N FRANCISCO STATE OF CALIFORNIA EARL WARREN. Governor DEPARTMENT OF NATURAL RESOURCES WARREN T. HANNUM, Director DIVISION OF MINES FERRY BUILDING, SAN FRANCISCO 11 OLAF P. JENKINS, Chief SPECIAL REPORT 32 JULY 1953 GEOLOGICAL INVESTIGATIONS OF STRONTIUM DEPOSITS IN SOUTHERN CALIFORNIA By CORDELL DURRELL United States Geological Survey Digitized by the Internet Archive in 2012 with funding from University of California, Davis Libraries http://archive.org/details/geologicalinvest32durr CONTENTS Page Celestite deposits near Ocotillo, San Diego County, California 5 Celestite deposits at Bristol Dry Lake, near Amboy, San Bernardino County, California 9 Celestite deposits near the southern end of Death Valley, San Bernardino County, California 15 The Solomon and Boss strontianite deposits, Mud Hills, San Bernardino County, California 23 Celestite deposits near Ludlow, San Bernardino County, California 37 (3) I- < < — a. x UJ a> > o sz a.-*- si T3 ° O . Q O) — -C ^_ o — o^o Q) a> c O c 0J ro m (D a o 03 ft S3 ft (4) CELESTITE DEPOSITS NEAR OCOTILLO SAN DIEGO COUNTY, CALIFORNIA* By Cordell Durrell ' OUTLINE OF REPORT Page ;ract 5 oduction 5 logy 5 ■rence 7 Illustrations ire 1. Map showing locations of strontium deposits in South- ern California 4 2. Map showing location of celestite deposit near Oco- tillo, San Diego County, California 5 3. Geologic map of the celestite deposit near Ocotillo, San Diego County, California 6 ABSTRACT •lestite rock is associated with bedded gypsum in Tertiary sedi- ary rocks about 9$ miles south of Ocotillo, San Diego County, lornia. The celestite is a cap 2 to 8 feet thick on the top of •al small hills. A part of the celestite has been mined. INTRODUCTION elestite occurs in the south end of a small range of about 9^ miles south of Ocotillo, California, a few fired yards west of the road from Ocotillo to the gyp- quarries on Fish Creek Wash, and just north of Fish l;k Wash. The deposit is almost on the boundary be- Isn San Diego and Imperial Counties, at an elevation i-een 500 and 600 feet (fig. 2). The region is extremely ■ le area has been described previously only by Moore •wett et al., 1936, p. 154) , but his report was not accom- i ed by a map. The Pan-Chemical Company, of Clare- ( t, California, owns the deposit, ie field work for this paper was done in 1947 by the I . Geological Survey, in order to complete the study J n during World War II on the strontium deposits in a ■ ornia. GEOLOGY ratigraphy. The celestite rock caps several small 1 . and overlies sedimentary rocks of probably Middle • pper Tertiary age. The oldest exposed rock of the 'i is sedimentary breccia that comprises the lower i:s of the hills on which the celestite lies. The breccia mposed predominantly of a gray granitic rock, but I :s of pegmatite, schist, gneiss, and quartzite are pres- it Although the section exposed shows no bedding, the I nentary origin is certain, for some well-rounded 1 lers are present. A sandy matrix can be seen in a few I cuts, but it is not evident on the eroded hill-slopes. t ekness of about 165 feet of breccia is exposed near the 1 sit. '. e breccia is overlain by gypsum, but there is a transi- ts 1 zone about 10 feet thick between the two in which ie are alternations of sand, sandy silt, and argillaceous I im, with the gypsum increasing toward the top. The I] un is thinly bedded and dark colored, with impuri- " car the base. It is more massive and lighter colored I >, except for a gray to black zone 20 to 30 feet above ie ase that contains powdery manganese oxides. ' 1 ilication authorized by the Director, U. S. Geological Survey, [anuscript submitted for publication January 1953. I logist, U. S. Geological Survey. The upper part of the gypsum has a fine columnar structure, with the columns apparently normal to the bedding planes. Toward the top, the gypsum is cavernous owing to solution in weathering, which has permitted considerable gravity collapse near the hilltops. The highest points in the area are capped by celestite rock. Evidently the celestite occurred as lenses in the gypsum and now is present only as erosion remnants. The interval between the base of the gypsum and the base of the celestite is about 90 feet on the west hill and 150 feet on the east hill ; hence the celestite cannot all be at the same stratigraphic horizon. t^Io_Sano ego ^ Ocoti llo' BENSONS DRY LAKE F-===JS 111 IN [-170... up 52 1 1 "*"■> ^HALFHILt\ DRY LAKE T ! j — J •i 1! CELESTITE DEPOSIT \^ f>'" O 1 i i z i 3-.LES J\ \ GYPSUM QUARRY / i Figure 2. Map showing location of celestite deposit near Ocotillo, San Diego County, California. Structure. The beds dip gently to the east in the west- ern part of the area and a little more steeply in the same direction in the eastern part. Attitudes cannot be reliably determined, owing to slumping on the steep slopes, but the maximum dip is about 15°. Many small faults are visible in the outcrop but only three were mapped. Two of these probably have displace- ments of only a few feet. The largest of the three strikes in a northerly direction through the deposit and dips west. The beds on the west are downthrown about 18 feet on the north side of the hill and about 40 feet on the south side of the hill. (5) Special Report 32 o a O O a si m O O , E > < ;:■;.-:■::;;; ■ 4«: v ::-; Strontium Deposits, Southern California Character of the Celestite. The celestite is resistant to ■ athering and forms a cliff at its margin. It is bent down i the edges of the hill owing to collapse of the gypsum ueath. In places a breccia of angular blocks of celestite :1 gypsum 2 to 5 feet thick that no doubt formed by the lapse of cavernous gypsum lies below the celestite lenses. The celestite is very white on fresh surfaces but nthers to a dull reddish brown. Some of it is massive, ; much is porous, with needlelike crystals lining the . ities. Much of it is marblelike in appearance, but a con- jrable amount has a columnar structure that probably ■ iseudomorphous after the columnar gypsum. 'he following analysis is of a representative sample i.ected by Moore (Hewett et al., 1936, p. 161). Analysis of celestite rock* Percent 0.90 0.49 0.50 2.47 0.05 SiO a A1 2 3 Fe 2 3 CaO MgO SrO 52.88 BaO 1.53 MnO Trace SOs 41.44 C0 2 0.71 H.0 0.16 Analyst, Charles Milton. 101.13 The celestite ranges in thickness between 2 and 8 feet and averages about 5 feet. REFERENCE Hewett, D. F., Moore, B. M., Callaghan, E., Nolan, T. B., Rubey, W. W., and Schaller, W. T. (1936), Mineral resources of the region around Boulder Dam: U. S. Geol. Survey Bull. 871, 197 pp. CELESTITE DEPOSITS AT BRISTOL DRY LAKE, NEAR AMBOY SAN BERNARDINO COUNTY, CALIFORNIA* By Cordell Durrell OUTLINE OF REPORT hstract Page 9 itroduction q leneral geology q escription of the celestite concretions,. " 12 Iieniical composition of the celestite ~ 12 rigin of the celestite 13 eferences ~ -.a Illustrations igure 4. Map showing location of celestite deposits at Bristol Dry Lake, near Amboy, San Bernardino Countv, Cali- fornia 9 5. Section of the test pit 10 11 Geologic map of celestite deposit at Bristol Dry Lake, near Amboy, San Bernardino, California ABSTRACT Concretions of celestite have been found along the south margin Bristol Dry Lake for a distance of 3 miles, both east and west of e county road from Amboy to Twentynine Palms. So far as known ey are most abundant in sec. 6, T. 4 N., R. 12 E., S.B., where they >re exposed by plowing. A test pit 3 feet deep showed concretions three horizons to a depth of 1.6 feet. The very rough, irregular concretions are in sandy gypsiferous clay d in thin-bedded sand. They probably replaced the sediment in nch they are found. Strontium is present in the sediment below i concretions and in the waters of the playa. This fact and the ■ucture of the concretions suggest that the concretions are forming present. INTRODUCTION Bristol Dry Lake is a large playa in southern San ■rnardino County, California, a short distance south of e town of Amboy, which is 85 miles east of Barstow and miles west of Needles, on U. S. Highway 66 and on the ;chison, Topeka & Santa Fe Railway. The dry lake, hch is about 6 miles wide and 10 miles long, is at an :itude of 600 feet. The celestite deposit is near the south ge of the lake 6 miles south of Amboy, in the Si sec. 6, 4 N., R. 12 E., S.B., and 1 mile west of the countv road >m Amboy to Twentynine Palms (fig. 4) . AMBOY •% CELESTITE/tS% DEPOSIT « Twentynine Palms 1URE 4. Map showing location of celestite deposits at Bristol Dry L ake, near Amboy, San Bernardino County, California. ublication authorized by the Director, U. S. Geological Survey Manuscript submitted for publication January 1953. 2—74750 The work on which this report is based was apparently the first geological study to be made of the deposit, and was undertaken as a part of the World War II program of the investigation of strategic minerals by the U S Geological Survey. The only previous notice concerning the deposit is in a California state report on the mineral resources of San Bernardino County (Tucker and Samp- son. 1943, p. 544). 1 Concretions of celestite are present on the surface of the playa at several places east of the deposit, and a few are reported to have been found near Amboy. The presence of celestite has apparently been known locally for some time through the finding of occasional concretions The deposit is on public land held by the National Chloride Company as mineral claims. Celestite did not show at the surface, but was discovered accidentally in 1941 by M. M. Stephens, who was in charge of field operations for the company, while grading a road near the south edge of the playa. The present work was greatly aided by the courtesy of Frank Thomas and M. M. Stephens of the Desert Prop- erties Company, former owners of the deposit. A. Cowles Daley assisted the writer in the field and in the prepara- tion of the geologic map. GENERAL GEOLOGY Almost nothing is known about the geology of the country surrounding Bristol Dry Lake ; there are no ade- quate maps of the region, and the writer has only a meager knowledge of the part of the area adjacent to "the lake. The playa is surrounded by broad areas of alluvial fans bordered by high, rugged mountains. The mountains on the west and northwest are of Tertiary volcanic rock and older intrusive igneous rocks. Basalt and andesite and their tuffs are probably dominant among the volcanics, but rhyolite tuff is also present. The older rocks are quartz monzonite and granite. Granitic rocks occur south of the lake also. It is probable that a wide variety of rocks, in- cluding sedimentary and metamorphic rocks as well as igneous rocks, is present in the basin. Adjoining the lake on the west and partly buried beneath the surface layers of clay is a large body of olivine basalt of recent age that occupies a roughly circular area 6 to 8 miles in diameter centered on a large cinder cone. The flow is probably several hundred feet thick near the vent. The age of the basalt is not known exactly, but it is prehistoric and is probably not earlier than late Pleistocene. The surface of the playa is composed of powdery yellowish-brown silty clay that gives wav abruptly to gravel at the margin of the playa. Windblown sand is present here and there near the edge of the playa and on the gravel south of the celestite deposit. The central part of the lake contains a large body of halite. According to Moore (Hewett et al., 1936, p. 94) the top of the salt is 5 feet below the surface of the piaya ; the salt body is 5 feet thick where it is being mined, and it underlies 5,000 acres. The salt beds range from an inch to a foot in thickness, and are separated by thin layers of clay. The salt body is porous and contains an interstitial brine rich in calcium chloride. Several companies produce salt and two produce calcium chloride from this deposit. (9) 10 Special Report 32 Feet Surface of Playa 3 1 - m iirnrnf" 1 ^ 1 iwiiii!m»'..irni -=" SuuriTiMii ■ j^ifailwlrtMitlV\WWWwtaW^UMV\\*yf.lU|lMWUi£ interval 0.0-0.3 Soft yellowish gray silt with surface crust cemented by halite. 0.3-0.6 Porous yellow-brown sandy clay with gypsum crystals up to 3 inches in length. Scattered small celestite nodules. 06-1.1 Celestite nodules in coarse-bladed gypsum with yellow-brown clay motnx at the top becoming sandy toward the base. Half -inch crust of gypsum ai the base. I.I - 1.3 Medium-grained porous gypsum with yellow clay matrix. 13-1.6 Fme g.ay to yellow silty sand containing a few nodules of celestite. Quarter-inch gypsum crust at the base. 1.6-1.9 Fme yellow clayey sand and sandy clay. 1.9-2.0 Yellow sandy clay with crust of gypsum crystals at the base. 2.0-2.3 Thin-bedded clayey gray, brown, and reddish fine sand. 2.3-2.8 Brownish sandy clay at top grading downward into brown clay with costs of halite crystals and irregulor small cavities. 