$B 117 452 ommon als ana ( , CROSBY" /B E R K E L E Y * UNIVERSITY OF V CALIFORNIA r of Natural ^i GUIDES FOR SCIENCE-TEACHING No. XII COMMON MINERALS AND ROCKS BY WILLIAM O. CROSBY D. C. HEATH & CO., PUBLISHERS BOSTON NEW YORK CHICAGO Copyright BY THE BOSTON SOCIETY OF NATURAL HISTORY 1881 I D 2 INTRODUCTION. MINERALS and rocks, or the inorganic portions of the earth, constitute the proper field or subject-matter of the science of Geology. Now the inorganic earth, like an animal or plant, may be and is studied in three quite distinct ways, giving rise to three great divisions of geology, which, as will be seen, correspond closely to the main divisions of Biology. First, we may study the forces now operating upon and in the earth the geological agencies such as the ocean and atmosphere, rivers, rain and frosts, earthquakes, volcanoes, hot springs, etc., and observe the various effects which they produce. We are con- cerned here with the dynamics of the earth ; and this is the great division of dynamical geology, correspond- ing to physiology among the biological sciences. Or, second, instead of geological causes, we may study more particularly geological effects, observing the different kinds of rocks and of rock-structure pro- duced by the geological agencies, not only at the present time, but also during past ages. This method of study gives us the important division of structural geology, corresponding to anatomy and morphology. 6 INTRODUCTION. All phenomena present two distinct and opposite aspects or phases which we call cause and effect; and so in dynamical and structural geology we are really studying the opposite sides of essentially the same classes of phenomena. In the first Division we study the causes now in operation and observe their -effects ; and then, guided by the light of the experience thus gained, we turn to the effects produced in the past and seek to refer them to their causes. These two divisions together constitute what is properly known as physiography ; and they are both subordinate to the third great division of geology, historical geology, which corresponds to embry- ology. The great object of the geologist is, by studying the geological formations in regular order, from the oldest up to the newest, to work out, in their proper sequence, the events which constitute the earth's history ; and dynamical and structural geology are merely introductory chapters, the alphabet, as it were, which must be learned before we are prepared to read understandingly the grand story of the geological record. Our work in this short course will be limited to the first two divisions, i.e., to dynamical and structural geology- We will attempt, first, a general sketch of the forces now concerned in the formation of rocks and rock-structures ; and after that we will study the composition and other characteristics of the common minerals and rocks. The scope of this work, and its relations to the whole field of geology, are more clearly indicated by the fol- lowing classification of the geological sciences : GEOLOGY INTRODUCTION. 'DYNAMICAL GEOLOGY (P^y^l Geology. I Chemical Geology. {Mineralogy. I Petrology. .HISTORICAL GEOLOGY. Many teachers will desire to fill in some of the details of the outline sketch presented in this Guide, and for this purpose the following works are especially recom- mended : ELEMENTS OF GEOLOGY. By Prof. Joseph LeConte. 1882. D. Appleton & Co., New York. Nearly 600 pages. MANUAL OF GEOLOGY. By Prof. J. D. Dana. Third edition. 1880. 800 pages. TEXT-BOOK OF GEOLOGY. By- Prof. A. Geikie. 1882. Mao millan & Co. London. Nearly looo pages. As a reference-book for mineralogy, the following treatise is unsurpassed : TEXT-BOOK OF MINERALOGY. By Edward S. Dana. 1883. John Wiley & Sons, New York. And, as an introduction to the study of minerals, and, through these, to the study of rocks, FIRST LESSONS IN MINERALS. Science Guide No. XIII. By Mrs. E. H. Richards. cannot be too highly recommended. Teachers will find this little primer of 46 pages invaluable with young children, and with all who have had no previous train- ing in chemistry. As an admirable continuation of the work begun in these pages, teachers are referred to Professor Shaler's " First Book in Geology." In this our brief sketch of 8 1NTR OD UC TION. the geological agencies is amplified and beautifully illustrated; and rarely have the wonderful stories of the river, ocean-beach, glacier, and volcano been told so effectively. In the chapter on the history of life on the globe the main outlines of historical geology are skillfully brought within the comprehension of begin- ners. The directions to teachers are fully in accord with the modern methods and ideas, and are a very valuable feature of the book. DYNAMICAL GEOLOGY. WHEN we think of the ocean with its waves, tides, and currents, of the winds, and of the rain and snow, and the vast net-work of rivers to which they give rise, we realize that the energy or force manifested upon the earth's surface resides chiefly in the air and water in the earth's fluid envelope and not in its solid crust. And it would be an easy matter to show that, with the exception of the tidal waves and currents, which of course are due chiefly to the attraction of the moon, nearly all this energy is merely the transformed heat of the sun. Now the air and water are two great geological agen- cies, and therefore the geological effects which they produce are traceable back to the sun. Organic matter is another important geological agent ; but all are familiar with the generalization that connects the energy exhibited by every form of life with the sun ; and, besides, it is scarcely necessary to allude to the ob- vious fact that all animals and plants, so far at least as any display of energy is concerned, are merely differ- entiated portions of the earth's fluid envelope. And so, if space permitted, it might be shown that, with the exception of the tides, nearly every form of force 10 DYNAMICAL GEOLOGY. manifested upon the earth's surface has its origin in the sun. Of this trio of geological agencies operating upon the earth's surface and vitalized by the sun water, air, and organic matter the water is by far the most important, and so it is common to call these collec- tively the aqueous agencies. Hence we have solar agencies and aqueous agencies as synonymous terms. The aqueous agencies include, on one side, air and water, or inorganic agencies ; and, on the other, animals and plants, or organic agencies. Let us notice briefly the operation of these, begin- ning with the air and water. I. AQUEOUS AGENCIES. i. Air and Water, or Inorganic Agencies. CHEMICAL EROSION. Attention is invited first to the specimens numbered i, 2, 3, and 4. No. i is a sound, fresh piece of the rather common rock, diabase ; and those who are acquainted with minerals will recognize that the light-colored grains in the rock are feldspar, and the dark, augite. This specimen came from a depth in the quarry, and has not been exposed to the action of the weather. The second specimen differs from the first, appar- ently, as much as possible ; and yet, except in being somewhat finer grained, it was originally of precisely similar composition and appearance. In fact, it is a portion of the same rock, but a weathered portion. In this we can no longer recognize the feldspar and augite AQUEOUS AGENCIES. II as such, but both these minerals are very much changed, while in the place of a strong, hard rock we have an incoherent friable mass, which is, externally at least, easily crushed to powder ; and with the next step in the weathering, as we may readily observe in the natural ledges, the rock is completely disintegrated, forming a loose earth or soil. We have two examples of such natural powders in the specimens numbered 3 and 4 ; and by washing these (especially the finer one, No. 4) with water, we can prove that they consist of an impalpable substance which we may call clay, and angular grains which we may call sand. The sand-grains are really portions of the feldspar not yet entirely changed to clay. Thus we learn that the result of the exposure of this hard rock to the weather is that it is reduced to the condition of sand and clay. What we mean especially by the weather are moisture and certain constituents of the air, particularly carbon dioxide. The action of the weather on the rocks is almost en- tirely chemical. With a very few exceptions, the prin- cipal minerals of which rocks are composed, such as feldspar, hornblende, augite, and mica, are silicates, i.e., consist of silicic acid or silica combined with various bases, especially aluminum, magnesium, iron, calcium, potassium, and sodium. Now the silica does not hold all these bases with equal strength; but carbon dioxide, in the presence of moisture, is able to take the sodium, potassium, calcium, and magnesium away from the silica in the form of carbonates, which, being soluble, are carried away by the rain-water. 12 DYNAMICAL GEOLOGY. The silicate of aluminum, with more or less iron, takes on water at the same time, and remains behind as a soft, impalpable powder, which is common clay. In the case of our diabase, contined exposure to the weather would reduce the whole mass to clay. But other rocks contain grains of quartz, a hard mineral which cannot be decomposed, and it always forms sand. Certain classes of rocks, too, such as the limestones and some iron-ores, are completely dissolved by water holding carbon dioxide in solution, and nothing is left to form soil, except usually a small proportion of insol- uble impurities like sand or clay. Let us see next how these agents of decay get at the rocks. Neither water nor air can penetrate the solid rock or mineral to any considerable extent, so that practically the action is limited to surfaces, and whatever multiplies surfaces must favor decomposition. First, we have the upper surface of the rock where it is bare, but more especially where it is covered with soil, for there it is always wet. All rocks are naturally divided by joints into blocks, which are frequently more or less regular, and often of quite small size. Water and air penetrate into these cracks and decompose the surfaces of the blocks, and thus the field of their operations is enormously ex- tended. These rock-blocks sometimes show very beautifully the progress of the decomposing agents from the outside inward by concentric layers or shells of rotten material, which, in the larger blocks v pften envelop a nucleus of the unaltered rock. It is interesting to observe, too, that these concentric lines of decay cut off the angles of the original blocks* AQUEOUS AGENCIES. 13 so that the undecomposed nucleus, when it is found, is approximately spherical instead of cuboidal. Both these points are well illustrated by specimen No. 2 ; for although now nearly spherical, it was originally perfectly angular, and has become rounded by the peeling off, in concentric layers, of the decomposed material, and in most cases several of these layers are distinctly visible, like the coats of an onion. But by stripping these off we should discover, in all the larger balls at least, a solid, spheroidal nucleus, while in the smaller balls the decomposition has penetrated to the centre. In the rocks also we find many imperfect joints and minute cracks. In cold countries these are extended and widened by the expansive power of freezing water, and thus the surfaces of decomposition become con- stantly greater. Nearly all rocks suffer this chemical decomposition when exposed to the weather, but in some the decay goes on much faster than in others. Diabase is one of the rocks which decay most readily ; while granite is, among common rocks, one of those that resist decay most effectually. The caverns which are so large and numerous in most limestone countries are a splendid example of the solvent action of meteoric waters, being formed entirely by the dissolving out of the limestone by the water circulating through the joint cracks. The pro- cess must go on with extreme slowness at first, when the joints are narrow, and more rapidly as they are widened and more water is admitted. We get some idea, too, of the magnitude of the results accomplished 14 DYNAMICAL GEOLOGY. by these silent and unobtrusive agencies when we re- fleet that almost all the loose earth and soil covering the solid rocks are simply the insoluble residue which carbon dioxide and water cannot remove. In low lati- tudes, where a warm climate accelerates the decay of the rocks, the soil is usually from 50 to 300 feet deep,, MECHANICAL EROSION. On the edge of the land. Let us trace next the mechanical action of water and air upon the land. First we will consider the edge of the land, where it is washed by the waves of the sea. Whoever has been on the shore must have noticed that the sand along the water's edge is kept in con- stant motion by the ebb and flow of the surf. Where the beach is composed of gravel or shingle the motion is evident to the ear as well as the eye ; and when the surf is strong, the rattling and grinding of the pebbles as they are rolled up and down the beach develops into a roar. The constant shifting of the grains of sand, pebbles, and stones is, of course, attended by innumerable col- lisions, which are the cause of the noise. Now it is practically impossible, as we may easily prove by ex- periment, to knock or rub two pieces of stone together, at least so as to produce much noise, without abrading their surfaces ; small particles are detached, and sand and dust are formed. That this abrasion actually occurs in the case of the moving sand is most beautifully shown by the sand-- blast. We are to conclude, then, that every time a pebble, large or small, is rolled up or down the beach it becomes smaller, and some sand and dust or clay are formed which are carried off by the water. AQUEOUS AGENCIES. 15 But what are the pebbles originally? This question is not difficult. A little observation on the beach shows us that the pebbles are not all equally round and smooth, but many are more or less angular. And we soon see that it is possible to select a series showing all grada- tions between the most perfectly rounded forms and angular fragments of rock that are only slightly abraded on the corners. The three principal members of such a series are shown in specimens 5, 6, and 7 from the beach on Marblehead Neck ; but equally instructive specimens can be obtained at many other points on our coast. It is also observable that the well-rounded pebbles are much smaller on the average than the angu- lar blocks. From these facts we draw the legitimate inference that the pebbles were all originally angular, and that the same abrasion which diminishes their size makes them round and smooth. A little reflection, too, shows that the rounding of the angular fragments is a natural and necessary result of their mutual collisions ; for the angles are at the same time their weakest and most exposed points, and must wear off faster than the flat or concave surfaces. Having traced each pebble back to a larger angular rock-fragment, the question arises, Whence come these angular blocks ? Behind our gravel-beach, or at its end, we have usually a cliff of rocks. As we approach this it is dis- tinctly observable that the angular pebbles are more numerous, larger, and more angular; and a little observation shows that these are simply the blocks produced by jointing, and that the cliff is entirely 1 6 DYNAMICAL GEOLOGY. composed of them. In other words, our cliff is a mass of natural masonry, which chemical agencies, the frost, and the sea are gradually disintegrating and removing. As soon as the blocks are brought within reach of the surf their mutual collisions make them rounder and smaller ; and small round pebbles, sand, and clay are the final result. For a more complete account of the formation of pebbles, teachers are referred to the first or introduc- tory number of this series of guides, by Prof.' Hyatt, "About Pebbles." Where the waves can drive the shingle directly against the base of the cliff, this is gradually ground away in the same manner as the loose stones them- selves, sometimes forming a cavern of considerable depth, but always leaving a smooth, hard surface, which is very characteristic, and contrasts strongly with the upper portion of the cliff, which is acted on only by the rain and frost. A good example of such a pebble-carved cliff may be seen behind the beach on the sea-ward side of Marblehead Neck. The sea acts within very narrow limits vertically, a few feet or a few yards at most ; but the coast-lines of the globe (including inland lakes and seas) have an aggregate length of more than 150,000 miles. Hence it is easy to see that the amount of solid rock ground to powder in the mill of the ocean-beach annually must be very considerable. MECHANICAL EROSION. On the surface of the land. I next ask attention to the mechanical action of water upon the surface of the land. It is a familiar fact that after heavy rains the road- AQUEOUS AGENCIES. 