.
chromium molybdate, 116.
chromisulphocyanide, 250.
chromoc yanide, 250.
cobalt sulphate, 262.
copper chloride, 127.
copper sulphate, 131, 262.
citrate, 249.
cyanate, 249.
cyanide, 249.
di chromate, 248-249.
didymium sulphate, 133.
ferric yanide, 250.
ferrocyanide, 250.
ferrosulphate, 262.
fluoride, 250.
fluo boride, 234.
fluo germanate, 251.
fluo titanate, 266.
formate, 251.
gold chloride, 141.
hippurate, 142.
hydroxide, 251.
hypophosphate, 260.
hypophosphite, 260.
iodate, 252.
iodide, 252-253.
iodide and bromide, 236.
iodide and chloride, 243.
iodide and PbI 2 . 167.
iodide and Hg(CN) 2 , 197.
iron sulphate, 161.
lead cobaltic yanide, 165.
363
INDEX
Potassium lead ferricyanide, 165.
magnesium chloride, 181.
magnesium chromate, 181.
magnesium cyanide, 181.
magnesium sulphate, 185.
manganese vanadate, 189.
mercuric cyanide, 197.
nickel sulphate, 212, 262.
nitrate, 24, 29, 254258.
nitrate + Ba.(NOJ 2 , 50.
nitrate + KBr, 237.
nitrate + KC1, 244.
nitrate + NaCl, 300.
nitrate + NaNO 3 , 308.
nitrite, 254.
oxalate, 258-259.
perchlorate, 241.
perchlorate + KMnO 4 , 260.
persulphate, 264.
permanganate, 259-260.
phosphate, 260.
phosphite, 260.
phosphomolvbdate, 261.
platinic bromide, 232.
platinic chloride, 232-233.
selinate, 261.
sodium carbonate, 239.
sodium sulphate, 263.
sodium sulphite, 264.
sodium thio sulphate, 264.
stannate, 261.
sulphate, 24, 32, 261-264.
sulphate + KC1, 245.
sulphate + KNO 3 , 256.
sulphate + NaCl, 300.
sulphate + Na 2 SO 4 , 312.
sulphocyanide, 265, 291.
tartrate, 265-266.
tellurium bromide, 332.
thio cyanate, 291.
tri chromate, 249.
uranyl butyrate, 343.
uranyl carbonate, 239.
uranyl chloride, 342.
uranyl nitrate, 343.
uranyl sulphate, 344.
vanadate, 266.
zinc vanadate, 266.
Praseodymium sulphate, 267,,
Propio nitril, 267.
Propionic acid (amido), 10.
aldehyde, 267.
Propylene, 268.
Propyl acetate, butyrate, etc., 267-
268.
acetic acid, 348.
alcohol in aq. K 2 CO 3 , 239.
ammonium iodide (tetra), 28.
anisol (p), 35.
bromide, chloride, etc., 268.
formate, 268.
malonic acid, 186.
Pseudo cumidin, 132.
Pyrene, 268.
Pyrogallol, 268.
Pyrotartaric acid, 140.
Quinine and salts, 117, 269.
Racemic acid, 331.
Resorcinol, 270
Rhodium salts, 270.
sodium nitrite, 309.
Rubidium alums, 15, 271.
bromide, 271.
brom iodide, 273.
cadmium bromide, 72
cadmium chloride, 75.
cadmium sulphate, 274.
carbonate, 271.
chlorate, 271.
chloride, 272.
chromate, 272.
cobalt nitrate, 122.
cobalt sulphate, 274
copper sulphate, 274.
di chromate, 272.
fluo boride, 271.
fluo silicate, 273.
gold chloride, 141.
hydroxide, 272.
iodate, 272.
iodide, 272-273.
iron sulphate, 274.
nitrate, 273.
mercuric chlorides, 192.
perchlorate, 271.
permanganate, 273.
permanganate + KMnO 4 , 260
platinic chloride, 232.
selena te, 273.
silico tungstate, 273.
sulphate, 273-274.
tellurium bromide, 332.
tellurium chloride, 272, 332
thallium chloride, 272.
uranyl chloride, 342.
uranyl nitrate, 343.
Saccharine, 61.
Salicylamid, 355.
Salicylic acid, 61, 274276.
Salol, 227.
Selenious acid, 277.
Selenium, 276.
Senfol, 205.