2.8-2.9 Medium-grained cleon groy sand with half-inch gypsum crystals at top. 2.9-30 Yellow silty cloy. Figure 5. Section of the test pit. The clays above the salt body are hygroscopic, probably because they contain calcium chloride, and the color of the moist clay outlines the salt body. The salt body evi- dently does not extend as far south as the celestite de- posit. Concretions of celestite are present on the surface ot the playa near its south edge and beside the county road that traverses the dry lake ; and many more are present in the first few inches of the clay. Those on the surface have been exposed by deflation. Concretions also occur sporadically on the surface for 2 miles east of the county road along the south edge of the playa. The deposit of the National Chloride Company is a mile west of the countv road and about 750 feet from the margin of the playa; but concretions were not present on the surface there. Celestite is thus known to be present here and there for a distance of 3 miles along the south side of the playa. It has also been reported near the north edge, near Amboy. Exploration might show it to be present all around the plava. After celestite was discovered on the holdings ot the National Chloride Company, an attempt was made in 1942 to develop the ground and determine the extent of the deposit. Furrows were plowed at intervals of about 10 feet with a heavy plow that penetrated about a foot. Some of the celestite uncovered in this manner was stacked in the field and two carloads were shipped in 1942. The area has remained idle since then, although several car- loads of concretions remain on the ground. The deposit was fairly well outlined by the plowing, and the ground so explored is shown on figure 6,as is the area of greatest concentration of concretions. Scattered concretions are known outside the last line, and the limits of the celestite deposit are not yet known. Celestite is not present in the two pits south of the deposit ; only a little is visible in the well at the east end, and none is exposed in the furrows at the extreme west end of the deposit. The northern limit of the deposit is undetermined. In order to examine the occurrence of the concretio. in detail, and to obtain information on the amount celestite present, a test pit 3 feet square and 3 feet de was dug near the center of the deposit in ground that h, not been previously disturbed. The section of the roc; exposed in the test pit is shown in figure 5. The first celestite was encountered between 0.3 and G of a foot below the surface. The largest concretion the' was only about 2 inches long and the total weight of cek tite recovered from the layer was only 12 ounces. The ec cretions were the same in all respects as those in the zoi below. Most of the celestite— 159 pounds of the total of l) pounds recovered from the pit — was between 0.6 of a f(t and 1.1 feet below the surface. The top of this zone l marked by a well-defined bedding plane. Above it is san J gypsiferous clay that contains the uppermost collec- tions ; below it is yellow-brown clay with nearly vertnl blades of gypsum 3 to 6 inches long. The clay contaim: the abundant celestite nodules becomes sandy at abet 0.3 of a foot below the top of the bed, and the base> marked by a half-inch layer of porous gypsum with bla» o u * Q 03 I ' E C3 12 Special Report 32 Bladed gypsum with a yellow clay matrix underlies the half -inch-thick layer of porous gypsum at the base of the concretion-bearing beds. Underneath this, from 1.3 to 1.6 feet below the surface of the playa, is a layer of thin- bedded, fine, gray to yellow silty sand that also contains celestite concretions. This layer is much sandier than the two higher celestite-bearing zones, but the concretions are not very numerous. Only 9 pounds 4 ounces of celestite was recovered from it. The concretions are simple in out- line, and the largest was only about 8 inches long. The beds below the lowest celestite-bearing stratum con- sist of fine sand, sandy clay, and clay with two thin beds of gypsum. The clay from about 2.3 to 2.8 feet beneath the surface contains abundant casts of halite crystals as much as a quarter of an inch on an edge, and many irregu- lar cavities as well. Many of the cavities are lined with a black film of manganese oxide. All the sediments were moist with brine on April 24, 1945, when the pit was dug. The clay with casts of halite crystals and the lower beds were saturated with a strong brine, and brine oozed into the bottom of the pit. On the same day the water level in the well 800 feet east of the test pit was 5 feet below the surface. The sediments exposed to a depth of 3.5 feet below the surface at the well are essentially the same as those in the test pit, and a few small celestite concretions are present in yellow clay with bladed gypsum from 1.0 foot to 1.2 feet below the surface. Perhaps celestite concretions are present at greater depth in the playa sediments, but no information is avail- able concerning the beds deeper than 3.5 feet. DESCRIPTION OF THE CELESTITE CONCRETIONS The smaller concretions are fairly regular in outline. The larger concretions are knobby and closely resemble potatoes in size and shape. Still larger concretions are much more irregular and were evidently formed by the coalescence of adjacent concretions. They have the form of irregular chains and rings and complex forms that defy description. The junctions are usually weak, so that the component parts break apart readily, and for that reason it is not possible to give the maximum size that is reached by a continuous body of celestite. The largest dimension of the simpler concretions is generally not more than 6 inches. This may be taken as a rough expression of the maximum spacing of the centers about which the concretions started to form. Most concretions are composed of dense creamy white celestite in thick basal tablets that range in maximum di- mension from 0.02 to 0.08 mm, and contain a trace of gypsum in minute grains. "Cracks about a quarter of an inch deep that bound polygonal areas from a quarter to half an inch wide are present on the lower surfaces of most of the concretions. The celestite of the polygons is soft, and some of it has a mushy consistency. Unindurated celestite also is pres- ent on the tips of knobs, and at the connecting links be- tween the larger portions of the complex concretions. The margin of the concretions, a zone from 0.5 to 5 mm thick, is finer grained ; the grain size ranges from 0.01 to 03 mm. The marginal part also contains a little gypsum, small rhombs of a carbonate— probably calcite— and clastic grains, among which quartz, plagioclase, horn- blende, augite, microcline, and partly glassy andesitic or basaltic rock fragments were identified. In most con cretions the clastic grains are confined to the fine-grainec margin. The clastic grains are most numerous and bes- rounded at the surface of the concretions, and are les: numerous, smaller, and less well rounded progressively inward. The surfaces of the grains inward from the sur face of the concretion are pitted as though attacked b solution. By the growth of such solution pits the grain become smaller, are divided into several parts, are re duced to shreds, flakes, and angular fragments, an< finally disappear. No large gypsum crystals have been found enclose* within the concretions, although some external gypsur crystals are partly embedded in celestite. The embedded parts are reduced in size and have irregular, pitted sui faces as though they had undergone solution. _ Nearly all the concretions contain cavities, some o which are lined with small crystals of celestite. Some o the cavities, particularly the smaller ones, are very ij regular in form, but most are shaped like a double conve lens. Some of the lens-shaped cavities are very small, bv others have a maximum diameter of 2 to 3 inches. A fe- were found that passed nearly through the concretion The concretions of the lower zone are essentially tb same as those in the first and secend zones. They wei formed, however, in thin-bedded silty sand, and tl bedding planes show on the surfaces of the concretions ; irregularities. The bedding planes are not evident in tl interiors of the concretions. The concretions present at other places east of this d posit are identical with those found here, and they als are in gypsif erous sandy clay at a depth of about a foo CHEMICAL COMPOSITION OF THE CELESTITE Although it was evident from the hand-specimen ai microscopic examinations that the concretions are almo pure celestite, the following analysis of celestite from tl zone of most abundant concretions, exposed in the te pit, was made for confirmation. Anaylsis of celestite concretions * Si0 2 A1 2 3 FeaOs MgO CaO Na=0 CO* SO3 CI MnO BaO SrO Organic carbon _ Prese nt 99.17 Less 0=C1 Total Percent . 1.06 . 0.21 . 0.13 . (a) . 1.58 . 0.45 - (a) _ 42.40 _ 0.54 - (a) - (a) . 52.80 99.05 ^Analysir^rG.'FaTrchnd. Sample from depth of 0.6 of a foot to 1.1 tetta»j in SW1 sec. 6. T. 4 N., R. 12 E., S. B., Bristol Dry Lake, San Bernardino Con. California. When recalculated the above analysis gives the ft lowing : NaCl J88 SrSO* — - -- 9 |g CaSO, 2.86 Clastic grains, etc loi ^ Total 9 9 - 05 A partial analysis of the silty clay in the test pit below [i celestite shows some strontium to be present there also. Strontium Deposits, Southern California 13 CaO BaO SrO CI __ C0 2 S0 3 - Pariial analysis of silty clay * 7.00 (a) 0.03 1.05 1.48 6.3S Less than 0.01 percent. 1 lalysis by J. B. Fairchild. Sample from depth of 2.3 to 2.8 feet in test pit in SWJ I sec. 6, T. 4 N., K. 12 E., S. B., Bristol Dry Lake, San Bernardino County, California. This analysis is recalculated as follows, and the con- jtuents so calculated were separately confirmed as : ; isent : Na.SO-4 4.62 NaCl 3.22 CaSO* 12 74 CaCOs 3.36 SrSO* 0.05 The sample contained casts of halite crystals, films of ick manganese oxide, small soft concretions of CaC0 3 , 1 crystals of gypsum. The analysis indicates the pres- >e of strontium sulfate in small amounts in the sedi- pts surrounding the concretions. In order to determine whether or not strontium was : terally present in Bristol Dry Lake, two samples of wa- 1 were analyzed. Analysis of waters from Bristol Dry Lake in parts per million* I II 17,190 43,300 598 1,074 393 962 46,070 57,370 1,479 3,303 104,600 172,900 Ca Mg Sr Na K CI SO* 1,048 B4O7 88 210 30 Jyses by W. W. Brannock. Sample I from shallow well in SEJ sec. 6, T. 4 N., R 12 !., S. B., within the area containing celestite concretions. Sample II from drainage anal in salt body of Bristol Dry Lake at mill of National Chloride Company, 6 miles outh of Amboy. 'hese anaylses indicate that strontium is probably sent in solution in the water contained in the sedi- 1 its throughout the playa. ORIGIN OF THE CELESTITE h is clear that the celestite concretions form by pre- tation of strontium sulfate from the strontiuni-bear- 1 waters of the playa, and that they form within the W of sediment. The growth of the concretions has re- led in the disappearance of the gypsum and clastic ; ment that formerly occupied the space. There is no iirtion of the thin-bedded sand around the concre- 1 9 of the lower zone, as would be expected were the jrth of the concretions accomplished by pushing aside ii slastic material. The course of replacement of clastic ■ trials by celestite can be traced by the gradual disap- (•ance inward of the clastic grains enclosed in the I ?ins of the concretions. ie structure of the concretions indicates that the celes- • precipitated at the margins of the concretions as a grained mush that then recrystallized to a coarser ' a size, became more compact, and shrank as the con- ^d clastic grains dissolved. The polygonal cracks and internal openings lined with crystals are evidence of such shrinkage. The features mentioned above likewise indicate that the concretions are being formed at the present time. The polygonally cracked mushy celestite is obviously the re- cently deposited material that has not yet become thor- oughly recrystallized. It is to be expected, of course, that deposition of celestite, as well as gypsum and halite, is taking place now, because the brine contains strontium and the basin is a site of evaporation. Were the reverse true — that the strontium in the brine comes from the solu- tion of concretions — the concretions should lack the mushy outer zones, and should also lack the thin margin that contains partly dissolved clastic grains. The immediate cause of deposition of strontium sulfate is doubtless the evaporation of water from the suface of the marginal part of the playa, which causes the residual brine to become saturated with that substance. Since the amount of evaporation varies with the season as does the accession of water to the lake clays, the celestite is proba- bly deposited intermittently. Neither detailed geological study nor chemical analysis is likely to shed much light on the initial source of the strontium until a great deal of information on the geology of the basin as a whole and on the subsurface conditions of the playa becomes available. Several possible sources of the strontium that merit some discussion can, however, be postulated. The strontium may have been derived by weathering from the rocks of the drainage basin, and then concentrated in the waters of the playa by evaporation ; it may have been carried into the playa as a dispersed con- stituent of pyroclastic rocks or lava flows and then re- leased in soluble form by alteration; or, it may have come from an original igneous source and have reached the surface somewhere in the drainage basin or the playa through solfataric activity or spring waters partly of juvenile origin. The strontium content of most rocks is very small ; yet, since little is known about the rocks of the basin surround- ing Bristol Dry Lake, the possibility that the strontium could have been derived by general weathering followed by concentration through evaporation cannot be ruled out. Perhaps, under this view, the Tertiary tuffs and flows are the most likely sources, for deposits of celestite and strontianite of Tertiary age are present elsewhere in the Mojave Desert region in close association with similar volcanic rocks. There is no information, however, on the strontium content of the Tertiary volcanic rocks either in the Bristol Lake basin or in adjacent regions. The olivine basalts west of the playa cannot have been the source for they are so recent as to be scarcely weathered. It may be postulated as a special case that the strontium was derived by weathering of an older deposit of strontium minerals. The largest known nearby strontium deposit of Tertiary age is the celestite body near Ludlow, 35 miles west of Bristol Dry Lake. Perhaps similar deposits are present in the Bristol Lake basin buried beneath the ex- tensive alluvial fans. The celestite deposit near Ludlow cannot have been the source, for, although the two areas were separated by only a single drainage divide until the recent eruption of the olivine basalt, the region is ex- tremely arid, and the basins were probably never con- nected by either surface or subsurface drainage. 