17 side rills carry along much sanfl and clay (which we know have been produced by the previous action of chemical forces), and also frequently small pebbles 01 gravel. It is easy to show that in all important respects the rill differs in size only from brooks and rivers ; and the former afford us fine models of the systems of val- leys worn out during the lapse of ages by rivers. The turbidity of rivers is often very evident, and in shallow streams we can sometimes see the pebbles rolled along by the current. Now here, just as on the beach, the collisions of rock-fragments are attended by mutual abrasion, sand and clay are formed, and the fragments become smaller and rounder. Our series of pebbles from the beach might be matched perfectly among the river-gravel. In mountain streams especially we may often observe that pebbles of a particular kind of rock become more numerous, larger, and more angular as we proceed up stream, until we reach the solid ledge from which they were derived, showing the same gradation as the beach pebbles when followed back to the parent cliff. The pebbles, however, not only grind each other, but also the solid rocks which form the bed of the streams in many places, and these are gradually worn away. When the rocky bed is uneven and the water is swift, pebbles collect in hollows where eddies are formed, by which they are kept whirling and turning, and the hollow is deepened to a pot-hole, while the pebbles, the river's tools, are worn out at the same time. By these observations we learn not only that run- ning water carries away sand and clay already formed, but that it also has great power of grinding down hard l8 DYNAMICAL GEOLOGY. rocks to sand and clay. J Of course the pulverized rock always moves in the same direction as the stream which carries it ; and, in a certain sense, all streams run in one direction, viz., toward the sea. Therefore the con- stant tendency of the rain falling upon the land is to break up the rocks by chemical and mechanical action and transport the debris to the sea. Rivers, as we all know, are continually uniting to form larger and larger streams ; and thus the drainage of a wide area sometimes, as in the case of the Missis- sippi Valley, reaches the sea through a single mouth. By careful measurements made at the mouth of the Mis- sissippi it has been shown that the 20,000,000,000,000 cubic feet of water discharged into the Gulf of Mexico annually carries with it no less than 7,500,000,000 cubic feet of sand, clay, and dissolved mineral matter ; and this, spread over the whole Mississippi basin, would form a layer a little more than -^Vs f a f ot m thick- ness. So that we may conclude that the surface of the continent is being cut down on the average about one foot in five thousand years. We can only allude in passing to the very important geological action of water in the solid state, as in gla- ciers and icebergs. The moisture precipitated from the atmosphere, and falling as rain, makes ordinary rivers ; but falling in the form of snow in cold regions, where more snow falls than is melted, the excess ac- cumulates and is gradually compacted to ice, which, like water, yields to the enormous pressure of its own mass and flows toward lower levels. When the ice- river reaches the sea it breaks off in huge blocks, which float away as icebergs. Moving ice, like moving water, AQUEOUS AGENCIES. 19 is a powerful agent of erosion ; and the glacial marks or scratches observable upon the ledges everywhere in the Northern States and Canada attest the magni- tude of the ice-action at a comparatively recent period. We have already noticed incidentally the powerful disintegrating action of water where it freezes in the joints and pores of the rocks ; and it is probable that it thus facilitates the destruction of the rocks in cold countries nearly as much as the higher temperature and greater rain-fall do in warm countries. Our observations up to this point show us that ero- sion, by which we mean the breaking up by chemical and mechanical action of the rocks of the land and the transportation of the debris into the sea, is one great result accomplished by the inorganic aqueous agencies. MECHANICAL DEPOSITION. Next let us notice what becomes of all this vast amount of clay, sand, and gravel after it is washed into the ocean. By taking up a glass of turbid water from our roadside rill, and observing that as soon as the water is undisturbed the sand and clay begin to settle, we learn that the solid matter is held in suspension by the motion of the water. But it does not remain in suspension long after being washed into the sea, for otherwise the sea would, in the course of time, become turbid for long distances from shore ; and it is a well-known fact that the sea-water is usually clear and free from sensible turbidity close along shore and even near the mouths of large rivers, while at a distance of only 50 or 100 miles we find the transpar- ency of the central ocean. Putting these facts together, we see that the ocean, noth withstanding tl?e ceaseless and often violent undu- *0 DYNAMICAL GEOLOGY. lations of its surface, must be as a whole a vast body of still water ; and to the reflecting mind the almost perfect tranquillity of the ocean is one of its most im- pressive features. For it is in striking contrast, in this respect, with the more mobile aerial ocean above it. We have got hold, now, of two facts of great geo- logical importance : ( i ) The debris washed off the land by waves and rivers into the still water of the ocean very soon settles to the bottom ; and (2) it nearly all settles on that part of the ocean-floor near the land. And now we have in view the second great office of the inorganic aqueous agencies, deposition, the counterpart or complement of erosion. The land is the great theatre of erosion and the sea of deposition ; the rocks which are constantly wasting away on the former are as constantly renewed in the latter. We will now observe the process of deposition a little more closely. Each of these two bottles contains the same amount of fine yellow clay, but in one the water is fresh, and in the other it is salt. At the beginning of the lesson, as you may have observed, I brought the clay in both bottles into suspension by violent agita- tion, and since then they have remained undisturbed. The main point is that the salt water has become quite clear, while the fresh water is still distinctly turbid, showing that the salt favors the rapid deposition of the clay. At the second lecture, a week later, these two bottles, yet undisturbed, were exhibited, and the fresh water seen to be still sensibly turbid. The fact is, the clay is not held in suspension wholly by the motion of the water ; but, just as in the case of dust in the atmos- AQUEOUS AGENCIES. 21 phere, a small portion of the medium is condensed around or adheres to each solid particle, *>., each clay particle in our experiment has an atmosphere of water which moves with it and buoys it up. Now the effect of the salt is to diminish the adhesion of the water to the particles, i.e., to diminish their atmos- pheres, and consequently their buoyancy. The dimin- ished adhesion of the salt water is well shown by the smaller drops which it forms on a glass rod. The geological importance of this principle is very great ; for it is undoubtedly largely to the saltness of the sea that we owe its transparency, and the fact that the fine, clayey sediment from the land, like the coarse, is deposited near the shore. This bottle of fresh water contains some fine gravel, coarse sand, fine sand, and clay. By agitating the water, all this material is brought into suspension. Now, suddenly placing the bottle in a state of rest, we observe that the gravel falls to the bottom almost instant- ly, followed quickly by the coarse sand, and very soon afterward by the fine sand ; and then there appears to be a pause, the fine particles of clay all remain in sus- pension ; but finally, when the water is quite motion- less, they begin to settle ; they fall very slowly, however, and the water will not be clear for hours. This is a very instructive experiment. We learn- from it : . First, that the power of the water to hold particles in suspension is inversely proportional to the size of the particles ; Second, that all materials deposited in water are as* sorted according to size ; 22 DYNAMICAL GEOLOGY. Third, and this is one of the most important facts in geology, all water-deposited sediments are arranged in horizontal layers, i.e., are stratified. And we have now traced to its conclusion, though very briefly, the process of the formation of one great division of stratified rocks, the mechanically-formed orfragmental rocks. These are so called because the clay, sand, and gravel are, in every instance, fragments of pre-existing rocks ; and because the formation, transportation, and especially the deposition of these fragments, are the work chiefly or entirely of mechanical forces. CHEMICAL DEPOSITION. It is a well-known fact that the sea holds in solution vast amounts of common salt as well as many other substances; and analyses of river-waters show that dissolved minerals derived from the chemical decomposition of the rocks of the land are being constantly carried into the sea. Portions of the sea which are cut off from the main body, and which are gradually drying up, like the Great Salt Lake, Dead Sea, and Caspian Sea, become saturated solutions of the various dissolved minerals, and these are slowly deposited. This process is very nicely illustrated along our shores in summer, where> during storms, salt-water spray is thrown above the reach of the tides, and, collecting in hollows in the rocks, gradually dries up, leaving behind a crust of salt. When the sea lays down matter which it held in sus- pension, we call the process mechanical deposition, and the result is mecham'ca/fy-formed rocks. But when it lays down matter which it held in solution, we call the process chemical deposition, and the result is chemicall-iQimzd. rocks. AQUEOUS AGENCIES. 23 The principal substances which the sea deposits chemically are common salt, forming beds of rock-salt ; sulphate of calcium, forming beds of gypsum ; carbonate of calcium, forming beds of limestone ; and the double carbonate of calcium and magnesium, forming beds of dolomite. Inorganic deposition, like inorganic erosion, is both chemical and mechanical. 2. Animals and Plants, or Organic Agencies. We turn now to the consideration of the organic agencies. And I will merely allude in passing to the vast importance of the fossil organic remains found in the stratified rocks as marks by which to determine the relative ages of the formations. As regards the destruction of rocks erosion plants and animals are almost powerless ; but in the role of rock-makers they play a very important part, being very efficient agents of deposition. FORMATION OF COALS AND BITUMENS. Specimen No. 8 is an example of peat from the vicinity of Bos- ton ; but just as good specimens may be obtained in thousands of places in this and other States. The general physical conditions under which peat is formed are familiar facts. We require simply low, level land, covered with a thin sheet of water and abundant vegetation; in other words, a marsh or swamp. If plants decay on the dry land, the decomposition is complete ; they are burned up by the oxygen of the air to carbon dioxide and water just as surely as if 24 DYNAMICAL GEOLOGY. they had been thrown into a furnace, though less rapidly, and nothing is returned to the soil but what had been taken from it by the plants during their growth. But if the plants decay under water, as in a peat-marsh or bog, the decay is incomplete, and most of the carbon of the wood is left behind. Now, if this incomplete combustion of vegetable tissues takes place in a charcoal-pit, where the wood is out of con- tact with air from being covered with earth, we call the carbonaceous product charcoal ; but if under the water of a marsh, in Nature's laboratory, we call the product peat. Peat is simply a natural charcoal ; and, just as in ordinary charcoal, its vegetable origin is always perfectly evident. But when the deposit becomes thicker, and especially when it is buried under thick formations of other rocks, like sand and clay, the great pressure consolidates the peat ; it becomes gradually more min- eralized and shining, shows the vegetable tissues less dis- tinctly, becomes more nearly pure carbon, and we call it in succession lignite, bituminous coal, and anthracite. This is, briefly, the way in which all varieties of coal, as well as the more solid kinds of bitumen, like asphal- tum, are formed. But the lighter forms of bitumen, such as petroleum and naphtha, are derived mainly, if not entirely, from the partial decomposition of animal tissues. These, ic is well known, decay much more readily than vegetable tissues ; and the water of an or- dinary marsh or lake contains sufficient oxygen for their complete and rapid decomposition. In the deeper parts of the ocean, however, the conditions are very different, for recent researches have shown, con- trary to the old idea, that the deep sea holds an abun- AQUEOUS AGENCIES. 25 dant fauna. All grades of animal life, from the highest to the lowest, have need of a constant supply of oxy- gen. On the land vegetation is constantly returning to the air the oxygen consumed by animals, but in the abysses of the ocean vegetable life is scarce or wanting ; and hence it must result that over these greater than continental areas countless myriads of animals are living habitually on short rations of oxygen, and in water well charged with carbon dioxide, the product of animal respiration. As a consequence, when these animals die their tissues do not find the oxygen essential for their perfect decomposition, and in the course of time become buried, in a half-decayed state, in the ever- increasing sediments of the ocean-floor. It is important to observe that an abundance of or- ganic matter decaying under water is not the only con- dition essential to the formation of beds of coal and bitumen ; for this condition is realized in the luxuriant growth of sea-weeds fringing the coast in every quarter of the globe ; and yet coals and bitumens are rarely of sea-shore origin. These organic products, even under the most favorable circumstances, accumulate with extreme slowness ; far more slowly, as a rule, than the ordinary mechanical sediments, like sand and clay, with which they are mixed, and in which they are often completely lost. Consequently, although the deposi- tion of the carbonized remains of plants and animals is taking place in nearly all seas, lakes, and marshes, it is only in those places where there is little or no mechani- cal sediment that they can predominate so as to build up beds pure enough to be called coal or bitumen. In all other cases we get merely more or less carbonaceous 26 DYNAMICAL GEOLOGY. sand or clay. Now these especially favorable locali- ties will manifestly not be often found along the sea- shore, where we have strewn the sand and clay brought down by rivers or washed off the land directly by the ever-active surf; but they must exist in the central portions of the ocean, where there is almost no mechan- ical sediment and yet an abundance of life, and in swamps and marshes, where there is scarcely sufficient water to cover the vegetation, and no waves or currents to wash down the soil from the surrounding hills. FORMATION OF IRON-ORES. The iron-ores are another class of rocks which are formed only through the agency of organic matter. Iron is an abundant and wide-spread element in the earth's crust, and, but for the intervention of life, we might say that, while there is iron everywhere, there is not much of it in any one place, since it is originally very thinly diffused. All rocks and soils contain iron, but it is mainly in the form of the peroxide, in which state it is entirely insol- uble, and hence cannot be soaked out of the soil by the rain-water and concentrated by the evaporation of the water at lower levels in ponds and marshes, as a soluble substance like salt would be. If carried off with the sand and clay, by the mechanical action of water, it remains uniformly mixed with them, and there is no tendency to its separation and concentration so as to form a true iron-ore. But what water cannot do alone is accomplished very readily when the water is aided by decaying organic matter, which is always hungry for oxygen, being, in the language of the chemist, a powerful reducing agent. The soil, in most places, has a superficial stratum of AQUEOUS AGENCIES. 27 vegetable mould or half-decayed vegetation. The rain- water percolates through this and dissolves more or less of the organic matter, which is thus carried down into the sand and clay beneath and brought in contact with the ferric oxide, from which it takes a certain proportion of oxygen, reducing the ferric to the ferrous oxide. At the same time the vegetation is burned up by the oxygen thus obtained, forming carbon dioxide, which immediately combines with the ferrous oxide, forming carbonate of iron, which, being soluble under these conditions, is carried along by the water as it gradually finds its way by subterranean drainage to the bottom of the valley and emerges in a swamp or marsh. Here one of two things will happen : If the marsh contains little or no decaying vegetation, then as soon as the ferrous carbonate brought down from the hills is exposed to the air it is decomposed, the carbon dioxide escapes, and the iron, taking on oxygen from the air, returns to its original ferric condition ; and being then quite insoluble, it is deposited as a loose, porous, earthy mass, commonly known as bog-iron- ore, which becomes gradually more solid and finally even crystalline through the subsequent action of heat and pressure. When first deposited, the ferric oxide is combined with water or hydrated, and is then known as limonite (specimen No. 1 2) ; at a later period the water is expelled, and we call the ore hematite (specimen No. 13) ; and at a still later age it loses part of its oxygen, becomes magnetic and more crystalline, and is then known as magnetite (specimen No. 14). Thus it is seen that the iron-ores, as we pass from bog-limonite to magnetite, form a natural 28 DYNAMICAL GEOLOGY. series similar to and parallel with that afforded by the coals as we pass from peat to graphite. If the drainage from the hills is into a marsh contain- ing an abundance of decaying vegetation, i.e., if peat is forming there, the ferrous carbonate, in the presence of the more greedy organic matter, will be unable to obtain oxygen from the air ; and as the evaporation of the water goes on, it will sooner or later become sat- urated with this salt, and the latter will be deposited. Here we find an explanation of a fact often observed by geologists, viz., that the carbonate iron-ores are usually associated with beds of coal, The formation of the iron-ores, like that of the coals and bitumens, is a slow process ; and the ores, like the coals, etc., will be pure only where there is a complete absence of mechanical sediment, a condition that is realized most nearly in marshes. FORMATION OF LIMESTONE, DIATOMACEOUS EARTH, ETC. Marine animals take from the sea- water certain min- eral substances, especially silica and carbonate of calcium, to form their skeletons. Silica is used only by the lowest organisms, such as Radiolaria, Sponges, and the minute unicellular plants, Diatoms. The prin- cipal animals secreting carbonate of calcium are Corals and Mollusks. These hard parts of the organisms remain undissolved after death ; and over portions of the ocean-floor where there is but little of other kinds of sediment they form the main part of the deposits, and in the course of ages build up very extensive for- mations which we call diatomaceous earth or tripolite, if the organisms are siliceous, or limestone if they are calcareous. A very satisfactory account of the for- AQUEOUS AGENCIES. 