SOLUBILITIES
OF
INORGANIC AND ORGANIC
SUBSTANCES
A HANDBOOK OF THE MOST RELIABLE
QUANTITATIVE SOLUBILITY
DETERMINA TIONS
RECALCULATED AND COMPILED BY
ATHERTON SEIDELL, PH.D. (J-H.U.)
Chemist, Division of Pharmacology, Hygienic Laboratory of the U. S
Public Health and Marine-Hospital Service, Washington, D. C~
Formerly Assistant Chemist, Bureau of Chemistry
U. S. Department of Agriculture
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D. VAN NOSTRAND COMPANY
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1917
COPYRIGHT, 1907 AND 1911 BY
D. VAN NOSTRAND COMPANY
Stanhope preea
N. OILBON COMPANY
BOBTO N. U. S. A.
PREFACE
DURING the years which have elapsed since Professor Arthur M.
Comey's admirable "Dictionary of Chemical Solubilities" went
to press (March, 1894), the literature upon solubilities has grown
to such an extent that it has appeared desirable to make a new
compilation of it. Soon after beginning work upon this volume the
author realized that it would not be possible to prepare a com-
pilation of solubility results which would fulfill completely the
various requirements of theoretical, technical, analytical, and
other classes of chemists, and he has therefore endeavored to meet
some of the needs of all chemists rather than provide information
especially arranged for any particular class.
The following features have been considered of chief impor-
tance in preparing the present compilation: completeness of the
data, reliability of the determinations, uniformity in expression
of results, convenience of arrangement of material, and the index-
ing of the cross-references to tables.
The material has been collected almost entirely from the origi-
nal sources, and not from text-books or works of reference.
The plan followed has been to search diligently the tables of con-
tents or indices of twenty -five of the principal chemical journals
issued since 1875, and to consult all articles in these as well as in
other journals to which references could be obtained. In this
connection, however, it should be stated that indexed references
to work on solubility usually appear under the name of the sub-
stance employed, and not under the heading "solubility." Fur-
thermore, solubility determinations are often incidental to other
investigations, and consequently are not indicated in the title
of the article or included in the index of the journal. Consid-
ering these difficulties there can be little hope of making such
a compilation complete in every detail, and in the present case
the best that can be said is that an earnest effort has been made
to omit nothing of importance. This has been done not only
for the author's personal satisfaction in perfecting the work,
but also to give the reader a reasonable assurance that the ab-
sence from these pages of results upon a particular substance is
good evidence that such determinations of satisfactory reliability
iii
395316
PREFACE
are not readily obtainable from the usually accessible chemical
journals.
Although at the time Professor Comey compiled his book it
appeared inadvisable to attempt, in the majority of cases, to
select the most reliable determinations of the solubility of the
same substance reported by different investigators, the present
author believes that this can now be done with advantage. The
selections have been made in all cases by calculating the avail-
able determinations to a common basis and drawing curves
through the points plotted on cross-section paper. A comparison
of the curves, together with a study of the details of the methods
by which the determinations were made in the several cases, has
usually furnished clear evidence for a reliable selection. For
some substances, however, this plan could not be followed, and
it has therefore been necessary to present two or more sets of
disagreeing results.
In many instances the calculations and study necessary to
ascertain the most reliable figures have required much labor,
and perhaps in some cases the author has not succeeded in
selecting the ones nearest the truth; but it is believed that the
economy of space required to present the material, and the saving
of the time of the reader in making the necessary selections him-
self, will far overbalance the disadvantage resulting from the
accidental inaccuracies introduced through extended computa-
tions.
An additional advantage resulting from the recalculation of
different determinations to a common basis is the increased
uniformity in the expression of results throughout the volume.
On this account it has been possible to give the solubility of most
substances for regular intervals of temperature and in terms of
weight of dissolved substance per given weight of solvent or of
solution.
Quantitative results alone have been included in this com-
pilation, since it is assumed that qualitative determinations, if
desired, can be readily made by simple tests in the laboratory,
and therefore the effort necessary to collect such observations
from the literature is out of proportion to the value of the inform-
ation obtained.
In regard to the names and formulas of the compounds in-
cluded, the author wishes to say that they are, for the most part,
given as found in the original papers from which they were taken ;
and in some cases a lack of uniformity in the manner of their
iv
PREFACE
expression will be noted. This is especially true of the molecules
of water of crystallization in the formulas given in connection
with the guide names placed in heavy type at the head of the
tables for all substances considered. As is well known, many
compounds, besides gaining or losing water in air, also crystal-
lize with different numbers of molecules of water even at the
ordinary temperature, and it was therefore thought best to include
such information at the proper place in the tables under the
heading "Solid Phase" rather than to select in doubtful cases
the number of molecules of water which the particular substance
was considered to carry under ordinary conditions.
Although the arrangement of the material is alphabetical accord-
ing to the customary English names, an index has been added
which also provides for those cases where there appears a doubt
as to which name is preferable, and furnishes cross-references to
those tables which contain results upon more than one substance.
A glance through the pages of this book will show the incom-
pleteness of the data for many of the most common chemical
compounds. Furthermore many of the results given are of
doubtful accuracy, although the best available. It is hoped,
therefore, that a realization of the present incomplete state of our
information concerning solubilities as evidenced in these pages
will stimulate investigations of many of those substances which
have hitherto been studied incompletely or not at all.
This volume went to press January ist, 1907, and the subject
matter is brought up to November, 1906.
In conclusion, the author begs all indulgence for errors and
omissions, and will thank any one for calling them to his attention
or making suggestions such as would improve a possible future
edition of this "Handbook."
A. S.
WASHINGTON, D.C., Feb. 22, 1907.
ABBREVIATIONS
Abs. Absolute.
Abs. Coef . Absorption Coefficient.
Aq. or a.q. Aqueous.
At. Atmosphere.
b. pt. Boiling Point.
cc. Cubic Centimeter.
cone. Concentrated.
d. Dextro.
dt. Density.
f. pt. Freezing Point.
G., g., or gm. Gram.
Gms. or gms. Grams.
G.M. or Gm. Mol. Gram Molecule.
/. Laevo.
m. Meta.
Mg. or mg. Milligram.
Mgs. or mgs. Milligrams.
Mg. Mol. Milligram Molecule.
Millimols. Milligram Molecules.
Mol. Molecule.
m. pt. Melting Point.
N. or n. Normal.
o. Ortho.
ord. Ordinary.
p. Para.
ppt. Precipitate.
pptd. Precipitated.
pt. Part.
sat. Saturated.
sol. Solution.
Sp. Gr. Specific Gravity.
t. Temperature in degrees C.
temp. Temperature.
vol. Volume.
wt. Weight.
vii
ABBREVIATIONS OF TITLES OF JOURNALS
Am. Ch. J. The American Chemical Journal, Baltimore.
Am. J. Sci. American Journal of Science and Arts, New Haven.
Analyst. The Analyst, London.
Ann. See Liebig's Ann.
Ann. chim. anal. appl. Annales de chimie analytique applique"e, Paris.
Ann. chim. phys. Annales de chimie et de physique, Paris.
Ann. Physik. A^nnalen der Physik und Chemie, Leipzig. See also Pogg.
Ann. and Wied. Ann.
Apoth.-Ztg. Apotheker Zeitung, Berlin.
Arch. Pharm. Archiv der Pharmacie, Halle.
Ber. Berichte der deutschen chemischen Gesellschaft, Berlin.
Biedermann's Centr. Biedermann's Centralblatt fur Agrikulturchemie,
u. s. w., Leipzig.
Bull. soc. chim. Bulletin de la socie'te' chimique de Paris.
Chem. Centralbl. Chemisches Centralblatt, Berlin.
Chem. Ind. Die Chemische Industrie, Berlin.
Chem. News. The Chemical News, London.
Chem.-Ztg. Chemiker Zeitung, Cothen.
Compt. rend. Comptes rendus hebdomadaires des Seances de 1'Academie
des Sciences, Paris.
Dingier pol. J. Dingier' s polytechnisch.es Journal, Stuttgart.
Gazz. chim. ital. Gazzeta chimica italiana, Palermo.
Jahresber. Chem. Jahresbericht iiber die Fortschritte der Chemie, Giessen.
J. Am. Chem. Soc. Journal of the American Chemical Society, Easton.
J. Anal. Chem. The Journal of Analytical and Applied Chemistry, Easton.
T. Chem. Soc. Journal of the Chemical Society of London.
'. pharm. chim. Journal de pharmacie et de chimie, Paris.
r . Physic. Chem. Journal of Physical Chemistry, Cornell.
: . pr. Chem. Journal fiir praktische chemie, Leipzig.
\. russ. phys. chem. Ges. Journal of the Russian Chemical Society, St.
Petersburg.
J. Soc. Chem. Ind. Journal of the Society of Chemical Industry, London.
Landw. Vers-Stat. Landwirthschaftlichen Versuchs-Stationen, Berlin.
Liebig's Annalen. Justus Liebig's Annalen der Chemie, Leipzig.
Monatsh. Ch. Monatshefte fur Chemie, u. s. w., Vienna.
Mon. Sci. Le Moniteur Scientifique, Paris.
Mulder. Scheikundige Verhandelingen en Onderzoekingen, Vol. 3, Pt. 3.
Bijdragen tot de Geschiedenis van Het Scheikungig Gebonden Water by
G. J. Mulder, Rotterdam, 1864.
Pharm. J. Pharmaceutical Journal and Transactions, London.
Phil. Mag. The Philosophical Magazine, London.
Physic. Rev. Physical Review, Cornell.
Pogg. Ann. Annalen der Physik und Chemie, edited by Poggendorf. See
also Ann. Physik and Wied. Ann.
Proc. Am. Acad. Proceedings of the American Academy of Arts and
Sciences, Boston.
Proc. Roy. Soc. Proceedings of the Royal Society of London.
Rec. trav. chim. Recueil des travaux chimiques des Pays-Bas, Leiden.
Sitzber. Akad. Wiss. Berlin. Sitzungsbericnte der koniglichen preussischen
Akademie der Wissenschaften zu Berlin.
Sitzber. Akad. Wiss. Wien. Sitzungsberichte der mathematische naturwissen-
schaftlichen classe der kaiserlichen Akademie der Wissenschaften zu
Wien.
U. S. P. Pharmacopoeia of the United States, 8th Revision, 1900.
ix
ABBREVIATIONS OF TITLES OF JOURNALS
Wied. Ann. Annalen der Physik und Chemie, edited by Wiederman. See
also Pogg. Ann. and Ann. Physik.
Wiss. Abh. p. t. Reichanstalt. Wissenschaftlichen Abhandlung der physik-
alische technische Reichstalt, Charlottenburg.
Z. anal. Chem. Zeitschrift fiir analytische Chemie, Wiesbaden.
Z. angew. Chem. Zeitschrift fiir angewandte Chemie, Berlin.
Z. anorg. Chem. Zeitschrift fur anorganische Chemie, Hamburg and Leipzig.
Z. Elektrochem. Zeitschrift fiir Elektrochemie, Halle.
Z. Krystallogr. Zeitschrift fiir Krystallographie und Mineralogie, Leipzig.
Z. physik. Chem. Zeitschrift fiir pnysikalische Chemie, Leipzig.
Z. Ver. Zuckerind. Zeitschrift fiir Rubenzucker-Industrie, Berlin.
The above abbreviations with a few necessary exceptions are taken from
the list adopted by the editor of the Journal of the American Chemical Society
for the new abstract journal, "Chemical Abstracts," and will in general be
familiar to many of those who use this volume. In a large number of in-
stances Chem. has been contracted to Ch., but with this exception, and possibly a
few inaccuracies which have slipped in, the abbreviations of journal titles used
in this book conform to the above list.
AOENAPHTHENE C 12 H 10 .
SOLUBILITY IN SEVERAL ORGANIC SOLVENTS.
(Speyers Am. J . Set. [4] 14, 294, 1902.)
NOTE. In the original paper the results are given in terms of gram
molecules of acenaphthene, acetamide, acetanilide, etc., per 100 gram
molecules of solvent, at temperatures which varied with each solvent and
with each weighing of the solutions. The tabulated results here given
were obtained by recalculating and reading the figures from curves plotted
on cross section paper.
In Methyl Alcohol.
In Ethyl Alcohol.
In Propyl^Alcohol.
t . ' (a)*
(b)*
(c)*" (a)
(b)
(c) '
(a)
(b)
(c)
O
8l
33
1. 80
O
39 81
.1
1-9
o-57
82.3
2.26
0.88
IO
80
.40
1.70
O
.38 80
3
2.8
0.84
8! .8
2.40
I .00
20
79
.60
2.25
O
.48 79
.6
4.0
1.20
81.4
3-40
1 .35
30
79
.00
3-50
.72 79
.1
5-6
1.70
80.9
4-75
1.90
40
78
45
6.00
I
.20 78
7
8.4
2.60
80.6
7.10
2.90
50
78
9.00
I
77 78
.8
13.2
3-90
80.7
II. 10
4.40
60
78
30
ii .70
2
35 79
4
23-2
7-00
81.5
19.60
8.20
70
78
.60
14.30
2
.90 80.75
40-5
I2.5O
83-9
37.00
16.20
In Chloroform.
In
Toluene.
t .
(a)
(b)
(c)
(a)
(ft)
(c)
143
,8
16.4
12.7
90.7
13.18
7-9
10
140
I
20.6
16.0
90.8
18.0
10.7
20
136
3
27.0
19-5
91.0
24-5
14-5
30
132
4
34-o
25.0
91.8
33-5
20.5
40
128
42-5
32.0
92.7
47-o
28.0
50
123,
4
40.0
94-o
60.5
35-7
60
119-3
62.5 50-0
95 5
74-o
43-5
70
97.2
89.0
52-5
AOETAMIDE CH 3 CO.NH 2 .
SOLUBILITY IN
WATER AND IN ALCOHOL.
(Speyers.)
In Water.
In
Ethyl Alcohol.
t 8 .
(a)
(*)
(c)
(a)
(b)
W
105
5
70.8
29.6
85.62
17-3
18.5
10
104
9
81.0
34-o
86.2
24.0
26.0
20
104
3
97-5
40.8
87-3
31-5
33-8
30
103
7
114.0
47-7
88.8
40-5
43-o
,
40
103
o
133 .0
55-5
90.7
50.0
53-5
SO
102
3
154.0
64.0
93 o
6s .0
64-5
.
60
101
6
177 5
74-o
95-5
72.0
76-5
ACETANILIDE C 6 H 5 NH.COCH 3 .
100 grams H 2 O dissolve 0.55 gram at 25, and 5.55 grams at b. pt.
* (o) Weight of 100 cc. solution in grains. * (b) Grams dissolved substance per zoo grams solvent.
* (c) Gram molecules of dissolved substance per ioc gram molecules of solvent.
AOETAKILIDS
t '
a
SOLUBILITY OF ACETANILIDE IN ORGANIC SOLVENTS.
(Speyers.)
In Methyl Alcohol. In Ethyl, Alcohol. In Chloroform.
O
10
20
30
40
50
60
(a)
86.0
86.4
87-5
89.2
91.1
93-2
95 7
(ft)
22-7
30-0
41 -o
54-0
75-5
107.0
145.0
(0
5-4
7-o
9.8
13.2
18.0
25.2
84
84
85
86
87
89
92
.2
4
-O
.0
4
5
.0
(ft)
14.7
20-0
27.0
36.0
49.0
65.0
87-0
(c)
5-o
6.6
9-0
12.2
16.2
22.
30-0
(a)
147
144
139
131
127
3
5
.8
-4
4
.2
(ft)
3-66
7-80
12.00
17.0
23.0
31.0
41-0
(c) "
3-24
7.00
10.50
15-0
20.4
27.6
36-0
SOLUBILITY IN MIXTURES OF ETHYL ALCOHOL AND WATER AT 25.
(Holleman and Antusch Rec. trav. chim 13, 293, 1894.)
Vol. % Gms. CgHgNO per ~ Pr
AlcohS. loo Gms. Solvent. S P' Gr '
Vol. % Gms. CgHsNO per c ~
Alcohol. loo Gms. Solvent. &p ' (jT '
100
32-93
0.8512
55
13 13
0-9335
95
36.65
0-8737
9-74
0.9396
93
38.04
0.8813
45
7-25
0.9449
90
38.20
0.8896
40
5.10
0.9508
87
37.80
0-8959
35
3-58
0.9567
85
36.83
0.8996
3 1
2.56
0.9617
80
33-62
0.9072
25
1.73
0.9683
75
29.25
0.9133
20
1.30
0.9736
24-73
0.9185
IS
1.03
o 9795
65
20.42
0.9185
10
o 94
0.9845
60
16.51
0.9287
0-54
0.9970
ACETIC ACID CH 3 COOH.
SOLUBILITY IN WATER.
(Dahms Ann. Phys. [4] 60, 122, '97.)
t o Gms. CHaCOOH per Solid ,0 Gms. CHaCOOH per Solid
* ' 100 Cms. Solution. Phase. 100 Gms. Solution. Phase.
-5 15.1 Ice -20 66.3 CHaCOOH
-10 28.2 " -io 76.7
-15 39.5 " - o 87.0
-20 49.5 +10 90.8
25 57.0 " 16.5 ioo-otr.pt. "
-26.6 58.9 Ice-fCH 3 COOH
DISTRIBUTION OF ACETIC ACID BETWEEN:
Water and Amyl Alcohol at 20. Water and Benzene at 25.
(Herz and Fischer Ber. 37, 4747, '04) (H. and F. Ber. 38, 1140, '05.)
Cms. CHaCOOH
per 100 cc.
G. M. CHaCOOH
per 100 cc.
Gms. CH S COOH
per loo cc.
G. M.
per
CHaCOOH
1OO CC.
H a O
Alcoholic
HaO
Alcoholic
H 2 O
QH
H20
CoH
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
I
0.923
0.01
0.0095
5
0.130
0.05
0.0014
2
1.847
0-03
0.0280
10
0.417
o.io
0.0005
3
2-741
0-05
0.0460
20
-55
O-2O
O.OO3O
4
3.694
0-07
0-0645
30
3 03
0.30
0.0290
5
4.587
0-09
0.0830
40
4.95
0.50
0.051
6
5-475
O.II
IOIO
0-70
0.090
7
6-434
0.13
0-1190
8
. . .
AOETIO AOID
DISTRIBUTION OF ACETIC ACID BETWEEN WATER AND BENZENE.
(Waddell J. Phys. Ch. 2, 237, 1898.)
Results in terms of grams per 100 grams solution.
Upper Layer.
Lower Layer.
t. CHaCOOH.
C 6 H a .
H 2 6.
25
o
.46
99
52
.02
25
3
.10
96
75
o
1$
25
5
.20
94
55
o
25
25
8
7
90
.88
o
-42
25
16
3
82
.91
o
79
25
30
5
67
37
2
13
25
5
39
.60
7
.60
35
i
.2
98
.68
o
.08
35
5
7
93
97
o
33
35
9
.0
90
.42
58
35
45
.0
49
.00
6
.0
35
5 2
.2
39
4
8
4
CHaCOOH
. CeHa.
H 2 0.
9-4
0.18
90.42
28.2
o-53
71.27
37-7
0.84
61.46
48-3
1.82
49-88
61 .4
6.1
32-5
66.0
13-8
20-2
52-8
39-6
7 .6
16.4
0.62
89.98
36.8
1.42
62.78
49.0
2.10
48.90
61-3
25-5
13.2
52.2
39-4
8. 4
DISTRIBUTION OF ACETIC ACID BETWEEN WATER AND CHLOROFORM:
At Room Temperature. At 25.
(Wright, Thomson and Leon Proc. Roy.
Soc-49, 185, 1891-)
Results in parts per 100 parts of solution.
Upper Layer. Lower Layer.
(HerzandLewy;Rol
Cms. CHaCOOH
per TOO cc.
CHaCOOH. CHC1 3 .
H 2 O. CH 3 COOH
. CHC1 3 .
H 2 0.
Layer.
CHC1 3
Layer.
O
,84
99
.16
o
99-
OI
0.
99
2
0.089
6.46
o.
92
92
.62
1.04
98.
24
0.
72
4
0.313
17.69
0.
79
81
S 2
3-83
94-
98
I .
19
6
0.596
25.10
I.
21
73
.69
6.77
91.
85
I.
38
8
0.974
33-71
2.
97
63
32
11.05
87-
82
I.
13
10
1.430
44.12
t
30
4 8
58
17.72
80.00
2.
28
12
1.982
50.18
IS-
ii
34
25-75
70.
13
4-
12
20
5-10
30
10.2
40
15-3
50
21-9
52-3
39-54
G. M. CHaCOOH
per 100 cc.
CHC1,
Layer.
0.0032
O.0062
0.0100
H 2
Layer.
0.05
0.075
O.IOO
0.150 0.0198
0.175 0.0260
0.0325
0.070
0.170
0.275
o-335
0.200
0.30
0.50
O.70
0.80
0.87
0.659
The figures in the table for 25 were read from the curve plotted
from the results of H. and L., Z. electro. Ch. u, 818, 1905, and of R.
and W., Z. phys. Ch. 40, 623, 1902.
The influence of electrolytes upon the distribution of acetic acid
between the aqueous and chloroform layers was investigated by
Rothmund and Wilsmore, and the following results expressed in gram
molecules per liter at 25 were obtained:
Cone, of Cone, of CHaCOOH Cone*
Cone, of Cone. CH 3 COOH Cone.*
ectro- I
Electrolyte
n
CHaCOOl
* Electro- *
.lectrolyte
in'
C
H 3 COOH
lyte.
Aq.
Aq.
CHC1 3 "
H 2 O
lyte.
Aq.
,
\q.
C
:HC1 3 '
H 2 O
Layer.
Layer.
Layer.
Layer.
Layer.
L
ayer.
]
-ayer.
Layer.
ICl
0.463
0.876
0.0907
0.946
i H 2 SO 4
0.514
I.
099
1315
I.I68
0.463
I-538
0.2435
1.680
"
1.029
i.
555
.2714
1.787
0.926
0-813
0.0938
0.966
0.926
1.586
0.2902
1.858
NH 4 NO a
I.O
i.
136
o
I 3 I 3
1.168
NO,
0.316
0.936
0.0927
0.958
"
I.O
i.
991
o
.3481
2-053
0.316
1.694
0.2537
1.720
LiNO 3
I.O
892
.1005
I.OOO
0.633
0.965
0.0981
0.988
* *
I.O
I.
513
o
.2581
1-737
0.633
1.631
0.2486
1.702
* Calculated from table above.
ACETIC ACID 4
DISTRIBUTION OF ACETIC ACID AT 25 BETWEEN:
Water and Carbon Bisulphide. Water and Carbon Tetrachloride.
(Herz and Lewy.) (Herz and Lewy.)
Gms. CHaCOOH G. M. CHaCOOH Gms. CHaCOOH G. M. CHaCOOH
per ipo cc. per 100 cc. per 100 cc. per ipo cc.
HjO CST H 2 O CIST H 2 O CCk ' H 2 O CC1 4
Layer. Layer. Layer. Layer. Layer. Layer. Layer. Layer.
65 2.64 i.i 0.45 30 1.8 0.5 0.03
70 3.0 1.2 0.55 40 3.0 0-7 0.055
75 3-3 1-2 0.80 50 4.8 0.9 0.095
80 5.4 1-35 o-97 60 5.8 i.i 0.155
85 6.4 1-4 1-3 70 12.0 1.2 0.235
76.2 25.2 1.27 0.420
DISTRIBUTION OF ACETIC ACID AT 25 BETWEEN:
Water and Bromoform. Water and Toluene.
(H. and L. Z. electro. Ch. n, 818, '05.) (H. and F. Ber. 38, 1140, '05.)
Gms. CHaCOOH G. M. CHaCOOH Gms. CHaCOOH G. M. CH 3 COOH
per IPO cc. per ipo cc. per ipo cc. per 100 cc.
1*5 CHBra" ' H 2 O CHBr 3 'H 2 O CeHsCHa ' H 2 O C 6 H 6 CH3
Layer. Layer. Layer. Layer. Layer. Layer. Layer. Layer.
20 1.5 0.4 0.035 5 0.119 o.i 0.0025
30 3.0 0.6 0.070 10 0.328 0.2 0.0075
4O 4-8 0.8 0.120 20 I.I32 0-4 0.0260
50 7.8 i.o 0.20 30 2.265 0.6 0.0530
60 12. o i.i 0.28 40 3-725 0.8 0.090
65 15.6 1.15 0.395 5 5-841 i.o 0.140
70 27.0 60 8.344
DISTRIBUTION OF ACETIC ACID AT 25 BETWEEN:
Water and o or p Xylene. Water and m Xylene.
(Herz and Fischer.) (Herz and Fischer.)
Gms. CH 8 COOH G. M. CHaCOOH Gms. CHaCOOH G. M. CH 3 COOH
per IPO cc. per 100 cc. per 100 cc. per 100 cc.
TTO .? 9 r P wn
5 0.24 o.i 0.004 5 0-06 o.i 0.0015
10 0.48 0-2 O-OIO 10 0-30 0-2 0.007
20 1.13 0.4 0.025 20 o 95 0.4 0.022
30 2.15 0.6 0-047 30 1.91 0.6 0.042
40 3.40 0.8 0-079 4 3 4 0-8 0-072
50 5-10 I.O 0-122 50 4-65 I.O O.III
60 7-27 1.2 O.23O 60 6.65 1.2
70 12.52
NOTE. The distribution results as presented in the original
papers to which references are given in the above tables, are reported
in millimolecules per 10 cc. portions of each layer in the several cases.
To obtain the figures given in the above tables, the original results be-
fore and after calculating to gram quantities were plotted on cross-
section paper, and from the curves thus obtained, readings for regular
intervals of concentration of acetic acid in the aqueous layer were
selected.
5 Chlor ACETIC ACID
Chlor ACETIC ACID CH 2 C1COOH.
DISTRIBUTION OF CHLORACETIC ACID BETWEEN:
(Herz and Fischer.)
Water and Benzene at 25. Water and Toluene at 25.
3ms. CH 2 C1COOH
per 100 cc.
G. M. CH 2 C1COOH
per ipo cc.
Gms. CH 2 C1COOH
per 100 cc.
G. M. CH 2 C1COOH
per 100 cc.
H 2
Layer.
Layer.
H 2
Layer.
Layer.
H 2
Layer.
Layer*
H 2
Layer.
C 6 H 5 CH 3
Layer.
0.25*
8.69
O.OO25
O
.090
O
.!*
5
.22
O
OOI
0-055
o-5
15-59
O.OO5
O
r 55
O
5
20
31
O
.005
O-2O
I.O
27.87
O-OIO
O
.28
I
.0
34
.87
O
OIO
0.36
IS
41.10
0.015
415
I
5
49
14
O
.015
0.50
2.0
52.90
0-02
54
2
.0
60
.46
.02
O.62
3-o
68.01
0.03
O
.70
3
.0
72
.28
03
0-77
4-0
76.52
O.O4
O
79
4
.0
81
.72
O
.04
0.85
5
.0
86
94
O
05
0.90
DISTRIBUTION OF CHLORACETIC ACID BETWEEN:
(Herz and Lewy.)
Water and Chloroform at 25*
Water and Bromoform at 25.
Gms. CH2C1COOH
G. M. CH 2 C1COOH
Gms. CH 2 C1COOH
G. M. CH 2 C1COOH
per 100 cc.
per ipo cc.
per loo cc.
per 100 cc.
H 2 O CHC1 3
Layer. Layer.
'H 2 O CHC1 3 '
Layer. Layer.
H 2 O CHBrs
Layer. Layer.
H 2 O CHBra
Layer. Layer.
5* 0.283
0.05 0.0025
40* 0.850
0.45 o.on
10 0.614
o.io 0.0060
50 1.889
0.50 0.0165
20 I. 088
O.2O O.OI35
60 2.994
O.6o O.O28
4O 2 . 948
O.4O O.O29
70 4.241
0.70 O.O4O
50 3.684
0.60 0-045
80 5 . 620
0.8o 0.053
60 4-440
0.70 0.061
90 7.560
0.90 0.067
70 7.086
0.75 0-077
91.6 II-340
0-97 0.120
DISTRIBUTION OF CHLORACETIC ACID BETWEEN:
(Herz and Lewy.)
Water and Carbon Bisulphide
at 25.
Water and Carbon Tetra-
chloride at 25.
Gms. CH2C1COOH
per 100 cc.
G. M. CH 2 C1COOH
per 100 cc.
Gms. CH 2 C1COOH
per 100 cc.
G. M. CH 2 C1COOH
per 100 cc.
H^
CS 2
HzO
cs^
H 2
ecu
H 2
ecu"
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
60*
0.426
0.6
O.OO42
90*
I.4I7
o-95
0.0150
80
0.691
0.8
O.OO7
95
2.031
1. 00
0.0195
90
0-803
I.O
O.OO9
100
2.645
1.05
O.O27O
100
1.040
1.05
0.0105
I0 5
4.26
1. 10
0.0415
105
1.464
1. 10
0.015
106.7
5-19
1-13
0.0550
106.7
1.890
1-13
O-020
* See Note, page 4.
Chlor ACETIC ACIDS
SOLUBILITY OF MONOCHLOR, DICHLOR, AND OF TRICHLORACETIC ESTER
IN AQUEOUS ALCOHOL AT ROOM TEMPERATURE.
(Bancroft Phys. Rev. 3, 193, 1895-96, from results of PfcifLr, Z. physik. chem. 9, 469, '92.)
cc. Elhyl
Alcohol in
Mixtures.
cc. H2O added to cause separation of a second phase
in mixtures of the given amts. of Alcohol and 3 cc. of :
CH2C1COOC 2 H 5 .
CHCl2COOC 2 H 3
CCbCOOQjHfi.
3
1.32
O.QO
0.65
6
4-OI
2-45
1. 80
9
7-30
4-33
3-02
12
10.78
6.60
4-50
15
16.16
9-20
6.50
18
22.16
...
t
21
28.74
. . .
a AOETNAPHTHALIDE C 2 H,ONH(C 10 H 7 ).
SOLUBILITY IN MIXTURES OF ALCOHOL AND WATER AT 25.
(Holleman and Antusch Rec. trav. chim. 13, 289, 1894.)
Vol.%
Alcohol.
Gms. per
100 Gms.
Solvent.
Sp. Gr. of
Solutions.
Alcohol
Gms. per
100 Gms.
Solvent.
Sp. Gr. of
Solutions.
100
4-02
0.7916
65
I. 7 8
0.8977
95
4-31
0.8150
60
1-44
0.9091
90
4-II
0.8344
55
I .02
0.9201
85
3-69
0.8485
5o
0-71
0-9290
80
3 .l8
0.8624
35
0.25
Q-9537
75
2-73
0.8761
20
O.O9
0.9717
70
2.31
0.8798
10
O-O4
0.9841
ACETONE (CH 3 ) 2 CO.
SOLUBILITY OF ACETONE AT 25 IN AQUEOUS SOLUTIONS OF:
Electrolytes. Non-Electrolytes.
(Bell J. Phys. Ch. 9, 544, 1005; Linebarger Am. Ch. J. 14, 380, 1892.)
Gms. Electro-
lyte per
Gms. (CH 3 ) 2 CO per 100 Gms.
Solvent in Solutions of:
Gms. Non- Gms. (CH 3 ) 2 CO per too Gms
Electrolyte Solvent in Solutions of:
100 Gms. Aq
Solution.
K 3 C0 3
Na 2 CO 3 (NH4) 2 CO 3 MgCO 3 Aq. Solution. C^Hg*
Anethol* (C 6 H 5 ) 2 CO,
I
2 5
. . .
.
83-5
5
92-5
103.0
90.0
2
50
51.0
no
O
65 -o
10
117.0
I2 3
.0
108.5
5
CO
65.0
38.0
73
5
47-o
20
137.0
144
5
126.0
7
5
46.5
27-5
57
O
38.0
30
14^-5
155
.0
133 .0
10
34-5
19-5
44
5
29.0
40
155-5
162
O
136.0
12
5
25-5
14.0
35
.0
. . .
5
159-5
1 66
.0
135-5
15
.0
18.0
9-0
28
.0
. . .
00
160-2
165
.0
131 .5
20
o
8.0
2-7
. . .
70
155-0
158
.0
123.0
25
O
3-7
. .
. . .
80
108.5
30
.0
1.6
90
82.0
* Anethol - p Propenylanisol CHs.CHrCHUJQ^OCHj. Naphthalene results at 35.
NOTE. The original results were recalculated and plotted on cross-
section paper. From the curves so obtained the above table was
constructed. See also Note, page 7.
ACETONE
SOLUBILITY OF ACETONE IN AQUEOUS SOLUTIONS OP CARBOHYDRATES
(Krug and McElroy J. Anal. Ch. 6. 184, '92; Bell J. Phys. Ch. 9, 547. '05.)
Per cent
Sugar.
10
20
30
35
40
45
50
55
60
65
70
In Aqueous Solutions of Cane Sugar.
Cms. (CH 3 ) 2 CO per too Cms. Sugar Solution at:
is.
30.
2S-
30.
35
40.
597-2
581.8
574-8
272.5
250.0
251.8
172.4
150.0
150.6
. . .
. . .
. . .
110
. . .
96.4
92.8
89.8
85
. . .
71.9
68.8
65-7
62
50.8
48.1
45-9
42
35-8
33-8
32-5
29
25.2
24.2
23-4
. . .
18.3
17.7
17.0
13.2
12.8
12.5
In Aqueous Dextrose Solutions.
In Aqueous Maltose Solutions.
Per
cent
Gms. (CH 3 ) 2 CO per
Solvent at:
ioo Gms.
Per
cent
Gms.
(CH 3 ) 2 CO per ioo Gms.
Solvent at:
Dextrose.
' 15.
25-
3S-
Maltose.
"iS. 25.
3S."
10
73 6
7
747
9
76I-5
10
353
.6
348
.1
342-0
2O
255
3
247
7
24O.8
20
I8 5
4
181
.2
176.9
30
157
5
149
.8
142.5
30
119
9
116
O
II2.4
40
86
9
79
.6
74-0
40
78
4
74
7
70-5
50
36
.2
33
.0
31.2
50
4 6
.2
42
9
39-8
NOTE. The above determinations were made by adding successive
small quantities of acetone to mixtures of known amounts of water
and the carbohydrate, and noting the point at which a clouding due
to the separation of a second phase occurred. This method was also
used for the solubility of acetone in the aqueous electrolyte solutions
(see previous page). In the case of the aqueous non-electrolyte
solutions, however, successive small amounts of water were added to
mixtures of known amounts of acetone and the non-electrolyte.
DISTRIBUTION OF ACETONE BETWEEN WATER AND BENZENE AT 25.
(Herz and Fischer Ber. 38, 1142, '05.)
Gms. (CH 3 ) 2 CO
per ioo cc.
G. M. (CH 3 ) 2 CO
per ioo cc.
Aq.
Layer.
CH
Layer.
' Aq.
Layer.
QH,
Layer.
I*
I .20
0.025*
0.025
5
4.17
0.05
0.047
10
10.15
o.io
o-975
15
15-59
0.15
0.150
20
22.50
O-2O
0.215
0.25
0.275
*
See Note, page 4.
ACET-PHENETIDINE 8
ACET-PHENETIDINE p (PHENAOETINE) C H 4 (OC 2 H 5 )NHCH 3 CO.
SOLUBILITY IN WATER, ALCOHOL, ETC.
(U. S. P.)
Cms. C 6 H4(OC2H5)NHCH 3 CO per 100 Cms.
b.pt.
H 2 0.
CzHeOH.
(CH 3 ) 2 0.
CHCl,.
0.108
8-33
I -59
S-oo
i-43
50.0
ACET-TOLUIDE p CH 3 .C 6 H 4 NH.C 2 H 3 O.
SOLUBILITY IN MIXTURES OF ALCOHOL AND WATER AT 25.
(Holleman and Antusch Rec. trav. chim. 13, 288, '94.)
Alcohol.
Gms. per
100 Gms.
Solvent.
Sp. Gr.
of
Solutions.
100
I0.l8
0.8074
95
10-79
0.8276
90
IO.62
o . 8440
85
9.62
0-8576
80
8-43
0.8685
75
7.04
0.8803
70
5-81
o . 8904
65
4-39
0.9021
60
3-59
0.9115
55
2.69
0.9207
Alcoho?.
Gms. per
loo Gms.
Solvent.
Sp. Gr.
of
Solutions.
50
1.92
0.9306
45
I.4I
0.9380
40
0.96
o . 9460
35
0.66
0.9544
2 5
0.31
0.9668
20
0.23
0.9725
15
0.16
0.9780
5
0.13
0.9903
0.12
0-9979
ACETYLENE C 2 H 2 .
SOLUBILITY IN WATER.
(Winkler ; see Landolt and Bernstein's Tabellen, sd ed. p. 604,
t e .
O
5
10
20
25
3
73
49
3 1
03
o-93
0.84
O.2O
O.I7
O.I5
0.13
0-12
O-II
0.09
a, " Absorption Coefficient," = the volume of gas (reduced to o
and 760 mm. pressure) taken up by one volume of the liquid at the
given temperature when the partial pressure of the gas equals 760 mm.
mercury.
<7, " Solubility," = the amount of gas in grams which is taken up by
100 grams of the pure solvent at the given temperature if the total
pressure, i.e., the partial pressure of the gas plus the vapor pressure of
the liquid at the absorption temperature is 760 mm.
9 AOETYLAOETONE
ACETYLACETONE CH 3 COCH 2 COCH .
SOLUBILITY IN "WATER.
(Rothmund Z. phys. Ch. 26, 475, '98.)
Cms. CH S COCH,COCH 8 per too Cms.
to
' H 2
Acetyl Acetone
Layer.
Layer.
30
15.46
95-02
40
I7-58
93.68
5<>
2O.22
91.90
60
23-23
89.41
70
27.10
85-77
80
33-92
78.82
87.
7 (crit. temp.) 56.8
NOTE. Weighed amounts of water and acetylacetone were placed in
small glass tubes, which were then sealed and slowly heated until the
contained mixtures became homogeneous. The temperature was then
allowed to fall very gradually and the point noted at which cloudiness
appeared. This point was accurately established for each tube by repeated
trials. The curve plotted from these determinations shows two percentage
amounts of acetylacetone which cause cloudiness at each temperature
below the critical point. Of these two points, for each temperature, one
represents the aqueous layer, i.e., the solubility of acetylacetone in water;
and the other represents the acetylacetone layer, i.e., the solubility of
water in acetylacetone. This method is known as the " Synthetic Method,"
and yields results in harmony with those obtained by the analytical method,
i.e., by analyzing each layer after complete separation occurs.
ACONITINE (Amorphous) C3 4 H 47 NO n .
SOLUBILITY IN SEVERAL SOLVENTS.
(At 25 U.S.P.; at i8-22, Miiller Apoth.-Ztg. 18, 2, '03.)
Cms. C3iH 4 7NOi per Cms. CaJL^NOn per
Solvent. IPO Gms. Solvent at: Solvent. 100 Gms.^Solvent at:
i8-22. 25? i8-22. 25. "
Water . . . 0-054 0.031 Benzene *7 -&S
Alcohol 4-54 * Carbon Tetrachloride i . 99
Ether ... 1.44 2.27 Petroleum Ether . . 0-023 0.028
ADIPIO ACID (Normal) (CH 2 ) 4 (COOH) 2 .
100 grams H 2 O dissolve 1.44 grams adipic acid at 15.
(Henry Compt. rend. 99* 1157, '84; Lamowoux Ibid. 128, 908, '99.)
AIR.
10
AIR
SOLUBILITY IN WATER.
(Winkler Her. 34, 1409, '01; see also Peterson and Sondern Ber. 22, 1439, '89.)
cc.* of atmospheric O and N per liter of:
Dist. H 2 O (at 760 mm.). Sea Water (at 760 mm.).
t".
B.
Oxygen.
Nitrogen.
Oxygen.
Nitrogen.
o
0.02881
0.02864
IO.I9
18.45
7-77
I4-85
5
02543
.02521
8.91
16.30
6-93
13.32
10
.02264
.02237
7.87
14.50
6.29
12 .06
15
.02045
.02011
7-04
13.07
5-7o
11.05
20
.01869
.01826
6-35
II .91
IO.25
25
.01724
.01671
5-75
10.96
9.62
30
.Ol6o6
01539
5-24
10.15
40
.OI4l8
OI3I5
4.48
8.67
50
.01297
.01140
3-85
7-55
60
OI2l6
.00978
3-25
6.50
80
.OII26
.00600
1.97
4-03
100
.01105
.OOOOO
o.oo
0-00
B = " Coefficient of Absorption," i.e., the amount of gas dissolved
by the liquid when the pressure of the gas itself without the tension
of the liquid amounts to 760 mm.
B r = " Solubility," i.e., the amount of gas, reduced to o and 760
mm., which is absorbed by one volume of the liquid when the barometer
indicates 760 mm. pressure.
* Reduced to o and 760 mm.
SOLUBILITY OF AIR IN AQUEOUS SULPHURIC ACID AT 18 AND 760 MM.
(Tower Z. anorg. Ch. 50, 382, '06.)
Wt. % H 2 SO 4 98 90 80 70 60 50
Solubility Coef. 0.0173 0.0107 0.0069 0.0055 0.0059 0.0076
SOLUBILITY OF AIR IN ALCOHOL, ETC.
(Robinet Compt. rend. 58, 608, '64.)
Solvent .
Alcohol (95 . i%) . . 14.1 Oil of Lavender . ... 6.9
Petroleum 6.8 Oil of Turpentine . . . 24.2
Benzene 14.0
Solvent.
Vols. Air per io<
Vols. Solvent.
Vols. Air per 100
Vols. Solvent.
ALANINE (a Aminopropionic Acid) CH 3 CH(NH 2 )COOH.
SOLUBILITY IN MIXTURES OF ALCOHOL AND WATER AT 25.
(Holleman and Antusch Rec. trav. chim. 13, 297, '94.)
Vol.%
Alcohol.
Gms. per
100 Gms.
Solvent.
Sp. Gr. of
Solutions.
16.47
I .0421
5
14-37
I.03II
10
12.43
I -O2OO
IS
10.49
I -OIOI
20
8.48
0.9984
25
7.11
0.9886
31
5-53
0-9761
Vol. %
Alcohol.
Gms. per
100 Gms.
Solvent.
Sp. Gr. of
Solutions.
35
4.91
0.9670
40
3 -89
o-9577
50
2-38
o-9355
60
i-57
0.9102
70
0.85
0.8836
80
o-37
o 8556
ii ALDEHYDE
ALDEHYDE.
SOLUBILITY OF p FORMALDEHYDE (TRIOXYMETHYLENE) IN AQUEOUS
SODIUM SULPHITE SOLUTIONS AT 20.
(Lumiere and Seyewetz Bull. soc. chim. [3] 27, 1213, 'oa.)
Grams Sodium Sulphite per 100 cc. H 2 O 5 10 20 28
Gms. Trioxymethylene per 100 cc. solution 22 24 26 27
100 gms. H 2 O dissolve 12.5 paraldehyde at 25, and 6.6 gms. at b. pt.
ALCOHOLS.
SOLUBILITY OF AMYL ALCOHOL IN WATER AT 22.
(Herz Ber. 31, 2671, '98.)
ioo cc. water dissolve 3.284 cc. amyl alcohol. Sp. Gr. of solu-
tion = 0.9949, Volume = 102.99 cc.
ioo cc. amyl alcohol dissolve 2.214 cc. water. Sp. Gr. of solu-
tion = 0.8248, Volume = 101.28 cc.
Sp. Gr. of H 2 O at 22 = 0.9980; Sp. Gr. of amyl alcohol at 22= 0.8133.
SOLUBILITY OF AMYL ALCOHOL IN WATER AT DIFFERENT TEMPERA-
TURES, " SYNTHETIC METHOD" (see Note, page 9).
(Alexejew Ann. phys. Chem. 28, 305, '86.)
Gms. CsHuOH per ioo Gms. Gms. CsHnOH per ioo Gms.
t o Aqueous Alcoholic t o ' Aqueous Alcoholic '
Layer. Layer. Layer. Layer.
o 97 ioo 2.0 80
20 6 94 120 4.0 77
40 4 9 J 4o 7.0 73
60 2 87 150 9.0 72
80 1.5 83
SOLUBILITY OF AMYL ALCOHOL IN AQ. ETHYL ALCOHOL SOLUTIONS.
(Bancroft Phys. Rev. 3, 193, '95-96.)
cr Fthvl cc.H 2 O added to cause Separation of a
AV*2a Second Phase in Mixtures of the given
in \!KT?. Amounts of Ethyl Alcohol and 3 cc.
Portions of Amyl Alcohol at:
' 9-1. 19- 2.'
3 13-21 3-50
6 10 .35 10.80
9 18.34 19.10
12 27.47 29.15
15 41-25 43-15
NOTE. The effect of various amounts of a large number of salts
upon the temperature (39.8) at which a mixture of 20 cc. of amyl
alcohol + 20 cc. of ethyl alcohol + 32.9 cc. of water becomes homo-
geneous has been investigated by PfeifTer (Z. phys. Ch. 9, 444, '92).
The results are no doubt of interest from a solubility standpoint, but
their recalculation to terms suitable for presentation in the present
compilation has not been attempted.
SOLUBILITY OF ISOAMYL ALCOHOL IN WATER.
Gms. Iso Amyl Alcohol per ioo Gms.
H20 Layer. 'Alcoholic Layer.
13 .7 2.0 Balbrano Ber. 9, 1437, '76
16.5 2.5 92.9 Wittstein Jahrb. 408, '62
22 2-61 97-36 Herz Ber. 31, 2669, '98
f.
'Aqueous
Layer.
Alcoholic
Layer.
20
27
66
10
28
00
27-5
56
10
26.0
57
20
22.5
00
30
18
63-5
40
16
65-5
60
13
67
80
15
63
IOO
20
S 2
107 crit.
temp. 33
120
ALCOHOLS 12
SOLUBILITY OF QUTY.L ALCOHOLS IN WATER, " SYNTHETIC METHOD "
(see Note, page 9).
(Alexejew Ann. phys. Chem. 28, 305, '86.)
Secondary Butyl Alcohol I so Butyl Alcohol
and Water. and Water.
Cms. Secondary Butyl Alcohol per 100 Cms. Cms. Iso Butyl Alcohol per too Gms.
Aqueous Alcoholic
Layer. Layer.
13 85
9 84
7-5 83
7 82
7 77-5
8 72
. . . ...
16 62
130 28 50
133 crit. temp. 40
DISTRIBUTION OF ETHYL ALCOHOL BETWEEN WATER AND BENZENE
AT 25.
(Taylor J. Phys. Ch. x, 468, '97.)
Composition of 10 cc. of Upper Layer. Composition of 10 cc. Lower Layer.
5.92 o. 2 6o 3.48 4-37 i-o7 4-5 6
6.43 0.48 3.09 3.54 1-41 S-5
7.40 0.29 2.31 2.04 2.27 5.69
8.13 0-17 1.70 i. 08 3.22 8.70
8.65 o.io 1.25 0.59 4-06 5.35
9.05 0.06 0.89 0.28 4.99 4.73
ALUMINIUM CHLORIDE A1C1 3 6 H 2 O.
SOLUBILITY IN WATER.
(Gerlach Z. anal. Ch. 8, 250, '69.)
ioo gms. saturated solution contain 41.13 gms. A1C1 3 at 15, Sp. Gr.
of solution = 1.354.
ALUMINIUM SULPHATE A1 2 (S0 4 ) 3 18 H 2 O.
SOLUBILITY IN WATER.
(Poggiale Ann. chim. phys. [3] 8, 467, '43.)
Gms. A1 2 (SO 4 )3 per 100 Gms. Gms. Al 2 (SO 4 )a. per ioo Gms.
t*. Water. Solution. t. Water. Solution.
o 31.3 23.8 60 59.1 37-2
J o 33-5 25.1 70 66.2 39.8
20 36.1 26.7 80 73-1 42 2
30 40.4 28.8 90 80.8 44.7
40 45-7 3 I -4 ioo 89.1 47.1
50 52.1 34.3
ioo gms. of a saturated solution of aluminium sulphate in glycol con-
tain 14.4 gms. A1 2 (SO 4 ) 3 . (de Coninck Bull. acad. roy. Belgique, 3 S9, '05-)
ALUMS
ALUMS.
SOLUBILITY OF AMMONIUM ALUM AND OF POTASSIUM ALUM
IN WATER.
(Mulder; Poggiale Ann. chim. phys. [3] 8, 467, '43; Locke Am.Ch. J.z6, 174, '01; Marino
Gazz. chim. ital. 35, II, 351, '05; Berkeley Trans. Roy. Soc. 203 A, 214, '04.)
Ammonium Alum.
Potassium Alum.
t.
Gms. (NH 4 ) 2
A1 2 (S0 4 ) 4
Gms. (NH*)*
A1 2 (S0 4 ) 424 H 2
G.M.(NH 4 ) 3
A1 2 (S0 4 ) 4
Gms. K 2
A1 2 (S0 4 ) 4
Gms. K 2
A1 2 (S0 4 ) 4 2 4 H 2
G. M. K 2
A1 2 (S0 4 ) 4
per 100 g.
per 100 g.
per 100 g.
per loo g.
per 100 g.
per loo g.
H 2 0.
H 2 O.
H 2 0.
H 2 O.
H 2 O.
H^.
2.IO
3-90
O.OO44
3.0
5-65
0-0058
5
3-50
6.91
O.OO74
3-5
6.62
O.OO68
10
4-99
9-52
O.OIO5
4-0
7.60
0.0077
IS
6-25
12.66
0.0132
5 -
9-59
0.0097
20
7-74
15.13
0-0163
5-9
11.40
O.OII4
2 5
9.19
19.19
O.OI94
7-23
14.14
O.OI4O
30
10.94
22 -OI
O.O23I
8-39
16.58
O.OI62
40
14.88
30.92
0.0314
ii .70
23-83
O.O227
50
20. 10
44-10
0.0424
17.00
36.40
0.0329
60
26.70
66.65
0.0569
24-75
57-35
0.0479
70
40.0
110.5
0.0774
80
71.0
321-3
0.1374
90
109.0
2275.0
O-2IIO
92 5
119.0
oo
0.2313
95
109.7
00
0.2312
NOTE. The potassium alum figures in the preceding table were
taken from a curve plotted from the closely agreeing determinations of
Mulder, Locke, Berkeley, and Marino. For the higher temperatures
(above 60), however, the results of Marino are lower than those of
the other investigators, and are omitted from the average curve.
Locke called attention in his paper to the fact that Poggiale's results
upon ammonium and potassium alum had evidently become inter-
changed through some mistake. This explanation is entirely sub-
stantiated, not only by Locke's determinations, but also by those of
Mulder and Berkeley. The ammonium alum figures given above were
therefore read from Poggiale's potassium alum curve, with which
Locke's determination of the solubility of ammonium alum at 25 is in
entire harmony.
SOLUBILITY OF AMMONIUM ALUM IN PRESENCE OF AMMONIUM SUL-
PHATE AND IN PRESENCE OF ALUMINIUM SULPHATE IN WATER.
Mixture Used.
(Rudorff Ber. 18, 1160, '85.)
TOO Gms. Saturated Solution Contain:
Grams (NH 4 ) 2 SO 4 + Grams A1 2 (SO 4 ) 3 .
Saturated Ammonium Alum at 18.5 1.42 3-69
20 cc. above sol. + 6 gms. cryst. A1 2 (SO 4 ) 3 . . . 0.45 16.09
20 cc. above sol. -f 4 gms. cryst. (NH 4 ) 2 SO 4 . . . 20.81 0.29
ALUMS
SOLUBILITY OF MIXTURES OF POTASSIUM ALUM AND ALUMINIUM SUL-
PHATE AND OF POTASSIUM ALUM AND POTASSIUM SULPHATE
IN WATER.
(Marino Gazz. chim. ital. 35, II, 351, '05.)
Gms. per logo Gms. H 2 O.
K 2 S0 4 .
243-73
23-45
O.I
20
824.25
30.85
I 5- 1
35
911 .02
35-29
24.1
5o
1243.21
59-55
33-5
65
1598.00
ii9-43
43.1
77
1872.11
183.80
50-5
5.06
75.83
O.I
0.5
8.66
75.18
0.2
5-
16.07
85.78
0-4
10
18.52
96.50
o-5
15
20.56
109.30
0-55
30
39.60
147.8
I .0
40
73-88
163.1
1.9
50
126.0
195-4
3-4
60
249-7
238-8
6-7
70
529.0
3 2 3 7
14.2
80
1044.0
517-27
28.1
Gm. Mols. per i OOP Mols. H 2 O.
Al 2 (S0 4 ) 3 .i8H 2 0. K 2 S0 4 /
2-3
3-6
6.1
12.6
18.9
7-8
7-7
8.8
99
II. 2
15.2
16.8
20. i
24.6
32.6
53-4
Solid
Phase.
K 2 A1 2 (S0 4 ) 2 . 24 H 2
+ A1 2 (S0 4 ),
K 2 A1 2 (S0 4 ) 2 . 24 H 2
+ K 2 S0 4
SOLUBILITY OF MIXTURES OF POTASSIUM ALUM AND OF THALLIUM
ALUM IN WATER AT 25.
(Fock Z. Kryst. Min. 28, 397, '97.)
K 2 A1 2 (S0 4 ) 4 .2 4 H 2 ; T1 2 A1 2 (SO 4 ) 4 .2 4 H 2 O.
Composition of Solution.
Solid Phase
Mol. % of
Potassium
KAl(SO 4 ) 2 j>er Liter.
T1A1(SO 4 ) 2 per Liter.
Mol. % Sp. Gr. of
Grams.
Mg. Mols.
Grams.
Mg. Mols.
KA1(SO 4 ) 2 . Solutions.
Alum.
69.90
270.5
o.oo
0-00
100
.0591
100.
74-56
288.2
0.48
I-I3
99.61 ]
.0601
99 32
67.90
262.8
1.72
4.07
98.48 3
.0598
96.84
65-30
252.7
4.52
10-67
95-95 i
.0603
90-84
64-95
251.4
9.60
22.67
91.73 .]
0605
82.94
53-23
205.9
18.44
43.56
82.54 i
.0609
68.24
45-32
175-4
24.60
58.10
7S-"
0609
58.23
38.02
147.2
32.48
76.75
65.73 1.0611
46.72
34-54
133-6
35-59
84.10
61.36 1.0611
44-23
28-35
109.7
42.99
101.60
51.93 1.0623
32.07
10.94
42-4
66.12
156.2
21.34 1-0654
7-94
O-OO
O-O
75-46
178-3
o.oo 1.0674
0-00
ALUMS
SOLUBILITY OF SODIUM ALUM IN WATER.
100 gms. H 2 O dissolve 51.0 gms. (?anhy.) Al 2 Na 2 (SO 4 ) 4 .24H 2 O at 16.
(Auge Compt. rend, no, 1139, '90.)
ioo gms. H 2 O dissolve no.o gms. Al 2 Na 2 (SO 4 ) 4 .24H 2 O at o.
(Tilden J. Ch. Soc. (Lond.) 45, 269, '84.)
SOLUBILITY OF CAESIUM ALUM, RUBIDIUM ALUM, AND OF THALLIUM
ALUM IN WATER.
(Setterburg Liebig's Annalen, 211, 104, '82; Locke Am. Ch. J. 26, 183, '01; Berkeley Trans.
Roy. Soc. 203 A, 215, '04.)
Caesium Alum.
Rubidium Alum.
Thallium Alum.
Gms. per ioo Gms. HaO.
Gms. per ioo Gms. H2O.
Gms. per ioo Gms. H 2 O.
Al2Cs 2 (S0 4 ) 4 . A1 .f 4 % ( 2 S (? 4) *
Al 2 Rb 2 (S0 4 ) 4 . A1 f 4 ^)*
A1 2 T1 2 (S0 4 ) 4 . A1 {|(J>
0-21 0.34
0.72 I. 21
3- I 5 4-84
5
0-25 0-40
0.86 1.48
3 .80 5.86
10
0.30 0-49
1.05 1.81
4.60 7-12
2O
o . 40 o . 65
1.50 2.59
6.40 10.00
25
0.50 0.81
i. 80 3.12
7.60 11.95
30
0-60 0.97
2.20 3.82
9.38 14.89
40
0.85 1.38
3 2 5 5.69
14.40 23.57
50
1.30 2. II
4.80 8.50
22.50 38.41
60
2.00 3.27
7.40 13.36
35-36 65.19
70
3-20 5.27
12.40 23.25
80
5.40 9-01
21. 60 43.25
... ...
90
10.50 i8.ii
...
IOO
22.70 42-54
...
...
NOTE. Curves were plotted from the closely agreeing determina-
tions recorded by the above named investigators and the table con-
structed from the curves.
AMINES.
METHYL AMINE AND TRI METHYL
Water and Amyl Alcohol.
(Herz and Fischer Ber. 37, 4751, '04.)
AMINE, DISTRIBUTION BETWEEN:
Water and Benzene.
(Herz and Fischer Ber. 38, 1143, '05.)
Gms. NH 2 (CH 3 )
per ioo cc.
Millimols NH 3 (CH 3 )
per 10 cc.
Gms. N(CH3) 3
per i po cc.
Millimols N(CH 3 ) 3
per^io cc.
Aq.
Alcoholic
Aq.
Alcoholic
Aq.
i
CeH*
Aq.
CaHe
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
o-37
O-I2
1.155
.3804
O
345
O
.174
O
5 8 4
0.295
0.94
o 33
3-036
I
.070
O
.812
O
396
I
377
0-670
i .57
o-54
5-054
I
759
I
075
545
I
.819
0.921
i.8 9
0.69
6.083
2
.219
I
.462
731
2
474
1.237
2.00
0.72
6.429
2
.315
2
139
I
.077
3
.619
1.823
2-53
0.92
8.126
2
981
2
757
I
376
4
.663
2.328
3-30
1.24
10.613
3
974
3
.292
z
683
5
.568
2.847
3
996
2
053
6
.760
3-474
6
582
3
465
ii
5.861
AMINES
16
SOLUBILITIES OF Di ETHYL
AMINE AND WATER.*
(Lattey Phil. Mag. [6] 10, 398, '05.)
Cms. NH(C2Hs) 2
per 100 Gms.
t.
155
ISO
148
146
145
144
Aqueous
Layer.
21-7
23-6
24.8
26-3
28.0
3 I.O
Amine
Layer.
S9-o
55-5
53-5
51.0
49.0
45-o
DISTRIBUTION OF TRI ETHYL AMINE
BETWEEN WATER AND AMYL
ALCOHOL AT 25.
(Herz and Fischer Her. 37, 4751, '04.)
Gms. N(C 2 Hc) 3 Millimols N(C2H6) S
per zoo cc. per 10 cc.
Aqueous
Layer.
Alcoholic
Layer.
Aqueous
Layer.
Alcoholic
Layer.
0.0885
0.1683
o . 1866
0.2502
2.299
4-457
4.922
6.491
0.0875
o . 1664
0-1846
0.2474
2.273
4-408
4.868
6.418
143.5 (crit-t) 37-4
Tri Ethyl AMINE
N(C 3 H 5 ) 3 .
SOLUBILITY IN WATER.
(Rothmund Z. phys. Ch. 26, 433, '98.)
h o Gms. N(C 2 Hs)s per too Gms. 1
Gms. N(C2H 6 )3 per 100 Gms.
Aq. Layer.
Amine Layer.
Aq. Layer.
Amine Layer.
18.6 (crit. temp.) 51
9
40
3-65
96.48
20
14.24
72.0
50
2.8 7
96.4
25
7-30
95.18
55
2-57
96.3
30
5-80
96.60
60
2.23
9 6 3
35
4.58
9 6 -5
65
1.97
96 3
SOLUBILITY OF TRI ETHYL AMINE IN MIXTURES OF WATER AND ETHYL
ALCOHOL AT DIFFERENT TEMPERATURES.*
(Meerburg Z. phys. Ch. 40, 647, '02.)
o% Alcohol. 13-33% .Alcohol. 28.08% Alcohol. 38.84% .Alcohol. 60.16% Alcohol
t . per loo t.
G. NCCaHjOa G. N(
per 100 t . per
CgHs'
100
13 G. N(<
t. per
-2Hs]
100
3 G. N(C 2 H 6 ) 3
t . per 100
g.sol.
g.sol.
g.sol.
g.sol.
g. sol.
69.2
i-7
38-3
8.2
54-5
22
.8
73
4
31
.2
76-77 71.2
30.8
5-6
13-9
29
.8
65
4
33
3
74-75 75-o
23.1
8-5
28.0
21.6
33-4
51
.1
5i
.6
40
.6
72-73 80.0
I8. 7
25-8
26.4
30.6
63
7
42
-i
So
.6
I8. 7
37-2
24.9
40.5
30-3
68
5
40
9
54
7
19-5
51-8
24.2
49-8
28.5
82
.2
34
.2
70
.6
20-5
68.6
24.1
60.7
35-o
9i
.8
33
O
77
5
20-5
84.0
24.0
69.7
34
7
88
20.5
89.7
23-5
73-6
40
5
91
.3
21-4
92.4
24.0
81-5
25-8
95-5
24.2
87.4
26-5
96.1
25.0
92.0
NOTE. Results for Tri Ethyl Amine, Water and Ethyl Ether, and for
Tri Ethyl Amine, Water and Phenol are also given by Meerburg.
100 gms. abs. methyl alcohol dissolve 57.5 grams NH(C 6 H S ) 2 at 19.5.
100 gms. abs. ethyl alcohol dissolve 56.0 grams NH(C 6 Hg) 2 at 19.5.
(de Bruyn Z. phys. Ch. 10, 784, 1802.)
* Determinations made by " Synthetic Method," see Note, page 9.
i; AMINES
SOLUBILITY OP Di PHENYL AMINE AND ALSO OF TRI PHENYL AMINE IN
CARBON BISULPHIDE.
(Arctowski Compt. rend. 121, 123, '5.)
NH(C6H 5 ) 2 in CS 2 . N(C 6 H 5 ) 3 in CS*
A.O Gms. per 100 . o Gms per 100
Cms. Solution. Gms. Solution.
-88i 0.87 -83 1.91
-117 0-37 -91 1.56
~ IO2 1.24
-II3i 0.98
SOLUBILITY OF Di PHENYL AMINE IN HEXANE AND IN CARBON
BISULPHIDE.
(Etard Ann. chim. phys. [7] 2, 570, '94.)
Gms. NH(C6H 8 ) 2 Gms. NHCCeHsk
per IPO Gms. Sol, in: per 100 Gms. Sol, in;
Hexane. CS^ Hexane. CS^
60 ... 1.3 o 2.6 33.7
50 ... 2.2 +10 3.8 46.8
40 ... 3.8 20 6.7 60-9
~30 0-5 7-2 30 13.8 76.0
20 0.8 12.5 40 47.0
io 1.4 21.6 50 94.0
AMMONIA NH 3 .
SOLUBILITY OF AMMONIA IN WATER.
(Roscoe and Dittmar Liebig's Annalen, 112, 334, '50; Raoult -
Am. Ch. J. 19, 807, '97.)
- Ann. chim.
[5] i. *6a, '74; Mallet
At 760 mm. Pressure.
At 760 mm. Pressure.
t tt .
G. NH 3
per 100 g.
H 2 0.
Vol. NHa
per i g.
H 2 0.
t.
GJSTHa
per TOO g.
H 2 0.
Vol. NHa
per i g.
%0.
-40
-30
20
294.6
278.1
176.8
...
20
2$
30
52.6
46.0
40-3
710
635
595 (28)
io
III-5
87-5
1299
35
40
35-5
30-7
5
10
15
77-5
67.9
60.0
1019
910
802
45
5o
56
27.0
22.9
18.5
...
SOLUBILITY OF AMMONIA IN AQUEOUS SALT SOLUTIONS.
(Raoult.)
la Calcium Nitrate Solutions In Potassium Hydroxide Solutions
Gms. NH 3 per too Gms. NHa per 100
Gms. Solvent in: Gms. Solvent in:
cS&. IBfP
o 96.25 104-5 72-0 49.5
8 78.50 84.75 57-o 37-5
16 65.00 70.5 46.0 28.5
24 ... ... 37-3 21.8
AMMONIA 18
MUTUAL SOLUBILITY OP AQUEOUS AMMONIA AND POTASSIUM CARBON-
ATE SOLUTIONS.
(Newth J. Chem. Soc. 77, 7?6, 1900.)
The solutions used were: Potassium Carbonate saturated at 15
(contained 57.2 grams K 2 CO 3 per 100 cc.). Aqueous Ammonia of
0.885 Sp. Gr. (contained about 33 per cent ammonia). The determina-
tions were made by adding successive small quantities of one of the
solutions to a measured volume of the other, and observing the point
at which opalescence appeared.
Saturated K 2 COa in Aq. Ammonia. Aq. Ammonia in Saturated K 2 COs.
t. cc. KzCOs per %K 2 CO 3 Solution cc. Ammonia %K 2 CO 3 Solution
100 cc. Ammonia. in Mixture. in 100 cc. K 2 COa. in Mixture.
I 2.0 2.0 37-5 72.7
6 3.0 3.0 47-5 6 7-6
ii 5.0 4-7 5 2 5 6 5-o
16 6.5 6.1 60-0 63.0
21 8.5 8.0 77.5 56.3
26 10.5 9.5 105-0 49.0
31 12.5 ii. i 152.5 39.0
38 20.0 16.6 195 .o 33.0
39 21.0 17.0 220-0 31.0
42 25.0 20- o 250-0 28.5
43 35.0 26.0 285.0 26.5
Above 43 the solutions are completely miscible. If 10 per cent of
water is added to each solution the temperature of complete miscibility
is lowered to 25. The mutual solubilities are:
Per cent K 2 CO 3 Solution in:
t. Ammonia K 2 CO 3 Sol.
Layer. Layer.
o 8 62
10 ii 52
20 15 38
25 (crit. pt.) 25
With the addition of 12.9 per cent of water to each solution the
temperature of complete miscibility (crit. pt.) is lowered to 10. With
the addition of 18.1 per cent water this temperature becomes o.
SOLUBILITY OF AMMONIA IN ABSOLUTE ETHYL ALCOHOL.
(Delepine J. pharm. chim. [5) 25, 496, 1892; de Bruyn Rec. trav. chim. ii, 112, '92-)
A O
Cms
. NH 3
Cms. NHs per 100 Gms. Solution.
Gms. NHs per 100 Gms. Alcohol
t .
Density.
per loo cc.
Solution.
(Delepine.)
(de Bruyn.)
(Delepine.)
(de Bruyn.)
0-782
!3
OS
20
95
19
7
26
5
24
5
5
0-784
12
OO
19
.00
17
5
23
.0
21
.2
10
0-787
10
85
16
43
15
.0
19
.6
17
.8
IS
0.789
9
.20
13
.00
13
.2
15
o
*s
.2
20
0.791
7
SO
10
.66
II
5
II
9
13
.2
25
0-794
6
OO
10
o
10
.0
II
.0
II
.2
30
0.798
5
IS
9
7
8
.8
10
7
9
5
AMMONIA
SOLUBILITY OF AMMONIA IN AQUEOUS ETHYL ALCOHOL.
(Delepine.)
In 96%. Alcohol.
In 90%. Alcohol.
In 8o% A Alcohol.
t.
Sp. Gr.
Solution.
G. NH 3 per'
100 Gms. Sol.
Sp. Gr.
Solution.
G. NH 8 per
too Gms. Sol.
Sp. Gr.
Solution.
G. NH S per
loo Gms. Sol.
O
0.783
24-5
0.800
30.25
0.8o8
39-o
10
0.803
18.6
Q-794
28.8
O.8OO
28.8
20
0.788
14.8
0-795
15-8
0.821
19.1
30
0.791
10.7
0.796
II.4
0.826
12.2
In 60% Alcohol.
In 50% Alcohol.
t.
Sp. Gr.
G. NH 3 per
Solution.
100 Gms. Sol
O
0.830
50-45
IO
0.831
37-3
20
0.842
26.1
30
0-846
21 .2
Sp. Gr.
Solution.
0.835
0-850
0.869
0.883
G. NHs per
100 Gms. Sol.
69.77
43-86
33-8
25 -2
SOLUBILITY OF AMMONIA IN ABSOLUTE METHYL ALCOHOL.
(de Bruyn Rec. trav. chim. n, 112, '92.)
. G. NHs per 100 Grams.
G. NH 3 per^ioo Grams.
Solution. Alcohol.
o 29.3 41.5
5 26.5 36.4
10 24.2 31.8
15 21.6 27.8
20
25
30
Solution.
19.2
I6. S
14-0
Alcohol.
23-8
2O. O
16.0
DISTRIBUTION OF AMMONIA BETWEEN:
Water and Amyl Alcohol at 20'
(Herz and Fischer Ber. 37t
4747, '04.)
Water and Chloroform at 20.
(Dawson and McCrae J. Ch. Soc. ?g, 496, '01; see
also Hantsch and Sebaldt Z.phys.Ch.ao, 258, '99.)
Gms.NHsperioocc.
G
. M. NHs per 100 cc.
Gms. NHs per 100 cc.
G.
M. NH$ per 100 cc.
Aq.
Alcoholic
Aa.
Alcoholic
Aq.
CHClg
Aq.
CHC1 3
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
o-5
0.072
2 5
0.0035
0.2
O.OO7
O
.01
.00038
I .0
0-147
50
0.0073
0-4
0.015
O
.02
.00073
2 -O
O.272
I
OO
0-0148
0.6
0.023
O
03
O
OOII4
3-o
0.438
2
OO
0-0295
0.8
0.031
O
.04
.OOI52
4-0
o-595
3
OO
0-0460
I.O
0-039
O
05
.00193
5-o
0.756
I .2
0-046
.06
.00232
1-4
0-055
O
-08
.00311
1.6
0-063
O
.10
O
.00396
NOTE. The influence of a large number of electrolytes upon the
distribution of ammonia between water and chloroform was also
investigated. For calculations of above distribution results, see Note,
page 4.
AMMONIUM ARSENATES 20
SOLUBILITY OF AMMONIUM CALCIUM ARSENATE AND AMMONIUM
MAGNESIUM ARSENATE IN WATER, ETC.
(Field J. Ch. Soc. u, 6, '73.)
Grams per too Grams Solvent.
Solvent.
NH4CaAs0 4 *H,0 . . _____
Water 0.02 o 014
Aq. Ammonia 10% (Sp. Gr. 0.88) o.ooi 0.007
Aq.NH 4 Cl 5% 0.415
Aq. NH 4 Cl 10% . . 0.095
AMMONIUM BENZOATE NH 4 C 7 H 6 O 2 .
SOLUBILITY IN WATER AND IN ALCOHOL.
Gms. NH 4 C7HsO2 per ioo Gms. Solvent in :
t. Water. Alcohol.'
25 9.52 4.0
b- pt. 83.33 13.2
AMMONIUM BROMO PLATINATE (NH 4 ) 2 PtBr 6 .
ioo gms. sat. aq. solution contain 0.59 gm. (NH 4 ) 2 PtBr 6 at 20.
(Halberstadt Ber. 17, 2965, '84.)
AMMONIUM BROMIDE NH 4 Br.
SOLUBILITY IN WATER.
(Eder Abh. K. Akad. Wiss. (Berlin) 82 ii, 1284, '80.)
Gms. NH 4 Br. per ioo Grams. Gms. NH 4 Br. per ioo Grams.
t. 'Solution. Water." t. Solution. Water.
10 39.8 66.2 50 48-5 94-3
20 42.5 74-0 60 50.2 IOI.O
30 44.8 81.3 80 53.5 II5.0
40 46.7 87.5 ioo 56.1 128.2
SOLUBILITY OF AMMONIUM BROMIDE IN ABSOLUTE ETHYL ALCOHOL,
METHYL ALCOHOL, AND IN ETHER.
(Eder; de Bruyn Z. phys. Ch. 10, 783, '92-)
In Ethyl Alcohol. In Methyl Alcohol. In Ether (0.729 Sp. Gr.).
Gms. NH^r Gms. NH^r Gms. NH^r
per ioo Grams. per ioo Grams. per ioo Grams.
t. Solution. Alcohol. Solution. Alcohol. Ether.
15 2.97 3.06 0.123
19 3-12 3.22 II. I 12.5
78 9-5 10.50 *;"
Solubility of Tetra Ethyl AMMONIUM BROMIDE N(C 2 H 5 ) 4 Br, and
of Tetra Methyl Ammonium Bromide N(CH 3 ) 4 Br in Acetonitril.
(Walden Z. phys. Ch. 55, 712, '06.)
ioo cc. sat. solution in CH 3 CN contain 9.59 gms. N(C 2 H 5 ) 4 Br at 25.
ioo cc. sat. solution in CH 3 CN contain 0.17 gm. N(CH 3 ) 4 Br at 25.
AMMONIUM CADMIUM BROMIDE NH 4 Br.CdBr 2 .H 2 O.
ioo parts of water dissolve 137.0 parts NH 4 Br.CdBr 2 .iH 3 O.
ioo parts of alcohol dissolve 18.8 parts NH 4 Br.CdBr 2 .$H 2 O.
ioo parts of ether dissolve 0.36 part NH 4 Br.CdBr 2 .$H 2 O.
(Eder Dingier polyt. J. 221, 89, *76.>
21
AMMONIUM CARBONATE
AMMONIUM CARBONATE (NH 4 ) 2 CO 3 .
100 grams H 2 O dissolve 100 grams (NH 4 ) 2 CO 3 H 2 O at 15.
100 grams glycerine dissolve 20 grams (NH 4 ) 2 CO 3 at 15.
(Divers J. Ch. Soc. 23t 171, J ?o.)
AMMONIUM BICARBONATE NH 4 HCO 3 .
SOLUBILITY IN WATER.
(Dibbits J. pr. Ch. [2] 10, 417. '74 )
9 Cms. NILJICOs per 100 Grams.
Solution. Water'.
O 10.6 II-9 20
5 I2 -i I 3-7 25
10 13.7 i5- 8 30
15 J 5-5 l8 -3
Grams NHjNCOs per TOO Grama.
Solution. Wate?.
17.4 21.0
19.3 23.9
21.3 27.0
SOLUBILITY OP AMMONIUM BICARBONATE IN AQUEOUS SOLUTIONS OP
AMMONIUM CHLORIDE SATURATED WITH CO 2 .
(Fedotieff Z. phys. Ch. 49, 168, '04.)
Per 1000 cc. Solution.
Per 1000 Grams HjO.
4.0 Wt.OI
* i cc. Sol.
o
G.
NP
M.
uci.
G. M. Gms.
NILJICOs. NH4C1.
Gms
NILJI
COa.
G. M.
NH4C1.
o.o
G. M.
NILJICO
I .22
Gms.
3. NIL^Cl.
o.o
Gms.
NILJICOs.
II9.0
o 1.077
4
.41
o-37
235-9
2 9
.2
5-42
0.46
290.8
36.0
15
.064
.0
2.12
o.o
I6 7
.2
o.o
2.36
o.o
186.4
15
.063
o
5
1.84
26.8
145
.2
0.56
2.06
29.9
162.9
15
.O62
I
.0
I .59
53-5
125
5
1-13
1. 80
60.6
142.2
15
.062
I
.41
1.42
75-4
112
.2
I .60
85-1
126.9
15
-06 5
I
.89
4.28
100.8
101
.1
2.18
1.48
II6.8
II6.8
15
.069
2
.87
0-99
153-3
78
.2
3-42
1.18
183.0
93-3
15
.076
3
.84
0-79
205.2
62
5
5-03
0.98
269.3
77-3
15
.085
4
.82
0.65
257-9
5 1
4
6.21
0.84
332.5
66.4
085
4
95
O.62
264.8
48
9
6.40
0.81
343-5
64.2
3 ...
o.o
3-42
o.o
270.0
7O
7.4
i .ic
107.0
OI.O
SOLUBILITY OF AMMONIUM BICARBONATE IN AQUEOUS SOLUTIONS OP
SODIUM BICARBONATE SATURATED WITH CO 2 .
(Fedotieff.)
Per looo cc. Solution. Per 1000 Grams H^O.
t.
o
o
15
15
7O
Wt ' f , r G. M. G. M. Gms. Gms.
i cc. bol. NaHCC , 3 . NILJICOa. NaHCO 3 . NILJICOs.
G. M. G. M. Gms.
NaHCOs. NILJICOs. NaHCO 3 .
o.o 1.51 o.o
0.58 1.39 48.2
o.o 2.36 o.o
0.71 2.16 59-2
o.o 3.42 o.o
0.8.1 2.01 70-0
Gms.
II9.0
109.4
186.4
170.6
270.0
210-0
1.072 0.53
1.064 o.o
1.090 0.63
1.28
2.12
1.92
44.6
o.o
52.5
101.4
167.2
151-3
AMMONIUM BICARBONATE 22
SOLUBILITY OF MIXTURES OF AMMONIUM BICARBONATE, SODIUM
BICARBONATE, AND AMMONIUM CHLORIDE IN WATER
SATURATED WITH CO 2 .
(Fedotieff.)
Solid
Phase.
a -h c
u
t o Wt.of
* icc. Sol.
o 1.114
Gms HaO. Gms ' *** IOO Gms ' H2 '
NaHC0 3 . NaCl.
O-59 0.96
NH*U.
4.92
NaHC0 3 .
49.61
NaCl.
56.16
NH4C1.
263.4
o 1.187
O
.12
4
83
2
74
10
.09
282.6
146.7
15 1.116
93
5 1
6
.28
78
.18
29.84
336.2
15 1.178
O
.18
4
44
3
73
15
13
259.8
199.6
15
.151
O
30
3
.09
4
56
25
.22
l8o.8
244.1
.128
5 1
z
68
5
45
42
87
98.28
291.7
15
.112
O
99
o
35
5
65
83
.22
20-47
302.4
15
.I08
I
.07
20
5
.21
89
95
11.70
278.9
15
.IO6
I
.12
ii
4
.92
94
.14
6.44
263.4
r 5
.101
I
.16
o
14
4
OO
97
52
8.19
2I4.I
.090
O
93
o
95
2
03
78
.18
55-58
108.6
a = NaHCO 3 , b = NH 4 HCO 3 , c = NH 4 C1.
AMMONIUM URANYL CARBONATE 2 (NH 4 ) 2 CO 3 UO 2 CO 3 .
(Ebelmen.)
100 grams H 2 O dissolve 5 grains of the salt at 15.
AMMONIUM LEAD COBALTICYANIDE NH 4 PbCo(CN) 6 .3H 2 O.
(Schuler Sitz. Ber. K. Akad. W. (Berlin) 79, 302.)
100 grams H 2 O dissolve 12.0 grams of the salt at 18.
AMMONIUM CHLORIDE NH 4 C1.
SOLUBILITY IN WATER.
(Mulder; below o, Meerburg Z. anorg. Ch. 37, 203, 1003.)
Gms. NH4C1 per 100 Gms. Gms. NH 4 C1 per TOO Cms.
Solution. Water. Solution. Water.
-15 19.7 24.5 40 31-4 45-8
-10.9 20-3 25.5 50 33.5 50.4
-5.7 21.7 27.7 60 35.6 55.2
o 22.7 29.4 70 37.6 60.2
+ 5 23.8 31.2 80 39-6 65.6
10 24.9 33.3 90 41-6 7i-3
15 26.0 35.2 100 43 - 6 77-3
20 27.1 37.2 no 45-6 83.8
25 28.2 39.3 115.6 46.6 87.3
30 29.3 41.4
Density of saturated solution at o = 1.088, at 15 = 1.077, at I 9 <
- 1.075.
23 AMMONIUM CHLORIDE
SOLUBILITY OF AMMONIUM CHLORIDE IN AQUEOUS AMMONIUM BI-
CARBONATE SOLUTIONS SATURATED WITH CO 2 .
(Fedotieff Z. phys. Ch. 49, 169, 1904.)
Wt f
Per 1000 cc. Solution.
Per 1000 Gms. H 2 O.
t p .
i cc. Sol.
G.M.
G
. M.
Gms. Gms.
G.M.
G
. M.
Gms.
Gms.
NH 4 HCO 3 .
NI
NH 4 HCO 3 . NH4C1.
NH4HC03.
NP
NHHC1.
NH4C1.
o
I
.069
O-O
4
.60
o.o 246.1
o.o
5-
57
0-0
298.0
I
.077
o-37
4
41
29.2 235.9
0.46
5-
42
36.0
290-8
15
I
.077
o.o
5
29
o.o 283.1
o.o
6.
64
0-0
355-o
15
I
085
0.62
4
95
48.9 264.8
0.81
6.
40
64.2
343-5
30
0-0
7-
78
O-O
416.4
2O
I .IS
7 .
40
OI .0
307 .0
SOLUBILITY OF AMMONIUM CHLORIDE IN AQUEOUS SOLUTIONS OF
SODIUM CHLORIDE SATURATED WITH CO 2 .
(Fedotieff.)
Per 1000 cc. Solution.
Per 1000 Gms. H 2 O.
t.
Wt. of
G.
M.
G. M. Gms. Gms.
G.
M.
G.
M.
Gms.
Gms
^
i cc. Sol.
NaCl.
NH4C1. NaCl. NH4C1.
NaCl.
NH 4 C1.
NaCl.
NH 4 C1.
I .069
O
.0
4.60 o.o 246.1
O
O
5-
57
o.o
298.
o
o
1.085
4
.04
2 .26 236.5 121 -O
4
.89
2.
73
286.4
146.
i
15
1.077
o
O
5.29 o-o 283.1
o
.0
6.
64
o.o
355-
15
1.097
.81
4.71 47.5 252.1
I
.02
5-
9i
59-8
316-
4
15
I .I2O
I
.68
4.13 98.0 221-7
2
.09
5-
18
122.4
277.
o
15
I - I 53
2
.87
3.38 168.0 180.7
3
57
4-
20
208.9
224.
7
15
I - I 75
3
65
2.98 213.5 159.4
4
55
3-
72
266.8
198.
8
30
.0
7-
78
o.o
416.
4
30
1.166
3
30
3.70 193.0 198.0
4
.26
4-
77
249.0
255-
4
45
O
9-
03
o-o
483-
7
45
4
.0
6.
02
233-9
322.
i
SOLUBILITY OP
AMMONIUM CHLORIDE IN
AQUEOUS
SOLUTIONS OP
HYDROCHLORIC ACID AT
0.
(Engel Ann. chim. phys. [6] 13,
379, '88.)
Sp. Gr. of
Solutions.
Milligram Molecules per
10 cc. Solution.
Grams per 100 cc.
Solution.
HC1. NH4C1.
'HC1.
NH4C1.
i
.076
o-o 46.12
.0
24.61
i
.069
2.9 43 - 6
I
05
23.16
i
.070
5-5 4i-o
I
99
21.78
i
.071
7-85 39 -!5
2
.84
20.79
i
073
10.85 36.45
3
93
19.36
i
.078
21.4 27.37
7
74
14-54
i
.106
53.0 10.87
19
.18
5-78
I
.114
61.0 8.8
22
.07
4.67
Sat.
HClati2
3. 7 at
17
AMMONIUM OHLORIDE
24
SOLUBILITY IN AQUEOUS AMMONIA SOLUTIONS AT o.
(Engel Bull. soc. chim. [3] 6, 17, 1891.)
Sp. Gr. of
Solutions.
1.067
1.054
1.031
1.025
I .017
0-993
0.992
0-983
o-953
0.931
Milligram Molecules
per 10 cc. Solution.
NH 3 .
NH4C1.
5-37
45-8
12.02
45-5
38.0
44-5
47-0
44.0
54-5
43 -63
80.0
43.12
90.0
44.0
95-5
44-37
130.0
49-75
169-75
60-0
Grams per 100 cc.
Solution.
NH40H.
NH4C1.
0.92
24.52
2.05
6.48
8.02
24-35
23.82
9-30
13-66
23-35
23-09
16.29
22.18
28.97
23 75
26.63
32.14
SOLUBILITIES OF MIXTURES OF AMMONIUM CHLORIDE AND OTHER SALTS
IN WATER.
(Riidorff, Karsten, Mulder.)
Both salts present in solid phase.
AO Grams per 100 Grams H2O.
<> Grams per 100 Grams H 2 O.
19.5 29 . 2 NH 4 C1+ 1 74 . o NH 4 NO 3 R
21.5 26.8 " + 4 6.5(NH 4 ) 2 SO 4 R
20.0 33.8 " + n.6BaCl 2 R
18.5 39.2 " + i7.oBa(NO 3 ) 2 K
15.0 28.9 " + I6.9KC1 R
22.0 30.4 " -f- 19.1 KC1 R
b.pt. 67.7NH 4 Cl+2i. 9 KCl M
14.8 38.8 " + 34 .2KNO 3 K
18.5 39.8 " + 3 8.6KN0 3 K
14.0 36.8 " H-i 4 .iK 2 S0 4 R
18.7 37.9 " +i 3 . 3 K 2 S0 4 K
18.7 22.9 " +23. 9 NaCl R
SOLUBILITY OF AMMONIUM CHLORIDE IN ABSOLUTE ETHYL AND METHYL
ALCOHOL AT 19 AND IN AQUEOUS ETHYL ALCOHOL
SOLUTIONS.
100 grams absolute ethyl alcohol dissolve 0.62 grams NH 4 C1.
100 grams absolute methyl alcohol dissolve 3.35 grams NH 4 C1.
(de Bruyn Rec. trav. chim. u, 156, '92.)
In Aqueous Alcohol at 30.
(Bathrick J. Physic. Chem. i, 159, '96.)
Wt. per cent
Alcohol.
G. NH 4 C1
per 100 g.
Alcohol.
Wt. per cent
Alcohol.
G. NH 4 C1
per 100 g.
Alcohol.
40.4
45-9
17-0
8.3
35-3
54-3
14.0
16.9
3i-8
65 -o
9 .6
25-9
27-5
75-6
6. 4
34-4
21.7
87.9
2-9
In Aq. Alcohol of 45 Wt. %.
(Gerardin Ann. chim. phys. [4] 5, 147, '65.)
f ~
G. NH 4 C1
t .
per 100 g.
Alcohol.
4
II .2
8
12 .6
27
19.4
38
23-6
56
30.1
AMMONIUM CHLORIDE
SOLUBILITY OF AMMONIUM CHLORIDE IN AQUEOUS GLYCERINE SOLU-
TIONS AND IN AQUEOUS ACETONE SOLUTIONS AT 25.
(Herz and Knoch Z. anorg. Chem. 45, 263, 267, '05.)
In Aqueous Glycerine.
(Sp. Gr. of Glycerine 1.255, Impurity about 1.5%.)
In Aqueous Acetone.
Wt.%
NKUCl per 100 cc. Sp. Gr.
Solution. 25
AceloiT
NH 4 C1 per 100 cc.
Solution.
Sp. Gr.
.25
Glycenne. ^u^^
o. 585.1
Grams.
3I-32
4
0793
Millimols
585-I
. Grams.
3I-32
r
I
0793
13.28
544-6
29.16
.0947
10
534
.1
28.59
I
-O6l8
25.98
502.9
26.93
.1127
20
464
.6
24.87
I
0451
45 -3 6
434-4
23.26
.1452
30
396
7
21.23
I
0263
54-23
403-5
21 .60
.1606
40
328
5
*7-59
9998
83.84
291.4
15.60
2225
* 4 6
5
L
283
7
O
9800
IOO-OO
228.4
12.23
.2617
*8 5
-7
U
18
9
1. 01
O
.8390
90
9
4
0.50
o
8274
* Between these two concentrations of acetone,
lower layer, U indicates tipper layer.
the solution
separates into
two layers
L indicates
Solubility of Tetra Ethyl AMMONIUM CHLORIDE N(C 2 H 5 ) 4 C1, and
also of Tetra Methyl Ammonium Chloride N(CH 3 ) 4 C1 in Acetonitril.
100 cc. sat. solution in CH 3 CN contain 29.31 gms. N(C 2 H S ) 4 C1 at 25.
100 cc. sat. solution in CH S CN contain 0.265 gms. N(CH 3 ) 4 C1 at 25.
(Walden Z. physik. Chem. 55, 712, '06.)
AMMONIUM CHROMATES.
SOLUBILITY IN WATER AT 30.
(Schreinemaker Z. physic. Chem. 55, 89, '06.)
Composition in Wt. per cent of:
Solid Phase.
(NH 4 ) 2 CrO
(NH 4 ) 2 Cr0 4 + (NH 4 ) 2 Cr 2 7
(NH 4 ) 2 Cr 2 O 7
(NH 4 ) 2 Cr 2 O 7 + (NH 4 )aCr,O lto
(NH 4 ) 2 Cr 3 10
U
(NH 4 ) 2 Cr 3 10 +(NH 4 ) 2 Cr 4 18
(NH 4 ) 2 Cr 4 3
(NH 4 ) 2 Cr 4 O J3 +CrO,
Cr0 3
CrOa
100 gms. of the sat. aq. solution contain 28.80 gms.(NH 4 ) 2 CrO 4 at 30.
100 gms. of thesat. aq. solution contain 32. 05 gms. (NH 4 ) 2 Cr 2 O 7 at 30.
The Solution.
The Residue.
% Cr0 3 .
% NH 3 .
% Cr0 3 .
% NH 3 .
6-933
22.23
9.966
16-53
47-59
20-44
16.973
8.20
. . .
22-53
6-37
38.03
12.15
27.09
6.87
48.02
12.01
26.19
5-7
47-38
8.81
25-99
5.10
41.56
7-58
30.16
3.50
38.89
3.10
61.08
8.80
42.44
59-72
6.75
44-08
2.27
54-90
4.14
52.91
i .11
60.88
3-09
54-56
1.03
63.07
3-09
56-57
o-97
65-70
2-95
58.87
0.65
69.74
3-24
62.48
0.46
71-93
O
63.60
0.40
73-68
1.18
63.66
0.41
71-47
2.07
62.94
O.2I
. . .
62.28
0-0
. . .
AMMONIUM FLUOBORIDE
26
AMMONIUM FLUOBORIDE NH 4 3BF 3 .
100 parts of water dissolve 25 parts salt at 16, and about 97 parts
at b. pt. (Stolba Chem. Techn. Cent. Anz. 7, 459.;
AMMONIUM FORMATE HCOONH 4 , and also Ammonium Acid
Formate.
SOLUBILITY IN WATER.
(Groschuff Her. 36, 4351, '03.)
Solid.
Phase.
2O
O
20
40
60
80
Gms. HCOONH*
per i go Gms.
Solution. Water.
41.9 72 HCOONH 4
IO2 "
50-5
67.1 204
75-7 3"
84. 2 531
116 f. pt.
\jms. per ioo \jrns.
t. Solution.
Solid.
HCOONH-J + HCOOH:
- 6.5
46.7
34-1
HCOONH 4 .HCOOH
+ i-5
49.6
36.2
H
6.0
37-4
a
8.5
52.1
38.0
"
- 7
49.6
36.2
HCOONH 4 labil.
+ 13
S3-
38.6
stabil.
29
55-8
40.7
39
57.8
42.2
H,O free solution.
SOLUBILITY OF AMMONIUM FORMATE IN FORMIC ACID SOLUTIONS.
(Groschuff.)
30 grams of HCOONH 4 dissolved in weighed amounts of formic acid
and cooled to the point at which a solid phase separated.
Gms. G. M.
HCOONH 4 HCOONH4
t. per per
ioo Gms. xooG.M.
Solid
Phase.
~ 3
+ 8.5
21-5
Solution.
35-3
40.6
50.0
HCOOH.
39.9 HCOONH 4 . ii
HCOOH 39
49-9 7 8
Gms. G. M.
HCOONH 4 HCOONH 4
per per
ioo Gms. ioo G. M.
Solution. HCOOH.
HCOONH 4 labil.
Solid
Phase.
50.0 73.0
57.
73-
116 m.pt. 100.0
IOO.O
199.0
00
stabil.
AMMONIUM IODATE NHJO 3 .
ioo parts H 2 O dissolve 2.6 parts salt at 15 and 14.5 parts at 100.
(Rammelsberg Pogg. Ann. 44, 555, 1838.)
Tetra Methyl AMMONIUM IODIDE N(CH 8 )J.
SOLUBILITY IN SEVERAL SOLVENTS.
(Walden Z. physik. Chem. 55. 708, '06.)
o Sp. Gr. of
Gms. N(CH 3 ) 4 I
per ioo.
Solreat.
Formula.
Solution.
cc
. Solution.
Gms.
Solution.
Water
H 2
O
I
.0188
2
.01
I
97
Water
H 2
25
I
0155
5
.31-5
.89
5
.22
Methyl Alcohol
CH 3 OH
O
o
.8025
.l8-0
.22
.22
Methyl Alcohol
CHaOH
25
.7920
.38-0
.42
. 4 8
Ethyl Alcohol
C 2 H 5 OH
25
.7894
.09
Glycol
(CH 2 OH),
O
I
.OI4
Glycol
(CH 2 OH) 8
25
X
.0678
.240
.224
Acetonitril
CHsCN
25
o
.650
Nitro Methane
CHaNO,
o
I
1387
.25-0
32
o
.22
Nitro Methane
CH 3 N0 2
25
I
.1285
34-0
38
.21
Acetone
(CH 3 ) 2 CO
. . .
o
.118
Acetone
(CH 3 ) 2 CO
25
. . .
o
.187
Salicyl Aldehyde
C 6 H 4 .OH.COH
o
I
.1492
.302
'.'063
Salicyl Aldehyde
C 6 H 4 .OH.COH
25
I
1379
0.510
.484
AMMONIUM IODIDE
Tetra Ethyl AMMONIUM IODIDE N(C 2 H S )J.
SOLUBILITY IN SEVERAL SOLVENTS.
(Walden Z. physik. Chem. 55. 6pS, '06.)
Solvent.
Formula.
t o Sp.Gr.of
' Solution.
Cms. N(C2H 5 ) 4 I per 100.
cc. Solution.
Gms.
Solution.
Water
H 2
o
I
.0470
16
31
15
58
Water
H 2
2 5
I
.IO2I
36
33(35-5)
44
Methyl Alcohol
CH 3 OH
o
.8326
3
7-4-3
4
44
Methyl Alcohol
CHsOH
25
.8463
10
5 (10.7)
12
.29
Ethyl Alcohol
C 2 H 5 OH
.7928
348
439
Ethyl Alcohol
C 2 H 5 OH
25
.7844
.98 (0.88)
I
.249
Glycol
(CH 2 OH) 2
o
I
.1039
3
27
2
97
Glycol
(CH 2 OH) 2
25
I
.0904
7
63(7-55)
7
.00
Acetonitril
CH 3 CN
o
.8163
2
.24
2
74
Acetonitril
CH 3 CN
25
7929
3
04 (3-54)
3
83
Propionitril
CH 3 CH 2 CN
o
.8059
.618
.767
Propionitril
CH 3 CH 2 CN
25
.7830
.81-1.01
i
.29
Benzonitril
C 6 H 5 CN
25
.467
Methyl Sulphocyanide
CH 3 SCN
25
I
.0828
4
.40
4
.06
Ethyl Sulphocyanide
C 2 H 5 SCN
25
I
OOI2
475
47
Nitro Methane
CHgNO 2
o
I
.1658
3
59
3
.004
Nitro Methane
CH 3 NO 2
25
I
.1476
5
.61-6.27
5
.61
Nitroso Dimethylin
(CH 3 ) 2 N.NO
25
I
.0059
2
.67
2
.66
Acetyl Acetone
CH 3 COCH 2 COOCH 3
25
.268
Furfurol
C 4 H 3 O.COH
o
I
1738
3
.91
3
33
Furfurol
C 4 H 3 O.COH
25
I
.1692
5
33
4
55
Benzaldehyde
C C H 5 COH
25
43
Salicylaldehyde
C 6 H 4 .OH.COH
25
change-
able-17-7
Anisaldehyde
C6H 4 .OCH 3 .COH
25
. . .
59
.
. .
Acetone
(CH 3 ) 2 CO
o
o
-799I
.174
o
218
Acetone
(CH 3 ) 2 CO
25
.249
o.
218
Ethyl Acetate
CH 3 COOC 2 H 5
25
.00039
. .
Ethyl Nitrate
C 2 H 6 ON0 2
25
I,
0984
.062
o.
056
Benzoyl Ethyl Acetate
C 6 H 5 COCH 2 COOC 2 H 5
25
I.
*303
.321
o.
284
Di-Methyl Malonate
CH 2 (COOCH 3 ) 2
25
I .
040
o.
035
Methyl Cyan Acetate
CH 2 CNCOOCH 3
o
I.
1341 1.82
I .
605
Methyl Cyan Acetate
CH-jCNCOOCHa
25
... 2.83
Ethyl" Cyan Acetate
CH 2 CNCOOC 2 H 6
I .
0760
I.
057
o.
981
Ethyl Cyan Acetate
CH 2 CNCOOC 2 H 6
25
I .
0607
I .
I .
4i
AMMONIUM IODIDE
28
Tetra Propyl AMMONIUM IODIDE N(C 3 H 7 )J.
SOLUBILITY IN SEVERAL SOLVENTS.
(Walden Z. phyaik. Chem. 55, 709, '06 .)
Q ,, . Cms. N(C 3 H 7 ) 4 I per too.
ap. or. ot i f
Solvent.
Formula.
A. O Op. VJi . Ul
' Solution.
cc. Solution.
Gms.
Solution.
Methyl Alcohol
CH 3 OH
o 0.9756
40
.92
41-
94
Methyl Alcohol
CH 3 OH
25 1.0187
56
.42
55-
37
Ethyl Alcohol
C 2 H 6 OH
o 0.8349
6
.5-6.8
8.
14
Ethyl Alcohol
C 2 H 6 OH
25 0.8716
19
.88-20.29
2 3-
28
Acetonitril
CH 3 CN
o 0.8553
13
03
IS-
24
Acetonitril
CH 3 CN
25 0-8584
18
.69
21.
77
Propionitril
C 2 H 5 CN
o 0.8280
6
37
7-
66
Propionitril
CjjHjiCN
25 0.8191
9
65
ii .
76
Benzonitril
C 6 H 6 CN
25 1.0199
8
44
8.
35
Nitro Methane
CHgNOa
o
.181
14
79
12 .
5 2
Nitro Methane
CH 3 NO 2
25
.158
22
.24
19.
21
Nitro Benzol
C 6 H 5 NO 2
25
.193
5
7 1
4-
79
Benzaldehyde
CeHfiCOH
o
.0581
7
.06
6.
67
Benzaldehyde
C 6 HcCOH
25
0549
9
.87
9-
35
Anisaldehyde
C 6 H 5 .OCH 3 .COH
o
.1114
5
.60
5-
04
Anisaldehyde
C 6 H 5 .OCH 8 .COH
25
.1004
6
75
6.
14
Salicylaldehyde
C 6 H 6 .OH.COH
52
39
.28
.
. .
Ethylnitrite
C 6 H 5 ON0 2
o
.1207
0.522
O-
466
Ethylnitrite
C 6 H S ON0 2
25
.1025
o
653
o.
592
Di-Methyl Malonate
CH 2 (COOCH 3 ) 2
1532
o
.298
o.
259
Di-Methyl Malonate
CH 2 (COOCH 3 ) 2
25
I 34S
o
.320
o.
282
Acetone
(CH 8 ) 2 C
o 0.8259
2
.692
3
26
Acetone
(CH 3 ) 2 CO
25 0.8049
3
944
4.90
Ethyl Acetate
CH 3 COOC 2 H 6
25 0.8975
o
.0063
o
007
AMMONIUM NITRATE NH 4 NO 3 .
SOLUBILITY IN WATER.
(Schwarz Ostwald's Lehrbuch, xd ed. p. 425; Muller and Kaufmann Z. phjsik.Chem.
42, 497. 'oi-'o2.)
t.
Sp. Gr.
Solution.
G. Mols.
NH 4 N0 3 per
zoo Mols. H 2 C
Gms. NH4NO 3 per
100 Gms.
Solid
Phase.
* Solution.
Water.
o
26-63
54
19
118
3
NH 4 NO 3 rhomb, ft
12
2 1-2945
34
50
60
53
*$3
4
a
2O
.2
.3116
43
30
65
80
192
4
2 5
O
3 J 97
4 8
.19
68
i7
214
2
tt
30
O
3299
54
.40
70
73
241
8
(i
32
.1
3344
57
.60
7i
97
256
9
NH 4 NO 3 rhomb, ft + rhomb, a
35
.0
3394
59
.80
72
64
265
8
NH 4 NO 3 rhomb.
4o
.0
3464
66
.80
74
82
297
O
ti
50
.0
77
.41
77
49
344
M
60
.0
94
73
80
81
421
.0
tt
70
.0
112
30
83
32
499
O
tt
80
.0
*3o
So
85
2 5
580
.0
tt
90
.0
166
So
88
08
740
NH 4 NO 3 rhombohedral ?
100
.0
196
oo
89
7i
871
O
29 AMMONIUM NITRATE
SOLUBILITIES OF MIXTURES OF AMMONIUM NITRATE AND OTHER
SALTS.
(Riidorff Mulder.)
ioo gms. H 2 O dissolve 162.9 gms. NH 4 NO 3 + 77.1 gms. NaNO, at
i6R.
ioo gms. H 2 O dissolve 88.8 gms. NH 4 NO 3 + 40.6 gms. KNO. at
9 M.
ioo gms. H 2 O dissolve 101.3 gms. NH 4 NO 3 + 6.2 gms. Ba(NO 8 ) 2 at
9M.
SOLUBILITY OF AMMONIUM NITRATE IN AMMONIA.
(Kuriloff Z. physik. Chem. 25, 109, '98.)
Gms.
Mols. NILJSTOs
Gms. per ioo Mols.
Gms.
Mols. NH^Os
Gms. Der TOO MnU.
f.
NH 3 .
NH 4 NO 3 t.
+ NH 3 .
NH4NOS.
NH 3 . NI^NOg
+ NH a .
-80
O
IOO
O
.0
33
3
O
9358
O
2352
45-9
-60
1.3918
4.4327
6
25
35
9
.7746
O
1857
47-o
-44-5
0.9526
1-2457
13
9
68
.8
4
.2615
7747
53-8
-30
0.8308
0.3700
32
3
94
O
6439
.0665
67-3
-10.5
0.9675
0-35*5
36
9
190
.8
o
7578
.0588
74-2
o
o . 7600
o . 2607
38
3
168
.0
IOO-O
t temperature of equilibrium between solution and solid phase.
SOLUBILITY OF AMMONIUM NITRATE IN NITRIC ACID.
(Groschuff Ber. 37, 1488, '04.)
Determinations by the " Synthetic Method," see Note, page 9.
Gms. Mols. Gms. Mols.
Solid t o NH 4 NO 3 NH 4 NOa Solid
per ioo per ioo Phase. per ioo per ioo Phase.
Gms. Sol. Mols. HNO 8 . Gms. Sol. Mols. HNO 3 .
8 21. 1 21. 1 NI^NOa^HNOa n.o 51.7 84.3 NH.NO 8 .HNO S
23 28.7 31.6 a 12.0 54.7 95.1 " labil.
29. 5m.pt. 38. 8 50.0 11.5 57.6 108.0 " b
27.5 44.6 63.4 b 11.5 54.0 92.4 NI^NOa kbit.
23.5 49.4 76.8 17.0 54.7 95.1 " stabil.
17.5 54.0 92.4 27.0 56.2 101.0
16.5 54-3 93-5 vmxTrTiiwr* 4 9' 6 '4 120.0
4.0 45-8 66.7 NHtfWfcJWO^ 79 o 68>I l6g Q
a= solution in HNO 8 , 6 = solution in NH NO,.
SOLUBILITY OF AMMONIUM TRI-NITRATE IN WATER.
(Groschuff.)
Gms. NI^NOa
Gms. HNO 3
Mols. NH4NO3* Mols. NH^Oa
to
per ioo
per ioo
per ioo
per ioo Solid
.
Gms.
Gms.
Mols.
total Mols. Phase
Solution.
Solution.
H20.
Solution.
-8
34-2
53-9
22.0 NH.NO3.2HNO3
-2.5
34-8
54-8
75 - 1
23-1
35-4
55-8
90.0
24-3
8^5
36.6
5 6 -9
113.0
25-7
19-5
37-4
58-9
225 .0
29.0
25.0
38-1
60.0
450.0
31.0
29.5 m. pt.
38.8
61.2
o.o
00 (I
* or NH*NO 8 . 2 HNO 8 .
AMMONIUM NITRATE 30
SOLUBILITY OF AMMONIUM NITRATE IN AQUEOUS ETHYL ALCOHOL.
(Fleckcnstcin Physic. Z. 6, 419, '05.)
Grams of NH4NO 3 Dissolved per 100 Grams Aq. Alcohol of (Wt.%).
V .
100%.
86.77%.
76.12%.
51.65%.
25.81%.
0%.
20
2-5
II.
23.0
70-0
140
J 95
30
4.0
14.0
32.0
90.0
165
230
40
5-o
18.0
43 -
115.0
196
277
50
6.0
24.0
5S-o
144-0
244
365
60
7-5
30.0
70.0
183.0
320
70
9.0
41 .0
93-o
230.0
80
10.5
56.0
NOTE. The figures in the preceding table were read from curves
shown in the abridged report of the work, and are therefore only
approximately correct. Determinations of the solubility in methyl
alcohol solutions were also made but not quoted in the abstract. The
" Synthetic Method" (see Note, page 9) was used.
100 grams absolute ethyl alcohol dissolve 4.6 grams NH 4 NO 3 at
14 and 3.8 grams at 20.5.
100 grams absolute methyl alcohol dissolve 14.6 grams NH 4 NO 3 at
14 and 17.1 grams at 20.5.
(Schiff and Monsacchi Z. physik. Chem. 21, 277, '96; at 20.5 de Bruyn Ibid., 10, 783, '92.)
AMMONIUM MAGNESIUM NITRATE 2NH 4 NO 3 .Mg(NOa) 2 .
100 parts water dissolve 10 parts salt at 12.5.
(Foucroy.)
AMMONIUM MANGANIC MOLYBDATE 5(NH 4 ) 2 MoO 4 .Mn 2 (Mo 2 O 7 ) 3 .
i 2 H 2 0.
100 parts water dissolve 0.98 Darts salt at 17.
(Struve J. pr. Chem. 61, 460, '54 ,)
AMMONIUM OXALATE (NH 4 ) 2 C 2 O 4 .
100 grams H 2 O dissolve 2.215 grams (NH 4 ) 2 C 2 O 4 at o Sp. Gr. of
solution = 1.0105.
(Engel Ann. chim. phys. [6] 13, 359- '88.>
SOLUBILITY OF NEUTRAL AMMONIUM OXALATE IN AQUEOUS SOLU
TIONS OF ACID AMMONIUM OXALATE.
(Engel.)
i Milligram Mols. per 10 Grams per 100 cc.
cc. Solution. Solution.
(NH 4 ) 2 C 2 O 4
3.54 o.o 2.19 o.o
2.65 1.45 1.63 0.77
2-475 2 -5 2 5 1-5* T -34
2.38 2 90 1.47 1-54
* Both salts present in solid phase
AMMONIUM OXALATE
SOLUBILITY OP AMMONIUM OXALATE AND OXALIC ACID IN WATER AT 25.
(Walden Am. Ch. J. 34, 149, '05.)
Mixtures of the two substances were dissolved in warm water and
the solutions allowed to cool in a thermostadt held at 25.
Composition of Solution.
Solid Phase.
HaO and (NH) 2 C 2 O 4 .3H 2 C2O 4 .4H 3 O
Double salt,
Grams per 100 Gms.
Solution.
Mols. per 100 Mols.
H 2 0.
(NH^aCaO*.
H 2 Ca0 4 :
(NH4)2C204
. HaC 2 4 .
0.28
10-20
0.045
2.281
0.46
7.24
0.072
1-570^
2-44
2-59
0.372
0-546
3-65
2.80
0.566
0-599
4-99
3-41
0.791
Q-745 )
5.20
3-55
0.824
0.781
5-36
3-38
0.853
0.741 i
6.27
3-4
1. 00
0.671 5
7-03
2.90
1-13
0.645 >
7.08
2.70
I.I4
0-599
6.92
Q-775
(N
rH 4 ) 2 C 2 4 . 3 H 2 C 2 4 . 4 H 2
(NH 4 ) 2 C 2 4 .H 2 C 2 4 .H 2
and
Double salt, (NH 4 ) 2 .CaO 4 .H 2 C 2 O 4 .HaO
(NH 4 ) 2 C 2 O 4 .H 2 C 2 O 4
(NH 4 ) 2 C 2 4
AMMONIUM HYDROGEN PHOSPHITE (NH 4 H)HPO 3 .
100 grams water dissolve 171 grams (NH 4 H)HPO 3 at o, 190 grams
at 14.5 and 260 grams at 31.
(Amat. Compt. rend. 105, 809, '87.'
AMMONIUM PERMANGANATE NH 4 MnO 4 .
100 parts water dissolve approximately 8 parts of NH 4 MnO 4 at 15.
(Aschoff.)
AMMONIUM FLUO SILICATE (NH 4 ) 2 SiF 6 .
100 parts water dissolve 18.5 parts (NH 4 ) 2 SiF e at 17.5, Sp. Gr. 1.096.
(Stolba Chem. Centr. 418, 1877.)
AMMONIUM SALICYLATE C 6 H 4 (OH)COONH 4 .
100 parts H 2 O dissolve ui.i parts C 6 H 4 (OH)COONH 4 at 25; 100
parts alcohol dissolve 43.5 parts at 25 and 100 parts at the b. pt.
(U. S. P.)
AMMONIUM SULPHATE (NH 4 ) 2 SO 4 .
SOLUBILITY IN WATER.
(Mulder.)
Grams (NHi) 2 SO 4 per 100 Grams.
Grams (NH 4 ) 2 SO 4 per too Grams.
'Water.
Solution.
* *
Water.
Solution.
o
70.6
41.4
30
78.0
43-8
5
7 1.8
41.8
40
81.0
44.8
10
73-o
42.2
60
88.0
46.8
15
74-2
42.6
80
95 3
48.8
20
75-4
43-o
100
103-3
50 8
25
76.7
43-4
108.9
107-5
5i-8
Sp. Gr. of saturated solution at 15 1.248; at 19 = 1.241.
AMMONIUM SULPHATE 32
SOLUBILITY OF MIXTURES OF AMMONIUM SULPHATE AND COPPER
SULPHATE AT 16, AND OF AMMONIUM SULPHATE AND
POTASSIUM SULPHATE AT 19.1.
(Riidorff Ber. 6, 482, '73.)
+ CuSO 4 .
G. per i oo g. Solution. . . G. per ioo g. Solution
Preparation of Solution. f -^^^ Preparation of Solution. ^_ cr> ^ gA
Both salts in excess 8.55 7.12 Both salts in excess 39.3 37.97
1 5 cc. sat. sol. + 3 gms. 1 5 cc. sat. sol. + 4 g.
(NH 4 ) 2 SO 4 1.77 18.16 K 2 SO 4 4 -94 33-26
15 cc. sat. soL + 3 gms. 15 cc. sat. sol. + 4 g.
CuSO 4 .sH 2 O 15.85 5.65 (NH 4 ) 2 SO 4 2.05 40.80
SOLUBILITY OF AMMONIUM SULPHATE IN AQUEOUS ETHYL ALCOHOL
SOLUTIONS.
(Traube and Neuberg Z, physik. Chem. i, 510, '87; Bodlander Ibid. 7, 318, '91; Schreinemaker
Ibid. 23, 657, '97 ; deBruyn Ibid. 32, 68, 'oo; Linebarger Am. Ch. J. 14, 380, '92.)
Upper Layer Results. Lower Layer Results.
Grams per 100 Gms. Solu- Gms. QHsOH Gms - (NH 4 ) 2 SO 4 per ioo g.
tion at io-4o. pe r IOO Gms. Solution at:
C 2 H 6 OH. (NH 4 ) 2 SO 4 . Solution. 6 . 5 <>. 15 <> ^^
ioo o.o o 42.0 42.6 44
80 o.i 2.5 39.0 40.2 ?
70 0-3 5-0 36.2 37.2 ?
60 1.4 7-5 33-2 34-5 42
50 3.2 10. o 30.0 31.0 35
45 4.8 12.5 27.2 28.0 ?
40 6.6 15-0 24.6 25.2 ?
35 9.2 17.5 22.0 22.4 ?
30 12.2 2O. O 2O. O 2O. O ?
25 14.6
NOTE. When ammonium sulphate is added to aqueous solutions
of alcohol, it is found that for certain concentrations and temperatures
the solutions separate into two liquid layers, the upper of which con-
tains the larger percentage of alcohol.
Most of the determinations which have been made upon this system,
as contained in the papers referred to above, are given in terms of
grams of ammonium sulphate, of alcohol and of water per ioo grams
of these three components taken together. Those results which are
given in other terms can be readily calculated to this basis, and it is
therefore possible to make a comparison of the several sets of de-
terminations by plotting on cross-section paper and drawing curves
through the points. In the present case the grams of alcohol per ioo
grams of solution were taken as ordinates, and the grams of ammo-
nium sulphate in the same quantity of each solution taken as abscissae.
It was found that a single curve could be drawn through practi-
cally all the points representing the upper layer solutions at the
several temperatures, but the points for the solutions containing the
larger amounts of water gave curves which diverged with increase of
temperature. The results given for 33 in the above table are not
to be accepted as correct until further work has been done.
33 AMMONIUM SULPHATE
SOLUBILITY OF AMMONIUM SULPHATE IN AQUEOUS PROPYL ALCOHOL
SOLUTIONS AT 20.
(Linebarger Am. Ch. J. 14, 380, '92.)
Gms. per ioo Gms.
Solution.
Gms. per ioo Gms.
Solution.
CsHjOH.
(NH 4 ) 2 SO 4 .'
C 3 H 7 OH.
(NH4) 2 SO 4 ;
70
60
50
0.4
1.0
2.0
40
30
20
3-2
4-8
6. 7
AMMONIUM CADMIUM SULPHATE (NH 4 ) 2 Cd(SO 4 ) 2 6H 2 O.
100 cc. H 2 O dissolve 72.3 grams (NH 4 ) 2 Cd(SO 4 ) 2 at 25.
(Locke Am. Ch. J. 27 459. *ox.)
AMMONIUM CHROMIUM SULPHATE (Alum) (NH 4 ) 2 Cr 2 (SO 4 ) 4 .
2 4 H 2 0.
loocc. H 2 O dissolve 10.78 grams anhydrous or 21.21 grams hydrated
salt at 25.
(Locke Am. Ch. J. 26, 174, '01.)
AMMONIUM COBALT SULPHATE (NH 4 ) 2 Co(SO 4 ) 2 .6H 2 O.
SOLUBILITY IN WATER.
(Tobler Liebig's
t.
O
10
20
25
30
AnnalenQS, 193, '<;<;; v. Hauer J. pr. Chem. 74* 433. '58; at 25, Locke Am.
Ch. J. 27, 459. '01.)
Gms. (NH 4 ) 2 Co(SO 4 ) 2 Gms. (NH4) 2 Co(SO 4 ) 2
per 100 Gms. 4. per 100 Gms.
\Vater.
6.0
9-5
13.0
14.72
17.0
Solution.
5-7
8.7
"5
12.8
14-5
40
So
60
70
80
Water.
22 -O
27.0
33-5
40.0
49.0
Solution.
18.0
21-3
25-1
28.6
32-9
NOTE. The determinations reported by the above named inves-
tigators were plotted on cross-section paper and although considerable
variations were noted, an average curve which probably represents
very nearly the true conditions was drawn through them, and the above
table made from this curve.
AMMONIUM COPPER SULPHATE (NH 4 ) 2 Cu(SO 4 ) 2 .6H 2 O.
ioo grams H 2 O dissolve 26.6 grams salt at 19, Sp. Gr. of sol. =1.1336
(Schiff Liebig's Ann. 109, 326, '59.)
AMMONIUM IRON SULPHATE (Alum) (NH 4 ) 2 Fe 2 (SO 4 ) 4 .2 4 H 2 O.
ioo cc. H 2 O dissolve 44.15 gms. anhydrous or 124.40 gms. hydrated
salt at 25. Sp. Gr. of saturated solution at 15 = 1.203.
(Locke Am. Ch. J. 26, 174, 'oi.J
AMMONIUM IRON SULPHATE (ferrous) (NH 4 ) 2 Fe(SO 4 ) 2 .6H 2 O.
SOLUBILITY IN WATER.
(Tobler; at 25, Locke Am. Ch. J. 27, 459. '01.)
t o G. (NH 4 ) 2 Fe(S0 4 ) 2 t o G. (NH 4 ) 2 Fe(SO 4 ) 2 t o G. (NH 4 ) 2 Fe(SO 4 ) 2
per ioo g. H 2 O. per ioo g. H 2 O. per ioo g. H 2 O.
o 12.5 25 25.0 (T) 50 40
15 20.0 25 35.1 (L) 70 52
40 33-o
AMMONIUM INDIUM 34
SULPHATE
AMMONIUM INDIUM SULPHATE (NH 4 ) 2 In 2 (SO 4 ) 4 .2 4 H 2 O.
100 g. H 2 O dissolve 200 gms. salt at 16 and 400 gms. at 30.
(Rossler J. pr. Chem. [2] 7, 14, '73.)
AMMONIUM MAGNESIUM SULPHATE (NH 4 ) 2 Mg(SO 4 ) 2 .6H 2 O.
SOLUBILITY IN WATER.
(Average curve, from results of Mulder, Tobler, Locke, at 25.)
G. (NI
I 4 ) 2 Mg(SO 4 ) 2 G. (NH 4 ) 2 Mg(SO 4 ) 2
t.
per
100 Gms.
t.
per
100 Gms.
Water.
Solution.
Water.
Solution.
9.0
8.8
40
27.0
21.3
10
13.0
"5
50
32.0
24.4
20
18.0
60
37.0
27.0
25
19.9
16.6
70
42.0
29.6
30
22 -O
18.0
80
47-0
32.0
AMMONIUM MANGANESE SULPHATE (NH 4 ) 2 Mn(SO 4 ) 2 .6H 2 O.
100 cc. water dissolve 37.2 gms. (NH 4 ) 2 Mn(SO 4 ) 2 at 25.
(Locke Am. Ch. J. 27. 459, *oi.)
AMMONIUM NICKEL SULPHATE (NH 4 ) 2 Ni(SO 4 ) 2 .6H 2 O.
SOLUBILITY IN WATER.
(Average curve from Tobler, Locke, at 25.)
G. (NH 4 ) 2 Ni(S0 4 ) 2
G. (NH4) 2 Ni(S0 4 ) 2
t.
per loo Gms.
t .
per
loo Gms.
Water. Solution.
Water.
Solution.
i.o o-99
40
12.0
10.72
10
4.0 3.85
50
14-5
12.96
20
6.5 6.10
60
17-0
14-53
25
7-57 7-04
70
2O- O
16.66
30
9.0 8.45
AMMONIUM SODIUM SULPHATE NH 4 NaSO 4 . 2 H 2 O.
100 gms. water dissolve 46.6 gms. NH 4 .NaSO 4 .2H 2 O at 15, Sp. Gr.
Sol. = 1.1749.
.
AMMONIUM VANADIUM SULPHATE (Alum) (NH 4 ) 2 V 2 (SO 4 ) 4 .
2 4 H 2 0.
100 cc. H 2 O dissolve 31.69 gms. anhydrous or 78.50 gms. hydrated
Salt at 25. (Locke.)
AMMONIUM ZINC SULPHATE (NH 4 ) 2 Zn(SO 4 ) 2 .6H 2 O.
SOLUBILITY IN WATER.
(Average curve, see Note, p. 33, Tobler, Locke, at 25.)
G. (NH 4 ) 2 Zn(S0 4 ) 3
G. (NH 4 ) 2 Zn(S0 4 ) 2
t. per TOO Gms. t.
per 100 Gms.
Solution.
Water.'
Solution.
Water. "
O
6-54
7-0
40
16.66
20
10
8.67
9-5
So
20-0
25
20
II .11
12.5
60
23.1
30
25
12.36
14.1
70
25-9
35
30
13-79
16.0
80
29.6
42
35 AMMONIUM PERSULPHATE
AMMONIUM PERSULPHATE (NH 4 ) 2 S a O 8 .
100 parts H a O dissolve 58.2 parts (NH 4 ) 2 S 2 O 8 at o.
(Marshall J. Chem. Soc. 59. 77L '91.)
AMMONIUM SODIUM HYDROGEN SULPHITE (NH 4 )Na 2 H(SO 8 ) 2
4H 2 O.
100 gms. H 2 O dissolve 42.3 gms. salt at 12.4 and 48.5 gms. at 15.
(Schwincker Ber. 22, 1732, '89.)
AMMONIUM SULPHOCYANIDE NH 4 SCN.
100 parts water dissolve 128.1 parts NH 4 SCN at o and 162.2 parts
at 20.
(Clowes Z. Ch. 190, 1866.)
AMYL ACETATE BUTYRATE, FORMATE, etc.
SOLUBILITY IN WATER AND IN AQUEOUS ALCOHOL AT 20.
(Bancroft Phys. Rev. 3. 131, 196, 205, '95- '06; Traube. Ber. 17, 2304, '84.)
T? t , cc. Ester per Sp. Gr. v . cc. Ester per Sp. Gr.
loocc. H 2 0. of Ester. 100 cc. H 2 O. of Ester.
Amyl acetate 0.2 0.88 Amyl propionate o.i 0.88
Iso amyl acetate 0.2(1.2?) ... Iso amyl formate 0.3 (gms. at 22)
Amyl butyrate o . 06 0.85
Solubility of Iso Amyl Acetate Solubility of Amyl Acetate and Amy]
in Aq. Alcohol Mixtures. Formate in Aq. Alcohol Mixtures.
cc. H 2 O added to cause separation
of second phase in mixtures of the
rr given amounts of alcohol and 3 cc.
in Mixture
Per 5 cc. C 2 H 5 OH. * portions of :
7 o-4
6 0.7
5 i-3
3.61 3.0
3.01 4.0
2.60 5.0
Amyl
Amyl
Formate.
Acetate.
3
i. 80
I. 7 6
9
8.77
9-03
15
17.01
I7-52
21
27.06
26.99
27
38-3I
37-23
33
50-7I
48.41
39
65.21
45
85.10
48
94-20
ANETHOL (p Propylanisol) CH 3 CHCH[ 4 ]C 6 H 4 OCH 3 .
SOLUBILITY IN AQ. ALCOHOL AT 20.
(Schimmel and Co. Reports, Oct 1895, p. 6 )
Vol. per cent alcohol = 20 25 30 40 50
Gm. Anethol per liter aq. alcohol=o.i2 0.20 0.32 0.86 2.30
ANILINE
36
ANILINE C 6 H 5 (NH 2 ).
SOLUBILITY IN WATER AT 22.
(Herz Ber. 31, 2671, '98; see also Vaubel J. pr. Chem.f2) 52, 72, '95: Aignan and Dugas
Compt. rend. 129, 643, 99.)
ioo cc. H 2 O dissolve 3.481 cc. C 6 H 6 (NH 2 ) Vol. of Sol. = 103.48,
Sp. Gr. = 0.9986.
ioo cc. C 6 H 6 (NH 2 ) dissolve 5.22 cc. H 2 O Vol. of Sol. = 104.96,
Sp. Gr. = 1.0175.
SOLUBILITY OF ANILINE IN WATER AT DIFFERENT TEMPERATURES.
(Alexejew Ann. Physik. Chem. 28, 305, '86; calc. by Rothmund Z. physic. Chem. 26, 475, '98.)
Determinations by " Synthetic Method " see Note, p. 9. Figures read from curve.
Cms. C H S (NH 2 ) per TOO Grams. i0 Cms. CeH5NH 2 per ioo Grams.
Aq. Layer.
Aniline Layer.
Aq. Layer. Aniline Layer.
20
3-2
95-5
140
13-0
83-5
40
3-5
95-o
150
18.0
79.0
60
3-8
94-7
160
27-5
71.0
80
4-5
93-5
165
36.0
63.0
ioo
6.0
92.0
167.5(0-11. temp.) 48.6
120
8-5
88-5
SOLUBILITY OF ANILINE IN AQUEOUS SALT SOLUTIONS AT 18.
(Euler Z. physik. Chem. 40, 307, '04.)
Aq. &
-.lutinn * jms> aau ms - ^* n
slution. pgj. liter p^ JQO g ,
H 2
alone
o
3.61
*N
KC1
37-3
3-i5
N
KC1
74-6 .
2.68
N NaCl
58.5
2-55
Aq. Cms. Salt G
Solution. per liter, per ioo g. sol vent.
N NaOH 40.06 1.90
N LiCl
N CuCl
42.48
67.25
2.80
3.00
SOLUBILITY OF ANILINE IN AQUEOUS ANILINE HYDROCHLORIDE
SOLUTIONS AT 18.
(Lidow J. russ. phys. chem. Ges. 15, 420, '83; Ber. 16, 2297, '83.)
Per cent CeHcNKfeHCl Gms. C6N 6 NH 2
per ioo g. Sol vent.
3-8
Per cent QHeNHa-HCl
in Solvent.
Cms.
per loog. Sol vent.
insolvent,
5 3- 30 39-2
12 5-3 35 50-4
25 l8 -3
DISTRIBUTION OF ANILINE BETWEEN:
(Vaubel J. pr. Chem. [2] 67, 477. '3-)
Water and Ether. Water and Carbon Tetrachloride.
Composition of Solutions. Gms. CsHcNHjin: Composition of Solutions. Gms.CeHsNI^ in:
1.24^8
1.2478
1.2478
50 cc. H 2 O
-f 2occ. Ether
50 cc. H 2 O
+ 5occ. Ether
50 cc. H 2 O
-f ioo cc. Ether
0.1671
0.0835
0.0594
1.0807
1.1643
1.1884
0.3478
1.2478
1.2478
50 cc. H 2 O
+ 20CC.CC1 4
50 cc. H 2 O
+ 50 cc. CC1 4
50 cc. H 2 O
+ ioocc.CC! 4
]
0.
0.
o.
3358
2767
1845
0.012
I.97I
1.063
SOLUBILITY OF ANILINE IN SULPHUR.
(Alexejew Ann. Physik. Chem. 28, 305, '86.)
IOO
no
120
Gms.C6H6NH 2 per loog.
S. Layer. Anilin Layer".
4 75
6 70
10 64
Gms. CflH s NH 2 per ioog.
S. Layer.
W J 5
135 17-5
138 (crit. temp.)
Anilin Layer'.
5 8
47
23 . .
37
ANILINE
DISTRIBUTION OF ANILINE BETWEEN WATER AND TOLUENE AND
BETWEEN AQUEOUS SALT SOLUTIONS AND TOLUENE AT 25
(RbcLl Z. physik. Chem. 56, 243, '06.)
NOTE. Mixtures of Aniline and Toluene were shaken with water or
with aqueous salt solutions, and after separation of the two layers the
Sp. Gr. of the A : T mixture (layer) was determined and also the amount of
Aniline in each layer.
Solution Shaken with
A : T Mixture.
Vol. per cent !
Aniline : Toluene
in Mixtures Used.
Sp. Gr. of A : T
Mixture after
Separation.
Cms. C 6 H 5 N1
^2 in 100 cc. of:
A : T Layer.
Aq. Layer.
H 2
50:50
0.9257
41-5
2.14
"
25:75
0.8928
20-7
I .5
"
12.5:87.5
0-8737
8.62
0.86
"
0.8661
3-87
0-45
M
2.5:97.5
0.8627
1.68
O-2I
o.xN *i
50:50
0.9297
44-o
2-09
2
14
25:75
0-8901
19.03
1.38
'
12.5:87.5
0.8739
8-77
0.81
M
5-5:94-5
0.8663
3-94
0.42
M
0-8629
1.81
0.21
o.iN KBO 2
50:50
0-9257
41 .61
2. II
M
25:75
0.8870
17.08
i-34
14
12.5:87.5
0.8748
9-34
0.92
ii
0.8661
3-85
o-44
11
2-5:97-5
0.8627
1.72
0.21
XT Ba(OH)
O.OIOQ4N > '
2 50:50
0-9334
46.52
2.IO
2
11
25:75
0.8929
20.78
I .46
ft
12.5:87.5
0.8749
9.41
0.88
11
5-5:94 5
0.8663
3 96
o-43
it
2-5:97-5
0.8628
1.72
O-2O
XT Sr(OH) 2
o.io4N s
50:50
o-9333
46-45
2.13
2
M
25:75
0.8929
20.78
1.46
XT Sr(OH).
o . I044N \ L
L i2. 5 :8 7 -5
0.8750
9.46
0.88
2
M
5-5:94-5
0.8662
3-96
0-43
f XT or(Oxr)
o.io63N s fl
L 2.5:97.5
0.8628
i-75
O-2O
2
. 04 N Ca ( QH )2
50:50
0-9333
46.18
2. 2O
2
"
25:75
0.8925
20.59
1.51
II
12.5:87.5
0.8749
9-43
0.91
"
0.8662
3 -89
0-44
M
2.5:97.5
0.8627
1.70
0-21
ioo cc. aqueous solution contain 3.607 gms. Aniline at 25.
ANILINE
SOLUBILITY OF ANILINE, PHENOL MIXTURES IN WATER.
(Schreinemaker Z. physik. Chem. 29, 584; 30, 460, 'go.)
Mixture used = 50 Mols. Aniline
+ 50 Mols. Phenol
Gms. of Mixture per 100 Gms.
40
60
80
100
no
104 (crit. temp.) 33
Mixture used = 2<;.4 Mols. Aniline
+ 74 6 Mols. Phenol
Gms. of Mixture per 100 Gms. *
Aq. Layer.
5-5
8.0
12.5
19.0
A. + P. Layer.
86.0 4
82.0 8
77.0 10
67.0 12
5 6 -5 13
'35
Aq. Layer.
4-0
5-5
8.0
A. + P. Layer.
91-5
85-5
82.0
*3-5
19.0
23-5
73-5
66.0
58-0
140 (crit. temp.) 35
Determinations" in above" table by "Synthetic Method," see NOTE, p. 9.
Schreinemaker gives results for several other mixtures of Aniline and
Phenol which yield curves entirely similar to those for the two mixtures
here shown.
NitrANILINES C 6 H 4 NH 2 NO 2 . o, m, and p.
SOLUBILITY IN WATER.
(Carnelly and Thomson J. Chem. Soc. 53, 768, '88; Vaubel J. pr. Chem. [2] 52, 73, '95; above ao
Lowenherz Z. physik. Chem. 25, 407, '98.)
Grams NHraniline per Liter of Solution.
20
24.2
27.3
Ortho Nitranilinc.
1.25(25)
Mcta Nitraniline.
I.I4-I.67
1.205
1-422
Para Nitraniline.
0.77-0.80
SOLUBILITY OF ORTHO AND OF META NITRANILINE IN HYDROCHLORIC
ACID.
(Lowenherz.)
Ortho Nitraniline at 25.
G. Mols. per Liter. Grams per Liter
Meta Nitraniline.
G. Mols. per Liter. Grams per Liter.
'HCl
CeHsNHa.
TJ/~M C* U VT LJ "
ri.V^.1 i^grT^INri^.
'HCl
C 6 H 5 NH 2 .
HCl C 6 H 5 NH 2 .
]O2(o)
NO 2 (o) NO 2 (w)
N0 2 (m)
o.o
.0091
O
.0
i
2 5
(25) o.o
.OO9I
o.o
1.20
0.63
O
.0143
22
97
' i
97
(26. 5) 0.0125
.0183
0.46
2-53
0.95
.0174
34
63
2
.40
(23. 3) 0.0247
.0274
0.90
3-85
1.26
.0215
45
94
a
97
SOLUBILITY OF META AND OF PARA NITRANILINE IN ORGANIC
SOLVENTS AT 20.
(Carnelly and Thomson.)
Solvent.
Methyl Alcohol
Ethyl Alcohol
Propyl Alcohol
Iso Butyl Alcohol
Iso Amyl Alcohol
Ethyl Ether
Gms. per Liter.
Meta.
no. 6
70-5
56.5
26.4
85-1
78.9
Para.
95-9
58-4
43-5
19.1
62.9
61 .o
Solvent.
Benzene
Toluene
Cumene
Chloroform
Carbon Tetra Chloride
Carbon Bisulphide
Gms. per Liter.
Meta.
24-5
I7.I
"5
30.1
2.1
3-3
Para.
19.8
9-0
23.1
2.6
ANISIC ACID (p-Methoxybenzoic acid) CH 3 O.C G H 4 .COOH. See also p. 61.
100 cc. sat. aq. solution contain 0.2263 8 m - Anisic acid at 25.
(Paul Z. physik. Chem. 14, xn, '94.)
39
ANTHRACENE
ANTHRACENE C U H 10 .
SOLUBILITY IN LIQUID SULPHUR DIOXIDE IN
(Centnerswer and Teletow Z. Electrochem.
Weighed amounts of anthracene and liquid
tubes which were then sealed, rotated at
temperature and the point at which the solid
THE CRITICAL REGION*
9. 799. '03.)
SO 2 were placed in glass
a gradually increasing
disappeared, observed.
40.1
45-8
47-9
Gms. C M H 10
per 100 g.
Solution.
2. II
2.48
2 .65
Gms.
per 100 g.
Solution.
65.0
7 8.2
88.0
4-0
5 .66
7.14
98.0
99-1
106.5
Gms. C u H 10
per 100 g.
Solution.
9-95
12.78
SOLUBILITY OF ANTHRACENE IN ABSOLUTE ETHYL AND METHYL
ALCOHOLS.
(v. Becchi; at 19.5, de Bruyn Z. physik. Chem. 10, 784, '92.)
Grams C u HIO per 100 Grams Alcohol at;
In Ethyl Alcohol
In Methyl Alcohol
16.
0.076
19-5.
1.90
1. 80
b. pt.
0.83
SOLUBILITY OF ANTHRACENE IN BENZENE.
(Findlay J. Chem. Soc. 81, 1221, '02.)
Gms. C M H 10
per 100 Gms.
Mols. C M H 10
per 100 Mols.
C 6 He-
CeHe.
0-979
0.429
1.118
0-49 1
I .296
0.567
!-53 2
0.673
1-830
0.803
I-95 1
0.856
2-175
0-954
5
10
20
25
26
30
12.94 parts at 100 (v. Becchi).
t<
Gms. C M H,
s . per 100 Gms.
Mols. C M H,
per too Mols.
38
4 2.773
I.2I3
40
.0 2.987
I.3I2
44
.6 3.368
1-473
50
3.928
60
4.941
2.164
70
6.041
2.649
80
7-175
3- J 43
irt
s anthracene at
16.5 and
SOLUBILITY OF ANTHRACENE IN ALCOHOLIC PICRIC ACID SOLUTIONS
AT 25.
(Behrend Z. physik. Chem. 15, 187, *94-)
; per
Solu
ilution.
Picric
Acid.
O
I-OI7
2.071
2.673
3-233
Anthracene .
0.176
0.190
O.2O6
O.2I5
0.228
3.469 0.236
Solid Phase.
Anthracene
tt
Anthracene and
Anthracene Picrate
Grams per 100 Gms.
Solution.
Picric
Acid.
3-999
5.087
5-843
6.727
7-5 11
7-452
Anthracene.
O.2O2
0.180
O.l62
O.I5I
0.149
Solid Phase,
Anthracene Picrate
Anthracene Picrate
H- Picric Acid
Picric Acid
ANTHRAQUINONE 40
ANTHRAQUINONE (C 6 H 4 ) 2 (CO) 2 .
SOLUBILITY IN LIQUID SULPHUR DIOXIDE IN THE CRITICAL REGION.
(Centnerswer and Teletow Z. Electrochem. 9, 799, '08.) (See Anthracene, page 39).
_ _ Cms. CuHgOj Cms. C M H 8 O 3
t. per zoo g. t. per 100 g. t. per ipo g.
Solution. Solution. Solution.
39.6 0.64 92.1 2.81 118.5 S-6o
51.5 0.88 101.4 3.67 141.6 7.53
67.9 1.73 106.3 4.23 160.0 9.60
82.4 2.24 108.7 4.40 J 79-o 12.70
183.7 18.30
100 parts of absolute ethyl alcohol dissolve 0.05 part anthroquinone
at 18 and 2.249 parts at b. pt. (v. Becchi).
SOLUBILITY OF ANTHRAQUINONE IN ETHER.
(Smits Z. Electrochem. g, 663, '03.)
Weighed amounts of ether and anthraquinone were placed in glass
tubes which were then sealed. The temperature noted at which the
anthraquinone disappeared and also at which the liquid phase disap-
peared (critical temp.). The two curves cross at 195 and again at
241. Between these two temperatures the critical curve lies below
the solubility curve, hence for this range of temperature no solubility
curve is shown. The following figures were read from the curves, and
are therefore only approximately correct.
Cms. CuHjAi Cms. CuHgOz Cms.
t. per loo g. t. per 100 g. t^ per 100 g.
Solution. Solution. Solution.
130 3 241 30 260 80
150 4 245 40 270 90
170 4-5 2 47 50 275 100
195 5.0 250 60
100 parts of toluene dissolve 0.19 part anthraquinone at 15 and
5.56 parts at 100 (v. Becchi).
ANTIMONY TRICHLORIDE SbCl s .
SOLUBILITY IN WATER. SOLID PHASE SbCl 3 .
(Meerburg Z. anorg. Chem. 33, 299, 1903.)
Mols. SbCls Cms. SbCU Mols. SbOa Cms. SbCl
t. per loo per 100 t. per 100 per 100
Mols.H 2 0. gVHaO. % Mols. H 2 O. g. H^.
o 47-9 601.6 35 91.6 1152.0
15 64.9 815.8 40 108.8 1368.0
(72.4 910.1 50 152.5 - 1917.0
(74.1 931-5 60 360.4 453 I -o
25 78.6 988.1 72 oo o
30 84.9 1068. o
4 i ANTIMONY TRICHLORIDE
SOLUBILITY OF ANTIMONY TRICHLORIDE IN AQUEOUS HYDROCHLORIC
ACID. SOLID PHASE SbCl 3 . TEMP. 20.
(Meerburg.)
Mols. per
100 Mok. H 2 O.
Cms. per
100 g. H 2 O.
Mols. per
100 Mols. H 2 O.
Gms. per
100 g. HjO.
HC1. SbCls/
o 72.4
2.4 71.2
6.1 69 . 9
8.3 68.2
"HC1. SbCl 3 .
O-O QIOiI
4-86 895.4
12-34 879.0
16.80 857.6
fid. SbCla". '
9-1 68.9
11.7 68.1
28.7 62.8
HC1. SbCW
18.41 866.4
23.68 856.3
58.08 789.8
ioo grams absolute acetone dissolve 537.6 grams SbCl 3 at 18.
(Naumann Ber. 37, 4332, '04.)
ANTIMONY TRI IODIDE SbI 3 .
SOLUBILITY IN METHYLENE IODIDE AT 12.
(Retgers Z. anorg. Ch. 3, 344, '93.)
ioo parts CH 2 I 2 dissolve 1 1.3 parts SbI 3 . Sp. Gr. of solution = 3.453.
ANTIMONY POTASSIUM TARTRATE K(SbO)C 4 H 4 O 6 .iH 2 O.
ioo grams glycerine dissolve 5.5 grams of the tartrate at 15.5.
ARGON, A.
t o Cor. Bar.
SOLUBILITY IN WATER.
(Estreicher Z. physik. Chem. 31, 184, '99.)
Vol. Vol. Absorbed Absorption Coefficients.*
Solubility.
Pressure. HafJ.
Argon.
a.
/.
q.
.
.
.0578
O-OIO2
I
764
9
77
.40
4
34
o
0561
0561
O.OO99
5
765
.0
77
39
3
.92
.0507
.0508
0.0090
10
765
3
77
.41
3
49
.0450
0453
0.0079
15
762
4
77
.46
3
.13
.0404
o
.0410
0.0072
20
757
.6
77
53
2
.86
o
.0369
0379
O.OO66
25
766
7
77
.62
2
.64
o
0339
0347
O.OO6O
30
760
.6
77
73
2
43
o
.0312
.0326
0-0056
35
757
.1
77
.86
2
.24
.0288
0305
0.0052
40
758
3
77
99
2
.07
o
.0265
.0286
0.0048
45
756
4
78
I
.92
o
.0246
.0273
0-0045
5
747
.6
78
3 1
I
73
o
O22I
o
.0257
O.OO4I
a = under barometric pressure minus tension of H 2 O vapor.
/ under 760 mm. pressure.
q = grams argon per ioo g.H 2 O when total pressure is equal to 760 mm.
* See Acetylene, page 8.
ARSENIC PENTOXIDE As 2 O 6 .
ioo parts H 2 O dissolve .244.8 parts As 2 O 4 302.3 parts HaAsO 4 at
12.5. Sp. Gr. of solution = 2.18 at 15.
(Vogel.)
ARSENIC IODIDE AsI 3 .
SOLUBILITY IN METHYLENE IODIDE AT 12.
(Retgers Z. anorg. Chem. 3, 344, 1893.)
ioo grams CH 2 I 2 dissolve 17.4 gms. AsI 3 . Sp. Gr. of solution 3.449.
ARSENIC TRIOXIDE
ARSENIO TRIOXIDE
42
As 2 3 .
SOLUBILITY OF THE:
Crystallized Modification. Amorphous Modification.
In Water. In Water.
A.O Gms. As 2 O 3 per
100 cc.H 2 O.
ord. temp. 3 . 7
b. pt. 11.86
In Alcohol, Ether and CS 2 .
G. As 2 O 3 per 100 g. Solvent.
Alcohol o . 446
Ether 0.454
CS 2 o.ooi
(Winkler J. pr. Chem. [2] 31, 347, '85-)
Gms. AsgOa
t.
per TOO cc.
Sat. Solution.
2
I -2OI
15
I-657
25
2.038
39-8
2.930
b. pt.
6.+
(Bruner and St. Tolloczko Z. anorg. Chem. 37, 456,
'03; Chodounsky Listy. Chem. 13, 114, '88.)
ASPARAGINE C 4 H 8 N 2 O 3 .H 2 O.
SOLUBILITY /S-/-ASPARAGINE C 4 H 8 N 2 O 3 .H,O AND OF /S-/-ASPARAGINIC
ACID C 4 H 7 NO 4 IN WATER.
Determined by " Synthetic Method," see Note, page 9.
(Bresler Z. physik. Chem. 47, 613, '04.)
/3-/-Asparaginic Acid.
/3-J-Asparagine.
O
7'
28,
41.
7
9
4
Gms.
: 4 H 8 N 2 3 .H 2 C
per 100 g.
H 2 0.
0.9546
I .4260
2.1400
3.I7IO
5.6500
55
87
98
5
7
.0
.0
Gms.
C 4 H8N 2 3 .H 2
per 100 g.
H 2 0.
10.650
19.838
36-564
52-475
*~
Gms.
Gms.
t.
C 4 H 7 NO 4
t.
C 4 H 7 N0 4
per 100 g.
per 100 g.
H 2 0.
H 2 0.
0.2
0.2674
51.0
1.2746
9-5
o . 4042
63-5
1.8147
16.4
0.5176
70.0
2.3500
31 .5
0-75*4
80.5
3.2106
40.0
0.9258
97-4
5-3746
ATROPINE C 17 H 23 NO 3 .
SOLUBILITY OF ATROPINE C 17 H 23 NO 3 AND OF ATROPINE SULPHATE
(Ci 7 H,3NO 3 ) 2 .SO 2 (OH) 2 IN WATER AND OTHER SOLVENTS.
(U. S. P. ; Miiller Apoth.-Ztg. 18, 244, '03.)
Grams Atro-
Grams Atropine per 100 Grams. pine Sulphate
Solvent. t. , * N per TOO Grams
Solution. Solvent. (U. S. P.) Solvent.
(U. S. P.)
263.1
454-5
27.0
52-6
0.047
0.161
Water
25
1.782 (20)
0.222
Water
80
"S
Alcohol
2 5
. . .
68.44
Alcohol
60
III .11
Ether
25
2-21 (20)
6. 02
Chloroform
2 5
68.03 (20)
64.10
Benzene
20
3-99
. . .
Carbon Tetrachloride
20
0.661
1.136
Ethyl Acetate
20
3.88
. . .
Petroleum Ether
2O
0.83
. . .
Glycerine
IS
3-o
* Schnidelmeiser Chem. Ztg. 25, 129, '01.
43 AZELAIO ACID
AZELAIC ACID C 7 H 14 (COOH) 2 .
SOLUBILITY IN WATER.
(Lamouroux Compt. rend. 128, 998, '99.)
t= o 15 20 35 50 65
Gms. C 7 H U (CO9H) 2
per 100 cc. solution = o.io 0.15 0.24 0.45 0.82 2.20
AZOPHENETOL (/>) C 6 H 5 N 2 .C 6 H 4 .OC 2 H 5 .
SOLUBILITY IN 100 PER CENT ACETIC ACID.
(Dreyer and Rotarski Chem. Centr. 76, II, 1016, '05.)
t= 89.2 91 93 95.6 97.2 99.6
Mols. per liter. 0.153 0.176 0.185 0.209 0.232 0.252
A knick at 94.7 corresponds to the transition temperature of the
a modification into the modification.
BARIUM ACETATE Ba(CH 3 COO) 2 .
SOLUBILITY IN WATER.
(Walker and Fyffe J. Ch. Soc. 83, 179, '03; Krasnicki Monatsh. Chem. 8, 597, '87.)
Solid Phase.
Ba(C 2 H 3 2 ) a
Gms. Ba(CH 3 COO) 2
t o < per 100 Gms. Solid Phase.
t
Gms. Ba(CH 3 COO) 2
. per 100 Gms.
Water.
Solution.
Water.
Solution.
3
58.8
37
.0
Ba(C 2 H 3 2 ) 2 . 3 H 2
40
5
79
.0
44
.1 I
7
9
61 6
38
.1
u
4i
5
78
7
44
.0
J 7
5
69.2
40
9
u
44
5
77
9
43
.8
21
.6
72.8
42
.1
5i
.8
76
5
43
4
24
. i
78.1
43
9
(4
63
.0
74
.6
42
7
26
.2
76.4
43-3
Ba(C 2 H 3 2 ) 2 .H 2
73
.0
73
5
42
4
30
.6
75-i
42
9
it
84
.0
74
42
5
35
.0
75-8
43
.i
(i
99
.2
74
.8
42
.8
39
.6
77-9
43
.8
a
Transition temperatures 24.7 and 41'
BAEIUM ARSENATE Ba 3 (AsO 4 ) 2 .
100 gms. H 2 O dissolve 0.055 gm. Ba 3 (AsO 4 ) 2 ; 100 gms. 5% NH 4 C1
dissolve 0.195 gm., and 100 gms. 10% NH 4 OH dissolve 0.003 S 10 -
Ba 3 (AsO 4 ) 2
(Field J. Ch. Soc. n 6, 1850-)
BARIUM BROMATE 44
BARIUM BROMATE
SOLUBILITY IN WATER.
(Trantz and Anschiitz Z. physik. Chem. 56, 238, '06; Rammelsberg Pogg. Ann. 52, 81, '41-)
Cms. Ba(BrO 3 ) 2 Gms. Ba(BrO 3 ) 2 Gms. Ba(BrO 3 )j
t. per 100 Gms t. per 100 Gms. t. per 100 Gms.
Solution. Solution. Solution.
0.034 0.28 30 0.95 70 2.922
o 0.286 40 1.31 80 3-521
-Mo 0.439 5 *-7 2 9 4-26
20 0.652 60 2.271 98.7 S- 2 56
25 0.788 99.65 5.39
BARIUM BROMIDE BaBr 2 . 2 H 2 O.
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 99, 47, '56; Etard Ann. chim. phys. [7] 2, 540, '94.)