14 Special Report 32 Little can be said about the second possibility for noth- ing is known about the sediments of the playa beyond a depth of 5 feet. The olivine basalt flows west of the lake are partly buried by the uppermost sediments of the playa, but the extent to which they underlie the playa is not known nor are there any data concerning the stron- tium content of the lava. It is possible that the strontium ivas derived from the basalt either by its liberation in the volatile constituents given off as the lava solidified or by alteration of the lava subsequent to burial by the sedi- ments of the playa. The third possibility, involving the concentration of rare elements by means of, or in association with, igneous processes, is at least as acceptable and perhaps more ac- ceptable than concentration by epigene processes. If strontium was concentrated in a hydrothermal solution in the same manner as hypogene ore-forming solutions in general, it could have been brought to the surface any- where in the drainage basin through solfataras or spring water partly of juvenile origin and then carried into the playa by meteoric waters, or it could have been introduced directly into the wet sediments of the playa from below. Once the strontium was in solution in the brine it could have been deposited in the celestite nodules under the control of processes ordinarily called sedimentary. It would be affected by the ground-water regime and by the character and disposition of the chemical and clastic sediments. Such an origin involves a combination of hydrothermal and sedimentary processes, with the lattei process, which is also the last to operate, controlling the final position and character of the deposit. REFERENCES Hewett, D. F., Moore, B. N., Callaghan, Eugene, Nolan, T. B. Rubey, W. W., and Schaller, W. T. (1936), Mineral resources o the region around Boulder Dam : U. S. Geol. Survey Bull. 871 197 pp. Tucker, W. B., and Sampson, R. J. (1943), Mineral resources o San Bernardino County, California : California Jour. Mines an Geology, vol. 39, pp. 427-549. CELESTITE DEPOSITS NEAR THE SOUTHERN END OF DEATH VALLEY SAN BERNARDINO COUNTY, CALIFORNIA* By Cordell Durrell OUTLINE OF REPORT Page A, tract 15 I reduction 15 Ology 16 stratigraphy 16 tructure 18 ■ummary of the geologic history 18 '•ccurrence of celestite 19 •rigin of the celestite 20 'hemical composition of the celestite 21 Berves _ 21 Berences _ 21 Illustrations te 1. Geologic map. Celestite deposits near the southern end of Death Valley, San Bernardino County, Cali- fornia '__In pocket ure 7. Map showing location of the celestite deposits near the southern end of Death Valley, San Bernardino County, California l_ 15 ABSTRACT he celestite deposits near the southern end of Death Valley in Tertiary sediments along the north base of the Avawatz liitains. The sedimentary rocks of Tertiary age have been di- d into four units. These are basal breccias and salt that rest x giant breccia named the Amargosa chaos, red sandstone and , gypsum and gypsiferous clays associated with sandstone and e conglomerate, and gray and brown sandstones and conglom- es. The sediments of Tertiary age are overlain unconformably :he Funeral fanglomerate of Pliocene (?) age, upon which are ace deposits and alluvium of Quaternary age. he structures of the region are complex, and include overturned 5 and thrust faults and possibly low-dipping overthrusts. he celestite was deposited as beds and concretions in gypsum, dferous clay, clay, and sandstone and is present for a distance miles along the strike of the beds. The celestite probably orig- ed by replacement of the sediments that enclose it. he largest of the celestite bodies is 2,100 feet long and has a imum thickness of 12.7 feet. Many of the celestite bodies are 1 or 2 feet thick and a few tens of feet long. By far the greater of the celestite is in small lenses and concretions. INTRODUCTION ocation of the Area. The celestite deposits near the thern end of Death Valley are in Tertiary sediments t flank the northern side of the Avawatz Mountains . 7) . The ereseent-shaped Avawatz Mountains rise to iltitude of 6,200 feet above sea level, and stand almost 10 feet above Saratoga Spring on the adjacent floor )eath Valley. The central mass of the range is corn- id of plutonic and metamorphic rocks, but a narrow p of sediments and tectonic breccias of Tertiary age ■nds northwestward along the northern base for about piles from a point about 4 miles east of Sheep Creek ings. A northwest-trending spur of the range, which nds into the Death Valley trough, and two small iso- i groups of hills west and northwest of the spur are composed of Tertiary rocks. These geographical fea- is are shown on the Avawatz Mountains topographic 1 of the U. S. Geological Survey. he lands which include the celestite deposits are in 8 N., Rs. 4, 5, and 6 E., S. B., and T. 17 N., Rs. 5 and , S. B., and belong to the Avawatz Salt and Gypsum ^pany. The area ranges in altitude from 1,000 to 2,500 Approximately 50 claims, most of which are patented, cover almost all of the known mineral deposits. In 1945, the deposits were reached by several roads that extended southward from the graded but unpaved road through the south end of Death Valley (fig. 7). Fair ungraded roads traversed Cave Springs Wash and Denning Springs Wash. A poor road extended from the Death Valley road into the Salt Basin via Pipe Line Wash, but the Salt Basin could also be reached by a branch of the road in Cave Springs Wash. The road to Sheep Creek Springs was washed out in 1945 but could be easily repaired. A road that extends northwestward along the base of the range from the mouth of Sheep Creek Canyon was all but im- passable (fig. 7). The deposits are as much as 14 miles over unpaved roads from the paved highway at Salt Springs. From Salt Springs it is 60 miles to Dunn Station, the nearest railroad loading platform. The connection at Riggs Station on the now-abandoned Tonopah & Tide- water Railroad, mentioned in older reports on this area, is no longer available. The region has a desert climate. Snow falls on the higher parts of the Avawatz Mountains, but very little precipi- tation in the area of Tertiary sediments is indicated by the abundant outcrops of salt. Good water is available in quantity at the springs in Sheep Creek and at Sara- toga Spring on the opposite side of Death Valley. A little water is available at Cottonwood Spring, but there is none farther west. The strip of Tertiary sediments is flanked on the south by the steep rugged slope of the Avawatz Mountains and on the north by boulder-strewn alluvial fans. The area of Tertiary rocks is cut into badlands. Closely spaced shallow steep- to vertical-walled canyons and ravines are characteristically cut in the soft sediments. Previous Work. The first published report on the area is probably that by Phalen (1914), who described the stratigraphy of the Tertiary beds and the occurrence of salt, gypsum, and celestite. A part of the area was exam- 1 Jlication authorized by the Director, U. S. Geological Survey lanuscript submitted for publication January 1953. Figure 7. Map showing location of the celestite deposits near the southern end of Death Valley, San Bernardino County, California. (15) 16 Special Keport 32 ined by Moore (1935, pp. 1-24; Hewett et al., 1936, pp. 158-160), who described and measured sections at two places at the western end of the area but did not visit the deposits east of Cave Springs Wash. Brief notes on the salt, gypsum, and celestite have been published in several California state reports (Tucker and Sampson, 1930, p. 323; 1943, p. 543) on the mineral re- sources of San Bernardino County. A recent paper by Noble (1941) on the Virgin Springs area, 20 miles to the north, has an important bearing on this report, for the breccias there called "chaos" by Noble are present in the Avawatz area. The base map used in the present report was made in 1911 by J. O. Lewis to accompany a private report on the area for the Avawatz Salt and Gypsum Company. Scope of the Report. This report is based on only eight days of field work and must be regarded merely as a reconnaissance. The work was clone as a part of the "World War II program of the IT. S. Geological Survey for the investigation of strategic minerals. All the celestite de- posits exposed within the mapped area probably were found, but the exact dimensions of the numerous beds were not determined, so that precise estimates of re- serves cannot be made. Celestite may be present beyond the limits of this mapped area, plate 1, though such de- posits are unknown. Many problems in structure, stra- tigraphy, and origin of the rocks and mineral deposits remain to be solved. Acknowledgments. The writer is indebted to B. N. Moore for the sections at the Celestite Hills, which were taken verbatim from his report. L. F. Noble furnished the writer with a copy of the base map used in this report, and also contributed orally much information about the immediate area and the Death Valley region in general. A. C. Daley assisted in the field and in the preparation of the maps. H. H. Kerkthoff, Jr., of the Avawatz Salt and Gypsum Company, San Marino, California, gave permis- sion to make the study and to publish the results. GEOLOGY Stratigraphy Because the concept of the stratigraphy presented be- low is based on only a few days' work, it can be regarded only as provisional. Careful study and mapping will be required to solve all the problems involved. The oldest rocks of the district, which do not appear on plate 1, are those of the higher parts of the Avawatz Mountains. They were not examined by the writer, but judging from the material brought down by the streams, they are plutonic and metamorphic rocks that are doubtless pre-Tertiary in age. The crystalline rocks of the range are separated from the Tertiary sequence by a broad crush zone of gouge and breccia that is probably the Garlock fault. Amargosa Chaos. The oldest rocks north of the Gar- lock fault are those of the puzzling giant breccia, named the Amargosa chaos by Noble (1941, pp. 964-965) for its occurrence in the Amargosa Range on the east side of Death Valley, 20 miles to the north. The Amargosa chaos, which is described in great detail in Noble's report, is believed by him to be a gigantic tectonic breccia that rests on the Amargosa thrust fault. Three phases of the chaos are distinguished by the character of the constituent blocks and their structural position. The Amargosa chao: of the Avawatz area is the latest and highest phase, ac cording to Noble (oral communication, 1945) and wai named by him the Jubilee phase. The chaos of the Avawatz area has the typical structure described by Noble. Blocks, of dimensions ranging fron inches to scores of feet, bounded by faults and shatterei internally, yet with the internal structures not seriousl; disturbed, are closely packed against each other withou intervening matrix or gouge. The blocks are predomi nantly of granitic rocks, and relatively large areas con tain nothing but rocks of that type. Elsewhere dolomites limestones, quartzite, or sandstones are mixed with gra nitic rocks, or are locally predominant. Hornfelsed am epidotized thin-bedded calcareous shales and mica schist are locally abundant. The base of the chaos has not bee found within the area, and its thickness is not known. Th age of the Amargosa thrust, and therefore the chaos res 1 ing on it, is not older than Miocene according to NobI (1941, p. 981), for the Jubilee phase contains Tertiar rocks that are probably Miocene in age. Andesite. Southeast of the Jumbo Salt area there is narrow strip of purplish-gray vesicular andesite that in fault contact with the Amargosa chaos. On the soutl ern side the andesite is apparently in depositional conta< with red sandstones of the succeeding salt-bearing bed Thus the andesite appears to be a flow, older than the sa beds, and therefore probably originally erupted onto tl surface of the Amargosa chaos. Possibly, however, tl: andesite is properly a part of the chaos, though Tertiar volcanic rocks have not been seen elsewhere in the cha< in this district. In the Virgin Springs area the Jubih phase does contain Tertiary andesite and other volcan rocks. Tertiary Sediments. The top of the Amargosa eha< is well exposed in the Salt Basin, where it is compose largely of quartzite that is overlain by a sedimentai breccia of angular blocks of the same quartzite. The sec mentary breccia is not more than 30 feet thick, shows i internal bedding, and is overlain by red salt clays ai salt. North of the Jumbo Salt area, there are poorly be ded breccias of black sandstone, and hornfelsed and epid tized calcareous shale identical with those found in tl chaos that are equivalent to and in part older than tl salt. The chaos is present north of the breccia, and, thou;. the contact between it and the breccias was not examhn or mapped, the relationship is almost certainly the sar as that at the Salt Basin. Apparently sedimentary bre cias locally derived from the underlying chaos were c posited on the chaos after overthrusting ceased. At Big Gypsum Hill, west of Cave Springs Wash,! well-bedded unit mapped as conglomerate but consistii of blocks of granitic rocks in a sandy matrix, is believ to occupy the same position as the breccias farther ea The structure is complex, however, and this interpret tion may be incorrect. Possibly the breccia and conglomerate should be cc sidered more properly as part of the Amargosa eha<. Either these beds were deposited diseontinuously in loci basins or they are merely phases of the underlying cha <• The breccias are succeeded by the salt-bearing beds, i the central part of the area there are two strips of Ter- ary sediments separated by a strip of Amargosa cha. Strontium Deposits, Southern California 17 ;he salt-bearing beds in the northern strip consist of >ek salt alternating with laminated red shales, massive i'd clays, fine thin-bedded red sands, and beds of breccia iith a matrix of red clay. The blocks of the breccias are ..entical with those in the breccia below the salt and in lases of the Amargosa chaos. In both the Salt Basin and lie Jnmbo Salt area are breccias of the black sandstone id epidotized shale with a matrix of salt. Almost no pure salt is present in the mapped part of the suthern strip of Tertiary sediments, though one of the rgest salt bodies of the area is in that strip west of Cave )rings Wash. East of Cave Springs Wash the salt beds Insist of laminated red shale, massive red clay, fine to !