29 mation of limestone on a stupendous scale by the polyps in coral reefs and islands is contained in No. IV. of this series of guides. The rocks here considered may be, and, as we have already seen, sometimes are, deposited in a purely chemical way, without the aid of life ; and it is impor- tant to observe that in no case do the organisms make the silica and carbonate of calcium of their skeletons, but they simply appropriate and reduce to the solid state what exists ready made in solution in the sea-water. These minerals, and others, as we know, are produced by the decomposition of the rocks of the land, and are being constantly carried into the sea by rivers ; and, if there were no animals in the sea, these processes would still go on until the sea-water became saturated with these substances, when their precipitation as limestone, etc., would necessarily follow. Hence it is clear that all the animals do is to effect the precipitation of certain minerals somewhat sooner than it would otherwise occur ; so that from a geological standpoint the differences between chemical and organic deposition are not great. This section of our subject may be summarized as follows : Animals and plants contribute to the forma- tion of rocks in three distinct ways : i. During their growth they deoxidize carbon dioxide and water, and reduce to the solid state in their tissues carbon and the permanent gases oxygen, hydrogen, and nitrogen ; and after death, through the accumulation of the half-decayed tissues in favorable localities, marshes, etc., these elements are added to the solid crust of the earth in the form of coal and bitumen. 3 o DYNAMICAL GEOLOGY. 2. During the decomposition, i.e., oxidation, of the organic tissues, the iron existing everywhere in the soil is partially deoxidized, and, being thus rendered soluble, is removed by rain-water and concentrated in low places, forming beds of iron-ore. 3. Through the agency of marine organisms, certain mineral substances are being constantly removed from the sea-water and deposited upon the ocean floor, forming various calcareous and siliceous rocks. I now bring our study of the aqueous or superficial agencies to a conclusion by noting once more that the great geological results accomplished by air, water, and organic matter or life are : ( i ) Erosion, or the wearing away of the surface of the land; and (2) Deposition, or the formation from the debris of the eroded land of two great classes of stratified rocks, the mechan- ically formed or fragmental rocks, and the chemically and organically formed rocks. II. IGNEOUS AGENCIES. We pass next to a very brief consideration of opera- tions that originate below the earth's surface. The records of deep mines and artesian wells show that the temperature of the ground always increases downwards from the surface ; and the much higher temperatures of hot springs and volcanoes show that the heat continues to increase to a great depth, and is not a merely super- ficial phenomenon. The observed rate of increase is not uniform, but it seldom varies far from the average, which is about i Fahr. per 53 feet of vertical descent, or, in round numbers, 100 per mile. This rate, if IGNEOUS AGENCIES. 31 continued, would give a very high temperature at points only a few miles below the surface ; and until within a few years the idea was generally accepted by geologists that the increase of temperature is sensibly uniform for an indefinite distance downward ; that in the cen- tral regions of the earth the temperature is far higher than anything we can conceive, and that everywhere below a depth of 20 to 40 miles the temperature is above the fusing-point of all rocks ; and hence that the earth is an incandescent liquid globe covered by a thin shell or crust of cold, solid rock. Our limited space will not permit us to enter into a discussion of the condition of the earth's interior, and I will merely point out in a few sentences the posi- tion occupied by geologists at the present time. The reasoning of Thompson has shown that the tempera- ture cannot increase downward at a uniform rate, but at a constantly and rapidly diminishing rate ; and that everywhere below a depth of 300 miles the tem- perature is probably sensibly the same, and nowhere, probably, above 8000 to 10,000 Fahr. Unlike water, all rocks contract on solidifying and expand on melting, and consequently the high pres- sures to which they are subjected in the earth's inte- rior 10,000,000 to 20,000,000 pounds per square inch must raise their fusing-points enormously, and the probabilities are that they are solid, in spite of the high temperature. But Thompson and Darwin have shown us farther that the phenomena of the oceanic tides could not be what they are known to be if the earth were any less rigid than a globe of solid steel ; while Hopkins has proved that the astronomical phe- 32 DYNAMICAL GEOLOGY. nomena of precession and nutation could not be what they are if the earth's crust were less than 800 or 1000 miles thick. Putting these considerations together, geologists are almost universally agreed that, while the earth has an incandescent interior, it is still continu- ously solid from centre to circumference, with the exception of a thin plastic stratum at a depth not exceeding 40 or 50 miles, which forms the seat of vol- canic action. The earth is not only a very hot body, but it is rotat- ing through almost absolutely cold space, and there- fore must be a cooling body. But, except at the very beginning of the cooling, the loss of heat has gone on almost entirely from the interior; and since cooling means contraction, the heated interior must be con- stantly tending to shrink away from the cold external crust. Of course no actual separation between the crust and interior or nucleus can take place, but there is no doubt that the crust is left unsupported to a certain extent, and it must then behave like an arch with a radius of 4000 miles, and the result is an enormous horizontal or tangential pressure. This lateral pressure in the earth's crust is one of the most important and most generally accepted facts in geology, and lies at the bottom of many geological the- ories. According to what seems to me to be the most probable theory of the origin of continents and ocean- basins, they are broad upward and downward bendings or arches into which the crust is thrown by the tan- gential pressure. Finally, the strain becomes great enough to crush the crust along those lines where it is IGNEOUS AGENCIES. 33 weakest. When the crust is thus mashed up by hori- zontal pressure, a mountain range is formed, the crust becomes enormously thicker, and a weak place becomes a strong one. During the formation of mountains the stratified rocks, which were originally horizontal, are thrown into folds or arches, and tipped up at all possible angles ; they are fractured and faults produced ; and by the immense pressure the structure known as slaty cleavage is developed. In fact, a vast amount and variety of structures are produced during the growth of a moun- tain range. These great earth-movements are not always per- fectly smooth and steady, but they are accompanied by slipping or crushing now and then ; and, as a result of the shock thus produced, a swift vibratory movement or jar, which we know as an earthquake, runs through the earth's crust. Extensive fissures are also formed, opening down to the regions where the rocks are liquid or plastic, and through these the melted rocks flow up to or toward the surface. That portion which flows out on the surface builds up a volcanic cone, while that which cools and solidifies below the surface, in the fissures, forms dikes. Thus among the igneous or eruptive rocks we have two great classes, the dike rocks and the volcanic rocks. It is important to observe that all these subterranean operations the formation of continents, of mountain- ranges with all their attendant phenomena of folds, faults and cleavage, and every form and phase of earth- quake and volcanic activity depend upon or originate 34 DYNAMICAL GEOLOGY. in the interior heat of the earth. And over against the superficial or aqueous agencies, originating in the solar heat and producing the stratified or sedimentary rocks, we set the subterranean or igneous agencies originating in the central heat, and producing the unstratified or eruptive rocks. STRUCTURAL GEOLOGY. IN geology, just as in biology, there are two ways of studying structure, the small way and the large way. In the case of an organism, we may select a single part or organ, and, disregarding its external form and rela- tions to other parts, observe its composition and minute structure, the various forms and arrangements of the cells, etc. This is histology, and it is the complement of that larger method of studying structure which is ordinarily understood by anatomy. The divisions of structural geology corresponding to histology and anatomy are lithology and petrology. Lithology is an in-door science ; we use the microscope largely, and work with hand specimens or thin sections of the rocks, observing the composition and those small structural features which go under the general name of texture. In petrology, on the other hand, we consider the larger kinds of rock-structure, such as stratification, jointing, folds, faults, cleavage, etc. ; and it is essen- tially an out-door science, since to study it to the best advantage we must have, not hand specimens, but ledges, cliffs, rail way- cuttings, gorges, and moun- tains. 36 STRUCTURAL GEOLOGY. LITHOLOGY. A rock is any mineral, or mixture of minerals, oc- curring in masses of considerable size. This distinction of size is the only one that can be made between rocks and minerals, and that is very indefinite. A rock, whether composed of one mineral or several, is always an aggregate ; and therefore no single crystal or min- eral-grain can properly be called a rock. Before proceeding to study particularly the various kinds of rocks, a little more preliminary work should be done. As already intimated, the more important characteristics of rocks may be grouped under two general heads, composition and texture. Composition of Rocks. Rocks are properly defined as large masses or ag- gregates of mineral matter, consisting in some cases of one and in other cases of several mineral species. Hence it is clear that the composition of rocks is of two kinds : chemical and mineralogical ; for the va- rious chemical elements are first combined to form minerals, and then the minerals are combined to form rocks. Of course those minerals and elements which can be described as principal or important rock-constituents must be the common minerals and elements. Now it is a very important and convenient fact that although chemists recognize about sixty-five elementary sub- stances, and these are combined to form nearly one thousand mineral species, yet both the common ele- ments and the common minerals are few in number. LITHOLOGY. 37 So that, although it is very desirable and even necessary for the student of lithology to know some- thing of chemistry and mineralogy, it by no means fol- lows that he or she must be master of those sciences. A knowledge of the chemical and physical character- istics of a few common minerals is all that is absolutely essential, though it may be added that an excess of wisdom in these directions is no disadvantage. Chemical Composition of Rocks. The elementary substances of which rocks are chiefly composed, which make up the main mass of the earth so far as we are acquainted with it, number only fourteen : Non-Metallic or Acidic Elements. Oxygen, silicon, carbon, sulphur, chlorine, phosphorus, and fluorine. Metallic or Basic Elements. Aluminum, magne- sium, calcium, iron, sodium, potassium, and hydrogen. The elements are named in each group in about the order of their relative abundance ; and to give some idea of the enormous differences in this respect it may be stated that two of the elements oxygen and sili- con form more than half of the earth's crust. Silicon, calcium, and fluorine, although exceedingly abundant, are also very difficult to obtain in the free or uncombined state, and specimens large enough to ex- hibit to a class would be very expensive. With these exceptions, however, examples of these common rock- forming elements are easily obtained. My purpose in calling attention to this point is sim- ply to suggest that the proper way to begin the study ef minerals and rocks with children is to first familiarize 38 STRUCTURAL GEOLOGY. them with the elements of which they are composed. The most important thing to be known about any min- eral is its chemical composition ; and when a child is told that a mineral corundum, for example is com- posed of oxygen and aluminum, he should have a dis- tinct conception of the properties of each of those elements, for otherwise corundum is for him a mere compound of names. It is very important, too, if the pupil has not already studied chemistry, that he should be led to some com- prehension of the nature of chemical union and of the difference between a chemical compound and a me- chanical mixture. For this purpose a few simple ex- periments (the details of which would be out of place here) with the more common and familiar elements will be sufficient. Mrs. Richard's " First Lessons in Minerals " should be introduced here. Mineralogical Composition of Rocks. The fourteen elements named above are combined to form about fifty minerals with which the student of geology should be acquainted ; but not more than one- half of these are of the first importance. It is desired to lay especial emphasis upon the importance of a per- fect familiarity with these few common minerals. There is nothing else in the whole range of geology so easily acquired which is at the same time so valuable ; for it is entirely impossible to comprehend the defini- tions of rocks, or to recognize rocks certainly and sci- entifically, unless we are acquainted with their con- stituent minerals. With one or two exceptions, these common rock- forming minerals may be easily distinguished by their LIT HO LOGY. 39 physical characters alone, so that their certain recogni- tion is a matter of the simplest observation, and entirely within the capacity of young children. Furthermore, being common, specimens of these minerals are very easily obtained, so that there is no reason why teachers should not here adopt the best method and place a specimen of each mineral in the hands of each pupil. Typical examples, large enough to show the character- istics well, ought not to cost, on the average, over two cents apiece. A MINERAL is an inorganic body having theoretically a definite chemical composition, and usually a regular geometric form. THE PRINCIPAL CHARACTERISTICS OF MINERALS. These may be grouped under the following general heads : (i) Composition, (2) Crystalline form, (3) Hardness, (4) Specific gravity, (5) Lustre, (6) Color and Streak. i. Composition. This, according to the definition of a mineral, ought to be definite, and expressible by a chemical formula. When it is not so, we usually con- sider that the mineral is partially decomposed, or that we are dealing with a mixture of minerals. It is well to impress upon the mind of the pupil the important fact that the more fundamental properties of the ele- ments, such as specific gravity and lustre, are not lost when they combine, but may be traced in the com- pounds. In other words, the properties of minerals are, in a very large degree, the average of the proper- ties of the elements of which they are composed ; min- erals in which heavy metallic elements predominate being heavy and metallic, and vice versa. 40 STRUCTURAL GEOLOGY. To fully appreciate this point it is only necessary to compare a mineral like galenite a common ore of lead, and containing nearly 87 per cent, of that heavy metal; or hematite (specimen 13), containing 70 per cent, of another heavy metal, iron with quartz (specimen 15), which is composed in nearly equal parts of oxygen and silicon, two typical non- metallic elements. Many minerals contain water, i.e., are hydrated. Now water, whether we consider the liquid or solid state, is one of the lightest and softest of mineral constituents ; and it is a very impor- tant fact that hydrated minerals are invariably lighter and usually softer than anhydrous species of otherwise similar composition. Other striking illustrations of this principle will be pointed out in the descriptions of the minerals which follow. 