Silicon, 277.
Silico tungstic acid, 277.
Silver, 278.
and Pt alloys, 232.
acetate, 278.
benzoate, 279.
borate, 279.
bromate, 279-280.
bromide, 280-281.
butyrate, 281.
caproates, 282.
carbonate, 282.
chlorate, 282.
364
INDEX
Silver chloride, 283-286,
chromate, 286.
citrate, 286.
cyanide, 286.
di chromate, 286.
di ethyl acetate, 279.
di propyl acetate, 278.
fluoride, 287.
fulminate, 287.
heptoate, 287.
hydroxide + AgCl, 285.
iodate, 287.
iodide, 277, 287-288.
iso butyrate, 281.
malate, 288.
methyl ethyl acetate, 279.
mono chlor acetate, 278.
nitrate, 288-289.
nitrate + KNO 3 , 257.
nitrite, 289.
onanthylate, 287.
oxalate, 289.
oxide, 289.
permanganate, 289.
phosphate, 289.
propionate, 290.
salicylate, 290.
sodium cyanide, 286.
succinate, 290.
sulphate, 290291.
sulphate + CaSO 4 , 101.
sulphocyanide, 291.
tartrate, 291.
thallous cyanide, 286.
thio cyanate, 291.
tri methyl acetate, 279.
valerates, 291292.
vanadate, 292.
Sodium acetate, 292293.
acid formate, 305.
alum, 15.
ammonium sulphate, 34.
ammonium sulphite, 35.
arsenate, 293.
benzoate, 293.
bicarbonate, 22, 297298.
bicarbonate + NaCl, 300.
bisulphate, 315.
borate, 294.
bromate, 294.
bromide, 295.
cadmium bromide, 72.
cadmium iodide, 78.
cadmium sulphate, 80.
carbonate, 296-297.
carbonate in aq. acetone, 6.
chlorate, 298-299.
chloride, 24, 299-303.
chloride + BaCl 2 , 46.
chloride + CaCl 2 , 89.
chloride + FeCl 3 , 159.
chloride + Hg(CN) 2 , 191.
chloride + KC1, 245.
Sodium chloride -f KNO 3 , 256.
chloride + Na 2 CO 3 , 298.
chloride + NaClO 3 , 299.
chromates, 303-304.
citrate, 305.
copper sulphate, 131.
ferrocyanide, 305.
fluoride, 305.
fluoride phosphate, 310.
fluo silicate, 305.
fluo zirconate, 316.
formate, 305.
gold chloride, 141.
hydrogen arsenate, 293.
hydroxide, 306.
hydroxide + NaCl, 301.
hypophosphates, 311.
hypophosphite, 311.
iodate, 306.
iodide, 306.
iodide + Hg(CN) 2 , 197.
mercuric chloride, 193.
mono chromate, 303-304.
molybdate, 307.
nitrate, 29, 307-309.
nitrate + KNO 3 , 256.
nitrate + NaCl, 301.
nitrate + AgNO 3 , 288.
nitrite, 309.
p nitro phenol, 310.
oxalate, 309-310.
phosphates, 310.
phosphites, 311.
potassium carbonate, 239.
potassium sulphate, 263.
potassium sulphite, 264.
potassium thio sulphate, 2640
rhodonitrite, 309.
salicylate, 275, 355.
selinate, 311.
silver cyanide, 286.
stannate, 311.
sulphate, 311315.
sulphate + CoSO 4 , 122.
sulphate + CuSO 4 , 131.
sulphate + FeSO 4 . 161.
sulphate + NiSO 4 , 2ir.
sulphate + ZnSO 4 , 353.
sulphite, 315.
telluriate, 315.
tetra borate, 293.
tetra chromate, 304.
thio sulphate, 315.
tri molybdate, 307.
tungstate, 316.
uranyl chromate, 343.
wolfromate, 316.
Stannous, stannic, see Tin.
Strontium benzoate, 316.
bicarbonate, 316.
bromate, 316.
bromide, 316.
carbonate, 316.
365
INDEX
Strontium chlorate, 317.
chloride, 317.
chromate, 318.
di tungstate, 321.
fluoride, 318.
hydroxide, 318.
hyposulphate, 170.
iodate, 318.
iodide, 318.
iodide + Hg(CN) 2 , 197.
malate, 319.
molybdate, 319.
nitrate, 319.
nitrate -f Pb(NO 3 ) 2 , 168.
oxalate, 319.
salicylate, 319.
sulphate, 320.
tartrate, 320321.
tungstate (di), 321.