>arse red sandstone, and bright-yellow shale and sand. •rusts of salt resulting from efflorescence are present >arly everywhere, and a whitish bloom of salt is common, reshly broken rock tastes distinctly salty. The thickness of the salt beds has not been measured, it it ranges from about 100 to 600 feet. In the Jumbo dt area, where the red beds and salt combined are thin, e greater part of the thicker Salt Basin section is repre- |nted by breccia. The lateral gradation is accomplished rough thickening of the basal and interbedded breccias id thinning of the salt beds in the intervening area. Gradation from salt beds to breccia toward the north ross the axis of the anticline north of the Jumbo Salt also a result of the same cause. This is shown diagram- atically in section D-D', plate 1. The breccias in salt atrix are well exposed in the crest of the anticline on e line of the section, and salt bloom is present on the rface of the breccia as far as the summit of the hill at Je north end of the section. Interbedded salt and breccia ie well exposed in the cliffs on the east side of the large ish east of the Jumbo Salt area. South and southeast ■ the Jumbo Salt area red salty sand and shale appear be interbedded with the Amargosa chaos, though the ructure is complex and the relationship is therefore icertain. lOne small lens of celestite was found in the salt-bear- fa; beds 2,000 feet east of Cave Springs Wash, in the Jiiithern strip of Tertiary rocks. The salt beds are overlain by a sequence of highly ! psiferous beds of light-tan shale and sandstone that tatains nearly all of the celestite. The contact between |3 salt beds and the gypsiferous beds is gradational. Cpsuni is present to a minor degree in the top of the liderlying red beds, but becomes abundant at the hod- s' i where the color changes. Gypsum is most abundant i the lower part of the sequence, where it is present in lie-grained form in beds a fraction of an inch to several i 't thick that alternate with tan and greenish-yellow t ;.ys. The gypsum is mostly tan, gray, or greenish from ( ( stic impurities. The lower 50 feet of the sequence is 1 edominantly gypsum. South of Salt Basin, northwest eep Creek the gypsiferous unit is party conglomerate. The gypsiferous beds in the southern strip of sediments are neither so rich in gypsum nor so distinctly different from the salt beds as they are in the northern strip. Red and gray sands and red, gray, and tan shales alternate with thin beds of impure gypsum. Cross-bedding and graded-bedding are well developed in the sandstone of the gypsiferous unit, and numerous observations in the vicinity of the Salt Basin and the Jumbo Salt area show that the top of the beds is upward or toward the south. The salt beds therefore lie beneath the gypsiferous unit. The thickness of the gypsiferous unit is probably between 600 and 800 feet. Celestite forms nodules or concretions of small size in the gypsum and gypsiferous shale of the northern strip of sediments and in the Celestite Hills. Most of the celestite beds are closely associated with gypsum, but some are present in sandstone and shale without gypsum, particularly in the southern strip of sediments. The next higher unit consists of a heterogenous group of sediments that rest conformably and with gradational contact on the gypsiferous unit. Immediately southwest of the Salt Basin this unit consists dominantly of yellow and brown well-cemented sandstone, and therefore it crops out more prominently than the lower beds. Gray to brown clay shale and thin beds of gypsum constitute a minor fraction of the section. Here, and in the cliffs along Pipe Line Wash east of Salt Basin, cross-bedding and graded-bedding in the sandstone show that the beds are in normal position above the gypsiferous unit. West of Cottonwood Spring in the south strip of sedi- ments this higher unit consists largely of predominantly brown conglomerate and sandstone. The section becomes more conglomeratic and the pebbles become larger to- ward the top of the section. The pebbles of the conglom- erate are well-rounded, are in an abundant matrix of sand, and the bedding is well developed. From their general aspect the sediments are probably lacustrine in origin, though undoubtedly they are a near-shore facies. They are definitely not fanglomerates, as are the rocks of the succeeding Funeral fanglomerate. The unit has not been measured, but it is probably nearly a thousand feet thick. All of the sediments above the Amargosa chaos are probably Middle Tertiary or younger. If the Amargosa thrust is not older than Miocene, and if the Amargosa chaos contains Miocene rocks, then the sediments of the Avawatz are probably not older than upper Miocene, and they may be in part Pliocene. Funeral Fanglomerate. Gray to tan unconsolidated fanglomerate that rests unconformably on the sediments of Tertiary age are present south of the southern strip of sediments east of Cave Springs Wash, in Big Gypsum Hill, and in the Celestite Hills. The unconformity is well exposed at numerous places. These rocks have been corre- lated by Noble (oral communication, 1945) with the Fu- neral fanglomerate, which was named originally for an exposure farther north in the Death Valley region. Ac- cording to Noble the Funeral fanglomerate is probably late Pliocene but may be in part early Pleistocene in age. The nature of the unconformity is shown dia- gramatically in sections A-A' and C-C, plate 1. Quaternary Deposits. Terrace deposits of fanglomer- ate and stream gravel, formed in an earlier erosion cycle, 18 Special Report 32 cap many of the ridges far back toward the main mass of the Avawatz Mountains, and rise more than 100 feet above the level of the present streams. Structure The principal structural features of the region are il- lustrated on plate 1. The sections are only diagrammatic, however, as sufficient data for accurate sections could not be collected in the brief time devoted to the study. Two major faults of the region are virtually unknown to the writer. In the Virgin Springs area to the north, the base of the Amargosa chaos is the Amargosa thrust. Pre- sumably the Amargosa thrust is also present at the base of the chaos in the Avawatz area, but it is not exposed at any of the localities visited. South of the Tertiary sedi- ments and separating them from the crystalline complex of the Avawatz Mountains is a huge crush zone of gouge and breccia that was only casually examined in Sheep Creek. Several hundred feet of crushed rock is visible there, and the southern contact was not yet evident. The crush zone is subject to rapid erosion and thereby be- comes intricately gullied. The distribution of the gullied ground suggests that the fault zone extends the full length of the mapped area. According to Noble (oral com- munication, 1945) this is the Garlock fault, which extends far to the west of the area and beyond the town of Mojave, to where it eventually meets the San Andreas rift. After the episode of thrusting that resulted in the for- mation of the Amargosa chaos, the region became the site of a lake in which Tertiary sediments were deposited. The lake sediments and the Amargosa chaos Avere then folded and probably faulted. The area was then eroded and the Funeral fanglomerate was deposited across the cut sur- face. The beds were then folded and faulted a second time. Probably normal faulting, unaccompanied by fold- ing, took place at a still later date, for the large topo- graphic features of the- region as a whole are of the basin and range type. The double cycle of folding is illustrated in section A-A', taken across the Celestite Hills. Here the first period of folding was more intense than the second. West of Cave Springs Wash the Funeral fanglomerate is gently arched into an anticline tbat spans the full width of both strips of sediments. Although this part of the area was not mapped, the anticline does not appear to be broken by the large fault that separates the north strip of Tertiary sediments from the Amargosa chaos in the Salt Basin. The evidence suggests that the major faulting in the Ter- tiary accompanied the first period of folding. The fault mentioned above as present south of Salt Basin is shown in section C-C as a reverse fault in the middle limb of an overturned anticline. At the Jumbo Salt area the relationship is the same. Presumably the same fault continues eastward to and beyond Sheep Creek, and everywhere forms the south boundary of the northern strip of Tertiary sediments. The structural relations of the southern strip of Ter- tiary sediments are less clear. South of the Jumbo Salt area the structure is so complex that little could be made of it in the time available. A fault lies between the Amar- gosa chaos and the andesite; farther south another lies between the chaos and the salt-bearing beds. Between the two faults are alternating strips of chaos and salt-bear- ing sediments. Whether these strips are a depositional sequence or an imbricate structure remains to be deter- mined. The structure of Big Gypsum Hill is exceedingly in- tricate and involves low-dipping thrusts that have brought the gypsiferous unit of the Tertiary over Amar gosa chaos and the lower conglomerate. Well-exposec zones of gouge make the writer sure that the contact sur faces are faults. Section B-B' is an attempt to explain thi; structure. The arching of the thrust may be the result o: folding at the time of the second cycle, or it may con ceivably be an original curvature. Further study is re quired before a final interpretation can be made. At the northern end of section B-B' the Funeral fan glomerate is over-ridden by the gypsiferous beds on a re verse fault. This fault is important, for the fanglomerate are overturned beneath it, yet they have a gentle dip onb a few hundred feet away. Another post-Funeral fan glomerate reverse fault that dips in the opposite directioi is present at the head of Pipe Line Wash, where the faul is perfectly exposed at several places. Farther northwes the Funeral fanglomerate rests unconformably on th gypsiferous beds ; so the fault probably passes wholl; within the fanglomerate in that direction. The marked lack of mapped cross-faults is probably f o want of more detailed work. A small cross-fault is locate* at the west end of the Jumbo Salt area, and a relativel; large cross-fault must exist beneath the alluvium of th wash west of Cottonwood Spring, for geologic sequence on the two sides of the wash are different. Summary of the Geologic History Noble (1941, pp. 941-999) postulated the formation o the Amargosa chaos by movement along a flat thrust. I this mass of rock is of tectonic origin, it is easy to pictur a surface on it that lacked complete drainage. The writer impression is that there were one or more closed basins o that surface in the area, and that these were filled by lake or lakes. In the early stages the basins were the site of deposition of sedimentary breccias produced by redii tribution of the surface rocks of the chaos itself. The el mate must have been arid, for some of the breccias haV a matrix of salt. Continued sedimentation and evapor; tion resulted in the deposition of salt beds of considerabl thickness associated with beds of breccia, and red shal and fine-grained red sandstone were also depositee Around the margins of the basins of evaporation red seel ments that contain only a little salt were deposited. Prol ably the lakes then expanded, or perhaps several lake coalesced, as the water deepened to form a larger lake i which the succeeding series of gypsiferous beds were d posited. At this time the celestite was deposited also. Tl subsequent beds were less gypsiferous and more sand, and eventually conglomerate was deposited. The coar: clastic sediments may represent marginal deposits, or the may represent a final filling of the basin. One cannot 1 sure that the drainage remained closed throughout th time, but it likely did, as gypsum persists into beds ne; the top. The sediments were then compressed closely and tl folds were overturned. Reverse faults developed in tl overturned section, and the underlying chaos was thru over the gypsiferous unit. In the northwest part of tl area a thrust developed at a low angle, but younger bei remain over older beds. Strontium Deposits, Southern California 19 After a subsequent period of erosion the Funeral fanglo- j ^rate was deposited across the folded and faulted older ;rtiary rocks. The Funeral fanglomerate was then folded ; to gently dipping anticlines and synclines. Reverse f ault- :g accompanied this deformation, and the older Tertiary cks were thrust over Funeral fanglomerate along the :Tthern and southern sides of the area. Renewed erosion dissected the Funeral fanglomerate, jid resulted in the deposition of fanglomerates which now jle terrace deposits. A further slight uplift, or lowering j the base level, has caused the entrenchment of the pres- et streams below the terrace level. The role of the Garlock pit in this history is unknown. Occurrence of Celestite 1 Celestite is found in both the northern and the southern rips of Tertiary sediments, mostly in the gypsiferous lit. It is present over a distance of approximately 7 miles, om a little west of Cottonwood Spring to the Celestite ills. The most important deposits are in the southern ; ?ip east of Cave Springs Wash and in the Celestite Hills. Individual beds or groups of celestite beds, where large >; ough to be shown without too much exaggeration, were ipped separately. That part of the gypsiferous unit lich contains thin beds and concretions of celestite too tall to be shown on the map was mapped as a separate lit. The celestite is present in three related modes of deposi- >n : as small nodules or concretions in gypsum, as typical iheroidal concretions in clastic sediments, and as beds : gypsum and in clastic sediments usually closely asso- rted with gypsum. The nodules in gypsum are composed of very pure dense ■ lite fine-grained celestite. They range in diameter from '. :s than an inch to 6 inches. Most of them are between and 3 inches. They are generally regular in shape; ] ttened or elongated spheroidal forms are most common. . few have knobby surfaces, and most of them have a ' iread crust" appearance, owing to polygonal cracks over ; )art of the surface. These celestite concretions are strewn abundantly over fe surface of the gypsiferous beds in the Celestite Hills ; : d at Big Gypsum Hill. They also are present in the gyp- m south of Salt Basin, and are sparingly present else- T iere in the area. At the Celestite Hills they are very :undant on the surface, but they can be found in place ( ly with difficulty. Apparently the nodules were concen- Uted on the surface as the surface was lowered by ero- s;n. Several concretions found in place there show the 'read crust" surface, which is therefore an original fiture. The celestite concretions in the clastic sediments are 1 s pure than those in the gypsum. Most of them are gray ( brown in color ; many are highly porous and contain s id grains, particularly in the outer portions. They i lge in size from an inch in diameter to 15 feet in length <1 3 feet in thickness. They usually are in interbedded c y shale, silty or sandy shale, and sandstone. A number c the smaller bodies shown on the map are of this type. The beds of celestite vary considerably in appearance i m place to place. In the Celestite Hills, where several c sely spaced beds form a large lens, they are in gypsum i erbedded with shale. Some of the celestite is porous c 1 granular and some is dense and granular. Much of it is composed