2. Crystalline form. A crystal is bounded by plane surfaces symmetrically arranged with reference to cer- tain imaginary lines passing through its centre and called axes. Crystals of the same species are always constant in the angles between like planes, while simi- lar angles usually vary in different species ; so that each species has its own peculiar form. " Besides external symmetry of form, crystallization produces also regularity of internal structure, and often of fracture. This regularity of fracture, or tendency to break or cleave along certain planes, is called cleavage. The surface afforded by cleavage is often smooth and brilliant (see specimens 17, 18, and 21), and is always parallel with some external plane of the crystal. It should be understood that the cleavage lamellae are not in any sense present before they are made to ap- pear by fracture." (Dana.) LITHOLOGY. 41 Crystals are arranged in six systems, based upon the number and relations of the axes, as follows : Isometric System. Three equal axes crossing at right angles. Example, cube. Tetragonal System. Two axes equal, third un- equal, all crossing at right angles. Example, square prism. Orthorhombic System. Three unequal axes, but intersections all at right angles. Example, rhombic prism. Monoclinic System. Three unequal axes, one intersection oblique. Example, oblique rhombic prism. Triclinic System. Three unequal axes, all cross- ing obliquely. Example, oblique rhomboidal prism. Hexagonal System. Three equal axes lying in one plane and intersecting at angles of 60, and a fourth axis crossing each of these at right angles and longer or shorter. Example, hexagonal prism. By the truncation and bevelment of the angles and edges of these fundamental forms a vast variety of sec- ondary forms are produced. The limits of the guide will not permit us to follow this topic farther ; but it may be added that for the proper elucidation of even the simpler crystalline forms the teacher should 'be provided with a set of wooden crystal models and Dana's " Text-Book of Mineralogy." The crystallization of a mineral may be manifested in two ways : first, by the regularity of its internal struc- ture -or molecular arrangement, as shown by cleavage and the polarization of transmitted light ; and, second, by the regularity of external form which follows, undef 42 STRUCTURAL GEOLOGY. favorable conditions, as a necessary consequence of symmetry in the arrangement of the molecules. When a mineral is entirely devoid of crystalline structure, both externally and internally, it is said to be amorphous. Perfect and distinct crystals are the rare exception, most mineral specimens being simply aggregates of im- perfect crystals. In such cases, and when the min- eral is amorphous, the structure of the mass may be: Columnar or fibrous. Lamellar, foliaceous, or micaceous. Granular. When the grains or crystalline par- ticles are invisible to the naked eye the mineral is called impalpable, compact, or massive. And the external form of the mass may be : Botryoidal, having grape-like surfaces. Stalactitic, forming stalactites or pendant columns. Amygdaloidal or Concretionary, forming separate globular masses in the enclosing rock. Dendritic, branching or arborescent. 3. Hardness. By the hardness of a mineral we mean the resistance which it offers to abrasion. But hardness is a purely relative term, calcite, for example, being hard compared with talc, but very soft com- pared with quartz. Hence mineralogists have found it necessary to select certain minerals to be used as a standard of comparison for all others, and known as the scale of hardness. These are arranged at nearly equal intervals all the way from the softest mineral to the hardest, as follows : LITHOLOGY. 43 Scale of Hardness. (1) Talc. . (4) Fluorite. (8) Topaz or Beryl (2) Gypsum. (5) Apatite. (9) Corundum. (3) Calcite. (6) Orthoclase. (10) Diamond. (7) Quartz. If a mineral scratches calcite and is scratched by fluorite, we say its hardness is between 3 and 4, per- haps 3.5 ; if it neither scratches nor is scratched by orthoclase, its hardness is 6 ; and so on. There are very few minerals harder than quartz, and hence the first seven members of the scale are sufficient for all ordinary purposes ; and these are all included in the series of specimens accompanying this Guide. Although it is desirable to be acquainted with the scale of hardness, and to understand how to use it, still the student will learn, after a little practice, that almost as good results may be obtained much more conven- iently by the use of his thumb-nail and a good knife- blade or file. Talc and gypsum are easily scratched with the nail ; calcite and fluorite yield easily to the knife or file, apatite with more difficulty ; while ortho- clase is near the limit of the hardness of ordinary steel, and quartz is entirely beyond it. 4. Specific Gravity. The specific gravity of a mineral, by which we mean its weight as compared with the weight of an equal volume of water, is deter- mined by weighing it first in air and then in water, and dividing the weight in air by the difference of the two weights. Minerals exhibit a wide range in specific gravity ; from petroleum, which floats on water, to gold, 44 STRUCTURAL GEOLOGY. which is nearly twenty times heavier than water. Al- though this is one of the most important properties of minerals, yet, being more difficult to measure than hardness, it is less valuable as an aid in distinguishing species. One can with practice, however, estimate the density of a mineral pretty closely by lifting it in the hand. 5 . Lustre. Of all the properties of minerals de- pending on their relations to light the most important is lustre, by which we mean the quality of the light re- flected by a mineral as determined by the character or minute structure of its surface. Two kinds of lustre, the metallic and vitreous, are of especial importance ; in fact all other kinds are merely varieties of these. The metallic lustre is the lustre of all true metals, as copper and tin, and characterizes nearly all minerals in which metallic elements predominate. The vitreous lustre is best exemplified in glass, but belongs to most minerals composed chiefly of non- metallic elements. Metallic minerals are always opaque, but vitreous min- erals are often transparent. Other kinds of lustre are the adamantine (the lustre of diamond), resinous, pearly, and silky. When a mineral has no lustre, like chalk, it is said to be dull. It should be made clear to children that lustre and color are entirely distinct and independent. Thus, iron, copper, gold, silver, and lead are all metallic ; while white or colorless quartz, black tourmaline, green beryl, red garnet, etc., are all vitreous. Generally speaking, any color may occur with any lustre. 6. Color and Streak. The colors of minerals are of two kinds, essential and non-essential. By the LITHOLOGY. 45 essential color in any case we mean the color of the mineral itself in its purest state. The non-essential colors, on the other hand, are chiefly the colors of the impurities contained in the minerals. Metallic minerals, which are always opaque, usually have essential colors ; but vitreous minerals, which are always more or less transparent, often have non-essen- tial colors. The explanation is this : In opaque min- erals we can only see the impurities immediately on the surface, and these are, as a rule, not enough to affect its color ; but in diaphanous minerals we look into the specimen and see impurities below the surface, and thus bring into view, in many cases, sufficient impurity so that its color drowns that of the mineral. To prove this we have only to take any mineral (ser- pentine is a good example in our series) having a non- essential color, and make it opaque by pulverizing it or abrading its surface, when the non-essential color, the color of the impurity, immediately disappears ; just as water, yellow with suspended clay, becomes white when whipped into foam, and thus made opaque. What we understand by the streak of a mineral is its essential color, the color of its powder ; and it is so called because the powder is most readily observed by scratching the surface of the mineral, and thereby pul- verizing a minute portion of it. The streak and hard- ness are thus determined at the same time. The streak of soft minerals is easily determined by rubbing them on any white surface of suitable hardness, as paper, porcelain, or Arkansas stone. ESSENTIAL AND ACCESSORY MINERALS. Lithologists, regarding minerals as constituents of rocks, divide them 46 STRUCTURAL GEOLOGY. into two great classes : the essential and the accessory The essential constituents of a rock are those mineral* which are essential to the definition of the rock. For example, we cannot properly define granite without naming quartz and orthoclase ; hence these are essen- tial constituents of granite ; and if either of these min- erals were removed from granite it would not be granite any longer, but some other rock. But other minerals, like tourmaline and garnet, may be indiffer- ently present or absent ; it is granite still ; hence they are merely accidental or accessory constituents. They determine the different varieties of granite, while the essential minerals make the species. This classification, of course, is not absolute, for in many cases the same mineral forms an essential con- stituent of one rock and an accessory constituent of another. Thus, quartz is essential in granite, but ac- cessory in diorite. PRINCIPAL MINERALS CONSTITUTING ROCKS. Having studied in a general way the more important charac- teristics of minerals, brief descriptions of the chief rock-forming species are next in order. We will notice first and principally those minerals occurring chiefly as essential constituents of rocks. i . Graphite. Essentially pure carbon, though often mixed with a little iron oxide. Crystallizes in hexago- nal system, but usually foliated, granular, or massive. Hardness, 1-2, being easily scratched with the nail. Sp. gr., 2.1-2.3. Lustre, metallic ; an exception to the rule that acidic elements have non-metallic or vitreous lustres. Streak, black and shining (see pencil-mark on white paper). Color, iron-black. Slippery or greasy LITHOLOGY. 47 feel. Every black-lead pencil is a specimen of graphite. Specimen 9. The different kinds of mineral coal are, geologically, as we have seen, closely related to graphite, but they are such familiar substances that they need not be de- scribed here. 2. Halite (common salt). Chloride of sodium: chlorine, 60.7; sodium, 39.3; =100. Isometric sys- tem, usually forming cubes. Hardness, 2.5, a little harder than the nail. Sp. gr., 2.1-2.6. Lustre, vit- reous. Streak and color both white, and hence color is essential. Often transparent. Soluble ; taste, purely saline. In specific gravity and lustre it is a good ex- ample of a mineral in which an acidic element pre- dominates. Specimen n. 3. Limonite. Hydrous sesquioxide of iron : oxygen, 25 ; iron, 60 ; water, 15 ; = 100. Usually amorphous ; occurring in stalactitic and botryoidal forms, having a fibrous structure ; and also concretionary, massive, and earthy (yellow ochre) . Hardness, 5-5.5. Sp. gr., 3.6-4. Lustre, vitreous or silky, inclining to metallic, and some- times dull. Color, various shades of black, brown, and yellow. Streak, ochre-yellow ; hence color partly non- essential. Specimen 12. 4. Hematite. Sesquioxide of iron: oxygen, 30; iron, 70 ; = 100. Hexagonal system, in distinct crystals, but usually lamellar, granular, or compact, columnar, botryoidal, and stalactitic forms being common. Hard- ness, 5.5-6.5 ; good crystals are harder than steel. Sp. gr., 4.5-5.3. Lustre, metallic, sometimes dull. Color, iron-black, but red when earthy or pulverized (red ochre) . Streak, red, and color, therefore, mainly non 48 STRUCTURAL GEOLOGY. essential ; sometimes attracted by the magnet. Speci- men 13. Hematite has the same composition as limontte, minus the water ; and by comparing the hardness and specific gravity of these two minerals we see that they are a good illustration of the principle that hydrous minerals are softer and lighter than anhydrous minerals of analogous composition. Limonite and hematite are two great natural coloring agents, and almost all yel- low, brown, and red colors in rocks and soils are due to their presence. 5. Magnetite. Protoxide and sesquioxide of iron : oxygen, 27.6; iron, 72.4; = 100. Isometric system, usually in octahedrons or dodecahedrons. Most abun- dant variety is coarsely to finely granular, sometimes dendritic. Hardness, 5.5-6.5, same as hematite. Sp. gr., 4.9-5.2. Lustre, metallic. Color and streak, iron- black, and hence color essential. Strongly magnetic ; some specimens have distinct polarity, and are called loadstones. Specimen 14. The three iron-oxides just described limonite, hematite, and magnetite are all important ores of iron, and form a well-marked natural series. Thus limonite is never, hematite is usually, and magnetite is always, crystalline. Again, limonite with 60 per cent, of iron is never magnetic, hematite with 70 per cent, is sometimes magnetic, while magnetite with 72.4 per cent, is always magnetic. As the iron increases so does the magnetism. We have here an excellent illustration of the principle that the properties of the elements can be traced in those minerals in which they predominate. Iron is the only strongly magnetic LIT HO LOGY. 49 element : magnetite contains more iron than any other mineral, and it is the only strongly magnetic mineral. These three iron-ores are easily distinguished from each other by the color of their powders or streak, limonite yellow, hematite red, and magnetite black, and from all other common minerals by their high specific gravity. 6. Quartz. Oxide of silicon or silica : oxygen, 53.33 ; silicon, 46.67 ; = 100. Hexagonal system. The most common form is a hexagonal prism terminated by a hexagonal pyramid. Also coarsely and finely granular to perfectly compact, like flint ; the compact or cryptocrystalline varieties often assuming botryoidal, stalactitic, and concretionary forms. It has no cleav- age, but usually breaks with an irregular, conchoidal fracture like glass. Hardness, 7, being No. 7 of the scale ; scratches glass easily. Sp. gr., 2.5-2.8. Lustre, vitreous. Pure quartz is colorless or white, but by admixture of impurities it may be of almost any color. Streak always white or light colored. Quartz is usually, as in specimen 15, transparent and glassy, but may be translucent or opaque. It is almost absolutely infusible and insoluble. The varieties of quartz are very numerous, but they may be arranged in two great groups : 1. Pheno crystalline or vitreous varieties, including rock-crystal, amethyst, rose quartz, yellow quartz, smoky quartz, milky quartz, ferruginous quartz, etc. 2. Cryptocrystalline or compact varieties, including chalcedony, carnelian, agate, onyx, jasper, flint, chert, etc. Only three varieties, however, are of any great geological importance ; these are : common glassy quartz (spec. 15), flint (spec. 16), and chert. 50 STRUCTURAL GEOLOGY. Quartz is one of the most important constituents of the earth's crust, and it is also the hardest and most durable of all common minerals. We have already observed (p. 12) that it is entirely unaltered by exposure to the weather ; i.e., it cannot be decom- posed ; and, being very hard, the same mechanical wear which, assisted by more or less chemical decom- position, reduces softer minerals to an impalpable powder or clay, must leave the quartz chiefly in the form of sand and gravel. This agrees with our obser- vation that sand (spec. 30) , especially, is usually merely pulverized quartz. Opal is a mineral closely allied to quartz, and may be mentioned in this connection. It is of similar com- position, but contains from 5 to 20 per cent, of water, and is decidedly softer and lighter. Hardness, 5.5-6.5 ; sp. gr., 1.9-2.3. 7. Gypsum. Hydrous sulphate of calcium : sulphur trioxide (SO 3 ),46.5 ; lime (CaO), 32.6; water (H 2 O), 20.9 ; = 100. Monoclinic system. Often in distinct rhombic crystals ; also foliated, fibrous, and finely gran- ular. Hardness, 1.5-2 ; the hardest varieties being No. 2 of the scale of hardness. Sp. gr., 2.3. Lustre, pearly, vitreous, or dull. Color and streak usually white or gray. The principal varieties of gypsum are (a) sele- nite, which includes all distinctly crystallized or trans- parent gypsum; (b) fibrous gypsum or satin-spar ; (c) alabaster, fine-grained, light-colored, and translu- cent. Gypsum is easily distinguished from all com- mon minerals resembling it by its softness and the fact that it is not affected by acids'. Specimen 1 7, 8. Calcite. Carbonate of calcium : carbon dioxide LITHOLOGY. 51 (C O 2 ), 44 ; lime (CaO), 56 ; = 100. Hexagonal system, usually in rhombohedrons, scalenohedrons, or hexago- nal prisms. Cleavage rhombohedral and highly perfect (specimen 18). Also fibrous and compact to coarsely granular, in stalactitic, concretionary, and other forms. Hardness, 2.5-3.5, usually 3 (see scale of hardness). Sp. gr., 2.5-2.75. Lustre, vitreous. Color and streak usually white. Transparent crystallized calcite is known as Iceland-spar, and is remarkable for its strong double refraction. When finely fibrous it makes a satin-spar similar to gypsum. Geologically speaking, calcite is a mineral of the first importance, being the sole essential constituent of all limestones. It is readily distinguished from allied species by its perfect rhombohedral cleavage ; by its softness, being easily scratched with a knife ; and above all by its lively effer- vescence with acids, for it is the only common mineral effervescing freely with cold dilute acid. To apply this test it is only necessary to touch the specimen with a drop of dilute chlorohydric acid. The effervescence, of course, is due to the escape of the carbon dioxide in a gaseous form. Specimen 18. 