Gms. BaBr 2 per TOO Grams. Gms. BaBr 2 per TOO Grams.
t. 'Water. Solution. t. ' Water. Solution.
(Kremers.) (Kremers.) (Etard.) (Kremers.) (Kremers.) (Etard.)
20
. . .
45- 6
40
114
53-2
S^S
O
98
49-5
47-5
So
118
54-i
52-5
10
101
50.2
48-5
60
123
55-i
53-5
20
104
51.0
49-5
70
128
56-1
54-5
25
106
5i-4
50.0
80
J 35
57-4
55-5
30
109
52-i
50.6
IOO
149
60.0
57-8
140
59-4
Sp. Gr. of saturated solution at 19.5 = 1.710.
The results of Kremers and Etard are both given, since it is uncer-
tain which is the more correct.
SOLUBILITY OF MIXTURES OF BARIUM BROMIDE AND BARIUM IODIDE
IN WATER AT DIFFERENT TEMPERATURES.
(Etard.)
e Grams per i oo Gms. Solution. Grams per ioo^Gms. Solution.
BaBr 2 . " BaI 2 . BaBr 2 . Bal^.
16 4.8 58.4 170 ii. o 67.4
+60 5.5 66.0 210 14-9 6 7-7
135 9.2 67 . 2 Both salts present in solid phase.
SOLUBILITY OF BARIUM BROMIDE IN METHYL AND ETHYL ALCOHOLS.
We Bruyn Z. physik. Chem. 10, 783, 92 ; Richards Z. anorg. Chem. 3, 455, '93 ; Rohland Ibid.
15 412, '97.)
Parts BaBr 2 per 100 Parts BaBr 2 .2H 2 O per 100
t o parts Aq. C 2 H 6 OH of: parts of Aq. CH 3 OH of:
100%. 97%- 87%. 100%. 93-5%' SG%.
15.0 .- 0.48 (BaBr 2 .2H 2 O) .. 45.9 27.3 4-O
22.5 3 6 56.1
BARIUM BUTYRATE Ba(C 4 H 7 O 2 ) 2 .2H 2 O.
SOLUBILITY IN WATER.
(Deszathy Monatsh. Chem. 14, 249, '93.)
e Gms. Ba(C 4 H 7 O 2 ) a per 100 Gms. Gms. Ba(C 4 H 7 Q 2 ) 2 per 100 Gms.
Water. Solution". Water. Solution.
o 37.42 27.24 50 36.44 26.77
10 36.65 26.82 60 37-68 27.36
20 36.12 26.55 70 39.58 28.36
30 35 - 8 5 26.38 80 42.13 29.64
40 35 -82 26.37
45 BARIUM CAPROATE
BARIUM GAPROATE AND BARIUM ISO CAPROATE.
SOLUBILITY IN WATER.
(Kulisch Monatsh. Chem. 14, 567, '93.) (Konig Monatsh. Chem. 15, 23, '94.)
Barium Caproate (Methyl 3 Pentan.) Barium Iso Caproate (Methyl 2 Pentan )
Ba(CH3.CH 2 CH(CH 3 )CH 2 COO) 2 . Ba(CH3CH(CHg)CH 2 .CH 2 COO) 2 .
Gms.Ba(C 6 H u 2 ) 2
t 8 . per TOO Gms. Solid Phase.
Gms. Ba(C 6 H n O 2 ) 2
per TOO Gms.
Solid Phase.
Water. Solution.
Water.
Solution.
II
7i
10
.49 BaCQHuOa^iHaO
14.
34
12
54 *'<
i(C6H u 2 ). 4 HaO
10
8
38
7
73
13-
33
II
77
"
20
6
.89
6
45
12 .
67
II
.26
"
30
5
87
5
55
12.
37
II
.01
40
50
5-79
6.63
5
6
47
.21
12 .
12.
42
83
II
II
3
::
60
8
39
7
74
13 .
63
II
99
70
ii
.09
9
.98
14.
68
12
.80
44
80
14
12
.82
16.
24
13 ,
97
44
00
19
.28
16
.16
17-
95
I5-23
BARIUM CARBONATE BaCO,.
SOLUBILITY IN WATER.
(Holleman, Kohlrausch and Rose Z. physik. Chem. 12, 139, 241, '93.)
Electrolytic conductivity method used.
i liter H 2 O dissolves 0.016 g. BaCO 3 at 8.8, 0.022 g. at 18, and
0.024 g- at 24.2.
SOLUBILITY OF BARIUM CARBONATE IN WATER CONTAINING CO 2 .
The average of several determinations at about 10, by Bineau,
Lassaigne, Foucroy and Bergmann is i.io gms. BaCO 3 per liter water.
Wagner (Z. anal. Ch. 6, 167, '67) gives 7.25 gms. BaCO 3 per liter of
water saturated with CO 2 at 4-6 atmospheres pressure.
BARIUM CHLORATE BajClO^H a O.
SOLUBILITY IN WATER.
(Tfantz and Anschiitz Z. physik. Chem 56, 238, '06; Kremers Pogg. Ann. 99, 43, '56; Tilden and
Shenstone Trans. Roy. Soc. 34, '84.)
Gms. Ba(ClO 3 ) 2 Gms. Ba(ClO 3 ) 2 Gms. BaCClOs)*
t. per too Gms. t. per too Gms. t. oer 100 Gms.
Solution.
Solution
Solution.
~ 2-75
15.28
30
29 43
90
4 8 .70
O
16.90
40
33 -16
99.1
5 1 I 7
4-10
21.23
5
36-69
105
52.62
20
25.26
60
40-05
116
66.0
25
27-53
7o
43-04
146
78.0
80
45-90
BARIUM CHLORIDE 46
BARIUM CHLORIDE BaCl 2 . 2 H 2 O.
SOLUBILITY IN WATER.
(Mulder; Engel Ann. chim. phys. [6] 13, 372, '88; Etard Ibid. [7] 2, 535, '94-)
A0 Gms. BaCl 2 l
)er ioo Gms.
A0 Gms. BaCh per ioo Gms.
*
Water.
Solution!
'
'Water.
Solution.
31-6
24.0
60
46.4
3 I -3
10
33-3
25.0
70
49.4
33- 1
20
35-7
26.3
80
52-4
34-4
25
37-o
27.0
IOO
5 8.8
37.0
30
38.2
27.7
130
59-5
37-3
40
40.7
28.9
160
63.6
38-9
50
43-6
30-4
215
75-9
43 - 1
Sp.
Gr. of solution saturated at o
- 1-25;
at 20
= 1.27.
SOLUBILITY OF MIXTURES OF BARIUM CHLORIDE AND BARIUM NITRATE
IN WATER.
Both salts present in solid phase.
(Etard.)
o Grams per ioo Gms. Solution. Grams per ioo Gms. Solution.
BaCl 2 . Ba(N0 3 ) 2 . BaCl 2 . Ba(NO 3 ) 2 .
o 22.5 4.3 ioo 31 14
20 24.5 6.0 140 32 20
40 26.5 7.5 180 33 26
60 28.5 9.5 210 32 32
SOLUBILITY OF MIXTURES OF BARIUM CHLORIDE AND MERCURIC
CHLORIDE IN WATER.
(Foote and Bristol Am. Ch. J. 32, 248, '04.)
t.
Gms. per ioo Gms.
Solution .
Solid
Phase.
t.
Gms. per ioo Gms.
Solution.
Solid
Phase.
BaCl 2 .
HgCl 2 .
BaCl 2 .
HgCl 2 .
10.4
23-58
50.54 I
BaCl,2H,O+
Hg'd 2 '
10.4
22. IO
51.66]
Brctl I . e 3 H a ga 2 .6H 2 0.
10.4
10.4
23-44
22.58
50-74
51-23
Double Salt
BaC^HgCl,
IO.4
25
21.64
23.02
5i-74
54.83
BaCI,.2H,O+HgCl,.
10.4
22.48
5 I -4i
SOLUBILITY OF MIXTURES OF BARIUM CHLORIDE AND POTASSIUM
CHLORIDE IN WATER.
(Foote Am. Ch. J. 32, 253, '04.)
ioo grams saturated solution contain 13.83 grams BaCl 2 + 18.97
grams KC1 at 25.
SOLUBILITY OF MIXTURES OF BARIUM CHLORIDE AND SODIUM
CHLORIDE IN WATER.
(Precht and Wittgen Ber. 14, 1667, '81; Rudorff Ber. 18, 1161, '85.)
, Gms. per ioo Gms. H 2 O. Gms. per ioo Gms. Solution.
BaO^ NaCl. BaCl 2 . NaCl.
20 4-1 33-8 2.9 25.0
40 6.3 33.6 4-5 2 3-o
60 9.7 33-5 6 - 8 2 3-4
80 13.9 33-6 9.4 22.8
IOO 17-9 33-6 II .8 22.2
47 BARIUM CHLORIDE
SOLUBILITY OF BARIUM CHLORIDE IN AQUEOUS SOLUTIONS OP
HYDROCHLORIC ACID AT o.
(Engel Ann. chim. phys. [6] 13, 371, '88.)
>. Gr. of
10
cc. Sol.'
Gms. per
100 CC. Sol.
Gms. per
ioo g. So!
)lutions.
HC1.
iBaCW
'HC1.
BaCl 2 .
'HC1.
BaCl 2 .
1.250
O
28.90
30.10
24.07
1.242
I .1
27.80
0.40
28.95
0.32
23-3I
1.228
2.8
26.07
1.02
27-I5
0.83
22.11
I .2IO
5-o
23.40
1.82
24.36
*-5*
2O.I4
143
14.4
I4.0O
5-24
J 4-57
4-58
12.76
.Il8
18.8
10.20
6.84
10.47
6.13
9-37
.099
22.7
6.67
8. 99
6-95
7-55
6-33
.079
32.0
2.74
11.66
2.85
10.81
2.64
.088
5o-5
0.29
18.41
0-30
16.92
0.28
Less than i part of BaCl 2 is soluble in 20,000 parts of concentrated
HC1 and in 120,000 parts of cone. HC1 containing $ volume of ether.
(Mar Am. J. Sd.[ 3 ] 43, 521, '92.)
SOLUBILITY OF BARIUM CHLORIDE IN ABSOLUTE METHYL ALCOHOL
AND IN GLYCERINE.
(In Alcohol, de Bruyn Z. physik. Chern. 10, 783, '92.)
ioo parts of CH 3 OH dissolve 2.18 parts BaCl 2 at 15.5, and 7.3 parts
BaCl 2 .2H 2 O at 6.
ioo parts by weight of glycerine dissolve 10 parts of BaCl 2 at 15.5.
SOLUBILITY OF BARIUM CHLORIDE IN AQUEOUS ETHYL ALCOHOL AT 15.
(Schiff Liebig's Ann. 118, 365, '61; Rohland Z. anorg. Ch. 15, 412, '97.)
Wt. per cent alcohol 10 20 30 40 60 80 97
Gms.BaCl 2 .2H 2 Oper
ioo g. aq. alcohol 31.1 21.9 14.7 10.2 3.5 0.5 0-014
BARIUM CHROMATE BaCrO 4 .
SOLUBILITY IN WATER AND IN SALT SOLUTIONS.
t. Solvent. Gms " 1 ** U ** Observer.
( (Kohlrausch & Rose
18 Water 0.0038 ]z. physic. Ch. 12, 241,
( '93-)
ord. temp. o . 0062 (ignited BaCrO 4 ) ( (Schweitzer z. anal.
ord. temp. " o.o ioo (not ignited) j ch. 29, 4M, '90.)
V\ i-kt " ^ I^AI ( (Mescherzerski Z.
D - P l - o .043 j ^ ch ai 399> , 8a }
Ord. temp. 1.5% Am. Acetate O.O2O (Fresenius - Z. anal.
ord. temp. 0.5% Am. Nitrate o .022 ( Ch - 2 * 418, V-)
BARIUM CITRATE Ba 3 (C 6 H 6 O 7 ) 2 .7H 2 O.
SOLUBILITY IN WATER AND IN ALCOHOL.
ioo grams water dissolve 0.0406 gram Ba 3 (C 6 H s O 7 )2.7H 2 O at 18,
and 0.0572 gm. at 25.
ioo grams 95% alcohol dissolve 0.0044 gram Ba 3 (C 6 H s O 7 ) 2 .7H 2 O at
18, and 0.0058 gm. at 25.
(Partheil and Hiibner Archiv. Pharm. 241, 413, '03.)
BARIUM CYANIDE 48
BARIUM CYANIDE Ba(CN) 2 .
SOLUBILITY IN WATER AND IN ALCOHOL AT 14.
(Joannis Ann. chim. phys. [5] 26, 489, '82.)
ioo parts water dissolve 80 parts Ba(CN) 2 .
100 parts 70% alcohol dissolve 18 parts Ba(CN) 2 .
BARIUM FERROOYANIDE AND BARIUM POTASSIUM FERRO-
CYANIDE.
(Wyrouboff Ann. chim. phys. [4] 16, 292, '69.)
ioo parts water dissolve o.i part Ba 2 Fe(CN) 6 .6H 2 O at 15, and i.o
part at 75.
ioo parts water dissolve 0.33 part BaK 2 Fe(CN) 6 .5H 2 O at ord. temp.
BARIUM FLUORIDE BaF 2 .
(Kohlrausch Z. physik. Chem. 50, 365, 'o4~'os.)
i liter of water dissolves 1.63 gms. BaF 2 at 18. Electrolytic conduc-
tivity method.
BARIUM FORMATE Ba(HCOO) 2 .2H 2 O.
SOLUBILITY IN WATER.
(Krasnicki Monatsh. Chem. 8, 597, '87.)
t o Gms . Ba(HCOO) 2 per i oo Gms. t <> Gms. Ba(HCOO) 2 per too Gms.
Water. Solution. Water. Solution.
o 27.76 21.72 40 34-81 25.82
10 28.46 21.15 50 37-14 27.10
20 30.11 23.15 00 38.97 28.03
25 31-20 23.80 70 39-95 28.54
30 32.34 24.45 80 39.71 28.42
BARIUM HYDROXIDE Ba(OH) 2 .
SOLUBILITY IN WATER. SOLID PHASE Ba(OH) 2 .8H 2 O.
(Rosenthiel and Riihlmann Jahresber. Chem. 314, '70.)
t o Gms. Ba(OH) 2 per ioo Gms. t o Gms. Ba(OH) 2 per ioo Gms.
'Water. Solution." Water. Solution
o 1-67 1.65 30 5.59 5.29
5 1.95 1.92 40 8.22 7.60
10 2.48 2.42 50 13.12 ii. 61
15 3.23 3.13 60 20.94 17-32
20 3.89 3.74 75 03-5 1 38-85
25 4.68 4.47 So 101.40 50.35
SOLUBILITY OF BARIUM HYDROXIDE IN AQUEOUS ACETONE AT 25.
(Herz and Knoch Z. anorg. Chem. 41, 321, '04.)
Ba(OH) 2 per ioo cc. Sat. Gms. Ba(OH) 2
Sp. Gr.of Vol.% Solution. Per
Solutions. Acetone. / " > ioo Gms.
Millimols. Grams. Solution.
1.0479 55 -8 4-722 4-506
i. 0168 10 31-84 2.730 2.686
0.9927 20 17.79 1-525 I -53<5
0.9763 30 9.10 0.779 0.798
0.9561 40 4-75 -407 0.426
0-939* 50 i-54 0.132 0.141
0.9179 60 0.48 0.041 0-045
0-8956 70 0-08 0.007 0-018
.
49 BARIUM IODATE
BARIUM HTOATE Ba(IO 3 ) 2 .H 2 O.
SOLUBILITY IN WATER.
(Trantz and Anschutz Z. physik. Chem. 56, 238, '06.)
t o Cms. Ba(IO 3 ) 2 per t<3 Gms. Ba(IO 3 ) per t o Gms. Ba(IO 3 ) 2 per
100 Gms. Solution. 100 Gms. Solution. 100 Gms. Solution.
- 0.046 O.OOS 30 0.031 70 0.093
-f 10 0.014 40 0.041 80 0.115
2O O-O22 5O 0-056 9O O.I4I
25 0.028 60 0-074 100 o- J 97
BARIUM IODIDE BaI 2 .
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 103, 66, 1858; Etard Ann. chim. phys. [7] 2, 544, '94.)
Gms BaI 2 per loo Gms. t. G ' Bal2 ^"ooGms.
Water. Solution. Water. Solution.
-20 143-9 59.0 BaI 2 .6H 2 O 40 231.9 69.8 BaI 2 .2 H 2 O
o 170.2 63.0 60 247.3 7 1 - 2
4-10 185.7 65.0 80 261.0 72.3
20 203.1 67.0 100 271.7 73.1 "
25 212.5 68.0 120 281.7 73.8
30 219.6 68.7 " 160 294.8 74.6 "
Sp. Gr. of saturated solution at 19. 5 = 2.24.
For method of interpolating above results, see Note, page 33.
100 grams 97% Ethyl Alcohol dissolve 1.07 g. BaI 2 .2H 2 O at 15.
(Rohland Z. anorg. Chem. 15, 417, 1807.)
BARIUM MALATE BaC 4 H 4 O 5 .
SOLUBILITY IN WATER.
(Cantoni and Basadonna Bull. soc. chim. [3] 35, 731, '06.)
t o
per 100 cc. Sol. per 100 cc. Sol. per 100 cc.
20 0.883 35 0.895 60 i. on
25 0.901 4O 0-896 7O I.O4I
30 0.903 50 0.942 80 1.044
SOLUBILITY IN WATER AND IN ALCOHOL.
(Bartheil and Hiibner Archiv. Pharm. 241, 413, '03.)
ioo grams water dissolve 1.24 gms. BaC 4 H 4 O 5 at 18, and 1.3631
gms. at 25.
too grams 95% alcohol dissolve 0.0038 gms. BaC 4 H 4 O 8 at 18, and
0.0039 g m - a ^ 2 5-
BARIUM MALONATE BaC 3 H 2 O 4 .N 2 O.
SOLUBILITY IN WATER.
(Miczynski Monatsh. Chem. 7t 263, '86.)
Gms. BaC 3 H 2 O 4 per ioo Gms. Gms. BaC8H 2 O 4 per ioo Gms.
Water. "" Solution. Water. Solution.
o 0.143 0.143 50 0.287 0.285
10 0.179 0.179 60 0.304 0.303
20 0-212 0-2II 70 0.317 0.316
3O O.24I O.24O 80 0.326 0-325
4O O.266 0.265
BARIUM MOLYBDATE BaMoO 4 .
ioo parts water dissolve 0.0058 part BaMoO 4 at 23.
(Smith and Bradbury Ber. 24, 3930, '91.)
BARIUM NITRATE 50
BARIUM NITRATE Ba(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Mulder; Gay Lussac; Etard Ann.chim. phys.f?] 2, 528, 94; Euler Z. physik. Chem. 49, 3is,'o4.)
Cms. Ba(N0 3 ) 2
Gms. Ba(NO 3 ) 2
t.
per 100 Gms.
t.
per 100 Gms.
Water. Solution.
Water. Solution.
5-0 4.8
80
27.0 21-3
10
7.0 6.5
100
34-2 25.5
20
9-2 8. 4
120
42.0 29.6
25
10.4 9-4
140
5o-o 33-3
30
n. 6 10.6
160
58.0 36.7
40
14.2 12.4
180
67.0 40.1
50
17.1 14.6
200
76.0 43-2
60
20.3 16.9
215
84.5 45-8
Sp. Gr. of saturated solution at 19.5 = 1.072.
SOLUBILITY OF MIXTURES OF BARIUM NITRATE AND LEAD NITRATE
IN WATER AT 25.
(Fock. Z. Kryst. Min. 28, 365, '97; at 17, Euler Z. phyisk. Chem. 49, 315, '04.)
J.11 O01UUU11.
A
In Solid Phase
Sp. Gr. of
Solution.
Gms.
per Liter.
Mg. Mols.
per Liter.
Mol.%
Ba(NO 3 ) 2 .
Mol.%
Ba(N0 3 ) 2
Ba(NO 3 ) 2 .
Pb(N0 3 ) 2 .
Ba(N0 3 ) 2 .
Pb(N0 3 ) 2 '
1.079
102.2
O
391.0
O
100
IOO
1. 088
54-9
I7-63
2IO.I
53-3
79.78
98.30
I.IOS
86.5
49.80
330-7
!5o-7
68.70
96.74
I .119
79-7
68.10
304-9
205.7
59-69
94.80
I .140
77.0
97.20
294.4
293.6
50.09
93.62
1.163
69.8
130.7
266.8
395-o
40.31
92-49
1.198
66.0
177-3
252.5
535-6
32-03
90.07
1.252
57-5
247-7
222 .6
748.5
22.91
83-47
1.294
25-9
334-3
99-2
1010.3
8. ii
75-44
I-376
28.8
429.7
IIO-3
1298.0
7-77
35-n
*-459
553-8
O-O
1673.0
0-0
o.o
Tables of results are also given for 15, 30, and 47.
SOLUBILITY OF MIXTURES OF BARIUM NITRATE AND POTASSIUM
NITRATE IN WATER AT 25.
(Foote Am. Ch. J. 32, 252, '04.)
Per TOO Grams Solution.
' Pm K>in Grams ' Solid Phase.
Gms. KN0 3 . B a (N0 8 ) 2 .
14 .89 6 .62 Ba(NO 3 ) 2 and 2 KNO 3 .Ba(NO 3 , 2
1 6 . 30 5 . 49 \ Double salt,
21 99 3 .04 J 2 KN0 3 .Ba(N0 3 ) 2
27 . 76 2 .04 KN0 3 and 2 KNO 3 .Ba(NO 3 ) 2
BARIUM NITRATE
SOLUBILITY OF BARIUM NITRATE IN AQUEOUS PHENOL SOLUTIONS
AT 25.
(Rothmund and Wilsmore Z. phyisk. Chem. 40, 620, '02.)
G. Mols. per Liter. Gms. per Liter. G. Mols. per Liter. Gms. per Liter.
CflHcOH 'Ba(N0 3 ) 2 . C 8 H 5 OH. Ba(NO 3 ) 2 .' C 6 H 5 OH. Ba(NO 3 ) 2 .
0-000 0.3835 0.0 100.2 0.310 0.3492
0.045 0.3785 4.23 98.97 0.401 0.3400
0.082 0.3746 7.71 97-95 0.501 0.3299
0.146 0.3664 13-73 95 - 8
29.12 9 I -3 I
37.73 88.90
47.11 86.26
0.728 (sat.) 0.3098 68.45 81.00
BARIUM NITRITE Ba(NO 2 ) 2 .H 2 O.
SOLUBILITY IN WATER.
(Vogel Z. anorg. Chem. 35. 389, '03.)
Gms. Ba(NO 2 ) 2 per 100 gms. H 2 O
58
20 C
63
30
82
35
97
BARIUM OXALATE BaC 2 O 4 .
SOLUBILITY OF THE THREE HYDRATES IN WATER.
(Groschuff Ber. 34, 3318, '01.)
BaC 2 43 *H 2 0.
BaC 2 O 4 .2HoQ.
t . Gms.BaC 2 O 4 G.M.BaC 2 O 4
per per 100 Mol.
Gms. BaC 2 O 4
per
G. M. BaC 2 O 4
per 100 G. M.
1000 g. Sol.
H 2 O.
looo g. Sol.
H 2 0.
O
0.058
O.OOO46
0-053
O.OOO42
9-5
0.082
o .00066
18
O.II2
O.OOO9O
0-089
O.OOO7I
3
0.170
0.00136
O-I2I
O.OOO97
40
0.152
O-OOI22
45
0.169
0-00135
50
55
O-2I2
O.OOI70
60
. . .
65
0.250
0-OO2OO
73
0.285
0.00228
75
90
100
. . .
.
BaC 2 O 4 .}H 2 O.
Gms.BaC 2 O< G.M. BaC 2 O 4
per per 100 Mol.
1000 g. Sol. H 2 O.
0-089 O.OOO7O
0.124 0.00099
O.I4O O-OOII2
O.I5I O.OOI2I
0.164 O.OOI3I
0.175 0.00140
0.188
O-2OO
O.2II
O.OOI5I
O.OOI6O
0.00169
SOLUBILITY OF BARIUM OXALATE (BaC 2 O 4 .$H 2 O) IN AQUEOUS
ACETIC ACID AT 26-27.
(Herz and Muhs. Ber. 36, 3715, '03.)
of Acetic
Acid.
per
S see
CHaCOOH. Oj ^j ate
of Acetic
Acid.
per 50 cc.
CHaCOOH.
Ba Oxalate
O
O
,0077
o.oo
.0154
3-85
O
.0564
23
.12
O.II27
0-565
O
.0423
3-39
.0845
5-79
.0511
34
.76
0-I02I
I-425
O
.0520
8-55
.1039
O
.0048
103
.90
0-0096
2.85
055 6
17.11
.1111
* Dried
at 70.
BARIUM AOID OXALATE 52
BARIUM AOID OXALATE BaC 2 O 4 .H 2 C 2 O 4 . 2 H 2 O.
SOLUBILITY IN WATER.
(Groschuff.)
Gms. per 100 Gms. Solution.
ll .
H 2 C 2 4 .
BaC 2 4 :
H 2 C 2 4 .
BaC 2 4 . '
per i Mol.Ba<
0.27
0.030
0-054
O.OO24
22
18
0.66
0.070
0.130
0.0056
24
20.5
0.76
0.076
0.15
0-0061
25
38
1.61
0.16
o-33
0.013
25
41
1.82
0.18
o-37
O.OI5
25
53
2 .92
0.31
0.60
O.O26
24
60
3.60
0.40
o-75
0-033
22-5
80
6.21
0.81
O.O7O
19
90
7.96
i .11
1.75
0-098
18
99
10.50
i .55
2-39
O.I4I
17
BARIUM PROPIONATE Ba(C 3 H 6 O 2 ) 2 .H 2 O. also 6H 2 O.
SOLUBILITY IN WATER.
(Krasnicki Monatsh. Chem. 8, 597, '87.)
Gms. Ba(CaH 5 O 2 ) 2 Gms. Ba(C 3 H 5 O 2 ) 2
t e . per loqGtns. t. per 100 Gms.
Water. Solution. Water. Solution.
o 47 -9 8 3 2 -4i 50 62.74 38.57
10 5 J -5 6 34-02 60 64.76 39-3 1
20 54-82 35.42 70 66.46 39.93
30 57-77 3 6 - 6 5 8o 6 7-85 40-42
40 60.41 37.66
BARIUM SULPHATE BaSO 4 .
SOLUBILITY IN WATER.
Electrolytic Conductivity Method.
(Holleman; Kohlrausch and Rose Z. physik. Chem. 12, 131, 241, '93.)
t 2 10 19 26 34 37-7
Gm. BaSO 4 per liter 0.0017 0.0020 0.0023 0.0026 0.0029 0.0031
SOLUBILITY OF BARIUM SULPHATE IN AQUEOUS SOLUTIONS OF HYDRO-
CHLORIC AND OF NITRIC ACIDS.
(Banthisch J. pr. Chem. 29, 54, 1884.)
In Hydrochloric Acid. In Nitric Acid.
^ _^ / A, _^
cc. containing Mgs. BaSO 4 Gms. per 100 cc. cc . containing Mgs. BaSO 4 Gms. per 100 cc.
iMg.Equiv. per i Mg. Equiv. Solution. i Mg.Equiv. per i Mg.Equiv. Solution.
ofHCl ofHCl. HC1. BaS0 4 : of HNO 3 . of HNO 3 . HNO 3 . BaSO 4 .
2.0 0.133 1.82 0.0067 2.0 0.140 3- J 5 0.0070
i.o 0.089 3.65 0.0089 i.o 0.107 6.31 0.0107
0.5 0.056 7.29 o.oioi 0.5 0.085 12. 61 0.0170
O-2 O.OI7 18.23 O.OO86 O-2 0.048 3I-52 O.O24I
100 cc. HBr dissolve 0.04 gms. BaSO 4 ; 100 cc. HI dissolve 0.0016
gms. BaSO 4 at the boiling point.
(Haslam Chem. News 53, 87, '86.)
53
BARIUM SULPHATE
SOLUBILITY OF BARIUM SULPHATE IN AQUEOUS SOLUTIONS OF IRON,
ALUMINUM AND MAGNESIUM CHLORIDES AT 20 25.
(Fraps. Am. Ch. J. 27, 290, '01.)
Cms.
Chloride
Milligran
is BaSO 4 per
Liter in:
Cms.
Chloride
Mgs.
BaSO 4 per
Liter in:
per Liter.
Aq. FeCla-
Aq. AlCla-
Aq. MgCl 2 .
per Liter.
Aq. FeCl 3 .
Aq. AlCla.
Aq.MgCl 2 .
I
58
33
30
25
J 5o
116
50
4
72
43
30
50
160
170
50
5
"5
60
33
100
170
J 75
SO
10
123
94
33
BARIUM PerSULPHATE BaS 2 O 8 . 4 H 2 O.
TOO parts water dissolve 39.1 parts BaS 2 O 8 or 52.2 parts BaS 2 O 8 .
4H 2 O at o.
(Marshall J. Ch. Soc. 59, 771, '91.
BARIUM SULPHITE BaSO 3 .
SOLUBILITY IN WATER AND IN AQUEOUS SUGAR SOLUTIONS.
(Rogowicz Z. Ver Zuckerind. 938, 1905.)
Cone, of
Gm. BaSC
) 4 per 100 cc. Sol.
Cone, of
Gm. BaSO 4 per
100 CC. Sol.
Sugar Sol.
at 20.
at 80.
Sugar Sol.
at 20.
at 80.
oBx
0.0197
0.00177
40 Bx
0-0048
0.00158
10 "
O-OIO4
0-00335
50 "
O.OO3O
O.OOI49
20 "
0-0097
0.00289
60 " (sat.)
O.OO22
0-OOII2
30 "
0-0078
0.00223
BARIUM SUGGINATE AND BARIUM ISO SUGGINATE
Ba.CH 2 CH 2 (COO) 2 . Ba.CH 3 CH 2 (COO) 2 .
SOLUBILITY OF EACH IN WATER.
(Miczynski Monatsh. Chem. 7, 263, 1886.)
Gms. Ba. Iso Succinate
per IPO Gms.
Gms. Ba. Succinate
t. per zoo Gms.
Water.
Solution.
0.421
0.420
10
0.432
0.430
20
0.418
0.417
30
o-393
0.392
40
0.366
0-365
50
o-337
0.336
60
0.306
0-305
70
0.273
0.272
80
0-237
0.237
Water.
Solution.
1.884
1.849
2.852
2.774
3 .6l8
3-493
4.l8l
4-014
4-542
4-346
4-700
4-594
4.656
4-450
4-410
4.224
3.962
3.810
100 gms. H 2 O dissolve 0.396 gms. Ba Succinate at 18 and 0.410
gms. at 25.
100 gms. 95% alcohol dissolve 0.0015 gms. Ba Succinate at 18 and
0.0016 gms. at 25.
(Partheil and Hiibner Archiv. Pharm. 241, 413, '03.)
BARIUM TARTRATE Ba(C 2 H 2 O 3 ) 2 .
SOLUBILITY IN WATER.
(Cantoni and Zachoder Bull. soc. chim. [3] 33, 751, '05; see also Partheil and Hiibner.)
Gms.
Gms. Ba(C 2 H 2 O 3 ) 2
t .
per loo cc.
Solution.
t .
per 100 cc.
Solution.
o
O.O2O5
30
0-0315
10
20
25
O.O242
0.0279
0.0297
40
50
60
0.0352
0-0389
O.O44O
70
80
90
Gms. Ba(C 2 H 2 O a )2
per 100 cc.
Solution.
o . 0480
0.0527
0.0541
BARIUM TARTRATE 54
SOLUBILITY OF BARIUM TARTRATE IN AQUEOUS ACETIC ACID
SOLUTIONS at 26-2j.
(Herz and Muhs Ber. 36, 3715, '03.)
Ul rVL-CUC
Acid.
per 50 VK*
Sol.
CHaCOOH. Ba tartrate.' Add
per 50 cc.
Sol.
CH 3 COOH.
Ba tartrate
O
O
.0328
O-O
0655
3-77
.1866
22
.62
0.3728
0.565
O
.1151
3-39
.2300
5-65
O
.1865
33
.90
0.3726
1.425
- ^-559
8-55
3 JI 5
16.85
O
.02l8
101
.10
0.0436
2 -85
o
. 17 39
17.11
o
3475
.
* Dried at 70.
ioo grams 95% alcohol dissolve 0.032 gm. Ba tartrate at 18 and
0-035 6 m - at 2 5- (Partheiland Hiibner.)
BENZALDEHYDE C 6 H 6 COH.
ioo gms. H 2 O dissolve 0.3 gm. benzaldehyde at room temperature.
(Fluckiger Arch. Pharm. [3] 7, 103, '75.)
BENZAMIDE C 6 H 5 CONH 2 .
SOLUBILITY IN ETHYL ALCOHOL.
(Speyers Am. J. Sci. [4] 14, 295, '02.)
t.
G.M. Gms.
Sp. Gr. of C 6 H 6 CONH 2 C 6 H 5 CONH 2 t o
Solutions, per ioo G.M. per ioo Gms.
Sp. Gr. of
Solutions.
G.M.
C 6 H 6 CONH 2
per ioo G.M.
C 2 H 5 OH.
Gms.
C 6 H 5 CONH 2
per ioo Gms.
0-833
3
.1
8
J 5
40
0.848
II
28.92
10
0.832
4
.2
ii
.04
5o
0.862
14
2
37
34
20
0.833
5
9
J 5
52
60
0.881
J 7
2
45
.22
25
0.835
6
.8
17
87
70
0.913
20
4
53
63
30
0.838
8
.2
21
56
.
SOLUBILITY OF BENZAMIDE IN MIXTURES OF ALCOHOL AND WATEP
AT 25.
(Holleman and Antusch Rec. trav. chim. 13, 294, '94.)
Alcohol.
IOO
95
90
85
83
80
75
BENZENE C 6 H,.
SOLUBILITY IN WATER AT 22.
(Herz Ber. 31, 2671, '98.)
ioo cc. water dissolve 0.082 cc. C 6 H 6 , Vol. of Sol. 100.082,
Sp. Gr. = 0.9979.
ioo cc. C 6 H 6 dissolve 0.211 cc. H 2 O, Vol. of sol. = 100.135,
Sp. Gr. = 0.8768.
Gms.
Gms.
C 6 HeCONH 2
per ioo Gms.
Sp. Gr. of
Solutions.
Vol. %
Alcohol.
C 6 H 6 CONH 2
per ioo Gms.
Sp. Gr. of
Solutions.
Solvent.
Solvent.
17.03
0.830
70
2 3 -87
0.925
21 .12
0.856
60
18.98
0-939
24.50
0.878
50
13-74
0.949
26.15
0-895
40
8.62
0-958
26.63
0.900
31
5-33
0.967
26.43
0-907
2.28
0.912
25.41
0.917
o
i-35
o-999
55 BENZENE
BENZENE, ACETIC ACID, WATER MIXTURES.
(Lincoln J. Physic. Chem. 8, 251, '04.)
NOTE. To mixtures of known amounts of acetic acid and benzene,
water was gradually added until clouding occurred. The same degree
of clouding did not represent the end point in all cases, as was assumed
by Waddel. (J, Physic. Chem. 4, 161, 'oo.)
_ At 25. _ ^ _ At 35. _
cc. cc. cc. cc. cc. cc.
CHaCOOH. C 6 H 6 . H 2 O. CH 3 COOH. C 6 H. H 2 O.
5 10. 06 0.45 ioo 18.10 1.14
5 8.04 0.55 ioo 16.09 I - 22
5 6.03 0.64 ioo 10.06 1.55
5 3.02 0.98 ioo 6.03 2.17
5 2 .01 1.28 ioo 4.02 2.77
5 i .01 1.89 ioo 3.01 3.26
5 0.60 2.80 ioo i .00 7.01
5 0.35 4-54 ioo 0.65 10.10
5 o- 1 ? 9-53 I0 o-47 J 3- 6 4
BENZENE, AQ. ALCOHOL MIXTURES; BENZENE, AQ. ACETONE MIX-
TURES AT 20.
H 2 O added to mixtures of known amounts of the other two and
appearance of clouding noted.
(Bancroft Phys. Rev. 3, 31, 1895.96.)
C 6 H 6 ,C 2 H 5 OH and H 2 O C 6 H 6 ,CH 3 OHandH 2 O C 6 H 5 ,(CH 3 ) 2 COandH 2 O
Per 5 cc. C 2 H 5 OH. Per 5 cc. CH 3 OH. Per 5 cc. (CH 3 ) 2 CO.
cc. H 2 O. cc. C 6 H C .~
8.O O-IO
3-o Q-395
2.O 0-69
1.3 i.o
0-51 2.0
0.295 3.0
O.2 4.0
0.15 5-0
MUTUAL SOLUBILITY OF BENZENE AND /3 NAPHTHALENE PICRATE
C 6 H 2 (N0 2 ) 3 OH.C 10 H 7 OH.
" Synthetic Method " used see Note, p. 9.
(Kuriloff Z. physik. Chem. 24, 442, '97.)
cc. HzO.
cc. C 6 H.
'cc. H 2 0.
cc. C 6 H:
20
0.03
5-o
0.15
8
0.13
3-o
0.215
4
o-39
2.O
0.59
2
1.17
1.4
1 .0
i-5
1.87
I.O
1.9
i.o
3-57
0.8
3-o
0.605
8.0
0.69
4.0
0.34
20. o
0.49
8.0
t o Gms.
Gms.
e Gms.
Gms.
Picrate.
Benzene
a
Picrate.
Benzene.
ct.
157
IOO
O
. . .
100.0
in
.6
i
173
I
37
19 2
148.4
2
.128
O.II5
79-3
102
.0
i
.087
I
.780
II. 2
137-4
I
.274
0.170
61.1
29
5
390
8
430
o-95
134.2
I
384
0-297
49-3
4
.6
i
3 2 9
21
.80
0.48
126.8
I
.019
0-343
38-3
5
.02
IOO
o
a = Mols. Naphthalene Picrate per ioo Mols. of Napthalene
Picrate plus Benzene.
Determinations for a large number of isothermes are also given.
BENZENE 56
SOLUBILITY OF BENZENE IN SULPHUR.
By " Synthetic Method, " see Note, p. 9.
(Alexejew Ann. Physik. Chem. 28, 305, '86.)
t o Gms. C 6 He per 100 Gms. t <> Cms. C 6 H 8 per 100 Gms.
S Layer. C 6 H Layer. S Layer. C 8 H Layer.
loo 6 75 140 16 61
no 8 72.5 150 19 55
120 10 70 160 25 45
130 12 66 164 (crit temp.) 35
Di Brom BENZENE (p) C 6 H 4 Br 2 .
SOLUBILITY IN ETHYL, PROPYL, Iso BUTYL ALCOHOLS, ETC.
(Schroder Z. physik. Chem. n, 456, '93.)
Determinations by " Synthetic Method" see Note, p. 9.
Grams C 6 H 4 Br 2 (/>) per 100 Grams Sat. Solution in:
1 .
C 2 H 6 OH.
CjjHyOH.
(CH 3 )CH.CH 2 OH.
(C 2 H 6 ) 2 0.
CS 2 .
C 6 H 6 .
C 6 H 6 Br.
27
10
30
34
34
22
20
38
43
43
29
30
14
'5
47
53
53
36
40
*9
2O
57
62
62
45
50
26
27
30
67
72
7i
54
00
38
40
44
77
81
80
67
70
57-6
67
65
87
90
88
79
75
80.5
85
77
. .
84
80
94-4
95
94.6
90
Chlor BENZENE C.H.Q.
SOLUBILITY OF CHLOR BENZENE IN SULPHUR.
" Synthetic Method, " see page 9.
(Alexejew.)
Grams C 8 H S C1 per 100 Grams.
** Sulphur Chlor Beri-
Layer. zene Layer.
00 13 70
ioo 18.5 63
no 27 53
116 (crit. temp.) 38
For the solubility of Mixtures of di Chlor Benzene and di Brom
Benzene in aqueous Ethyl Alcohol solutions see Thiel.
(Z. physik. Chem. 43, 656, 1903.)
Di Nitro BENZENE (m) C 6 H 4 (NO 2 ) 2 .
SOLUBILITY IN BENZENE, BROM BENZENE AND IN CHLOROFORM.
" Synthetic Method."
(Schroder.)
Gms. C 6 H4(NO 2 ) 2 per ioo Gms. C 6 H4(NO,) 2 per
t. Gms. Sol, in: jo ioo Gms. Sol, in:
CH 6 . C 6 H 6 Br. CHClg. C 6 H 6 . C 6 H 5 Br.
15 17.5 ... 22.2 40 52.0 38.0 42.0
20 26.0 18.5 25.0 50 62.5 47.5 52.5
2 5 33-o 23.7 29.0 60 71.0 57.0 65.0
30 40-0 28.7 33.0 ...... .....
57
BENZENES
Solubilities of Di-Nitro BENZENES and of Tri-Nitro BENZENES in
Several Solvents.
, (de Bruyn Rec. trav. chim. 13, 116, 150, '94.)
Grams per 100 Grams Solvent.
Solvent.
**' (N(Sv ( <$$r $8fir
(NO!': wcwo*
Methyl Alcohol
Ethyl Alcohol
20
2O.
5
5
3
i.
3<>
9
6
3-
75
5
0.69
0.4
4
i
9
9
(16) 16.2 (15.5)
(16) 5.45 (IS. 5)
Propyl Alcohol
2O.
5
i .
00
2.
4
0.298
9
Carbon Bi-Sulphide
17.
6
0.236
I.
35
0.148
25
Chloroform
17-
6
27.
i
3 2 -
4
1.82
6
.1
Benzene
18.
2
5.66
39-
45
2.56
6
.2
(16)
Ether
17'
5
. .
.
..
i
5
Ethyl Acetate
18.
*
12.
96
36-
27
3-56
t
Toluene
16.
2
3-
62
66
2.36
fm
Carbon Tetra Chloride
16.
2
0.
J 43
i.
18
0.12
,
Water
(ord.)
O.
014
o.
5 2 5
0.008
..
.
Symmetrical Tri-Nitro BENZENE.
SOLUBILITY IN AQUEOUS ALCOHOL AT 25.
(Holleman and Antusch Rec. trav. chim. 13, 206, '94.)
Vol.%
Alcohol.
G. C 6 H 3 (N0 3 )3(5)
per 100 g.
Solvent.
Sp. Gr. of
Solutions.
Vol.%
Alcohol.
G. C 8 H 3 (N0 8 )3to
per roo g.
Solvent.
Sp. Gr. of
Solutions.
100
2-34
Q-7957
80
o-57
0.8582
95
i-57
0.8131
75
o-47
0.8708
90
1. 12
0.8288
70
o-37
0.88o8
85
0-79
0.8436
60
0.23
0.9064
BENZOYL PHENYL HYDRAZINE C 6 H 5 .NH.NH.C 7 H e O.
SOLUBILITY IN AQUEOUS ALCOHOL.
(Holleman and Antusch Rec. trav. chim. 13, 291, '94.)
Vol.%
Alcoho
IGms. Hydrazine
per loo g.
Solvent.
Sp. Gr.
Solutions.
100
2-39
0-793
95
2.43
0.814
93
3. co
0.822
90
2.26
0.831
Vol.%
Alcohol.
Gms. Hydrazine
per 100 g.
Solvent.
Sp. Gr.
Solutions.
80
70
1 59
1. 08
0.859
0.884
55
40
0.51
0.16
0.917
0.946
BENZO SULPHONIG ACIDS.
SOLUBILITY IN WATER.
(Bahlman Liebig's Ann. 186, 309, '77.)
Name of Acid.
0- Amido benzo sulphonic acid.
Amido brom benzo sulphonic acid.
Mono brom amido benzo sulphonic acid.
Barium di-brom benzo sulphonic acid.
Barium nitro brom benzo sulphonic acid
(hydrated).
Barium nitro brom benzo sulphonic acid
(anhydrous).
* At 18 = i.
Gms. Sulphonic Acid per 100 Gms.
Solution at:
11 = 1.301
8 = 0.737
12 = 0.431
14 =L7I3
16 0.527
8 = 0.156
15 = 1.436
16 = 1.131*
15 = 0.463
9 = 1.098
30 = 0.914
BENZINE 58
BENZINE (Petroleum) C 6 H 12 C 6 H 14 .
ioo parts of alcohol dissolve about 16 parts benzine of 0.638
0.660 Sp. Gr., at 25.
BENZOIO ACID C 6 H 8 COOH.
SOLUBILITY IN WATER.
(Bourgoin Ann. chim. phys. [5] 15, 171, '78.)
Grams. QHsCOOH Grams. C 6 HsCOOH
t. per ioo Gms. t. per ioo Gms.
Water. Solution. Water. Solution.
o 0.170 0.170 40 0.555 0-55 1
10 0.210 0.209 50 0.775 0.768
20 0.290 0.289 60 I - I 55 1.142
25 0.345 0.343 80 2.715 2.643
30 0.410 0.408 ioo 5- 8 75 5-549
ioo grams saturated aqueous solution contains 0.340 gram
C 6 H 6 COOH at 25; 0.353 g ra m at 2 6.4 ; 0.667 gram at 45.
(Paul Z. physik. Ch. 14, in, '94; Noyes and Chapin Ibid. 27, 443, '08; Hoffman and Langbeck
Ibid. 51, 393, '05; Philip J. Ch. Soc. 87, 992, '05 ; see also Alexejew Ann. Phys. Ch. 28,
305, '86; Ost J.pr. Ch.[2] 17, 232, '78; Vaubel Ibid.\2\ 52, 73, '95.)
SOLUBILITY OF MIXTURES OF LIQUID BENZOIC ACID AND WATER.
(Alexejew.)
Determinations by " Synthetic Method," see Note, p. 9. Figures
read from curve.
Gms. C r ,H 5 COOH per ioo Gms. e Gms. C 6 H 5 COOH per ioo Gms.
Aq. Layer. Benzoic Ac. Layer. Aq. Layer. Benzoic Ac. Layer.
70 6 83 ioo 12. o 69.0
80 7.5 79.5 no 18.0 59.0
90 8.5 76 116 (crit. temp.) 35
SOLUBILITY OF BENZOIC ACID IN AQUEOUS SOLUTIONS OF:
(Hoffman and Langbeck.)
Nor-
mality
Potassium Chloride at 25.
J!f- Dissolved CfiHsCOOH. ^~ v
Potassium Nitrate at 25.
^335; Dissolved QHgCOOH.
of Aq.
KC1
LJJ^ Mol. Cone. Wt. per cent. KNOs
per
Liter.
Mol. Cone
Wt. per cent.
0-02
1-49
5 . 0254-10"*
0.
339
O.02
2.
02
5.0326-10-*
0.340
0.05
3-73
4.9801
o.
333
0.05
5-
06
5.0421
a
0.341
0.20
14.92
4-7639
o.
322
0.20
20.
24
5.0297
ft
0.340
0.50
37-30
4-3632
o.
295
0.50
50-
59
4.9400
if
0-334
I -OO
IOI .
19
4 . 7646
0.322
SOLUBILITY OF BENZOIC ACID IN AQUEOUS SOLUTIONS OF:
(Hoffmann and Langbeck.)
Sodium Chloride.
Sodium Nitrate.
Nor-
mality
of Aq
Gms.
NaCI
Gms. CfiHsCOOH
per ioo Gms. Sol.
Nor-
mality
of Aq
NaNC-3
Gms. CgHgCOOH
per ioo Gms. Sol.
NaCI.'
liter.
at
25-
at
45.
NaNO 3 .
L^ter.
at 25.
at 45:
o.oo
.00
O-
340
o.
667
0-02
1.70
340
0.666
O-O2
I
17
0-
339
o.
663
0-05
8. 5 I
O
339
0.663
O.O5
2
93
O-
335
o.
654
O-2O
17 .02
O
333
0.647
0.20
II
.70
o.
336
o.
6l 7
0.50
42-54
3i9
0.613
0.50
29
25
0-
282
o.
546
I.OO
85.09
o
.294
. . .
I.OO
58
50
.
o-
449
59
BENZOIO ACID
SOLUBILITY OF BENZOIC ACID IN AQUEOUS SOLUTIONS OF SODIUM
ACETATE, FORMATE, BUTYRATE, AND SALICYLATE.
(Noyes and Chapin Z. physik. Chem. 27, 443, '98; Philip J. Ch. Soc. 87. 993, '05.)
Grams
Gram:
s QjH 5 COOH
per Liter of S<
)lution in:
Sodium
Salt per
CHaCOONa.
HCOONa.
CaHrCOONa. CoH^OH.COi
Liter.
At 25.
At 26. 4 6 .
At 25.
At 26.4.
At 26.4.
At 26.4".
O
3-41
3-53
3-41
3-53
3-53
3-53
I
4-65
4-75
4-25
4-35
4.50
3-62
2
5-7
5-85
4-75
4.85
5-40
3
6.70
6.90
5-20
5-30
6-15
3-8o
4
7.60
7-85
5-6o
6.90
3-87
6
8.40
4.00
8
4-10
Sodium Salt
per Liter.
O-OO
O-OI
O-O2
0.03
0-04
O-o6
CH 3 COONa.
HCOONa.
CaH 7 COONa.
At 26.4.
0.0289
0.0376
0.0455
0.0525
0-0596
CaH4OH.COONa
At 26.4.
0.0289
0.0300
0.0312
0.0321
0.0328
0.0342
At 25.
0.0279
0-0362
o . 0440
0.0508
0.0572
At
o.
O-
o.
o.
o.
26.4.
0289
0370
0448
0518
0586
At 25.
0.0279
0.0330
0-0364
0.0392
O.O4I6
0-0460
At 26.4.
0.0289
0.0336
0.0372
0-0398
0.0423
0-0466
SOLUBILITY OF BENZOIC ACID IN ABSOLUTE ALCOHOLS.
(Tirrofeiew Compt. rend. 112, 1137, '91; at 15, Bourgoin Ann. chim. phys., [5] 13, 406, '78.)
In Methyl Alcohol. In Ethyl Alcohol.
G. CeH 6 COOH
per IPO Cms.
G. CeH 5 COOH
per 100 Gms.
In Propyl Alcohol.
G. QH 6 COOH
per 100 Gms.
3
'5
21
CHaOH.
50-16
Solution.
33-39
69.29 40.93
C 2 H 5 OH.
40.16
46.70
54-09
Solution.
28.65
31.80
35 -io
CaH 7 OH.
29.88
Solution.
23.00
40.64 28.90
SOLUBILITY OF BENZOIC ACID IN 90% ALCOHOL, IN ETHER AND IN
CHLOROFORM.
(Bourgoin.)
Solvent.
90% Alcohol
Ether
Chloroform
Gms. CgHsCOOH per 100 Grams.
Solvent. Solution."
15 41.62 29.39
15 3 r -35 23.86
25 14-30 12.50
SOLUBILITY OF BENZOIC ACID IN AQUEOUS SOLUTIONS OF DEXTROSE.
Normality of
<Vq. Dextrose.
Gms. CeH l2 <
per Liter.
O-O2
3-67
0.05
9-00
0.204
36.73
o-533
1. 068
96.15
192.30
(Hoffman and Langbeck.)
Dissolved CH 6 COOH at 25.
5.0322.10 4
o-34
5-0403 "
o-34
5-0303 "
0-34
5-032I '
o-34
5-0443 "
0-341
Dissolved CeHsCOOH at 45.
Veight
er Cent.
Mol. Cone.
Weight "
Per Cent.
o-34
9.9o88.io~ 4
0.674
o-34
9.9328 "
0-669
0-34
9-9323 "
0.669
o-34
IO-OIOI '
0.674
0.341
10.0369 "
0.676
BENZOIO AOID
60
SOLUBILITY OP BENZOIC ACID IN AQUEOUS SOLUTIONS OP UREA AND
OP THIO UREA.
(Hoffman and Lang beck.)
Normality Cms. CaH 6 COOH Dissolved at 25.
of Solution. per Liter. Mol. Cone. Wt. per cent.
In Aqueous Urea o.io 6.01 CO(NHg)j 5-i876.io~ 4 0.350
In Aqueous Thio Urea 0.20 15.23 CS(NH2) 2 5-4994 " 0.372
Amido BENZOIO ACIDS C 6 H 4 .NH 2 .COOH (m).
SOLUBILITY IN WATER AND IN OTHER SOLVENTS.
(de Coninck Compt. rend. 116, 758, '93.)
In Organic Solvents.
In Water.
...
Cms.
CeH4.NH 2 .COOH(f)
per zoo cc. H^.
0-43
10
20
30
0.52
0-67
0.87
40
1 fI 5
5
i. So
00
2-15
7o
3-i5
Solvent.
Ethyl Alcohol (95%)
Methyl Alcohol (pure)
Acetone
Methyl Iodide
Ethyl Iodide
Chloroform
Bromoform
t.
12-5
10.5
"3
10.0
o.o
12.0
8.0
Gms.
CH4.NH 2 .COOH(m)
per 100 cc. Solvent.
2 .92
4-05
6.22
0-04
0.02
O.O7
trace
SOLUBILITY OF THE THREE ISOMERIC AMIDO NITRO BENZOIC ACIDS.
In Ether.
Cms. CH3.NO3.NH2.COOH
. o per zoo cc. Ether.
Ortho. Meta. Para.
2-7 10.84 1.70 6.41
5.8 16.05 (6.8) 1.81 8.21
3
9 .6
In Ethyl Alcohol (90%).
Cms. CeHgNOs-NHa.COOH
per TOO cc. Alcohol.
Ortho. Meta. Para.
8.13 1.79 8.4
10.70 2.20 II-3
SOLUBILITY IN WATER OF THE THREE ISOMERIC:
(Vaubel J. pr. Chem. [2] 52, 72, '95.)
Amido Benzo Sulphonic Acids. Amido Phenols.
G. C6H4.NH 2 .SO 2 H per 100 g. Aq. Sol. ^ G . QH^OH) .NH 2 per 100 g. Aq. Sol.
Ortho. Meta. Para. Ortho. Meta. Para.
7 i. 06 1.276 0.592 (6) o 1.7 2.6(20) i.i
Brom, Chlor, and lodo BENZOIO ACIDS.
SOLUBILITY IN WATER AT 25.
(Paul Z. hysik. Chem. 14, in, '94; Lowenherz Ibid.
Compound.
Brom benzoic acid.
Brom benzoic acid.
Brom benzoic acid.
Chlor benzoic acid,
lodo benzoic acid,
lodo benzoic acid.
Formula.
C 6 H 4 Br.COOH (ortho).
C 8 H 4 Br.COOH (meta).
C,H 4 Br.COOH (para).
C,H 4 C1.COOH (ortho).
C 8 H 4 LCOOH (ortho).
C C H 4 I.COOH (meta).
Sf 401, '98; Vaubel.)
Per looo cc. Aqueous Solution.
Grams. Gram Mol.
1.856 0.00924
o .402 o .00200
0.056 0.00028
2.087 0.01333
0.95
0.12
6i
BENZOIC ACIDS
SOLUBILITY OF ORTHO HYDROXY BENZOIC ACID (SALICYLIC ACID), META
HYDROXY BENZOIC ACID, AND PARA HYDROXY BENZOIC ACID (ANISIC
ACID) IN WATER, BENZENE, ETC. (See also pp. 38 and 274.)
(Walker and Wood J. Ch. Soc. 73, 622, '98; Vaubel J. pr. Chem. [2] 52, 73, *9S.)
ioo gms. aq. solution contain 0.225 S m - C 6 H 4 .OH.COOH (o) at
15 (Vaubel).
ioo gms. aq. solution contains 0.794 gm. C 6 H 4 .OH.COOH (p) at
15 (Vaubel).
Gms. C H 4 .OH.COOH
per too Gms. HfeO.
10
20
25
30
35
40
So
60
80
23
Meta.
o-S5
0-90
1. 08
1.64
2.10
Para.
0.25
0.50
0-65
0.81
i. 01
1.24
2.12
Gms. CflH4.OH.COOH
per ioo Gms.CaHfl.
Meta.
Para."
. . .
O.OOlS
0.008
O.OO27
o.oio
0.0035
0-012
O-OO45
0.015
0.0060
0.017
0.0082
0.028
0.0162
0.047
0.028
0.066
In Acetone.
G. CeH4.OH.COOH
per ioo cc. Sol.
Meta. Para^
26.0 22-7
In Ether.
G. C 8 H4.0H.COOH
per ioo cc. Sol.
17
Meta.
9-73
Para.
9-43
Methyl BENZOIO ACIDS C 6 H 4 COOH.CH 3 . o, m, and p.
SOLUBILITY IN WATER.
(Vaubel.)
Gms. CflH4COOH.CH 3 per 1000 Gms. Sat. Solution.
25
Ortho.
1.18
Meta.
0.98
Para.
o-35
Nitro BENZOIO ACIDS C 6 H 4 .NO 2 .COOH. o, m, and p.
SOLUBILITY IN SEVERAL SOLVENTS.
(de Coninck Compt. rend. 118, 471, '94; for solubility in H2O, see also Paul, Vaubel, LSwenherz,
and Goldschmidt Z. physik. Chem. 23. 95, '96.)
Gms. CflH4.NO 2 .COOH per ioo cc. Solvent.
ocuvem. * .
Ortho. Meta.
Para.
Water 20
0.682(0.654G.) 0.315
0.039
Water 25
0-743-0-779 0.341
0.028
Water 30
0.922
. . .
Methyl Alcohol 10
42.72 47.34
9 .6
Ethyl Alcohol 10
28.2 33.1(11.7)
0-9
Ethyl "(33Vol.%)is
0.64(11.8) 0.52
0-055
Acetone 10
41-5 41-5
4-54
Benzene 10
0.294 0.795
0.017(12.5)
Carbon Bi-Sulphide 10
0-012 0.10(8.5)
0.007
Chloroform 10
o.45S(-) 5-678
0-066
Ethei 10
21.58 25.175
2.26
Ligrbin 10
trace 0.013
o.oo
BENZOIO ACIDS 62
SOLUBILITY OF PARA NITRO BENZOIC ACID IN AQUEOUS SOLUTIONS
OF ANILIN AND OF PARA TOLUIDIN AT 25.
(Lowenherz Z. physik. Chem. 25, 395, '98.)
In Anilin. In ^-Toluidin.
G. Mols. per Liter. Cms, per Liter. G. Mols. per Liter. Cms, per Liter.
cdc-H 2 '
CcH 5 NH 2
COOH 2 CH 3 . *" COOH. 2
C 6 H 4 NH 2 -
CH 3 .
CH4N(V
COOH.
O-O
.00164
0-0
o
274
O-O
O
.00164
O
.0
0.274
O-OI
o
.00841
0.91
X
406
O-OI
OIOO
I
.071
I .671
O-O2
o
.01379
1.82
2
34
0-02
0174
2
.142
2.902
0.04
.02172
3- 6 4
3
629
0-03
o
.0245
3
.213
4-097
0.08
o
0347
7.29
5
798
SOLUBILITY OF ORTHO NITRO BENZOIC ACID IN AQUEOUS SOLU-
TIONS OF SODIUM BUTYRATE, ACETATE, FORMATE, AND
SALICYLATE AT 26.4.
(Philip J. Chem. Soc. 87, 992, '05.)
Original results in terms of - per liter.
Cms. Na Salt
<jras. v-rino v^cn4V^wv-n.iNv^2 per j_>iier 01 ooiuuon in:
per Liter.
C 3 H 7 COONa.
CH 3 COONa.
HCOONa.
C 6 H4.OH.COONa.
O
7-85
7-85
7-85
7-85
o-5
8-35
8-50
8.60
8-35
I.O
8.90
9-15
9-50
8.70
2
IO-O
I0.8o
"$
9-4
3
II .2
12-55
13-5
II.
4
12-4
i4-5
I 5 .6
"5
6
15-2
SOLUBILITY OF ORTHO NITRO BENZOIC ACID IN AQUEOUS SOLUTIONS
OF DEXTROSE, SODIUM CHLORIDE, AND OF SODIUM NITRATE.
Original results in molecular quantities.
(Hoffman and Langbeck Z. physik. Chem. 51, 412, '05.)
In Dextrose. In NaCl. In NaNO 3 .
1
G. CeH l2 8
per 100 cc.
G.(o)C 6 H4N0 2 .COOH G. NaCl.
per 100 g. Solvent. WI IOO cc
G.&OC.EUN02.COOH G .NaNO 3
. per loo g. Solvent. pe r I00 cc .
G.(o)C6H 4 N0 2 .COOH
per TOO g. Solvent.
Solution.
At 25. At 35.
Solution.
At 25.
At 35.
Solution.
At 25.
At 35.
0-0
0.736
-063
O.II7
O
743
I .072
.170
.746
1.074
0.36
0.736
.064
0.195
O
.746
1-075
.284
754
I.OSO
1. 80
0.732
O6l
0.585
O
749
I .O7O
.851
.767
I -096
9-50
O.722
.051
2.425
.688
0.967
4
255
774
1.097
20-00
0.703
.030
5.80
o
597
0.831
8
.510
748
1.047
BENZOIO SULPHINIDE (Saccharine) C 6 H 4 <^Q 2 >NH.
100 parts water dissolve 0.4 part at 25 and 4.17 parts at 100.
loo parts alcohol dissolve 4 parts at 25 (U. S. P.).
BENZOPHENONE
BENZOPHENONE (C 8 H 5 ) 2 CO.
SOLUBILITY IN AQUEOUS ALCOHOL AND IN OTHER SOLVENTS.
(Derrien Compt. rend. 130, 722, 'oo; Bell J. Physic. Chem. 9, 550, '05.)
In Aqueous Alcohol at 40.
(Bell.)
Akoh?l
Cms. (CoH 6 ) 2 CO
per loo^Gms.
in Solvent.
Solvent.
Solution.
40
2
1-9
45
5
4-8
SO
8
8-3
55
II
99
60
16
13-8
65
28
22.6
Wt.%
Gms. (CH 8 ) 2 CO
Alcohol
per 100 Gms.
in Solvent.
Solvent. Solution.
67-5
39 28.1
70
5 6 359
71
67 39.2
72
90 47-4
72-5
105 51.2
73
156 61.0
In Aqueous Alcohol and other Solvents.
(Derrien.)
Solvent.
97% Ethyl Alcohol 17
8500. 97% Alcohol + i5CC.H 3 O "
80" " +20"
75" " +26"
Methyl Alcohol (pure) 9 .8
15.0
Acetic Ether (pure) 9.6
Carbon Bisulphide 16.1
Gms.
(C6H 6 ) 2 CO
per 100 g.
Solvent.
13-5
3-8
2 .2
II .O
14-3
19 .2
66.6
Solvent.
Benzene
Xylene
Nitro Benzene
Chloroform (com.)
Bromoform
Toluene
Ligroine
II*
15-8
16.5
17-3
I? 'A
14.6
Gms.
(CeH 5 ) 2 CO
per
100 g.
Solvent.
76.9
38.4
58.8
55-5
33-3
55-5
6.7
BERYLLIUM HYDROXIDE Be(OH) 2 (See also Glucinium, page 140).
SOLUBILITY IN AQUEOUS SOLUTIONS OF SODIUM HYDROXIDE.
(Rubenbauer Z. anorg. Chem. 30 334, '02.)
Moist Be(OH) 2 used, solutions shaken 5 hours, temperature prob-
ably about 20.
Molecular
Gms. per IOQ^CC. Solution.
'NaOH. Be(OH) 2 ."
Per 20 cc.
Solution.
Dilution
of the
NaOH.
0.68
o-53
0.27
Gms. Na.
o-335 8
0.6716
0.8725
I-7346
Gms. Be.
0.0358
0.0882
O.II75
0-2847
2.917
5.840
18.310
BERYLLIUM SULPHATE BeSO,.
SOLUBILITY IN WATER.
(Levi, Malvano Z. anorg. Chem. 48, 446, '06.)
0.850
2.094
2.789
6.760
Mols. H 2 O
per i M ol
Gms. BeSCu per
100 Gms.
Solid
Mols. H 2
4. o per i Mol.
Gms. BeSO 4 per
100 Gms.
Solid
t.
BeS0 4 . "
Water.
Solution.
Phase.
* ' BeS0 4 .
Water.
Solution.
Phase.
31
ii. 18
52-23
34-32
BeSO 4 .6H,O
95-4
6.44
90.63
47-55
BeSO. 4 H O
5
9.62
60.67
37-77
"
107.2
5.06
^5-3
53.58
'
72.2
7-79
74-94
42-85
in
4-55
I2-S.3
56.19
77-4 7- J 3
81.87
45.01
80
6.89
84.76
45-87
BeSO
.2H,C
3
13.33
43.78
3-45
BeSO
4 H,0
91.4
5-97
97-77
49.42
*
40
12.49
46.74
*
IO 5
4-93
118.4
54.21
68
9.42
61.95
38-27
1
119
3-9 1
149-3
59-88
1
85
7-65
76.30
43-28
*
BISMUTH 64
BISMUTH Bi.
MUTUAL SOLUBILITY OP BISMUTH AND ZINC.
(Spring and Romanoff Z. anorg. Chem. 13, 34, '06.)
266
419
475
Upper Layer.
Lower^ Layer.
584
650
75o
Upper Layer.
Lower Layer.
%Bi. %Zn."
86 14
84 16
%Bi. %Zn.
3 97
5 95
%Bi. %Zn.
80 20
77 23
70 30
%Bi. %Zn.
10 90
15 85
27 73
810-820 (crit. temp.)
BISMUTH CHLORIDE BiCl 3 .
100 grams absolute acetone dissolve 17.9 grams BiCl 3 at 18.
(Naumann Ber. 37, 4332, 1004.)
BISMUTH IODIDE BiI 3 .
100 grams absolute alcohol dissolve 3.5 grams BiI 3 at 20.
(Gott and Muir J. Chem. Soc. 57. 138, '90.)
ioo grams methylene iodide CH 2 I 2 dissolve 0.15 gram BiI 3 at 12.
(Retgers Z. anorg. Chem. 3, 343, '93.)
BISMUTH NITRATE Bi(NO 3 ) 8 .5H 2 O.
ioo grams acetone dissolve 48.66 grams Bi(NO 3 ) 3 .5H 2 O at o, and
41.7 grams at 19.
(von Laszczynski Ber. 27, 2285, '94.)
BISMUTH OXIDE Bi 2 O 3 .
SOLUBILITY OF BISMUTH OXIDE IN AQUEOUS NITRIC ACID AT 26.
(Rutten and van Bemmelen Z. anorg. Chem. 30, 386, '02.)
Present in Shaker
Flask.
Gms. per ioo Gms.
Solution.
Mols. per ioo Mols. H 2 O.
Solid
Per i part Bi 2 O 3 .
3N 2 O 5 .ioH 2 O.
Bi 2 O 3
N 2 5
Bi 2 3
N 2 5 R
1N 2 B 2 , 3
Phase.
24.4 parts H a O
3.2 parts H 2 O
0-321
6-37
0.963
7.17
o 126
2.844
1.61
13.82
J
j
12.8
4.8
Bi 2 8 .N,0 6 .2H,0
Dilute HNO,
Dilute HNO 3
18.74
31.48
15-9
2 3-7
10.50
27.2
I
3-6
3.0 J
Bi s O,N 1 5 .H,0
Dilute HNO 3 =
6.13% N 2 6
32-93
24.83
30.15
97.97
I
3-2
f Bi 2 O 3 .N 2 Oj5.H,O and
Bi 2 O s .3N,O 6 .ioH 2 O
6.816% N 2 5
32.67
24.70 '
29.70
96.57
j
3-2]
24.0% N 2 O 6
51.0% N 2 O 5
24.16
11.66
28.25
46.62
19.65
10.81
98.76
186.23
X
I
5-0
17.2
-Bi 2 O s .3N 2 O 5 .ioH,O
70.0% N 2 O 5
20.76
53-75
33-51
355.87
I
10.6,
27.85
51.02
51.0
403.0
I
7-9
Bi 2 O 8 .3N 2 O 5 .ioH 2 O and
Bi 2 O s .3N 2 O s .3H 2 O
Anyhdrous HNO
Bi 3 O 3 + "
38.56
4.05
68.28
74.90
14.35
7.45
492.0
592-9
I
j
34-3
79.5
Bi,0,. 3 N,Os.3H,0
Results are also given for 9, 30, and 65.
65 BORIC AOID
BOEIO ACID (Ortho) H 3 BO 3 .
SOLUBILITY IN WATER.
(Ditte Corapt. rend. 85, 1069, 77; Herz and Knoch Z. anorg. Chem. 41, 319, '04.)
Gms. H 3 BO 3 per
jo_ 100 Gms.
Gms. B 2 O 3
penooGms. t.
Gms. HsBO 3 per
loo Gms.
Gms. B2C
per 100 Gn
Water.
Solution.
H 2 O.
Water.
Solution. H2O.
O
I
95
I
.91
I
.1
40
7-0
6
54
3-95
IO
2
.70
2
63
I
5
5
8.8
8
.09
5-o8
20
4
.0
3
85
2
25
60
II.
9
.91
6.2
25
4
7
4
49
2
65
80
16.8
14
38
9-5
30
5
4
5
.12
3
05
IOC
27-5
21
57
I 5-5 2
The above results of Ditte are probably low.
Herz and Knoch find for 13, 3.845 grams H 3 BO 3 per 100 cc. solution,
for 20, 4-99> 2 5> 5-593' and 26 > 5- 6 37-
Bogdan finds 5.753 grams H 3 BO 3 per 100 grams H 2 O at 25.
SOLUBILITY OF BORIC ACID IN AQUEOUS SOLUTIONS OP HYDROCHLORIC,
SULPHURIC, AND NITRIC ACIDS AT 26.
(Herz Z. anorg. Chem. 33, 355, 34, 205, '03.)
Normality of
the TToSO HfM
Normality of
Dissolved.
Gms. Strong Acid
Gms.
B(OH) 3 per 100 cc.
Solution.
ine xi2ov^/4, riv^i
or HNO 3 .
B(OH) 3 .
Solution.
In HC1.
In H 2 SO 4 .
In HNO 3 .
O
0-91
O
5- 6 4
5- 6 4
5.64
o-S
0-78
5
4-0
4.25
4-50
I .0
0.71
10
3-2
3-6
3-9
2.O
0.58
15
2-45
3-o
3-35
3-0
0-49
20
1.8
2-5
2-9
4-0
0-41
25
2.0
2-55
5 -
o-35
30
*-55
2.1
6.0
0.26
35
1-75
The determinations given in the original tables in terms of normal
solutions when plotted together lay close to an average curve drawn
through them. The figures in the tables here shown 'were read (and
calculated) from the average curve.
SOLUBILITY OF BORIC ACID IN AQUEOUS SOLUTIONS OF ELECTROLYTES
Gms. Electro-
AT 25.
(Bogdan Ann. Scient. Univ. Jassy, 2, 47, 'o2-'o3.)
Grams H 3 BO 3 per too Gms. H2O in Aq. Solutions of:
lytc per 100
Gms. H 2 O.
NaCl.
KCl.
NaNO 3 .
KNO 3 .
Na 2 SO 4 .
K 2 S0 4 .
O
5-75
5-75
5-75
5-75
5-75
5-75
IO
5-75
5.80
5-78
5.81
5-88
5-92
20
5-74
5.86
5.81
5-88
6.00
6.10
40
5-72
5-98
5-87
6.04
6.33
6.50
60
5-72
6.12
5-95
6. 20
6.70
6.92
80
5-7i
6.29
6. 02
6.37
7.10
7.40
Interpolated from the original.
100 parts alcohol dissolve 6.5 parts H 3 BO 3 at 25 and 23 parts at
b. pt. (U. S. P.).
BORIC ACID
66
SOLUBILITY OF BORIC ACID IN AQUEOUS SOLUTIONS OF UREA, ACE-
TONE, AND OF PROPYL ALCOHOL AT 25.
(Bogdan.)
Grams of
CO(NH 2 )2,(CH3) 2 CO
or of CsHyOH per
100 Gms. H 2 O.
10
20
40
60
Gms. HaBOs per 100 g. H 2 O in Aq.
Solutions of:
JL
CO(NH 2 ) 2
5-75
5-84
5-93
6-13
6.31
(CH 3 ) 2 CO.
5-75
5-84
5-93
6.12
6.29
C3H 7 OH,
5-75
5-8o
5-85
5-94
6.03
SOLUBILITY OF BORIC ACID IN AQUEOUS SOLUTIONS OF :
Acetic Acid at 26.
(Herz Z. anorg. Chem. 34, 205, '03.)
Acetone at 20.
(Herz and Knoch Ibid. 41, 319, '04.)
Normality of Solutions.
Gms. per TOO cc. Solution.
cc. Acetone
B(OH)s per 100 cc. Solutioi
CH 3 COOHT
B(OH) 3 .
CHsCOOH.
B(OH) 3 .
per 100 cc.
Solvent.
^lillimols.
Grams!
0-91
5- 6 4
O
79 -15
4.91
I
0.82
5
4-7
20
81.71
5-07
2
0.65
10
4.2
30
83-35
4
0-42
20
3-
40
82.72
5 - J 3
6
0.25
30
2.0
50
81.62
5.06
60
76.40
4-74
70
67.62
4.19
80
55-05
3-4i
IOO
8.06
0.50
SOLUBILITY OF BORIC ACID IN:
Pure Glycerine (Sp.Gr. =1.260
at 15.5).
(Hooper Pharm. J. Trans. [3] 13, 258, '82.)
Aq. Solutions of Glycerine
at 25.
(Herz and Knoch Z. anorg. Chem. 45, 268, '05.)
Gms. B2O 3
t o 3H 2 Oper
TOO CC.
Glycerine
- Gms. B(OH) 3 per 100
Gms.
Wt. % Millimols
Glycerine B(OH) 3 per
in Solvent. 100 cc. Sol.
Sp. Gr.
*:
Gms. B(OH) 3
per 100
Glycerine. Solution.
cc. Solution
Gms.So-
' lution.
O
20
I5-87
J 3
17
90.1
1.017
5
59
5-50
10
24
19.04
16
CO
7
*5
9O.I
1.038
5
59
5-38
20
28
22 .22
18
.21
20
44
90.6
1.063
5
.62
5.28
30
33
26.19
20
75
31
55
92.9
i .090
5
.76
5-29
40
38
30.16
23
i7
40
95
97-0
1.113
6
.02
5-41
50
44
34-92
25
95
48.7
103.0
i-i33
6
39
5- 6 4
60
50
39.68
28
.41
6 9
.2
I4O.2
1.187
8
.69
7-32
70
56
44-65
30
72
IOO
.0
390-3
1.272
24
.20
19.02
80
61
48.41
32
.61
90
67
53-18
34
.70
IOO
72
57-14
36
36
6; BORIC ACID
DISTRIBUTION OF BORIC ACID BETWEEN WATER AND AMYL ALCOHOL
AT 25.
(Fox Z. anorg. Chern. 35, 130, '03.)
Millimols B(OH) 3 in Cms. B(OH) 3 in 100 cc. Millimols B(OH) 3 in Gms. B(OH) 3 in TOO cc
Aq.
Alcoholic
Aq.
Alcoholic
Aq
Alcoholic
Aq.
Alcoholic
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
265.8
7 6
.6
1.648
O
475
8 7
9
33-2
545
O.2O6
196.5
59
5
I .219
3 6 9
75
.2
22.7
.466
O.I4I
159.6
47
5
0.990
o
.294
64
.6
19.76
.400
0.123
126.0
37
.1
0.781
O
230
BORIC ACID (Tetra) H 2 B 4 O 7 .
100 grains water dissolve 2.69 grams H 2 B 4 O 7 at 15, Sp. Gr. == 1.015.
(Gerkcb Z. anal. Chem. 28, 473, '89.)
BORON TRI-FLUORIDE BF 3 .
i cc. H 2 O absorbs 1.057 cc. BF 3 at o and 762 mm., i cc. cone.
H 2 SO 4 (Sp. Gr. 1.85) absorbs 50 cc. BF 3 .
BROMINE Br.
SOLUBILITY IN WATER.
(Winkler Chem. Ztg. 23, 687, '99; Roozeboom Rec. trav. chim. 3, 29, 59, 73, 84, '84; Dancer
J. Chem. Soc. 15, 477, '62; at 15, Dietze Pharm. Ztg. 43, 200, '98.)
Grams Bromine per 100 Grams.
** Water. Solution.
(W.) (R. D. & D.) (W.) (R. D. & D.)
4.17
4.22
3.98
4-05
5
10
2O
3-92
3-74
3-65
3-58
3-7
3-4
3-25
3.20
3-77
3.61
3-52
3 46
3-57
3-29
3.10
25
3 -48
3-17
3 ^6
3 -7
30
3-44
3 I 3
3-32
3-03
40
3-45
3-33
50
60
3-52
. . .
3-40
. . .
80
. . .
. . .
. . .
* "Solubility."*
a. q.
60.5 43-1
45.8 32.4
35.1 24.8
27.0 I9.O
21-3 14.8
17.0 II.;
13.8 9.4
9.4 6.2
6.5 4.0
4.9 2.8
3.0 I.I
* For " Absorption Coefficient " a and " Solubility " q. of Bromine Vapor in water, see Acetylene,
page 9.
BROMINE
68
SOLUBILITY OF BROMINE IN AQUEOUS SOLUTIONS OF POTASSIUM SUL-
PHATE, SODIUM SULPHATE, AND OF SODIUM NITRATE AT 25.
(Jakowkin Z. physik. Chem. 20, 38, '96.)
v t InK 2 SO 4
^"fution GmS ' ^ Liter '
In Na 2 SO 4
Gms. per Liter.
In NaNOa
Gms. per Liter.
\ 91.18
i 45-59
i 22.79
i n-39
A 5-69
Br.
25.14
29.44
31.46
32.70
Na 2 SO 4 .
63-55
15.88
7-94
3-97
Br. '
25.07
29.20
31-33
32-94
32.26
NaNO 3 .
85.09
42.54
21.27
10.63
5-3 1
Br.
28.80
31-35
32.62
33-33
33-74
SOLUBILITY OF BROMIN& IN NORMAL AQUEOUS SALT SOLUTIONS
AT 25.
(McLauchlan Z. physik. Chem. 44, 617, '03.)
Gms.
Normality
Gms.
Gms.
Normality
Gms.
Salt.
Salt per
of Dis-
Br. per
.Salt.
Salt per
of Dis-
Br. per
Liter.
solved Br.
Liter.
Liter.
solved Br.
Liter.
Water
O.O
0.424
33-95
NH 4 NO 3
80. II
0.688
55-15
Na 2 SO 4
63-55
0.286
23-9
NaCl
58-50
o .701
55-90
K 2 S0 4
91 .l8
0.310
24.8
KC1
74.60
0.718
57-40
(NH 4 ) 2 S0 4
70.04
0.971
77-7
NH 4 C1
53-5 2
1.028
82.2
NaNO 3
85.09
0-3495
28.0
CH 3 COONH 4
77.09
4-26
340.5
KNO 3
IOI.I9
0.362
28.95
H 2 S0 4 *
49-03
0.366
29.26
Wildeman.
SOLUBILITY OF BROMINE IN AQUEOUS POTASSIUM BROMIDE SOLUTIONS.
(Worley J. Chem. Soc. 87, 1107, '05; see also Wildeman
Z. physik. Chem. n, 421, '93.)
Gram Mols. KBr Gms. KBr
Br. per Liter Dissolved at 26.5.
Br. per Liter Dissolved at 18.5.
per Liter. per Liter.
G. Mols. Grams.
G. Mols. Grams.
o.oo o.oo
0.4282 34.23
0.4448 35.56
O.O2 2.l8
0-4671 37-35
0.4823 38.56
0.04 4.38
0.5101 40.79
0.5243 41.91
0-06 6.55
0.5530 44-21
0.5668 45.31
0.08 8.76
0.5920 47.33
0.6059 48.44
o.io 10.91
0.6488 51.87
0-6533 52.23
0.20 21.82
0.8591 68.69
0.8718 69.69
0.40 43-82
1.2704 101.60
I.3I24 104.90
0.60 65.46
1.6717 133-70
I.77I2 I4I.6o
0.80 87.64
2.1029 168.10
2.2354 178.70
0.90 98.19
2.3349 186.20
2.4851 198.70
ioo grams saturated
solution of Bromine in
Carbon Bisulphide con-
tain 45.4 grams Br at
" 95 39 grams at -
no. 5, and 36.9 grams
at - 116.
(Arctowski
Z. anorg. Chem. u, 274, *95-'o6.)
BROMINE
DISTRIBUTION OP BROMINE AT 25 BETWEEN WATER AND:
(Jakowkin Z. physik. Chem. 18, 588, '95.)
Carbon Bisulphide.
Bromoform.
Carbon Tetra Chloride.
Gms. Br.
per Liter of:
Gms. Br.
jxr Liter of:
Gms. Br.
per Liter of:
Aq. Layer.
CSa Layer.
Aq. Layer.
CHBr 3 Layer.
Aq. Layer.
CC1 4 Layer.
0-5
36
o-5
33
-5
IS
I
80
i
66
i
28
2
163
2
136
2
60
3
240
3
206
3
90
4
330
4
276
4
123
5
420
5
346
5
156
6
515
6
415
6
190
7
62O
...
8
2OO
10
340
12
430
14
520
BRUCINE C 21 H 20 (OCH 3 ) 2 N 2 2 . 4 H 2 0.
SOLUBILITY IN SEVERAL SOLVENTS AT i8-22.
(Muller Apoth. Ztg. 18, 232, '03.)
Solvent.
Water
Ether
Acetic Ether
Benzene
Gms. Brucine
per 100 Gms.
Solution.
0.0563
0-749
4-255
I. II
Solvent.
Gms. Brucine
per 100 Gms.
Solution.
Petroleum Ether 0.088
Carbon Tetra Chloride 0.078
Carbon Tetra Chloride* i .937
Glycerine 2 . 2
* Schindelmeiser Chem. Ztg. 25, 129, '01.
BUTANE C 4 H 10 .
SOLUBILITY IN WATER AT t. AND 760 MM.
Vois.
per ioo vols.
o 4 10 15 20
3 . 147 2.77
Iso BUTYL ACETATE, etc.
SOLUBILITY IN WATER.
(Traube Ber. 17, 2304, '84; at 20, Vaubel J. pr. Chem. 59, 30, '99.)
22
22
20
Compound.
Grams Com-
pound per 100
Grams HaO.
Iso Butyl Acelate 0.5
Iso Butyl Formate i . o
Normal Butyric Aldehyde 3.6
Iso Butyric Aldehyde 10.0
BUTYL ACETATE 70
SOLUBILITY OF BUTYL ACETATE AND OF BUTYL FORMATE IN MIXTURES
OF ALCOHOL AND WATER.
(Bancroft Calc. from Pfeiffer Phys. Rev. 3, 205, '95- '96.)
cc. HjjO added to cause separation of a
Alcohol second phase in mixtures of the given
in Mixture quantity of alcohol and 3 cc. portions of:
Butyl Formate.
Butyl Acetate.
3
3-45
2.08
6
8.83
6.08
9
14-75
10.46
12
21.45
15-37
15
29.65
20.42
i8
39-o
25.60
21
51 .8
31 .49
24
00
37-48
27
43-75
30
50-74
33
s
59-97
100 cc. H 2 O dissolve 0.7 cc. iso butyl acetate at 25 (Bancroft)
Iso BUTYRIC ACID (CH 3 ) 2 CH.COOH.
SOLUBILITY IN WATER.
(Rothmund Z. physik. Chem. 26, 475, '98.)
Synthetic Method used, see Note, p. 9.
Gms. Iso Butyric Acid per 100 Gms.
i .
Aq. Layer.
Iso Butyric Ac. Layer.
5
16.4
73-4
10
17.5
68.5
15
19.4
62.5
20
22.6
53-9
22
25.8
49.6
24-7
(crit. temp.)
36.3
CADMIUM BROMIDE CdBr,
SOLUBILITY IN WATER.
(Dietz Ber. 32, 95, '99; Z. anorg. Chem. 20, 260, '99; Wiss. Abh. p.t. Reichanstalt, 3, 433, 'oo; see alsf
Eder Dingier polyt. J. 221, 189, '76; Etard Ann. chim. phys. [7] 2, 536, '94.)
Gms. CdBr 2 Mols. CdBr 2 Gms. CdBr 2 Mols. CdBr 2
t. per 100 Gms. per 100 Solid Phase. t. per looGms. per 100 Solid Phase.
Solution. Mols. H 2 O. Solution. Mols. H2O.
o 37.92 4.04 CdBr 2 .4H 2 O 40 60.65 10.20 CdBr 2 .H 2 O
18 48.90 6.21 45 60.75 10.24
30 56.90 8.73 60 61.10 10.39
38 61.84 10.73 8o 62 - 2 9 10.48
35 60.29 10.05 CdBr 2 .H 2 O 100 61.63 IO - 6 3
Density of saturated solution at 18= 1.683.
7i CADMIUM BROMIDE
SOLUBILITY OF CADMIUM BROMIDE IN ALCOHOL, ETHER, AND
IN ACETONE.
ioo gms. sat. solution of CdBr 2 .4H 2 O in abs. alcohol contain 20.93
gms. CdBr 2 at 15 (Eder).
ioo gms. sat. solution of CdBr 2 .4H 2 O in abs. ether contain 0.4 gm.
CdBr 2 at 15 (Eder).
ioo gms. absolute acetone dissolve 1.559 S ms - CdBr 2 at 18.
(Naumann Ber.37, 4332, '04.)
CADMIUM (Mono) AMMONIUM BROMIDE CdBr 2 .NH 4 Br.
SOLUBILITY IN WATER.
(Rimbach Ber. 38, 1553, '05; Eder.)
A0 ioo Grams Solution contain Gms.
Atomic Relation . G. CdBra-NHJSr
Cd.
Br.
NH 4 .
Cd
: Br
: NH 4 '.
|Jti. n-nj VJrilia*
Solution.
1.0
16.33
34.87
2.6 3
I
3
I
53-82
14.8
17.40
37-15
2.80
I
3
I
58.01
52 -2
19.79
42.38
3-21
I
3
I
65-3I
IIO- 1
22 .99
49.17
3-72
I
3
I
75 -98
ioo gms. sat. solution of CdBr 2 .NH 4 Br in abs. alcohol contain 15.8
gms. double salt at 15 (Eder).
ioo gms. sat. solution of CdBr 2 .NH 4 Br in abs. ether contain 0.36
gm. double salt at 15 (Eder).
CADMIUM (Tetra) AMMONIUM BROMIDE CdBr 2 .4NH 4 Br.
SOLUBILITY IN WATER.
(Rimbach.)
The double salt is decomposed by water at temperatures below 160.
ii .
c
d.
i
r.
NH4. ' C
d : Br :
NH,. '
Cd
: E
r :
NH 4 .
0.8
H
.72
5
.46
6.67 :
4.82
2.82
I
10
.02
8.02
13.0
14
95
5 1
.48
6.85
4-85
2.85
I
II
57
9-57
44.0
15
.01
53
85
7-35
5-4
3-04
I
6
.84
4.84
76.4
14
.6
54
.28
7.80 .3
5-32
3-32
I
6
63
4-63
123-5
15
.5
59
5
8-45
5-38
3-38
I
7
40
5-40
160.0
14
7
62
67
9-43
5-99
3-99
I
6
03
4-03
CADMIUM (Mono) POTASSIUM BROMIDE CdBr 2 .KBr.H a O.
SOLUBILITY IN WATER.
(Rimbach; see also Eder.)
^ ioo Gms. Solution contain Gms.
Atomic
Relation in Sol.
Gms.CdBr 2 .KBr
Cd.
Br.
K.
Cd :
Br
: K".
per ioo Gms*
Solution.
0-4
I5-4I
33-o
5-42
I
3
I
53-63
15 .8
16.85
35-96
5-86
I
3
I
58.61
50.0
19.58
41.86
6-85
I
3
I
67.87
112.5
22.24
48.28
8.14
0.98
3
1.03
78.11
CADMIUM BROMIDE 72
CADMIUM Tetra POTASSIUM BROMIDE is decomposed by water at
ordinary temperatures.
CADMIUM (Mono) RHUBIDIUM BROMIDE CdBr 2 .RbBr.
SOLUBILITY IN WATER.
(Rimbach.)
ioo Cms.
Solution contain Gms.
Atomic Relation in Sol . Gms. CdBr 2 .RbBr
t.
per ioo Gms.
Cd.
Br.
Rb.
Cd :
Br
Rb.
Solution.
0.4
8-37
17-93
6-43
I
3
1. 01
32- 6 5
14.5
10.72
23.02
8.30
0.99
3
1. 01
41-87
49.2
15.01
3 2 -!3
11.51
I
3
I
S8-54
^7-5
19.65
41.12
14.06
I .02
3
0.96
75-77
CADMIUM (Tetra) RHUBIDIUM BROMIDE CdBr 2 .4RbBr.
SOLUBILITY IN WATER.
(Rimbach.)
ioo Gms. Solution contain Gms. Atomic Relation in Sol. Gms.CdBr 2 .4RbBr
I .
' Cd
Br
Rb. '
Cd :
Br
: Rb.
per ioo \jrrn
Solution.
o-5
5-70
24.94
17.97
0.98
6
4-05
47-95
13-5
6-55
28. 7 4
20.74
0-97
6
4-05
55-J7
Si'S
8-25
35-5 1
25-39
0.99
6
4-02
68.82
H4-5
9-5o
40.67
29.00
1. 00
6
4-0
79.04
CADMIUM (Mono) SODIUM BROMIDE CdBr 2 .NaBr 2 iH,O.
SOLUBILITY IN WATER, ETC., AT 15.
(Eder Ding, polyt. J. 221, i8g, '76.)
Gms. CdBr 2 .NaBr per ioo Gms. Solid
S lvCnt - 'Solution. ' Solvent.' Phase.
Water 49.0 96.1 CdBr 2 .NaBr.2iH 2 O
Absolute Alcohol 21.2 27.0
Absolute Ether 0.52 0.53 "
CADMIUM CHLORATE Cd(ClO 3 ) 2 .2H 2 O.
SOLUBILITY IN WATER.
(Meusser Ber. 35, 1422, '02.)
Gms. Mols. Gms. Mols.
t o Cd(C10a) 2 Cd(C10,) 2 solid Phase t Cd(ClO 3 ) 2 Cd(ClO 3 ) 2 Solid Phase.
1 per ioo Gms. per ioo Mols. aoua rnasc. * ' per looGms. per ioo
Solution. HzO. Solution. Mols. HzO.
-20 72.18 22.47 Cd(ClO 3 ) 2 .2H 2 O 18 76.36 27.98Cd(ClO 8 ) 2 .2H 2 O
-15 72-53 22.87 49 80.08 34.82
o 74.95 25.92 65 82.95 42.14
Density of the saturated solution at 18 = 2.284.
73
CADMIUM CHLORIDE
SOLUBILITY IN WATER.
(Dietz W. Abh. p. t. Reichanstalt 3, 433, 'oo; above 100, Etard Ann. chim.phys-t?] 2, 536, '04.)
G. CdCl 2 perMols.CdCl 2 Solid G.CdCUper
t . ioo Gms. oer ioo ^ " t . 100 Gms.
Mols.CdCl,
per ioo
Solution.
Mols.H 2 0.
Solution.
MSs.H.0.
- 9
43.58
7-5'
+ 10
57-47
13.3'
o
49-39
9.6
f~*Af~*] .TT f) 2O
57-35
13.2
+ 10
55-58
12.3
4O
57-51
13-3
15
59.12
I4-2J
60
57-7i
13-4
10
44-35
7-8
80
58.41
13-8
o
47-37
9.0
IOO
59-52
14-4.
+ 18
52-53
10.9
CdCl 2 . 2 JH 2 O 150
64.8
30
56.91
12.8
(monoclinic) 2OO
72.0
36
57-91
J 3-5.
270
77-7
T>UOC
Phaae '
Density of saturated solution at 18= 1.741.
100 gms. abs. ethyl alcohol dissolve 1.52 gms. CdCl 2 at 15. 5.
100 gms. abs. methyl alcohol dissolve 1.71 gms. CdCl 2 at 15. 5.
(de Bruyn Z. physik. Chem. 10, 783, 'pa.)
CADMIUM AMMONIUM CHLORIDE CdCl 2 .NH 4 Cl.
SOLUBILITY IN WATER.
(Rimbach Ber. 30, 3075, 1897.)
IOQ Gms. Solution contain Gms. Gms.
per 100 Gms.
I .
Cd.
Cl.
Nrt .
Solution.
Water. '
2.4
14.26
13-44
2.24
29.94
42.74
16.0
15.82
15-07
2-56
33-45
50.26
41.2
18.61
17.46
2.89
38.96
63-83
63.8
20.92
19-73
3-34
43-99
78.54
105.9
24.70
23-5 2
4-oi
52-23
109-33
CADMIUM (Tetra) AMMONIUM CHLORIDE CdCl 2 .4NH 4 Cl.
IN CONTACT WITH WATER.
The salt is decomposed in aqueous solution.
(Rimbach.)
. ioo Gms. Solution contain Gms. Atomic Relation in Solution.
*
Cd.
Cl.
NH 4 .
3-9
5-75
18.17
7-37
16.1
6.96
20.26
7 97
40.2
9.91
23.84
8.92
58-5
12.50
26-53
9-35
112.9
16.66
31-79
10.78
ii3-9
16.51
32-71
11.30
Cd
Cl
9.96
9-2O
7 .6i
6. 7 i
6. 02
6.26
NH*.
7.96
7-13
5-61
4-66
4.02
4.26
SOLUBILITY OF MIXTURES OF CADMIUM TETRA AMMONIUM CHLORIDE
AND CADMIUM AMMONIUM CHLORIDE IN WATER.
(Rimbach Ber. 35, 1300, '02.)
t
ioo Gms.
Solution contain Gms.
Atomic Relation.
Solid Phase,
Mol. per cent of:
Cd.
Cl.
NH4.
Cd
: Cl :
NH*.
CdCla.
CdCla.
4NH4C
I
.1
5
34
17
.62
7.27
i
10-47
8.50
49-6
50-4
M
7
.12
19
.86
7-84
i
8.84
6.87
47-o
53-o
40
7
10
.24
23
.82
8.85
i
7-37
5-37
77.0
23 o
53
5
12
50
26
53
9-35
i
6. 7 I
4.66
CADMIUM CHLORIDE
74
SOLUBILITY OF MIXTURES OP CADMIUM TETRA AMMONIUM CHLORIDE
AND AMMONIUM CHLORIDE IN WATER.
(Rimbach.)
ioo Gms. Solution
t*^ contain Gms.
Atomic
Relation
Solid Phase,
Mol. per cent of:
Cd. Cl.
NH.
Cd
: Cl :
NH 4 .
' NH 4 C1. CdCl 2 . 4 NH 4 d.
1.0
2.82
17
.11
7
.82
I
19.21
17.28
59-o
4i
.0
!3-2
2. 7 6
18
.84
8
7 1
I
21 .62
19.62
74-o
26
.0
40.1
3-16
22
56
10
49
I
22 .65
20.74
71.0
29
.0
58-2
3-51
25
.21
II
.72
I
22.79
20.89
69.0
3i
.0
OADMIUM BARIUM CHLORIDE 2(CdCl 2 ).BaCl 2 .5H 2 O.
SOLUBILITY IN WATER.
(Rimbach Ber. 30, 3083, '97.)
t.
22.6
41-3
53-9
62.2
69-5
107.2
CADMIUM
t 8 .
22.5
3 2 -9
41.4
53-4
62.0
97.8
108.3
109.2
100 Gms. Solution
contain Gms.
Gms. 2(CdCl 2 ).BaCl 2
per 100 Gms.
'Cd. Cl. Ba. Solution. Water.
17.71 16.89 ii -o 45-6o 83.82
19.22 18.15 n-77 49 I 4 96.62
19.85 18.75 12.41 51-04 104.25
20.59 19.66 12.83 53- 08 II 3- I 3
21.20 20.18 13-09 54-47 119-64
24.25 23.23 14.90 62.38 165.85
BARIUM CHLORIDE CdCl 2 .BaCl 2 .4H 2 O.
SOLUBILITY IN WATER.
(Rimbach.)
100 Gms. Solution Gms. CdCl 2 .BaClj
contain Gms. per 100 Gms.
Cd. Cl. Ba.
11.98 15-19 I 4-7 I
12.40 16.18 16.09
13.05 16-95 16.81
13.96 18.21 18.13
14.73 l8 -8i l8 -74
17.57 22.48 22.00
18-53 23.51 22 -79
18.67 23.69 29.95
Solution. Water.
41.88 72.06
44.67 80.73
46.81 88.01
50.30 IOI-2I
52.28 109.56
62.05 163.^0
64.83 184.33
65.31 188.27
OADMIUM MAGNESIUM CHLORIDE 2 (CdCl 2 )MgCl 2 .i2H 2 O.
SOLUBILITY IN WATER.
(Rimbach.)
ioo Gms. Solution
Gms. 2(CdCl 2 ).MeCl 2
contain Gms.
per ioo Gms.
Cd.
Cl.
Mg.
Solution.
Water.
2-4
22.14
21 .06
2.41
45.61
83-86
20.8
24.30
22.80
2-55
49.69
98. 77
45-5
26.24
24-55
2.72
53-5 1
115 .IO
67.2
28.45
26.71
2.98
58-14
I38.QO
121. 8
31-84
30-20
3-44
65.48
189.69
75
CADMIUM CHLORIDE
CADMIUM (Mono) RHUBIDIUM CHLORIDE CdCl 2 .RbCl.
SOLUBILITY OF CADMIUM MONO RHUBIDIUM CHLORIDE IN WATER.
(Rimbach Ber. 35, 1303, '02.)
100 Gms. Solution ontain Gms.
Gms. CdCl 2 .RbCl per 100 Gms.
I .
Cd.
Cl.
Rb.
Solution.
Water.
I .2
4.80
4-53
3.63
12-97
14.90
14-5
6. 20
5-88
4-75
16.80
20.19
41.4
9-34
8.86
7.14
25 -3 1
33 -89
57-6
11.40
10.78
8.63
30-83
44-58
103.9
17.14
16.37
13.39
46.62
87.36
CADMIUM (Tetra) RHUBIDIUM CHLORIDE CdCl 2 . 4 RbCl.
IN CONTACT WITH WATER.
(Rimbach.)
The double salt decomposes to CdCl 2 .RbCl and RbCl.
t .
ioo Gms. Solution contain
Gms.
Atomic Relation.
Solid Phase,
Mol. per cent of:
Cd.
Cl.
Rb.
Cd
: Cl
: Rb.
CdClo.
RbCl.
CdCl 2 . "
4 RbCl.
0.7
O
65
6-52
14
73
I
31.88
2 9
.88
30
70
8.8
I
07
7-37
16
I
21.89
19
.89
24
7 6
13.8
I
32
7.86
16
93
I
18.88
16
83
16
84
42-4
3
.21
ii .35
22
45
I
II .21
9
.21
14
86
59 o
4
.6l
13 .41
25
I
9-23
7
23
33
67
108.4
8
94
l8 -57
3 1
15
I
6-57
4
59
SOLUBILITY OF MIXTURES OF CdCl 2 .4RbCl AND RbCl IN WATER.
(Rimbach.)
Solid Phase,
Mol. per cent of:
ioo Gms. Solution contain Gms.
Atomic Relation.
Cd.
0.4
14.8
17.9
Cl.
12.86
13 .62
14.0
Rb.
30-97
32.81
33-71
Cd
Cl : Rb.
I I
I I
I I
CdCl 2 . 4 RbCl RbCl.
55 45
67 33
80 20
THE EFFECT OF THE PRESENCE OF HC1, CaCl 2 AND OF LiCl UPON
THE DECOMPOSITION OF CADMIUM TETRA RHUBIDIUM
CHLORIDE BY WATER AT 16.
(Rimbach Ber. 38, 1570, '05.)
ioo Gms. Solution contain Gms. Mols ^ J00 Mf)ls HzO Molecular Ratio>
Total Cl.
Cl.
HCl.
c
d.
N
Rb.
C.
:dci 2 .
t
.bCl.
HCl. CdC
:i 2 : Rbci:
36-44
0.84
36.61
41
i-39
.109
483
29.76 1
[ 4-43
28.45
0.80
28.44
35
1-38
o
.082
.422
20-35
5-J5
12 .09
3-24
9.11
o
69
6.74
o
139
X
772
5.60
J2-75
Ca.
CaCl 2 .
CaCl 2 .
14-98
7-56
20.91
73
2.80
o
159
o
799
4-59
5-04
12.70
5-77
15.96
77
4.87
o
163
I
353
3-4i
8.31
10-85
3-78
14.47
l'
oo
8.51
o
.211
2
365
2.24
II .22
9-o8
1.84
5-10
I
24
12 .14
o
.262
3
385
i -09
12.92
Li.
Lid.
Lid.
26.49
4.8 7
29-40
56
3-87I
J 39
i
.271
19.40
t 9 13
20-37
3-33
2O- 1 1
o
52
7.84
.122
2
433
12-54
[ 19.88
See Note on next page.
CADMIUM CHLORIDE 76
CADMIUM (Mono) POTASSIUM CHLORIDE CdCl 2 .KCl.H a O.
SOLUBILITY IN WATER.
(Rimbach Ber. 30, 3079, '97; see also Croft Phil. Mag. [3] 21, 356, '42.)
100 Gms. Solution Gms. CdCb-KCl
t. contain Gms. per ipo Gms.
Cd. CT R. Solution. Water.
2.6 9.53 9.03 3.31 21.87 2 7-99
15.9 11.63 10.98 3.99 26.60 36.24
41-5 15-47 14-73 5-45 35 - 66 55-34
60.6 17.68 16.80 6.20 40.67 68.55
105.1 22.46 21.34 7.87 5*-67 106.91
CADMIUM (Tetra) POTASSIUM CHLORIDE CdCl 2 . 4 KCl.
IN CONTACT WITH WATER.
(Rimbach.)
The double salt is decomposed when dissolved in water at ordinary
temperature.
zoo Grams Solution contain Gms.
l> .
Cd.
Cl.
K.
4
3- 6 4
9.84
8-31
23.6
5.66
14.02
11.52
50.2
9.10
18.09
13.60
108.9
11.94
23 .11
17.16
NOTE. The effect of the presence of certain chlorides upon the
decomposition of cadmium tetra potassium chloride by water at 16
was investigated by Rimbach in a manner similar to that used in the
case of cadmium tetra rhubidium chloride (see preceding page). The
results, which show the extent to which increasing amounts of the
several chlorides force back the decomposition of the double salt, were
plotted on cross-section paper, and the points at which the decom-
position was prevented, were determined by interpolation. These
values which show the minimum amount of the added chlorides which
must be present to insure the crystallization of the pure double salt are
shown in the following table.
/\aaea
Chloride.
CdCl 2 .
KCl.
Added!
Chloride.
jLeusuy 01
Solutions.
CdCl 2 .
KCl.
Added
Chloride.
HC1
0.074
.296
19
.80
I
.1403
0-033
o
.132
8.828
LiCl
0-344
I
376
9
30
I
.1380
0.166
.663
4.483
CaCl,
0-544
2
.176
3
.80
I
2333
0-270
I
.808
1.887
KCl
1.034
6
514*
2
-378
I
.214
0-507
3
.195*
I .167
* Total.
CADMIUM CYANIDE Cd(CN) 2 .
100 gms. H 2 O dissolve 1.7 gms. Cd(CN) 2 at 15.
(Joannis Ann. chim. phys. [5] 26, 489, '82.)
77
CADMIUM FLUORIDE
CADMIUM FLUORIDE CdF 2 .
SOLUBILITY IN WATER.
100 cc. saturated aqueous solution contain 4.36 gms. CdF 2 at 25.
(Jager Z. anorg. Chem. 27, 34, '01.)
CADMIUM HYDROXIDE Cd(OH) 2 .
SOLUBILITY IN WATER.
i liter of aqueous solution contains 0.0026 gm. Cd(OH) 2 at 25.
(Bodlander Z. physik. Chem. 27, 66, '98.)
CADMIUM IODIDE CdI 2 .
SOLUBILITY IN WATER.
(Dietz W. Abh. p. t. Reichanstalt 3, 433, 'oo; see also Kremers Pogg. Ann. 103, 57, '58; Eder
Dingl. polyt. J. 221, 189, '76; Etard Ann. chim. phys. [7] 2, 536, '94.)
A0 Gms. CdI 2 per ioo Gms.
Mols. CdI 2
Gms. CdI 2 r^er ioo Gms.
Mols. CdI 2
Solution.
Water.
MoTs.'SzO.
Solution.
Water.
Mob 1 U^O.
O
44-4
79.8
3-9
30
47-3
89.7
4-43
10
45-4
83.2
4-1
40
48-4
93-8
4.6
15
45-8
84.5
4.17
50
49-35
97-4
4.8
18
46.02
85.2
4.2
75
52.65
III .2
5-4
20
46-3
86.2
4.26
IOO
56.08
127.6
6-3
25
46.8
87.9
4-34
Density of saturated solution at 18 = 1.590.
SOLUBILITY OF CADMIUM IODIDE IN ORGANIC SOLVENTS.
Observer.
(Eder.)
(Timofeiew Compt. rend. 112, 1224, '91.)
(Timofeiew Compt. rend. 112, 1224, '91.)
(Timofeiew Compt. rend. 112, 1224, '91.)
(Eder.)
(Naumann Ber.37, 4332, '04.)
Solvent.
t.
Gms. CdI 2 per
ioo Gms.
Solution.
Solvent.
Absolute Alcohol
15
50
5
102
o
Ethyl Alcohol
20
42
.6
74
.27
Methyl Alcohol
20
59
.0
J 43
7
Propyl Alcohol
20
28
9
40
.67
Absolute Ether
15
21
7
27
7
Absolute Acetone
18
20
25
.0
CADMIUM AMMONIUM IODIDES (Mono and Di) .
SOLUBILITY IN WATER, ETC.
(Rimbach Ber. 38. 155?. 'os; at 15 Eder Dingl. polyt. J. 221, 189, '76.)
Cd. Mono
Ammonium Iodide.
Solvent.
Water
Abs. Alcohol
Abs. Ether
Gms. CdI 2 .NH4l per
t > ioo Gms.
15
15
15
Solution.
52.6
53
29.4
Solvent.
Ill .O
"3
41.7
Cd. Di
Ammonium Iodide.
14.5
15
Gms. CdI 2 .2NHJ per
ioo Gms.
Solution.
59
10
Solvent.
611.6
ii
CADMIUM IODIDES 78
CADMIUM POTASSIUM IODIDES, Mono
Di= CdI 2 .2KI. 2 H 2 O.
CdI 2 .KI.H 2 O,
CADMIUM Di SODIUM IODIDE Cdl2.2NaI.6H 2 O.
SOLUBILITY IN WATER, ETC., AT 15.
(Eder.)
Gms. CdI 2 .KI
Gms. CdI 2 . 2 KI
Gms. CdI 2 .2NaI
Solvent. ^ per IPO Gms.
per 100 Gms.
per 100 Gms.
Solution.
Solvent.
Solution.
Solvent.
Solution.
Solvent.
Water 51.5
106
57-8
137
61-3
158.8
Abs. Alcohol
. . .
41.7
71
53-7
116.2
Abs. Ether
39
4.1
9.0
99
CADMIUM NITRATE Cd(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt 3 440, 'oo.)
Mols. Cd(NO 3 ) 2 Solid
per 100 Mols. H 2 O. Phase.
4.55 Cd(N0 3 ) 2 . 9 H 2
6.85
8.50
8.37 Cd(N0 3 ) 2 . 4 H 2
9.61
10.7
12. 1
25.0
Density of saturated solution at 18 = 1.776.
Gms. Cd(NO 3 ) 2
t o. per loo^Gms.
-13
I
Solution.
37-37
47-33
Water.
89.86
+ I
52-73
in. 5
+ 18
52-37
55-9
109.7
126.8
30
40
59-5
61 .42
76.54
140.4
159.2
326.3
CADMIUM OXALATE CdC 2 O 4 . 3 H 2 O.
i liter of sat. aqueous solution contains 0.033 g m - CdC 2 O 4 at 18.
(Kohlrausch Z. physik. Chem. 44, 197, '03.)
CADMIUM SULPHATE CdSO 4 .
SOLUBILITY IN WATER.
(Mylius and Funk W. Abh. p. t. Reichanstalt 3, 444, 'oo; see also Kohnstamm and Cohn Wied
Ann. 65, 344, '98; Steinwehr Ann. der Phys. (Drude) [4] 9. 1050, '02; Etard Ann. chim. phys
[?] 3 536, '94-)
Solid
Phase.
Gms. CdS0 4
t . per TOO Gms.
Solution.
Water.
-17
44-5
80.2
-10
4 6.1
85-5
5
48.5
94.2
18
43-35
76.52
10
43-27
76.28
o
43 - OI
76.48
+ 10
43-18
76.00
20
43-37
76.60
CdSO 4 .7H 2 O
CdSO 4 .|H 2 O
Gms. CdSO 4
t. per TOO Gms.
Solid
Solution.
Water.
ase.
40
43-99
78.54
CdSO 4 .fH 2 O.
60
44-99
83.68
"
73-5
46.6
87.28
M
74-5
46.7
87.62
CdSO 4 .H 2 O
77
42.2
73.02
a
85
39-6
"
90
38.7
63.13
tt
100
37-8
60.77
tt
79 CADMIUM SULPHATE
SOLUBILITY OF CADMIUM SULPHATE IN AQUEOUS SOLUTIONS OF SUL-
PHURIC ACID AT o.
(Engel Compt. rend. 104, 507, '87.)
Equivalents per 10 Gms. H2O. Density Grams per 100 Grams H 2 O.
HaS0 4 . CdS0 4 . of Solutions. H 2 SO 4 . CdSCv "
o. 71.6 1.609 - 74 -61
3.87 70.9 1.591 1.90 73.87
12.6 62.4 I -545 6.18 65.03
28.1 50.6 1.476 13.78 52.73
43.3 40.8 1.435 21.23 42-52
47.6 37.0 1.421 23.34 38.56
53.8 32.7 1.407 26.38 34.07
71.5 23.0 1.379 35.06 23.96
SOLUBILITY OF MIXED CRYSTALS OF CADMIUM SULPHATE AND FERROUS
SULPHATE IN WATER AT 25.
(Stortenbecker Z. physik. Chem. 34, 109, 'oo.)
i^om position 01 ooiunoii. _ . . .
^ ^ JL Mnl n*r rent PH in
Gms. per
too Gms. H 2 O.
Mols. per 100
Mols. H 2 0.
Mol. % Cd.
in Sol.
Crystals of
Solid Phase.
CdSO 4 .
FeSO 4 .
' Cd.
Fe. '
Crystals with 2 Mols. H 2 O.
76.02
o.o
6-57
o.o
100
100
57-61
10.63
4.98
1.26
79-8
99 .0
Crystals with 7
Mols. H 2 0.
57-61
10.63
4.98
1.26
79-8
3 6.6
78-5
34-6
. . .
. . .
. . .
. . .
44.6
n. i
. . .
. . .
. . .
. . .
24.4
4-8
o.o
26.60
o.o
3 -165
o.o
o.o
CADMIUM POTASSIUM SULPHATE CdK 2 (SO 4 ) 2 .
SOLUBILITY IN WATER.
(Wyrouboff Bull. soc. chim. [3] 25, 121, f oi.)
,o G. CdK t (SO 4 ) 2 per Solid
100 Gms. H 2 O. Phase.
t o G. CdK 2 (SO 4 ) 2 Solid
' per 100 Gms. H^. Phase.
16
42.89
CdK 2 (S0 4 ) 2 . 2 H 2
26
42.50
CdK 2 (S0 4 ) 2 .iiH 2
3i
46.82
u
3 1
42.80
40
47-40
u
40
43-45
a
6 4
44.90
u
CADMIUM SODIUM
SULPHATE
80
CADMIUM SODIUM SULPHATE CdNa 2 (SO 4 ) 2 . 2 H 3 O.
SOLUBILITY IN WATER, ALSO WITH THE ADDITION OF CADMIUM SUL-
PHATE AND OF SODIUM SULPHATE.
(Koppel, Gumpery Z. physik. Chem. 52, 413, '05.)
Gms. per 100 Gms.
t. Solution.
Gms. per 100 Gms.
H 2 O.
Mols. per 100 Mols.
H ?- Solid Phase.
CdSO 4 .
Na 2 S0 4 .
CdSO 4 .
Na 2 S0 4 .
CdSO 4 .
Na 2 S0 4 .
24
22
25
15
.07
35
49
24
.04
3
.07
3-05)
30
22
55
15
.29
36
.28
24
.60
3
.14
3.12 VCdNa 2 (S0 4 ) 2 . 2 H 2 O
40
22
.89
15
65
37
.24
25
45
3
.22
3-28J
40
32
4
85
73
54
8
85
6
36
10
39
.91
5
.24
72
77
9
55
6
30
.2i)cdNa 2 (S0 4 ) 2 . 2 H 2
20
40
.26
5
.16
73
81
9
45
6
39
.20 1 +CdSO 4 -fH 2 O
40
39
.89
7
.18
75
38
13
56
6
52
7*1
14.8 40
.18
4
.60
72
68
8
32
6
.29
/
' s i
o
10
20
37
32
22
3o
53
.69
6
8
14
53
.69
66
55
32
34
ii
14
23
.62
.78
52
5
4
3
74
79
.14
\'V 1 CdNa 2 (S0 4 ) 2 . 2 H 2
lyi + Na 2 S0 4 .ioH 2
25
16
33
19
.82
25
60
.06
2
.21
3-94'
30
9
.21
27
.80
14
62
44
.14
I
.26
4 59 1 /""fl^ji fQO ^ oTT (~l
35
40
8
9
.26
.98
29
28
35
.27
16
26
24
47
46
.06
.27
I
I
.41
If 6 j +*W
CAESIUM ALUMS
SOLUBILITY OF CAESIUM CHROMIUM ALUM, CAESIUM IRON ALUM,
CAESIUM INDIUM ALUM, AND OF CAESIUM VANADIUM ALUM IN
WATER.
(Locke Am. Ch. J. 27, 174. *oi.)
Formula of Alum.
Cs 2 Cr 2 (S0 4 ) 4 . 24 H 2
C S- Fe 2 (S0 4 ) 4 . 24 H 2
Cs 2 In 2 (S0 4 ) 4 . 24 H 2
Cs 2 V 2 (S0 4 ) 2 .2 4 H 2
25
30
35
40
25
35
40
25
2 5
Gms. per 100 cc. H^.
Anhydrous
Salt.
Hydrated"
Salt.
o-57
0.96
i .206
o 94
!-52
1.91
i .53
2-43
1.71
2.72
2.52
3-75
6.04
4-oi
6.01
9.80
7-57
ii .73
0.771
1 -3 1
Gram Mols. Salt per
zoo cc. H^.
O.OOI5I
0.0025
0.0032
0.00405
0.0045
O.OO66
O-OO99
0.0156
0.0172
O.OO2O4
8 1 CAESIUM CHLORAURATE
OAESIUM CHLORAURATE CsAuCl 4 .
SOLUBILITY IN WATER.
(Rosenbladt Her. 19, 2537, '86.)
...
Gms. CsAuC^
per 100 Gms.
Solution.
Gms. CsAuCU
t. per TOO Gms. t.
Solution.
Gms. CsAuOt
per 100 Gms.
Solution.
10
o-5
40
3-2
80
16.3
20
0.8
SO
5-4
00
21.7
30
1.7
60
8.2
100
27-5
70
12.0
OAESIUM FLUOBORIDE CsBFl 4 .
100 grams water dissolve 0.92 gram CsBFl 4 at 20, and 0.04 gram
at 100. (Godeffroy Ber. 0, 1367, '76.)
CAESIUM MERCURIC BROMIDE CsBr. 2 HgBr 2 .
100 grams saturated aqueous solution contain 0.807 gram CsBr.
2HgBr 2 at l6. (Wells Am. J. Sci. [3} 44. 221, '92.)
CAESIUM CARBONATE Cs 2 CO 3 .
100 grams absolute alcohol dissolve u.i grams Cs 2 CO*at 19, and
20.1 grams at b. pt. (Bunsen.)
OAESIUM CHLORIDE CsCl.
SOLUBILITY IN WATER.
(Berkeley Trans. Roy. Soc. (Lond.) 203 A, 208, '04; see also Hinrichsen and Sachsel Z. physik.
Chem. 50, 99, '04- '05; at 25, Foote.)
G. CsCl per IPO Gms. G.Mol.CsCl t o G. CsCl per 100 Gms. G. Mol. CsCl
Solution,
Water.
per Liter.
Solution
. Water.
per Liter.
O
61
7
161
4
6
74
60
69.7
229
7
8.28
IO
63
.6
174
7
7
.11
70
70.6
239
5
8.46
20
65
.1
186
5
7
38
80
71.4
250
o
8.64
3
66
4
I 97
3
7
63
90
72.2
260
.1
8.80
40
67
5
208
.0
7
.86
100
73-o
270
5
8.96
50
68
.6
218
5
8
.07
119.4
74-4
200
o
9-22
SOLUBILITY OF MIXTURES OF CAESIUM CHLORIDE AND MERCURIC
CHLORIDE IN WATER AT 25.
(Foote Am. Ch. J. 30, 340, '03.)
Gms. per 100 Gms. Gms. per 100 Gms.
Solution. Solid Phase. Solution. 5^4 p^^.
CsCl^ HgCl 2 . CsCl 2 . HgCl 2 .
65.61 o.o CsCl 38.63 1.32 )
65.78 0.215 CsCl + Cs,HgCl B 17.03 0. 5 i ( gBWkSjg^OCi
62.36 0.32 ) Double Salt 1-53 0.42 )
57.01 0.64 > CssHgCl 6 0.6i 2.64 CsHg +CsHg,Cl s
52.35 1.23 ) -65-1% CsCl . 49 2<9I 1 DoubleSalt
51.08 1.44 Cs s HgCl 5 + CsjHgCl* 0.40 3.78 J CsHgjCls = 23.7% CsCl
49.30 1.49 I DoubleSalt 0.44 4.63 CsHg,Cl 6 + CsHgsClu
45.95 !- 6 9 ) Cs H gCU = 55.4%CsCl 0.41 4-68 ) DoubleSalt
45-23 1-73 Cs,HgCU + CsHgCl, 0.25 5.65 J CsHfoCU^n.^CBCl
. 1 8 7.09 CsHg B Cl u + HgCl,
o.o 6.90 HgCl,
CAESIUM CHLORTELLURATE 82
CAESIUM CHLORTELLURATE CsTeCl 6 .
SOLUBILITY IN AQUEOUS HYDROCHLORIC ACID.
(Wheeler Am. J. Sci. [3] 45. 267, '93-)
ioo parts HC1 (Sp. Gr. 1.2) dissolve 0.05 part CsTeCl 6 at 22.
100 parts HC1 (Sp. Gr. 1.05) dissolve 0.78 part CsTeCl 6 at 22.
CAESIUM THALLIC CHLORIDE 3 CsCl.TlCl 3 .2H 2 O.
ioo parts H 2 O dissolve 2.76 parts 3CsCl.TlCl 3 .2H 2 O at 17, and 33.3
parts at I00.
(Godeffroy Z. Osterr. Apoth. Ver. No. 9, 1886).
CAESIUM IODATE CsIO 3 .
ioo parts H 2 O dissolve 2.6 parts CsIO 3 at 24, and 2.5 parts 2CsIO 3 .
I 2 O fi at 21
(Wheeler Am. J. Sci. [3] 44, 123, '92.)
CAESIUM IODIDE Csl.
SOLUBILITY OF MIXTURES OF CAESIUM IODIDE AND IODINE IN WATER.
(Foote Am. Ch. J. 29, 210, '03.)
t.
-4
-4
-4
0.2
Gms. per ioo Gms.
Solution.
35-6
35-6
35-6
35-6
Gms. per ioo Gms.
Solution.
Solid Phase at
Csl
Csl and CsI 3
CsI 3 and CsI 5
CsI 5 and I
Csl. I.
27.68 o.o
27.52 0.09
3.18 0.31
0.85 0-34
Csl. I.
51.48 o.o
51.66 0.71
10.72 1.78
3.74 I. 60
t .
52-
S 2 -
52-
52-
73
73
73
Gms. per ioo
Solution.
Gms.
2
2
2
2
Csl.
16.75
6.69
6.72
6.65
26.98
16.66
6.27
4
3
3
3
15
10
' 4
I.
36
32
45
.07
50
.08
In Separated Heavy Solution
Gms. per ioo Gms. Solution. ^?
Csl.
I.
. . .
CsI 3 and CsI 5
. . .
CsI 5 and I
22.94
73-72
CsI 5
22.80
74-63
I
CsI 3 and CsI B
27.56
68.40
Csl.
17.68
80.02
I
CAESIUM (Tri) IODIDE CsI 3 .
ioo cc. saturated aqueous caesium iodide (about 17 per cent Csl)
solution contain 0.97 gram CsI 3 at 20, density of solution = 1.154.
(Wells Am. J. Sci. [3] 44, 221, '92.)
CAESIUM NITRATE CsNO 3 .
SOLUBILITY IN WATER.
(Berkeley Trans. Roy. Soc. (Lond.) 203 A, 213, '04.)
Gms. CsNOs per
t. ioo Gms.
G. Mols.
CsN0 3 t .
per Liter.
Gms. CsNOs per
ioo Gms.
G. Mols CsNOt
per Liter.
Solution.
Water.
Solution.
Water".
8-54
9
33
,476
60
45
.6
83
.8
3-41
10
12.97
14
9
O
725
70
5 1
7
107
O
4-10
20
18.7
2 3
.0
I
.11
80
57
3
134
.0
4-8l
30
25-3
33
9
j
58
90
62
.0
I6 3
.0
5-50
40
32.1
47
.2
2
.12
IOO
66
3
197
.0
6.19
50
39-2
64
4
2
73
106.2
68
.8
220
3
6.58
CAESIUM OXALATE
CAESIUM OXALATE Cs 2 C 2 O 4 .H 3 O.
SOLUBILITY OF MIXTURES OP CAESIUM OXALATE AND OXALIC ACID IN
WATER AT 25.
(Foote and Andrew Am. Ch. J. 34 156, '05.)
Varying amounts of the two substances were dissolved in hot watei
and the solutions allowed to cool in a thermostadt held at 25.
Solid
Phase.
H 2 C 2 4 .2H 2 0+H 3 Cs(C 2 4 ) 2 . 2 H 2
Double Salt.
H 3 Cs(C 2 4 ) 2 .2H,0
H 3 Cs(C 2 4 ) 2 2H 2 + H 4 Cs 2 (C 2 4 ) 3
Double Salt.
H 4 Cs 2 (C 2 4 ) 3
H 4 Cs 2 (C 2 4 ) 3 +HCsC 2 4
Double Salt.
HCsC 2 O 4
HCsC 2 4 +H 6 Cs 8 (C 2 4 ) 7
Double Salt.
H 6 Cs 8 (C 2 4 ) 7
H 6 Cs 8 (C 2 4 ) 7 +Cs 2 C 2 4 .H 2
Cs 2 C 2 O 4 .H 2 O
Gms. per 100 G. Mols. per 100
Gms. Solution. G. Mols. H 2 O.
Hi
Cs 2
Cs6 4 . H 2 C 2 4 .
Cs^zO*.
10
.20
.
2.274
10
.29
O
.61 2.314
O
035
7
.90
9
.92
924
O
614 {
4
.11
2 5
.12 ]
.162
I
81 J
4
32
27
55
.279
2
06
4
27
28
30
.267
2
14 I
4
40
35
.90
.476
3
07 J
4
-82
40
.10
752
3
.71
4
45
42
32
.672
4
05 )
3
05
48
.80 1.268
5
16 [
i
.04
68
.69 0.688
ii
56 )
o
.91
71
.24 o . 648
13
06
77
73
45 0.598
14
5 1 I
75
74
.04 0.596
14
.96 J
74
75
.20 0.625
15-93
.0
75
.82 o.o
IS
97
CAESIUM PERMANGANATE CsMnO 4 .
100 cc. sat. aqueous solution contain 0.097 gm. CsMnO 4 at i, 0.23
gm. at 19, and 1.25 gms. at 59. (Patterson J. Am. Chem. Soc. 28, 1735, '6.)
CAESIUM SELENATE Cs 2 SeO 4 .
100 grams H 2 O dissolve 245 grams Cs 2 SeO 4 at 12.
(Tutton J. Chem. Soc. 7L 850, '97 )
CAESIUM SULPHATE Cs 2 SO 4 .
SOLUBILITY IN WATER.
(Berkeley Trans. Roy. Soc. (Lond.) 203 A, 210, '04.)
Gms. Cs 2 SO 4 per
G. Mols.
Gms. Cs 2 SO 4 per
G. Mols.
J. too^Gms.
Cs 2 S0 4 t.
100 Gms.
C S2 S0 4
Solution.
Water.
per
Liter.
Solution.
Water.
per Liter.
62.6
I6 7
.1
3
.42
60
66
7
199
9
3-78
10
63-4
173
.1
3
.49
70
67
.2
205
O
3-83
20
64.1
I 7 8
7
3
56
80
67
.8
2IO
3
3-88
30
64.8
184
.1
3
.62
00
68
3
214
9
3-92
40
65-5
189
9
3
.68
100
68
.8
220
3
3-97
5
66.1
194
9
3
73
108.6
69
.2
224
5
4.00
CAESIUM DOUBLE 84
SULPHATES
SOLUBILITY OF CAESIUM DOUBLE SULPHATES IN WATER AT 25.
(Locke Am. Ch. J. 27. 459, 'ox.)
Cms. Anhydrous Salt G m. Mols.
Name. Formula. per 100 Gms. Salt per 100
Solution. Water. Gms. H 2 O.
Caesium Cadmium Sulphate Cs 2 cd(sO4) 2 .6H 2 o 58.16 139.9 0.2455
Caesium Cobalt Sulphate CszCoCso^-eHzO 29.52 41.9 0.081
Caesium Copper Sulphate Cs,Cu(so 4 ) 2 .6H 2 o 31-49 46.0 0.0882
Caesium Iron Sulphate Cs 2 Fe(so 4 ) 2 .6H 2 o 50.29 101.1 0.1967
Caesium Magnesium Sulphate CsjsMgtso^HaO 34-77 53-3 o . 1 106
Caesium Manganese Sulphate Cs2Mn(SO 4 ) 2 .6H2O 44-58 80 . 4 0.157
Caesium Nickel Sulphate Cs2Ni(so 4 )2.6H 2 o 20.37 25.6 0.0495
Caesium Zinc Sulphate Cs2Zn(so 4 ) 2 .6H 2 o 27.87 38.6 0.0738
CAFFEINE C 6 H(CH 3 ) 3 N 4 2 .H 2 0.
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P. ; Gockel J. Chem. Soc. 74 32?, '98; CommaiUe Compt. rend. 8x, 819, '75.)
Grams Caffeine per 100 Grams Solvent at:
Solvent.
25. 80.
U.S. P.
18.
Gockel.
b.pt.
is
.17 b.
CommaiUe.
pt.
Water
2.19 19-23
.
. .
.
I
3 T J
45-
54
Alcohol
1.88 5.85*
,
.
.6iJ
3.
Ether
0.267
o.
119
2 95
O
044|
o.
3^1
Chloroform
12.5
II .
77
15
12
97t
19.
02%
Benzene
- . . ...
o.
911
5
.29
.
,
Carbon Tetra
Chloride
... ...
o.
089
.702
.
Carbon Bisulphide
...
.
0585*
o.
454J
* 60. t 65.
t Gms. anhydrous caffeine.
Abs. alcohol and abs .
ether.
CALCIUM ACETATE Ca(CH 3 COO) 2 . 2 H 2 O.
SOLUBILITY IN WATER.
(Lumsden J. Chem. Soc. 81, 355. '02-, Krasnicki Monatsh. Chem. 8, 597, '87.)
Gms. CaCCHaCOOa Gms. Ca(CH 3 COO) 2
t. per IPO Gms. Solid Phase. t. per 100 Gms. Solid Phase.
Solution. Water. Solution. Water.
O 27.2 37.4 Ca(CH 3 COO) 2 .2H 2 O 60 24.6 32.7 Ca(CH 3 COO) 2 .2H 2 O
10 26.5 36.0 Ca(CH 3 COO) 2 .2H 2 O 80 25.! 33.5 Ca(CH3COO) 2 .2H 2 O
20 25.8 34.7 Ca(CH 3 COO) 2 . 2 H 2 O 84 25.3 33.8 Ca(CH 3 COO) 2 .2H 2 O'
2 5 25.5 34.2 Ca(CH3COO) 2 .2H20 85 24.7 32.9 Ca(CH 3 COO) 2 .H 2 O
3 2 5-3 33 " 8 Ca(CH 3 COO) 2 . 2 H 2 90 23.7 31.1 Ca(CH 3 COO) 2 .H 2 O
40 24.9 33.2 Ca(CH 3 COO) 2 . 2 H 2 IOO 22-9 29.7 Ca(CH3COO) 2 .H,O
SOLUBILITY OP CALCIUM ACETATE IN AN AQUEOUS SATURATED SOLU-
TION OF SUGAR AT 31.25.
(Kohler Z. Ver. Zuckerind. 47, 447, *97-)
TOO gms. solution contain 8.29 gms. Ca(CH 3 COO) 2 + 60.12 gms. sugar,
loo gms. water dissolve 26.3 gms. Ca(CH 3 COO) 2 + 190.3 gms sugar.
CALCIUM ACETATES
CALCIUM (Tri) Methyl ACETATE Ca[(CH 3 ) 3 CCOO] 3 .
CALCIUM (Di) Ethyl ACETATE Ca[(C 2 H 5 ) 2 CHCOO] 2 .
CALCIUM Methyl Ethyl ACETATE Ca[CH 3 (C 2 H 6 ).CHCOO] 2 .
SOLUBILITY OF EACH IN WATER.
(Landau Monatsh. Chem. 14, 717, '93; Keppish Ibid. 9, 600, '88; Sedlitzki Hid. 8, 573, '87-j
Ca. Tri Methyl Acetate. Ca. Di Ethyl Acetate. Ca. Methyl Ethyl.
Acetate.
Gms. Ca(C 5 H 9 O 2 )2
Gms. Ca(C6H n O2) 2
Gms. (
:a(C5H 9 2 ) s
4 o per 100 Gms.
per
loo Gms.
per
loo Gms.
Water.
Solution.
'Water
, Solution.
Water.
Solution.
O
7-30
6.81
30-3
23.22
28.78
22-35
10
6.84
6.40
27.8
31 .71
24.07
20
6-54
6.14
25.6
20-38
33.76
25.23
30
6.40
6.01
23-7
19.16
34-92
25.89
40
6.44
6.05
22 .1
I8.IO
35-20
26.04
50
6.64
6.22
20-8
17.22
34.60
25-7I
60
6.86
6.42
19.9
16.60
33 .11
24.89
70
7.11
6-64
19.2
16.11
30-74
23.41
80
7-38
6.87
27.49
21 .56
CALCIUM Methyl Propyl ACETATE Ca[CH 3 (C 3 H 7 ).CHCOO],.
CALCIUM (Di) Propyl ACETATE Ca[(C 3 H 7 ) 2 CHCOO] 2 .
CALCIUM (Iso) Butyl ACETATE Ca[(CH 3 ) 2 CH(CH 2 ) 2 COO] 2 .
SOLUBILITY OF EACH IN WATER.
(Stiassny Monatsh. Chem. 12, 596, '91; Furth Ibid. 9. 313. '88; Konig Ibid. 15, 22, '94.)
Ca. Methyl Propyl Acetate. Ca. Di Propyl Acetate. Ca. Iso Butyl
Acetate.
Gms. Ca(C 8 H 15 O 2 ) 2
per IPO Gms.
Water. Solution.
9-57 8.73
8-35
7.19
6. ii
Gms. Ca(C 6 H u O 2 )2
t o. per 100 Gms.
Water.
Solution.
O
16.58
14.22
10
15.80
I3-65
20
15.14
13.15
30
I4.6l
12-75
40
14.21
12-45
50
J 3-94
12 .24
60
13-79
12.13
70
I3-78
12.12
80
13.89
12.20
90
7.71
6.71
5-77
5.09 4.84
4.14 3.98
$*$
2-38
per iop Gms.
Water. Solution.
7.48 6.96
6.38 5.99
5-66 5-36
5-3 1 5-04
3-25
2-44
1-65
5.68
6.41
1.62
5-04
5-37
6.02
7.51 6.98
8.97 8.23
10.79 9-74
CALCIUM BROMIDE CaBr 2 .
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 103, 65, '58; Etard Ann. chim. phys. [7] 2, 532, '94, gives results which
yield an irregular curve and are evidently less accurate than those of Kremers.)
Gms. CaBr 2 per TOO Gms. Gms. CaBr 2 per 100 Gms.
Water. Solution. Water. Solution.
ioi 50.5 34-2 185 65
22
O
10
20
25
I2 5
132
55-5
57.0
143 58-8
153 60.5
34-2
40
60
80
105
213
278
295
312
68.1
73-5
74-7
75-7
Density of saturated solution at 20 = 1.82.
CALCIUM BUTTRATE
86
CALCIUM (Normal) BUTTEATE Ca[CH 3 (CH 2 ) 2 eOO] 2 .H 2 O.
CALCIUM (Iso) BUTYRATE Ca[(CH 3 ) 2 CH.COO] 2 .sH 2 O.
SOLUBILITY OF EACH IN WATER.
(Lumsden J. Chem. Soc. 81, 355, '02; see also Chancel and Parmentier Compt. rend. 104, 474,
'87; Deszathy Monatsh. Chem. 14, 251, '93, and also Hecht Liebig's Annalen 213, 72, '82, give
results for the normal salt which are somewhat below those of Lumsden for the lower temperatures.
SedHtzki Monatsh. Chem. 8, 566, '87, gives slightly different results for the iso salt.)
Calcium Normal Butyrate.
Calcium Iso Butyrate.
Gms. Ca(C 4 H 7 2 ) 2
t . per 100 Gms.
t.
Gms. Ca(C 4 H 7 O 2 ) 2
per 100 Gms.
Solid
PttftM
Water. Solution.
Water.
Solution.
iDclSC.
O
20
3i
16
.89
2O
IO
16
.78
Ca(C 4 H 7 2 ) :
, 5 H 2
10
19
.15
16
.08
20
22
40
18
30
fi
20
18
.20
J 5
39
30
23
.80
!9
23
ii
25
17
.72
15
5
40
25
.28
20
65
K
30
17
25
14
7i
60
28
40
22
.12
t(
40
16
.40
14
.09
62
28
.70
22
30
a
60
15
.15
J 3
.16
65
28
25
22
03
Ca(C 4 H 7 3 )
2 .H,0
80
*4-95
13
.01
80
27
OO
21
.26
100
J 5
85
13
.69
100
26
.10
20
.69
M
CALCIUM CAPROATE Ca[CH 3 (CH 2 ) 4 COO] 2 .H 2 O.
CALCIUM 3 Methyl PENTANATE Ca[CH 3 .CH 2 .CH(CH 3 )CH,.
COO] 2 . 3 H 2 0.
CALCIUM CAPRYLATE Ca[CH 3 (CH 2 ) 6 COO] 2 .H 2 O.
SOLUBILITY OF EACH IN WATER.
(Lumsden; the Pentanate, Kulish Monatsh. Chem. 14, 566, '93; see also Keppish Ibid. 9, 594,
'88, and Altschul Ibid. 17, 571, '96, for results on the Caproate.)
Ca. Caproate.
Gms. Ca(C6H u 2 ) 2
per 100 Gms.
H 2 0.
O
20
40
50
60
80
100
18
15
2 .23
2
2 ,
2.10
2-15
2.30
2-57
Ca.
3 Methyl Pentanate.
Gms. Ca(C5HnO 2 ) 2
per 100 Gms,
Water.
12-33
I7.I8
18.99
18-73
17.71
*3-37
9-94
Solution.
10.98
14.66
J 5-97
I5-78
15.04
11.80
9.04
Ca. Caprylate.
Gms. Ca(C 8 H 15 O 2 ) s
per 100 Gms.
H 2 0.
. o-33
0.31
0.28
0.26
0.24
0.32
0.50
CALCIUM CARBONATE CaCO,.
SOLUBILITY IN WATER, AS DETERMINED BY THE ELECTROLYTIC
CONDUCTIVITY METHOD.
(Holleman, Kohlrausch, and Rose Z. physik. Chem. 12, 129, 241, '93.)
i liter solution contains o.oi gram CaCO 3 at 8.7, and 0.012 gram
at 20.
87 CALCIUM BICARBONATE
CALCIUM BICARBONATE Ca(HCO 3 ) 2 .
SOLUBILITY IN WATER AT 15.
Calcium carbonate in presence of water, free from and containing
carbon dioxide, dissolves as the hydrogen carbonate.
(Among the investigators who have reported results upon the solubility of calcium bicarbonate may be
mentioned, Cossa Z. anal. Chem. 8, 145, '69; Schloesing Com pt. rend. 74, 1522, '72; Caro Arch.
Pharm. [3] 4, 145, '74; Reid Proc. Roy. Soc. (Edin.) 15, 151, '87- '88^ Irving and Young J. Chem.
" Ann. chim. phys.
L'Orosi 19, 217, '96,
ippear ot most interest and reliability are the following by Tread-
well and Reuter Z. anorg. Chem. 07, 185, '96.)
cc. CO 2 per 100 cc.
Partial Pres-
Gms. per
100 cc. Saturated
Solution.
sure of COa
(o and 760 mm.).
in mm. Hg.
Free CO 2 .
Ca(HC0 3 ) 2 .
Ca.""
8.94
67.9
0.1574
0.1872
0.0462
6-O4
45-9
0.0863
0-1755
0-0433
5-45
41.4
0-0528
0.0394
2.18
16.6
0-0485
0-I540
0.0380
1.89
14.4
0-0347
0.1492
0.0368
1.72
13 .1
0.0243
0-I33 1
0.0329
o 79
6.0
O.OI45
o . i 249
0.0308
0.41
3- 1
0-0047
0.0821
O.O2O3
0-25
1.9
O.OO29
0-0595
O.OI47
0.08
0.6
0.0402
O.OO99
0.0385
0.0095
Therefore i liter sat. solution at 15 and o partial pressure of CO 2
contains 0.385 gram Ca(HCO 3 ) 2 .
SOLUBILITY OF CALCIUM BICARBONATE IN AQUEOUS SODIUM CHLORIDE
SOLUTION AT 15.
(Tread well and Reuter.)
The NaCl solution contained about 5 grams per liter, and was there-
fore approximately T V normal.
cc. CO 2 per 100 cc.
Gaseous Phase
(o and 760 mm.).
16.95
11-47
6.07
3-16
0.50
Partial Pres-
sure of CO 2
in mm. Hg.
128.8
8 7 .2
46.1
24.0
3 *
3-4
Grams per 100 cc. Saturated Solution.
Free CO 2 .
Ca(HC0 3 ) 2 .
Ca.
0.1325
0.2184
0-0539
O-IIOI
0.2143
0.0529
0.0235
0.1492
0.0368
0.0135
0.1183
0.0292
O.OO27
0-0739
O.Ol82
0.0003
0.0400
O-OI2I
0.0349
0.0086
0.0332
0.0082
CALCIUM BICARBONATE
88
SOLUBILITY OF CALCIUM BICARBONATE IN AQUEOUS SOLUTIONS op
AMMONIUM NITRATE, SODIUM CHLORIDE AND OF SODIUM SULPHATE.
(Cameron and Seidell J. Physic. Chem. 6, 50, '02; Berju and Kosminiko Landw. Vers. Stat. 60,
422, '04.)
In NH4NG-3 Solutions at 18.
Grams per Liter Solution.
In NaCl Solutions at 25.
Grams per Liter Solution.
In Na2SO 4 Solutions at 24.
Grams per Liter Solution.
fHUNOs
. Ca(HC0 3 ) 2 .
NaCl.
Ca(HC0 3 ) 2 .
Na 2 S0 4 .
Ca(HCO 3 ) 2 total.
Ca(HCO 3 ) 2 .
0.210
O
o . 1046
O
0.092
0.092
5
10
20
0.340
0.415
o-547
5
10
20
0.150
O.lSo
0.210
5
10
20
0-175
0.232
0.277
0-175
O.22O
O.262
40
80
0.744
0.940
40
80
O.225
O-22O
40
80
0.332
0.4OO
0.307
0-347
100
150
2OO
0.215
0.192
0.170
100
200
0.432
0.510
O.6OO
o-355
0.382
0.400
250
0.137
250
0.725
0-435
CALCIUM CHLORATE Ca(ClO 3 ) 2 .2H 2 O.
100 grams saturated aqueous solution contain 64.0 grams Ca(ClO 3 )L
at 1 8. Density of solution is 1.729.
(Mylius and Funk Ber. 30, 1718, '97.)
CALCIUM CHLORIDE CaCl 2 .
SOLUBILITY IN WATER.
(Roozeboom Z. physik. Chem. 4, 42, '80; see also Mulder; Ditte Compt. rend. 92, 242, '81; Eng*'
Ann. chim. physic. [6JI3, 381, '88; Etard Ibid. [7] 2, 532, '94.)
Gms. CaCl 2 per
$0. ioo Gms.
Solid
t>u<.
t.
Gms. CaCl 2 per
ioo Gms.
Solid
Phase.
Water. Solution.
Water.
Solution.
55
42
5
29.
8
Ice -f CaCl 2 .6H 2 O
60
I 3 6
.8
57
.8
CaCl 2 .2H 2
25
50
.0
33-
3
CaCl 2 .6H2O
70
141
7
58
.6
CaCl 2 . 2 H 2 O
o
59
5
37-
3
CaCl 2 .6H 2 O
80
147
-0
59
-5
CaCl 2 .2H 2 O
10
65
.0
39-
4
CaCl 2 .6H 2 O
90
152
7
60
.6
CaCl 2 .2H 2 O
20
74
5
42.
7
CaCl 2 .6H2O
IOO
X 59
.0
61
4
CaCl 2 . 2 H 2 O
30.2
IO2
7
7
CaCl 2 .6H 2 O
1 20
*73
.0
63-4
CaCl 2 . 2 H 2 O
20
91
.0
47-
6
CaCl 2 . 4 H 2 Oa
140
191
.0
65
.6
CaCl 2 . 2 H 2 O
29.8
IOO
.6
50.
i
^H 2 O a -f .6H 2 O
160
222
5
69
O
CaCl 2 . 2 H 2
40
IJ 5
3
53-
4
.4H 2 Oa
170
2 55
7 1
.8
CaCl 2 . 2 H 2
20
104
5
5 1 -
i
CaCl 2 4H 2 O ft
J75-5
297
.0
74
.8]
! -r CaClz-ii^
29.2
112
.8
53
wiH 2 O 6 + .6H 2 O
180
300
.0
75
.0
CaCl 2 .H 2 O
35
122
5
55
wtH 2 O8
200
3"
.0
75
7
CaCl a .H2O
38-4
127
5
56
o
^H 2 0/3+CaCl 2 .2H 2
235
332
-O
76
.8
CaC^.HzO
45-3
130
.2
56
6
-4H2O a + CaCl 2 . 2 H2O
260
347
.0
77
.6
CaCl 2 .H 2
Density of saturated solution at o =
1.417.
1.367, at 15= 1.399* at l8 '
8 9
CALCIUM CHLORIDE
SOLUBILITY OF CALCIUM CHLORIDE IN AQUEOUS SOLUTIONS OP
HYDROCHLORIC ACID AT o.
(Engel Compt. rend. 104, 434, '87.)
G. Mols. in Mgs.
per 10 cc.
Solution.
*CaCl 2 .
92.7
83-7
77.1
66.25
53-75
HCl.
O.O
9-1
16.0
29.25
43-45
36-25 63.5
20.3 95.0
Density of
Solutions.
1.367
1-344
1.326
i .310
1.283
1.250
1.238
Grams per 100 cc.
Solution.
CaCl 2 .
HCl.
5^45
O.O
46.45
3-32
42.80
5-83
3 6 -77
10.66
29.84
15.84
2O- 12
23-I5
II .29
34.62
SOLUBILITY OP MIXTURES OF CALCIUM CHLORIDE AND ALKALI
CHLORIDES.
(Mulder; Riidorff.)
ioo grams H 2 O dissolve 63.5 grams CaCl 2 +4.9 grams KC1 at 7 (M)
100 grams H 2 O dissolve 57.6 grams CaCl 2 + 2.4 grams NaCl at 4 (M)
ioo grams H 2 O dissolve 59.5 grams CaCl 2 +4.6 grams NaCl at 7(M)
ioo grams H 2 O dissolve 72.6 grams CaCl 2 + 16.0 grams NaCl at i5(R)
SOLUBILITY OF CALCIUM CHLORIDE IN AQUEOUS ALCOHOL AT ROOM
TEMPERATURE.
(Bodtker Z. physik. Chem. 22, 570, '97.)
Solution
Used.
15 Cms. CaCl 2 .6H 2 O
+ 20 cc. alcohol
15 Gms. CaCl 2 .6H 2 O
+ 20 cc. alcohol
15 Gms. CaCl 2 .6H 2 O
+ 20 cc. alcohol
15 Gms. CaCl 2 .6H 2 O
+ i Gm. CaCL
Vol.
per
cent
Alcohol.
9 2 -3
97-3
99-3
99-3
Gms.
CaCl 2
1.430
1.409
1.429
1.529
Solution
Used.
15 Gms. CaCl 2 .6H 2 O +20 cc.
alcohol + 2 Gms. CaC^
" +3 "
" +4 "
" +5 "
Vol.
per
cent
Alcohol.
" 3
Gms.
CaCl 2
."si*
1.561
1.590
1.641
1.709
SOLUBILITY OF CALCIUM CHLORIDE IN A SATURATED SOLUTION OP
SUGAR AT 31.25.
(Kohler Z. Ver. Zuckerind. 47, 447, '97.)
ioo grams saturated solution contain 42.84 grams sugar + 25.25
grams CaCl 2 , or ioo grams water dissolve 135.1 grams sugar + 79.9
grams CaCl 2 .
CALCIUM CITRATE Ca 3 (C 6 H 6 O 7 ) 2 . 4 H 2 O.
SOLUBILITY IN WATER AND IN ALCOHOL AT 18 AND AT 25.
(Partheil and Hiibner Archiv. Pharm. 241, 413, '03.)
Solvent.
Grams
per ioo
Water
Alcohol (Sp. Gr. 0.8092 = 95%)
18.
0.08496
0.0065
2S-
0.0959
0-0089
CALCIUM OHROMATE
90
CALCIUM CHROMATE CaCrO 4 .
SOLUBILITY OP THE SEVERAL HYDRATES IN WATER.
(Mylius and Wrochem Wiss. Abh. p. t. Reichanstalt 3, 462, 'oo.)
ft o Gms. CaCrO 4 per 100 Gms. Mols. CaCr0 4 Gms. CaCrO 4 per looGms. Mols.CaCrO 4
1 /-=; : > per 100 Mols. * '
Water. Solution. H 2 O.
Solid Phase, a CaCrO 4 .2H 2 O. (Monoclinic.)
O 17.3 14-75 2.0
18 16.68 14.3 1.93
20 16.6 14.22 i-93
30 16.5 13.89 1.85
45 14-3 I2 -53 J - 6 5
Solid Phase, /5 CaCrO 4 . 2 H 2 O (Rhombic.)
O
18
40
O
18
25
40
00
75
100
10.9 9.8
11.5 10.3
ii. 6 10.4
Solid Phase, CaCrO 4 .H 2 O.
1.25
i-33
i-34
13.0
10.6
10. o
8-5
6.1
4.8
3-2
"5
9.6
9.1
7.8
5-7
4-6
50
22
0.98
O.7O
0.56
o-37
Water. Solution.
per 100 o
H 2 O.