of matted acicular crystals of celestite 1 to 3 mm long in either dense or porous aggregates. It varies in color, depending probably on included impurities. Some is white, light green, and pink ; most of it is gray and some is quite black, owing to included manganese oxides. Single celestite beds range in thickness from an inch to H feet. Several beds separated only by partings of clay or gypsum constitute celestite-rich units as much as 6 feet thick. The surfaces of the beds are generally well defined, but close examination revealed a narrow transi- tion zone between the celestite and the adjacent sedi- ments. The transition zone, which is only a few millimeters thick, consists of celestite, sand grains, clay, and gypsum. The amount of celestite decreases gradually, and the amount of sediment increases outward from the celestite bed. Moore (Hewett et al., 1936, p. 159) measured five sections in the Celestite Hills, three of which are repro- duced below. Sections 1, 2, and 3, located respectively at the middle of the celestite lens, at the thickest part of the lens, and at the north end, are Moore's sections 1, 3, and 4 and 5 combined. Section 1. Celestite Hilh: middle of lens. Feet Inches Gypsum 4 Massively bedded medium-grained celestite rock 3 Green gypsiferous celestite rock 3 Gypsiferous celestite rock 2 2 Greenish gypsiferous clayey celestite rock 3 Massively bedded medium-grained celestite rock 2 2 Manganiferous, gypsiferous celestite rock 1 + Total thickness 13 + Total celestite 9 Section 2. Celestite Hills: thickest part of lens. Feet Inches Gypsum Massively bedded medium-grained celestite rock, man- ganiferous at base 3 6 Massively bedded medium-grained celestite rock 2 6 Manganiferous gypsum 1 6 Massively bedded medium-grained celestite rock, man- ganiferous 6 Massively bedded medium-grained celestite rock 1 7 Interbedded celestite rock and gypsum 6 Gypsum 5 6 Gypsiferous clays Total thickness 22 5 Total celestite 13 11 Section 3. Celestite Hills: north end of lens. Feet Inches Manganiferous gypsum, with masses of medium-grained celestite rock near base 4 Gypsiferous and manganiferous celestite rock 2 Manganiferous gypsum ; contains much celestite in scattered crystals 1 6 Gypsum with reniform nodules of medium-grained celestite H Nodules of medium-grained celestite, forming bed 6 Gypsum 4 Massively bedded medium-grained celestite rock 3 Gypsum 4 Gypsiferous clays Total thickness 27 3 Total celestite 6 9 The bedded celestite in the southern strip of sediments east of Cave Springs Wash is in fine red and gray sand- stone and red shale immediately above gypsum. The celes- tite is gray on fresh surfaces, but weathers dull brown. 20 Special Report 32 The bulk of it is fine grained and porous in texture, and some of the cavities are lined with small crystals. Most of the celestite feels light in the hand. Because of the porosity the aggregate specific gravity is probably less than 3. Internal bedding planes are usually lacking, but faint traces of bedding often present near the margins are the result of included sand grains. Nearly all of the celestite at this locality contains a little sand. The surfaces of the beds are smooth and well defined, but a narrow transition zone separates the celestite from the adjacent clastic sediments. Concretions of celestite are present also ; they are confined to certain zones where they are separated laterally from each other by a few inches to several feet of sediment. A section measured across the large body of celestite at a sharp bend in the creek about 1,200 feet east of Cave Springs "Wash is presented below as section 4. Section .}. East of Cave Springs Wash. Feet Thin-bedded red and gray sandstone and shale Massive porous celestite in short concretionary lenses 1.0 Thin-bedded red silty and sandy shale 7.2 Massive porous celestite 0.8 Thin-bedded red silty sandstone 6.1 Massive porous celestite 2.4 Red and gray silty shale and sandstone 13.5 Massive porous celestite in short concretionary lenses 1.0 Red shale and silty sandstone 15.7 Massive porous celestite 3.3 Thin-bedded red silty shale and silty sandstone 6.4 Massive porous celestite 2.2 Red clay 0.4 Massive porous celestite 2.0 Thin-bedded red and gray sandstone and silty clay Total thickness 62.0 Total celestite 12.7 The separately mapped lenses of celestite south of Salt Basin are like the last-mentioned beds. The celestite beds in the larger body range in thickness from 0.3 to 1 foot. The total thickness of celestite is about 4 feet. All of it is porous and feels light in the hand. Both of the lenses shown on the map terminate in depth above the level of the adjacent streams. A few of the larger bodies in the vicinity of the Jumbo Salt area are shown on the map, though greatly exag- gerated in thickness. They are mostly no more than 1^ feet thick and 30 to 50 feet long. Four prominent lenses are present at the east end of the Jumbo Salt area. The northern lens contains about 10 feet of celestite in 25 feet of beds. The two central lenses are each about 1^ feet thick, and the southern lens consists of a chain of short concretionary beds 1 to 2 feet thick and 10 to 25 feet long. In addition to the celestite bodies separately shown there are innumerable beds an inch to a foot thick and 5 to 100 feet long in that part of the gypsiferous unit shown as Tg on plate 1. This unit ranges from about 100 feet at the west end of the Jumbo Salt area to 50 feet near the east end, beyond which it thickens again. Five to 10 per- cent of this unit is estimated to consist of porous celestite in thin beds and concretions that weather dark brown. It is also estimated that not more than 70 percent of celestite rock is strontium sulfate. The celestite in the northern strip of sediments between the Jumbo Salt area and the wash northwest of Cottonwood Spring is similar to that in the Celestite Hills. It is mostly in gypsum that contains streaks of manganese oxides ; moreover, most of the celes- tite contains manganese. The maximum thickness of the lens shown on the map is about 4 feet. Concretions and thin lenses are also included in the celestite-bearing beds there to an extent not exceeding 5 percent. The celestite in Big Gypsum Hill is similar to that in the Celestite Hills. It is mostly in gypsum as beds nol more than a foot thick, and in short concretionary lenses a foot thick and as much as 10 feet in diameter. Small nodules are present in the gypsum and are strewn ovei the surface of the hills. The beds lie nearly flat, and the celestite-bearing part of the section is exposed in severa" trenches. The maximum thickness of celestite is about l feet, and the average thickness is probably about 1 foot Most of the celestite is porous and weathers brown ; hut a little is dense, light-colored, and heavy. Origin of the Celestite Beds and concretions of celestite, widely distributee laterally and rather closely confined stratigraphically, ir lake sediments that also contain salt and gypsum lead a' once to the assumption that the celestite is sedimentary ir origin. The writer has found no reason to doubt that this is true. Moore (1935, pp. 3, 15) was of the opinion tha 1 the celestite was sedimentary, and also that it was a direc precipitate from the lake waters. He stated that th< celestite bodies "show no signs of replacement, but ar< apparently the result of deposition of masses of crystal line celestite and gypsum as a chemical precipitate." The opinion of the present writer is, however, that the celestiti bodies were formed by replacement. In the Celestite Hills, at Big Gypsum Hill, south o: Salt Basin, and northwest of Cottonwood Spring, smal nodules of dense white celestite occur in the gypsum. Un doubtedly these nodules were formed by some process o replacement after the gypsum was deposited. They hav no internal structures to indicate that they formed h accretion. It is difficult to conceive of them as direct pre cipitates. The strontium sulfate must have been precipi tated from the connate water that saturated the gypsum Concretions of porous celestite in clastic sediments hav been described in the preceding section. They range frori an inch in diameter to 15 feet in length and 3 feet ii thickness. They are smoothly rounded at the margins truncate the bedding of the enclosing sediments, and the; are not internally bedded. The abutting bedding plane show distinctly on the surface of the concretions, whicl are impure near the margins owing to residual inclusion of sand and clay. The present writer believes that thes concretions were formed by replacement of the clasti sediments without disturbance of the stratification of th surrounding material. No concept of direct precipitatio: from the lake waters can account for their form an* boundary relationships. Like the concretions in gypsun they must have been formed by the precipitation of stron tium sulfate from connate waters within the sediments The celestite beds in clastic sediments are not differen from the concretions in the clastic sediments other tha: in their dimensions, for they grade continuously in siz from thin short beds that are only very thin concretion up to the largest beds which are 3 feet thick and severa hundred feet long. Concretions a foot thick and severa feet in diameter, confined to a bed and separated fror each other in the bedding plane by only a few inches t Strontium Deposits, Southern California 21 few feet of sediment, are present at two horizons in •etion 4, east of Cave Springs Wash. If these concretions id grown a little larger, they would have coalesced to »rm beds only a foot thick. Texturally and structurally ley are identical with the neighboring celestite beds, hese facts indicate to the writer that the beds of celestite •e only greatly elongated concretions. They may aetu- \\y have developed by the growth and coalescence of lmerous concretions formed at the same horizon and >ntrolled in position by lithologic differences in the pre- ;isting sediments. Under this view the beds are also re- acement deposits. i In the Celestite Hills there are beds in gypsum that are mposed of matted needles of celestite. Most of the >edles are so disposed that their length is in, or nearly in, e bedding plane. Moore (1935, pp. 3, 15) believed that is celestite was precipitated directly from the lake aters above. This possibility must be seriously enter- ined, but if it is the origin of these beds, it accounts for dy a very small part of the celestite in the district. On e other hand, it is equally probable, perhaps more so in |ew of the associated celestite nodules of replacement igin, that this material was also formed by replacement, ie formation of relatively pure crystals of many min- !als in wet clays of the playas of the desert region by ecipitation of their constituents from the interstitial liter of the sediments is a familiar phenomenon. The ■ ientation of the needles in the bedding planes could well the result of the influence of bedding planes, or of clay ; d gypsum crystals oriented in sedimentation. The au- or favors the view that these beds are also of replace- ment origin. Chemical Composition of the Celestite Three chemical analyses of celestite are available from italen's report (1914, p. 530). Analyses I and II, by " . C. AVheeler, of the U. S. Geological Survey, are partial < alyses of material collected by Phalen near the west id of the area studied. Analysis III, by R. A. Perez, of 1 s Angeles, California, was furnished to Phelan by the . awatz Salt and Gypsum Company. I II in !rO 38.41 47.92 50.99 JaO 0.75 $aO Trace i0 3 42.38 [iO, 0.92 ■: Total 95.04 rSO, - 68.11 84.98 90.42 average, 81 percent. The data are hardly sufficient to use in calculating re- serves for such a large area, but, in the judgment of the writer the bulk of the celestite is no better in grade than the average of the three analyses, which is therefore satis- factory for preliminary estimates. RESERVES No precise estimates can be given of the reserves of celestite in the area studied, for the dimensions of the many celestite bodies have not been accurately deter- mined, and the analytical data are insufficient. It is estimated, however, that the deposits contain between 250,000 and 300,000 tons of celestite rock to a depth of 50 feet. This estimate includes all the exposed celestite bodies that can possibly be considered to have economic im- portance, and some that evidently do not. In addition there are numerous small lenses and concretions that contain from a ton to several hundred tons of celestite. The calculations are based on an assumed weight of the- celestite rock of 200 pounds per cubic foot, which corre- sponds to a specific gravity of slightly more than 3. Almost half of the total celestite is in the celestite- bearing gypsiferous beds in the Jumbo Salt area. Yet considering that the celestite is widely distributed through at least 10 times that amount of shale, sand, and gypsum, and that only a few small bodies could be mined for celestite rock alone, it is unlikely that any of the- celestite could be profitably recovered. The larger body at the Salt Basin is very small, though it could be easily mined. It is probably not of economic importance. The two areas that are most likely to be of commercial importance are the Celestite Hills and the area east of Cave Springs Wash in the southern strip of sediments. REFERENCES Hewett, D. F., Moore, B. N., Callaghan, Eugene, Nolan, T. B. r Rubey, W. W., and Schaller, W. T. (1936), Mineral resources of the region around Boulder Dam : U. S. Geol. Survey Bull. 871, 197 pp. Moore, B. N. (1935), Some strontium deposits of southeastern California and western Arizona : Am. Inst. Min. Met. Eng. Tech. Pub. 599, pp. 1-24. Noble, L. F. (1941), Structural features of the Virgin Springs area, Death Vallev, California : Geol. Soc. America Bull. 52, pp. 941-999. Phalen, W. C. (1914), Celestite deposits in California and Ari- zona : U. S. Geol. Survey Bull. 540, pt. 1, pp. 521-533. Tucker, W. B., and Sampson, R. J. (1930), Los Angeles field divi- sion : California Jour. Mines and Geology, vol. 26, pp. 202-324. Tucker, W. B., and Sampson, R. J. (1943), Mineral resources of San Bernardino County, California : California Jour. Mines and. Geology, vol. 39, pp. 427-549. THE SOLOMON AND ROSS STRONTIANITE DEPOSITS, MUD HILLS SAN BERNARDINO COUNTY, CALIFORNIA * By Cordell Durrell OUTLINE OF REPORT Page !