Strychnine and salts, 321.
Suberic acid, 321.
Succinic acid, 322-323.
anhydride, 322.
nitril, 323.
Succinimid, 323.
Sugar, 324-326.
in aq. acetone, 7.
+ K. Butyrate, 238.
+ MgS0 4 , 185.
Sulphanilic acid, 326.
Sulphonal, 355.
Sulphonic acids, 57.
Sulphur, 327328.
in anilin, 36.
in benzene, 56.
dioxide, 329-331.
trioxide, HgO and H 2 O, 200.
Syngenite, 101.
Tannic acid, 331.
Tartar emetic, 41.
Tartaric acid, 331.
Telluric acid, 332.
Tellurium, 331.
caesium bromide, 332.
caesium chloride, 82, 332.
chromium alum, 116.
mercuric cyanide, 197.
potassium bromide, 332.
rubidium bromide, 332.
rubidium chloride, 272, 332.
Terephthalic acid, 228.
Tetra boric acid, 67.
chlor methane, 201.
ethyl ammonium bromide, 20.
ethyl ammonium chloride, 25.
ethyl ammonium iodide, 27.
methyl ammonium iodide, 26. *.
propyl ammonium iodide, 28.
sodium chromate, 304.
Tetronal, 355.
Thallium alum, 14, 15, 332.
bromate, 332.
bromide, 332.
caesium chloride, 82.
carbonate, 338.
chlorate, 333.
chloride, 333~335.
chromate, 335.
copper sulphate, 338.
cyanide, 336.
fluoride, 336.
iodate, 336.
iodide, 336.
nickel sulphate, 338.
nitrate, 336.
nitrate + KNO 3 , 257.
oxalate, 336-337.
perchlorate, 338.
phosphate, 337.
picrate, 337.
platinic chloride, 232.
rubidium chloride, 272.
silver cyanide, 286.
sulphate, 338.
sulphide, 338.
sulphite, 339.
sulphocyanide, 338.
vanadates, 339.
zinc sulphate, 338.
Thallous tri chromate, 335.
Thallo thallic chloride, 335.
Theobromine, 339.
Thio urea (phenyl), 344-346.
Thorium selenate, 339.
sulphate, 339.
Tin chloride, 340.
hydroxide, 340.
iodide, 340-341.
sulphate, 341.
Toluene, 341.
Toluidine, 341-342.
Toluyl acids, 341.
Tolyl carbamide, 104.
Tri acetin, 355.
brom phenols, 226.
chlor phenols, 226.
chlor acetic acid, 6.
ethyl amine, 16.
methyl amine, 15.
nitro benzene, 57.
oxymethylene, n.
phenyl amine, 17.
phenyl guanidine, 141.
phenyl methane, 201.
Trional, 355.
Tungsto silicic acid, 277.
Uranyl ammonium carbonate, 22.
ammonium propionate, 343.
chloride, 342.
366
INDEX
Uranyl double chlorides, 342.
double nitrates, 343.
nitrate, 343.
potassium butyrate, 343.
potassium carbonate, 239.
potassium sulphate, 344.
sodium chr ornate, 343.
sulphate, 344.
Urea, 344-346.
Urethane, 347.
Uric acid, 347.
Valerianic acid, 348.
Valeramide, etc., 355.
Vanadium ammonium sulphate, 34,
caesium alum, 80.
rubidium alum, 271.
tellurium alum, 332.
Ytterbium sulphate, 348.
Yttrium iodate, 348.
Zinc and Pt alloys, 232.
Zinc acetate, 348.
ammonium sulphate, 34, 129.
Zinc benzoate, 348.
bromide, 348.
caesium sulphate, 84.
carbonate, 349.
chlorate, 349.
chloride, 349-350.
cyanide, 349.
fluoride, 350.
hydroxide, 350-351.
iodate, 351.
iodide, 351.
nitrate, 351.
oxalate, 352.
potassium sulphate, 262.
potassium vanadate, 266.
sulphate, 352-353.
sulphate + CuSO 4 , 130.
sulphite, 353.
tartrate, 353.
tellurium sulphate, 334.
valerate, 353.
367
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