Solid Phase, CaCrO 4 .*H 2 O.
7-3
6.8
0.84
18
4-8
4-4
0.51
31
3-84
3-7
0-44
38.5
2.67
2.6
0.31
50
1-63
1.6
0.19
00
1-13
i.i
0.13
100
0.81
0.8
0.09
Solid Phase,
CaCr0 4 .
,
4-5
4-3
' 0.52
18
2.32
2.27
0.27
3i
2.92
1.89
0.22
50
1. 12
I. II
0.13
00
0.83
0.82
O.II
70
0.80
0-79
O.O9
100
0.42
O.42
O.O5
Densities of the saturated solutions of the above several hydrates
at 18 are: a CaCrO 4 .2H 2 O, 1.149; CaCrO 4 .2H 2 O, 1.105; CaCrO 4 .H 2 O,
1.096; CaCrO 4 .iH 2 O, 1.044; CaCrO 4 , 1.023.
100 cc. 29% alcohol dissolve 1.206 grams CaCrO 4 .
100 cc. 53% alcohol dissolve 0.88 gram CaCrO 4 .
(Fresenius Z. anal. Chem. 30, 672, '91.)
CALCIUM POTASSIUM FERROCYANIDE CaK 2 Fe(CN) 6 . 3 H 2 O.
100 parts H 2 O dissolve 0.125 part salt at 15, and 0.69 part at b. pt.
(Kunheim and Zimmerman Dingt. polyt. J. 252, 478, '84.)
CALCIUM FLUORIDE CaF 2 .
i liter of saturated aqueous solution contains 0.016 gram CaF 2 at
1 8. Determined by the electrolytic method.
(Kohlrausch Z. physik. Chem. 44. 197, '03.)
CALCIUM FORMATE Ca(HCOO),.
SOLUBILITY IN WATER.
(Lumsden J. Chem. Soc. 81, 355, '02; see also Krasnicki Monatsh. Chem. 8, 597, '87.)
Gms.Ca(HCOO) 2
^^ per loo Gms. 4
Gms.Ca(HCOO) 2
per loo Gms.
20
40
Water.
16.15
16.60
17-05
Solution.
13.90
14.22
14.56
60
80
100
Water.
I7-50
17-95
18.40
Solution.
14.89
15.22
15-53
9 i CALCIUM HEPTOATE
CALCIUM HEPTOATE (Oenanthate) Ca[CH 3 (CH 2 ) 6 COO] 2 .H 2 O.
SOLUBILITY IN WATER.
(Lumsden J. Chem. Soc. 81, 355, '02; see also Landau Monatsh. Chem. 14, 712, '93; Altschul
Ibid. 17, 575, '96.)
t. o. 20. 40. 60. 80. ioo.
G. Ca(C 7 H 13 O 2 ) 2 per
i oo gms. solution 0.94 0.85 0.81 0.81 0.97 1.24
CALCIUM HYDROXIDE Ca(OH) ? .
SOLUBILITY IN WATER.
(Average curve from the results of Lamy Ann. chim. phys. [5] 14, 145, '78; Mahen Pharm. J. Trans
[3] 14, S5, '83-84; Herzfeld Z. Ver Zuckerind. 34 820, '97, and Guthrie J. Soc. Chem. Ind. 20,
224, 'ox.)
Grams per 100 Grams HjO. Grams, per TOO Grams H2O.
Ca(OH) 2 . CaO. ' Ca(OH) 2 . CaO. '
o 0.185 0.140 50 0.128 0.097
10 0.176 0.133 60 0.116 0.088
20 0.165 0.125 70 '0.106 0.080
25 - I 59 0.120 80 0.094 0.071
30 o<1 53 0.116 90 0.085 0.064
40 0.141 0-.I07 100 0.077 0-058
SOLUBILITY QF CALCIUM HYDROXIDE IN AQUEOUS SOLUTIONS OP
AMMONIUM CHLORIDE AT 25.
(Noyes and Chapin Z. physik. Chem. 28, 520, '99.)
Millimols per Liter. Grams per Liter of Saturated Solution.
NH 4 C1. Ca(OH) 2 . NI^Cl. c7(OH) 2 = CaO.
o.oo 20.22 o.oo 1-50 1.13
21.76 29.08 1-165 2.16 1.63
43-52 39-23 2.330 2.91 2.20
83-07 59-68 4.447 4-42 3-45
SOLUBILITY OF CALCIUM HYDROXIDE IN AQUEOUS SOLUTIONS OF
CALCIUM CHLORIDE.
(Zahorsky Z. anorg. Chem. 3, 41, '93; Lunge J. Soc. Chem. Ind. n, 882, '92.)
Concentration Grams CaO Dissolved per 100 cc. Solvent at;
of CaCb Solutions, Wt.%.
O
5
10
15
20
25
30
* Indicates cases in which a precipitate of calcium oxychloride
separated and thus removed some of the CaCl 2 from solution.
The results in o% CaCl 2 solutions, i.e., in pure water, are high when
compared with the average results given above.
4
20.
40.
00.
80.
100.
c.
1374
.Il62
O
.IO26
.0845
.0664
,1370
.Il6o
.1020
.0936
.0906
,1661
o
.1419
1313
1328
.1389
o
1993
.I78l
.1706
.1736
o
.1842
o
.1857*
.2249
o
.22O4
2295
o
2325
.1661*
o
.3020*
o
.2989
3261
.3710
1630*
.3680*
.3664
.4122
.4922
CALCIUM HYDROXIDE
92
SOLUBILITY OP CALCIUM HYDROXIDE IN AQUEOUS SOLUTIONS OP
POTASSIUM CHLORIDE AND OF SODIUM CHLORIDE.
(Cabot J. Soc. Chem. Ind. 16, 417, '97.)
In
KC1 Solutions.
In NaCl Solutions.
Gms. of the
Chloride
Gms. CaO per Liter at:
Gms. CaO per Liter at:
per Liter.
o.
15-
99*. o. 15.
09.
i. 3 6
1.31
635
.36 3
3 1
0-635
30
I .701
1.658
o
.788 ]
.813
703
0.969
60
I-72S
1.674
o
.876
.824
I .004
120
I.7I8
i. 606
o
.894 1
.86
.722
I.OI5
240
1.248
1.199
.617
37
.274
0.771
320
.054 0.929
0-583
SOLUBILITY OF LIME IN AQUEOUS SOLUTIONS OF SODIUM CHLORIDE
ALONE AND CONTAINING SODIUM HYDROXIDE.
(Margiet Bull. soc. chim. [3] 33, 631, '05.)
G. NaCl
per Liter
Gms. CaO per Liter of Solution.
G. NaCl.
per Liter. W
W
Gms. CaO per Liter of Solution.
Without o.8 9 .NaOH 4 .o 9 .NaOH
NaOH. per Liter. per Liter.
ithout
aOH.
o.8 9 .NaOH
per Liter.
4.09.NaOH
per Liter.
O
I
3
O
.8 0.22
J 5o
65
I
25
0-44
5
I
4
9
175
.6
I
.2
. . .
10
I
.6
I
.0
182
.6
I
.2
25
I
7
I
.1
225
4
I
O
. . .
50
I
.8
I
25
250
3
9
75
I
9
I
4 0.55
300
.1
O
7
0.22
IOO
I
85
I
4
SOLUBILITY OF CALCIUM HYDROXIDE IN AQUEOUS SOLUTIONS OF
SODIUM HYDROXIDE.
(d'Anselme Bull. soc. chim. [3] 29, 938, '03.)
Concentration of NaOH:
Grams CaO per Liter Sat. Solution at:
Normality.
Gms. per Liter
N/ioo
0-4
N/2 5
1.6
N/i5
2.66
N/8
5-oo
N/5
8.00
N/2
20-00
20.
50.
70.
100.
1.170
0.94
0.880
0.65
o-75
o-53
o-54
o-35
o-57
o-35
0.225
0.14
o 39
0.18
0-20
O-o6
O.II
0-04
0.05
O-OI
O.II
O-O2
o.oi
trace
0.02
trace
o.oo
0-00
For results upon mixtures of calcium hydroxide and alkali carbonates
and hydroxides, see Bodlander Z. angew. Chem. 18, 1138, '05.
93
CALCIUM HYDROXIDE
SOLUBILITY OF CALCIUM HYDROXIDE IN AQUEOUS SOLUTIONS OF
GLYCERINE AT 25"
deter
Arch. Phann. [3] 4, 558, '74.)
(Herz and Knoch Z. anorg. Chem. 46, 193, '05; for older determinations, see Berthelot Ann. chim.
phys. [3] 46, 176; and Carles ,
density of
Solutions
Wt. per cent
Glycerine
in Solution.
MilUmols
*Ca(OH) 2 per
100 cc. Solution.
I .0003
.0244
o.o
4-3
8.13
0537
.0842
20-44
14.9
22.5
1137
1356
.2072
40.95
48.7
69.2
40.1
44.0
95-8
Gms. per 100 cc. Solution.
Ca(OH) 2
= CaO.
0.1593
o.i 206
0.3013
O.228l
0.5522
0.4180
0-8339
0.6313
1.486
I.I25
1 1631
1.234
3-550
2.687
SOLUBILITY OF LIME IN AQUEOUS SOLUTIONS OF SUGAR.
(Weisberg Bull. soc. chim. [3] 21, 775, '99.)
The original results were plotted on cross-section paper and the
following table constructed from the curves.
ist series, t = i6'-i7.
2d, series t = 15.
Gms. per
Solu
100 Gms.
tion.
G. CaO per 100
Gms. Sugar in Sol.
Gms. per 100 Gms.
Solution.
G, CaO per 100
Gms. Sugar in Sol.
Sugar.
CaO.
Sugar.
CaO.
I
0.30
35-
I
0.50
62.5
2
0-56
28.
7
2
0-75
36.0
3
0.85
28.
o
3
1.02
32-5
4
I .12
27.
7
4
1.22
30.2
5
1.40
27.
5
5
i-45
28.5
6
1.65
27.
5
6
1.67
27.7
8
2.22
27.
5
8
2.22
27-5
10
2.77
27.
5
10
2-77
27-5
12
3-27
27.
5
12
3-27
27-5
14
3-85
27.
5
14
3-85
27-5
In the second series a very much larger excess of lime was used than
in the first series. The author gives results in a subsequent paper,
Bull. soc. chim. [3] 23, 740, 'oo, which show that the solubility is also
affected by the condition of the calcium compound used, i.e., whether
the oxide, hydrate, or milk of lime is added to the sugar solutions.
CALCIUM IODATE 94
CALCIUM IODATE Ca(IO 3 ) 2 .6H 2 O.
SOLUBILITY IN WATER.
(Mylius and Funk Ber. 30, 1724, '97; W. Abb. p. t. Reichanstalt 3, 448, 'oo.)
Cms. Mols. Gms. Mols.
t o Ca(I0 3 ) 2 Ca(10 3 ) 2 Solid t Ca(IO 3 ) 2 Ca(IO 3 ) 2 Solid
per 100 per 100 Phase. ' per ioo per 100 Phase.
Gms. Sol. Mols. H 2 O. Gms. Sol. Mols. H^.
o o.io 0.0044 Ca(IO 3 ).6H 2 O 21 0.37 0.016 Ca(IO 3 ) 2 .H 2 O
10 0.17 0.0075 35 0-48 0.021
18 0.25 o.oii 40 0.52 0.023
30 0.42 0.019 45 0.54 0.024
40 0.61 0.027 50 0.59 0.026
50 0.89 0.040 60 0-65 0.029
54 1.04 0.046 80 0.79 0.034
60 1.36 0.063 " 100 0.94 0.042 "
Density of solution saturated at 18 = i.oo.
CALCIUM IODIDE CaI 2 .
SOLUBILITY IN WATER.
(Average curve from the results of Kremers Pogg. Ann. 103, 65, '58; Etard Ann. chim. phys. [7]
2, 532, '94-)
. o Gms. CaI 2 per TOO t Gms. CaI 2 per 100 . Gms. CaI 2 per 100
Gms. Solution. Gms. Solution. Gms. Solution.
o 64.6 30 69 80 78
10 66.0 40 70.8 loo 81
20 67.6 60 74
Density of solution saturated at 20 = 2.125.
CALCIUM (Neutral) MALATE Ca(C 4 H 4 O 5 ).3H 2 O.
CALCIUM (Acid) MALATE Ca(C 4 H 5 O 5 ) 2 .6H 2 O.
CALCIUM MALONATE Ca(C 3 H 2 O 4 ).4H 2 O.
SOLUBILITY OF EACH IN WATER.
(Iwig and Hecht Liebig's Ann. 233. 167, '86; Cantoni and Basadonna Bull. soc. chim. [3] 35,
731, '06; the malonate, Miczynski Monatsh. Chem. 7, 261, '86.)
Ca. Neutral Malate. Ca. Acid Malate. Ca. Malonate.
Gms. Ca(C 4 H 4 O 5 ) per 100. Gms. Ca(C 4 H 5 O5)3 Gms. Ca(C 3 H 2 O 4 )
t. Gml G cTSoT . *** I0 ? Gms - . pP" 1 ^
HzO. Sol. (CandB). Water. Solution. Gms. H 2 O.
o ... ... ... ... ... o . 290
10 0.85 0.84 1.8 1.77 0.330
20 0.82 0.81 0.907 1.5 1.48 0-365
30 0.78 0-77 0.835 2.0 1.96 0.396
40 0.74 0.73 0.816 5.2 4.94 0.422
50 0.66 0.65 0.809 15.0 13-09 0.443
57 0.57 0.56 32.24 24.29
60 0.58 0.58 0.804 26.0 20.64 0.460
70 0.63 0.63 0.795 II - 9-9 1 0.472
80 0.71 0.70 0.754 6.8 6.37 0.479
90 ... o . 740
SOLUBILITY OF CALCIUM MALATE IN WATER AND IN ALCOHOL.
(Partheil and Hiibner Archiv. Pharm. 241, 413, '03.)
ioo grams H 2 O dissolve 0.9214 gram CaC 4 H 4 O 5 .H 2 O at 18, and
0.8552 gram at 25.
ioo grams 95% alcohol dissolve 0.0049 gram CaC 4 H 4 O c .H 2 O at 18,
and 0.00586 gram at 25.
95 CALCIUM NITRATE
CALCIUM NITRATE Ca(NO 3 ) 2 .2H 2 O.
SOLUBILITY IN WATER AT 18.
(Mylius and Funk Ber. 30, 1718, '97.)
ioo grams saturated solution contain 54.8 grams Ca(NO 3 ) 2 . Density
of solution, 1.548.
CALCIUM OXALATE Ca(COO) 2 .H 2 O.
SOLUBILITY IN WATER, BY ELECTROLYTIC CONDUCTIVITY METHOD.
(Holleman, Kohlrausch, and Rose Z. physik. Chem. 12, 129, 241, '93; Richards, McCaffrey,
and Bisbee Z. anorg. Chem. 28, 85, '01.)
. Cms. CaC 2 O 4 per t o Cms. CaC 2 O 4 per
Liter of Solution. Liter of Solution.
13 0.0067 (H) 25 0.0068 (R, McC and B)
18 0.0056 (K and R) 50 0.0095
24 0.0080 (H) 95 0.0140 "
SOLUBILITY OF CALCIUM OXALATE IN AQUEOUS SOLUTIONS OF ACETIC
ACID AT 26-27.
(Herz and Muhs Ber. 36, 3715, '03.)
Normality of
Acetic Acid.
G. CH 3 COOH
per ioo cc. Sol.
Residue from 50.052
cc. Solution.
O-OO
O.OOI7
0.58
3-48
O.OO48
2.89
J 7-34
0.0058
5-79
34-74
O.OOO4
The residues were dried at 70 C.
CALCIUM OXIDE. See Calcium Hydroxide, p. 91.
CALCIUM PHOSPHATE (Tribasic) Ca 3 (PO 4 ) 2 .
SOLUBILITY IN WATER.
The determinations of the solubility of this salt in water, as stated
in the literature, are found to vary within rather wide limits, due, no
doubt, to the fact that so-called tribasic calcium phosphate is apparently
a solid solution of the dibasic salt and calcium oxide, and therefore
analyses of individual samples may show an excess of either lime or
phosphoric acid. When placed in contact with water, more PO 4 ions
enter solution than Ca ions, the resulting solution being acid in reaction
and the solid phase richer in lime than it was, previous to being added
to the water. For material having a composition approximating
closely that represented by the formula Ca 3 (PO 4 ) 2 the amount which
is dissolved by CO 2 free water at the ordinary temperature, as cal-
culated from the calcium determination, is o.oi to o.io gram per liter,
depending upon the conditions of the experiment. Water saturated
with CO 2 dissolves 0.15 to 0.30 gram per liter.
A list of references to papers on this subject is given by Cameron
and Hurst J. Am. Chem. Soc. 26, 903, '04; see also Cameron and
Bell, Ibid. 27, 1512, '05.
CALCIUM PHOSPHATE
96
CALCIUM PHOSPHATE (Dibasic) CaHPO 4 .2H a O.
SOLUBILITY IN WATER.
(Cameron and Seidell J. Am. Chem. Soc. 26, 1460, '04; see also Rindell Compt. rend. 134, ua, 'oa;
Magnanini Gazz. chim. ital. 31, II, 544, *oi.)
i liter of CO 2 free water dissolves 0.136 gram CaHPO 4 at 25.
i liter of water sat. with CO 2 dissolves 0.561 gram CaHPO 4 at 25.
SOLUBILITY OF Di CALCIUM PHOSPHATE AND OF MONO CALCIUM PHOS-
PHATE IN AQUEOUS SOLUTIONS OF PHOSPHORIC ACID AT 25.
(Cameron and Seidell J. Am. Chem. Soc. 27, 1508, '05; Causse Compt. rend. 114, 414, '92.)
Grams per Liter of
Solution.
Gms. per Liter
Calc. frOP 1 r*aO FminrT
PzO 6 per Liter
tt E combLe f d Solid Phase.
CaO.
F 2 Os.
with Ca.
I.7I
4.69
4.15
CaHPO 4
2-53
CaHP0 4 . 2 H 2
n-57
36.14
28.05
tt
21-5
(4
23 -3 1
75-95
56.53
tt
46.45
tt
39.81
139.6
97-oi
tt
89.0
11
49.76
191.0
120.7
tt
128.0
If
59-40
234.6
144.1
tt
J 59-4
ft
70-3 1
279.7
170.6
tl
190.7
tt
77.00
317.0
(174.2
(321.3
CaHP0 4 or
CaH 4 (P0 4 ) 2
226.0
122 .2
CaHP0 4 .2H,0
CaH 4 (PO ) a .H,
+
72.30
3S x "-9
301.6
CaH 4 (P0 4 ) 2
169.0
CaH 4 (P0 4 ) 2 .H 2
69.33
361 .1
289.3
tt
186.1
tt
59-98
419.7
250.2
11
267.9
tt
53-59
451 .7
223.7
it
316.1
tt
44-52
505-8
185.8
it
393-1
tt
39-89
538.3
166.4
it
437-4
"
Density of the solution in contact with both salts at 25 = i. 29.
SOLUBILITY OF Di CALCIUM PHOSPHATE IN AQUEOUS N/2oo SOLUTION
OF ACID POTASSIUM TARTRATE AT 25.
(Magnanini .)
i liter of the solution contains 0.08 gram Ca = 0.235 gram CaHPO 4 .
CALCIUM PHOSPHATE (Monobasic) CaH 4 (PO 4 ) 2 .H 2 O.
SOLUBILITY IN WATER.
This salt is stable in contact with the aqueous solution only when
there is present free phosphoric acid to the extent indicated by the
above table.
CALCIUM PEL ARGON ATE (Nonate) Ca[CH 3 (CH 2 ) 7 COO] 2 .H 2 O.
CALCIUM PROPIONATE Ca(CH 3 .CH 2 COO) 2 .H 2 O.
SOLUBILITY OF EACH IN WATER.
(Lumsden J. Chem. Soc. 81, 355, '02; Krasnicki Monatsh. Chem. 8, 597, '87.)
Calcium Pelargonate.
Grams
t. Ca[CH 8 (CH 2 )7COO]2
per loo Grams H 2 O.
o 0.16
20 0.14
40 0.13
60 0.12
80 0.15
90 0.18
100 . 26
Calcium Propionate.
Grams Ca(CH 3 .CH 2 COO) 2 per 100 Grams.
Water. Solution.
42.80 29.97
39.85 28.48
38.45 27.76
38.25 27.67
39.85 28.48
42.15 29.66
48.44 32-63
97
CALCIUM SELENATE
CALCIUM SELENATE CaSeO 4 .
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 532, '94.)
t. -i. +5. 20. 37.
Gms. per ioo gms. sol. 7.4 7.3 7.6 6.8
The accuracy of these results appears questionable.
67.
5.1
CALCIUM SILICATE CaSiO 3 .
SOLUBILITY IN WATER AND IN AQUEOUS SUGAR SOLUTIONS AT 17.
(Weisberg Bull. soc. chim. [3] 15, 1097, '96.)
The sample of calcium silicate was air dried.
Grams per ioo cc. Saturated Solution.
Solvent.
Water
10% sugar sol.
20% sugar sol.
At 17. After Boiling and Filtering Hot.
CaO(det.)
0.0046
0.0065
0-0076
CaSiO 3 (calc.)
0.0095
0.0135
0.0157
CaO(det.)
0.0094
O-OI2O
CaSiO s (calc.)
0.0195
O.O249
(JALCIUM SUCCINATE Ca(C 2 H 2 O 2 ) 2 .
CALCIUM (Iso) SUCCINATE CaCH 3 .CHC 2 O 4 .H 2 O.
SOLUBILITY OF EACH IN WATER.
(Miczynski Monatsh. Chem. 7, 261, '86.)
Calcium Succinate.
Calcium Iso Succinate.
t.
Gms.
Ca(C 2 H 2 2 ) 2
per ioo Gms.
Gms.
t o Ca(C 2 H 2 O 2 ) 2
' per ioo Gms.
Gms.
t o Ca(C 2 H 2 2 ) 2
" per ioo Gms.
Gms.
t o Ca(C 2 H 2 2 ) 2
' per ioo Gms.
H 2 0.
H 2 0.
H 2
H 2 0.
o
I.I27
50
I
.029
.522
50
O
.440
10
I .220
60
O
.894
10
O
524
60
o
396
20
I .276
70
O
.770
20
o
5*7
70
342
40
I.I77
80
657
40
o
475
80
o
279
ioo cc. H 2 O dissolve 1.424 grams succinate (CaC 4 H 4 O 4 .H 2 O) at i8 t
and 1.436 grams at 25.
ioo cc. 95% alcohol dissolve 0.00136 gram succinate (CaC 4 H 4 O 4 .
H 2 O) at 18, and 0.00136 gram at 25.
(Partheil and Hubner Archiv. Pharm. 241, 413, '03.)
CALCIUM SULPHATE CaSO 4 . 2 H 2 O.
SOLUBILITY IN WATER.
and Allen, also Euler Z. physik. Chem. 49, 313, '04. Determinations by the electrolytic conductivity
method Holleman, Kohlrausch and Rose Z. physik. Chem. 12, 129, 241, '93.)
Gms. CaSO 4
Millimols.
Density of t o
Gms. CaSO 4
Millimols
Density of
t.
per ioo cc.
Solution.
per Liter.
Solutions.
per ioo cc.
Solution.
per Liter.
Solutions.
O
0-1759
12.926
I
.00197
40
O
.2097
15
413
O
99439
10
0.1928
14.177
I
.00173
55
O
.2009
14
.765
O
,98796
18
0.2016
14.817
I
.00059
65
3 o
.1932
14
2OO
o
,98256
2 5
o . 2080
I5-295
O
.99911
75
O
.1847
13
575
o
97772
30
o . 2090
I5-36I
O
.99789
IOO
O
.1619
II
.900
35
o . 2096
I5-405
.99789
107
II
390
CALCIUM SULPHATE
98
SOLUBILITY OP CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF HYDRO-
CHLORIC, NITRIC, CHLOR ACETIC, AND FORMIC ACIDS.
(Banthisch J. pr. Chem. 29, 52, '84; Lunge J. Soc. Chem. Ind. 4, 32, '85.)
In Hydrochloric.
In Nitric. In Chlor Acetic. In Formic.
Grams Acid Grams CaSO 4 per
per 100 cc. 100 cc. Sol.
Gms. CaSO 4 per
100 cc. Solution
Gms. CaSO 4 per
100 cc. Sol.
Gms. CaSO 4 per
zoo cc. Sol.
Solution.
at 25.
at io2 6 .
at 25.
at 25.
at 25.
0.208
0.160
0.208
O.2O8
0.208
I
0.72
1.38
0.56
. . .
...
2
I .02
2-38
0.82
3
1.25
3.20
1.02
4
1.42
3- 6 4
1.20
0.22
0.24
6
I.6 S
4-65
1.48
. . .
8
1-74
1.70
. . .
10
1.84
0.25
12
. . .
...
I .08
...
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF PHOS-
PHORIC ACID AT 25.
(Taber page 61, Bull. 33, Bureau of Soils U. S. Dept. Agr., 1906.)
Gms. per Liter.
o.o
5-o
10.5
21.4
46-3
CaS0 4 .
2.126
3- I 43
3-734
4-45 6
5.760
Sp. Gr. of
Solutions at $f .
0.9991
Gms. per Liter.
Sp. Gr. of
Solutions at f .
1.106
P 2 5 .
145 - 1
CaSCV
7.920
1.002
205.0
8-383
I - I 45
1.007
I .Ol6
I -35
395-8
494.6
6.848
5-572
I .221
1.280
1-344
I -75
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF SUL-
PHURIC ACID.
(Cameron and Breazeale J. Physic. Chem. 7, 574, '03.)
Grams H 2 SCu Results
at 25.
per Liter of
Solution.
Gms. CaSO 4
per Liter.
Wt. of i cc.
Sol.
O
.00
2
.126 0.9991
grams
O
.48
2
.128
0025
n
4
.87
2
.144 ]
.OO26
a
8
.11
2
203 3
.0051
(i
16
.22
2
.382 "I
.0098
u
48
.67
2
.727
.0302
(I
75
OO
2
.841 1-0435
It
97
35
2
779 '
[-0756
(I
146
.01
2
571
ft
194
.70
2
3*3 ]
[.1134
11
243
35
I
.901 1.1418
292
.02
I
.541 1.1681
11
Results at 35.
Gms. CaSO 4
per Liter.
Results at 43.
Gms. CaSO 4
per Liter.
2-145
2.209
2.236
2.451
2.456
2.760
3.II6
3-397
3-843
4.146
3.606
3-i5o
4-139
3-55 1
2-959
. - ,
2.481
99
CALCIUM SULPHATE
SOLUBILITY OP CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF
AMMONIUM SALTS.
(In NH^Cl and NH 4 NO3, Cameron and Brown J. Physic. Chem. 9, 210, '05 ; In (NH 4 ) 2 SO 4 at 25*,
Sullivan J. Am. Chem. Soc. 27, 529, '05; In (NH 4 ) 2 SO 4 at 50, Bell and Tabor J. Physic. Chem. 10,
119, '06.)
In NH 4 C1 In NH 4 NO 3
In NH 4 C1
In NH 4 NO 3
at 25. at 25.
at 25.
at 25.
Cms. Ammo- G.CaSO 4 G. CaSO 4
nium Salt Dissolved Dissolved
Gms. Ammo- G. CaSO 4
nium Salt Dissolved
G. CaS0 4
Dissolved
per Liter. per Liter. per Liter -
per Liter. per Liter.
per Liter.
O 2 . 08 2 . 08
300 10.10
I0.8o
20 5-00 3.70
375 7-40
40 7-00 5-10
400
11-40
60 8.00 6.05
600
12.15
80 8.50 7-00
800
12.10
100 9.10 7.65
IOOO
II.Sl
150 10.30 8.88
1400
IO-O2
200 10-85 9.85
sat.
7-55
In (NH 4 ) 2 SO 4 at 25.
In (NH 4 ) 7 SO 4
at 50.
Grams per Liter Sol. \vt. of 100 cc.
Grams per Liter Sol.
Sp. Gr.
(NH 4 ) 2 S0 4 . CaS0 4 . Sat. Sol.
(NH 4 ) 2 S0 4 . CaSO 4 . '
of Solutions.
o-oo 0-208 99-91
o-oo 2.168
0.129 0-204 99-9I
15.65 1.609
.0026
0.258 0.199 99-92
30-67 1.750
.0113
0.821 0.181 99-95
91.6 2.542
.0440
1.643 0.166 99-99
160.4 3-402
.0819
3.287 0.154 100.10
221.6 4.068
.II08
6.575 0.144 100.34
340-6 5-084
1653
13.15 0.146 100.82
416.5 5-354
.1964
26.30 0.162 101.76
428.4 4-632
.2043
84.9 0.233 105.34
53O.8 2.152
1-2437
169.8 0.333 110.32
566.0 I .08
1.2508
339.6 0.450 H9-J5
566.7 o.oo
1.2510
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF
CALCIUM SALTS AT 25.
1 J. Physic. Chem. 5, 643, '01; Seldell and Smith Ibid. 8, 493, '04; Cameron
and Bell J. Am. Chem. Soc. 28, 1220, '06.)
(Cameron and Seidell
In Calcium
Chloride.
Grams per Liter Sol.
In Calcium
Nitrate.
Gms. per Liter Sol.
Wt. of
In Calcium Hydroxide and
vice versa.
Gms. per Liter Sol. Solid
CaCl 2 . ^
CaSO 4 .
Ca(N0 3 ) 2 .
CaSO 4 .
r
cc. Sol.
CaO.
CaS0 4 .
Phase.
o.oo
2
.06
O-O
2.08
O
.998
O
O
2
.126
CaS0 4 . 2 H 2
7-49
I
.24
25
1.24
I
014
.062
2
.030
**
ii .96
I
.18
50
1.20
I
.032
O
.176
I
.918
M
25-77
I
.10
100
I .13
I
.067
O
349
I
853
M
32-05
I
.08
2OO
o-93
I
137
O
.61
I.
.722
(t
51-53
I
.02
300
I
.204
o
939
j
634
it
97.02
O
.84
4OO
o-57
I
.265
I
.222
I
.588
1 CaS0..2lLO+
t Ca(OH).
192.71
47
500
0.40
I
.328
I
.242
I
.214
Ca(OH),
280.30
o
.20
544
o-35
I
352
I
.150
.666
"
367-85
03
I
.166
O
.00
M
CALCIUM SULPHATE
100
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS op
MAGNESIUM CHLORIDE AND OF MAGNESIUM NITRATE AT 25.
(Cameron, Seidell, and Smith.)
In Magnesium Chloride.
Grams per Liter of Sat. Solution.
MgCl 2 .
CaS0 4 .
H 2 6.
o.o
2.08
997-9
8.50
4.26
19.18
5.69
994-5
46.64
7-59
989.1
121.38
8.62
972.2
206.98
6-57
949-9
337-o
2-77
908.7
441.1
1.39
878.6
In Magnesium Nitrate.
Gms. per
Liter Sol. \y
t. of i cc.
>olution.
Mg(N0 3 ) 2 .
CaS0 4 .'
o.o
2 . 08 O . 998 I
25
5-77 1.0205
50
7-88 1.0398
100
9 . 9 2
.0786
200
13-34
.1498
300
14.00 1
.2190
400
14.68
.2821
5*4
15.04
3553
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF MAG-
NESIUM SULPHATE AT 25.
(Cameron and Bell J. Physic. Chem. 10, 210, '06.)
Grams per Liter Solution.
MgS0 4 .
CaSO 4 .
0-0 J
2.046
3-20 J
.620
6-39
507
10.64
.471
21.36
.478
42.68
558
64.14
.608
85.67 :
[.617
128.28 3
c .627
Sp. Gr. of
Solutions at sf.
1.0032
1-0055
.0090
-OIl8
.O226
.0419
.0626
0833
.II9O
Grams per Liter Solution.
Sp. Gr. of
MgS0 4 .
149.67
l6 5-7
CaS0 4 .
i-597
1-549
Solutions at i
I-I377
I. 1479
171 .2
198.8
1.474
i .422
I - I 537
1.1813
232.1
265.6
298.0
330-6
1.254
1.070
0.860
0.647
1.2095
1.2382
i .2624
1.2877
355-o
0.501
1-3023
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF POTAS-
SIUM CHLORIDE, BROMIDE, AND IODIDE AT 21.
(Ditte Ann. chim. phys. [7] 14, 294, '98.)
In KC1 Solutions. In KBr Solutions. In KJ Solutions.
Grams of the
Potassium Salt
per Liter.
Gms. CaSO 4
per Liter.
O
10
2.05
3-6
20
40
60
4-5
5-8
6.6
80
7-2
100
I2 5
7-5
double salt
200
250
300
Gms. CaSO 4
per Liter.
2.05
3-i
3-6
4-5
5- 2
5-9
6-3
6.7
7-o
7-3
double salt
Gms. CaSO 4
per Liter.
2.O5
2.8
3- 2
3-9
4-5
4-85
5- 1
5-45
5-8
5-95
6.00
double salt
101
CALCIUM SULPHATE
SOLUBILITY OP CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF POTAS-
SIUM NITRATE AND OF POTASSIUM SULPHATE AT 25.
(Seidell and Smith J. Physic. Chem. 8, 493, '04; Cameron and Breazeale 7Wd.8, 335, '04.)
In Potassium Nitrate. In Potassium Sulphate.
Gms. per Liter
Solution.
Wt.of ice.
Solution.
KN0 3 . CaS0 4 .
o-o 2.08
0.9981
12-5 3.28
I .0081
25.0 4-08
I.OI54
50.0 5.26
I.032I
ioo. o 6.86
I .0625
150 7.91
1.0924
200 8.69
I .1224
260 syngenite
I-I539
Gms. per
Solutior
" ter v
ft. of i cc.
Solution
K 2 S0 4 . (
: a so 4 .
0-0 J
z.o8 <
5.9981
4.88
.60 3
.0036
5-09
.56 ]
.0038
9-85
45 J
.0075
19-57
49
.0151
28-35
55 J
.0229
30-66
57
.0236
32-47
.58*
* Solid phase syngenite. Results for the solubility of syngenite in solutions of potassium sulphate are
also given in the original paper.
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF
SODIUM CHLORIDE AT 26.
(Cameron J. Physic. Chem. 5, 5
phys. chem. Ges. 37. 949. '02
372, '03.)
Grams per ioo cc. Solution.
[56, '01; see this pa]
; Cloez Bull, soc
Wt. of i cc.
Solution.
0.9998
I . 0644
1.0981
I .IOI2
>er for references to other work, a
. chim. [3] 29, 167, '03; d'Anse
Grams per ioo cc. Solution.
IsoOrloff T.russ-
Ime Ibid. [3] 29*
Wt.of ice.
Solution.
1.1196
I.I488
I.I707
1.2034
NaCl.
0-00
9-II5
14-399
14.834
CaSO 4 .
O.2I2I
0.666
0.718
0.716
' NaCl.
17.650
22.876
26.417
32.049
CaS0 4 . '
0.712
0.679
0-650
0.572
SOLUBILITY OF MIXTURES OF CALCIUM SULPHATE AND CALCIUM CAR-
BONATE IN AQUEOUS SOLUTIONS OF SODIUM CHLORIDE AT 23.
(Cameron and Seidell J. Physic. Chem. 5, 643, '01.)
Grams per Liter Solution. Grams per Liter Solution.
NaCl.
Ca(HC0 3 ) 2 .
CaSO 4 .
o.oo
0.060
1-930
3-63
0.072
2.720
11.49
0-089
3-446
39.62
O-IOI
5-I56
NaCl.
Ca(HC0 3 ) 2 .
CaSO 4 .
79-52
O.o6o
6.424
121 .90
0.056
5.272
193.80
0-048
4-786
267 .60
O.O4O
4.462
SOLUBILITY OF MIXTURES OF CALCIUM SULPHATE AND SILVER SUL-
PHATE IN WATER.
(Euler Z. physik. Chem. 49, 313. '04.)
...
Per Liter
of Solution.
Total Salt
per ioo Gms.
Solution.
Sp. Gr. of
Solutions.
Gms. Salt.
Gms. Equiv.
Salt.
^ojCaSO,
2.31
7-235
0-034
0-0464
Q-9473
1.0083
jCaS0 4
25 Ug 8 S0 4
2.61
8. ii
0.0383
O.O52O
1.062
1. 010
CALCIUM SULPHATE
102
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SOLUTIONS OF
SODIUM NITRATE AND OF SODIUM SULPHATE AT 25.
(Seidell, Smith, Cameron, Breazeale.)
In Sodium Nitrate. In Sodium Sulphate.
Grams per Liter Solution. \\TJ of i cc Grams per Liter Solution. \Vt. of i cc.
NaNO 3 . CaSO 4 . Solution. Na;zSO 4 . CaSO 4 . Solution.
o 2.08 0.9981 2.39 1.65 1.0013
25 4.25 1.0163 9.54 1-45 1.0076
So 5-50 1-0340 14-13 J -39 1-0115
ioo 7.10 1.0684 24.37 1.47 1.0205
2OO 8.79 1.1336 46.I5 1-65 I.O39I
300 9.28 1.1916 115.08 2.10 1-0965
600 7.89 i-3 6 39 146.61 2.23 1.1427
655 7.24 L3904 257.10 2.65 1. 2120
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS AND ALCOHOLIC
MONO POTASSIUM TARTRATE SOLUTIONS AT 20.
(Magnanini Gazz. chim.ital.3i, II, 544, '.)
Gms. CaSO 4 Gms. CaSO. 4
Solvent. per ioo Gms. Solvent. per ioo Gms.
Solution. Solution
Water 0.2238 10% alcoholic N/ 2 oo KHC 2 H 4 O 6 0.0866
Aq. N/200 KHC 4 H 4 O. o . 2323 Aq. N/2OO KHC 2 H 4 O 6 + 5%
10 per cent alcohol 0.0970 tartaric ac. 0.2566
10% ale. N/400 KHC^Os + 5%
tartaric ac. 0.1086
SOLUBILITY OF CALCIUM SULPHATE IN AQUEOUS SUGAR SOLUTIONS.
(Stolle Z. Ver. Zuckerind. 50, 331, 'oo.)
Per cent Concen- Grams CaSO 4 Dissolved by i Liter of the Sugar Solutions at:
tration of Sugar
Solutions.
O
10
20
27
35
42
49
55
CALCIUM SULPHIDE CaS.
SOLUBILITY IN AQUEOUS SUGAR SOLUTIONS.
(Stolle.)
r
30.
40.
50.
60.
70.
80.
2
J 57
i
730
' i
730
i
.652
i
,710
2
.041
I
730
i
730
i
574
i
574
i
,613
I
.808
I
.652
i
.419
i
.380
i
.419
i
.263
I
550
I
438
i
.361
i
-283
i
.283
972
I
.263
I
050
i
.088
i
.108
.914
I
.030
777
o
.816
855
o
.729
564
739
o
5 6 4
.603
o
486
.486
505
.486
3 6 9
0.330
Per cent Concen-
Grams CaS Dissolved per Liter of the
JL
Sugar Solutions at:
tration ot ougar f
Solutions.
30.
4 o.
50.
60. 70.
80.
90.
O
i
.982
2 .123
I
235
I
390
I
.696
2.032
2.496
10
i
.866
1.316
I
.441
I
673
I
.560
1.634
1-544
20
2
.187
1.696
I
.802
I
905
I
.879
1.892
1.930
27
2
522
2.097
2
059
a
.226
2
342
2.304
2-357
35
2
.689
2.265
2
304
2
.406
2
342
2-857
2-947
42
2
342
2.136
2
.226
2
.522
2
574
2.509
2.689
49
2
445
2.290
2
458
2
.638
2
.728
2.818
3-063
55
2
509
2 .226
2
"340
2
.882
2
.766
2.972
3.616
103 CALCIUM SULPHITE
CALCIUM SULPHITE CaSO,.
SOLUBILITY IN WATER AND IN AQUEOUS SUGAR SOLUTIONS AT 18.
(Weisberg Bull. soc. chim. [3] 15, 1097, '96.)
Grams CaSO 3 per 100 cc. Solution.
Solent. ' . R0 After Boiling
Solution 2 Hours.
Water 0.0043
10 Per cent Sugar 0-0083 0.0066
30 Per cent Sugar o . 0080 o . 0069
CALCIUM TARTRATE CaC 4 H 4 O 6 .4H 2 O.
SOLUBILITY IN WATER.
(Cantoni and Zachoder Bull. soc. chim. [3] 33, 747, '05.)
t o Gms. CaC 4 H 4 O 6 .4HjO t o Gms. CaC^Qj -411,0 t o Gms. CaC^Oa.^sO
per 100 cc. Sol. per 100 cc. Sol. per 100 cc. Sol.
o 0.0365 30 0.0631 70 0.1430
10 0.0401 40 0-0875 80 0.1798
20 0.0475 5 o.noo 85 0.2190
25 0.0525 60 0.1262
ioo gins. aq. Ca. tartrate solution contain 0.0185 g. CaC 4 H 4 O 6 .4H 2 O
at 18, and 0.029489 at 25.
ioo gms. 95% alcohol solution contain 0.0187 g. CaC 4 H 4 O 6 .4H 2 O at
l8, and 0.02352 at 25. (Partheil and Hiibner Archiv. Pharm. 241, 413, '03.)
ioo gms. aq. Ca. tartrate solution contain 0.0364 g. CaC 4 H 4 O 6 at 20.
ioo gms. 10% alcohol solution contain 0.0160 g. CaC 4 H 4 O 6 at 20.
ioo gms. 10% alcohol 4- 5% tartaric acid solution contain 0.1632 g.
CaC 4 H 4 O 6 at 20 . (Magnanini Gazz. chim. ital. 31, II, 544, '01.)
SOLUBILITY OF CALCIUM TARTRATE IN AQUEOUS ACETIC ACID
SOLUTIONS AT 26-27.
(Herz and Muhs Ber. 36, 3715, '03; see also Enell Pharm. Centrallh. 38, 181; Z. anal. Chem. 38,
368, '99.)
Normality of Gms.CH 3 COOH Residue from Normality of Gms.CH 3 COOH Residue from
Acetic Acid. per ioo cc. Sol. 50x552 cc. Sol. Acetic Acid, per ioo cc. Sol. 50.052 cc. Sol.
o o 0.0217 3 .80 22.80 0.2042
0.57 3.42 0.1082 5.70 34-20 0.1844
I -42$ 8.55 0.1635 10.09 60.54 0.1160
2.85 17.10 0.1970 16.505 93.03 0.0337
The residue was dried at 70 C.
CALCIUM BITARTRATE CaH 2 (C 4 H 4 O 6 ) 2 .
SOLUBILITY IN WATER AND IN AQUEOUS SOLUTIONS OF ACIDS AND
OF SALTS.
(Warington J. Chem. Soc. 28, 946, '75.)
In Hydrochloric Acid. In other Acids and in Salt Solutions at 14.
CO Gms f p?r CI G.n Acid or Salt Gms. Acid or Salt Gms. CaH 2 (C 4 H 4 O 6 ) a
ioo Gms. Sol. "At 22. ' At So / ^ I0 C ' S L *** IO CC - SoL
o 0.600 4.027 Acetic Acid 0.81 0.422
0.68 3-01 5-35 Tartaric Acid 1.03 0.322
2.15 6.88 n-35 Citric Acid 0.84 0.546
4.26 11.19 20.23 Sulphuric Acid 0.685 1.701
8.36 22.75 4 -93 Hydrochloric Acid 0.504 1-947
16.13 48-31 80.12 Nitric Acid 0.845 1.969
Potassium Acetate i . 387 o . 744
Potassium Citrate 1.397 0.843
CALCIUM VALERATE
104
CALCIUM VALERATE Ca[CH 3 (CH 2 ) 3 COO] 2 .H 2 O.
CALCIUM (Iso) VALERATE Ca[(CH 3 ) 2 .CH.CH 2 .COO] 2 . 3 H 2 O.
SOLUBILITY OP EACH IN WATER.
(Lumsden T. Chem. Soc. 81. 355, '02: see also Furth Monatsh. Chem. 9, 313, '88; Sedlitzky
/Wd,8, 566, '87.)
Calcium Valerate.
Gms. Ca(C5H 8 C>2)2
t* per TOO Gms. 40.
Calcium Iso Valerate.
Gms. Ca(C 5 H 9 2 ) 2 ...
per 100. Gms. Solid
Water.
Solution.
Water.
Solution.
O
9
.82
8
94
26
05
20
.66 Ca(C 5 H 9 O 2 ) 2 .
10
9
25
8
47
10
22.7O
18
5
20
8
.80
8
.09
2O
21
.80
17
.90
30
8
.40
7
75
30
21
.68
17
.82
40
8
05
7
45
40
22
.00
18
.18
50
7
85
7
.28
45-5
22
35
18
.42 "
57
7
75
7
.19
50
19
95
16
.63 Ca(C 5 H 9 2 ) 2 .
60
7
.78
7
.22
60
18
38
15
52
70
7
.80
7
.24
70
17
.40
14
.82
80
7
95
7
36
80
16
.88
14
44 "
90
8
.20
7
58
90
16
65
14
.28
100
8
.78
8
.07
100
16
55
14
.20
CAOUTCHOUC.
SOLUBILITY IN ORGANIC SOLVENTS.
(Hanausek J. pharm. chim. [5] 15, 509, '87.)
Grams. Caoutchouc Dissolved per 100 Gms. Solvent.
Ceara.
Tete Noire.
Sierra Leone.
2-5
3-6
4-5
4-5
5-o
4.6
3-o
3-7
3 -
i .5
4-5
4-0
4-4
5-
4-7
0.4
o.o
o.o
Solvent.
Ether
Turpentine
Chloroform
Petroleum
Benzene
Carbon Bisulphide
CAMPHORIC ACID C 8 H 14 (COOH) 2 .
100 grams of water dissolve 0.8 gram C 8 H 14 (COOH) 2 at 25, and 10
grams at the b. pt. (U.S. P.)
CARBAZOLE (Di Phenylene imid) (C 6 H 4 ) 2 NH.
100 grams abs. alcohol dissolve 0.92 gms. (C 6 H 4 ) 2 NH at 14, and
3.88 grams at b. pt.
100 grams toluene dissolve 0.55 gm. (C 6 H 4 ) 2 NH at 16.5, and 5.46
grams at b. pt.
CARBAMIDES.
* SOLUBILITY IN SEVERAL SOLVENTS.
as Methyl Phenyl Carbamide (m. pt. 82), Benzyl Carbamide (m. pt.
149). o Tolyl Carbamide(m.pt. 185) and Tolyl Carbamide (m.pt. 173).
(Walker and Wood J. Chem. Soc. 73, 626, '08.)
Grams Carbamide per 100 cc. Sat. Solution.
aoivem.
i
as
Methyl
Phenyl.
Benzyl.
P Tolyl.
Tolyl.
Water
45
74
j
71
O
307
o
.251
Acetone
23
29.
4
3
.10
2
.66
O
.462
Ether
22
5
2 .
28
o
053
.062
O
.Ol62
Benzene
44
.2
12 .
4
0597
O
043
0155
CARBON DIOXIDE
V .
3.
ft.
i.
0-335
1 -7*3
5
0.277
1.424
10
0.231
1.194
15
0.197
i .019
1.070
20
0.169
0.878
. . .
25
0.145
0-759
0.826
30
0.126
0.665
40
0.097
0-530
50
0.076
0.436
60
0.058
0-359
In 17.62%
NaCl.
CARBON DIOXIDE CO 2 .
SOLUBILITY IN WATER AND IN AQUEOUS SODIUM CHLORIDE SOLUTIONS.
(Bohr Wied. Ann. Physik. [3] 68, 303, '99; Geffcken Z.physik.Chem. 49, 271, '04; Just Ibid.
37, 354, *oi-)
Solubility in Water. ^tci^
"ft.
0.675
0-577
0-503
0.442
o-393
0-352
0.319
0.263
0-235
ft.
1.234
1.024
0.875
o-755
0.664
0-583
0-5*7
0.414
0.370
0-305
183
q *= wt. of gas dissolved by i oo grams of solvent at a total pressure of 7 60 mm.
p = the Bunsen Absorption Coefficient which signifies the volume (v) of
the gas (reduced to o and 760 mm.) taken up by unit volume (V) of the liquid
when the pressure of the gas itself minus the vapor tension of the solvent is
760 mm. _ v
* = V(i + 0.00367 i) '
I = the Ostwald Solubility Expression which represents the ratio of the
volume (v) of gas absorbed at any pressure and temperature, to the volume
(V) of the absorbing liquid, i.e. / = p This expression differs from the
Bunsen Absorption Coefficient, p, in that the volume (v) of the dissolved gas
is not reduced to o and 760 mm. The solubility / is therefore the volume
of gas dissolved by unit volume of the solvent at the temperature of the
experiment. The two expressions are related thus:
/ = p (i + 0.00367 /), p = - ; .
(i + 0.00367 /)
SOLUBILITY IN WATER AT PRESSURES ABOVE ONE ATMOSPHERE.
(Wroblewski Compt. rend. 94, 1335, '82.)
^Pressure
in Atrnos-
Coefficient of Saturation * at:
Pressure
in Atmos-
Coefficient of Saturation * at :
pheres. - 12.4.
pheres.
o .
12.4.
I
1-797 I
.086
2O
21
65
17.11
5
8.65
5
.15
25
30
55
20.31
10
16.03
9
65
30
33
74
23-25
* Coefficient of Absorption is no doubt intended.
SOLUBILITY OP CO 2
IN AQUEOUS
SOLUTIONS OP ACIDS AND
SALTS
(Geffcken.)
Aq.
Cms
Acid C0 2 Dissolved, / at:
Aq.
Cms
Salt
COa Dissolved, / at:
Solvent.
per Liter.
15.
25.
Solvent.
per Liter.
15.
25
HC1
18
23
043
0.8o6
CsCl
8 4
17
I
.006
O
.781
"
36
.46
.028
o-799
KC1
37
30
.976
759
(4
72
.92
coo
o-795
KC1
74
.60
O
.897
.700
HNO S
3i
52
.078
0.840
KI
83
.06
.992
775
*
63
.086
0-853
KI
166
.12
923
727
"
126
.10
.100
0.877
KBr
59
55
.986
o
.768
H0 t
24
5 2
.018
0.794
KBr
119
.11
.914
7i3
tt
49
.04 0.978
0.770
KN0 3
50
59
' I
005
.784
tt
98
.08 0-917
0.730
KNO 3
IOI
.19
946
o
749
t(
147
.11 0.870
0.698
RbCl
60
47
.989
o
.769
tt
196
.15 0.828
0.667
RbCl
120
95
o
.921
o
.788
CARBON DIOXIDE 106
SOLUBILITY IN AQUEOUS SOLUTIONS OP SALTS.
(Mackenzie Wied. Ann. Physik. [2] i, 450, '77.)
Salt in
Solution.
Gms. Salt per
zoo Gms. Solution.
Density of
Solution 15.
Absorption Coefficient a at:
' 8. i S . 22 r
KC1
6.05
I .021
0.988 0.777 0.670
it
8.646
1-053
0.918 0.777 0.649
"
11.974
I .080
0.864 0.720 0.597
"
22 .506
1-549
0-688 0.571 0.480
NaCl
7-062
1.038
0-899(6.4) 0-735
M
12.995
1.080
0-633(6.4) 0.557 0.482
"
17.42
1.123
0.518(6.4) 0.431 0.389
"
26.00
0-347(6-4) 0-297 0.263
NH 4 C1
6.465
1. 021
1.023 0-825 0.718
"
8.723
1-047
i .000 0.791 0.702
"
12.727
1-053
0.922 0.798 0.684
"
24-233
1.072
0.813(10) 0.738 0.600
8. l6.S. 22. 30.
BaCI,
7.316
i. 068
0-969 O-744 O-68O 0.566
"
9-753
i .092
I- O2 I O.645 O.6O7 0.543
"
14.030
i .137
0.618 0.524 0.467
u
25 215
1.273
0.495 0-618 0.383 0.315
SrCL,
9-5 11
1.087
0.779 0-663 0.581 0.508
tt
12-325
1.1159
o-737 0.586 0.507 0.539
tl
I7-7I3
i .173
0-606 0.473 0.444 0.367
11
3 I - I 94
1-343
0.285 0.245 0.247 0.223
CaCL,
4-365
1.036
0-942 0-759 0.673 0.596
"
5-739
1.049
0-855 0.726 0-616 0.527
H
8.045
i. 068
0-838 0-674 0.581 0.500
"
15-793
I - I 39
0.632 0.520 0.471 0.400
SOLUBILITY OF CARBON DIOXIDE IN ALCOHOL.
(Bohr Wied. Ann. Physik [4] i, 247, 'oo.)
In 99 per cent Alcohol. In 98.7 per cent Alcohol.
cc. CC>2 (at o and 760 mm.) per i cc. cc. CO2 (at o and 760 mm.) per i cc.
Alcohol. Sat. Solution.
Alcohol. Sat. Solution.
-65
38-41
35-93
39.89
37.22
2O
7-5i
7.41
7-25
7.16
10
5-75
5-69
5-43
5-38
o
4-44
4.40
4-35
4-3i
+ 10
3-57
3-55
20
2.98
2 .96
25
2.76
2-74
30
2-57
2.56
...
...
40
2.20
2 .19
45
2.01
2.00
...
...
107 CARBON DIOXIDE
SOLUBILITY IN AQUEOUS ALCOHOL AT 20.
(Muller Wied. Ann. Physik. [2] 37t 39. '89; Lubarsch Ibid. [2] 37, 525, '89.)
Density of Per cent Alcohol Abs. Coef.
Density of Per cent Alec
Alcohol.
By Wt.
Of CO2, *.
Alcohol.
By Wt.
0-998
1.07
0.861
0.922
49-o
0-969
22 .76
0.841
0-870(18.8)
71.1
0-960 (22.4)
28.46
0.792
0.835(16)
85-3
0.956
3 I - I 7
0.801
o-79S to )
99-7
0-935(17)
42.15
0.877
Of C0 2) a.
0.982
1.293
1-974
2.719
SOLUBILITY OF CARBON DIOXIDE IN ORGANIC SOLVENTS.
(Just Z. physik. Chem. 37t 354. *oi.)
Sol . of CO 2 , Ostwald Expression * Sol . of CO 2 , Ostwald Expression *
Solvent. > Solvent.
aoiveni.
IK-
ISO-
/15-
/26-
fe.
/i*.
CS 2
.870
.889
945
C 3 H 7 OH 2
.498
C.H.NH,
I
324
1
434
i
531
C 2 H 5 OH( 95 %) 2
-706
2
923
3-I30
C.HUOH
I
8 3 I
i
.941
2
.058
C 6 H 5 COH
.841
3
057
3-304
C 6 H 5 Br
I
.842
i
.964
2
.092
CHClg 3
-430
3
.681
3-958
CC1 4
2
.294
2
.502
2
.603
CH 3 OH 3
837
4
.205
4-606
G^CEt,
2
305
2
.426
2 ,
557
CHjCOOH 4
691
5
.129
5.614
C.H.
2
425
2
540
2 .
716
(CH 3 CO) 2 5
.206
5
.720
6.18
C.H.NO,
2
45 6
2
655
2 .
845
(CH 3 ) 2 CO 6
295
6
.921
* See p. 105.
Determinations are also given for the solubility in glycerine, iod
benzene, o and m toluidine, eugenol, benzene tri chloride, cumol,
carvene, di chlor hydrine, iso butyl alcohol, benzyl chloride, meta xylol,
ethylene bromide, chlor benzene, propylene bromide, amyl bromide,
carvol, amyl chloride, iso butyl chloride, butyric acid, ethylene chloride,
pyridine, amyl formate, propionic acid, amyl acetate, iso butyl
acetate, and in methyl acetate.
See Woukoloff Compt. rend. 108, 674; 109, 62, '89, for the solubility
of CO 2 in CS 2 and CHC1 3 at different pressures.
CARBON MONOXIDE CO.
SOLUBILITY IN WATER.
(Winkler Ber. 34, 1416, '01.)
t.
ft, "Absorp,
Coef."
. *
1', " Solu-
bility."
t.
/3
, "Absorp.
Coef."
ft
:', "Solu-
bility."
9-
o
0-03537
0.03516
.0044
40
01775
01647
0.0021
5
0.03149
O
.03122
O
0039
50
.01615
O
.OI42O
0-OOlS
10
O.O28l6
O
.02782
o
0035
60
O
.01488
O
OII97
O.OOI5
15
0.02543
o
.02501
.0031
70
o
.OI44O
o
00998
O.OOI3
20
0-02319
o
.O2266
o
.0028
80
o
01430
o
.00762
O-OOIO
25
0.02142
o
.02076
.0026
90
o
.OI42O
.00438
0.0006
30
0.01998
o
.01915
o
.0024
100
.01410
o
OOOOO
o.oooo
/? = vol. of CO absorbed by i volume of the liquid at a partial pres-
sure of 760 mm. See page 105.
/8' = vol. of CO (reduced to o and 760 mm.) absorbed by i volume
of the liquid under a total pressure of 760 mm.
q = grams of CO dissolved by 100 grams H 2 O at a total pressure of
760 mm.
CARBON MONOXIDE
1 08
SOLUBILITY OF CARBON MONOXIDE IN AQUEOUS ALCOHOL SOLUTIONS
AT 20 AND 760 MM. PRESSURE.
(Lubarsch Wied. Annalen Physik. [2] 37, 525, '89.)
Wt.% Alcohol. Vol.% Absorbed CO. Wt.% Alcohol. Vol. % Absorbed CO.
o-oo
9-09
16.67
23.08
2.41
1-87
J-75
1.68
28.57
33-33
50.00
1.50
!-94
3.20
SOLUBILITY OP CARBON MONOXIDE IN ORGANIC SOLVENTS.
(Just Z. physik. Chem. 37, 361, 'or.)
Results in terms of the Ostwald Solubility Expression, see p. 105.
Solvent.
/25.
/20.
Solvent.
/25.
/
20-
Water
. 02404
.02586
Toluene
0.
1808
0.
1742
Anilin
05358
o
555
Ethyl Alcohol
0.
1921
0.
IOOI
Carbon Bisulphide
.08314
.08112
Chloroform
0.
1954
o.
1897
Nitro Benzene
.09366
.09105
Methyl Alcohol
0.
1955
0.
1830
Benzene
o
.1707
o
.1645
Amylacetate
o.
2140
o.
2108
Acetic Acid
.1714
.1689
Acetone
0.
2225
0.
2128
Amyl Alcohol
.1714
o. 1706
Iso Butyl Acetate
0.
2365
0.
2314
Xylene
o
.1781
1744
Ethyl Acetate
0.
2516
0.
2419
ioo volumes of petroleum absorb 12.3 vols. CO at 20, and 13.4 vols.
at 10.
(Guiewasz and Walfisz Z. physik. Chem. I, 70, '87.)
SOLUBILITY OP CARBON MONOXIDE IN MIXTURES OF ACETIC ACID AND
OTHER SOLVENTS AT 25.
(Skirrow Z. physik. Chem. 41, 148, '02.)
Results in terms of the Ostwald Solubility Expression, see p. 105.
Mixture of
Acetic Ac. and
/<
7 V^AJ.
inM
ixture.
CO.
!
' By Wt.
By Vof.
Anilin
IOO
.0
IOO
.0
o
173
tt
86
5
90
.8
.110
"
58
3
68
5
o
.070
"
13
.8
25
.1
o
.058
"
o
O
053
Benzene
67
5
63
4
o
.199
tt
33
.6
29
.6
.198
tt
19
.2
16
5
.190
"
.0
o
o
.174
Mixture of
Acetic Ac. and :
% CH 3 COOH
in Mixture.
CO.
ByWt.
By
Vol.
Chloroform
56
4
64
.5
o
.196
11
O
.0
.0
.206
Nitro Benzene
88
4
84
.8
o
.156
tt
49
.0
66
3
.130
tt
o
.0
.0
093
Toluene
74
7
7i
.0
.191
tt
56
9
52
.6
195
fl
20
5
17
.8
o
.190
tt
.0
.182
109
CARBON MONOXIDE
SOLUBILITY OP CARBON MONOXIDE IN MIXTURES OF ACETONE AND
OTHER SOLVENTS AT 25.
(Skirrow.)
Mixture of %(CH 3 ) 2 CO in Mixture. CO.
Acetone and: By Wt. By Vol. fcs-
Mixture of
Acetone and:
%(CH 3 ) 2 CO in
Mixture.
CO.
7_.
By Wt. By Vol. '"'
Anilin
100.0
IOO.
o
o.
238
Chloroform
66.
6
78.
9
0.226
"
79.2
85.
9
0.
179
"
26.
5
40.
4
0.212
"
44.9
56.
7
0.
no
11
o.
O.
o
0.207
"
O.O
0.
0.
053
ft Naphthol
86.
93-
9
0.190
Carbon Bisulphide
82.0
83.
8
o.
236
"
73-
i
87-
i
0.169
"
50-5
61.
8
0.
227
Nitro Benzene
78.
4
88.
5
0.207
u
26.0
35-
7
o.
187
tt
46.
8
69.
5
- I 57
H
*4- 5
21.
2
0.
144
"
o.
0.
0.090
tt
0.0
O.O
0.
096
Phenanthrene
87-
2
95-
4
0.205
Naphthalene
86.7
93-
5
0.
199
"
75-
90.
2
0.183
'*
72.6
85-
4
o.
187
SOLUBILITY OF CARBON MONOXIDE IN MIXTURES OF BENZENE AND
OTHER SOLVENTS AT 25.
(Skirrow Z. physik. Chem. 41, 144, '02.)
The solubility of the CO given in terms of the Ostwald Expression,
see p. 105.
Mixture of
Benzene and:
%C6H 6 in
Mixture.
CO.
}~,
Mixture of
Benzene and:
%C 6 H 6 in
Mixture.
CO.
By Wt.
By Vol.
ByWt
. By Vol.
Naphthalene
100.0
IOO.
o
.174
Anilin
87.
3
89.1
.156
"
88.5
92.
6
.164
"
71-
7
75-2
131
"
66.2
76.
3
.141
tt
42.
6
47.0
095
Phenanthrene
89.2
95-
i
0.144
tt
21.
2
24-3
.068
"
72.6
8
0.127
O.
O
O.O
053
a Naphthalene
96-5
98.'
i
.149
Nitro Benzene
71.
8
80. 1
152
"
87.9
93-
i
139
"
45.
i
5 6 -4
o
.127
Ethyl Alcohol
47-7
44-
9
o
.181
H
O.O
O.O
093
O.O
0.
o
.192
SOLUBILITY OF CARBON
MONOXIDE IN MIXTURES
OF
TOLUENE
AND
OTHER
SOLVENTS AT 25.
(Skirrow.)
Mixture of
5 CH 3 in
ture.
1 CO.
/
Mixture of
Toluene mid*
%CoHsCH3 in
Mixture.
CO.
/.
Toluene and:
B'y Wt.
By Vol.
*zo
'By Wt.
By Vol.
*O*
Anilin
100.0
IOO-O
.182
a Naphthol
95-
5
97-1
.171
tt
94-4
93
5
.169
u
2
94-2
l62
"
80. i
80-3
.148
Nitro Benzene
81.
7
85-7
.160
tt
55-4
55-6
o
.115
tt
5-
8
58.1
o
131
"
25-4
25.6
o
.077
"
23-
7
29-3
o
.108
tt
o.o
o
053
"
o.
o
O-O
093
Naphthalene
92.9
94
.8
.169
Phenanthrene
94-
4
97.0
.170
"
84.9
88
7
.161
tf
88.
8
93-9
.l6l
"
77-3
82
5
.153
"
78.
4
87.5
.147
CARBON MONOXIDE no
SOLUBILITY OF CARBON MONOXIDE IN MIXTURES OF ORGANIC
SOLVENTS AT 25.
(Skirrow.)
Mixture Composed of: % of Latter in Mixture. C O.
By Wt. By Vol. fee-
Chloroform and Methyl Alcohol o . o o . 207
" " 13-0 0.202
" " 100 0.196
Carbon Bisulphide and Ethyl Di Chloride 100 o . 147
75 0.157
51 0.160
18.4 0.140
o.o 0.083
Methyl Alcohol and Glycerine o.o o.o 0.196
39.6 30.1 0.096
" " 60.5 50.1 0.052
77.1 68.9 0.025
" " 100. o 100. o very small
NOTE. From the results shown in the preceding five tables, it is
concluded that the solubility of carbon monoxide in various mixtures
of organic solvents is, in general, an additive function.
CARBON BISULPHIDE CS 2 .
SOLUBILITY IN WATER.
(Chancel and Parmentier Compt. rend. 100, 773, 85; Rex Z. physik. Chem. 55, 355, '06.)
Grams CSg per 100 Grams CS2 pe 1 100
** cc. Solu- Cms. H 2 O t . cc. Solu- Gms. H 2 O
tion. (Rex). tion. (Rex).
o 0.204 0.258 30 0.155 0.195
5 - I 99 35 o- x 37
10 0.194 0.239 40 o.in
15 0.187 ... 45 0.070
20 0.179 o.ioi 49 0.014
25 0.169
100 cc. H 2 O dissolve o.i 74 cc. CS 2 at 22; Vol. of solution = 100.208,
Sp. Gr. = 0.9981.
100 cc. CS 2 dissolve 0.961 cc. H 2 O at 22; Vol. of solution= 100.961,
Sp. Gr. = 1.253. (Herz Ber. 31, 2670, '98.)
SOLUBILITY OF CARBON BISULPHIDE IN:
Aq. Solutions of Ethyl Alcohol at 17. Methyl Alcohol.
(Tuchschmidt and Folleuins Ber. 4, 583, '71.) (Rothmund Z. physik. Chem. 26, 475, '08.)
Wt. per Gms. CS2 Wt. per Gms. CS 2 Wt. per centCS 2 in:
cent per 100 cc. cent per 100 cc. t . CHaOH GST" 1
Alcohol. Solvent. Alcohol. Solvent. Lajer. La7 er .
loo oo 91.37 50 10 45-i 9 8 -3
98.5 l82 84.12 30 20 50.8 97.2
98.15 132 76.02 20 25 54.2 96.4
96.95 100 48.40 2 30 58.4 95.5
93-54 7o 47-90 o 35 64.0 93.5
40.5 (crit. temp.) 80.5
Ill
CARBON OXYSULPHIDE
SOLUBILITY OP CARBON OXYSULPHIDE IN WATER.
(Winkler; see Landolt and Bernstein's Tabellen, sd ed. p. 602, 1906.)
O
5
10
15
1-333
i .056
0-835
0.677
0-356 20 0.561 0.147
0.28l 25 0.468 0.122
O-22I 3O 0.403 O.IO4
0-179
For /3 and q see Carbon Dioxide, page 105.
CARBON TETRACHLORIDE. See p. 201.
CARVOXIME C 10 H 4 :NOH.
SOLUBILITY IN r LIMONENE.
(Goldschmidt and Cooper Z. physik. Chem. 26, 714, '98.)
Gms. CinH:NOH
Gms. CioHUiNOH
t .
per 100 Gms.
Solid Phase.
t.
per 100 Gms.
Solid Phase.
r Limonene.
r Limonene.
24.6
44-6
/ Carvoxime
4 8
198.7
/ Carvoxime
30.0
59-2
/ Carvoxime
49-4
199.7
r Carvoxime
30-3
63-3
r Carvoxime
55-4
325-I
' I Carvoxime
38.4
104.3
/ Carvoxime
55-9
346.6
r Carvoxime
39-4
103.1
r Carvoxime
58.8
560-0
r Carvoxime
43 - 1
130.8
/ Carvoxime
63.2
126.93
r Carvoxime
CERIUM ACETATE, BUTYRATE, FORMATE, etc.
SOLUBILITY IN WATER.
(Wolff Z. anorg. Chem. 45, 102, '05.)
Grams Anhydrous Salt per 100 Gms. Solution at:
Salt.
Acetate
Butyrate
Iso Butyrate
Formate
Propionate
Formula.
Ce(C 2 H 3 2 ) 3 .i$H 2
Ce(C 4 H 7 2 ) 3 , and 3 H 2
Ce(C 4 H 7 2 ) 3 . 3 H 2
Ce(CH0 2 ) 3
Ce(C 3 H 5 O 2 ) 3 .H 2 O, an
3-544
15
19.61
3.406
6.603(20.4)
18.99
76.
12.97
1.984
3-39
0-374(75-3)
15-93
CERIUM AMMONIUM NITRATE (Ceri) Ce(NO 3 ) 4 .2NH 4 NO 3 .
SOLUBILITY IN WATER.
(Wolff.)
f.
Gms. per 100 Gms.
Solution.
*
Atomic Gms.Ce(N0 3 )4.2NH 4 NO 3
Relation. per 100 Gms.
NIL,.
Ce.
NIL, : Ce.
Solution. Water.
25
4.065
15.16
2.08
i
58.49 140.9
35-2
4-273
16.10
2 .06
i
61.79 161.7
45-3
4.489
16.69
2.08
i
64.51 174.9
64-5
4.625
(i7-4oCe
( 15. 03 Ce IV
2.06
2-39
LCe
iCelV
66.84 201.6
85.6
4 .7 7 8
(i8.i6Ce
1 15 -79 Ce IV
2 .04
2-34
i Ce
iCe IV
69.40 226.8
22.82 Ce
2.08
iCe
112
.117
i6.22CeIV
2-95
iCelV
88-03 735-4
CERIUM AMMONIUM NITRATE 112
CERIUM AMMONIUM NITRATE (Cero) Ce(NO 3 ) 3 .2NH 4 NO,. 4 H a O.
SOLUBILITY IN WATER.
(Wolff.)
t.
Gms. per 100 Gms.
Solution.
Atomic Relation.
Gms. Ce(NO 3 ) 2 .2NH
per 100 Gms.
NH 4 .
Ce. "
NIL.
Ue.
Solution.
Water."
8
75
4
.787
18
56
I
999
I
70
.2
235-5
25
.0
5
.09
19
.80
I
995
I
74
.8
296.8
45
.0
5
53
21
.06
2
037
I
80
4
410.2
60
6
.01
22
77
2
054
I
87
.2
681.2
65
06
6
.11
23
.42
2
.022
I
89
.1
817.4
CERIUM AMMONIUM SULPHATE Ce 2 (SO 4 ) 3 .(NH 4 ) 2 SO 4 .8H 2 O.
SOLUBILITY IN WATER.
(Wolff.)
Gms.
_ Ce 2 (S0 4 ) 3 .(NH 4 ) 2 S0 4
1 per 100 Gms.
Solid
Phase.
.8H 2 (
Solution. Water.
22.3 5.06 5.33
35.1 4.93 5.18
45-2 4.76 4.99
45-o
55-25
75-4
85-2
Gms.
Ce 2 (S0 4 ) 3 .(NH 4 ) 2 S0 4
per 100 Gms.
Solution. Water.
2.91 2.99
2.16 2.21
I . 46 I . 48
1.17 1.18
Solid
Phase.
Anhydride
CERIUM SULPHATE Ce 2 (SO 4 ) 3 .
SOLUBILITY OF THE SEVERAL HYDRATES IN WATER.
(Koppel Z. anorg
anorg. Chem. 16, 455,
to be inaccurate.)
Gms.
Ce2(S0 4 ) 3 - (
t. per 100 **
. Chem. 41, 377, '04; the previous determinations
'98, and by Wyrouboff Bull. soc. chim. [3] 25,
Mols. CerfSC>4)s
i 8 ?^? 61 " Solid Phase. t. oer 10^ '
by
121
2e*(
Muthman and Rolig Z.
, '01, are shown by Koppel
Mols.
Gms.
Solution.
H 2 0.
SoluTion. H2 '
14
.20
O
.525 Ce2(S0 4 ) 3 .i 2 H20
20-5
8
.69
O
.302
Ce 2 (S0 4 ) 3 .8H 2 O
18.8
14
.91
555
40
5
.613
.188
"
19.2
IS
.04
.561
60
3
.88
.129
"
o
17
35
o
. 665 Ce5(SO 4 ) 3 .9H 2 O
45
8
.116
.280
Cej(S0 4 ) 3 .sH30
15
10
.61
.376
60
3
145
o
.103
"
21
8
.863
o
.308
80
I
.19
.0382
"
31-6
6
.686
o
.227
100.5
.46
.0149
45-6
4
.910
. 164
35
7
.8
o
.27
Ce 2 (S0 4 ) 3 . 4 H,0
50
4
465
. 148
40
5
.71
.19
60
3
73
.123
5
a
.31
.11
"
65
3
47
.114
65
I,
85
o
.06
"
o
15
95
. 605 Ce 2 (SO 4 ) 3 .8H 2 O
82
o
9 8
.032
"
15
9
95
o
350
100.5
o
42
014
H3 CHLORAL HYDRATE
CHLORAL HYDRATE C 2 HC1 3 O.H 2 O.
SOLUBILITY IN WATER, ETHYL ALCOHOL, CHLOROFORM, AND IN
TOLUENE.
. (Speyers Am. J. Sci. [4] 14* 294, '02.)
Calculated from the original results, which are given in terms of
gram molecules of chloral hydrate per 100 gram mols. of solvent.
In Chloroform.
In Toluene.
I . /
w.
s.
W.
s
w.
s.
w
S.
o
433
189-7
[ -II
123
3
1-530
3-
7
o.
898
3-2
5
.460
233-o
[.16
130
o
1 .515
4-
o
o.
900
4.0
10
485
275.0
23
140
o
1 .510
5-
o
o.
910
7-o
15
.510
330.0
30
160
1-505
9-
o
o.
915
II.
20
535
383-0
36
185
o
1.510
19.
o.
94
21.0
25
555
433-o
.42
215
o
1.520
34-
o
o.
97
36.0
30
.580
480 . o ]
49
245
o
1.540
56.
o
I.
02
56.0
35
59
516.0 J
55
280
1.570
80.
o
I .
13
80.0
40
.605
]
[.60
320
1.590
no.
I.
40
no.o
45 J
.620
.
W = wt. of i cc.
grams solvent.
saturated solution, S = Gms. C 2 HC1 3 .H 2 O per 100
CHLORINE Cl.
SOLUBILITY IN WATER.
(Winkler Landolt and Bernstein's Tabellen, 3d ed. p. 532, 601, '06; Roozeboom Rec. trav. chirn.
3t 59.
:ems labellen, 3d ed. p. <;32, ooi, 06; Kooze
'84; 4, 69, '85; Z. physik. them. 2, 452, '88.)
Gms. Cl per
Solid
* -
"
9-
*
100 Gms. H^.
Phase.
o
4.610
1.46
0.24
0.492
Ice+C1.8aq.
3
3-947
1-25
o
0-507-0.560
C1.8 aq.
6
3-4H
1. 08
2
0.644
tt
9
3-031
0.96
4
0.732
tt
9.6
2.980
o-94
6
0-823
"
12,0
2.778
0.88
8
0.917
10
3-095
o-997
9
0.965-0.908
tt
IS
2-635
0.849
20
I-8 S
tt
20
2 .260
0-729
28.7
tt
25
1.985
0.641
30
1.769
o-572
40
I.4I4
0-459
50
1.204
o-393
60
1. 006
0-329
70
0-848
0.279
80
0.672
0.223
90
0.380
0.127
100
o.ooo
o.ooo
ft' = vol. of Cl (red. to o and 760 mm.) absorbed by i vol. H 2 O at
total pressure of 760 mm.
q = Gms. Cl per 100 gms. H 2 O at a total pressure of 760 mm.
CHLORINE 114
SOLUBILITY IN WATER.
(Goodwin Ber. 15, 3039, '82.)
The saturated aqueous solution of the chlorine was cooled until
chlorhydrate separated; the temperature was then gradually raised
and portions withdrawn for analysis at intervals. Slightly different
results were obtained for solutions in contact with much, little, or no
chlorhydrate. The following results are taken from an average
curve.
^o Solubility t o Solubility .<> Solubility
Coefficient. Coefficient. Coefficient.
2-5 1.76 II 3-0 25 2.06
5.0 2.00 12.5 2.75 30 1.8
7.5 2.25 15 2.6 40 1.35
10 2-7 20 2-3 50 1.0
SOLUBILITY OF CHLORINE IN AQUEOUS SOLUTIONS OF HYDROCHLORIC
ACID AND OF POTASSIUM CHLORIDE.
(Goodwin.)
Coefficient of Solubility in:
t.
HC1
HC1
HCl
KCl
(1.046 Sp. Gr.).
(1.08 Sp. Gr.).
(1.125 Sp. Gr.).
(20 g. per 100 cc.).
o
4-i
6. 4
7-3
i-5
5
5-i
5-2
6.7
2.0
10
4.1
4-5
6.1
2.2
IS
3-5
3-9
5-5
1.6
20
3-o
3-4
4-7
I .2
25
2 -5
3-o
4-0
1.0
30
2.O
2.4
0-9
40
1.25
1.6
Goodwin also gives results for solutions of NaCl, CaCl 2 , MgCl 2 , SrCl 2 ,
Fe 2 Cl 2 , CoCl ? , NiCl 2 , MnCl 2 , CdCl 2 , LiCl, and in mixtures of some of
these, but the concentrations of the salt solutions are not stated.
SOLUBILITY OF CHLORINE IN AQUEOUS SOLUTIONS OF SODIUM
CHLORIDE.
(Kumpf Wied. Ann. Beibl. 6, 276, '82; Kohn and O'Brien J. Soc. Chem. Ind. 17, 100, '08.)
Coefficient of Solubility in:
l> .
9-97% NaCl.
i6.oi%NaCl.
19-66% NaCl.
26 .39% NaCl.
o
2-3
1-9
1.7
0.5
5
2.0
1.6
1.4
0.44
10
I .7
I .3
I .15
0.4
15
1.4
1. 06
o-95
0.36
20
I .2
0-9
0.8
0.34
2$
0-94
0-75
0.65
o-3
50
O.2
80
. . .
0.05
ioo cc. of 6.2 per cent CaCl 2 solution dissolve 0.245 gram Cl at 12.
100 cc. of 6.2 per cent MgCl 2 solution dissolve 0.233 gram Cl at 12.
ioo cc. of 6.2 per cent MnCl 2 solution dissolve 0.200 gram Cl at 12.
For coefficient of solubility see page 105.
ii5 CHLORINE MONOXIDE
CHLORINE MONOXIDE C1,O.
ioo volumes of water at o absorb 200 volumes of C1 2 O gas.
CHLORINE TRIOXIDE C1 2 O 3 .
SOLUBILITY IN WATER AT APPROX. 760 MM. PRESSURE.
(Brandan Liebig's Ann. 151, 340, '69.)
t. 8.5. 14-0. 21. 93".
Gms. Cl^Og per ioo gms. ILfl 4-7^5 5-012 5-445 5.651
Garzarolli and Thurnbalk Liebig's Ann. 209, 184, '81, say that
C1 2 O 3 does not exist, and above figures are for mixtures of C1 2 O and Cl.
CHLOROFORM CHC1 3 .
SOLUBILITY IN WATER.
(Chancel and Parmentier Compt. rend, ioo, 473, 85; Rex Z. physik. Chem. 55, 355, '06.)
t o Gms. CHC1 3
ioo Gms. H 2 O
t.
Gms. CHC1 3 per
Liter of Solution,
Density
of Solutions.
o
9.8 7
1.00378
3-2
8.90
17-4
7-12
1.00284
29.4
7-05
I .00280
41.6
7.12
I .00284
54-9
7-75
I .00309
O
10
20
30
1.062
0.895
0.822
0.776
ioo cc. H 2 O dissolve 0.42 cc. CHC1 3 at 22; Vol. of sol. = 100.39 cc -
Sp. Gr. = 1.0002.
ioo cc. CHC1 3 dissolve 0.152 cc. H 2 O at 22; Vol. of sol. = 99.62 cc.,
Sp. Gr. = 1.4831.
(Herz Ber. 31, 2670, '98.)
SOLUBILITY OF CHLOROFORM IN AQUEOUS ETHYL ALCOHOL, METHYL
ALCOHOL, AND ACETONE MIXTURES AT 20.
(Bancroft Phys. Rev. 3, 29, '95, '96.)
In Ethyl Alcohol. In Methyl Alcohol.
Per 5 cc. C 2 H 5 OH. Per 5 cc. CH 3 OH.
cc. H 2 O.
10
cc. CHC1 3 .
O.2O
8
-3
6
0-5 1 !
4
*-*3
2
I
2-51
4.60
0.91
0.76
6.0
O-55
8.0
0.425
IO.O
0.20
20. o
0.125
30.24
cc. H 2 0.
cc. CHC1 3 .
IO
O.IO
5
4
0.48
0.8o
2
4-0
1.49
7-0
8.0
I .12
IO.O
In Acetone.
Per 5 cc. (CH 3 ) 2 CO
cc. H 2 O.
cc. CHC1 3 .
0.16
4-0
O-22
2 .O
o-33
0.58
I.O
0-955
o-79
0-505
1. 12
1. 60
0.30
2.50
0.21
3-50
0.19
0.16
4-0
5-o
0.12
IO.O
CHROMIUM ALUMS 116
SOLUBILITY OP CHROMIUM ALUMS IN WATER AT 25.
(Locke Am. Ch. J. 26, 174, 'ox.)
Per IPO cc. Water.
Mum. Formula. 'Grams Grams Gram "
Anhdyrous. Hydrated. Mok.
Potassium Chromium Alum KjCr^SO^. 241^0 12.51 24.39 0.0441
Tellurium Chromium Alum Te 2 Cr 2 (SO 4 ) 4 .24H 2 O 10.41 16.38 0.0212
CHROMIUM CHLORIDE (ic) CrCl 3 .6iH 2 O.
100 grams H 2 O dissolve 130 grams (green modification) at 15.
(Recoura Compt. rend. 102, 518, '86.)
CHROMIUM DOUBLE SALTS.
SOLUBILITY IN WATER.
(Jorgensen J. pr. Chem. [2] 20, 105, '79; [2] 30, i, '84; [2] 42, 208, '90; Struve Ibid. [2] 61, 457,
'99.)
Gms. per
Name of Salt. Formula. t . too Gms.
H 2 O.
Chloro Tetra Amine Chromium
Chloride CrCl(NH 3 ) 4 (OH 2 )Cl 2 15 6.3
Chloro Purpureo Chromium Chloride CrCl(NH 3 ) 5 Cl 2 16 0.65
Luteo Chromium Nitrate Cr(NH 3 ) 6 (NO 3 ) 3 ? 2.6
Chloro Purpureo Chromium Nitrate CrCl(NH 3 ) 5 (NO 3 ) 2 17.5 1.4
Chromic Potassium Molybdate 3K 2 O.Cr 2 O 3 .i2MoO 3 .2oH 2 O 17 2.5
CHROMIUM TRIOXIDE CrO 3 .
SOLUBILITY IN WATER.
(Mylius and Funk Wiss. Abh. p. t. Reichanstalt, 3, 451, 'oo.)
o
15
18
50
99 7 39 37 - 1
Density of solution saturated at 18 = 1.705.
CHROMIUM SULPHATES (ous and ic).
SOLUBILITY m WATER (ous at o).
Salt. G 5i. P H 2 a Solid Phase. Authority.
ChromOUS 12.35 CrSO 4 .7H 2 O (Moissan Bull. soc. chim. [2] 37. 206, '8a )
Chromic 1 20 . Cr 2 (SO 4 ) 3 . iSH^O (Etard Compt. rend. 84, 1090, '77.)
CHRYSAROBIN CH at O 7 .
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.)
Gms. CrOa per 100
g. Solution.
Mols. CrO 3 per
100 Mols. H 2 O.
Solid Phase.
62.08
29.4
CrO,
62.38
29.8
62.45
29.91
it
6 4-55
32-7
tt
Water 0.021 0.046 Chloroform 5-55
Alcohol 0.324 0.363 (60) Ether 0.873
Benzene 4.0 ... Amyl Alcohol 3.33
Carbon Bisulphide 0-43
ii; OHRTSEN
OHBYSEN C 18 H 12 .
SOLUBILITY IN TOLUENE AND IN ABS. ALCOHOL.
(v. Becchi.)
ioo gms. toluene dissolve 0.24 gm. C 18 H 12 at 18, and 5.39 gms. at
100.
ioo gms. abs. alcohol dissolve 0.097 gm. C 18 H 12 at 16, and 0.170 gm.
at b. pt.
CINCHONA ALKALOIDS. (See also Quinine, p. 269.)
SOLUBILITY OF CINCHONINE, CINCHONIDINE, QUININE, AND QUINIDINE
IN SEVERAL SOLVENTS AT i8-22.
(Miiller Apoth.-Ztg. 18, 233, '03; see also Prunier J. pharm. chim. [4] 39, 136, '79.)
Grams of the Alkaloid per ioo Grams Solution.
Solvent.
i x
Quinine
Cinchonine
C* U XT C\
Cinchonidine
CH N O
r* IT
CjoH;
M N,O,.
Quinidine
P H M O
Cl9MNt->.
19^23-^2^.
Hydrate.
Anhydride.
<-204 i>l a'-'-
Ether
0-10
O.2II
I .619
0.876
0.776
Ether sat. with H.,0
0.123
0.523
5.6l8
2.794
1.629
Hp sat. with Ether
O.O25
0.0306
0.0667
0.0847
0.031
Benzene
0-0545
0.099
O.2O54
I .700
2.451
Chloroform
0.6979
9.301
100 +
100 +
100 +
Acetic Ether
.0.0719
0.3003
4.65
2.469
1.761
Petroleum Ether
0-0335
0-0475
O.OIO3
O-O2II
O.O24I
Carbon Tetra Chloride
0-0361
0.0508
0.203
0.529
0-565
Water
0.0239
0-0255
o-574
0.0506
0-0202
Glycerine (15.5)
0.50
0.50
ioo grams chloroform dissolve 0.565 gm. cinchonine at 50.
ioo grams abs. ether dissolve 0.264 gm. cinchonidine at 32.
(Kohler Z. anal. Ch. 18, 242, '79.)
SOLUBILITY OF CINCHONINE AND CINCHOTINE SULPHATE, TARTRATE,
BlTARTRATE, OXALATE, AND HYDROCHLORIDE IN WATER.
(Forst and Bohringer Ber. 14, 1266, '81.)
Cinchonine Salts. Cinchotine Salts.
Gms. per
Formula. t . ioo Gms. Formula.
2 (C 19 H 22 N 2 0)S0 4 H 2 . 2 H 2
2 (C 19 H 22 N 2 O) C 4 H 6 O 6 . 2 H 2 O
wa....
(C 19 H 22 N 2 O) .C 2 H 4 O 4 .H 2 O
19 H 22 N 2 O.HC1. 2 H 2 O
13
1 6
1 6
20
10
1.52 2(C 19 H 24 N 2 0)S0 4 H 2 . 2 H 2 13
3.0 2(C 19 H 24 N 2 O)C 4 H 6 O 6 . 2 H 2 O 1 6
0.99 C 19 H 24 N 2 O.C 4 H 6 6 . 4 H 2 16
0.06 2 (CjgH^NaO) .C 2 H 2 O 4 .H 2 O 10
4.16 C 19 H 24 N 2 O.HC1. 2 H 2 O 10
Gms. pet
ioo Gms.
H 2 0.
3.28
1.76
1.28
1.16
2.12
SOLUBILITY OF CINCHONINE SULPHATE AND OF CINCHONIDINE SUL-
PHATE IN SEVERAL SOLVENTS.
Solvent.
(U. S. P.)
Gms. (C 19 H22N 2 2 ) 2 H 2 S04.2H 2
per ioo Gms. Solvent.
' At 25.
At 80. "
Water
1.72
3- 1
Alcohol
10.
19.2(60)
Ether
0.04
. . .
Chloroform
i-45
. . .
Glycerine
6-7 (i5)
i ...
Gms. (C 1 oH 22 N 2 O) !! .H 2 S04.3H 2 O
per ioo Gms. Solvent.
At 25
1. 60
1-4
0-02
O-II
At 80
4.80
(60)
CINNAMIC ACID 118
OINNAMIO ACID C 6 H 5 CH:CH.COOH.
SOLUBILITY OF CINNAMIC ACID IN AQUEOUS SOLUTIONS OF SODIUM
ACETATE, BUTYRATE, FORMATE, AND SALICYLATE AT 26.4.
(Philip J. Chem. Soc. 87, 992, '05.)
Calculated from the original results, which are given in terms of
molecular quantities per liter.
Gms Na Salt Gms> CaH 5 CH:CH.COOH per Liter in Solutions of:
per Liter.
O
I
2
3
4
8 ... ... ... 0.90
i liter of aqueous solution contains 0.491 gm. C 6 H 5 CH:CH.COOH
at 25 (Paul).
SOLUBILITY OF CINNAMIC ACID IN AQUEOUS SOLUTIONS OF ANILIN
AND OF PARA TOLUIDIN AT 25.
(Lowenherz Z. physik. Chem. 25, 394, '98.)
Original results in terms of molecular quantities per liter.
In Aqueous Anilin. In Aqueous p Toluidin.
Grams per Liter. Grams per Liter.
CH 3 COONa.
CaHyCOONa.
HCOONa.
Ce^.OH.COONa.
0.56
0.56
0.56
0-56
1.50
1.30
0.92
0.62
2.12
1.85
I .12
0.70
2.52
2-25
1.27
o-73
2.85
2.60
1.40
0.77
3-05
2.90
i-47
0.80
: CHCOOH. C^CHgNHa. C 6 H 5 CH :CHCOOH.
0.49 o 0.49
1 1.20 I 1.52
2 1-65 2 2.20
3 2.02 3 2.83
4 2.35 4 3-35
6 2.92 5 3.80
SOLUBILITY OF CINNAMIC ACID IN METHYL, ETHYL, AND PROPYL
ALCOHOLS.
(Timofeiew Compt. rend. 112, 1137, '91.)
Grams C 6 H 5 CH:CH.COOH per 100 Grams of:
CHaOH. C 2 H 6 OH.
o 20.65 15-61 10.63
19.5 28.91 22.03 I 5-4i
SOLUBILITY OF BROM CINNAMIC ACIDS.
a Brom and ft Brom Cinnamic Acid a Brom Cinnamic Acid in Aq.
in Water at 25. Solutions of Oxalic Acid at 25.
(Paul Z. physik. Chem. 14, in, '94.) (Noyes Z. physik. Chem. 6, 245, '90.)
Per 1000 cc. Solution. Normality of Solutions. Grams per Liter.
Acid. Grams. Millimols. ' (COOH) 2 . CeH 6 CH': (COOH) 2 . QHsCH^
CBr:COOH. CBrCOOH.
a, C 6 H 6 CH: CBrCOOH 3.9325 *7'3 2 0.0176 o.o 3.995
ft C 6 H 5 CBr: CHCOOH 0.5255 2.315 0.0275 0.0140 2.448 3.178
0.0524 0.0129 4.716 2.928
1 1 9 CITRIC AOID
OITBIO AOID C 3 H 4 (OH)(COOH) 3 .H 2 O.
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; Bourgoin Ann. chim. phys. [5] 13, 406, '78.)
_ . Cms. C3H 4 (OH)(COOH)3.H 2 per 100 Cms.
bolvent. t . - ; >
solution. bolvent.
Water 25 64.8 185
Water b. pt. 70.3 250
Alcohol (90%) 25 34.6 75.9
Alcohol (U.S.P.) " 39-2 64.5
Alcohol (Abs.) 43.2 52.8
Ether " 2.21 2.26
Ether (U.S.P.) " 5-2 5-55
COBALT BROMIDE CoBix
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 537, '94.)
t. 59. 75. 97.
Gms. CoBr 2 per 100 gms. solution 66.7 66.8 68.1 (blue)
COBALT DOUBLE SALTS.
SOLUBILITY IN WATER.
(Jorgensen J.pr. Chem. [2] 18, 205, '78; iQt 49. '795 Kurnakoff J. russ. phys. chem. Ges. 24, 629,
'92.)
Gms. Salt
Name. Formula. t. per zoo
Gms. H 2 O
Chloro purpureo cobaltic bromide CoCl(NH 3 ) 5 Br 2 14.3 0.467
Bromo purpureo cobaltic bromide CoBr(NH 3 ) 5 Br 2 16 0.19
Chloro tetra amine cobaltic chloride CoCl(NH 3 ) 4 (OH 2 )Cl 2 2 . 50
Chloro purpureo cobaltic chloride CoClCNH.,)^^ o 0.232
Chloro purpureo cobaltic chloride CoCl(NH 3 ) 5 CL5 I 5-S 0.41
Chloro purpureo cobaltic chloride CoCl(NH 3 ) 5 Cl2 46 6 i .03
Luteo cobaltic chloride Co(NH 3 ) 6 Cl 3 o 4.26
Luteo cobaltic chloride Co(NH 3 ) 6 CL, 46.6 12.74
Roseo cobaltic chloride Co(NH 3 ) 5 (OH 2 )Cl s o 16.12
Roseo cobaltic chloride Co(NH 3 ) 5 (OH 2 )Cl 3 16 . 2 24 .87
Chloro purpureo cobaltic iodide CoC^NH,,)^ 19.2 2.0
Chloro purpureo cobaltic nitrate CoCl(NH 3 ) 5 (NO 3 ) 2 15 1.25
Chloro purpureo cobaltic sulphate CoCl(NH 3 ) 5 SO 4 .2H 2 O 17.3 0.75
Nitrato purpureo cobaltic nitrate Co(NO 3 )(NH3)(NO 3 ) 2 16 0.36
COBALT CHLORATE Co(ClO 3 ) 2 .
SOLUBILITY IN WATER.
(Meusser Ber. 35, 1419, '02.)
Mols.
Solid
Phase.
Co(C10 3 ) 3 .4H 2 0.
t
Gms.
Co(C10a) 2
Mols.
Co(C10 3 ) 2 Solid
Gms.
Co(C10 3 ) 2
Mols.
Co(C10 3 ) 2
per 100 Gms.
Solution.
per 100 Phase.
Mols.HaO.
' per 100 Gms
Solution.
per 100
Mols. H 2 O.
12
2 9
97
3
.41
Ice
18
6 4
.19
14
.28
21
53
30
9
.08
Co(ClO 8 ) 2 .6H 2 O
. 21
6 4
39
14
51
-19
53
.61
9
.20
35
6 7 -
09
16
10
O
57
45
IO
75
"
47
6 9 .
66
18
29
10.5
61
83
12
.90
"
61
7 6.
12
25
39
Density of solution saturated at
18 =
1.861.
COBALT CHLORIDE 120
COBALT CHLORIDE CoCl 2 .
SOLUBILITY IN WATER.
(Etard Compt. rend. 113, 699, '91; Ann. chim. phys. [7] 2, 537, '94-)
Cms. Cms.
t o CoCl 2 per Solid CoCl 2 per Solid
100 Cms. Phase. 100 Gms. Phase.
Solution, Solution.
-io 27.0 CoO^HjO (red) 35 38.0 CoCl 2 .H 2 O (violet)
o 29.5 40 41.0
+ 10 3 J -5 5o 47-o
20 33-5 60 47-5 CoOyHjO (blue)
25 34-5 80 49-5
30 35.5 100 51.0
SOLUBILITY OP COBALT AMMONIUM CHLORIDES IN WATER.
(Kurnakoff J. russ. phys. chem. Ges. 24, 629, '93; J. Chem. Soc. 64, ii, 509, '93.)
c . Grams per 100 Grams H 2 O at:
salt. / v
o. 16.9. 46.6'
0.232 ... 1.031
16.12 24.87 ...
CoClg.6NH 3 4.26 ... 12.74
SOLUBILITY OF COBALT CHLORIDE IN AQUEOUS HYDROCHLORIC
ACID SOLUTIONS AT o.
(Engel Ann. chim. phys. [6] 7, 355, '89.)
Milligram Mols.
per 10 cc. Sol.
Sp. Gr. of
Ss%1iitirkn<s_
Gms. per 100 Gms.
Solution.
Gms. per 100 cc.
Solution.
*CoCl 2 .
HCl.
CoCl 2 .
HCl.
CoCl 2 .
HCl.
62.4
i
343
30
17
O
.00
40.
5
o
58.52
3
7
i
-328
28
.62
.102
38
o
0-135
50.8
II
45
i
299
25
39
.321
33
o
0.417
37-25
25
.2
i
.248
19
43
738
24
.2
0.919
12.85
55
O
i
.167
7
15
I
.718
8
34
2.00
4-75
74
75
i
.150
2
.68
2
369
3
.08
2.72
12.0
104
5
i
.229
6
34
3
.099
7'
79
3-8i
25.0
139
.0
i
323
12
27
3
.829
16,
.24
5-07
SOLUBILITY OF COBALT CHLORIDE IN AQUEOUS ALCOHOL
AT 11.5.
(Bodtker Z. physik. Chem. 22, 509, '97.)
10 gms. of CoCl 2 .6H 2 O were added to 20 cc. of alcohol and in addition
the amounts of CoCl 2 shown in the second column. The solutions were
shaken 2 hours, 5 cc. withdrawn, and the amount of dissolved CoCl a
determined by evaporation and weighing.
Vol.%
Gms. CoCl 2
Gms. per 5 cc.
Solution.
Vol.
%
Gms. CoCl 2 Gms - Per 5 cc. Sol.
Alcohol.
Added.
H 2 0.
CoCl 2 .
Alcohol.
Added.
H 2 0.
CoCl 2 .
91-3
o.o
I-325
I
.168
99
3
O
.612
O
.764
1-459
98.3
o.o
I-I34
I
.214
99
3
-8l 3
.688
1.568
98.3
o.o
1. 068
I
.l8l
99
3
I
.022
O
634
1.713
99-3
0-0
1.045
I
.199
99
3
I
.240
o
553
1.831
99-3
0.194
0.899
I
.204
99
3
I
.446
o
483
I -943
99 3
0.400
0.829
I
325
99
3
I
.650
o
500
2-183
100 gms. sat. solution in alcohol (0.792 Sp. Gr.) contain 23.66 gms.
Cod* Sp. Gr. = I.OI07. (Winkler-J.pr.Chem.9i. 207, '6 4
121
COBALT CHLORIDE
SOLUBILITY OF COBALT CHLORIDE IN ORGANIC SOLVENTS.
Solvent.
Gms. per ioo^Gms. Solvent.
Acetone
o
22.5
25
18
Ethyl Acetate 14
79
Ether
Glycol
CoCl 2 .
9.11
9.28
8.62
2.75
0.08
0.26
0.021
CoCl 2 .2H 2 0.
Authority.
17 l6 (St. von Laszczynski Ber. 27, 2285, '94.)
17 .06 (St. von Laszczynski Ber. 27, 2285, '94.)
(Kmg and McElroy J. Anal. Ch. 6, 184, '92.)
(Naumann Ber. 37, 4332, '04.)
. . . (St. von Lasczczynski.)
O . 0291 (Bodtker Z. physik. Chem. 22, 509, '97.)
10 . 7 (per 100 g.SOl.) (de Coninck BuU.acad.roy.Belglque, 359/05 J
COBALT IODATE Co(IO 3 ) 2 .
SOLUBILITY IN WATER.
(Meusser Ber. 34, 2435, 'ox.)
Solid Phase:
t o. Co(I0 3 ) 2 . 4 H 2 0. Co(I0 3 ) 2 .2H 2 0.
Co(IO a ) 2 .
G.
M.
" G.
M.
G.
M.
O
o
54
0.028
o.
32
.014
.
. .
. . .
18
S3
0-038
o.
45
o
.020
I
03
.046
30
I
03
0.046
o.
S 2
o
.023
o
.89
o
.040
50
I
.46
0.065
o.
67
o
.030
8S
o
.030
60
I
.86
0.084
.
65
2
17
0-098
.
. .
. . .
.
. . .
75
.
o.
84
o
.038
o
75
033
100
.
I.
02
o
045
.69
o
.031
G =
Gms. Co(IO 3 ) 2 per
ioo gms.
solution.
M-
Mols.
Co(I0 3 ) a
per ioo Mols. H 2 O.
COBALT IODIDE CoI 2 .
SOLUBILITY IN WATER.
(Etard Compt. rend. 113, 699, '91; Ann. chim. phys. [7] 2, 537, '94.)
The accuracy of these results is doubtful.
Gms. CoI 2
per ioo Gms.
Solution.
10
55-5 CoI 2
o
58.0
10
61.5
15
63.2
20
65-2
25
67
COBALT NITRATE
Solid Phase.
25
30
50
80
no
Gms. CoI 2
per ioo Gms.
Solution.
67-5
7O.O
75-o
79.0
80.0
81.0
Solid Phase.
(olive)
CoI^O (yellow)
Co(N0 3 > 2 .
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt 3, 439, 'oo.)
t
-26
20-5
21
IO
- 4
o
+ 18
Gms. Mols.
Co(N0 3 ) 2 Co(N0 3 ) 2
per_ioo Gms. per 100
Solution.
39-45
42.77
4i-55
43-69
44-85
45-66
49-73
Solid Phase.
H 2 0.
6.40 Co(NOs) 2 .9H 2
35
Co(NO 8 ) 2 .6H2O
7
6.98
7.64
7-99
8.26
9.71
t.
Gms.
Co(N0 3 ) 2
per ioo Gms.
Mol
Co(NC
per i
Solution.
Mols.E
41
55-96
12.5
56
62.88
I6. 7
55
61.74
15-8
62
62.88
I6. 7
70
64-89
18.2
84
68.84
21-7
91
77-21
33-3
Co(NO,) 2 .6H 8
Co(N03) 2 . 3 H,0
Density of solution saturated at 18 = 1.575.
COBALT NITRATE 122
SOLUBILITY OF COBALT NITRATE IN GLYCOL.
(de Coninck Bull. acad. roy. Belgique, 359, '05.)
100 grams saturated solution contain 80 gms. Cobalt Nitrate.
COBALT RUBIDIUM NITRITE Rb 3 Co(NO 2 ) 6 .H 2 O.
100 grams H 2 O dissolve 0.005 gram of the salt.
(Rosenbladt Ber. 19, 2531, '86.
COBALT SULPHATE CoSO 4 .7H 2 O.
SOLUBILITY IN WATER.
(Mulder; Tobler Liebig's Ann. 95, 193, '55; Koppel VVetzel Z. physik. Chem. 52, 395, '05.)
Gms. CoSO 4
t. per 100 Gms.
Mols. CoS0 4
per 100 t.
Gms. CoSO 4 Mols. CoSO 4
per 100 Gms. p^ I00
Solution. Water. Mols. t! 2 U. Solution. Water. Mols. H;zO.
o 20:35 25.55 2.958 35 31.40 45-80 5.31
5 21.90 28.03 3-251 40 32-81 48.85 5-664
10 23.40 30.55 3.540 50 35.56 55.2
15 24.83 33.05 3.831 60 37.65 60.4
20 26.58 36.21 4-199 7 39-66 65.7
25 28.24 39.37 4.560 80 41.18 70.0
30 29.70 42.26 4-903 I0 45-35 83.0
SOLUBILITY OF MIXTURES OF CoSO 4 .7H 2 O AND Na 2 SO 4 .ioH 2 O
IN WATER.
(Koppel; Wetzel.)
Gms. per Gms. per Mols. per
$. 100 Gms. Solution. 100 Gms. H 2 O. 100 Mols. H 2 O. Solid Phase.
'CoS0 4 .
N a2 S0 4 .
CoSO 4 .
Na 2 SO 4 .
CoSO 4 .
Na 2 S0 4 .
5
16.56
17.46
7
9
63
59
21
23
85
94
10
.07
2
2
54
77
1.27
1.6 7
CoS0 4 . 7 H 2 +
Na 2 S0 4 .ioH 2 O
10
17.90
ii
73
25
.41
16
67
2
94
2. II
M
20
17-59
16
43
26
65
24
.91
3
.09
3-15
CoNa 2 (S0 4 ) 2 . 4 H 2
25
17.06
15
70
25
36
23
32
2
95
2-97
30
15-94
14
93
23
21
.61
2
.70
2.74
"
35
15-73
14
52
22
54
20
85
2
.62
2 .64
"
40
14-87
14
.22
2O
.98
20
05
2
.46
2-53
. "
18.5
18-75
15
.61
28
.61
23
.82
3
32
3.02
CoNa 2 (S0 4 ) 2 . 4 H 2
20
19.30
15
.10
29
.42
23
.01
3
.41
2.92
+ CoS0 4 . 7 H 2 O
2 5
20-30
13
.60
30
74
2O
58
3
56
2 .6l
3o
21.67
12
05
32
.70
18
.17
3
79
2.30
<
35
22.76
IO
43
34
.06
15
.61
3
95
I. 9 8
"
40
24-05
9
.16
35
OI
13
72
4
.81
1.74
44 ,
18.5
16.87
16
97
2 5
5o
25
65
2
.96
3-25
CoNa 2 (S0 4 ) 2 . 4 H2O
20
I5-4I
18
.12
23
.18
27
.26
2
.69
3-45
+Na 2 SO 4 .ioH 2 O
25
10.63
23
.26
16
.07
35
.17
I
.86
4.46
4 ,
30
6.01
28
.6 7
9
.20
43
74
I
.07
5-54
35
40
4-56
4.72
3i
.14
.78
7
7
.19
45
5o
79
. 10
835
.864
6.44
6-34
CoNauCSOJz^HjO
+ Na 2 S0 4
COBALT SULPHATE
SOLUBILITY OF COBALT SULPHATE IN METHYL AND ETHYL ALCOHOL
AND IN GLYCOL.
Solvent.
Gms. per 100 Gms.
Solvent.
'CoSO 4 .
Observer.
Methyl Alcohol (abs.)
CoSO 4 .7H 2 O.
42 . 8 (de Bruyn Z. physik. Ch. 10, 784, '92.)
50.9
54-5
13-3
1.8
3
15
18 1.04
(93-5%) 3 ."
(50%) 3
Ethyl Alcohol (abs.) 3 ... 2.5
Glycol . .(penoogms.
solution) 3 . i
COCAINE C 17 H 21 NO 4 .
COCAINE HYDROCHLORIDE C 17 H 21 NO 4 .HC1.
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; at i8-22; Mttller Apoth.-Ztg. 18, 248, '03.)
Gms. per too Gms. Solvent.
(de Coninck Bull, a cad. roy. Belgique,
359. '05.)
Gms.
L.i7rl 2l J\(J 4 . Ci7ri2i-l->*~'4""*-'J-
per zoo Gms.
Solvent.
Water
25
0.17
250
Ether +KLO
18-22
34-o
Water
80
0-38
1000
11,0+ Ether
18-22
0.254
Alcohol
25
2O-O
38
Benzene
1 8-2 2
100
Ether (U.S.P.)
25
26-3
CC1 4
17
18.5
Ether
18-22
ii. 6
Acetic Ether
1 8-2 2
5 8 -99
Chloroform
18-22
100 +
Petroleum Ether 1 8-2 2
2-37
CODEINE C 18 H 21 NO 3 .H 2 O, also the Phosphate and Sulphate.
COLCHICINE C 22 H 25 N0 6 .
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; at i8-22, Miiller.)
Grams, per 100 Grams Solvent.
Solvent.
t.
Codeine
Codeine
~**
c
'i8H2iNO3H 2 O.
H 2 SO 4 .s Aq.
C 22 H 25 NO 6 .
Water
18-22
9.616
Water
25
I .13
44-9
3-3
4-5
Water
80
1.70
217.0
16.0
5.0
Alcohol
25
62.5
0.383
0.096
Alcohol
60
108.7
1.03
0.27
Ether
25
8.0
0.075
0.64
Ether
18-22
. . .
. . .
0.126
Ether sat. with H^O
18-22
. . .
...
. . .
0.18
H 2 O sat. with Ether
18-22
12.05
Benzene
18-22
0-939
Benzene
25
1.15
Chloroform
25
151 .5
0-015
100 +
Carbon Tetra Chloride
17
1.328
O.I2I
Acetic Ether
18-22
. .
1.342
Petroleum Ether
18-22
0.058
'COLLIDINE 124
COLLIDINE (2, 4, 6, Tri Methyl Pyridine) C 6 H 2 N(CH,) a .
SOLUBILITY IN WATER.
(Rothmund Z. physik. Chem. 26, 433, '98.)
Gms. Collidin per 100 Gms. Gms. Collidin ^per 100 Gms.
Aq. Layer. Collidin Layer. Aq. Layer. Collidin Layer.
5.7 (crit.t.) 17.20
10 7.82 41.66 80 1.73 86.12
20 3.42 54-92 100 1.78 88.07
30 2.51 62.80 120 1.82 88.98
40 1.93 70.03 140 2.19 89.10
60 1.76 80.19 160 2.93 87.2
180 3.67
COPPER ACETATE Cu(C 2 H 3 O 2 ) 2 .H 2 O.
100 grams of glycerine dissolve 10 grams of copper acetate at 15.5.
COPPER BROMIDB (ous) Cu 2 Br 2 .
SOLUBILITY OP CUPROUS BROMIDE IN AQUEOUS SOLUTIONS OF POTAS-
SIUM BROMIDE AT i8-2o.
(Bodlander and Storbeck Z. anorg. Chem. 31, 460, '02.)
Millimols per Liter. Grams, per Liter.
KBr.
Total Cu.
Total Br. Cu (ic).
Cu (ous).
KBr.
Total Cu.
Cu (ic).
Cu (ous).
0.3157
0.4320 o.
2096
O
.1061
O
0.0201
.0133
0.0067
25
0.119
0.
OI2
.107
2.
98
0.0076
.0007
0.0068
40
O.200
0.
013
O
.187
4-
76
0.0127
o
.0007
0.0119
60
0.310
0.
025
.285
7-
i5
0.0197
.0015
0.0181
80
0.423
0.
012
.411
9-
53
0.0266
.0007
0.0261
IOO
0.584
...
o
.584
n.
0.0371
0.0371
120
0.693
...
.693
14.
29
0.0441
0.0441
500
8.719
...
8
.719
59-
55
0.5540
0.5540
COPPER CHLORATE (ic) Cu(ClO 3 ) 2 . 4 H 2 O.
SOLUBILITY IN WATER.
(Meusser Ber. 35, 1420, '02.)
Gms. Mols. Gms. Mols.
t Cu(ClO 3 ) 2 Cu(ClO 3 ) 2 Solid t <> Cu(ClO 3 ) 2 Cu(ClO 3 ) 2 Solid
per i oo Gms. per 100 Mols. Phase. per 100 Gms. per 100 Mols. Phase.
Solution. H 2 0. Solution. H 2 O.
12 30.53 3.43 Ice l8 62.17 12.84 Cu(ClO3) 2 .4H2O
31 54-59 9-39 Cu(ci03) 2 .4H20 45 66.17 15.28
2i 57-12 10.41 " 59.6 69.42 17.73
-ho. 8 58.51 11.02 " 71 76.9 25.57
Density of solution saturated at 18 = 1.695.
COPPER CHLORIDE (ic) CuCl 2 .
SOLUBILITY IN WATER.
(Reicher and Deventer Z. physik. Chem. 5, 560, '90; see also Etard Ann. chim. phys. (7] 2, 528, '94.)
Gms. CuCl 2 Gms. CuCl 2 Gms. CuClj
t. per loo Gms. t. per 100 Gms. t. per 100 Gms.
Solution. Solution. Solution.
o 41-4 25 44.0 50 46.65
10 42-45 3 44-55 6o 47-7
20 43.5 40 45.6 80 49 -8
TOO 51.9
Density of solution saturated at o = 1.511, at 17.5 = 1.579.
125 COPPER CHLORIDE
SOLUBILITY OF CUPRIC CHLORIDE IN AQUEOUS SOLUTIONS OF HYDRO-
CHLORIC ACID AT o.
(Engel Ann. chim. phys. [6] 17, 351, '89.)
Milligram Mols.
per 10 cc. Sol.
Sp Gr. of
Gms. per
too cc. Sol.
Gms.
per too Gms. Sol.
*CuCl 2 .
HC1.
Solutions.
CuCl 2 .
HCf.
CuCl 2 .
HCI:
9 J -75
O
I
49
61
.70
o.
o
41
41
o.o
86.8
4
5
I
475
58
37
I .
64
39
58
1 .11
83-2
7
.8
I
458
55
95
2.
84
38
37
J-95
79-35
10
5
I
435
53
37
3-
83
37
.19
2.67
68.4
20
25
I
389
46
.01
7-
38
33
.11
5-3 1
50.0
37
5
I
3 J 9
33
.62
*3-
67
25
5o
10.37
22.8
70
2 S
I
.231
IS
33
25-
61
12
.46
20.80
23-5
102
5
I
.288
I 5
.81
37-
36
12
.27
29.00
26.7
128
.0
I
323
*7
.96
46.
66
J 3
57
35-26
29
o
Sat
. HC1
SOLUBILITY OF CUPROUS CHLORIDE IN AQUEOUS SOLUTIONS OF HYDRO-
CHLORIC ACID.
(Engel Ibid. [6] 17. 372, '89; Compt. rend. 121, 520, '95.)
Milligram Mols
. per 10 cc. Sol. So. Gr. of
Gms. per TOO cc. Sol.
Gms. per 100 Gms. Sol
iCu 2 C! 2 .
HCI. Solutions.
C U2 C1 2 .
HCI. CU;>C1 2 .
HCl-
Results at o.
O
475
8
975 1-05
O
471
327
448
0.312
I
5
17
I
486
.638
I
.418
0.6o8
2
9
26
.0 i .065
2
8 7 2
.948
2
.697
0.932
4
5
34
5
.080
4
457
I
257
4
.127
I .164
8
2 5
47
.8
.135
8
172
I
743
7
.199
I -S3S
15
5
68
5
.261
15
7
2
497
12
.46
1.980
33
.0
104
.0
345
32
68
3
.827
24
.30
2.845
Results at 15-! 6.
7
4
54
4
.19
7
33
i
983
6
159
1.666
10
.8
68
9
.27
10
69
2
5 11
8
.422
1.977
12
.8
75
o
.29
12
68
2
734
9
.826
2.119
16
92
.0 1.38
IS
.84
3
346
ii
.48
2.424
COPPER CHLORIDE, AMMONIUM CHLORIDE MIXTURES IN AQUEOUS
SOLUTION AT 30.
(Meerburg Z. anorg. Chem. 45. 3. 'osO
Grams per 100
Gms. Sat. Solution.
CuCl 2 .
O
1.9
3-6
NH4C1.
29-5
28.6
25-9
10.5
16.5
19.9
9-4
29.4
4.9
41.4
2.1
43-2
2-0
43-9
Grams per 100
Gms. Solid Phase.
CuCl 2 .
6.0
37-o
21.7
28.5
35- 1
NEUCl.
4 8-2
34-9
23-1
18.4
15-3
13-3
6.6
Solid Phase
NH4C1
NH4C1 + CuCl-s-aNEUCl ^HjO
CuClj -
aH^ + CuCl 2 .2H 2 O
COPPER AMMONIUM 126
CHLORIDE
COPPER AMMONIUM CHLORIDE CuCl 2 .2NH 4 C1.2H,O.
SOLUBILITY IN WATER.
(Meerburg.)
Gms.
t . CuCl 2 . 2 NH 4 Cl Solid
oer 100 Gms. Phase.
Gms.
t o CuCl2.2NHCl
' per 100 Gms.
Solution.
Solution.
10.5
3-
87
Ice
30
27
.70 (
10.8
20.
12
Ice
40
3
47
ii
20.
3
Ice + CuCl 2 .2NH 4 Cl. 2 H 2 O
50
33
.24
10
20.
46
CuCl i .2NH 4 C1.2H 2
60
36
13
22.
02
*'
70
39
35
12
24.
26
"
80
43
.36
20
25.
95
u
Solid
Phase.
CuCl 2 .2NH 4 Cl. 2 H 2 O
SOLUBILITY OF CUPROUS CHLORIDE IN AQUEOUS SOLUTIONS OF CUPRIC
SULPHATE AT ABOUT 20.
(Bodlander and Storbeck Z. anorg. Chem. 31, 22, '02.)
Millimols per Liter.
Grams per Liter.
CuSO 4 .
Total Cu.
Total Cl.
Cu(ic).
Cu(ous).
CuS0 4 .
Total Cu.
Total Cl.
Cu(ic).
Cu(ous).
2.880
5-3 12
2.258
O.622
o.
o
O.
183
0.188
0.143
O.O4O
0.987
3.602
4.908
3-145
0-457
0.
158
0.
229
0.174
O. 2OO
0.029
1-975
4-553
4.687
4-I3 1
0.422
0.
3 I 5
O.
290
0.166
0.263
0.027
2.962
5-*93
4.256
4.625
0.509
0.
473
0.
330
0.151
0.292
0.032
4-937
7.276
4-329
6.546
0.730
0.
788
0.
463
0.154
0.416
0.046
SOLUBILITY OF CUPROUS CHLORIDE IN AQUEOUS SOLUTIONS OF POTASSIUM
CHLORIDE AT i8-2o EXCEPT DETERMINATIONS IN 3RD, 7TH, STH, AND
LAST LINE, WHICH ARE AT 1 6.
(Bodlander and Storbeck.)
Millimols per Liter.
Grams per Liter.
KC1
. Total Cu.
Total Cl.
Cu(ic).
Cu(ous).
KC1.
Total Cu.
Total Cl.
Cu(ic).
Cu(ous)
2.851
5.436
2.222
0.629
0.
O.lSl
0.193
o. 141
O.O4O
2.
5 I -955
6.015
I.42I
534
0.
186
O.I24
0.213
O.OOO
0.034
5
1.522
7.525
1.008
5M
0.
373
0.097
0.267
0,069
0.033
10
1.236
n-735
0.475
o
.761
0.
746
0.079
0.416
0.030
0.048
20
1.446
21.356
0.324
I
.122
I.
492
0.092
0.759
0.021
O.O7I
5
2.411
not det.
0. 1088 2
.302
3-
730
0.153
not det.
O.OO7
o. 146
100
4.702
M
o.ooo
4
.702
7-
460
0.299
n
0.000
0.209
2OO
9-485
11
0.000
9
.485
14-
920
0.603
it
0.000
0.603
1000
97.0
it
0.000
97
.O
74-
60
6.170
ft
0.000
6.170
2OOO
384.0
tt
0.000
384
.0
149.
2
24.42
tt
0.000
24.420
SOLUBILITY OF COPPER CHLORIDE IN AQUEOUS SOLUTIONS OF SODIUM
CHLORIDE.
(Hunt Am. J. Sci. [2] 49, 154, '70.)
Grams CuCl 2 per 100 cc. Solution of:
II
40
90
Sat. NaCl.
8.9
11.9
16.9
15% NaCl. 5% NaCl.
I.I
2.6
127
COPPER CHLORIDE
SOLUBILITY OP COPPER CHLORIDE AND POTASSIUM CHLORIDE DOUBLE
SALTS AND MIXTURES IN WATER.
(Meyerhoffer Z. physik. Chem. 5, 102, '90.)
39-4
49-9
60.4
79.1
90-5
93-7
98.8
o
39-6
50.1
5 2 -9
60.2
72.6
64.2
72-5
Cl per i Gram Solution.
Present as
Present as'
CuCl 2 .
KC1.
O.I2O
o . 107
0.129
O.II5
0.142
0.125
0.168
0.142
0.188
0.154
0.194
0.156
0.197
O.l62
0.214
0.021
0.232
O.O49
0-233
0-059
0.241
O.O62
0.246
0.066
0-255
0.063
Mols.penoqMols.HzO.
CuCl 2 .
KCl.
5.56
9-93
6 39
ii. 4
7.71
13.6
n. i
18.8
14.9
24.4
16.2
26.0
17.5
28.7
9.84
1.94
12.9
5-44
13-7
6.90
14.8
7-63
15.8
8.49
16.8
8-35
14.9
n. 6
14.8
15.0
Solid
Phase.
CuCl 2 .2KC1.2H 2 + Kd
CuCl 2 .KCl + KC1
CuCl 2 .2KC1.2H 2 H- Cud 2 .2H 2 O
CuCl 2 .KCl + CuCl 2 . 2 H 2 O
CuCl 2 . 2 KC1.2H 2 O + CuCl 2 .KCl
CuCl 2 JCCl
SOLUBILITY OP CUPRIC CHLORIDE IN SEVERAL SOLVENTS.
(Etard Ann. chim. phys. [7] 2, 564, '94; de Bruyn Z. physik. Chem. 10, 783, '92; de Coninck
Compt.rend. 131, 59, 'oo; St. von Laszczynski Ber. 27 2285, '94.)
Solvent.
Methyl Alcohol
Ethyl Alcohol
Propyl Alcohol
Iso Propyl Alcohol
n Butyl Alcohol
Allyl Alcohol
Ethyl Formate
Ethyl Acetate
Acetone (abs.)
Acetone (80%)
Ether
* (CuCl 2 .2 Aq.)
For the solubility of cupric chloride in mixtures of a number of
organic solvents, see de Coninck.
Grams CuCl 2 per
100 Grams Sat. Solution at:
0.
15.
20. 4 0. 80.
36
40.
5 (de B.)
36
5
37
O
32
35-
o (deB.)
35
7
39
O
29
30
5
30
5
. . .
... *
16
o 30
.0
15
15
3
16
.0 16
5
23
23
.0
.
10
9
.0
8.
o
...
. . .
3
.0
2
5 I
3 (
72)
8.86*
8.
9 2 t
2
.88
(18) ..
i
.40
(56;
18
9*
.
o.
043 ()
o
.11
.
q.) f (CuCl 2 .2 Aq.)
t (23 CuCl 2 .2 Aq.)
COPPER CHLORIDE
128
IN AQUEOUS ALCOHOL AT 11.5.
Chem. 22, 507, '97.)
indicated amounts of CuCl 2 were
The solutions shaken two hours,
SOLUBILITY OF CUPRIC CHLORIDE
(Bodtker Z. physik.
10 gms. of CuCl 2 2H 2 O and the
added to 20 cc. portions of alcohol.
5 cc. portions withdrawn.
Vol.% Gms.CuCl 2 Gms. per 5 cc. Solution.
Alcohol. Added. H 2 O. CuCl 2 ."
89.3 o.o 0.794 I - I 37
92.0 o.o 0.648 1.090
96.3 o.o 0.478 1.116
99.3 o.o 0.369 i. 208
COPPER NITRATE (ic) Cu(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt, 3, 440, 'oo.)
Vol. % Gms. CuCl 2
Alcohol. Added.
Gms. per 5 cc. Solution.
H 2 0.
CuCl 2 . '
99-3
0.223
0.330
1.295
99-3
0.887
0.247
1.639
99-3
1.540
O.I9I
2.086
99-3
i-957
0.164
2.400
Gms.
Mols.
Gms.
Mols.
Cu(N0 3 ) 2 Cu(N0 3 ) 2
t . per 100 Gms. per 100 Solid Phase.
Solution. Mols. H 2 O.
Cu(N0 3 ) 2 Cu(N0 3 ) 2
t . per 100 Gms. per 100 Solid Phase.
Solution. Mols. H 2 O.
23
36
.08
5
, 42 Cu(NO3)2^H2O
20
55
58
12
.0
Cu(NO 3 ) 2 .6H 2 O
20
40
.92
6
.65
26.4
63
39
16
7
"
.
21
39
S 2
6
27 Cu(N03) 2 .6H 2
25
60
.01
14
4
Cu(N0 3 ) 2 . 3 H20
45
.00
7
,8 7
40
61
5i
I 5
.2
"
+ 10
48
79
9
J 5
60
64
17
17
.2
18
53
,86
ii
20
80
67
5i
20
O
II4-5
77
59
33
3
to
Density of solution saturated at 18 = 1.681.
COPPER SULPHATE CuSO 4 .5H 2 O.
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 528, '94; Patrick and Aubert Trans. Kansas Acad. Sci. 19, '74 ;
15, Cohen Z. Electrochem. 9, 433, '03; at 25, Trevor Z. physik. Chem. 7, 470, '91.)
Gms. CuSO 4 per too Gms.
I .
10
Solution.
12-5
14.8
Water.
14-3
17.4
20
25
17.2
I8. 5
20-7
22-7
30
40
20-0
22-5
25.0
28-5
50
25.0
33-3
i .
Solution.
Water.
60
28.5
40-0
80
35-5
55-o
100
43-o
75-4
120
44-o
78.6
140
44-5
80.2
160
44.0
78.6
180
43-o
75-4
SOLUBILITY OF COPPER SULPHATE IN AQUEOUS SOLUTIONS OF SUL-
PHURIC ACID AT o.
(Engel Compt. rend. 104, 507, '87.)
Grams per 100 Grams
Milligram Equiv. per 10
Gms. H 2 O.
Sp. Gr. of
H 2 SO 4 .
CuSO 4 .
OU1UUU11S.
H 2 S0 4 .
CuSO 4 .
o.o
18.6
1.144
o.oo
14-85
4.14
17.9
1. 143
2.03
14.29
14.6
19.6
1.158
7.16
15.65
31-0
12.4
1.170
15.20
9.90
54-2
8.06
1-195
26.57
6-43
5 6 -25
7-75
I. 211
27-57
6.19
71.8
5-o
1.224
35-2
3-99
1 29 COPPER SULPHATE
SOLUBILITY OF COPPER SULPHATE IN AQCJEOUS SOLUTIONS OP AMMO-
NIUM SULPHATE AT o.
(Engel Compt. rend. 102, 114, '86.)
Milligram Equiv. per Grams per
10 cc. Solution. fP- ^ r - 100 cc. Solution.
Solutions.
(NH 4 ) 2 SO 4 . CuSO 4 . (NH 4 ) 2 SO 4 . CuSO 4 .
o.o 18.52
5-45 20.15
7.0 10.5
7.4 9.1
8.45 6.425
n-35 3-7
18.6 1.178
31.2 i.o
.144 o.o 14-79
.190 3.61 16.09
.108 4.63 8.38
099 4.90 7.26
8l 5 5-59 5-13
.071 7.51 2.95
.082 12.31 0.94
.116 20.65 0.80
MIXTURES OF COPPER AMMONIUM SULPHATE AND NICKEL AMMONIUM
SULPHATE IN WATER AT 13 1 4.
(Fock Z. Kryst. Min. 28, 394, '97.)
CuSO 4 .(NH 4 ) 2 SO 4 .6H 2 O NiSO 4 .(NH 4 ) 2 SO 4 .6H 2 O.
Mol. % in Solution.
Mols. per 100 Mols. H 2 O.
Mol.
% in
Solid Phase.
CuT
Salt.
Ni Salt.
Cu Salt.
Ni Salt. '
Cu.
Salt.
Ni Salt.
o
OO
100
.00
O
.00
O
.521
O
.00
100
OO
33
34
66
.66
.1476
0.295
10
.29
8 9
71
56
05
43
95
O
.2664
.2089
30-59
6 9
-41
73
.89
26
.20
.4165
.1449
52
23
47
77
79
.92
20
.08
o
.4785
.1202
78
.80
21
.20
100
.00
O
OO
I
0350
o
.00
100
.0
O
.00
MIXTURES OF COPPER AMMONIUM SULPHATE AND ZINC AMMONIUM
SULPHATE IN WATER AT i3-i4.
(Fock.)
CuSO 4 .(NH 4 ) 2 SO 4 .6H 2 O ZnSO 4 .(NHJ 2 SO 4 .6H 2 O.
Mol.% in Solution. Mols. per TOO Mols. H 2 O. Mol. % in Solid Phase.
Cu. Salt. Zn Salt. ' Cu Salt. Zn Salt." Cu. Salt. Zn Salt.'
4-97 95-03 0.0422 0.8069 2.39 97-61
10.65 89.35 0.0666 0.5638 4.52 95.48
19.24 80.76 0.1218 0.5115 9.03 90.97
30.19 69.81 0.2130 0.4924 14-67 85.33
44.44 55.56 0.3216 0.4022 22.62 77.38
100.00 o.oo I -35 o.ooo 100 o-ooo
SOLUBILITY OF COPPER SULPHATE IN AQUEOUS SOLUTIONS OF
MAGNESIUM SULPHATE AT o.
(Diacon Jahresber. Chem. 61, '66.)
Grams per 100 Gms.HzO. Solid Grams per ioo Gms. HzO. Solid
CuS0 4 . "MgS0 4 . ' CuS0 4 . MgS0 4 .
O 26.37 MgSO 4 .6H2O 12.03 15-67 CuSO 4 .sH20
2.64 25.91 " I3-6l 8.64
4.75 25.30 " 14-99 o.oo
9-01 23 . 30 MgSO 4 .6H2O + CuSO^sHaO
COPPER SULPHATE
130
COPPER SULPHATE, MANGANESE SULPHATE, MIXED CRYSTALS AT 25.
(Stortenbecker Z. physik. Chem. 34, 112, 'oo.)
Gms. per 100 Gms. H 2 O.
CuSO 4 . MnSOl.
Triclinic Crystals with sH 2 O.
20. 2 O
19.76 3.69
I3-65 3I-52
ii. 61 39.41
Mols. per 100 Mols. H 2 O.
Mn. '
Cu.
2.282
2.23
Mol. % Cu
in Solution.
Mol. % Cu
in Crystals.
I-3 1
O
0-44
3-76
4-70
9-39
46.77
i. 06
5-59
6.47
53-39
o-73
6-37
3.01
58 93
o-34
7-03
o.o
61.83
o.o
7-375
100
100
90.5
83-5
99-3
74.1
97-3
57-7
31.0
81
29.0
26.1
21.8
70.4
21 .2
42.6
20. o
34-4
15-9
13-45*
22.9
15.2*
10.27
10.5
4*6
4-9
2.31
2-15
o.o
IOO.O
Monoclinic Crystals with 7H 2 O.
9-39 46 77 i -06
6-47 53-39 -73
O-O
o.o
5-58
6-37
8*
20. o
J 3-45
10.27
4.6*
o.o
28.2
23-5
20.8
16.0
S-8*
100
Indicates points of labil equilibrium.
COPPER SULPHATE, ZINC SULPHATE, MIXED CRYSTALS IN WATER.
(Stortenbecker Z. physik. Chem. 22, 62, '97.)
Triclinic Crystals with sH 2 O.
ols. per TOO I
Aols. H 2 O.
Mol.% Cu
Mol.% Cu
Cu.
Zn.
in Solution.
in Crystals.
2.28
O
100
100
83
2.08
46.8
94-9
-41
3-60
28.1
86.4
.19
5-oi
19.2
77-9
.86
3-36
36.2
40.4
.22
4-45
21-5
29-5-3I-9
-01
4-72
17.6
24.1-28.
0.82
5-03
14.0
19.0-22.
0.51
5-59
8.36
12.4-14.9
0.30
5-56
4.87
7.02
o.o
6.42
o.o
o
1.19
5-oi
19 2
5.01
0.51
5-59
8.^6
1.97
0.267
5-77
4.42
I-I5
o.o
5-94
o.o
0-00
Monoclinic Crystals with 7H 2 O.
Rhombic Crystals with 7H 2 O.
COPPER SULPHATE
SOLUBILITY OF COPPER SULPHATE, SODIUM SULPHATE MIXTURES IN
WATER.
(Koppel Z. physik. Chem. 42, 8, 'oi-'o2; Massol and Maldes Compt. rend. 133, 287, '01.)
Mols. per 100 Mols.
. per
Sol
CuSO 4 .
Na,S0 4 .
CuS0 4 .
Na 2 SO 4 .
13
.40
6
23
I
.88
.98
10
14
.90
9
.46
2
23
I
56
15
15
.18
ii
.64
2
23
2
.02
17
7
14
34
13
34
2
.24
2
34
23
.0
14.36
12
.76
2
23
2
.21
40
15
13-73
12
.26
2
.10
2
.10
17
7
14
99
13
.48
2
37
2
39
23
16
.41
II
35
2
57
I
99
40
.15
20
56
8
.0
3
-25
I
47
18
13
53
13
.84
2
.10
2
.41
20
II
34
15
.70
I
.76
2
73
25
6
.28
21
.20
O
.98
3
.70
30
2
.607
28
38
O
43
5
.21
33
9
I
475
32
30
O
25
6
.18
37
.2
I
494
3 1
.96
O
25
6
.08
30
5
38
22
17
.1
3
.69
25
37
3
i
57
32
.09
Solid Phase.
CuSO 4 . 5 H 2 O + Na 2 S0 4 .ioH 2 O
CuSO 4 .Na 2 SO 4 .6HjO
44
CuSO 4 .Na 2 S0 4 .6H2O + CuSO^sHzO
CuSO 4 .Na 2 S0 4 .6H 2 O + Na,SO 4 .ioH 2 O
CuSO 4 .Na 2 SO 4 .6H 2 O + increasing
amts. of Na 2 SO 4 .ioH 2 O
SOLUBILITY OF COPPER POTASSIUM SULPHATE CuK 2 (SO 4 ) 2 .6H 2 O m
WATER AT 25.
100 grns. H 2 O dissolve 11.14 gms. CuK 2 (SO 4 ) 2 .
(Trevor Z. physik. Chem. 7, 470, '91.
SOLUBILITY OF COPPER SULPHATE IN METHYL AND ETHYL ALCOHOL,
ETC.
(de Bruyn Z. physik. Chem. 10, 786, '92; de Coninck Bull. acad. roy. Belgique, 257, '05.)
Gms. per 100 Gms. Solvent. SOLUBILITY IN AQUEOUS
Cuso 4 . CuS0 4 . 5 H 2 o. ALCOHOL AT i5 P .
I .05 15 .6 (Schiff Liebig's Ann. 118, 365, '6i/>
0.93
0.40
Solvent.
Methyl Alcohol Abs. 18
93-5% 18
50% 18
Abs. 3
Ethyl Alcohol Abs. 3
Glycol 14.6
Glycerine 15.5
Alcohof.
Gms. CuSO 4 . 5 H 2 O
per 100 g. Solvent.
... I.I
... 7 .6*
30.0
* Per 100 g. sol.
10
20
40
3-2
0.25
COPPER SULPHIDE CuS.
SOLUBILITY IN AQUEOUS SUGAR SOLUTIONS.
(Stolle Z. Ver. Zuckerind. 50, 340, f oo.)
% Sugar
in Solvent.
Gms. <Jui> per
.Liter ol Aq. sugar
ooiuuon M;
^i7-5.
45.
7S-
10
30
50
0.5672
0.8632
0-9076
0.3659
O.722O
1.0589
I-I345
1-2033
I . 2809
COPPEB TARTRATE 132
COPPER TARTRATE CuC 4 O 6 H 4 . 3 H 2 O.
SOLUBILITY IN WATER.
(Cantoni and Zachoder Bull. soc. chim. [3] 33, 7^1, '05.)
t<>.
Cms.
per ioo cc.
t. C
Cms.
:uC 4 6 H 4 . 3 H 2
per ioo cc.
tv
Cms.
CuC 4 6 H 4 . 3 H 2
per ioo cc.
Solution.
Solution.
Solution.
15
0.0197
40
0.1420
65
0.1767
20
o . 0420
45
0.1708
70
0.1640
25
0.0690
50
O.I92O
75
'. 0.1566
30
0-0890
55
0.2124
80
0.1440
35
0.1205
60
0.1970
85
0.1370
ORE80L C 6 H 4 (OH).CH 3 o, m and p.
SOLUBILITY IN WATER AT 20.
(Vauhel J. pr. Chem. [2] 52, 72, 'PS-) *
ioo grams of the saturated aqueous solution contain :
^_ . * ^
2.45 grams o cresol, 2.18 grams m cresol, 1.^94 grams p cresol.
DISTRIBUTION OF CRESOL BETWEEN WATER AND ETHER.
(Vaubel J. pr. Chem. [2] 67, 472. '03.)
Composition of Solvent. Cms. Cresol in JJ 2 O Layer. In Ether Layer.
200 cc. H 2 O+ ioo cc. Ether -5Jf. I -0760
200 cc. 1^0 + 200 c.c. Ether o.oi^o i .1144
OUMINIC ACID C 3 H 7 C 6 H 4 .COOH (p Iso Propyl Benzoic Acid).
SOLUBILITY IN WATER AT 25.
(Paul Z. physik. Chem. 14, in, '94.)
1000 cc. sat. solution contain 0.1519 gm. or 0.926 millimol Cuminic
Acid.
PseudoOUMIDINE (CH ;! ) 3 .C 6 H 2 .NH 2 (sym. 5 Ammo, i, 2, 4, Trimethyl
benzene).
SOLUBILITY IN WATER.
(Lowenherz Z. physik. Ch. 35, 412. *98.)
t. 19.4. 23.7. 28.7.
Cms. ^ Cumidine per liter H 2 O i . 198 j . 330 i .498
CYANOGEN CN.
SOLUBILITY IN SEVERAL SOLVENTS AT 20.
(Gay Lussac.)
Solvent. Vols. CN per i Vol. Solvent.
Water 4.5
Alcohol 23.0
Ether 5.0
Oil of Turpentine 5 -o
133 DIDYMIUM SULPHATE
DIDYMIUM SULPHATE Di 2 (SO 4 ) 3 .
SOLUBILITY IN WATER.
(Marigrac Ann. chim. phys. [3] 38, 170, '53.)
o t ._
Gins.HaO.
12 43-1
18 25.8
25 20.6
38 13.0
50 n. o "
Gms.HjsO.
Phase.
?
19
34-o
II.7
Di,(S0 4 ) 3 .6H 2 O
Di 2 (S0 4 ) 3 .8H 2
40
8.8
H
50
6.5
tt
IOO
1.8
tt
DIDYMIUM POTASSIUM SULPHATE K 2 SO 4 .Di 2 (SO 4 ),. 2 H 2 O.
(Marignac.)
ioo gms. H 2 O dissolve 1.6 grams double salt at 18.
ERBIUM SULPHATE Er 2 (SO 4 ) 8 .
SOLUBILITY IN WATER.
(Hoglund.)
ioo gms. H 2 O dissolve 43.0 gms. Er 2 (SO 4 ) 3 at o.
ioo gms. H 2 O dissolve 23.0 gms. Er 2 (SO 4 ) 3 .8H 2 O at 20.
EBYTHRITE CH 2 OH(CHOH) 2 CH 2 OH.
ioo grams saturated solution in pyridine contain 250 gms. at 26.
(Holty J. Physic. Chem. 9, 764, '35 v
ETHANE C 2 H fl .
SOLUBILITY IN WATER.
(Winkler Ber. 34, 1421, 'ox.)
t.
ft.
p.
<?
t.
ft-
p.
o
o
.0987
o
.0982
0.0132
40
o
.0292
o
0271
0.0037
5
.0803
.0796
0.0107
50
o
.0246
.0216
0.0029
10
.0656
o
.0648
0.0087
60
,0218
0175
0.0024
15
o
0550
.0541
0.0073
70
,0195
0135
0.0018
20
.0472
.0462
0.0062
80
o
0183
.0097
0.0013
2 5
.0410
.0398
0.0054
90
o
0176
o
.0054
0.0007
30
.0362
0347
0.0049
IOO
0172
.0000
o.oooo
/? = Absorption coefficient, i.e., the volume of gas (reduced to o
and 760 mm.) absorbed by i volume of the liquid when the pressure
of the gas itself without the tension of the liquid amounts to 760 mm.
/?' = Solubility, i.e., the volume of gas (reduced to o and 760 mm.)
which is absorbed by one volume of the liquid when the barometer
indicates 760 mm. pressure.
q the weight of gas in grams which is taken up by ioo grams erf
the pure solvent at the indicated temperature and a total pressure
(that is, the partial pressure of the gas plus the vapor pressure of the
liquid at the absorption temperature) of 760 mm.
ETHER
ETHER (C 2 H 6 ) 2 0.
RECIPROCAL SOLUBILITY OP ETHER
AND WATER.
(Klobbie Z.physik.Chem. 24, 619, '97; Schuncke Ibid. 14,334, '94; St.Tolloczko
'96-)
Ibid. 20, 407,
Solubility of Ether in Water.
Lower Layer Aqueous.
, Gms. (C 2 H 5 ) 2 O per 100 Cms.
Solubility of Water in Ether.
Upper Layer Ethereal.
Gms. H 2 O per too Gms.
i r
Water.
Solution.
o
13.12
ii. 6
5
II. 4
IO.2
10
9-5
8. 7
15
8.2
7 .6
20
6-95
6-5
25
6.05
5-7
3
5-4
5- 1
*4o
4-7
4-5
*5<D
4-3
4.1
*6o
3-8
3-7
* 7 o
3-3
3-2
*8o
2.9
2.8
Ether.
OI
Solution.
I .0
.06
1.05
.12
1. 12 (2
.6, S.)
.16
I .15
.20
1.20 (2
65, S.)
.26
1.26
33
1.32
1.52
1.50
i.S 3
1.8
2.04
2.0
2.25
2.2
* Indicates determinations made by Synthetic Method, for which see page 9.
100 cc. H 2 O dissolve 8.11 cc. ether at 22; Vol. of solution 107.145 cc.,
Sp. Gr. 0.9853.
100 cc. ether dissolve 2.93 cc. H 2 O at 22; Vol. of solution 103.282,
Sp. Gr. 0.7164. (Herz Ber. 31, 2671, '98.)
For recent determinations of the density of ether, see Christomanos
Z. anorg. Chem. 45, 136, '05.
SOLUBILITY OF ETHER IN AQUEOUS SOLUTIONS OF HYDROCHLORIC
ACID.
(Schuncke Z. physik. Chem. 14, 334, '94; in 38.52% HC1, Draper Chem. News, 35, 87, '77.)
In 38.52 %HC1.
In 31.61 %HC1.
In 20 % HC1.
cc. Ether
cc. Ether
Gms. per i Gram H 2 O. cc. Ether Gms. per i g. HjjO.
t . per 100 cc.
Solvent.
per 100 cc.
Solvent.
HCl.
(C 2 H 5 ) 2 0.
er 100 cc.
Solvent. rid.
(C 2 H 6 ) 2 0,
-6
181
149
0.4622
I-387
67.2 o.
253
0.5637
177.
5
142
0.4622
1.308
58.3 o.
253
0.4863
4-6
172.
5
131 .5
0.4622
1.2075
51.1 o.
253
0.4231
15
163
I2I-7
(14
)
0.4622
I.I075
40 . 5 o .
253
0.3299
20
158
116.9
(20.
8)
0.4622
1.0005
33.1 o.
253
0.2688
26
'35
104.2
0-4622
0.9360
27.5 o.
253
O-222I
In
12.58
% HCl.
In 3.65 % HCl.
t
cc
. Ether per Gms . per i Gram H 2 O .
cc. Ether per
Gms. per i Gram H 2 O.
* .
IOOCC.
Solvent.
HCl.
(C 2 H S ) 2 0.
100 cc. Solvent
HCl.
(C 2 H5)20.
-6
26
45
.144
O
2IO6
19.23
0-0308
O-
1454
22
.19
O
.144
o
1748
4-6
J 9
.18
.144
I5 O 3
I4-3 1
0.0308
O-
1070
15
15
.61
.144
o
1210
11.83
0-0308
o.
0868
20
.76
o
.144
o
,1059
10.52
0-0308
o-
0769
26
12
.70
o
.144
0970
9.24
0-0308
o.
0673
135
ETHER
SOLUBILITY OP ETHER IN AQUEOUS SALT, ETC., SOLUTIONS AT 18.
(Euler Z. physik. Chem. 49, 306, '04.)
Aq. Solu-
tion of:
Gms. per
Liter Added
Salt.
Gms. (C^)^
per 100 cc.
Solvent.
^MSM?" Liter Added p' 100*0:.
Salt. Solvent.
Water
o.o
7-8
Na 2 S0 4
59-54
3-7
KNO 3
101.19
5-4
Mannite
91.06
6.7
KC1
73-6
4-7
H 2 S0 4
49.0
6.6
LiCl
42.48
S- 2
U
122.5
5 -65
NaCl
58-5
4-5
(t
245.0
4-55
SOLUBILITY OF ETHER IN AQUEOUS ETHYL ALCOHOL AND IN AQUEOUS
METHYL ALCOHOL MIXTURES AT 20.
(Bancroft Phys. Rev. 3, 122, '95-' 96.)
In Ethyl Alcohol.
In Methyl Alcohol.
Per 5 cc. Alcohol.
Per 5 cc. Alcohol.
Per i cc. CH 3 OH.
Pence CHaOH.
cc.HaO*
cc.tCijHjOzO.f
cc.H 2 O* cc.l
[CaHdaO.t cc.H 2 0.
cc.(C2Ht)30.
cc.HzO.
cc.(C 2
50
I
30
4-45
7
.0
10
1.13
0.83
I
.80
25
I
.70
4-0
7
.8
7
0.85
0.64
3
.00
10
2
.41
3-87
8
.0
4
o.oo
0.52
5
-o
8
3
35
3.10
10
.0
2
5
0.56
o-44
10
o
6
5
.10
2.08
15
.0
I
.8
0.63
o-45
15
.0
5-2i 6
.00
1.77
J 7
5
I
.0
1.23
* Saturated with ether.
t
Saturated with water.
ETHYL ACETATE CH 3 COOC 2 H 6 .
SOLUBILITY IN WATER AND IN AQUEOUS SALT SOLUTIONS AT 28.
(Euler Z. physik. Chem. 31, 365, '99; 49, 306, '04.)
Cone, of Salt C
Solution.
HaCOOCijHi}
per Liter.
Solvent f
Cone, of Salt
Solution.
CH3COOC2H6
per Liter.
Solvent.
Nor- Gms per
mality. Liter.
Gram
Mols.
Grams.
Nor- Gms. per Gram
mality. Liter. Mols.
Grams.
Water
O
O
O.
825
75-02
NaCl(at 18)
|
14.62
0.76
67.0
KNO 3
i
50.
59
0.
77
67.81
*
29.25
0.67
59-o
"
I
101.
o.
72
63-40
(t (t
I
58-5
0. 5 I
45-o
it
2
202.
38
0.
625
55-4
Na 2 SO 4
I
71.08
0.465
40.96
KC1
*
18.
4
o.
747
65.79
" (at 18)
\
35-54
0.61
54-o
"
i
36.
8
0.
685
65-33
I
71.08
0.42
37-o
a
I
73-
6
o.
575
50.64
MgS0 4
1
16.30
0-733
64.55
"
2
147.
2
0.
4i
36.11
tt
\
32.6
0-655
57-68
NaCl
J
14.
62
0.
745
65.61
it
I
65.21
0-505
44-47
"
29.
25
o.
677
59.62
ZnSO 4
\
20.18
0-733
64.55
"
I
58.
5
o.
545
47-99
"
\
40.36
0-653
57-5
tt
2
117.
0.
27.74
u
I
80.73
0.500
44-03
ETHYL ACETATE 136
SOLUBILITY OF ETHYL ACETATE IN AQUEOUS ETHYL ALCOHOL, METHYL
ALCOHOL, AND ACETONE MIXTURES AT 20.
(Bancroft Phys. Rev. 3, 122, 131, 'ps-'pe.)
In Ethyl Alcohol. In Methyl Alcohol. In Acetone.
Per i cc. C2H 5 OH. Per i cc. CH 3 OH. Per i cc.
cc. H 2 0*
10
CHaCOOC 2 H,.t cc ' H2 '
0.25 10
CHaCObCaHB. cc. H 2 O. CHsCOOCzH,.
I. 08 10 I. 01
8
0.27 3
O
.68
5
0.60
4
0-35
5
I
.69
2
0.43
2
1.02
.29
2
So
I
5
0.47
I
.06
2.50
.0
4
9
I
.0
0.63
65
S-o <
>. 9 8
7
o
O
.8
0.74
o
54
7.0
.0
8
.0
O
5 1
1. 00
o
44
10.
03
10
-0
o
25
2.00
o
.29
5-00
* Saturated 'with ethyl acetate.
t
Saturated with water.
ioo cc. H 2 O dissolve 7.26 g. ethyl acetate at 28.
(Euler Z. physik. Chem. 31, 360, '99.)
ioo cc. H 2 O dissolve 9.26 cc. ethyl acetate at 20.
ioo cc. ethyl acetate dissolve 2.94 cc. water at 20.