>stract 23 itroduction 23 eology of the Mud Hills 24 eology of the Solomon strontianite deposit 25 eology of the Ross strontianite deposit 34 eferences 36 Illustrations Plate 2. Geologic map of the Ross strontianite deposit. Mud Hills, San Bernardino County, Cali- fornia In pocket 3. Structure sections, east end of Mud Hills, San Bernardino County, California In pocket 4. Columnar sections, Tertiary beds of the Bar- stow syncline, east end of Mud Hills, San Bernardino County, California In pocket 5. Geologic map of the Solomon strontianite deposit, Mud Hills, San Bernardino County, California In pocket 6. Structure sections, Solomon strontianite de- posit, Mud Hills, San Bernardino County, California In pocket 7. Map showing abundance of strontianite, Solo- mon strontianite deposit, San Bernardino County, California In pocket igure S. Map showing location of the Solomon and Ross strontianite deposits 23 9. Detail of strontianite-rock lens 30 10. Detail of strontianite rock transgressing bedding 30 11. Diagrams showing strontianite rock localized by faults 31 12. Location and claims map, Ross and Solomon stron- tianite deposits east end of Mud Hills, San Bernar- dino County, California 35 ABSTRACT The Solomon and Ross strontianite deposits, about half a mile art, are in the east end of the Mud Hills, northeast of Barstow, '.lifornia, in the extreme southeast corner of the Searles Lake adrangle. The strontianite occurs as bedlike and crosscutting bodies that alaced clays and tuffs that have been generally referred to as the >samond series. At the Solomon deposit two principal zones out 10 and 25 feet thick, separated by about 20 feet of barren ly, contain most of the strontianite. At the Ross deposit numerous dular and lenticular beds of strontianite are distributed vertically •ough 186 feet of green clay. The strontianite-bearing zone of the >ss deposit is 465 feet higher in the stratigraphic section than it of the Solomon deposit. The Solomon deposit, which was first worked in 1917, yielded a all production at that time and has been inactive since. In ent years small amounts of strontianite have been mined from ! Ross deposit. INTRODUCTION The Solomon and Ross strontianite deposits described this report are in the Mud Hills, which comprise the ;?ond range north of the town of Barstow and are in e extreme southeast corner of the Searles Lake quad- ngle (1:250,000), at an altitude between 3,000 and )00 feet (fig. 8). The northern part of the hills is com- sed of granitic rocks; the southern part consists of ■rtiary tuffs and lacustrine and fluviatile sediments that a folded into an east-trending trough which has been ' 'led the Barstow syncline. The lacustrine clays and ben- •ublication authorized by the Director, U. S. Geological Survey. Manuscript submitted for publication January 1953. tonites in the trough of the syncline are readily converted to slippery mud by even slight rains, a fact that probably accounts for the name of the hills. The region is arid and is sparsely covered with desert shrubs and Joshua trees. No flowing streams or springs are present either within the Mud Hills or in nearby areas. The Solomon strontianite deposit is in sec. 20, T. 11 N., R. 1 W., S. B., at an altitude of 3,200 to 3,400 feet, on the north limb of the Barstow syncline. A fair dirt road leads from the paved highway to the east end of the deposit. The Ross strontianite deposit is half a mile to the southwest in the NWi sec. 30, T. 11 N., R, 1 W., S. B., on the south limb of the syncline. The Ross deposit, between 3,050 and 3,100 feet in altitude, is reached by a dirt road leading north- ward from a graded but unpaved road that traverses the valley south of the hills and that branches westward from the paved road a little south of the valley trough. History of the Area. Strontianite was discovered in the Mud Hills in 1915 by Henry Hart and T. G. Nicklin. Soon thereafter the deposits were examined by Adolph Knopf (1918) who prepared a report that includes a sum- mary of the early history of the area. A few additional historical facts of interest that have become known to the present writer are added here. Knopf recorded the output of strontianite rock in 1917 as 500 tons. Lubin J. Henderson of Barstow, who is one of the original claimants, told the writer that he and T. G. Nicklin shipped ' ' several tons ' ' of carefully hand-picked R2W ri w tun TION T9N Figure 8. Map showing location of the Solomon and Ross strontianite deposits. (23) 24 Special Report 32 material that ran 84.32 percent strontium carbonate. Earl T. Ross, research chemist for the Stauffer Chemical Company, Los Angeles, who is the present owner of the Ross strontianite deposit, states that a shipment was made at about that time to the Rare Metals Refining Company of Pasadena, California, by whom he was then employed. The strontianite was refined into strontium salts and presumably was marketed. Henderson and Nicklin then sold their claims to Thomas J. Neilan of San Francisco, who, according to Mr. Henderson, shipped 16 carloads of strontianite rock to a plant near San Francisco, where it was dumped be- cause it was of too low grade. About 1920 the claims were sold to Mr. C. Solomon, Jr., of San Francisco, who patented them in 1923 and who is the present owner. The production noted above is believed to have come entirely from section 20 and therefore from the area des- ignated in this report as the Solomon deposit. This is af- firmed by Mr. Ross, and the writer has seen no cuts or excavations of any size outside of that area. There has apparently been no more recent production from the Solomon deposit. Knopf (1918, p. 260) referred to the strontianite in the sediments of the south limb of the Barstow syncline and spoke of this as the western part of the area. Probably this is the area herein called the Ross deposit, owned by Earl T. Ross. No other record has been found concern- ing this deposit prior to its rediscovery by Ross. Though it is the lesser deposit, it is the one from which production has recently been made. At intervals Mr. Ross extracts strontianite rock, which he converts and markets as chemically pure strontium hydrate. The locations and names of claims are shown on figure 12. No significant amounts of strontianite are known out- side of these two deposits near the eastern end of Mud Hills, though small amounts are found elsewhere in the vicinity. According to Mr. Henderson, strontianite has also been found in the area of granitic rocks in the north- ern part of the Mud Hills. No geologic work more recent than that of Knopf has been done on the area, though brief mention of the de- posits is made in several reports of the California State Division of Mines on the Mineral Resources of San Ber- nardino County (Tucker and Sampson, 1930, p. 323; 1943. p. 543) and in a chapter on strontium minerals by B. N. Moore in a U. S. Geological Survey report on the mineral resources of the region around Boulder Dam (Hewett et al., 1936, p. 160). The present project was a part of the IT. S. Geological Survey's World War II program for the investigation of strategic minerals. The field work was done in 1945. Acknowledgments. The writer is indebted to Mr. Lubin J. Henderson, of Barstow, California, for informa- tion on the early history of the deposits. Mr. C. Solomon, Jr., of San Francisco, kindly supplied information con- cerning his property and gave his permission to study the deposit and to publish the data resulting from the study. Mr. Earl T. Ross gave much information about the history of the area. He furnished nine partial chemical analyses of strontianite rock presented in this report as well as an outline map summarizing his knowledge of the area ; he gave his permission to publish all the data. The writer is grateful to these persons for their assistance The author was assisted in the field and in the preparatior of the maps by Mr. A. Cowles Daley. GEOLOGY OF THE MUD HILLS Stratigraphy. The northern half of the Mud Hills i: : composed of granitic rocks of indefinite but certainly pre Tertiary age. The southern half of the hills is composec of relatively soft and easily eroded tuffs and lacustrim sediments of Tertiary age, which have been folded into ; complex east-trending structure generally known as th Barstow syncline. The sediments of the central and south ern portions of the syncline were beveled by erosion am covered by alluvial deposits of Pleistocene or Recent age Later an elevation of the range, or, conversely, a lowerin) of base level, resulted in the cutting of new canyons int< the Tertiary sediments, which are generally separate* from one another by terrace remnants of the older al luvial deposits. The lower courses of the main canyon are flanked by extensive areas of colorful badlands. Th headward parts of the stream canyons, which traverse th somewhat more resistant and higher-standing basal tuff and breccias, were incised at the same time to form vei tical-walled gorges, some of which are barely passable o: foot. Vertebrate fossils in the higher beds of the section a the west end of the Mud Hills were brought to the atten tion of J. C. Merriam in 1911, who prepared a series o papers on the remains. This work is summarized in final paper by Merriam (1919). A geological reconnais sance of the Mojave Desert region by C. L. Baker (191L made in connection with the paleontological investigf tions of Merriam, was published in 1911. This report cor tains a large amount of information on the west and cer tral parts of the Mud Hills and includes a cross sectio but not a geologic map. The Tertiary rocks of the Mud Hills, the higher bee of which are upper Miocene (Merriam, 1919, p. 454) i age, are generally known as the Rosamond series, a nan first applied by Hershey (1902, pp. 349-372) to beds nee Rosamond and Mojave, and extended to the Barstow svi cline by Baker (1911, pp. 339-341). Because of rapid changes in lithology, it has not bee possible to correlate the stratigraphy at the east end < the Mud Hills with that given by Baker for the west em The writer has, therefore, measured his own stratigraph sections at the east end of the hills near the strontiani deposits. The lines of these sections are shown on figui 12 and the data are presented both as structure section plate 3, and as columnar sections, plate 4. The Tertiary rocks rest unconformably on the granit rocks of the northern part of the hills. These Tertiar rocks consist of 265 feet of thin-bedded tuff and clast sediments at the base, which in turn are overlain co formably by slightly more than 2,500 feet of rhyolite tu: breccia and granitic breccia. The granitic breccia mostly at the top in this section, but rapid changes tal place along the strike, and great lenses of granitic bre cia, scarcely distinguishable from granite in place, cor and go in the tuff-breccia. There is scarcely any trace bedding in this section, except for a rather persistent th bed of sand and conglomerate at the base of the first thi granitic breccia. Strontium Deposits, Southern California 25 In two places granitic breccia has been intruded by ikes of dense, white rhyolite breccia. A heavy conglomerate, composed almost exclusively of Spite boulders, overlies the uppermost granitic breccia id forms the uppermost unit of a thick sequence of larse and almost unstratified sedimentary materials that ,'e certainly of continental origin, probably lacustrine. j The succeeding black-weathering algal limestone unit, n feet thick, marks the beginning of a change to finer astic sediments, although conglomerates are not absent the higher beds. The limestone is overlain by 137 feet ' dark-green and gray tuffaceous sandstone that include ■ me conglomerate ; this sandstone is in turn overlain by 2- to 4-foot bed of white to gray calcareous rhyolite tuff. ,bove the tuff is 25 feet of beds that are in part like the nd beds below the tuff, but are also in places bright red nd and shale. On the south limb of the syncline the red •els are 65 feet thick (see sec. C-C, pi. 3). The red beds are overlain on the north limb of the syn- ine by about 120 feet of yellow and green clay, buff arl, and white tuff, all of which are gypsiferous, and ihich include the strontianite-bearing beds of the Solo- on deposit (see sec. A- A' and B-B', pi. 3). The cor- isponding lithologically similar beds on the south limb the syncline south of the Ross deposit are 75 feet thick eesec. C-C, pi. 3). The succeeding beds form a highly varied sequence out 1,300 feet thick composed predominantly of green id buff clay, brown bentonite, white, yellow, and gray *ff, and buff limestone, with some fine sandstone and nglomerate at the base. The strontianite-bearing green liy of the Ross deposit rests directly on the sandstone . d conglomerate (see sec. C-C, pi. 3). Algal nodules are common in the finer sediments, and • lcareous concretions are found everywhere. The whole i raence is gypsiferous ; the gypsum forms veinlets and ilitary crystals but no beds. The lithology varies rapidly ong the strike, as may be seen by comparing the strat- i 'aphic section measured along cross section C-C with at measured along cross section A- A', plate 3. The full ickness of the sequence of finer clastic sediments that 1 gins at the base with the black-weathering algal lime- j me is about 1,700 feet. All these finer sediments are of 1'ustrine origin. The upper 450 feet along section A- A', plate 3, is com- ]sed of yellow and brown poorly sorted and poorly con- f idated cross-bedded sandstone, conglomeratic sand- i»ne, and conglomerate. This sandstone and conglomer- wn on section B-B', plate 3, just south of the synclinal £ s. The lower beds contain no strontianite beyond the I -its of the geologically mapped area. The upper beds c itain a small amount as far as the line of section B-B', I I only in the most northern exposure, for in the trough of the Barstow syncline, where the beds are well exposed, no strontianite could be found. The distance in an easterly direction over which stron- tianite rock crops out is about a mile. How much farther east and southward down the dip it may extend is un- known. The strontianite-bearing sandstones occur only in the east-central part of the area. Because they are so re- stricted and do not constitute a distinct stratigraphic unit, they need no further consideration. Abundance of Strontianite Bock. Six stratigraphic sections, four across the upper strontianite-bearing beds and two across the lower beds, were measured in order to determine the amounts of strontianite rock contained in them. These sections, which also give the detailed lithol- ogy of the two beds, were chosen so as to be as repre- sentative of the area as exposures and convenience would permit. Their