9. Dolomite. Carbonate of calcium and magne- sium : carbonate of calcium (CaCO 3 ), 54.35 ; carbon- ate of magnesium (MgCO 3 ),45.65 ; =100. Hexagonal system, being nearly isomorphous with calcite. Rhom- bohedral cleavage perfect. Hardness, 3.5-4 ; sp. gr., 2.8-2.9, being harder and heavier than calcite. Lus- tre, color, and streak same as for calcite, from which it is most easily distinguished by its non -effervescence or only feeble effervescence with cold dilute acid, though effervescing freely with strong or hot acid. Spec. 19. 52 STRUCTURAL GEOLOGY. 10. Siderite. Carbonate of iron : carbon dioxide (C O 2 ), 37.9 ; protoxide of iron (Fe O), 62.1 ; = 100. Crystallization and cleavage essentially the same as for calcite and dolomite. Hardness, 3.5-4.5, and sp. gr., 3.7-3.9. Lustre, vitreous. Color, white, gray, and brown. Streak, white. With acid, siderite behaves like dolomite. It is distinguished from both calcite and dolomite by its high specific gravity, which is easily explained by the fact that it is largely composed of the heavy element, iron. With one exception, the fifteen minerals which we have yet to study belong to the class of silicates, which includes more than one-fourth of the known species of minerals, and, omitting quartz and calcite, all of the really important rock-constituents. The silicate min- erals may be very conveniently divided into two great groups, the basic and acidic. This is not a sharp division ; on the contrary, there is a perfectly gradual passage from one group to the other ; and yet this is, for geological purposes at least, a very natural classifi- cation. The dividing line falls in the neighborhood of 60 per cent, of silica ; i.e., all species containing this proportion of silica or less are classed as basic, since in them the basic elements predominate ; while those containing more than 60 per cent, of silica are classed as acidic, because their characteristics are determined chiefly by the acid element or silica. The principal bases occurring in the silicates, named in the order of their relative importance, are aluminum, magnesium, calcium, iron, sodium, and potassium ; and of these, magnesium, calcium, iron, and usually sodium, are especially characteristic of basic species. LITHOLOGY. 53 Iron is the heaviest base ; but all the bases, except sodium and potassium, are heavier than the acid silica ; consequently basic minerals must be, as a rule, heavier than acidic minerals. And since basic mine- rals contain more iron than acidic, they must be darker colored. In general, we say, dark, heavy silicates are basic, and vice versa. All this is of especial importance because in the rocks nature keeps these two classes separate in a great degree. 1 1 . Amphibole. Silicate of aluminum, magnesium, calcium, iron, and sodium. The bases occur in very various proportions, forming many varieties ; but the only variety of especial geological interest is horn- blende, the average percentage composition of which is as follows : silica (SiO 2 ), 50; alumina (A1 2 O 3 ), 10 ; magnesia (MgO), 18; lime (CaO), 12; iron oxide (FeO and Fe 2 O 3 ), 8; and soda (Na 2 O), 2; = 100. Monoclinic system : usually in rhombic or six-sided prisms which may be short and thick, but are more often acicular or bladed. Hardness, 5-6 ; sp. gr., 2.9-3.4. Lustre, vitreous ; color, black and greenish black ; and streak similar to color, but much paler. Compare with quartz, and observe the strong contrast in color possible with minerals having the same lustre. Specimen 20. 12. Pyroxene. Like amphibole, this species em- braces many varieties, and these exhibit a wide range in composition ; but of these augite alone is an impor- tant rock-constituent. Hence in lithology we practi- cally substitute for amphibole and pyroxene, horn- blende, and augite respectively. Augite is very similar in composition to hornblende, 54 STRUCTURAL GEOLOGY. but contains usually more lime and less alumina and alkali. Physically, too, these minerals are almost identical, crystallizing in the same system and in very similar forms, and agreeing in hardness, color, lustre, and streak. Augite is heavier than hornblende, sp. gr., 3.2-3.5. A certain prismatic angle, which in augite is 875 f , is i243o' in hornblende. Slender, bladed crystals are more common with hornblende than augite. When examined in thin sections with the polarizer, augite does not afford the phenomenon of dichroism, which is strongly marked in hornblende. However, as these minerals commonly occur in the rocks, in small and imperfect crystals, these distinctions can only be observed in thin sections under the microscope ; so that, as regards the naked eye, they are practically indistinguishable. It might appear at first that the distinction of mine- rals so nearly identical is not an important matter ; but nature has decreed otherwise. Augite and hornblende are typical examples of basic minerals ; but augite is, both in its composition and associations, the more basic of the two. In proof of this we need only to know that it very rarely occurs in the same rock with quartz, while hornblende is found very commonly in that association. Quartz in a rock means an excess of acid or silica, and almost necessarily implies the absence of highly basic minerals. In other words, hornblende is often, and augite very rarely, found in connection with acidic minerals ; and it is this difference of association chiefly that makes their distinction essential to the proper recognition of rocks ; while at the same time it affords an easy, though of course not absolutely cer- LITHOLOGY. 55 tain, means of determining whether the black constit- uent of any particular rock is hornblende or augite. Mica Family. Mica is not the name of a single mineral, but of a whole family of minerals, including some half-dozen species. Only two, however, mus- covite and biotite, are sufficiently abundant to engage our attention. These are complex, basic silicates of aluminum, magnesium, iron, potassium, and sodium. The crystallization of biotite is hexagonal, and of mus- covite monoclinic ; but both occur commonly in flat six-sided forms. Undoubtedly the most important and striking characteristic of the whole mica family is the remarkably perfect cleavage parallel with the basal planes of the crystals, and the wonderful thinness, and above all the elasticity, of the cleavage lamellae. The cleavage contrasts the micas with all other common minerals, and makes their certain identification one of the easiest things in lithology. The micas are soft minerals, the hardness ranging from 2 to 3, and being usually easily scratched with the nail. Sp. gr. varies from 2.7-3.1. Lustre, pearly; and streak, white or uncolored. The distinguishing features of muscovite and biotite are as follows : 13. Muscovite. Contains 47 per cent, of silica, 3 per cent, of sesquioxide of iron, and 10 per cent, of alkalies, chiefly potash ; and the characteristic colors are white, gray, and, more rarely, brown and yellow. Non-dichroic. Usually found in association with acidic minerals. The mica used in the arts is muscovite. Specimen 21. 14. Biotite. Contains only 36 per cent, of silica. 56 STRUCTURAL GEOLOGY. 20 per cent, of oxide of iron, and 17 per cent, of mag- nesia ; colors, deep black to green. Strongly dichroic. Commonly occurs with other basic minerals. Com- pare color with per cent, of iron. These differences are tabulated below : Muscovite = Biotite Acidic mica. Basic mica. Non-ferruginous mica. Ferruginous mica. Potash mica. Magnesian mica. White mica. Black mica. Non-dichroic mica. Dichroic mica. Feldspar Family. Like mica, feldspar is the name of a family of minerals ; and these are, geologically, the most important of all minerals. They are, above all others, the minerals of which rocks are made, and their abundance is well expressed in the name, feldspar being simply the German for field-spar, implying that it is the common spar or mineral of the fields. Chemically, the feldspars are silicates of aluminum and potassium, sodium or calcium. They crystallize in the monoclinic and triclinic systems ; and all pos- sess easy cleavage in two directions at right angles to each other, or nearly so. The general physical char- acters, including the cleavage, are well exhibited in the common species, orthoclase (specimen 22). In hardness the feldspars range from 5 to 7, being usually near 6, and almost always distinctly softer than quartz. Sp. gr. varies from 2.5-2.75 ; lustre, from vitreous to pearly; color, from white and gray to red, brown, green, etc., but usually light. Streak, always white ; rarely transparent. By exposure to the weather, feldspars gradually lose their alkalies and lime, become LITHOLOGY. 57 hydrated, and are changed to kaolin or common clay. A similar change takes place with the micas, augite, and hornblende ; but these species, being usually rich in iron, make clays which are much darker colored than those derived from feldspars. The fact that the feld- spars contain little or no iron undoubtedly explains their low specific gravity and light colors, as compared with the other minerals just named. The only com- mon minerals for which the feldspars are liable to be mistaken are quartz and the carbonates. From the latter they are easily distinguished by their supertor hardness and non-effervescence with acids ; and from the former, by possessing distinct cleavage, by being rarely transparent, by being somewhat softer, and by changing to clay on exposure to the weather. The feldspars of greatest geological interest are five in number, and may be classified chemically as fol- lows : Orthoclase, silicate of aluminum and potassium, or potash feldspar. A-lbite, . " " " sodium, or soda feldspar. Anorthite, " " " calcium, or lime feldspar. Oligoclase, " sodium, and calcium, or soda-lime feldspar. Labradorite, " " calcium, and sodium, or lime-soda feldspar. This appears like a complex arrangement, but it can be simplified. Orthoclase crystallizes in the monocli- nic system, and all the other feldspars in the triclinic system. With the exception of albite, which is a com- 58 STRUCTURAL GEOLOGY. paratively rare species, the triclinic feldspars all contain less silica than orthoclase ; i.e., are more basic. This is shown by the subjoined table giving the average com- position of each of the feldspars : SiO 2 A1 2 O 3 K 2 O Na 2 O CaO Total. Orthoclase, 65 18 17 = 100 Albite, 68 20 12 = 100 Oligoclase, 62 24 9 5 100 Labradorite, 53 30 4 13 = 100 Anorthite, 43 37 20 = 100 As we should naturally expect, the triclinic feldspars occur usually with other basic minerals, while the mono- clinic species, orthoclase, is acidic in its associations ; furthermore, the triclinic feldspars are often intimately associated with each other, but are rarely important constituents of rocks containing much orthoclase. In other words, the distinction of orthoclase from the basic or triclinic feldspars is important and comparatively easy, while the distinction of the different basic feld- spars from each other is both unimportant and difficult. Hence, in lithology, we find it best to put all these basic feldspars together, as if they were one species, under the name plagiodase, which refers to the oblique cleavage of all these feldspars, and contrasts with orthoclase, which refers to the right-angled cleavage of that species. This statement of the relations of the feldspars is, of course, beyond the comprehension of many children j and yet it should be understood by the teacher who would lead the children to any but the most superficial views. 15. Orthoclase. This is the common feldspar, and LITHOLOGY. 59 the most abundant of all minerals, being the principal constituent of granite, gneiss, and many other impor- tant rocks. The most characteristic colors are white, gray, pinkish, and flesh-red. Specimen 22. 1 6. Plagioclase. Like orthoclase, these species may be of almost any color ; yet these two great divi- sions of the feldspars are usually contrasted in this respect. Thus, bluish and grayish colors are most common with plagioclase, and white or reddish colors with orthoclase. Specimen 23 is labradorite, and, in every respect, a typical example of plagioclase. On certain faces and cleavage-surfaces of the plagioclase crystals we may often observe a series of straight parallel lines or bands which are often very fine, fifty to a hundred in a single crystal. These striae are due to the mode of twinning, and are of especial importance, since, while they are very characteristic of plagio- clase, they never occur in orthoclase. As stated, these twinning striae in plagioclase are often visible to the naked eye ; and when they are not, they may usually be revealed by examining a thin section under the microscope with polarized light. Plagioclase decays much more rapidly when exposed to the weather than orthoclase. This point becomes perfectly clear when we compare weathered ledges of diabase (or any trap- rock, see specimen 2) and granite; for plagioclase is the principal constituent of the former rock, and orthoclase of the latter. Hydrous Silicates. Many silicates contain water, and some of these are of great geological importance. What has been stated on a preceding page concerning the softness and lightness of hydrated minerals is espe- 60 STRUCTURAL GEOLOGY. cially applicable here ; for all the geologically important hydrous silicates are distinctly softer and lighter than anhydrous minerals of otherwise similar composition. Furthermore, they usually have an unctuous or slippery feel ; and, with one exception (kaolin) , are of a green or greenish color. 1 7. Kaolinite (Kaolin). Hydrous silicate of alum- inum : silica (SiO 2 ), 46; alumina (A1 2 O 3 ), 40; and water (H 2 O), 14; = 100. Orthorhombic system, in rhombic or hexagonal scales or plates, but usually earthy or clay-like. Hardness, 1-2.5 > S P- g r v 2.4-2.65. The pure mineral is white ; but it is usually colored by impurities, the principal of which are iron oxides and carbonaceous matter. Kaolin is the most abun- dant of all the hydrous silicates, and it is the basis and often the sole constituent of common clay, a very common mineral, but rarely pure. We have already (p. u) noticed the mode of origin of kaolin or clay. It results from the decomposition of various aluminous silicate minerals, especially the feldspars. Under the combined influence of carbon dioxide and moisture, feldspars give up their potassium, sodium, and calcium, and take on water, and the result is kaolin. This min- eral is believed to be always a decomposition product. Perhaps the best, or at least the most convenient, test for kaolin is the argillaceous odor, the odor of moist- ened clay. Specimen 24. 1 8. Talc. Hydrous silicate of magnesium: silica (SiO 2 ), 63 (acidic); magnesia (MgO), 32; water (H 2 O), 5 ; = 100. Orthorhombic system, but rarely in distinct crystals. Cleavage in one direction very per- fect the cleavage lamellae are flexible, but not elastic, LITHOLOGY. 6 1 as in mica. Hardness, i ; see scale. Sp. gr., 2.55-2.8. Lustre, pearly. Color, apple-green to white ; and streak, white. The feel is very smooth and greasy ; and, in connection with the color and foliation, affords the best means of distinguishing talc from allied minerals. Talc sometimes results from the alteration of augite, horn- blende, and other minerals, but it is not always nor usually an alteration product. 19. Serpentine. Hydrous silicate of magnesium : silica (Si O 2 ), 44 (basic) ; magnesia (Mg O), 44 ; water (H 2 O), 12 ; =100. Essentially amorphous. Hardness, 2.5-4; sp.gr., 2.5-2.65. Lustre, greasy, waxy, or earthy. Color, various shades of green and usually darker than talc, but streak always white. Feel, smooth, sometimes greasy. Distinguished from talc by its hardness, compactness, and darker green. Sometimes results from the alteration of olivine and other magnesian minerals, but usually we are to regard it as an original mineral. Specimen 25. 20. Chlorite. This is, properly, the name of a group of highly basic minerals of very variable compo- sition, but they are all essentially hydrous silicates of aluminum, magnesium, and iron ; and the average composition of the most abundant species, prochlorite, is as follows : silica (SiO 2 ), 30 ; alumina (A1 2 O 3 ), 18 ; magnesia (MgO), 15 ; protoxide of iron (FeO), 26 ; and water (H. 2 O), n ; =100. The chlorites crystallize in several different systems, but in all there is a highly perfect cleavage in one direction, giving, as in talc, a foliated structure with flexible but inelastic laminae. The cleavage scales, however, are sometimes minute, and the structure massive or granular. Hardness of 62 STRUCTURAL GEOLOGY. prochlorite, 1-2 ; between talc and serpentine. Sp.gr., 2.78-2.96. All the chlorites have a pearly to vitreous lustre. Color usually some shade of green ; in pro- chlorite a dark or blackish green, darker than serpentine, as that is darker than talc. Streak, a lighter, whitish green. Less unctuous than talc, but more so than ser- pentine. The chlorites are produced very commonly, but not generally, by the alteration of basic anhydrous silicates, like augite and hornblende. Specimen 26. 