ETHYL BUTYRATE C 3 H 7 COOC 2 H 6 .
SOLUBILITY IN WATER AND IN AQUEOUS ETHYL ALCOHOL MIXTURES
AT 20.
ioo g. H 2 O dissolve 0.5 g. ethyl butyrate at 22.
(Traube Ber. 17, 2304, '84.)
ioo cc. H 2 O dissolve 0.8 cc. ethyl butyrate at 20. (Bancroft.)
ioo cc. ethyl butyrate dissolve 0.4 0.5 cc. H 2 O at 20.
Per 5 cc. ( cc. H 2 O 10 6 4 2.96 2.10
Ethyl Alcohol ( cc. C 3 H 7 COOC 2 H 5 0.34 0.96 2.47 4.00 6.0
ETHYL FORMATE HCOOC 2 H 5 .
ioo grams water dissolve 10 grams'ethyl formate at 22. (Traube.)
ETHYL PROPIONATE C 2 H 5 COOC 2 H 6 .
SOLUBILITY IN WATER AND IN AQUEOUS ETHYL ALCOHOL MIXTURES.
(Bancroft.)
ioo grams H 2 O dissolve 1.7 grams ethyl propionate at 22. (Traube.>
.... cc. HaO to cause separation of a second phase in
cc. Aicoi ixtures of the given amounts of Alcohol and 3 cc.
in Mixture. portions of Ethyl Propionate.
3 2 -32
6 6.87
9 I2 35
12 19-17
27.12
36.84
21 50.42
24 oo
3
1.42
39
53 -13
9
7.18
45
63.60
J S
14-13
57
90-53
21
22.40
72
131.0
27
31.62
81
180.0
33
41 .62
i 3 7 ETHTL VALERATE
ETHYL VALERATE C 4 H 8 COOC 2 H 6 .
ETHYL (Iso) VALERATE (CH,) 2 .CH.CH 2 COOC 2 H 6 .
SOLUBILITY OF EACH IN WATER AND IN AQUEOUS ALCOHOL
MIXTURES AT 20.
(Bancroft.)
ioo cc. water dissolve 0.3 cc. ethyl valerate at 25.
100 cc. water dissolve 0.2 cc. ethyl iso valerate at 20.
ioo cc. ethyl iso valerate dissolve 0.4+ cc. water at 20.
Mixtures of Ethyl Alcohol, Mixtures of Ethyl Alcohol,
Ethyl Valerate and Water. Ethyl Iso Valerate and Water.
Per 5 cc. Ethyl Alcohol.
ec. Alcohol* cc.H20.t cc. Alcohol* cc.H^.f ' ~ " C c Ethyl "
cc.H 2 0. IsoVal / rate .
10 0-15
8 0.23
6 0.46
5 0.72
4 1-23
* cc. Alcohol in mixture.
t cc. H^ added to cause the separation of a second phase in mixtures of the given amounts of alcohol
and 3 cc. portions of ethyl valerate.
Di ETHYL KETONE (3 Pentanon) (C 2 H 5 ) 2 CO.
SOLUBILITY IN WATER.
(Rothmund Z. physik. Ch. 26, 433, '08 )
Determinations made by Synthetic Method, see page 9.
Cms. Di Ethyl Ketone Cms. Di Ethyl Ketone
t. per ioo Gms. t. per TOO Cms.
Aq. Layer. Ketone Layer. Aq. Layer. Ketone Layer.
20 4 . 60 ... ioo 3 . 68 93-io
40 3-43 97-42 120 4-05 90.18
60 3.08 96.18 140 4.76 87.01
80 3.20 94-92 ioo 6.10 83.33
ETHYL BROMIDE C 2 H 6 Br.
SOLUBILITY IN ETHER.
(Parmentier Compt. rend. 114, 1002, '92.)
t. 13. o. 12. 22.5. 32.
G. C 2 H 5 Br per ioo gms. Ether 632 561 462 302 253
SOLUBILITY OF ETHYL BROMIDE, ETC., IN WATER.
(Rex Z. physik. Chem. 55, 355, '06.)
Grams per ioo Grams H 2 O at:
Dissolved Substance.
o. 10. 20. 30.
Ethyl Bromide 1.067 0.965 0.914 0.896
Ethyl Iodide 0.441 0.414 0.403 0.415
Ethylene Chloride 0.922 o . 885 o . 869 o . 894
Ethylidene Chloride 0.656 0.595 0.550 0.540
ETHYL OARBAMATE 138
ETHYL OARBAMATE CO(OC 2 H 5 )NH 2 . (See also Urethane, p. 347.)
SOLUBILITY IN SEVERAL SOLVENTS AT 25.
(U. S. P.)
Solvent. Water. Alcohol. Ether. Chloroform. Glycerine.
Cms. CO(OC 2 H 5 )NH 2 ,,
per 100 gms. solvent Ioo+ l66 77 33
ETHYLENE C 2 H 4 .
SOLUBILITY IN WATER AND IN ALCOHOL.
(Bunsen and Carius; Winkler Landolt and Bornstein, Tabellen, jd ed. p. 604, '06.)
* - ft - Solubility in Alcohol,
o 0.226 0.0281 . ~
t o Vols. C2H 4 per
5 O.IQI O.O237 100 Vols. Alcohol.
10 0.162 0.0200 o 359-5
15 0.139 0.0171 4 337.5
2O O.I22 O.OI5O IO 308.6
25 0.108 0.0131 15 288.2
30 0.098 0.0118 20 271.3
For )3 and q see Ethane, page 133.
SOLUBILITY OF ETHYLENE IN METHYL ALCOHOL AND IN ACETONE.
(Levi Gazz. chim. ital. 31, II, 513, '01.)
Results in terms of the Ostwald Solubility Expression /. See p. 105.
t.
In Methyl Alcohol.
In Acetone.
t.
In Methyl Alcohol.
In Acetone.
o
3-3924
4.0652
30
1-8585
1. 8680
10
2.8831
3-3580
40
I -343 2
1.0852
20
2.3718
2.6278
50
0.8259
0.2772
25
2.II54
2.2500
60
0.3506
The formulas from which the above figures were calculated are:
In Methyl Alcohol, / = 3 .3924 0.05083 / o.ooooi t z .
In Acetone, / = 4.0652 0.06946 / 0.000126 t 2 .
FATS.
SOLUBILITY OF THE FATTY ACIDS OBTAINED FROM SEVERAL SOURCES
IN ALCOHOL AND IN BENZENE.
(Dubois and Fade Bull. soc. chim. [2] 44, '85.)
r* T?_i r* AI__
Gms. Fats
per 100 Gms.
Benzene at 12.
14.70
15.89
26.08
27.30
69.61
13-53
Crude
Fatty
Acid of:
rai per 100 ^
Alcohol at:
Tins. rt.DS.
0.
10.
26.
Mutton
2,48
, S-o 2
^7.96
Beef
2.51
6.05
8/T23
Veal
5.00
13-78
137.10
Pork
5-6 3
11.23
118.98
Butter
10. 61
24.81
158.2
Margarine
2-37
4-94
47.06
139 FUMARIO AOID
FUMARIC ACID COOH.CH:CH.COOH.
MALEIC ACID (CH) 2 (COOH) 2 .
SOLUBILITY IN WATER.
(Vaubel J. pr. Chem. [2] 59, 30, '99-)
ioo gms. water dissolve 0.672 gram fumaric acid at 165.
100 gms. water dissolve 50.0 grains maleic acid at 100.
FURFUROL C 4 H 3 OCHO.
SOLUBILITY IN WATER.
(Rothmund Z. physik. Chem. 26, 475, '98.)
Determinations by Synthetic Method, for which see page 9.
t o Gms. C 4 H3OCHO per ioo Gms. t<J Gms. C 4 H 3 OCHO per ioo Gms.
Aq. Layer. Furfur ol Layer. Aq. Layer. Furfurol Layer.
40 8.2 93.7 ioo 18.9 83.5
50 8.6 93.0 no 24.0 78.5
60 9.2 92.0 115 28.0 74-6
70 10.8 90.7 120 34.4 68.1
80 13.0 89.0 122.7 (crit. t.) 51-0
90 15.5 86.6
GADOLINIUM SULPHATE Gd 2 (SO 4 ) 3 .8HO.
SOLUBILITY IN WATER.
(Benedicks Z. anorg. Chem. 22, 409, *oo.)
t.
Gms. Gd 2 (SO 4 ) 3 per ioo
Gms H 2 0.
Solid Phase.
3-98
Gd 2 (S0 4 ) 3 .8H 2
10
3-3
tt
14
2.8
It
25
2.4
tt
34-4
2.26
tt
GALACTOSE C 6 H 12 O 6 .
ioo grams saturated solution in pyridine contain 5.45 grams C e H 12 O t
at 26, density of solution 1.0065.
(Holty J. Physic. Chem. 9, 764, '05 )
GALLIC ACID C 6 H 2 (OH 8 ) (3, 4, 5) COOH + H 8 O.
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; Bourgoin Ann. chim. phys. [5] 13, 406, '78.)
Gms. C 7 H 6 O5.H 2 O per ioo Gms.
soivem.
i .
Solvent.
Solution.
Water
25
I .20
1.18
Wafer
IOO
33-3
25.0
Alfohol (Abs.)
23-3
18.1
Alcohol (U.S.P.)
2 5
24.1
19-3
Alcohol 90%
38.8
18.9
Ether
25
2.56
2.50
Glycerine
25
8-3
7.66
GERMANIUM DIOXIDE 140
GERMANIUM DIOXIDE GeO 2 .
100 gms. H 2 O dissolve 0.405 gm. GeO 2 at 20, and 1.07 gins, at
100.
(Winkler J. pr. Chem. [2] 34, 177, '86; 36, i?7. '87-)
GERMANIUM (Mono) SULPHIDE GeS and GERMANIUM (Di)
SULPHIDE GeS 2 .
100 gms. H 2 O dissolve 0.24 GeS and 0.45 gm. GeS 2 .
(Winkler.)
GLASS.
For data on the solubility of glass in water and other solvents, see :
(Cowper J. Chem. Soc. 41, 254, '82; Emmerling Liebig's Annalen, 150, 257, '69; Bohling Z.
anal Chem. 23, 518, '84; Kreusler and Herzhold Ber. 17, 34. '84; Kohlrausch Ber. 24, 3561, '91;
Wied Ann. 44, 577, '91; Forster Ber. 25, '92; Mylius and Forster Ber. 22, noo, '89; Ber. 25, 70,
'92; Wartha Z. anal. Chem. 24, 220, '85, etc.)
GLYCOLIC ACID CH 2 OH.COOH.
SOLUBILITY IN WATER.
(Emich Monatsh. Chem. 3, 336, '84.)
t. 20. 60. 80. ioo.
Gms. Cl4OH(COOH)
per io?gms. H 2 '33 ' 2 35 0.850
GLUCINIUM SALTS. (See also Beryllium p. 63).
SOLUBILITY IN WATER AND IN ACETIC ACID SOLUTIONS.
(Marignac; Sestini Gazz. chim. ital. 20, 313, '90.)
Gms. Anhydrous Salt
Salt. Formula. Solvent. per 100 Gms. Solvent.^
At 20. At 100.
Glucinium potassium fluoride G1F 2 .KF Water 2.0 5.2
sodium " GlF 2 .NaF " 1.4 2.8
Glucinium hydroxide G1(OH) 2 Water + CO 2 sat. 0.0185 (G1O) ...
phosphate G1 3 (PO 4 ) 2 .6H 2 O 2% CH 3 COOH 0.055
10% 0.1725
CtLUTARIO ACID (Pyrotartaric) (CH 2 ) 3 (COOH) 2 .
SOLUBILITY IN WATER.
(Lamouroux Compt. rend. 128, 098, '99.)
GOLD Au.
SOLUBILITY OF GOLD IN POTASSIUM CYANIDE SOLUTIONS.
(Maclaurin J. Chem. Soc. 63, 729, '93.)
Gold disks placed in Nestler tubes with KCN solutions.
Grams Au Dissolved in 24 Hours in Nessler Tubes :
ici von
KCN.
Full.
*Full.
Oxygen
Passed in.
Oxygen -f-
Agitation.
O.I
1.0
5-o
O.OOI95
O.OOI62
0.0032
0.00331
0.00418
0.0046
0.00845
0-01355
O.OlSy
0.0472
20.0
SO.
0-0012
0-00043
0.00305
0.00026
O.OII5
0.00505
0.0314
O.OIOS
I4i GOLD CHLORIDE
GOLD CHLORIDE (Auric) AuCl 3 .
SOLUBILITY IN WATER, ETC.
100 gms. H 2 O dissolve 68 grains AuCl s .
AsCl 3 and SbCl 3 each dissolve about 2.5% AuCl 3 at 15, and 22% at
1 60.
SnCl 4 dissolves about 4% AuCl 3 at 160, and a trace at o.
(Lindet BuU. soc. chim. [2] 45, 149, '86.)
GOLD PHOSPHORUS TRI CHLORIDE (Aurous) AuClPCl 3 .
100 gms. PC1 3 dissolve i gram at 15, and about 12.5 grams at 120.
(Lindet Compt. rend. 101, 1492, '85.)
GOLD ALKALI DOUBLE CHLORIDES.
SOLUBILITY OF SODIUM GOLD CHLORIDE, LITHIUM GOLD CHLORIDE,
POTASSIUM GOLD CHLORIDE, RHUBIDIUM GOLD CHLORIDE, AND
CAESIUM GOLD CHLORIDE IN WATER.
(Rosenbladt Ber. 19, 2537, '86.)
Grams Anhydrous Salt per 100 Grams Solution.
If
NaAuCU.
LiAuCL,.
KAuCU.
RbAuCU.
CsAuCU.
10
58.2
53-i
27.7
4 .6
o-S
20
60.2
57-7
38.2
9.0
0.8
30
64.0
62.5
48.7
13-4
i-7
40
69.4
67-3
59 2
17.7
3-2
50
77-5
72.0
70.0
22.2
54
60
90.0
76.4
80.2
26.6
8.2
70
81.0
3 I.O
12.0
80
85-7
35-3
16.3
90
39-7
21.7
100
44-2
27-5
GUAIACOL C 6 H 4 (OH)OCH 3 1:2. GUAIAGOL CARBONATE C 6 H 4
(OCH 3 )O 2 .CO.
SOLUBILITY IN WATER, ALCOHOL, ETC.
(U. S. P.)
t Gms. per 100 Gms. Solvent.
Guuiacol. Guaiacol Carbonate.
Water 25 1.89
Alcohol 25 ... 2.08
Chloroform 25 ... 66.6
Ether 25 ... 7-69
Glycerine 25 100
aTriPhenyl GUANIDINE C 6 H 6 N:C(NHC 6 H 6 ) 2 .
SOLUBILITY IN MIXTURES OF ALCOHOL AND WATER AT 25.
(Holleman and Antusch Rec. trav. chim. 13, 292, '94.)
Gms. Gms.
Vol.% C 6 H 4 N:C(NHC 6 H 6 ) 2 Density Vol. % C 6 H 6 N:C(NHC 6 H 5 ) 2 Density
Alcohol. per too Gms. of Solutions. Alcohol, per 100 Gms. of Solutions.
Solvent. Solvent.
loo 6.23 0.8021 80 i. 06 0.8572
95 3.75 0.8158 75 0.67 0-8704
90 2.38 0.8309 70 0.48 0.8828
85 1.58 0.8433 60 0.22 0.9048
HELIUM
142
HELIUM He.
SOLUBILITY IN WATER.
(Estreicher Z. physik. Chem. 31, 184, '99.)
Absorption Coefficient.
^0 Cor. Barometic Vol. of
Pressure. Water.
Vol. of
He.
At Bar. Pressure
Minus H 2 O
Vapor Tension.
At 760 mm.
Pressure.
O
.
.
o
.000270
O.OI5O
0.5
764
.0
73
584
I
093
O
.0149
O.OI49
5
758
.0
73
578
I
.062
.OOO26O
O
.0144
0-0146
10
758
.0
73
597
X
.046
.000255
o
.0142
0-0144
15
757
.8 73.641
I
.008
.OOO246
o
.0137
O.OI4O
2O
758
4
73
.707
.996
.OOO242
o
0135
0.0139
25
762
3
73
793
983
.000238
o
0133
0.0137
30
764
4
73
897
985
. 000238
0.0133
0-0138
35
764
5
74
.0167
.972
.000234
o
.0131
0-0138
40
762
74
.147
O
957
o
.000232
o
.0129
0.0139
45
761
7
74
294
947
0.000229
.0127
O.OI4O
760
9
74
,461
.920
o
.OOO223
o
.0124
O.OI4O
For q and also Absorption Coefficient, see Ethane, page 133.
HEXANE C 6 H 14 .
SOLUBILITY IN METHYL ALCOHOL.
(Rothmund Z. physik. Chem. 26, 475, '98.)
Determined by Synthetic Method, see page 9.
Cms. Hexane^per 100 Cms.
t 'Alcoholic Hexane
Layer. Layer.
10 26.5 96.8
20 31.6 95.9
3 38-3 93-7
Cms. Hexane per 100 Cms.
* Alcoholic Hexane
Layer. Layer.
35 43-6 9*-2
40 52-7 85.5
42.6(crit. t.) 68.9
Solid
Phase.
C.H9NO,
HIPPURIO ACID C 6 H 6 CONH.CH 2 COOH.
SOLUBILITY IN AQ. POTASSIUM HIPPURATE SOLUTIONS AT 20.
(Hoitsema Z. physik. Chem. 27, 3*7. '98-)
Grams per Liter Solution.
C 9 H 9 N0 3 . KCDHgNO-j.
3.276 o.o
2.919 2.39
3.278 15.43
4.191 55.18
11.47 295.4
23.46 480.1
26.32 504.1 )CH 9 N
27.40 52I.4J C***
23-82 543-1
15.04 654.0
12. 18 775.7
ii. 60 777-8
5-55 773-4
1.917 771.3
773-4
Density
Gram Mols
per Liter Sol.
Solutions.
C e H 9 N0 3 .
KC 9 H 8 NO 3 .
OO2
O.Ol82
O
.003
0.0163
O.OII
.008
0.0183
0.071
O22
0-0234
0.254
.114
0-064
I. 3 6
I.I82
O.I3I
2.21
I .192
0.147
2.32
^^S
0-153
2-40
I. 201
0-133
2.50
1.239
0-084
3-oi
E.282
0.068
3-57
1.282
0.065
3-58
[.276
0.031
3-56
[.277
O-OII
3-55
1.277
o.oo
3-56
C 9 H 9 NO 3 .KC 9 H8NO 3 .H2O
+ KC 9 H 8 N0 3
143 HOMATROPINE HYDRO-
BROMIDE
HOMATROPINE HYDROBROMIDE C 16 H 21 NO 3 .HBr.
SOLUBILITY IN WATER, ETC.
(U. S. P.)
100 grains water dissolve 17.5 grams salt at 25.
100 grams alcohol dissolve 3.08 grams salt at 25, and 11.5 grams
at 60.
100 grams chloroform dissolve 0.16 gram salt at 25.
HYDRASTINE HYDROCHLORIDE
HYDRASTINE C 21 H 21 NO 6 .
C U H U NO 2 .HC1.
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; Muller Apoth.-Ztg. 18, 249, '03.)
Solvent.
Water
Alcohol
Benzene
Acetic Ether
Gms. C2iH 2l NOe per 100 Gms.
Solution .
Solvent.
Ether
Ether +H 2 O
Chloroform
CC1 4
Gms. per 100 Gms.
Solution at i8-22.
At l8-22.
0.0033
S.8 9
4-05
At 80.
0.025
5.9(60)
0.51
0.80
100 +
0.123
CuHuNOa-HCf.
0.078(25)
0.35(25 )
Petroleum Ether 0.073
HYDRAZINE SULPHATE N 2 H 4 .H 2 SO 4 .
100 grams water dissolve 3.055 grams N 2 H 4 .H 2 SO 4 at 22.
(Curtius and Jay J. pr. Chem. [2] 39, 39, '89.)
HYDROBROMIC ACID HBr.
SOLUBILITY IN WATER.
(Roozeboom Z. physik. Chem. 2, 454, '88; Rec. trav. chim. 4, 107, '85; 5, 358, '86; see also Pickering
Phil. Mag. [5] 36, 119, '93.)
Gms.HBr Dissolved^ 7 6o-76 5 mm.)
P 61 " I0 Cjms -
Water.
Solution.
- 2.5
255-0
7I-83
-15
239.0
70.50
O
221 .2
68.85
+ 10
210-3
67-76
15
2O4-O
67.10
25
193.0
65.88
50
63-16
75
I50-5
60.08
100
130.0
56-5 2
For p see
Ethane, page
J 33-
611.6
581.4
532-i
468.6
406.7
344-6
Gms. HBr Dissolved at
Lower Pressures per too
Gms. H 2 0.
1^5.0 (10 mm.)
108 . 5 (5 mm.)
HYDROCHLORIC ACID 144
HYDROOHLORIO AOID HC1.
SOLUBILITY IN WATER AT DIFFERENT TEMPERATURES AND
PRESSURES.
(Deicke
; Roscoe and Dittmar Liebig's Ann. 112, 334, '59; below o, Roozeboom Rec. trav.
cbim.3, 104, '84.)
At Different Temperatures and 760 mm. Pressure. At Different Pressures and o.
t.
cc. HClper
loocc.HgO.
Density.
Cms. HC1 per
100 g. Sol.
Gms. HC1 per
100 g. H 2 O.
Pressures.*
Gms. HC1 per
100 g. H 2 O.
525-2
1.2257
45-15
82.31
60
fa -3
4
497-7
I .2265
44-36
79-73
100
65-7
8
480.3
1.2185
43-83
78.03
'50
68.6
12
471-3
1.2148
43-28
76.30
200
70.7
14
462.4
1.2074
42.83
74.92
300
73-8
18
451.2
I . 2064
42-34
73-41
400
76-3
23
435-o
I .2OI4
41-54
71.03
500
78.2
30
. . .
. . .
40.23
67.3
600
80.0
40
38.68
63-3
750
82.4
So
37-34
59-6
1000
85.6
60
...
35-94
56.1
1300
89-5
* Pressures in mm. Hg minus tension of HjO vapor.
SOLUBILITY IN WATER AT TEMPERATURES BELOW o:
At a pressure of 760 mm. At pressures below and above 760 mm.
t. q. t. q. t. mm. Pressure. q.
-24 IOI.2 -15 93.3 -23.8 ... 84.2
~2i 98.3 -io 89.8 -2i 334 86.8
18.3 96.0 5 86.8 19 580 92.6
18 95.7 o 84.2 18 900 98.4
-17.7 1073 101.4
For value of q, see Ethane, page 133.
SOLUBILITY OF HYDROCHLORIC ACID GAS IN METHYL ALCOHOL, ETHYL
ALCOHOL, AND IN ETHER AT 760 MM. PRESSURE.
(de Bruyn Rec. trav. chim. n, 129, '92; Schuncke Z. physik. Chem. 14, 336, '94.)
Grams HC1 gas per 100 Grams Solution in:
10
- 5
o
+ 5
10
15
20
*5
30
CH 3 OH.
C 2 H 6 OH.
(C 2 H 5 ) 2 0.
^4.6
37 5 1 (-9
.2)
37-o
5!-3
45-4
35-6
44.2 (6.5)
33 - 1
42.7(11.5)
30.35
27 .62
47-0(18)
41 .0
24.9
40.2 (23.5)
22.18
43-0(31-7)
38.1(32)
19.47
145
HYDROFLUORIC AOID
HYDROFLUORIC ACID HF.
100 grams H 2 O dissolve in grams HF at 35.
(Metzner Compt. rend, 119, 683, '94.)
HYDRIODIO AOID HI. IODIC AOID HIO 3 .
For determinations of the freezing points of aqueous solutions of HI,
and isolation of the several hydrates at temperatures below o, see
Pickering Ber. 26, 2307, '93.
SOLUBILITY OF IODIC ACID AND ITS MODIFICATIONS IN WATER.
(Groschuff Z. anorg. Chem. 47, 343, '05.)
t.
Grams per 100
Gms. Solution.
Gram Mols. IzOs
per i oo Gm. Mols.
Solid
HIO 3 .
I20 6 .
H*
Solution.
Phase.
14
72
.8
69
.1
12
.1
10
.8
Ice +
mo,
o
74
.1
70
3
12
.8
II
3
HI0 3
16
75
.1
7i
7
13
7
12
.0
40
77
7
73
7
.1
13
.2
Cl
60
80
.0
75
9
17
.0
14-5
((
80
82
5
78
3
19
4
16
3
It
85
83
.0
78
7
20
.0
16
7
u
IOI
85
.2
80
.8
22
.8
18
.6
11
no
86
5
82
.1
24
7
19
.8
HIO,
+ HLO.
125
87
.2
82
7
^5
9
20
.6
HI,0,
140
88
3
83
.8
27
9
21
.8
It
160
90
5
85-9
32
.8
24
7
(1
SOLUBILITY OF IODIC ACID IN NITRIC ACID.
(Groschuff.)
Grams HIOs per 100 Grams.
O
20
40
60
Aq.
Solution.
27-73% HN0 3
Solution.
40.88% HNOi
Solution.
74-1
18.0
9.0
75-8
21 -O
10.
77-7
27.0
14.0
80.0
38.0
18.0
HYDROGEN H.
SOLUBILITY IN WATER.
(Winkler Ber. 24, 99, '91; Bohr and Bock Wied. Ann. 44, 318, '91; Timofejew Z. physik.
Chem. 6, 147, '90-)
o 0.0214
. . .
0.0214
0.000193
5 0.0203 0.0209
0.0241
0.0204
0-000184
10 0.0193 0-0204
0.0229
0.0195
0.000176
15 0-0185 O-O2OO
0.0217
0.0188
0.000169
20 0.0178 0-0196
0.0205
0.0182
0.000162
25 0.0171 0.0193
0.0191
0.0175
0.000156
30 0.0163
. . .
0.0170
0.000147
40 0.0153
0.0164
0.000139
50 0.0141
0.0161
0.000129
60 0.0129
0.0160
0.000119
80 0.0085
0.0160
0.000079
100 0.0000
0.0160
o.oooooo
/ Ostwald Solubility Expression, sec
i page 105.
For 0', j8, and q,
see Ethane, page 133.
HYDROGEN 146
SOLUBILITY OF HYDROGEN IN AQUEOUS SOLUTIONS OF ACIDS AND
BASES AT 25.
(Geffcken Z. physik. Chem. 49, 268, '04.)
Gram Equiv,
Acids and
Bases
per Liter.
o.o
o-S
I .0
2.0
3-o
4.0
Solubility
Of H (/a; =
Ostwald Expression) in Solutions of:
-*-
HC1.
0.0193
0.0186
0.0179
0.0168
0.0159
HN0 3 .
0.0193
0.0188
0.0183
0.0174
0.0167
0.0160
*H 2 SG 4 .
0.0193
0.0185
0.0177
0.0163
0-0150
O.OI4I
CHgCOOH.
0.0193
0.0192
O.OI9I
0.0188
0.0186
0.0186
CH 2 C1COOH
0.0193
0.0189
0.0186
0.0180
KOH.
.0193
.0167
.0142
NaOH.
0-0193
0.0165
0.0139
0.0097
O.OO72
0.0055
The above figures for the concentrations of acids and bases were
calculated to grams per liter, and these values with the corresponding
/ 26 values for the solubility of hydrogen plotted on cross-section paper.
From the resulting curves the following table was read.
Grams Acids
Solubility of H (fa = Ostwald Expression) in Solutions of:
per Liter. HC1.
HN0 3 .
iH 2 SO 4 . CH 3 COOH.
CH 2 C1COOH. KOH.
NaOH.
O
0.0193
O
.0193
O
.0193
.0193
O
.0193
0.0193
O.OI93
20
0.0185
.0189
.0186
.0192
.0191
0.0172
0.0165
40
0.0179
.0186
.0180
.0191
.0190
0.0153
O.OI4O
60
0.0173
.0183
.0174
.0190
.0188
0.0135
O.OII7
80
0.0167
.0180
.0168
.0189
.0187
0.0097
100
0.0160
.0179
.0162
.0189
.0185
. . .
O.O082
150
.0171
.0148
.0188
.0182
0.0058
200
. . .
.0165
.0140
.0186
.0179
. . .
250
.0160
.0184
For Ostwald Solubility Expression, see page 105.
SOLUBILITY OF HYDROGEN IN AQUEOUS SOLUTIONS OF AMMONIUM
NITRATE AT 20.
(Knopp Z, physik. Chem. 43, 103, '04.)
P'
Normality
(per 1000 Gms.)
H 2 0.
Molecular
Concentra-
tion.
Absorption
Coefficient
of Hydrogen.
Density
of Solutions.
o.oo
o.oo
o.oo
0.0188
. . .
1.037
0.1308
0.002352
0.01872
I .0027
2.167
0.2765
0-004956
0.01845
1.0072
3-378
0.4363
0.007799
0.01823
I -OI22
4.823
0-6333
O.OIT280
0.01773
I .Ol82
6-773
0-9069
0.016447
0.01744
I -0262
1-6308
0-028525
0.01647
I .04652
147
HYDROGEN
SOLUBILITY OP HYDROGEN IN AQUEOUS SOLUTIONS OF
CHLORIDE.
(Braun Z. physik. Chem. 33, 735, 'oo.)
BARIUM
Gms.BaCl 2
per 100 Gms.
Solution.
O-OO
3-29
3-6
6.45
7.00
Coefficient of Absorption of Hydrogen at :
5.
0-0237
O-O2II
O.O2O9
0.0196
O.OI94
10.
0-0221
0-0198
0.0197
0.0186
0.0183
15'
0.0206
0.0185
0.0184
0.0173
0.0172
20.
0.0191
0.0172
0.0170
0.0161
0.0159
2S-
0.0175
0.0157
0.0156
0.0147
0.0146
SOLUBILITY OF HYDROGEN IN AQUEOUS SOLUTIONS OF CALCIUM CHLOR-
IDE, MAGNESIUM SULPHATE, AND LITHIUM CHLORIDE AT 15.
(Gordon Z. physik. Chem. 18, 14, '95.)
Coefficient of Absorption of hydrogen in water at 15= 0.01883.
In Calcium In Magnesium In Lithium
Chloride. Sulphate. Chloride.
Gms.
CaCl 2
G.M.
CaCl 2
Absorption
Coefficient
Gms.
MgS0 4
G.M.
MgS0 4
Absorption
Coefficient
Gms.
LiCl
G.M.
LiCl
Absorption
Coefficient
per
100 g. Sol.
Lhe r r.
of H.
per
loo g. Sol.
per
Liter.
of H.
per
100 g. Sol.
per
Liter.
of H.
3-47
0.321
0.01619
4-97
0-433
O.OI50I
3.48
0-835
O.pl6l9
6.10
0.578
0.01450
10.19
0.936
0.01159
7-34
1.800
0.01370
JI -33
I. 122
0.01138
23.76
2.501
0.00499
14.63
3-734
0.0099
17-52
I.I827
0.00839
26.34
2.962
0.00519
For definition of Coefficient of Absorption, see page 105.
SOLUBILITY OF HYDROGEN IN AQUEOUS SOLUTIONS OF POTASSIUM
CARBONATE, CHLORIDE, AND NITRATE AT
(Gordon.)
15'
In Potassium
In Potassium
In Potassium
Carbonate.
Chloride.
Nitrate.
Gms.
K 2 C0 3
G.M.
K 2 C0 3
Absorption
Coefficient
Gms.
KC1
G.M.
KCl
Absorption
Coefficient
Gms.
KNO 3
G. M.
KNO 3
Absorption
Coefficient
per
100 g. Sol.
per
Liter.
of H.
per
100 g. Sol.
per
Liter.
of H.
per
100 g. Sol.
&.
of H.
2.82
0.209
0.01628
3.83
0.526
0.01667
4-73
0.482
0.01683
8.83
0.690
0.01183
7.48
1.051
0.01489
8-44
0.879
0.01559
16.47
1.376
0.00761
12.13
1-755
0.01279
16.59
1.820
0.01311
24-I3
2. 156
0.00462
19.21
2.909
O.OIOI2
21.46
2.430
O.OIlSo
4I.8l
4-352
0.00l6o
22.92
3-554
0.00892
SOLUBILITY OF HYDROGEN IN AQUEOUS SOLUTIONS OF POTASSIUM
CHLORIDE AND NITRATE AT 20.
(Knopp Z. physik. Chem. 43, 103, '04.)
In Potassium Chloride. In Potassium Nitrate.
p-
Normality
(per looo
g. H,0).
Absorption
Coefficient.
Density
of
Solutions.
P-
Normality
(per looo
g.HzO).
Absorption Density
Coefficient. ^^
1.089
O
J 475
0.01823
I
.0052
I
.224
0-1245
0-01835 1.0059
2.123
.2907
o
01757
I
-OIl8
2
094
O.2II4
O.OlSlS
.0113
4.070
.5687
o
01661
I
.0243
4
OIO
0.4127
0-01785
.0236
6-375
.9127
OI53 1
I
0394
5
925
0.6225
0-01743
0359
7.380
I
.0682
01472
I
.0460
7
.742
0.8293
0-01667
.0477
13.612
2
.1222
o
I2 55
I
.0875
13
.510
I-5436
0-01436
.0865
HYDROGEN
148
SOLUBILITY OP HYDROGEN IN AQUEOUS SODIUM CARBONATE AND
SULPHATE SOLUTIONS AT 15.
(Gordon.)
In Sodium Carbonate.
Gms. NajCOa G.M.
per 100 Gms. NasCOa
Solution. per Liter.
2-15
8.64
"53
per
0.207
0.438
1.218
Absorption
Coefficient
of H.
0.01639
0.01385
0-00839
In Sodium Sulphate.
Gms. Na2SO 4 G.JM. Absorption
per 100 Gms. Na2SO4
Solution. per Liter.
Coefficient
of H.
4.58 0-335
O.OI5I9
8.42 0.638
O.OI54
16.69 J -364
0.00775
SOLUBILITY OF HYDROGEN IN AQUEOUS SOLUTIONS OF SODIUM
CHLORIDE.
(Braun; Gordon.)
Gms.NaCl
Coefficient of Absorption of Hydrogen at:
per 100 Crins.
Solution.
5.
10.
15.
20.
25.
1.25
0.0218
O.O2O5
0.0191
0.0177
0.0162
3 .80
0-0198
0-0188
0.0176
0.0162
0.0148
4-48
0.0192
0.0182
0.0171
O.OI59
0.0143
6.00
O.Ol84
0.0175
0.0164
0.0153
0.0138
14-78
0.0093
23.84
0.00595
SOLUBILITY OF HYDROGEN IN AQUEOUS SOLUTIONS OF SODIUM
NITRATE.
In Sodium Nitrate at 20.
(Knopp.)
In Sodium Nitrate at 15.
(Gordon.)
p.
Normality
(per 1000
Absorption
Coefficient
Density
of
Gms.NaNOa
per loo Gms.
G.M.
NaNO 3
Absorption
Coefficient
Gms. H 2 O).
of H.
Solutions.
Solution.
per Liter,
of H.
1 .041
0.1236
0-01839
I .0052
5-57
0.679
0.01603
2 .192
0.2634
0.01774
I .0130
II .l6
I-4I3
0.0137
4-405
0.5416
0-01694
I .0282
19.77
2.656
0.01052
6.702
0.8442
0-01518
I .04411
37-43
5 -7 I3C
0.00578
12.637
1-7354
0.0130
1.08667
SOLUBILITY OF HYDROGEN IN ALCOHOL.
(Timofejew Z. physik. Chem. 6, 147, '90.)
A
Coefficient of Abs. in
to
.
08.8% Alcohol.
.
0-0676
4
6.2
0.0693
18.8
13-4
0.0705
18.8
O.O74O
Coefficient of Abs. in
99.7% Alcohol.
0.0749
O.O74O
SOLUBILITY IN AQUEOUS ALCOHOL SOLUTIONS AT 20 AND 760 MM.
PRESSURE.
(Lubarsch Wied. Ann. [2] 37, 525. '89-)
Vol. % Absorbed H.
2>02
2.55
Wt. % Alcohol.
Vol. % Absorbed H.
Wt. % Alcoh
o.oo
i-93
28.57
9.09
16.67
23.08
i-43
1.29
1.17
33-33
50-0
66.67
149
HYDROGEN
SOLUBILITY OP HYDROGEN IN AQUEOUS SUGAR SOLUTIONS AT 15.
(Gordon Z. physik. Chem. 18, 14, '95.)
Gms.
xoo Gms.
C.
16.67
30.08
Gm. Mols. Sugar
per Liter.
0.520
o-993
1.699
Absorption
Coefficient of H.
0.01561
0.01284
0.00892
SOLUBILITY OF HYDROGEN IN WATER AND IN ORGANIC SOLVENTS.
Results in terms of the Ostwald Expression, see page 105.
(Just Z. physik. Chem. 37, 359, f oi.)
Solvent. /25- /so.
Amyl Acetate 0.0774 0.0743
Xylene 0.0819 0.0783
Ethyl Acetate 0.0852 0.0788
Toluene 0.0874 0.0838
Ethyl Alcohol (98.8%) o. 0894 o. 0862
Methyl Alcohol 0.0945 0.0902
Iso Butyl Alcohol 0.0976 0.0929
Solvent.
Water
Anilin
Amyl Alcohol
Nitro Benzene
Carbon Bisulphide
Acetic Acid
Benzene
Acetone
/26-
0.0199
0.0285
0.0301
0.0371
0.0375
0.0633
0.0756
0.0764
0.0200
0.0303
0.0353
0.0353
0.0336
0.0617
0.0707
0.0703
SOLUBILITY OP HYDROGEN IN CHLORAL HYDRATE
AT 20.
SOLUTIONS
(Knopp.)
P.
Normality (per
1000 Gms. H a O).
Molecular
Concentration.
Absorption
Coefficient of H.
Density
of Solutions.
4.91
0.310
0.005594
0.01839
I .O2O2
7.69
0.504
0.008992
0.01802
1.0320
14.56
1.030
0.018223
O.OI7I2
1.0669
29-50
2 -530
0-043601
0.01542
I.I466
38.42
3-770
0.063647
O.OI44O
1.1982
49-79
6.000
0.097493
0-01353
1.2724
63.90
10.700
o. 161660
0.01307
1-3743
SOLUBILITY OF HYDROGEN IN PROPIONIC ACID SOLUTIONS.
(Braun.)
G. C 2 HcCOOH
Coefficient of Absorption of Hydrogen at:
per 100 Gms.
Solution.
' 5.
10.
IS -
20.
25.
2.63
O.O2245
0.0214
O-O2OO
0.0188
0.0172
3-37
O.O222
O.O2I2
0.0199
0.0187
0.0171
5-27
0-0224
O-O2I2
0.0198
0.0184
0.0171
6.50
0.0218
o . 0209
0.0193
0.0183
0.0169
9.91
0.0213
0.0203
O.OI9I
0.0178
0.0160
SOLUBILITY OP HYDROGEN IN PETROLEUM.
(Griewasz and Walfisz Z. physik. Chem. I, 70, '&J./
Coefficient of absorption at 20 0.0582, at 10 0.0652.
HYDROGEN SULPHIDE {50
HYDROGEN SULPHIDE H 2 S.
SOLUBILITY IN WATER AND IN ALCOHOL AT t AND 760 MM. PRESSURE.
(Bunsen and Carius; Fauser Math, u Natur. W. Ber. (Ungarn.) 6, 154, '88.)
In Alcohol.
i Vol. Alcohol Absorbs
1 7 . 89 Vols. H 2 S(at o and 760 mm.)
14-78
11.99
9-54
7.42
5-96 (24)
For ft and q see Ethane, page 133.
SOLUBILITY OF HYDROGEN SULPHIDE IN AQUEOUS SALT SOLUTIONS
In Water.
t.
i Vol
. H 2 Absorbs
/3.
3 .
o
4-37
Vols. H 2 S(ato and 760 mm.)
4-686
0.710
5
3-97
M
4.063
0.6l5
10
3-59
H
3-520
0-530
15
3-23
H
3-056
0-458
20
2 .91
u
2.672
0.398
25
2 -6l
"
30
2-33
It
35
2.08
"
. . .
40
1.86
"
AT 25.
(McLauchlan Z. physik. Chem. 44 615, '03.)
NOTE. The original results are given in terms of y which is the
^0
iodine titer (/) of the H 2 S dissolved in the salt solution divided by the
titer (/ ) of the H 2 S dissolved in pure water. These figures were multi-
plied by 2. 6 1 (see 25 results in preceding table) and the products
recorded in the following table as volumes of H 2 S absorbed by i vol.
of aqueous solution.
Solution.
Grams Salt I Vols. H 2 S
per Liter, fo. per i Vol. Sol
. Solution. Gms^Salt
I Vols. H 2 S
/. per i Vol .Sol
n NH 4 Br
9 8.
I.
00
2.61
n
KBr
119.0
0.
945
2.47
n NH 4 C1
53-
4
0.
96
2.40
n
KC1
74-5
0.
853
2. 22
n NH 4 NO 3
80.
0.
99
2.58
n
KN0 3
IOI.O
O.
913
2.38
in (NH 4 ) 2 SO 4
33-
0.
82
2.14
in
K 2 S0 4
43-5
0.
78
2.04
In (NH 4 ) 2 S0 4
16.
5
0.
9i
2.37
in
K 2 SO 4
21.7
0.
89
2.32
n NH 4 C 2 H 3 2
77-
i
I.
09
2.84
n
KI
166.0
o.
98
2. 5 6
n (NH 2 ) 2 CO
60.
i
I.
02
2.66
n
NaBr
103.0
0.
935
2.44
InHCl
18.
22
0.
975
2-54
n
NaCl
58.5
o.
847
2. 21
n H 2 SO 4
24.
52
0.
905
2.36
in
NaCl
29.2
0.
93
2.42
n C 4 H 6 O 6
150.
0.
944
2.46
n
NaNO 3
85.0
0.
893
2.32
3 n C 4 H 6 O 6
45
0.
858
2.24
in
Na 2 SO 4
35-5
0.
73
1.90
Pure C 3 H 5 (OH) 3
IOCX).
o.
863
2.26
in
Na 2 S0 4
17.8
0.
89
2.32
HYDROQUINONS C 6 H 4 (OH) 2 1:4, also Resorcin C 6 H 4 (OH) 2 1:3 and
Pyrocatechin C 6 H 4 (OH) 2 1:2.
SOLUBILITY IN WATER.
(Vaubel J. pr. Chem. [2] 59, 30, 'oo.)
ioo grams solution contain 6.7 grams hydroquinone at 20. Sp. Gr.
of sol. = i. 01 2.
ioo grams solution contain 63.7 grams resorcin at 20.
TOO grams solution contain 31.1 grams pyrocatechin at 20.
IS* HYDEOQUINONE
SOLUBILITY OF HYDROQUINONE IN SULPHUR DIOXIDE IN THE
CRITICAL VICINITY.
(Centnerswer and Teletow Z. Electrochem. 9, 799, '03.)
Determinations made by the Synthetic Method, for which see Note
page 9.
t o Cms. Hydroquinone t o Cms. Hydroquinone ^o Cms. Hydroquinone
per IOQ Cms. Sol. per 100 Cms. Sol. per 100 Cms. Solution.
63 0.89 117.6 4.46 136.7 10.31
73-5 1-22 123.3 5-66 141-4 13-3
89.2 2.18 134.2 8.31 145.0 14.9
HYDROXYLAMINE NH 2 (OH). HYDROXYLAMINB HYDRO-
CHLORIDE NH 2 (OH).HC1.
SOLUBILITY IN SEVERAL SOLVENTS.
(de Bpuyn Rec. trav. chim. n, 18, '92; Z. physik. Chem. 10, 783, 'yt.)
Grams NH 2 OH Grams NH 2 (OH).HCl
Solvent. t. per 100 Cms. t. per 100 Gms.
Solution. Solvent.
Methyl Alcohol (abs.) 5 35.0 19 .75 16.4
Ethyl Alcohol (abs.) 15 15.0 19-75 4-43
Ether (dry) (b. pt.) 1.2
Ethyl Acetate (b. pt.) 1.6
For densities of NH 2 (OH).HC1 solutions, see Schiff and Monsacchi
Z. physik. Ch. 21, 277, '96.
HYOSCYAMINE C 17 H 21 NO 3 .
SOLUBILITY IN SEVERAL SOLVENTS AT i8-22.
(Miiller Apoth.-Ztg. 18, 249, '03.)
Gms. CnHnNOs Gms.
Solvent. per 100 Gms. Solvent. per 100 Gms.
Solution. Solution.
Water -355 Chloroform 100+
Ether 2.02 Acetic Ether 4-903
Ether sat. with HO 3.913 Petroleum Ether 0.098
Water sat. with Ether 3.125 Carbon Tetra Chloride 0.059
Benzene o . 769
HYOSOINE HYDROBROMIDE, etc.
SOLUBILITY IN SEVERAL SOLVENTS AT 25.
(U.S. P.)
. Grams per 100 Grams Solvent.
Solvent. Hyoscine
Hyoscyamine
Hyoscyamine
Hydrobromide
C,7H 21 N04.HBr.3H 2 O.
Hydrobromide
CnHaNOa-HBr.
Sulphate
(C,7H 23 N0 3 ) 2 .H 2 S04.
Water 66.6
very soluble
very soluble
Alcohol 6 . 2
So
is-6
Ether
0-062
0.04
Chloroform o . 133
40.0
0.043
IODINE
IODINE I.
to
Gms. I per Liter
.
Solution.
15
0.272-0.283
25
0.279
25
0.304
25
o-339
25
0.340
30
o-457
152
SOLUBILITY IN WATER.
Authority.
(Dietz Pharm. Ztg. 43, 290, '98.)
(McLauchlan Z. physik. Chem. 44, 617, '03.)
(Herz and Knoch Z. anorg. Chem. 45, 269, '05.)
(Jakowkin Z. physik. Chem. 18, 590, '95.)
(Noyes and Seidensticker Z. physik. Chem. 27, 359, '98.)
(Dietz.)
SOLUBILITY OF IODINE IN AQUEOUS POTASSIUM IODIDE
SOLUTIONS AT 25.
(Noyes and Seidensticker; Bruner Z. physik. Chem. 2<5 147, '98.)
Millimols
per Liter.
KI.
(I 2 ).
o.ooo
1.342
0.830
I.8I4
1.661
2-235
3-322
3-052
6.643
4-667
13.29
8.003
26.57
14.68
53-15
28.03
106.3
55-28
Gms. per Liter.
KI.
0.00
2-75
11.03
22.07
44-I5
88.3
176.6
I.
0.340
0.461
0.568
0-775
i
2
3
7
14.04
185
.032
.728
.119
Results by Bruner.
Gms. KI per Gms. I
1000 g. Sol. per Liter.
10 0.78*
20 I 60
40 3-25
60 5 04
80 6.94
ioo 8.96
* There is some uncertainty in regard to the position of the decimal point in this column,
lation from the original it should be one place further to the right.
By calcu
SOLUBILITY OF IODINE IN AQUEOUS SALT SOLUTIONS AT 25.
(McLauchlan.)
Salt.
Gms. Salt Gms. Dissolved I
per Liter. per Liter.
Salt.
Gms. Salt Gms. Dissolved I
per Liter. per Liter.
Na 2 S0 4
2 9
77
o
.160
NH 4 C1
53
4
735
K 2 S0 4
43
5
o
.238
NaBr
103
.0
3
.29
(NH 4 ) 2 S0 4
33
.0
.246
KBr
119
.0
3
.801
NaNO 3
-85
.0
o
257
NH 4 Br
98
.0
4
.003
KN0 3
101
.2
o
.266
NH 4 C 2 H 3 2
77
.1
o
.440
NH 4 NO 3
80
O
375
(NH 4 ) 2 C 2 H 4
86
9
o
.980
NaCI
58
5
o
575
H 3 B0 3
55
.8
300
KC1
73
.6
o
.658
SOLUBILITY OF IODINE IN ARSENIC TRI CHLORIDE.
(Sloan and Mallet Chem. News, 46, 194, '82.)
t. o. 15. 96.
Gms. I per ioo gms. AsCl 3 8.42 11.88 36.89
153 IODINE
SOLUBILITY OF IODINE IN AQUEOUS ETHYL AND NORMAL PROPYL
ALCOHOL SOLUTIONS AT 15.
(Bruner Z. physik. Chem. 26, 147, '08.)
In Aq. Ethyl Alcohol. In Aq. Propyl Alcohol.
Gms.
Gms.
Gms.
Gms.
Gms.
Gms.
Gms.
Gms.
per loo Gms.
I per
100 CC.
per 100 Gn
! I per
IS. 100 CC.
CsHyOH
per 100 Gms.
I per
100 CC.
CsH 7 OH
per 100 Gms.
I per
100 CC.
Solvent.
Solution.
Solvent.
Sol.
Solvent.
Sol.
Solvent.
Sol.
IO
O.O5
60
I.I4
IO
0-05
60
2.71
2O
O.o6
70
2-33
2O
O.II
70
4-10
30
o.io
80
4.20
30
0-40
80
6.05
40
O.26
90
7-47
40
0-94
90
9.17
50
0-88
ICO
x 5- 6 7
50
I .64
100
14-93
SOLUBILITY OF IODINE IN BENZENE, CHLOROFORM, AND IN ETHER.
(Arctowski Z. anorg. Chem. n, 276, '95-'o6.)
In Benzene.
In Chloroform.
In Ether.
t o Gms. I per ioo
Gms. Solution.
A o Gms.
* ' Gms.
I per ioo
Solution.
A o Gms. I per ioo
Gms. Solution.
4-7
8
.08
-49
o
.188
-83
15.
39
6.6
8
63
-55*
o
.144
-90
14.
58
10.5
9
.60
-60
.129
-108
15 .
09
13-7
IO
44
-6 9 i
o
.089
16.3
ii
23
-73*
o
.080
+ 10
I
.76 per
ioo gms.
CHCL,
(Duncan -
- Pharm. J. Trans. 22,
544, 'pi-'
SOLUBILITY OF IODINE IN BROMOFORM, CARBON TETRA CHLORIDE, AND
IN CARBON BISULPHIDE AT 25.
(Jakowkin Z. physik. Chem. 18, 590, '95.)
i liter of saturated solution in CHBr 3 contains 189.55
i liter of saturated solution in CC1 4 contains 30.33 gms. I.
i liter of saturated solution in CS 2 contains 230.0 gms. I.
SOLUBILITY OF IODINE IN CARBON BISULPHIDE SOLUTIONS.
(Arctowski Z. anorg. Chem. 6, 404, '94.)
. o Gms. I per ioo ^ o
Gms. Solution.
Gms. I per ioo
Gms. Solution.
t.
Gms. I per ioo
Gms. Solution.
IOO
0.32
7.89
30
19.26
-80
0.51
10
10.51
36
22.67
-63
1.26
15
12-35
40
25.22
2O
4.14
20
14.62
42
26.75
IO
5-52
25
16.92
IODINE 154
SOLUBILITY OF IODINE IN MIXTURES OF CHLOROFORM AND ETHYL
ALCOHOL, CHLOROFORM AND NORMAL PROPYL ALCOHOL, CHLOROFORM
AND BENZENE, AND CHLOROFORM AND CARBON BISULPHIDE AT 15.
(Bruner.)
Cms. CHC1 3
Grams I Dissolved per
ioo cc. of Mixtures of:
of Mixtures. C
Hda+CaHfl
OH. CH 3 C1 + C 3 H 7 OH
. CHgCl + CeHfi.
CH 3 CI -f CS 2 .
IS-67
14-93
IO.4O
17.63
10
9-43
13.16
9.84
J 5-93
2O
8.69
II .20
8.78
14.20
30
7.80
8.98
7-74
12 .l6
40
7.09
8.09
6.96
10.20
50
6.62
7-82
6.20
9.08
60
6.24
7.09
5-34
7-72
70
5-77
6.42
4.89
6.42
80
5-o6
5-54
4-53
5-27
90
4-34
4-52
4.07
4-32
IOO
3.62
3-62
3-62
3.62
SOLUBILITY OF IODINE IN MIXTURES OF CARBON TETRA CHLORIDE AND
BENZENE AND IN MIXTURES OF CARBON TETRA CHLORIDE
AND CARBON BISULPHIDE AT 15.
(Bruner.)
Gms.CCUper Cms. I per loocc. of Mixture of: Gms.CCUper Gms.Iper loocc. of Mixture
TSNTH Cl-mc r\f ^ A -w^^. nvo nf _ ^
Mixtures.
CCU+CeHe.
CC1 4 + CS 2 .
J.UU VJII1S. Ul
Mixtures.
CCU + C 6 H 6 .
CC1 4 +CS 2 .
10-40
17.6
60
4.90
5-55
10
9.44
14.44
70
4.09
4-5
20
8-53
"33
80
3-4i
3-37
30
7-77
10.34
90
2.74
2.60
40
6.63
8.60
IOO
2.06
2.06
50
5-7o
6.83
SOLUBILITY OF IODINE IN AQUEOUS GLYCERINE SOLUTIONS
AT 25.
(Herz and Knoch Z. anorg. Chem. 45, 269, '05.)
Density of glycerine at 25/4 1-2555; impurities about 1.5%.
Wt.% Glycerine Millimols I Grams I per Density of
in Solvent, per ioo cc. Solution, ioo cc. Solution. Solutions at 2S/4.
o 0.24 0.0304 Q-9979
7.15 0.27 0.0342 1.0198
20.44 0-38 0-0482 1.0471
31.55 0.49 0.0621 1-0750
40.95 0.69 0.0875 1-0995
48.7 1.07 0.135 1.1207
69.2 2. 2O 0.278 1.1765
100.0 9.70 1-223 1.2646
155
IODINE
DISTRIBUTION OP IODINE BETWEEN CARBON BISULPHIDE AND
AQ. POTASSIUM OXALATE.
(Dawson Z. physik. Chem. 56, 610, '06; Dawson and McRae J. Chem. Soc. 8x, 1086, '02.)
Concentration
of
.o Equiv.
.o "
.o "
.2
Gms. I per Liter of
Aq. Layer.
2.408
3-555
5.766
6.861
CS-z Layer.
10.82
16.32
27.91
34-Qi
17.07
Vol. of Solution
which Contains
i Mol. I.
Fraction of I
Uncombined
in Solution.
105-3
71-37
0.005495
0.00561
43-99
36.98
71.97
0.005915
0.000055
0.005645
DISTRIBUTION OP IODINE BETWEEN AMYL ALCOHOL AND WATER AND
BETWEEN AMYL ALCOHOL AND AQUEOUS POTASSIUM IODIDE
SOLUTIONS AT 25.
(Herz and Fischer Ber. 37, 4752, '04.)
The original results were plotted on cross-section paper, and the
following tables made from the curves.
Millimols I per 10 cc. of H 2 O and of Aq. KI Layers.
Amyl Alcohol Layer
~
N
2N
N
4N
ioN ""*
in Each Case.
HoO.
K I .
KI.
KI*
KI.
*" " KJ
10
10
10
10
10
2-5
O-OI2
0-135
0.160
O.I7O
O.I7O
. . .
3-o
O-OI4
0.150
0.185
O.2OO
0.200
0.160
4-0
0-OlS
0.180
0-235
0-255
0.270
0.240
5
O.O2I
O.2IO
0.280
0-340
0-315
6
O.O25
0.230
0-330
o-375
O.4IO
0.390
7
O.O29
0.250
0-375
0.430
0.480
0.470
8
0.260
0.420
0.490
0-550
o-555
9
0.270
0.45
o-55o
O.62O
0.640
10
0.280
0.470
0.605
0.690
0.720
12
0.490
0.700
0.830
0.900
14
0.510
0.790
0.980
1.200
20
0-575
Gms. I per loocc.
Gms. I per
ioo cc. of H 2 O and of KI
Layers.
Amyl Alcohol Layer
f~
N
aN
^N
4N
ioN "^
in Each Case.
HoO.
KI.
KI.
KI
^~ yy
KI
IO
IO
10
IO
10
3
0.014
O.l64
0.20
0.21
0.21
4
0.016
0.196
0.24
O.26
0.26
0.21
6
0.026
0.252
o-34
0-38
0.40
o-37
8
0-033
0-297
o-43
0-49
o-54
0.51
10
0-040
0.328
0.51
0.61
0.67
0.69
12
. . .
0.341
0.58
-73
0.81
0.84
14
0.60
0-83
o-95
1. 00
16
0.63
0.91
1.09
1.20
18
0.64
25
0.71
The original figures for sN/io and xoN/io KI solutions give prac-
tically identical curves.
Results for the distribution of Iodine between N/io KI solutions on
the one hand, and mixtures in various proportions of C 8 H e + CS 2>
C 6 H 5 CH 8 +CS 2 , C 6 H 6 +C 6 H 6 CH 3 , C 6 H 6 + light petroleum, CS 2 + light
petroleum, CS 2 +CHC1 3 , CHC1 3 + C 6 H 6 , CC1 4 + CS 2 and CC1 4 + C 8 H 6 CH 3
on the other hand, are given by Dawson J. Chem. Soc., 81, 1086, '02,
IODINE
156
DISTRIBUTION OF IODINE BETWEEN WATER AND BROMOFORM, WATER
AND CARBON BISULPHIDE, AND WATER AND CARBON
TETRA CHLORIDE AT 25.
(Jakowkin Z. physik. Chem. 18, 590, '95.)
Original results plotted on cross-section paper and table made from curves. Jakowkin points out that
the results of Berthelot and Jungfleisch Ann. chim. phys. [4] 26, 400, '72, are incorrect on account of
the presence of HI.
Grams I per Liter of Grams I per Liter ot^
HjO Layer in Each Case.
0.05
O.IO
0.15
0.20
0.25
IODOFORM CHI 3 , IODOL CJ 4 NH (Tetra lodo Pyrrol).
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; Vulpius Pharm. Centrh. 34, 117, '93.)
CHBrs Layer.
CS 2 Layer.
CCU Layer.
2O
3<>
4-0
45
60
8-5
71
91
13.0
IOO
126
17-5
130
160
22.0
Solvent. t .
Water 25
Alcohol 25
Alcohol b. pt.
Ether 25
Chloroform 25
Grams per ioo^Grams Solvent.
LaL CJ4NH.
0.0106 0.0204
2.14 (i .43 gms. (V.)) 1 1. 1
(lo.ogms. (V.)) ...
19.2 (!6.6gms. (V.)) 66.6
0.95
IRIDIUM DOUBLE
Double Salt.
Irido Pentamine Bromide
" Bromonitrate
" Tri Chloride
" Chloro Bromide
Chloro Iodide
" Chloro Nitrate
" Chloro Sulphate
" Nitrate
Aquo Pentamine Bromide
Chloride
" " Nitrate
SALTS.
SOLUBILITY IN WATER.
(Palmaer Ber. 23, 3817; 24, 2090, '91.)
Formula.
Ir(NH 3 ) 6 Br 3
Ir(NH 3 ) 6 Br(N0 3 ) 2
Ir(NH 3 ) 5 Cl 3
Ir(NH 3 ) 6 ClBr 2
Ir(NH 3 ) 5 ClI 2
Ir(NH 3 ) 5 Cl(N0 3 ) 2
Ir(NH 3 ) s ClSO 4 .2H 2 O
Ir(NH 3 ) 6 (N0 3 ) 3
Ir(NH 3 ) 5 (OH 2 )Br 3
Ir(NH 3 ) s (OH 2 )Cl 3
Ir(NH 3 ) 5 (OH 2 )(N0 3 ),
Gms, per 100
t .
Gms. HjjO.
12.5
0.284
18
5.58
15.1
6-53
15
0.47
15
o-95
15-4
1.94
15.0
0.74
16
0.28
ord. temp.
25.0
ord. temp.
74-7
17
IO.O
IEON BROMIDE (Ferrous) FeBr2.6H 2 O.
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 537. '94-)
t o Gms. FeBr 2 t <>
per loo Gms. Sol.
Gms. FeBr 2 t Gms. FeBr 2
per zoo Gms. Sol. per 100 Gms. Sol.
20
47-0
30
55-o
60
59 -o
50-5
40
56-2
80
61 .5
20
53-5
IOO
64.0
IRON CARBONATE (Ferrous) FeCO 3 .
TOO gms. HjO saturated with CO 2 at 6-8 atmospheres dissolve 0.073
gram FeCO,. (Wagner Jahresber. Chem. 135, '67.)
157
IRON CHLORIDE
IRON CHLORIDE (Ferrous) FeCl 2 . 4 H 2 O.
(Etard.)
SOLUBILITY IN WATER.
10
15
25
30
40
So
Gms. FeCfe
per loo Gms.
Solution.
39-2
40.0
4i-5
42.2
43-6
45-2
Solid Phase.
60
80
87
90
100
1 20
Gms. FeCla
per 100 Gms.
Solution.
47-0
50.0
51.2
51-3
51-4
51-8
Solid Phase.
FeCl 2
SOLUBILITY OF IRON CHLORIDE
(Roozeboom Z. physik.
(FERRIC) Fe 2 Cl 6 IN WATER.
Chem, 10, 477, '92.)
Mols. Fe 2 Cl Gms. FeCl 3 per 100
t. Der 100 Mols. Gms.
H 2 0.
H 2 0.
Solution.
Solid Phase, Fe-sCla.izHaO.
-55
2
75
49
52
33
.12
-27
2
.98
53
.00
34
93
4
13
74
39
42
.66
+ 20
5
.10
9i
85
47
.88
30
5
93
106
.8
5 1
.64
37
8
33
150
.0
60. 01
30
ii
.20
2OI
7
66
85
20
12
83
231
.1
69
79
8
J 3
7
246
7
7i
*5
Solid Phase,
Fe 2 Cl6. 7 H 2 0.
20
ii
35
2O4
4
67
.14
32
13
55
244
.0
70
.92
30
15
.12
272
4
73
J 3
25
15
54
280
o
73
.69
Solid Phase,
Fe 2 Cl6.5H 2 0.
12
12
.87
231
.8
69
87
27
14
85
267
5
72
.78
Mols. Fe 2 Cl6 Gms. FeCl 3 per 100
t. per 100 Mols. Gms.
HaO. HaO. Solution.
Solid
Phase, FeaCle-sH
zO (con.).
35
15
.64
28l
.6
73
79
50
17
50
315
.2
75
.91
55
19
15
344
.8
77
52
55
20
32
365
9
78
54
Solid Phase, FeaCIe^HaO.
50
19
.96
359
3
78
23
55
20
32
365
9
78
54
60
20
.70
372
.8
78
.86
69
21
53
387
7
79
5o
73-5
25
.0
450
.2
81
.81
70
27
9
502
4
83
.41
66
29
.2
525
9
84
03
Solid Phase, Fe 2 Cle.
66 29.2 525.9 84.03
75 28.42 511.4 83.66
80 29.20 525.9 84.03
100 29.75 535-8 84.26
SOLUBILITY OF FERRIC CHLORIDE IN AQUEOUS SOLUTIONS OF
AMMONIUM CHLORIDE AT 25, 35, AND 45.
(Mohr Z. physik. Chem. 27, 197, '08.)
Results at 25. Results at 35. Results at 45.
Mols. per
100 Mols. HaO.
Mols. per
100 Mols. H 2 O.
Mols. per
100 Mols. H 2 O.
. .Solid Phase
NH4C1.
O
10.98
NHiCl.
O
FeaCU.
I3-36
NH4C1.
o.o
33-4
FeaCU-iaHaO (s-HaO at 4 S)
I .57
10.74
I.4I
I3-05
Hydrate + Double Salt
2.48
9.02
3-08
9.28
4.08
9-58
Double Salt
5-28
7-73
6.98
7.64
-
9-59
6.77
10.76
6.70
13.09
6.31
H
9-83
6.70
II .60
6-52
13-54
6.28
Double Salt + Mixed Crystals
9-65
6.07
12.28
6.08
12.91
5-49
Mixed Crystals
9-93
5-23
II .57
3 -98
13-49
4.84
9.92
3-97
11.89
3-38
13.46
4-99
10.31
2.05
I3-23
i 38
*
x 3-3
o.o
14-79
o.o
16.28
o.o
NH*a
IRON CHLORIDE
IS8
SOLUBILITY OF FERRIC CHLORIDE IN AQUEOUS SOLUTIONS OF
AMMONIUM CHLORIDE AT 15.
(Roozeboom Z. physik. Ch. 10, 148, '92.)
Mols.per TOO Mols.H2O. Grams per ipo Gms.H 2 O. Solid
NH4C1. FeCl 3 . " NHiCl. FeCla,' Phase.
O.O 9-30 0.0 83.88 FerClo.^HaO
I -9 9-57 3- 2 4 86.32
J -3 6 9-93 4-03 9I.6l Fe2Cl6.i2H 2 -f- Double Salt
2 . OO 9.27 5 9 2 83 . 64 Double Salt
2.79 8.71 8. 3 I 78.77
4.05 8.09 12. 08 73-2O
6.41 7.18 19.12 64.83
10.78 6.21 32.04 56.00
7 .82 6.75 23 . 21 60 .83 Mixed Crystals containing 7.29% FeQ 3
7.62 5.94 22.63 53-47 " " 5.55
"
7.70 5.03 22.90 45-42 " " 4-4
"
7-8i 4-34 23.23 39.13 3 .8
(i
8.52 2.82 25.33 25.43 x . 64
10.95 - 68 32-55 6 - I 5 - - o. 3 i
11.88 0.0 35-30 0.0 NH4C1
SOLUBILITY OF FERRIC CHLORIDE IN AQUEOUS HYDROCHLORIC ACID
SOLUTIONS AT DIFFERENT TEMPERATURES.
(Roozeboom and Schreinemaker Z. physik. Chem. 15, 633, '94.)
Mols. per too Mols. Gms. per 100 Gms. Mols. per 100 Mols. Gms. per 100 Gms.
H,0. H 2 0. Solid H 2 0. H 2 0.
Solid
HC1. FeCl 3 . HC1. FeCl 3 . -^hase. HC1. FeCl 3 . HC1. FeCl a
Phase
Results at o. Results at 25 (con.).
o 8.25 o 74-3'
o.o 29.00 o.o 261.1"
7.52 6.51 15.22 58.62
7.5 29.75 15.18 267.9
- FC2 %>
13-37 6.33 27.06 57.01
19-5 35-25 39-46 317. 4 j
5-"2v-'
16.80 8.70 33.99 78-34
*9-5 35- 2 5 39.46 317. 4 >
18.45 J0.23 37-34 92-10
20.40 15.40 41.28 138.7
Fe 2 Cl 6 20.6 35-34 41-68 318.3
I2H2 3 I -34 41-58 63.42 374.4
Fe 2 Cl 6
20.10 16.00 40.67 144.1
33-oo 43-oo 66.77 387-3
19-95 J 7-70 40.37 J 59-4
34.65 44.80 70.11 403.4^
19.00 22.75 38-45 2 4- 8
40.41 40.25 81.77 362.4'
18.05 23.41 36.53 210.8 J
39.03 41.38 78.98 372.7
* 62 .2HC1
18.05 23.40 36.53 210.8 ;
Fe 2 Cl6 35.74 45-24 72.33 407.4-
+ 4H2O
19.50 25.93 39.55 233.5 \
7H2O
Results at 40.
24.12 30.04 48.81 270.5
26.00 32.16 52.60 289.6
26.00 32.16 52.60 289.6
34.60 38.11 70.01 343.2
37.27 36.60 75.41 329.6 ,
34.60 38.11 70.01 343.2 ;
^HaO 32.4 0.0 291.7
., _. 13-4 37-45 27.11 337.3
2 .4H 2 o I 3-4 37-45 27.11 337.3
Fe 2 Cl 6 2 7- 50.80 54.64 457.5
.2HC1 58.0 0.0 522.3'
+ 4 H20 27 5Q g 54 64 457 5
L Fe 2 Cl
Results at 25. 42.01 48.64 85.00 438.0,
1
o.o 10.90 o.o 98. 151 42.50 47.52 86.72 428.0
2-33 23.72 4.715 213.6 K.^042.01 48.64 85.00 438.0
Fe 2 Cl 6
. 2 HC1
+ 4 H 2
O.O 24.5 0.0 220. 7 J
o.o 23.5 o.o 211. 6^| Results for other temperatures
2.33 23.72 4.715 213.4 |Fe 2 ci are also given in the
7.50 29.75 I 5- I 8 267.9 f - 7H2 paper.
original
o.o 31.50 o.o 283.6 J
159
IRON CHLORIDE
SOLUBILITY OP THE SALT PAIR FeCl a .NaCl IN WATER AT 21.
(Hinrichsen and Sachsel Z. physik. Chem. 50, 94, *o4-'os.)
Grams Used.
Gms. per 100
Gms. Solution.
G. Mols. per
iooMols.H 2 0. Solid
FeCI a . NaCl.
FeCl 3 . NaCl.
' Feds- " NaCl.'
o 3.6
o 36.10
O 1 1 2 NaCl
1.8 3.0
24.27 9-10
2 . 69 2.8 Mix Crystals
3-6 2.5
25.40 8.45
2.8l 2.6
5-5 2.0
26.40 5 .25
2.93 2-54
7.2 1.5
3 8 - I 5 3-9o
4.23 1.22
9.0 i.o
45 -3 8 2.45
5-03 o-75
10.8 0.5
46.75 2. ii
5.18 0.65
10.8 o.o
83.39 o.o
9.3 O.O FeCli
SOLUBILITY OF
THE SALT PAIR FeCl 5
,.KC1 IN WATER AT 21.
(H. and S.)
Grams Used.
Gms. per xoo
Gms. Solution.
Gm. Mols. per 100
Mols. H 2 0. SoM
Feda. KC1.
FeCl 3 . KC1.
FeCl 3 . " KCi:
o 35
o 34-97
8.45 KCI
13 28
13.44 24.45
I . 49 5 9O Mix Crystals
18 21
23.18 16.54
2-57 3-99
23 i8-5
28.05 11-69
3-II 2.82
28 16
35.72 11.68
3.96 2.82
3i 10.5
36.62 11.19
4 . 06 2 . 70 Double Salt
36.2 9
37-35 r 3-67
4-14 3-30
46.5 6
5!- 6 9 7-54
5-73 1-82
J5-5 o
83.89 o.o
9.3 0.0 FeCl 3
SOLUBILITY OF
THE SALT PAIR FeCl 3
.CsCl IN WATER AT 21.
(H. and S.)
Grams Used.
Gms. per 100
Gms. Solution.
Gm. Mols. per 100
Mols. H 2 O. Sond
FeCli. CsCll
' FeCl 3 . CsCl. "
'Fed,.' CsCL
o 65
o.o 65.0
O-O 6.95 CsCl
0.6 II. 6
0-45 55- 18
-5 5-9 FeCl 3 .CsCl.H 2 O
1.4 IO.2
2.1 5 2 -3 8
0.23 5.6
2.2 8.8
5.24 51.44
o-57 5-5
2.0 7.4
7.8 47-70
0.86 5.1 FeCl 3 .2CsCl.H 2
3.8 6.0
8.93 41.15
0.99 4.4
4.6 4.6
15-34 25.25
1.70 2.7
5-4 2.8
21.65 14.96
2.40 1.6
6.2 1.4
27.96 8.42
3.10 0.9
35.0 0.2
48.71 0.94
5.40 o.i
35.0 o.o
83.89 o.o
9.3 0.0 FeCls
ioo gms. abs. acetone dissolve 62.9 gms. FeCl 3 at 18.
(Naumann Ber.37, 4332, 04.)
IBON NITRATE
160
IRON NITRATE (Ferrous) Fe(NO 3 ) 2 .
Cms.
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt 3, 438, 'oo.)
Mols. Cms. Mols.
Fe(N0 3 ) 2
Fe(N0 3 ) 2 MM
Fe(N0 3 ) 2
Fe(N0 3 ) 2
Solid
t.
per 100
Cms.
per 100
Mols.
Phase.
t .
per 100
Cms.
per 100
Mols.
Phase.
Sol.
H 2 0.
Sol.
H 2 0.
-27
35-66
5-54
Fe(N0 3 ) 2 .oH 2
-9
39-68
6-57
Fe(NO 3 ) 2 .6H 2 O
-21.5
36.10
5-64
u
41-53
7.10
-19
36-56
5-76
18
45-14
8-23
>
- x s-s
37-17
5-9i
M
24
46.51
8.70
"
60.5
62 .50
16.67
M
Density of solution saturated at 18 = 1.497.
IRON OXIDES, HYDROXIDE and SULPHIDE.
7n Suear
in Sol-
SOLUBILITY IN AQUEOUS SUGAR SOLUTIONS.
(Stolle Z. Ver Zuckerind. 50, 340, 'oo.)
One Liter of Sugar Solutions Dissolves Milligrams of:
Fe 2 (OH) 6 at;
FegOa at:
Fe 3 O 4 at:
FeS at:
vent.
17.4.
45.
75.
17.5.
45.
17-5.
45.
75: '
17.5.
45.
75.
IO
3-4
3-4
6.1
1.4
2.0
10.3
10-3
12.4
3-8
3-8
5-3
30
2 -3
2.7
3-8
1-4
12-4
10-3
12.4
7-i
9.1
7.2
50
2-3
1.9
3-4
0.8
I .1
14-5
10-3
14-5
9-9
19.8
9.1
IRON PHOSPHATE Fe 2 (PO 4 ) 3 .
THE ACTION OF WATER AND OF AQUEOUS SALT SOLUTIONS UPON
FERRIC PHOSPHATE.
(Lachowicz Monatsh. Chem. 13, 357, '92; Cameron and Hurst J. Am. Chem. Soc. 26, 888, '04.)
The experiments show that the ordinary precipitation methods for
the production of ferric phosphate give products which do not conform
to the formula Fe 2 (PO 4 ) 3 . By digesting such samples with water
very little is dissolved, but the material is decomposed to an extent
depending upon the relative amounts of solid and solvent used. The
amount of PO 4 dissolved per gram of Fe 2 (PO 4 ) 3 varies from about
0.0026 gram removed by 5 cc. H 2 O to 0.0182 gram removed by 800 cc.
H 2 O at the ordinary temperature.
IRON SULPHATE (Ferrous) FeSO 4 .7H 2 O.
SOLUBILITY IN WATER.
(Franckel Heidelberg '05, Landolt and Bernstein's Tabellen, 3d ed. p. 537, f o<5.)
Gms. FeSO 4 , ,. .
t . per 100 g ld
Gms. H 2 O. Phase -
56.6 54-58 FeSO 4 .7H 2 + FeSO 4 .4H 2 O
00
70
75-8
80
90
t.
Gms. FeS0 4 -,.,
oKSSb. St.
-1.82
14.98 Ice+FeS0 4 .7H 2 O
o
15.62 FeSO 4 .7H 2 O
10
20.85
20
26.42
30
33.00
40
40 . 20
5
48.55
55-02
56.04
56.8 FeSO 4 .4H 2 O -f FeSO 4 H 2 O
50.6 FeSCu-HjO
43.0
ioo grams sat. solution in Glycol contain 6.0 grams FeSO 4 at ordi-
nary temperature. (de Coninck.)
161 IRON POTASSIUM SULPHATE
IEON POTASSIUM SULPHATE (Ferrous) FeSO 4 .K 2 SO 4 .6H 2 O.
SOLUBILITY IN WATER.
(Tobler Liebig's Ann. 95, 193, '55.)
35
40
55
65
70
t.
Cms. K2Fe(SO 4 ) 2
per 100 Grams
H 2 0.
o
19.6
10
24-5
14.5
29.1
16
30-9
25
36.5
per 100 Grams
HjjO.
41 .o
45-o
56.0
57-3
64.2
SOLUBILITY OF MIXTURES OF FERROUS SULPHATE FeSO 4 .7H 2 O AND
SODIUM SULPHATE Na 2 SO 4 .ioH 2 O IN WATER.
(Koppel Z. physik. Chem. 52, 405, '05.)
Cms. per 100 Gms. Cms. per 100 Cms.
t. Solution. H 2 O. Solid Phase.
FeS0 4 .
Na 2 S0 4 .
FeS0 4 .
Na 2 s6 4 .
O
14
54
4
93
18
.06
6
.11
FeSQ 4 .7H 2 O + Na 2 SO 4 .ioHaO
15-5
17
.76
II
32
25
05
15
97
21.8
16
57
15
32
24
34
22
5 1
FeNa-zCSO^^H^
24.92
16
.21
15
13
23
.62
22
.04
"
35
16
35
14
.98
23
.91
21
83
"
40
16.37
15
.42
24
.01
22
.62
"
18.8
18
13
13
.8
26
63
2O
.28
FeNa 2 (SO 4 )2-4H 2 O + FeSO^HjO
23
19
58
12
5
28
.82
18
4
27
20
97
II
3
30
95
16
.64
"
31
22
.91
9
.71
33
99
14
.41
4 <
35
23
85
9
.26
35
.61
13
85
4 ti
40
26
32
7
85
39-98
II
.92
18.8
18
23
14
83
27
- 2 3
22
.16
FeNa 2 (SO 4 ) 2 4H 2 O + N a2 SO 4 .ioH 2 O
23
13
83
18
.04
20
.31
26
.48
28
7
.66
24
.41
ii
.28
35
94
>
31
4
58
29
50
6
95
44
75
1C
35
4
.04
30-49
6
.16
46
58
FeNa 2 SO 4 4H 2 O + NaaSO 4
40
4
.10
30
.60
6
.27
46
99
M ti
LANTHANUM BROMATE 162
LANTHANUM BROMATE La(BrO 3 ) 3 . 9 H 2 O.
100 gms. H 2 O dissolve 28.5 gms. lanthanum bromate at 15.
(Marignac.)
LANTHANUM SULPHATE La 2 (SO 4 ) 3 . -f 4/f y6
SOLUBILITY IN WATER.
(Muthmann and Rolig Ber. 31, 1723, '98.)
t. c
rms.LaiiCSO^a per 100 Gms.
Solution. Water.
>ms. La 2 (SO 4 )3 per 100 Gms.
Solution.
Water.
o
14
30
2.91
2-53
2.6
1.9
50
75
100
1.47
o-95
0.68
0.96
0.69
LEAD Pb.
MUTUAL SOLUBILITY OF LEAD AND ZINC.
(Spring and Romanoff Z. anorg. Chem. 13, 34, 'p6.)
Upper Layer. Lower Layer. Upper Layer. Lower Layer.
*
jox
%P
08
b.
.8
%Zn/
I .2
%
Pb.
%
Zn.
%Pb. %Zn.'
6CO &2 O 1*7 O
%P
b.
/-\
%Zn.
c\ *? r\
66**
y
u^u t^ . \j i i . <j
U
93 -
419
i
5
98
5
740 79 .0 21.0
10
.0
90.0
450
92
.0
8.0
.
.
800 75 .0 25.0
14
.0
86.0
475
91
.0
9.0
2
O
98
O
900 59.0 41.0
25
5
74-5
584
86
o
14.0
5
.0
95
.0
910-920 (crit. temp.)
LEAD ACETATE Pb(C 2 H 3 O 2 ) 2 . 3 H 2 O.
SOLUBILITY IN SEVERAL SOLVENTS.
Solvent.
(U. S. P.)
Grams Pb(C 2 H 3 O 2 )2 per 100 Grams Solvent at:
25. b. pt.
Water 50 200
Alcohol 3.3 100
Alcohol (0.941 Sp. Gr.) 12.5 (per 100 cc. at 15.5)
Glycerine 20.0 (15)
LEAD BENZOATE Pb(C 7 H 5 O 2 ) 2 .H 2 O.
SOLUBILITY IN WATER.
(Paietta Gazz. chim. ital. 36, II, 67, '06.)
t. 18. 40.6*. 49.-C.
Gms. Pb(C 7 H 6 2 ) 2 .H 2
per 100 gms. sat. solution 0.149 0.249 0.310
LEAD BEOMATE Pb(BrO,) 2 .H 2 O.
100 gms. cold water dissolve 1.33 gms. lead bromate.
(Rammelsberg Pogg. Annalen. 52, 06, '41; BOttger Z. physik. Chem. 46, 6oa, '03.)
LEAD BROMIDE
LEAD BROMIDE PbBr,
SOLUBILITY IN WATER.
(Lichty J. Am. Chem. Soc. 25, 474, '03.)
Density
4.O f^t Q/\1iitirmc
Cms. PbBr 2 per 100
Milligram Mols. PbBr 2 per 100
v OI oOlUtlons,
HzO at o.
cc.
Solution.
Cms. H 2 O.
cc. Solution.
Cms. H 2 O.
.0043
4554
O
4554
I
.242
I .242
15
0053
O
7285
O
7305
I
.987
I. 9 8 9
25
.0061
O
.9701
9744
2
.646
2-655
35
.0060
I
.3124
j
3220
3
577
3-603
45
.0059
I
7259
I
7457
4
705
4-760
55
.0046
2
.1024
2
1376
5
731
5-827
65 i .0028
2
.516
2
574
6
859
7.016
80 i .0000
3
2 35
3
343
8
.819
9-II3
95 o-9995
4
.1767
4
3 6l 3
n
.386
11.890
100
4
550
4
75i
12
.40
12.94
SOLUBILITY OF LEAD BROMIDE IN AQUEOUS HYDROBROMIC ACID
AT 10.
100 grams H 2 O containing 72.0 grams HBr dissolve 55.0 grams
PbBr 2 per 100 gms. solvent, and solution has Sp. Gr. 2.06.
(Ditte Compt. rend 92, 719, '81.)
LEAD CARBONATE PbCO 3 .
SOLUBILITY IN WATER BY ELECTRICAL CONDUCTIVITY METHOD.
(Kohlrausch and Rose Z. physik. Chem. 12, 241, '93; Bottger Ibid. 46, 602, '03.)
i liter of water dissolves o.oon 0.0017 gram PbCO 3 at 20.
LEAD CHLORATE Pb(ClO 3 ) 2 .
100 grams H 2 O dissolve 151.3 grams Pb(ClO 3 ) 2 , or 100 grams sat.
solution contain 60.2 gms. Pb(ClO 3 ) 2 at 18. Density of solution, 1.947.
(Mylius and Funk Ber. 30, 1718, '97.)
LEAD CHLORIDE PbCl 2 .
SOLUBILITY IN WATER.
(Lkhty, see also Formanek Chem. Centrb. 18, 270, '87; Bell Chem. News, 16, 69, '67; Ditte
Compt. rend. 92, 718, *8i.)
Density
t nf Solutions
Gms. PbCl 2 per 100
Milligram Mols. PbCl 2 per 100
. 01 ooiuiions,
H 2 at o.
cc.
Solution.
Gms. HzO!
cc.
Solution.
Grams H^."
.0066
O
.6728
O
.6728
2
421
2
.421
15
.0069
O
.9070
.9090
3
265
3
.272
25
.0072
I
.0786
I
.0842
3
.882
3
903
35
.0060
I
3*50
I
3244
4
733
4
767
45
.0042
I
549 8
I
5673
5
579
5
644
55
.0020
I
.8019
I
.8263
6
.486
6-573
65 0.9993
2
.0810
2
.1265
7
.490
7
.651
80 0.9947
2
.5420
2
.6224
9
.150
9
439
95 0.9894
3
0358
3
.1654
10
.926
ir
394
100
3
.208
3
342
ii
52
12
.01
LEAD CHLORIDE 164
SOLUBILITY OP LEAD CHLORIDE IN AQUEOUS SOLUTIONS OP HYDRO-
CHLORIC ACID.
(At 0, Engel Ann. chim. phys. [6] 17, 359, '89; at 25, Noyes Z. physik. Chem. 9, 623, '92; at differ-
ent temperatures, Ditte Compt. rend. 92, 718, '81; see also Bell J. Chem. Soc. 21, 350, '68.)
Gms. HCl
per
Liter.
Gms. PbCl 2 per
Liter at:
Gms. HCl
per loo
Gms. H 2 O.
Gms. PbCl 2 per 100 Gms. Solution at:
25.
0.
20.
40.
55.
' 80.
5
83
10
79
O
8
O
ii .8
17 .0
21 .O
31.0
o-5
4
5
9.0
IOO
i
.2
1.4
3-2
5-5
12.0
1.0
3
.6
7
.6
150
i
5
2.0
S-o
7-5
16.0
2.0
2
.2
6
.0
200
3
5
5-o
8.2
11.7
21.5
3-o
I
.6
5
.0
250
6
5
8.0
13.0
16.2
28.5
6
I
4
.1
300
IO
7
12.5
17-5
22.
10
I
.2
i
.8
400
21
5
24.0
100
I
.2
.
200
5
.2
.
_ f
250
10
5
.
300
17
5
.
400 40.0
SOLUBILITY OF LEAD CHLORIDE IN AQUEOUS SALT SOLUTIONS
AT 25.
(Noyes; in HgCl 2 solutions at 20, Formanek Chem. Centralb. 270, '87.)
In Aqueous Solutions of:
HCl, KC1, MgCl 2 , CaCl 2 , MnCl 2 In CaCl 2
and ZnCl 2 Gram Equivalents Gram Equiv.
per Liter of: per Liter.
In HgCl 2
Gram Equiv.
per Liter.
In Pb(NO 3 ) 2
Gram Equiv.
per Liter.
Salt. PbCl 2 .
CdCl 2 . PbCl 2 .
HgCl 2 . PbCl 2 .
Pb(NO 3 ) 2 . PbCl 2 ".
o.o 0.0777
0.05 0.050
o.io 0.035
o.oo 0.0777
0.05 0.0601
o.io 0-0481
o.o 0.0777
o.i 0.0992
o.o 0.0777
O.2 0-0832
0.20 0-021
0.20 0-0355
The above results were calculated to grams per liter plotted on cross-
section paper, and the figures in the following table read from the
curves.
Gms. Salt
Grams
PbCl 2 per
Liter in Aqueous Solutions of:
-JL
per
Liter.
HCl.
KC1.
MgCl 2 .
CaCl 2 .
MnCl 2 . ZnCl 2 .
CdCl 2 .
HgCl 2 .
Pb(N0 3 ) 2
10.79
10.79
10.79
IO
79
IO
79 io-79
10.79
IO-79CN) 9-7i(F) 10.79
I
8-5
9-3
7-7
8
7
9
5
IO.2
II .0
9 .8
10.8
2
6-5
8.2
6-5
7
.6
8
.3
9-7
11.4
IO.O
10.85
3
S- 2
7-2
5-7
6
7
7
3
9.2
11.7
10.3
10.87
4
4-3
6.5
S- 2
6
.0
6
3
8.6
12.0
10.5
10.90
6
3- 2
5-3
4-4
4
.8
5
.0 ...
7-7
I2. 7
II. O
10.95
8
2-5
4-5
3
9
4
.1
7.0
13-3
ii. 6
ii .00
10
2.1
3-9
3
3
3
5
6-3
14.0
12.2
11.05
U
3-i
.
2
.8 3.0
5-4
I 3 .2
11.15
20
4.7
14 8
1 1 . 20
40
} U
IO.O
ii .70
i6 5 LEAD CHLORIDE
SOLUBILITY OF LEAD CHLORIDE IN GLYCERINE.
(Presse Ber. 7, 599, '74.)
i part glycerine + 7 parts H 2 O dissolve 0.91 per cent PbCl 2 .
i part glycerine + 3 parts H 2 O dissolve 1.04 per cent PbCl 2 .
i part glycerine + i part H 2 O dissolves 1.32 per cent PbCl 2 .
Pure glycerine dissolves 2.00 per cent PbCl 2 .
LEAD GHROMATE PbCrO 4 .
One liter of water dissolves 0.0002 gram PbCrO 4 at 18 (conductivity
method) . (Kohlrausch Z. physik. Chem. 50, 365, 'o 4 -'o 5 .)
SOLUBILITY OP LEAD CHROMATE IN AQUEOUS POTASSIUM HYDROXIDE
SOLUTIONS.
(Lacland and Lepierre Bull. soc. chim. [3] 6, 230, '91.)
t . Grams KO H per i oo cc . Grams P bCrO 4 per i oo cc .
15 2.308 I.I9
60 2.308 1.62
80 2.308 2.61
102 2.308 3.85
LEAD CITRATE Pb(C 6 H 5 O 7 ) 2 .H 2 O.
SOLUBILITY IN WATER AND IN ALCOHOL.
100 gins. H 2 O dissolve 0.04201 gm. Pb(C 6 H 5 O 7 ) 2 .H 2 O at 18, and
0.05344 gm. at 25.
100 gms. alcohol (95%) dissolve 0.0156 gm. Pb(C 6 H 6 O 7 ) 2 .H 2 O at
1 8, and 0.0167 g m - at 2 5- (Partheil and Hubner Archiv. Pharm. 241, 413, '03.)
LEAD DOUBLE CYANIDES.
SOLUBILITY IN WATER.
(Schuler Sitzber. Akad. Wiss. Wien, 79, 302, '79.)
Double Salt. Formula. t. ^' ^0
Lead Cobalticyanide Pbg[Co(CN) 6 ] 2 .7H 2 O 18 56.5' '
Lead Cobalticyanide PbJCo(CN) 6 ] 2 .7H 2 O 19 61.3
Lead Potassium Cobalticyanide PbKCo(CN) 6 .3H 2 O 18 14.8
Lead Cobalticyanide Nitrate Pbg[Co(CN) 6 ] 2 .Pb(NO 3 ) 2 .i2H 2 O 18 5.9
Lead Ferricyanide Nitrate PbjFe(CN) 6 ] 2 .Pb(NO 3 ) 2 .i2H 2 O 16 7.5
Lead Potassium Ferricyanide PbKFe(CN) 6 .3H 2 O 16 21.0
LEAD FLUORIDE PbF 2 .
One liter of water dissolves 0.64 gram PbF 2 at 18 (conductivity
method) . (Kohlrausch Z. physik. Chem. 50, 365, 'o 4 -'os.)
LEAD FORMATE Pb(HCOO) 2 .
SOLUBILITY OF LEAD FORMATE IN AQUEOUS SOLUTIONS OF BARIUM
FORMATE AT 25.
(Fock Z. Kryst. Min. 28, 383, '97.)
Mol. % in Solution. Grams per Liter. Sp. Gr. of In Solid Phase Mol.% of
Pb(HCO 2 ) 2 . Ba(HCO 2 ) 2 .
O-OO IOO.O
0.29 99.71
0-74 99.26
1.24 98.76
2.91 97.09
5.92 94.08
100.00 o.o
Pb(HC0 2 ) 2 .
Ba(HCO 2 ) 2 - Solutions.
Pb(HC0 2 ) 2 .
Ba(HC0 2 ) 2 .
28.54
.22O4
0-0
100
I.I04
28.6 5
.2213
1.72
98.28
2.803
28.90
.2251
5- 2 9
94.71
5-309
32.24
.2529
11-94
88.06
II .42
29.29 ]
.2341
24.81
75 *9
23.11
28.13 ]
2355
56.54
43-46
28.35
]
.0911
IOO.O
O-O
LEAD HYDROXIDE
166
LEAD HYDROXIDE Pb(OH) 2 .
SOLUBILITY OF LEAD HYDROXIDE IN AQUEOUS SOLUTIONS OF SODIUM
HYDROXIDE. (Moist Lead Hydroxide used, temperature not given.)
(Rubenbauer Z. anorg. Chem. 30, 336, '02.)
Viol. Dilution Grams per 100 cc. Solution,
of NaOH. ' NaOH. Pb(OH) 2 .
2.27 1-759 0-590
1.44 2.778 i .010
0.785 5-10 2.056
0.485 8.235 2-370
0.258 15-470 3-Qio
Amt. of Na
Amt. of Pb,
in 20 cc.
in 20 cc.
o . 2024
O.IOI2
0.3196
0.1736
0-5866
0-353 2
0.9476
o . 407 i
1.7802
0.5170
LEAD IODATE Pb(IO 3 ) 2 .
One liter of water dissolves 0.019 gm. Pb(IO 3 ) 2 at 18.
(Kohlrausch; Bottgen
LEAD IODIDE PbI 2 .
SOLUBILITY IN WATER.
(Lichty J. Am. Chem. Soc. 25, 471, '03.)
to
Densitv.
Grams PbI 2 per 100
Millimols PbI 2 per TOO
.
(H 2 O at o.)
cc. Solution.
Grams H 2 O.
cc. Solution.
Grams H 2 O.
o
I .OOO6
0.0442
o . 0442
0-096
0-096
15
o 9998
0-0613
0-0613
0-133
0-133
25
o - 9980
0-0762
0-0764
0.165
0.166
35
0-9951
0-1035
o . 1042
0-224
0.226
45
0-9915
0.1440
0.1453
0.312
0-315
55
0.9872
0-1726
0-1755
o-374
0.381
65
0.9827
O.2I4O
0.2183
0.464
0-473
80
0-9745
0.2937
0.3023
0-637
0.656
95
0.9671
0.3814
0.3960
0.828
0.859
100
0-420
0.436
0.895
0.927
SOLUBILITY OF LEAD IODIDE IN ACETONE, ANILIN AND AMYL ALCOHOL.
(von Laszczynski Ber. 27, 2285, '94.)
Solvent.
(CH 3 ) 2 CO
C 6 H 5 NH 2
C 6 H 5 NH 2
C 5 H 7 OH
t.
59
13
184
133-5
Grams PbI 2 per too Grams Solvent.
0.02
0-50
1. 10
i6 7
LEAD IODIDE
SOLUBILITY OF MIXTURES OF LEAD IODIDE AND POTASSIUM IODIDE
IN WATER.
(Ditte Ann. chim. phys. [5] 24, 226, '81; Schreinemaker Z. physik. Chem. 9, 65, '92.)
Grams per 1000 Cms. H-jO.
Mols. per 1000 Mols. H 2 O.
* .
PbI 2 .
KI.
PbI 3 .
K 2 i 2 :
5
I6 3
8.8
20
9
200
o-3
14.1
28
25
325
0.9
17.6
39
45
449
1.8
24-3
67
255
75 1
9.9
40.7
80
73 1
1186
28.5
64-3
80
5 J 9-9
976.4
22 .2
52-9
104.5
1411
1521
55-i
82.5
1 20
2151
1812
83-9
98.2
137
2874
2097
112 .2
113.8
J 75
5 6 o3
2947
218.7
159-9
189
3339
181.0
9
96.6
1352
3-77
73-3
*3
U4-3
1384
4.46
75-05
23
186.3
1510
7.27
81.08
50
526.7
1906
20.56
103-3
64
789-3
2161
30.8
117.2
83-5
1108.6
2434
43-2
i3i-9
92
1273
2566
49-7
139-3
137
2382
3278
93-o
117.7
165
4187
4227
163.4
229.1
218
10303
402.3
241
12803
7998
499.9
433-6
242
12749
497-8
250
15264
596.0
Solid
Phase.
Double Salt + PbI 2
Double Salt + KI
157
172
186
194
2OI
Cms. PbI 2 .2KI per
1000 Gms. H 2 O.
Mols. PbI 2 .2KI per
1000 Mols. H 2 O.
52l8
6489
141.07
175-5
7903
9266
II320
213.7
250.6
306.0
Solid Phase.
PbI 2 .2KI.2iH 2 O
LEAD MALATE Pb.C 4 H 4 O 6 . 3 H 2 O.
SOLUBILITY IN WATER AND ALCOHOL.
(Partheil and Hubner Arcbiv. Pharm. 241, 413, '03.)
ioo gms. H 2 O dissolve 0.0288 gm. PbC 4 H 4 O 5 .3H 2 O at 18, and
0.06504 gm. at 25.
ioo gms. 95% alcohol dissolve 0.0048 gm. PbC 4 H 4 O 5 .3H 2 O at 18-
25-
Density of alcohol employed = 0.8092.
LEAD NITRATE 168
LEAD NITRATE Pb(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Mulder; Kremers Pogg. Ann. 92, 497, '54; at 15, Michel and Kraft Ann. chim. phys. [3] 41,
471, '54; at 17 , Euler Z. physik. Chem. 49, 314, '04.)
Grams Pb(NOg) 2 per 100 Cms. Grams Pb(NO 3 ) 2 per 100 Cms.
Water.
Solution.
Water.
Solution.
36-
5 (I)
38
.8< 2 >
27
33 (3)
40
69.4
75
.0
41.9
10
44
4
48
3
31
.6
5
78.7
85
.0
45.0
17
50
.0
54
34
.2
60
88.0
95
.0
47-8
2O
S 2
3
56
5
35
.2
80
107.6
"5
o
52-7
25
56
4
60
.6
36
9
100
127.0
138
.8
30
60
7
66
.0
38
.8
17
52.76*
34-54 51
* Euler.
(i) Mulder, (2) Kremers, (3) Average of M and K.
Density of saturated solution at 17 = 1.405. (Euler.)
SOLUBILITY OP LEAD NITRATE IN ETHYL AND METHYL ALCOHOL.
Cms. Pb(NO 3 ) 2 per 100 Grams Solvent at:
Solvent. / * -v
4. 8. 22. 40. 50.
Aq. C 2 H 6 OH (Sp. Gr. .9282) 4.96 5.82 8.77 12.8 14.9 (G)
Abs. C 2 H 6 OH o. 04 (20.5) (de B)
Abs. CH 3 OH 1.37 "
(Gerardin Ann. chim. phys. [4] 5, 129, '65; de Bruyn Z. physik. Chem. 10, 783, '92.)
SOLUBILITY OF MIXED CRYSTALS OF LEAD NITRATE AND STRONTIUM
NITRATE IN WATER AT 25.
(Fock Z. Kryst. Min. 28, 372, '97.)
Mol. per cent in Solution.
Cms. per 100 cc. Solution.
Sp. Gr. of
Mol. per cent in Solid Phase.
Pb(N0 3 ) 2 .
Sr(N0 3 ) 2 .
Pb(N0 3 ) 2 .
Sr(N0 3 ) 2 .
Solutions.
Pb(N0 3 ) 2 .
Sr(N0 3 ) 2 .
100
.0
4 6
31
o.o
I
4472
100
O
.0
87.41
12
39
50
47
4-5 6
I
4336
99
05
95
78.68
21
32
53
.92
8.14
I
.4288
9 8
.11
I
.89
5 6 -39
43
.61
45
34
17.81
I
.4263
97
.02
2
.98
60.29
39
7 1
44
.48
18.74
I
4245
96
.06
3
94
33-70
66
30
25
23
35-03
I
.4468
83
.84
16
.16
24-58
75
.42
19
!3
37-54
I
.4867
32
.88
67
.12
o.o
100
o
o
.0
71.04
I
5*41
100
.00
LEAD OXALATE PbC 2 O 4 .
One liter of water dissolves 0.0015 gm. PbC 2 O 4 at 18 (conductivity
method). (Bottger Z. physik. Chem. 46, 602, '03; Kohlrausch Ibid 50, 356, W-'os.)
LEAD OXIDES. SOLUBILITY IN WATER.
(Bottger; Ruer Z. anorg. Chem. 50, 273, '06.)
No - Description of Oxide. " pe?L?ter.
1. Yellow Oxide, by boiling Pb hydroxide with 10% NaOH i . 03 X io~* o. 023
2. Red Oxide, by boiling Pb hydroxide with cone. NaOH 0.56X10"* 0.012
3. Yellow Oxide, by heating No. i to 630 1.05X10"* 0.023
4. Yellow Oxide, by heating No. 2 to 740 i.ooXio" 4 0.022
5. Yellow Oxide, by heating com. yellow brown oxide to 620 i . 09 X io~ 4 o. 024
6. Yellow Brown Oxide commercially pure i.ioXio" 4 0.024
7. Yellow Brown Oxide, by long rubbing of No. 5. 1.12X10"* 0.025
Bottger gives for three samples of lead oxide, 0.017, 0.021, and 0.013
gm. per liter respectively.
i6 9 LEAD PALMITATE
LEAD PALMITATE, LEAD STEARATE.
100 cc. absolute ether dissolve 0.0138 gm. palmitate and 0.0148
gm. stearate.
(Lidoff Bull. soc. chim. [3] 10, 356, '93.)
LEAD PHOSPHATE (Ortho) Pb 3 (PO 4 ) 2 .
One liter of 4.97 per cent aqueous acetic acid solution dissolves 1.27
gms. Pb 3 (P0 4 ) 2 .
(Bertrand Monit. Scknt. [3] io, 477. '68.)
LEAD SUCCINATE PbC 4 H 4 O 4 .
SOLUBILITY IN WATER AND IN ALCOHOL.
(Partheil and Hxibner Archiv. Pharm. 241, 413, '03.)
ioo gms. H 2 O dissolve 0.0253 gm. PbC 4 H 4 O 4 at 18, and 0.0285
gm. at 25.
ioo gms. 95% alcohol dissolve 0.00275 gm. PbC 4 H 4 O 4 at 18, and
0.003 g m - a "k 2 5-
Density of alcohol used = 0.8092.
LEAD SULPHATE PbSO 4 .
One liter of water dissolves 0.041 gm. PbSO 4 , by conductivity
method.
(Kohlrausch; Bottger. Dibbits Z. anal. Chem. 13, 139, '74, finds 0.038 gram by gravimetric method.)
SOLUBILITY OF LEAD SULPHATE IN AQUEOUS SOLUTIONS OF STRONG
ACIDS.
(Schultz Pogg. Ann. 113, 137, '61; Rodwell J. Chem. Soc. 15, 59, '62.)
In Aq. H 2 SO 4 . In Aq. HC1. In Aq. HNO 3 .
(a). (&). (c). (a). (i). (c). (a). (6). (c).
1.540 63.4 0-003
J -793 85.7 O.OII
1.841 97.0 0.039
.05 10.6 0.14 i. 08 ii. 6 0.33
.08 16.3 0-35 1. 12 17.5 0-59
II 22.0 0.95 1.25 34.0 0.78
.14 27.5 2. II 1.42 6o.O I. 01
.16 31.6 2.86
(a) Sp. Gr. of Aq. Acid. (6) Gms. Acid per ioo Gms. Solution, (c) Gms.PbSO 4 per ioo Gms. Solvent.
SOLUBILITY OF LEAD SULPHATE IN AQUEOUS SOLUTIONS OF AMMO-
NIUM ACETATE AND OF SODIUM ACETATE.
(Noyes and Whitcomb J. Am. Chem. Soc. 27, 756, '05; Dunnington and Long Am. Ch. J. 22,
217, '99; Dibbits Z. anal. Chem. 13, 139, '74.)
In Ammonium Acetate. In Sodium Acetate.
At 25 (N. and W.). At 100 (D. and L.). (D.).
Millimols
per Liter.
Grams per Liter. ^
}.NH 4 C 2 H 3 O 2 G.PbSO 4
per ioo cc. per ioo g.
Solution. Solution.
Gms. per ioo Gms. H 2 O.
z . PbSO 4 .
NH 4 C 2 H 3 6 2 .
PbS0 4 .
NaC 2 H 8 O 2 . PbSO 4 .
o.o
2O7.I
0.134
2.IO
4-55
o.o
7.98
15.96
O.O4I
0-636
L38
28
32
37
7.12
9.88
10.58
2.05
8.2
41.0
0.054
0.853
11.23
4I4.I
10.10
31.92
3.02
45
ii .10
LEAD (Hypo) SULPHATE 170
SOLUBILITY OP MIXTURES OF LEAD HYPOSULPHATE AND STRONTIUM
HYPOSULPHATE AT 25.
(Fock Z. Kryst. Min. 28. 389. '97 )
Mol. per cent in Solution.
Grams per Liter.
Sp. Gr. of
Mol. per cent in Solid Phase
PbSg.
SrSzO."
PbS 2 6 .
SrS 2 6 .
Solutions.
PbS 2 6
SrSjOe
^HzO.
-4H 2 O.
.4!!^.
0.0
100.
o.o
145.6
I .1126
o.o
IOO-O
1.05
98.95
2-97
I5I.2
I .1184
0.30
99 7
15 .31
84-69
40.82
152.5
I-I503
3-87
96.13
46.80
53-20
149.2
II4-5
I.2I47
9.84
90.16
62.30
37-70
256.1
85.0
1.2889
19.26
80.74
75-75
24.25
310.3
67.0
I-3252
23-73
76.27
78.09
21 .91
373-7
70-8
1.3726
32.24
67.76
88.29
11.71
509-5
45 - 6
1.4671
49-97
50-I3
IOO-O
O-OO
374-3
o.o
1.6817
o.oo
0-00
LEAD TARTRATE PbC 4 O 6 H 4 .
SOLUBILITY IN WATER.
(Cantoni and Zachoder Bull. soc. chim. [3] 33, 751, '05; Partheil and Hiibner Archiv. Pharm. 241,
413. '03-)
f0 Cms. PbC 4 OeH4 per t o Gms. PbC 4 C>6H 4 per t o Cms. PbC 4 O<jH 4 per
100 cc. Solution. 100 cc. Solution. 100 cc. Solution.
l8 O.OIO (P. and H.) 50 O-OO225 70 0.0032
25 0.0108 " 55 0.00295 75 0.0033
35 0.00105 60 0.00305 80 0.0038
40 0-0015 65 0.00315 85 0.0054
NOTE. The positions of the decimal points here shown are just
as given in the original communications.
100 gms. alcohol of 0.8092 Sp. Gr. (about 95%) dissolve 0.0028 gm.
PbC 4 O 6 H 4 at 1 8, and 0.00315 gm. at 25. (P . and H .)
LEVULOSE C 6 H 12 O 6 .
100 gms. saturated solution in pyridine contain 18.49 g ms - C 6 H,.,O 8
at 26, Sp. Gr. I.052I. (Holty J. Physic. Chem. 9, 764, '05.)
LIGROIN.
100 cc. H 2 O dissolve 0.341 cc. ligroin at 22 Vol. of solution = 100.34,
Sp. Gr. 0.9969.
100 cc. ligroin dissolve 0.335 cc. H 2 O at 22 Vol. of solution = 100.60,
Sp. Gr. 0.6640. (Herz Ber.3i, 2671, '98)
LITHIUM BENZOATE C 6 H 5 COOLi.
100 gms. H 2 O dissolve 33.3 gms. at 25, and 40.0 gms. at b. pt.
100 gms. alcohol dissolve 7.7 gms. at 25, and 10.0 gms. at b. pt.
(u. s. P.)
LITHIUM BORATE Li 2 OB 2 O 3 .
SOLUBILITY IN WATER.
t o 10 20 30 40 45
Gms. Li 2 OB 2 O 3 per 100 Gms. H 2 O 0.7 1.4 2.6 4.9 11.12 20
(Le Chatelier Compt. rend. 124, 1094, '97.)
i7i LITHIUM BROMATE
LITHIUM BROMATE LiBrO 3 .
ioo gms. H 2 O dissolve 153.7 gms. LiBrO 3 at 18, or ioo gms. saturated
solution contain 60.4 gms. Sp. Gr. of sol. = 1.833.
(Mylius and Funk Ber. 30, 1718, '97.)
LITHIUM BROMIDE LiBr.
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 104, 133, '58.)
t o Gms. LiBr per ioo Gms. Gms. LiBr per ioo Gms.
Water. Solution. Water. Solution.
O 143 58.8 40 202 66.9
10 161 61.7 50 214 68.2
20 177 63.9 60 224 69.1
25 184 64.8 80 245 71.0
30 190 65.5 ioo 266 72.7
ioo gms. saturated solution in glycol, C 2 H 4 (OH) 2 .H 2 O, contain 37.5
gms. LiBr at 14. 7. (de Coninck Chem. Centr. 76, II, 883, '05.)
LITHIUM CARBONATE Li 2 CO 3 .
SOLUBILITY IN WATER.
(Bevade J. russ. phys. chem. Ges. 16, 591, 84; Bull. soc. chim. [2] 43, 123, '85; Fliickiger Arch.
Pharm.[ 3 ]25, 542, '87; Draper Chem. News, 55, 169, '87.)
An average curve was constructed from the available results and
the following table read from it.
Gms.Li 2 CO 3 per ioo Gms. Gms. Li 2 CO 3 per ioo Gms.
Water. Solution. Water. Solution.
o 1.54 1.52 40 1.17 1.16
10 1.43 1.41 50 i. 08 1.07
20 1-33 1.31 60 I. 01 I. 00
25 1.29 1.28 80 0.85 0.84
30 1.25 1.24 ioo 0.72 0.71
Density of saturated solution at o = 1.017; at I 5 = 1.014.
SOLUBILITY OF LITHIUM CARBONATE IN AQUEOUS SOLUTIONS OF
ALKALI SALTS AT 25.
(Geffcken Z. anorg. Chem. 43, 197, '05.)
The original results were calculated to gram quantities and plotted
on cross-section paper. The figures in the following table were read
from the curves.
Gms Salt Grams Li 2 COa per Liter in Aqueous Solutions of:
per Liter.
O
10
20
30
40
60
80
IOO
120
140
170
2OO ... 12.2 ... ... ... ... 29.0
ioo gms. aq. alcohol of 0.941 Sp. Gr. dissolve 0.056 gm. Li 2 CO s at
KC10 3 .
KNO 3 .
KCl.
NaCl.
K 2 S0 4 .
Na 2 S0 4 .
NI^Cl.
(NH 4 ) 2 S0 4 .
12.63
12
6 3
12
63
12.63
12
63
12
63
12 .63
12.63
12 -95
13
05
*3
.10
13-4
13
9
14
O
16.0
20-7
13.10
13
3
I 3
5
I 3-9
14
7
15
.0
19.2
25.0
13-25
13
.6
13
.8
14-3
15
4
16
.0
21.5
28.2
13.40
13
.8
14
o
14.6
16
.0
16
.6
23-3
30.8
13
.8
14
.2
i4-5
16
9
17
.8
26.O
35-2
J 3
.6
14
O
14.4
17
7
18
.6
2 7 .6
38-5
13
.5
13
9
14.2
18
.2
iQ
4
28.4
41 .0
13
3
13
7
14.0
19
9
28.7
42.6
13
.0
13
3
20
4
28.8
43-5
. .
12
.6
28.0
LITHIUM (Bi) CARBONATE 172
LITHIUM (Bi) CARBONATE LiHCO,.
100 grams H 2 O dissolve 5.501 grams LiHCO 3 at 13.
(Bevade Ber. 17, R 406, '84.)
LITHIUM CHLORATE LiClO 3 .
100 grams H 2 O dissolve 213.5 grams LiClO 3 at 18, or 100 grams sat.
solution contain 75.8 grams. Sp. Gr. of sol. = 1.815.
(Mylius and Funk Ber. 30, 1718, '97.)
LITHIUM CHLORAURATE LiAuCl 4 .
SOLUBILITY IN WATER.
(Rosenbladt Ber. 19, 2538, '86.)
* o Gms. LiAuCU per
100 Gms. Solution
t o Gms. LiAuCU per 1 Gms. LiAuCU
. 100 Gms. Solution. ' 100 Gms. Solu
10
53-i
40
67-3
60
76.4
2O
57-7
50
72.0
70
81.0
30
62.5
80
85-7
LITHIUM CHLORIDE LiCl.
SOLUBILITY IN WATER.
(Average curve from results of Gerlach Z. anal. Chem. 8, 281, '69.)
Gms. LiCl per 100 Gms. Gms. LiCl per 100 Gms.
** Water. Solution/ * Water. Solution.
o 67 40.1 40 90.5 47-5
10 72 41.9 50 97.0 49.2
20 78.5 44.0 60 103.0 51.9
25 81.5 49.9 80 115.0 53.5
30 84.5 45.8 100 127.5 5 6 -
Density of saturated solution at o, 1.255; at I 5 I - 2 7S-
SOLUBILITY OP LITHIUM CHLORIDE IN AQUEOUS SOLUTIONS OP HYDRO-
CHLORIC ACID AT o.
(Engel Ann. chim. phys. [6] 13, 385, '88.)
Milligram Mols. per
10 cc. Solution.
Gms. per 10 cc.
Solution.
Sp. Gr. of
fcci.
HCl.
LiCl.
HCI:
Solutions.
120
o.o
5 I.O
0-0
1-255
97-5
22-5
41.4
8.2
1.243
67.0
66.0
28-5
24.1
1.249
58.0
81.0
2 4 .6
29-5
I .251
SOLUBILITY OP LITHIUM CHLORIDE IN SEVERAL SOLVENTS.
(von Laszczynski Ber. 27, 2285, '94; de'Coninck Chem. Centrh. 76, II, 883, '05.)
In Acetone.
(von L.)
Gms. LiCl
t . per 100 Gms. t
(CH3) 2 CO.
o 4 . 60 46
12 4-41 53
25 4.11 58 2.14
.e.
In Pyridine.
In Glycol.
(von L.)
(de C.)
Gms. LiCl
Gms. LiCl
Gms. LiCl
per 100 Gms.
t . per 100 Gms.
t . per ioo Gms.
(CH 3 ) 2 CO.
C 5 H 6 N.
Sat. Sol.
3-76
15 7-78
IS
II.
3-12
ioo 14.26
LITHIUM CHROMATE
LITHIUM CHROMATE Li 2 CrO 4 .2H 2 O.
LITHIUM BICHROMATE Li 2 Cr 2 O 7 .2H 2 O.
SOLUBILITY IN WATER AT 30.
(Schreinemaker Z. physik. Chem. 55, 79, '06; at 18, Mylius and Funk Ber. 30, 1718, '97-)
Composition in Weight per cent:
Of Solution.
Of Residue.
Phase.
%Cr0 3 .
%Li 2 0.
%Cr0 3 .
%Li 2 0.
.0
7
.09
.
.
LiOH.H 2 O
6
.986
7
744
4
.322
18.
538
"
16
564
8
.888
10
.089
19.
556
41
2 5
.811
10
.611
15
479
21.
106
"
33
.618
12
.886
24
-365
19.
398
"
37
.411
14
.306
44
555
17 .
411
LiOH.H 2 + Li 2 CrO 4 .2H2O
.588
14
381
36
331
18.
552
37
495
13
075
16.
384
Li 2 Cr0 4 . 2 H 2
40 . 280
10
858
.
.
"
43
.404
II
.809
S3
793
14.
070
Li 2 Cr 2 O 4 .2H 2 O + Li 2 Cr 2 O 7 .aH2O
45-130
9
5*5
56
.085
10.
190
Li 8 Cr 2 7 .2H20
47
945
7
951
58
.029
9-
238
"
57
031
6
432
65
.560
8.
733
M
67
731
5
.687
8.
5*3
Li 2 Cr 2 O 7 .2H 2 O + CrO
67
.814
5
.689
80
452
3-
780
"
65
200
4
.661
.
CrO,
63
257
2
.141
85
.914
o.
758
M
62
.28
i . .
. .
.
"
A saturated aqueous solution contains:
40.985 per cent Li 2 CrO 4 , or 100 grams H 2 O dissolve 00.04 grams
Li 2 Cr0 4 at 30 (S.).
56.6 per cent Li 2 Cr 2 O 7 , or 100 grams H 2 O dissolve 130.4 grams
Li 2 Cr 2 O 7 at 30 (S.).
52.6 per cent Li 2 CrO 4 , or 100 grams H 2 O dissolve 110.9 grams
LiCrO 4 at 18 (M. and P.).
Sp. Gr. of sat. solution at 18 = 1.574.
LITHIUM CITRATE C 3 H 4 (OH)(COOLi) 3 .
100 gms. H 2 O dissolve 50 gms. citrate at 25, and 66.6 gms.at b. pt.
100 gms. alcohol of 0.941 Sp. Gr. dissolve 4 gms. citrate at 15.5.
(U. s. P.)
LITHIUM FLUORIDE LiF.
100 grams H 2 O dissolve 0.27 gram LiF at 18. Sp. Gr. of sol.
1.003.
(Mylius and Funk.)
LITHIUM FORMATE
174
LITHIUM FORMATE HCOOLi.
SOLUBILITY IN WATER.
(Groschuff Ber. 36, 179, '03.)
Gms.
Mols.
Gms.
Mols.
HCOOLi
HCOOLi
Solid
HCOOLi
HCOOLi
Solid
t *.
per ioo
per ioo
Phase.
t .
per ioo
per ioo
Phase.
Gms.
Mols.
Gms.
Mols.
Solution.
H20.
H 2 0.
H 2 0.
20
21.14
9.28
HCOOLi ,H 2 O
91
54.16
40.90
HCOOLi .H 2
24.42
ii. 18
"
9 8
57-05
45-99
HCOOLi
18
27-85
!3-3 6
"
104
57 -4
47-11
49-5
35-60
19.14
"
120
59-63
5I-I3
74
44.91
28.22
M
Sp. Gr. sat. sol. at 18 = 1.142.
SOLUBILITY OF NEUTRAL LITHIUM FORMATE IN ANHYDROUS
FORMIC ACID.
Cms. per ioo Cms. Solution.
v .
HCOOLi.
HCOOH.
25-4
47-02
18
25-9
46.92
39
26.4
46.92
60
26.9
46.94
79
27.8
47-02
Mols. per ioo Mols. H 2 O.
HCOOLi. HCOOH.
II.So
12. II
12.42
12-74
I3-36
39-27
39- 1 *
39-13
39-13
39.26
Solid
Phase.
HCOOLi
LITHIUM HYDROXIDE LiOH.
SOLUBILITY IN WATER.
(Dittmar J. Soc. Ch. Ind. 7. 730, '88; Pickering J. Chem. Soc. 63, 009, '93.)
t
Gms. per ioo Gms.
Solution.
Gms. LiOH
per ioo Gms. t.
Gms. per ioo Gms.
Solution.
Gms. LiOH.
per ioo Gms
LizO. LiOH.
H 2 0.
Li 2 O.
LiOH.
H 2 0.
O
6.67
10
.64
12
7
40
7.29
II
.68
13
.0
IO
6.74
IO
.80
12
7
5o
7-56
12
.12
13
3
20
6.86
10
99
12
.8
60
7.96
12
.76
13
.8
25
6-95
II
.14
12
9
80
8.87
14
.21
*5
3
30
7-05
II
.27
12
9
IOO
10.02
16
05
!7
5
LITHIUM IODATE Li(IO 3 ).
ioo grams H 2 O dissolve 80.3 grams LiIO 3 at 18, or ioo grams solu-
tion contain 44.6 grams. Sp. Gr. of sol. = 1.568.
(Mylius and Funk Ber. 30, 1718, '9?-)
175
LITHIUM IODIDE
LITHIUM IODIDE Lil.
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 104, 133, '58; in, 60, '60.)
Gms. Lil per 100 Gms.
Grams Lil per 100 Gms.
i> .
Water.
Solution.
O
151
60.2
10
157
61.1
20
165
62.2
25
I6 7
62.6
171
63.1
I
Water.
Solution.
40
179
64.2
5
I8 7
65-2
60
2O2
66.9
70
230
69.7
75
263
72-5
ioo grams sat. solution in Glycol (C 2 H 4 (OH) 2 .H 2 O) contain 28.0
grams Lil at 15.3. (de Coninck Chem. Centrb. 76, II, 883, '05.)
ioo cc. saturated solution in Furfurol (C 4 H 3 O.COH) contain 45.86
gms. Lil at 25.
ioo cc. saturated solution in Nitro Methane (CH 3 NO 2 ) contain
1.219 g ms - Lil at o, and 2.519 gms. at 25.
(Walden Z. physik. Ch. 55, 713, 718, '06.)
LITHIUM NITRATE LiNO 3 .
SOLUBILITY IN WATER.
(Donnan and Burt J. Chem. Soc. 83, 335, '03.)
t o Gms.LiNO 3 per Solid
ioo Gms. Solution. Phase.
O.I
34-8
LiNO 3 .3H 2
10-5
12. 1
37-9
38-2
13-75
39-3
"
19.05
40.4
"
21 .1
42.9
"
27-55
47-3
"
29.47-
29.78
55-09
it
t o Gms. LiNO 3 per Solid
i oo G ms . Solution . Phase .
29.87
56.42
LiN0 3 .3H20
29.86
56.68
"
29.64
57-48
"
29-55
58-03
43 - 6
60.8
LiNOa.iHaO
5o-5
61.3
"
55-o
63.0
"
60.0
63.6
64.2
64.9
LiNOa
70.9
66.1
Cryohydrate point of the trihydrate, 17.8. Transition points, 29.6
and 61.1.
LITHIUM OXALATE Li 2 C 2 O 4 .
SOLUBILITY OF MIXTURES OF LITHIUM OXALATE AND OXALIC
ACID IN WATER AT 25.
(Foote and Andrew Am. Ch. J. 34, 153, '05.)
Mixtures of the two substances were dissolved in water, and the
solutions cooled in a thermostadt to 25.
Gms. per ioo Gms. Solution.
H 2 C 2 4 . ' Li 2 C 2 4 .
10.20
10.66
iQ-55
8.08
2.60
2.16
Mols. per ioo Mols. H 2 O.
Solid
2.12
2 .96
3- 11
3 .l8
5-03
6-54
1.61
5-87
H 2 C 2 4 .
Li 2 C 2 4 .'
Phase.
2.274
H2C 2 4 .2H 2
2-457
O.622
H 2 C 2 4 .H 2 and HLiC 2 O 4 .I
1.823
o-5 6 3
0-633)
0.962)
Double Salt
HLiC 2 4 . 4 H 2
= 39.2H 2 C 2 O 4 and 44 -7 Li ;
0.469
1.273
HLiC 2 O 4 .H 2 O and Li 2 C 2 O 4
I .90!
Li 2 C 2 4
LITHIUM PHOSPHATE 176
LITHIUM PHOSPHATE Li 3 PO 4 .
100 grams H 2 O dissolve 0.04 gram Li 3 PO 4 . (Mayer Liebig's Ann. 98. 193, '56.)
LITHIUM (Hypo) PHOSPHATE Li 4 P 2 O 6 .7H 2 O.
100 grams H 2 O dissolve 0.83 gram hypophosphate at ord. temp.
(Rammelsberg J. pr. Ch. [2] 45, 153, '92.)
LITHIUM PERMANGANATE LiMnO 4 .3H 2 O.
100 grams water dissolve 71.4 grams permanganate at 16.
(Ashoff.)
LITHIUM SALTS of Fatty Acids.
SOLUBILITY IN WATER AND IN ALCOHOL OF 0.797 SP. GR. AT 18
AND AT 25.
(Partheil and Ferie Archiv. Pharm. 241, 554, '03.)
Grams Salt per 100 cc. Sat. Solution in:
Salt. Formula. Water at Alcohol at
18. 25. 18. 25.
Stearate C 17 H 35 COOLi o.oio o.on 0.041 0.0532
Palmitate C 15 H 31 COOLi o-on 0.018 0.0796 0.0956
Myristate C 13 H 27 COOLi 0.0232 0.0234 0.184 0.2100
Laurinate C n H 23 COOLi 0.158 0.1726 0.418 0.4424
Oleate C^HggCOOLi 0.0674 0.1320 0.9084 i.oio
LITHIUM SULPHATE Li 2 SO 4 .
SOLUBILITY IN WATER.
(Average curve from Kremers Pogg. Ann. 95, 468, '55; Etard Ann. chim. phys. [7] 2, 547, '94.)
t o Gms. Li 2 SO 4 per
100 Gms. Solution
t o Gms. Li 2 SO 4 per
. zoo Gms. Solution
t o Gms. Li 2 SO 4 per
. 100 Gms. Solution.
2O
18.4
2O
25-S
50
24-5
10
24.2
25
25'3
60
24.2
O
26.1
30
25-1
80
23-5
IO
25-9
40
24-7
100
23.0
NOTE. For equilibrium between lithium sulphate ammonia and
water, see Schreinemaker and Cochert Chem. Weekblad. 2, 771; 3,
157, '06.
EQUILIBRIUM BETWEEN LITHIUM SULPHATE, ALUMINUM SULPHATE,
AND WATER AT 30.
(Schreinemaker and De Waal Chem. Weekblad. 3, 539, '06.)
Composition in Weight per cent:
Of Solution.
Of
Residue.
Solid
Phase.
% Li 2 S0 4 .
% A1 2 (S0 4 ) 3 .
% Li 2 SO 4 .
% A1 2 (S0 4 ) 3 .
25.1
O
Li 2 SO 4 .H2O
21-93
5-34
'
16.10
14.89
63.70
4-02
13-63
20.76
14.72
3 I -*7
| Li 2 S0 4 .H 2 +
\ Al 2 (S0 4 ) 3 .i8H 2
13.24
21.71
61 .24
7.22
ii .73
22 .08
6.92
33-54
Al 2 (SO 4 ) 3 .i8H2O
6-75
24-34
3-77
37.06
3-44
26.12
o.o
28.0
...
NOTE. For solubility of lithium sulphate in mixtures of alcohol
and water at 30, see Schreinemaker and Van Dorp, ]r. Chem. Week-
blad. 3, 557, '06.
I 7 7 MAGNESIUM BROMATE
MAGNESIUM BROMATE Mg(BrO 3 ) 2 .6H 2 O.
100 cc. sat. solution contain 42 grams Mg(BrO 3 ) 2 , or 0.15 grammols.
at 1 8.
(Kohlrausch Sitzb. K. Akad. Wiss. (Berlin), i, 90, 'o?J
MAGNESIUM BROMIDE MgBr 2 .6H 2 O.
SOLUBILITY IN WATER.
(Menschutkin Chem. Centrb. 77, I. 646, '06; at 18, Mylius and Funk Ber. 30, 1718, '97.)
Grams MgBr 2 per 100 Gms. Grams MgBr 2 per icx> Grams.
Solution. Water. Solution. Water.
io 47.2 89.4 40 50.4 101.6
o 47-9 9 I -9 5 5 1 - I0 4-i
io 48.6 94.5 60 51.8 107.5
18 49.0 96.1 80 53.2 113.7
18 50.8 103.4 (M. and F.) 100 54-6 120.2
20 49.1 96.5 120 56.0 127.5
25 49.4 97.6 140 58.0 138-1
30 49.8 99.2 . 160 62.0 163.1
Density of saturated solution at 18 = 1.655 ( M - and ?.)
Etard Ann. chim. phys. [7] 2, 541, '94, gives solubility results
which are evidently too high.
SOLUBILITY or MAGNESIUM BROMIDE ALCOHOL COMPOUNDS IN THE
CORRESPONDING ALCOHOLS.
(Menschutkin Chem. Centrb. 77, I, 334, 647, '06.)
In the Corresponding Alcohols.
Results Expressed in Mols. per cent.
. A -_v
MgBr 2 .6CH 3 OH MgBr 2 .6C 2 H 5 OH
in CH 3 OH. in C 2 H 6 OH.
6.0
2.0
20
6.4
4 .6
40
6.9
8. 4
50
7.2
10-9
60
7-5
I4.I
80
8-25
22.1
100
9.6
3 8.6
150
16.7
IOO.O
(108.5)
190
IOO.O
Determinations are also given for the solubility of MgBr 2 .6C 3 H 7 OH
in C 3 H 7 OH, of MgBr 2 .6(CH 3 ) 2 C 2 H 3 OH in (CH 3 ) 2 C 2 H 3 .OH, and of MgBr 2 .
6(CH 3 ) 2 C 2 H 3 OH in (CH 3 ) 2 C 2 H 3 OH, also of MgBr 2 . 4 (CH 3 ) 2 ,CHOH in
iso propyl alcohol and in tri methyl carbinol.
For the solubility magnesium bromide mono etherate (MgBr 2 .
(C 2 H 6 ) 2 O) in ethyl ether, see Menschutkin Chem. Centrb. 77, 1, 1868,
'06; also Z. anorg. Ch. 49, 208, '06. For magnesium bromide di
etherate (MgBr 2 .2C 4 H 10 O) in ethyl ether, see Menschutkin Z. anorg.
Ch. 49, 35, '06. For magnesium bromide hexa formic acid and mag-
nesium bromide hexa acetic acid compounds in anhydrous solutions of
the corresponding acids, see Iswietja d. Petersburger, Polytechn. Inst.
5, 293, '06; Chem. Centrb. 77, II, 1482, '06.
MAGNESIUM CARBONATE 178
MAGNESIUM CARBONATE MgCO,.
SOLUBILITY IN WATER IN PRESENCE OF CARBON DIOXIDE AT 15*
(Treadwell and Reuter Z. anorg. Ch. 17, 200, '08.)
cc. CO2 per 100 cc.
Gas Phase (at o
and 760 mm.).
Partial
Pressure of CO S
in mm. Hg.
Grams per
too cc. Solution.
/"""" *
Free CO 2 .
MgC0 3 .
Mg(HC0 3 ) 2 .
Total Mg.
18.86
143-3
O.IIQO
I.2I05
0.2016
5-47
41 .6
0.0866
I.2I05
0.2016
4-47
33-8
0.0035
I .2105
0.2016
i-54
11.7
0-0773
I .0766
0.2016
i-35
10.3
0-0765
0.7629
0.1492
1.07
8.2
. . .
0-0807
0-595 2
O.I224
0.62
4-7
. . .
0.0701
0.3663
0.0865
0.60
4-6
0-0758
0.3417
0.0788
o-33
2-5
0-0748
0.2632
0-0655
0.21
1.6
0.0771
O.2229
0-0594
0-14
i.i
0.0710
0.2169
0-0566
0.03
o-3
0.07II
o . 2036
0-0545
0.0685
0.2033
0.0536
. . .
0-0702
0.1960
0.0529
0-0625
o . 2036
O.O52O
0-0616
0.1954
0.05II
0-0641
0.1954
0.0518
Therefore at o partial pressure of CO 2 and at 1 5 and mean barometric
pressure, one liter of saturated aqueous solution contains 0.641 gram
of MgCO 3 plus 1.954 grams Mg(HCO 3 ) 2 .
SOLUBILITY OF MAGNESIUM CARBONATE IN WATER CHARGED WITH CAR-
BON DIOXIDE AT PRESSURES GREATER THAN ONE ATMOSPHERE.
(Engel and Ville Compt. rend. 93, 340. '81; Engel Ann. chim. phys. [6] 13, 349, '88.)
Pressure of
CO 2 in
G. M
:f?CO 3 * per Liter.
Pressure of
G. MgCO 3 * per Liter.
Atmospheres. At 12.
0-5 20-5
At 19.
Atmospheres. At
4.0 42
12.
.8
At 19.
I .0
26.5
25
.8
4
7
43
5
2-0
34-2
33
.1(2.
i At.)
6
.0
5o
.6
48
.5(6.2
At.)
3-o
39-o
37
2(3
.2 At.)
9
.0
56
.6
SOLUBILITY IN WATER SATURATED WITH CO 2 AT ONE ATMOSPHERE.
(Engel.)
t o Cms. MgCO 3 * t o Cms. MgCO 3 * t o Gms. MgCO 3 *
per Liter. per Liter. per Liter.
5 3 6 3 2I 6o I]C
10 31 40 17 80 5
20 26 100 O
* Dissolved as Mg(HCO 3 ) 2 .
179 MAGNESIUM CARBONATE
SOLUBILITY OF MAGNESIUM CARBONATE IN AQUEOUS SOLUTIONS OF
SODIUM CARBONATE AT 25. The solutions being in equilibrium
with an atmosphere free from CO 2 .
(Cameron and Seidell J. Physic. Ch. 7, 588, '03.)
Wt. of i Liter Grams per Liter. Reacting Weights per Liter.
of Solution.
N a2 C0 3 .
MgCOa.
" NazCOs.
MgC0 3 .
996.8
o.oo
0.223
o.ooo
O.OO266
1019.9
23.12
0.288
0.220
0.00344
1047-7
50-75
0.510
0.482
O.OO62O
1082.5
86.42
0.879
O.82O
0.01027
1118.9
127.3
1-3*4
I .209
0.01570
1147.7
160.8
1.636
I .526
0.01955
1166.1
181.9
1.972
1.727
0.02357
1189.4
213 .2
2.317
2.024
0.02770
SOLUBILITY OF MAGNESIUM Bi CARBONATE AND OF MAGNESIUM CAR-
BONATE IN AQUEOUS SOLUTIONS OF SODIUM CHLORIDE AT 23. The
solutions being in equilibrium with an atmosphere of CO 2 in the
one case, and in equilibrium with air free from CO 2 in the other.
(C. and S.)
In Presence of CO 2 as Gas Phase. In Presence of Air Free from CO 2 .
Cms. NaCl
per Liter.
Gms. Mg(HCO 3 ) 2
per Liter.
Wt. of i
Liter.
Gms. NaCl
per Liter.
Gms. MgCO 3
per Liter.
7-0
30.64
996.9
o.o
0.176
56.5
30.18
IOI6.8
28.0
0.418
119.7
27.88
I04I.I
59-5
0.527
163.9
24.96
1070.5
106.3
0.585
224.8
20.78
1094-5
147-4
0-544
306.6
10.75
II42.5
23I.I
0.460
II70.I
272.9
0-393
II99-3
331-4
0.293
SOLUBILITY OF MAGNESIUM CARBONATE IN AQUEOUS SOLUTIONS OF
SODIUM SULPHATE AT 24 AND AT 35.5. The solutions being in
equilibrium with an atmosphere free from CO 2 .
(Cameron and Seidell.)
Results at 24. Results at 35.5.
Wt. of Gms. Na 2 SO 4 Gms. MgCO 3 Wt. of Gms. Na^O^ Gms. MgCO 3
i Liter. per Liter. per Liter. i Liter. per Liter. per Liter.
997.5 o.oo 0.216 995- 1 -3 2 0.131
1021.2 25.12 0.586 1032.9 41.84 0.577
1047.6 54-76 0.828 1067.2 81.84 o-753
1080.9 95-68 i .020 1094.8 116.56 0.904
1133.8 160.8 i .230 1120.4 I 48-56 0.962
1157.3 191.9 1.280 1151-7 l86 -7 1-047
1206.0 254.6 2.338 1179.8 224.0 i. 088
1242.0 305.1 1.388 1236.5 299.2 1.130
MAGNESIUM CHLORATE
180
MAGNESIUM CHLORATE Mg(ClO 3 ) 3 .
SOLUBILITY IN WATER.
(Meusser Ber. 35, 1416, '02.)
Cms. Mols.
Mg(C10 8 ) 2 Mg(C10 8 ) 2
pencx>Gms. per 100
Solution. Mols. H 2 O.
18
o
18
29
35
51.64
S3- 2 7
56-50
60.23
63-65
10.05
10.73
12.22
14.25
16.48
Solid
Phase.
Mg(C10 8 ) 8 .6H a O
t.
Gms.
o Mg(C10 3 ) 2
Mols.
Mg(C10 8 ) 2
Solid.
* per 100 Gms
Solution.
per 100
Mols.H 2 O.
Phase.
42
63
.82
16
.16
M g (C10 3 ) 3 ^H 3
65
5
69
.12
20
.08
"
39
5
65
37
17
-76
Mg(C10 8 ) a .aH 2
61
.0
6 9
46
21
40
it
68
70
.69
22
.69
93
(73
(26
38)
M
Sp. Gr. of saturated sol. at + 18 = 1.564.
MAGNESIUM CHLORIDE MgCl 2 .
SOLUBILITY IN WATER.
(van "t Hoff and Meyerhoffer Z. physik. Chem. 27, 75, '98; Engel; Lowenherz. Results quoted
from Landolt and Bornstein Tabellen, sd, ed. p. 549, '06.)
Gms. MgClgper TOO Gms Solid
t".
Gms. MgC^penoo Gms" Solid
*
Solution.
Water.
Phase.
Solution. Water.
Phase.
10
ii
.1
12
5
Ice
O
34
5
52.8
MgCl 2 .6H 2 O
2O
16
.0
19
.0
"
10
34
9
53-5
"
30
19
4
24
.0
11
20
35
3
54-5
"
33-
6
20
.6
26
.0
Ice+MgCl 2 .i2H 2 O
22
35
.6
55-2
"
12
26
7
36
5
MgCl 2 .i 2 H 2
25
36
.2
56.7
"
16.
4
30
.6
44
f.pt.
40
36-5
57-5
"
16.
8
31
.6
46
.2
( MgCl 2 .i2H 2 O +
( MgCl 2 .8H 2 O a
60
37
9
61.0
"
17-
19.
9-
3-
4
4
6
4
32
33
33
34
3
3
9
4
47
49
5 1
S 2
.6
9
3
3
( MgCl 2 .i2H 2 O-f-
\ MgCl 2 .8H 2 O/3
JMgCl 2 .i 2 H 2 +
( MgCl 2 .6H 2 O
j MgCl 2 .8H 2 /3
t + MgCl 2 .6H 2
( MgCl 2 .8H 2 O a +
1 MgCl 2 .6H 2 O about
80
100
116
152
181
39
42
7 46
6 49
5 55
.8
.2
.2
.1
.8
66.0
73-o
85-5
96.4
126.0
( MgCl 2 .6H 2 O +
{ MgCl 2 . 4 H 2 G
MgCl 2 . 4 H 2
f MgCl 2 .4H 2 +
\ MgCl 2 . 2 H 2
186
56
.1
128.0
MgClz.aHaO
SOLUBILITY OF MAGNESIUM CHLORIDE IN AQUEOUS SOLUTIONS OP
HYDROCHLORIC ACID AT o.
(Engel Compt. rend. 104, 433, '87.)
Grams per Liter of Solution.
Milligram Mols. per i occ. Solution. So.Gr of
HC1.
*MgCl 2 . Solutions.
o.o
99-55
362
4-095
95-5
354
9-5
90.0
344
17.0
82.5
.300
20.5
79-o
.297
28.5
71.0
.281
42 .0
60.125
58 v75
46.25
76.0
32.0
HCl.
MgCW
o.o
474.2
14.93
454-8
34.63
428.6
61.97
393-o
74-74
376.2
103.9
338.3
153 - 1
286.4
214.2
220.3
277.1
152.0
sat. HCl (Ditte)
6-S
181 MAGNESIUM CHLORIDE
SOLUBILITY OP MIXTURES OF MAGNESIUM CHLORIDE AND OTHER
SALTS IN WATER AT 25.
(LSwenherz Z. physik. Chem. 13. 479, '94.)
Mixture.
MgCl 2 .6H 2 O + MgSO 4 .6H 2 O
Gram Mols. per 1000 Mols. H2O. Gms. per Liter of Solution.
104 MgCL, + 14 MgSO 4 25.0 Cl + 4.4 SO 4
M g Cl2.7H 2 0-t-MgS0 4 .6H 2 73 +15 19.5 "+5.3
MgCl 2 .6H 2 + M g Cl 2 .KC1.6H 2 106 Cl+i K 2 +io 5 Mg 26.9 C1+ 0.3 K+ 45-7 SO 4
Results for the remaining possible combinations of magnesium
sulphate and potassium chloride are also given.
MAGNESIUM CHROMATE MgCrO 4 -7H 2 O.
100 grams H 2 O dissolve 72.3 grams MgCrO 4 at 18, or 100 grams
solution contain 42.0 grams. Sp. Gr. = 1.422.
(Mylius and Funk Ber. 30, 1718, '97.)
MAGNESIUM POTASSIUM OHROMATE MgCrO 4 .K 2 CrO 4 .2H 2 O.
100 grams H 2 O dissolve 28.2 grams at 20, and 34.3 grams at 60.
MAGNESIUM PLATINIC CYANIDE MgPt(CN) 4 .
SOLUBILITY IN WATER.
(Buxhoevden and Tamman Z. anorg. Ch. 15, 319, '97.)
Gms.MgPt(CN) 4
t. per loo Gms. Solid Phase.
Gms. MgPt(CN) 4
t . per 100 Gms. Solid Phase.
Solution.
Solution.
-4.12
24.90
MgPt(CN) 4 .6.8-8.iH2O
48.7
40.89
MgPt(CN) 4 . 4 H 2
o-5
26.9
" (Red)
55
41-33
(1
5-5
28.65
"
58-1
42.15
II
18.0
32.46
"
69.0
43-49
36.6
39-53
77 .8
44.90
"
4S-o
4i-33
87.4
45-5 2
46.2
42 .0
"
9O.O
45-05
"
42.2
40.21
MgPt(CN) 4 . 4 H20
93-o
45-04
46-3
39-85
" (Bright Green)
96.4
44-33
MgPt(CN) 4 .aH 2
100.
44.0
(White)
MAGNESIUM FLUORIDE MgF 2 .
One liter of water dissolves 0.076 gram MgF 2 at 18 by conductivity
method. (Kohlrausch Z. physik. Ch. 50, 356/04- '05.
MAGNESIUM HYDROXIDE Mg(OH) 2 .
One liter of water dissolves 0.008 0.009 S m - Mg(OH) 2 at 18 by
Conductivity method. (Dupre and Brutus Z. angew. Ch. x6> SS, W
SOLUBILITY OF MAGNESIUM OXIDE IN AQUEOUS SOLUTIONS CONTAINING
SODIUM CHLORIDE AND SODIUM HYDROXIDE.
(Maigret Bull. soc. chim. 33, 631, '05.)
Grams MgO per Liter Solution with Added:
per Liter.
125
140
160
0.8 g. NaOH
per Liter.
O.O7
0-045
none
4.0 g. NaOH
per Liter.
0.03
none
MAGNESIUM HYDROXIDE 182
SOLUBILITY OF MAGNESIUM HYDROXIDE IN AQUEOUS SOLUTIONS OF
AMMONIUM CHLORIDE AND OF AMMONIUM NITRATE AT 29.
(Herz and Muhs Z. anorg. Ch. 38, 140, '04.)
NOTE. Pure Mg(OH) 2 was prepared and an excess shaken with
solutions of ammonium chloride and of ammonium nitrate of different
concentrations.
Concentration of
NHjCl or of NH4NO 3
Acid Required
for Liberated
Normality of:
(Normal.)
' NH 4 OHin2SCC.
(Normal.)
Mg(OH) 2 . NH 4 C1.
7 (NH 4 C1)
0.09835
0.156 0.388
o . 466
O.IIOS
O.IO8 0.250
o-35
0.09835
0-089 0.172
0-233
O.IIOS
0.0638 0.106
o-i75
O.IIOS
0.049 O.O77I
0.35 (NEUNO8)
O.IIOS
0.0833 0.1834
0.175 "
O.IIOS
0-0495 0.076
Grams per Liter.
Mg(OH) 2 . NH^Cl.
4-55
2 .60
1.86
i-43
20.86
13-39
9.21
5-67
4-13
i-45 6 -o9
MAGNESIUM IODATE Mg(IO 3 ) 2 .
SOLUBILITY IN WATER.
(Mylius and Funk Ber. 30, 1722, '97; Wiss. Abh. p. t. Reichanstalt 3, 446, 'oo.)
Gms.
Mols.
Gms.
Mols.
t o Mg(T6 3 ) 2 Mg(I0 3 ) 2 Solid
per 100 per 100 Mols. Phase.
Gms. Solution. H 2 O.
t o Mg(I0 3 ) 2 Mg(I0 3 ) 2 Solid
per 100 per i oo Mols. Phase.
Gms. Solution. H 2 O.
O
3- 1
0.15 Mg(IO 8 )2.ioH 2 O
O
6.8
o-34
Mg(I0 3 ) 2 . 4 H 2
20
IO.2
0-55
IO
6.4
0.30
"
30
17.4
I .01
18
7.6
0.40
"
35
21. 9
i-35
20
7-7
0.40
M
50
67-5
IO-O
35
8.9
0.47
"
63
12.6
0.69
"
100
19-3
I-I3
"
Sp. Gr. of solution sat. at 18= 1.078.
MAGNESIUM IODIDE MgI 2 .
SOLUBILITY IN WATER.
(Menschutkin Chem. Centrb. 77, I, 646, '06; at 18, Mylius and Funk Ber. 30, 1718, '97.)
t o Grams MgI 2 per Solid
" 100 Grams Solution. Phase.
t o Gms. Mgla per
' 100 Grams Solution.
50.0
10
51 .65
18
53-o(59-7 M - andF ->
20
53-4
2 5
54-4
30
55-4
40
57-8
45
59-9
Solid
Phase.
MgI 2 .8H 2 O
50
70
90
110
140
160
200
6l.6
61.85
62.1
62 .25
62 .5
63.0
64.1
MgI 2 -6H 2
Density of saturated solution at 18= 1.909. (M. andF.)
183 MAGNESIUM IODIDE
SOLUBILITY OF MAGNESIUM IODIDE ALCOHOL COMPOUNDS IN THE
CORRESPONDING ALCOHOLS.
(Menschutkin Chem. Centrb. 77, I, 335, '06.)
Results expressed in molecular per cent.
t o MgI 2 .6CH 3 OH MgI 2 .6C 2 H 5 OH t > MgI 2 .6CH 3 OH MgI 2 .6C 2 H 5 OH '
* ' in CH 3 OH. inC 2 H 8 OH. * ' in CH 3 OH. inQHjOH.
o 6.3 2.3 ioo 10.5 19.7
10 6.6 3-1 120 II. 8 28.2
20 7.0 4.0 140 13.4 S3- 6
40 7.8 6.2 160 15.7 80.3(145)
60 8.6 9.3 180 18.7 100-0(146.5)
80 9.5 13.5 200 23.1
SOLUBILITY OF MAGNESIUM IODIDE Di ETHERATE (MgI 2 .2C 4 H 10 O) IN
ETHYL ETHER.
(Menschutkin Z. anorg. Ch. 49, 46, '06.)
Synthetic Method used, see Results in the Critical
page 9. Vicinity.
Grams per TOO pms. Solution. Gms. per ioo Gms. Solution.
MgI 2 . MgI 2 .2C4H 10 O. " ' MgI 2 .
5.4 1.45 2.2 37.3 19.4 29.3
ii. 8 2.43 3.7 38.5 22.45 34-4
15.6 3.46 5.3 38.5 26.07 39.9
18.1 5.4 8.3 38.5 29.8 45.7
20.4 7-55 "-6 3 8 32-8 5-3
22.2 11.28 17.3
Two liquid phases appear near the melting point of the magnesium
iodide di etherate. The lower may be considered as a solution of ether
in di etherate, and the upper as a solution of the lower layer in ether.
The critical temperature is 38.5.
Lower Layer. Upper Layer.
Gms. per ioo Gms. Solution. Gms. per ioo Gms. Solution
I .
MgI 2 .
MgI 2 . 2 C 4 H 10 0. '
i .
MgI 2 .
MgI 2 . 2 C 4 H lo O.
14.8
35-5
54-4
18.6
13-57
20.8
20.
35-8
54-8
23.2
14.4
22 . 1
28.4
35-5
54-4
24.4
14.6
22-4
33
35-7
54-7
32-4
15.82
24.2
35
35-3
54-i
The solubility of double compounds of magnesium iodide and
alkyl esters in the corresponding acetates is given by Menschutkin
Chem. Centrb. 77, I, 647, '06. For the solubility of magnesium iodide
hexa acetic acid compound in anhydrous acetic acid solutions, see Chem.
Centrb. 77, II, 1482, '06.
MAGNESIUM NITRATE 184
MAGNESIUM NITRATE Mg(NO 8 ) 2 .
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt 3, 437, 'oo.)
Gms.
Mols.
Gms.
Mols.
Mg(N03) 2
Mg(NO ? ) 2 Solid
Mg(N0 3 ) 2
Mg(N0 3 ) 2
Solid
t
per ioo Gms.
Solution.
per ioo Mols. Phase.
t.
per ioo Gms.
Solution.
per ioo Mols.
H 2 0.
Phase.
-23
35-44
6 . 6 Mg(NOg) 2 .9H2O
40
45-87
10-3 Mg
(N0s) 2 .6:
20
36.19
7-o
80
53.69
14.6
"
-18
38-03
7-4
90
57-81
16.7
"
-18
38-03
7.37 Mg(N0 3 ) 2 .6H20
8 9
63.14
2O-9 |
- 4
5 39-50
7.92
77
5 65-67
23.2 V *
o
39.96
8.08
67
67-55
25-1 )
+ 18
42-33
8. 9
* Reverse
curve.
Sp. Gr. of solution saturated at 18 = 1.384.
MAGNESIUM OXALATE Mg.C 2 O 4 .2H 2 O.