positions are indicated on the geologic map, plate 5. Section 1, Solomon strontianite deposit: upper strontianite beds. Feet Buff and light-green laminated clay 1.9 Buff marl 0.1 Buff and light-green laminated tuffaceous clay 0.3 Light-green massive tuff or tuffaceous clay 2.9 Buff and light-green laminated clay 0.9 Buff marl 0.2 Strontianite rock (has replaced buff clay) 0.4 Interbedded buff marl and brown clay 0.9 Brown claystone 0.25 Buff and light-green laminated clay 0.1 Strontianite rock (has replaced paper-thin laminated clay) 0.05 Buff and light-green laminated tuffaceous clay 1.0 Cream-colored thin-bedded tuff and tuffaceous clay 0.3 Buff and light-green laminated tuffaceous clay 1.3 Dark-green tuffaceous claystone Total thickness 10.6 Total thickness of strontianite 0.45 Percent strontianite 4.2 Section 2, Solomon strontianite deposit: upper strontianite beds. Feet Light cream-colored nodular algal limestone 1.0 Buff to white laminated clay with laminae of cream to white limestone 1.3 Strontianite rock (has replaced buff and light-green tuffaceous clay and buff tuff) 1.3 Buff and light-green laminated clay 0.3 Light-green massive tuff or tuffaceous clay 2.5 Strontianite rock (has replaced buff tuffaceous clay and a few thin stringers of marl) 1.2 Light-green massive clay 0.3 Buff marl 0.4 Light-green massive clay 0.2 Strontianite rock, and thin veinlets of celestite (has replaced buff and light-green laminated tuffaceous clay and a few thin stringers of marl) 0.6 Buff and light-green laminated tuffaceous clay and a few thin streaks of marl 1.6 Gray to cream laminated calcareous tuff 0.4 Buff marl and tuffaceous marl 0.4 Buff and light-green laminated tuffaceous clay 1.2 Cream-colored laminated calcareous tuff 0.3 Dark-green massive claystone Total thickness 13.0 Total thickness of strontianite 3.1 Percent strontianite 23.8 28 Special Report 32 Section 3, Solomon strontianite deposit: upper strontianite beds. Feet Light-yellow sandstone 0.2 Buff to light-yellow sandy tuff 1.4 Light-green tuffaceous clay 0.4 Light-yellow sandy tuff 0.6 Light-green tuffaceous clay 0.4 Buff thin-bedded tuff 0.2 Light-green tuffaceous clay 0.9 Buff and light-green laminated clay 0.4 Buff and light-green laminated clay, probably partly replaced by strontianite 0.5 Buff and pale-green laminated clay, buff to white tuff and buff marl 0.8 Buff to yellow marl 0.6 Buff to light-green thin-bedded calcareous tuff 0.3 Strontianite rock (has replaced buff and green laminated clay) 0.3 Buff tuffaceous marl 0.4 Strontianite rock (has replaced buff and light-green laminated clay) 0.2 Buff and light-green laminated clay, probably partly replaced by strontianite 0.1 Strontianite rock (has replaced buff and light-green laminated clay) 0.1 Buff to white thin-bedded tuff 0.3 Buff and light-green laminated tuffaceous clay 1.1 Dark-green tuffaceous claystone Total thickness 9.2 Total thickness of strontianite 0.6 Percent strontianite 6.52 Section Jf, Solomon strontianite deposit: upper strontianite beds. Feet Light-green tuffaceous clay 1.0 Strontianite rock 0.5 Light-green tuffaceous clay 1.1 Strontianite rock and veinlets of celestite (has replaced marly tuff) 0.6 Buff and light-green laminated tuffaceous clay with a few thin stringers of marl 0.8 Strontianite rock (has replaced marly tuff) 0.3 Mostly green massive tuffaceous clay but contains a few thin beds of buff and light-green laminated clay 4.2 Buff marly tuff 0.2 Buff and light-green laminated tuffaceous clay 2.3 Dark-green tuffaceous claystone Total thickness 11.0 Total thickness of strontianite 1.4 Percent strontianite 12.7 Section J, Solomon strontianite deposit: lower strontianite beds. Section 5a, upper part. Feet Buff and green laminated clay with few thin buff limestone laminae 0.7 Buff and pale-green laminated clay with streaks of sand 1.9 Sandy tuffaceous green clay ; beds as much as 0.2 foot thick — 1.8 AVhite to buff tuffaceous clay in paper-thin laminae and thin limestone laminae 0.7 Buff tuffaceous marl 0.2 Buff and green laminated tuffaceous clay 0.7 Strontianite rock and thin veinlets of celestite (has replaced buff and light-green laminated tuffaceous clay) 1.0 AVhite to brown laminated tuffaceous clay with abundant laminae of limestone and argillaceous limestone 5.1 Buff and light-green massive tuffaceous clay 1.9 Buff and light-green laminated tuffaceous clay 0.9 Light-green massive tuffaceous clay 1.45 White biotite-bearing tuff 0.05 Total thickness 16.4 Total thickness of strontianite 1.0 Percent strontianite 6.1 Section ob, loner part. White biotite-bearing tuff Light-green massive tuffaceous clay Buff and brown massive silty clay Buff tuffaceous marl Massive to laminated buff tuffaceous clav Buff marl Buff massive tuffaceous clay Buff laminated tuffaceous clay Buff massive tuffaceous clay Gray and buff laminated clay and silty clay and veinlets of celestite parallel to bedding; three bands each one-fourth inch thick probably contain some strontianite ; this zone carries strontianite at other places Buff and green laminated tuffaceous clay ; probably contains some strontianite Buff and brown laminated to massive tuffaceous clay Fine green silty clay Fine-grained reddish-brown silty sandstone Fe CL : l.i O.J 2.: o.: 0.( 4.1 0.- Total thickness 13.j Total thickness of strontianite 0.1 Percent strontianite 0.0 Total thickness of lower beds, sections 5a and 5b com- bined 30.: Percent strontianite for lower beds, sec- tions 5a us strontianite thereby forms irregular veinlike m^ .es within the dense strontianite rock. mong the pieces of fibrous float found near the east I of the body are some pieces that contain crystals of in tz and feldspar, indicating that this material may m resulted from the recrystallization of the dense ma- iei 1 that had previously replaced tuffs. In any case it 9ft s clear that the long fibrous material is later than the 'le e variety. At several places near the west end of the le sit, final cavities remaining between the spherules of fibrous strontianite have been filled with grayish-brown chalcedony. Celestite in small amounts is present throughout the deposit. It is easily recognizable by its white color and slender tapering crystals with a rhombic cross section. Crude crystals form matlike masses a millimeter or two thick parallel to the bedding of the clay. Many portions of the strontianite rock that are porous show minute but perfect and brilliant crystals. In the concretionary bodies of strontianite rock controlled by faults, there are in nearly all cases thin veinlets of celestite in the actual fault surfaces. The amount of celestite is never large, probably never more than 5 percent of the strontianite rock, and more usually only about 1 percent. Celestite is slightly more abundant in the lower horizon than in the upper. Knopf (1918, p. 264) thought that the celestite was probably secondary, produced by reaction of the stron- tianite with calcium sulfate solutions formed by surface water and the ubiquitous gypsum. The present writer agrees with this view except for the celestite that fills the faults along which the strontianite rock replaced the tuff- aceous clay. This celestite is perhaps primary in the same sense as the strontianite, though it is younger. Chemical Composition of the Strontianite Bock. It has been shown that the strontianite rock was formed by the replacement of other rocks ; much of it is impure be- cause the replacement was incomplete. Grains of quartz and feldspar and fragments of other minerals and rocks are megascopically evident in most of it. Knopf (1918, p. 261) reported that strontianite is never pure SrCC>3, but always contains CaC0 3 isomorphously. A carefully se- lected sample collected by Knopf, probably near the east end of the Solomon deposit (table 1), contains 10.25 per- cent CaCOs in solid solution. The available analyses of material from the Solomon deposit are given in table 1 below. Analyses I and II are by R. C. Wells, from U. S. Geological Survey Bulletin 660. Analyses III to VIII are by Earl T. Ross, research chemist for the Stauffer Chemical Company, Los An- geles, California, and owner of the Ross strontianite de- posit, and were made available by him. Analysis I represents a selected specimen of stron- tianite. Analyses II to VII are of strontianite rock. An- alysis VIII is obviously of a limestone and need not be considered further. Though the exact locality of the sam- ples is not known, the analyzed specimens probably are quite representative of the deposit. The analyses indicate that materials other than the carbonates of strontium and calcium generally constitute from 5 to 20 percent of the samples and average about 13 percent. The author's observations in the field con- firm a value of this magnitude. Strontium carbonate con- tent ranges from 59 to 87 percent and averages about 73 percent. The ratio of the weight of calcium carbonate to strontium carbonate averages 0.18, and for the most part, is probably less than 0.2 in most of the material that is considered as strontianite rock. Material other than the two carbonates includes celes- tite, gypsum, quartz, feldspar, and fragments of other rocks and minerals insoluble in cold acid. It is the au- thor's opinion, based solely on field observation, that the amount of celestite does not ordinarily exceed 5 percent of the rock, and is probably generally less than 1 percent. 32 Special Report 32 Table 1. Analyses of stroniianite rock. I II Ill IV V VI VII VIII Averages II-V SrO 60.99 6.40 None 29.86 (computed) 0.05 55.20 5.19 None 28.18 0.28 5.59 1.17 59.51 20.91 19.58 82.51 12.32 5.16 71.08 14.05 14.87 87.. 13_. n.d. 84.0 16.0 n.d. 1.5 98.5 n.d. CaO BaO . . COj - - SOj . . Si02.-- - . - Al-Ch SrC0 3 . ._. . 97.30 87. 10.2.3 95.61 78.6 9.3 12.1 73 CaCOj 14 13 CaCO. 97.25 0.118 100.0 0.118 100.00 0.352 99.99 0.149 100.00 0.198 100 0.15 100.0 0.19 100.0 0.18 SrCOj I. Strontianite, selected sample. [Probably from a locality near the east end of the Solomon deposit.] Analyst, R. C. Wells, U.S.G.S. Bull. 660, p. 262. II. Faintly banded aphanitic rock resembling a drab limestone [strontianite rock]. Under microscope is seen to be composed of extremely small obscure spherulites of strontianite. Analyst, R. C. Wells, U.S.G.S. Bull. 660, p. 260. [Probably from the Solomon deposit.] III. Hard brown strontianite rock. East end of Solomon deposit, north of road [east of wash?]. Analyst, Earl T. Ross. IV. Brown crystalline strontianite rock, outcrop 25 feet long, 3 feet thick. Near west end of Solomon deposit. Analyst, Earl T. Ross. The greater part of the insoluble materials is represented by common rock-forming minerals not replaced by car- bonates. The amount of unreplaced clay is unknown but is probably variable and not very large. It must repre- sent only a small part of the noncarbonate fraction. Possible Origins of the Strontianite Rock. Knopf (1918, p. 264), in his brief report on this area says, "at first glance the appearance of the layers of gray sphe- rulitic strontianite suggests that they are beds of stron- tianite that were deposited as chemical precipitates from the lake in which the gypsiferous clays were laid down. ..." He then goes on to say that more probably the strontianite rock originated by the replacement of lime- stone, principally algal in origin, "doubtless by cold meteoric water. ' ' He evidently believed that the stron- tium carbonate was an original sedimentary constituent of the rocks concentrated in the manner of formation of ordinary concretions. Undoubtedly the strontianite rock is replacement of other rocks. This origin is indicated by the preservation of pre-existing sedimentary and tectonic structures in the strontianite rock, and by the relationships at the boundaries of strontianite rock masses as previously de- scribed. Knopf's choice of limestone as the pre-existing rock was apparently determined by observation mostly at the "western part of the field," probably the area now called the Ross deposit. The present writer agrees that this may be the relationship there. At the Solomon de- posit, however, the principal replaced rock was the finely laminated, thin-bedded tuffaceous clay. To a lesser ex- tent tuff and tuffaceous marls were also replaced, but to a marked degree the carbonate rocks were left untouched. Pre-existing rocks were replaced by strontium car- bonate, and the replacement followed the tectonic dis- turbance of the sediments, for tectonic breccias and other fault features are preserved in the strontianite rock. The important question that remains is whether the stron- V. Hard dense white ore [strontianite rock]. Outcrop 13 feet long, 2 feet thick. N center of Solomon deposit. Analyst, Earl T. Ross. VI. Light-brown granular crystalline ore [strontianite rock]. Near west end of Solor deposit. Analyst, Earl T. Ross VII. Heavy light-brown satiny ore [strontianite rock]. Selected, east end of Solor deposit. [Probably from upper strontianite-bearing beds.] Analyst, Earl T. R> VIII. Light-brown granular ore [limestone?]. Near west end of Solomon deposit. Anal Earl T. Ross. Notes in brackets are by the present author. tium carbonate was an original constituent of the sec ments or whether it was introduced in hydrotherni solutions. No conclusive answer can be given as yet, b, the second possibility is favored by the present writi Favoring the view that the strontium carbonate ; syngenetic with the sediments are the facts that the strc- tianite rock is confined to a few thin and characteris: stratigraphic units, and, except for the strontianite-be;- ing sandstones, these units are lithologically simi!" among themselves and lithologically distinct from i- jacent nonstrontianitic beds. Furthermore, the strc- tianite-bearing beds singly and in total are very thin i relation to their areal extent. Granting this origin of the strontium carbonate, ft concentration may then be accepted as due to the sa? circumstances by which concretionary bodies of calcin carbonate are formed. Yet the source of the strontiu in the lake waters remains a puzzle. It may, however, ha been introduced as a constituent of volcanic materi, which is a major component of the sediments both of I strontianite-bearing and nonstrontianite-bearing pas of the section, or it may have been carried into the la in solution, having originated as a by-product of volcac activity through gaseous exhalations or through spr z waters partly of juvenile origin. A choice between the possibilities cannot yet be made, but in any event I strontium carbonate would then have been precipita 1 from the connate waters of the sediments in sucla manner as to replace the previously deposited clay. This hypothesis is supported by the occurrence of ORT 32 Table 2. Analyt es of strontianite rock — Ross deposit. I II III IV Average I-IV SrO 20.50 32.10 33.32 11.37 8.93 34 . 