2 1 . Hydro-mica. This, too, is properly the name of a group of minerals ; but for geological purposes they may be regarded as one species. Taking a gen- eral view of the composition, these are simply the an- hydrous or ordinary micas, which we have already studied, with from 5 to 10 per cent, of water added. In crystallization and structure they are essentially mica-like. Although not distinctly softer than the common micas, they are lighter, always more unctuous and slippery, and usually of a greenish color. The micaceous structure with elastic laminae serves to dis- tinguish the hydro-micas from other hydrous silicates. 22. Glauconite* Hydrous silicate of aluminum, iron, and potassium : silica(SiO 2 ),5o ; alumina (A1 2 O 3 ), protoxide of iron (FeO), and potash (K 2 O), together, 41 ; and water (H 2 O),9 ; = 100. Amorphous, forming rounded and generally loose grains, which often have a microscopic organic nucleus. It is dull and earthy, like chalk, and always soft, green, and light, but not particularly unctuous. Glauconite is the principal, often the sole, constituent of the rock greensand, which occurs abundantly in the newer geological formations, and is now forming in the deep water of the Gulf of LITHOLOGY. 63 Mexico and along our Atlantic sea-board. Speci- men 27. This completes our list of minerals occurring chiefly as essential constituents of rocks ; and following are three of the more common and important minerals occurring chiefly as accessory, rarely as essential, rock- constituents. 23. Chrysolite (Oiivine). Silicate of magnesium and iron: silica (SiO 2 ), 41; magnesia (MgO), 51; protoxide of iron (Fe 2 O 3 ), 8 ; = 100. Orthorhombic system ; but usually in irregular glassy grains. Hard- ness, 6-7. Sp. gr., 3.3-3.5. Lustre, vitreous ; color, usually some shade of green ; and streak, white. Chrysolite sometimes closely resembles quartz, but its green color usually suffices to distinguish it. It is a common constituent of basalt and allied rocks. By absorption of water it is changed into serpentine and talc. See examples in specimen. 24. Garnet. The composition of this mineral is extremely variable ; but the most important variety is a basic silicate of aluminum and iron : silica (SiO 2 ), 37 ; alumina (A1 2 O 3 ), 20 ; and protoxide of iron (FeO),43 '> = 100. Isometric system, usually in distinct crystals, twelve-sided (dodecahedrons) and twenty-four-sided (trapezohedrons) forms being most common. Hard- ness, 6.5-7.5 ; average as hard as quartz. Sp. gr., 3.15-4.3 ; compare with the high percentage of iron. Lustre, vitreous ; colors, various, usually some shade of red or brown ; and streak, white. Some varieties con- tain iron enough to make them magnetic. Garnet is easily distinguished by its form, color, and hardness from all other minerals. It is a common but not an I 64 STRUCTURAL GEOLOGY. abundant mineral, occurring most frequently in gneiss, mica schist, and other stratified crystalline rocks. See examples in specimen. 25. Pyrite. Sulphide of iron : sulphur, 53.3 ; iron, 46.7; = 100. Isometric system, occurring usually in distinct crystals, the cube and the twelve-sided form known as the pyritohedron being the most common. Hardness, 6-6.5, striking fire with steel. Sp. gr., 4.8- 5.2 ; heavy because rich in iron. Lustre, metallic and splendent. Color, pale, brass-yellow, and streak, greenish or brownish. Pyrite is sometimes mistaken for gold, but it is not malleable ; while its color, hard- ness, and specific gravity, combined, easily distinguish it from all common minerals. As an accessory rock- constituent, pyrite occurs usually in isolated cubes or pyritohedrons. Specimen 10. Textures of Rocks. Texture is a general name for those smaller struc- tural features of rocks which can be studied in hand specimens, and which depend upon Reforms and sizes of the constituent particles of the rocks, and the ways in which these are united. By "constituent particles" we mean, not the atoms or molecules of matter composing the rocks, but the pebbles in conglomerate, grains of sand in sandstone, crystals of quartz, feldspar, and mica in granite, etc. The four most important textures are : (\)Fragmental texture. The rock is composed of mere irregular, angular, or rounded, but visible, frag- ments. Examples : sand, sandstone, gravel, conglom- erate, etc. Specimens 30, 31, 28, 29. LITHOLOGY. 65 (2) Crystalline texture. The constituent particles are chiefly, at least, distinctly crystalline, as shown either by external form, or cleavage, or both. Exam- ples : granite, diabase, gneiss, etc. Specimens 45, i, 41. (3). Compact texture. The constituent particles are indistinguishable by the naked eye, but become visi- ble under the microscope, appearing as separate crystal- line grains or as irregular fragments. In other words, if, in the case of either the granular or crystalline textures, we conceive the particles to become microscopically small, then we have the compact texture. Examples : clay, slate, many limestones, basalt, etc. Specimens 34, 35, 39- (4 ) Vitreous texture. The texture of glass, in which the constituent particles are absolutely invisible even with the highest powers of the microscope, and may be nothing more than the molecules of the substance, which thus, so far as our powers of observation are concerned, presents a perfectly continuous surface. Examples : obsidian, glassy quartz, and some kinds of coal. Specimens 47, 15. These four textures, which, it will be observed, are determined by the forms and sizes of the constituent particles, may be called the primary textures, because every rock must possess one of them. We cannot con- ceive of a rock which is neither fragmental, crystalline, compact, nor vitreous. But in addition to one of the primary textures, a rock may or may not have one or more of what may be called secondary textures. These are determined by the way in which the particles are united, the mode or pattern of the arrangement, etc. 66 STRUCTURAL GEOLOGY. Following are definitions of the principal secondary textures : 1 i ) Laminated texture. This exists where the par- ticles are arranged in thin, parallel layers, which may be marked simply by planes of division, or the alter- nate layers may be composed of particles differing in composition, form, size, or color, etc. Among the laminated textures we thus distinguish : (a) the banded texture, where the layers are contrasted in color, tex- ture, or composition, but cohere, so that there is no cleavage or easy splitting parallel with the stratification ; and (b) the schistose or shaly texture, where such fissility or stratification-cleavage exists. If a fragmental, com- pact, or vitreous rock is fissile, we use the term shaly; but a fissile, crystalline rock is described as schistose. The banded texture may occur with the fragmental, banded sandstones, etc. ; with the crystalline, many gneisses, etc. (specimen 41); with the compact, many slates, limestones, felsites, etc. (specimens 34, 42); with the vitreous, banded obsidian, furnace slags, and some coal. The schistose texture may occur with the crystalline, mica schist, etc. (specimen 43) ; and the shaly texture with the compact and fragmental, but rarely with the vitreous. (2) Porphyritic texture. We have this texture when separate and distinct crystals of any mineral, but most commonly of feldspar, are enclosed in a relatively fine-grained base or matrix, which may be either crystal- line, compact, or vitreous, but rarely fragmental. Speci- mens 5, 6, 7 are examples of the porphyritic compact texture. LIT HO LOGY. 67 (3) Concretionary texture. When one or more constituents of a rock have the form, in whole or in part, not of distinct angular crystals, but of rounded concre- tions, the texture is described as concretionary, the concretions taking the place in this texture of the iso- lated crystals in the porphyritic texture. This texture occurs in connection with all the primary textures, but the most familiar example is oolitic limestone. (4) Vesicular texture. A rock has this texture when it contains numerous small cavities or vesicles. These are most commonly produced by the expansion of steam and other vapors when the rock is in a plastic state ; and hence the vesicular texture is found chiefly in volcanic rocks. Except rarely, it is associated only with the compact texture, ordinary stony lavas (spec- imen 49) ; and with the vitreous texture, pumice (specimen 48). (5 ) Amygdaloidal texture. In the course of time the vesicles of common lava are often filled with various minerals deposited by infiltrating waters, giving rise to the amygdaloidal texture, from the Latin amygdalum, an almond, in allusion to a common form of the vesicles, or amygdules, as they are called, after being filled. The amygdaloidal texture is thus necessarily preceded by the vesicular, and is limited to the same classes of rocks. Specimen 50. Besides the foregoing, there are many minor sec- ondary textures. The rocks known as tufas have what may be called the tufaceous texture. Then we have kinds of texture depending on the strength of the union of the particles, as strong, weak, friable, earthy, etc. 68 STRUCTURAL GEOLOGY. Classification of Rocks. Having finished our preliminary observations on the characteristics of rocks, we are now about ready to begin a systematic study of the rocks themselves ; but it is needful first to say a few words about the classifi- cation of rocks, since upon this depends not only the order in which we shall take the rocks up, but also the ideas that will be imparted concerning their relations and affinities. The classifications which have been proposed at different times are almost as numerous as She rocks themselves. Some of these are confessedly, and even designedly, artificial, as when we classify stones according to their uses in the arts, etc. But we want something more scientific, a natural classification ; that is, one based upon the natural and permanent characteristics of rocks. Rocks have been classified according to chemical composition, mineralogical com- position, texture, color, density, hardness, etc. ; but these arrangements, taken singly or all combined, are inadequate. A natural classification may be defined as a concise and systematic statement of the natural relations exist- ing among the objects classified. Now the most, im- portant relations existing among rocks are those due to their different origins. We must not forget that lithology is a branch of geology, and that geology is first of all a dynamical science. The most important question that can be asked about any rock is, not What is it made of? but How was it made ? What were the general forces or agencies concerned in its formation? Rocks are the material in which the earth's history is Classification of Rocks, Sedimentary or Stratified Rocks. MECHANICALLY FORMED. Unconsolidated. Consolidated. Conglomerate group. Gravel. Conglomerate. A renaceous group. Sand. Sandstone. A rgillaceous group. Clay. Slate. CHEMICALLY AND ORGANICALLY FORMED. Coal group. Iron-ore group. C ale ar tons group. Me amorphic group (Silicates'), Acidic. Basic. 85 80 70 60 SO 40 30 Peat. Lignite. Bit. Coal. Anthracite. Graphite. Asphaltum. Limonite. Hematite. Magnetite. Siderite. Limestone. Dolomite. Gypsum. Rock-salt. Phosphate Rock. Feldspathic. Gneiss. [ Diorite. Syenite. Norite. Siliceous group. Non-Feldspathic. Mica Schist. Tripolite. Flint. Siliceous Tufa. Novaculite. Hornbl. Schist. Amphiboli e. Talc Schist. Chi. Schist. i Greensand Serpentine. Eruptive or Unstratified Rocks. PLUTONIC. Thisp is a blan no erupt which ar minerals irt of the clas k, for the re. ive rocks ar e chiefly com jelonging to t a Elements, C Sulphates, or , all eruptive nown, are pi 1 of minerals V. ss of Silicates sification ison that e known posed of ic classes 'hlorides | I | Granite. Diori e. Syenite. D abase. VOLCANIC. Oxides, ates; i.e far as k composec to the cla Carbon- rocks, so incipally elonging Feldspathic. Rhyol te. Andesite. Trachyte. Basalt. Obsidian. Tachylite. Petrosilex. Porphyrite. Felsite. Melaphyr. , ,- ; LITHOLOGY. 71 written, and what we want to know first concerning any rock is what it can tell us of the condition of that part of the earth at the time it was made and subsequently. The geological agencies, as we have already learned, may be arranged in two great classes : first, the aqueous or superficial agencies originating in the solar heat, and producing the sedimentary or stratified rocks ; and, second, the igneous or subterranean agencies originat- ing in the central or interior heat, and producing the eruptive or unstratified rocks. Hence, we want to know first of any rock whether it is of aqueous or igneous origin. Then, if it is a sedimentary rock, whether it has been formed by the action chiefly of mechanical forces, or of chemical and organic forces. And, if it is an eruptive rock, whether it has cooled and solidified below the earth's surface in a fissure, and is a dike or trappean rock, or has flowed out on the sur- face and cooled in contact with the air, and thus be- come an ordinary lava or volcanic rock. Here we have the outlines of our classification, and it will be observed that we have simply reached the conclusion, in a somewhat roundabout manner, that there should always be a general correspondence be- tween the classification of rocks and the classification of the forces that produce them. The general plan of the preceding scheme of the classification must now be clear, and the details will be explained as we go along. 72 STRUCTURAL GEOLOGY. Descriptions of Rocks. I. Sedimentary or Stratified Rocks. i. MECHANICALLY FORMED OR FRAGMENTAL ROCKS. These consist of materials deposited from suspension in water, and the process of their formation is through- out chiefly mechanical. The materials deposited are mere fragments of older rocks ; and, if the fragments are large, we call the newly deposited sediment gravel ; if finer, sand ; and, if impalpably fine, clay. These fragmental rocks cannot be classified chemically, since the same handful of gravel, for instance, may contain pebbles of many different kinds of rocks, anjj thus be of almost any and very variable composition. Such chemical distinctions as can be established are only partial, and the classification, like the origin, must be mechanical. Accordingly, as just shown, we recognize three principal groups based upon the size of the frag- ments j viz. : (1) Conglomerate group. (2) Arenaceous group. (3) Argillaceous group. This mode of division is possible and natural, simply because, as we observed in an early experiment, mate- rials arranged by the -mechanical action of water are always assorted according to siz When first depos- ited, the gravel, sand, and clay are, of course, perfectly loose and unconsolidated ; but in the course of time they may, under the influence of pressure, heat, and chemical action, attain almost any degree of consoli- dation, becoming conglomerate, sandstone, and slate, LITHOLOGY. 73 respectively. The pressure may be vertical where it is due to the weight of newer deposits, or horizontal where it results from the cooling and shrinking of the earth's interior. The heat may result from mechanical movements, or contact with eruptive rocks ; or it may be due simply to the burial of the sediments, which, it will be seen, must virtually bring them nearer the great source of heat in the earth's interior, on the same principle that the temperature of a man's coat, on a cold day, is raised by putting on an overcoat. The effect of the heat, ordinarily, is simply drying, cooper- ating with the pressure to expel the water from the sediments ; but, if the temperature is high, it may bake or vitrify them, just as in brick-making. Sediments are consolidated by chemical action when mineral substances, especially calcium carbonate, the iron oxides, and silica are deposited between the particles by infiltrating waters, cementing the particles together. This principle is easily demonstrated experimentally by taking some loose sand and wetting it repeatedly with a saturated solution of some soluble mineral, like salt or alum, allowing the water to evaporate each time before making a fresh application. The interstices between the grains are gradually filled up, and the sand soon becomes a firm rock. But the student should clearly understand that, in geology, gravel, sand, and clay are just as truly rocks before their consolidation as after. It is plain then that in each of the principal groups of fragmental rocks we must recognize an unconsolidated division and a consoli- dated division. (i) Conglomerate group. The rocks belonging in 74 STRUCTURAL GEOLOGY. this group we know before consolidation as grave}, and after consolidation as conglomerate. Gravel. The pebbles, as we have already seen, are usually, though not always, well rounded or water- worn ; and they may be of any size from coarse grains of sand to boulders. As a rule, however, the larger pebbles, especially, are of approximately uniform size in the same bed or layer of gravel, with, of course, suf- ficient fine material to fill the interstices. Although the same limited mass of gravel may show the widest possi- ble range in chemical and mineralogical composition, yet hard rocks are evidently more likely than soft rocks to form pebbles ; and hence quartz and quartz-bearing rocks usually predominate in gravels. Specimen 28. Conglomerate. Consolidated gravel. Children should be led to an appreciation of this point by a careful comparison of the forms of the pebbles in the gravel and conglomerate. The conglomerate seems to contain a larger proportion of fine material than or- dinary gravel. But this is because the gravel is usually, as with our specimen, taken from the surface of the beach, where, of course, the pebbles are clean and sep- arate ; but if it had remained there to be covered by a subsequently deposited layer, enough fine stuff would have been sifted into the holes to fill them. And in the finished gravel, just as in the conglomerate, the pebbles are usually closely packed, with just sufficient sand and clay, or paste, as the material in which the pebbles are imbedded is called, to fill the interstices. The paste is usually similar in composition to the peb- bles, with this difference : hard materials predominate in the pebbles and soft in the paste. LITHOLOGY. 