One liter of water dissolves 0.3 gram MgC 2 O 4 at 18 (conductivity
method) . (Kohlrausch Z. physik. Ch. 50, 356, '05.)
MAGNESIUM (Hypo) PHOSPHATE Mg 2 P 2 O 6 .i2H 2 O.
One liter of water dissolves 0.066 gram hypophosphate.
(Salzer Liebig's Ann. 232, 114, '86.)
One liter of water dissolves 5.0 grams magnesium hydrogen
hypophosphate MgH 2 P 2 O 6 .4H 2 O. (Salzer.)
MAGNESIUM SALICYLATE Mg(C 7 H 5 O 3 ) 2 . 4 H 2 O.
One liter of saturated solution contains 8.015 grams of the salt.
(Barthe Bull. soc. chim. [3] n, 519, '94.)
MAGNESIUM FLUOSILICATE MgSiF 6 .6H 2 O.
One liter of water dissolves 652 grams of the salt at 17.5. Sp. Gr.
Of Solution = 1.235. (Stolba Chem. Centrb. 578, '??.)
MAGNESIUM SULPHATE MgSO 4 .
SOLUBILITY IN WATER.
(Mulder; Tilden J. Ch. Soc. 45, 409, '84; Etard Compt. rend. 106, 741, '88.)
Etard's results for the lower temperatures are somewhat low.
Mulder's and Tilden' s results agree very well.
Gms. MgSOj per 100 Gms. Solid t<5 Gms. MgSO 4 per 100 Gms. g^d
Solution. Water. Phase. Solution. Water. Phase.
O 21.2 26.9 MgSO 4 .7H 2 O 50 33.5 50.3 MgSO^HzO
10 24.0 31.5 " 60 35.5 55.0
20 26.5 36.2 70 37.5 59.6
25 28.2 38.5 80 39-1 64.2
30 29.0 4O.9 " 9O 4O.7 .68.9
40 31.2 45.6 ioo 42.5 73.8
no 45-5 8 3-6
For temperatures between 123 and 190, grams MgSO 4 per ioo grams
solution =48.5 0.4403 t. (Etard).
For densities of aqueous solutions of MgSO 4 , see Barnes and Scott
J. Physic. Ch. 2, 542, 'q8.
185 MAGNESIUM SULPHATE
SOLUBILITY OF MAGNESIUM SULPHATE IN METHYL AND ETHYL
ALCOHOLS.
(de Bruyn Rec. trav. chim. n, 112, '92.)
Solvent. t. Per 100 Gms. Solvent. Solvent. t. Per 100 Cms. Solvent.
Abs. CH 3 OH 18 1.18 gms. MgSO 4 93% Methyl Ale. 17 9.7 gms.MgSO 4 .7H2O
17 41-0 " MgS0 4 . 7 H 2 50% " " 3-4 4.1 "
3-4 29.0 " " Abs. C 2 H 5 OH 3 1.3 "
SOLUBILITY IN AQUEOUS ETHYL ALCOHOL.
(Schiff Liebig's Ann. 118, 365, '61.)
Wt. per cent Alcohol 10 20 40
G. MgSO 4 .7H 2 O per 100 gms. solvent 64.7 27.1 i .65
SOLUBILITY OF MAGNESIUM SULPHATE IN SATURATED SUGAR SOLUTION
AT 31.25.
(Kohler Z. Ver. Zuckerind. 47, 447, *97.)
ioo grams saturated aqueous solution contain 46.52 grams sugar +
14.0 grams MgSO 4 .
ioo grams water dissolve 119.6 grams sugar + 36.0 grams MgSO 4 .
MAGNESIUM POTASSIUM SULPHATE MgK 2 (SO 4 ) 2 .6H 2 O.
SOLUBILITY IN WATER.
(Tobler Liebig's Ann. 95, 193, '55.)
t.-o 20 30 45 60 75
Gms. MgK 2 (S0 4 ) 2
per ioo gms. H 2 O 14.1 25.0 30.4 40.5 50.2 59.8
MAGNESIUM SULPHITE MgSO 3 .6H 2 O.
ioo grams cold water dissolve 1.25 grams sulphite; ioo grams boil-
ing water dissolve 0.83 gram.
(Hager Chem. Centrb. 135, '75.)
MALONIC ACID CH 2 (COOH) 2 .
SOLUBILITY IN WATER.
(Klobbie Z. physik. Chem. 24, 622, '97; Miczynski Monatsh. Ch. 7, 259, '86; Henry Compt. rend,
99, 1157, '84; Lamouroux Ibid. 128, '998, '99.)
Grams CH 2 (COOH) 2 per ioo Grams CH 2 (COOH) 2 per ioo
Gms. Solution.* cc. Solution (L.). Gms. Solution.* cc. Solution (L.).
o 52-0 61.0 50 71.0 93 -o
10 56.5 67.0 60 74.5 loo.o
20 60.5 73 .o 70 ... 106.0
25 62.2 76.3 80 82.0
30 64.0 80.0 ioo 89.0
40 68. o 86.5 132 (m. pt.) 100-0
* Average curve from results of K., M., and H.
MALONIC AOID
186
SOLUBILITY OP MALONIC ACID IN ETHER.
(Klobbie.)
fc.
Gms. CH2<COOH)j
per ioo Gms.
Solution.
*.
Gms. CH 2 (COOH) 2
per ioo Gms.
Solution.
10
7-74
30
80
10-5
33-o
20
9.00
90
39-o
25
9-7
Gms. CH 2 (COOH) t
t. per 100 Gms.
Solution.
100 46.0
no 56.0
120 70.0
132 (m. pt.) ioo. o
100 grains saturated solution of malonic acid in pyridine contain
14.6 grams at 26.
(Holty J. Physic. Ch. 9, 764, '05.)
SOLUBILITY OF SUBSTITUTED MALONIC ACIDS IN WATER.
(Lamouroux.)
Grams per ioo cc. Saturated Aqueous Solution.
f .
Malonic
Methyl
Malonic
Ethyl
Malonic
n Propyl
Malonic
n Butyl
Malonic
Iso Amyl
Malonic
Acid.
Acid.
Acid.
Acid.
Acid.
Acid.
61.1
44-3
52-8
45-6
ii .6
38.5
15
70.2
58-5
6 3 .6
60. i
3 -4
5 i.8
25
76-3
67.9
71.2
70.0
43-8
79-3
30
92.6
91-5
90.8
94.4
79-3
83.4
MANGANESE BORATE MnH 4 (BO 3 ) 2 H 2 O.
SOLUBILITY IN WATER AND IN AQUEOUS SALT SOLUTIONS.
(Hartley and Ramage J. Ch. Soc. 63, 137, '93.)
Grams MnH4(BO 3 ) 2 per Liter in Solutions of:
t.
H 2 O-f
Na 2 S0 4
Na 2 SO 4
NaCl
CaCl 2
trace
(0.2 Gms.
(20 Gms.
(20 Gms.
(20 Gms.
N a2 S0 4 .
per Liter).
per Liter).
per Liter).
per Liter).
14
0-94
I .7
. . .
18
0-77
I .31
2 .91
40
0.50
0.69 (52 C
') 0.65
2.44
60
0.36
0.6o
2.25
80
O.o8
O-I2
0.29
'35
MANGANESE BROMIDE MnBr 2 . 4 H 2 O.
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 537, '94.)
*
Gms. MnBr 2
per ioo Gms.
Solution.
Solid
Phase.
t>.
Gms. MnBrj
per ioo Gms.
Solution.
Solid
Phase.
20
52-3
MnBr^HaO
40
62.8
MnBr 2 . 4 H 2 O
10
54-2
"
So
64-S
56-0
"
60
66.3
10
57-6
M
70
68.0
M
20
59-5
"
80
69.2
MnBr. 2 H 2 O
25
60.2
M
90
693
61.1
ioo
695
i8;
MANGANESE CHLORIDE
MANGANESE CHLORIDE MnCl 2 . 4 H 2 O.
SOLUBILITY IN WATER.
(Etard; Dawson and Williams Z. physik. Chem. 31, 63, '09.)
f.
20
IO
O
+ 10
2O
25
30
40
60
70
80
90
IOO
120
140
Sp. Gr. of Grams MnCl 2 per ioo Grams
Jutions.
Water.
Solution.
. . .
53-8
35-o
. . .
58-7
37-o
63-4
38.8
68.1
40-5
73-9
42-5
4991
77.18
43-55
5049
80.71
44-68
5348
88.59
46.96
5744
98.15
49-53
.6097
105.4
5*-33
.6108
108.6
52.06
1.6134
no. 6
52-52
112.7
52.98
114.1
53-2
115 .3
53-5
118.8
54-3
119-5
55-o
Mols. MnC! 2
per ioo Mols. H 2 O.
II. 08
n-55
12.69
14.05
15.10
15-55
I5-85
16.14
Solid
Phase.
MnCl2.2H.jO
One liter of water dissolves 87.0 grams MnCl 2 . One liter of sat. HC1
dissolves 19.0 grams MnCl 2 at i2 c
(Ditte Compt. rend. 92, 242, '81.)
MANGANESE FLUO SILICATE MnSiF 6 .6H 2 O.
ioo grams H 2 O dissolve 140 grams salt at 17.5. Sp. Gr. of solution
= 1.448. (Stolba Chem. Centrb. 292, '83.)
MANGANESE NITRATE Mn(NO 3 ) 2 .6H 2 O.
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt 3, 438, f oo.)
t.
Gms.
Mn(N0 3 ) 2
Mols.
Mn(NO 3 ) 2 Solid
per ioo
Gms. Sol.
per ioo Phase.
Mols. H 2 0.
-29
42.29
7-37
Mn(NO 3 ) 2 .6H 2 O.
-26
43-15
7-63
"
21
44-30
8.0
"
-16
45-52
8.4
- 5
48.88
9.61
M
o
50-49
10.2
"
+ 11
54-50
12.0
"
Sp. Gr. of solution saturated at 18
t.
Gms.
Mn(N03) 2
Mols.
Mn(NO3) 2
per ioo
Gms. Sol.
per ioo
Mols.H 2 O.
18
57-33
13.5
25
62.37
!6. 7
27
65.66
19.2
29
66.99
20.4
30
67.38
20.7
34
71 .31
24.9
35-5
76.82
33-3
DO
1.624.
Solid
Phase.
Mn(NO 3 ) 2 .6H 2 O.
MANGANESE (Hypo) PHOSPHITE Mn(PH 2 O 2 ) 2 H 2 O.
ioo grams H 2 O dissolve 15.15 grams salt at 25, and 16.6 grams at
b. pt.
MANGANESE SULPHATE
188
MANGANESE SULPHATE MnSO 4 .5H 2 O.
SOLUBILITY IN WATER.
(Cottrell J. Physic. Ch. 4, 651, '01; Richards and Fraprie Am. Ch. J. 26, 77, *oi. The results
f Linebarger Am. Ch. J. 15, 225, '93, were shown to be incorrect by Cottrell, and this conclusion
as confirmed by R. and F.)
Grams MnSO 4 per Grams MnSO 4 per
t. ico^Gms. Solid Phase. t. 100 Gms. Solid Phase
Water.
Solution.
' Water.
Solution r
10
47-96
32
.40 MnSO 4 .7H 2 O
16
63
94
38
99
MnSO 4 ^H 2 O
53-23
34
73
18
5
6 4
.19
39
.10
"
5
56.24
35
99
25
65
32
39
53
it
9
59-33
37
.24
3
66
-44
39
93
1
12
61.77
38
.19
39
9
68
.81
40
77
"
14-3
39
.00 "
49
9
72
6 3
42
.08
"
5
58.06
36
. 69 MnSO 4 .sH 2 O
41
4
60
87
37
.84
MnSO 4 .H 2 O
9
59 -!9
37
.18
5
58
17
36
.76
"
15
61.08
37
.91
60
55
.0
35
.49
M
25
64-78
39
.31
70
52
o
34
.22
"
67.76
40
.38
80
48
.0
3 2
43
35-5
71.61
4i
74
90
42
5
29
83
"
100
32
.0
24
.24
"
SOLUBILITY OP MANGANESE SULPHATE, COPPER SULPHATE MIXED
CRYSTALS IN WATER AT 18.
(Stortenbecker Z. physik. Chem. 34, 112, 'oo.)
Mols. per 100 Mols. Mol. per cent
H 8 0. Cu in :
'Cu. Mn. Solution. Crystals.
Solid Phase, CuMnSO 4 . S H 2 O, Triclinic.
2.282
2.23
1-54
Mols. per 100 Mols.
H 2 0.
Mol. per cent
Cu in:
^
ciT Mn. Solution. Crystals-
Solid Phase, CuMnSO 4 . S H 2 O. Triclinic.
[1.06
O
100
100
. . .
90.5
0.44
83-5
74.1
97-3
57-7
95 - 1
. . .
31.0
81.3
3-76
29.0
26.1
70.4
4.70
21.8
21 .2
42 .6
20-0
34-4
5.58
15-9
22.9]
13 9
15-2*
[0.73
-34
6.37
7-3
10.27
5.0
10.5]
4-9
2.15
2.31
7*^7^ O O O O
/ \j t %}
Solid Phase. CuMnSO 4 . Monoclinic. ?H 2 O.
20-4 28.2*
[1.06 5.58 15.9 23.5]
20.8
16.0]
[o-73 6 -37
12-45
10.27
O-O
5-8*
o.o
* Indicates meta stabil points.
CuMnSO 4 .5H 2 O = 100-90.8 and 2.11-0 mol. percent Cu.
CuMnSO 4 .7H 2 O 37.8-4.92 mol. per cent Cu.
SOLUBILITY OF MANGANESE SULPHATE IN GLYCOL.
100 grams saturated solution contain 0.5 gram MnSO 4 .
(de Coninck Bui. acad roy. Belgique, 359, '05.)
i8 9 MANGANESE SULPHATE
SOLUBILITY OF MANGANESE SULPHATE IN AQUEOUS ETHYL AND
PROPYL ALCOHOL SOLUTIONS AT 20.
(Linebarger Am. Ch. J. 14, 380, '92; Snell J. Physic. Ch. 2, 474, '98.)
Cone, of Alcohol Cms. MnSO 4 per 100 Cms. Aq. Cone, of Alcohol Gms. MnSO 4 per 100 Cms. Aq.
in Wt. per cent. Ethyl Ale. Propyl Ale. in Wt. per cent. Ethyl Ale. Propyl Ale."
34 9-5 6 - 44 3-3 i-9
36 7.2 4.6 48 2.2 1.4
38 5.8 3.5 52 1.4 i.i
40 4-7 2.8
MANGANESE POTASSIUM VANADATE MnKV 6 O u .8H 2 O.
100 grains H 2 O dissolve 1.7 grams salt at 18.
(Radan Liebig's Ann. 251, 120, '89.)
MANNITE C 6 H 8 (OH) 6 .
SOLUBILITY IN WATER.
(Campetti Abs. in Z. physik. Chem. 41, 109, '02.)
Grams CH8(OH)6 per 100 Grams.
' Water. Solution. "
10 13.94 12.78
15 16.18 14-63
20 18.98 16.86
100 grams of saturated solution of mannite in Pyridine contain 0.47
gram C 6 H 8 (OH) 6 at 26. (Holty- J. Physic. Ch. 9. 764, '05.)
MANNITOL C 6 H 8 (OH) 6 .
SOLUBILITY IN WATER.
(Findlay J. Ch. Soc. 81, 1219, '02.)
Gms. G.M.
t o Wt. of i cc. Mannitol Mannitol t <> Wt. of i cc.
in Grams. per 100 per 100 in Grams.
Gms.
Mannitol
per loo
G. M.
Mannitol
per loo
Gms.
H 2 0.
G.M
.H 2 0.
Gms.H 2 O.
G.M.H 2 0.
O
1.044
7
59
O
75
50
1.099
(47-7)
47
.01
4.65
IO
II
63
I .
60
60
.01
5-94
15
1.05
14
38
I
42
70
1.148
(68)
74
50
7-35
20
17
I
75
80
5
9.04
25
21
39
2
ii
9
1.207
(85-9)
no
.8
10.96
30
1.076(31.1
) 2 5
.40
2
5 1
IOO
133
.1
I 3- I 7
40
35
.40
3
5
NOTE. In the original paper the author writes, " grams of sub-
stance in zoo grams of solvent (percentage solubility) " and " moles
of substance in 100 mols of solvent (percentage molar solubility)," thus
implying equivalence of the terms and giving rise to uncertainty as to
which is really intended.
MERCURY BROMIDE (ic) HgBr 2 . SOLUBILITY IN WATER.
g I .06 (Lassaigne J. chim. med. 12, 177, '76.)
25 O . 6l (Sherrill Z. physik. Ch. 43, 727. '03-)
IOO 2O-25 (Lassaigne.)
MERCURY BROMIDE
190
SOLUBILITY OF MERCURIC BROMIDE ORGANIC SOLVENTS.
In Carbon Bisulphide. In Other Solvents at i8-2o.
(Arctowski Z. anorg. Ch. 6, 267, '94.)
t*.
Cms. HgBr 2
per 100 Gms.
Solution.
t.
Gms.HgBr 2
per 100 Gms.
Solution.
10
- 5
0.049
0.068
0.087
I 5
20
25
0.140
0.187
0.232
+ 5
0.105
30
0.274
10
0.122
(Sulc. Ibid. 25, 401, 'oo.)
Solvent.
Chloroform
Bromoform
Tetra Chlor Methane
Ethyl Bromide
Cms. HgBr 2
Formula. periooGms.
Solvent .
O.I26
0.679
0.003
2.31
CHC1 3
CHBr 3
CC1 4
C 2 H 5 Br
Ethylene Di Bromide C 2 H 4 Br 2 2.34
Mercurous bromide Hg 2 Br 2 . One liter of saturated aqueous solution
contains 0.000039 gram Hg 2 Br 2 at 25. (Shemii)
MERCURY CHLORIDE (ic) HgCl 2 .
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 563, '94; at 25, Foote and Levy Am. Ch. J
temp. Rohland Z. anorg. Ch. 18, 328' '98; see also Poggiale Ann. chim.
35t 238, '06; at room
phys. [3] 8, 468, '43.)
t .
Gms. HgCl 2 per
loo Gms. Solution.
t.
Gms. HgCl 2 per
zoo Gms. Solution.
t.
Gms. HgCl 2 per
100 Gms. Solution.
O
3-5
30
7-2
100
38.0
10
20
25
4-5
5 . 4 (6.88,R.
6.9 (F.andL.)
40
60
80
9-3
14.0
23.1
120
I4O
J 5o
59-o
77.0
78-5
SOLUBILITY OF MERCURIC CHLORIDE IN AQUEOUS SOLUTIONS OF
SODIUM CHLORIDE.
(Homeyer and Ritsert Pharm. Ztg. 33, 738, '88.)
Per cent Concentration Gms ' H * C1 * ** I0 Gn - NaC1 ^"^ at:
of NaCl Solutions.
o-5
1.0
IO-O
25.0
26.0 (saturated) 128
^5
65
100
10
13
44
14
18
48
3
36
64
58
68
no
I2O
142
196
128
152
208
SOLUBILITY OF MERCURIC CHLORIDE IN AQUEOUS SOLUTIONS OF
HYDROCHLORIC ACID AT:
(Engel -
Mg. Mols. per
0.
Ann. chim. phys. [6] 17,
100 cc. Sol. Gms. per
20-25 (?).
362, '89.) (Ditte Ibid. [5] 22, 551, '81 .)
100 cc. Sol. S p. Gr. of Parts HC1 Part _ s HgCl2
HC1.
*HgCl.
HCl.
Hg0 2 . Solutions.
per 100
Parts H 2 0.
per 100
Parts Solution.
4-3
9-7
i-57
I3.II
.117
O-O
6.8
9.9
19.8
3.61
18.04
.238
5-6
46.8
I 7 .8
35-5
6.49
3 2 -44
.427
10- I
73-7
26.9
55-6
9.81
49.04
.665
13-8
87.8
32-25
68.9
n .76
58.80
.811
21 .1
127.4
34-25
72.4
12.48
62 .40
.874
31.0
141.9
41-5
85 5
i$-i3
75.65 2-023
50.0
148.0
48.1
88 6
17-54
87.70 2.066
6o.o
154.0
70-9
95-7
25.84
129.20 2.198
191
MERCURIC CHLORIDE
SOLUBILITY OF MIXTURES OP SODIUM AND MERCURIC CHLORIDE IN
WATER AT 25.
(Foote and Levy Am. Ch. J. 35, 239, '06.)
Gms. per loo Gms. Solution. Gms. per 100 Gms. Undissolved Residue. Solid
NaCl.
HgCl 2 .
NaCl.
HgCl 2 .
H 2 0.
26-5
none
IOO
none
none NaCl
18.66
5!-35
. . .
16.39
18.71
18.64
5*-32
51.42
21.98
65.42
NaCl and
NaCl.HgCl 2 .2H 2 O
18.87
51 .26
71 .25
14-97
57-74
i6'. 3 8
74.18
9.44 '
Double Salt
14.03
13-25
59-69
62.16
16.36
16.16
74-21
74.70
9-43
9.14
NaCl.HgCl 2 .2H 2 O
' Calc. Comp. = 16.01% NaC!
74-14% HgC1.9.8s% H,0
13 .17
62.59
15.96
74.76
9.28 .
12.97
*3-M
62 .50
62.48
78.20
88.64
1 NaCl.HgCl 2 . 2 H 2 O
f and HgCl 2
13 -15
62-55
90-83
... J
Two determinations made at
10.3 gave:
19.46
46.49
67.46
29.19
3-35
19.48
46.50
22.83
68.85
8.32
SOLUBILITY OF MIXTURES OF POTASSIUM AND MERCURIC CHLORIDES
IN WATER AT 25.
(Foote and Levy.)
Composition of Solution.
Grams per 100 Grams
Solution.
Percentage Composition
of Undissolved
Residue
Solid
Phase.
' KC1.
26.46
26.24
26.43
26.33
HgCl 2 .
none
15 .04
15 .02
15.02
K'Cl.
IOO
HgCl 2 .
none
3-63
26.15
52.01
H 2 0.
ill]
KC1
KC1 and
2KCl.HgCl 3 .H 2 O
26
33
14.92
61
.04'
23
74
18.91
34
.61
61
.66
3-
73)
2 KCl.HgCl 2 .H 2 O
22
21
36
39
21.39
23.88
34
34
77
05
62
61
.02
.84
3-
3-
Calc. Composition
34.05% KC1, 6i.8 4 %HgCl 2 ,
4.11% H 2
20.32
2O.26
27 .62
27.38
65
73
.24
. 9 8
;; j
2 KCl.HgCl 2 .H 2 and
KCl.HgCl 2 .H 2 O
17
85
25-34
21
'.89
75
.10
3-
on
9
.26
18.95
21
.02
73
36
5-
6 2 |
KC1.H S C1 2 .H 2
7
'6
.80
.84
19.56
22.81
2O
20
7.6
75
73
74
.06
54
6.
4-
18
71
,. Calc. Composition
20.52%KC1, 74-53% HgCl 2 ,
5.47% H 2
6
.66
24.32
20
54
73
99
5-
47,
6
6
52
.64
25- x 3
25.16
76
80
.46
.60
KCl.HgCl 2 .H 2 O and
KC1.2HgCl 2 . 2 H 2
6
27
2 5 -ii
12
.09
83
.20
4-
?i
KC1.2HgCl 2 . 2 H 2 O
Calc. Composition
5
77
24-73
II
.87
83
. 18
4-
95
n.43%KCl, 83.os%HgCl 2 .5.52%H 2
4
.68
24-75
. '
84
.46
4
.66
25- J 7
.
. .
93
.68
.
KC1.2HgCl 2 .2H 3 and HgC; a
4
.69
24.82
.
98
5o
-
none
6.90
none
IOO
.00
none
Hga 2
MERCURIC CHLORIDE
192
SOLUBILITY OF MIXTURES OF RUBIDIUM AND MERCURIC CHLORIDES
IN WATER AT 25.
(Foote and Levy.)
Composition of Solution.
Grams per 100 Grams.
Solution.
Percentage Composition
of Undissolved Residue. Solid
Phase.
RbCl.
HgCl 2 .
RbCl.
HgCl 2 .
H 2 6.
48.57
none
IOO.O
none
none RbCl
46.76
9.18
88.04
ii .24
0.72 ]
47-54
47-55
9-49
9-39
60.33
37-5 1
40-75
2.16
2.66
- RbCl and 2 RbCl.HgCl 2 .H 2
47-3
9-47
46.73
49-38
3.88 J
47-65
10-35
19.58
46.50
50.92
50.80
2-58 }
3-22 :
2RbCl.HgCl 2 .H 2 O Calc. Com-
position 45.55% RbCl.si 05%
HgCl 2 .3-4%H 2 O
34-77
19.94
43-07
52-44
4-49
2RbCl.HgCl 2 .H 2 Oand 3 RbCl.
34.76
20-10
41 .10
55.36
3-54
2HgCl 2 .2H 2 O
30.27
29.20
27-38
20.17
20-55
20.63
39-07
39.10
38.67
57-34
57-47
57-40
3-59
3-43 .
3-93
3 RbC1.2HgCl ? .2H 2 O
Calc. Composition
3 8. 5 5%RbCl, 57.62%HgCl 2 .
3 .82%H 2
26.83
27.09
20.87
20.97
38.48
31.40
57-36
64-35
4- J 6 I 3 RbC1.2HgCl 2 . 2 H 2 O and
4.25 RbCl.HgCl 2 .H2O
26.15
20.58
30-34
65.48
4.18 J
23.81
18.71
30.87
65.10
. ~ ^ RbCl.HgCl 2 .H 2 O
4-3 Calc. Composition
18.10
14.25
29.87
65.28
4.8? \ 2 9 .49%RbCl, 66.11% HgCl 2 ,
D 4.40%H 2 O
10.87
10.42
29-33
66.15
4-52 J
10.68
10.56
28.59
67-99
3-42
RbCl.HgCl 2 -H 2 O and 3 RbCl
10. 06
10.05
26.22
72 .20
1.58
4 HgCl 2 .H 2
io.c6
9.86
25.28
73-38
0-84
8.48
8.46
8.71
8.80
25-30
25-44
73-15
73-67
i-55
0.89
3KbCl. 4 HgCl 2 .H 2 O
Calc. Composition
' 24.76% RbCl, 74-01% HgCl*
5-68
8.70
25.09
73-46
i-45
i.2 3 %H 2 O
5.10
8-33
24.92
73-93
i .15
3-43
8-25
22.79
75-72
i-49
3 RbCl. 4 HgCl 2 .H 2 Oand RbCl
sHgC! 2
3-38
8.00
12.68
86.74
0-58 ^
2.98
1.89
1.50
7.71
7-64
7-55
8.40
8.38
8.30
91.24
91.78
91.81
RbCl. S HgCl 2
Calc. Composition
' 8 .20% RbCl, 9 1 -8% HgCl 2
I .10
7.21
8.07
91.58
o-79
7.16
6.91
93 -15
RbCl.sHgCl 2 and HgCl 2
0.84
7.42
2.27
97-09
none
6.90
none
IOO.O
HgCl 2
i 9 3 MERCURIC CHLORIDE
SOLUBILITY OF MERCURIC CHLORIDE IN METHYL, ETHYL PROPYL,
w BUTYL, Iso BUTYL AND ALLYL ALCOHOLS.
(Etard Ann. chim. phys. [7] 2, 563, '94.)
NOTE. For the solubility in Me, Et, and propyl alcohols at room
temperature, see Rohland Z. anorg. Ch. 18, 328, '98; at 8.5, 20 and
38. 2, see Timofejew Compt. rend. 112, 1224, '91; in Me and Et
alcohols at 25, see de Bruyn Z. physik. Ch. 10, 783, '92. The deter-
minations of these investigators agree well with those of Etard, which
are given below.
Grams HgC! 2 per 100 Grams Saturated Solution in:
l> .
CHaOH.
C 2 H 5 OH.
C-jHzOH. CH 3 (CH 2 ) 3 OH. (CH3) 2 CHCH 2 OH.
CH 2 .CH.CH,OH.
-30
14-5
15.0
...
20
20.1
15-7
13-5
21.0
10
15-2
26-5
16-5
13-7
25-5
20.1
29.8
17.4
14.0
5-2
30.0
+ 10
26. 3
30.6
18.0
14-3
6.0
37-5
20
34-o
32.0
18.8
14.6
6.8
46-5
25
40.0
32-5
I9-S
*5 5
7.2
30
44.4
33-7
20.0
16.5
7-5
40
58.6
35-6
23.0
19.6
9-7
. . .
60
62.5
41.2
29.8
26.5
17.0
. . .
80
66.0
47-5
36.8
33-o
24.9
. . .
100
70.1
54-3
43-8
3 I -7
. . .
120
73-5
61-5
50.6
39-2
150
78-5
SOLUBILITY OF MERCURIC CHLORIDE IN ACETIC ACID.
(Etard.)
Cms.
Gms.
Gms.
t.
HgCl 2 per
100 Cms.
t.
HgCl 2 per
zoo Gms.
t.
HgCJ 2 per
loo Gms.
Solution.
Solution.
Solution.
20
2-5
70
8-5
no
13-6
30
3-5
80
9-7
120
I6. 5
40
4-7
90
II -O
I 3
20.7
50
6.0
IOO
12.4
140
25.2
60
7-2
1 60
34-8
SOLUBILITY OF MERCURIC CHLORIDE AND SODIUM CHLORIDE IN ETHYL
ACETATE AT 40.
(Linebarger Am. Ch. J. 16, 214, '94.)
Solid
HgCl 2
Mols. per 100 Mols.
Acetate.
Gms. per 100 Gms.
Acetate.
Gms. per 100 Gms.
Solution.
NaCl.
HgCl 2 .
NaCl.
H g ci 2 :
NaCl.
H g ci 2 :
0.8
12-9
0.53
39-7
o-53
28.4
2.3
12-4
I .53
38-15
27.61
4-3
I6. 4
2 .8 S
5 -44
2 '.78
33-54
9.1
22.85
6.05
86.14
5-6o
46.28
18.5
34-9
12 .29
107.4
10.95
5!-7 6
20. o
40.0
13.29
123.0
II -73
55.18
The double salt (HgCl 2 ) 2 .NaCl is formed under proper conditions.
MERCURIC CHLORIDE
194
SOLUBILITY OF MERCURIC CHLORIDE IN ETHYL ACETATE AND IN
ACETONE.
(Etard; von Laszcynski Ber. 27, 2285, '94; Krug and McElroy J. Anal. Ch. 6, 186, '92; Linebar-
ger Am. Ch. J. 16, 214, 94; Aten Z. physik. Ch. 54, 121, '05.)
NOTE. The results obtained by the above named investigators
were calculated to a common basis and plotted on cross-section paper.
The variations which were noted could not be satisfactorily harmonized,
and therefore all the results are included in the following table.
SOLUBILITY.
In Ethyl Acetate.
In Acetone.
Grams HgCl 2 per TOO Grams Solution.
Gms. HgCl2 per TOO Gms. Solution.
Laszcynski.
Aten. Lanebarger.
Etard . K and McE . Laszcynski . Aten .
Etard
k
10
23-
O
40
44.0*
57-
22 .O
23-
2
32
.0
40
49-7
43 .0 *
61.
7
+ 10
22.2
23-
5
32
5
40
52.0
51.0 *- 5 8. 9 f
61.
7
20
22-5
23-
4
32
7
40
54
58- 5 t
61.
7
25
22 .7
23
5
33
-O
40
37-4 55-2
5 8. 2 t
61.
7
30
23.0
.
33
.2
40
... ...
61.
7
40
23-5
33
5
40
61.
7
50
24.0
.
33
5
41
... ...
61.
7
60
24-7
42
5
... ...
61.
7
80
26.0
45
.2
... ...
61.
7
100
. .
. .
.
.
. .
48
.0
... ...
. .
1 20
.
50
.8
...
.
150
55
.0
...
.
(*)
Solid phase HgCl 2 (CH 3 ) 2 CO.
(t) Solid Phase HgCl 2 .
100 grams absolute acetone dissolve 143 grams HgCl 2 at 18.
(Naumann Ber. 37, 4332, '04.)
SOLUBILITY OF MERCURIC CHLORIDE IN SEVERAL SOLVENTS.
(Arctowski Z. anorg. Ch. 6, 267, '94; von Laszcynski; Sulc. Z. anorg. Ch. 25, 401, 'oo.)
In Carbon Bisul-
phide (A.).
Gms. HgCl 2
t V
per 100 Gms.
Solution.
10
O-OIO
0-018
10
0.026
15
0.032
20
O.O42
25
0-053
30
0-063
In Benzene
(von L.).
In Several Solvents
at 18-20 (S.).
Gms. HgCl 2
Gms. HgCl 2
t.
per 100 Gms.
Solution.
Solvent.
per loo Gms.
Solvent.
15
o-537
CHBr 3
0.486
41
0.616
CHC1 3
0.106
55
0.843
CC1 4
0.002
84
1.769
C,H 5 Br
2 -OIO
C 2 H 4 Br 2
1-530
I 9 5 MERCURIC CHLORIDE
SOLUBILITY OF MERCURIC CHLORIDE IN ABSOLUTE ETHYL ETHER.
(Etard; Laszcynski ; Kohler Z. anal. Ch. 18, 242, '79.)
t o Gms. HgCl 2 per t <> Gms. HgCl 2 per t <> Gms. HgCl 2 per
100 Gms. Solution. ' 100 Gms. Solution. 100 Gms. Solution.
6.0 60 6.0 90 7.5
6.0 70 6.4 100 8.0
6.0 80 7.0 no 8.5
SOLUBILITY OF MERCURIC CHLORIDE AND OF DOUBLE MERCURIC AND
TETRA METHYL AMINE CHLORIDE (CH 3 ) 4 NC1.6HgCl 2 IN AQ. ETHER
AT I 7. (Stromholm J. pr. Ch. [2] 66, 443, '02; Z. physik. Chem. 44, 64, '03.)
Molecular Concentration per Liter. Grams per Liter of Solution.
H 2 O.
HgCl 2 (*).
HgCl 2 (t).
H 2 0.
HgCl 2 (*).
HgCl 2 (f).
O-O
o-i5 J 5
0.0342
O
4I.I6
9.26
0-0656
o-i795
0.0428
1.18
48.64
II. 60
O.I3II
o . 2069
0-0516
2.36
56-08
I4.OO
0.1956
0.2339
0-0603
3-5 2
63.38
16.34
0.26II
0.2489
0-0690
4.70
70-16
18.70
0.3267
o . 2849
0.0779
5.88
77-20
21.10
0.3922
0.3100
0.0866
7.06
84.02
23.48
- ^J-y - *J -^ -1
(*) Results in this column are for solutions in contact with the Solid Phase HgCfe. (t) Results in
this column are for solutions in contact with the Solid Phase (CH 3 ) 4 NC1.6HgCl2.
SOLUBILITY OF MERCURIC CHLORIDE AND OF DOUBLE MERCURIC AND
TETRA METHYL AMINE CHLORIDE IN ALCOHOL-ETHER SOLUTIONS
AT 17. (Stromholm.)
Grams C 2 H 5 OH per Liter. Grams HgCI 2 (*) per Liter. Grams HgCl 2 (t) per Liter.
o.o 41.16 9.26
4.58 50.00 11.87
9-l6 58.76 14-38
13.74 66.96 16.90
SOLUBILITY OF DOUBLE MERCURIC CHLORIDES IN AQUEOUS AND PURE
ETHER AT 16.6.
(Stromholm.)
Mol. Cone, of HgCl 2 per Liter of: Gms. HgCl 2 per Liter of:
Pure Aq. Aq. Aq. Pure Aq. Aq. Aq. 1 h 'J
Ether. Ether Ether Ether Ether. Ether Ether Ether Fhase>
(i). (2). (3). (4). (S). (6).
0.1515 0.2387 0.2647 0.3196 41.04 64.69 71.71 86.58 HgCl 2
0.0673 0.0673 - I2 93 -i 6 i7 l8 - 2 3 l8 - 2 3 35-5 43-79 (CH 3 .CH 3 C 2 H 4 ) 2 SC1.6HgCl2
0.0404 0.0720 0.0835 0.1034 10.95 I 9-5 I 22.61 28.01 (CH 3 .C 2 H 5 CH3C 2 H4) 2 SC1.6HgClt
0.0342 . . . 0.0706 . . . 9.26 ... 19.10 ... (CH3) 4 NC1.6HgCl 2
0.0264 . . . 0.0568 . . . 7.14 . . . 15.39 . . (C 2 H 6 ) 3 SC1.6HgCl 2
0.0209 0.0400 0.0460 0.0594 5.66 10.83 12.48 16.10 (CH 3 .C 2 H 5 ) 2 SC1.6HgCI 2
0.0063 ... 0.0144 i'7 ... 3-90 ... (CH 3 ) 2 .H 2 NC1.2HgCl2
(i) containing 0.21055 m ol- H 2 O pec liter. (2) 0.2756 mol. H 2 O per liter. (3) 0.421 mol. H 2 O per lite*
(4) containing 3.79 gms. H 2 O per liter. (5) 4.97 gms. H 2 O per liter. (6) 7.59 gms. H 2 O per liter.
MERCURIC CHLORIDE
196
DISTRIBUTION OF MERCURIC CHLORIDE BETWEEN WATER AND
TOLUENE AT 24.
(Brown J. Physic. Ch. 2, 50, '98.)
Cms. HgCJ 2 per 100 cc. Gms. HgCIg per TOO cc.
Layer.
C*H 6 CH 3
Layer.
H 2 O
Layer.
Layer .
0.442
O.O27O
1.816
0.130
0.732
0.0488
3.766
0.292
0.780
0.0542
3-754
0.298
I.I92
0.0812
6.688*
0.528*
* This solution saturated.
MERCUROUS CHLORIDE HgCl.
One liter water dissolves 0.002 gram HgCl at 18, by conductivity
method.
(Kohlrausch Z. physik. Ch. 50, 356, '04- '05.)
SOLUBILITY OF MERCUROUS CHLORIDE (CALOMEL) IN AQUEOUS SOLU-
TIONS OF SODIUM CHLORIDE, BARIUM CHLORIDE, CALCIUM
CHLORIDE AND OF HYDROCHLORIC ACID AT 25.
(Richards and Archibald Proc. Am. Acad. 37, 345, 'oi-'o2.)
Solid phase in each case. Calomel -f about o.i gram of mercury.
In Aqueous NaCl.
In Aqueous BaCl 2 .
3. Gr. of
Grams
per Liter.
Sp. Gr. of
Grams per Liter.
>olutions.
' NaCl.
HgCl 2 . '
Solutions.
BaCl 2 .
HgCl 2 .
5-85
O.OO4I
1. 088
104.15
O-O44
.040
58-50
0.041
I-I34
156.22
0.088
.078
119.00
0.129
I.I74
208.30
0.107
093
148.25
0.194
1.263
312.45
0.231
.142
222.3
0.380
.188
292.5
0.643
In Aqueous CaCl 2
In Aqueous HC1.
>. Gr. of
Grams per Liter. gp. Gr. of
Grams per Liter.
>lutions.
' CaCl 2 .
HgCl 2 . Solutions.
HC1.
H g ci 2 :
39-96
O.O22
31.69
0.034
55-5
0.033
36.46
0.048
.064
III .0
O.oSl
.042
95-43
0.207
.105
138.75
O.IlS
.069
158.4
o-399
iS*
I95-36
0.231
.091
209.2
0.548
.205
257-52
0.322
.114
267.3
0-654
243
324.67
0.430
.119
278.7
0.675
3*5
432-9
0.518
.132
3*7-3
0.670
I-358
499-5
0.510
J 53
364.6
0.673
100 grams bromoform, CHBr 3 , dissolve 0.055 gram HgCl at i8-2o.
(Sulc. Z. anorg. Ch. 25, 401, *oo.)
i 9 7
MERCURIC OTANIDE
MERCURIC CYANIDE Hg(CN) 2 .
Solvent.
Water
Abs. Ethyl Alcohol
Abs. Methyl Alcohol
Glycerine
SOLUBILITY IN SEVERAL SOLVENTS.
Observer.
(Guthrie Phil. Mag. [5] 6, 40, '78.)
(Wittstein.)
(Griffiths.)
(de Bruyn Z.physik. Ch. 10, 784, '92.)
t.
Gms. Hg(CN) 2 per
100 Gms. Solvent.
-0.45
15.2
about ii .0
8.0
101 .1
53.85
19-5
10. 1
19-5
44.2
15-5
27.0
SOLUBILITIES OF MERCURIC CYANIDE DOUBLE SALTS IN WATER AND
IN ALCOHOL.
Double Salt.
Hg(CN) 2 . 2 KCN
Hg(CN) 2 . 2 TlCN
Hg(CN) 2 . 2 TlCN
2 Hg(CN) 2 .CaBr 2 . 5 H 2 cold
2Hg(CN) 2 .CaBr 2 .5H 2 O boiling
Hg(CN) 2 .KCl.H 2
Hg(CN) 2 .KBr.2H 2 O
Hg(CN) 2 .KBr. 2 H 2
Hg(CN) 2 .BaI 2 . 4 H 2
Hg(CN) 2 .BaI 2 .4H 2
Hg(CN) 2 .KI
Hg(CN) 2 .NaI.2H 2 O
Hg(CN) 2 .SrI 2 .6H 2
* .
Water.
cold
22.7
i
12.6
10
9-7
cold
100.
boiling
400.0
18
14.81
18
7-49
boiling
100.0 +
cold
6.42
boiling
250.0
cold
6.2
18
22.2
18
14-3
Gms. per 100 Grams.
'Alcohol. '
50.0
100. O
Observer.
(Fromuller Ber. n, 92, 's80
(Custer.)
(Brett.)
4.42 (Custer.)
62.5 (90% Ale.)
1. 04 (34 B Ale.) (Caillot.)
15.4 (90% Ale.) (Custer.)
25.0 (90% Ale.)
SOLUBILITY OF MERCURIC CYANIDE IN ORGANIC SOLVENTS
AT l8-20.
(Suk Z. anorg. Ch. 25, 401, 'oo.)
Solvent. Formula.
CHBr 3
CC1 4
C 2 H 5 Br
C 2 H 4 Br 2
Bromoform
Carbon Tetra Chloride
Ethyl Bromide
Ethylene Di Bromide
G. Hg(CN) 2 per
100 Gms. Solvent.
O.OO5
O-OOI
0.013
0.001
MERCURY FULMINATE C 2 HgN 2 O 2 .
One liter of water dissolves 1.738 -1.784 grams C 2 HgN 2 O 2 at 12.
(Holleman Rec. trav. chim. 15, 159, '96.)
MERCURIC IODIDE HgI 2 .
SOLUBILITY IN WATER.
t . Grams Hglj per Liter. Observer.
1 8 O.OOO4 (conductivity method) (Kohlrausch Z. physik. Ch. 50, 356, 'o4-'os.)
17.5 O . O4O (Bourgoin Bull. soc. chim. [2] 42, '84.)
22 0.054 (Rohland Z. anorg. Ch. 18, 328, '08.)
MERCURIC IODIDE
198
SOLUBILITY OF MERCURIC IODIDE IN ALCOHOLS.
Alcohol. Formula.
Methyl CH 3 OH
(i
Ethyl C 2 H 5 OH
Propyl C 3 H 7 OH
Amyl C 5 H U OH
Iso Propyl (CH 3 ) 2 CH.OH
Iso Butyl (CH 3 ) 2 CHCH 2 OH io 5 -io7~(b. pt.) ... 2.433
...
Sp.Gr.of
Solution.
G. HgI 2 per
100 Gms.
Alcohol.
Observer.
15-20
0.799
3-24
(Rohland.)
19-5
3-16
(de Bruyn.)
66 (b. pt.)
6.512
(Sulc.)
15-20
O.SlO
1.42
(Rohland.)
18
1.48
(Bourgoin.)
19-5
2.09
(de Bruyn.)
25
0.803
2.19
(HerzandKnoch.)
78 (b. pt.)
4.325
(Sulc.)
1520
0.816
0.826
(Rohland.)
13
0.66
(Laszcynski.)
3.66
"
100
5-30
M
133-5
81 (b. pt.)
9-57
2.266
(Suk.)
SOLUBILITY OF MERCURIC IODIDE IN AQUEOUS ETHYL ALCOHOL:
At 1 8. At 25.
(Bourgoin.)
(Herz and Knoch Z. anorg. Ch. 45, 266, '05.)
Solvent.
Gms. HgI 2
per Liter.
Wt.% Alcohol
in Solvent.
HgI 2 per loo cc. Solution.
Sp. Gr. of
olutions as /,
Millimols.
Grams.
Abs. Alcohol
11.86
100
3
.86
I
754
O
8033
HO + 80% 90 Ale.
2-857
95
.82
2
56
I
.162
O
.8095
H 2 O+io% 90 Ale.
0.086
92
44
I
.92
873
O
.8154
86
74
I
38
O
623
O
.8300
78
75
O
935
425
O
.8405
67
63
45
.204
O
.8721
SOLUBILITY OF MERCURIC IODIDE IN ACETONE IN ETHYL ACETATE
AND IN BENZENE.
(Sulc; Krug and McElroy J. Anal. Ch. 6, 186, '92; Laszcynski Ber. 27, 2285, '94.)
In Acetone.
In Ethyl Acetate.
Gms. HgI 2
Gms. HgI 2
t. per 100 Gms.
t
per loo Gms.
(CH 3 ) 2 CO.
(
:H 3 COOC2H 6<
I 2.83
20
1-49
18 3-36
+17.5
1.56
25 2 .09 (K.andMcE.)
21
1.64
40 4-73
40
2-53
58 6.07
55
3.19
56 (b.pt.) 3 . 249 (Sulc.)
76
4-3 1
In Benzene.
Gms. HgI 2
per zoo Gms.
15 0.22
60 0.88
6 5 0.95
84 1.24
80 (b.pt.) 0.825 (Sulc.)
74-78 (b.pt.) 4 . 20 (Sulc.)
I 9 9 MERCURIC IODIDE
SOLUBILITY OF MERCURIC IODIDE IN CARBON BISULPHIDE.
(Linebarger Am. Ch. J. 16, 214, '94; Arctowski Z. anorg. Ch. 6, 267, '94; n, 274, '95.)
f0 Cms. HgI 2 per t o Cms. HgI 2 per t o Cms. HgI 2 per
io3 Gms. Solution. 100 Cms. Solution. 100 Cms. Solution.
116 0.017 5 0.141 15 0.271
93 0.023 o 0.173 20 0.320
86.5 0.024 + 5 0.207 25 0.382
10 0.107 10 0.239 30 0.445
SOLUBILITY OF MERCURIC IODIDE IN SEVERAL ORGANIC SOLVENTS.
(Sulc Z. anorg. Ch. 25, 401, 'oo.)
Solent. Formula. t".
Chloroform CHC1 3 18-20 0.040
Chloroform CHC1 3 61 (b. pt.) 0.163
Bromoform CHBr 3 18-20 0.486
Tetra Chlor Methane CC1 4 18-20 0.006
Tetra Chlor Methane CC1 4 75 (b. pt.) 0.094
Ethyl Bromide C 2 H 5 Br 18-20 0.643
Ethyl Bromide C 2 H 5 Br 38 (b. pt.) 0.773
Ethylene Di Bromide C 2 H 4 Br 2 18-20 0.748
Ethyl Iodide C 2 H 5 I 18-20 2.041
Ethylene Di Chloride C 2 H 4 Cl2 85.5 (b. pt.) i .200
Iso Butyl Chloride (CH 3 ) .CHCH 2 C1 69 " 0.328
Methyl Formate HCOOCH 3 36-38 " 1.166
Ethyl Formate HCOOC 2 H 6 52-55 " 2.150
Methyl Acetate CH 3 COOCH 3 56-59 " 2.500
Acetal CH 3 CH(OC 2 H 5 ) 2 105 " 2.000
Epi Chlor Hydrine CH 2 .O.CH.CH 2 C1 117 " 6.113
Hexane C C H 14 67 ... 0.072
SOLUBILITY OF MERCURIC IODIDE IN ETHER AND IN METHYLENE
IODIDE.
In Ether. In Methylene Iodide.
(Sulc; Laszcynski.) (Retgers Z. anorg. Ch. 3, 253, '93.)
^.0 Gms. HgI 2 per 100 ^.o Gms. HgI 2 per 100
Gms. (C 2 H 8 ) 2 O. Gms. CR 2 I t .
o 0.62 15 2.5
36 0.97 loo 16.6
35 (b.pt.) 0.47 (Sulc) 180 58.0
SOLUBILITY OF MERCURIC IODIDE IN FATTY BODIES.
(Mehu J. pharm. chim. [5] 12, 249, '85.)
*o Gms. HgI 2 per Cni wn t *o Gms. HgI 2 per
* ' 100 Gms. Solvent. * ' 100 Gms. Solvent.
Bitter Almond Oil 25 0.5 Vaseline 25 0.025
Bitter Almond Oil 100 i . 3 Vaseline 100 o . 20
Castor Oil 25 4.0 Poppy Oil 25 i .o
Castor Oil 100 20.0 Olive Oil 25 0.4
Nut Oil 100 1.3 Carbolic Acid 100 2.0
100 grams oil of bitter almonds dissolve 5.0 grams HgI 2 .KI at 25.
(Mehu.)
MERCURY OXIDE
200
MERCURY OXIDE HgO.
SOLUBILITY IN WATER.
(Schick Z. physik. Ch. 42* 163, 'oi-'oa.)
* Grams per 1000 cc. Solution.
25
100
0.0518 yellow HgO
0.410 yellow HgO
0-0513 red HgO
0.3 79 red HgO
EQUILIBRIUM IN THE SYSTEM, MERCURY OXIDE, SULPHUR TRI-
OXIDE, WATER.
(Hoitsema Z. physik. Chem. 17, 651, '95.)
Results expressed in molecules per sum of 100 molecules of the
three components of the system.
Results at 25.
Results at 50.
Liquid Phase.
Solid
Liq
uid
Phas
ie.
Solid
H 2 0.
S0 3 .
HgO. *
Phase.
H 2 0.
S0 3 .
HgO.
Phase.
98-5
I
.24
o-33
3HgO.SO$
9 8
9
0.96
O
17
3 HgO.SO,
96.6
2
.49
0.92
N
9 6
O
3
05
O
93
94.4
3
93
1-65
41
93
.2
4
.92
I
.90
"
93-9
4
.24
1-85}
3 HgO.SO 3 and
92
.8
5
10
2
.09
"
94.4
4
52
2.12 j
3 HgO.2SO8.2H 2 O
92
.8
5
,16
2
.06
"
93-4
4
65
1-94
3 HgO.2SO 3 .2H2O
92
5
5
34
2
.12
"
92.9*
4
.81
2.29
3 HgO.SO 3
92
.2
5
57
2
.20
3 HgO.SO 3 and
92.9
5
.11
I. 9 8
3 HgO. 2 SO 3 .2H2O
3 Hg0.2S0 3 . 2 H 2
92.3*
5
.20
2-54
3 HgO.S0 3
92
.1
5
75
2
.11
3 HgO. 2 SO 3 .2H 2 O
9 2 -3
5
58
2.09
3 HgO. 2 SO 3 .2H 2 O
92
O
5
,80
2
.16
"
92.1
5
.81
2.08
"
9 1
.2*
6
27
2
56
3 HgO.SO 3 and
91.9
5
97
2.90
3 HgO.S03
HgO.S0 3
91.9
6
i5
2.05
3 Hg0.2S0 3 .2H 2
9i
5
6
34
2
.19
3 HgO.2SO a . 2 H 2 O
9 J -3
6
54
2.13
and HgO.SO 3
91 .2
6
77
2.02
HgO.S03.H20
9 1
3*
6
37
2
30
HgO.SO 8
9 J -3
6
.90
1. 80
9i
.6
6
.69
I
75
9!-3
7
.67
1. 01
9i
.1
8
3 2
57
"
9i-3
91 -o
7
8
.84
36
0.8 9 j
o.6 9 j
HgO.SO 3 .H 2 O
and HgO-SOa
89
3i
.6
.6
10
68
.2
4
0.23
0.03
n
4
90-5
8
95
o-53
HgO.S0 3
89.2
10
.6
0.22
75-8
24
.2
trace
39-2
60
7
trace
"
* Indicates unstable equilibrium.
MEROUROUS SULPHATE Hg 2 SO 4 .
SOLUBILITY IN WATER, IN SULPHURIC ACID AND IN POTASSIUM
SULPHATE AT 25.
(Drucker Z. anorg. Ch. 28, 3 62, '01; Wright and Thomson Phil. Mag. [5] 17, 288; 19, i, '&4-'&s;
Wilsmore Z. physik. Ch. 35, 3 os, 'oo.)
Solvent.
Water
Aq.H 2 SO 4 ( i .96 gms. per liter)
Aq.H 2 SO 4 ( 4.90 gms. per liter)
Aq.H 2 SO 4 (9.80 gms. per liter)
4 (34.87 gms. per liter)
Hg 2 SO 4 per Liter.
Gram Mols. Grams.
11.71 I0~* O . 058(0.047 W.and T^ 0.059 W.)
8.31 " O.O4I
8.78 " 0.044
8.04 " O.O4O
9.05 " 0.045
2OI
METHANE
METHANE CH 4 .
SOLUBILITY IN WATER.
(Winkler Ber. 34, 1418, 'ox.)
t .
/5.
0'.
?
t.
/.
ft'.
9.
0.05563
05530
0.00396
40
.02369
.02198
.00159
5
0.04805
.04764
0.00341
50
.02134
.01876
.00136
10
0.04177
o
.04127
0-00296
60
.01954
.01571
.00115
J S
0-03690
o
.03628
O.OO26O
70
.01825
.01265
.00093
20
0.03308
o
03233
O.OO232
80
.01770
o
.00944
o
.00070
25
O.O3OO6
.02913
0.00209
90
01735
00535
o
.00040
30
O.O2762
.02648
O.OOI9I
100
.01700
o
.00000
.00000
For the values otp,p' and q see Ethane, page 133.
SOLUBILITY OF METHANE IN METHYL ALCOHOL AND IN ACETONE.
(Levi Gazz. chim. ital. II, 513, *oi; abs. in Z. physik. Ch. 41, no, '02.)
In methyl alcohol / (Ostwald expression, see page 105) 0.5644
0.0046 J o. 00004 i 2 .
In acetone / (Ostwald expression) = 0.5906 0.00613* ~~ 0.0000146*'.
From which is calculated the following values:
In Methyl Alcohol.
In Acetone.
o 0.5644
10 0.5144
20 0.4564
30 0.3904
40 0.3164
50 0.2344
60 0.1444
70 o . 0464
o o . 5906
10 0.5278
20 0.4622
30 0.3936
40 0.3220
50 0.2476
60 0.1702
70 0.0900
Tetra Chlor METHANE CC1 4 (Carbon Tetra Chloride).
SOLUBILITY IN WATER.
(Rex Z. physik. Chem. 55, 355, '06.)
t. o. 10. 20.
Grams CC1 4 per 100 gms. H 2 O i .097 0.083 0.080
Tri Phenyl METHANE CH(C 6 H 5 ) 3 .
SOLUBILITY IN ANILIN.
(Hartley and Thomas J. Ch. Soc. 89, 1026, '06.)
By synthetic method, see page 9.
Gms.
30.
0.085
t . per zoo '
Gms. So-
j Mol. per
cent
CH(CH 5 ) 3 .
Solid
Phase.
lution.
23.0
5-4
1.85 a
rhombs
35-3
9-5
3-8
43-o
13-5
5-6
"
52.1
21.9
9-7
"
61 .4
36-5
17.8
66.0
47.2
25-4
44
68.7
54-8
31-6
M
70.1
64.6
40.9
M
Gms.
t.
C^CaHc)
per 100
Gms. So-
3 Mol. per
cent
CH(CeH 6 ) 3 .
Solid
Phase.
lution.
71-3
67.9
44.6 CH <
v*6"6/3 .V^il^IM 112
rhombs
71.6
71 .7
49-1
71 .2
76-3
55.1
t
70.6
78.3
57-9
71.6
82.1
63 . 5 CH(CeHa) 3 monoclinic
74-3
84-9
68.2
tt
82.1
91 .7
80.9
87-3
96.1
00.2
44
Tri Phenyl METHANE
202
SOLUBILITY OF TRI PHENYL METHANE IN BENZENE.
(Linebarger Am. Ch. J. 15, 45, '93.)
Gms.
QHa.
3-9
3-90
QH + CH(CflH
4.0
4.06
CH(C ft H 6 ) 3 .C 6 H,
12. 5
5-18
"
16.1
6.83
44
19.4
7.24
"
23-1
8-95
44
37-5
10.48
+ CH(CeH5) 3
42 .0
19.61
CH(CeH 6 ) 3
44.6
22.64
44
50.1
30.64
44
55-5
40-51
44
71.0
I4O.OO
44
76.2
319.67
"
(Hartley and Thomas.)
Gins . \>r/\i
CHCCaffi). f2 nt
per ioo Gms. rmr H \
Solution. CH(QH 6 ) 8 .
Solid Phase.
33
12.6
4-4
CH(C6H 6 ) 3 .QHj
49-4
24.0
8.8
44
65.6
38-9
17.2
44
73-8
57-5
30.2
14
77.1
67-4
39-7
"
77-9
76.3
5o-7
44
77-5
80.2
56-4
"
76.2
84.1
62.8
44
74.6
87-5
69.1
CH(C6H 5 ) 3
monoclinic
76.0
89.0
72.2
44
78.8
9o-5
75-3
"
82.3
93- 1
81-3
"
86.6
95-7
87.8
"
NOTE. Hartley and Thomas call attention to the inaccuracy of Linebarger's results and the cor-
rectness of Kuriloff 's determinations (Z. physik. Chem. 22, 547, J 97)-
Gms. CH(CeHs) 3
Gms. CH(CH 5 ) 3
t.
per ioo Gms.
Solution.
t.
per ioo Gms.
Solution.
II3.C
1 0-98
-40
7-5
IO2
1.24
20
13 -7
- 91
I. 5 6
25.8
- 8 3
I.9I
+ 10
38-7
~ 60
3-4
20
43-2
30
5 2 -9
SOLUBILITY OF TRI PHENYL METHANE IN CARBON BISULPHIDE.
(Etard Ann. chim. phys. [7] 2, 570, '94; below-8o, Arctowski Z. anorg. Ch. n, 273, '95-)
40
50
60
70
80
Gms.
per ioo Gms.
Solution.
63-7
72-4
78.6
85.6
92.2
SOLUBILITY OF TRI PHENYL METHANE IN HEXANE AND IN
CHLOROFORM.
(Etard.)
Gms.
ioo Gms.
Solution in:
l> .
Hexane.
Chloroform.
-50
10-5
-30
I .2
IS' 2
2O
1.6
19.0
10
2 -2
23-5
O
3-5
28.9
+ 10
5-6
35 -o
20
8-3
4i-5
Gms. CH(C 6 H 5 ) 3 per ioo Gms.
Solution in:
Hexane.
Chloroform.
30
12-5
48.8
40
20. o
5 6.1
50
2 5 .8
6 3 .8
00
45-7
71-7
70
62.0
79.8
80
78-5
8 7 .2
90
97.0
20 3
Tri Phenyl METHANE
SOLUBILITY OF TRI PHENYL METHANE IN PYRIDINE.
(Hartley and Thomas J. Ch. Soc. 89, 1028, '06.)
Synthetic method used, see note, page 9.
22.8
3i-7
37-9
48.7
Cms. Mol.
CH(CcH 6 )3 per Solid
per 100 Gms. cent Phase.
Solution. CH(C6H S ) 3 .
46.2
53-3
57-6
66.6
70.1
22.0
27.2
30-7
39-5
43-5
CH(C6H 5 ) 3
monoclimc
Gms. Mol.
CH(CH 6 ) 3 per
per 100 Gms. cent.
Solution. CH(C 8 H 5 ) 3 .
59-3
67.8
72.8
80.6
86.8
75-6
81.9
85-7
9i-5
95-8
50-3
59-7
66.4
77.2
88.1
Solid
Phase.
SOLUBILITY OF TRI PHENYL METHANE IN:
(Hartley and Thomas.)
Pyrrole.
Gms. Mol.
t o CH(CHe)3 Per Solid
" per loo Gms. cent Phase.
Thiophene.
Gms. Mol.
t o CH(C6H 6 ) 3 per Solid
" per i oo Gms. cent Phase.
Sol.
CH(CH 5 ) 3 .
Solution. CH(C6H 5 ) 3 .
24.6
24
3
8
.1 CH(C 6 H 6 ) 3 .CANH
25
7
26
.0
10
.8
CH(C ft H 6 ) 3 .C 4 H 4 S
,, rhombs
29.0
29
.8
IO
4
33
5
3 1
.1
13
5
3 r -5
33
4
12
.1
44
.0
43
.6
21
.1
"
36.8
40
.6
15
.8 CH(C6H6) 8
monoclinic
47
.6
48
4
24
4
"
42.7
49
i
20
9
53
5
58
7
32
9
"
46.9
56
.0
25
9
57
4
70
.2
44
7
"
53-2
63
9
32
.8
57
.6
74
.8
50.6
60.0
72
76
3
7
41
47
4
62
67
7
.0
78
81
7
9
56
60
.0
.8
CH(CH 5 ) 3
,, monoclinic
68^5
81
9
55
.6
67
.2
82
.1
61
3
"
71.1
84
4
59
.8
74
.2
87
4
70
5
"
80.0
9 1
5
74
o 4i
79
O
90
3
76
3
"
89.2
97
.6
Q tt
87
.2
96
.2
89
9
"
METHYL ACETATE, Butyrate and Propionate.
SOLUBILITY IN WATER AT 22.
(Traube Ber. 17, 2304, '84.)
100 grams H 2 O dissolve 25.0 grams CH 3 COOCH 3 ; 1.7 grams C 3 H 7
COOCH 3 ; 5.0 grams C 2 H 6 COOCH 3 .
METHYL IODIDE, Methylene Chloride and Methylene Bromide.
SOLUBILITY OF EACH IN WATER.
(Rex Z. physik. Chem. 55, 355, '06.)
Grams per 100 Grams H2O.
O
10
20
30
CH 3 I.
CH 2 C1 2 .
CH 2 Br 2 .
i-5 6 5
2-363
I-I73
1.446
2.122
I .146
1.419
2 .OOO
I.T48
1.429
1.969
I.I76
METHYL BUTYRATE, 204
METHYL BUTYRATE, METHYL VALERATE.
SOLUBILITY OF EACH IN AQUEOUS ALCOHOL MIXTURES.
(Bancroft Phys. Rev. 3, 193, '95.)
ioo cc. H 2 O dissolve 1.15 cc. methyl butyrate at 20.
cc. Alcohol
cc.
H 2 O Added*
in Mixture.
Butyrate.
Valerate.
3
2-34
1.66
6
6.96
5-o6
9
12 .62
9-03
12
I9'45
13.40
15
28.13
18.41
18
33-80
24.00
21
55- 6 4
30.09
24
00
36.72
cc. Alcohol
in Mixture.
cc. H 2 O Added *
Valerate.
27
4I-I5
30
33
36
52-37
62.25
74.15
39
91-45
42
00
* cc. HjO added to cause the separation of a second phase in mixtures of the given amounts of ethyl
alcohol and 3 cc. portions of methyl butyrate and of methyl valerate respectively.
METHYL ETHYL KETONE CH 3 .CO.C 2 H 5 .
SOLUBILITY IN WATER.
(Rothmund Z. physik. Chem. 26, 475, '08.)
By synthetic method, see Note, page 9.
0> Cms. Ketone per ioo Cms.
Aq. Layer. Ketone Layer.
-io 34-5 8 9-7
+ 10 26.1 90.0
30 21.9 89.9
50 17.5 89.0
70 16.2 85.7
90
no
130
140
Cms. Ketone per ioo Gms.
Aq. Layer. Ketone Layer,
16.1 84.8
17.7 80.0
21.8 71 .9
26.0 64.0
151 .8 (crit. temp.)44.2
MOLYBDENUM TRIOXIDE MoO 3 .
ioo gins, cold H 2 O dissolve 0.187 gm. MoO 3 .
(Dumas; Buchlolz.)
ioo ems. hot H 2 O dissolve 0.104 gm. MoO 3 .
(Hatchett.)
MORPHINE C 17 H 19 N0 3 .H 2 0.
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; Muller Apoth.-Ztg. 18, 257, '03.)
Solvent. Gms. Morphine per ioo Gms. Solution.
At i8-22. At 25. At8o d .
Solvent.
Gms. Morphine per ioo Gms.
Solution.
0.0283
Water
Alcohol
Ether
Ether sat. with
H,O 0.0094
H,O sat. with
Ether 0.0447
Benzene 0.0625
0.030
0.600
0.0131 0.0224
0.0961 Chloroform
i .3 1 (60) Amyl Alcohol
At l8-22.
0.0655
Ethyl Acetate 0.1861
Petroleum
Ether 0.0854
Carbon Tetra
Chloride 0.0156
Glycerine 0.45 (15.5)
At 25.
0-0555
0.88 10
0.1905
0.032 (17)
205 MORPHINE
SOLUBILITY OF MORPHINE IN AQUEOUS SOLUTIONS OF SALTS AND
BASES AT ROOM TEMPERATURE, SHAKEN EIGHT DAYS.
(Dieterich Pharm. Centrh. 31, 395, '90.)
In N/io Salt or Base. In N/i Salt or Base.
Grams per Liter. Grams per Liter.
[. sa.ii or case. <
Salt or Base.
Morphine.
Salt or Base.
Morphine. '
NH 4 OH
3-51
0.20
35-08
0-505
(NH 4 ) 2 CO,
4.80
0.031
48.03
O.O4O
KOH
4.62
2.78
46.16
K 2 C0 3
6.92
0.20
69.15
0-379
KHCO 3
10.02
0.024
ioo. 16
0.040
NaOH
4-OO
3-33
40.05
. . .
Na 2 CO 3
5-30
0.09
53-03
0.14
NaHCOg
8.41
0.032
84.06
0.044
Ca(OH) 2 (sat.)
1.00(25)
MORPHINE ACETATE CHaCOOH.C^H^NC^^HA Morphine
Hydrochloride HC1.C 17 H 18 NO 3 . 3 H 2 O, Morphine Sulphate H 2 SO 4 .
(C 17 H 19 NO 3 ) 2 .5H 2 O, and Apo Morphine Hydrochloride HC1.C 17
H 17 NO 2 .
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.)
Grams per ioo Grams of Solvent.
Solrent.
Water
Alcohol
Chloroform
Ether
Glycerine
Acetate.
Hydrochloride.
Sulphate . Apo M . Hydrochloride .
25
44.
4-
0.
19.
9
6
21
2
80.
50.O
40.0*
25.
2.4
20. Of
* 60.
80. 25.
2OO.O 6.53
2.8* 0.22
80. "
166.6
0-53*
2-53
2.62
0.026
0-053
&
6.
3-
25
33
t 15-5.
ioo gms. H 2 O dissolve 1.69 gms. apo morphine hydrochloride at
15.5, and 2.04 gms. at 25.
ioo gms. 90% alcohol dissolve 1.96 gms. apo morphine hydro
Chlorde at 2 5 . (Dolt Pharm. J . [4] 22. 345, '75 )
ioo gms. H 2 O dissolve 4.17 gms. morphine sulphate at 15.
(Power Am. J. Pharm. March, '82.)
MUSTARD OIL Allyl Isosulphocyanic Ester CS:NC 3 H 5
SOLUBILITY IN SULPHUR BY SYNTHETIC METHOD. See Note, p. 9.
(Alexejew Ann. Physik. Chem. 28, 305, '86.)
Grams Mustard Oil per ioo grams.
Sulphur Layer. Mustard Oil Layer.
90 10 72
IOO 12 67
no 15 62
120 23 51
124 (crit. temp.) 35
NAPHTHYLAMINE
206
a NAPHTHYLAMINE p Sulphonic Acid (Naphtion Acid), i : 4
C, H 6 NH 2 .SO 2 H and a Naphthalamine o Sulphonic Acid, i : 2
a C 10 H 6 NH 2 .SO 2 H-.
SOLUBILITY OF EACH IN WATER.
(Dolinski Ber-38, 1836, '05.)
Gms. per 100 Gms. H 2 O.
Gms. per zoojGms. H 2 O.
t.
p Sulphonic
o Sulphonic
t.
p Sulphonic
o Sulphonic
Ac.
Ac.
Ac.
Ac.
O.O27
O.24
50
0.059
0.81
10
O.O29
0.32
60
0-075
I .OI
20
0.031
0-41
70
0.097
I .37
30
0.037
0.52
80
0.130
1. 80
40
0-048
0.65
90
0.175
2 .40
100
0.228
3- J 9
NAPHTHALENE C 10 H 8 .
SOLUBILITY IN METHYL, ETHYL, AND PROPYL ALCOHOLS.
(Speyers Am. J. Sci. [4] 14, 294, '02 ; at 19.5, de Bruyn Z. physik.Chem. 10, 784, '92 ; at 11, Timo
feiew Compt.rend. 112, 1137, '91.)
The original results were calculated to a common basis, plotted on
cross-section paper, and the following table read from the curves.
In Methyl Alcohol.
In Ethyl Alcohol.
In Propyl Alcohol.
f .
W lu f tion CC - I
CH^CH 1 * 5
Wt. of i cc.
Solution.
Gms. CioHg lift nf T re
per 100 Gms . W <L f t ; C '
C 2 H 6 OH. Solution.
Oms* Cxjotig
per 100 Gms.
o
0.8194
3-48
O
8175
5
.0
o
.8285
4
45
10
0.812
5-6
O
.814
7
.0
o
.824
5
.6
20
0.807
8.2
.8lO
9
.8
o
.821
8
.2
25
0.805
9.6
O
.809
ii
3
o
.820
9
.6
30
0.804
II .2
O
.809
13
4
o
.820
ii
4
40
0.805
16.2
O
.812
5
o
.823
16
4
50
0.813
26.O
O
.822
35
.0
837
26
.0
60
0.837
50.0
855
67
.0
o
.867
50
.0
65
0.870
. . .
O
.890
96
.0
o
897
80
.0
70
0.9023 (68)
O
930
179
.0
o
933
J 34
.1 (68
5)
SOLUBILITY OF NAPHTHALENE IN AQUEOUS ACETONE.
(Cady J. Physic. Ch. 2, 168, '98.)
Grams per 100 Grams Solution.
65-5
55-3
45
38
32.2
28.5
28.2
The isotherms for intervals of 10 lie so close together that they
are practically indistinguishable for the greater part of their length.
Acetone.
Water.
Naphthalene.
10.
89.92
O.O5
19.91
8o.O
0.09
29.92
69.67
0.41
40.8l
58.22
0-97
48.67
48.68
2.6 5
57-43
36.64
5-93
60.43
25-75
13.82
207
NAPHTHALENE
SOLUBILITY OP NAPHTHALENE IN:
Chloroform.
(Speyers; Etard.)
Carbon Tetra
Chloride.
Carbon Di
Sulphide.
(Schroder Z. physik. (Arctowski Compt.
Ch. u, 457, '93.) rend, 121, i23,'9s; Etard.)
Wt. of i cc.
Solution.
-108
- 82
~ 50
- 30
10
o
+ 10
20
25
30
40
50
60
70
393
355
.300
.280
255
205
.150
.090
.040
Gms. CioHg per
100 Grams
CHC1 3 .
8-8
15-6
19-5
25-5
31-8
35-5
40.1
49-5
60.3
73-i
87.2
Gms. CioHg per
100 Gms. Sat.
Solution.
9.0
14-0
20-0
23.0
26
35
47
62
80
Gms.
100 Gms. Sat.
Solution.
O.62
I. 3 8
2-3
6.6
14-1
19.9
27-5
36-3
41.0
46.0
57-2
67.6
79.2
po-3
NOTE. Speyers' results upon the solubility of C 10 H 8 in CHC1 3 ,
when calculated to grams per 100 grams of solvent, agree quite well
with Etard's (Ann. chim. phys. [7] 2 570, '94 figures, reported on the
basis of grams C 10 H 8 per 100 grams saturated solution.
Benzene.
SOLUBILITY OP NAPHTHALENE IN:
(Schroder; Etard; Speyers.)
Chlor Benzene. Hexane. Toluene.
Gms. CioHg
Gms. CioHs
Gms. CioH 8
YVf r\{ r r>r>
Gms. C 10 H
t.
per 100 Gms.
Solution.
per 100 Gms.
Solution.
per 100 Gms.
Solution.
wr. 01 i cc
Solution.
per 100 Gms.
QHs.CHa.
-50
o-3
20
1-9
5-5
0.9124
+ 10
27-5
24-0
9.0
0.9126
I 5 .0
2O
36.0
3 I.O
14.0
0-9*35
28.0
25
40-5
35-o
J 7-5
o-9 J 55
36.0
30
45-5
39-o
21 .O
0.9180
42.0
40
54-0
48.0
30.8
0.9250
56.0
50
65.0
57-5
43-7
0-935
69-5
60
77-5
7o-5
60.6
Q-9475
83.0
70
88.0
85.0
78.8
o . 9640
97-5
80
0.9770
in .0
NAPHTHOIC ACID C 10 H 7 COOH.
One liter of aqueous solution contains 0.058 gram C 10 H 7 COOH at
5. (Paul Z. physik. Ch. 14, in, '94.)
ft NAPHTHOL 208
ft NAPHTHOL C 10 H 7 OH.
100 grams H 2 O dissolve 0.105 gram at 25, and 1.33 grams at b. pt.;
100 grams alcohol dissolve 164.0 grams at 25.
NAROEINE.
100 grams pure carbon tetra chloride dissolve o.on gram narceine
at 17. (Schindelmeiser Chem.-Ztg. 25, 129, 'ox.)
NEODYMIUM CHLORIDE NdCl 3 .
100 grams H 2 O dissolve 98.7 grams NdCl 3 at 13, and 140. 4 grams at
IOO . (Matignon Compt. rend. 133, 289, '01 )
NEODYMIUM SULPHATE Nd 2 (SO 4 ) 3 .
SOLUBILITY IN WATER.
(Muthmann and Rolig Ber. 31, 1728, '08.)
Gms. Nd 2 (SO 4 ) 3 per 100 Gms. Gms. Nd 2 (SO^) 3 per 100 Gms.
Solution. Water. Solution. Water.
o 8.7 9.5 50 3.5 3.7
16 6.6 7.1 80 2.6 2.7
30 4.7 5.0 108 2.2 2.3
NICKEL BROMATE Ni(BrO 3 ) 2 .6H 2 O.
loo grams cold water dissolve 27.6 grams nickel bromate.
NICKEL BROMIDE NiBr 2 .
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 539, '94.)
t o G ms.NiBr 2 per t o Gms. NiBr 2 per t <> Gms. NiBr 2 per
loo Gms. Solution. too Gms. Solution. 100 Gms. Solution.
-20 47-7 25 57.3 80 60.6
io 50.5 30 58.0 loo 60.8
o 53.0 40 59 - 1 120 60.9
+ 10 55 -o 50 60.0 140 61 .o
20 56.7 60 60.4
NICKEL CHLORATE Ni(ClO 3 ) 2 .
SOLUBILITY IN WATER.
(Meusser Ber. 35, 1410, '02.)
Gms. Mols. Gms. Mols.
ft0 Ni(ClO 3 ) 2 Ni(ClO 3 ) 2 Solid t <> Ni(ClO 3 ) 2 Ni(ClOs) 2 Solid
' per 100 Gms. per 100 Phase. penooGms. per 100 Phase.
Solution. Mols.H 2 O. Solution. Mols.H 2 O.
18 49-55 7^4 Ni(ClO 3 ) 2 .6H2O 48 67.60 16.65 N(ClOs)f.4HiO
- 8 51.52 8.49 " 55 68.78 17.59
o 52.66 8.88 " 65 69.05 18.01
H-i8 56.74 10.47 " 79-5 75-50 24.68
40 64-47 15-35 M -*3-5 3 r -85 3-73 Ice
9 26.62 2.90
Sp. Gr. of solution saturated at + 18 = 1.661.
20 9
NICKEL CHLORIDE
NICKEL CHLORIDE NiCL.
SOLUBILITY IN WATER.
(Etard; at 12, Ditte Compt. rend. 92, 242, '81.)
t o Gms. NiCl 2 per t Gms. NiCl 2 per t o Cms. NiCfe per
100 Gms. Solution. 100 Gms. Solution. 100 Gms. Solution.
-17
29.7
2 5
40.0
60
45-i
35-o
30
40.8
70
46.0
+ 10
37-3
40
42-3
78
46.6
20
39-i
So
43-9
100
46.7
1000 cc. sat. HC1 solution dissolve 4.0 grams NiCl 2 at 12.
100 grams abs. alcohol dissolve 53.71 grams NiCl 2 .6H 2 O at room
temperature.
100 grams abs. alcohol dissolve 10.05 grams NiCl 2 at room temperature.
(Bodtkcr Z. physik. Chem. 22, 511, '97.)
100 grams abs. alcohol dissolve 2.16 grams NiCl 2 .7H 2 O at 17, and
1.4 grams at 3'
(de Bruyn Rec. trav. chim. n, 156, '92.)
100 grams saturated solution in glycol contain 16.2 grams NiCl 2 at
room temperature. (de Coninck Bui. acad. roy. Belgique, 359, '05.)
NICKEL IODATE
Ni(I0 3 ) 2 .
SOLUBILITY IN WATER.
(Meusser Ber. 34, 2440, f oi.)
Gms. Mols.
Ni(I0 3 ) 2 Ni(I0 3 ) 2 Solid
per 100 Gms. per 100 Mols. Phase.
Ni(IO 3 ) 2 . 4 H 2 O
Ni(I03) 2 .2H 2 (i)
Solution.
H 2 0.
o
o-73
0-033
18
i .01
0.045
3o
1.41
0.063
o
o-53
0.023
18
0.68
0.030
30
0.86
0.039
50
1.78
O.oSo
8
0.52
0.023
Ni(I0 3 ) 2 . 2 H 2 (2)
(i) a Dihydrate.
Gms.
t o Ni(I0 3 ) 2
' per 100 Gms,
Mols.
Ni(IOa)2
, per 100 Mol:
S Solid
Phase.
Solution.
H 2 0.
18
o-55
0-0245
Ni(IO,) 2 .2E
5
0.81
0-035
"
75
1.03
0.045
"
80
I .12
0-049
14
3
I-I35
0.050
Ni(I0 3 ) 8
5
1.07
0-046
"
75
1.02
0.045
"
90
0.988
O.O44
44
(2) /3 Dihydrate.
NICKEL IODIDE
NiI 2 .
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 546, '94.)
f o Gms. NiI 2 per
100 Gms. Solution.
t o Gms. NiI 2 per
100 Gms. Solution
2O
52.0
2 5
60.7
O
55-4
30
61.7
10
57-5
40
63-5
20
59-7
So
64.7
60
70
80
90
Gms. NiI 2 per
100 Gms. Solution.
64.8
65.0
65-2
653
NIOKEL NITRATE
210
NIOKEL NITRATE Ni(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichaastalt, 3, 439, 'oo.)
Gms.
Mols.
o Ni(NO 3 ) 2 Ni(NO 3 ) 2 Solid
per ioo Gms. per 100 Mols. Phase.
Solution. H 2 O.
23
39
.02
6-31
Ni(N0 3 ) 2 . 9 H 2
21
39
.48
6-43
M
10
5 44
13
7-79
"
21
39
94
6-55
Ni(NO 3 ) 2 .6H 2 O
12
5 4 1
59
7.01
"
10
42
.11
7.16
"
6
43
.00
7-44
"
44
32
7.86
"
18
48
59
9-3
"
Cms. Mols.
Ni(N0 3 ) 2 Ni(N0 3 ) 2 Solid
per 100 Gms. per 100 Mols. Phase.
Solution. H 2 O.
Ni(NO 3 ) 2 .6H 2 O
Ni(NO 3 ) 3 .3H 2 O
2O
49-06
9-49
41
55-22
12. 1
56
7 62.76
I6. 7
58
61.61
15-9
60
61.99
16.0
6 4
62.76
16.6
70
6 3-95
17.6
90
70.16
23.1
95
77.12
33-3
100 grams sat. solution in glycol contain 7.5 grams Ni(NO 3 ) at
room temperature. (d e Coninck.)
NICKEL SULPHATE NiSO 4 .
SOLUBILITY IN WATER.
(Steele and Johnson J. Ch. Soc. 85, 116, '04; see also Etard and Mulder.)
Grams NiSO 4 per
t_ ioo Gms.
5
Solution.
20.47
Water. '
25-74
o
21.40
27.22
9
22 .6
30
23-99
27.48
29.99
31-55
37-90
42.46
32-3
33
30-57
3I-38
44-02
45-74
34
31.20
45-5
32-3
30-35
43-57
33-o
34-o
30.25
30-49
43-35
43-83
Solid
Phase.
NiSO 4 .6H 2 O
" (blue)
Transition points, hepta hydrate <= hexa hydrate = 31.5*
Hexa hydrate (blue) + hexa hydrate (green) = 53.3.
Grams NiSO 4 per
t. ioo Gms.
35-6
44-7
Solution.
30-25
30-45
32-45
Water.
43-35
43-79
48.05
50.0
53-o
33-39
34-38
50.15
52-34
54-5
57-o
60
34-43
34-81
35-43
52.50
53-40
54.80
7o
80
99
37-29
38.71
43-42
59-44
63.17
76.71
Solid
NiSO 4 .6H 2 O
4 (blue)
(green)
211
NICKEL SULPHATE
SOLUBILITY OF MIXTURES OF NICKEL SULPHATE AND COPPER SULPHATE.
Results
Gms. per 100
at 35.
Gms. HuO.
^JPMVfc^^* Jvjyai* i^iiu. .
Mol. per cent in Solution.
* J/ y/'j
Mol . per cent in Solid Phase. Crystal
CuS0 4 .
NiS0 4 . '
CuS0 4 .
NiS0 4 .
CuS0 4 .
NiS0 4 . "
Form.
9.62
583-9
I .57
98.43
o-35
99-65
Rhombic
41.66
484.4
7.69
92.31
2 .12
97.88
"
75-39
553-5
11.66
88.34
4-77
95-23
Tetragonal
106.40
506-5
16.92
83.08
6.52
93-48
"
172 .0
483.8
2 5 -63
74-37
13.88
86.17
"
186.9
468.0
27.90
72.10
(18.77
(94.91
81.23
5-09
Tetragonal
Triclinic
Results
at 67.
20.04
729-3
2-65
97-35
o-93
99.07
Monoclinic
66.01
706.2
8-31
91.69
2.86
97.14
"
88.08
501.6
J 3-55
86.45
3-92
96.08
47-94
675.0
16:39
83.61
6.66
93-34
"
249-9
747-8
24.46
75-54
22.32
77-68
{Triclf^ 1 "
SOLUBILITY OF MIXTURES OF NICKEL SULPHATE AND SODIUM SUL-
PHATE, ETC.
(Koppel; Wetzel Z. physik. Chem. 52, 401, '05.)
t.
Gms. per too
Gms. Solution.
Gms. per 100
Gms. H 2 O.
Mols. per 100
Mols. H 2 O. J*>lid
NiS0 4 .
Na 2 S0 4 .
NiS0 4 .
Na 2 S0 4 ."
NiS0 4 .
Na 2 S0 4 . '
O
16
94
7 .6l
22
.46
IO.OQ
2
.61
I
.28 ]
5
17
99
10.85
25
.28
15
.24
2
94
I
!NiS0 4 . 7 H20 +
93 f Na 2 S0 4 .ioH 2 O
10
18
97
I3-85
28
.26
2O
.64
3
.29
2
* * ^ v
.61 J
20
18
76
17.21
29
3i
26
87
3
.410
3
.404 NiNa 2 (S0 4 ) 2 . 4 H 2
25
17
85
16.54
27
33
25
33
3
.l8l
3
.208
30
16
74
J5-34
24
.64
22
58
2
.868
2
.861
35
16
.28
14.91
23
.66
21
-67
2
753
2
744
40
15
35
14.49
21
.88
2O
65
2
546
2
.616
18.5
*9
.61
16.49
30
.70
2 5
.80
3
.56
3
.27 '
20
20
*3
16.15
31
59
25
35
3
.67
3
.21
2 5
21
.20
14.77
33
.11
23
.06
3
85
2
92 NiNa 2 (SO 4 ) 2 . 4 H 2 O -f-
30
22
.60
12.80
34.98
19
.82
4
.07
2
59
35
23
.62
10.78
36
.01
16
43
4
.19
2
.08
40
24
.92
9-39
37
93
14
.29
4
.41
I
.81 J
18.5
16
.80
18.93
26
.14
29
45
3
.04
3
.72 1
20
25
15
10
.48
.92
20.18
24.12
24
16
.06
.81
3i
37
37
13
2
I
.80
.96
3
4
.07 1 NiNa^SO^jMHoO -f
^ NasSO.-ioH^
30
6
.40
28.71
9
.87
44
25
I
X 5
5
.60 J
35
4
54
31-65
7
J 3
49
59
.838
6
28 ) NiNa 2 (S0 4 ) 2 ^H 2 +
40
4
63
31-37
7
.24
49-03
843
6
2I j Na 2 S0 4
NICKEL SULPHATE 212
SOLUBILITY OF NICKEL POTASSIUM SULPHATE NiK 2 (SO 4 ) 2 .6H 2 O IN
WATER.
(Tobler Liebig's Ann. 95. 93. 'SSJ v. Hauer J. pr. Ch. 74, 433, '58.)
Grams NiK 2 (SO 4 ) 2 Grams NiK^SO^a
t o per IPO Gms. H2O. t o per 100 Cms. HaO.
(Tobler.) (v. Hauer.) (Tobler.) (v. Hauer.)'
o 5.3 ... 50 30
10 8.9 60 35.4 20.47
20 13.8 9.53 70 42-0
30 18.6 80 46.0 28.2
40 . 24-0 I4-03
SOLUBILITY OF NICKEL SULPHATE IN METHYL AND ETHYL ALCOHOLS.
(de Bruyn Z. physik. Ch. 10, 783, '92.)
ioo grams abs. ethyl alcohol dissolve 1.3 grams NiSO 4 .7H 2 O at 17.
100 grams abs. methyl alcohol dissolve 46.0 grams NiSO 4 .7H 2 O at
17, and 24.7 grams at 4.
ioo grams abs. methyl alcohol dissolve 0.5 gram NiSO 4 at 18.
ioo grams abs. methyl alcohol dissolve 31.6 grams NiSO 4 .6H 2 O at 17.
ioo grams 93.5% methyl alcohol dissolve 10.1 grams NiSO 4 .7H 2 O at
4, and 7.8 grams NiSO 4 .6H 2 O at 18.
ioo grams 50.0% methyl alcohol dissolve 2.0 grams NiSO 4 .7H 2 O at
4, and 1.9 grams NiSO 4 .6H 2 O at 18.
ioo grams sat. solution in glycol contain 9.7 grams NiSO 4 at room
temperature.
(de Coninck Bull. acad. roy. Belgique 359, '05.)
NICOTINE C 10 H 14 N 2 .
SOLUBILITY IN WATER.
(Hudson Z. physik. Chem. 47, 114, '04.)
Determinations made by Synthetic Method, for which see Note, page
9. Below 60 and above 210 both liquids are miscible in all propor-
tions; likewise with percentages of nicotine less than 6.8 and above 82
per cent the liquid does not show two layers at any temperature.
Below 94 the upper layer is water. Above 94 the upper layer is
nicotine. The curve plotted from the following results makes a com-
plete circle.
in the Mixture.
6.8 94 95
7-8 89 155
10. o 75
14-8 65 200
32.2 61 210
49-o 64 205
66.8 72 190
80.2 87 170
82.0 129 130
2i 3 NITROGEN
NITROGEN N.
SOLUBILITY IN WATER.
iraun Z. physik.
44, 318,
t o " Coefficient of Absorption " ft .
(Winkler Her. 24, 3606, '91; Braun Z. physik. Chem. 33, 732, 'oo; Bohr and Bock Wied. Ann.
44, 318. 'pi-)
0.0235*
o-02 39 t
...t
0.0233*
0.00239'
5
0-0208
0-0215
0.0217
0.0206
0.00259
10
0.0186
0-0196
0-0200
0.0183
0.00230
i5
0-0168
0-0179
0.0179
0.0165
0.00208
2O
0-0154
0-0164
0.0162
0.0151
0.00189
25
0-0143
0-0150
0-0143
0.0139
0.00174
30
0-0134
0-0138
. . .
0.0128
o. 00161
35
0-0125
0.0127
0.0118
0.00148
40
0-0118
0.0118
O-OIIO
0.00139
5
0-0109
0-0106
. . .
0.0096
O-OOI2I
60
O-OIO2
O-OIOO
. . .
0.0082
0.00105
80
0.0096
0.0051
0.00069
100
0-0095
O-OIOO
o.oooo
O-OOOOO
* W. t B. and B. $ B.
For values of J3, ft' t and q, see Ethane, page 133.
SOLUBILITY OF NITROGEN IN AQUEOUS SALT SOLUTIONS.
(Braun.)
Coefficient of Absorption of N in Barium Chloride Solutions of:
t.
13-83
11.92
6.00
3-87
3-33
per cent.
per cent.
per cent.
per cent.
per cent.
5
0.0127
0-0137
0-0160
O-Ol8o
0-0183
10
O.OII7
O.OI25
O-OI47
0.0166
0-01^8
15
O-OIO4
0-OII4
0.0132
0.0148
0-0150
20
O.OO92
0-0098
O-OIlS
0.0132
0.0135
25
0-0078
0-0086
0-0104
O-OII4
O-OII9
Coefficient of Absorption of N in Sodium Chloride Solutions of:
t.
"73
8.14
6.4
2.12
0.67
per cent.
per cent.
per cent.
per cent.
per cent.
5
O-OIO2
0-0127
0.0138
O.OI79
O-O2OO
10
0.0093
0-OII3
O.OI26
0-0164
0.0185
!<;
0-OoSl
O.OIOI
O.OII3
0.0147
0.0164
20
O.OO66
0.0087
0.0098
O.OI3I
0-0148
25
O-OO47
0.0075
0.0083
O.OH3
O.OI3O
SOLUBILITY OF NITROGEN IN ALCOHOL.
(Bunsen.)
t o 5 10 15 20 24
Vols. N * 0.1263 0.1244 0.1228 0.1214 0.1204 0.1198
dissolved by i Vol. Alcohol.
* At o and 760 mm.
NITROQFN
214
SOLUBILITY OF NITROGEN IN MIXTURES OP ALCOHOL AND WATER
AT 2 5 .
(Just Z. physik. Ch. 37, 361, 'ox.)
Results in terms of the Ostwald solubility expression, see page 105,
Vol. H 2 O in Mixture. Vol. Alcohol in Mixture. Dissolved N fa).
100 o 0.01634
80 20 0.01536
67 33 0.01719
o ioo (99 . 8 % Alcohol) o . 1 43 2
SOLUBILITY OF NITROGEN IN SEVERAL SOLVENTS AT 20 AND 25.
(Just.)
Solvent. /25- ^20-
Toluene 0.1235 o. 1186
Chloroform 0.1348 0.1282
Methyl Alcohol o. 1415 o. 1348
Ethyl Alcohol (99.8%) o. 1432 o. 1400
Acetone o. 1460 o. 1383
Amyl Acetate 0.1542 0.1512
Ethyl Acetate o. 1727 o. 1678
Iso Butyl Acetate 0.1734 0.1701
Solvent.
Water
Aniline
Sulphur Dioxide
Nitro Benzene
Benzene
Acetic Acid
Xylene
Amyl Alcohol
b.
0.01634
0.03074
0.05860
0.06255
0.1159
o. 1190
o. 1217
0.1225
fe.
0.01705
0.02992
0.05290
0.06082
0.1114
0.1172
o. 1185
o. 1208
SOLUBILITY OF NITROGEN IN PETROLEUM. COEFFICIENT OF ABSORP-
TION AT 10 = 0.135, AT 20 = O.II7.
(Gniewasz and Walfisz Z. physik. Ch. i, 70, '87 )
SOLUBILITY OF NITROGEN IN AQUEOUS PROPIONIC ACID AND UREA
SOLUTIONS.
(Braun.)
Coefficient of Absorption of N in C 2 H 6 COOH Solutions of:
fc .
11.22
per cent.
9.54 per cent.
6.07
per cent.
4.08
per cent.
3-82
per cent.
5
10
I 5
20
o.
o.
o.
o.
0195
0178
0159
0146
O
O
O
.O2O4
.0182
.0163
.0147
O
O
o
o
.0208
.0186
.0164
.0148
O
O
o
.0210
.OI92
.0169
.0154
o
.O2O9
0191
.0167
o I 55
25
o.
0130
.0134
o
.0134
o
.0137
o
.0137
Coefficient of Absorption of N in CO(NH 2 ) 2 Solutions of:
* .
15.65 percent.
1 1 .9 per cent .
9. 4 2 per cent.
6.90 per cent.
5.15 per cent.
2 .28 per cent .
5
10
'5
20
0.0175
O.Ol62
O.OI5O
O.OI4O
O.OI79
0-0167
O.OI49
0.0139
O.OI9O
0.0176
0-0158
O.OI46
0.0198
0.0183
0.0165
O.OI5I
0.0197
O.Ol82
0.0165
O.OI5I
O.OI99
0-0184
O.OI7I
0.0155
25
0.0130
O.OI30
0.0133
0.0137
0.0135
0.0139
215 NITROUS OXIDE
NITROUS OXIDE N 2 CX
SOLUBILITY IN WATER.
(Bunsen; Gordon Z. physik. Ch. 18, 9, '95; Roth Ibid. 24, 123, '97; Knopp Ibid. 48,106, '04
Geffcken Ibid. 49, 276, '04.)
Coefficient of Absorption ft.
t.
(B.)
(G.)
(R.)
(K.)
9
CR.)
(K.)
(G.)
5
1.0950
1-0955
i .1403
0.205
i .161
I .067
10
0.9196
0.9200
0.9479
. . .
0.171
0.9815
0.9101
15
0.7778
0.7787
0.7896
0.143
0-8315
0.7784
20
o . 6700
0.6700
0.6654
0.6270
O.I2I
o 7131
0.6739
0.6756
2 5
0.5961
...
-575 2
0.104
0.6281
0.5992
* Calculated by Geffcken.
NOTE. Knopp and also Geffcken call attention to the fact thsfct
Roth in making his determinations used a rubber tube between the
gas burette and the shaking flask, and give this as an explanation of
the high results which he obtained.
SOLUBILITY OF NITROUS OXIDE IN AQUEOUS SULPHURIC ACID.
(Lunge Ber. 14, 2188, '81; see also Geffcken 's results.)
Sp. Gr. of H 2 SO 4 i .84 i .80 i .705 i .45 i .25
Vols. N 2 O dissolved
by 100 vols. H 2 SO 4 75-7 66.0 39.1 41.6 33 -o
100 vols. of KOH solution of 1.12 Sp. Gr. absorb 18.7 vols. N 2 O.
100 vols. of NaOH solution of i.io Sp. Gr. absorb 23.1 vols. N 2 O.
SOLUBILITY OF NITROUS OXIDE IN AQUEOUS SOLUTIONS OF ACIDS.
(Geffcken.)
Results in terms of the Ostwald Solubility Expression (/). See p. 105,
In Hydrochloric Acid. In Nitric Acid. In Sulphuric Acid.
Cms. HC1
N 2 O Dissolved
Gms.HNOa N 2 O Dissolved
Gms. H 2 SO* N zO Dissolved
per Liter.
,
b.
/ 25 . ' per Liter. ' / 15 .
/25-
per Liter. / 15 .
/PS-"
18.22
0.
755
0-577
36.
52
0.777
0-597
2 4 .
52
0.734
0.566
36.45
O.
738
0.568
63-
05
0.777
0.602
49-
04
0.699
o-543
72.90
0.
716
0-557
126.
10
0-775
0.611
98.
08
0.645
0.509
147-
12
0.602
0.482
196.
16
0.562
0.463
SOLUBILITY OF NITROUS OXIDE IN AQUEOUS SOLUTIONS OF:
(Roth.)
Phosphoric Acid. Oxalic Acid.
t
Coefficient of ADS. in H 3 PO 4 Solutions of:
Coefficient of Abs. in
(COOH)2jolutions of:
3-38%.
4-72%.
8.84%.
9.89%.
13.35%.
0.812%.
3.70%.
5
1-057
I
0365
.9883
o
9635
0.9171
I
.1450
1.1094
10
0.8827
.8665
.8296
.8101
0.7711
.9526
0.9264
15
0-7388
7258
.6977
.6826
0.6505
O
.7940
0.7745
20
0.6253
.6147
.5926
.5810
0-5555
o
.6694
0.6538
25
0.5427
5329
5*43
5054
o . 4860
o
5784
0-5643
NITROUS OXIDE
216
SOLUBILITY OF NITROUS OXIDE IN AQUEOUS SOLUTIONS OF PROPIONIC
ACID AT 20.
(Knopp.)
Gms. C 2 H 6 COOH
per liter 15 .15 60.42
Coef. of Absorp-
tion of N 2 O 0.6323 0.6369
158.4 176.6 344.0
0.6504 0.6534 0.7219
SOLUBILITY OF NITROUS OXIDE IN AQUEOUS SALT SOLUTIONS.
Results by Geffcken
page 105.
Salt.
Ammonium Chloride
Ammonium Chloride
Caesium Chloride
Lithium Chloride
Lithium Chloride
Potassium Bromide
Potassium Bromide
Potassium Chloride
Potassium Chloride
Potassium Iodide
Potassium Iodide
Potassium Hydroxide
Potassium Hydroxide
Rubidium Chloride
Rubidium Chloride
in terms of the Ostwald expression (/). See
Fnrrrmli
Cone, of Salt per Liter.
Solubility of N 2 O.
l* ormuia, *
Gram Equiv.
Grams.
/IS-
/26-
NH 4 C1
o-S
26.76
0.730
0-557
NH 4 C1
I .0
53-5 2
O.69I
0.529
CsCl
o-5
84.17
0.710
0-544
LiCl
o-5
21 .24
0.697
o-535
LiCl
i.o
42.48
0.623
0.483
KBr
o-5
59-55
0.697
o-53 6
KBr
i .0
119.11
0.627
0.485
KC1
o-5
37-3
0.686
0.527
KC1
i .0
74.6
0.616
o-475
KI
o-5
83.06
0.702
0.541
KI
I.O
166.12
0-633
0.492
KOH
o-5
28.08
0.668
0.514
KOH
I .0
56.16
o-559
0.436
RbCl
o-S
60.47
0.695
o-533
RbCl
i .0
120.95
0.625
0.483
Results by Knopp, in terms of the coefficient of absorption. See
page 105.
Salt.
Formula.
Potassium Nitrate KNO,
Sodium Nitrate
NaNO
Cone, of Salt
per Liter.
Coef. of Absorption
Normality.
Grams.
of N 2 O at 20.
0.1061
10-74
0.6173
0.2764
27.94
0.6002
0.5630
56-97
0-57I3
1.1683
118.2
0-5196
0.1336
n-37
0.6089
0.3052
25-97
0.5876
0.6286
53-50
0.5465
1. 1200
95-30
0.4926
Results by Roth, in terms of the coefficient of absorption.
Grams NaCl per
100 Grams
Solution.
o-99
1. 808
3.886
5-865
Coefficient of Absorption of N 2 O at:
A
5.
I .0609
1.0032
0.9I3I
0.8428
10. 15. 20.
0.8812 0.7339 0.6191
0.8383 0.7026 0.5962
0.7699 0.6495 0.5520
0.7090 0.5976 0.5088
25.
0.5363
0.5190
0-4475
0.4224
2i 7 NITROUS OXIDE
SOLUBILITY OF NITROUS OXIDE IN AQUEOUS SALT SOLUTIONS.
Results by Gordon in terms of coefficient of absorption. See p. 105.
Concentration of Salt. Coefficient of Absorption of N 2 O at:
Salt. Grams per Gram
100 Grams Mols. 5. 10. 15.
Solution. per Liter.
Calcium Chloride 5-79 -547 0.819 0.697 0.591 0.500
9.86 0.964 0.668 0.586 0.509 0.435
" J 3-99 1-416 0.510 0.441 0.380 0.328
Lithium Chloride 1.35 0.319 0.986 0.831 0.700 0.594
" 3.85 0.928 0.878 0.743 0.629 0.536
11.48 2.883 0.606 0.512 0.437 0.382
Lithium Sulphate 2.37 0.219 0.934 0.792 0.670 0.569
5.46 0.521 0.795 0.665 0.557 0.474
8.56 0.836 0-646 0.555 0.477 0.415
Magnesium Sulphate 5.90 0.521 0.766 0.664 0.561 0.471
7.66 0.687 0.708 0.586 0.488 0.414
10.78 0.997 0.569 0.491 0.417 0.346
Potassium Chloride 4.90 0.676 0.879 0.751 0.643 0.555
7.64 1.037 o-799 0-693 0591 0.494
" 14-58 2.147 0.654 0.574 0.500 0.430
22.08 3.414 0.544 0.459 0.390 0.339
Potassium Sulphate 2.62 0.154 0.986 0.831 0.701 0.605
" 4.78 0.285 0.918 0.763 0.637 0.542
Sodium Chloride 6.20 1.107 0.800 0.682 0.585 0.509
8.88 1.614 -7 I 3 0-603 0.510 0.434
12.78 2.391 0.634 0.532 0.449 0.386
Sodium Sulphate 5.76 0.427 0.808 0.677 0.584 0.495
8-53 0.646 0.692 0.574 0.482 0.416
" 12.44 0.974 0.559 0.486 0.417 0.354
Strontium Chloride 3.31 0.215 0.928 0.788 0.671 0.578
5.73 0.380 0.848 0.709 0.610 0.550
13.24 0.939 0.644 0.547 0.463 0.390
SOLUBILITY OF NITROUS OXIDE IN ALCOHOL AND IN AQUEOUS CHLORAL
HYDRATE SOLUTIONS AT 20.
(Bunsen; Knopp Z. physik. Ch. 48, 106, '04.)
In Alcohol (B.). In Aq. Chloral Hydrate (K.).
Vols. N 2
t . (at o and 760 mm .)
peri Vol. Alcohol.
Normality
C 2 HCl3O.H 2 0.
Cms.
C 2 HC1 3 O.H 2 O
per Liter.
Coef . of
Abs. of NaO.
O
4.178
0.184
30-43
0.618
5
3-844
0-445
73.60
0-613
IO
3-541
0.942
155-8
0-596
15
3.268
1 .165
192.7
0.589
20
3-025
1.474
243-8
0-579
24
2.853
1 .911
316.4
0.567
SOLUBILITY OF NITROUS OXIDE IN PETROLEUM. COEFFICIENT OF
ABSORPTION AT 10 = 2.49, AT 20 = 2.11.
(Gniewasz and WaJfisz Z. physik. Ch. I, 70, '87.)
NITROUS OXIDE
218
SOLUBILITY OF NITROUS OXIDE IN AQUEOUS SOLUTIONS OF GLYCERINE
AND OF UREA.
(Roth.)
Coefficient of Absorption of N2O in Glycerine Solutions of:
t .
5
10
r 5
20
25
3.46 per cent. 6.73 per cent. 12.12 per cent. 16.24 per cent.
1.097 1-055 0-999 0.959
0.917 0.887 0.841 0.810
0.767 0.745 0.710 0.686
0.647 0.630 0.605 0.585
0.556 0.542 0.527 0.508
Coefficient of Absorption of N 2 O in Urea Solutions of:
3.31 per cent. 4.97 per cent. 6.37 per cent. 7.30 per cent
5 1.104 1.096 i. 088 i.ioi
10 0.921 0.920 0.909 0.921
15 0.771 0.773 0-76I 0.772
20 0.653 0.656 0.644 0.655
25 0.569 0.567 0-559 0.570
NITRIC OXIDE NO.
SOLUBILITY IN WATER.
(Winkler Ber. 34, I4T4, '01.)
9.97 per cent.
I .069
0.901
0.761
0.651
0.569
t.
ft
P'.
9-
t.
ft.
r.
7-
O
.0738
0734
0-00984
40
035 1
0325
O.OO4
5
.0646
.0641
O.OO86O
50
o
0315
.0277
O.OO3
10
0571
.0564
0.00757
60
.0295
0237
0.003
15
o
0515
.0506
O.OO68O
70
.0281
.0195
O.OO2
20
.0471
.0460
0.0o6l8
80
.0270
.0144
O-OOI
25
o
.0430
.0419
0-00564
90
.0265
.0082
0.001
30
.0400
.0384
O.OO5I7
100
.0263
OOOO
o.ooo
For values oi ft, ft' and q, see Ethane, page 133.
SOLUBILITY OF NITRIC OXIDE IN AQUEOUS SULPHURIC ACID
SOLUTIONS AT 18.
(Lunge Ber. 18, 1391, '85; Tower Z. anorg. Ch. 50, 382, '06.)
Wt. per cent H 2 SO 4
in Solution.
9 8
90
80
70
60
SO
Sp. Gr.
at 15.
1.8 4
1.82
i-733
1.616
1 399
Tension of
H 2 O Vapor.
o.i mm.
0.4 "
6.2
Solubility Coefficient *
of NO at 18.
0.0227 (0.035, L.)
0.0193
O.OII7
O.OII3
0.0118 (0.017, L.
O.OI2O
* Volume of NO (at 760 mm.) per i volume of aqueous H 2 SO 4 .
SOLUBILITY OF NITRIC OXIDE IN ALCOHOL.
(Bunsen.)
t o 5 10 15 20
Vols. NO* 0.316 0.300 0.286 0.275 0.266
absorbed by i vol. Ale.
24
0.261
* At o and 760 mm.
2i 9 OXALIC ACID
OXALIC ACID (COOH) 2 . 2 H 2 O.
SOLUBILITY IN WATER.
(Average curve from results of Alluard; Miczynski Monatsh. Ch. 7, 258, '86; Henry Compt. rend.
9 H57 '84; Lamouroux Ibid. 128, 998, 'oo; at 25, Foote and Andrew
Am. Ch. J. 34, 154, '05.)
Grams (COOH) 2 per 100 Grams ^ Grams (COOH) 2 per 100 Grams
H 2 O. Solution. H 2 O. Solution.
o 3-45 3-33 40 21.15 17.46
10 5-55 5-26 50 31-53 23.97
20 8.78 8.07 60 45.55 31-37
25 II-36 10.21 70 63.82 38.95
30 13-77 II -9 I
SOLUBILITY OF OXALIC ACID IN ALCOHOLS.
(Timofeiew Compt. rend. 112, 1137, '91; Bourgoin Ann. chim. phys. [5] 13, 406, '78).
Grams (COOH) 2 per 100 Grams of:
Methyl Alcohol. Ethyl Alcohol. Propyl Alcohol.
i 36.26 20.25 9-73
+ 20 47-24 26.23 I5-I4
SOLUBILITY OF OXALIC ACID IN ABSOLUTE AND IN AQ. ETHER AT 25.
(Bodtker Z. physik. Ch. 22, 512, '97; Bourgoin.)
ioo grams absolute ether dissolve 1.47 grams (COOH) 2 .2H 2 O.
100 grams absolute ether dissolve 23.59 grams (COOH) 2 .
In Aqueous Ether Solutions.
Gms. Solid Acid Added per ioo cc. Ether Solution. Grams per ioo cc. Ether Solution.
(COOH) 2 . 2 H 2 O. (COOH) 2 . H 2 O. (COOH) 2 .
(1) 5.0 o.o 1-250 0.742
(2) 5.0 o.o 0.788 0.720
5.0 o.o 0.418 1.044
S-o 2.44 0.360 3.388
5.0 4.82 0.484 6.038
5-o 7-i4 0.558 8.538
5.0 9.42 0.632 10.996
5.0 11.63 0.676 13-316
5.0 13.79 0.761 15-684
5.0 18.18 0.816 17.818
5.0 22.73 0.816 17.818
(i) Ether saturated with water. (2) Ether containing 0.694 per cent water.
ioo grams glycerine dissolve 15 grams oxalic acid at 15.5.
DISTRIBUTION OF OXALIC ACID BETWEEN WATER AND AMYL ALCOHOL
AT 20.
(Herz and Fischer Ber. 37. 4748, '04.)
Millimols i(COOH) 2 per 10 cc. Grams (COOH) a per ioo cc.
Aq. Layer.
Alcoholic Layer.
Aq. Layer.
Alcoholic Layer.
o.68c6
O.I45I
0.306
0.0653
2.364
0.7233
1.064
0.320
6.699
2-550
3-015
I.I48
10.029
4.300
4-5"
1-934
OXYGEN 220
OXYGEN O. SOLUBILITY IN WATER.
(Winkler Ber. 34, 3609, '91; Bohr and Bock Wied. Ann. [2] 44. 318, '91.)
t. Coef. of Absorpdon /3. 9>
cc. O per
Liter HzO.
10.187
8.907
7.873
7.038
6.356
5.776
5.255 1
tB
t. Coef. of Absorpdon ft. ?<
O
5
10
15
20
25
30
0.0489*
0.0429
0.0380
0.0342
O.O3IO
0.0283
O.O26l
0.0496!
0.0439
0.0390
0.0350
0.0317
O.029O
0.0268
0.00695
0.00607
0.00537
0.00480
0.00434
0.00393
0.00359
*W.
40 o.
50 o.
60 o.
70 o.
80 o.
90 o.
:oo o.
. and B.
0231*
0209
0195
0183
0176
0172
0170
0.0233!
O.O207
0.0189
0.0178
O.OI72
0.0169
0.0168
o.
o.
0.
0.
0.
0.
o.
00308
00266
00227
00186
00138
00079
ooooo
For values of ft and q see Ethane, page 133.
SOLUBILITY OF THE OXYGEN OF AIR IN WATER.
t. 5.2 5-65 14-78 24.8
Solubility* 8.856 8.744 7.08 5.762
* cc. Oxygen per 1000 cc. H 2 O saturated with air at 760 mm.
SOLUBILITY OF OXYGEN IN WATER AND IN AQUEOUS SOLUTIONS OF
ACIDS, BASES AND SALTS.
(Geffcken Z. physik. Ch. 49, 269, '04.)
Aq. Solution of:
Concentration per Liter.
Solubility of
Oxygen.*
Gram Equiv. Grams.
/ 15 .
/26-
Water alone
... ...
0-0363
0.0308
Hydrochloric Acid
0-5 18.22
0.0344
O.O296
"
i -o 36-45
0.0327
0.0287
"
2.0 72.90
O.O299
0.0267
Nitric Acid
-5 36-52
0.0348
O.O3O2
u
i.o 63.05
0.0336
0.0295
(I
2.O I26.IO
0-0315
O.0284
Sulphuric Acid
0.5 24.52
0-0338
0.0288
"
i.o 49-04
0.0319
0.0275
"
2.0 98.08
0-0335
O.O25I
"
3-o i47- I 2
0.0256
O.O229
"
4.0 196.16
0.0233
0.0209
5.0 245.20
0.0231
O.OI94
Potassium Hydroxide
0.5 28.08
O.O29I
O.O252
"
i.o 56.16
0.0234
O.O2O6
Sodium Hydroxide
0.5 20.03
0.0288
O.O250
"
i.o 40.06
0.0231
O.O2O4
"
2.0 80. I 2
O.OI52
0.0133
Potassium Sulphate
o-5 43-59
0.0294
0,0253
"
i.o 87.18
0.0237
O.O2O7
Sodium Chloride
o-5 29.25
O.O262
n
i.o 58.5
O.O26o
O.O223
u
2.0 H9.0
0.0182
O.OI58
* In terms of the Ostwald Solubility Expressions
. See page 105
SOLUBILITY OF OXYGEN IN AQ. POTASSIUM CYANIDE SOLUTIONS AT 20.
(Maclaurin J. Ch. Soc 63, 737, '93.)
Cms. KCN per 100 gms. sol. i 10 20 30 50
Coefficient of absorption of O 0.029 0.018 0.013 0.008 0.003
221 OXYGEN
SOLUBILITY OF OXYGEN IN ETHYL ALCOHOL, METHYL ALCOHOL AND
IN ACETONE.
(Timofejew Z. physik. Ch. 6, 151, '90; Levi Gazz. chim. ital. 31, II, 513, 'ox.)
t0 In Ethyl Alcohol of 99.7% (T.). Atohofci'!) In Acetone (L.)
P fj / =
o 0.2337 0.2297 0.31864 0.2997
5 0.2301 0.2247 0.30506 0.2835
10 0.2266 0.2194 0.29005 0.2667
15 0.2232 0.2137 0.27361 0.2493
20 0.2201 0.2073 0.25574 0.2313
25 0.2177 (24) 0.2017 (24) 0.23642 0.2127
30 ... 0.21569 0.1935
40 ... ... 0.16990 0.1533
50 ... ... 0.11840 0.1057
For values of /3 and p', see Ethane, page 133. / Ostwald Solu-
bility Expression. Seepage 105.
The formulae expressing the solubility of oxygen in methyl alcohol
and in acetone as shown in the above table are as follows:
In Methyl Alcohol / = 0.31864 0.002572 t 0.00002866 1*.
In Acetone /= 0.2997 0.00318* 0.000012**.
SOLUBILITY OF OXYGEN IN AQUEOUS ALCOHOL AT 20 AND 760 MM.
(Lubarsch Wied. Ann. [2] 37. 5S. '89.)
yss!*
Vol. per cent
Absorbed O.
Wt. per cent
Alcohol.
Vol. per cent
Absorbed O.
Wt. per cent
Alcohol.
Vol. per cent
Absorbed O.
o.oo
9.09
16.67
2.98
2.78
2.63
23.08
28.57
33-33
2.52
2-49
2.6 7
50.0
66.67
8o.O
3-50
4-95
5.66
SOLUBILITY OF OXYGEN IN PETROLEUM. COEFFICIENT OF ABSORP-
TION AT 10 = 0.229, AT 20 = 0.202.
(Gniewasz and Walfisz Z. physik. Ch. I, 70, '87.)
OZONE O,.
SOLUBILITY IN WATER.
(von Mailfert Compt. rend. H9t 051, W. Carius; Schone Ber. 6, 1194, '73.)
t. W. G. R. t*. W. G. R.
o 39.4 61.5 0.641 27 13.9 51.4 0.270
6 34.3 61.0 0.562 33 7.7 39.5 0.195
ii. 8 29.9 59.6 0.500 40 4.2 37.6 0.112
13.0 28.0 58.1 0.482 47 2.4 31.2 0.077
15-0 25.9 56.8 0.456 55 - 6 J 9-3 0-Q3 1
19.0 21. o 55-2 0.381 60 o.o 12.3 o.ooo
W Milligrams Ozone dissolved per liter water. G Milligrams
Ozone in one liter of the gas phase above the solutions. R = Ratio
of the dissolved to undissolved Ozone ( W -3- G) .
PARAFFINE
222
SOLUBILITY OF OZOKERITE PARAFFINE OF MELTING POINT 64-6s (
AND SP. GR. AT 20 = 0.917 IN SEVERAL SOLVENTS AT 2O.
(Pawlewski and Filemonowicz Ber. 21, 2973, ' 88 -)
Solvent.
Carbon Bisulphide
Benzine, boiling below 75
Turpentine, b.pt. i58-i66
Cumol, com. b.pt. 160
" frac. 150-! 60
Xylene, com.b.pt. 135-
" frac. i35-i38
Toluene, com.b.pt. io8-i 10
" frac. io8-io9
Chloroform
Benzene
Ethyl Ether
Iso Butyl Alcohol, com.
Gms. Paraffine per 100
Gms.
cc.
Solvent.
Solvent.
Solvent.
12.99
Acetone
' 11-73
8] 4 8
Ethyl Acetate
3 6.06
5-21
" Alcohol
4.26
3-7 2
Amyl Alcohol
3-99
3 3-95
3-39
3-43
Propionic Acid
Propyl Alcohol
4-39
3-77
Methyl Alcohol
10 3.88
3-34
Methyl Formate
3-92
2.42
3-4i
3.61
Acetic Acid
" Anhydride
1.99
J -75
Formic Acid
Ethyl Alcohol 75%
Gms.Paraffine per TOO
0.285 0.228
Gms.
cc.
Solvent.
Solvent.
o. 262
o. 209
0.238
o. 219
O. 2O2
o. 164
0.165
o. 141
O.O7I
0.056
O.O60
O.O6O
0.063
O.O25
0.013
o. 015
o. 0003
PAPAVERINE C 20 H 21 N0 4 .
100 grams pure carbon tetra chloride dissolve 0.203 gram at 17.
(Schindelmeiser Chem.-Ztg. 25, 129, '01.)
PHENANTHRENE C 14 H 10 .
SOLUBILITY IN ALCOHOL AND IN TOLUENE.*
(Speyers Am. J. Sci. [4] 14, 295, '02.)
In Alcohol. In Toluene.
t
Gms. CuHio pe
100 Grams
r Sp. Gr. of
Solutions
Gms. Ci 4 Hi per
100 Grams
Sp. Gr. of
Solutions
CjjHsOH.
(H20 at 4 .)
C 6 H 6 .CH3
(H 2 at 4-)
o
3-65
0.8l4
23.0
0.925
10
3 .80
0-807
30-0
0.929
20
4-6
O.Soi
42 .O
0-934
25
5-5
o-799
5-
0-939
30
6.4
0-797
5 8.0
0-943
40
8.2
o-795
76.0
o-955
50
10.6
o-794
95-o
0.971
60
15-6
0-797
115.0
0.989
70
0.815
135 .0
i .007
80
0.865 (76.
4) ISS-O
1.027
* Calculated from the original results which are given in terms of gram molecules of Phenanthrene
per 100 gram molecules of solvent, and for irregular intervals of temperature.
Behrend Z. physik. Ch. 10, 265, '92, finds 2.77 grams phenan-
threne per 100 grams alcohol at 12.3, and 3.09 grams at 14.8.
223 PHENANTHRENE
SOLUBILITY OF PHENANTHRENE PICRATE IN ABSOLUTE ALCOHOL.
(Behrend Z. physik. Ch. 10, 205, '92.)
Grams per 100 Grams Saturated Solution.
,
Picric Acid H
h Phenanthrene =
Phenanthrene Picrate.
12-3
0.91
0.71
1.62
14-3
1. 00
0.78
1.78
17-5
1.05
0.82
1.87
SOLUBILITY OF PHENANTHRENE PICRATE IN ALCOHOLIC SOLUTIONS
CONTAINING PICRIC ACID AND ALSO PHENANTHRENE.
(Behrend.)
Grams Added to 62 cc. Abs. Alcohol. Gms. per 100 Cms. Sat. Solution.
P. Picrate + Picric Ac. -j- Phenanthrene.
Picric Ac. + Phenanthrene
P. Picrate.
12-3
1.4
o
o-5
o-534
1-413
1-947
12-3
1.4
0.9
0.409
2.141
2 -550
12.3
0.8
o
2.1
o-354
2.77
3.124
I2. 3
0.8
4-0
0.139
5.626
5-765
17-5
1.4
O.I
I - I 59
o-75
I.9I
17-5
1.4
0.2
O
1.285
0.68
1.97
17-5
1.4
1.0
o
2-45
o-37
2.82
J 7-5
1.4
4.0
6.15
0.195
6-345
17-5
1.4
0-0
2.2
0.423
3.276
3- 6 99
PHENOL C 6 H 5 OH.
SOLUBILITY IN WATER.
(Alexejew Wied. Ann. 28, 305, '86; Schreinemaker Z. physik. Ch. 33, 79, 'oo; Rothmund Ibid
26, 474. '98-)
Determinations were made by the " Synthetic Method," for which
see Note, page 9.
Grams Phenol per 100 Grams
10
20
30
40
50
55
60
65
68.3 (crit. temp.) 33.4
Vaubel J. pr. Ch. [2] 62, 73, '95, states that 100 grams sat. aque-
rus solution contain 6.1 grams phenol at 20. Sp. Gr. of solution
1.0057.
SOLUBILITY OF PHENIC ACID (PHENOL, C 6 H 5 OH) IN PARAFPINE
AND IN BENZENE.
(Schweissinger Pharm. Ztg. '84-'8s.)
Grams CaH 5 OH per 100 Grams Solvent at:
Solvent. f *- >
16. 21. 25. 43.
Paraffine 1.66 ... ... 5.0
Benzene 2.5 8.33 10.0 100.0
Aqueous Layer.
Phenol
Layer.
7-5
75
.0
8-3
72
.1
8.8
6 9
.8
9.6
66
9
12.0
62
7
I4-I
59
5
I6. 7
55
4
21-9
49
.2
PHENOL
224
SOLUBILITY OF PHENOL IN AQUEOUS ACETONE SOLUTIONS.
(Schreinemaker.)
In 4.24 %
Acetone.
In 12.2%
Acetone.
In 24.4%
Acetone.
Grams Phenol per
Gms. Phenol per
Gms. Phenol per
to
ioo Gms.
ioo Gms
ioo Gms.
.
Aq. Acetone
Phenol
Aq . Acetone
Phenol
Aq. Acetone
Phenol
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
20
.
...
. .
. . .
3
5.0
74.0
4.0
71.0
6.0
69.5
40
5-5
70.0
5
60
1.1
67.0
61.0
5 :
67.0
8.0
64.0
70
9.0
51.0
7-5
57-5
19.0
57-
80
14.0
34-0
10.5
49-5
14.0
52-5
(84) 22.5
20. 4*
30-5*
23- of
47. ot
(90. 3) 25-0
26. 5t
44.0$
(9- 5) 35-
o
go
t8 5
t87.s
45
In 59-9%
Acetone.
Gms. Phenol per
ioo Gms.
Aq . Acetone Phenol
Layer. Layer
26. O 60. 5
28.5 57.0
32.0 52.0
34.5$ 49- c
36.511 46.50
(49.5) 41.5
!l47.S
The figures in the above table were read from curves plotted from
the original results.
SOLUBILITY OF PHENOL IN AQUEOUS SOLUTIONS d TARTARIC ACID.
(Schreinemaker.)
In 5.093% Acid.
Gms. Phenol per ioo Gms.
In 19.34% Acid.
Gms. Phenol per ioo Gms.
In 40.9% Acid.
Gms.Phenol per ioo Gms.
Aq. Acid Phenol ~~
Layer. Layer.
13.0
16.5 77.0
20.0 74.0
26.5 71.0
39-o 63.5
54-0
30
50
60
65
I 7 ' 5
69
Aq. Acid
Layer.
7-5
10.5
i4.5
19-5
25.0
47-
Phenol
Layer.
72.5
65.5
58.0
48.5
5
60
70
75
77
Aq. Acid
Layer.
10.
12-5
19.0
29.0
47.0
Phenol
Layer.
77.0
72.0
64.0
56.0
70
80
85
90
95
97
DISTRIBUTION OF PHENOL BETWEEN:
AMYL ALCOHOL AND WATER AT 25.
(Herz and Fischer Ber. 37, 4747, '04.)
Millimols Phenol
per lo cc.
Gms. Phenol
per ioo cc.
Volumes of Solvents
Alcoholic Aqueous
Layer. Layer.
Alcoholic Aqueous
Layer. Layer.
used per
i Gm. Phenol
o. 75 o. 047
o. 705 o. 0441
5occ.H 2 O+ 5occ.C a I
0.9 0.05
o. 846 o. 047
" +IOOCC. "
i.i 0.07
1.035 0.066
" +15000. "
2. 6 o. 16
2.445 - X 5
" +200CC.
54- r 3.83
50.88 3.601
5 6 -3 3-9
52.93 3.667
BENZENE AND WATER AT 2oc
(Vaubel J. pr. Ch. [2] 67. 476. V 3.)
Gms. Phenol in-
'H 2 CeHo '
Layer. Layer
O. 286 o. 714
o. 1188 0.8212
0.0893 0.9107
0.0893 0.9107
22 5
PHENOL
DISTRIBUTION OP PHENOL BETWEEN WATER AND BENZENE AND
BETWEEN AQUEOUS K 2 SO 4 SOLUTIONS AND BENZENE AT 25.
(Rothmund and Wilsmore Z. physik. Ch. 40, 623, '02.)
NOTE. The original results, which are given in terms of gram
mols. per liter, were calculated to grams per liter, and plotted on cross-
section paper. The following figures were read from the curves
obtained.
Between H 2 O and CaHa.
Effect of K 2 SO 4 upon the Distribution.
Grams C
WHsOH
Cms. K 2 SO 4
(i) Cms. CsHsOH
(a)Gms. CH 6 OH
per Liter of:
per Liter
per Liter of:
per Liter of:
fi,0
Layer.
CeH,
Layer.
Aq.
Solution.
Aq.
Layer.
Layer.
Aq.
Layer.
Layer.
5
10
1.36
17.08
59-96
9-52
26.28
10
28
2.72
16.92
60.63
9-50
26.38
15
52
5-44
16.85
60.92
9.46
26.55
20
84
10.89
16.44
62.73
9-35
27.06
25
128
21.79
15.89
65.19
9.09
28.27
30
200
43-59
14-85
69.71
8.68
30.21
35
300
87.18
12.92
78.00
7-79
34.38
40
410
45
520
50
610
(i) First series.
(*)
Second series.
DISTRIBUTION OF PHENOL AT 25 BETWEEN:
(Herz and Fischer Ber. 38, 1143, '05.)
Water and Toluene.
Water and m Xylene.
Millimols Cel^OR
per 10 cc.
Grams CeHsOH
per TOO cc.
Millimols CftHsOH
per 10 cc.
Grams QjHeOH
per 100 cc_
C 8 H,CH 3
Layer.
H 2 O
Layer.
CH 5 CH3
Layer.
H 2 O
Layer.
'*%
ELXCHg)
ayer.
t H 2 0*
Layer.
mCH4(CH3)
Layer.
2 H 2 0'
Layer.
1.244
0.724
I
.169
0.681
I
6lO
I
.071
I
5 J 4
1.007
3-047
1.469
2
.865
1.381
4
.787
2
.726
4
.501
2-563
4.667
2.2OO
4
.389
2.068
12
.210
5
.168
II
.22
4.860
6.446
2.861
6
.061
2 .691
22
.718
6
994
21
36
6-577
14.960
4-750
14
07
4.467
34
.827
8
.124
32
75
7.640
I7-725
5-346
16
.69
5.027
5 1
352
9
.123
4 8
.28
8.578
47-003
7.706
44
.20
7.246
77
703
10
.050
73
.07
9-450
53 -783
8.087
50
58
7.604
90.287
9.651
84
.89
9.074
DISTRIBUTION OF PHENOL BETWEEN WATER AND CARBON TETRA
CHLORIDE AT 20.
(Vaubel J. pr. Ch. [2] 67, 4?6, '03.)
Grams Phenol in:
Gms. Phenol
Used.
Volumes of Solvents.
50 cc. H 2 O+ 10 cc. CC1 4
+ 20 CC.
+ 30 cc.
+ 50 cc.
-f 100 CC.
H-I50CC.
+ 200 CC.
H:zO Layer.
CCL, Layer.
0.8605
0.1285
0.7990
0.1900
0.7275
0.2015
0.6435
0.3455
o . 4680
0.5210
0.3645
0.6245
0.3240
0.6650
PHENOLATE 226
PHENOLATE of Phenyl Ammonium.
SOLUBILITY IN WATER.
Figures read from Curve. (Alexejew Wied. Ann. 28, 305, '86.)
By Synthetic Method, See page 9.
Gms. Phenolate per 100 Gms. Gms. Phenolate per 100 Gms.
Aq. Layer. Phenolate Layer. Aq. Layer. Phenolate Layer.
10 3 94 no 9 76
30 4 93 120 12 69
50 5 91 130 17.5 60
70 6 87.5 140 (crit. temp.) 40
90 7 83
PHENYL (Di) AMINES C 6 H 4 (NH 2 ) 2 .
SOLUBILITY IN WATER AT 20.
(Vaubel J. pr. Ch. [2] 52, 73, '95-)
Aminp Gms. per 100 Sp. Gr. of
Gms. Solution. Solution.
m Phenyl di Amine 23.8 1.0317
P 3-7 1-0038
Nitro PHENOLS C 6 H 4 .OH.NO 2 .
100 grams saturated aqueous solution contain: 0.208 gram ortho,
2.14 grams meta, 1.32 grams para nitro phenol at 20.
(Vaubel.)
Di Nitro PHENOL C 6 H 3 .OH.(NO 2 ) 2 .
SOLUBILITY IN ALCOHOLS AT 19.5.
(de Bruyn Z. physik. Ch. 10, 784, '92.)
ioo grams abs. methyl alcohol dissolve 6.3 grams C 6 H 3 .OH.(NO 2 ) 2 .
100 grams abs. ethyl alcohol dissolve 3.9 grams C 6 H 3 .OH.(NO 2 ) 2 .
SOLUBILITY OF MIXTURES OF 5 TRI BROM PHENOL AND 5 TRI CHLOR
PHENOL IN METHYL ALCOHOL AT 25.
(Thiel Z. physik. Ch. 43, 667, '03; from Wurfel Dissertation Marburg, '96.)
Molecular per
cent C 6 H 2 .OH.Br 3
n Solubility of ^
In Solid.
In Solution.
C 6 Ho.OH.CJ 3 .
C 6 H 2 .OH.Br 3 .
O
O
O.204
O
O.2O4
4-49
3-59
0.194
O.OO7
0.201
10.13
7-58
0.191
0.016
0.206
16.28
12.15
0.172
0.024
0.196
62.44
13.07
0.204
0.031
0-235
69.88
15.86
0.150
0.028
0.178
81.76
19.01
0.096
0.023
O.IlS
84.66
24.05
0.069
O.O22
O.O9I
87-53
32.46
0-043
O-O2I
0.063
93.62
47-87
O-O2I
O.OI9
O.O4O
100.0
IOO.O
O-O
O.OI9
O.OI9
227 PHENYL SALIOYLATE
PHENYL SALICYLATE (Salol) C 6 H 4 (OH).COOC 6 H 5 i: 2 .
TOO grams H 2 O dissolve 0.043 gram salicylate at 25. 100 grams
alcohol dissolve 20.0 grams at 25.
(u. s. P.)
Di PHENYL C 6 H 5 .C,H 6 .
100 grams absolute methyl alcohol dissolve 6.57 grams at 19.5.
100 grams abs. ethyl alcohol dissolve 9.98 grams at 19.5.
(de Bruyn Z. physik. Ch. 10, 784, '92.)
PHOSPHO MOLYBDIC ACID P 2 O 5 .2oMoO 3 .5 2 H 2 O.
SOLUBILITY IN ETHER.
((Parmentier Compt. rend. 104, 686, '87.)
t o 8.1 19.3 27. 4 C
Gms. Acid per ioo gms. Ether 80.6 84.7 96.7 103.9
107.9
PHOSPHORUS P. (yellow)
SOLUBILITY IN BENZENE.
(Christomanos Z. anorg, Ch. 45, 136, '05.)
t.
Gms. P p
ioo Gms. C
er Sp. Gr. ofj
5 H<j. Solution.
t.
Gms. P per
Sp. Gr. of
5. Solution.
O
1.513
. . .
23
3-399
0-8875
5
1-99
. . .
25
3-70
0.8861
8
2.31
0.8990
30
4.60
10
2.4
0.8985
35
5-17
15
2-7
0.894
40
5-75
. . .
18
3 - 1
0.892
45
6. ii
. . .
20
3-2
0.890
50
55
60
65
70
75
81
Gms. P per
iooGms.C 6 H 8
6.80
7-32
7.90
8.40
8.90
9.40
10.03
SOLUBILITY OF PHOSPHORUS IN ETHER.
(Christomanos.)
*.
Gms. P per
ioo Gms.
(C 2 H 6 )20.
Sp. Gr. of
Solutions.
Gms. P per g Gr f
* ' (QH? )2 x> s : &**.
Gms. P per
t . ioo Gms.
(C 2 H 6 ) 2 0.
O
0-434
. . .
15
0.90
0.723
28
i. 60
5
O.62
. . .
18
I .01
0.719
30
i .75
8
0-79
0.732
20
I .04
0.718
33
i. 80
10
0.85
0.729
23
I .12
0.722
35
2 -OO
25
i-39
0.728
ioo grams CS 2 dissolve about 1750 grams yellow P at room temper-
ature. (Vogel Jahresber. Chem. 149, '68.)
ioo grams alcohol of 0.799 Sp. Gr. dissolve 0.312 gram P cold and
0.416 gram hot. (Buchner)
PHOSPHORUS 228
SOLUBILITY OP YELLOW PHOSPHORUS IN SEVERAL SOLVENTS AT 15.
(Stich Pharm. Ztg. 48, 343, '03.)
Solvent. Cms. P per 100 Cms. Solution.
Almond Oil 1.25
Oleic Acid i -06
Paraffine i -45
Water 0.0003
Acetic Acid o . 105
PHTHALIO ACIDS C 6 H 4 (COOH) 2 .
SOLUBILITY IN WATER.
(Vaubel J. pr. Ch. [2] 52, 73, '95; 59. 3. '99-)
Acid. t . Cms. per 100 Cms. Solution.
o Phthalic Acid 14 0.54
Iso Phthalic Acid 25 0.013
Tere Phthalic Acid . . almost insoluble
SOLUBILITY OF o PHTHALIC ACID IN ALCOHOL AND IN ETHER AT 15*
(Bourgoin Ann. chim. phys. [5] 13, 406, '78.)
Grams QHUCCOOH^ o per 100 Grams
Solution. Solvent.'
Absolute Alcohol 9 . 1 56 1 1 . 70
90 per cent Alcohol 10.478 10.08
Ether 0.679 0.684
CO
PHTHALIO ANHYDRIDE C 6 H 4 <co>-
SOLUBILITY IN WATER.
(van der Stadt Z. physik. Ch. 41, 358, '02.)
All determinations, except first three, made by the Synthetic Method.
See page 9.
1 Grams C 8 H 4 O3 per 100 Gms. Mol. i
>er cent
t
Grams CsI^Oa per 100 Gms. J^ ^
Water.
Solution. C 8H43-
w
Water.
Solution.
CsHtOz
O
0.00295
. 00295
.00036
189.
5
1076
QI.
66
5 6 -73
25
0.6194
.6150
0.0754
188.
8
1265
92.
68
60.63
5
1.630
I
.604
.198
187.
X
1474
93-
65
64.22
94-3
4 8
54
10
3
181.
8
2332
95-
88
73-95
165.4
210. O
6 7
75
20
36
176.
2
3334
97-
07
80.23
179-4
3I9-3
76
13
27
.98
169.
4
5745
98.
28
87.49
186.2
449.6
81
.81
35
37
130.
9
37570
99-
72
97.89
189.6
546.1
84
50
39
93
83010
99-
86
99.02
191.0
821.5
89
.19
50
.00
131.
2
00
100.
00
100.00
190.4
863.4
89
.62
24
On page 362 of the original paper the solubility of C 8 H 4 O, at o is
given as 0.2722 gram per 100 grams of solution.
229 PHTHALIC ANHYDRIDE
SOLUBILITY OF PHTHALIC ANHYDRIDE IN CARBON BISULPHIDE.
(Arctowski Compt. rend. 121, 123, '95; Etard Ann. chim. phys. [7] 2, 570, '94-)
Gms. CgHjOa
Gms. C 8 H4O 3
Gms. CgH 4 O3
t.
per ioo Gms.
t.
per ioo Gms.
t.
per ioo Gms.
Solution.
Solution.
Solution.
112.5
0.013
+ 10
o-3
70
2-3
- 93
0.013
20
0.7
90
3-7
- 77-5
0.016
30
0.8
IOO
5-o
- 40
0.03
40
1.2
120
8.0
20
0.06
50
-3
I4O
J 3-3
10
o.io
60
i-7
160
20.7
O.2O
180
30.2
PHYSOSTIGMINE SALIOYLATE C 6 H 4 (OH)COOH.C 16 H tl N,O 2 and
Physostigmine Sulphate H 2 SO 4 (C 1S H 21 N 3 O 2 ) 2 .
SOLUBILITY IN WATER, ALCOHOL, ETC.
(U. S. P.)
e Gms. per 100 Gms. Solvent.
"Salicylate. Sulphate/
Water 25 1.38 very soluble
Water 80 6.66
Alcohol 25 7.87 "
Alcohol 60 25.00
Chloroform 25 n.6
Ether 25 0.57 0.083
PICRIC ACID C 6 H 2 .OH.(NO 2 ) 3 .
SOLUBILITY IN WATER.
(Dolinski Ber. 38, 1836, '05; Findlay J. Ch. Soc. 81, 1219, '02.)
Gms. CeHgNgOr per 100 Grams Gms. QjHsNgOr per 100 Grams
Solution. Water. Solution. Water.
O 0.67(D.) 0.68 (D.) 1.05 (F.) 60 2-77(D.) 2.8KD.) 3.I7(F4
10 .80 0.81 i. 10 70 3.35 3.47 3- 8 9
20 1. 10 I. II 1.22 80 4-22 4.41 4.66
30 1.38 1.40 1.55 oo 5.44 5-72 5-49
40 1.75 1.78 1.98 100 6.75 7.24 6.33
50 2.15 2.19 2.53
Dolinski does not refer to the previous determinations of Findlay.
PICRIC ACID
230
SOLUBILITY OF PICRIC ACID IN WATER AND IN AQUEOUS SALT
SOLUTIONS AT 25.
(Levin Z. physik. Ch. 55, 520, '06.)
One liter of aqueous solution contains 0.05328 gram mols. = 12.20
grams C e H 2 .OH(NO 2 ) 3 at 25.
Gm. Mols. Salt
per j-.uer in /\
*
q- oomuuiis 01
per Liter.
NaCl.
NaNQs. Na 2 SO 4 .
LiCl.
Li 2 S0 4 .
NItiCl.
0.01
0.05524
0.05529 o
.05604
0.05480
0.05661
0.05487
O.O2
0-05559
0.05872 o
05872
0-05558
0.06053
0.05540
O.O5
0.05729
0.06632 o
.06632
0.05703
0.06691
0.05771
0.07
0.05862
0.07093 o
.07093
0.05878
0.07013
0.05865
O.IO
0.05902
0.07670 o
.07670
0.06132
0.07437
0.50
O.O79O
0.123
I .OO
O-IlSo
0.149
Gm. Mols.
Grams Picric
Acid per Liter in Aq. Solutions of:
Salt per Liter
NaCl.
NaN0 3 .
Na 2 SO.
LiCl.
Li 2 S0 4 .
NH4C1.
O.OI
12.66
12.67
12.83
I2 -55
12-97
12-57
O-O2
12.74
13-45
13-45
12.74
I3-87
12.69
O.O5
13.12
i5- J 9
15 -!9
13.06
15-33
13.22
0.07
13-43
16.25
16.25
13-47
16.06
13-44
O.IO
I3-5 2
17-57
17-57
14.05
17.04
0.50
18.09
28.18
I .00
26.98
34-14
Solubility in Aq. Cane Sugar.
Solubility in Aq. Grape Sugar.
Gm. Mols.
Sugar
per Liter.
Picric Ac. per
Liter Solution.
Sp. Gr.
Solution.
Gm. Mols.
Grape Sugar
per Liter.
Picric Acid per
Liter Sol.
Gm. Mols.
Gms.
G. Mols.
Gms.
O.IO
0.05202
II .92
I .0122
O.IO
0-0530
12.14
0.25
0-04978
II .40
I.03I9
0.25
0.0521
n-93
0.50
0.0482
II .04
I .0654
0.50
0.0509
11.66
I -OO
0-0443
IO.I5
I.I294
1. 00
0.0474
10.86
SOLUBILITY OF PICRIC ACID IN ABSOLUTE ALCOHOL.
(Behrend Z. physik. Ch. 10, 265, '92.)
TOO gms. sat. solution contain 5.53 grams CeHgNgOy at 12.3, and
5.92 grams at 14.8. Sp. Gr. of the latter solution = 0.8255.
SOLUBILITY OF PICRIC ACID IN BENZENE.
Gms. Mols.
^HsNsOr C 6 H 3 N 3 7
per 100 per 100
"viols. C 6 H 6 .
(Findlay.)
t
Gms.
Mols.
per_ioo
Gms. i
per 100
Mols.CeHe.
5
10
*5
20
25
26.
35
5
7
9
12
37
29
56
,66
21.38
1.26
1.83
2.48
3-25
4-30
4.60
7. .6
38.4
26.15
8.88
45
33-57
ii .40
55
50-65
17.21
58-7
58.42
19.83
65
71 .31
24.20
75
96.77
32.92
231
PICRIC AOID
SOLUBILITY OP PICRIC ACID IN ETHER.
(Bougault J. pharm. chim. [6] 18, 116, '03; Apoth.-Ztg. 21, 74, '06.)
Solvent.
Ether of Sp. Gr. 0.721
Ether of Sp. Gr. o . 725 (0.8 pt. H 2 O per 100)
Ether of Sp. Gr. 0.726 (i.o pt. H 2 O per 100)
Ether saturated with H 2 O
H 2 O saturated with Ether
t.
Gms. CeHaNa
C>7 per Liter.
13
10.8
(B.)
13
36.8
M
13,
4O.O
M
*5
51-2
15
13-8
DISTRIBUTION OF PICRIC
Water and Amyl Alcohol.
(Herz and Fischer Ber. 37, 4747, '04.)
ACID AT 25 BETWEEN:
Water and Toluene,
(H. and F. Ber. 38. 1142, '05.)
Millimols CeHsNgO?
per 10 cc.
Gms. Cs-HsNgOY
per 100 cc.
Millimols CeHgNaOr
per 10 cc.
Gms. CsHaNsOy
per loo cc.
Aq.
Alcohol
Aq.
Alcohol
Aq.
Toluene
Aq.
Toluene
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
0-0553
0.0930
O
.127
O
213
O
075
O.I26
o.
172
0.289
0.0920
0.1850
O
.211
.424
O
.109
0.230
o.
250
0.527
0.1613
0.4127
O
369
.946
O
.163
0.482
o.
374
I .IO4
0.1869
0.5182
.428
I
.188
O
.244
I .026
o.
559
2-351
0.3161
1.079
O
724
2
473
O
389
2-347
o.
891
0.4471
1.638
I
.024
3
753
.496
3-747
I .
137
8.586
0.5624
2.189
I
.288
5
.017
.583
5-135
I .
336
11.770
0.6423
2-549
I
.472
5
839
DISTRIBUTION OP PICRIC ACID AT 25 BETWEEN:
Water and Bromoform.
(Herz and Lewy Z. Electrochem. n, 820, '05.)
Water and Chloroform.
(H. and L.)
Millimols CeHsNsO?
Gms.
CVHjNsCV
Millimc
Is CoHaNaOr
Gms.
CoHsNgOr
per 10 cc.
per
IOO CC.
per
10 CC.
per
IOO CC.
Aq.
Bromoform
Aq.
Bromoform
Aq.
Chloroform
Aq.
Chloroform
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
Layer.
0.321
0-365
0.736
0-836
0.207
0.254
0-474
0.582
0.401
Q -5*S
0.919
I.lSo
0.329
o-547
0-754
I - 2 53
o-475
- 6 55
1. 088
I.50I
0.488
1.09
1.118
2.498
o-575
0.871
I-3I7
J-995
0.561
1.41
1.285
3-230
0.674
1.14
i-545
2 .6l2
0-588
i-53
1-348
3-505
PILOCARPINE HYDROCHLORIDE C n H 16 N 2 O 2 .HCl, Pilocarpine Ni-
trate C n H 16 N 2 O 2 .HNO 3 , and Piperine C 17 H 19 NO 3 in Several Solvents.
(U. s. P.)
Grams per 100 Grams Solvent.
*-! _ A. ft
OU1VCLH.
i> .
C U H 16 N 2 2 .HC1. (
:nH 16 N20 2 .HN(
>a. CnHwNoV
Water
25
333
25
insoluble
Alcohol
25
4-35
1.66
6.66
Alcohol
60
9-09
6.2
22.7
Chloroform
2 5
0.18
. . .
58.8
Ether
25
2.8
PLATINUM ALLOYS 232
SOLUBILITY OF PLATINUM ALLOYS IN NITRIC ACID.
(Winkler Z. anal. Ch. 13, 369, '74-)
j
Alloy. I
Pt
^pprox. Grams Alloy Dissolved per 100 Grams HNOs Solution ot
in AUoy.
i. 39 8Sp.Gr.
i.2o8Sp.Gr.
i.igoSp.Gr.
i.2o8Sp.Gr.:
Pt and Silver
10
57
44
6 9
37
11
5
69
57
51
35
tt
2-5
62
61
69
"
i
75
70
7 6
Pt and Copper
10
46
27
II
51
"
5
36
34
14
4i
"
2-5
5 1
40
30
"
i
52
4 1
37
Pt and Lead
10
7
9
8
u
5
8
9
10
u
2-5
22
17
ii
It
21
18
23
Pt and Bismuth
10
14
19
4
3
n
5
21
20
6
18
(l
2-5
25
42
8
(l
I
49
6 4
10
Pt and Zinc
10
10
II
19
5
"
5
16
12
6
ii
"
2-5
16
24
19
"
I
20
32
37
PLATINUM BROMIDE PtBr 4 .
100 grams sat. aqueous solution contain 0.41 gram PtBr4 at 20.
(Halberstadt Ber. 17, 2962, '84.)
PLATINIC POTASSIUM BROMIDE K 2 PtBr 6 .
100 grams sat. aqueous solution contain 2.02 grams K 2 PtBr 6 at 20.
(Halberstadt.)
PLATINIC DOUBLE CHLORIDES of Ammonium, Caesium, Potas-
sium, Rubidium and Thallium.
SOLUBILITY IN WATER.
(Crookes Chem. News 9, 37, 205, '64; Bunsen Pogg. Ann. 113, 337, *6i.)
Grams per 100 Grams Water.
o
10
0.024
0.666 (15) 0.050
0.74
0.90
Rb 2 PtCl6.
0.184
0.154
0.0064(15)
20
25
0.079
0.095
I .12
1.26
0.141
0.143
. . .
30
40
O.IIO
0.142
I.4I
I. 7 6
0.145
0.166
'.".
50
60
0.177
0.213
2.17
2.64
0.203
0-253
70
80
0.251
0.291
3-79
0-329
0.417
90
100
0.332
1.25 0.377
4-45
0.521
0.634
0.050
233 PLATINIC CHLORIDES
SOLUBILITY OF AMMONIUM PLATINIC CHLORIDE AND OF POTASSIUM
PLATINIC CHLORIDE IN ALCOHOL AT i5-2o.
(Fresenius: Peligot Z. aaal. Ch. 36, 322, '97.)
Gms. per Liter Solution. Cms, per Liter Solution.
" ' (NHifcPtO*
55% Alcohol 0.150 ... 95% Alcohol 0.0037 0.030
76 " 0.067 0.026 Abs. " ... 0.0082-0.0023
85 " ... 0.180 80 Vol.% Alcohol + 20
Vol. % Ether ... 0.027
90 " ... o. 100 Abs. Methyl Alcohol ... 0.072
PLATINO AMINES.
SOLUBILITY IN WATER.
(Cleve.)
Amine. Formula.
S-LJ-TT \ f*i Gms. per ioo Gms. H 2 O.
Platino Semi Di Amine Chloride Pt<g^'** 0.26 at o 3.4 at 100
Chloro Platin Amine Chloride C1 ' Pt <NHCl ' 14 " 3 ' "
Chloro Platin Semi Diamine Chloride Cl 3 Pt(NH 3 ) 2 Cl o. 33 " i . 54 "
POTASSIUM ACETATE CH 3 COOK.
SOLUBILITY IN WATER.
ioo gms. sat. aq. solution contain 73.65 gms. CH 3 COOK, or ioo
gms. H 2 O dissolve 286.3 ms - a ^ 31.25.
(Kohler Z. Ver. Zuckerind. 47, 447, '97.)
ioo gms. H 2 O dissolve 188 gms. CH a COOK at 5, 229 gms. at 13.9,
492 gms. at 62.
(Osann.)
ioo gms. 99 per cent ethyl alcohol dissolve 33.3 gms. CH 3 COOK at
15, and 50.0 gms. at 80.
POTASSIUM (Di Hydrogen) ARSENATE KH 2 AsO 4 .
ioo gms. sat. aq. solution contain 15.9 gms. KH 2 AsO 4 , or ioo gms.
H 2 O dissolve 18.86 gms. at 6. Sp. Gr. of solution = 1.1134.
(Field J. Ch. Soc. ix. 6, '59.)
POTASSIUM BENZOATE KC 7 H 5 O 2 . 3 H 2 O.
SOLUBILITY IN WATER.
(Paietta Gazz. chim. ital. 36, II, 67, '06.)
t- 17-5 2 5 33.3 50
Gms. KC 7 H 5 O 2 per ioo Gms. 41.4 42.4 44.0 46.6
Solution.
POTASSIUM BORATES
234
SOLUBILITY OF POTASSIUM BORATES IN WATER AT 30.
(Dukelski Z. anorg. Chem. 50, 42, '06, complete references given.)
Gms. per 100 Gms. Solution. Gms. per 100 Gms. Residue.
K 2 0.
B 2 3 .
K 2 0.
B 2 3 .
47-50
46.36
0.91
46.13
9-02
40-51
1.25
41 .62
9.71
36.82
1. 80
39-90
I3-I9
3 2 -74
3-5 1
37-22
14-58
29.63
6.98
35-05
17.92
24-84
17 .63
30.02
21.70
23-30
18.19
26.84
31-49
16.21
13.10
25.12
33-18
11.78
9.82
20.57
26.43
9.18
8.00
22.38
3I-30
6.22
9.13
20.87
31.06
7-73
13-37
22 .21
36.24
7.81
13.28
I7-50
34-18
7.71
13.21
11-49
3 4.8l
7-63
13.28
12 .51
40.52
3 42
7-59
10-77
37-35
i. 80
4-iS
5-88
20-00
0.51
10.81
40.89
o 33
4-58
7.72
34-21
0.31
4.46
3-9i
30.68
3-54
Solid
Phase.
KOH. 2 H 2 O
K20.2B 2 3 .4H 2
K 2 0.2B2O 3 . 4 H 2 +K 2 0.sB 2 O 3 .8H 2 O
K2O.sB 2 O 3 .8H 2 O
K2O.sB 2 O 3 .8H 2 0+ B(OH) 8
POTASSIUM (Fluo) BORIDE KBF 4 .
100 gms. H 2 O dissolve 0.44 gm. KBF 4 at 20, and 6. 27, gms. at 100
(Stolba Chem. techn. Centr. Anz. 7, 459, '89.)
POTASSIUM BROMATE KBrO 3 .
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 97, 5. '56; Rammelsberg Ibid. 55, 79, '42; Pohl Sitzber. Akad. Wiss
Wien. 6, 595, '51-)
Gms. KBrO 3 per 100 Gms.
c .
'Water.
Solution.
3.1
3-o
10
4-8
4-6
20
6.9
6-5
25
8.0
7-4
30
9-5
8.7
Gms. KBrO 3 per 100 Gms.
* .
Water.
Solution.
40
13.2
II-7
50
17 .5
14-9
60
22-7
18.5
80
34-o
25-4
100
50. o
33-3
Sp. Gr. of solution saturated at 19.5 = 1.05.
235 POTASSIUM BROMATE
SOLUBILITY OF POTASSIUM BROMATE IN AQUEOUS SOLUTIONS OF
SODIUM NITRATE AND OP SODIUM CHLORIDE.
(Geffcken Z. physik. Chem. 49, 296, '04.)
In Sodium Nitrate. In Sodium Chloride.
Grams per Liter. Mols. KBrO 3 Grams P Liter. Mols. KBrOs
NaN0 3 . KBr0 3 . per Liter. NaCl. KBrO 3 . per Liter.
o.o 78-79 0.4715 o.o 78-79 0.4715
42.54 96.01 0.5745 29.25 82.24 0.5220
85.09 108.6 0.6497 5&-5o 93-87 0.5616
170.18 128.3 0.7680 117.0 100.9 0.6042
2 55- 2 7 I 5-9 0.9026 175.5 IQ 4 3 0.6244
340.36 172.3 1.031 234.0 106.9 0.6400
POTASSIUM BROMIDE KBr.
SOLUBILITY IN WATER.
(Average curve from results of Meusser Z. anorg. Chem. 44, 79, '05; Etard Compt. rend. 98, 1432,
'84; Ann. chim. phys. [7] 2, 526, '94; de Coppet ?'''* - -
Shenstone Phil. Trans. 175. 23,
T 8 4 .)
c Grams KBr per ioo Grams
t
Grams KBr per ioo Grams
'
Solution.
Water.
I .
' Solution.
Water.
6.5
20. o
2 5 -O
30
41.4
70.6
- 8. 5
26-5
35-7
40
43-o
75-5
-10-5
29-5
41.8
50
44-5
80.2
-"5
31.2
45-3
60
46.1
85-5
10
31.8
46.7
70
47-4
90.0
- 5
33-3
50-0
80
48.7
95-o
34-9
53-5
90
49-8
99-2
5
36-1
56-5
IOO
51.0
104.0
10
37-3
59-5
no
52-3
109.5
15
38-5
62.5
140
54-7
120.9
20
39-5
65 .2
181
59-3
145.6
25
40.4
67-7
SOLUBILITY OF MIXTURES OF POTASSIUM BROMIDE AND AMMONIUM
Grams per Liter Solution.
BROMIDE IN WATER AT 25
(Fock Z. Kryst. Min. 28, 357, '97.)
Mol. per cent in Solution. Sp. Gr. of
o
Mol. per cent in Solid Phase
NH 4 Br.
KBr.
NH4Br.
KBr.
Solutions.
NH4Br.
KBr.
o.oo
558-I
o.o
IOO
I-375 6
0-00
IOO
6.4
554-2
I. 3 8
98.62
1-3745
0.26
99-74
24.64
536-5
5-29
94-71
1-3733
1.27
98.73
51-34
516.8
10-77
89.23
1.3721
3-02
96.98
152.9
441.2
29.63
70-37
1.3711
8.42
91.58
262.2
347-3
47.84
52.16
!-37i5
17.20
82.80
. 347-6
262.3
61 .69
38.31
1-3753
27-98
72.02
381.4
260.3
64.03
35-97
1-3753
32-53
67.47
417.8
232.2
68. 61
3*-39
1.3766
39-45
6 o.55
432-5
222.3
70.27
29-73
1-3777
variable
variable
480.8
179.9
76.47
23-53
1.3766
98.53
i-47
577-3
o.o
100.0
o.o
1-3763
100.0
0-00
POTASSIUM BROMIDE
236
SOLUBILITY OP POTASSIUM BROMIDE IN AQUEOUS SOLUTIONS OF
POTASSIUM HYDROXIDE.
(Ditte Compt. rend. 124, 30, '97.)
Grams per 1000 Grams H 2 O.
KOH. KBr.
36.4 558.4
"3-5 433-6
177-2 358.1
231.1 281.2
Grams per 1000 Grams HgC
KOHL KBr. '
277.6 248.1
434-7 I 37- 1
579.6 64.8
806.9 33.4
SOLUBILITY OP MIXTURES OF POTASSIUM BROMIDE AND CHLORIDE AND
OF MIXTURES OF POTASSIUM BROMIDE AND IODIDE IN WATER.
(Etard Ann. chim. phys. [7] 3, 275, '97.)
Mixtures of KBr and KC1. Mixtures of KBr and KI.
Grams per 100 Gms. Solution. Grams per 100 Grams Solution.
'
KBr.
KCl.
20
J 7-5
10.5
21.5
10.8
10
23.2
II .0
20
24.8
II .2
25
25-5
"3
30
26.3
xx .4
40
28.0
n-5
60
30.6
n. 8
80
33-4
12. 1
100
35-7
12.6
120
38.0
I2. 9
r 5o
40.6
13-4
KBr.
KI.
9-2
42-5
9-9
45-3
10.2
46.6
10-5
47-5
10-7
48.0
IO-9
48.6
II .2
49.6
xx .9
5i-3
12.6
52-7
13.2
53-8
14.0
54-8
14.9
55-5
SOLUBILITY OF POTASSIUM BROMIDE IN AQUEOUS SOLUTIONS OF
POTASSIUM CHLORIDE, AND OF POTASSIUM CHLORIDE IN AQUEOUS
SOLUTIONS OF POTASSIUM BROMIDE, AT 25.2.
(Touren Compt. rend. 130, 1252, 'oo.)
KBr in Aq. KCl Solutions.
KCl
in Aq.
KBr Solutions.
Mols. per Liter.
Grams
per Later.
Mols. per Liter.
Grams per Liter.
KCl.
KBr.
KCl.
KBr
KBr.
KCl.
KBr.
KCl.
o.o
4
.76!
O
.0
567.
O
.0
4.18
o.oo
3II.8
0.67
4
.22
50
.0
502.
5
O
49
3-85
58-4
287.2
0.81
4
15
60
4
494.
2
O
85
3-58
IOI-3
267 .-I
1.35
3
.70
100
7
440.
7
I
3-19
156.1
2 3 8.0
1.48
3
54
no
4
421.
6
I
-78
2 .91
211 .9
2I7.I
1.61
3
.42
1 20
.0
407.
2
2
25
2.58
268.0
192.4
1.70
3
34
126
.8
397-
7
2
.69
2-33
320.4
173-8
2.46
2
50
183
5
297.
7
3-775
5 2 5
2 8i
.6
625.
3
237
POTASSIUM BROMIDE
SOLUBILITY OF POTASSIUM BROMIDE IN AQUEOUS SOLUTIONS OP
POTASSIUM NITRATE, AND OF POTASSIUM NITRATE IN AQUEOUS
SOLUTIONS OF POTASSIUM BROMIDE, AT 14.5 AND AT 25.2.
(Touren Compt. rend. 130, 908, 'oo.)
!Br in Aqueous
Mols. per Liter.
KNO 3 Solutions.
Grams per Liter.
KNO 3 in Aq.
Mols. per Liter.
KBr Solutions.
Grams per Liter.
KNOg.
KBr.
KNO 3 .
KBr.
KBr.
KNOs.
KBr.
KN0 8 .
Results at
14.2.
Results at 14.20.
O-O
4-332
O
.0
5 J 5
9
.0
2
.228
O-O
225.4
0.362
4.156
36
.6
494
9
O
-356
2
.026
42-4
205 -O
0.706
4-093
71
4
487
4
O
.784
I
835
93-4
185-7
1-235
3-939
124
9
469
.1
I
.092
I
73
130.0
175-0
I
577
I
587
187.8
l6o.6
Results at
25-2.
2
542
I
.406
302.7
142.2
0-0
4.761
O
o
566
.2
3
-536
z
-308
421.1
J 32-3
O.I3I
4.72
13
3
561
O
Results at 25.2.
0.527
4.61
53
3
549
.1
.0
3
.217
o.o
325-5
0.721
4-54
72
9
540
.8
38
3
.026
45-3
306.2
1.09
4-475
no
3
533
.0
O
93
2
.689
no. 8
272.0
I.I70
4.44
118
4
528
.8
I
37
2
.492
163.1
252.2
1.504
4-375
152
.2
52i
.1
I
.208
2
.216
143-8
224.3
2
.87
I
958
341.8
198.1
3
55
I
.807
422.8
182.8
SOLUBILITY OF POTASSIUM BROMIDE IN ALCOHOLS AT 25.
(de Bruyn Z. physik. Chem. 10, 783, '92; Rohland Z. anorg. Chem. 18, 327, '08.)
Grams KBr Dissolved by 100 Gms. Alcohol at:
Methyl Alcohol
Ethyl Alcohol
Propyl Alcohol
Room Temp. (R.).
1.92
0.28 (Sp. Gr. o
0-055
.81)
25 (de B.).
1.51 Abs. Alcohol
0.13
SOLUBILITY OF POTASSIUM BROMIDE IN AQUEOUS ALCOHOL.
(Taylor J. Physic. Ch. i, 724, 'o6-'97-)
Results
at 30.
Results
at 40.
Wt. per cent Alcohol
Gms. KBr per 100 Gms.
Gms. KBr per
ioo Gms.
in Solution.
'Sat. Solution.
Solvent.
Sat. Solution.
Solvent.
41 .62
71.30
43-40
76.65
5
38.98
67.25
40.85
72.70
10
36-33
63.40
38.37
69.00
20
31.09
56.40
33-27
62.30
30
25.98
50-I5
28.32
56-45
40
21 .24
44-95
23.22
50.46
50
16.27
38-85
18.11
44-25
00
11.50
32-50
13.02
37-40
70
6.90
24.70
7.98
28.90
80
3-09
!5-95
3-65
18.95
90
0.87
8.80
1.03
10.45
ioo gm. acetone dissolve 0.023 gm. KBr at 25.
(Krug and McElroy J. anal. Chem. 6, 184, '93.)
POTASSIUM BROMIDE
238
SOLUBILITY OF POTASSIUM
(Herz and Knoch Z. anorg.
Aqueous Acetone.
BROMIDE AT 25
Chem. 45, 262, '05.)
IN:
Aqueous Glycerine.
cc. Acetone Per 100 cc. Sat. Solution.
Sp. Gr.
Solutions.
Wt. %
Glycerine
in Solvent.
KBr per 100 cc. Sol.
bp. dr.
Millimols. Gms. Solutions
per 100 cc. Millimols
Solvent. KBr.
Gms.
KBr.
Gms.
H 2 0.
481
3
57-3
80.6
j
3793
481.3
57
32
3793
20
3 66
7
43-67
69-5
|
2688
13.28
444-3
5 2
9i
3704
30
3 IO
5
36-98
62.97
I
2118
25.98
404.0
48
IT
3655
40
2 59
.0
30- 8 5
55-60
I
1558
45 -3 6
340-5
40
55
3594
5
2O2
9
24.16
47.60
r
.0918
54-23
310.4
36
98
-3580
60
144
9
17 .22
39 - T 5
i
.0275
83.84
219.25
26
ii 1.3603
70
95
3
n-35
29.78
959 1
100.00
172.65
20
56 1.3691
80
46
5
5-54
20- 10
.8942
90
10
.1
i .20
10.15
.8340
100 cc. sat. solution of potassium bromide in furfurol (C 4 H 3 O.COH)
Contain 0.139 gm. KBr at 25. (Walden Z. physik. Chem. 55, 713, '06.)
POTASSIUM BUTYRATE C 3 H 7 COOK.
100 grams water dissolve 296.8 grams C 3 H 7 COOK, or 100 grams
sat. solution contain 74.8 grams at 31.25.
100 grams of an aq. solution saturated with sugar and C 3 H 7 COOK
contain 49.19 grams sugar + 34.78 grams C 3 H 7 COOK + 16.03 grams
H 2 O at 31.25. (K6hler Z. Ver. Zuckerind. 47, 447, '97-)
POTASSIUM CARBONATE K 2 CO 3 .
POTASSIUM (Bi) CARBONATE KHCO 3 .
SOLUBILITY OF EACH IN WATER.
(Mulder; Dibbits J. pr. Chem. [2] 10, 439, '74.)
Grams ^COg per 100 Grams
Grams KHCO 3 per 100 Grams
(l .
Solution.
Water.
Solution.
Water.
o
47-2
89.4
18.3
22-4
10
52-2
IO9.O
21-7
27.7
20
52.8
112 .O
24.9
33-2
30
53-3
II4.O
28.1
39-o
40'
54-o
II7.0
31.2
45-3
60
56.0
127.0
37-5
60.0
IOO
60.9
156.0
Kohler (loc. cit.) gives for the solubility of K 2 CO 3 in water, 48.91
grams K 2 CO 3 per 100 grams solution, or 95.9 grams per 100 grams
H 2 O at 31.25. In saturated sugar solution at the same temperature
he finds 56.0 grams sugar + 22.24 grams K 2 CO 3 + 21.76 grams H 2 O
per loo grams sat. solution. Engel (Ann. chim. phys. [6] 13, 366, '88)
finds 1 1 i.o grams K 2 CO 3 per 100 grams H 2 O or 52.6 grams per 100 grams
sat. solution at o. Sp. Gr. of solution = 1.542. For potassium bi car-
bonate he finds 23 grams KHCO 3 per 100 grams H 2 O, or 18.7 grams
per loo grams solution. Sp. Gr. of solution = 1.127.
239 POTASSIUM CARBONATfc
SOLUBILITY OF POTASSIUM Bi CARBONATE IN AQUEOUS SOLUTIONS OF
POTASSIUM CARBONATE AT o.
(Engel.)
Milligram Mols. per 10 cc. Solution. Sp. Gr. of Grams per 100 cc. Solution.
iK 2 C0 3 . KHC0 3 Solutions. ' K 2 CO 3 . KHCO 3 .'
o.o 21.15 I - I 33 o.o 21.2
17.14 15-28 1.182 ii. 8 15.3
24.10 12.65 I -203 16.7 12.6
34.50 10.25 I.24I 23.8 10-3
49-20 7.55 1.298 34.0 7.6
62.14 5.86 i-35 43-o 5-9
74.60 4.90 1.398 51.6 4.9
87.50 3.75 1.448 60.5 3.8
117.75 o.o 1.542 81.4 o.o
SOLUBILITY OP POTASSIUM CARBONATE IN AQUEOUS SOLUTIONS OF
ETHYL AND PROPYL ALCOHOLS AT 20.
(Linebarger Am. Ch. J. 14, 380, '92; de Bruyn Rec. trav. chim. 18, 87, '99.)
In Aq. Ethyl Alcohol. In Aq. Propyl Alcohol.
Nt. per cent Gms. K 2 CO 3
C 2 HsOH in per 100 Gms.
Wt. per cent
C 2 H 6 OH in
per 100 Gms.
Wt. per cent
CsH-rOH in
Gms. K 2 CO 3 per
loo Gms.
Solvent. :
Sat. Solution.
Solvent.
Sat. Solution.
Solvent.
Sat. Solution.
10
24
50
2-5
40
4-3
20
16
55
1.8
45
30
10
60
I .1
50
2.0
40
5-6
65
0.8
55
I .3
45
4
6 9
0.4
60
0.8
65
ioo grams glycerine of 1.225 Sp. Gr. dissolve 7.4 grams K 2 CO 3 .
(Vogel N. Rep. Pharm. 16, 557, '67.)
POTASSIUM SODIUM CARBONATE KNaCO 3 .6H 2 O.
ioo gms. H 2 O dissolve 184 gms. salt at 15. Sp. Gr. of sol. = 1366.
(Stolba J. pr. Chem. 94, 406, '65.)
POTASSIUM URANYL CARBONATE 2 K 2 CO 3 .(UO 2 )CO 3 .
ioo gms. H 2 O dissolve 7.4 gms. salt at 15.
(Ebelmen Liebig's Ann. [3] 5, 189, '52.)
POTASSIUM CHLORATE KC1O 3 .
SOLUBILITY IN WATER.
(Gay-Lussac Ann. chim. phys. ii, 314, 1819; Pawlewski Ber. 32, 1040,5*99; above 100, Tilden
and Shenstone Proc. Roy. Soc. 35, 345. '81; see also Blarez Compt. rend. 112, 1213, '91;
Etard Ann. chim. phys. [7] 2, 526, 94; at 99, Kohler Z. anal. Chem. 18, 242, '79.)
Gms. KC1O 3 per ioo Gms. Gms. KCl(\per ioo Gms.
Solution. Water. 'Solution. Water."
o
3
.04
O
.14
3-3*
70
22
55
29
.16
32-5'
10
4
.27
4
45
5-o
80
26
97
3 6 -93
39-6
20
6
.76
7
.22
7- 1
90
3 1
36
46
.11
47-5
25
7
56
8
17
8.6
100
35
83
55
-54
56.0
30
8
.46
9
.26
10. 1
120
42
4
73
7
73-7
40
ii
75
I 3
3 1
14-5
I 3 6
49
7
98
5
99.0
50
15
.18
*7
95
19.7
190
64
.6
183
.0
183.0
60
18
97
2 3
.42
26.0
330
96
7
2930
.00
*
Gay Lussac.
POTASSIUM CHLORATE 240
SOLUBILITY OF POTASSIUM CHLORATE IN AQUEOUS SOLUTIONS OP
POTASSIUM BROMIDE AT 13.
(Blarez Compt. rend. 112, 1213, V-)
Cms. per 100 Gms.
Solution.
Gms. per 100 Gms.
Solution.
Gms. per 100 Gms.
Solution.
'KBr.
KC1O 3 .
'KBr.
KClOa-
KBr,
KClOa.
0.20
5.18
1.0
5-04
6.0
3-46
O-6o
5.20
2 .O
4.60
8.0
2.8o
0.8
5.06
3-o
4.2
IO.O
2.40
4.0
4.0
SOLUBILITY OF POTASSIUM CHLORATE IN AQUEOUS SOLUTIONS OF
OTHER POTASSIUM SALTS AT 14-! 5.
(Blarez.)
Salt.
KOH
KC1
n
KBr
tt
KI
Gms. per TOO Gms. Solution.
Gms. per too Gms. Solution.
K Salt.
i-43
KC10 3 .
4-47
1.91
3.82
4-45
3-58
3-05
6.10
4.49
3.60
4-25
8.51
4-59
3-65
K Salt.
KC10 3 .
KN0 3
2-59
4-5 1
It
5 .l8
3-88
K 2 S0 4
2 .23
4.71
11
4.46
3-98
K 2 C 2 O 4
2-42
4-72
"
4-85
3-93
SOLUBILITY OF POTASSIUM CHLORATE IN AQUEOUS SOLUTIONS OP
POTASSIUM CHLORIDE AT 20.
(Winteler Z. Electrochem. 7 360, 'oo.>
Sp. Gr. of
Grams
per Liter.
Sp. Gr. of
Grams
per Liter.
Solutions.
KC1.
KC10 3 ".
Solutions.
KC1.
KC10 3 '.
1.050
O
7I.I
1.098
120
24-5
1.050
10
58.0
I.IOS
140
22-5
1.050
20
49.0
I .119
1 60
21 .0
1.054
40
39-5
I.I30
180
20-0
1.064
60
34-o
I .140
200
20-0
1-075
80
30.0
1.168
250
20. o
1. 086
100
27.0
SOLUBILITY OF POTASSIUM CHLORATE IN AQUEOUS SOLUTIONS OF
POTASSIUM NITRATE.
(Arrhenius Z. physik. Chem. n, 397, '93.)
Results at 19.85'
Mols. per Liter.
Grams r^er Liter.
Results at 23.87.
Mols. per Liter. Grams per Liter.
KN0 3 .
KC10,/
KNO 3 .
KC10 3
KN0 3 . KC10 3 '
KNO 8 . K<
O
O
O
570
o.o
6 9
.88
.0 0.645
o.o 79
.09
O
.125
529
12.65
6 4
.86
5 -5 I 5
50.59 63
.14
2 5
492
25.29
60
33
I
.0
374
101 .19
45
85
2
-O
328
202.38
40
.22
241
POTASSIUM CHLORATE
SOLUBILITY OF POTASSIUM CHLORATE:
(Taylor J. Physic. Chem. i, 720, '96- '97; see also Gerardin Ann. chim. phys. [4] 5, 148, '65.)
In Aqueous Alcohol.
In Aqueous Acetone.
Wt. per cent _ A * A?X
Alcohol or Gms. KC10 3 per
of Acetone 1O Gms -
Gr
At 40.
as. KC1O 3 per
100 Gms.
At 30. At 40.
Gms. KC1O 3 per Gms. KC1O 3 per
100 Gms. ioo Gms.
mSolvent. Solution
. Water.
Solution.
Water.
Solution.
Water.
Solution.
Water.
o
9-23
IO.I7
12
23
J 3
93
9-23
10.17
II
23
*3-93
5
7.72
8.80
10
.48
12
33
8.32
9-5 6
II
.10
13.11
10
6.44
7^5
8
.84
IO
77
7.63*
9.09
10
.28*
12. 60
20
4-51
5-90
6
.40
8
56
6.09
8.10
8
.27
II .26
30
3.21
4-74
4
.67
7
.00
4-93
7.40
6
.69
IO.24
40
2-35
4.00
3
-4T
v)
,88
3-90
6.76
5
36
9-45
50
i .64
3-33
2
.41
4
94
2.90
5-98
4
03
8.40
60
I .01
2-53
I
.41
2
.69
2.03
5-i7
2
.86
7-35
70
0-54
1.82
O
.78
2
63
1.24
4.18
I
.68
5.68
80
0.24
I .22
34
I
73
o-57
2.88
79
3-97
90
0.06
O.62
o
.12
I ,
17
0.18
1.82
O
.24
2-45
* Solvent, 9.09 Wt. per cent Acetone.
ioo grams glycerine dissolve 3.5 grams KC1O 3 at 15.5.
ioo grams sat. solution of KC1O 3 in glycol contain 0.9 gram KC1O 3 .
(de Coninck Bui. acad. roy. Belgiquc, 359, '05.)
POTASSIUM (Per) CHLORATE KC1O 4 .
SOLUBILITY IN WATER AND IN ALCOHOL.
(Muir Chem. News, 33, 15, '76; Wenze Z. angew. Ch. 5, 691, '91 .)
In Water. (M.)
In Alcohol. (W.)
to.
Gms.KClO 4 per
iooGms.H 2 O.
Sp. Gr. of
Solutions.
Wt . per cent Gms . KC1O 4 per
Alcohol. ioo Gms. Alcohol.
6
0-7
1.0005
97.2
0.0156
2 5
1.9
I.OI23
95-8
0.020
6-45
1.0181
90.0
0-036
00
20.0
i .0660
POTASSIUM CHLORIDE KC1.
SOLUBILITY IN WATER.
(Average curve from the results of Meusser Z. anorg. Chem. 44, 79, '05; at 31.25, Kohler 2
Ver. Zuckerind. 47, 447, '97; Andrae J. pr. Chem. [2] 2Q, 456, '84; Gerardin Ann. chim. phy:
[4] 5. i37. '65; de Coppet Ibid. [5] 30, 411, '83; Etard Ibid. [7] 2,526, '94; Mulder; above 100, Tilde
and Shenstone Proc. Roy. Soc. (Lond.) 35, 345, '83.)
A0 Gms. KCl per too Gms. A0 Gms. KCl per ioo Gms.
Gms.
KCl per ioo
Gms.
Solution.
Water.
Solution.
Water.
' Solution.
Water.
-9
19-3
23
9
40
28
.6
4O.O
147
41
5
70.8
-4-5
20. 6
5
29
9
42.6
180
43
7
77-5
o
21.6
27
.6
60
31
3
45-5
Solid Phase
Ice
5
22.7
29
3
70
32
.6
48-3
-9
19
3
23-9
10
23-7
3 1
.0
80
33
.8
5 1 - 1
-8
17
7
21 .5
15
24-5
3 2
4
90
35
.1
54-o
-8
16
7
20. o
20
25-4
34-o
IOO
36
.2
56-7
-7
14
9
I7-S
2 5
26.2
35
5
130
39
.8
66.0
-6
13
.6
15-7
30
27.1
37
.0
-5
5 I2
5
14 3
Sp. Gr. of solution sat. at o = i.iso; at 15 = 1.172.
POTASSIUM CHLORIDE
242
SOLUBILITY OF MIXTURES OF POTASSIUM CHLORIDE AND AMMONIUM
CHLORIDE IN WATER AT 25.
(Fock Z. Kryst. Min. 28, 353, '97.)
Grams per Liter
Solution.
KCl.
3II-3
293-3
278.7
273.2
234.6
204-2
157-7
II6.8
123.0
III .O
102.2
53-16
3 J -24
o.oo
Grams per Liter
Solution.
Mol. per cent
in Solution.
NH 4 C1.
KCl.
o.oo
100.0
9.41
90.59
15.04
84.96
34.26
65.74
46.59
53-44
5 J - 6 3
48.37
63-56
36-44
73-49
26.51
73-48
26.52
79.10
20.90
82.14
17.86'
87.96
12.04
93-45
6.55
100.00
o.oo
Sp. Gr. of
Solutions.
Mol. per cent in
Solid Phase.
1807
1716
1678
*493
1461
i
i
i
i
i
i
i .
1.1326
1.1329
1.1245
I .1212
I .1009
I .O9I2
1.0768
NH4C1.
0-0
1 .21
2 -II
6.18
8.90
J o-53
17.86
60.20
76.88
97-5 1
97-79
98-85
99-33
100.0
KCl.
IOO
98.79
97.89
93.82
91 .10
89.47
82.14
39.80
23 -12
2-49
2.21
1*1$
0.67
o.oo
NH4C1.
O.OO
22 -8l
35-39
89.17
127.8
147.2
197-3
232-5
244-5
261 .9
259.0
278.6
320.7
273-5
SOLUBILITY OF MIXTURES OF POTASSIUM CHLORIDE AND POTASSIUM
BROMIDE AT 25.
(Fock.)
Milligram Mols. Mo i. p^ cent Mo i. _,. cent
per Liter. KCl in P KCl in
KB7 KCl. Solution.
4686.2 o.o o.o I -3756
4462.7 314.2 6.16 1.3700
4228.5 624.3 12.86 1-3648
3817.8 1108.0 22.49 J-3544
3188.1 1830.7 36.48 1.3320
2727.6 2237.4 45-06 1-3119
1830.2 2868.0 60.30 1.2689
uSi.i 3363.9 74.01 1.2455
291.7 398.8 3911.4 85.22 1-1977
311.3 o.o 4173-1 100.00 1-1756
KBr.
558.1
531-5
503-6
454-6
KCl.
O-OO
23-44
46.57
82.62
379.6 136.6
324.8 166.9
213.9
250.9
218.0
140.7
47-5
o.o
Solid Phase.
O.OO
O.OO
8.2 3
15.68
33-66
63-5 1
82.29
88.04
96.98
100.00
SOLUBILITY OF POTASSIUM CHLORIDE IN AQUEOUS SOLUTIONS OF
HYDROCHLORIC ACID AT o.
(Jeannel Compt. rend. 103, 381, '86; Engel Ann. chim. phys. [6] 13, 377, '88.)
ram Mols.
per 10 cc. <
Srams per 100 cc. Solution,
Sp. Gr. of
KCl.
HCI:
KCl.
HCI.
Solutions.
34-5
o.o
25-73
O-O
I-I59
30.41
3-9
22.69
1.42
I.I52
27-95
6.6
20.84
2.41
I.I50
27-5
7-i
20.51
2-59
I.I47
23-75
ii .1
17.71
4-05
I-I37
16.0
23.0
11 -93
8-39
I. Ill
10.
34-o
7.46
12 .40
I . IO5
7-5
41.0
5 60
T 4-95
I.I05
2.O
65-5
i-49
23.88
I .121
2-4
148.8 (sat.)
1.52
54.26
I .224
TOO cc. saturated HCI solution dissolve 1.9 grams KCl at 17.
(Ditte Compt. rend. 92, 142, '86.)
243
POTASSIUM CHLORIDE
SOLUBILITY OF POTASSIUM CHLORIDE IN AQUEOUS POTASSIUM
HYDROXIDE SOLUTIONS.
(Engel Bull. soc. chim. [3] 6, 16, '91; Winteler Z. Electrochem. 7, 360, 'oo.)
Resu
<
Mg. Mols. per
10 cc. Solution Sp.
Its at
Engel.)
Gr. of
>lution.
0.
Gms. per 100 cc.
Solution.
Results at
(Winteler
Gms. per zoo cc.
Solution.
20.
>
Sp. Gr. of
Solution.
KC1.
KOH.
KC1.
KOH.
KCl.
KOH."
35-5
O
159
26.83
O
o
29
3
I
.0
1.185
31.0
2
375
.146
23-44
I
33
21
.1
10
o
I. 210
28.3
4
*53
21.39
2
.64
14
.8
2O
.0
1.245
23.0
9
9
.172
17-39
5
56
10
4
30
.0
1.295
18.38
15
i
^95
13.89
8
.46
6
.8
40
.0
I -345
*4-43
20
1. 2l6
10.91
ii
2 3
4
.0
50
.0
x -397
n-43
24
.63 1.239
8.64
13
83
2
.2
60
.0
1.450
8.98
29.25 1.261
6-78
16
43
I
4
70
.0
1.500
6.28
35
.13 1.294
4-74
19
72
1
.1
80
.0
J -55o
O
9
85
.0
1.580
SOLUBILITY OF MIXTURES OF POTASSIUM CHLORIDE AND POTASSIUM
IODIDE IN WATER.
(Etard Ann. chim. phys. [7] 3, 275, '94.)
Grams per too Gms. Solution.
Grams per 100 Gms. Solution.
**
KCl.
KI.
&
KCl.
KI.
o
3-7
50-5
100
6.2
61 .0
20
4.2
53-o
140
7-3
63-7
40
4-7
55-3
180
8-3
65-5
60
S- 2
57-5
220
9-4
66 3
80
5-7
59-4
245
10.0
66.5
SOLUBILITY OF POTASSIUM CHLORIDE IN AQUEOUS MAGNESIUM
CHLORIDE SOLUTIONS.
(Precht and Wittgen Ber. 14, 1667, '81.)
Grams KCl per 100 Grams Sat. Solution in:
t. 11%
Mcrru.
MgClo.
21-2% 30%
MgClo. McrCl->.
20% MgCl 2 .
10
14
3
9
9
5'
\J
1.9
4
.2 KC1+5-7 NaCl
20
15
9
ii
3
6
5
2.6
6
.0
1 +5-9
M
30
17
5
12
7
*
,6
3-4
6
9
" +6.0
u
40
19
.0
14
.2
8
.8
4.2
7
9
" +6.1
M
50
20
5
IS
.6
10
.0
5-o
8
9
" +6.3
tt
60
21
9
17
.0
ii
.2
5-8
9
9
" +6.4
(I
80
24
5
.5
13
.6
7-3
10
9
" +6.6
11
90
25
.8
2O
.8
14
7
8.1
ii
9
" +6.7
tt
100
27
.1
22
.1
15
9
8.9
*3
.0
" +6.9
Ii
POTASSIUM CHLORIDE
244
SOLUBILITY OP POTASSIUM CHLORIDE IN AQUEOUS SOLUTIONS OF
POTASSIUM NITRATE, AND OF POTASSIUM NITRATE IN AQUEOUS
SOLUTIONS OF POTASSIUM CHLORIDE, AT SEVERAL TEMPERATURES.
(Touren Compt. rend. 130, 908, 'oo; Bodlander Z. physik. Ch. 7, 360, '91; Nicol Phil. Mag.
(Lond.) 31, 369, '91; Soch J. Physic. Ch. 2, 46, '98.)
KC1 in Aq. KNO 3 Solutions at:
14.5 (T.).
KNO.
O
20.64
32.18
62.23
82.77
115.9
II9.I
123.4
KCI.
288.3
284.2
282.1
276.8
273-5
270.7
268.3
267.2
I
7-5 (B.).
25-2 (T.).
ofctSns
Gms. per Liter.
Gms. per Liter.
'KN0 3 . KCI".
kNo 3 . KCI:
.173
o.o 293.9
o.o 311.8
. 198
65.8 275.0
13.76 306.6
.2IO
88-3 273.4
32.18 303.6
.225
124.8 265.3
91.26 293.2
.236
148.3 259.8
122.7 287.2
- 2 39
152.2 259.6
141.4 284.2
239
154.9 259.5
182.7 276.0
.241
153.3 262.4
20, etc. (N.).
Gms. per 1000 Gms.
H 2 0.
KN0 3 .
O.OO
56.18
168.54
at 21
225.8
KCI.
345-2
342.15
334-39
341-3
at 80
1175.0 402.0
KNO 3 in Aq. KCI Solutions at:
14-5.
Grams per Liter Solution.
KCI.
O.O
31-63
65.64
132.6
164.4
196.5
236.9
KNO 3 .
225.4
219.8
208.2
185.2
I S9-5
144.0
25-2".
Grams per Liter Solution.
KCI. KN0 3 .
O.O 32C.C
49.22
100.7
J 55-2
207.3
226.8
3 I2
288
-3
.7
254.0
224.4
203.9
196.9
20'
Grams per ioooGms.H 2 O.
KCI. KN0 3 . "
0.0
82.9
165.8
248.7
310.8
311.1
256.8
221.7
2O2.O
501.6
KNO 3 in Aq. KCI at 20.5 (B.), KCI in Aq. KNO 3 at 20.5 (B.).
Gms. per
ioo Gms.
Solution. Sp. Gr. of
ci.
KNO,.
0.0
27.68 1.1625
4.72
24-39
.1700
7-74
22.44 J
1765
12.23
20.23
.1895
J 5-i5
18.96
.1983
19.61
17.67 ]
.2150
22.17
I7-II
.2265
24-96
16 79 1.2400
Gms. per
Solu
ioo Gms.
tion.
Sp. Gr. of
" 1 *.'
KN0 3 .
KCI.
Solutions.
O.O
29-39
.1730
6.58
27.50
.1980
8.88
27-34
.2100
12.48
26-53
.2250
14.83
25.98
.2360
15.22
25-96
.2390
15-49
25-95
.2388
15-33
26.24 :
[.2410
245
POTASSIUM CHLORIDE
SOLUBILITY OF MIXTURES OF POTASSIUM CHLORIDE AND POTASSIUM
SULPHATE IN WATER.
t.
10
15.8
20
25
30
Gms.
per too Gms.
H 2 0.
KCI
28
33
36
4
.1
K 2 SO.
1.32
2-3
i-43
2-93
Observer.
(Precht and Wittgen.)
(Kopp.)
(P.and W.)
(Van't Hoff and Meyerhoffer.)
(P. and W.)
t e .
Gms. per roo Gms.
H 2 0.
KCI -i
- K 2 so;.
40
38.7
1.68
5
41-3
1.82
60
43-8
i-94
80
49.2
2.21
100
54-5
2-53
Observer.
(P. and W.)
SOLUBILITY OF MIXTURES OF POTASSIUM CHLORIDE AND SODIUM
CHLORIDE IN WATER.
( (i) Precht and Wittgen Ber. 14, 1667, '81; at 25 and'at 80, (3) Soch T. Physic. Ch. 2. *6 '08
(2) Etard Ann. chim. phys. [7] 3, 275, '97-)
Grams per 100 Grams H 2 O.
KCI. NaCl.
Grams per 100 Grams H 2 O.
KCI. NaCl. *
22.0(1)19.0(2) 27.7(1)32.3(2)
24.6 20.6 27.2 32.8
27-3 32-5 26.8 34.1
30.0(3)25.2(3) 26.4(3)34.0
32.9 28.4 26.1 32.3
34-7 32-3 25.8 30.6
NOTE. Page and Keightly, Rudorff and also Nicol, give single
determinations which lie nearer the results of Precht and Wittgen
than to those of Etard.
o
II.
2(1
)n
.2(2'
> 30,
oO
[ )3O
0(2)
5
10
12.
5
12.3
29
7
30
5
60
20
14.
7
13
.8
29
.2
3 1
.0
70
25
15.8(3)14
5
29
.0(3)31
3
80
30
17-
2
15
4
28
7
3 1
5
90
40
19.
5
.0
28
.2
9
100
SOLUBILITY OF POTASSIUM CHLORIDE IN AQUEOUS SOLUTIONS OP
SODIUM CHLORIDE, AND OF SODIUM CHLORIDE IN AQUEOUS SOLU-
TIONS OF POTASSIUM CHLORIDE, AT 20.
(Nicol Phil. Mag. (Lond.) 31, 369, '91.)
KCI in Aq. NaCl Solutions.
Grams per 100 Grams H 2 O.
' NaCl. KCI.
O-O
6-5
13.0
34-52
29-37
4-71
.42
NaCl in Aq. KCI Solutions.
Grams per 100 Grams H>O.
KCI.
o.o
4-i4
8.29
12.42
35.91
34-39
32.71
3 I -3
100 gms. 40 per cent by wt. alcohol dissolve 5.87 gms, KCI + 12.25
gms. NaCl at 25.
100 gms. 40 per cent by wt. alcohol dissolve 5.29 gms. KNO 3 + 10.06
gms. KCI at 2 5. ( s ch - j. physk. Ch. 2, 4 6, '98.)
100 gms. abs. ethyl alcohol dissolve 0.034 gm. KCI at 18.5.
100 srrns. abs. methyl alcohol dissolve 0.5 gm. KCI at 18.5.
(de Bruyn Z. physik. Ch. 10, 783, '92; Rohland Z. anorg. Ch. 18, 327, '98,)
POTASSIUM CHLORIDE
246
SOLUBILITY OP POTASSIUM CHLORIDE IN AQUEOUS ALCOHOL.
(Gerardin Ann. chim. phys. [4] 5, 140, '65.)
Interpolated from the original results.
Grams KCl per 100 Gms. Aq. Alcohol of Sp. Gr.:
t.
0.9004
= 5-5
0.9848
9-35
0.9793
= 13.6
0.9726
= 19.1
0.9573
30
0.939
= 40
0.8967
= 60
v
0.8244
= 90
Wt.%.
Wt.%.
Wt.%.
Wt.%.
Wt.%.
Wt.%.
Wt.%.
Wt.%.
o
23-4
19-5
15-5
"$
7.0
4.0
i-7
o.o
5
25.0
21 .0
16.8
12.8
8.0
4.8
2 .2
o.o
10
26.4
22.5
18.0
14.0
9.0
5-6
2.7
o.o
J 5
26.8
24.0
19.2
15.2
IO-O
6.4
3-i
0.04
20
29.1
25-3
20.3
16.1
10.8
7.2
3-5
0.06
2 5
30-4
26.8
21-5
17.1
n. 6
7-9
3-9
0.08
3
31-7
28.0
22 .6
18.2
12.5
8-5
4.2
O-IO
40
34-3
30-8
24.8
20. o
14.0
9-9
4.8
O.20
5
37-o
33-5
27.0
21.8
15-5
10.8
5- 2
0.30
60
16.8
ii. 8
5-5
O.4O
SOLUBILITY OF POTASSIUM CHLORIDE IN AQUEOUS ALCOHOL AT
i5- 14.5.
(Schiff Liebig's Ann. 118, 365, '61.) (Bodlander Z. physik. Ch. 7, 316, f px->
Sp. Gr. Wt. G. KCl per
of per cent 100 cr AQ
Sp. Gr.
of Sat.
Grams per 100 cc. Solution.
Alcohol. Alcohol. Alcohol.
Solutions.
C 2 H 6 OH.
H 2 O.
KCl.
0.984 10 19.8
I.I720
...
88.10
29.10
O.972 2O 14.7
I.I542
2.79
85.78
26.85
0.958 30 10-7
I .1365
4.98
84.00
24.67
0.940 40 7.7
I.I075
10.56
79-63
20-56
0.918 50 5.0
I .1085
15-57
75-24
17.24
0.896 60 2.8
1-0545
2O.66
70.52
14.27
o . 848 80 o . 45
i -0455
24.25
67.05
I3-25
Gerardin's results at 15 agree
0.9695
40.42
50.18
6-35
well with the above deter-
-93!5
48.73
40.60
3.82
minations.
0.8448
68.63
15-55
0.30
30 and 40.
(Bathrick J. Physic. Chem. I, 160, '96.)
Wt.
per cent
Gms. KCl per 100 Gms.
Aq. Alcohol.
Wt.
per cent
Gms. KCl per 100 Gn
Aq. Alcohol.
Alcohol.
At 30.
At 40.
Alcohol.
At 30.
At 40.
O
38.9
41.8
43.1
II. I
I3-I
5-28
33-9
35-9
55-9
6.8
8.2
9-43
30.2
33-3
65 9
3-6
4.1
16.9
24.9
27 .6
78.1
i-3
1.6
2 5-i
19.2
21.8
86.2
0.4
o-5
IS -6
17.2
247
POTASSIUM CHLORIDE
SOLUBILITY OF POTASSIUM CHLORIDE IN AQUEOUS ACETONE
SOLUTIONS.
(Snett J. Physic. Ch. 2, 484, '98; at 20, Herz and Knoch Z. anorg. Ch. 41, 317, '04.)
Per cent
Acetone
in
KCl
At 20.
per loo cc.
Solution.
At 30.
Gms. per 100 Gms.
Solution.
At 40.
Gms. per 100 Gms.
Solution.
At 50.
Gms. per 100 Gms.
Solution .
Solvent.
Millimols.
Grams.
Acetone.
KCl.
Acetone.
KCl.
Acetone.
KCl.
O
410,
5
3-
62
O. O
27.27
O.
o
28.69
0.0
30.0
9.1
351
, 7
26.
23
6.96
23.42
6.
79
25-33
. . .
.
2O
286
.6
21.
38
16.22
18.90
15-
75
21.28
. . .
30
223.
, 7
16.
69
25-45
15.06
two layers
25.67
14.42
40
166.
r
12.
42
35-52
11.31
36.03
9-93
50
i*5
4
8.
61
45.98
8.04
a
46.46
7.07
60
7 1
, 2
5.
31
56.91
5-i2
"
57-37
4-38
70
38.
5
2.
87
68.18
2.60
"
68.56
2.22
80
12,
9
0.
96
78.43
0.76
79-
34
0.58
79.25
0.94
9
2
,0
0.
J 5
89.88
0.13
89.
84
o. 16
8i+sat.sol.
IOO
O
,o
o.
100.0
0.00
IOO.
00
0.00
NOTE. For the 20 results the per cent acetone in the solvent is
stated in terms of volume per cent, and the concentration of the second
solution is 10 per cent instead of 9.1 which is the concentration of the
solvent for the corresponding results at the other temperatures.
AT THE TEMPERATURE 40 AND FOR CONCENTRATIONS OF ACETONE
BETWEEN 20 AND 80 PER CENT THE SATURATED SOLUTION SEPAR-
ATES INTO Two LAYERS HAVING THE FOLLOWING COMPOSITIONS:
Upper Layer.
Grams per 100 Grams Solution.
HgO.
(CH 3 ) 2 CO.
KCl.
55-2
31.82
12.99
53-27
35-44
ii .29
51 .23
48-50
10.27
50.3 +
39-88
9-77
48.O2
43.18
8-79
46.49
45-34
8.17
58.99
25.24
15-77
Lower Layer.
Grams per 100 Grams Solution.
H 2 0.
(CH 3 ) 2 CO.
KCl.
28.14
69.42
2-44
30.96
65-97
3-07
32.64
63-79
3-56
34-07
62.01
3-92
37-44
57-67
4.89
38-. 68
56-I7
5-25
23.66
74-91
1-43
zoo cc. sat. solution of potassium chloride in furfurol (C 4 H 3 O.COH)
contain 0.085 gm. KCl at 25.
(Walden Z. physik. Ch. 55, 7i3,'o6.)
POTASSIUM CHLORIDE
248
SOLUBILITY OF POTASSIUM CHLORIDE IN AQUEOUS SOLUTIONS OP
GLYCERINE AT 25.
(Herz and Knoch Z. anorg. Ch. 45, 267, '05.)
Sp. Gr. of Glycerine at 25/4 = I - 2 555-
Impurity about 1.5%.
Wt. per cent
Glycerine in
Solvent.
KCl per ioo cc.
Solution.
Sp. Gr. of
Solutions.
Wt. per cenl
Glycerine ii
Solvent,
KCl per ioo cc.
! Solution
Sp. Gr. of
Solutions.
Millimols.
Grams.
Millimols.
Grams.
424
5
3 1
,66
I.lSo
54-23
238.5
17.79
I
.219
13.28
383
4
28,
.61
1.185
83.84
149.0
II. II
I
259
25.98
339
3
25
3 1
I.I94
100.00
no. 6
8.25
I
.286
45-36
271
4
20
.24
I .211
ioo grams H 2 O dissolve 246.5 grams sugar 4- 44.8 grams KCl at
31.25, or ioo grams of the sat. solution contain 62.28 grams sugar
+ 11.33 grams KCl.
(Kohler Z. Ver. Zuckerind. 47. 447. '97 )
POTASSIUM CHEOMATE K 2 CrO 4 .
POTASSIUM (Di) CHEOMATE K 2 Cr 2 O 7 .
SOLUBILITY OF EACH IN WATER.
(Alluard Compt. rend. 50, 500, '64; Nordenskjold and Lindstrom Pogg. Ann. 136, 314, '69;
Etard Ann. chim. phys. [7] 2, 527, '94; Kremers Pogg. Ann. 92, 497, '54; Tilden and Shenstone
Phil. Trans. 23, 1884.)
Potassium Chromate.
Grams per ioo Grams Water.
Potassium Di Chromate.
o
5 8.2*
59 -3t
60.2$
10
6o.O
61.2
62.5
20
61.7
63.2
64-5
25
62.5
64.2
64-5
30
63.4
65-2
66.5
40
65 .2
67.0
68.6
50
66.8
69.0
70.6
6
68.6
71.0
72.7
70
70.4
73-o
74-8
80
72.1
75-o
76.9
90
73-9
77.0
79.0
IOO
75-6
79.0
82.2
'25
79.0
15
83.0
Grams per ioo Grams Water.
5*
S
7
7
12
12
16
16
20
20
26
27
34
37
43
47
52
58
61
70
70
82
80
97
no
145
H3
205
* Etard.
t Alluard.
$ N. and L.
A., K., T. and S.
249
POTASSIUM CHROMATE
SOLUBILITY OF POTASSIUM CHROMATES IN WATER AT 30.
(Schreinemaker Z. physik Ch. 55, 83, '06.)
Composition in Wt. per cent of:
The Solution.
The Residue.
'er cent CrO 3 <
Per cent KjO.
Per cent CrO 3 .
Per cent KaO.
O
47
o.o
47.16
12.59
47-54
0.1775
34.602
10-93
37-47
I-35 1
26.602
16.482
32.532
20.584
37-I3I
39-922
15-407
19.225
27.966
29.377
20-67
19.17
. . .
19.096
17.30
37 . 64
22 .6l
I]C -35
7.88
17-93
3.412
2 C 8<\
7 .82
43.51
3.01
49-45
9.91
44.46
3-245
53-94
12 .40
46.368
2.823
60.314
12 .935
49-357
2-353
63.044
11.684
53-215
1.360
62.958
8.002
62-55
0.796
67.944
6.731
0.621
70.0
4-0
62.28
o.o
. . .
. . .
Solid
Phase.
KOH-aHaO
K 2 Cr0 4 +K 2 Cr 2 0,
K 2 Cr 4 O l3 -hCrO,
CrO 3
ioo gms. sat. solution in glycol C 2 H 4 (OH) 2 .H 2 O contain 1.7 gms.
K 2 CrO 4 at 15.4.
ioo gms. sat. solution in glycol C 2 H 4 (OH) 2 .H 2 O contain 6.0 gms.
K 2 Cr 2 O 7 at 14.6. (d e Coninck Bull. acad. roy. Belgique, 25?. '05.)
POTASSIUM CITRATE C 3 H 4 (OH)(COOK) 3 .H 2 O.
SOLUBILITY IN WATER AND IN SATURATED SUGAR SOLUTION AT 31.25.
(Kohler Z. Ver. Zuckerind. 47, 447, '97.)
ioo gms. H 2 O dissolve 169.7 gms. C 6 H 5 O 7 K 3 , or ioo gms. sat. solu-
tion contain 61.11 gms.
ioo gms. H 2 O dissolve 198.3 gms. C 6 H 5 O 7 K 3 4- 303.9 gms. sugar,
or ioo gms. sat. solution contain 32.83 gms. C 6 H 5 O 7 K 3 4- 50.3 gms.
sugar.
POTASSIUM CYANATE KCNO.
SOLUBILITY IN ALCOHOLIC MIXTURES.
(Erdmann Ber. 26, 2439, '93.)
o _. _ t Grams KCNO per
3olvent - Liter Solvent at bYpt.
80 per cent Alcohol + 20 per cent Water 62
80 per cent Alcohol +20 per cent Methyl Alcohol 76
80 per cent Alcohol + 10 per cent Acetone 82
POTASSIUM CYANIDE KCN.
ioo gms. H 2 O dissolve 122.2 gms. KCN, or ioo gms. sat. solution
contain 55.0 gms. KCN at 103.3. (Griffiths.)
ioo gms. abs. ethyl alcohol dissolve 0.87 gm. KCN at 19.5.
ioo gms. abs. methyl alcohol dissolve 4.91 gms. KCN at 19.5.
(de Bruyn Z. physik, Ch. 10, 783, '93.)
ioo gms. glycerine dissolve 32 gms. KCN at 15.5.
POTASSIUM CYANIDES 250
POTASSIUM OHROMOCYANIDE K 3 Cr(CN) 6 .
100 gms. H 2 O dissolve 32.33 gms. K 3 Cr(CN) 6 at 20.
(Moissan Ann. chim. phys. [6] 4, 136, '85; Christensen J. pr. Ch. [2] 31, i66,'3s.)
POTASSIUM OHROMISULPHOCYANIDE K 2 Cr(SCN) 6 . 4 H 2 O.
100 gms. H 3 O dissolve 139 gms. salt.
(Karsten Ann. Suppl. 3, 170.)
POTASSIUM CARBONYL FERROOYANIDE K 3 FeCO(CN) 5 . 3 m,O.
100 gms. H 2 O dissolve 148 gms. salt at 16.
(Muller Com pt. rend. 104, 992, '87.)
POTASSIUM FERRICYANIDE K 3 Fe(CN) 6 .
POTASSIUM FERROCYANIDE K 4 Fe(CN) 6 . 3 H 2 O.
SOLUBILITY OF EACH IN WATER.
(Wallace J. Ch. Soc. 7. 8, '85 ; Etard Ann. chim. phys. [7] 2, 526, '94; Schiff Liebig's Ann.
H3t 35 '60; Michel and Krafft Ann. chim. phys. [3] 41, 478, '58; Thomsen.)
NOTE. The available determinations fall very irregularly when
plotted on cross- section paper, and the following figures, which are
averages, are therefore hardly more than rough approximations to the
true amounts. The figures under K 4 Fe(CN) 6 show the limits between
which the correct values probably lie.
Grams per 100 Gms. H2O. Grams per TOO Gms. HuO.
K3Fe(CN) 6 . K 4 Fe(CN) 6 . KaFe(CN) 6 .
o 31 13 ... 40 60 38 70
10 36 20 20 60 66 52 83
20 43 25 40 80 ... 66 89
25 46 28 48 100 ... 76 91
30 50 32 57 104.4 82.6
POTASSIUM FLUORIDE KF.2H 2 O.
100 gms. H 2 O dissolve 92.3 gms. KF, or 100 gms. sat. solution
contain 48 gms. KF at 18. Sp. Gr. of solution =1.502.
(Mylius and Funk Ber. 30, 1718, '97.)
SOLUBILITY OF POTASSIUM FLUORIDE IN HYDROFLUORIC ACID AT 21.
(Ditte Compt. rend. 123, 1282, '96.)
Gms. per 100 Gms. H^O. Gms. per 100 Gms. HoO. Gms. per TOO Gms. H2O.
HF. KF.
o.o 96.3
I. 21 72.0
1.61 61 .o
3-73 40-4
4-03 32.5
6.05 30.4
HF.
KF.
HF.
KF.
9-25
29.9
20.68
38.4
11.36
29.6
28.60
46.9
12 .50
30-5
41.98
61.8
13 ,95
53-71
74.8
15.98
33-4
74-20
105.0
17.69
35 - 62
119.20
169.5
25 1
POTASSIUM FORMATE HCOOK.
POTASSIUM FORMATE
SOLUBILITY OF POTASSIUM FORMATE AND OF THE ACID SALT
IN WATER.
(Groschuff Ber. 36, 1785, 1903.)
Solid Phase : HCOOK
Solid Phase : HCOOK. HCOOH.
Gms.
HCOOK
t. per ioo
Gms.
Mols.
HCOOK
per ioo
Mols.
Gms. HCOOK Gms.
.HCOOH HCOOK
t . per ioo per ioo t .
Gms. Gms.
Gms,
HCOOK
per ioo
Gms
Mols.
HCOOH
Solution.
H 2 0.
Solution.
Solution.
Solution
. HCOOK.
20
7 2.8
57
4
O
60.4
39
o
o
36
3
3-21
+ 18
76.8
o
25
69.8
45
.1
19-5
38
.2
2 .96
50
80.7
89
.8
50
79.2
5 1
.2
39-3
40
.8
2.65
90
86.8
141
.0
80
90.7
58
.6
60
44
.0
2-33
1 2O
92.0
247
.0
70
45
9
2 .l6
140
96.0
90
S 2
.1
1.68
n;7
IOO.O
00
Sp. Gr. of sat. sol. at 18= 1.573.
NOTE. Since the acid salt is less soluble at ordinary temperatures
than the neutral salt, it can be precipitated from the solution of the
neutral salt by addition of aqueous formic acid. Proceeding in this
way an impure product is obtained, giving solubility values (expressed
in HCOOK) as shown in the last three columns above.
POTASSIUM FLUOGERMANATE K 2 GeF 6 .
SOLUBILITY IN WATER.
(Winkler; Kruss and Nilson Ber. 20, 1696, '87.)
ioo gms. H 2 O dissolve 173.98 gms.ICGeF 6 at 18, and 34.07 gms.
at 100 (W. ).
ioo gms. H.,O dissolve 184.61 gms. K 2 GeF e at 18, and 38. 76 gms. at
100 (K. and N.).
POTASSIUM HYDROXIDE KOH.
SOLUBILITY IN WATER.
(Pickering J. Ch. Soc. 63, 908, '93; at 15, Ferchland Z. anorg. Ch. 30, 133, '02.)
Solid
Phase.
KOH. 2 H 2
t fl
Gms. KOH
', per ioo Gms.
Solid
T>U^.
Gms. KOH
t o. per ioo Gm?.
Water.
Solution.
Water. Solution.
22
3
7
3
.6
Ice
15
107
5 1
7
20
,7
22
5
18
4
"
20
112
S 2
.8
-65
2
44
5
3
.8
30
126
55
.76
-36
.2
36
.2
26
.6
KOH. 4 H 2 O
32-5
135
57
44
-32
7
77
94
43
.8
50
I4O
58
33
-33
80
44
4 KOH^HizO+KOH.aHjjO
IOO
I 7 8
64
03
-23
2
85
45
9
KOH. 2 H 2 O
125
213
68
.06
o
97
49
.2
"
143
3 11
7 75
73
10
I0 3
50
7
<
KOH.2H;
[20 +
KOH-HzO
KOH.H 2
Sp. Gr. of sat. solution at 15 = 1.5355.
POTASSIUM IODATE 252
POTASSIUM IODATE KIO 3 .
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 97, 5. '56; at 30, Meerburg Ch. Weekbl. I, 474, '04.)
t 20 30 40 60 80 100
Cms. KIO 3 per
100 gms. H 2 O 4.73 8.13 11.73 I2 -8 18.5 24.8 32.2
100 gms. H 2 O dissolve 1.3 gms. potassium hydrogen iodate(KH(IO s ) 2
at 15, and 5.4 gms. at 17. (Serullas - Ann. chim. phys. 22, 118.)
ioo gms. H 2 O dissolve 4.0 gms. potassium di hydrogen iodate
KH 2 (IO 3 ) 2 at 1 5. (Meineke Liebig's Ann. 261. 360, '91 ,)
POTASSIUM IODIDE KI.
SOLUBILITY IN WATER.
(Mulder; de Coppet-j- Ann. chim. phys. [5] 30, 417, '83; Etard Ibid. [7] 2. 526, '94; Meusser
Z. anorg. Ch. 44, 80, '05; see also Tilden and Shenstone Phil. Trans. 23, J 84; Schreinemaker
Z. physik. Chem. 9, 71, '92.)
Gms. KI per ioo Gms. Gms. KI per ioo Gms.
Water. Solution. *- Water. Solution.
-io 115.1 53.5 80 192 65.8
- 5 119.8 54.5 90 200 66.7
- I 122.2 55.0 IOO 208 67 5
o 127.5 5 6 - no 215 68 3
10 136 57.6 120 223 69 O
20 144 59.0
25 148 59.7 Ice Curve
30 152 60.3 - 5 25.7 22 5
40 160 61.5 7 42.6 29.9
50 168 62.7 - 9.5 51.5 34.0
60 176 63.7 -H-5 6 4-7 39-3
70 184 64.8 14 75-8 4 2 7
SOLUBILITY OF POTASSIUM IODIDE IN ABSOLUTE ALCOHOLS.
(de Bruyn Z. physik. Ch. io, 783, '92; Rohland Z. anorg. Ch. 18, 327, '98.)
ioo gms. methyl alcohol dissolve 16.5 gms. KI at 20.5.
ioo gms. ethyl alcohol dissolve 1.75 gms. KI at 20.5.
ioo gms. propyl alcohol dissolve 0.46 gm. KI at i5-2o (R.)
SOLUBILITY OF POTASSIUM IODIDE IN:
Ethyl Alcohol
of 0.9496 Sp. Gr.
Aqueous Ethyl Alcohol at 1 8.
f ~
Gms. KI per
Sp. Gr.
Weight
Gms. KI
Sp. Gr.
Weight Gms. KI
t 8 .
IOO
Gms. Alcohol
of
Alcohol.
per cent
Alcohol.
per ioo Gms.
Alcohol.
of
Alcohol.
per cent per ioo Gms
Alcohol. Alcohol.
8
67.4
0.9904
5- 2
I30-5
0.9390
45 66.4
13
69.2
0-9851
9-8
119.4
0.9088
59 48-2
2 5
75- 1
0.9726
23.0
IOO. I
0.8464
86 11.4
46
84.7
0.9665
29.0
89.9
0.8322
91 6.2
55
87-5
0.9528
38.0
76.9
62
90.2
(Gerardin
Ann. chim. phys. [4] 5, 155, '65.)
253 POTASSIUM IODIDE
SOLUBILITY OF POTASSIUM IODIDE IN ACETONE AND IN PYRIDINE.
(von Laszcynski Ber. 27, 2285, '94; at 25, Krug and McElroy J. Anal. Ch. 6, 184,, '92.)
Solvent.
Gms. KI per 100 Gms. Solvent at:
-2.5. 10. 22. 25. 56. 119.
Acetone 3-08 ... 2.38 2.93 1.21
Pyridine ... 0.26 ... ... ... o-ii
100 gms. glycerine dissolve 40 gms. KI at 15.5.
SOLUBILITY OF POTASSIUM IODIDE IN SEVERAL SOLVENTS.
(Walden Z. physik. Ch. 55, 714, '06.)
Solvent .
Formula
t |P- G .r. of
Gms. KI per
too
' Solution.
cc. Solution. Gms. Solution .
Water
H 2 O
O I . 6699
94
5
56.32
Water
H 2
25 L7254
102
.70
59-54
Methyl Alcohol
CH 3 OH
o 0.8964
II
.6l
I2 .95
Methyl Alcohol
CH 3 OH
25 0.9003
13
5-14.3
14.97
Ethyl Alcohol
C 2 H 5 OH
o 0.8085
I
.197
1.479
Ethyl Alcohol
C 2 H 5 OH
25 o. 7908
I
.520
1.922
Glycol
(CH 2 OH) 2
o 1.3954
43
.28
31-03
Glycol
(CH 2 OH) 2
25 1.3888
47
23
33-oi
Acetonitril
CH 3 CN
o 0.8198
1.852
2-259
Acetonitril
CH 3 CN
25 0.7938 I
57
2.003
Propionitril
C 2 H 5 CN
o 0.8005
o
34-0.41
0.0429
Propionitril
C 2 H 5 CN
25 0.7821
.32-0.36
0.0404
Benzonitril
C 6 H 5 CN
25 I . 0076
o
.051
0.0506
Nitro Methane
CH 3 NO 2
o 1.1627
.314-0.366
0-315
Nitro Methane
CH 3 N0 2
25 1.1367
o
289-0.349 0.307
Nitro Benzene
C 6 H 5 N0 2
25
.0019
Acetone
(CH 3 ) 2 CO
o 0.8227
I
732
2.105
Acetone
(CH 3 ) 2 CO
25 o. 7968
I
.038
1.302
Furfural
C 4 H 3 O.COH
. . .
15
.10
. . .
Furfural
C 4 H 3 O.COH
25
.2014
5
93
4.94
Benzaldehyde
C 6 H 6 COH
25
.0446
343
0.328
Salicyl aldehyde
C 6 H 4 .OH.COH
.1501
I
257
1.093
Salicyl aldehyde
C 6 H 4 .OH.COH
25
1373
549
0.483
Anis aldehyde
C 6 H 4 .OCH 3 .COH
.1223
I
.520
1-355
Anis aldehyde
C 6 H 4 .OCH 3 .COH
25
.1180
.720
0.644
Ethyl Acetate
CH 3 COOC 2 H 5
25
o
.0013
Methyl Cyan Acetate
CH 2 CNCOOCH 3
.1521
3.256
2.827
Methyl Cyan Acetate
CH 2 CNCOOCH 3
25
.1358
2
459
2.165
Ethyl Cyan Acetate
CH 2 CNCOOC 2 H a
25
.0628
O
.989
0.930
POTASSIUM NITRITE 254
POTASSIUM NITRITE KNO 2 .
100 gms. H 2 O dissolve about 300 gms. KNO 2 at 15.5.
(Divers J. Ch. Soc. 75. 86, '99-)
POTASSIUM NITRATE KNO,.
SOLUBILITY IN WATER.
(Mulder; Andrae J. pr. Ch. [2] 29, 456, '84; Gerardin Ann. chim. phys. [4] 5, 150, '65; Etard
Ibid. [7] 2, 526, '94; Ost J.pr. Ch-feTi?, 233, '78; at 31-25. Kohler Z. Ver. Zuckerind. 47, 447,
'97; Euler Z. physik. Ch-49, 315, '04; Tilden and Shenstone Phil. Trans. 23, '84;Berkeley Trans.
Roy. Soc. 203 A, 213, '04.)
Average Curve.
Gms. KNOa per ioo Gms. Gms.KNO 3 per TOO Gms.
Water. Solution. Water. Solution.
o 13-3 11.7 70 138 58.0
10 20.9 17.3 80 169 62.8
20 31.6 24.0 00 202 66.9
25 37.3 27.2 ioo 246 71.1
30 45-8 3 x -4 no 300 75.0
40 63.9 39.0 120 394 79.8
50 85.5 44.0 125 493 83.1
60 no.o 52.0
SOLUBILITY OF MIXTURES OF POTASSIUM NITRATE AND BARIUM
NITRATE IN WATER.
(Euler Z. physik. Ch. 49, 313, '04.)
t. Sp. Gr. of Sat. Solution. Grams per ioo Grams HaO.
17 1. 120 i3.26KNO 3 + 6.31 Ba(NO 3 ) 2
21.5 ... 17.00 " + 7.58
30 1.191 24.04 " 4- 9-99 "
50 49-34 +18.09
SOLUBILITY OF POTASSIUM NITRATE IN AQUEOUS SOLUTIONS OF NITRIC
ACID AT o.
(Engel Compt. rend. 104, 913, '87.)
Sp. Gr. of
Equivalents per 10 cc. Solution.
Grams per ioo cc. Solution.
Solutions*
1.079
i2.5KNO 3 o HNO 3
i2.65KNO 3 o.ooHNO 8
9.9 "
5-87
10.02 "
3-7 1
"
1.093
8.28 "
13-2
8. 3 8 "
8.38
tt
1.117
7-4 "
2i-55
7-49
13-58
Is
1.144
7-4
31.1 "
7-49 "
19.47
H
i .202
7.6
48.0
7.68 "
30.04
M
1.289
10.3 "
68.0
10.42 "
42.86
M
1.498
28.3 "
120.5 "
28.64 "
75-95
M
255
POTASSIUM NITRATE
SOLUBILITY OF POTASSIUM NITRATE AND OF ACID POTASSIUM NITRATES
IN NITRIC ACID.
(Groschuff Ber. 37, 1490, '04.)
NOTE. - Determinations made by the so-called thermometric
method, i.e., by observing the temperature of the disappearance of
the separated, finely divided solid from solutions of known concen-
tration.
Grams per 100 Gms.
Gms. per 100 Gms.
t . Solution.
Solid
Phase.
t . Solution.
Solid
T>Un
KNO 3 .
HN0 3 .
KNO 3 .
HN0 3 .
.rnase.
- 6
24.4
75-41
KN0 3 . 2 HNO 8 (i)
22-5
47-2
52-93
KNO 3 .HNO 3
+ 14
32-6
67.42
(stabil)
47-8
52.11
" (stabil)
17
34-8
65.04
44
25-5
48.6
51.46
"
19
5 37-2
62 .90
44
27.0
49-4
50.78
44
22
44-5
55-46
44
29.0
50.1
49-94
KN0 3 .HN0 3
21
5 47-8
52.11
KN0 3 . 2 HN0 3 (2)
30-5
5-9
49-15
(labil)
21
5 48.6
51.46
(labil)
21 .O
49-4
50.78
KNO 8 (labil)
20
50-9
49-15
44
39-o
5 -9
49-15
" (stabil)
- 4
37-2
62.81
KNO 3 .HNO 8
5o
51 .7
48-32
-16
5 44-5
55-46
(labil)
C>
Solution in
HNOs.
(')
Solution in
KNO 3 .
CONDUCT
OF ACID POTASSIUM
NITRATE TOWARDS WATER.
Gms. per 100 Gms.
t. Solution.
Solid
Phase.
Gms. per 100 Gms.
t_ Solution.
Solid
Phase.
KN0 3 .
HN0 3 .
KN0 3 .
HN0 3 .
22
44-5
55-5
KNO 3 .2HNO 8
50
38.7
48.3
KNOj
20
5 44-i
55-o
44
61
36.0
44 .8
44
18
43-8
54-5
41
63
34-5
43 -
44
12
43 -
53-6
60.5 30.9
39-5
41
6
42-3
52-7
44
56
27 .6
34-4
44
41 .6
51-8
44
43
20.8
25-9
44
J 2
4i-3
51 .4
KNO 3
17
ii. 7
16.6
44
22
40.9
51-0
44
-5
5-54
6.91
44
40
39-9
49-8
44
SOLUBILITY OF MIXTURES OF POTASSIUM NITRATE AND POTASSIUM
CHLORIDE IN WATER.
(Etard Ann. chim. phys. [7] 3, 283, '94; at 20, Riidorff Ber. 6, 482, '73; Nicol Phil. Mag. [5]
31, 385, '91.)
Gms. per 100 Gms.
t. Solution.
Gms. per 100 Gms.
t. Solution.
Gms. per 100 Gms.
t. Solution.
KN0 3 .
KCl.
KN0 3 .
KCl.
KN0 3 .
KCl.
O
5-o
2O
O
30
16
.0
21
.2
70
39-5
17-5
10
8.0
2O
.8
40
21
-0
21
80
45-5
15-8
20
12.6
21
.2
50
27
20
O
100
57-5
ii. 6
25
14-0
21
3
60
33
5
19
O
120
69.0
7-7
POTASSIUM NITRATE 256
SOLUBILITY OP POTASSIUM NITRATE IN AQUEOUS SOLUTIONS OF:
(Touren Compt. rend. 131, 259, 'oo.)
Potassium Carbonate. Potassium Bi Carbonate.
Results at 14.5. Results at 14.5.
Mols. per Liter. Gms. per Liter. Mols. per Liter. Grams per Liter.
KaCO,.
KN0 3 .
KjC0 3 .
KJ\0 3 .
KHC0 3 .
KN0 3 .
KHCOs.
KN0 3 .
o.o
2
.228
o
o
225
O
2
33
0.0
236
0-48
I
85
66
4
188
39
2
i7
39-o
22O
I - 2 5
I
39
172
9
141
O
.76
2
03
76.0
205
2.58
.86
356
9
87
I
.16
I
.92
116
194
3-94
.64
544
9
65
I
55
I
.81
J 55
I8 3
Results at
35.
Results at
35.
o.o
3
.217
o
o
326
o
.0
3
.28
o.o
332
o-59
2
.62
81
.6
265
.89
2
.84
8 9
287
i-35
I
97
186
7
199
I
33
2
65
J 33
268
2 .IO
I
.46
290
5
148
I
.91
2
45
191
249
2.70
I
.14
373
.6
"5
3-58
0.79
495
.1
80
SOLUBILITY OF MIXTURES OF POTASSIUM NITRATE AND POTASSIUM
SULPHATE IN WATER.
(Euler Z. physik. Ch. 49, 313, '04.)
t". Sp. Gr. of Sat. Solution. Grams per 100 Grams Water.
15 1.165 24.12 KNO 3 " 5.65K 2 SO 4
20 ... 30.10 " 5.58 "
25 I. 210 3 6.12 5.58
SOLUBILITY OF MIXTURES OF POTASSIUM NITRATE AND SODIUM
CHLORIDE IN WATER.
(Etard Ann. chim. phys. [7] 3, 283, '94;
agree well with those of Etard.)
Gms. per 100 Gms.
t. Solution. t t
the older determinations of Riidorff, Karsten, Mulder, etc,
Gms. per 100 Gms. Gms. per 100 Gms.
Solution. t. Solution.
KNOs.
NaCl
KN0 3 .
NaCl.'
KN0 3 .
NaCl.
O
13
24
40
30-5
19
120
73
8
.0
10
16
23
5o
36
17
140
77
7
.0
20
20
22
00
42-5
15
160
79
5
6
.0
25
23
21
5
80
55
12
170
80
5
c
5
30
25
20
5
100
67
9-5
SOLUBILITY OF POTASSIUM NITRATE IN AQUEOUS SOLUTIONS OF SODIUM
NITRATE AND VICE VERSA AT 20.
(Carnelly and Thomson J. Ch. Soc. 53, 782, '88; Nicol Phil. Mag. 31, 369, '91.)
KNO a in Aq. NaNO 3 Solutions. NaNO 3 in Aq. KNO 3 Solutions.
Grams per TOO Grams HgO. Grams per 100 Grams I^O.
NaN0 3 . KN0 3 " KNO 3 . " NaNOa. "
o 31.6 o 88
10 30 .5 10 90
20 31 .0 20 92
40 33-o 25 93
60 35.5 30 94
80 41-0 35 96
257 POTASSIUM NITRATE
SOLUBILITY OF MIXTURES OF POTASSIUM NITRATE AND SILVER NITRATE
IN WATER.
(Etard Ann. chim. phys. [7] 3, 283, '94.)
Gms. per 100 Gms. Sol.
A Gms. per 100 Gms. Sol.
t .
Gms. per 100 Gms.S
t .
KN0 3 .
AgNOa.
KN0 3 -
AgNO 3 .
'
KNO 3 .
AgN0 3 .
*3-5
43
O
30
26
.8
49
4
80
36.2
55-i
10
IQ.O
44
7
40
29
.6
51
5
100
38.3
55-3
20
23.0
47
.0
SO
3 2
.0
54
.0
120
4O.O
55-6
2 5
25.0
48
.0
60
33
5
54
.8
I4O
41-5
55-8
SOLUBILITY OF MIXED CRYSTALS OF POTASSIUM NITRATE AND SILVER
NITRATE IN WATER AT 25.
(Herz Inaug. Diss. (Berlin) '05; Calc. by Fock Z. Kryst. Min. 28, 405, '97.)
Grams
per Liter.
Mg. Mols.
per Liter.
Mol. per cent
AgNO 3 in
Solution.
Mol. per cei
AgN0 3 in
Solid Phas,
AgN0 3 .
KNO 3 .
AgN0 3 .
KNO 3 .
45-9
321.8
270
3 l8o
7-83
0-2896
IIO-7
322.6
65!-3
3^4
16.96
o . 6006
176.8
333-7
IO4O
3298
23-97
o 9040
259.6
364.0
1528
3597
29.81
1.054
365-6
456-4
2151
45 11
32 .28
I .604
57-9
387.2
2988
3816
43^5
2-439
745-9
398.6
4388
3960
52.70
8.294
SOLUBILITY OF MIXED CRYSTALS OF POTASSIUM NITRATE AND THAL-
LIUM NITRATE IN WATER AT 25.
(Fock.)
Grams per Liter.
Mg. Mols. per Liter.
Mol. per cent
T1NO 3
Sp. Gr.
of
Mol. per cent
T1NO
TlNOg.
KNO 3 .
T1N0 3 .
KN0 3 .
in Solution.
Solutions, in Solid Phas;.
O-OO
35 I -o
o.o
3468.2
o.oo
I .2632
O-OO
2-37
329.0
8. 9
325I-5
0-43
1.1903
0.08
6.15
332-4
23.1
3285.1
0.70
1.1956
O.2O
17.64
333-7
66.3
3298.1
1.97
I .2050
o-57
49-74
333-3
186.9
3294.4
5-37
I .2196
1.78
63.60
321.0
239.0
3172.4
7.01
1.2436
2.19
86.18
330-5
323 .8
3265-8
9.02
I .2617
2-77
123.8
428.3
465.2
4232.6
9.90
1.2950
{6.00
27.04
101 .3
245.1
380.6
2423-3
I3-58
I .2050
93-33
116.1
O-O
463.1
o.o
IOO. 00
I .0964
100.00
SOLUBILITY OF POTASSIUM NITRATE IN AQUEOUS ALCOHOL SOLUTIONS
(Gerardin Ann. chim. phys. [4] 5, 151, '65.)
Grams KNO 3 per 100 Grams Aqueous Alcohol of Sp. Gr.:
t .
0.9904
0.9843
0.9793
0.9726
09571
0-939
0.8967
0.8429
w\ 5 %.
Wt'f.
= 13.6
Wt.%.
= 19.1
Wt.%.
=30
Wt.%.
= 40
Wt.%.
= 60
Wt.%.
=90
Wt.%.
IO
17
13
10
7
4-5
3
I
O-2
18
22-5
18.5
14-5
10
6.2
4-5
1.6
o-3
20
24
20
16
ii
7.0
5
2
o-3
25
29
24-5
20
13 .5
9.0
6-5
2-5
0.4
30
36
30
25
17
8
o-5
40
52
43
36
27
ll'.s
ii
4
0.6
50
72
61
38
23.0
16
6
o-7
60
93
79
69
5 2
31.0
21
8
i .1
POTASSIUM NITRATE 258
SOLUBILITY OF POTASSIUM NITRATE IN AQUEOUS ALCOHOL AT 18,
(Bodlander Z. physik. Ch. 7, 316, '91.)
Sp. Gr. of
Gms. per 100 re. Solution. gp
.. Gr. of
Gms. per IOCD cc. Solution.
Solution.
C 2 H 6 OH. H 2 O.
KN0 3 .
alution.
C 2 H 6 OH. H 2 O.
KN0 3 .
I .1480
89.80
2 5
O
i
.0120
23
33
69.81
8.06
1.1085
3
3o
87-44
2O
.11
9935
28
. ii
64-74
6.50
I .IOIO
5
.24
86.26
18
.60
9585
37
53
54-21
4-II
1.0805
8
.69
83.18
16
.18
O
9450
42
.98
48.15
3-37
I -755
9
.06
83.10
IS
39
O
.9050
5 1
23
27-32
i-95
1-0655
14
.08
77-93
14
54
O
.8722
61
65
24.74
0.83
i .0490
16
.27
76.36
12
.27
8375
69
.60
13-95
0.20
1-0375
*9
97
72.93
10
85
SOLUBILITY OF POTASSIUM NITRATE IN AQUEOUS ALCOHOL AND IN
AQUEOUS ACETONE.
(Bathrick J. Physic. Ch. i, 160, '96.)
In Aqueous Alcohol. In Aqueous Acetone at 40.
Wt. per cent Gms. KNO 3 per 100 Gms. Aq. Alcohol. Wt. per cent Gms '
Alcohol. At3Q o At4QO> Acetone. ^Solvent.
o 45-6 64.5 o 64.5
8-25 32.3 47.1 8.5 51.3
17.0 22.4 33.3 16.8 38.9
25.7 15.1 24.1 25.2 22.8
35-0 11.4(34.4) 16-7 34.3 24-7
44.9 7.0 11.6(44) 44-i i7-o
54-3 4-5 7-2(55) 53-9 "-9
65.0 2.7 4.4 64.8 7.2
75-6 i-3 2.0(76.3) 76.0 3.0
88.0 0.4 0.6(88.5) 87.6 0.7
100 grams H 2 O saturated with sugar and KNO 3 dissolve 224.7 gms.
sugar + 41 .9 gms. KNO 3 , or 100 gms. of the saturated solution contain
61.36 gms. sugar + 11.45 g ms - KNOa at 31.25.
(Kohler Z. Ver Zuckerind. 47, 447, '97.)
POTASSIUM OXALATE K 2 C 2 O 4 . 4 H 2 O.
SOLUBILITY OF MIXTURES OF POTASSIUM OXALATE AND OXALIC ACID
IN WATER AT 25.
(Foote and Andrew Am. Ch. J. 34, 155, '05.)
Gms. per 100 Gms. Solution. Mols. per too Mols. H 2 O.
' n-,^ " -F7T ' wr n " v r n Solid Phase.
xl 2 C 2 (J 4 . Jv 2 C 2 U 4 . rl 2 L. 2 (J 4 . JV2C 2 (J 4 .
10.2 2.274 H2C 2 4 . 2 H 2
10.31 O.O4 2. 302 O- CO5 H 2 C 2 O 4 . 2 H 2 O + H 3 K(C 2 O 4 ) 2 .2H 2 O
9.26 O-I3 2.O46 O-Ol6 ) ~ ,, lTTT^//-/-,\ TT/-V
J } Double salt H 3 K(C 2 O 4 ) 2 -2H 2 O
3-39 0.63 0.707 0.071 i
2 . 06 4.26 O 440 O 495 H 3 K(C 2 O 4 ) .2H 2 O + HKC 2 O 4
1.16 ii. so 0.266 1-427 I _
, ' I Double salt HKC 2 O 4
0.99 16.93 0.240 2.235 '
0.85 2 1. 08 0-221 2.928 HKC 2 4 +H 2 K 4 (C 2 4 ) 3 . 2 H 2
O.82 21-49 O-2II 2.998 "j
O 64 23.52 O . 169 3 36l f Double salt H 2 K 4 (C 2 O 4 ) 3 .2H 2 O
0-57 24.88 0.153 3-6I7 j
0.43 27.52 0-122 4-14 H 2 K 4 (C 2 O 4 ) 3 .2H 2 O + K 2 C 2 O 4 .H 2 O
27 -40 ... 4.09 K 2 C 2 4 .H 2
259
POTASSIUM OXALATE
SOLUBILITY OF POTASSIUM OXALATE AND ACID POTASSIUM OXALATE IN
WATER.
(Alluard; results at o, Engel Ann. chim. phys. [6] 13, 362, '88.)
ioo gms. H 2 O dissolve 25.24 gms. K 2 C 2 O 4 , or 100 gms. of sat. solu-
tion contain 20.62 gms. K 2 C 2 O 4 at o. Sp. Gr. of solution = 1.161.
Acid Oxalate in Solutions of Neutral Oxalate at o.
Acid Oxalate in Water
n H 2 SO 4 Corre-
n KOH Corre- Q ^ r, ~t
Gms.
per
Gms. KHC 2 O 4
sponding to K spending to Free ^imiVinT I0 C 9 - ^'-
t.
per ioo Gms.
T T /~\
K 2 C2O 4 .
H 2 C 2 4 .
H 2 O.
28
5
4 1.164
23
53
18
o
2
2
10
.8
O
925
8
9i
O
41
IO
3
I
6
.8
I
075
.042
5
61
O
48
20
5
2
4
78
I
25
.031
3
94
o
56
40
10
5
3
83
I
.025
3
16
o
65
60
20
5
3
35
I
53
.022
2
76
o
68
80
34
7
2
.6 (i)
I
85
.018
2
!5
o
83
IOO
2
o (2)
2
.25 1.007
I
65
I
oo
45(3)
I
.25 1.004
37
56
(i) Sat. with acid potassium oxalate.
(2) Sat. with both acid oxalate and tetroxalate.
(3) Sat. with tetroxalate.
POTASSIUM PERMANGANATE KMnO 4 .
SOLUBILITY IN WATER.
(Baxter, Boylston, and Hubbard J. Am. Ch. Soc. 28, 1343, >o6 Patterson Ibid, 28, 1735, '06.)
Grams KMnO 4 per ioo :
Grams KMnO 4 per ioo :
Gms. Solution
. Gms. H 2 O
. cc. Solution (P).
Gms. Solution.
Gms. H 2 O.
2-75
2.83
2.84
34-8
9.64
10.6;
9-8
4-13
4.31
. . .
40
ii. 16
12.56
15.0
. . .
. . .
5-22
45
12.73
14.58
19.8
5-96
6-34
5o
14-45
16.89
24.8
7.06
7 59
. . .
55
16.20
r 9-33
29.8
8.28
9-03
8.69
65
20-02
25-03
Sp. Gr. of saturated solution at 15 = 1-035.
SOLUBILITY OF POTASSIUM PERMANGANATE IN:
Water. Aqueous Acetone Solutions at 1 3.
(Voerman Chem. Centrb. 77, I, 125, '06.)
(Herz and Knoch Z. anorg. Ch. 41, 317 '04.)
t
Gms. KMnO 4 per
ioo Gms. Solid
cc. Acetone KMnO 4 per ioo cc.
per ioo cc. Solution.
Solution.
Water.
Solvent.
Millimols.
Grams.
.18
o
58
.58 Ice
O
I 4 8
5
4
.70
27
o
99
I
.01
10
162
.2
5
13
.48
I
.98
2
O2 "
20
177
3
5
.61
58
2
.91
3
00 Ice + KMnO 4
30
208
.2
6
59
-f 10
o
4
OI
4
22 KMnO 4
40
257
4
8
.14
*5
4
95
5
.20 "
50
28 9
7
9
.16
25
7
.00
7
53
60
316
.8
10
.02
40
10
.40
ii
.61
70
328
.0
IO
38
So
14
35
16
75
80
312
5
9
.89
90
227.0
7
.18
IOO
6 7
.0
a
.14
POTASSIUM PERMAN- 260
GANATE
SOLUBILITY OF MIXED CRYSTALS OF POTASSIUM PERMANGANATE AND
POTASSIUM PERCHLORATE AT 7.
(Muthmann and Kuntze Z. Kryst. Min. 23, 368, '94; recalculated by Fock Ibid. 28, 402, '97.)
Milligram Mols. per Liter. Grams per Liter.
KMn0 4 . KC10 3 . KMnO 4 . KC1O 4 . " Crystals of Solid
Phase.
o.o 63.91 o.oo 8.86 o.oo
29.37 54.48 4.65 7.55 2.84
67-73 42-75 10.71 5-93 9-78
79-04 39-59 12.50 5.49 10.81
99.81 38.63 15.79 5.36 15.96
122.24 34-39 19-34 4-77 23.56
119.21 38-91 18.84 5-39 24.28
128.08 33-77 20.26 4.68 26.40
I44-46 33-14 22.86 4.59 34.32
167.81 29.53 26.55 4-09 44-42
183.09 25.19 28.97 3.49 67.33
197.82 20.16 3!-3o 2.80 77-95
233-75 28.26 36.98 3.92 94.37
264.27 o.oo 41.81 o.oo 100-00
SOLUBILITY OF MIXED CRYSTALS OF POTASSIUM PERMANGANATE AND
RUBIDIUM PERMANGANATE AT 7.
(Muthmann and Kuntze, calc. by Fock.)
Milligram Mols. per Liter. Grams ger Liter. KMnO 4 in
KMnO 4 . RbMnO 4 . KMnO 4 . RbMnO/. Crystals of Solid
Phase.
27.04 22.69 4- 2 8 4-64 3-50
75.00 22.22 11.84 4-54 13-75
120.26 31-29 J 9-o3 6.40 34-29
188.30 38.98 29.80 7.97 71.45
198.36 41-29 31.39 8.44 92.50
205.76 42-50 32-56 8.69 99-47
225.12 26.00 35.61 5.32 99.32
264.27 o-oo 41.81 o.oo loo.oo
POTASSIUM PHOSPHATE KH 2 PO 4 (Monobasic).
One liter aqueous solution contains 249.9 grams at 7.
(Muthmann and Kuntze.)
POTASSIUM HYPOPHOSPHATE, etc.
SOLUBILITY IN WATER.
(Salzer Liebig's Ann. 211, i, 82.)
Salt. Formula. Gms -
Cms. Salt per i
H 2 0.
Cold. Hot.
Potassium Hypophosphate K 4 P 2 O 6 .8H 2 O 400
" Hydrogen Hypophosphate K 3 HP 2 O 6 .3H 2 O 200
" Di Hydrogen Hypophosphate K 2 H 2 P 2 O 6 .3H 2 O 33 100
Tri Hydrogen Hypophosphate KH 3 P 2 O 6 66.6 200
" Penta Hydrogen Hypophosphate K 3 H 5 (P 2 O 6 ) 2 . 2H 2 O 40 125
" Hydrogen Phosphite KH 2 PO 3 172 (20)
" Hypophosphite KH 2 PO 2 200(25) 333
Hypophosphite KH 2 PO 2 * 14.3(25) 28
* Solvent alcohol.
261 POTASSIUM PHOSPHO-
MOLYBDATE
POTASSIUM PHOSPHOMOLYBDATE K 3 PO 4 .nMoO 3 .iiH 2 O.
100 gms. H 2 O dissolve 0.007 gms. at 30.
100 gms. aqueous 10 % HNO 3 dissolve 0.204 gms. at 30.
(Donk Proc. Assoc. Official Agrl. Chemists Bull. No. oo, Bureau of Chemistry,
U. S. Dept. of Agr., '05.)
POTASSIUM SELINATE K 2 SeO 4 .
SOLUBILITY IN WATER.
t. -20. -5. +5. 18. 97.
Gms. K 2 SeO 4 per 100 gms. solution 51.5 51. 7 52. o 52. 6 54.9
(Etard Ann. Chim. phys. [7] 2, 550, '94.)
POTASSIUM STANNATE K 2 SnO 3 .3H 2 O.
100 gms. H 2 O dissolve 106.6 gms. at 10, and 110.5 g ms - at 20
Sp. Gr. at 10 = 1.618 at 20 = 1.627.
(Ordway Am. J. Sci. [2] 40, 173, '65.)
POTASSIUM SULPHATE K 2 SO 4 .
SOLUBILITY IN WATER.
(Mulder; Andrae J. pr. Ch. 20,456, '84; Trevor Z. physik. Ch. 7, 468,01; TUdenand Shenstone
- Phil. Trans. 31, '84; Berkeley Trans. Roy. Soc. 203 A, 209, '04; see also Etard Ann. chim. phys.
[?] 2, 549, '94-)
Gms. K 2 SO 4 per ioo Gms
Gms. K 2 SO 4 per ioo Gms.
Gms. K 2 SO 4 per ioo Gms
Water.
Solution.
Water.
Solution.
I ,
Water.
Solution.
O
7-35
6.85
40
14.76
12.86
90
22.8
18-57
10
9.22
8-44
5
16.50
14.16
IOO
24.1
19.42
2O
ii .11
10.00
60
18.17
I5-38
120
26-5
20-94
2 5
12 .04
10.75
7o
19-75
16.49
143
28.8
22.36
30
12-97
11.48
80
21-4
17.63
170
32-9
24.76
Sp. Gr. of solution saturated at 18 = 1.083.
SOLUBILITY OP POTASSIUM SULPHATE IN AQUEOUS AMMONIA
SOLUTIONS AT 20.
(Girard Bull. soc. chim. [2] 43, 552, '85.)
Gms. NH 3 per i oo cc. solution o 6.086 15-37 24.69 31-02
Gms. K 2 SO 4 per i oo cc. solution 10-80 4.10 0-83 0-14 0-04
SOLUBILITY OF MIXED CRYSTALS OF POTASSIUM SULPHATE AND
AMMONIUM SULPHATE AT 25.
(Fock Z. Kryst. Min. 28, 375, '97.)
Grams per Liter.
Milligram Mols. per Liter.
K 2 S0 4 . (NH 4 ) 2 S0 4 - '
Mol. per cent
K 2 SO 4 in
Solution.
Sp. Gr.
of
Solution.
Mol. per cent
K 2 SO 4 in
Solid Phase.
KjjSO*.
(NH 4 ) 2 S0 4 .
127.9
O-O
734
o.o
IOO
1. 086
IOO
135-7
II5-7
778.5
874.6
47-1
I.I49
91.28
84.20
28l.I
483
2126
18.5
1.200
80-05
59.28
355-o
340
2685
11.13
1.226
68.63
40.27
482.7
231
3650
1.246
27-53
o.oo
542-3
o.o
4100
o.oo
1.245
o.oo
Results are also given for 14, 15, 16, 30, 46, and 47.
POTASSIUM SULPHATE 262
SOLUBILITY OF MIXED CRYSTALS OF POTASSIUM COPPER SULPHATE
AND AMMONIUM COPPER SULPHATE IN WATER.
CuSO 4 .K 2 SO 4 .6H 2 O and CuSO 4 (NH 4 ) 2 SO 4 .6H 2 O at i3-i4.
(Fock.)
Mols. per IPO Mols. H 2 O Mol. per cent K Salt Mols. per 100 Mols. H 2 O Mol. per cent K Salt
K~Sair 'NH 4 Salt: m Solution, in Solid. K Salt. ' NH* Salt. ' in Solution. ' in Solid. '
o-oo I -O35 o.oo o.oo 0.2946 0.5096 36.63 58.20
0.0897 0.8618 5.06 10.34 0.3339 0.3319 50.15 75.34
0.2269 0.6490 16.76 33-05 0.4560 0.1961 69.93 83.86
0-2570 0.5887 30.40 46.22 0.4374 o.oo 100.00 100-00
SOLUBILITY OF SOME POTASSIUM DOUBLE SULPHATES IN
WATER AT 25.
(Locke Am. Ch. J. 27, 459, 'ox.)
D "*le Salt- Formula. j
Potassium Cobalt Sulphate K 2 CO(SO 4 ) 2 .6H 2 O 12.88
Copper " K 2 Cu(SO 4 ) 2 .6H 2 O 11.69
Nickel " K 2 Ni(SO 4 ),.6H 2 O 6.88
Zinc " K 2 Zn(S0 4 ) 2 .6H 2 O 13.19
SOLUBILITY OF POTASSIUM NICKEL SULPHATE AND ALSO OF POTASSIUM
ZINC SULPHATE IN WATER AT DIFFERENT TEMPERATURES.
Grams per 100 Gms. H 2 O. Grams per TOO Grams HjjO.
*- ' K2Ni(S0 4 ) 2 K2Zn(S0 4 ) 2 ' *- 'K 2 Ni(SO 4 ) 2 K 2 Zn(SO 4 ) 2 '
.6H;}O. .6H 2 O. .6H 2 O. .6HO 2 .
o 6 13 40 23 45
10 9 19 50 28 56
20 14 26 60 35 72
25 16 30 70 43 88
30 l8 35
SOLUBILITY OF THE THREE HYDRATES OF POTASSIUM FERRO SULPHATE
IN WATER AT DIFFERENT TEMPERATURES.
(Kuster and Thiel Z. anorg. Ch. ax, 116, '99.)
K ? SO 4 .FeS0 4 .6H 2 0. K 2 SO 4 .FeSO 4 .4H 2 O. K 2 SO 4 .FeSO 4 .2H 2 O.
t< cc.N/ioKMnO 4 Gms. K 2 SO 4 cc.N/ioKMnO 4 Gms.K 2 SO 4 cc.N/ioKMnO 4 Gms.K 2 SO
per 2cc.
Solution.
.FeSO 4 per
100 cc. Sol.
per 2 cc.
Solution.
.FeSO 4 per
100 cc. Sol.
per 2 cc.
Solution.
.FeS0 4 per
loo cc. Sol.
o-5
12.4
18.36
15-5
22-94
15-4
22.79
17.2
17.0
25 .16
18.1
26.79
21.6
31.98
40.1
2 4 .8
36.72
21 .9
32.41
27 .6
40.86
60
29.0
42-93
24-1
35-68
28.8
42.63
80
30.6
45-29
27-3
40.46
28.6
42.34
90
29.6
43-82
28.9
42.73
95
29.8
44.11
27.7
41 .01
263 POTASSIUM SULPHATE
SOLUBILITY OF POTASSIUM SULPHATE IN AQUEOUS SOLUTIONS OP
POTASSIUM CHLORIDE, BROMIDE, AND IODIDE.
(Blarez Compt. rend. 112, 939, '91.)
Interpolated from the original results.
Gram K2SO 4 per 100 cc. in Aq.
Grams Halogen Solutions of:
Salt per 100
cc. Solution.
O
2
4
6
8
10
12
SOLUBILITY OP MIXED CRYSTALS OF POTASSIUM SULPHATE AND
POTASSIUM CHROMATE AT 25.
(Fock Z. Kryst. Min. 28, 379, '97.)
KC1
KBr
KI
at 12.5.
at 14.
at 12.5.
9.9
10.16
9-9
8-3
9.1
9-2
7.0
8.2
8. 4
5-7
7-4
7-7
4.6
6.6
7-2
3-5
6.0
6.6
5-5
6.0
Milligram Mols. per Liter
Grams per Liter.
Mol. per cent
K 2 S0 4 in
Solution.
Sp. Gr.
of
Solution.
Mol. per cent
K2S0 4 in
Solid Phase.
K 2 SO 4 .
K 2 Cr0 4 .
K 2 S0 4 .
K 2 Cr0 4 .
618.1
o.o
107-7
O-OO
IOO.O
1.083
IOO.O
608.4
103
106.0
2O.O2
85-51
I .092
99.65
341.0
691.8
59-46
134-5
33-oi
I .141
97-30
174.8
1496.0
30-47
290.5
10.50
I.23I
91.97
110.7
2523
19.30
490-5
4.21
I-356
28.43
100.6
2687
17-54
5 2 2-3
3.60
i-377
2.41
o.o
2847
o.o
553-5
o.oo
1.398
o.oo
734-o
o.o
127.9
o.o
IOO.O
i .0863
IOO.O
617 .0
103.4
107.6
20.1
85-65
i .0934
99.78
463
452-7
80.72
88.0
55-55
I - I2 35
98-49
279
948.2
48.64
184.4
22.72
1.1700
96.07
153
1469
26.68
285.6
9.41
1-2255
85-77
296
2681
51.61
521 .2
21 .09
1.3688
25 -73
o.o
2715
o.oo
527.8
o.oo
1.3781
o.oo
SOLUBILITY OF POTASSIUM SODIUM SULPHATES IN WATER.
Double Salt. t. Gm's.^cT Authority.
3K 9 SO 4 .Na 9 SO 4 103 . 5 40 . 8 (Penny Phil. Mag. [4] 10, 401, 'SS-)
5K 2 SO 4 .Na 2 SO 4 4.4 9.2 (Gladstone J. Ch. Soc. 6, it, '54.)
12.7 10.1
" 100.0 25.0
POTASSIUM SULPHATE
264
SOLUBILITY OF POTASSIUM SULPHATE IN AQUEOUS ALCOHOL.
(Gerardin Ann. chim. phys. [4] 5, 147, '65; Schiff Liebig's Ann. 118, 362, *6i.)
In Aq. Alcohol of 0.939
Sp. Gr.= 4o Wt. %.
Alcohol of Different
Strengths at 15.
40
80
60
Cms. K 2 SO 4
per 100 Gms.
Alcohol.
0.16
O.2I
0.92
Weight
per cent
Alcohol.
Gms. K 2 SO 4
per ioo Gms.
Sat. Sol.
10
20
30
3-90
I .46
0.56
40
0-21
100 gms. glycerine of 1.255
temp.
- Gr. dissolve 1.316 gms. K 2 SO 4 at ord.
(Vogel Neues Report, Pharm. 16, 557 '67.)
SOLUBILITY OF POTASSIUM SULPHATE IN AQUEOUS ACETIC ACID AND
IN AQUEOUS PHENOL SOLUTIONS AT 25.
(Rothmund and Wilsmore Z. physik. Ch. 40, 619, '02.)
In Aq. Phenol.
Mols. per Liter. Grams per Later.
CH 3 COOH
K 2 SO 4 . CeHfiOH.
K 2 S0 4 .
C 6 H 5 OH.
K 2 S0 4 .
O
o
117
.0
.0
o
.6714
o.
o
1X7
.0
4
.2
"5
4
o
.032
o
.6598
3-
01
S
.0
8
.22
114
4
.064
.6502
6.
02
.3
19
.68
no
.8
o
.127
o
.6310
II .
94
no
.0
34
.68
106
3
.236
.6042
22 .
J 9
!05
3
69
.06
96
.87
o
.308
5834
28.
97
101
7
128
58
82
.70
.409
o
5572
38.
46
97
.2
.464
.5480
43-
63
95-5
.498 (sat.)
5377
46.
82
93
.8
In Aq. Acetic Acid.
Mols. per Liter. Grams per Liter.
CHaCOOH.' KzS0 4 .
o.o 0.6714
0.07 0-6619
0.137 0-6559
0.328 0-6350
0.578 0.6097
1.151 0.5556
2.183 -4743
100 grams water dissolve 10.4 grams K 2 SO 4 + 219.0 grams sugar at
31.25, or 100 grams sat. solution contain 3.18 grams K 2 SO 4 + 66.74
grams Sugar. (Kahler Z. Ver. Zuckerind. 47, 447, '97.)
POTASSIUM ACID SULPHATE KHSO 4 .
SOLUBILITY IN WATER.
(Kremers Liebig's Ann. 92, 497, '54.)
t 20 40 100
Gms. KHSO 4 per ioo gms. H 2 O 36.3 51.4 67.3 121.6
POTASSIUM PERSULPHATE K 2 S 2 O 8 .
ioo gms. H 2 O dissolve 1.77 gms. K 2 S 2 O 8 at o.
(Marshall J. Ch. Soc. 59, 771, '91.)
POTASSIUM SODIUM THIOSULPHATE KNaS 2 O 3 .2H 2 O.
POTASSIUM SODIUM HYDROGEN SULPHITE KNa 2 H(SO 3 ) 2 .
4 H 2 0.
ioo grams H 2 O dissolve 213.7 grams KNaS 2 O 3 .2H 2 O (a) at 15.
ioo grams H 2 O dissolve 205.3 grams KNaS 2 O 3 .2H 2 O (b) at 15.
ioo grams H 3 O dissolve 69.0 grams KNa 2 H(SO 3 ) 2 .4H 2 O at 15.
(Schwicker Ber. 22, 1731, '89.)
20
265 POTASSIUM SULPHO-
CYANIDE.
POTASSIUM SULPHOCYANIDE KSCN.
100 grams H 2 O dissolve 177.2 grams K*SCN at o, and 217.0 grams at
' (Rxidorff Her. 2, 68, '69.)
SOLUBILITY OF POTASSIUM SULPHOCYANIDE IN ACETONE, AMYL
ALCOHOL, ETC.
(von Laszcynski Ber. 27, 2285, '94.)
In Acetone. In Amyl Alcohol. In Ethyl Acetate. In Pyridine.
Gms. KSCN per Gms. KSCN per Gms. KSCN per Gms. KSCN per
t. 100 Gms. t. 100 Gms. t. 100 Gms. t. 100 Gms.
(CH 3 ) 2 CO.
CsHnOH. CH 3 COOC 2 H6.
CgHijN.
22
20-75
13
0.18
o
0.44
O
6-75
58
20.40
65
i-34
14
0.40
20
6-15
100
2.14
79
0.20
58
4-97
133-5
3-15
97
3-88
"5
3.21
POTASSIUM (Bi) TARTBATE (Mono) KHC 4 H 4 O 6 Cream of Tartar.
SOLUBILITY OF MONO POTASSIUM TARTRATE IN WATER.
F"
(Alluard Liebig's Ann. 133, 292, '65; Roelofsen Am. Ch. J. 16, 466, '94; Blarez
2, 434, '91; at 20, Magnanini Gazz. chim. ital. 31, II, 542, '01; at 25, Noyes an
physik. Ch. 13, 413, '94.)
Compt. rend,
and Clement
Gms. KHC4.ri.4Oft
Gms. KHC^HjOft
t. per 100 Gms. Solution.
t. per loo Gms. Sol
!ution.
o. 3 o(R.)
0.32 (A)
o.35 (B.)
4O 0.96
i3
1.29
IO
o-37
0.40
0.42
50 1-25
1.8
I. 80
20
0.49
o-53(M.)
0.60
60
2.4
25
30
0.58
0.69
o.654(N. and C.)
0.9 (A.)
0.74
0.89
80
IOO ....
4.4
6-5
SOLUBILITY OF POTASSIUM ACID TARTRATE (KHC 4 H 4 O 6 ) IN NORMAL
SOLUTIONS OF ACIDS AT 20.
(Ostwald; Huecke J. pr. Ch. [2] 29, 49, '84.)
Purified tartrate was added in excess to normal solutions of the acids,
and after shaking clear i cc. portions of each solution were withdrawn
and titrated with approximately N/io Ba(OH) 2 solution; i cc.
normal acid requiring 10.63 cc - f tne Ba(OH) 2 solution.
Acid.
Gms.
Acid
cc. N/io
Ba(OH) 2
Gms.
KHC4H4O,
1 Acid
Gms. cc. N/io Gms
Acid Ba(OH) 2 KHC 4 H 4 O 8
per loo cc.
Solvent.
per i cc.
Solution.
per loocc.
Solution.
per loo cc.
Solvent.
per i cc. per icocc
Solution. Solution'
HN0 3
6.
31
5-
77*
10.
21
C 2 H 5 SO 3 H
II. O
5
.01*
8.87
HC1
3-
65
5-
32
9-
42
HO.(CH 2 ) 2 SO 3 H
12. 6l
5
33
9-43
HBr
8.
IO
5-
38
9-
75
C 6 H 5 S0 3 H
15.81
5
25
9.29
HI
12.
80
5-
43
9-
61
HCOOH
4.60
45
0.80
H,S0 4
4-
00
3-
97
7-
03
CH 3 COOH
6.00
.27
0.48
HCH,SO 4
ii.
21
5-
58
12.
44
CH 2 C1COOH
9-45
i
.01
1.79
HC 2 H 6 S0 4
12.
61
5-
9-
58
C 2 H 5 COOH
7.40
o
.24
0.42
HC 3 H 7 S0 4
14.
01
5-
21
9-
22
C 3 H 7 COOH
8.8!
0,
23
0.41
* The figures in this column show the amount of the Ba(OH)z solution in excess of that which would
have bsen required by the normal acid solution alone in each case, viz., 10.63 cc. They, therefore, corre-
spond to the amount of KHC^H^Oe dissolved in i cc. of each saturated solution, and when multiplied
by i-77give the grams of KHC^Oa per 100 cc. solution.
POTASSIUM TARTRATE.
266
SOLUBILITY OF MONO POTASSIUM TARTRATE (KHC 4 H 4 O 8 ) IN AQUEOUS
SOLUTIONS OP ELECTROLYTES AT 25.
(Noyes and Clement Z. physik. Ch. 13, 413, '94; Magnanini Gazz. chim. ital. 31, II, 542, f oi.)
Gms.
Equiv.
Gms.
per
Gm. Equiv.
Grams
per
Electro-
per
Liter.
100 CC.
Electro-
per Liter.
IOO CC.
lyte.
Electro- KHC 4
Electro-
KHCi
lyte.
Electro-
KHC,"
Electro-
KHC 4
lyte.
H 4 6 .
lyte.
IL^OS.
lyte.
lyte.
ILXV
KC1
0.025
0.0254
1.86
0.4788
CH 3 COOK
0.05
0.0410
4.91
0.7718
"
0.05
0.0196
3-73
0.3680
"
O.IO
0.0504
9.82
0.9486
((
O.IO
0.0133
7-46
0.2509
"
O.2O
0.0634
19.63
1.1930
"
O.2O
0.0087
14.92
0.1636
KHS0 4 (20)
O-OI
0-0375
1.36
0.706
KC10 3
O.025
0.0256
3.06
0.4821
"
O.02
0.0500
2.72
0.941
M
0.05
0.0197
6.13
0.3716
it
O.IO
0-1597
13.62
3.006
"
O.IO
0.0138
12.26
0.2601
KHC 2 O 4 * (20) o.oi
0.0369
1.28
0.694
"
O.2O
0.0092
24.52
0.1728
"
O.O2
0.0424
2.56
0.798
KBr
O.O5
0.0197
5-95
0.3699
"
O.IO
O.II32
12.82
2.130
M
O.IO
0.0134
11.91
0.2517
HC1
0.013
0.0367
o-45
0.690
"
O.2O
0.0087
23.82
0.1629
M
0.025
0.0428
0.91
0.806
KI
0.05
0.0196
8.30
0.3687
tt
0.050
0.0589
1.82
1.109
"
O.IO
0.0132
16.61
0.2492
NaCl
0.05
0.0376
2.92
0.708
ii
O.2O
0.0086
33-22
0.1619
M
O.IO
0.0397
0.748
KNO 3
O.O5
0.0195
0.3676
ii
O.2O
0.0428
11.70
0.80^
"
O.IO
0.0136
10.12
0-2551
NaClOs
0.05
0.0382
5-32
0.718
"
O.2O
0.0090
2O.24
0.1696
11
O.IO
0.0405
10.65
0.763
K 2 S0 4
O.O5
0.0208
4.36
0.3921
"
O.2O
0.0446
21.30
0.840
"
O.IO
0.0147
8. 7 2
0.2769
* Acid potassium oxalate.
'*
0^20
O.OIOO
17.44
0.1881
SOLUBILITY OF MONO POTASSIUM TARTRATE IN AQUEOUS ALCOHOL
SOLUTIONS.
(Roelofsen Am. Ch. J. 16, 466, '94; Wenger Ibid. 14, 624, '92-)
NOTE. The original results were plotted on cross-section paper and
the following figures read from the curves.
Milligrams KHC 4 H < O 6 per 10 cc. of Aq. Alcohol of:
If .
10
20
3
40
60
- N
80
per cent.
per cent.
per cent.
per cent.
per cent.
per cent.
o
17
II
7
6
6
6
10
22
14
8
7
6
6
20
29
18
ii
8
6
6
2 5
34
21
12
9-5
6-5
5-5
30
40
2 5
J 3
ii
7
5-5
40
55
36
J 9
14
7-5
5
50
87
55
29
19
8
5
POTASSIUM FLUO TITANATE K 2 TiF 6 .H 2 O.
SOLUBILITY IN WATER.
(Marignac Ann. chim. phys. [4] 8, 65, '66.)
t o 3 6 10 14 20
Gms. K 2 TiF e per 100 gms. H 2 O 0.55 0.67 0.77 O.QI 1.04 1.28
26; POTASSIUM VANADATE
POTASSIUM VANADATE K 3 V 6 O 14 .5H 2 O.
100 grams H 2 O dissolve 19.2 grams at 17.5.
(Radan Uebig's Ann. 351, xao, "89.)
POTASSIUM ZINC VANADATE KZnV 5 O 14 .8H 2 O.
100 grams H 2 O dissolve 0.41 gram of the salt (Radan).
PRASEODYMIUM SULPHATE Pr 2 (SO 4 ) 3 .
SOLUBILITY IN WATER.
(Muthmann and Rolig Ber. 31, 1727, '98.)
Gms. Pr 2 (SO 4 >3
t . per 100 Gms.
Solid ft0
Phase.
Gms. Pr 2 (SO 4 ) 3
per 100 Gms.
Solid
Phase.
Solution.
Water.'
Solution. Water.
O
I6. 5
19.8 Pi
2 (SO 4 ) 3 .8H 2 O 75
4-0 4-2
Pr 2 (S0 4 ) 3 .8H 2
18
12-3
I4-I
85
J -5 *-55
Pr 2 (S0 4 ) 3 .8H 2 -f-
35
9-4
10-4
"
55
6.6
7- 1
95
1.0 I .01
PraCSO^.sHzO
PROPIONIO ALDEHYDE C 2 H 5 COH.
100 grams H 2 O dissolve 16 grams aldehyde at 20.
(Vaubel J. pr. Ch. 59. 30, '99-)
PROPIONITRIL C 2 H 5 CN.
SOLUBILITY IN WATER.
Synthetic method used. See Note, page 9.
(Rothmund Z. physik. Ch. 26, 474, '98.)
Wt. per cent C 2 H 6 CN in; Wt. per cent CjjHfiCN in:
* ' Aq. C2H 6 CN ** A^ C 2 H 6 CN
Layer. Layer. Layer. Layer.
40 10.7 92.1 95 19.6 78.0
50 ii. 6 90.5 ioo 22.4 75.5
60 12.7 88.5 105 26.0 72.1
70 13.2 86.1 no 32.0 66.5
80 14.9 83.4 113.1 (crit. temp.) 48.3
90 17.6 80.2
PROPYL ACETATE, Butyrate and Propionate.
SOLUBILITY OF EACH IN AQUEOUS ALCOHOL MIXTURES.
(Bancroft Phys. Rev. 3, 205, '95, calc. from Pfeiffer.)
cc. H 2 O Added to Cause Separation* in:
Vb4 .TVH.U-
hoi in
P. Ace-
P. Buty-
P. Propio-
cc. /uco-
hoi in
P. Ace-
P. Buty-
P. Propio-
Mixture.
tate.
rate.
nate.
Mixture.
tate.
rate.
nate.
3
4-50
I.I9
1-58
21
58.71
19.68
27.83
6
10.48
3-55
4.70
24
oo
23.72
33-75
9
17.80
6.13
8-35
30
32.10
47-15
12
26.OO
9-05
12.54
36
41-55
63.18
15
35 -63
12.31
17 .15
42
51 .60
83.05
18
47-50
15.90
22.27
48
62 .40
107.46
54
73-85
* cc. HsO added to cause the separation of a second phase in mixtures of the given amounts of alcohol
and 3 cc. portions of propyl acetate, butyrate and propionate.
PROPYL ACETATE 268
SOLUBILITY OP PROPYL ACETATE, FORMATE, AND PROPIONATE
IN WATER.
100 cc. H 2 O dissolve 1.7 gms. propyl acetate at 22.
100 cc. H 2 O dissolve 2.1 gms. propyl formate at 22.
(Traube Ber. 17, 2304, '84.)
ioo cc. H 2 O dissolve 0.6 cc. propyl propionate at 25. (Bancroft.)
PEOPYL OHLORIDE, Bromide, etc.
SOLUBILITY IN WATER.
(Rex Z. physik. Ch. 55, 355. '06.)
Grams P. Compound per too Gms. H2O at:
Propyl Compound.
(normal) 0.376 0.323 0.272 0.277
CH 3 CH 2 CH2Br " 0.298 0-263 0.245 0.247
CH 3 CH 2 CH 2 I " 0.114 0.103 0.107 0.103
(CH 3 ) 2 CHC1 (iso) o . 440 o . 363 o . 305 o . 304
(CH 3 ) 2 CHBr 0.418 0.365 0.318 0.318
(CH 3 ) 2 CHI " 0.167 0.143 0.140 0.134
PROPYLENE C 3 H 6 . SOLUBILITY IN WATER.
(Than Liebig's Ann. 123, 187, '62.)
t.
p.
?
0.4465
0.0834
5
0-3493
0.06504
10
0.2796
0.0519
15
0.2366
0.0437
20
0.2205
0.0405
and q,
see Ethane, page
133-
For values of
PYRENE C 16 H 10
SOLUBILITY IN TOLUENE AND IN ABSOLUTE ALCOHOL.
ioo gms. toluene dissolve 16.54 gms. pyrene at 18.
ioo gms. absolute alcohol dissolve 1.37 gms. pyrene at 10 and 3.08
gms. at b. pt.
PYROGALLOL C 6 H 3 (OH) 3 i, 2, 3.
SOLUBILITY IN WATER, ETC.
(U. S. P.)
ioo gms. water dissolve 62.5 gms. C 6 H 3 (OH) 3 at 25.
ioo gms. alcohol dissolve 100.0 gms. C 6 H 3 (OH) 3 at 25.
ioo gms. ether dissolve 90.9 gms. C 6 H 3 (OH) 3 at 25,
269
QUININE
QUININE C 20 H 24 N 2 O 2 . (See also Cinchona alkaloids, p. 117.)
SOLUBILITY OF QUININE AND OF QUININE SALTS IN WATER AND
OTHER SOLVENTS.
(U. S. P.)
Grams. Quinine Compound per 100 Grams Solvent in:
Compound.
C 20 H 24 N 2 2
C 20 H 24 N 2 2 . 3 H 2
C 20 H 24 N 2 O 2 HC1.H 2 O
C 20 H 24 .N 2 2 . 2 C 6 H 4 (OH).
COOH.H 2 O
(C 20 H 24 N 2 2 ) 2 .H 2 S0 4 . 7 H 2
C 20 H 24 N 2 2 .H 2 S0 4 .7H 2
C 20 H 24 N 2 2 .HBr.H 2
Water.
Alcohol.
Ether. Chloroform. Glycerine.
At
*5.
At
80.'
At 25.
At
25 -
At 25.
At 25.
0.
057
0.
123
166.
6
22
.2
52-
6
O.
633
0.
06 5
0.
129
166.
6
7 6
9
62.
5
.472
5
55
250.
166.
6
.417
122.
12
.2
I
30
2.
86
9-
09
.91
2.
,70
6
25
0.
i39
2.
22
i.
16
.
O.
25
2
.78
II.
77
117.
7
5-
55
.056
0.
109
5-55
2.
5
33-
3
149.
2
6
.2
.
12
5
SOLUBILITY OF QUININE IN AQUEOUS SOLUTIONS OF CAUSTIC ALKALIES.
(Doumer and Deraux J. pharm. chim. [6] i, 50, '95.)
METHOD. A one per cent solution of quinine sulphate containing
a very small amount of HC1 was gradually added to 200 cc. portions
of the caustic alkali solutions of the various concentrations stated,
and the point noted at which a precipitate of the appearance cor-
responding to that of i cc. of milk in 100 cc. of water, remained
undissolved.
In Aq. Ammonia. In Aq. Sodium Hydrate. In Aq. Pot. Hydrate.
Gms.NHa
per 200 cc.
Solution.
Gms. Anhydrous
Quinine
Dissolved.
Gms. NaOH
per 200 cc.
Solution.
Gms. Anhydrous
Quinine
Dissolved.
Gms.KOH
per 200 cc.
Solution.
Gms. Anhydrous
Quinine
Dissolved.
0.52
0-084
O.OO7
O.O92
0.612
0.088
0.65
0.084
O-OI2
0.091
I.5I2
0.082
4-59
0.096
0.740
O.O9O
3-456
0.068
13.08
O.I22
2.l6o
0.079
10.944
0.039
18.88
0.144
3.188
0.056
44 74
O.OO6
25.19
0.174
6.172
0.044
35-79
0.184
8-537
0.021
17.074
0.015
SOLUBILITY OF QUININE SALTS IN WATER.
(Regnault and Willejean Chem. Centralb. 18, 252, '87.)
Salt.
Brom Hydrate (basic)
(neutral)
Chlor Hydrate (basic)
Lactate
t.
Gms. Salt per
iooGms.H 2 O.
Salt.
t.
Gms. Salt per
100 Gms. H 2 O
14
2
.06
Salicylate (basic)
15
O
.114
12
12
33
Sulphate "
14
o.
139
14
13
.19
a tt
16
o.
16
14
79
a
18
o.
160
15
14
.20
" (neutral)
15
8.
50
12
3
.80
it n
17
8.
90
14
4
.14
it tt
18
9-
62
IS
4
2 5
Valerate (basic)
I2-l6 2.
59
15
10
03
37
16
.18
RESORCINOL. 270
RESOROINOL C 6 H 4 (OH) 2 i, 3.
SOLUBILITY IN:
Water.
Ethyl Alcohol.
(Speyers
Am. J. Sci.
[4] 14, 294, '02.)
(Speyers.)
.
Sp.
Gr.of
Gms.CoHtCOH);; per 100 Gms.
Sp
.Gr.of
Gms. GjH4(OH) 2 per 100 Gms.
Solutions.
Water.
Solution.
Solutions.
Alcohol.
Solution.
O
I
.101
60
37-5
I
033
2IO
6 7
.8
10
I
.118
8l
44-8
I
.036
223
6 9
.0
20
I
134
103
50-7
I
.041
236
70
3
25
I
.142
117
53-9
I
045
243
70
.8
30
I
.148
I3 1
56-7
I
.048
250
71
4
40
I
.157
161
58.9
I
056
266
72
7
50
I
.165
198
66.5
I
065
286
74
i
60
I
.172
246
71.1
I
075
311
75
7
70
I
.176
320
76.2
I
.087
341
77
3
80
I
.179
487
82.9
I
.104
375
78
9
NOTE. The original results of Speyers are given in terms of
mols. per 100 mols. H 2 O.
According to Vaubel, 100 gms. H 2 O dissolve 175.5 ms - C 6 H 4 (OH) 2 ,
or 100 gms. sat. solution contain 63.7 gms. at 20. Sp. Gr. of sol.
= I - I 335- (J. pr. Ch. [2] 52, 73. '95-)
SOLUBILITY OF RESORCINOL IN BENZENE.
(Rothmund Z. physik. Ch. 26, 475, '98.)
Synthetic method used. See Note, p. 9.
Gms. C6H4(OH) 2 per 100 Gms. Gms. QH^OIty; per 100 Gms.
CeHe Layer. C 6 H4(OH) 2 Layer. C 6 H 6 Layer.
60 4.8 79.4 90 13.0 71.3
70 6.6 77.5 ioo 19.5 65.7
80 9.2 75 .o 105 24.6 60.7
109.3 ( cr it- temp.) 42.4
DISTRIBUTION OF RESORCINOL BETWEEN WATER AND ORGANIC
SOLVENTS AT ORDINARY TEMPERATURE.
(Vaubel J. pr. Ch. [2] 67, 478, '03.)
Gms. Gms. CeH^OH) in:
C 6 H4(OH) 2 Solvents. Organic
Used. H 2 Layer. S o\v?llyer.
1.191 6occ. H 2 O+ 30 cc. Ether 0.2014 0.9896
1.191 60 cc. H 2 O + 60 cc. Ether 0.2475 0.9525
0-800 40 cc. H 2 O+ 40 cc. Benzene 0.5873 0.2127
0.800 40 cc. H 2 O+ 80 cc. Benzene 0-5773 0.2227
0.500 50 cc. H 2 O+ 50 cc. CC1 4 0.4885 0.0115
0.500 50 cc. H 2 O+ioo cc. CC1 4 0.4880 0.0120
0.500 50 cc. H 2 O+i5o cc. CC1 4 0.4880 0.0120
RHODIUM SALTS. SOLUBILITY IN WATER.
(Jorgensen J. pr. Ch. [2] 27, 433. '83; 34. 394. '86; 44, 51. '91-)
Salt. Formula. t
Chloro Purpureo Rhodium Chloride ClRh(NH 3 ) 5 Cl 2 17 0.56
Luteo Rhodium Chloride Rh(NH 3 ) 6 Cl 3 8 13.3
Luteo Rhodium Nitrate Rh(NH 3 ) 6 (NO 3 ) 3 ord. t. 2.1
Luteo Rhodium Sulphate [Rh(NH 3 ) 6 ] 2 (SO 4 ) 3 .5H 2 O 20 2.3
2 7 I
RUBIDIUM ALUMS
formula.
i .
Anhydrous
. Hydrated.
G. Mols.
RbAl(SO 4 ) 2 .i2H 2 O
25
1.81
3-15
0.0059
(4
3
2.19
0.0072
<(
35
2.66
0.0087
11
40
3.22
.
0.0106
RbCr(SO 4 ) 2 .i2H 2 O
25
2-57
4-34
0.0079
M
3
3-17
. . .
0.0096
"
35
4.11
0.0128
40
5-97
0.0181
RbV(S0 4 ) 2 .i2H 2
RbFe(SO 4 ) 2 .i2H 2 O
25
25
5-79
9-74
9-93
16.98
0.0177
0.0294
"
3
20. 24
0.0617
RUBIDIUM ALUMS.
SOLUBILITY IN WATER.
(Locke Am. Ch. J. 27, 174, '01.)
Gms. Alum per 100 Gms. HjO.
Alum.
Rb. Aluminum Alum
Rb. Chromium Alum
Rb. Vanadium Alum
Rb. Iron Alum
Biltz and Wilke (Z. anorg. Ch. 48, 299, '06) find for the solubility of
rubidium iron alum in water, at 6.6, 4.55 gms. per 100 cc. solution;
at 25, 29.0 gms.; and at 40, 52.6 gms.
RUBIDIUM FLUOBORIDE RbBF 4 .
100 gms. H 2 O dissolve 0.55 gm. RbBF 4 at 20, and i.o gram at 100.
(Godeffroy Ber. 9, 1337, '76.)
RUBIDIUM BROMIDE RbBr.
SOLUBILITY IN WATER.
(Rimbach Ber. 38, 1557, '05.)
Gms. RbBr per 100 Gms. Gms. RbBr per 100 Gms.
' Water. Solution. Water. Solution.
0.5 89.6 47-26 39.7 131-85 5 6 - 8 7
5.0 98.0 49-5 57-5 i5 2 -47 60.39
16.0 104.8 51-17 113-5 205.21 67.24
RUBIDIUM CARBONATE Rb 2 CO 3 .
100 gms. absolute alcohol dissolve 0.74 gm. Rb 2 CO 3 .
(Bunsen.)
RUBIDIUM CHLORATE RbClO 3 .
SOLUBILITY IN WATER.
(Reissig Liebig's Ann. 127. 33. '63-)
t. 4.7. 13-0 '. 18.2*. 19-0.
Gms. RbClO 3 per 100 grams H 2 O 2.8 3.9 4-9 5 - 1
RUBIDIUM (Per) CHLORATE RbClO 4 .
100 grams H 2 O dissolve 1.08 grams RbClO 4 at 21.3.
(Longuimine Liebig's Ann. 121, 123, '62.)
RUBIDIUM CHLORIDE 272
t
RUBIDIUM CHLORIDE RbCl.
SOLUBILITY IN WATER.
(Rimbach Ber. 35, 1304, '02; Berkeley Trans. Roy. Soc. (Lond.) 203 A, 207, '04.)
*
Mols. RbCl
Gms. RbCl
per 100 Gms.
t *.
Mols. RbCl
Gms. RbCl per 100 Gm
*
per Liter.
Water.
Solution.
per Liter.
Water.
Solution.
5.17
77-0
43-5
60
6.90
"5-5
536
10
5-55
84.4
45-8
70
7-12
121 .4
54-8
20
5-88
9I.I
47-7
80
7-33
127.2
56.0
3
6.17
97.6
49-4
90
7-52
133 - 1
57-i
40
6-43
103-5
50-9
100
7.71
138.9
58-9
So
6.67
109.3
52.2
112.9
7-95
146.6
59 5
RUBIDIUM TELLURIUM CHLORIDE Rb 2 TeCl,.
100 gms. Aq. HC1 of 1.2 Sp. Gr. dissolve 0.34 gm. Rb 2 TeCl 6 at 23.
100 gms. Aq. HC1 of 1.05 Sp. Gr. dissolve 13.09 gms. Rb 2 TeCl 6 at 23.
(Wheeler Am. J. Sti. [3] 45. 267, '93-)
RUBIDIUM THALLIUM CHLORIDE 3RbClTlCl 3 .2H 2 O.
100 gms. H 3 O dissolve 13.3 gms. at 18, and 62.5 gms. at 100.
(Godeffroy Zeit. allgem. Oster. Apoth. No. 9, '80.)
RUBIDIUM GHROMATE (Mono) Rb 2 CrO 4 .
SOLUBILITY IN WATER.
(Schreinemaker and Filippo Chem. Centralb. 77, I, 1321, '06.)
Gms. RbCrO 4
Gms. RbCrC-4
Gms. RbCrOv
t.
per zoo
t . per 100
t. per 100
Gms. Solution.
Gms. Solution.
Gms. Solutioi
- 7
36.65
50 47-44
2.40 J 5-58
o
3 8.27
60.4 48.90
3.25 20-03
10
40.23
Solid Phase, Ice
4.14 24.28
20
42.42
0.6 6.95
-5-55 3<>- I 5
30
44.11
i.i 7.22
-6.71 34-3 1
40
46.13
-1.57 9.87
about 7 36.65
RUBIDIUM (Di) CHROMATE Rb 2 Cr 2 O 7 .
100 grams saturated aqueous solution contain 9.47 grams Rb 2 Cr 2 O 7
at 30.
(Schreinemaker and Filippo.)
RUBIDIUM HYDROXIDE RbOH.
100 grams sat. aqueous solution contain 63.39 grams RbOH at 30.
(Schreinemaker and Filippo.)
RUBIDIUM IODATE RbIO 3 .
100 grams H 2 O dissolve 2.1 grams RbIO 3 at 23.
(Wheeler Am. J. Sci. [3] 44. "3. '92-)
RUBIDIUM IODIDE Rbl.
100 grams H 2 O dissolve 137.5 grams Rbl at 6.9, and 152.0 grams at
17-4. (Reissig Liebig's Ann. 127. 33. '63-)
273 RUBIDIUM IODIDE
SOLUBILITY OF RUBIDIUM IODIDE IN ORGANIC SOLVENTS.
(Walden Z. physik. Ch. 55, 713, 718, '06.)
Solvent.
Acetonitril
Propionitril
Nitromethane
Acetone
Furfurol
Formula.
CH 3 CN
C 2 H 5 CN
CH 3 N0 2
(CH 3 ) 2 CO
C 4 H 3 O.COH
Grams Rbl
per 100 cc. Solution.
1.478 at o
0.274 "
0-567 "
0.960 "
i. 350 at 25
0-305 "
0.518 "
0.674 "
4-930 "
RUBIDIUM BROM IODIDE RbBrJ.
loo gms. sat. aq. solution contain about 44.0 gms. RbBr 2 I, and
the Sp. Gr. of the solution is 3.84.
(Wells and Wheeler Am. J. Sci. [3] 43, 475, '92.)
RUBIDIUM NITRATE RbNO 3 . SOLUBILITY IN WATER.
(Berkeley Trans. Roy. Soc. (Lond.) 203 A, 207, '04.)
Mols. OramsRhNO, rv>r rooGms. Mols.
K. DIN 03 '
Per Liter.
Water.
Solution.
i\i)iM\J3
Per Liter.
Water.
Solution .
1.27
19-5
16.3
60
7-99
200
66.7
10
2 .04
33-o
24.8
70
9.02
2$I
71 .5
20
3-10
53-3
34-6
80
9-93
309
75-6
30
4-34
81.3
44.8
90
10.77
375
78.9
40
5.68
116.7
53-9
IOO
n-54
452
81.9
50
6.88
I 55- 6
60.9
118.3
12 .76
617
86.1
RUBIDIUM PERMANGANATE RbMnO 4 .
One liter of aqueous solution contains 6.03 grams RbMnO 4 at 7.
(Muthmann and Kuntze Z. Kryst. Min. 23, 377, '94.)
loo cc. sat. aq. solution contain 0.46 gm. RbMnO 4 at 2, 1.06 gms. at
19 and 4.68 gms. at 60. (Patterson J. Am. Ch. Soc. 28, 1735, '06.)
RUBIDIUM SELENATE Rb 2 SeO 4 .
loo grams H 2 O dissolve 158.9 grams Rb 2 SeO 4 at 12.
(Tutton J. Ch. Soc. 71, 850, '97-)
RUBIDIUM FLUO SILICATE Rb 2 SiF 6 .
loo gms. H 2 O dissolve 0.16 gm. Rb 2 SiF 6 at o, and 1.36 gms. at 100.
(Stolba J. pr. Ch. 101, i, '67.)
RUBIDIUM SILICO TUNGSTATE Rb 8 SiW 12 O 42 .
loo gms. H 2 O dissolve 0.65 gm. Rb 8 SiW 12 O 42 at 20, and 5.1 gms. at
I OO. (Godeffroy Ber. 9, 1363, '76.)
RUBIDIUM SULPHATE Rb 2 SO 4 . SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 550, '94; Berkeley Trans. Roy. Soc. (Lond.) 203 A, 207, '04.)
t*.
Mols. c
RW50, *
per Liter.
ims. Rb 2 SO 4 per 100 Gms. A0
Mols. Gms. Rb 2 SO 4 per 100 Gms.
Water.
Solution.
per Liter.
Water.
Solution.
o
1.27
3 6 -4
27-3
60
2.15
67.4
40-3
10
I. 4 6
42 .6
29.9
7
2.25
71.4
41.7
20
I .64
48.2
32-5
80
2-34
75 -
42.9
30
1-79
53-5
34-9
90
2.42
78.7
44-o
40
I .92
58-5
36.9
IOO
2.49
81.8
45 -o
SO
2 -O4
63-1
38.7
102.4
2 -SO
82.6
45-2
RUBIDIUM SULPHATE
274
SOLUBILITY OF RUBIDIUM DOUBLE SULPHATES IN WATER AT 25.
(Locke Am. Ch. J. 27, 459, '01.)
Formula.
Rb 2 Cd(S0 4 ) 2 .6H 2
Rb 2 Co(S0 4 ) 2 .6H 2
Rb 2 Cu(S0 4 ) 2 .6H 2
Rb 2 Fe(SO 4 ) 2 .6H 2 O
Per IPO cc. H 2 O.
Gms. Mols.
Anh. Salt. Salt.
76.7 0.1615
9.28 0.022
IO.28 O.O24I
24.28 0.0579
Formula.
Rb 2 Mn(SO 4 ) 2 .6H 2 O
Rb 2 Mg(S0 4 ) 2 .6H 2
Rb 2 Ni(S0 4 ) 2 .6H 2
Rb 2 Zn(SO 4 ) 2 .6H 2 O
Per IPO cc. H 2 O.
Gms. Mols.
nh. Salt. Salt.
35-7
20.2
5.98
10.10
0.0857
0.0521
0.0142
0.0236
SALICYLIC ACID C 6 H 4 .OH.COOH 1:2.
SOLUBILITY IN WATER. (See also p. 61.)
.. 315. '9; tummann ana i^angoeck iota. 51
with the following, see Alexejew -Ann. Physik. Chem. 28, 305, '86; Bourgion
IS* 165, '?8; Ost. J. pr. Ch. [2] 17, 232, '78.)
O
10
20
Gms.
Cel^OHCOOH
per
Liter Solution.
0.8
I .2
1.8
25
30
40
50
Gms.
Q,H 4 OH.COOH
per
Liter Solution.
2.2
2-7
3-7
5-4
60
70
80
Ann. chim. phys. [5]
Gms.
CeH 4 OH.COOH
per
Liter Solution.
8.2
I 3 .2
20-5
SOLUBILITY OF SALICYLIC ACID (LIQUID) IN WATER.
(Alexejew.)
Determinations by Synthetic Method. See Note, page 9. Figures
read from curve.
Gms. CeH 4 OHCOOH
per 100 Gms.
60
70
80
00
95
temp.)
Aqueous
Layer.
Salicylic Acid
Laver.
7
68
8
64
12
58
19
49
32
SOLUBILITY OF SALICYLIC ACID IN AQUEOUS SALT SOLUTIONS AT 25*
AND AT 35.
(Hoffmann and Langbeck Z. physik. Ch. 51, 407, '05.)
Salt.
KC1
KN0 3
NaCl
Normality
of Salt
Gms.
C^OHCOOH <
dissolved at 25.
dissolved at 35.
Solution.
Liter. Gms. per 1000 G. Molecular Gms. per 1000 G. Molecular
gms. Sat. Sol. percentage, gms. Sat. Sol. percentage.
o
.0
O.
2
.206
2.8851
3
.197
.020
I
49
2
.24
2 .9216- ICT 4
3
23
4
.2206.
10"
100
7
.46
2
25
2-9377 "
3
23
4
.2203
n
.492
36
73
2
.02
2.6321 "
3
.9268
tt
I
.004
74
.92
I
.89
2-4759
2
.68
3
5003
u
.020
2
.02
2
25
3.9351 "
3
25
4
2499
tt
.100
10
.12
2
30
3-OJ03 "
3
32
4
3334
it
o
504
5 1
.10
2
38
3.1061 "
3
38
4
.4123
tt
I
.004
101
.60
2
39
3.1249
3
36
4
.3848
it
.020
i
.19
2
23
2.9110
3
.22
4
.2062
tt
.100
5
95
2
.22
2.9027 "
3
.20
4
.1806
tt
497
29
.50
2
OO
2.6128
2
85
3
.7171
tt
o
.988
58
.80
I
72
2.2487 "
2
43
3
.1596
it
275
SALICYLIC ACID
SOLUBILITY OF SALICYLIC ACID IN AQUEOUS SOLUTIONS OF SODIUM
FORMATE, ACETATE, AND BUTYRATE AT 26.4.
(Philip J. Ch. Soc. 87, 992, '05.)
*_i_ Mols.
Per Liter in:
100
per Liter.
i<_nj
HCOONa. CH 3 COONa. C
:3H 7 COONa^
O
I.7I I.7I
I.7I
I
2-35 2.47
2.50
2
3-05 3-35
3 -48
3
3-7 4-2
4-35
4
5
4-3 5- 1
48 6.1
5-3
63
Per Liter in:
Ocfcll
per Liter.
O
I
2
3
4
5
HCOONa. CHsCOONa. C 3 H 7 COONa
2-36 2.36 2.36
3-7 3-6
5-o 5.2
6.2 6.75
7.2 8.3
3-3
4-5
5-65
6.85
8.1
SOLUBILITY OF SALICYLIC ACID IN AQUEOUS SOLUTIONS OF SODIUM
SALICYLATE AT 20.1.
(Hoitsema Z. physik. Ch. 27. 315, '98.)
Gram Mols. per Liter. D. Gr.
Grams per Liter.
CsttiOH
COOH.
C6H4OH of
COONa. Solutions.
Cfitt^OH
COOH.
C6H 4 OH
COONa.
Solid
Phase.
O
.0132
1.002
I
-823
O
.0
C^OHCOOH
OII2
-017
.003
I
55
2
705
"
O
-OI24
.113
.009
I
7i
17
.98
O
0143
O
.226
.016
I
97
35
.96
i
0164
344
.024
2
.26
54
74
"
0203
.500
034
2
.80
79
56
"
062
I
.70 1
.098
8
56
270.1;
o
095
2
.11
137
13
.11
335
f Cel^OHCOOH.Cel^OHCOONa
7 ( + CH40HCOOH
o
OQI
2
.19
.144
12
56
348
4
CH4OHCOOH.CH40HCOONa
o
086
3
.41 1.215
II
.88
542
.6
o
081
4
.23 1.263
II
.19
673
^ J CaHUOHCOOH.C^OHCOONa
( +C6H4OHCOONa
o
048
4
.18 1-259
6.63
665
.1
CH4QHCOONa
021
4
.12 1-258
2
.90
665
5
OO
4
r 5 1-257
O
.0
660
3
SOLUBILITY OF SALICYLIC ACID IN ALCOHOLS IN ETHER AND IN
ACETONE.
(Timofeiew Compt. rend. 112. 1137, '91; at 15, Bourgoin Ann. chim. phys. [5] 13, 405, '78;
at 17 and 23, Walker and Wood J. Ch. Soc. 73, 6>, '98.)
Solvent.
CH 3 OH
CH 3 OH
C 2 H 5 OH
C 2 H 5 OH
C 2 H 5 OH
CpHUOH 90%
t.
-3
-f 21
-3
+ 15
21
15
Cms. Ce^OHCOOH
per loo Gms.
Solvent.
C 3 H 7 OH()
C 3 H 7 OH()
(CH 3 ) 2
(CH 3 ) 2
(CH 3 ) 2 CO
* Per
Gms. CH4OHCOOH
4 t per 100 Gms.
Solvent. Solution.
40.67 28.91
62.48 38.46
36.12 26.29
49.63 33-17
53-53 34.87
42.09 29.62
Solvent. Solution,
3 26.12 20.71
+ 21 37.69 27.36
15 50.47 33-55
17 23.4*
23 3i 3*
ioo cc. Sat. Solution.
SALICYLIC ACID 276
SOLUBILITY OF SALICYLIC ACID IN AQUEOUS SOLUTIONS OP ETHYL
ALCOHOL, Iso BUTYL ALCOHOL, DEXTROSE, CANE SUGAR, AND OF
LEVULOSE AT 25 AND AT 35.
(Hoffmann and Langbeck Z. physik. Ch. 51, 400, '05.)
Aq. Solvent.
H 2 O
C,H 5 OH
u
II
ll
C 4 H 9 OH (iso)
ii
ii
C 6 H 12 8
Cone, of
Solvent.
CH 4 OHCOOH dis-
solved at 25.
C 8 H 4 OHCOOH dis-
solved at 35.
Normality.
O.O
Gms. per
Liter.
0.0
Grams Grams Grams
molecular per ioo gms. molecular
percentage. sat. solution, percentage
2.8851 0.22064.1844
Grams
per ioo gms.
sat. solution.
0.3197
O.
0249
I.
146
2.
8966. 10~ 4 0.222
4
.2044.IO""" 4
0.
322
O.
0560
2.
578
2.
9150 "
0.223
4
.2348
ii
0.
324
0.
1747
8.
04
2.
9901
0.229
0.
2399
II.
05
4
4341
ii
0.
339
I.
03
47-
4
3-
5279 "
0.270
5
.28l6
ii
0.
404
I.
638
75-
44
3-
9253
0.300
O.
O2O
i.
496
2.
909
0.223
4
.229
ii
0.
324
0.
051
3-
74
2.
955
0.226
4
.289
ii
0.
329
0.
IOO
7-
48
3-
033
0.232
4
435
ii
O.
339
0.
5 21
38.
60
3-
718 "
0.285
5
.624
ii
O.
0.
02
6
2.
886 "
0.221
4
.184
n
0.
321
0.
IO
18.
2.
898
O. 222
4
.202
ii
0.
322
O.
50
89.
6
2.
954
0.226
4
.263
ii
O.
326
I.
00
180.
3-
015 "
0.231
4
.360
ii
0.
334
O.
02
6.
88
2.
885 "
O. 221
4
.206
ii
0.
322
0.
IO
34-
97
2.
964 "
0.227
4
.28 7
ii
O.
328
0.
50
172.
3-
239
0.248
4
.697
ii
0.
360
I.
10
376.
3
3-
633 "
0,278
5
.236
ii
0.
401
0.
02
3-6
2.
888 "
0.221
. . .
0.
06
10.
8
2.
895 "
0.221
. . .
0.
25
45-
2.
944 "
C.225
C 6 .H 12 O a
SOLUBILITY OF SALICYLIC ACID IN BENZENE.
(Walker and Wood J. Ch. Soc. 73, 620, '98.)
Gms. Gms. Gms.
t o QjIL^OHCOOH t o C6H4OHCOOH t <, C^OHCOOH
per ioo Gms. per ioo Gms. per ioo Gms.
r* TT r* XT r* TT
eerie. i^6"6- v^ng.
II-7 0.460 30.5 0.991 49.4 2.380
18.2 0.579 34.6 1.261 64.2 4.40
36.6 1.430
SELENIUM Se.
SOLUBILITY IN CARBON BISULPHIDE.
(Marc Z. anorg. Ch. 48, 425, '06.)
ioo cc. CS 2 dissolve 0.065 g m - amorphous Se at room temperature.
Se which is heated to 180 for 6-7 hours is insoluble in CS 2 . Se crystal-
lized from the melt at 200 is insoluble in CS 2 . Se heated once quickly
to 140 is very slightly soluble in CS 2 .
ioo gms. methylene iodide (CH 2 I 2 ) dissolve 1.3 gms. Se at 12.
(Retgers Z. anorg. Ch. 3, 346, '93.)
277
SELENIOUS ACID
SELENIOUS ACID H 2 SeO 3 .
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 551, '94.)
Cms. H 2 SeO 3
100 Gms. Soli
10
O
+ 10
20
per
ution.
42.2
47-4
55-o
62 .5
t o Gms. H 2 SeO3 per
100 Gms. Solution
t Gms. HjSeOs per
* 100 Gms. Solution.
2 5
67.0
60
79-3
30
40
70.2
77-5
70
80
79-3
79-3
50
79.2
90
79-4
SILICON Si.
SOLUBILITY IN LEAD AND IN ZINC.
(Moissan and Siemens Ber. 37, 2088, '04.)
In Lead.
t.
Gms. Si per 100
Gms. Solution.
1250
0-024
1330
0.070
1400
0-150
1450
!55
O-2IO
0.780
600
650
730
800
850
In Zinc.
Gms. Si per 100
Gms. Solution.
0-o6
o-57
0.92
i .62
SILICON IODIDES Si 2 I 6 , SiI 4 .
SOLUBILITY IN CARBON BISULPHIDE.
(Friedel and Lachburg Bull. soc. chim. [2] 12, 92, '69; Friedel Liebig's Ann. 149, 96, '69.)
ioo gms. CS 2 dissolve 19 gms. Si 2 I 6 at 19.
100 gms. CS 2 dissolve 26 gms. Si 2 I 6 at 27.
ioo gms. CS 2 dissolve 2.2 gms. SiI 4 at 27.
SILICO TUNGSTIC ACID H 8 SiW 12 O 42 .
ioo gms. H 2 O dissolve 961.5 crystallized silico tungstic acid at 18,
and solution has Sp. Gr. 2.843.
SILVER 278
For equilibrium between metallic Silver and mercury (Silver amai
gam) and mixed aqueous solutions of their nitrates, determined foe
mixtures of the two metals in all proportions, see Reinders Z. physik.
Ch. 64, 609, '06.
SILVER ACETATE CH 3 COOAg.
SOLUBILITY IN WATER.
(Nernst Z. physik. Ch. 4, 379,' 89;
Nauman and Rucker Ber. 38, 2293
Arrhenius Ibid, u, 396, '93; Goldschmidt Ibid. 25, 93, '98,
, '05; Raupenstrauch Monatsh. Ch. 6, 585, '85; Wright and
Thompson Phil.
Mag. [5] 17, 288, '8
4; 19, it
'85. )
t o Gms . Ag( C 2 H 3 O 2 ) 1
per Liter.
Gms.Ag(C 2 H 3 O 2 )
per Liter.
f.
Gms. Ag(C 2 H 3 O 2 )
per Liter.
O
7-22
25
II. 2
50
16.4
10
8-75
30
12 .1
60
18.9
15
9-4
40
I4-I
70
21.8
2O
10.4
80
25.2
SOLUBILITY OF SILVER ACETATE IN AQUEOUS SOLUTIONS OP:
Silver Nitrate. Sodium Acetate.
Gms^ Gms. CH 3 COOAg per Liter at: CHaCOONa Gms - CH 3 COOHg per Liter at:
pe/Liter. 16 (Nernst). i9.8(Arrhenius). per Liter * 16 (N.,N.andR.). i8.6(A.). '
o 10.05 9-85 o Jo- 05 9.9
5 8.2 7.9 5 6.3 6.6
10 7.0 6.6 10 4.6 4.9
15 6 -4 5-5 X 5 3-8 4-i
20 5-7 4-5 20 3.3 3.5
30 4-4 30 2.8
40 3.2 ... 40 ... 2.4
SILVER Mono Chlor ACETATE CH 2 ClCOOAg.
One liter aqueous solution contains 12.97 grams CH 2 ClCOOAg at
16.9. (Arrhenius)
SOLUBILITY OF SILVER MONO CHLOR ACETATE AT 16.9 IN
AQUEOUS SOLUTIONS OF:
Silver Nitrate. Sodium Chlor Acetate.
Gms.
AgN0 3
per Liter.
Gms.
CH 2 ClCOOAg
per Liter.
Gms.
CH 2 ClCOONa
per Liter.
Gms.
CH 2 ClCOOAg
per Liter.
o.o
9 .6
17.0
12-97
10.05
7-55
O-O
3-88
7-77
!5-53
12.97
10.05
8.16
6.02
31.07
58.26
4.19
3.26
SILVER Di Propyl ACETATE AgC 8 H 15 O 2 .
100 gms. H 2 O dissolve 0.123 m - AgC 8 H 15 O 2 at 11.7, and 0.190 gm.
at 72.