75 Stratified rocks generally show the stratification in parallel lines or bands differing in color, composition, etc. ; but nothing like this can be detected in our specimens of conglomerate ; and the question might be asked, How do we know that this is a stratified rock ? In answer, it can be said that our hand-speci- mens appear unstratified simply because the rock is so coarse ; but when we look at large masses, and espe- cially when we see it in place in the quarry, that parallel arrangement of the material which we call strat- ification is usually very evident ; and we often see pre- cisely the same thing in gravel banks. It is, however, wholly unnecessary that we should see the stratification in order to know certainly that this is a stratified or aqueous rock, because the forms of the pebbles show very plainly that they have been fashioned and de- posited by moving water ; and we have in the smallest specimen proof positive that our conglomerate is a consolidated sea-beach. Conglomerate shows the same variations in compo- sition and texture as gravel ; it may be composed of almost any kind of material in pebbles of almost any size. We recognize two principal varieties of con- glomerate based on the forms of the pebbles ; if, as is usual, these are well rounded and water-worn, the rock is true pudding-stone (specimen 29) ; but, if they are angular, or show but little wear, it is called breccia. (2) Arenaceous Group. The conglomerate group passes insensibly into the arenaceous group ; for, from the coarsest gravel to the finest sand, the gradation is unbroken, and every sandstone is merely a conglome- rate on a small scale. 76 STRUCTURAL GEOLOGY. Sand. Like gravel, sand may be of almost any composition, but as a rule it is quartzose ; quartz, on account of its hardness and the absence of cleavage, being better adapted than any other common mineral to form sand. Where the composition of a sand is not specified, a quartzose sand is always understood. By examining a typical sand with a lens, and noting the glassy appearance of the grains, and then testing their hardness on a piece of glass, which they will scratch as easily as quartz, the pupil is readily convinced that each grain is simply an angular fragment of quartz. Specimen 30. Sandstone. Consolidated sand. In proving this, children will notice first the granular or sandy appear- ance of the sandstone ; and then, with the lens, that the grains in the sandstone have the same forms as the sand-grains. The stratification cannot be seen very distinctly in our hand-specimens, but in larger masses it is usually very plain, as may be observed in the blocks used for building, and still better in the quarries. However, even if the stratification were not visible to the eye, we could have no doubt that sandstone is a mechanically formed stratified rock ; because the form of the grains, just as in the conglomerate, tells us that. Many sandstones, too, contain the fossil remains of plants and animals, and these are always regarded as affording positive proof that the rocks containing them belong to the aqueous or stratified series. There are many varieties of sandstone depending upon differences in composition, texture, etc., but we have not space to notice them in detail. In sandstone, just as in sand, quartz is the predominant constituent, LITHOLOGY. 77 although we sometimes find varieties composed largely or entirely of feldspar, mica, calcite, or other minerals. Specimen 31 is an example of the architectural variety known as freestone, which is merely a fine-grained, light-colored, uniform sandstone, not very hard, and breaking with about equal freedom in all directions. The consolidation of sandstones is due chiefly to chem- ical action. The cementing materials are commonly either : ferruginous (iron oxides), giving red or brown sandstones ; calcareous, forming soft "sandstones, which effervesce with acid if the cement is abundant; or siliceous, making very strong, light-colored sandstones. Ferruginous sandstones are the most valuable for archi- tectural purposes ; for, while not excessively hard, they have a very durable cement. Siliceous sandstones are too hard ; and the calcareous varieties crumble when exposed to the weather because the cement is soluble in water containing carbon dioxide, as all rain-water does. Specimen 32 is a good example of a ferruginous sandstone, and it is coarse enough so that we can see that each grain of quartz is coated with the red oxide of iron. The mica scales visible here and there in this specimen are interesting as showing that the grains are not necessarily all quartz ; and it is important to observe that the mica was not made in the sandstone, but, like the quartz, has come from some older rock. Quartzite. This rock is simply an unusually hard sandstone. Now the hardness of any rock depends upon two things : ( i ) the hardness of the individual grains or particles ; and (2) the firmness with which they are united one to another. Therefore, the hard- est sandstones must be those in which grains of quarts 78 STRUCTURAL GEOLOGY. are combined with an abundant siliceous cement ; and that is precisely what we have in a typical quartzite, such as specimen 33. Quartzite is distinguished, in the hand-specimen, from ordinary quartz by its granu- lar texture (compare specimens 15 and 33) ; and of course in large masses the stratification is an impor- tant distinguishing feature. 3. Argillaceous group. Just as the conglomerate group shades off gradually into the arenaceous group, so we find it difficult to draw any sharp line of division between the arenaceous group and the argillaceous, but we pass from the largest pebble to the most minute clay-particle by an insensible gradation. For the sake of convenience, however, we draw the line at the limit of visibility, and say that in the true clay and slate the individual particles are invisible to the naked eye ; in other words, these rocks have a perfectly compact tex- ture, while the two preceding groups are characterized by a granular texture. Although clay, like sand and gravel, may be of almost any composition, yet it usually consists chiefly, often entirely, of the mineral kaolin. The reason for this is easily found. Quartz resists both mechanical and chemical forces, ana is rarely reduced to an impalpable fineness ; but all the other common minerals, such as feldspar, hornblende, mica, and cal- cite, on account of their cleavage and inferior hardness, are easily pulverized ; but it is practically impossible that this should happen without their being broken up chemically at the same time. Decomposition follows disintegration ; and, while calcite is completely dis- solved and carried away, the other minerals are reduced, as we have seen, to impalpable hydrous silicates of LITHOLOGY. 79 aluminum, /.., are each composed of several minerals ; but some silicate rocks and all the rocks of the other divisions are simple, each species consisting of a single mineral only. ( i ) Coal Group. These are entirely of organic origin, and include two allied series, which are always merely the more or less extensively transformed tissues of plants or animals ; viz. : 82 STRUCTURAL GEOLOGY. Coals and Bitumens. At the first lesson we exam- ined a sample of peat (specimen 8), and considered the general conditions of its formation, peat being in every instance simply partially decayed marsh vegeta- tion. It was also stated that, as during the lapse of time the transformation becomes more complete, the peat is changed in succession to lignite, bituminous coal, anthracite, and graphite. The coals, indeed, make a very beautiful and perfect series, whether we consider the composition there being a gradual, pro- gressive change from the composition of ordinary woody fibre in the newest peat to the pure carbon in graphite, or the degree of consolidation and mineral- ization since there is a gradual passage from the light, porous peat, showing distinctly the vegetable forms, to the heavy crystalline graphite, bearing no trace of its vegetable origin. This relation is easily appreciated by a child, if a proper series of specimens is presented. The coals also make a chronological series, graphite and anthracite occurring only in the older formations, and lignite and peat in the newer, while bituminous coal is found in formations of intermediate age. Bituminous coal is the typical, the representative coal; and from a good specimen of this variety we may learn two important facts : (1) That true coals, no less than peat, are of vege- table origin. To see this we must look at the flat or charcoal surfaces of the coal. These soil the fingers like charcoal, and usually show the vegetable forms distinctly. (2) That coals are stratified rocks. These dirty charcoal surfaces always coincide with the stratification, LITHOLOGY. 83 being merely the successive layers of vegetation de- posited and pressed together to build up the coal ; and when we look at the edge of the specimen the stratifi- cation shows plainly enough. The bitumens form a similar though less perfect series, beginning with the organic tissues, and ending, in the opinion of some of the best chemists and miner- alogists, with diamond. In fact the coals and bitumens form two distinct but parallel series. The coals are exclusively of vegetable origin, while the bitumens are largely of animal origin. The organic tissues in which the two series originate are chemically similar, the animal tissues, which produce the lighter forms of bitu- men, however, containing more hydrogen and less carbon and oxygen than vegetable tissues ; while the final terms, as just shown, are probably chemically identical, being pure carbon, graphite for the coals and diamond for the bitumens ; so that the entire pro- cess of change in each series is essentially carboniza- tion, a gradual elimination of the gaseous elements, oxygen and hydrogen, until pure solid carbon alone remains. The principal differences between the coals and bitumens are the following : Coals are rich in carbon, with some oxygen and little hydrogen. Bitumens are rich in hydrogen, with some carbon and little or no oxygen. Coals are entirely insoluble. Bitumens are soluble in ether, benzole, turpentine, etc., and the solid forms are soluble in the more fluid, naphtha-like varieties. Coals are never liquid, and cannot be melted or, with trifling exceptions, even softened by heat. Many bitumens are naturally liquid, and all become so on the application of heat. 4 STRUCTURAL GEOLOGY. The coals partake of the characteristics of their chief constituent element, carbon, the most thoroughly solid substance known ; while the bitumens similarly show the influence of hydrogen, the most perfectly fluid substance known. The two bitumens of the greatest geological impor- tance are asphaltum or mineral pitch and petroleum ; but these substances are too familiar to require any farther description here. (2) Iron-ore Group. These interesting and im- portant stratified rocks include the three principal oxides of iron, limonite, hematite, and magnetite, as well as the carbonate cf iron, siderite ; and the rocks have essentially the same characteristics as the minerals. In economical importance they are second only to the coals ; and the history of their formation through the agency of organic matter is one of the most interesting chapters in chemical geology (see page 26). The three oxides are easily distinguished from each other by the colors of their powders or streaks, and the magnetism of magnetite, and from all other common rocks by their high specific gravity. Magnetite is the richest in iron, and limonite the poorest. As regards the degree of crystallization and order of occurrence in the formations, they form a series parallel with the coal series, thus : Limonite, never crystalline, and found in recent formations. Hematite, often crystalline, and found in older formations. Magnetite, always crystalline, and found in oldest formations, Siderite effervesces with strong acid ; and this sepa- rates it from all other rocks, except limestone and dolomite ; and from these it is distinguished by its LITHOLOGY. 85 high specific gravity. As a mineral, siderite is often light colored ; but as a rock it is always dark, and usually black, from admixture chiefly of carbonaceous matter. In studying dynamical geology, we have learned (page 28) tru; reason for the intimate asso- ciation of siderite with beds of coal, and this accounts equally for the carbon contained in the rock itself. The connection of this rock with the coal-formations adds much to its value as an ore of iron. Finally, the iron-ores, at least where of much eco- nomical importance, are truly stratified. This can often t>e seen in hand-specimens ; and is well shown by their relations to other rocks, in quarries and mines ; and in many cases, for limonite and hema- tite, by the fossils which they contain. (3) Siliceous Group. These rocks are composed of pure silica in the forms of quartz and opal. When first deposited, whether organically, like tripolite, or chemically, like siliceous tufa, the siliceous rocks are soft and light, and the silica is in the form of opal. Subsequently it changes to quartz, and the rocks as- sume the much harder and denser forms of chert and novaculite, respectively. Tripolite or Diatomaceous Earth. This interest- ing rock is soft, light, and looks like clay ; but it is lighter, and the argillaceous odor is faint or wanting. It does not effervesce with acid. Hence, it is neither clay nor chalk. Notwithstanding its softness, it is really composed of a hard substance, viz., silica, in the form known as opal. By rubbing off a little of the dust, and examining it- under the microscope, we easily prove that the silica is mainly or entirely of organic origin ; 86 STRUCTURAL GEOLOGY. for the dust is seen, to be simply a mass of more or less fragmentary organic remains, occurring in great variety, and of wonderful beauty and minuteness. There are few rocks so unpromising on the exterior, and yet so beautiful within. We have already learned that these organic bodies are principally Diatom cases, Radiolaria shells, and Sponge spicules. We can form some idea of their minuteness from Ehrenberg's estimate that a single cubic inch of pure tripolite contained no less than 41,000,000,000 organisms. The lightness of tripolite (sp. gr., 1-1.5) * s due to the facts that opal is a light mineral (sp. gr., 1.9-2.2), and that many of the shells are hollow. Tripolite is a good example of a soft rock composed of a hard min- eral ; and it owes its value as a polishing material to the fact that it consists of a hard mineral in an exceed- ingly fine state of division. Tripolite, when pure, is snow-white ; but it is rarely pure, being commonly either argillaceous or calcareous. This rock is now forming in thousands of places, in both fresh water and the ocean. Flint and Chert. During the course of geological time, beds of tripolite are gradually consolidated, chiefly by percolating waters, which are constantly dissolving and re-depositing the silica ; and, finally, in the place of a soft, earthy rock, we get a hard, flinty one, whicn we call flint if it occurs in the newer, or chert if it occurs in the older, geological formations. Besides forming beds of nearly pure silica, which we call tripo- lite, the microscopic siliceous organisms are diffused more or less abundantly through other rocks, especially chalk and limestone. In such cases the consolidatiois LITHOLOGY. 87 of the silica implies its segregation also ; /.f origin into three classes as follows : Fig. 36. Quarry showing two systems of parallel joints. i . The parallel and intersecting joints. This is by far the most important class, and has its best develop- ment in stratified rocks, such as sandstone, slate, lime- stone, etc. These joints are straight and continuous cracks which may often be traced for considerable distances on the surface. They usually run in several definite directions, being arranged in sets or systems by their parallelism. Thus in Fig. 36 one set of joints is represented by the broad, flat surfaces in 190 STRUCTURAL GEOLOGY. light, and a second set crossing the first nearly at right angles, by the narrower faces in shadow. By the inter- sections of the different sets of joints the rock is divided into angular blocks. Although many explanations of this class of joints have been proposed, it has long been the general opinion of geologists that they are due to the contrac- tion of the rocks, i.e., that they are shrinkage cracks. We shall soon see, however, that they lack the most important characters of cracks known to be due to shrinkage ; and the present writer has advanced the view that movements of the earth's crust, and especially the swift, vibratory movements known as earthquakes, are a far more adequate and probable cause. It is well known that earthquakes break the rocks ; and, if space permitted, it could be shown that the earthquake- fractures must possess all the essential features of par- allel and intersecting joints. 2. Contraction joints or shrinkage cracks. That many cracks in rocks are due to shrinkage, there can be no doubt. The shrinkage may result from the drying of sedimentary rocks ; but more generally from the cooling of eruptive rocks. Every one has noticed in warm weather, the cracks in layers of mud or clay on the shore, or where pools of water have dried up ; and we have already seen that these sun-cracks are often preserved in the hard rocks. They have certain characteristic features by which they may be distin- guished from the joints of the first class. They divide the clay into irregular, angular blocks, which often show a tendency to be hexagonal instead of quad- rangular. The cracks are continually uniting and PETROLOGY. 191 dividing, but are not parallel, and rarely cross each other. Sun-cracks never affect more than a few feet in thickness of clay, and are an insignificant structural feature of sedimentary rocks. In eruptive rocks, on the other hand, the contraction joints have a very exten- Fig. 37. Columnar dike. sive, and, in some cases, a very perfect development, culminating in the prismatic or columnar jointing of the basaltic rocks. This remarkable structure has long excited the interest of geologists, and, although the basalt columns were once regarded as crystals, and later as a species of concretionary structure, it is now generally recognized as the normal result of slow cool- 192 STRUCTURAL GEOLOGY. ing in a homogeneous, brittle mass. The columns are normally hexagonal, and perpendicular to the cooling surface, being vertical in horizontal sheets and lava flows, as in the classic examples of the Giant's Cause- way and Fingal's Cave, and horizontal in vertical dikes (Fig. 37). They begin to grow on the cooling surface of the mass and gradually extend toward the centre, so that dikes frequently show two independent sets of columns. 3. The concentric joints of granitic rocks. In quarries of granite and other massive crystalline rocks, it is often very noticeable that the rock is divided into more or less regular layers by cracks which are ap- proximately parallel with the surface of the ground, some of the granite hills having thus a structure re- sembling that of an onion. The layers are thin near the surface, become thicker and less distinct down- wards, and cannot usually be traced below a depth of fifty or sixty feet. These concentric cracks are of great assistance in quarrying, and are now regarded as due to the expansion of the superficial portions of the granite caused by the heat of the sun. In reference to this view of their origin these may be properly called expansion joints. STRUCTURE OF MOUNTAIN-CHAINS. Mountains are primarily of two kinds, volcanic and non- volcanic. The structure of the former belongs properly with the original structures of the volcanic rocks ; but the latter the true mountains owe their internal struc- ture and altitude or relief almost wholly to the crump- ling and mashing together of great zones of the earth's crust, being, as already pointed out, the culminating PETROLOGY. 193 points of the plication, cleavage, and faulting of the strata. " A mountain-<:to'# consists of a great plateau or bulge of the earth's surface, often hundreds of miles wide and thousands of miles long. This is usually more or less distinctly divided by great longitudinal valleys into parallel ranges and ridges ; and these, again, are serrated along their crests, or divided into peaks by transverse valleys. In many cases this ideal chain is far from realized, but we have instead, a great bulging of the earth's crust composed on the surface of an inextricable tangle of ridges and valleys of ero- sion, running in all directions. In all cases, however, the erosion has been immense ; for the mountain- chains are the great theatres of erosion as well as of igneous action. As a general fact, all that we see, when we stand on a mountain-chain every peak and valley, every ridge and canon, all that constitutes scen- ery is wholly due to erosion." LE CONTE. The structure of mountains thus falls under two heads : ( i ) The internal structure and altitude, which are due to the action of the subterranean agencies. (2) The external forms, the actual relief, which are the product chiefly of the superficial agencies or erosion. The study of mountains has shown that : ( i ) They are composed of very thick sedimentary for- mations. Thus the sedimentary rocks have a thickness of 40,000 feet in the Alleghanies ; of 50,000 feet in the Alps ; and of two to ten miles in all important moun- tain-chains. Such thick deposits of sediments, as we have already seen, must be formed on a subsiding sea- floor, and in many mountain-chains, as in the Alle- ghanies, the great bulk of these sediments are still 194 STRUCTURAL GEOLOGY. below the level of the sea. Again, thick sedimentary deposits can only be formed in the shallow, marginal portions of the sea; and when such a belt of thick shore deposits yields to the powerful horizontal thrust, and is crumpled and mashed up, it is greatly shortened in the direction of the pressure and thickened verti- cally, so that its upper surface is lifted high above the level of the sea, and a mountain-chain is formed and added to the edge of the continent. We thus find an explanation of the important fact that on the several continents, but notably on the two Americas, the prin- cipal mountain-ranges are near to and parallel with the coast lines. 2. The mountain-forming sediments are usually strongly folded and faulted, and exhibit slaty cleavage wherever they are susceptible of that structure ; and the older rocks, especially, in mountains are often highly metamorphosed, and are traversed by numer- ous veins and dikes, the infallible signs of intense igneous activity. " In other words, mountain regions have been the great theatres (i) of sedimentation before the moun- tains were formed; (2) of plication and upheaval in the formation of the range ; and (3) of erosion which determined the present outline. Add to these the metamorphism, the faults, veins, dikes, and volcanic outbursts, and it is seen that all geological agencies concentrate there." LE CONTE. Since mountain-ranges are great up-swellings or bulgings of trfe strata, their structure is always essen- tially anticlinal ; and they sometimes consist of a sin- gle more or less denuded anticline (Fig. 38), the PETROLOGY. IQS oldest and lowest strata exposed forming the summit of the range. More commonly, however, the single great arch or uplift is modified by a series of longitudi- nal folds, as shown in the section of the Jura Moun- tains (Fig. 21). Still more commonly the folds are closely pressed together, overturned, broken, and al- most inextricably complicated by smaller folds, con- tortions, and slips. The strata on the flanks of the mountains are usually less disturbed than those near the axis of the range, and are sometimes seen to rest unconformably against Fig. 38. Anticlinal mountain. the latter. In this way it is proved that some ranges are formed by successive upheavals. But we have still more conclusive evidence that mountains are formed with extreme slowness in the fact that rivers sometimes cut directly through important ranges. This proves, first, that the river is older than the mountains ; second, that the deepening of its channel has always kept pace with the elevation of the range. CONCRETIONS AND CONCRETIONARY STRUCTURE. Folds, cleavage, faults, and joints all the subsequent structures considered up to this point are the prod- uct of mechanical forces. Chemical agencies, although very efficient in altering the composition and texture of rocks, are almost powerless as regards the develop- iq6 STRUCTURAL GEOLOGY. ment of rock-structures ; and the only important structure having a chemical origin is that named above. Concretions are formed by the segregation of one or more of the constituents of a rock. But there are three distinct kinds of segregation. If the water per- colating through or pervading a rock, dissolves a cer- tain mineral and afterwards deposits it in cavities or fissures, amygdules, geodes, or veins are the result. If the mineral is deposited about particular points in the mass of the rock, it may form crystals, the rock be- coming porphyritic ; or it may not crystallize, but build up instead the rounded forms called concretions, the texture or structure of the rock becoming concretionary. A great variety of minerals occur in the form of con- cretions, but this mode of occurrence is especially characteristic of certain constituents of rocks, such as calcite, siderite, limonite, hematite, and quartz. Con- cretions may be classified according to the nature of the segregating minerals ; and in each class we may distinguish the pure from the impure concretions. A pure concretion is one entirely composed of the seg- regating mineral. Most nodules of flint and chert, quartz, geodes, concretions of pyrite, and many hollow iron-balls are good illustrations of this class. In all these cases the segregating mineral has been able in some way to remove the other constituents of the rock, and make room for itself. But in other cases it has lacked this power, and has been deposited between and around the grains of sand, clay, etc. ; and the concretions are consequently impure, being composed partly of the segregating mineral, and partly of the PETROLOGY. 197 other constituents of the rock. The calcareous con- cretions known as clay- stones are a good example of this class, being simply discs of clay, all the minute interstices of which have been filled with segregated calcite. The solid iron-balls are masses of sand filled in a similar manner with iron oxides. Concretions are of all sizes, from those of micro- scopic smallness in some oolitic limestones up to those twenty-five feet or more in diameter in some sand- stones. The point of deposition, when a concretion begins to grow, is often determined by some concrete particle, as a grain or crystal of the same or a different mineral, a fragment of a shell, or a bit of vegetation, which thus becomes the nucleus of the concretion. The ideal or typical concretion is spherical ; but the form is influ- enced largely by the structure of the rock. In porous rocks, like sandstone, they are frequently very perfect spheres ; but in impervious rocks, like clay, they are flat or disc-shaped, because the water passes much more freely in the direction of the bedding than across it ; while the concretions in limestones, the nodules of flint and chert, are often remarkable for the irregularity of their forms. In all sedimentary rocks the concre- tions are arranged more or less distinctly in layers parallel with the stratification, which usually passes undisturbed through the impure concretions. Many silicious and ferruginous concretions are hollow, ap- parently in consequence of the contraction of the sub- stance after its segregation ; and the shrinkage due to drying is still further indicated by the cracks in the septaria stones. The hollow, silicious concretions are 198 STRUCTURAL GEOLOGY. usually lined with crystals (geodes), while the holiow iron-balls frequently enclose a smaller concretion. Rocks often have a concretionary structure when there are no distinct or separable concretions. And the appearance of a concretionary structure (pseudo- concretions) is often the result of the concentric de- composition of the rocks by weathering, as explained on page 13. SUBSEQUENT STRUCTURES PRODUCED BY THE SUPER- FICIAL OR AQUEOUS AGENCIES. The superficial agen- cies, as we have seen in the section on dynamical geology, are, in general terms, water, air, and organic matter. Geologically considered, the results which they accomplish, may be summed up under the two heads of deposition and erosion the formation of new rocks in the sea, and the destruction of old rocks on the land. In the role of rock-makers they produce the very important original structures of the stratified rocks ; while as agents of erosion they develop the most salient of the subsequent structures of the earth's crust the infinitely varied relief of its surface. As a general rule, to which recent volcanoes are one im- portant exception, the original and subterranean struc- tures of rocks are only indirectly, and often very slightly, represented in the topography; for this, as we have seen, is almost wholly the product of erosion. Therefore, what we have chiefly to consider in this sec- tion is to what extent and how erosion is influenced by the pre-existing structures of rocks. Horizontal or very slightly undulating strata, espe- cially if the upper beds are harder than those below, give rise by erosion to flat-topped ridges or table- PETROLOGY. 199 mountains (Fig. 39). But if the strata be softer and of more uniform texture, erosion yields rounded hills, often very steep, and sometimes passing into pinnacles, as in the Bad Lands of the west. Broad, open folds, as we have seen, give, normally, synclinal hills and anticlinal valleys (Fig. 22), when the erosion is well advanced. But in more strongly, closely folded rocks Fig. 39. Horizontal strata and table-mountains. the ridges and valleys are determined chiefly by the outcrops of harder and softer strata, as shown in Fig. 40, the symmetry of the reliefs depending upon the dip of the strata. This principle of unequal hardness or durability also determines most of the topographic Fig. 40. Ridges due to the outcrops of hard strata. features in regions of metamorphic and crystalline rocks, in which the stratification is obscure or wanting. The boldness of the topography, and the relation of depth to width in valleys, depends largely upon the altitude above the sea ; but partly, also, upon the dis- tribution of the rainfall, the drainage channels or val- leys being narrowest and most sharply defined in arid regions traversed by rivers deriving their waters from 200 STRUCTURAL GEOLOGY. distant mountains. That these are the conditions most favorable for the formation of canons is proved by the fact that they are fully realized in the great plateau country traversed by the Colorado and its tributaries, a district which leads the world in the mag- nitude and grandeur of its canons. But deep gorges and canons will be formed wherever a considerable altitude, by increasing the erosive power of the streams, enables them to deepen their channels much more rapidly than the general face of the country is lowered by rain and frost. This is the secret of such canons as the Yosemite Valley, and the gorge of the Columbia River, and probably of the fiords which fret the north- west coasts of this continent and Europe. For a full description and illustration of the topographic types developed by the action of water and ice upon the surface of the land, and of the various characteristic forms of marine erosion, teachers are referred to the larger works named in the introduction, especially Le Conte's Elements of Geology, and to the better works on physical geography. We will, in closing this section, merely glance at some of the minor erosion- forms, which are not properly topographic, but may be often illustrated by class-room and museum specimens. Mere weathering, the action of rain and frost, develops very characteristic surfaces upon different classes of rocks, delicately and accurately expressing in relief those slight differences in texture, hardness, and solu- bility, which must exist even in the most homogeneous rocks. Every one recognizes on sight the hard, smooth surfaces of water-worn rocks. They are exemplified in beach and river pebbles, in sea-worn cliffs, and PETROLOGY. 201 where rivers flow over the solid ledges. The pot-hole (page 17) is a well-marked and specially interesting rock-form, due to current or river erosion. Ice has also left highly characteristic traces upon the rocks in all latitudes covered by the great ice- sheet. These consist chiefly of polished, grooved, and scratched or striated surfaces, the grooves and scratches showing the direction in which the ice moved. The organic agencies, as already noted, accomplish very little in the way of erosion, especially in the hard rocks, but the rock-borings made by certain mollusks and echinoderms may be mentioned as one unimpor- tant but characteristic form due to organic erosion. APPENDIX The following collections are especially pre- pared and arranged for use with this text : 2 1 Opalized wood *22 Gypsum *23 Calcite 24 Dolomite 25 Siderite *26 Hornblende 27 Pyroxene *28 Muscovite 29 Biotite *3 numbered, labelled and mounted on blocks or in improved trays, for museum display and laboratory work $40.00 (The same, labelled but unmounted, $30.00) 204 APPENDIX Collection No. F2. Same as above, but small museum size, mounted in improved trays (2^x3^) .... $25.00 Collection No. fj. Same as Fz, but hand size speci- mens (2x2) 12.50 Collection No. F4. 80 specimens, omitting those marked (), in individual trays (2^x1^) and two cloth-board cases, numbered to correspond with ac- companying printed list (no labels) 5.00 Collection No. F^. 40 specimens marked (*), mounted as collection F4 2.50 Collection No. F6. 100 pupils' fragments (ixi), num- bered, in paper bags. (Single collection $1.25.) In lots of 5 or more, each i.oo Collection No. Fj. 80 pupils' fragments (like F6). (Single $1.00.) In lots of 5 or more, each .... .75 Collection No. F8. 40 pupils' fragments (like F6). (Single 5oc.) In lots of 5 or more, each .40 Collection No. Fg. 25 museum size specimens, illus- trating structure, faults, stratification, etc. Mounted and labelled 10.00 For further information or in ordering, address WARD'S NATURAL SCIENCE ESTABLISHMENT 84-102 College Ave., Rochester, N. Y. 14 DAY USE RETURN TO DESK FROM WHICH BORROWED EARTH SCIENCES LIBRARY This book is due on the last date stamped below, or on the date to which renewed. Renewed books are subject to immediate recall. LD 21-40m-5,'65 General Library University of California % c 5.30