(Fiirth Monatsh. Ch. 9. 311, '88.)
279 SILVER ACETATES
SILVER Methyl Ethyl ACETATE Ag.CH 3 .CH 2 .CH(CH 3 )COO.
SILVER Di Ethyl ACETATE Ag.[(C 2 H 5 ) 2 CH.COOj.
SILVER Tri Methyl ACETATE Ag.(CH 3 ) 3 CCOO.*
SOLUBILITY OF EACH WATER.
(Sedlitzky Monatsh. Ch. 8, 563, '87; Keppish Ibid, g, 589, '88; Stiassny Ibid. 12, 601, '91.)
Gms. per 100 Gms. H2O. Gms. per 100 Gms. H2O.
I/ .
Ag.C 5 H 9 O 2 .
AgC 6 H n 2 .
AgC 5 H 9 O 2 *
It .
AgC 5 H 9 2 .
AgQHnOs.
AgC6H 9 O 2 *
o
I .112
0.402
1. 10
50
I .602
0-536"
i-47
IO
I .126
0.413
I - I 5
60
1.827
0-585
i-57
20
I.l82
0.432
1.22
70
2.093
0.643
1.68
30
1.280
0.458
I .22
80
2.402
i. 80
40
I .420
0.494
I -37
SILVER BENZOATE C 6 H 6 COOAg.
One liter of aqueous solution contains 1.763 gms. C 6 H 5 COOAg at
14.5, and 2.607 gms. at 25.
(Holleman Z. physik. Ch. 12, 129, '93; Noyes and Schwartz Ibid. 27, 287, '98.)
SOLUBILITY OF SILVER BENZOATE AT 25 IN AQUEOUS SOLUTIONS OF:
Nitric Acid (N. and S.). Chlor Acetic Acid (N. and S.).
Millimols^per Liter. Grams per Liter. Millimols per Liter. Grams per Liter.
HN0 3 . COOAg. HN 3- COOAg. C1COOH. COOAg. C1COOH. COOAg,
o.o 0.01144 o.o 2.607 -o 0.01144 o.o 2.607
0.004435 0.01395 0.280 3.195 0.00394 0.01385 0.371 3.172
0.00887 0.01698 0.559 3-889 0.00787 o 01612 0.744 3.691
0.00892 0.01715 0.562 3.926 0.01574 0.02093 1.487 4.792
0.01774 0.02324 1.118 5.321
0.02674 0.03071 1.686 7-031
One liter of cold alcohol dissolves 0.169 g m - C 6 H 5 COOAg; one liter
Of boiling alcohol dissolves 0.465 gram. (Liebermann Ber. 35, 1094, '02.)
SILVER BORATE AgBO 2 .
One liter of aqueous solution contains about 9.05 gms. AgBO 2 at 25.
(Abegg and Cox Z. physik. Ch. 46, n, '03.)
SILVER BROMATE AgBrO 3 .
SOLUBILITY IN WATER.
t. Gms. AgBrO 3 per Liter. Authority.
2O I .586 (Bottger Z. physik. Ch.46, 602, '03.)
24.5 I.9II (Noyes Z. physik. Ch. 6, 246, '90.)
25 I . 68 (Longi Gazz. chim. ital. 13, 87, '83.)
SOLUBILITY OF SILVER BROMATE IN AQUEOUS AMMONIA AND NITRIC
ACID SOLUTIONS AT 25.
(Longi.)
Grams AgBrOs per
Solvent.
1000 cc. Sol. 1000 Gms. Sol.
Ammonia Sp. Gr. 0.998=5% 35 .10 35-54
Ammonia Sp. Gr. 0.96 =10% 443.6 462.5
Nitric Acid Sp. Gr. 1.21 =35% 3.81 3.12
SILVER BROMATE 280
SOLUBILITY OF SILVER BROMATE AT 24.5 IN AQUEOUS
SOLUTIONS OF:
Silver Nitrate (Noyes). Potassium Bromate (N.).
Normal ^Content. Gms. per Liter. Normal Content. Cms, per Liter.
AgN0 3 . AgBr0 3 .' AgNO 3 . AgBrO 3 . KBrO 3 . AgBrO 3 . KBrO 3 . AgBrOs-
o.o 0.0081 o.o 1.911 o.o 0.0081 o.o 1.911
0.0085 0.0051 1-445 I - 20 3 0.0085 0.00519 1.42 1.225
0-0346 0-0022 5.882 0.510 0-0346 0.00227 5.78 0-536
SILVER BROMIDE AgBr.
SOLUBILITY IN WATER.
t . Gms. AgBr per Liter. Authority.
2O O - 000084 (Bottger Z. physik. Ch. 46, 602, '03.)
25 O .OOOI37 (Abegg and Cox Z. physik. Ch. 46, xi, '03.)
100 O .00370 (Bottger Z. physik. Ch. 56, 93. '06.)
(See also Holleman Z. physik. Ch. 12, 129, '93; Kohlrausch Ibid. 50, 365, '05.)
SOLUBILITY OF SILVER BROMIDE IN AQUEOUS AMMONIA SOLUTIONS.
(Longi Gazz. chim. ital. 13, 87, '83; at 80, Pohl Sitzber. Akad. Wiss. Wien, 41, 267, '60.)
Gms. AgBr at 12 per G ras. AgBr at 80 per
Solvent. I000 cc . 1000 Gms. o Gms.
Solvent. Solvent. Solvent.
Ammonia Sp. Gr. 0.998=5% 0.114 0.114
Ammonia Sp. Gr. o . 96 =10% 3 .33-4-0 3-47
Ammonia Sp. Gr. 0.986 ... ... 0.51* I .ot
* Dried AgBr. t Freshly pptd.
SOLUBILITY OF SILVER BROMIDE IN AQUEOUS SOLUTIONS OF:
Ammonia at o. Monq Methyl Amine at 11.5.
(Jarry Ann. chim. phys. [7] 17, 363. *99-) (Jarry.)
Grams per 100 cc. Solution. Gms. per 100 cc. Solution.
AgBr. NH 3 Gas. AgBr. NH 2 CH 3 . AgBr.
3.07 0.080 26.27 1.067 ii. 01 0-07
4.88 0.096 31-26 1-568 13-17 0.12
6.69 0.172 33.89 1.987 15.13 0.16
8.29 0.212 36.52 2.669 J 7-97 - 2 8
11.51 0.349 37-22 2.888 32.58 0.55
J 5-32 0.557 37.70 2.930 35.62 0.73
18.09 0.722 39-26 2.892 43-n 1-27
19.53 0.741 39-95 2.852 48-44 2.89
SOLUBILITY OF SILVER BROMIDE IN AQUEOUS SOLUTIONS OF
SODIUM THIO SULPHATE AT 35.
(Richards and Faber Am. Ch. J. 21, 186, '99.)
Gms. Cryst. Na Thio Sulphate Gms. AgBr Dissolved Mols. AgBr Dissolved
per Liter. per Gram of Thio Sulphate. per Mol. of
ioo 0.376 0.496
200 0.390 o-5 I S
300 0.397 0.524
400 0.427 0.564
281 SILVER BROMIDE
SOLUBILITY OP SILVER BROMIDE IN AQUEOUS SALT SOLUTIONS.
(Valenta Monatsh. Ch. 15, 250, '94; see also Cohn Z. physik. Ch. 18, 61, '95.)
Gms.AgBr per 100 Cms. Aq. Solution of Concentration:
Salt Solution. t. / ^- N
1:100. 5:100. 10: 100. 15:100. 20:100.
Sodium Thio Sulphate 20 0.35 1.90 3.50 4.20 5.80
" Calc. by Cohn 20 0.50 2.40 4.59 6.58 8.40
Sodium Sulphite 25 0.04 ... 0.08
Potassium Cyanide 25 ... 6.55
" Calc. by Cohn 25 ... 6.85
Potassium Sulphocyanide 25 ... ... o . 73
Ammonium Sulphocyanide 20 ... 0.21 2.04 5-30
Calcium Sulphocyanide 25 0.53
Barium Sulphocyanide 25 ... ... 0.35
Aluminum Sulphocyanide 25 ... ... 4-50
Thio Carbamide 25 ... ... i .87
Thio Cyanime 25 0.08 0.35 0.72
NOTE. Cohn shows that the lower results obtained by Valenta
are due to the excess of solid AgBr used and the consequent formation
of the less soluble di salt 3(AgS 2 O 3 Na) 2 instead of the more soluble
salt (AgS 2 O 3 Na) 2 Na 2 S 2 O 3 .
TOO cc. H 2 O containing 10 per cent of normal mercuric acetate,
Hg(C 2 H 3 O 2 )2 + Aq., dissolve 0.0122 gram AgBr at 20.
100 gms. NaCl in cone. aq. solution dissolve 0.474 gm. AgBr at 15.
100 gms. NaCl in 21 per cent solution dissolve 0.182 gm. AgBr at 15.
100 gms. KBr in cone, solution dissolve 3.019 gms. AgBr at 15.
95 gms. NaCl + 10 gms. KBr in --cone. aq. solution dissolve 0.075
gm. AgBr at 15.
(Schierholz Sitzber. K. Akad. Wiss. (Vienna) xox. 2b, 4, '90-)
SILVER BUTYRATE C 3 H 7 COOAg.
SILVER (Iso) BUTYRATE (CH 3 ) 2 CHCOOAg.
SOLUBILITY OF EACH IN WATER.
Ch. 25, 93, '98; Arrhenius Ibid. II, 396, '93'. R'
Ch. 6, 589, '85.)
Gms. per 100 Grams H 2 O. Grams per 100 Gms. H 2 O.
(Goldschmidt Z. physik. Ch. 25, 93, '98; Arrhenius Ibid, u, 396, '93'. Raupenstrauch Monatsh
Ch. 6, 589, '85-)
Butyrate. Iso Butyrate. Butyrate. Iso Butyrate.
o 0.363 0.796 30 0.561(1.1020.) 1. 060
10 0.419 0.874 40 0.647
17.8 0.432 (A.) ... 50 0.742 1.313
18.8 0.445 (A.) 60 0.848
20 0-484(0.9990.) 0-961 70 0.901 1.670
25 ... (1.0440.) ... 80 1.14 1-898
SILVER BUTYRATE
282
SOLUBILITY OF SILVER BUTYRATE IN AQ. SOLUTIONS OF SILVER
ACETATE, SILVER NITRATE AND OF SODIUM BUTYRATE.
(Arrhenius Z. physik. Ch. n, 396, '93.)
In Silver Acetate at 17.8.
G. Mols. per Liter. Grams per Liter
CH 3 C 3 H 7
COOAg. COOAg.
O-O O-O22I
0.0270 0.0139
0-0506 O.OIO3
G. Mols. per Liter.
COONa.
O.O
O . OO66
0-0164
0.0329
C 3 H 7
COOAg.
O.O224
O.OI99
0.0169
O.OI3I
CH 3 C 3 H 7 Airivro
COOAg. COOAg.
o.o 4-32 o.o
4.51 2.71 0.0667
8.45 2.01 O.IOO
In Sodium Butyrate at
Grams per Liter. G. Mols.
O.O228
0.0078
0.0062
18.2.
per Liter.
' C 3 H 7 C 3 H 7 '
COONa. COOAg.
o.o 4-363
0-73 3-881
1.81 3-296
3:^2 2.555
' C 3 H 7
COONa.
0-0658
0.263
0-493
C 3 H 7
COOAg.
O.OO9I
o . 0060
0.0040
O.OO27
In Silver Nitrate at 18.8.
G. Mols. per Liter. Grams per Liter.
AgNO 3 .
o.o 4.445
11 -33 I -52i
17.00 1.209
Grams per Liter.
' C 3 H 7 C 3 H 7
COONa. COOAg.
7.24 1.774
14.47 I-I70
28.96 0.780
54.28 0.526
SILVER CAPROATES Ag(C 6 H n O 2 ).
SOLUBILITY IN WATER.
(Keppish Monatsh. Ch. 9, 589, '88; Stiassny Ibid. 12, 596, '91;
Ibid. 15, 26, '94; Altschul Ibid. 17,
; Kulisch Ibid. 14, 570, '93; Konig
568, '96.)
Results in terms of grams salt per 100 grams H 2 O.
2 Methyl Pentan M
A Normal Caproate \ C JH
*- CH 3 (CH 2 ) 4 COOAg. CHa.CH.CHa
ethyl 3 Pentan 4 Methyl Pentan
Acid 4 4 Acid
CH 3 .CH 2 CH 3 (CH 2 ) 2 CH(CH 3 )
:H 3 CH 2 COOAg. .COOAg.
.(CH 2 ) 2 COOAg. .CH(
0.076 (A.)
-078(Keppisch) o . l68 (Konig)
0-88o(Kulish)
0.510 (Stiassny)
IO
0.085
0-089 0-162
0.858
0-528
20
o.ioo
0.107 0.163
0-849
0-550
30
0.123
O.I3I O.I7O
0.854
o-574
40
0.154
0.161 0.183
0-871
0.602
50
0.193
0.198 0.203
0-902
0-632
60
0.240
0.243 0.229
0.946
0.666
70
0.295
o . 288 o . 263
1.003
0.702
80
o-354
0.300
1.073
0.742
90
0-347
I-I57
SILVER CARBONATE Ag 2 CO 3 .
SOLUBILITY IN WATER.
t. Gms. Ag 2 CO 3 per Liter. Authority.
15 .031 (Kremers Pogg. Ann. 85, 248, '52.)
25 O -033 (o- 00012 S m ' atoms Ag.) (Abegg and Cox Z. physik. Ch. 46, n, '03.)
IOO O 50 (Joulin Ann. chim. phys. [4] 30, 260, '73.)
15 O .85 (inH 2 O sat. with CO 2 ) (Johnson Ch. News, 54, 75, *86.)
SILVER CHLORATE AgClO 3 .
loo grams cold water dissolve 10 grams AgClO 3 (Vauquelin) ; 20
gms. AgClO 3 (Wachter).
283 SILVER CHLORIDE
SILVER CHLORIDE AgCl.
SOLUBILITY IN WATER.
(A large number of determinations are quoted by Abegg and Cox Z. physik. Ch. 46, n, '03; see also
Kohlrausch Ibid. 50, 356, 04- '05; BSttger Ibid. 46, 602, '03, 56, 93, '06.)
t. i4- 20. 25. 42. loo*.
Gms. AgCl per liter 0-0014 0.0016 0.0020 0.0040 0.0218
SOLUBILITY OP SILVER CHLORIDE IN AQUEOUS SOLUTIONS OF:
Ammonia at o. Mono Methyl Amine at 11.5.
(Jarry Ann. chim. phys. [7] 17, 342, '99.) (Jarry.)
Grams per 100 Grams Solution. Gms. per 100 Gms. Solution.
NH 3 Gas.
AgCl.
NH 3 Gas.
AgCl.
NH 2 CH 3 .
AgCl.
i-45
0.49
28.16
6 -59
I. 7 8
0.16
1-94
1.36
29.80
7.09
4-44
0.62
5 .60
3-44
30.19
7-25
5-51
0.83
6.24
4.00
32-43
5-87
7.66
1.32
11-77
4.68
34-5 6
4-77
I3-70
3-29
16.36
5-i8
37-48
3-90
18.69
5-43
36.69
9-93
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS SOLUTIONS OF
AMMONIA.
(Longi Gazz chim. ital. 13. 87, '83; at 25, Valenta Monatsh. Ch. 15, 250, '94; at 80, Pohl
Sitzber. Akad. Wiss, Wien, 41, 627, '60.)
Aq. Ammonia of 0.998 Sp. Gr. = 5% 12 0.233
0.96 Sp. Gr. = 10% 18 7.84
0.986 Sp. Gr. 80 1.49
= 3% 25 1.40
= 15% 25 7.58
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS SOLUTIONS OF
AMMONIUM CHLORIDE.
(Schierholz Sitzber. K. Akad. Wiss. (Vienna) 101, 2b, 8, '90; see also Vogel N. Rep. Pharm. 23,
335, '74. Hahn Wyandotte Silver Smelting Wks., 1877.)
Solubility at 15. Solubility at Different Temperatures.
Grams per 100 Gms. Solution. t o Gms. per 100 Gms. Solution.
frHCl.
AgCl.
NH4C1. AgCl.
10-00
0-0050
15
26.31 0-276
14 29
o 0143
40
0.329
17.70
0-0354
60
0-421
19-23
0.0577
80
0.592
21.98
O.I 10
90
0.7II
25-31
0.228
IOO
0.856
28-45
0.340 (24.5)
no
1-053
Sat. at ord. temp.
0.157
Sp. Gr,
of 26.31 % NH 4 C1 solution at
iS = i.o8.
SILVER CHLORIDE
284
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS SOLUTIONS OP
ALUMINUM AND AMMONIUM SALTS.
(Valenta; see also Cohn Z. physik. Ch. 18, 61, '95-)
Gms. AgCl per 100 Gms. Solvent of Concentration-
Aq. Salt Solution.
Aluminum Surphocyanide
Ammonium Carbonate
Sulphocyanide
" Thio Sulphate
i . r
i : 100.
s
IOO.
10 :
IOO.
k
2 5
2
.02
le
25
20
. . .
o.
08
O
05
54
te
Calc.
20
by Cohn*
o-57
0.64
I.
3-
32
07
3
5
.92
.86
* See Note, p. 281.
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS HYDROCHLORIC
ACID SOLUTIONS AT ORDINARY TEMPERATURE.
(Pierre J. pharm. chim. [3] 12, 237, '47; Vogel.)
Solvent.
kq.
i vol. Cone. HC1 + i vol. H,O
Sat.HCl. Sp.Gr.i.i6 5
Gms. AgCl
per Liter.
Solvent.
Gms. AgCl
per Liter.
S-o
ioo vol. sat.
HC1 -f 10 vol.
H 2 0.56
1.6
+ ?o "
" 0.18
2.98
"
+ 30 "
" 0.09
) 5-6o
"
+ 5
" o-35
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS SALT SOLUTIONS.
(Vogel; Hahn; Valenta )
Salt Solution.
Barium Chloride
Barium Chloride
Barium Sulphocyanide
Calcium Sulphocyanide
Calcium Chloride
Calcium Chloride
Copper Chloride
Ferrous Chloride
Ferric Chloride
Manganese Chloride
Magnesium Chloride
Magnesium Chloride
Magnesium Chloride
Strontium Chloride
Zinc Chloride
Potassium Chloride
Potassium Chloride
Potassium Cyanide
Potassium Cyanide
Potassium Sulphocyanide
Sodium Chloride
Sodium Chloride
Cone, of Salt.
t.
Gms. AgCl per
zoo Gms. Solution.
27-32%
24-5
0.057
(H.)
saturated
ord. temp.
0.014
(Vg.)
10 : 100
2 5
O-2O
(VI.)
10 : loo
2 5
0.15
(VI.)
41-26%
24-5
0-571
(H.)
saturated
ord. temp.
0.093
(Vg.)
u
24-5
0-053
(H.)
u
0.169
(H.)
It
O.OO6
(H.)
C(
ti
O.OI3
(H.)
50 : 100
25
0.50
(VI.)
36.35%
24-5
0-53 1
(H.)
saturated
ord. temp.
0.171
(Vg.)
a
0.088
(Vg.)
a
24-5
0-0134
(H.)
u
ord. temp.
0-0475
(Vg.)
24.95%
19.6
0.0776
(H.)
5: ioo
25
2-75
(VI.)
5 ' I0
25
5-24
(Cohn*)
10 : ioo
2 5
O.II
(VI.)
saturated
ord. temp.
0-095
(Vg.)
25-95%
19.6
0.105
(H.)
* See Note, page 281.
SILVER CHLORIDE
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS SOLUTIONS OF
POTASSIUM CHLORIDE AT 15.
(Schierholz Sitzber. K. Akad. Wiss. (Vienna) 101, 20, 8, '90.)
Grams per 100 Grams Grams
loo Grams
lution.
er 100 Grams
>lution.
KC1.
IO.O
14.29
16.66
20-00
AgCl.
O-OOO
0-004
O-OOS
O.O2O
KC1. AgCl.
22-47 0.045
24.0 O.O72
25.0 0.084
Sp. Gr. of 25% KC1 sol,= 1.179
MIXTURES OF SILVER CHLORIDE AND SILVER HYDROXIDE IN EQUI-
LIBRIUM WITH AQ. POTASSIUM HYDROXIDE SOLUTIONS AT 25.
(Noyes and Kohr J. Am. Ch. Soc. 24, 1144, '02.)
Normality Millimols per Liter. Grams per Liter.
ofKOH. KC1. KOH," KC1. KOH. Agfcl.
o-333 3-4I4 347-8 0.255 10.05 0.4896
0.065 0.598 65.0 0-0446 2.OO 0.0828
SOLUBILITY OF SILVER CHLORIDE IN AQ. SOL. OF SODIUM CHLORIDE.
(Schierholz; Vogel; Hahn.)
Solubility
at 15.
Gms. per 100 Gms.
Solution.
NaCl.
IO-O
AgCl.
O.OO25
14.29
18.18
O.OO7I
O.Ol82
21.98
2 3-53
25.64
26.31
0.0439
0.0706
0.103
O.I27
Solubility at Different
Temperatures.
Cms. AgCl per 100 Gms.
Solution in:
Sp. Gr. of 26.31% NaCl sol. = 1.207. 109
14% NaCl 26.3% NaCl.
15
0.007
0.128
30
O-OII
0.132
40
0.014
0.158
So
0.023
0.184
70
0-042
0.263
80
0.054
0.315
90
0.069
0.368
100
0.090
0.460
109
0.107 (104)
0.571
SOLUBILITY AT 20, 50, AND 90 (CALC. FROM ORIGINAL).
Gms. NaCl
per zoo cc.
Solution.
(Barlow J. Am. Chem, Soc, 28, 1446, '06,)
Gms, NaCl
Gms. AgCl dissolved per 100 cc.
Solution at:
20.
O-OOOlS
5 .
0.0016
per 100 cc.
Solution.
Gms. AgCl dissolved per 100 cc.
Solution at:
15-3
20".
O.OC3I
o . 0090
50.
O.OI24
O.OI9I
90.
0.0436
0.0732
90.
3.43 o.ooois o.ooio 0.0067
4.60 0-00025 0.0025 o.oioo
5.75 0.00047 0.0034 0.0135
7.67 0-00125 0-0058 0.0236
Results are also given for the solubility of silver chloride in aqueous
sodium chloride solutions containing hydrochloric acid.
23.0 0.0313 0.0889 0.1706
SOLUBILITY OF SILVER CHLORIDE IN AQ. SODIUM NITRATE SOLUTIONS.
30
45-55
Gms. per 100 Gms. H2O.
NaNO 3 . AgCl.
0.787 O.OOO86
0.787 O.OOI46
0-787 0.00233
0-787 0.00399
I5-2O
a
Gms. per TOO Gms. H2O.
NaN0 3 . AgCl. '
O-393 0-00096
0-787 0.00133
2.787 0.00253
(Mulder,)
SILVER CHLORIDE 286
SOLUBILITY OF SILVER CHLORIDE IN AQUEOUS SOLUTIONS OF
SODIUM THIO SULPHATE, ETC.
(Valenta ; Cohn ; Richards and Faber Am. Ch. J. 2i> 168, '99.)
Gms. AgCl per ioo Gms. Aq. Solutions of Concentration:
Salt Solution. t. , <
i : ioo. 5:100. 10 : ioo. 15:100. 20:100.
Sodium Sulphite 25 ... ... 0.44 ... 0.95
Sodium Thio Sulphate 20 0.40 2.00 4.10 5-50 6.10
" Calc. by Cohn* 0.38 1.83 3.50 5.02 6.41
Sodium Thio Sulphate 35 ... 9.08 f
Thio Carbamide 25 ... ... 0.83
Thio Cyanime 25 0.40 1.90 3.90
* See Note, page 281. f Gms. per ioo cc. solution (R. and F.).
SILVER CHROMATE Ag 2 CrO 4 .
One liter of water dissolves 0.026 gm. Ag 2 CrO 4 at 18, and
gm. at 25. (Abegg and Cox Z. physik.[Ch. 46, n, '03; Kohlrausch Ibid 50, 356, '04^
SOLUBILITY OF SILVER CHROMATE IN AQUEOUS SOLUTIONS OF
NITRATES AT 100.
(Carpenter J. Soc. Chem. Ind. 5t 286, '86.)
c , Gms. Salt Gms. Ag 2 CrO 4
per ioo cc. HjjO. per ioo cc. Solution.
Water o 0.064
Sodium Nitrate 50 0.064
Potassium Nitrate 50 o . 192
Ammonium Nitrate 50 0.320
Magnesium Nitrate 50 0.256
SILVER (Di) CHROMATE Ag 2 Cr 2 O 7 .
One liter of aqueous solution contains 0.00019 gram mols. or 0.083
gram Ag 2 Cr 2 O 7 at 15. (Mayer - Ber. 36, 1741, '03)
SILVER CITRATE C 6 H 5 O 7 Ag 3 .
ioo gms. H 2 O dissolve 0.0277 gm. C 6 H 5 O 7 Ag 3 at 18, and 0.0284
gm. at 2 5. (Partheil and Hubner Archiv. Pharm. 241, 413, ; o 3 .)
SILVER CYANIDE AgCN.
One liter of aqueous solution contains 0.000043 gm. AgCN at 17.5
and 0.00022 gm. at 20 (by Conductivity Method).
(Abegg and Cox Bottger Z. physik. Ch. 46, 602, '03.)
SOLUBILITY OF SILVER CYANIDE IN AQUEOUS AMMONIA SOLUTIONS.
(Longi Gazz. chem. ital. 139 87, '83.)
ioo gms. aq. ammonia of 0.998 Sp. Gr. = 5% dissolve 0.232 gm.
AgCN at 12.
ioo gms. aq. ammonia of 0.96 Sp. Gr. = 10% dissolve 0.542 gm.
AgCN at 18.
SILVER SODIUM CYANIDE AgCN.NaCN.
ioo gms. H 2 O dissolve 20 gms. at 20, and more at a higher tem-
perature, ioo gms. 85% alcohol dissolve 4.1 gms. at 20.
(Baup Ann. chim. phys. [3] 53, 468, 58.)
SILVER THALLOUS CYANIDE AgCN.TlCN.
ioo gms. H 2 O dissolve 4.7 gms. at o, and 7.4 gms. at 16.
(Fronmiller Ber 11. 92, '78 J
287 SILVER FLUORIDE
SILVER FLUORIDE AgF.
100 gms. H 2 O dissolve 181.8 gms. at 15.8. Sp. Gr. of sol. = 2.61.
(Gore Proc. Roy. Soc. 18, 158, '70.)
SILVER FULMINATE CAg 2 (NO 2 )CN.
One liter of aqueous solution contains 0.075 g*n. C2Ag 2 N 2 O 2 at 13,
and O.lSo gm. at 30. (Holleman - Rec. trav. chim. 15, 159, '96.)
SILVER HEPTOATE (Onanthylate) AgC 7 H 13 O 2 ,
SOLUBILITY IN WATER.
(Laudau Monatsh. Ch. 14, 709, '93; Altschul Ibid. 17, 568, '96.)
t o Gms. AgC 7 Hi 3 O2 per 100 Gms. H 2 O. ^ Gms. AgC 7 H l3 O2 per 100 Gms. H2O.
O O -0635 (Landau) O .0436 (Altschul) 50 O . 1652 (Landau) o .0858 (Altschul)
10 0-0817 0.0494 60 0.1906 0.1036
20 0.1007 -555 7 0.2185 0.1351
30 0.1206 0.0617 80 0.2495 0.1688
40 0.1420 0.0714
SILVER IODATE AgIO 3 .
One liter of aqueous solution contains 0.04 gram or 0.00014 g-
mols. at i8-2o, and 0.05334 gm. or 0.000189 g. mols. at 25.
(Longi; Bottger; Kohlrausch; Noyes and Kohr J. Am. Ch. Soc. 24, 1141, '02.)
SOLUBILITY OF SILVER IODATE IN AQUEOUS SOLUTIONS OP
AMMONIA AND OF NITRIC ACID AT 25.
(Longi Gazz. chim. ital. 13, 87, '83.)
ioo gms. aq. ammonia of 0.998 Sp. Gr. = 5% dissolve 2.36 gms. AgIO 3 .
100 gms. aq. ammonia of 0.96 Sp. Gr. = 10% dissolve 45.41 gms.
AgI0 3 .
ioo gms. aq. nitric acid of 1.21 Sp. Gr. = 35% dissolve 0.096 gm.
AgI0 3 .
SILVER IODIDE Agl.
One liter of aqueous solution contains 0.0000028 gm. Agl at 2o-25.
(Average of several determinations by Kohlrausch, Abegg and Cox, etc. Holleman gives higher figures.)
i liter of aq. ammonia of 0.96 Sp. Gr. = 10% dissolve 0.035 gm.
Agl at 12. (Longi.)
SOLUBILITY OF SILVER IODIDE IN AQUEOUS SALT SOLUTIONS.
' (Valenta Monatsh. Chem. 15, 250, '94; Cohn Z. physik. Ch. 18, 61, '95.)
Gms. Agl per ioo Gms. Aq. Solution of Concentration:
Aq. Salt Solution. t. / * N
i : ioo. 5 : ioo. 10 : ioo. 15 : ioo. 20 : ioo.
Sodium Thio Sulphate 20 0.03 0.15 0.30 0.40 0.60
" Calc. by Cohn* 0.623 2.996 5.726 8.218 10.493
Potassium Cyanide 25 ... 8.28
" Calc. by Cohn* ... 8.568 ...
Sodium Sulphite 25 ... ... o.oi ... 0.02
Ammonium Sulphocyanide 20 ... 0-02 0.08 0.13
Calcium 25 ... 0.03
Barium " 25 0.02
Aluminum " 25 0.02
Thio Carbamide 25 ... ... 0.79
Thio Cyan ime 25 0.008 0.05 0.09
* See Note, page 281.
SILVER IODIDE 288
SOLUBILITY OF SILVER IODIDE IN AQUEOUS SOLUTIONS OP SODIUM
CHLORIDE, POTASSIUM BROMIDE AND OP POTASSIUM IODIDE AT 15.
(Schierholz Sitzb. K. Akad. Wiss. (Vienna) 101, ab, 10, '90.)
In Sodium Chloride. In Potassium Iodide.
Cms. per 100 Gms. Solution. Gms. per 100 Gins. Solution.
NlCL AgL ' KL AgL
26.31 0.0244 59.16 53.13
25.00 0.00072 57- J 5 40-0
50.0 25.0
40.0 13.0
In Potassium Bromide. |3 3 \ ' 33
Gms. per 100 Gms. Solution. 2 5 ' z '75
KBr Agl 21-74 1-576
30.77 0.132 20-0 O 80
ioo gms. sat. silver nitrate solution dissolve 2.3 gms. Agl at 11,
and 12.3 gms. at b. pt.
ioo gms. pyridine dissolve o.io gm. Agl at 10, and 8.60 gms. at
121 . (von Laszcynski Ber. 27, 2285, '94.)
SILVER MALATE C 4 H 4 O.Ag..
ioo gms. H 2 O dissolve 0.0119 gm. at 18, and 0.1216 gm. at 25.
(Partheil and Hiibner Archiv. Pharm. 241, 413, '03.)
SILVER NITRATE AgNO 3 .
SOLUBILITY IN WATER.
(Etard Ann. chim. phys. [7] 2, 526, '94; Kremers Pogg. Ann. 92, 497, '54; Tilden and Shenstone
Phil. Trans. 23, '84.)
Grams AgNOg per ioo Gms. Grams AgNO 3 per ioo Gms.
Solution. Water. Solution. Water.
5 48 (Etard) . . ... 50 79 (Etard) 82 455
o 53 55 122 60 81.5 84 525
10 62 63 170 80 85.5 87 669
20 68 69 222 ioo 88.5 90^ 952
25 70.5 72 257 120 91 95 1900
30 7 2 -5 75 3oo 140 93-5
40 76-5 79 376 160 95
ioo gms. 2HNO 3> 3H 2 O dissolve 3.33 gms. AgNO 3 at 20, and 16.6
gms. at 100.
ioo gms. cone. HNO 3 dissolve 0.2 gm. AgNO 3 .
(Schultz Zeit. Chem. [2] 5, 531, '69.)
MUTUAL SOLUBILITY OF SILVER NITRATE AND SODIUM NITRATE IN
AQ. ETHYL ALCOHOL.
(Hissnik Z. physik. Ch. 32, 557, 'oo.)
Results at 25. Results at 50.
(In Aq. Alcohol of rf, 0.945 = 37 wt. %.) (In Aq. Alcohol of dn 0839 - 75 wt. %.)
Gms. per ioo
Gms. Sol.
Wt. per cent in
Mix Crystals.
Gms. per too
Gms. Sol.
Wt. per cent in
Mix Crystals.
AgN0 3 -
NaN0 3 .
AgN0 3 .
NaNO 3 .
AgN0 3 .
NaNO 3 .
AgN0 3 .
NaNOa".
47-32
O
O
IOO
o.o
29
.78
O
o
IOO
o.o
44-01
8
>7 8
99-1
0-9
27
9
2
5
99
5
0-5
3 6. 7 8
20
.42
42.9
57-i
26
4
4
.2
99
3
0-7
29.97
23
.2
33-6
66.4
23
o
6
3
42
9
57-i
24.56
24
.82
27.6
72.4
18
3
7
.1
3 1
.0
69.0
8.02
26
.41
9-9
90.1
9
5
8
3
17
5
82.5
o.o
26
77
o.o
100.0
.0
8
54
.0
100.0
289 SILVER NITRATE
SOLUBILITY OF SILVER NITRATE IN ALCOHOLS.
(de Bruyn Z. physik. Ch. 10, 783, '92.)
ioo gms. abs. methyl alcohol dissolve 3.72 gms. AgNO 3 at 19.
ioo gms. abs. ethyl alcohol dissolve 3.10 gms. AgNO 3 at 19.
SOLUBILITY OF SILVER NITRATE IN AQUEOUS ETHYL ALCOHOL.
(Eder J. pr. Ch, [2] 17, 45. '78.)
Sp. Gr.of Aq. Volume Gms. AgNO 3 per ioo Gms. Aq. Alcohol at:
Alcoholic per cent t * \
Mixture. Alcohol. 15. 50. 75.
0.815 95 3.8 7.3 18.3
0.863 80 10-3 ... 42.0
0-889 7O 22.1
0.912 60 30.5 58.1 89.0
o-933 5o 35 - 8
0.951 40 56.4 98.3 160.0
0.964 30 73.7
0.975 2O 107.0 214.0 340-0
0.986 10 158-0
ioo gms. of a mixture of i vol. (95%) alcohol + i vol. ether dis-
solve 1.6 gms. AgNO 3 at 15.
ioo gms. of a mixture of 2 vols. (95%) alcohol + i vol. ether dis-
solve 2.3 gms. AgNO 3 at 15.
ioo gms. H 2 O sat. with ether dissolve 88.4 gms. AgNO 3 at 15.
(Eder.)
ioo gms. acetone dissolve 0.35 gm. AgNO 3 at 14, and 0.44 gm,
&t Io . (von Lasczynski Ber. 27^ 2285, '94; Naumann Ber, 37, 4332, '04.)
SILVER NITRITE AgNO 2 .
SOLUBILITY IN AQUEOUS SOLUTIONS OF SILVER NITRATE AT 18.
(Naumann and Rucker Ber. 385 2293, '05.)
Mols. per Liter, Grams per Liter. Mols. per Liter Grams per Liter.
AgNO 3 . AgNO 2 . AgNO 3 . AgNO 2 . AgNO 3 . AgNO 2 . AgNO 3 . AgNO 2 .
0.0000 0.02067 0-000 3-184 0.02067 0.01435 3.512 2.201
0.00258 0.01975 0.439 3.042 0.04134 o. 01168 7.024 1.799
0.00517 0.01900 0.878 2.926 0.08268 0.00961 14.048 1.480
0.01033 0.01689 1-756 2.601
SILVER OXALATE C 2 O 4 Ag 2 .
One liter of H 2 O dissolves 0.035 gm. at 18, and 0.0365 gm. at 20.
(Bottger; Kohlrausch.)
SILVER OXIDE Ag 2 O.
One liter of H 2 O dissolves 0.021 gm. at 20, and 0,025 gm. at 25.
(Noyes and Kohr; Bottger; Abegg and Cox.)
SILVER PERMANGANATE AgMnO 4 .
ioo gms. cold water dissolve 0.92 gm.; hot water dissolves more.
(Mitscherlich Pogg. Ann. 25. 301, '3*.}
SILVER PHOSPHATE Ag 3 PO 4 .
One liter ot water dissolves 0.00644 grn. at 20.
(Bottger 2. physik. Chi 46, 6oa, '05.)
SILVER PBOPIONATE 290
SILVER PROPIONATE C 2 H 6 COOAg.
SOLUBILITY IN WATER.
(Raupenstrauch Monatsh. Ch. 6- 587, '85; Arrhenius Z. pfaysik. Ch. 1 1, 396, '93; Goldschmidt
Ibid. 25, 93. '98.)
t o Cms. C 3 H s O 2 Ag t o Cms. CsHsOgAg Gms. C 8 H 6 O2Ag
per Liter. per Liter. per Liter.
O 5.12 20 8.36(8.48) 50 13.35
10 6.78 25 9.06 70 17-64
18.2 8. 36 (A.) 30 9-93(9-7o) 80 20.30
SOLUBILITY OF SILVER PROPIONATE IN AQUEOUS SOLUTIONS OF:
(Arrhenius.)
Silver Nitrate at 19.7. Sodium Propionate at i8.2 u
Mols. per Liter. Grams per Liter. Mols. per Liter. Grams per Liter.
AgN0 3 .
Q
[HsOaAg.
AgN0 3 .
C3Hr,O 2 Ag. C 3 H5O2Na. CjjH^OaAg.
C3HsO 2 Na. CsHsOsAj
o.o
O
.0471
o.o
8
.519
.0
0.0462
O
.O
8.362
0.0133
.0415
2.289
7
5 11
o
.0167
0-0393
I
.607
7.114
0.0267
0379
4-577
6
.86
o
0333
0.0345
3
.215
6.244
0-0533
O
.0307
9-059
5
556
.0667
0.0258
6
.429
4-670
o.ioo
O222
16.997
4
.019
o
1333
0.0191
12
859
3-45 6
o
.2667
0.0131
25
.718
2.371
.5000
O-OIOI
4 8
77
1.828
SILVER SALIC YLATE C 6 H 4 .OH.COOAg 1,2.
One liter of aqueous solution contains 0.95 gm. at 23.
(Holleman Z. physik. Ch. 12, 129, '93.)
SILVER SUCCINATE C 4 H 4 O 4 Ag 2 .
100 gms. H 2 O dissolve 0.0176 gm. at 18, and 0.0199 g m - a "t 2 5-
(Partheil and Hiibner Archiv. Pharm. 241, 413: '03 }
SILVER SULPHATE Ag 2 SO 4 .
SOLUBILITY IN WATER.
(Euler Z. physik. Ch. 49, 314, '04; Wright and Thomson Phil. Mag. Is] 17, 288, '84; Wentzel
Dammer's "Handbuch " II, 2, 858; Drucker Z. anorg. Ch. 28, 362, *oi.)
t. Gms. Ag 2 SO 4 per Liter, Gm. Mols. Ag 2 SO 4 per Liter.
17 7.70 0.0247 (Euler.)
18 7.28 0-0233 (W. andT.)
25 8.01 0.0257 (D.)
ioo 14.60 ... (w.)
One liter of aqueous solution in contact with a mixture of silver
sulphate and silver acetate contains 3.95 gms. Ag 2 SO 4 + 8.30 gms.
CH 3 COOAg at 17. Sp. Gr. of solution = 1.0094. (Euler.)
SOLUBILITY OF SILVER SULPHATE AT 25 IN AQUEOUS SOLUTIONS OF:
(Drucker.)
Sulphuric Acid. Potassium Sulphate.
Mols. per Liter. Grams per Liter. Mols. per Liter. Grams per Liter.
'Ag 2 SO 4 . H 2 SO 4 ." Ag 2 SO 4 . H 2 SO 4 ". ' Ag 2 SO 4 . K 2 SO 4 ." Ag 2 SO 4 . K 2 SO 4 .
0.0260 0.02 8. ii 0.98 0.0246 0.02 7-67 i-74
0.0264 0.04 8.23 1.96 0-0236 0-04 7.36 3.49
0-0271 o.io 8.45 4.90 0-0231 o.io 7.20 8.72
0-0275 0.20 8.58 9.81 0-0232 0.20 7-24 17-44
291
SILVER SULPHATE
SOLUBILITY OF SILVER SULPHATE AT 18 IN AQUEOUS SOLU-
TIONS OF:
(Eder J. pr. Ch. [2] 17, 44, '?8.)
Gms. per ioo Gms.
Solution .
Gms. per 100 Gms.
Solution.
Gms. per 100 Gms
Solution.
(NH) 2 S04. Ag 2 S0 4 .
K 2 SO 4 . Ag 2 SO 4 .
Na 2 S0 4 . Ag 2 S0 4 .
5 0.66
6 0.60
12 0.65
15 0.85
18 0.76
32 0.8o
SILVER SULPHOCYANIDE AgSCN.
One liter of aqueous solution contains 0.0002 gm. at 25, and
0.0064 gm. at 100.
(Abegg and Cox Z. physik. Ch. 46, n, '03; Bottger Ibid. 46, 60, '05; 56, 93, '06.)
SOLUBILITY OF MIXTURES OF SILVER THIOCYANATE AND POTAS-
SIUM THIOCYANATE IN WATER AT 25.
(Foote Am. Ch. J. 30, 332, '03.)
ms. per
ioo Gms. Solution.
Mols. per
ioo Mols. H 2 O.
Solid
KSCN.
AgSCN.
KSCN.
AgSCN.
Phase.
70-53
44 -3 6
KSCN
66-55
9-32
5i-i3
4.19
KSCN + 2 KSCN.AgSCN
64.47
IO.62
47-98
4-60]
61.25
58-34
11.76
13-55
42.07
38.47
4-72 I
5-23|
Double Salt.
2 KSCN.AgSCN
53. 92% KSCN
53-21
50.68
17-53
20-43
33-71
32-52
6. 5 oJ
7.67
2 KSCN.AgSCN+
KSCN.AgSCN
49-43
20.32
30.29
7-28]
Double Salt.
32-5 1
18.34
12.26
4-o5f
KSCN.AgSCN -
36.9% KSCN
24.68
16.41
7-77
3-2 J
23.86
16.07
7-3 6
2.90
KSCNAgSCN + AgSCN
SILVER TARTRATE C 4 H 4 O 6 Ag 2 .
ioo gms. H 2 O dissolve 0.2012 gm. C 4 H 4 O 6 Ag 2 at 18, and 0.2031
gm. at 25. (Partheil and Httbner Archiv. Pharm. 341, 413, '03.)
SILVER VALERATES AgC 5 H 9 O 2 .
SOLUBILITY IN WATER.
Normal Valerate I so Valerate
CH 3 (CH 2 ) 3 .COOAg. CH 3 .CH(CH 3 ) 2 CH 2 COOAg.
(Furth Monatsh. Ch. 9, 3". '88; Sedlitzky Ibid. 8, 563, '87-)
Gms. per ioo Gms. H 2 O.
Gms. per ioo Gms. H 2 O.
i .
Normal V.
IsoV.
O.229
0-177
10
0-259
O-2II
20
0.300
0.246
30
0-349
0.283
40
0.408
0.321
t .
Normal V.
Iso V.
50
0-474
0-360
60
O-SS 2
O-4OI
70
0-636
0-443
80
. . .
0-486
ioo gms. H 2 O dissolve 0.73 gm. silver valerate at 20.
(Markwald Ber. 32, 1089, '99.)
SILVER VALERATE 292
SOLUBILITY OF SILVER VALERATE IN AQUEOUS SOLUTIONS OF
SILVER ACETATE, SILVER NITRATE AND OF SODIUM
VALERATE.
(Arrhenius Z. physik. Ch. n 396, '93.)
In Silver Acetate at 17.8. In Silver Nitrate at 16.5.
Mols. per Liter. Gms. per Liter. Mols. per Liter. Gms. per Liter.
CuHgOjjAg.
0-0
0-0067
0.0135
0.0270
0-0505
C 5 H 9 O 2 Ag. CizHgO-jAg. C-jHgOj^
0-0094 o.o 1.96
0.0070 1.13 1.46
0.0057 2.27 1.19
0.0037 4-54 0.77
0.00265 8.48 0.55
In Sodium
Mols. per Liter.
. AgNOg. CsHijO^g. AgNOg. (
o.o 0.0094 o.o
0-0067 O.OO68 I.I4
O.OI33 O.OO5I 2.29
0-0267 O.OO3I 4.58
O.IOOO O-OOI2 17.00
Valerate at 18.6.
Grams, per Liter.
i .96
1.42
1.07
0.65
0.25
C2HgO 2 Na. C 5 H 9 O 2 Ag.
o.o 0.0095
O.OI75 O.OO47
0.0349 0.0030
0-0698 0-00l8
0.1395 0.0015
C 2 H 3 2 Na. C5H 9 O 2 Ag.
o.o i 986
2.17 0.982
4-32 0.627
8.65 0-376
I7-3 1 0.313
SILVER VANADATE Ag 6 V 4 O 13 .
One liter of aqueous solution contains 0.047 gram at 14, and 0.073
gm. at 100. (Carnelly Liebig's Ann. 166, 155, '73.)
SODIUM ACETATE CH 3 COONa. 3 H 2 O.
SOLUBILITY IN WATER.
Interpolated from original.
(Schiavor Gazz. chim. ital. 32, II, 532, ? oz.)
Gms. CHgCOONa Gms. CH 3 COONa
* o per 100 Gms. + o per ioo Gms.
Water. Solution. Water. Solution.
o 34 25.4 25 53 34-7
10 41 29.1 30 57 36.3
20 49 32.9 40 65 39.4
100 gms. H 2 O dissolve 46.9 gms. CH 3 COONa at 31.5.
(Kohler Z. Ver. Zuckerind. 47, 447, '97.)
ioo cc. aqueous solution contain 41.11 gms. CH 3 COONa at 10.
(Enklaar.)
SOLUBILITY OF SODIUM ACETATE IN AQUEOUS SOLUTIONS OF
ACETIC ACID.
(Enklaar Rec. trav. chim. 20, 183, '01.)
Gram Mols. per Liter. Grams per Liter.
CH 3 COOH. CHgCOONa. CHgCOOH. CHgCOONa.
o 5.0 o-o 411.1
0.085 5.0 5.1 410.3
0.12 5-0 7-2 410.4
SOLUBILITY OF SODIUM ACETATE IN ABSOLUTE ALCOHOL AT
ROOM TEMPERATURE.
(Bodtker Z. physik. Ch. 22, 510, '97.)
ioo gms. alcohol dissolve 1.81 gms. CH 3 COONa or 7.49 gms. CH 3
COONa. 3 H 2 O.
293
SODIUM ACETATE
SOLUBILITY OP SODIUM ACETATE IN AQUEOUS ALCOHOL:
At Different Temperatures.
(Schiavor.)
At 1 8.
(Gerardin Ann. chim. phys. [4] 5, 158, '65.)
Wt. Gms.CHaCOONa
per cent
Alcohol.
per ioo Gms.
Aq. Alcohol.
* '
S- 2
38.0
8
9 .8
35-9
12
23.0
29.8
19
29.0
27-5
II
38.0
23-5
13
45-o
20.4
15
14.6
18
86.0
3-9
21
91 .0
2.1
23
t .
Degree
M
Gms. per ioo Gms. Alcohol.
Alcohol. 'cHaCOONa. CH 3 COONa. 3 H2O.*
8
98.4
2.08
3-45
12
98.4
2.12
3-5 1
19
98.4
2-33
3-86
II
90
2.O7
3-42
13
00
2.13
3-52
15
63
13.46
22.32
18
63
13.88
23-03
21
63
14.65
24.30
23
40
28.50
47.27
100 gms. H 2 O dissolve 237.6 gms. sugar + 57.3 grams CH 3 COONa,
or 100 gms. of the saturated solution contain 58.93 gms. sugar +
14.44 gms. CH 3 COONa at 31 . 25. (Kohier.)
SODIUM ARSENATE N a3 AsO 4 .i2H 2 O.
100 grams aqueous solution contain 21.1 grams Na 3 AsO 4 .i2H 2 O.
(=10.4 gms. NaaAsO 4 ) at 17. Sp. Gr. of solution = 1.1186.
(Schiff Liebig's Ann. 113, 350, 'oo.)
ioo grams glycerine dissolve 50 gms. sodium arsenate at 15.5.
(Pharm. Centralh. No. 30, '81.)
SODIUM HYDROGEN ARSENATE Na 2 HAsO 4 .i2H 2 O.
ioo gms. H 2 O dissolve 17.2 gms. Na 2 HAsO 4 .i2H 2 O (= 7.3 gms.
anhydrous) at o. 56.0 gms. (= 19.89 gms. anhydrous) at 14. Sp. Gr.
1.1722, 37.0 gms. anhydrous at 21, and 140.7 gms. hydrated at 30.
(Schiff Liebig's Ann. 113, 350, '60; Tilden J. Ch. Soc. 45, 409, '84-)
SODIUM BENZOATE C 6 H 6 .COONa.
ioo gms. H 2 O dissolve 62 gms. at 25, and 77 gms. at b. pt.
ioo gms. alcohol dissolve 2.3 gms. at 25, and 8.3 gms. at b. pt.
(U. s. P.)
SODIUM (Tetra) BORATE Na 2 B 4 O 7 .ioH 2 O (Borax).
SOLUBILITY IN WATER.
(Horn and Van Wagener Am. Ch. J. 30, 347, '"03.)
Gms. 1
^a 2 B40 7
Gms. Na 2 B 4 O 7
t. per ioo Gms.
t .
per ioo Gms.
H>!
3.
H 2 O.
5
.3
5
10-5
10
j
.6
54
13-3
21.
5 2
.8
55
14.2
30
3
9
56
15.0
37
5 5
.6
57
16.0
45
8
.1
Gms. Na2B 4 Or
per ioo Gms.
H 2 0.
19.4
22 .O
22.
00
62
65
70
80
90
IOO
Transition temperature Na 2 B 4 O 7 .ioH 2 O -
imately 62. Sp. Gr. of saturated solution at 15 = 1.032.
20.3
20.7
21.9
24.4
3i-5
41.0
52-5
Na 2 B 4 O 7 .5H 2 O approx-
SODIUM BORATES 294
SOLUBILITY OF SODIUM BORATES IN WATER AT 30.
(Dukelski Z. anorg. Ch. 50, 42, '06, complete references given.)
Solid
Phase.
NaOH.HjjO
Cms. per ioo Gms. Solution.
Gms. per ioo
Gms. Residue
KzO.
B 2 O 3 .
K 2 0.
B 2 3 .
42.0
41-37
5.10
43-54
4.19
38.85
5-55
37-20
II. l8
34-44
3-73
33-52
I0.8o
29-39
2.51
29.63
IO.II
26.13
2-75
27-85
15.21
23.00
3-82
24.91
II .60
16.61
13.69
21 .29
20.64
21.58
4-63
24.52
19.04
20.58
4.69
21 .6l
16.59
I5-32
6.21
19.70
17.84
12.39
9.12
18.05
18.17
8.85
10.49
II .72
2O.62
5-8i
6.94
10.82
21.31
1.88
2.41
7-31
15.50
1.38
5 -*6
7.16
17.44
2 .02
7-79
6.24
16.38
4.08
17.20
8.96
29.20
3-79
15.84
5-68
28.19
2 .26
12.14
5-21
29.19
1.99
11.84
5-74
39.66
1.86
ii. iS
i .06
28.78
0.64
6. ii
0.31
3 I - I 9
3-54
N a2 O.B 2 3 .4H20 -HNajO.B208.8H20
Na2O.B 2 03.8H 2 O
N a2 O.2B 2 O 3 .ioH 2 O + Na2O.sB2O 3 .i
Na 2 O.sB 2 O 3 .ioH 2 O
N a2 O.2B2O 3 .ioH 2 O + B(OH) 3
B(OH) 3
ioo gms. alcohol of 0.941 Sp. Gr. dissolve 2.48 gms. sodium borate
at 15.5.
ioo gms. glycerine dissolve 60.3 gms. at 15.5! and ioo gms. at 80.
(U.S. P.)
Gaudolphe J. pharm. chim. [4] 22, 366, '75 says that glycerine
dissolves its weight of sodium borate at ordinary temperatures.
SODIUM BROMATE NaBrO 3 .
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 94, 271, 55; 97 5 's6->
t. o 20 40 60 80 100
Gms. NaBrO 3 per ioo
Gms. H 2 O 27.5 34-5 5- 2 62.5 75.7 90.9
Sp. Gr. of saturated solution at 19.5 = 1.231. (Geriach.)
2 9 5 SODIUM BROMIDE
SODIUM BROMIDE NaBr. 2 H 3 O.
SOLUBILITY IN WATER.
(Etard Compt. rend. 98, 1432, '84; de Coppet Ann. chim. phys. [5] 30, 411, '83.)
LO Grams NaBr per 100
Gms. H 2 O.
20
57-5*
7i -4t
66
79-5
10
72
84-5
20
77
90-3
30
82.5
97-3
40
88.0
105.8
. o. Grams NaBr per 100
Gms. H 2 O.
50
95-112*
n6f
00
112
117
80
113
119
IOO
114
121
1 2O
116
124
I4O
118
* Etard.
t de Coppet.
Transition temperature for NaBr.2H 2 O * NaBr is approximately
50. Kremers Pogg. Ann. 97, 14, '56 gives results which fall near
those of de Coppet for the NaBr.2H 2 O, and near those of Etard for
the NaBr section tf the curve.
SOLUBILITY OF SODIUM BROMIDE IN AQUEOUS SOLUTIONS OF
SODIUM HYDROXIDE AT 17.
(Ditte Compt. rend. 124, 30, '97.)
Gms. per 100 Gms. H 2 O.
Gms. per 100
Gms. H 2 O.
Gms. per 100 Gms. H2O.
NaOH.
NaBr'.
NaOH.
NaBr.
NaOH.
NaBr.
o.o
91.38
17.17
63.06
28.43
48.00
3.26
79-86
19.12
62 .51
36.61
38.41
9.24
68.85
22-35
59.60
46.96
29-37
13-43
64.90
24.74
55-03
54-52
24.76
SOLUBILITY OF SODIUM BROMIDE IN ALCOHOLIC SOLUTIONS.
(Rohland Z. anorg. Ch. 18 327, '98; Z. anal. Ch. 44, 252, '05; de Bruyn Z. physik. Ch. 10, 783
'92; Eder Dingl. polyt. 221, 89, '75.)
Alcohol.
Concentration
of Aq. Alcohol.
Methyl Alcohol
^15 = 0-799
Ethyl
d 15 =o.8io
Propyl "
<f 15 =o.8i6
Ethyl
90% by vol.
Methyl "
Absolute
Ethyl
tt
Ethyl Ether
room temp.
19-5
Gms. NaBr
per TOO Gms.
Alcohol.
(R-)
21.7
7.14
2.01
4 . o (hydrated NaBr)
17.35 (de Bruyn.)
6.3 (NaBr2H 2 O) (Eder.)
0.08
SODIUM CARBONATE
296
SODIUM CARBONATE Na 2 CO 3 .ioH 2 O.
SOLUBILITY IN WATER.
(Mulder; Lowel Ann. chim. phys. [3] 33, 382, '51; at 15, Reich Monatsh. Ch. 12, 464, "91; at
32-34.5 Na 2 CO 3 .7H 2 O b, Ketner Z. physik. Ch. 39, 646, 'oi-'o2.)
Solid Phase:
Na 2 CO 3 .ioH 2 O. Na 2 CO 3 .7H 2 O (6). Na 2 CO 3> 7H 2 O (a).
Gms. Na 2 CO 3 Gms. Na 2 CO 3 Gms. Na 2 CO 3
^ e per 100 Gms. per 100 Gms. per 100 Gms.
Water. Solution."
Water.
Solution. Water.
So'ution.
7-0 6. 5
2O-4
16.9 32.0
24.2
5
9.5 6.9
23-2
18.8 35.0
25-9
10
12.5 II. I
26.2
20.8 37.8
27.4
15
16.4 14.1
29-5
22.8 41.2
29.2
20
21.5 17.7
33-5
25-1 45-5
31-3
25
28.2 (29.8*) 22 .O
38.0
27-5
37.8(40.9*) 27.4
43-5
30-3
32.5
46.2 31.6
(32.O46.6
3i-8
35
40
46.2 3 1 - 6
46.1(49.7*) 31-5
(33 -3) 48. 6
(34-5) 5i -3
32-7
33-9
60
46.0(46.4*) 3 J -5
Solid Phase Na 2 CO 3 .H 2 O
80
45.8(45.2*) 31.4
100
45-5 3 J -3
I0 5
45-2 3 1 - 1
* Epple Dissertation, Heidelberg, p. 26, 1899.
Sp. Gr. of solution saturated at 17.5, 1.165 (Hager) ; at 18, 1.172
(Kohlrausch) ; at 23, 1.222 (Schiff) ; at 30, 1.342 (Lunge). See also
Wegschroeder and Waller Monatsh. Chem. 26, 685, '05, for Sp. Gr.
determinations at other temperatures.
SOLUBILITY OF SODIUM CARBONATE IN AQUEOUS SOLUTIONS
OF SODIUM CHLORIDE AT 15.
(Reich.)
Gms. per 100
Gms. H 2 0.
Gms. NaCl Gms. Na 2 CO 3
per 100 per 100 Gms.
Gms. per too Gms. NaCl Gms. N a2 CO 3
Gms. H 2 U. per I00 p^ I00 Gms.
NaCl.
Na^O,
.ioH 2 O
Gms.
Solution.
NaCl
Solution.
NaCl.
Na 2 C03
.ioH 2 0.
Gms.
Solution.
NaCl
Solution.
o.o
61 .42
0.0
16.42
23.70
39.06
15.96
9.76
4-03
53-86
2.92
14.47
27-93
39-73
18.26
9.62
8.02
48.00
5-8o
12.87
3I-65
41.44
20.06
9-73
12 .02
43-78
8.61
II .62
35-46
43-77
2i-75
7-95
16.05
40.96
11.31
IO.7O
37-23
45.27*
22.46
10.13
19.82
39-46
i3-7i
IO.II
* Both salts in solid phase.
SOLUBILITY OF SODIUM CARBONATE IN AQUEOUS SOLUTIONS
OF ETHYL AND OF PROPYL ALCOHOL AT 20.
(Linebarger Am. Ch. J. 14, 380, '92.)
Wt. per cent
A1^ U 1
Gms. Na 2 COs
per 100 Gms. Sol.
Wt. per cent
Alt- 1
Gms. Na 2 CO 3
per 100 Gms. Sol.
Alcohol.
In Ethyl. In Propyl'.
Alcohol.
In Ethyl. In Propyl,
28
4-4
4 8
0.9 1-3
38
2.7
50
. 84 1.2
44
1.7 1.7
54
0-8o 0-9
46
1.13 1.5
62
0.4
297 SODIUM CARBONATE
SOLUBILITY OF SODIUM CARBONATE IN AQUEOUS SOLUTIONS OF
ETHYL ALCOHOL.
(Ketner Z. physik. Ch. 39, 646, 'oi-'o2.)
NOTE. The mixtures were so made that an alcoholic and an
aqueous layer were formed, and these were brought into equilibrium
with the solid phase.
Cms. per 100 Cms. Alcoholic Layer. Gms. per 100 Gms. Aq. Layer.
C 2 H 5 OH.
Na 2 CO 3 .
H 2 O.
C 2 HsOH.
Na 2 CO 3 .
H 2 0.
Phase.
35
62
9
o-3
36
.8
I
O
32-4
66.6
Na 2 C0 3 .H 2
40
61
.0
0-4
38
.6
I
.2
31-9
66.9
"
49
61
-0
0-4
38
.6
I
.2
31-5
67-3
"
68
55
.8
0.9
43
3
2
3
28.8
6$. 9
"
3 1
.2
5 2
4
0.8
46
.8
29-3
Na 2 C0 3 . 7 H 2 (b)
9
54
.8
0.7
44
5
I
7
29.8
68.5
"
32
3
56
.1
0.6
43
3
I
5
30.2
68.3
"
33
.2
58
.1
o-5
42
4
I
4
31.0
67.6
"
27.7 Crit. sol. 14% C 2 H 5 OHi 3 % Na 2 CO 3 7 3 % H 2 O
28.2 23.5 7.3 69.2 7.9 l8.6 73.5 Na 2 CO 3 .ioH2O
29-0 3 2 -7 3- 8 6 3-5 4-3 22.7 73.0
29.7 40-0 2.1 57.9 2.9 25.5 71.6
30.6 47.8 1.2 51.0 2.3 27.8 69.9
SOLUBILITY OF Na 2 CO 3 .ioH 2 O IN DILUTE ALCOHOL AT 21.
(Ketner.)
Grams per loo^Grams Solution. Grams per 100 Grains Solution.
Na 2 C0 3 . cSsOH. H^O. Na 2 CO 3 . C 2 H 6 OH. H^.
18.5 0-0 81.5 1.2 39.2 59.6
12.7 6.2 81.1 0.2 58.2 41.6
6.9 15.3 77.8 o.i 67.1 32.8
3-2 26.1 70.7 0-06 73.3 26.64
zoo gms. saturated solution in glycol contain 3.28-3.4 gms. sodium
Carbonate. (de Coninck Bull. acad. roy. Belgique, 359, '05.)
ioo gms. H 2 O dissolve 229.2 gms. sugar + 24.4 gms. Na 2 CO 3 , or
100 gms. sat. aq. solution contain 64.73 S 1118 - sugar + 6.89 gms. Na 2 CO 3 .
(Kohler Z. Ver. Zuckerind. 47, 447, '97.)
SODIUM (Bi) CARBONATE NaHCO 3 .
SOLUBILITY IN WATER.
(Dibbits J. pr. Ch. [2] 10, 439, '74.)
o Gms. NaHCOs per ioo Gms Gms. NaHCO per ioo Gms.
Water. Solution. Water. Solution.
o 6.9 6.5 30 ii. i 10.0
10 8.15 7.5 40 12.7 11.3
20 9.6 8.8 50 14-45 I2 -6
2 5 10-35 9-4 60 16.4 13.8
Sp. Gr. of sat. solution at 16 = 1.069. (Stolba.)
ioo gms. alcohol of 0.941 Sp. Gr. dissolve 1.2 gms. NaHCO 3 at 15.5.
ioo gms. glycerine dissolve 8 gms. NaHCO 3 at 15.5.
SODIUM (Bi) CARBONATE 298
SOLUBILITY OF SODIUM BICARBONATE IN AQUEOUS AMMONIUM
BICARBONATE SOLUTIONS SATURATED WITH CO 2 .
(Fedotieff Z. physik. Ch. 49, 169, '04.)
Solution.
NH 4 HC0 3 . NaHCO 3 .
'NH 4 HC0 3 .
NaHCOa.
O
1.072
i-39
0.58
109.4
48.3
tt
o.o
0.82
0-0
69.0
15
1.056
o.o
1.05
O-O
88.0
it
i .061
0.29
0.95
23.0
80.0
tt
i .065
0.56
0.89
44.0
74.6
ii
1.073
1 .08
0.79
85-7
66.7
it
i .090
2.16
0.71
170.6
59-2
30
o.o
1.65
0-0
138.6
(4
2.91
0.83
23.0
70.0
SOLUBILITY
OF SODIUM BICARBONATE
IN AQUEOUS SOLUTIONS
OF
SODIUM
CHLORIDE
SATURATED WITH
CO 2 .
(Fedotieff;
see also Reich
Monatsh.
Ch. 12, 464, '91.)
t o Wt. of i cc.
Mols.per loop Gms.H2O
Grams per
1000 Gms. H2O.
I .
Solution.
NaCl.
NaHCO 3 .
NaCl.
NaHC0 3 .
o
O-O
0.82
0-0
69.0
"
I. 208
6.0
O.O9
350-1
7-7
15
I .056
o.o
1.05
o.o
88.0
tt
1.063
0.52
0.82
30.2
68.6
tt
1.073
1.03
0-64
60. 1
53-6
tt
I .096
2. II
0.41
123-1
34-8
tt
I.I27
3.20
0.28
187.2
23.0
tt
1.158
4-39
O.I9
256.9
16.1
tt
1.203
6.06
O-I2
354-6
10.
30
1. 066
O-O
I-3 1
0-0
IIO- 2
1.079
1 .02
0-87
59-9
7 2.8
It
I .IOO
2.08
0.56
121 .9
47-3
tt
I .127
3.18
0.38
186.3
32.0
tt
I.I56
4.38
0.27
256.0
22-3
It
I.I99
6.12
0.17
358-1
*3-9
45
1.077
o.o
1.65
O-O
138.6
1. 086
1 .04
I .12
60.7
94-o
"
I.II5
2.65
0.62
155 .2
52.0
"
I.I27
3-24
0.52
189.4
43-4
I .155
4-38
0-37
256.1
30-7
"
I.I98
6.18
0.23
3 6l -5
loo grams alcohol of 0.941 Sp. Gr. dissolve 5.55 grains sodium
sulpho carbonate at 15.5.
SODIUM CHLORATE NaClO 3 .
SOLUBILITY IN WATER.
(Kremers Pogg. Ann. 97, 4, '56.)
t o Grams perjoo Grams 1 Grams per ^100 Grams
Water. Solution. Water. Solution.
o 81.9 45.0 60 147.1 59.5
12 89.3 47-2 80 175-6 63.7
20 99-0 49-7 IOO 232.6 69.9
40 123.5 55-3 I2 <> 333-3 7^-9
299 SODIUM CHLORATE
SOLUBILITY OF SODIUM CHLORATE IN AQUEOUS SODIUM CHLORIDE
SOLUTIONS AT 20.
(Winteler Z. Electrochem. 7, 360, 'oo.)
Volume Wt. Grams ger Liter. Volume Wt. Grams per Liter.
of Solutions. jsf^CL NaCl6 3 . of Solutions. NaCL NaCl6 3 .
.426 5 668 1.365 175 393
.419 25 638 1.345 200 338
.412 50 599 1.319 225 271
405 75 559 1-289 250 197
.398 100 522 1.256 275 120
.389 125 484 1-235 290 78
1-379 150 442 1-217 300 55
TOO gms. H 2 O dissolve 24.4 gms. NaCl + 50.75 gms. NaClO 3 at 12.
100 gms. H 2 O dissolve 11.5 gms. NaClH- 249.6 gms. NaClO 3 at 122.
(Schlosing Compt. rend. 73, 1273, '71.)
ioo gms. alcohol of 77 Wt. per cent dissolve 2.9 gms. NaClO 3 at 16.
(Wittstein.)
ioo gms. alcohol dissolve i gm. NaClO 3 at 25, and 2.5 gms. at b. pt.
ioo gms. glycerine dissolve 20 gms. NaClO 8 at 15.5.
SODIUM CHLORIDE NaCl.
SOLUBILITY IN WATER.
(Mulder ; de Coppet Ann. chim. phys. [5] 30, 411, '83; Andrae J. pr. Ch. [2] 29, 456, '84; above
100, Tilden and Shenstone Phil. Trans. 23, '84; Berkeley Trans. Roy. Soc. (Lond.) 203 A, 206,
'04; Etard Ann. chim. phys. [7] 2, 527, '94, gives irregular results.)
to
Gms. NaCl per Gms _'
NaCl
Gms. NaCl.
ner
Gms. NaCl
.
ioo Gms. H2O.
per
ioo g. Sol.
t .
ioo Gms. H2O.
per
ioo g. Sol.
35-7*
35
6 3 t
26
.28f
70
37
.8*
37
Sit
27-27t
10
35-2
35
.69
26
.29
80
38
4
38
.00
27-54
20
36.0
35
.82
26
37
90
39
.0
38
5 2 t
27.80
25
36.12
35
.92
26
43
IOO
39
.8
39
"{
28.12
36-3
36
03
26
-49
118
39
.8
28.46
40
36.6
36
32
26
65
140
42
.1
29.63
50
37-o
36
.67
26
83
160
43
.6
30-37
60
37-3
37
.06
27
.04
1 80
44
9
30.98
* M.; deC.
t A.
$ B
.
SOLUBILITY OF SODIUM CHLORIDE IN AQUEOUS SOLUTIONS OF
AMMONIUM CHLORIDE.
(Fedotieff Z. physik. Ch. 49, 170, '04.)
o Wt. of i cc. Mols. per 1000 Gms. H 2 O. Grams per 1000 Gms. H2O.
Solution. ' NH 4 C1. NaCl. N^Cl. NaCT.
O ... O-O 6.09 Q.O 35^-3
" I-l85 2-73 4.89 146.1 286.4
15 1.200 o.o 6.12 o.o 357-6
1.191 1.07 5.58 57.3 326.4
1.183 2.22 5.13 Il8.9 300-0
" 1.176 3.48 4.64 186.4 271.6
I.I75 3-72 4-55 198.8 266.8
30 ... o.o 6.16 o.o 360.3
" 1.166 4-77 4-26 255.4 249.0
45 ... o.o 6.24 o.o 365-0
" ... 6.02 4.0 322.1 233.9
SODIUM CHLORIDE
300
SOLUBILITY OF SODIUM CHLORIDE IN
HYDROCHLORIC
(Engel Ann. chim. phys. [6] 13, 374, '88; Enklaar -
At . (Engel.)
AQUEOUS SOLUTIONS OF
ACID.
-Rec. trav. chim. 20, 183, f oi.)
At io-io.5. (Enklaar.)
g. Mols. per 10 cc. So. Gr. of
Gms. per Liter.
Mols. per Liter.
Grams per Liter.
HC1.
NaCl. bolution.
HC1.
NaCl.
HC1.
NaCl.
HC1.
NaCl.
O-O
54
7 1.207
32.0
0-0
6. II
O
35-77
I -0
53
5 1-204
O
365
3*-3
0.27
5-77
9
8 4
33-76
1.8 5
52
2
.202
O
.674
30-5
o-35
5-67
12
7 6
33- I 9
5-i
4 8
5
.196
I
859
28.4
o-43
5-59
15
68
32- 7 1
9.28
44.0
.185
3
38
25-7
o-57
5-43
20
78
3i-77
15-05
37
9
173
5
49
22.2
0.72
5-28
26
06
30.89
30-75
23
.5
.141
ii
.20
13-7
2 .60
3-42
94
77
20. o i
56-35
6
.1
.119
20
54
3-6
2.80
3-i8
102
i
19.04
3-31
2.74
120
6
16.03
SOLUBILITY OF MIXTURES OF SODIUM CHLORIDE AND OTHER
SALTS IN WATER, ETC.
t o Gms. per 100 Gms. Solvent. Authority.
Solvent.
Water
Alcohol (40%) 25
Water
tt
17
26.4
NaCl+22.iNH 4 Cl*
17
34-5
" + 4.iBaCl 2
38-3
" +2 9 . 5 KN0 3
25
38-5
" +41-14 " .
80
39.81
" +168.8 "
25
I5-78
" +13-74 "
20
30-54
" +I3-95KC1 j,
25
28.90
" +16.12 " j
(Karsten.)
(Soch J. Physic. Ch. 2, 46, '98.)
(Quoted by Euler Z. physik. Ch.
49, 315. '04-)
* Sp. Gr. of solution at 17 = 1.179.
SOLUBILITY OF MIXTURES OF SODIUM CHLORIDE AND POTASSIUM
SULPHATE IN WATER AT VARIOUS TEMPERATURES.
(Precht and Wittgen Ber. 15, 1666, '82.)
4.0 Grams per 100
Grams
H 2 O.
f o Grams per 100 Grams H 2 O.
' NaCl
K 2 S0 4
KCl
NaCl
K 2 S0 4
KCl
10
33
4
8
.1
3
.2
60
36
4
xx .9
2-7
20
34
.0
8
9
3
.1
70
36
.6
12.8
3-2
30
34
.6
9
.6
2
9
80
36
.0
12.3
5 - 1
40
35
.2
10
4
2
.8
90
35
9
12.4
7.0
50
35
.8
ii
.1
2
.8
100
35'
6
12.6
8.8
SOLUBILITY OF SODIUM CHLORIDE IN AQUEOUS SOLUTIONS OF
SODIUM BICARBONATE SATURATED WITH CO 2 .
(Fedotieff.)
Grams per 10000 Gms. HsO.
t
Wt. of i cc.
Mols. per ipoo
Gms. H;
V
Solution.
NaHCO 3 .
NaCl. '
o
. . .
0-0
6.09
a
1. 208
O.O9
6.0
15
1.203
o.o
6.12
1.203
0-12
6.06
30
1.196
O-O
6.16
ft
I.I99
0-17
6.12
45
1.189
o-o
6.24
tt
1.198
0.23
6.18
NaHC0 3 .
NaCl.
o.o
356 3
7-7
35O.I
o.o
357-6
IO-O
354-6
0-0
360.3
13 9
358.1
o.o
356-0
0.23
361-5
3 oi
SODIUM CHLORIDE
SOLUBILITY OP SODIUM CHLORIDE IN AQUEOUS SODIUM HYDROXIDE
SOLUTIONS.
(Engel; Winteler Z. Electrochem. 7, 360, 'oo.)
At o (Engel). At 20 (Winteler).
Mg.Mols
. per 10 cc.
Sp. Gr. of
Solutions.
Grams per Liter.
NaOH. NaCl."
Gms. per Liter g
x Gr. of
lutions.
Na 2 0.
NaCl. "
NaOH.
NaCl. So
O
54
7
I
.207
o.o
320
.0
IO
308
.200
4
.8
49
38
I
.221
38-4
288
9
50
297
.230
6
73
47
.21
I
.225
53-8
276
.2
100
253
250
10
.41
42
38
I
2 3 6
183.2
247
9
J 5o
213
.270
M
.78
39
55
I
.249
118.2
231
4
200
I 39
305
30
5
24
95
I
295
244.0
146
.0
300
112
330
37
.88
19
3o
I
314
303-0
112
9
400
61
375
53
25
9
.41
I
.362
426,. o
55
.0
500
30
425
640
18
.490
SOLUBILITY OF SODIUM CHLORIDE IN AQUEOUS SOLUTIONS OF
SODIUM NITRATE AND VICE VERSA.
(Bodlander Z. physik. Ch. 7, 361, '91; Nicol Phil. Mag. [5] 3L 369, '91; results at 25 by Soch
J. Physic. Ch. 2, 46, '98.)
NaCl in Aqueous NaNO 3 . NaNO 3 in Aqueous NaCl.
Results at 15.5 (B.).
Results at 15 (B.).
Sp. Gr. of
Gms. per
ioo cc. Sat.
Solution. SD. Gr. of
Gms. per
ioo cc. Sat
. Solution.
Solutions.
NaNO 3 .
H 2 O.
NaCl." Solutions.
NaCl.
H 2 0.
NaNO 3 .
I
.2025
88
47
31
78
3720
74
.82
62.38
I
2 305
7-53
87
63
27
.89
3645
4-0
75
.69
5 6. 7 6
I
.2580
13.24
86
25
26
3 1
3585
7.24
75
7i
52.09
I
.2810
21.58
82
.66
2 3
.98
3530
II .36
76
.86
47-08
I
.3090
28.18
80
.42
22
30
3495
15-33
76
.96
42.66
I
3345
33-80
79
25
20
.40
3485
I7.8l
77
.14
39-90
I
3465
37-88*
77
37
19
.40*
3485
18.97*
77
J 5
38.73*
I
3465
37.64*
77
34
J 9
.67* 1.3485
19.34*
77
49
38.02*
Results at 20 (N.).
Grams per ioo Grams H 2 O. Grams per ioo Grams H 2 O.
o NaNO 3 35.91 NaCl
14.17 " 32.82 "
28.33 " 29.78
42.50 " 26.91 "
54- 6 3 5
24.92
*
o NaCl 87.65 NaNO 3
6-5
13.0
19.5
77-34
68.50 "
60.49 "
ioo gms. H 2 O dissolve 43.66* gms. NaNO 3 + 26.58* gms. NaCl
at 25.
ioo gms. H 2 O dissolve 121.6* gms. NaNO 3 + 17.62* gms. NaCl at
80.
ioo gms. aq. alcohol of 40 wt. per cent dissolve 22.78 gms. NaNO 3 -f
10.17 gms. NaCl at 25.
* Indicates solutions saturated with both salts.
SODIUM CHLORIDE
302
SOLUBILITY OF SODIUM CHLORIDE IN ALCOHOLS.
(At 18.5, de Bruyn Z. physik. Ch. 10, 782, '92? Rohland Z. anorg. Ch. iB, 327, '08.)
Gms. NaCl Gms. NaCl
t. Alcohol. per ioo t. Alcohol per ioo
Gms. Alcohol. Gms. Alcohol
18.5 Abs. Methyl 1.41 room temp. Methyl ^15= 0.799 I -33
" Ethyl 0.065 Ethyl ^ 5 =0.81 0.176
" Propyl d l6 =0.816 0.033
SOLUBILITY OF SODIUM CHLORIDE IN AQUEOUS ETHYL ALCOHOL
SOLUTIONS.
(Bodlander Z. physik. Ch. 7, 317, '91; Taylor J. Phys. Ch. i, 723, '97; also Bathrick Ibid. I,
159. '96.)
Results at 11.5 (B.). Results at 13 (B.).
Sp. Gr. of
Gms. per ioo cc. Solution.
Sp. Gr. of Gr
ns. per
ioo cc. So
lutio
n.
Solutions.
CzHeOH
. H 2 0.
NaCl.
Solutions.
C 2 H 5 OH.
H 2 0.
NaCl.
1-2035
O
86.62
31
73
I
.2030
O
88.70
31
.60
I . 1865
2.86
86.14
29
.66
I
1348
II
.Si
78.41
23
.26
I.I7IO
5-41
83 -93
27
77
I
,1144
15
99
74.64
2O
.81
I.I548
7-93
81.50
26
05
I
.0970
19
39
71-45
18
.86
I-I350
10.84
78-78
24
.28
I
.0698
24
95
69.80
16.23
I.I390
II .22
78.62
23
65
I
0295
32
33
57 -96
12
.66
I. 1088
16.85
73-40
2O
63
.9880
40
33
49-34
9
.13
9445
49
.28
38-54
5
93
9075
57
.91
29-37
3
47
.8700
63
,86
21 .62
i
52
.8400
72
,26
II .24
50
Results at 30 and
at 40
(T.)
Wt. per (
Alcohol in S<
:ent A
alvent.
t30, Gms.Ni
iCl per ioo Gms.
At 40
', Gms. NaCl per ioo Gms.
Solution.
Water.
Solution.
Water.
26.50
36-05
26
.68
36.38
5
24-59
34-29
24
79
34.69
10
22 .66
32-57
22
.90
33-oo
20
19.05
29.40
19
.46
30.20
30
15-67
26.53
16
.02
27.25
40
12.45
23.70
12
75
24-37
50
9-34
20.60
9
.67
21 .42
60
6.36
16.96
6
65
17.82
70
3-36
12-75
3
-87
13.10
80
1-56
7 95
i
.69
8.68
90
o-43
4-30
o
5
5.10
ioo gms. alcohol of 0.9282 Sp. Gr. = 54.0% by wt. dissolve at:
4 10 13 23 32 33 44 51 6o c
10.9 ii. i 11.43 "-9 I2 -3 I2 -5 I 3- 1 J 3 8 14 i gms. NaCl
(Gerardin Ann. chim. phys. [4] 5, 146, '56.)
ioo gms. of a mixture of equal parts of 96% alcohol and 98% ether
dissolve o.n gm. NaCl.
(Mayer Liebig's Ann. 98, 205, '56.)
3 o 3 SODIUM CHLORIDE
SOLUBILITY OF SODIUM CHLORIDE IN AQUEOUS SOLUTIONS OF:
Glycerine at 25.
(H. and K. Ibid. 45. 267, '05.)
Acetone at 20.
(Herz and Knoch Z< anorg. Ch. 41, 318, '04.)
cc. Acetone
per 100 cc.
Solvent.
O
10
20
30
32 ) Lower layer 308 . 5
87 j Upper layer
88
90
Impurities about 1.5%.
100 gms. sat. solution in glycol contain 31.7 gms. NaCl at 14.8.
(de Coninck Chem. Centralb. 76, II, 883, '05.)
ioo gms. H 2 O dissolve 236.3 gms. sugar + 42.3 gms. NaCl at 31.25,
or ioo gms. sat. aq. solution contain 62.17 gms. sugar + 11.13 g ms -
NaCl. (Kohler Z. Ver. Zuckerind. 47, 447, '9?-)
NaCl per ioo
cc. Solution.
Wt. per cent
Glycerine in
Solvent.
NaCl per ioo
cc. Solution
s
p. Gr. of
olution.
tfillimols. Grams.
Millimols.
Grams.
37
9
3 1
47
o.
o
545
6
31.
93
.1960
64
.6
27
18
13 .
28
501
.z
29
3i
.2048
94
.8
23
10
25-
98
448
4
26
23
2133
30
.1
19.32
45
36
37
.2
21
66
.2283
08
5
18
05
54
23
333
9
19
54
.2381
7
7
o
45
83
84
220
.8
12
91 1.2666
7
3
o
43
IOO
00*
167
.1
9
.78 1.2964
4-3
0.25
*Sp.
Gr.
of Glycerine,
1.2592.
SODIUM CHROMATES (Mono, Di, etc.)
SOLUBILITY IN WATER.
(Mylius and Funk Wiss. Abh. p. t. Reichanstalt 3, 451, 'oo; see also Salkowski Ber. 34, 1948, '01.)
Sodium Mono Chromate.
Sodium Di Chromate.
Gms. Na 2 Mols. Na 2
+ o CrO 4 per CrO 4 per Solid t
ioo Gms. ioo Mols Phase.
Gms. Na 2 Mols. Na 2
o Cr 2 O 7 per Cr) 7 per
ioo Gms. ioo Mols.
Solid
Phase.
Solution.
H 2 0.
Solution.
H 2 0.
O
24
.07
3
.52 Na 2 CrO 4 .ioH2O
o
61
.98
II
.2
Na.jCr207.2H2*
IO
33
.41
5
55
17
63
.82
12
.1
"
18*
40
.10
7
43
18:]
: 6 3
.92
12
.16
"
18,
5
41
65
7
94
34
5 67
36
14
.2
"
19
5
44
.78
9
.01
52
71
. 7 6
17
4
*
21
47
.40
10
.00
72
76
9
22
.8
"
25
.6
46
.08
9
52Na 2 CrO 4 .4H 2 O
81
79
.8
27
.1
"
3 r
5
47
05
9
-90
93
81
.19
29
.6
NazCraOr
36
47
.98
10
.2
98
81
25
2 9
.8
"
40
48
97
IO
.6
Sodium Tri Chromate.
45
50
.20
II
"
Gms. Na<
Mols.
Na
49
54
5
5
50-93
52.28
II
12
5
.2 "
t.
Cr 3 O, per
too Gms.
Solution.
Cr 3 10 pe'r
ioo Mols.
H 2
Solid
Phase.
59
5
53
39
12
7
O
80
03
J 9
9
65
55
23
13
7 Na2Cr0 4
15-1
\ 80
44
20
4
"
70
55
.15
13
.6
18
80
.60'
20
56
M
80
55
53
13
.8
55
82
.68
23
7
IOO
55
74
14
.0
99
85
78
2 9
9
"
*Sp. Gr. of sat. sol. at 18 = 1.432. tSp. Gr. of sat. sol. at 18 = 2.059,
|Sp. Gr. of sat. solution at 18 = 1.745.
SODIUM CHROMATES
34
Sodium Tetra Chromate.
Cms.
o
16
18*
22
per 100 Gms.
Solution.
72.96
74.19
74-60
76.01
Mols.
Na 2 Cr 4 O, 3
per loo
Mols.H 2 O.
10-5
II .2
11.27
12-3
Solid
Phase.
Na 2 Cr 4 O l3 . 4 H 2
* Sp. Gr. of sat. solution at 18= 1.926.
Tetra Sodium Chromate.
Gms.
Mols.
t
Na 4 Cr0 6
Na 4 Cr0 5
Solid
' per looGms.
Solution.
per zoo
Mols.H 2 O.
Phase
O
33-87
4-II 1
^CrOg.i
10
35-58
4.42
"
i8t
37-50
4.8l
M
27.7
40.09
5-38
"
37
45-13
6.62
M
t Sp. Gr. of sat. solution at 1 8 = 1.446.
SOLUBILITY OF SODIUM CHROMATES IN WATER AT 30.
(Schreinemaker Z. physik. Ch. 55, 91, '06.)
Composition in weight per cent :
Of Solution. Of Residue.
Solid Phase.
NaOH.H 2 O
NaOH.H 2 O + Na 2 CrOi
Na 2 Cr0 4
%Cr0 3 .
%Na 2 0.
%Cr0 3 .
%Na 2 0.
O
42
2.00
41.44
5-83
42.64
2.04
40.89
4-23
35-5 1
27.52
36.57
6.64
32-34
27.72
34.60
15 .19
27.06
37-07
32.20
IO.22
29-39
I5-48
28.41
8-93
28.49
18.09
26.89
8.62
26.91
13.12
23.91
18-57
25.92
18.44
22.86
. . .
19.26
22.98
21.54
25-3I
17.84
24.21
26.24
24.98
28.82
17.88
31-97
23-47
38.93
16.30
40-70
20.83
48.70
16.49
47-49
19-75
50.68
15-72
58.08
13.89
62.76
I7-38
66.13
13.70
69.48
16.06
65-98
14.15
69.46
15.15
68.46
10.95
73-88
13-38
66.88
9-85
71.27
10.67
70.06
11.85
83-95
9-57
69.04
11.04
81.80
6.43
67.84
9.81
82.85
5-42
64.48
4-5 1
79-49
2.71
62.28
o.o
IOO-OO
Na 2 Cr0 4
N^CrOs.iaHijO
5 .i 3 H 2 + Na 2 Cr0 4 . 4 H 2
N a2 CrO 4 . 4 H 2 O
zH 2 O + Na-jCrsOio-HzO
Na 2 Cr30 10 .H 2 O
Na 2 Cr 3 Oio.H 2 O + Na 2 Cr 4 Q, 3 4H 2 O
Cr0 3
100 gms. of a saturated aqueous solution contain at 30:
46.627 gms. Na 2 CrO 4 , or 100 gms. H 2 O dissolve 87.36 gms. Na 2 CrO 4 .
66.4 gms. Na 2 Cr 2 O 7 , or 100 gms. H 2 O dissolve 197.6 gms. Na 2 Cr 2 O T .
100 gms. absolute methyl alcohol dissolve 0.345 gm. Na 2 CrO 4 at 25.
(de Bruyn Z. physik. Ch. 10, 783, '92.)
305 SODIUM CITRATE
SODIUM CITRATE 2C 3 H 4 (OH)(COONa) 3 .nH 2 O.
100 gms. H 2 O dissolve 90.9 gms. citrate at 25, and 250 gms. at b. pt.
(U.SP.)
SODIUM (Ferro) CYANIDE Na 4 Fe(CN) 6 .
SOLUBILITY IN WATER.
(Conroy J. Soc. Chem. Ind. 17, 104, '98.)
t 20. 42. 80. 98.5*.
Gms. Na 4 Fe(CN) 6 per ioo gms. H 2 O 17.9 30.2 59.2 63.0
SODIUM FORMATE HCOONa. SOLUBILITY IN WATER.
(Groschuff Ber. 36, 1788, '03.)
Gms. Mols. Gms. Mols.
t o HCOONa HCOONa Solid t HCOONa HCOONa Solid
" per ioo Gms. per i oo Mols. Phase. per ioo Gms per ioo Mols. Phase.
Solution. H 2 O. Solution. H 2 O.
20 22.8o 7.82 HCOONa. 3 H 2 O 25.5 $0.53 27.0 HCOONa. 2 H 2 O
O 30.47 1 1. 6 " l8 49.22 25.65 HCOONa
+ 15 41.88 19.1 29 50.44 26.9
18 44-92 21.6 " 54 53-80 30.8
l8 44-73 2I -4 HCOONa.2H2O 74.5 56.82 34.8
21 46.86 23.3 100.5 6l -54 42-35
23 48.22 24.65 123 66.20 51-8
Sp. Gr. of the saturated solution of the dihydrate at 18= 1.317.
SOLUBILITY OF SODIUM ACID FORMATE (EXPRESSED AS NEUTRAL
SALT) IN AQUEOUS SOLUTIONS OF FORMIC ACID.
(Groschuff.)
Gms. Mols. Gms. Mols.
t o HCOONa HCOONa Solid t o HCOONa HCOONa Solid
per ioo Gms. per ioo Mols. Phase, * per ioo Gms. per ioo Mols. Phase.
Solution. H 2 0. Solution. HjzO.
O 22.35 J 9'5 HCOONa.HCOOH 45.5 38.85 43.! HCOONa
25.5 29.62 28.45 7o 41-27 47-5
66.5 41.08 47.1 85 43.09 51.2
SODIUM FLUORIDE NaF.
ioo gms. sat. aq. solution contain 4.3 gms. NaF at 18. Sp. Gr. of
Solution = 1.044. (Mylius and Funk Ber. 30, 1718, '97.)
SOLUBILITY OF SODIUM FLUORIDE IN AQUEOUS SOLUTIONS OF
HYDROFLUORIC ACID AT 21.
(Ditte Compt. rend. 123, 1282, '96.)
Grams per 1000 Grams HgO. Grams per 1000 Grams H 2 O.
o.o HF 41. 7 NaF 83-8HF 22. 9 NaF
io. o " 4i-4 " 129-7 " 23-8 "
45.8 " 22.5 " 596.4 " 48-8 "
56.5 " 22.7 " 777-4 ' 81.7
SODIUM FLUO SILICATE Na 2 SiF 6 .
ioo gms. H a O dissolve 0.65 gm. at 17.5* and 2.45 gms. at 100.
(Stolba Z. anal. Ch. u. ioo, '72.)
SODIUM HYDROXIDE
306
SODIUM HYDROXIDE NaOH.
SOLUBILITY IN WATER.
(Pickering J. Ch. Soc. 63, 890, '93; Mylius and Funk (Dietz) Wiss. Abh. p. t. Reichaastalt 3, 450, 'oo.)
t
Gms. NaOH
per TOO Gms.
Solid
Phase.
Gms. NaOH
t. per TOO Gms.
Solid
Solution
. Water.
Solution.
Water
7
.8
8
-0
8
7
Ice
20
52
.2
109
NaOH.H 2
20
16
.0
I 9
.1
30
54
3
119
"
-28
19
.0
23
5
Ice + NaOH. 7 H2O
40
56
3
129
"
-24
22
.2
28
5
NaOH.7H 2 O + NaOH.sH 2 O
50
59
.2
145
41
~I7
7
24
5
32
5
NaOH. 5 H 2 + NaOH^HaO a
60
63
5
174
"
O
29
.6
42
.0
NaOH. 4 H 2 O a
6 4
369
222
3 "f-pt
+ 5
32
.2
47-5
NaOH. 4 H 2 a + NaOH 3 *H 2
61
.874
.2
288
NaOH.HoO
+ NaOH
10
34
5 1
5
NaOH. 3 *H 2
80
75
.8
313
NaOH (?)
15
5
38
9
63
53
f. pt.
no
78
5
365
M
5
45
5
83
5
NaOH.siHzO + NaOH^H-zO
192
83
9
521
"
12
50
7
103
.0
NaOH. 2 H 2 O + NaOH.H 2 O
Sp. Gr. of sat. solution at 18 = 1.539.
For determinations of the Sp. Gr. of sodium hydroxide solution, see
Kohlrausch Wied. Ann. i, 1879; Wegschnider and Waller
Monatsh. Chem. 26, 685, '05.
SODIUM IODATE NaIO 3 .
SOLUBILITY IN WATER.
(Gay-Lussac; Kremers Pogg. Ann. 97, 5, '56.)
t. o. 20. 40. 60 80. 100.
Gms. NaIO 3 per 100 gms. H 2 O 2.5 9 15 21 27 34
SODIUM IODIDE NaL2H 2 O.
SOLUBILITY IN WATER.
(de Copper Ann. chim. phys. [5] 30, 411, '83; see also Etard Compt. rend. 98, 1434, '84; and Kremers
Pogg. Ann. 97, 14, '56.)
Grams Nal per 100 Gms.
Solution.
72.0
73-6
74.6
74.6
74-7
t
Grams Nal
per 100 Gms
Solid
Water.
Solution.
Phase.
20
148.0
59-7
NaI. 2 H 2 O
O
158.7
61 .4
"
IO
168.6
62.8
"
20
178.7
64.1
tc
25
184.2
64.8
M
30
190.3
65.6
"
40
205.0
67.2
II
50
227.8
69-5
Solid
Phase
60
65
NaI. 2 H 2
Nal
70
80
100
1 2O
140
75-6
76.3
Water.
256.8
278.4
293
294
296
302
3 IO
3 2I
SOLUBILITY OF SODIUM IODIDE IN SEVERAL SOLVENTS.
de Bruyn Z. physik. Ch. 10, 783, '92; at ord. temp., Rohland Z. anorg. Ch. 18, 327, '98;
Walden Z. physik. Ch. 55, 713. 7i8, '06.)
Gms. Nal
Gms. Nal per 100 Gms.
per 100 Solvent. Solution.
Gms. Solvent. ^ * j-
22.5 43-i Acetomtnl 22.09 J 8.43
ord. temp. 58.8 Propionitril 9.09 6.23
22.5 77.7
ord. temp. 83.3
ord. temp. 26.3
(At 22.5
Solvent.
Absolute Ethyl Alcohol
d l5 0.810 Ethyl Alcohol
Absolute Methyl Alcohol
d 15 o. 799 Methyl Alcohol
d ls o. 816 Propyl Alcohol
Solvent.
Acetonitril
Propionitril
Nitro Methane
Acetone
Furfurol
ato.
22.09
9.09
0.34 0.48
very soluble
25.10
307 SODIUM MOLYBDATE
SODIUM MOLYBDATE Na 2 MoO 4 .
SOLUBILITY IN WATER.
(Funk Ber. 33, 3697, 'oo.)
Gms. Mols, Gms. Mols.
Na 2 MoO 4 Na 2 MoO 4 ,. . Na 2 MoO 4 Na 2 MoO 4 c ,. ,
t . per 100 per 100 p S"J| t . per too per 100 * lld
Gms. Mols. Fhase - Gms. Mols. Phase "
Solution. H 2 O. Solution. H 2 O.
O 30-63 3 . 86 Na 2 MoO 4 .ioH 2 O 15.5 39-27
4 33.83 4.47 18 39.40 5.70
6 35-58 4.83 32 39.82 5.78
9 38.16 5.39 51.5 41-27 6.14
IO 39-28 5 . 65 Na 2 MoO 4 .2HaO IOO 45 '57 7 -32
zoo gms. H 2 O dissolve 3.878 gms. sodium tri molybdate Na 2 Mo 3 O 10
at 20 , and 13.7 gms. at 100.
(Ullik Liebig's Ann. 144, 244, '67.)
SODIUM NITRATE NaNO 3 .
SOLUBILITY IN WATER.
Trans. Roy
'75; " "
(Mulder; Berkeley Trans. Roy. Soc. (Lond.) 203 A, 211, '04; see also Ditte Compt. rend. 80, 1164,
;; Maumee Ibid. 58, 81, '64; Etard Ann. chim. phys. [7] 2, 527, '94-)
Gms. NaNO 3i per 100 Gms. Mols. per t <> Gms. NaNO 3 per 100 Gms. Mols. per
Solution. Water. Liter. Solution. Water. Liter.
o 42.2 72.9-73.0* 6.71* 80 59.7 148.0-148.0* 10.35*
10 44.7 80.8-80.5 7.16 ioo 64.3 180.0-175.8 11.30
20 46.7 87.5- 88.0 7.60 120 68.6 218. 0-208. 8t 12.22!
25 47.6 91.0- 92.0 7.80 180 78.1 356.7
30 48.7 94.9-96.2 8.06 220 83.5 506.0
40 50.5 102.0-104.9 8.51 225 91.5 1076.0
50 52.8 112.0114.0 8.97 3i3m.pt. 100.0 oo
60 54.9 122.0-124.0 9.42
* Berkeley. t up -
SOLUBILITY OF SODIUM NITRATE IN AQUEOUS SOLUTIONS OP
NITRIC ACID AT o.
(Engel Compt. rend. 104, 911, '87; see also Schultz Zeit. Ch. [2] 5, 531, '62.)
Equivalents per 10 cc. Solution. Sp. Gr. of Grams per ioo cc. Solution.
NaN0 3 . HNOY Solutions. NaNO 3 . HNO7-
66.4 o i-34i 56-5 o.oo
63.7 2.65 1.338 54.2 1.67
6o-5 5-7 I.33I 51-48 3-59
56.9 8.8 1.324 48.42 5.55
52.75 12-57 1.312 44.88 7.92
48.7 16.9 I-308 41-44 10-65
39-5 2 7- I - 2 9 I 33-6i 17-02
35.1 3 2 - 2 5 J - 28 5 29.86 20.33
31.1 37- 2 5 1.282 26.46 23.48
23.5 48.0 1.276 20.0 30.26
18.0 57.25 1.276 15.32 36.09
12.9 71.0 1.291 10.97 44-76
SODIUM NITRATE
308
SOLUBILITY OF MIXTURES OF SODIUM NITRATE AND POTASSIUM
NITRATE IN WATER AT 20.
(Carnelly and Thomson J. Ch. Soc. 53, 799, '88.)
Per cent
NaNO 3 in
Mixtures
Gins.
per 100 Gms.
H 2 O.
Used.
NaN0 3 .
KNO 3 .
100
86.8
o
90
96.4
13.2
80
98.0
38-5
60
90.0
47-6
50
66.0
40-0
Per cent
NaN0 3 in
Mixtures
Gms.
per too Gms.
H 2 0.
Used.
NaN0 3 .
KNOa.
45-7
53-3
34-7
40
45-6
35-5
2O
20.8
33-3
10
9-4
3i-5
o
O-O
33-6
ioo gms. H 2 O dissolve 24.9 gms. NaCl + 53.6 gms. NaNO 3 at 20.
(Riidorff Ber. 6, 484, '73; Karsten; Nicol Phil. Mag. [5] 3L 386, '91.)
SOLUBILITY OF SODIUM NITRATE IN AQUEOUS SOLUTIONS OF
SODIUM HYDROXIDE AT o.
(Engel Bull. soc. chim. [3] 6, 16, '91.)
.Sp. Gr.
of
Solutions.
I -341
I-338
1-333
1.327
i .326
1-332
i .401
SOLUBILITY OF SODIUM NITRATE IN ALCOHOLS.
ioo gms. abs. methyl alcohol dissolve 0.41 gm. NaNO 3 at 25.
ioo gms. abs. ethyl alcohol dissolve 0.036 gm. NaNO 3 at 25.
(de Bruyn Z. physik. Ch. 10, 783, '92.)
SOLUBILITY OF SODIUM NITRATE IN AQUEOUS ETHYL ALCOHOL
AT DIFFERENT TEMPERATURES.
(Bodlander Z. physik. Ch. 7, 317, '91; Taylor J. Physic. Ch. i, 723, '97; Bathrick Ibid, i, 162,796 )
Results at 13 (B.). Results at 16.5 (B.).
Milligram Mols. per 10
cc. Solution.
Na 2 O.
NaN0 3 .
o.o
66.4
2-875
62.5
6.1
57-15
12-75
47-5
26.0
29-5
39-o
17-5
45-88
13 -!9
60.88
6.05
Grams per ioo cc.
Solution.
NaOH.
NaN0 3 .
o.o
56.50
2.30
53 -!9
4.89
48.63
IO.2I
40.42
20.83
25 .IO
31.25
14.89
36. 7 6
II .22
48-75
5- J 5
>p. Gr. of
Gms. per 100 cc. Solution. So.Gr.of
Gms. per 100 cc. Solution.
solutions.
C 6 H 5 OH.
H 2 0<
NaNO 3 . Solutions.
C 6 H 5 OH.
H 2 O.
NaN0 3 .
.3700
O
o
75
34
61
66
3745
o.o
75
25
62.20
3395
3
.08
73
53
57
34
.3162
6.16
70
.82
54-64
.3120
6
.01
7i
.81
53
39
.2576
II .60
68
.IO
46.06
.2845
8
30
70
85
49
30
.2140
16.49
65
.04
39-87
.2580
IO
.91
69
47
45
42
.1615
22.17
61
.67
32-3 1
2325
13
77
67
.12
42
36
0855
32.22
S 2
.92
23-41
.2010
16
.46
66
.16
37
.48 1-0558
37-23
48
50
19.85
i .0050
43-98
42
.78
13-74
0.9420
52.60
32
J 3
9-47
0.9030
6o-OO
2 5
65
4-65
0-8610
63.16
21
3i
1.63
39
SODIUM NITRATE
Results at 30 (T.]
Results at 40.
(Bathrick.)
Wt. per cent
Alcohol in
Gms. NaNO 3
per 100 Gms.
Solvent.
Solution.
Water-
O
49-10
96-45
5
46.41
9 I - I 5
10
43-50
85 -55
20
37-42
74-75
30
65.10
40
25.14
55-95
50
18.94
46-75
60
12.97
37-25
70
7 .8l
28.25
90
I .21
12.25
Wt.
"per cent
Alcohol.
O
8.22
26.0
36.0
42.8
55-3
65-1
77-o
87-2
Gms. NaNOt
per 100 Gms.
Aq. Alcohol.
104.5
90.8
73-3
6l.6
48-4
40.6
27
18
i
i
9-4
4.2
SOLUBILITY OF SODIUM NITRATE IN AQUEOUS SOLUTIONS OP
ACETONE.
Results at 30.
(Taylor.)
Results at 40.
(Bathrick.)
Wt. per cent
Acetone in
Gms. NaNO 3
per 100 Gms.
Wt.
per cent
Gms. NaNOg
per 100 Gms.
Solvent.
Solution.
Water.
Acetone.
Aq. Acetone.
49-10
96.45
0-0
105
5
46.96
93-20
8-47
9 1.2
9.09
45 - 11
90.40
16.8
78.3
20
40.10
83-70
25.2
66.4
30
35.08
77.20
34-3
57-9
40
29.80
70.75
44.1
46.2
50
24-34
64.40
53-9
32-8
60
18.55
59-95
64.8
23.0
70
13 -is
50.50
76.0
10.8
80
7.10
38.20
87.6
3- 2
90
1.98
20-20
SODIUM NITRITE NaNO,.
100 gms. H 2 O dissolve 83.3 gms. at 15.
(Divers J. Ch. Soc. 75, 86, "99.)
100 gms. abs. methyl alcohol dissolve 4.43 gms. NaNO 2 at 19.5.
100 gms. abs. ethyl alcohol dissolve 0.31 gm. NaNO 2 at 19.5.
(de Bruyn Z. physik. Ch. 10, 783. 02.)
SODIUM RHODO NITRITE Na 6 Rh 2 (NO 2 ) 12 .
100 gms. H 2 O dissolve 40 gms. at 17, and 100 gms. at 100.
(Leidie Compt. rend, in, 107, '90.)
SODIUM OXALATE C 2 O 4 Na 2 .
SOLUBILITY IN WATER.
(Souchay and Leussen Liebig's Ann. 99, 33, '56; Pohl J. pr. Ch. 56, ai6, '52.)
t. 15-5. 2I-8 - 100.
Gms. Na 2 C 2 O 4 per 100 gms. H 2 O 3 . 22 3 . 74 6 .33
SODIUM OXALATE
310
SOLUBILITY OP MIXTURES OF SODIUM OXALATE AND OXALIC
ACID IN WATER AT 25.
(Foote and Andrew Am. Ch. J. 34, 154, '05.)
Gms. per 100 Gms. Mols. per 100 Mols.
Solution. H 2 0.
Na 2 C 2 4 . H 2 C 2 O 4 . Na 2 C 2 O 4 .
IO-2O ... 2 .274 . . . H 2 C 2 O 4 .2H 2 O
10.50 0.83 2.370 0.130 H2Cj8O4.2H2O4-HNaCisO4.H2O
9.15 0.71 2.032
^25 ^234 -I* Double Salt, HNaC.04^20
O-47 3. 2O 0-098
0.42 3.85 . 090 . 541 HNaC 2 O 4 .H 2 O + Na-jC^
3.60 ... 0.502 Na 2 C 2 O 4
SODIUM p NITEO PHENOL C 6 H 4 .ONa(i).NO 2 ( 4 ).
SOLUBILITY IN WATER AND IN AQUEOUS NORMAL SOLUTIONS OF
NON ELECTROLYTES.
(Goldschmidt Z. physik. Ch. 17, 154, '95.)
Gms. CH4.ONa(i).NO2(4) per 100 Gms. Solution in:
1>
Water.
Alcohol.
Urea.
Glycerine.
Acetone.
Propionitril.
Acetonitril
. Urethane
23.7
5-597
5-6I5
6.244
6.188
6.225
6.257
6.065
6.520
28.6
6.721
6.874
7.489
7.440
7.498
7.571
7.328
7.88 9
30.6
7.256
. . .
33.6
8.125
8.318
9-000
9.025
9.025
9.066
8.886
9-57
35-9
8.851
36-1
8.883
9.683
9.688
9.665
9.9II
9.667
10.248
40.2
9.881
10. 147
10.666
10.777
10.695
10.905
10.667
TI -379
45-2
n-235'
11.513
12.068
12.229
12.869
12.730
13.133
13-555
13-785
The solid phase is C 6 H 4 ONa.NO 2 . 4 H 2 O below 36, and C 6 H 4 ON ai
NO 2 .2H 2 O above 36 in each case.
SODIUM PHOSPHATES, Ortho, Hydrogen, and Pyro.
SOLUBILITY OF EACH IN WATER.
(Mulder; Poggiale.)
4,0 Gms. per loo^Gms. Water. 4,0 Gms. per 100 Gms. H 2 O.
NasPO 4 . Na 2 HPO 4 . Na 4 P 2 6 7 . NaaPO 4 . Na 2 HPO 4 . Na 4 P 2 6 7 .
o 1.5 2.5 3.16 40 31.0 63.9 13-50
10 4-1 3-9 3-95 50 43-o 82.5 17.45
20 II. O 9.3 6.23 00 55-0 91.6 21.83
25 15.5 15-4 8.14 80 81.0 96.6 30.04
30 20.0 24.1 9.95 100 I08.0 99-0 40-26
Solid phases, Na 3 PO 4 .i2H 2 O, Na 2 HPO 4 .i2H 2 O and Na 4 P 2 O 7 .ioH 2 O
respectively. Sp. Gr. of saturated solution of Na 2 HPO 4 at 15= 1.047,
100 gms. alcohol of 0.941 Sp. Gr. dissolve 0.33 gm. sodium phos-
phate at 15.5.
SODIUM (Double) PHOSPHATE, FLUORIDE Na 3 PO 4 .NaF.i 2 H 2 O.
100 gms. water dissolve 12 gms. of the double sodium salt at 25,
and 57,5 gms. at 70. Sp. Gr. of solution at 25= 1.0329; at 70=
(Briegleb Uebig's Ann. 97- 9S. 's6->
SODIUM PHOSPHITES
SOLUBILITY OP SODIUM PHOSPHITES, ETC., IN WATER.
Salt.
Hydrogen Phosphite
Formula.
(NaH)HP0 3 . 2 JH 2
Gms. Salt
per 100 Gms.
H 2 0.
Authority.
Hypophosphate
Hydrogen Hypophosphate
Tri Hydrogen "
Di Hydrogen "
Di Hydrogen "
Hypophosphite
Hypophosphite
SODIUM SELENATE
Na 4 P 2 O 6 .ioH 2
Na 3 HP 2 6 . 9 H 2
NaH 3 P 2 O 63 H 2
Na 2 H 2 P 2 O 6 .6H 2 O
Na 2 H 2 P 2 O 6 .6H 2
(NaH)HPO 2 .H 2 O
(NaH)HPO 2 .H 2 O
o
10
42
cold
cold
cold
b. pt.
b. pt.
66
193
3-3
6.7
2.2
2O. O
100. O
830
( (Amat. Compt.
. omp.
rend. 106, 1351, '88.)
(Salzer Liebig's
Ann. a xx. 1,^82.)
] (Salzer Liebig's
) Ann. 187, 33L '77
(U. S. P.)
Gms.
Mols.
Na 2 SeO 4 per
100 Gms.
Na 2 SeO 4 per
100 Mols.
Solid
Phase.
Solution.
H 2 0.
11.74
1.26 Ni
i2Se0 4 .ioI
25.01
3.18
M
29.00
3-90
u
36.91
5-57
44
39.18
6-13
44
Na 2 SeO 4 .ioH 2 O. SOLUBILITY IN WATER.
(Funk Ber. 33, 3697, 'oo.)
Gms. Mols.
t o Na 2 SeO 4 per Na 2 SeO 4 per Solid
loo Gms. loo Mols.
Solution. HoO.
Phase.
O H-74 1.26 Na2SeO 4 .ioH2O 35-2 45-47 7-94
15 25.01 3.18 " 39.5 45.26 7.87
18 29.00 3.90 50 44-49 7-^3
25.2 36.91 5.57 75 42.83 7.14
27 39 .18 6.13 100 42.14 6.93
30 44-05 7.50
Sp. Gr. of saturated solution at 18 = 1.315.
Na 2 Se0 4
SODIUM ST ANN ATE Na 2 SnO 3 .3H 2 O.
100 gms. H 2 O dissolve 67.4 gms. at o, and 61.3 gms. at 20.
Gr. of solution at o = 1.472; at 20 = 1.438.
Sp.
SODIUM SULPHATE Na 2 SO 4 .
(Ordway Am. J. Sci. [2] 40, 173, '65.)
SOLUBILITY IN WATER.
(Mulder; Lowel Ann.chim. phys. [3] 33, 382, '51; Tilden and Shenstone Proc. Ro;
35. 345. '83; Etard Ann. chim. phys. [7] 2, 527, '94; Funk Ber. 33, 3701, 'oo; Ber]
Roy. Soc. (Lond.) 203 A, 209, '04.)
Gms. Na 2 SO 4 per Mols. Q ,-j Gms. Na 2 SO 4 per Mols.
t. TOO Gms. Na 2 SO*per ? hd t- 100 Gms. Na 2 SO 4 p
Solution.
Water.
Liter (B.).
Solution.
Water. ^ter (L
4.76
5
o
O
.31 N a2 S0 4 .ioH20
50
31.8
4 6
7
2.92
5
6.0
6
4
"
60
31.2
45
3
2-83
10
8-3
9
.0
.631
80
3-4
43
7
2.69
15
ii. 8
13
4
IOO
29.8
42
5
2.60
20
16.3
19
4
I
32
1 20
29-5
4 1
95
25
21.9
28
o
140
29.6
42
27-5
25.6
34
.0
it
160
30-7
44
25
30
29.0
40
.8
2
.63
230
31 .7
46
4
30.6
44
o
N
o
16.3
19
5
32
32-3
47
.8
. . . '
5
19.4
24
32-75
33-6
50
65
3
.11
10
23.1
30
33
33-6
5o
.6
. . . N a2 SO 4
15
27.0
37
35
33-4
.2
... "
20
30.6
44
40
32.8
48
.8
3
.01
2 5
34-6
53
...
Na,S0 4
NaaS0 4 .7H,0
SODIUM SULPHATE
312
SOLUBILITY OF MIXTURES OF SODIUM SULPHATE AND MAGNESIUM
SULPHATE IN WATER (ASTRAKANITE) Na 2 Mg(So 4 ) 2 .4H 2 o.
(Roozeboom Rec. trav. chim. 6, 342, '87; Z. physik. Ch. 2, 518, '88.)
Solid
Phase.
Astrakanite
Astrakanite -f Na2SO 4
Astrakanite + MgSO 4
Mols.
per 100
Grams per 100
t.
Mols.
H 2 0.
Grams
^20.
Na 2 S0 4 .
MgSO 4 .
Na 2 S0 4 .
MgSO 4 .
22
2-95
4-70
23-3
31-4
24-5
3-45
3-68
27.2
24.6
30
3-59
3-59
28.4
24.1
35
3-7i
3-7i
29.4
2 4 .8
47
3-6
3-6
28.4
24.1
22
2-95
4-70
23-3
31-4
24-5
3-45
3.62
27.2
24.2
30
4-58
2.91
36.1
I9.I
35
4-3
2.76
33-9
18.44
18.5
3-4i
4.27
43-o
45-5
22
2.85
4-63
35-2
48.9
24-5
2.68
4.76
32-5
5o-3
30
2-3
5-3i
25-9
55-o
35
i-73
5-88
23-5
59-4
SOLUBILITY OF MIXTURES OF SODIUM SULPHATE, POTASSIUM
CHLORIDE, POTASSIUM SULPHATE, ETC., IN WATER.
(Meyerhoffer and Saunders Z. physik. Ch. 28, 469; 31, 382, '99.)
c f> t Mols. per 1000 Mols. H 2 O.
f. &T.5L* , * N Solid Phase.
Na a C1 2
*4-4 ... 5-42 14-39 5 T - 8 3 6o - 8
0.2 ... 3.35 12.78 50.93 60.36 NaaSO^xoHaO+KCl+NaCl
-0.4 ... 3.59 16.38 40.75 53.54 Na 2 S0 4 .ioH 2 0+KCl+K 3 Na(S0 4 ) 2
16.3 ... 4.72 17.58 50.56 63.42 K 3 Na(SO 4 ) 2 +KCl+NaCl
24.8 1.2484 4.37 20.00 48.36 64.01 KsNa(SO 4 )a+KCH-NaCl
*l6.3 ... 16.29 9- 16 6l.o6 53.93 K 3 Na(|0 4 ) 2 -hNaCl+Na 2 S0 4 .ioH 2 CH-
24.5 1.2625 14.45 9-90 58.46 53-91 K 3 Na 2 (S0 4 4)2+NaCl+Na 2 S0 4
0.3 ... 2.75 25.77 17.93 40-95 K3Na(S0 4 ) 2 +KCl+K 2 S0 4
25.0 1.2034 2.94 36.20 14.80 48.06 KsNa(SO 4 )2+KCl+K 2 SO 4
*l7-9 1.2474 13.84 0.0 62.57 48.70 Na 2 S0 4 .ioH 2 O+Na 2 SO 4 +NaCl
*30.I 1.2890 50.41 10.08 40.33 0.0 K 3 Na(SO 4 ) 2 +Na 2 SO 4 .ioH 2 O+Na 2 SO 4
21.4 ... ... ... 46.61 46.36 NaC1.2H 2 O+Na 2 SO 4 .ioH 2 O
-23.7 10.51 39.58 50.09 NaCl. 2 H 2 0+KCl
-10.9 ... 1.45 30.68 ... 29.23 KC1+K 2 S0 4
~3 ... 16.25 10.03 6 - 21 K 3 Na(S0 4 ) 2 +Na 2 SO 4 .ioH 2 O
3 ... 16.24 10.03 6 -2I ... K3Na(S0 4 )2-|-K 2 S0 4
-14 ... 1-39 25.59 8.78 32.94 K 3 Na(S0 4 ) 2 +Na 2 S0 4 .ioH 2 0+KCl
-14 ... 1-39 25.59 8.78 32.94 K 3 Na(S0 4 ) 2 +K 2 S04+KCl
-23.3 ... 0.41 15.15 44.20 58.97 Na 2 S0 4 .ioH 2 0+KCl+NaCl. 2 HaO
* Indicates transition points.
SODIUM SGLPHATB
SOLUBILITY OP SODIUM SULPHATE IN AQUEOUS SOLUTIONS OP
SULPHURIC ACID.
(D'Ans, Shepherd and Gunther Z. anorg. Chem. 49, 356-61, '06.)
Gms. per 1000 Cms. Solution. Mols. per 1000 gms. Solution.
H.SO 4
Na,SO 4
H,SO 4
NaaS04
O.O
219.0
O.O
I-54I
28.1
237-4
0.286
1.671
33-2
247-5
0.338
1.742
86.7
320.7
0.884
2.256
154.6
335-8
1.576
2.363
163.5
346.4
1.666
2-437
256.3
297.4
2.611
2.O9I '.
Solid Phase.
Na 2 SO4-ioH,O
Na 2 SO 4 10 H 2 O + Na 2 SO 4
Na 3 H(SO4) -H 2 + Na 2 SO 4
Na 3 H(SO 4 ) 2 + Na 2 S0 4
NaH(SO 4 ) 2 + Na 3 H(SO 4 ) 2 - H a O
SOLUBILITY OF SODIUM SULPHATE IN AQUEOUS SOLUTIONS OP
SODIUM CHLORIDE AT DIFFERENT TEMPERATURES.
Results at 10.
(Seidell Am. Ch. J. 27, 52, '02.)
Results at 21.5.
Results at 27'
Sp. Gr.
of
Gms. per TOO Gms. Sp. Gr.
H 2 O. of
Gms. per 100 Gms. Sp. Gr.
H 2 O. O f
Gms. per 100 Gms.
Solutions.
NaCl.
Na 2 S0 4 . Solutions.
' NaCl.
Na 2 S0 4 ." Solutions.
NaCl.
N aa SO 4 .
I.oSo
O.O
9
.14 1.164
O.O
21
33
.228
0-0
31.10
1.083
4.28
6
.42
.169
9-05
15
.48
.230
2.66
28.73
I .IO2
9.60
4
.76
.199
17.48
13
73
230
5-29
27.17
I.I50
I5-65
3
99
.214
20.41
13
.62
235
7.90
26.O2
I .164
21.82
3
97
243
26.01
15
05
259
16.13
24.83
I .192
28.13
4
*5
244
26.53
14
44
253
18.91
21-39
I .207
30.11
4
34
.244
27.74
13
39
249
19.64
20. 1 1
I .217
32.27
4
59
244
3I-25
10
.64
245
20-77
19.29
1.223
4
75
243
31.80
10
.28
238
32-33
9-53
245
32.10
8
43
.219
33.69
4
73
.212
34.08
2
77
.197
35-46
O
.00
Results at 30.
Results at 33.
Results at 35.
5p. Gr.
of
Gms. per 100 Gms. SD Gr.
HzO. of
Gms. per 100 Gms.
H 2 0.
Sp. Gr.
of
Gms. per
TOO Gms.
Solutions.
NaCl.
Na 2 SO 4 . Solutions.
NaCl.
Na 2 SO 4 .
Solutions.
NaCl.
Na 2 SO .
I.28l
0.0
39
.70 1.329
O.O
48.48
I
324
.0
47-94
1.282
2-45
38
-25 1.323
I .22
46.49
I
2
.14
43-75
.284
S .6l
36
.50 1.318
1.99
45.16
I
'256
13
57
26.26
.290
7.91
.96 1-315
2.64
44.09
I
238
18
78
19.74
.276
10.61
31
.64 1.309
3-47
42.6l
I
.231
31
.91
8.28
.270
12.36
29
.87
.265
12.14
29.32
I
193
35
.63
o.oo
.258
15-65
25
.02
237
21.87
16.83
.249
18.44
21
30
234
32.84
8.76
.244
20.66
!9
.06
.217
33-99
4-63
.236
32-43
9
.06
.208
34-77
2-75
SODIUM SULPHATE 314
SOLUBILITY OF SODIUM SULPHATE IN AQUEOUS ETHYL ALCOHOL.
(de Bruyn Z. physik. Chem. 32, 101, *oo.)
..
Content
of
Alcohol.
Gms. Na 2 SO 4
per 100 Gms.
Aq. Alcohol.
Gms. per 100 Gms. Solution. Solid
H 2 0.
C 2 H 5 OH.
Na 2 SO 4 . Phase.
15
0-7
12.7
88.7
0-0
II-3 Na 2 S0 4 .ioH 2 O
tt
9-2
6. 7
8 5 .I
8.6
6.3
tt
19.4
2.6
78.6
18.9
2.9
tl
39-7
0-5
6o.O
39-5
0-5
tl
O.I
4I.I
58.8
o.i
tt
72.0
o.o
28.0
72.0
o.o
tt
o.o
37-4
7 2.8
o.o
27.2 Na 2 S0 4 . 7 H2O
tc
II .2
16.3
76.5
9-5
14.0
tt
20.6
7.0
74-3
19.2
6.5
tt
30.2
2 .O
68.4
29.6
2.0
25
0-0
28.2
78.1
o.o
21-9 NajSO^ioHaO
10.6
13-9
78.5
9-3
12.2
tl
24.0
4-5
72.8
22.9
4-3
It
54-o
0.4
45-6
54-o
0.4
36
o.o
49-3
67.0
o.o
33 -o N a2 so 4
tt
8.8
29.2
70.6
6.8
22.6
tl
12.8
22.4
71.2
10.5
18.3
11
17.9
15-4
71.1
iS-5
13-4
It
J 5-3
71.0
15-7
13-3
It
28.9
5-4
66.5
28.4
5- 1
tl
48.7
0.8
50-9
48-3
0.8
1?
o.o
47-9
67.6
o.o
32.4
tt
9.0
27-5
71 .3
7 I
21.6
(I
14-5
19.2
7 i.8
12. 1
16,1
tl
20.6
12.3
70.6
18.4
IO.O
ft
31.0
65.6
29-5
4-9
Between certain concentrations of the aqueous alcohol the liquid
separates into two layers at 25, 36 and 45.
45
Upper Layer.
Lower Layer.
Gms. H 2 O.
Gms.C 2 HOH.
Gms. Na 2 SO 4 .
Gms.H 2 O.
Gms.C 2 H 5 OH.
Gms. Na 2 SO 4
66.5
27-3
6.2
67.4
5-i
27-5
68.1
23-9
8.0
68. 5
6.0
25-5
68. 3
23.1
8.6
68.3
6. 7
25.0
66.6
4-1
29-3
57-7
38-4
3-9
65.0
28. 3
6.7
68.8
5-9
25-3
68.1
21 .2
10.7
68.9
9.4
21-7
61.8
32-9
5-3
65.8
25-3
8.9
68.4
8.8
22.8
66.0
2/1.
IO.O
68.6
10. 1
21-3
3*5
SODIUM SULPHATE
SOLUBILITY OF SODIUM SULPHATE IN AQUEOUS PROPYL ALCOHOL
AT 20.
(Linebarger Am. Ch. J. 14, 380, '92.)
Gms. CsH 7 OH
per ioo Gms.
Alcohol-Water
Mixture.
42.20
49-77
55 - 6 5
ioo gms. H 2 O dissolve 183.7 m s. sugar + 30.5 gms. Na 2 SO 4 at
31.25, or ioo gms. sat. solution contain 52.2 gms. sugar + 9.6 gms.
Na 2 SO 4 . (K6hler Z. Ver. Zuckerind. 47, 447 , '97.)
rms. Na 2 SO 4
per ioo
Gms. Sat.
Solution.
Gms. CsH 7 OH
per ioo Gms.
Alcohol-Water
Mixture.
Gms. NajS'
per ioo
Gms. Sat.
Solution.
1-99
0.72
60.64
62.81
0-44
0.38
SODIUM (Bi) SULPHATE NaHSO 4 .
100 gms. H 2 O dissolve 28.6 gms. at 25, and 50.0 gms. at 100.
100 gms. alcohol dissolve 1.4 gms. at 25. <u. s. p.)
SODIUM THIO SULPHATE Na 2 S 2 O 3 .
SOLUBILITY IN WATER.
(Young and Burke J. Am. Chem. Soc. 26, 1417, '04.)
IO
20
25
30
35
40
45
20
25
28
2 9
30
ioo gms. alcohol dissolve 0.0025 g m - Na 2 S 2 O 3 and 0.0034 gm.
Na 2 S 2 O 3 .5H 2 O at room temperature. (Bsdtker z. physik. Chem. 22, 510, '97.)
100 gms. alcohol of 0.941 Sp. Gr. dissolve 33.3 gms. at 15.5.
(See also Parmentier Compt. rend. 122, 136, '96 )
SODIUM SULPHITE Na 2 SO,.
ioo gms. H 2 O dissolve 14.1 gms. at o, 25.8-28.7 gms. at 20, and
49.5 gms. at 40. (Kremers Pogg. Ann. 99, So, '56.)
Gms. Nc
IOO
128203 per
Gms.
Solid t o
Gms. Ns
IOO
128203
Gms.
** Solid
Tl_
Solution.
Water.
59-69
Pentahydrate (com.V 2O
Solution.
62 .11
Waten raase '
163.92 Monohydrate
41
.20
70
.07
25
62
73
168
.32
43
.15
75
.90
30
63
53
174
.20
45
.19
82
45
2O
55
122
68 Dihydrate
47
.71
9 1
.24
25
56
03
127
43
50
83
103
37
3
57
13
133
.27
55
33
123
.87
35
58
138
.84
49
38
97
55
Pentahydrate (8) 40
59
.17
144
.92
52
15
108
.98
50
62
.28
165
.11
54
.48
119
.69
33
5
58
59
141
48 Tetrahydrate (?)
55
85
126
36
.2
60
153
.23
56
57
130
.26
36
.6
62
.80
1 68
.82
SODIUM TELLURIATE Na 2 TeO 4 .2H 2 O.
ioo gms. H 2 O dissolve 0.77 gm. Na 2 TeO 4 at 18, and 2.0 gms. at
100. Solid phase Na 2 TeO 4 .2H 2 O.
ioo gms. H 2 O dissolve 1.43 gms. Na 2 TeO 4 at 18, and 2.5 gms. at 50.
Solid phase Na 2 TeO 4 .4H 2 O. (Myiius - Ber. 34. 2208, '01.)
SODIUM TUNGSTATE
3*6
SODIUM TUNGSTATE (Wolframate) Na 2 WO 4 . 2 H 2 O.
SOLUBILITY IN WATER.
(Funk Ber. 33, 3701, 'oo.)
to
Gms.
Na 2 W0 4 per
Mols.
Na 2 WO 4
100 Gms.
per
Solution.
X H O
-5
30.60
2. 70
-4
31 .87
2.86
-3
5 32.98
3.01
2
34-52
3-23
O
36-54
3-52
+ 3
39.20
3-95
5
41.02
4.26
Solid
Mols.
N W
Na 2 W0 4 .ioH 2 3.5
+5
" 18
21
" 43-5
80.5
" 100
41-67
41-73
42.0
42.27
43-98
47-65
49 .31
4-37
4-39
4.40
4.48
4-8i
5-57
5.95
Solid
Phase.
Na 2 W0 42 HoO
Sp. Gr. of sat. solution at 18 = 1.573. For Sp. Gr. determinations
of aqueous solutions at 20, see Pawlewski Ber. 33, 1223, 'oo.
SODIUM Fluo ZIRCON ATE 5 NaF.ZrF 4 .
100 gms. H 2 O dissolve 0.387 gm. at 18, and 1.67 gms. at 100.
(Marignac J. pr. Chem. 83, 202, '61.)
STRONTIUM BENZOATE Sr(C 7 H 6 O 2 ) 2 .H 2 O.
SOLUBILITY IN WATER.
(Paietta Gazz. chim. ital. 36, II, 67, '06.)
15.7
Gms. Sr (C 7 H 5 O 2 ) 2 per 100 gms. solution 5-31 5-4
24.7 31-4
40-9
5-77
STRONTIUM BROMATE Sr(BrO 3 ) 2 .
One liter of aqueous solution contains 0.9 gram molecules or 309
gms. Sr(BrO 3 ) 2 at l8. (Kohlrausch Sitzb. K. Akad. Wiss. (Berlin) oo, '97.)
STRONTIUM BROMIDE SrBr 2 .6H 2 O.
SOLUBILITY IN WATER.
(Average curve from results of Kremers Pogg. Ann. 103, 65, '58; and Etard Ann. chim.
phys. [7] 2, 540, '94.)
t e .
O
10
20
25
30
Gms. SrBr 2 per TOO Gms.
Solution. Water.'
46.0 85.2
48 S 9 3 o
IO2 .4
107.0
Gms. SrBra per TOO Gms.
50.6
ll'l
III .9
Solution.
Water.
40
55- 2
123.2
50
57-6
135-8
60
6O-O
150.0
80
64.5
181.8
100
69.0
222.5
Sp. Gr. of sat. solution at 20 approximately 1.70.
100 gms. abs. alcohol dissolve 64.5 gms. SrBr 2 at o. Sp. Gr. of
Solution = 1.2 1. (Fonzes; Diacon J. pharm. chim. [6] i, 59, '95.)
STRONTIUM CARBONATE SrCO 3 .
One liter of water dissolves 0.0082 gm. at 8.8 and 0.0109 gm.
at 24 by conductivity method.
(Holleman Z. physik. Chem. 12, 130, '93; Kohlrausch and Rose Ibia. 12, 241, '93.)
One liter of water saturated with CO 2 dissolves 1.19 gms. Sr(HCO 8 ),.
317 STRONTIUM CHLORATE
STRONTIUM OHLORATE Sr (C1O 3 ) 2 .
100 gms. H 2 O dissolve 174.9 gms. Sr(ClO) 2 , or 100 gms. sat. solution
contain 63.6 gms. at 18. Sp. Gr. of solution is 1.839.
(Mylius and Funk Ber. 30, 1718, '9?,)
STRONTIUM CHLORIDE SrCl 2 .6H 2 O.
SOLUBILITY IN WATER.
(Average curve from the results of Mulder; Etard; see also Tilden J. Chem. Soc. 45, 409, '84.)
t.
Gms. SrCl 2
per 100 Gm
s- Solid t o
Gms. SrCl2 per 100 Gms.
Solid
Solution.
Water.
Phase.
Solution.
Water '
Phase.
20
26.O
35-i
SrCMH-jO 60
4S-o
8l.8
SrCl 2 .6H 2 O
O
30-3
43-5
70
46.2
85-9
SrCl a .2H 2 O
IO
32-3
47-7
80
47-5
90-5
u
20
34-6
52-9
100
50.2
100.8
*
25
35-8
55-8
120
53-o
112. 8
M
30
37-o
58.7
140
55-6
125.2
M
40
39-5
65-3
160
58-5
141 -o
tl
50
42.0
72.4
180
62.0
163.1
M
Transition temperature about 62.5. Sp. Gr. of sat. solution at o
= 1.334; at 15 = 1.36.
SOLUBILITY OF STRONTIUM CHLORIDE IN AQUEOUS SOLUTIONS OF
HYDROCHLORIC ACID AT o.
(Engel Ann. chim. phys. [6] 13, 376, '88.)
;. Mols. per
10 cc. Solution.
Sp. Gr. of
Grams per
TOO cc. Solutioi
*SrCl 2 .
HC1.
Solution.
SrCl 2 .
HC1.
SI-6
O
1-334
40.9
o.o
44.8
6.1
1.304
35-5
2 .22
37-85
12-75
1.269
30.0
4-65
27.2
23-3
i .220
21.56
8.49
22.0
28. 3 8
i .201
17.44
10-35
14.0
37-25
1.167
ii .09
I3-58
4-25
5 2 -75
i-i33
3-37
19.23
ioo gms. abs. methyl alcohol dissolve 63.3 gms. SrCl 2 .6H 2 O at 6.
100 gms. abs. ethyl alcohol dissolve 3.8 gms. SrCl 2 .6H 2 O at 6.
(de Bruyn Z. physik. Chem, 10, 787, '92-)
SOLUBILITY OF STRONTIUM CHLORIDE IN AQUEOUS ETHYL
ALCOHOL SOLUTIONS AT 18.
(Gerardin Ann. chim. phys. [4] 5. 156, '65.)
Sp. Gr. of
Aq. Alcohol
ato.
Wt.
per cent
Alcohol.
Gms. SrCla
per too Gms.
Alcohol.
Sp. Gr. of
Aq. Alcohol
ato.
Wt.
per cent
Alcohol.
Gms. SrClj
per ioo Gms.
Alcohol.
0.990
6
49.81
Q-939
45
26.8
0.985
10
47-o
0.909
59
19.2
o-973
23
39-6
0.846
86
4-9
0.966
30
35-9
0.832
9 1
3-2
o-953
38
30-4
STRONTIUM CHROMATE 318
STRONTIUM CHROMATE SrCrO 4 .
SOLUBILITY IN WATER, ETC., AT 15.
(Fresenius Z. anal. Chem. 29, 4*9. 'oo; 3<>, 672, '91 >
Cms. SrCrO 4 Gms.SrCrO*
Solvent. per i oo Solvent. per ipo
Cms. Solvent. Gms. Solvent.
Water 0.12 Aq. Ethyl Alcohol (29%) 0.0132
Aq. NH 4 C1 (5 %) o . 195 Aq. Ethyl Alcohol (53 %) o .002
Aq. CH 3 COOH(i%) 1.57
STRONTIUM FLUORIDE SrF 2 .
One liter of water dissolves 1.87 mg. equiv. or 0.117 gm. SrF 2 at
1 8, by conductivity method. (Kohlrausch Z. physik. Chem. 50, 356, 'o4-'os.)
STRONTIUM HYDROXIDE Sr(OH) 2 .
SOLUBILITY IN WATER.
(Scheibler N. Z. Rubenzuckerind. 7. 257 ; abstract in J. pharm. chim. [5] 8, 540, '83.)
Grams per 100 Grams Solution. Grams per TOO cc. Solution.
' SKX Sr(OH) 2 .8H 2 0." SrO. Sr(OH) 2 .8H 2 O. "
o 0.35 0.90 0.35 0.90
10 0.48 1.23 0.48 1-23
20 0.68 1.74 0.68 1.74
30 i. oo 2.57 i .01 2.59
40 1.48 3-80 1.51 3-87
50 2.13 5.46 2.18 5.59
60 3.03 7.77 3-12 8.00
70 4-35 "- l6 4-55 JI - 6 7
80 6.56 16.83 7.02 18.01
90 12.0 30-78 i3- 6 4 34-99
100 18.6 47-7 1 22.85 58-61
STRONTIUM IODATE Sr(IO 3 ) 2 .
TOO gms. H 2 O dissolve 0.026 gm. at 15, and 0.72-0.91 gm. at
I OO. (Gay-Lussac; Rammelsberg Pogg. Ann. 44, 575, '38.)
STRONTIUM IODIDE SrI 2 .6H 2 O.
SOLUBILITY IN WATER.
(Average curve from the results of Kremers Pogg. Ann. 103, 65, '58; and Etard Ann. chim. phys.
[?] 2, 528, '74-)
Gms. Srl 2 per too Gms Solid t o Gms. Srlg per 100 Gms. Solid
' ' Solution. ' Water. Phase. ' Solution. Water. Phase.
O 62.3 165.3 SrI 2 .6H 2 O 90 78.5 365-2 SrI 2 .2H 2 O
20 64.0 177.8 " 100 79-3 383 .1
40 65.7 I9L5 " 120 80.7 4l8.I
60 68.5 217.5 " I 4 ^ 2 -5 47 x -5
80 73.0 270.4 " 175 85.6 594-4
Transition temperature about 90. Sp. Gr. of sat. solution at 20 =-
2.15.
100 gms. saturated solution of strontium iodide in absolute alcohol
contain 2.6 gms. SrI 2 at 20, 3.1 gms. at + 4, 4.3 gms. at 39, and 4.7
gms. at 82. (Etard.)
319 STRONTIUM MALATE
STRONTIUM MALATE SrC 4 H 4 O 6 .
SOLUBILITY IN WATER.
(Cantoni and Basadonna Bull. soc. chim. 35, 731. '06.)
t
Gms. per 100
cc. Solution.
t.
Gms. per 100
cc Solution-
t o Gms. per 100
cc. Solution.
20
0.448
40
I-385
55
2 .460
25
0-550
45
1-743
60
2.821
30
0.752 '
So
2.098
65
3-I48
35
1.036
70
3-3 6
STRONTIUM MOLYBDATE SrMoO 4 .
100 gms. H 2 O dissolve 0.0104 gm. SrMoO 4 at 17.
(Smith and Bradbury Ber. 24, 2930. '91.)
STRONTIUM NITRATE Sr(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Mulder; see also Etard for slightly lower results.)
Gms. Sr(NO 3 ) 2 per 100 Gms. Solid t o Gms. Sr(NO 3 )? per 100 Gms. Solid
'Solution. Water. Phase. Solution. ' Water, Phase.
O 28.3 39.5 Sr(N0 3 ) 2 .4H 2 40 47.7 91.3 Sr(NO3)t
10 35-5 54-9 5o 48-1 92.6
20 41-5 70.8 60 48.5 94 -o
25 44-1 79-o 80 49.3 97.2
30 46.7 87.6 " 100 50.3 101.1
Transition temperature about 31. Sp. Gr. of sat. solution at 20 =
1.44.
100 gms. absolute alcohol dissolve 0.024 gm. Sr(NO 3 ) 2 .
100 gms. rectified spirit dissolve 0.50 gm. Sr(NO 3 ) 2 .
(Hill Pharm. J. Trans. [3] 19, 420, '88.)
STRONTIUM OXALATE SrC 2 O 4 .H 2 O.
One liter of aqueous solution contains 0.52 mg. equivalent SrC 2 O 4
or 0.046 gm. at 18, conductivity method.
(Kohlrausch Z. physik. Chem. 50, 356, '04- '05.)
SOLUBILITY OF STRONTIUM OXALATE IN AQUEOUS ACETIC ACID
SOLUTIONS AT 26-27.
(Herz and Muhs Ber., 36, 3715, '03.)
Normality
Gms. per 100 cc. Solution.
Normality
Gms. per 100 cc. Solution.
of
Acetic Acid.
CH 3 COOH.
Residue
SrC 2 4 .H 2 0.
of
Acetic Acid.
CEaCOOH.
Residue
SrC 2 4 .H 2 O,
O-O
o.o
O.OO9
3-86
23.16
0.0898
0.58
3 -48
0.0526
5-79
34-74
0-0496
i-45
8.70
O.O622
16.26
97 -5 6
O.OO6O
2.89
17-34
0.0642
STRONTIUM SALIOYLATE Sr(C 6 H 4 OH.COO) 2 .2H 2 O.
100 gms. H 2 O dissolve 5.55 gms. at 25, and 28.6 gms. at b. pt.
(U. S. P.)
joo cc. aqueous solution contain 1.830 gms. anhydrous salt. (Barthe.)
100 gms. alcohol dissolve 1.5 gms. at 25, and 9.52 gms. at b. pt.
(U. S. P. ; Barthe Bull. soc. chim. [3] i j, 519, '94.)
STRONTIUM SULPHATE 320
STRONTIUM SULPHATE SrSO 4 .
One liter of aqueous solution contains 1.24 mg. equivalents or 0.114
gm. SrSO 4 at 18, by conductivity method.
(Kohlrausch Z. physik. Chem. 50, 356, '04 '05; Holleman Ibid. 12, 129, '93; Wolfmann Oster.
Ung. Z. Zuckerind. 25, 997, '97.)
SOLUBILITY OF STRONTIUM SULPHATE IN AQUEOUS SOLUTIONS OF
HYDROCHLORIC, NITRIC, CHLORACETIC AND FORMIC ACIDS.
(Banthisch J. pr. Chem. [2] 29, 52, '84.)
cc. of Aq.
Acid con-
In Aq. HC1
Gms. per 100 cc.
In Aq. HNO 3
Gms. per 100 cc.
In Aq.CH 2 ClCOOH
Gms. per 100 cc. Sol.
In Aq. HCOOH
Gms. per 100 cc.
O 1
Mg. Equiv.
in each case.
So'
So'
[.
' CH 2 C1
COOH.
SrS0 4 .
Sol
'HC1.
SrSO 4 .
HN0 3 .
SrS0 4 .
HCOOH.
SrSCv
0-2
18.23
0.161
3I-5 2
0.381
o-S
7.29
0.207
12. 6l
0.307
1.0
3-65
0.188
6.30
O.2I7
94-47
O.O26
46.02
O.O24
2.0
1.82
0.126
3-15
0.138
47-23
0.022
. . .
IO.O
0.36
0.048
0.63
0.049
SOLUBILITY OF STRONTIUM SULPHATE IN SULPHURIC ACID
SOLUTIONS.
r f Gms. SrSO 4
t . w In Per 100 Authority.
H2SO <- Gms. Acid.
Ord. Concentrated $-68 (Struve Z. anal. Chem. 9, 34, 1870.)
" fuming 9.77
91 % O .08 (Varenne and Paulean Compt. rend. 93, 1016, '81.)
70 Sp. Gr. 1 .843 = 99 / 14.0 (Garside Chem. News, 31. 245, '7S-)
SOLUBILITY OF STRONTIUM SULPHATE IN AQUEOUS SALT
SOLUTIONS.
(Virck Chem. Centralb. 402, '62.)
In Aq. NaCl. In Aq. KC1. In Aq. MgCl 2 . In Aq. CaCl 2 .
(a.)
(b.y
(a.)
(b.)
(a.)
(b.)
(a.)
(b.)
8-44
0.165
8.
22
O
193
i-59
o.
199
8.67
0.176
iS-54
0.219
12.
54
193
4-03
o.
2o6
16.51
0.185
22.17
0.181
18.
08
.251
J 3- 6 3
.242
33-70
0.171
(a) =
Gms. salt
per
IOO
gms.
aq. solution.
(6) =
Gms.
SrSO 4
per
100 gms
. solvent.
STRONTIUM TARTRATE SrC 4 H 4 O 6 . 3 H 2 O.
SOLUBILITY IN WATER.
(Cantoni and Zachoder BulL soc. chim. [3] 33, 751, '05.)
Gms. Gms. Gms:
SrC 4 H 4 O SrC 4 H 4 O 6 SrC^CV
t . , 3 H 2 per t . . 3 H 2 O per t . . 3 H 2 O
too cc. loo cc. per 100 cc.
Solution. Solution. Solution.
O O-II2 25 O.224 60 0.480
10 0.149 30 0.252 70 0.580
15 0.174 40 0-328 80 0.680
2O 0-200 50 0.407 85 0-755
32 1 STRONTIUM TARTRATE
SOLUBILITY OF STRONTIUM TARTRATE IN AQUEOUS SOLUTIONS OF
ACETIC ACID AT 26-27.
(Herz and Muhs Ber. 36, 3715, '03.)
Normality of Cms, per 100 cc. Solution. Normality of Gms. per 100 cc. Solution.
Acetic Acid. CHaCOOH. SrC 4 H 4 O 6 . 3 H 2 O. Acetic Acid. CHgCOOH.
o.o o.o 0.227 3.77 21.85 x -o5i
o-5 6 5 3-39 o- 6 78 5- 6 5 33-90 0.982
1.425 8.15 0.864 16.89 101.34 0.184
2.85 17.10 0.996
STRONTIUM (Di) TUNGSTATE SrW 2 O 7 . 3 H 2 O.
100 cc. H 2 O dissolve 0.35 gm. at 15.
(Lefort Ann. chim. phys. [5] 15, 326, '78.)
STRYCHNINE C 21 H 22 N 2 O 2 .
SOLUBILITY IN SEVERAL SOLVENTS.
(U. S. P.; at 20, Mttller Apoth.-Ztg. 18 258, '03; Schindelmeiser.)
Gms. C 2 iH 2 2N 2 O2 Gms. C 2 HazNaOa
per 100 Gms. per 100 Gms.
Solvent. < * Solvent. -
Solution Solvent Solution Solvent
at 20. at 25. at 20*. at 25.
Water 0.021 0.016 Petroleum Ether 0.0093
Water Sat. with Ether 0.0166 ... Acetic Ether 0.1972
Ether 0.0432 0.0182 Carbon Tetra Chloride 0.158 o. 645(1 7) (S.)
Ether Sat. with H 2 O 0.0513 ... Alcohol ... 0.909
Benzene o. 770 o. 666 Amyl Alcohol ... o. 555
Chloroform 100+ 16.6 Glycerine ... 0.25 (15)
100 gms. pyridine dissolve 1.24 gm. C 21 H 2 2N 2 O 2 at 26.
(Holty J. Physic. Chem. 9, 764, '05.)
SOLUBILITY OF STRYCHNINE NITRATE AND SULPHATE IN SEVERAL
SOLVENTS.
(U.S. P.)
Strychnine Nitrate. Strychnine Sulphate.
Gms. per 100 Gms. Solvent at: Gms. per too Gms. Solvent at:
Solvent. , ^ 8o o. 25. 80.
Water 2.38 12.5 3.23 16.6
Alcohol o . 83 i . 66 (60) 1.54 S-o (60)
Chloroform 0.64 ... 0.31
Glycerine 1.66 4.0(15) 22.5(15)
SUBERIC ACID C e H 12 (COOH) 2 .
SOLUBILITY IN WATER.
(Lamouroux Compt. rend. 128, 998, '99.)
t. o. 15. 20*. 35*. SO* 65
Gms. C 8 H 12 (COOH) 2
per 100 cc. solution 0.08 0.13 0.16 0.45 0.98 2.22
SUCCINIC ACID 322
.
SUCCINIC ACID (CH 2 ) 2 (COOH) 2 .
SOLUBILITY IN WATER.
(Miczynski Monatsh. Chem. 7, 263, '86; Van der Stadt Z. physik. Chem. 41, 355, '02; Lamouroux
Compt. rend. 128, 998, '99; for other concordant results, see Bourgoin Bull. soc. chim. [2] 21, no
'74; Henry Compt. rend. 99, 1157, '84.)
Gms. Succinic
Gms. (CH 2 ) 2 (COOH) 2 per 100
Anhydride
(CH 2 )aCOCOO
per
Mol.
per cent.
'
Gms. H 2 O.
cc. Solution.
H 3 O.
(CH 2 ) 2 COCOO.
100 Gms. H 2 O.
2.80
2 . 7 8(L.)
2-34
99.58
0.42
10
4-51
4-0
3.80
99-32
0.68
20
6.89
5-8
5-77
98.97
1.03
25
8.06
7-o
6.74
98.80
I .20
30
10-58
8-5
8-79
98.44
1-56
40
16.21
I2 -5
13.42
97.64
2. 3 6
50
24.42
18.0
!9 95
96.53
3-47
60
35.83
24-5
28.77
95 -7
4-93
70
51 .07
40.11
93.26
6-74
80
70.79
54-08
91 .12
8.88
89.4
95-45
70-62
88.71
ii .29
104.8
146.3
. . .
IOI .2
84.57
15-43
115.1
188.5
126.8
8l-4
18.6
134.2
335-4
187.8
74.72
25.28
159-5
748.2
. . .
295.2
65.27
34-73
180.6
1839.0
408.5
57-6
42.4
182.8
00
. . .
542-3
50.0
5-
174.4
808.5
40.7
59-3
153-3
2239.0
19.86
80.14
128.0
. . .
8865.0
5-89
94.11
118.8-119
00
o-oo
100.00
SOLUBILITY OF SUCCINIC ACID IN ALCOHOLS AND IN ETHER.
(Timofeiew Compt. rend. 112, 1137, '91; at 15, Bourgoin Ann. chim. phys. [5] 13, 405, '78.)
Gms. (CH 2 ) 2 (COOH) 2 per 100 Gms.
Solvent. / Solvent at:
-i- +iS. +21.5.
Abs. Methyl Alcohol 10.51 ... 1^9.40
Abs. Ethyl " 5.06 12.59 9.49
9 o% " 7-51
Abs. Propyl 2.11 ... 4-79
Abs. Ether ... 1.265
DISTRIBUTION OF SUCCINIC ACID BETWEEN WATER AND AMYL
ALCOHOL AT 20.
(Herz and Fischer Ber. 37, 4748, '04.)
Millimols iC4H 6 O 4
per 10 cc.
Gms. CHeO4 per
100 CC.
Millimols iC4HeO 4
per 10 cc.
Gms. C 4 H 6 O 4
per 100 cc.
Alcohol
Layer.
0.1888
0.3643
0.7077
1-440
2-7I5
Aq.
Layer.
0.2684
0.5252
I -0373
2.1266
4-0495
Alcohol
Layer.
O-III4
0.215
0.418
0.850
1.603
Aq.
Layer.
0.1584
0.310
0.612
I - 2 55
2.391
Alcohol
Layer.
3-899
5- J 99
6-334
7.119
Aq.
Layer.
6.0795
8.099
10.170
"555
Alcohol
Layer.
2.302
3.069
3-739
4.202
Aq.-
Layer.
3-588
4-779
6.000
6.821
323 SUCCINIC ACIE
SOLUBILITY OP SUCCINIC ACID IN AQUEOUS ACETONE AT 20.
(Herz and Knoch Z. anorg. Chem. 41, 320, '04.)
cc. Acetone per C 4 H 6 O 4 per ipo cc. Solution. cc. Acetone per CJIeO* per too cc. Solution
100 cc. Solution. Millimols. Grams. ' 100 cc. Solution. Millimols. Grams.
o 107.8 6.363 60 275.7 l6 -27
10 127.4 7.519 70 278.5 16.44
20 155-8 9.194 80 265.3 15.66
3O 186.7 II O2 90 2OI-9 11.91
40 225.4 13.30 loo 51.5 3.04
So 254.3 15.01
SOLUBILITY OP SUCCINIC ACID IN AQUEOUS GLYCERINE
SOLUTIONS AT 25.
(Herz and Knoch Z. anorg. Chem. 45, 268, '05.)
Wt.%
Glycerine
4^04 per 100 cc.
Solution.
Sp. Gr.
of
Wt.%
Glycerine
4^04 per 100 cc.
Solution.
Sp. Gr.
of
in Solvent.
Millimols.
Grams.
Solutions.
in Solvent.
Millimols.
Grams.
Solutions.
O
133
4
7
.874
I
O2I3
40
95
105 ..8
6.244
I .II2Q
7-15
128
.2
7
.566
I
0407
48
.70
99-9
5.896
I .1208
20-44
118
3
6
.982
I
.0644
69
.20
88.5
I . 1804
31-55
109
7
6
.476
I
.0897
IOO
.00*
74.6
4.440
I-2530
* Sp. Gr. of Glycerine 1.2555. Impurity about 1.5 per cent.
SUCCINIMID C 2 H 4 <>NH.
SOLUBILITY IN WATER AND IN ETHYL ALCOHOL.
Interpolated from original results. (Spey ers - Am. j. Sci. [ 4 ] 14, 204 , '02 .,
In Water. In Ethyl Alcohol.
t. Wt. of i cc. Mols. per Gms. per 100 Wt.oficc. Mols.penoo Gms. per 10
Solution. loo Mols. H 2 O. Gms. H 2 O. Solution. Mols.CjjHsOH. Gms.CtH 6 OH
o 1.025 1.58 8.69 0.815 0.88 1.89
10 1.035 2.4 14.0 0.809 1.35 2.7
20 1-052 4-0 23.0 0.8o6 2.00 4-1
25
30
40
50
60
70
80
.067 5.9 33.0 0.805 2.5 5.3
.086 8.0 45.0 0.804 3.1 6.8
.120 12.8 70.0 0.809 4.9 10.5
145 17.8 96.0 0.816 7.8 16.0
.167 22.6 124.0 0-835 12.3 26
.189 27.5 152.0 0.873
.204 32.8 0.954
SUCCINIC NITBIL (Ethylene Cyanide) CNCH 2 CH 2 CN.
The solubility of succinic nitril in water and also in aqueous sodium
chloride solutions at various temperatures has been determined by
Schreinemaker (Z. physik. Chem. 23, 439, '97), and the results
presented in terms of mols. of nitril per 100 mols. of nitril + H 2 O.
The following calculation of these results to gram quantities was
made by Rothmund. (Landolt and Bornstein, 3d ed. p. 596, '06.)
Gms. CNCH 2 CH 2 CN per 100 Gms. Gms. CNCH 2 CH 2 CN per 100 Gms^
Aq. Layer. Nitril Layer. . Aq. Layer. Nitril Layer.
18.5 10.2 92.0 53.5 33-2 66.4
20 ii. o 91.5 55 40-3 62.8
39 85 .2 55 .4 (crit. temp.) 51 .o
45 22.0
SUGAR 324
SUGAR C 12 H 22 O n (Cane Sugar.)
SOLUBILITY IN WATER.
(Herzfeld Z. Ver. Zuckcrind. 181, '92; see also Courtonne Ann. chim. phys. [5] 12, 569, '77.)
Cms. dzH-BOn per t*. Cms. QaHuOu per
ioo Gms. 100 Gms.
Solution. Water. Solution. Water.
o 64.18 179-2 40 70.42 238.1
5 64.87 184.7 45 7i-3 2 248-7
10 65.58 190-5 50 72.25 260.4
15 66.33 I 97- 74-i8 287.3
20 67.09 203.9 7 76.22 320.4
25 67.89 211.4 80 78.36 362.1
30 68.70 219.5 90 80. 61 415-7
35 6 9-55 228 -4 ioo 82.97 487-2
6p. Gr. of sat. solution at 15 = 1.329; at 25 = 1.340.
SOLUBILITY OP SUGAR IN AQUEOUS SALT SOLUTIONS AT 30, 50.
AND
Interpolated from original results.
AND 70.
t.
30
?f
It
tt
tt
to
it
(Schukow Z. Ver. Zuckerind. so, 313, 5 oo.)
Gms. Ci2H22Oii per ioo grams EfeO in Aq. Solution of:
<jms. oaii per
ioo Gms. HaO.
KC1.
KBr.
KNO 3 .
NaCl.
CaCl 2 .
219.5
219.5
219.5
219.5
219.5
10
216
218
217
210
197
20
221
220
216
211
I8 9
30
228
224
216
219
192
40
237
228
217
233
2OO
50
218
250
218
60
269
243
260.4
260.4
260.4
260.4
260.4
10
26l
262
260
255
239
20
266
266
261
260
228
30
274
272
262
269
228
40
284
2 7 6
262
284
236
50
296
280
263
302
253
60
276
320.5
320.5
320.5
320.5
320.5
10
326
324
321
323
295
20
334
328
324
330
286
30
345
334
327
344
286
40
357
34i
331
361
295
50
370
349
334
384
308
00
384
357
337
406
327
3*5
SUGAR
SOLUBILITY OP CANE SUGAR IN SATURATED AQUEOUS SALT
SOLUTIONS AT 31.25.
(KShler Z. Ver. Zuckerind. 47, 447, '97.)
Gms. Sugar per 100 Gms.
Salt.
CH 3 COOK
C 3 H 7 COOK
C 3 H 4 .OH.(COOK) 3
K 2 CO,
KC1
CI^COONa
NaCl
SOLUBILITY OP CANE SUGAR IN
(Scheibler Ber. 5, 343, '72;
Results at o.
Solution.
Water.
324-8
49.19
306.1
50-30
303-9
56.0
265.4
62.28
246.5
59-93
237.6
62.17
236-3
Salt.
Solution.
Na 2 C0 3 64.73
KNO 3 61.36
K 2 S0 4 66.74
CH 3 COOCa 60.12
Na 2 SO 4 52.20
CaCl 2 42.84
MgSO 4 46.52
Gms. Sugar per xooGms-
Water.
229.2
224-7
219.0
190.0
I83-7
119.6
AQUEOUS ALCOHOL SOLUTIONS.
correction Ber. 24, 434, '91.)
Results at 14. Results
Per cent
Alcohol
by Vol.
Sp. Gr.
of Solution
at 17.5.
Gms. Sugar Sp. Gr.
per 100 cc. of Solution
Solution. at 17.5.
Gms. per 100 cc. Solution.
V ^.^ .
Gms. Sugar
per 100 cc.
Solution.
Sugar. CaHsOH.
H 2 0/
I-325
85
.8 1.326
87
5
o
45
.10
10
1.299
80
7
.300
81
5
3-
9 1
44
.82
95-4
20
1.236
74
.2
.266
74
5
8.
52
43
83
90.0
30
I .229
65
5
233
67
9
13-
74
.87
82.2
40
I.I82
56
7
.185
58
.0
20-
24
40
38
74-9
50
I .129
45
9
.131
47
.1
28.
13
38
.02
63-4
60
1.050
32
9
.058
33
9
37-
64
34
47
49-9
70
0.972
18
.2 0.975
18
8
46.
28
29
57
80
0.893
6
4 0.895
6
6
61.
15
21
95
J 3-3
90
0.837
.7 0.838
9
71 .
18
12
83
2-3
97-4
0.8o6
o
08 0.808
o
36
77-
39
3
.28
o-5
SOLUBILITY OP CANE SUGAR IN AQUEOUS ALCOHOL SOLUTIONS AT 14.
(Schrefeld Z. Ver. Zuckerind. 44, '971 '94.)
Wt.
per cent
AlcohoL
O
5
10
20
30
40
Wt. Gms. Sugar per 100 Wt.
per cent cc. Alcohol-HjO per cent
Sugar. Mixture. Alcohol.
Wt. Gms. Sugar per 100
per cent cc. Alcohol-H2O
Sugar. Mixture.
66.2
195.8
So
38.55
62.7
64.25
179.7
60
26.70
36.4
62.20
164.5
70
12.25
13-9
58-55
141 .2
80
4-05
4.2
54-05
II7.8
90
o-95
0.9
47-75
9 s -3
IOO
o.oo
o.o
loo gms. absolute methyl alcohol dissolve 1.18 grns. sugar at 19.
(de Bruyn Z. physik. Chem. 10, 784, '92.)
SOLUBILITY OP SUGARS IN PYRIDINE AT 26.
(Holty J. Physic. Chem. 9, 764, '04-)
Gms. Sugar pe
100 Gms. Soluti
6-45
2.18
7.62
Sugar.
Cane Sugar
Milk Sugar
Grape Sugar
Formula.
CjjHjjOy
C 12 H 22 11 .H 2
C 8 H 12 O..H 2
Jjer
Uon.
Sp. Gr. of
utions.
Sp.
Soh
0.9811
I.052I
SUGAR 326
SOLUBILITY OF CANE SUGAR IN AQUEOUS ACETONE AT 25.
(Herz and Knoch Z. anorg. Chem. 41, 322, '04.)
c r . cc. Acetone Cms. Sugar Cms. per too cc. Solution.
Solutions. P- "' 5! --
1.3306 o.o 89.8 43-3 - 8 9- 8
1.2796 20-0 76.7 42.9 8.4 76.7
1.2491 30.0 72.1 39.5 13-4 7 2 - 1
1.2002 40-0 59.3 39-8 20-9 59.3
1.1613 45-o 5 2 -5 39-o 2 4-6 52.5
Above 45 cc. acetone per 100 cc. solvent the solution begins to
separate into two layers. The lower of these contains 51 gms. sugar
per 100 cc. and has Sp. Gr. 1.1522. The upper layer contains so
little sugar that the amount could not be determined by the method
employed. 100 cc. evaporated in a vacuum desiccator left a residue
of 3.68 gms. Above the concentration of 80 cc. acetone per 100 cc.
solvent the two layers unite. In pure acetone 100 cc. solution give
a residue of 0.18 gram sugar.
SOLUBILITY OF GRAPE SUGAR IN WATER AND IN AQ. ALCOHOL.
100 gms. H 2 O dissolve 81.68 gms. C 6 H 12 O 6 or 97.85 gms. C 6 H 12 O 6 .H 2 O
at 15.
100 gms. aq. alcohol of 0.837 Sp. Gr. = 85 wt. per cent dissolve
1.95 gms. C 6 H 12 O 6 at 17.5.
100 gms. aq. alcohol of 0.880 Sp. Gr. = 66 wt. per cent dissolve
8.10 gms. C 6 H 12 O 6 at 17.5.
100 gms. aq. alcohol of 0.910 Sp. Gr. = 53 wt. per cent dissolve
16.01 gms. C 6 H 12 O 6 at 17.5.
100 gms. aq. alcohol of 0.915 Sp. Gr. = 51 wt. per cent dissolve
32.50 gms. C 6 H 12 O 6 at 17.5.
SOLUBILITY OF MILK SUGAR IN WATER AND IN ABSOLUTE METHYL
ALCOHOL.
100 gms. H 2 O dissolve 17.03 gms. C 12 H 22 O U .H 2 O at 10, 20.8 gms.
at 25 (U. S. P.), 40 gms. at 100, and 100 gms. at b. pt.
100 gms. abs. methyl alcohol dissolve 0.084 gm. at 19.5.
(de Bruyn Z. physik. Chem. 10, 784, '92.)
SULPHANILIC ACID NH 2 .C 6 H 4 SO 3 H.
SOLUBILITY IN WATER.
(Dolinski Ber. 38, 1836, '05.)
Gms. Acid per 100 Gms. Gms. Acid per 100 Gms.
Solution. Water. Solution. Water.
o 0-64 0-64 60 3-oi 3-io
10 0.83 0.84 70 3.65 3.78
20 1.07 I. 08 80 4.32 4.51
30 1.47 i-49 90 5-25 5-54
40 i-94 i-97 100 6.26 6.67
50 2.44 2.51
327
SULPHUR
SULPHUR S
SOLUBILITY IN:
Tin Tetra Chloride.
(Gerardin Ann. chim. phys. [4] 5, 134, '65.)
Amyl Alcohol.
(Gerardin.)
99
101
Gms. S
per 100 Gms.
SnCl 4 .
5-8
6.2
Solid
Phase.
Solid S
a
95
1 10
Gms. S
per ioo Gms.
C 5 H U OH.
i-S
2.1-2.2
Solid
Phase.
Solid S
tt
no
112
8.7-9.1
94-9-9
it
Liquid S
112
120
2.6-2.7
Liquid S
121
17.0
"
I 3 I
5-3
"
SOLUBILITY OF SULPHUR IN ETHYL AND METHYL ALCOHOLS.
18.5
b. pt.
18.5
Alcohol.
Abs. Ethyl
Abs. Methyl
Gms.
per loo Gms.
Alcohol.
0.051
0-053
0.42
0.028
Authority.
(Pohl.)
(de Bruyn Z. physik. Chem. 10, 781, '92.)
(Payen Compt. rend. 34, 356, '52.)
(de Bruyn.)
SOLUBILITY OF SULPHUR IN AQUEOUS ACETONE AT 25.
(Herz and Knoch Z. anorg. Chem. 45, 263, '05.)
Wt. per cent
Acetone
in Solvent.
100
90.62
85-38
Sulphur per 100 cc.
Solution.
Millimols.
65.0
45-o
33-o
25-3
Grams.
2.084
1.442
1.058
O.SlI
Sp. Gr.
of
Solution.
0.7854
0.79II
0.8165
0-8295
SOLUBILITY OF SULPHUR IN BENZENE AND IN ETHYLENE Di
BROMIDE.
(Etard Ann. chim. phys. [7] 2, 571, '94; see also Cossa Ber. i, 139, '68.)
In C 6 H.
'
Gms. S
Gms. S
t.
per loo Gms.
t.
per loo Gms.
Solution.
Solution.
O
1.0
70
8.0
10
i-3
80
10.5
20
i-7
90
13-8
25
2 .1
IOO
17-5
30
2-4
no
23.0
40
3-2
120
29.0
50
4-3
130
36.0
60
6.0
In C 2 H 4 Br 2 .
Gms. S
Gms. S
t.
per ioo Gm:
5. t.
per ioo Gms.
Solution.
Solution.
o
I .2
50
6. 4
IO
1-7
60
8. 4
20
2-3
70
If .4
25
2.8
80
16.5
30
3-3
90
24.0
40
4-4
IOO
36.5
loo gms. sat. solution of S in benzoyl chloride, C 7 H 7 C1, contain
i gram S at o and 55.8 gms. at 134.
(Bogousky J. Soc. Phys. Chim. R. 37, 93, '05.)
SULPHUR 328
SOLUBILITY OP SULPHUR IN CARBON BISULPHIDE.
(Etard Ann. chim. phys. [7] 2* 571, '94; Cossa Ber. i, 138, '65; at 10, Retgers Z. anorg. Chem
3. 347t '93; below 77, Arctowski Ibid, n, 274, f 9S'-96.)
Gms. S perjtoo Gms. c Gms. S per ioo Gms. Gms. S per ioo Gms.
Solution. CSa Solution. CS2. Solution. CSj.
no 3.0 3.1 10 13.5 15-6 50 59.0 143-9
ioo 3.5 3.6 o 18.0 22.0 60 66.0 194.1
80 4.0 4.2 10 23.0* 29.9 70 72.0 257.1
6 3-5 3- 6 20 29.5 41.8 80 79.0 376.1
- 40 6.0 6.4 25 33.5 50.4 90 86.0 614.1
20 10.5 11.7 30 38.0 61.3 ioo 92.0 1150.0
40 50.0 loo.o
26.4 R.
Sp. Gr. of solution saturated at 15 containing 26 gms. S per ioo
gms. solution 1.372.
SOLUBILITY OF SULPHUR IN HEXANE (C,H 14 ).
(Etard.)
t o Gms. S per t o Gms. S per t o Gms. S per
ioo Gms. Solution. ioo Gms. Solution. ioo Gms. Solution.
20 0.07 60 i.o 130 5.2
o 0.16 80 1.7 140 6.0
20 0.25 ioo 2.8 160 7.2
40 0.55 120 4.4 180 8.2
SOLUBILITY OF SULPHUR IN SEVERAL SOLVENTS.
(Cossa Ber. I, 139, '68; Retgers; Cap and Garot J. pharm. chim. [3] 26, 81 '54; Kleven Chem.
Centralb. 434, '72.)
Solvent. t. ^* ms - o per Solvent. t.
C 6 H 5 NH 2 130 85.3 C 6 H 5 CH3 230 1.48
CHC1 3 22 i. 21 CH 2 I 2 10 io.o(R.)
(C 2 H 5 ) 2 23.5 0.97 C 10 H 4 N 2 * ioo 10.58
C 6 H 5 OH 174 16.35 C 5 H3(OH) 3 ord. t. 0.05-0.1 (C. and G.)
* Nicotine.
SOLUBILITY OF SULPHUR IN COAL TAR OIL, LINSEED OIL AND
IN OLIVE OIL.
(Pelouze Compt. rend. 68, 1179, '69; 69, 56, '69; Pohl.)
Grams S per ioo Grams Coal Tar Oil of: G S per 100 Gms
t o Sp.Gr.: 0.87
0.88
0.882
0.885 i -oi
1.02 Linseed VL- 1 / 6 *
' b. pt.: 8o-ioo. 8s -i2o.
1 20- 2 20.
. I50-200
. 2IO-300
. 220-;
too .
Oil ' 0.885 Sp.Gr.
15
2.1
2-3
2-5
2
.6
6.0
7-
O
O
4
23
30
3-o
4-0
5-3
5
.8
8-5
8.
5
O
.6
4-3
50
5-2
6.1
8-3
8
7
IO-O
12 .
I
.2
9.0
80
ii. 8
13-7
15.2
21
o
37-o
41.
o
2
.2
18.0
IOO
15.2
18.7
23.0
26
4
52-5
54-
o
3
O
25.0
1 10
23.0
26.2
3 1
.0
105 .0
5
o
3
5
30.0
120
27.0
32.0
38
.0
00
00
37-o
I 3
...
38-7
43
.8
oo
00
5
.6
43-o
(
160'
>) 10
.0
ioo gms. oil of turpentine dissolve 1.35 gms. S at i6,and 16.2 gms.
at b. pt. (Payen Compt. rend. 34. 356, '52.)
329
SULPHUR DIOXIDE
SULPHUR DIOXIDE SO 2 .
SOLUBILITY IN WATER.
(Schonfeld Liebig's Ann. 95, 5, '55
Sims Ibid. 118, 340, '6x; Roozcboom Rec. trav. chim. 3.
Schonfeld.
Vols. SOa (at o and Qms. SO 2 per
760 mm.) per i Vol. IOO Qms, HaO
Sims.
SOa per i Gm. H,O.
Roozeboom.
SO 2 Dissolved
per i pt. H 2
t. Sat. S0 2
+ Aq.
HaO.
total pressure t .
760 mm.
Gms.
Vols.
t . at 760 mm.
pressure.
O
68
.86
79
79
22
83
8
0.168
58.7
0.236
5
59
.82
67
.48
19
31
10
0.154
53-9
2
0.218
IO
5 1
38
56
65
16
.21
14
0.130
45-6
4
O.2OI
I 5
43
56
47
.28
13
54
20
0.104
3 6 -4
6
0.184
20
36
.21
39
37
II
.29
26
0.087
30-5
7
0.176
25
77
32
79
9
.41
30
0.078
27-3
8
0.168
30
25
.82
27
.16
7
.81
36
0.065
22.8
10
0.154
35
21
23
22
49
40
0-058
2O-4
40
17
.01
18
77
5
.41
46
0.050
17.4
12
O.I42
50
0.045
I5 .6
Sp.
Gr. of sat. solution
at
-
1.061
o/-\
; at 10,
1-055;
at 20
i
= 1.024.
rv
i gm. H 2 O dissolves 0.0909 gm. SO 2 = 34.73 cc. (measured at 25)
at 25 and 748 mm. pressure.
(Walden and Centnerszwer Z. physik. Chem. 42, 462, 'oi-'oa .
SOLUBILITY OP SULPHUR DIOXIDE IN SULPHURIC ACID OP
1.84 SP. GR.
Interpolated from original results.
(Dunn Chem. News, 45, 272, '82.)
Sp. Gr.
Coefficient
Sp. Gr.
Coefficient
t e .
of Sat.
Solution.
of Absorp-
tion (760 mm.).
t.
of Sat.
Solution.
of Absorp-
tion (760 mm
o
. . .
53-o
50
1. 8l86
9-5
10
1.8232
35-o
60
1.8165
7.0
20
1.8225
25.0
70
I.8I40
5-5
25
I.822I
21.0
80
1.8112
4-5
30
I.82I6
18.0
90
I .8080
4-0
40
1.8205
13.0
SOLUBILITY OF SULPHUR DIOXIDE IN AQUEOUS SULPHURIC ACID
SOLUTIONS.
(Dunn; see also Kolb Bull. soc. ind. Mulhouse 222, '72.)
Sp. Gr. of Approximate Coefficient
t . HsSO* Per cent of
Sp. Gr. of
t. H 2 S0 4
Approximate Coefficient
per cent of
Solution
H 2 SO 4 . Absorption.
Solution.
HaSO 4 . Absorption
6. 9
i
T 39
20
48
67
15
.2
173
25
3 1
.82
6. 9
i
.300
40
45
38
16
.8
.151
21
3 1
56
8.6
i
.482
58
39
9 1
14
.8
277
36
30
.41
9.8
i
703
78
29
03
15
.1
458
56
29
.87
5-5
i
.067
10
36
78
15
.6 ']
.609
70
25
17
6.0
i
.102
X 5
3.408 15
O 3
739
81
20
83
For Coefficient of Absorption, see Ethane page 133.
SULPHUR DIOXIDE 330
SOLUBILITY OF SULPHUR DIOXIDE IN AQUEOUS SALT SOLUTIONS.
(Fox Z. physik. Chem. 41, 461, '02.)
Pesults in terms of the Ostwald Solubility Expression. See page 105.
Aqueous Solubility Coefficient I of SO 2 in aq. Solutions of Concentrations:
ilt Solution.
0.5 Normal
1.0 N. 1.5
N.
2.0 N.
2.5 N.
3.0 N.
NH 4 C1
'25=34
58
36
37
38
.06
39
76
41
37
42.78
NH 4 Br
'25=36
25
39
.46
42
78
46
.06
49
52-25
NH 4 CNS
'25 = 37
.78
42
74
47
.26
5 2
.26
57
.01
61.46
NH 4 N0 3
'25 = 33
.96
35
.07
36
.28
37
.27
38
.01
39-14
NH 4 N0 3
'35=23
35
24
23
24
.78
25
57
26
.66
27-43
(NH 4 ) 2 S0 4
'25 = 33
35
33
.82
34
33
34
95
35
47
35 -96
(NH 4 ) 2 S0 4
'35=22
.91
23
.14
23
49
23
93
24
23
24.60
CdCl 2
.66
30
55
29
.46
28
.16
27
.09
26.06
CdCl 2
'35=21
73
21
23
20
55
20
.02
19
23
18.68
CdBr 2
'25 = 31
.91
31
.01
30
29
.27
28
15
27.46
CdBr 2
'35=21
.88
21
.46
2O
.81
20
.60
19
.70
19.17
CdI 2
'25 = 33
27
33
76
34
.16
34
74
34
.98
35-77
CdI 2
'35=22
75
23
.06
23
36
23
23
99
24.30
CdS0 4
'25=3!
.11
29
.71
28
.24
26
58
25
.14
23.76
CdSO 4
'35=21
45
20
43
19
.42
18
3 1
17
.41
16.25
KC1
'25 = 34
.42
36
05
37
76
39
32
40
.96
42.27
KC1
'35=23
74
25
26
54
27
94
28
93
30.02
KBr
'25=35-94
39
.11
42
.41
44
.96
48
87
52.26
KBr
'35=24
83
27
49
29
.64
3 1
93
34
.12
36.14
KCNS
'25=37
57
42
38
47
.02
5 1
.81
55
.87
6 1 .26
KCNS
'35=25
63
28
79
32
03
35
05
38
42-94
KI
'25 = 38
.66
44
76
58
56
75
62
63
68.36
KI
'35=26
3 30-25
34
.64
38
.04
41
.8 7
45-43
KNO 3
'25=33
.80
34
79
35
77
36
.66
37
57
38-52
KN0 3
'35=23
.27
24
03
24
79
25
72
26
54
27-33
K 2 SO 4
/,.= 77
.20
77
.61
2*~* v^ 4
NaBr
25 OO
'25=33
76
OO
34
54
35
27
36
.26
36
.84
37-74
NaCl
'25=32
.46
32
25
.96
.76
3 1
5 1
NaCNS
'25=35
44
38
.24
40
78
43
37
45
.86
48.34
Na 2 S0 4
'25=3!
.96
.14
30
45
29
5 1
28
.66
28.44
Na 2 S0 4
'35=21
.88
21
35
20
.81
20
.21
19
75
19.27
SOLUBILITY OF SULPHUR DIOXIDE IN ALCOHOLS AND IN OTHER
SOLVENTS.
(de Bruyn Rec. trav. chim. n, 128, '92; Schulze J. pr. Chem. [2] 24, 168, '81.)
In Ethyl Alcohol In Methyl Alcohol In Several Solvents
at 760 mm. at 760 mm. at o and 725 mm. (S.)
to Gms. S(\per 100 Gms. Gms. SO 2 per 100 Gms. Solvent SC^per i Gm. Solvent.
Solution. CjjHsOH. Solution. CH 3 OH.' Grams. Vols. '
o 53.5 115.0 71.1 246.0 Camphor 0.880 308
7 45.0 81 .o 59.9 149.4 CH 3 COOH 0.961 318
12.3 39.9 66.4 52.2 109.2 HCOOH 0.821 351
18.2 32.8 48.8 (17. 8) 44.0 78.6 (CH 3 ) 2 CO 2.07 589
26.0 244 32.3 31.7 46.4 SO 2 C1 2 0.323 189
33 1
SULPHUR DIOXIDE
DISTRIBUTION OF SULPHUR DIOXIDE AT 20 BETWEEN:
(McCrae and Wilson Z. anorg. Chem. 35, n, '03.)
Water and Chloroform.
Aq. HC1 and Chloroform.
Gms. SOa per
Liter in:
Gm. Equiv. iSOj
per Liter in:
Cone.
Gms. SOz per
Liter in:
Gm. Equiv. $SOj
per Liter in:
Aq.
Layer.
CHC1 3
Layer.
Aq.
Layer.
CHC1 3
Layer.
of
HC1.
Aq.
Layer.
CHClg
Layer.
Aq.
Layer.
CHCl,"
Layer.
I-738
I
.123
0-0543
O
035 1
O.O5
1.86
1.46
O
.0581
0-0456
i-753
I
.122
0.0547
O
0350
3-07
2.8 3
O
.0960
0.0884
2.346
I
703
0.0732
O
0532
II
4.28
4-07
I 33 6
O.I27I
2.628
I
.897
O.O82I
O
.0592
tt
5-34
5-42
.1667
0.1692
3-058
2
385
0-0955
0745
o.io
1.25
1.41
039
0-044
3-735
3
.062
0.1166
.0956
It
2.78
3-o8
.0868
o . 0962
4.226
3
.626
0.1319
.1132
(t
3-86
4-08
O
.1199
0.1275
5.269
4
.798
0.1645
.1498
tt
5.161
5-72
O
.1612
0.1784
6.588
6
I8 3
0.2057
O
.1930
0.2
1.268
i-5i
.0396
0.0471
31.92
33
.84
0.9968
I
056
tt
1.914
2.27
O
0597
0.0710
33-26
37
25
1.038
I
163
it
2.464
3-04
.0769
0.0949
tt
3-967
4.90
.1239
0.1530
0-4
i .202
1.61
.038
0-0504
tt
1.894
2.26
O
059
O.O7O6
TANNIC ACID C 13 H 9 O 7 COOH.
100 gms. H 2 O dissolve about 294 gms. at 25*
dissolve about 439 gms. at 25.
100 gms. alcohol
(U.S. P.)
TAETAEIC ACID C 2 H 2 (OH) 2 (COOH) 2 .
SOLUBILITY IN WATER.
(Leidie Compt. rend. 95, 87, '82.)
*. Grams Tartaric Acid per 100 Gms. KfeO. t. Gms. Tartaric Acid per 100 Gms. H 2 O.
'
Dextro
Racemic
Racemic
Dextro
Racemic
Racemic
and Laevo
Ac.
Ac.
and Laevo
Ac.
Ac.
Acids.
Anhydrous.
Hydrated.
Acids.
Anhydrous.
Hydrated
o
115.04
8.16
9 23
5o
195.0
5-
59-54
10
125.72
12.32
14.00
60
217-55
64.52
78.33
20
139-44
18.0
20.60
7o
243.66
80.56
99-88
25
147.44
21.4
24.61
80
273-33
98.12
124.56
30
156.2
25.2
29.10
90
306.56
117.20
I52-74
40
176.0
37-o
43-32
100
343-35
137.80
184.91
SOLUBILITY OF TARTARIC ACID IN ALCOHOL AND IN ETHER
AT 15.
(Bourgoin Ann. chim. phys. [5] 13, 405, '78.)
Gms. Tartaric Acid per 100 Gms.
Solvent - Sat. Solution. Solvent.
Absolute Alcohol 20 - 385 41 . 135
90% Alcohol 29 . 146 25 .604
Absolute Ether 0.389 0.40
TELLURIUM Te.
100 gms. methylene iodide CH 2 I 2 dissolve o.i gm. Te at 12.
(Retgers Z. anorg. Chem. 3, 340, '93
TELLURIC ACID
33*
TELLURIC AOID H,TeO 4 . 2 H 3 O.
SOLUBILITY IN WATER.
(Mylius Ber. 34, 2208, '01.)
f.
Cms.
HjTeO 4
penoo
Mols,
H 2 TeO 4 per Solid
100 Mols. Phase.
t.
Gms.
H a Te0 4
per 100
Mols.
HTe0 4 per Solid
xoo Mob. Phase.
Cms. Sol.
HaO.
Gms. Sol.
HjO.
13.92
1.51 H 2 TeO 4 .6HjO
30
33-36
4.67 HaTeCVaHaO
5
17.84
2.03
40
36.38
5-33
10
26.21
3-31
60
43-67
7-04
IS
32-79
4.41
80
51-55
9-93
IO
25.29
3.15 H 2 TeO 4 .aH 2 O
100
60.84
14-52
18
28.90
3-82
1 10
67.0
19.0 "
TELLURIUM DOUBLE SALTS
SOLUBILITY OP TELLURIUM DOUBLE BROMIDES AND CHLORIDES
IN AQUEOUS HYDROCHLORIC AND HYDROBROMIC ACIDS
AT 22.
(Wheeler Z. anorg. Chem. 3, 432, '93.)
Tellurium Double Salt.
Formula.
Solvent.
Gms. Double Salt per 100
Gms. Solvent
Te Caesium Bromide TeBr 4 .2CsBr Aq. HBr
Te Potassium Bromide TeBr 4 .2KBr
Te Rubidium Bromide
Te Caesium Chloride
Te Rubidium Chloride
TeBr 4 . 2 RbBr
TeCl 4 . 2 CsCl Aq. HC1*
TeCl 4 . 2 RbCl
* Sp. Gr. of Aq. HC1 solutions 1.2 and 1.05 respectively.
THALLIUM ALUMS
of i.4QSp.Gr.
of i .08 Sp. Gr.
0.02
0.13
6-57
62.90
0.25
3-88
0.05
0.78
o-34
13.09
Alum.
SOLUBILITY IN WATER AT 25
(Locke Am. Ch. J. 26. 174, f oi.)
Salt per TOO Grams HjO.
Formula.
Tl Aluminum Alum
Tl Vanadium Alum
Tl Chromium Alum
Tl Iron Alum
Gms.
Gms.
Gm.
Anhydrous.
Hydrated.
Mols.
7-5
11.78
0.0177
25-6
43 -3 1
0.0573
IO.48
16.38
0-0212
36-I5
64.6
0.0799
TlAl(S0 4 ) 2 .i 2 H 2
TlV(SO 4 ) 2 .i2H 2 O
TlCr(S0 4 ) 2 . I2 H 2
TlFe(S0 4 ) 2 .i 2 H 2
THALLIUM BROMATE TlBrO 3
One liter saturated aqueous solution contains 3.463 gms. TIBrOj at 19.96
(B.), and 7.355 gms. at 39.75 (N. and A.).
(Bottger Z. physik. Chem. 46, 602, '03; Noyes and Abbott Ibid. 16, 132, '95.)
THALLIUM BROMIDE TIBr
One liter saturated aqueous solution contains 0.42 gm. TIBr at 18,
0.476 gm. at 20, 0.57 gm. at 25, and 2.467 gms. at 68.5.
(Kohlrausch Z. physik. Chem. 50, 356, '04; Noyes Ibid. 6, 248, '90; Bottger.)
SOLUBILITY OF TIBr IN AQ. SOLUTIONS or T1NO 8 AT 68.5. (Noyes.)
Gram Molecules per Liter. Grams per Liter.
0.0163 T1NO!
0.0294 "
0.0955 "
0.00410 TIBr
0.00289 "
0.00148 "
4.336 T1NO,
7.820 "
25-400
i . 164 TIBr
0.821 "
0.420 "
333 THALLIUM CHLORATE
THALLIUM CARBONATE AND THALLIUM (Per) CHLORATE.
THALLIUM CHLORATE T1C1O*.
(See p. 338.)
SOLUBILITY IN WATER.
(Muir J. Chem. Soc. 29, 857, '76.)
20
50'
8o<
ioo c
Gms. T1C1O 3 per ioo gms. H^O 2.80 3.92 12.67 3 6 - 6 5 57
SOLUBILITY OP MIXED CRYSTALS OF THALLIUM CHLORATE AND
POTASSIUM CHLORATE IN WATER AT 10.
(Roozeboom Z. physik. Chem. 8, 532, '91.)
NOTE. Solutions of the two salts were mixed in different pro-
portions and allowed to crystallize, such amounts being taken that
not more than one or two grams would separate from one liter.
Grams per 1000 cc.
Solution.
Mg. Mols. per 1000 cc. Sp. Gr.
Solution . o f
Mol. per cent
KC10 3 in Mixed
TlClOa.
KC10 3 .
T1C10 3 .
KC1O 3 . Solutions.
Crystals.
25
637
8 9
.14
. .
1. 0210
19
637
6
.884
68
27
56
15 1.0222
2
.0
12
.001
26
.100
41
73
212
.89 1.0278
12
.61
9
036
40
.064
3 1
.42
326
79
0338
25
.01
7
7
.885
935
46
46
497
535
27
27
.42
.60
379
379
26 ]
57 J
0359 1
-0360 J
' 3 6 -30-97
93
6
.706
46
.410
23-32
378
55
0357
99
.28
6
729
47
.109
23
37
384
25 i
0363
99
.60
4
.858
47
.312
16
.89
385
.91 3
0345
99
.62
2
.769
47
9
63
384
.46 ]
0330
99.67
49
925
407
.22 ]
0330
IOO
.00
SOLUBILITY OF MIXED CRYSTALS OF THALLIUM CHLORATE AND
POTASSIUM CHLORATE IN WATER AT DIFFERENT
TEMPERATURES.
(Quoted by Rabe Z. anorg. Chem. 31, 156, '02.)
ioo gms. H 2 O dissolve 2.8 gms. T1C1O 3 + 3.3 gms. KC1O 3 at o.
ioo gms. H 2 O dissolve 10.0 gms. T1C1CX -f- 1 . 5 gms. KC1O 3 at 15.
ioo gms. H 2 O dissolve 12.67 gms.,TlC!O 3 + 16.2 gms. KC1O 3 at 50.
ioo gms. H 2 O dissolve 57.3 gms. T1C1O, + 48.2 gms. KClO,at 100.
THALLIUM CHLORIDE T1C1.
SOLUBILITY IN WATER.
(Average curve from results of Noyes Z. physik. Chem. 9, 609, '92; Bottger Ibid. 46, 602, '03; Kohl-
rausch Ibid. 50, 350, '04; Hebberling; Crookes; Lamy The results of Berkeley Trans. Roy.
Soc. (Lond.) 203 A, 208, '04 are also given.)
t o Gms. T1C1 per +
Liter.
o 2.1 (av.) 1.7 (B.) 25
10 2.5 2.4 30
20 3.3 3.4 40
50
Gms. T1C1 per .<>
Gms.
T1C1
per
Liter.
Liter.
3
.86
4
.0
60
8
.0
10
.2
4
.2
4
.6
80
12
o
16
-0
5
.2
6
.0
IOO
18
.0
24
.1
(99-3)
6
3
8
.0
THALLIUM CHLORIDE 334
THALLIUM CHLORIDE T1C1.
SOLUBILITY IN WATER AND IN AQ. SALT SOLUTIONS AT 25.
(Noyes; Noyes anji Abbott; Geffcken Z. physik. Chem. 49, 296, '04.)
Aq. salt aoiuuon.
Salt.
T1C1.
'Salt.
T1C1.
Ammonium Nitrate NIL^NOj
0-0
o. 01612
o.o
3-86i (G.)
M
o-5
0.02587
40.02
6.209
%l
I.O
O.O3I2I
80.05
7-473
"
2.0
0-03966
160.10
9-497
Barium Chloride BaClj
0.0283
0.00857
5-895
2.052 (N.)
o . 1468
0.00323
30-59
0-773
Cadmium Sulphate CdSC4
0.030
O.O2O6
6-255
4-933 (N.)
"
0-0787
0.0254
16.41
6.081
"
0.1574
0.0309
32.82
7-399
Hydrochloric Acid HC1
0-0283
0.00836
1.032
2-002 (N.)
"
0.0560
0.00565
2.043
1-353
||
0.1468
0.00316
5-357
0-757
Lithium Nitrate LiNOs
o-5
O.O2542
34-53
6.085(0.)
"
I.O
0-03035
69.07
7.266
w
2-O
0-03785
138.14
9.063
"
3-
0.04438
207.21
10 . 630
Potassium Chlorate KClOa
o-5
0.0237
61.28
5-674 (G.)
Potassium Nitrate KNOs
0.015
O.OI7O
i-5i7
4.070 (N.)
"
0.030
0.0179
3-033
4.286
M
0-0787
0.0192
7-775
4-597
it
0-1574
O-O2I2
15.920
5.076
M
o-5
0.0257
50-55
6-153(0.)
(t
I.O
0.0308
IOI.II
7-375
"
2.O
0.0390
202.22
9-340
Sodium Acetate CHsCOONa
0-015
0.0168
I.23I
4-023 (N.)
"
0.030
0.0172
2.462
4.118
"
0-0787
0.0185
6. 4 6
4-43
0-1574
0.0196
12.92
4-693
Sodium Nitrate NaNO,
o-5
0.02564
42.50
6.139 (G.)
"
i .0
0.03054
85.01
7-3I3
M
2-0
0.03851
170.02
9.221
"
3-o
0.04544
255-03
10.88
It
4.0
0.05128
340.12
12.28
Sodium Chlorate NaClOj
o-5
0.02320
53-25
5-555 (GO
'*
1.6
0.02687
106.5
6-433
M
2-0
0.03060
213.0
7.326
M
3-o
0-03303
3I9-5
7.909
**
4-0
0.03850
426.0
9.215
Thallium Bromate TIBrOi (at 39.75*) O .01567
0-01959
5 201
4.690 (N.andA.)
Thallium Nitrate TINOi
0.0283
0.0083
7.518
1.987 (N.)
"
0-0560
0.00571
14.89
1.368
"
o . 1468
0-00332
39.05
0-795
Thallium Sulphate TUSQi
0.0283
0.00886
14.27
2. 121 (N.)
"
0.0560
0.00624
28.23
1-494
Thallium Sulphocyanide TiSCN
Sat.
0.0119
Sat.
2.849(N.)
* <t 39-75)
0.02149
0.01807
5.504
4. 3 26 (N.andA.)
335
THALLIUM CHLORIDE
SOLUBILITY OP THALLIUM CHLORIDE IN AQUEOUS SOLUTIONS OP
SALTS AT 25.
(Noyes Z. physik. Chem. 9, 609, '92-)
Aa. Salt ,
Gram. Equiv. per Liter.
Grams, per Liter.
Grams per Liter.
Solution. gait.
T1C1.
Salt.
T1C1.
Salt.
T1C1. '
NH 4 C1 o.
NH4ClorHCl O.
01613
0.00 NH4C1 1.
861
0.
00
HC1 3
.861
and
alsoo.
025
0.
00873
1.338
2.
101
0.
886
2
.0
HC1
0.
05 0.00589
2.676
I.
421
I.
772
I
.402
0.
10
0.
00384
.
3-
545
.920
0.
20
0.
00262
10. 704
O.
649
7.090
" 0.608
CuCl 2
o.
025
CuCl 2 or CaCl 2 0.
00902
3.36
CuCl 2 2.
161
3-
77
CaCl 2 2
.161
and
alsoo.
05
" O.
00619
6. 7 2
I.
483
7-
55
44 I
.483
CaCl 2
o.
10
0.
00419
" I.
003
ii
4S I
.003
0.
20
41 o.
00287
26.90
O.
688
3-
22
.687
MgCl 2
0.
025MgCl 2 orMnCl20.
00901
2-381
MgCla 2.
158
3-
147
MnCl 2 2
.158
and
alsoo.
05
0.
00618
4.763
" I.
480
6.
295
44 I
.480
MnCl 2
0.
10
" o.
00412
9.526
0.
987
12.
59
.987
0.
20
0.
00278
19.052
44 O.
666
25.
18
O
.666
KC1
0.
025
KClorNaCl O.
00871
1.86
KC1 2.086
I.
46
NaCl 2
.086
and
alsoo.
05
0.
00592
3.73
I.
418
2.
925
I
.418
NaCl
0.
IO
O.
00397
7.46
" 0-951
5-
85
"
.951
0.
20
14 o,
00268
14.92
0.
642
ii.
70
44 0.642
T1C1O
3 0.
025TlClO3orTlN030.
00889
5.276
T1C10 3 2.
129
4-
74
T1NO 3 2
.129
and
alsoo.
05
o.
00626
.
9-
48
I
.500
T1NO 3 o.
IO
0.
00423
...
.
18.
96
44 I
.014
ZnCla
o.
025
ZnCla 0.
00899
3.41
ZnCl 2 2.
!53
0.
05
0.
00627
6.81
44 I.
502
o.
IO
O.
00412
13.63
0.
987
0.
20
0.
00281
27.26
0.
673
CdCl 3
0.025
CdCl 2 0.
0104
4.53
CdCl 2 2.
491
0.
5
0.
0078
9.16
" I,
868
o.
10
0.
00578
18.33 " 1.385
0.
20
" 0.
00427
36.66
I.
029
One liter of water dissolves 2.7 gms. thallo thallic chloride 3T1C1.T1C1,
at i5-i7, and 35.0 grams at 100.
(Crookes; Lamy; Hebberling.)
THALLOUS CHEOMATE Tl 2 CrO 4 .
100 gms. H 2 O dissolve 0.03 gm. Tl 2 CrO 4 at 60, and 0.2 gm. at 100.
(Browning and Hutchins Z. anorg. Chem. 22, 380, 'oo.)
One liter of aq. 31 per cent KOH solution dissolves 18 grams Tl 2 CrO 4 .
(Lepierre and Lachand Compt. rend. 113, 196, '91.)
One liter of H 2 O dissolves 0.35 gram Thallous Tri Chromate
Tl 2 Cr s O 10 at 15, and 2.27 grams at 100.
(Crookes.)
THALLOUS CYANIDE 336
THALLOUS CYANIDE T1CN and Double Cyanides.
SOLUBILITY IN WATER.
(Fronmuller Ber. n, 92, '78.)
Cyanide. Formula. Cms. Salt per xoo Gms. HjO,
Tl Cyanide T1CN at 28.5, 16.8
Tl Cobalti Cyanide Tl 3 Co(CN) 6 at o, 3.6 ; at 9.5, 5.86 ; at 19.5, 10.04
Tl Zinc Cyanide 2TlCN.Zn(CN) 2 at o, 8.7 ; at 14, 15.2 ; at 31, 29.6
Tl Ferro Cyanide Tl 4 Fe(CN) 6 .2H 3 O at 18, 0.37 at ioi 5 , 3.93.
(Lamy.)
THALLOUS FLUORIDE TIP.
100 gms. H 2 O dissolve 80 gms. TIP at 15.
(Buchner Sitzb. K. Akad. Wiss. (Wein) 52, a, 644, '65.)
THALLIUM IODATE T1IO 3 .
One liter aq. solution contains 0.578 gram T1IO 3 at 20.
(Bottger Z. physik. Chem. 46, 602, '03.)
THALLIUM IODIDE Til.
SOLUBILITY IN WATER.
(Average results from Bottger; Kohlrausch; Werther; Crookes; Lamy; Hebberling.)
t . o. 20. 40. 60. 80. 100.
Gms. Til per liter 0.02 0.06 0.15 o-35 0.70 1.20
One liter of 2$ per cent aq. ammonia dissolves 0.761 gm. T1C1.
One liter of 6J per cent aq. ammonia dissolves 0.758 gm. T1C1.
One liter of 90 per cent alcohol dissolves 0.0038 gm. T1C1.
One liter of 50 per cent alcohol dissolves 0.027 gm. T1C1.
(Long J. Anal. Ch. 2, 343, '88.)
THALLIUM NITRATE T1NO 3 .
SOLUBILITY IN WATER.
(Berkeley Trans. Roy. Soc. (Lond.) 203 A, 213, '04; see also Etard Ann. chim. phys. [7] a,
527, '94; Crookes; Lamy.)
t.
Gms. T1N0 3
per 100 Gms.
t.
Gms. T1NO 3 per 100 Gms.
Solution.
Water.
Solution. Water.
O
3-76
3-9 1
60
3 I -SS 46.2
10
5.86
6.22
70
41.01 69.5
SO
8. 72
9-55
80
52.6 m.o
30
12.51
14-3
90
66.66 200. o
40
17-33
20.9
IOO
80.54 414.0
50
2 3-33
3-4
io5
8S-59 594-o
Solid phase. T1NO 3 rhombic.
loo gms. H 2 O dissolve 43.5 gms. T1NO 3 4- 104.2 gms. KNO 3 at 58.
(Rabe Z. anorg. Chem. 31, 156, '02.)
THALLIUM OXALATE T1 2 C 2 O 4 .
One liter of saturated aqueous solution contains 15.77 grams
T1 2 C 2 O 4 at 20, and 18.69 m s. at 25.
(Bottger Z. physik. Chem. 46, 602, '03; Abegg and Spencer Z. anorg. Chem. 46, 406, '05.)
337
THALLIUM OXALATE
SOLUBILITY OF THALLIUM OXALATE AT 25 IN AQ. SOLUTIONS OP:
Thallium Nitrate.
(Abegg and Spencer.)
Potassium Oxalate.
(A. and S.)
Mol. Concentration.
Grams per Liter. Mol. Concentration.
T1N0 3 .
O-O
O.O4II4
0.0799
0-1597
T1 2 C 2 O 4 . T1NO 3 .
0.03768 o.oo
O.O2O4
O-OI95
0.01235
10-95
21.26
42.51
T1 2 C 2 4 .
18.69
13.10
9-68
6.128
K 2 C 2 4 .
0-0498
0-0996
o . 2467
0.4886
0.9785
T1 2 C 2 4 .
0-0351
0-03565
0-0390
0.04506
Grams pjer Liter.
K 2 C 2 O 4 . T1 2 C 2 4 ."
8.28l 17.42
16.57
41 .02
81.25
0-05536 162.6
17.69
19.36
22.37
27.48
THALLOUS PHOSPHATE (ortho) T1 3 PO 4 .
One liter of sat. aqueous solution contains 4.97 gms. T1 3 PO 4 at 15
and 6.71 gms. at 100. (Crookes.)
THALLIUM PICRATE T1OC 6 H 2 (NO 2 ) 3 .
SOLUBILITY IN WATER.
(Rabe Z. physic. Chem. 38, 179, '01.)
Gms.
Gms.
to
T1OC6H 2 (NO 2 ) 3 Solid
t
T10C6H 2 (NO 2 ) 3 Solid
.
per 100 Phase.
* .
per 100
Phase.
Gms. H 2 0.
Gms. HO 2 .
o
O . 135 Monoclinic Red
45
1.04
Triclinic Yellow
18
0.36
47
1. 10
"
3o
o-575
50
I .205
u
40
0-825
60
i-73
"
45
I .01
70
2-43
"
47
1.14
"
zoo gms. H 2 O dissolve 0.132 gm. C 6 H 2 (NO 2 ) 3 OT1 + 0.36 gram
C 6 H 4 (NO 2 ) 3 OK at o.
100 gms. H 2 O dissolve 0.352 gm. C 6 H 2 (NO 2 ) 3 OT1 4- 0.44 gram
C 6 H 4 (N0 2 ) 3 OKati 5 .
100 gms. H 2 O dissolve 0.38 gm. C 6 H 2 (NO 2 ) 3 OT1 + 0.23 gram
C 6 H 4 (NO 2 ) 3 OK at 20 . (Rabe.)
SOLUBILITY OF THALLIUM PICRATE IN METHYL ALCOHOL.
(Rabe.)
Solid
t.
Gms.
T1OC6H 2 (NO2) 3 Solid
Gms.
t. T10C6H 2 (N0 2 ) S
per 100 Phase.
per too
Gms. CHaOH.
Gms. CHaOH.
o
O. 39 Red Form (monodinic).
45
.195
18
0-59
48
.265
25
0.70
50
325
30
0-795
53
.41
35
0.00
57
54
40
1 . 02
60
65
45
I. 17
65
.84
47
1.265
Yellow Form (triclinic).
THALLIUM SULPHATE 338
THALLIUM SULPHATE T1 2 SO 4 .
SOLUBILITY IN WATER.
(Berkeley Trans. Roy. Soc. (Lond.) 203 A 211, '04; see also Crookes; Lamy.)
Gms. T1 2 SO 4 per 100
Gms. T1 2 SO 4 per 100
t*. Gms. t.
Gms.
Solution.
Water.
Solution.
Water.
2.63
2.70
60
9.89
10.92
10
3-57
3-70
70
II .31
12.74
2O
4.64
4-87
80
12-77
I4.6l
30
6.16
90
14.19
16 -53
SO
8^44
9-21
99-7
15-57
18.45
100 gms. H 2 O dissolve 4.74 gms. T1 2 SO 4 + 10.3 gms. K 2 SO 4 at 15.
100 gms. H 2 O dissolve 11.5 gms. T1 2 SO 4 + 16.4 gms. K 2 SO 4 at 62.
100 gms. H 2 O dissolve 18.52 gms. T1 2 SO 4 + 26.2 gms. K 2 SO 4 at 100.
(Rabe Z. anorg. Ch. 31, 156, '02.)
THALLIUM SULPHIDE T1 2 S
One liter of sat. aqueous solution contains 0.215 gm. T1 2 S at 20.
(Bottger Z. physic. Chem. 46, 602, '03 )
THALLIUM DOUBLE SULPHATES
SOLUBILITY IN WATER AT 25.
(Locke Am. Ch. J. 27, 459, '01.)
Salt per too cc. H 2 O.
Double Sulphate. Formula.
Gms. Anhydrous. Gram Mols.
Tl Copper Sulphate Tl 2 Cu(SO 4 ) 2 .6H 2 O 8.1 0.0122
Tl Nickel Sulphate Tl 2 Ni(SO 4 ) 2 .6H 2 O 4-61 0.007
Tl Zinc Sulphate Tl 2 Zn(SO 4 ) 2 .6H2O 8.6 0.0129
THALLIUM SULPHOCYANIDE T1SCN.
SOLUBILITY IN WATER AND IN AQUEOUS SALT SOLUTIONS.
(Bottger; Noyes; Noyes and Abbott.)
One liter sat. aq. solution contains 3.154 gms. T1SCN at 20, 3.905 gms.
at 25, and 7.269 gms. at 39.75.
Aq. Salt Solution. f. G. Mols. per Liter. Grams per Liter.
Salt. T1SCN. Salt. T1SCN.
Thallium Chloride T1C1 25 sat. O.OIO7 Sat. 2 . 805 (N.)
Thallium Bromate TIBrOi 39-75 0.014960.0221 4.966 5 . 793 (N. and A.)
Thallium Nitrate TINOi 25 O.O227 0.00852 6.04 2 . 233 (N.)
25 0.0822 0.00406 21.88 1.064
Potassium Sulphocyanide, KSCN 25 O.O227 0.0083 2 . 208 2 . 176 (N.)
THALLIUM CARBONATE T1 2 CO 3 .
SOLUBILITY IN WATER.
(Crookes; Lamy.)
t 15.5 18 62 100 100.8
Gms. T1 2 CO 3 per 100 gms. H 2 O 4.2(0.) 5.23 12.85 27.2(0022.4
THALLIUM (Per) CHLORATE T1C1O 4 .
100 grams H 3 O dissolve 10 gms. T1C1O 4 at 15, and 166.6 gms. at 100.
(Roscoe J. Chem. Soc. 19. 54. '66.)
339 THALLIUM SULPHITE
THALLIUM SULPHITE T1 2 SO 3 .
100 gms. H 2 O dissolve 3.34 gms. T1 2 SO 3 at 15.5.
(Seubert and Elken Z. anorg. Chem. 2 434, 'pa.)
THALLIUM VANADATES.
SOLUBILITY IN WATER.
(Carnelly J. Chem. Soc. [2] n, 323, '73-, Liebig's Ann. 116, 155, '60.)
Vanadate. Formula Gms. Vanadate per too Gms. H 2 O.
At 15. At 100.
Tl. meta Vanadate T1VO 3 0-087(11) 0.21
" ortho Vanadate T1 3 VO 3 i.o 1.74
" pyro Vanadate T1 4 V 2 O 7 0.20(14) 0.26
" Vanadate T1 12 V 8 O 28 0.107 0.29
THEOBROMINE C 5 H 2 (CH 3 ) 2 N 4 O 2 .
ioo gms. carbon tetra chloride dissolve 0.0212 gm. at b. pt.
ioo gms. ether dissolve 0.032 gm. at b. pt.
(Gockel Chem. Centralb. ii, 401, '97.)
80 cc. H 2 O containing 14.8 gms. tri sodium phosphate dissolve
3.5 gms. theobromine at 15.
(Brisse-Moret J. pharm. chim. [6] 7, 176, '98.)
THORIUM SELENATE Th(SeO 4 ) 4 .9H 2 O.
ioo gms. H 2 O dissolve 0.498 gm. Th(SeO 4 ) 4 at o and 1.972 gms.
at 100.
(Cleve Bull. Soc. chim. [2] 43. 166, '85.)
THORIUM SULPHATE Th(SO 4 ) 2 .
SOLUBILITY IN WATER.
(Roozeboom Z. physic. Chem. 5, 201, '90; Demarcay Compt. rend. 96, 1860, '83.)
Solid
Gms. Th(SO 4 ) 2
per
Solid
t.
Gms. Th(SO 4 )
2 per
'
ioo Gms.
HzO.
Phase.
ioo Gms. H 2 U.
O
o
74(R)
.88(D)
Th(S0 4 ) 2 . 9 H 2
O
I
R)
10
o
.98
I
.02
"
15
I
63
20
I
38
I
25
"
30
2
45
30
I
995
I
85
"
45
3
85
40
2
998
2
83
"
60
6
64
5o
5
22(51)
4
.86
"
17
9
.41 (D)
55
6
.76
6
5
"
40
4.04(R)4
5(35D
o
i
o
Th(S0 4 ) 2 .8H 2
50
2
54
i
94
(55)
15
i
38
60
I
63
2 5
i
85
H
70
I
.09
i
32
(75)
44
3
71
M
95
o
7 1
Th(S0 4 ) 2 .6H 2
TIN CHLORIDE 340
- ;"
TIN CHLORIDE (Stannous) SnCl 2 .
100 gms. H 2 O dissolve 83.9 gms. SnCl 2 at o and 269.8 gms. at 15,
Sp. Gr. of Solutions 1.532 and 1.827 respectively.
(Engel Ann. chim, phys. [6] 17, 347, '89; Michel and Krafft Ibid. [3] 41, 478,' 51.)
SOLUBILITY OF STANNOUS CHLORIDE IN AQUEOUS SOLUTIONS OF
HYDROCHLORID ACID AT o.
(Engel.)
Milligram Mols. per 10 cc. Sp. Gr.
Grams per ioo cc.
Solution. of
Solution.
HC1.
iSnCl,.
HC1.
SnCl 2 .
74-o
532
0-0
70.26
6.6
66.7
.489
2.405
6 3-33
13-54
63.75 3
.472
4-935
60.52
24.8
68.4
524
9.04
64.95
34-9
81.2
.625
12.72
77.11
40.0
94.2
724
14.58
89-45
44.0
117.6
.883
16.04
111.7
49-4
147.6 2.114
18.01
138.6
66.0
156.4 2.190
24.05
148.5
78.0
157.0 2.199
28.43
149.0
100 gms. acetone dissolve 55.6 gms. SnCl 2 at 18.
(Naumann Ber. 37, 4332, '04.)
ioo gms. ether dissolve 11.4 gms. SnCl 2 .2H 2 O at o-35.5.
100 gms. ethyl acetate dissolve 31.2 gms. SnCl 2 .2H 2 O at 2, 35.53
gms. at +22 and 73.44 gniS. at 82. (von Laszcynski Ber. 27, 2285, '94.)
TIN HYDROXIDE Sn(OH) 2 .
SOLUBILITY IN AQUEOUS SODIUM HYDROXIDE SOLUTIONS. MOIST
TIN HYDROXIDE USED, ORDINARY TEMPERATURE.
(Rubenbauer Z. anorg. Chem. 30, 335, '02.)
Gms. per 20 cc.
Solution.
Mol.
Dilution of the
NaOH.
1.86
!-25
0.72
Gms. per 20 cc.
Solution.
Mol.
Dilution of the
NaOH.
o-55
0.48
0-23
O
O
Na.
.2480
.3680
6394
O
O
O
Sn.
.1904
.2614
4304
O
2
Na.
.8326
.9661
.1234
O
I
Sn.
5560
.7849
8934
TIN IODIDE (Stannous) Snl a .
SOLUBILITY IN WATER AND IN AQUEOUS HYDRIODIC ACID.
(Young J. Am. Chem. Soc. 19, 851, '97.)
t. Gms. Snl2 per ioo Gms. Aqueous HI Solutions of:
o% = H 2 O.
5-83%.
9-60%.
15.2%.
20.44%.
24.8%.
30.4%.
36.82%.
20
0.98
O-2O
0.23
0.60
1.81
4-20
10.86
2 5 -3 1
30
1.16
0.23
0.23
0.64
1.81
4-o6
10.28
23.46
40
1.40
o-33
0.28
0.71
i .90
4-12
10-06
23-15
50
i .69
0.46
0.38
0.82
2 .12
4-34
10-35
23.76
60
2 .07
0.66
o-55
i .11
2.51
4-78
11.03
24.64
70
2.48
0.91
0.80
i-37
2.92
5-43
11.97
25.72
80
2-95
1.23
i .13
1.83
3-70
6.38
I3-30
27.23
90
3-46
1-65
1-52
2.40
4.58
7.82
I5-52
29.84
IOO
4-03
2.23
2.04
3-63
5-82
9.60
34-05
341 TIN IODIDE
TIN IODIDE (Stannic) SnI 4 .
SOLUBILITY IN CARBON BISULPHIDE.
(Sneider Pogg. Ann. 127. 624, '66; Arctowski Z. anorg. Chem. xx, 274, '95.)
t e . -H4.S -94* -89 -84 -58 ord. temp.
* '' 6 5 9-68 io. x6., 7 S 9-a(S.)
ioo gms. methylene iodide, CH 2 I 3 , dissolve 22.9 gms. SnI 4 at 10.
Sp. Gr. of Solution 3.481.
(Retgers Z. anorg. Chem. 3, 343, '93.)
TIN SULPHATE (Stannous) SnSO 4 .
ioo gms. H 2 O dissolve 18.8 gms. SnSO 4 at 19 and 18.1 gms. at 100.
(Marignac.)
TOLUENE C 6 H 5 CH 3 .
SOLUBILITY IN SULPHUR.
Figures read f-om curve, synthetic method used, see Note, page 9.
(Alexejew Ann. Physik. Ch. 28, 305, '86.)
Gms. CeHgCHg per ioo Gms. Gms. CeHsCHa per ioo Gms
**' "~S Toluene * ' "~S Toluene
Layer. Layer. Layer. Layer.
ioo 3 73 150 12.5 59
no 4 71 1 60 16 53
120 5 68 170 22 47
130 7 66 175 25 43
140 9.5 63 178 crit. temp. 34
TOLUIC ACIDS (Monomethyl Benzoic Acids) CH 3 .C ( ,H 4 .COOH.
SOLUBILITY IN WATER AT 25.
(Paul Z. physik. Chem. 14, in, '94.)
CH 3 .C6H 4 .COOH per Liter Solution.
Acid - 'Grams. " Millimols".
Meta Toluic Acid o . 9801 7 . 207
Ortho Toluic Acid i .1816 8.683
Para Toluic Acid o . 3454 2 . 540
TOLUIDINE C n H 4 CH 3 .NH 2 .
SOLUBILITY IN WATER.
(Vaubel J. pr. Chem. [2] 52, 72, '95; Lowenherz Z. physik. Chem. 25. 4 IO \
Gms. Gms.
VJins.
Solid
CutLCHaNHj
Solid
* '
per 1000
Gms. H 2 O.
Phase.
"
per 1000
Gms. H 2 O.
Phase.
20
16.26
Liquid ortho T.
20.8
7-39
ParaT.
20
0.15
Ortho T.
26.7
9-50
"
20
6-54
ParaT.
31-7
11-42
H
TOLUIDINE 342
SOLUBILITY OF PARA TOLUIDINE IN ETHYL ALCOHOL.
(Interpolated from original results of Speyers Am. J. Sci. [4] 14, 295, '02.)
Wt.
Mols. per
Gms. per
t.
of i cc.
100 Mols.
100 Gms.
Solution.
CaHsOH.
C 2 H 6 OH.
o
0-8885
20-72
48.1
5
0-8982
26.0
6o-0
10
0.9080
32.0
74.0
15
0.9180
3 8.6
90.0
Wt.
Mols. per
Gms. per
t.
of i cc.
100 Mols.
100 Gms.
Solution.
C 2 H S OH.
C 2 H B OH.
20
0-9265
47-0
IIO-O
25
0-9360
56.0
132.0
30
o . 9460
66.0
156.0
Distribution of para Toluidine between water and carbon tetra
Chloride. (Vaubel J. pr. Chem. [2] 67, 478, '03.)
Gms. * Toluidin
Used.
I -O
1.0
Volumes of Solvents.
200 cc. H 2 O + ioo cc. CC1 4
200 CC. H-jO + 200 CC. CC1 4
Gms. CaH 4 (CH 3 )NH 2 p in:
H 2 Laye,-. CCU Layer.'
0.1406 0.8594
0.0666 0.9334
URANYL CHLORIDE UO 2 C1 2 . 3 H 2 O.
100 gms. H 2 O dissolve 320 gms. UO 2 C1 2 at 18.
(Mylius and Dietz Ber. 34, 2774, *oi.)
URANYL DOUBLE CHLORIDES.
SOLUBILITY OF URANYL AMMONIUM CHLORIDE, U. TETRA METHYL
AMMONIUM CHLORIDE, U. TETRA ETHYL AMMONIUM CHLORIDE,
U. CAESIUM CHLORIDE, U. RUBIDIUM CHLORIDE, AND U. POTAS-
SIUM CHLORIDE IN WATER.
(Rimbach Ber. 37, 463, '04.)
Formula of
Double Salt.
UO 2 C1 2 .2NH 4 O.2H,O
Gms. per 100 Gms. Sat. Solution. Atomic Relation in Sol.
Solid
Phase.
i Mol. double salt
U02 C1 2 . 2 N(CH3) 4
29.8
19.85 " -
- 10.4402
= 41 -24 *
iUO 2
4.020
Double salt
**
80.7
20.23 " ~
- I0.52C1 2
= 4-9i *
iU0 2
3-98O
U0 2 O 2 .2N(C 2 H5) 4 O
27.1
80.7
15x22 " -
15.12 " -
- 7-8i0 2
- 7-78O 2
= 37.15 1
== 37.231
iUO 2
iUO 2
3-97C1
3-94O
UOzO^Csd
U0 2 O 2 .2RbC1.2H 2
29-75
24.8
22.11
27.18
- 22.5 Cs
1 6.6 Rb
= 56.04 1
+ i3.80
iUO 2
iUO 2 :
i-96Rb
3.900
UO 2 O 2 .2KO.2H 2 O
80.3
0.8
30.66
38.57
- 19.1 Rb
- 13-590
- I5-8O ||
- 3.86K
iUO 2 -
iUO 2 :
i.oSRb
2.690 .
3-95O
"
14-9
33-71
-i3-5iO
- ...K
iUO 2 :
3-o60
iio6K
The double salt
17-5
37.36
- 14.500
- 5.27K
iU0 2 :
2.o60 :
o g6 K
is decomposed
250
35-01
- 15-260
- ...K
iUO 2 :
3.33O :
I-33K
" by water at
4i.5
35.27
-15.920
- 7-39K
iUO 2 :
3-44O :
I.44K
temperatures
SO
34-18
- i6. S 6O
- ...K
iUO 2 :
3-7iO :
i.TiK
below 60.
60
34-19
- 17-250
- 9-1 4K
iU0 2 :
3-850 :
i.SsK
7 I- 5
33-55
17.440
- 9-28K
iUO 2 :
3-960 :
i.gbK Double salt
78.5
35-26 " H
- l8.2 4 O
+ 9-95K
iUO 3 :
3.95O :
I-95K
* UOaCl 2 .2N(CH s ) 4 0, t
= 57-9 gms. UO 2 Cl 2 .2RbO 2 ,
= 65.8 gms.
343 URANYL SODIUM
OHROMATE
URANYL SODIUM CHROMATE 2 (UO 2 )CrO 4 .Na 2 CrO 4 .ioH 3 O.
ioo gms. sat. aqueous solution contains 52.52 gms. (2UO 2 ).CrO4.
Na 2 CrO 4 at 20. (Rimbach.)
URANYL POTASSIUM BUTYRATE UO 2 (C 4 H 7 O 2 ) 2 -KC 4 H 7 O 2 .
The double salt is decomposed by water at ordinary temperatures
and the solution gets richer in uranyl butyrate. The solubility at
29.4 in water containing KC 4 H 7 O 2 is 2.10 gms. UO 2 (C 4 H 7 6 2 ) + 0.38
gms. KC 4 H 7 O 2 per ioo gms. solution. The atomic relation being i : 0.64.
(Rimbach.)
URANYL NITRATE UO 2 (NO 3 ) 2 .6H 2 O.
SOLUBILITY IN WATER, ETC.
(Bucholz; de Coninck Compt. rend. 130, 1304, 'oo.)
ioo gms. cold water dissolve 200 gms. UO 2 (NO 3 ) 2 .6H 2 O.
ioo gms. abs. alcohol dissolve 333 gms. UO 2 (NO 3 ) 2 .6H 2 O.
ioo gms. 85% alcohol dissolve 3.3 gms. UO 2 (NO 3 ) 2 .6H 2 O at 12 (de C.)
ioo gms. ether dissolve 25 gms. UO 2 (NO 3 ) 2 .6H 2 O.
ioo gms. abs. acetone dissolve 1.5 gms. UO 2 (NO 3 ) 2 .6H 2 O at 12 (de C.)
For densities of Uranium nitrate solutions in water and other
solvents see de Coninck Compt. rend. 131, 1219, 'oo.)
URANYL DOUBLE NITRATES.
SOLUBILITY OF URANYL AMMONIUM NITRATE, U. CAESIUM
NITRATE, U. POTASSIUM NITRATE, AND U. RUBIDIUM
NITRATE IN WATER.
(Rimbach.)
Formula of
t.
Gms. per ioo Gms.
Sat.
Solution. Atomic Relation
Salt.
UO* Total Salt. 1U ^ UU011 -
U0 2 (N0 3 ) 2 -NH 4 N0 3 0.5
29.71 +
2.92]
^1
J 4 =
... iU0 2 :i. 4 7NH 4
;3-47N0 3
24.9
36.46 +
3-54
zz
68.95
:i. 4 6 "
3-46
"
44-37 +
2.90
zz
: 0.98 "
:
2.98
"
"
807
44-95 +
2.98
"
zz
78-95
: i .00 "
3.00
"
U0 2 (N0 3 ) 2 .CsNCX
16.0
3I-39 +
6.59 Cs =
55-4
:o. 4 4Cs
U0 2 (NO,) 8 .KNO,
o-5
31.98 +
1.72
K
=
:2-37N0 3
-37
K
13.0
33-40 +
2.72
=
. . .
= 2-57
:
-57
'
25.0
37.07 +
4.01
*z=
64.82
: i. 60
:
0.76
1
42.t8 +
5.16
zz
. . .
: 2 .8 4
:
0.84
*
5Q.o
41-65 +
6.03
"
=
. . .
:3-oo
:
I.OO
1
"
80.6
43-7i +
6.38
zz
...
13.01
:
1. 01
1
UO 2 .(NO 3 ) 2 .RbNO 3
25.0
i
35-41 +
4.65]
*l
>f=
59.60
1 : 1-40
:
0-45
Rb
"
80.0
34.66+11.01
= 69.49 ' : 3-o
*
1. 01
'*
+ 23-5N03.
t + I9-74NO3.
URANYL AMMONIUM PROPIONATE 2 UO 2 (C 3 H 5 O 2 ) 2 .NH 4 C 3 H 5 O 2 .
2H 2 O and Uranyl Potassium Propionate 2UO 2 (C 3 H 6 O 2 ) 2 .KC 3 H 6 O 2 .
(Rimbach.)
ioo gms. aq. solution contain 16.48 gms. 2UO 2 (C 3 H 5 O 2 ) 2 .NH 4 C 3 H,O 2
at 29.8.
IQ-J gms. aq. solution contain 2.362 gms. UO 2 (C 3 H S O 2 )2 + 0.82 gm.
KC 3 H C O 2 at 29.4, atomic relation, 1:1.29.
TTRANYL SULPHATE 344
UEANYL SULPHATE (UO) 2 SO 4 . 3 H 2 O.
SOLUBILITY IN WATER, ETC.
(Buchdz; de Coninck Bull. Acad. Roy. Belgique, 350, p oi.)
ioo gms. H 2 O dissolve 16.6 gms. UO 2 (SO 4 ).3H 2 O at 13.2, 17.4 gins,
at 15.5, and 22.2 gms. at b. pt.
ioo gms. abs. alcohol dissolve 4.0 gms. UO 2 (SO 4 ).3H 2 O at 18.2
and 5.0 gms. at b. pt.
100 gms. 85% alcohol dissolve 2.6 gms. UO 2 (SO 4 ).3H 2 O at 16.
ioo gms. 16.2% alcohol dissolve 12.3 gms. UO 2 (SO 4 )-3H 2 O at 10.
URANYL POTASSIUM SULPHATE UO 2 SO 4 .K 2 SO 4 .2H 2 O
ioo gms. sat. aq. solution contain 10.41 gms. UO 2 SO 4 .K 2 SO 4 at 25
and 23.13 gms. at 70.5. (Rimbach.)
SOLUBILITY OF UO 2 SO 4 .2K 2 SO 4 . 2 H 2 O + UO 2 SO 4 .K 2 SO 4 .2H 2 O IN WATER.
Gms. per ioo Gms. Solution. Atomic Relation in Sol. Mol. % in Solid Phase.
t .
U0 2 .
K.
SO 4 .
UO S
. K.
S0 4 .
Mono Salt.
Di Salt.
14
0.85
4.19
5-71
I
35-75
18.88
29
7 1
50
6.70
8.1 5
12.37
I
5.20
8.40
7 6
24
80
14.29
8-54
15-53
I
4-13
306
12
88
UREA CO(NH 2 ) 2 .
SOLUBILITY IN WATER AND IN ALCOHOLS.
(Campetti Abstract, Z. physic. Chem. 41, 109, '02; Speyers Am. J. Sci. [4] 14, 259, '02.)
NOTE. Speyer's original results are in terms of Mols. CO(NH 2 ) 2
per ioo Mols. H 2 O at irregular temperatures.
In Water. In Methyl Alcohol. In Ethyl Alcohol.
. o Wt. of i cc.
* ' Solution.
Gms. CO(NH 2 ) 2 per w t . of i cc.
ioo Gms. H 2 O. Solution.
Gms.
CO(NH 2 ) 2
XT ioo Gms.
Gms.
Wt. of ice. CO(NH 2 ) 2
Solution, per ioo Gms
CH 3 OH.
(J 2 H 5 UH.
.121
55-9
0-861
138
0.8213
2 -5
10 !
134
66.0
8s'o(C)
0.863
16.0
0.8l4
3-5
2O 1
.I 4 6
79.0
io8.2(C)
0.869
20. o
0-809
5-o
30 3
.156
93-o
. . .
0.876
24.0
0.8o6
6-5
40
.165
106.0
. . .
0.890
30-0
0.804
8-5
50
173
I2O-O
. . .
0.908
37-o
0.803
10.5
60 I.lSo
132.0
0.928
47-0
13.0
70 1.187
145.0
J 7-5
ioo gms. abs. methyl alcohol dissolve 21.8 gms. CO(NH 2 ) 2 at 19.5.
ioo gms. abs. ethyl alcohol dissolve 5.06 gms. CO(NH 2 ) 2 at 19.5.
(de Bruyn Z. physic. Chem. 10, 784, '92.)
ioo gms. glycerine dissolve 50 gms. urea at 15.5.
Phenyl Thio UREA (Phenyl thio carbamide) CS.NH 2 .NHC 8 H 6 .
SOLUBILITY IN WATER.
(Rothmund Z. physic. Ch. 33, 406, 'oo; Biltz Ibid. 43, 42, '03; Holeman and Antusch Rec. tray,
chim. 13, 200, '94; Bogdan Ann. Scien. L'Univ. Jassy 2, 43, '02. '03.)
One liter aq. solution contains 2.12 gms. CS(NH 2 ).NHCH 6 at 20
(B.), (R.) and 2.4 gms. at 25. (H. and A.). Bogdan gives 2.547 gms
at 25.
345
Phenyl Thio UREA
SOLUBILITY OF PHENYL THIO UREA IN AQUEOUS SALT
SOLUTIONS AT 20.
(Biltz; Rothmund.)
Mfflimols and also Cms. CS(NH 2 )NHC8He Dissolved per Liter of Aqueous
Salt Solution of Concentration:
Salt
0.125 Normal
0.25 Normal
o.s Normal
I.O Normal
Solution.
Millimols
. Cms.
Millimols.
Cms. Millimols.
Gms.
Millimols.
Cms.
iA!CI 3
12
95
1-97
12.82
I .96
12
03
1.8 3
10
.69
1.61
NH 4 NO 3
14
*7
2.15
14.4
2 .21
14
53
2.22
14
.91
2.27
i(NH 4 ) 2 S0 4
*3
5 1
2.05
12.84
1.96
II
.78
1.79
9
.98
1.52
BaCl 2
13
12
1-99
12.92
1.97
12
.22
1.86
10
44
x -59
JBa(NO,) 2
13
9 8
2.13
I 3 . 9 8
2.13
13
-90
2.12
CsN0 3
14
53
2 .21
14.90
2.27
15
23
2-33
. . .
LiN0 3
13
96
2.13
13.96
2.13
J 3
93
2 .12
*3
73
2.10
iMgS0 4
13
40
2.04
12.78
i-95
ii
54
75
9
43
i-43
KC 2 H 3 O 2
13
40
2 .04
12-95
1-97
12
.14
85
10
74
1.62
KBr
13
5o
2.05
13-35
2 .04
12
.80
95
ii
.76
1.79
KC10 3
13
86
2. II
13 .60
2.O6
13
.12
99
.
KC1
J 3
40
2.04
12-73
i-94
12
.19
85
IO
54
i .60
Kl
14
12
2.15
14.48
2.21
14
31
2.18
14
.60
2.23
KNO 3
I 3
8 9
2.12
I3-85
2. II
13
52
2.05
12
.82
i .96
KNO 2
14
5 2
2 .21
14.65
2.23
13
.80
2. II
12
5i
i .92
iK 2 S0 4
13-25
2.03
12-49
I.9I
II
.11
I .69
8
73
*-33
RbNO 3
14
22
2.l6
14.44
2.19
14
39
2.18
14
.22
2.17
iNa 2 C0 3
J 3
.29
2.O4
12.52
I.9I
II
05
1.68
8
58
1.32
NaClO 3
13
75
2.09
J 3- 6 5
2.08
13
.07
1.98
12
.21
1.86
NaC10 4
14
i5
2.15
14.05
2.14
13
58
2.06
12
56
i .92
NaCl
I 3
28
2.02
12.83
i-95
II
.90
1.81
IO
.02
1.52
Nal
13
98
2-13
14.07
2.14
14
.29
2.18
13
.96
2.13
NaNO 3
!3
94
2 .12
13-77
2 .IO
13
32
2.04
12
57
i .92
NaNO 2
14
34
2.18
13.82
2. II
13
.06
1.98
II
52
J -75
}Na 2 S0 4
i3
.19
2.00
!2-35
1.87
IO
85
1-63
8
30
1.27
SOLUBILITY OF PHENYL THIO UREA AT 25 IN AQUEOUS
SOLUTIONS OF.
Potassium Nitrate.
Sodium Nitrate.
(Bogdan.)
(Bogdan.)
Gms. Mols.
KN0 3 per
Gms.
looo Gms
per
H 2 0.
Gms. Mols.
NaNOa per
Gms. per
looo Gms. HjO.
1000 Gms.
HaO.
KNO 3 .
CS(NH 2 )
.NHQjHs.
1000 Gms.
H 2 0.
NaNOa.
CS(NH 2 )
.NHQjHfi.
1.045
105-7
2.38
I .024
87.14
2 .26
0.5123
5I-84
2.48
0.5065
43-10
2.46
O.2O26
20.50
2-54
0.2031
17.28
2.51
0.1007
10.19
2 -56
0.0986
8-39
2-53
0.0503
5-09
2-55
0.0540
4-59
2-54
0-0333
3-36
2-55
0-0335
2.84
2-54
Phenyl Thio UREA
346
SOLUBILITY OF PHENYL THIO UREA IN MIXTURES OF ETHYL
ALCOHOL AND WATER AT 25.
(Holleman and Antusch Rec. trav. chim. 13, 290, '94.)
Cms.
Gms.
Vol.
per cent
CS(NH 2 )
NHQjHs
Sp. Gr.
of
Vol.
per cent
CS(NH 2 )
NHQHs
Sp.Gr.
of
Alcohol.
per 100 Gms.
Solutions.
Alcohol.
per 100 Gms.
Solutions.
Solvent.
Solvent.
ZOO
3-59
. . .
65
3-40
0.9018
95
4.44
0.8200
60
2.80
0-9128
90
4.69
0.8389
50
1.8 7
0.9317
85
4-99
0.8544
40
*-*3
0-9486
80
4.70
0-8679
25
0.56
0.9679
75
4-45
0.8810
15
0.38
0.9788
70
3-92
0.8915
O
0.24
0.9979
SOLUBILITY OF PHENYL THIO UREA IN AQUEOUS SOLUTIONS OF
PROPYL AND OF ETHYL ALCOHOL AT 25.
(Bagdan.)
G. Mols.
1000 Gms.
H 2 0.
0.5448
O.IO59
0.05526
0-04854
In Propyl Alcohol.
Gms. per 1000 Gms. H 2 O
C 3 H 7 OH.
62.10
32.688
6-354
CS(NH 2 )
NHCH 5 .
3.124
2.643
2-599
2.586
2.912
In Propyl Alcohol at o.
I -OOO 60-06 I. 21
o.ioo 6.01 1-047
In
G. Mols.
C 2 H 5 OH per
looo Gms.
H 2 0.
. Ethyl Alcohol.
Gms. per rooo Gms.H 2 O
C 2 HsOH.
CS(NH 2 )
NHCeHs-
I .1010
49.60
3- J 93
0-5355
o . 1094
0.05018
24.12
4-932
2.26
2.931
2 .629
2.589
0.03271
1-473
2-577
SOLUBILITY OF PHENYL THIO UREA IN AQUEOUS SOLUTIONS OF
ACETONE, MANNITE, CANE SUGAR, DEXTROSE, AND UREA.
(Bagdan.)
Aqueous
Non Electro-
to
Gms
. per looo Gms.
Aqueous
Non Electro- * o
Gms. per 1000 Gms.
H 2 0.
lyte.
Non Elec-
trolyte.
CS(NH 2 )
NH.CcHs.
lyte.
Non Elec-
trolyte.
CS(NH 2 )
NHCeHs.
(CH^CO
25
7
-478
2
.667
C 6 H 12 O fl 25
180
.40
3
.042
"
2
513
2
579
a ti
90
.46
2
83
"
ft
I
.908
2
573
tt n
29
.29
2
.69
C,H 8 (OH).
11
182
.11
3
.04
it ti
18
.01
2
654
tt
tt
91
05
2
.78
n it
9
554
2
.603
C^H^OH
25
338
.6
3
457
CCKNH,),
63
.08
3
.306
M
It
170
4
3
.015
" "
29
93
2
.892
"
((
34
36
2
634
a a
6
.132
2
.6l8
"
"
18
.28
2
-596
" "
4
.942
2
-60 5
"
tt
10
.09
2
572
n tt
2
.009
2
572
it
o
342
18
I
420
60
.11
I
.310
"
tt
34
.22
I
044
" "
6
.01
I
.048
347
URETHANE
URETHANE CO(NH 2 )OC 2 H 5 . SOLUBILITY IN SEVERAL SOLVENTS.
(Speyers Am. J. Sci. [4] 14, 294, '02.) See also Ethyl Carbamate, p. 138.
Interpolated and calculated from the original results which are
given in terms of molecules Urethane per 100 Mols. solvent.
Solubility in Water.
Solubility in Methyl Alcohol.
w* Mols.
Gms
/
\\Tt- ~t
Mols.
Gms.
CO(NH 2 )
CO(NH 2 )
Wt. ot
CO(NH 2 )
t.
lr OC 2 Hs per
ioo Mols.
OC 2 H 8 per
ioo Gms.
I CC.
Solu-
ioo Mols.
OC^per
ioo Gms.
Uon - H 2 0.
H 2 0.
tion.
CHaOH.
CH 3 OH.
o
.023 3.61
I 7 .8
0.956
31.18
86.76
10
.033 6.0
29.7
0-977
41.0
II4.I
15
.042 15.0
74-2
0.989
47-5
132.1
20
-060 31 -O
153-3
i .000
54-5
25
-073 50.0
247-3
1.013
62.5
173-9
30
.078 65.0
321.4
1.024
72.0
200-3
40
.065 77.0
380.7
1.045
89.0
247-7
Solubility in Ethyl
Alcohol.
Solubility
in Propyl
Alcohol.
w . nf Mols.
Gms.
TTfi -
Mols.
Gms.
i cc CO(NH a )
CO(NH 2 )
Wt. Ot
I CC.
CO(NH 2 )
CO(NH 2 )
t.
Solu- So^ScE*
ioo Gms.
Solu-
ioo Mols.
ioo Gms.
C 2 H 5 OH.'
tion.
CaH 7 OH.
o
0-8914 23.91
46.26
0.880
19.48
28.9
10
0-930 36.0
69.6
0.906
31-0
46.0
15
0.950 43-0
89.2
0-923
4O-O
59-3
20
0.968 50.0
96.7
0-942
51-0
75-7
25
0.985 59.0
II4.I
0-963
6o-0
89.0
30
I .001 70.0
135-4
0-983
68.0
100.9
40
1.035 88 -o
170.2
I .025
85.0
126.1
Solubility in Chloroform.
Solubility in Toluene.
..
Wf nf Mols.
Wt of C 0(NH 2 )
So 0( *&? er
Uon. X SJ8J?-
Gms.
CO(NH 2 )
OC 2 H, per
ioo Gms.
CHC1 3 .
Wt.of
I CC.
Solu-
tion.
Mols.
CO(NH 2 )
OC 2 H 6 per
ioo Mols.
Gms.
CO(NH 2 )
OCaH per
ioo Gms.
o
.404 27.56
20. 6
0.887
i 5 . 77
I.7I
10
.340 41
30.6
0-874
5-o
4-84
15
.310 46
34-4
0-875
10.0
9.68
20
280 53
39 6
0.883
16.0
15 -4 8
25
.240 60
44.8
0.902
25.0
24.18
30
.203 67
50.0
0-927
44.0
42.58
40
.125 80
59-7
o-995
85.0
82.24
URIC
ACID C 6 H 4 N 4 O 3 .
SOLUBILITY IN WATER.
(Blarez and Deniges Compt. rend. 104, 1847, '87; at 15 Magnier
483, '75.)
Bull. Soc. chim. [2] 23,
Gms. CsIL^N^Og.
Gms.
C 5 H4N 4 O3
Gi
us. GJLN^O
t*.
per ioo Gms.
t. per
ioo Gms.
t. per ioo Gms.
H 2 0.
H 2 O.
H^.
O.OO2
30 o
.0088
70
0-0305
10
0.0037
40 o
OI22
80
0.0390
*S
0.0053
50 o
.OI7O
90
0-0498
20
O.OO6
60 o
.0230
IOO
0-0625
VALERIANIO ACID 348
VALEBIANIO ACID n CH,(CH 2 ) 3 COOH ( Propyl acetic acid
Pentane acid) when shaken with water at 16 two layers are formed.
100 gms. of the aqueous layer contains 3.4 gms. CH 3 (CH 2 ) 3 COOH.
100 gms. of the acid layer contains 90.4 gms. CH 3 (CH 2 ) 3 COOH.
(Lieben and Rossi Liebig's Ann. 159, 60, '71.)
YTTRIUM IODATE Y(IO 3 ) 3 .3H 2 O.
100 gms. H 2 O dissolve 0.53 gm. yttrium iodate.
(Berlin.)
YTTRIUM SULPHATE Y 2 (SO 4 ) 3 .
100 gms. H 2 O dissolve 15.2 gms. Y 2 (SO 4 ) 3 at ord. temperature,
9.3 gms. Y 2 (SO 4 ) 3 .8H 2 O at ord. temp, and 4.8 gms. Y 2 (SO 4 ) 3 .8HO 2
at 100. (Cleve Bull. soc. chim. [2] ax, 344, '74.)
YTTERBIUM SULPHATE Yb 2 (SO 4 ) 3 .8H 2 O.
SOLUBILITY IN WATER.
(Cleve Z. anorg. Chem. 32, 143, '02.)
Gms. Yb2(SO 4 ) 3 Gms. Yb 2 (SO 4 ) 3 Gms. Yb2(SO 4 ) 3
t. per 100 gms. t. per 100 Gms. t. per 100 Gms.
H 2 0. H 2 O. H 2 0.
o 44-2 55 n-5 80 6.92
15.5 34.6 60 10.4 . 90 5.83
35 19.1 70 7.22 ico 4-67
ZINC ACETATE Zn(CH 3 COO) 2 .2H 2 O.
100 gms. H 2 O dissolve 40 gms. at 25 and 66.6 gms. at b. pt.
100 gms. alcohol dissolve 2.8 gms. at 25 and 166.0 gms. at b.pt.
(u. s. P.)
ZINC BENZOATE Zn(C 7 H 5 O 2 ) 2 .
SOLUBILITY IN WATER.
(Paietta Gazz. chim. ital. 36, II, 67, '06.)
t. 15-9 17 27.8 31.3 37.5 49.8 59
Gms. Zn(C 7 H 5 O 2 ) 2 per
loo gms. aq. solution 2.55 2.49 2.41 2.05 1.87 1.62 1.45
ZINC BROMIDE ZnBr 2 .
SOLUBILITY IN WATER.
(Dietz Wiss. Abh. p. t. Reizhanstalt 3, 431, 'oo; see also Etard Ann. chim. phys. [7] 2, 536, '94.)
Gms. ZnBr 2 Mols. ZnBr 2 ,,.. Gms. ZnBr 2 Mols. ZnBr 2 ,...
t. per TOO Gms. per 100 T * *- P 61 " I0 Gms - P 61 IO PV.
^Solution. Mols.H 2 0. Solution. Mols.H 2 O.
!5 77 -*3 2 7' ZnBr 2 . 3 H2O 25 82.46 37.6 ZnBr 2 . 2 H 2 O
io 78-45 2 9 - 1 3 84.08 42.3
- 5 80.64 33.3 37 86.20 50.0
--8 79-06 30-2 ZnBr 2 . 2 H a O 35 85.45 46.9 ZnBr 2
o 79-55 3 1 - 1 " 4o 85.53 47.4
+ 13 80.76 33.5 60 86.08 49.5
18 81.46 35-1 80 86.57 51.5
ico 87.05 53.8
349
ZINC CARBONATE
ZING CARBONATE ZnCO,.
One liter H 2 O dissolves o.oi gm. at 15.
One liter aq. 5.85 per cent NaCl solution dissolves 0.0586 gm.
at 14.
One liter aq. 7.45 per cent Nad solutions dissolves 0.0477 gm.
at 14'
(Cantoni and Passamanik Ann. chim. anal. appl. 10, 258, '05.)
Gms.
Zn(C10 3 ) 2
per i oo gms.
Solution.
-18
o
8
15
18
59 -!9
60.20
67.32
66.52
9.70
11.08
ii .72
15.96
15-39
Solid
Phase.
Zn(C10 3 ) 2 .6H 2 O
Zn(C10 3 ) 2 . 4 H 2
Gms.
Zn(C10 3 ) 2
per 100 Gms.
Solution.
ZINC CHLORATE ZnClO 3 .
SOLUBILITY IN WATER.
(Meusser Ber. 35, 1417, '02; at 18; Mylius and Funk Ber. 30, 1718, '97.)
Mols.
Zn(C10 3 ) 2
per too
ols.H 2 O.
30 76.66
4O 69 . 06
55 75-44
Ice curve
-13 30.27
9 26.54
Sp. Gr. of solution saturated at 18 = 1.916.
Mols.
Zn(C10 3 ) 2
per 100
Mols. H 2 O.
16.20
17.29
24.00
3-36
2.8o
Solid
Phase.
Ice
ZINC CHLORIDE ZnCl 2 .
SOLUBILITY IN WATER.
(Mylius and Dietz Z. anorg. Chem. 44, 217, '05; see also Dietz Wiss. Abh. p. t. Reichanstalt 3. 429,
'oo; Etard Ann. chim. phys. [?j 2, 536, '94.)
Gms.ZnCl 2 per looGms. Solid .o Gms.ZnCl 2 per looGms. Solid
Water.
Solution.
Phase. ' Water.
Solution.
Phase.
11
5
14
12
3
Ice 9
360
78
3
. 2 *H 2 0+.H 2
10
40
25
83
2O
45
.0
3
: J
385
2 9 8
79
74
4
9
ZnCl 2 . 2 }H 2
ZnCl 2 .i*H 2
-62
104
51
.0
Ice + ZnCl 2 .4H 2 O IO
330
76
.8
"
"~1
5
XI 3
53
.0
ZnCl 2 . 4 H 2 O - 20
368
78
.6
"
40
127
55
9
26
423
80
9
.HH 2 0+ZnCl 2 .H 2 O
-30
160
61
5
.4H 2 0+. 3 H 2 26.3
433
81
.2
.iJH 2 + ZnCl 2
10
189
65
4
ZnCl 2 . 3 H 2 O
342
77
4
ZnCl 2 .H 2
o
208
67
5
10
364
78
-4
"
f
5
230
69
7
20
39 6
79
.8
"
6-5
252
4 7 1
.6
28
436
81
3
ZnCl 2 .H 2 -f ZnCl 2
5
282
73
.8
3 1
477
82
7
ZnCl 2 .H 2 O
S^.
o
309
75
5
. 3 H 2 O -f .iiH 2 O 25
432
81
.2
ZnCl 2
t
o
2*<
7
.1
ZnCl2.2)HO 4O
452
81
9
"
6-5
OJ
252
7 1
.6
. 2 *H 2 O + -sHzO 60
488
83.0
10
272
73
.1
ZnCl^iHzO 80
543
84
4
"
12.5
303
75
.2
100
6 J 5
86
.0
"
"5
335
77
O
.2*H 2 + .liHjO 2 62
00
100
-0
it
ZINC CYANIDE Zn(CN) 2 .
100 cc. concentrated Zn(C 2 H 3 O 2 ) 2 + Aq. dissolve 0.4 gm. Zn(CN) 2 .
100 cc. concentrated ZnSO 4 + Aq. dissolves 0.2 gm. (joannis.)
ZINO CHLORIDE
350
SOLUBILITY OP ZINC CHLORIDE, AMMONIUM CHLORIDE MIXTURES
IN WATER.
(Meerburg Z. anorg. Ch^m. 37, 212, '03.)
Isotherm for o. Isotherm for 20. Isotherm for 30.
Gms. per ioo Gms. Gms. per too Gms. Gms. per ioo Gms.
Solution. Solid Solution. Solid Solution. Solid
*-. , , .. ,. TVirt, * Til . Tl_ _
ZnCl 2 .
NH 4 C1."
' ZnCl 2 .
NH 4 C1.
ZnCl 2 .
NH4C1.
O
22.8
NH4C1
.0
26
9
NEUCl
.0
29
5
NHa
3
5
23.0
5
.1
27
.1
9
.2
29
4
"
7
I
23-5
9
5
27
4
16
O
2 9
7
10
.2
23-9
12
7
27
5
20
.2
30
.1
"
15
I
24.7
15
7
27
7
24
7
30
4
18
.0
25-3
18
.0
27
9
26
3
30
.8
NH 4 Cl + <
22
4
26.O
23
5
29
.0
27
.2
30
.2
a
24
.2
26.1
26
.0
29
-5
NH 4 Cl + a 30
.1
2 9
.6
2 5
7
26-3
NH 4 Cl+a 29
5
28
.1
36
.8
28
2
"
27
5
26.4
32
3
27
7
42
4
27
3
"
30
7
25-7
35
.8
27
.0
43
.8
27
3
a + b
33
9
25-3
38
7
26
9
45
.0
24
4
b
38
.8
24.4
40
.2
26
.6
5 1
.2
17
.6
42
.6
24.6
a + b 41
9
26
3
61
9
IO
4
44
3
21-3
b 43
.2
26
.0
a + b 66
9
9
.2
ZnCl 2 -fi
49
.2
15-3
46
9
21
.0
b 75
.6
6
.1
ZnCl 2
5 2
.6
II-9
53
.2
14
5
70
3
7
.6
55
4
IO.O
58
4
II
.1
78
5
3
.2
i
59
3
7-5
62
7
8
7
76
-9
3
5
14
62
.1
6.8
66.6
7
9
79
.8
i
.6
to
81
.6
o
.0
II
a = ZnCl 2 .3NHCl 3 ..
b = ZnCl 2 . 2 NH 4 Cl.
ioo gms. abs. acetone dissolve 43.5 gms. ZnCl 2 at 18.
(Naumann Ber. 37, 4332, '04.)
ioo gms. glycerine dissolve 50 gms. ZnCl 2 at 15.5.
ZINC FLUORIDE ZnF 2 . 4 H 2 O.
One liter of water dissolves 16 gms. at 18.
(Dietz.)
ZINC HYDROXIDE Zn(OH) 2 .
One liter of water dissolves 0.0042 gm. ZnO at 18, conductivity
(Dupre and Bratas Z. angew. Chem, 16, 55, '03.)
SOLUBILITY OF ZINC HYDROXIDE IN ONE PER CENT AQUEOUS
SALT SOLUTIONS AT i6-2o.
(Snyder Ber. n, 936, '78.)
The CO 2 free Zn(OH) 2 dissolved is calculated as milligrams Zn per
method.
liter of the given salt solution,
given.
Additional determinations are also
Aq. Salt Mgs. Zn per
Solution. Liter Solution.
NaCl
KC1
CaCl 2
MgCl 2
BaCI,
5 1
43
57-5
65
38
Aq. Salt Mgs. Zn per
Solution. Liter Solution.
Aq. Salt Mgs. Zn per
Solution. Liter Solution.
K 2 S0 4
37-5
K 2 C0 3
o
MgS0 4
27
NH 4 C1
95
KN0 3
J 7-5
NH 4 NO 3
77
Ba(N0 3 ) 2
25
(NH 4 ) 2 S0 4
88
ZING HYDROXIDE
SOLUBILITY OF ZINC HYDROXIDE IN AQUEOUS SOLUTIONS OP:
Ammonia and Ammonia Bases
at i7-i9.
(Herz Z. anorg. Chem. 30, 281, '02.)
Sodium Hydroxide at
Ord. Temp.
(Rubenbauer Ibid. 30, 333, '02.)
Normality Normality
of of Dis-
Gms. ZnO
per 20 cc .
Gms. per 20 cc. Solution Mol.
the Base. solved Zn.
Solution.
Na. Zn. the NaOH.
o . 0942NH 3 o . ooi i
0.00185
0-IOI2 0.0040 4.50
0.236 " o.oiio
O.OlSo
0.1978 0.0150 2.33
0.707 " 0.059
0.0958
0.4278 0.0442 1. 06
o.o944NH 2 CH 3 0.0005
O.OOOS
0-6670 O.I77I 0.70
0.472 0.0081
O.OI32
0.9660 0.9630 0.48
0.944 " 0.03
0.0484
I.495I 0.2481 0.31
0.068 NH 2 C 2 H 5 0.0003
0.0005
2.9901 0.3700 0.16
0.51 " 0.0045
O.OO74
Moist Zn (OH) 2 used. So-
0.68 0.0098
O.OIOI
lutions shaken 5 hours.
Gms. ZnI 2 Mols. ZnI 2
per loo Gms. per 100 Mols. Solid Phase.
ZnI 2
ZINC IODATE Zn(IO 3 ) 2 .
loo gms. H 2 O dissolve 0.87 gm. Zn(IO 3 ) 2 cold and 1.31 gms. hot.
(Rammelsberg Pogg. Ann, 43, 665, '38.)
ZINC IODIDE ZnI 2 .
SOLUBILITY IN WATER.
(Dietz Wiss. Abh. p. t. Reichanstalt 3, 432, 'oo; see also Etard Ann. chim. phys. [7] 2, 526, '94.)
Gms. ZnI 2 Mols. ZnI 2
t. per loo Gms. per 100 Solid Phase, t'
Solution. Mols. H 2 O.
10 80.50 23.3 ZnI 2 . 2 H 2 O
- 5 80.77 23.7
o 81.16 24.3
+ 10 82.06 25.8
22 83.12 27.8
27 89.52 50.3
Sp. Gr. of sat. solution of the anhydrous salt at 18 = 2.725.
loo gms. glycerine dissolve 40 gms. ZnI 2 at 15.5.
ZINC NITRATE Zn(NO 3 ) 2 .
SOLUBILITY IN WATER.
(Funk Wiss. Abh. p. t. Reichanstalt, 3, 438, 'oo.)
Solution.
H 2 0.
O
8i.ii
24.2
18
81.20
24.4
40
81.66
25.1
60
82.37
26.4
80
83-05
27-5
IOO
83.62
28. 7
Solid
Phase.
Gms. Mols.
Zn(N0 3 ) 2 per ZnNO 3 per
zoo Gms. loo
Solution. Mols. H 2 O.
6.36 Zn(N0 3 ) 2 . 9 H 2 O l8
Gms. Mols.
Zn(N0 3 ) 2 per Zn(NO 3 ) 2 per
Solid
-25
4O-I2
0-30
22-5
40-75
6-54
20
42.03
6.89
-18
43-59
7-34
-18
44-63
7.67
~!5
45.26
7.86
-3
45 -5 1
7-94
12
45-75
8.01
O
48.66
9.01
+ 12.5
52-0
10.3
t".
loo Gms.
IOO
Phase.
Solution.
Mols. H 2 O.
18
53-50
IO.9
Zn(N03) 2 .6H,0
25
55-90
12 .O
l
3 6 -4
63-63
I6. 7
"
36
64.63
17.4
"
33-5
65.83
18-3
"
37
66.38
18.8
Zn(N0 3 ) 2 .3H0
40
67.42
19.7
"
4i
68.21
20.4
"
43
69.26
21.4
M
45-5
77-77
33-3
ZINC OXALATE 352
ZINC OXALATE ZnC 2 O 4 . 2 H 2 O.
One liter of water dissolve 0.083 Mg. equiv. = 0.0064 gm. ZnC 2 O 4
at 18.
(Kohlrausch Z. physik. Chem. 50, 356, '04- '05.)
ZINC SULPHATE ZnSO 4 .
SOLUBILITY IN WATER.
(Cohen
Z. physik. Chem. 34, 189, 'oo; at 50; Callender and Barnes Proc. Roy. Soc. 62, 149, '97;
Etard Ann. chim. phys. [7] 2, 536, '94; Poggiale Ibid. [3] 8, 467, '43; Mulder.)
t .
Gms.
ZnS0 4
per ioo
Gms. Solid
t .
Gms. ZnSO 4 per
100
Gms
Solid
Solution.
Water'. Phase.
Solution.
Water.
Phase.
- 5
28
.21
39-
30 ZnSO 4 .7H 2 O
25
38
94
63
74
ZnS0 4 .6H 2 O
O.I
29
54
93
39
41
.22
70
.06
.6H 2 O + .7H 2 O
9.1
32
OI
47-
09
5o
43
45
7 6
.84
ZnS0 4 .6H 2 O
15
33
.81
50-
88
70
47
5
88
7
.6H 2 + .H 2 O
2 5
36
.67
57-
90
80
46
4
86
.6
ZnSCvHzO
35
39
.98
66.
61
90
45
5
83
7
"
39
.21
70.
05
IOO
44
7
80
.8
"
- 5
32
OO
47-
08 ZnS0 4 .6H 2 O
1 20
41
7
71
5
"
OI
33
.09
49.48
140
38
.0
61
3
"
160
33
.0
49
3
"
ioo gms. abs. methyl alcohol dissolve 0.65 gm. ZnSO 4 at 18, 5.90
gms. ZnSO 4 .7H 2 O at 18.
ioo gms. 50 per cent methyl alcohol dissolve 15.7 gms. ZnSO.7H 2 O
at 1 8.
(de Bruyn Z. physik. Chem. 10, 783, '92.)
SOLUBILITY OF ZINC SULPHATE IN AQUEOUS ETHYL ALCOHOL.
(Schiff Liebig's Ann. 118, 365, '61.)
Concentration of Alcohol 10 per cent 20 per cent 40 per cent
Gms. ZnSO 4 .7H 2 O per ioo
Gms. Solution 51.1 39.0 3.45
ioo gms. glycerine dissolve 35 gms. zinc sulphate at 15.5.
353
ZING SULPHATE
SOLUBILITY OF ZINC SULPHATE SODIUM SULPHATE MIXTURES
IN WATER.
(Koppel Gumpery Z. physik. Chem. 52, 409, '05.)
to
Gms. per 100
Gms. Solution.
Gms. per 100
Gms. H 2 O.
Mols. per 100
Mols. H 2 0. Solid
.
ZnS0 4
Na 2 S0 4
ZnS0 4 . Na 2 S0 4 . ZnSO 4 .
Na 2 S0 4 : Pnase -
O
27.19
5-33
40.30
7-90
4-5
I .01 )ZnS0 4 . 7 H 2 +
5
2 7 -85
6.27
42.28
9-52
4.71
1. 21 ) Na 2SO 4 .ioH 2 O
25
I7-58
26.32
23.40
2-94
2.96 ZnNa 2 (S0 4 ) 2 .4H 2
30
17.66
I5-58
26.47
23-44
2-95
2.97
35
17-59
15 .70
26.36
23-52
2.94
2.98
40
J 7-75
I5-72
26.68
23-63
2.98
2.99
10
29.16
7.16
45-79
ii .24
5- 11
1-42 -
IS
30.70
6.40
48.81
10.17
5-45
1.29
20
32- 5 1
5-36
52.34
8.62
5-84
1.09
ZnNa 2 (SO ) H O
25
34-36
4.41
56.15
7.22
6.27
0.91
-j-ZnSO/.rHzO 2
30
36.28
3-8o
60-55
6-34
6.76
0.81
35
38.18
3 .30
65-25
5-64
7.28
0.71 >
38
40
38-83
38.26
2 .90
2.78
66.64
64.89
4-98
4.71
7-44
7.24
0.63
o .60
10
27.91
7-92
43-50
12.34
4-85
I -5 6 5
15
24.28
10.90
36.92
16.71
4.12
2 .12
20
19,14
14.58
28.77
2i-95
3-21
2.79
ZnNa 2 (S0 4 ) 2 ^H 2
+Na 2 S0 4 .ioH 2
25
13 .31
19.94
19-93
29-87
2 .22
3 .785
30
6.96
27-75
10.67
42-51
I.I9
5-39
35
5 -61
30-03
8.72
46.61
0-971
ZnNa 2 (SO 4 ) 2 . 4 H 2 O
40
5-96
28.65
9.16
43-83
I .02
5-555
+Na 2 S0 4
ZINC SULPHITE ZnSO 3 . 2 H 2 O.
100 gms. H 2 O dissolve 0.16 gm. ZnSO 4 .2H 2 O.
(Houston and Trichborne Brit. Med. Jour. 1063, '90
ZINC TARTRATE C 4 H 4 O 6 .Zn. 2 H 2 O.
SOLUBILITY IN WATER.
(Cantoni and Zachoder Bull. Soc. chim. [3] 33, 751, '05.)
Gms.
t.
CAO6.Zn.2HzO
per 100 cc. Solution.
15
O.OI9
2O
O.O22
25
0-036
30
O.O4I
35
0-055
40
45
5o
55
60
Gms.
C 4 H 4 O 6 .Zn. 2 H 2 O
per 100 cc. Solution.
0-o6o
0.073
0.087
0.116
0.104
Gms.
t.
C 4 H 4 0.Zn.2H20
per i oocc. Solution.
65
o.ioo
70
0.088
75
0.078
80
0.050
85
0.041
ZINC VALERATE (C 4 H 9 COO) 2 Zn. 2 H 2 O.
100 gms. H 2 O dissolve 2 gms. (C 4 H,COO) z .Zn.2H 3 O at 35.
100 gms. alcohol dissolve 2.8 gms. at 25.
(u. s. P.)
ADDENDUM
The distribution results shown in the following table were obtained
by agitating together equal volumes of olive oil and aqueous solutions
of the several narcotics, and determining the dissolved substance
present in the aqueous layer before and after the agitation. The sum
of the amount of substance in the oil and aqueous layers, as shown
in the table, is the amount originally in 100 cc. of each aqueous solu-
tion used.
The work was done for the purpose of testing the Overton-Meyer
Theory of Narcosis, that the anesthetic action of certain groups of
narcotics is proportional to their distribution between water and the
fatty material occurring in the nervous system, and olive oil was
selected as the solvent best fulfilling the analytical requirements
and at the same time offering a fair resemblance to the fatty substance
of the nervous system. The results are believed to be of interest
both as solubility studies and on account of their connection with
the Theory of Narcosis.
The author is indebted to Dr. Reid Hunt of the Hygienic Laboratory
for calling his attention to the papers containing the distribution
results here tabulated.
354
355
DISTRIBUTION OF SEVERAL SUBSTANCES BETWEEN WATER AND
OLIVE OIL.
(At ord. temp., Baum Archiv. exp. Pathql- u. Pharmakol, 42, 130, '99; at 3, 30 and 36; Meyer-*
Ibid. 46, 344, '01; at 15, Harrass Archiv. internal. Pharmacodynamie et Therapie, xx, 458, '03.)
Name of Substance.
Sulfonal
Trional
Tetronal
Di methyl sulphon
di methyl methane
Di ethyl sulphon me-
thane
Ethyl urethane
Methyl urethane
Formula.
(CH 8 ) 2 C(S0 2 .C 2 H 6 ) 2
(CH 3 )(C 2 H 6 )C(S0 2 .C 2 H 6 ) 2
(CH 3 ) 2 C(S0 2 .CH 3 ) 2
CH 2 .(S0 2 .C 2 H 5 ) 2
NH 2 .C0 2 .C 2 H 5
NH 2 .CO 2 .CH 3
Tertiary butyl alcohol (CH 3 ) 2 C(OH)CHs
Amylene hydrate (CH 3 )aC(OH)CH 2 .CH 3
Mono acetin C 3 H 6 (OH) 2 .(OC 2 H 3 O)
Di acetin
Tri acetin
Bromal hydrate
Butyl chloral hydrate
Chloral hydrate
Salicylamide
Benzamide
Ethyl alcohol
Acetone
C 3 H 5 (OH)(OC 2 H 3 0) 2
CBr 3 CH(OH) 2
C 3 H 4 C1 3 .CH(OH) 2
CClsCH(OH) 2
OH.CH4.CH 2 NHa
C 7 H 6 ONH 2
(CH 3 )2CO
Valeryl di ethyl amide CHs(CH 2 ) 3 cON(C3H6)2
Valeryl di methyl amide CHaCCH^sCONCCH^
Valeryl ethyl amide
Valer amide
Lactic acid di ethyl
amide
Sodium salicylate
Gms. Substance per
t o loo cc.
C(f.)
Water
Olive Oil
C(w.)
layer (w.).
layer (f.).
ord.
0.0700
0.0686
0-979
tt
0.0404
o. 1646
4.074
ft
0.0462
0.1446
3-756
"
0.6072
0.0622
0.103
((
0.610
0.092
0.151
"
4-52
0.615
. *36
"
7-50
0.275
0-037
"
8.744
!-539
0.176
M
6.605
6.605
I. 000
It
4.28
0.254
0.059
3
2-349
o. 229
0.099
36
2.417
0.161
0.066
ord.
3-
o-7
0.234
tt
2.72
0.80
0.295
n
9.81
6.52
0.665
it
2.04
3-24
1.589
a
16.31
3.10
0.100
tt
4.12
0.91
0.22
3
1.34
0.08
0-053
3
1. 15
0.27
0.237
3
0.056
0.126
2.25
36
0-075
0.107.
I.4O
3
1.062
0.706
0.66
36
1-235
0-533
0-43
3
3
2.69
3-90
0-09?
0.07$
0.026
30
30
2.64
3.82
0.14 )
o.i6S
0.047
3
3.07
o. So')
3
4.14
0-52 >
o. 146
3
3-92
0.61 )
30
30
3
2-73
3.86
o.737
0.81 >
0.87)
0.235
15
0.231
1-339
5-797
15
0.911
0-379
0.416
15
1.029
0.261
0.254
15
0.769
o. 241
0-313
15
1.256
0.194
0.154
15
1.444
0.156
0.108
INDEX
Acenaphthene, i.
Acetamide, i.
Acetanilide, i.
Acetic acid, 2-4.
in aq. benzene, 55.
Acetnaphthalide, 6.
Acetone, 6-7, 355.
in aq. benzene, 55.
in aq. ethyl acetate, 136.
in aq. potassium chlorate, 241.
in aq. potassium chloride, 247.
in aq. potassium nitrate, 258.
in aq. sugar, 326.
Acetphenetidine, 8.
Acet-toluide, 8.
Acetyl acetone, 9.
Acetylene, 8.
Aconitine, 9.
Adipic acid, 9.
Air, 10.
Alanine, 10.
Aldehyde, n.
propionic, 267.
Alcohols, ii, 355.
Alcohol in aq. benzene, 55.
in aq. etner, 135.
in aq. ethyl acetate, 136.
in aq. ethyl butyrate, 136.
in aq. ethyl propionate, 136.
in aq. ethyl valerate, 137.
in aq. methyl butyrate, 204.
in aq. propyl acetate, 267
in aq. potassium carbonate, 239,
in aq. potassium chlorate, 241.
in aq. potassium nitrate, 258.
in aq. sodium carbonate, 297.
in aq. sodium nitrate, 308-9.
in aq. sodium sulphate, 314.
in aq. sugar, 325.
Allyl isosulphocyanic ester, 205.
Aluminum chloride, 12.
rubidium alum, 271.
sulphate, 12.
sulphate + Lithium sulphate ,176.
tellurium alum, 332.
Alums, ammonium, potassium, etc.,
13-
caesium, 80.
chromium, 116.
iron ammonium, 33.
rubidium, 271.
tellurium, 332.
Amalgam, 278.
Amido benzoic acids, 60.
benzo sulphonic acids, 60.
Amido brom benzo sulphonic acid, 57,
nitro benzoic acids, 60.
propionic acid, 10.
phenols, 60.
Amines, methyl, etc., 15-17.
Ammonia, 17-19.
lithium sulphate, water, 176.
Ammonium acid formate, 26.
acid oxalate, 30.
alum, 13.
arsenate, 20.
benzoate, 20.
bicarbonate, 2122.
bicarbonate + NaHCO,, 298.
bichromate, 25.
bromide, 20.
bromide + KBr, 235.
bromp platinate, 20.
cadmium bromide, 20, 71.
cadmium chloride, 73.
cadmium iodides, 77.
cadmium sulphate, 33.
carbonate, 21.
carbonate in acetone, 6.
cerium nitrate, 111-112.
cerium sulphate, 112.
chloride, 22-25.
chloride and CuCl 2 , 125-126.
chloride and KC1, 242.
chloride and NaCl, 299-300.
chloride and ZnCl 2 , 350.
chromates, 25.
chromium sulphate, 33.
cobalt chlorides, 120.
cobalt sulphate, 33.
copper sulphate, 33, 129, 262.
fluo boride, 26.
fluo silicate, 31.
formate, 26.
iodate, 26.
iodide, 26-28.
iridium sulphate, 34.
iron sulphate, 33.
lead cobalticyanide, 2 a.
magnesium nitrate, 30.
magnesium sulphate, 34.
manganese molybdate, 30.
manganese sulphate, 34.
nickel sulphate, 34, 129.
nitrate, 24, 28, 30.
oxalate, 3031.
permanganate, 31.
persulphate, 35.
phosphite, 31.
platinic chloride, 232-233,
357
INDEX
Ammonium salicylate, 31.
sodium sulphate, 34.
sodium sulphite, 35.
sulphate, 24, 31-33.
sulphate + K 2 SO 4 , 261.
sulphocyanide, 35.
tetra chromate, 25.
tri chromate, 25.
tri nitrate, 29.
uranyl carbonate, 22.
uranyl chlorides, 342.
uranyl nitrate, 343.
uranyl propionate, 343.
vanadium sulphate, 34.
zinc sulphate, 34, 129.
Amyl acetate, 35.
alcohol, ii.
butyrate, 35.
formate, 35.
malonic acid, 186.
propionate, 35.
Amylene hydrate, 355.
Anethol, 35.
in aq. acetone, 6.
Anilin, 36-38.
Anis acid, 38, 61.
Anthracene, 39.
Anthraquinone, 40.
Antimony potassium tartrate, 41.
tri chloride, 40-41.
tri iodide, 41.
Apo morphine hydrochloride, 205.
Argon, 41.
Arsenic iodide, 41.
pentoxide, 41.
tri iodide, 42.
Asparagine, 42.
Astrakanite, 312.
Atropine, 42.
Aurous, auric, see Gold.
Azelaic acid, 43.
Azo phenetol, 43.
Barium acetate, 43.
acid oxalate, 52.
arsenate, 43.
bromate, 44.
bromide, 44.
butyrate, 44.
cadmium chloride, 74.
caproate, 45.
carbonate, 45.
chlorate, 45.
chloride, 24, 4647.
chloride + NaCl, 300.
chromate, 47.
citrate, 47.
cyanide, 48.
dibrom, etc., sulphonic acid, 57.
ferrocyanide, 48.
fluoride, 48.
formate, 48, 165.
hydroxide, 48.
iodate, 49.
Barium iodide, 49.
iodide -f BaBr 2 , 44.
iodide + Hg(CN) 2 , 197.
iso caproate, 45.
iso succinate, 53.
malate, 49.
malonate, 49.
molybdate, 49.
nitrate, 24, 29, 5051.
nitrate + BaCl 2 , 46.
nitrate + KNO 3 , 254.
nitrite, 51.
oxalate, 51.
persulphate, 53.
potassium ferrocyanide, 48.
propionate, 52.
succinate, 53.
sulphate, 52-53.
tartrate, 53-54-
Benzamide, 54, 355.
Benzaldehyde, 54.
Benzene, 54-56.
Benzine, 58.
Benzoic acids, 58-62, 341.
Benzoic sulphinide, 62.
Benzophenone, 6, 63.
Benzo sulphonic acids, 57, 60.
Benzoyl phenyl hydrazine, 57.
Benzyl carbamide, 104.
Beryllium, see also Glucinium.
Beryllium hydroxide, 63.
salts, 140.
sulphate, 63.
Beta Naphthol, 208.
Borax, 293.
Boric acid, 65-67, 294.
Boron tri-fluoride, 67.
Bismuth, 64.
and Pt alloys, 232.
chloride, 64.
iodide, 64.
nitrate, 64.
oxide, 64.
Bromal hydrate, 355.
Brom benzene (di) ,56.
benzoic acid, 60.
benzo sulphonic acid, 57.
cinnamic acid, 118.
phenols, 226.
Bromine, 6769.
Brucine, 69.
Butane, 69.
Butyl acetate, 69.
alcohol, 12.
alcohol tertiary, 355.
chloral hydrate, 355.
formate, 69-70.
malonic acid, 186.
Butyric acid (iso), 70.
aldehyde, 69.
Cadmium ammonium bromide, 20, 71.
ammonium chloride, 73.
ammonium iodides, 77.
358
INDEX
Cadmium ammonium sulphate, 33.
barium chloride, 74.
bromide, 70-71.
caesium sulphate, 84.
chlorate, 72.
cyanide, 76.
fluoride, 77.
hydroxide, 77.
iodide, 77.
magnesium chloride, 74.
nitrate, 78.
oxalate, 78.
potassium bromide, 71.
potassium chloride, 76.
potassium iodide, 78.
potassium sulphate, 79.
rubidium bromide, 72.
rubidium chloride, 75.
rubidium sulphate, 274.
sodium bromide, 72.
sodium iodide, 78.
sodium sulphate, 80.
sulphate, 78-79.
Caesium alums, 15, 80.
cadmium sulphate, 84.
carbonate, 81.
chloraurate, 81.
chloride, 81.
chloride + FeCl 3 , 159.
chlor tellurate, 82.
chromium alum, 80.
cobalt sulphate, 84.
copper sulphate, 84.
fluoboride, 81.
gold chloride, 141.
iodate, 82.
iodide, 82.
indium alum, 80.
iron alum, 80.
iron sulphate, 84.
magnesium sulphate, 84.
manganese sulphate, 84.
mercuric bromide, 81.
nickel sulphate, 84.
nitrate, 82.
oxalate, 83.
permanganate, 83.
platinic chloride, 232.
selenate, 83.
sulphate, 83.
tellurium halides, 332.
thallium chloride, 82.
uranyl chloride, 342.
uranyl nitrate, 343.
vanadium alum, 80.
zinc sulphate, 84.
Caffeine, 84.
Calcium acetate, 84-85.
bicarbonate, 8788.
bitartrate, 103.
bromide, 85.
bromide -f Hg(CN) 2 , 197.
butyrate, 86.
Calcium caproate, 86.
caprylate, 86.
carbonate, 86.
chlorate, 88.
chloride, 88-89.
chromate, 90.
citrate, 89.
di ethyl acetate, 85.
di propyl acetate, 85.
fluoride, 90.
formate, 90.
heptoate, 91.
hydroxide, 91.
hydroxide + CaSO 4 , 99.
iodate, 94.
iodide, 94.
iso butyrate, 86.
iso butyl acetate, 85.
iso .succinate, 97.
iso valerate, 104.
malate, 94.
malonate, 94.
methyl ethyl acetate, 85.
methyl pentanate, 86.
methyl propyl acetate, 85,
nitrate, 95.
nonate, 96.
oenanthate, 91.
oxalate, 95.
oxide, 91.
pelargonate, 96.
phosphates, 95-96.
potassium ferrocyanide, 90,
potassium sulphate, 101.
propionate, 96.
selenate, 97.
silicate, 97.
succinate, 97.
sulphate, 97-102.
sulphide, 102.
sulphite, 103.
tartrate, 103.
tri methyl acetate, 85.
valerate, 104.
Camphoric acid, 104.
Cane sugar, 324-326.
Caoutchouc, 104.
Carbamides, 104.
Carbazole, 104.
Carbon bisulphide, no.
dioxide, 105-107.
monoxide, 107-110.
oxysulphide, in.
tetra chloride, 201.
Carvoxime, in.
Cerium acetate, 1 1 1 .
ammonium nitrate, 111112.
ammonium sulphate, 112.
butyrate, in.
formate, in.
iso butyrate, in.
propionate, in.
sulphate, 112.
Chinin, 117.
359
INDEX
Chinidin, 117.
Chlor acetic acid, 5.
Chloral hydrate, 113, 355.
hydrate butyl, 355.
Chlor benzene, 56.
benzoic acid, 60.
Chlorine, 113-114.
monoxide, 115.
tri oxide, 115.
Chloroform, 115.
Chlor phenols, 226.
Chromic acid, 25, 116, 304.
Chromium alums, 116.
ammonium sulphate, 33.
caesium alum, 80.
chloride, 116.
double salts, 116.
potassium cyanide, 250.
potassium molybdate, 116.
rubidium alum, 271.
sulphate, 116.
tellurium alum, 332.
tri oxide, 25, 116, 304.
Chrysarobin, 116.
Chrysen, 117.
Cinchona alkaloids, 117.
alkaloids salts, 117.
Cinnamic acid, 118.
Citric acid, 119.
Cobalt ammonium chlorides, 120.
ammonium sulphate, 33.
bromide, 119.
caesium sulphate, 84.
chlorate, 119.
chloride, 120-121.
double salts, 119.
Cobalticyanide of NH 3 + Pb, 22.
Cobalt iodate, 121.
iodide, 121.
lead cyanide, 165.
lead potassium cyanide, 165.
nitrate, 121-122."
potassium sulphate, 262.
rubidium nitrite, 122.
rubidium sulphate, 274.
sulphate, 122-123.
Cocaine, 123.
hydrochloride, 123.
Codeine, 123.
salts, 123.
Colchicine, 123.
Collidin, 124.
Copper and Pt alloys, 232.
acetate, 124.
ammonium chloride, 125126.
ammonium sulphate, 33, 129.
bromide, 124.
caesium sulphate, 84.
chlorate, 124.
chloride, 124128.
nitrate, 128.
potassium chloride, 127.
potassium sulphate, 131, 262.
Copper rubidium sulphate, 274.
sodium sulphate, 131.
sulphate, 32, 128-131.
sulphate + CuCl 2 , 126.
sulphate + MnSO 4 , 188.
sulphate + NiSO 4 , 211.
sulphide, 131.
tartrate, 132.
tellurium sulphate, 334.
Cream of tartar, 265-266.
Cresol, 131.
Cumidin (pseudo), 132.
Cuminic acid, 132.
Cuprous, cupric, see Copper.
Cyanogen, 132.
Dextrose in aq. acetone, 7.
Di acetin, 355.
Di brom benzene, 56.
Di chlor acetic acid, 6.
Didymium potassium sulphate, 133.
sulphate, 133.
Di ethyl amine, 16.
ethyl ketone, 137.
ethyl sulphone, 355.
Di methyl sulphone, 355.
Di nitro benzenes, 56-57.
nitro phenols, 226.
Di phenyl, 227.
phenyl amine, 17.
Erbium sulphate, 133.
Ervthrite, 133.
Ethane, 133.
Ether, 134-135- .
in anthraquinone, 40.
Ethyl acetate, 135-136.
alcohol, see Alcohol.
amines, 16.
ammonium bromide, 20,
ammonium chloride, 25.
ammonium iodide, 27.
bromide, 137.
butyrate, 136.
carbamate, 138.
Ethylene, 138.
chloride, 137.
cyanide, 323.
Ethyl formate, 136.
Ethylidine chloride, 137.
Ethyl iodide, 137.
iso valerate, 137.
ketone, 137.
malonic acid, 186.
methyl ketone, 204.
propionate, 136.
urethane, 355.
valerate, 137.
Fats, fatty acids, 138.
Ferrous, ferric, see Iron.
Ferri, ferrocyanide of potassium, 250.
Formaldehyde, n.
Fumaric acid, 139.
Furfurol, 139.
Gadolinium sulphate, 139.
360
INDEX
Galactose, 139.
Gallic acid, 139,
Germanium dioxide, 140.
potassium fluoride, 251.
sulphide, 140.
Glass, 140.
Glucinium, see also Beryllium.
Glucinium hydroxide, 63.
salts, 140.
sulphate, 63.
Glutaric acid, 140.
Glycolic acid, 140.
Gold, 140.
alkali chlorides, 140.
caesium chlorides, 81.
chloride, 141.
phosphorus tri chloride, 141.
Grape sugar, 325-326.
Guaicol, 141.
carbonate, 141.
Guanidine, 141.
Helium, 142.
Hexane, 142.
Hippuric acid, 142.
Homatropine, hydrobromide, 143.
Hydrastine, 143.
chloride, 143.
Hydrazine sulphate, 143.
Hydriodic acid, 145.
Hydrobromic acid, 143.
Hydrochloric acid, 144.
Hydrofluoric acid, 145.
Hydrogen, 145149.
sulphide, 150.
Hydroquinone, 150-151.
Hydroxy benzoic acids, 61.
Hydroxylamine, 151.
hydrochloride, 151.
Hyoscyamine, 151.
Hyoscine hydrobromide, 151.
Indium ammonium sulphate, 34.
caesium alum, 80.
lodic acid, 145.
Iodine, 152154.
lodo benzoic acid, 60.
Iron ammonium alum, 33.
ammonium sulphate, 33.
caesium alum, 80.
caesium sulphate, 84.
chloride, 157159.
chloride mix crystals, 159.
hydroxide, 160.
lead cyanide, 165.
nitrate, 160.
oxide, 1 60.
phosphate, 160.
potassium sulphate, 161, 262.
rubidium alum, 271.
rubidium sulphate, 274.
sulphate, 160.
sulphate + CdSO 4 , 79.
sulphate + Na 2 SO 4 , 161.
sulphide, 160.
Iron tellurium alum, 332.
amyl acetate, 35.
amyl alcohol, 1 1 .
amyl formate, 35.
amyl malonic acid, 186.
Iso butyric acid, 70.
butyric aldehyde, 69.
butyl acetate, 6970.
butyl alcohol, 12.
phthalic acid, 228.
propyl benzoic acid, 132.
Ketone, di ethyl, 137.
methyl ethyl, 204.
Lactic acid di ethyl amide, 355.
Lanthanum bromate, 162.
sulphate, 162.
Lead, 162.
and Pt alloys, 232.
acetate, 162.
ammonium cobalticyanide,
22.
benzoate, 162.
bromate, 162.
bromide, 163.
carbonate, 163.
chlorate, 163.
chloride, 163-165.
chroma te, 165.
citrate, 165.
cyanides, 165.
fluoride, 165.
formate, 165.
hydroxide, 166.
hyposulphate, 170,
iodate, 166.
iodide, 166-167.
malate, 167.
nitrate, 168.
nitrate + Ba(NO 3 ) 8 , 50.
oxalate, 168.
oxides, 1 68.
palmitate, 169.
phosphate, 169.
succinate, 169.
sulphate, 169.
tartrate, 170.
Levulose, 170.
Ligroin, 170.
Lime, see Calcium hydroxide
Lithium benzoate, 170.
bicarbonate, 172.
bichromate, 173.
borate, 170.
bromate, 171.
bromide, 171.
carbonate, 171.
chlorate, 172.
chloraurate, 172.
chloride, 172.
chromate, 173.
citrate, 173.
fluoride, 173.
formate, 174.
INDEX
Lithium gold chloride, 141.
hydroxide, 174.
hypophosphate, 176.
iooate, 174.
iodide, 175.
la urinate, 176.
myristate, 176.
nitrate, 175.
oleate, 176.
oxalate, 175.
palmitate, 176.
permanganate, 176.
phosphate, 176.
stearate, 176.
sulphate, 176.
Magnesium ammonium nitrate, 30.
ammonium sulphate, 34.
bicarbonate, 178-179.
bromate, 177.
bromide, 177.
bromide alcoholates, 177.
bromide aliphatic compounds,
177.
bromide etherates, 177.
cadmium chloride, 74.
caesium sulphate, 84.
carbonate, 178-179.
carbonate in aq. acetone, 6.
chlorate, 180.
chloride, 180-181.
chroma te, 181.
fluoride, 181.
fluosilicate, 184.
hydroxide, 181-182.
hypophosphate, 184.
iodate, 182.
iodide, 182-183.
iodide alcoholate, 183.
iodide, alkyl esters, 183.
iodide, aliphatic compounds, 183.
iodide etherate, 183.
nitrate, 184.
oxalate, 184.
platinic chloride, 181.
platinic chromate, 181.
potassium sulphate, 185.
salicylate, 184.
sulpnate, 184-185.
sulphate + MgCl 2 , 181.
sulphate + Na 2 SO 4 , 312.
sulphite, 185.
Maleic acid, 139.
Malonic acid, 185-186.
Maltose in aq. acetone, 7.
Manganese ammonium molybdate,3o.
ammonium sulphate, 34.
borate, 186.
bromide, 186.
caesium sulphate, 84.
chloride, 187.
fluo silicate, 187.
hypophosphate, 187.
nitrate, 187.
Manganese potassium vanadate, 189.
sulphate, 188-189.
sulphate + CuSO 4 , 130.
Mannite, 189.
Mannitol, 189.
Mercury, 278.
bromide, 189-190.
caesium bromide, 81.
chloride (ic), 190-196.
chloride (ous), 196.
chloride + BaCl 2 , 46.
chloride + CsCl, 81.
cyanide, 197.
fulminate, 197.
iodide, 197199.
oxide, 200.
sulphate, 200.
tetra methyl amine chloride, 1 95 .
Methane, 200.
Methoxy benzoic acid, 38.
Methyl acetate, 203.
alcohol, 136.
amine, 15.
amine HgCl ? , 195.
ammonium iodide, 26.
benzoic acids, 61, 341.
butyrate, 203-204.
Methylene bromide, 203.
chloride, 203.
Methyl ethyl ketone, 204.
iodide, 203.
malonic acid, 186.
phenyl carbamide, 104.
propionate, 203.
urethane, 355.
valerate, 204.
Milk sugar, 325-326.
Molybdenum trioxide, 204.
Monoacetin, 355.
Mono chlor acetic acid, 6.
Morphine, 204-205.
salts, 205.
Mustard oil, 205.
Naphthalene, 206-207.
in aq. acetone, 6.
j8-Naphthalene picrate, 55.
Naphthoic acid, 207.
Naphthol, 208.
Naphthylamine sulphonic acid, 206.
Naphtion acid, 206.
Narceine, 208.
Narcotics, 355.
Neodymium chloride, 208.
sulphate, 208.
Nickel ammonium sulphate, 34, 129.
bromate, 208.
bromide, 208.
caesium sulphate, 84.
chloride, 208-209.
iodate, 209.
iodide, 209.
nitrate, 210.
potassium sulphate, 212, 262.
362
INDEX
Nickel sulphate, 210-212.
tellurium sulphate, 334.
Nicotine, 212.
Nitranilines, o, m, and p, 38.
Nitric oxide, 218.
Nitro benzene, 56-57.
benzoic acids, 6162.
Nitrogen, 213-214.
Nitrous oxide, 215-218.
Nitro phenols, 226.
Olive oil as solvent, 355.
Ortho boric acid, 65-67.
Oxalic acid, 31, 175, 219, 310.
Oxygen, 220-221.
Ozone, 221.
Papaverine, 222.
Paraffine, 222.
Pentane acid, 348.
Pentanon, 137.
Petroleum benzine, 58.
Phenacetine, 8.
Phenanthrene, 222-223.
picrate, 223.
Phenic acid, 223.
Phenol, 223-225.
Phenols (amido), 60.
Phenol anilin mixtures, 38.
Phenolate of phenyl ammonium, 226.
Phenyl ammonium, phenolate, 226.
amines, 17.
di amines, 226.
guanidine (tri), 141.
nydrazine (benzoyl), 57.
methane (tri), 201-203.
salicylate, 227.
thio carbamide, 344-346.
thio urea, 344-346.
Philocarpine salts, 231.
Phosphorus, 227-228.
Phosphomolybdic acid, 227.
Phthalic acids, 228.
anhydride, 228-229.
Physostigmine salts, 229.
Picric acid, 229231.
Pipeline, 231.
Platino amines, 233.
Platinum alloys, 232.
ammonium bromide, 20.
bromide, 232.
double chlorides, 232.
potassium bromide, 232.
Plumbic, see Lead.
Potassium acetate, 233.
acid formate, 251.
acid nitrate, 257.
acid oxalate, 259.
acid sulphate, 264.
alum, 13-14.
antimony tartrate, 41.
arsenate (di hydrogen), 233.
barium ferrocyanide, 48.
benzoate, 233.
bicarbonate, 238-239.
bitartrate, 265-266.
Potassium borates, 234.
boride (fluo), 234.
bromate, 234-235.
bromide, 235-238.
bromide and chloride, 242.
bromide + Hg(CN) 2 , 197.
butyrate, 238.
cadmium bromide, 71.
cadmium chloride, 76.
cadmium iodide, 78.
cadmium sulphate, 79.
calcium ferrocyanide, 90.
carbonate, 238-239.
carbonate in aq. acetone, 6.
carbonate in aq. ammonia, 18
carbonyl ferrocyanide, 250.
chlorate, 239-241.
chlorate + T1C1O 3 , 335.
chloride, 24, 241-248.
chloride + BaCl 2 , 46.
chloride + CaCl 2 , 89.
chloride + FeCl 3 , 159.
chloride + HgCl 2 , 191.
chloride + Hg(CN) 2 , 197.
chloride + KBr, 236.
chloride + KNO 3 , 255.
chloride + NaCl, 300.
chloride + Na 2 SO 4 , 312.
chromates, 248-249.
chromates + K 2 SO 4 , 263.
chromium alum, 116.
chromium molybdate, 116.
chromisulphocyanide, 250.
chromocyanide. 250.
cobalt sulphate, 262.
copper chloride, 127.
copper sulphate, 131, 262,,
citrate, 249.
cyanate, 249.
cyanide, 249.
di chromate, 248-249.
didymium sulphate, 133.
ferric yanide, 250.
ferrocyanide, 250.
ferrosulphate, 262.
fluoride, 250.
fluo boride, 234.
fluo germanate, 251.
fluo titanate, 266.
formate, 251.
gold chloride, 141.
hippurate, 142.
hydroxide, 251.
hypophosphate, 260.
hypophosphite, 260.
iodate, 252. ,
iodide, 252-253.
iodide and bromide, 236.
iodide and chloride, 243.
iodide and PbI 2 , 167.
iodide and Hg(CN) 2 , 197.
iron sulphate, 161.
lead cobalticyanide, 165.
363
INDEX
Potassium lead ferricyanide, 165.
magnesium chloride, 181.
magnesium chromate, 181.
magnesium cyanide, 181.
magnesium sulphate, 185.
manganese vanadate, 189.
mercuric cyanide, 197.
nickel sulphate, 212, 262.
nitrate, 24, 29, 254-258.
nitrate + Ba(NOg) 2 , 50.
nitrate + KBr, 237.
nitrate + KC1, 244.
nitrate + NaCl, 300.
nitrate + NaNO 3 , 308.
nitrite, 254.
oxalate, 258-259.
perchlorate, 241.
perchlorate + KMnO 4 , 260.
persulphate, 264.
permanganate, 259-260.
phosphate, 260.
phosphite, 260.
phosphomolybdate ,261.
platinic bromide, 232.
platinic chloride, 232-233.
selinate, 261.
sodium carbonate, 239.
sodium sulphate, 263.
sodium sulphite, 264.
sodium thio sulphate, 264.
stannate, 261.
sulphate, 24, 32, 261-264.
sulphate -f KC1, 245.
sulphate + KNO 3 , 256,
sulphate + NaCl, 300.
sulphate + Na 2 SO 4 , 312.
sulphocyanide, 265, 291.
tartrate, 265-266.
tellurium bromide, 332.
thio cyanate, 291.
tri chromate, 249.
uranyl butyrate, 343.
uranyl carbonate, 239.
uranyl chloride, 342.
uranyl nitrate, 343.
uranyl sulphate, 344
vanadate, 266.
zinc vanadate, 266.
Praseodymium sulphate, 267-
Propio nitril, 267.
Propionic acid (amido), 10.
aldehyde, 267.
Propylene, 268.
Propyl acetate, butyrate, etc., 267-
268.
acetic acid, 348.
alcohol in aq. K 2 CO 3 , 239.
ammonium iodide (tetra), 28.
anisol (/?), 35.
bromide, chloride, etc., 268.
formate, 268.
malonic acid, 186.
Pseudo cumidin, 132.
Pyrene, 268.
Pyrogallol, 268.
Pyrotartaric acid, 140.
guinine and salts, 117, 269.
acemic acid, 331.
Resorcinol, 270
Rhodium salts, 270.
sodium nitrite, 309.
Rubidium alums, 15, 271.
bromide, 271.
brom iodide, 273.
cadmium bromide, 72,
cadmium chloride, 75.
cadmium sulphate, 274.
carbonate, 271.
chlorate, 271.
chloride, 272.
chromate, 272.
cobalt nitrate, 122.
cobalt sulphate, 274,
copper sulphate, 274.
di chromate, 272.
fluo boride, 271.
fluo silicate, 273.
gold chloride, 141.
hydroxide, 272.
iodate, 272.
iodide, 272-273.
iron sulphate, 274.
nitrate, 273.
mercuric chlorides, 192.
perchlorate, 271.
permanganate, 273.
permanganate + KM
nO 4 , 260.
platinic chloride, 232.
selenate, 273.
silico tungstate, 273.
sulphate, 273274.
tellurium bromide, 332.
tellurium chloride, 272, 332
thallium chloride, 272.
uranyl chloride, 342.
uranyl nitrate, 343.
Saccharine, 61.
Salicylamid, 355.
Salicylic acid, 61, 274-276.
Salol, 227.
Selenious acid, 277.
Selenium, 276.
Senfol, 205.
Silicon, 277.
Silico tungstic acid, 277.
Silver, 278.
and Pt alloys, 232.
acetate, 278.
benzoate, 279.
borate, 279.
bromate, 279280.
bromide, 280281.
butyrate, 281.
caproates, 282.
carbonate, 282.
chlorate, 282.
364
INDEX
Silver chloride, 283-286,
chromate, 286.
citrate, 286.
cyanide, 286.
di chromate, 286.
di ethyl acetate, 279.
di propyl acetate, 278.
fluoride, 287.
fulminate, 287.
heptoate, 287.
hydroxide -f AgCl, 285.
iodate, 287.
iodide, 277, 287-288.
iso butyrate, 281.
malate, 288.
methyl ethyl acetate, 279.
mono chlor acetate, 278.
nitrate, 288-289.
nitrate + KNO 3 , 257.
nitrite, 289.
onanthylate, 287.
oxalate, 289.
oxide, 289.
permanganate, 289.
phosphate, 289.
propionate, 290.
salicylate, 290.
sodium cyanide, 286.
succinate, 290.
sulphate, 290291.
sulphate + CaSO 4 , 101.
sulphocyanide, 291.
tartrate, 291.
thallous cyanide, 286.
thio cyanate, 291.
tri methyl acetate, 279.
valerates, 291292.
vanadate, 292.
Sodium acetate, 292-293.
acid formate, 305.
alum, 15.
ammonium sulphate, 34.
ammonium sulphite, 35.
arsenate, 293.
benzoate, 293.
bicarbonate, 22, 297-298.
bicarbonate + NaCl, 300.
bisulphate, 315.
borate, 294.
bromate, 294.
bromide, 295.
cadmium bromide, 72.
cadmium iodide, 78.
cadmium sulphate, 80.
carbonate, 296-297.
carbonate in aq. acetone, 6.
chlorate, 298-299.
chloride, 24, 299-303.
chloride + BaCl 2 , 46.
chloride + CaCl 2 , 89.
chloride + FeCl 3 , 159.
chloride + Hg(CN) 2 , 191.
chloride + KC1, 245.
Sodium chloride + KNO 8 , 256.
chloride + Na,CO s , 298.
chloride + NaCIO,, 299.
chroma tes, 303304.
citrate, 305.
copper sulphate, 131.
ferrocyanide, 305.
fluoride, 305.
fluoride phosphate, 310.
fluo silicate, 305.
fluo zirconate, 316.
formate, 305.
gold chloride, 141.
hydrogen arsenate, 293.
hydroxide, 306.
hydroxide + NaCl, 301.
hypophosphates, 311.
hypophosphite, 311.
iodate, 306.
iodide, 306.
iodide + Hg(CN) 2 , 197.
mercuric chloride, 193.
mono chromate, 303-304.
molybdate, 307.
nitrate, 29, 307-309.
nitrate -f KNO 3 , 256.
nitrate 4- NaCl, 301.
nitrate + AgNO 3 , 288.
nitrite, 309.
p nitro phenol, 310.
oxalate, 309-310.
phosphates, 310.
phosphites, 311.
potassium carbonate, 239.
potassium sulphate, 263.
potassium sulphite, 264.
potassium thio sulphate, 264.
rhodonitrite, 309.
salicylate, 275, 355.
selinate, 311.
silver cyanide, 286.
stannate, 311.
sulphate, 311315.
sulphate -f CoSO 4 , 122.
sulphate + CuSO 4 , 131.
sulphate + FeSO 4 . 161.
sulphate + NiSO 4 , 211.
sulphate + ZnSO 4 , 353.
sulphite, 315.
telluriate, 315.
tetra borate, 293.
tetra chromate, 304.
thio sulphate, 315.
tri molybdate, 307.
tungstate, 316.
uranyl chromate, 343.
wolfromate, 316.
Stannous, stannic, see Tin.
Strontium benzoate, 316.
bicarbonate, 316.
bromate, 316.
bromide, 316.
carbonate, 316.
365
INDEX
Strontium chlorate, 317.
chloride, 317.
chromate, 318.
di tungstate, 321.
fluoride, 318.
hydroxide, 318.
hyposulphate, 170.
iodate, 318.
iodide, 318.
iodide + Hg(CN) 2 , 197.
malate, 319.
molybdate, 319.
nitrate, 319.
nitrate + Pb(NO 3 ) 2 , 168.
oxalate, 319.
salicylate, 319.
sulphate, 320.
tartrate, 320-321.
tungstate (di), 321.
Strychnine and salts, 321.
Suberic acid, 321.
Succinic acid, 322323.
anhydride, 322.
nitril, 323.
Succinimid, 323.
Sugar, 324-326.
in aq. acetone, 7.
+ K. Butyrate, 238.
+ MgSO 4 , 185.
Sulphanilic acid, 326.
Sulphonal, 355.
Sulphonic acids, 57.
Sulphur, 327-328.
in anilin, 36.
in benzene, 56.
dioxide, 329-331.
trioxide, HgO and H 2 O, 200.
Syngenite, 101.
Tannic acid, 331.
Tartar emetic, 41.
Tartaric acid, 331.
Telluric acid, 332.
Tellurium, 331.
caesium bromide, 332.
caesium chloride, 82, 332.
chromium alum, 116.
mercuric cyanide, 197.
potassium bromide, 332.
rubidium bromide, 332.
rubidium chloride, 272, 332.
Terephthalic acid, 228.
Tetra boric acid, 67.
chlor methane, 201.
ethyl ammonium bromide, 20.
ethyl ammonium chloride, 25.
ethyl ammonium iodide, 27.
methyl ammonium iodide, 26. >,
propyl ammonium iodide, 28.
sodium chromate, 304.
Tetronal, 355.
Thallium alum, 14, 15, 332.
bromate, 332.
bromide, 332.
caesium chloride, 82.
carbonate, 338.
chlorate, 333.
chloride, 333~335-
chromate, 335.
copper sulphate, 338.
cyanide, 336.
fluoride, 336.
iodate, 336.
iodide, 336.
nickel sulphate, 338.
nitrate, 336.
nitrate + KNO 3 , 257.
oxalate, 336-337.
perchlorate, 338.
phosphate, 337.
picrate, 337. ^
platinic chloride, 232.
rubidium chloride, 272.
silver cyanide, 286.
sulphate, 338.
sulphide, 338.
sulphite, 339.
sulphocyanide, 338.
vanadates, 339.
zinc sulphate, 338.
Thallous tri chromate, 335.
Thallo thallic chloride, 335.
Theobromine, 339.
Thio urea (phenyl), 344346.
Thorium selenate, 339.
sulphate, 339.
Tin chloride, 340.
hydroxide, 340.
iodide, 340-341.
sulphate, 341.
Toluene, 341.
Toluidine, 341-342.
Toluyl acids, 341.
Tolyl carbamide, 104.
Tri acetin, 355.
brom phenols, 226.
chlor phenols, 226.
chlor acetic acid, 6.
ethyl amine,- 16.
methyl amine, 15.
nitro benzene, 57.
oxymethylene, 1 1 .
phenyl amine, 17.
phenyl guanidine, 141.
phenyl methane, 201.
Trional, 355.
Tungsto silicic acid, 277.
Uranyl ammonium carbonate, 22.
ammonium propionate, 343.
chloride, 342.
366
INDEX
Uranyl double chlorides, 342.
double nitrates, 343.
nitrate, 343.
potassium butyrate, 343.
potassium carbonate, 239.
potassium sulphate, 344.
sodium chromate, 343.
sulphate, 344.
Urea, 344-346.
Urethane, 347.
Uric acid, 347.
Valerianic acid, 348.
Valeramide, etc., 355.
Vanadium ammonium sulphate, 34.
caesium alum, 80.
rubidium alum, 271.
tellurium alum, 332.
Ytterbium sulphate, 348.
Yttrium iodate, 348.
Zinc and Pt alloys, 232.
Zinc acetate, 348.
ammonium sulphate, 34, 129.
Zinc benzoate, 348.
bromide, 348.
caesium sulphate, 84.
carbonate, 349.
chlorate, 349.
chloride, 349-350.
cyanide, 349.
fluoride, 350.
hydroxide, 350-351.
iodate, 351.
iodide, 351.
nitrate, 351.
oxalate, 352.
potassium sulphate, 262.
potassium vanadate, 266.
sulphate, 352-353.
sulphate + CuSO 4 , 130.
sulphite, 353.
tartrate, 353.
tellurium sulphate, 334.
valerate, 353.
367
YC 21994
THE UNIVERSITY OF CAUFORNIA LIBRARY