59 30.92 20.87 89.0 11.0 n.d. 79.0 21.0 n.d. 53 40 7 CaO COz SrCOj CaCOs 97.29 29.23 57.35 11.37 95.31 12.70 61 . 85 20.87 CaCCh 97.95 1.96 95.42 4.87 100.0 0.12 100.0 0.27 1.80 SrCOa I. Dense, brown, radially fibrous strontianite in trench 100 feet northwest of instru station F. Analyst, J. G. Fairchild. II. Light-brown porous strontianite rock at instrument station I. Analyst, J. G. Falrcl III. Heavy, white, fine-grained ore. [From cut by instrument station F.] Analyst, T. Ross: supplied by courtesy of Mr. Ross. IV. Brown, radially fibrous ore. [From east end of deposit.] Analyst, Earl T. Ross; i plied by courtesy of Mr. Ross. Notes in brackets are by the present author. again exposed at the surface. The eastern limit is then fore unknown, and strontianite rock may continue fc some distance. The extent of strontianite rock in the direction of di is likewise unknown, though its continuation in that d rection is assumed to be several hundred feet. Nature of the Strontianite Bock. The strontianite roc is in short concretionary nodular beds that range froi 0.1 foot or less to 1.5 feet in thickness. Most beds ai highly nodular and the thickness varies rapidly fro? point to point. Most of the strontianite rock is very porous so th< both the weight and the apparent specific gravity ai poor guides to the quality. The color ranges from near! white to very dark reddish and blackish brown. A vei fine spherulitic texture is widespread, and here and the: may be found small amounts of fibrous spherulitic stro: tianite with fibers as long as half an inch. The long' fibers of strontianite form a lining of cavities, which al: usually contain white needles of celestite and dark-re dish-brown rhombohedrons of calcite. Bedding plan are not evident within the strontianite rock, and nonca bonate inclusions are not megascopically visible, thouj there is possibly some clay. Two partial analyses of the strontianite rock have be* made available by Earl T. Ross, owner of the deposit, ai two have been made by the U. S. Geological Survey. These data are not satisfactory for the estimation reserves, partly because the insoluble fractions were n determined in the analyses supplied by Mr. Ross ai partly because of the large variation in the ratio of SrO to CaCOs. The content of the samples is variable b some of the strontianite rock is quite high in SrC03. Origin of the Strontianite Rock. Little can be se at the Ross deposit that sheds any light on the origin the deposit. There is no evidence of the control of t' strontianite by tectonic structures as at the Solomon cj posit. The strontianite layers are bedded ; that is to si. they are parallel to the bedding planes of the enclosi: green clay, though they show no internal bedding ft- Strontium Deposits, Southern California 35 Strontium No I (potented) Strontium No 2 {patented) GEOLOGIC MAP SOLOMON STRONTlANlTf DEPOSIT 20 Old Home (patented) Geology by Cordell Durrell and AC. Ooley, December 1944 4000 6000 FEET Figure 12. Location and claims map, Ross and Solomon strontianite deposits east end of Mud Hills, San Bernardino County, California. 36 Special Report 32 Section 1, Boss Strontianite deposit. Feet Calcareous tuff 2.0 Light-green laminated clay 60.6 Brown-weathering buff limestone 1.9 Green clay 3.0 Brown-weathering buff limestone 0.6 Green clay 3.5 Brown-weathering buff limestone 0.5 Green clay 3.3 Strontianite rock 0.2 Green clay 12.7 Brown-weathering buff limestone 0.3 Green clay 1.4 Strontianite rock 0.3 Green clay 0.2 Strontianite rock 0.1 Green clay 16.2 Strontianite rock 0.3 Green clay 7.0 Strontianite rock 0.9 Green clay 32.2 Strontianite rock 0.3 Green clay 7.6 Strontianite rock 0.3 Green clay 19.5 Strontianite rock 0.3 Green clay 1.4 Strontianite rock 0.1 Green clay 1 3.2 Strontianite rock 0.1 Green clay 20.2 Strontianite rock 0.3 Green clay 10.4 Strontianite rock 0.2 Green clay 15.2 Strontianite rock 0.4 Green clay 3.4 Strontianite rock 0.4 Green clay 8.2 Strontianite rock 0.1 Green clay 2.5 Strontianite rock 1.3 Green clay 1.6 Strontianite rock 0.5 Green clay 1.2 Strontianite rock 0.7 Green clay 4.5 Strontianite rock 0.5 Green clay 4.5 Strontianite rock 0.5 Green clay 1.8 Strontianite rock 0.1 Green clay 2.7 Strontianite rock 0.2 Green clay at top, grading downward into tuffaceous and sandy sediments 49.7 Total thickness 311.1 Thickness from upper to lower strontianite beds 186.0 Thickness of strontianite rock 8.1 Percent of strontianite rock (of 186.0 feet) 4.4 tures. Very probably the strontianite has replaced pre- existing rocks, though this replacement is inferred and not demonstrated. Knopf's opinion (1918, p. 264) was that the stronti- anite had replaced limestone, particularly in what he called the "western part of the area," which is presumed to be the present Ross deposit. This limestone replace- ment may be possible, for the similarity is marked between the strontianite-bearing beds and the dark- Aveathering buff limestone beds and concretions that are also interbedded in the green clay. However, the lime- stone beds are not nodular, and the concretions have rather smooth surfaces. This difference from the stronti- anite rock leads the present writer to the belief that ch rather than limestone was the original rock. The strontium in solution in the lake water probab" did not originate by weathering of the rocks in the drai: age basin. More probably it originated in igneous activii and was carried into the lake with the tuffs that are : abundant in the section, by way of volcanic emanatio or by spring waters partly of juvenile origin. If this hypothesis is correct, then the Ross and Solomr deposits are independent of each other, for the latter believed to have formed later, after the folding faulting of the beds. On the other hand, no proof known that the Ross deposit is not also hydrother in origin, in which case the two deposits would probat have been contemporaneous. Reserves. The individual beds of strontianite were separately mapped as far as exposures would mit. The map (pi. 2), however, does not give a sat factory picture of the quantity of strontianite rock, probably only about half the extent of the beds is sho\ The section presented below was taken near the cei of the Ross area (see pi. 2). The location represents most complete exposure available, and it probably co tains an average number of beds. Much of the area ea of the section undoubtedly contains somewhat mo strontianite rock. The section was taken across the full thickness of green clay unit. Of the total thickness of 311.1 feet on 186.0 feet contains strontianite rock, for there are barr zones at the top and bottom that are respectively 75.4 i 49.7 feet thick. Of the 186.0 feet, 8.1 feet, or 4.4 perce is strontianite rock. The exposed area containing strontianite rock is 294,0 square feet. Using the value of 4.4 percent as the fraet of strontianite rock, and 200 pounds per cubic foot the weight of strontianite rock, about 13,000 tons of str tianite rock is present for each 10 feet of depth. A possi additional 1,000 to 1,500 tons per 10 feet of depth is c cealed beneath the terrace near the east end of the depo Should the deposit continue down dip for 100 feet, reserves would amount to around 140,000 tons of str tianite rock. No certain value for the strontium carbon content of the strontianite rock at the Ross deposit e be established from the analyses. The average of the fo analyses is 53 percent, but this figure may not be ai where near a proper value. REFERENCES Baker, C. L. (1911), Notes on the later Cenozoic history of Mojave Desert region in southeastern California : California Un Dept. Geol. Sci. Bull. 6, pp. 333-383. Hershey, O. H. (1902), Some Tertiary formations of southern C forni'a : Am. Geologist, vol. 29, pp. 349-372. Hewett, D. F., Moore, B. N., Callaghan. Eugene, Nolan, T. Rubey, W. W., and Schaller, W. T. (1936), Mineral resourccsf the region around Boulder Dam : U. S. Geol. Survey Bull. 8 197 pp. Knopf, Adolph (1918). Strontianite deposits near Barstow, Cal : U. S. Geol. Survey Bull. 660, pp. 257-270. Merriam, J. C. (1919), Tertiary mammalian faunas of the Moj.e Desert : California Univ., Dept. Geol. Sci. Bull. 11, pp. 438-585. Tucker, W. B., and Sampson, R. J., 1930, Los Angeles field divisii: California Jour. Mines and Geology, vol. 26. pp. 202-324. Tucker, W. B., and Sampson, R. J. (1943), Mineral resources of fa Bernardino County, California : California Jour. Mines and G - ogy, vol. 39, pp. 427-549. CELESTITE DEPOSITS NEAR LUDLOW SAN BERNARDINO COUNTY, CALIFORNIA* By Cordeix Durrell, OUTLINE OF REPORT Page itraet 37 reduction . 37 ilogy 37 tratigraphy 38 Pre-Tertiary rocks 38 Tertiary rocks 38 Quaternary rocks 39 tructure 39 [ineral deposits 39 illogy of the celestite deposits 39 tratigraphy 40 Tertiary rocks 40 Quaternary rocks 41 tructure 41 iccurrence of celestite 41 hemical composition of the celestite 45 >rigin of the celestite 45 Serves 47 {.erenees 48 3 te 8. Illustrations Geologic map of the southeastern part of the Cady Mountains, San Bernardino County, Cali- fornia In pocket 9. Geologic map of celestite deposits near Ludlow, San Bernardino County, California In pocket ABSTRACT he celestite deposits in sees. 29 and 30, T. 8 X., R. 7 E., S. B., i he south base of the Cady Mountains about 8 miles northwest )!"judlow, San Bernardino County, California, are in lacustrine k ments that are the highest exposed rocks of the Tertiary system, ii that are probably equivalent to the upper Miocene sediments in :1 Barstow syncline. The sediments, composed of fine, thin-bedded Us and clays, are overlain by gray limestones and rest upon a tl'k series of volcanic flows and tuffs that range in composition Er i basalt to rhyolite. The maximum exposed thickness of the 5t ments is about 700 feet. A part of the tuff and clay has been re- p) ed by varicolored chalcedony. he celestite is in beds and concretions in the tuff and clay, and is xposed in a number of relatively small outcrops, separated by al vial deposits that extend along the strike of the beds for a dis- t;> e of 6,300 feet. The maximum thickness of the celestite is 112 I is probable that the celestite is sedimentary in origin, but that it as precipitated, after the deposition of the tuff and clay, from the w ;rs contained in the sediments, and that it replaced the sedi- m ts. Single celestite beds reach a thickness of only 2 feet, but zones a; rick as 30 feet are estimated to be 75 percent celestite. The maxi- mi thickness of 112 feet is so distributed as to constitute nearly 3( percent of the section. The average content of strontium sulfate iude celestite rock, as determined by 14 chemical analyses, is 81 p< ent. he whole deposit is inferred to contain between 1,500,000 and 2, 5,000 tons of celestite to a depth of 50 feet. The extent to which th deposit continues in depth is unknown, but if it continues for ■ feet, which is not unreasonable for a deposit of such length and tl) mess, it may contain as much as 10,000,000 tons of celestite. INTRODUCTION he celestite deposits near Ludlow, California, were ft lied in order to determine the geological relation- st is of the deposits and to obtain a satisfactory esti- I 3 of the reserves of celestite. This project was a part oi the wartime program of investigation of strategic merals by the U. S. Geological Survey. hese deposits are located at the south base of the sc heastern part of the Cady Mountains, about 8 miles n< ;hwest of the town of Ludlow, San Bernardino * blication authorized by the Director, U. S. Geological Survey. Manuscript submitted for publication January 1953. County, California (pi. 8). The celestite-bearing lake beds, which dip to the south beneath the alluvial de- posits of the adjacent valley, are exposed discontinuously for a distance of 1J miles along the strike in sees. 29 and 30, T. 8 N., R. 7 E., S. B. Very probably the celestite-bearing beds, and celestite as well, are continuous beneath the alluvium that sepa- rates the several outcrops. Although the several areas of outcrops of celestite are referred to below as separate de- posits, they are essentially parts of a single deposit. The area of best exposures, and probably of most abundant celestite, generally known as the DuPont de- posit, is now owned by the Pan-Chemical Company, Claremont, California. It consists of two lode claims in the NEi sec. 30 (pi. 9)— the Redfire and Jasper #3— that were patented in 1917 by Dana Burke. The Rowe and Buehler deposit is located at the west end of the chain of outcrops in the NW^ sec. 30 (pi. 9). Wesley N. Rowe of Rosemead, California, and William C. Buehler of Pasadena, California, located about 18 lode and placer claims in the vicinity. Because of confusion in marking the claims, it has not been possible to establish on the map the boundaries of those that cover the celestite deposits. Section 29, which contains the easternmost occurrence of celestite, is owned by the Southern Pacific Land Com- pany. The deposits are reached by fair ungraded roads that branch from paved U. S. Highway 66 about 5| and 8 miles west of Ludlow. The deposits lie about 3 miles to the north of the highway. All passable roads of the district are shown on the accompanying geologic map of the south- eastern part of the Cady Mountains (pi. 8). The deposits are nearly as close to the railroad as they are to the highway. A spur of the Atchison, Topeka & Santa Fe Railway is at Argos, and loading facilities are available at Ludlow. The region is very arid and no source of water in any quantity is closer than Newberry, 30 miles to the west. Previous Work. The only previously published work on the area is that by Moore (1935, pp. 4-9 ; Hewett, et al., 1936, pp. 155-160). His two reports are nearly identical; each contains a small-scale geologic map, two measured sections, and 14 chemical analyses. The deposits are also mentioned briefly in two California State reports bv Tucker and Sampson (1930, p. 323; 1943, p. 543) on the mineral resources of San Bernardino County. Acknowledgments. The writer is indebted to B. N. Moore, whose reports have been previously noted, for the chemical analyses used in this report. The Metropolitan Water District of Southern California kindly supplied the topographic map which was used as a base for the geologic map of the southeastern Cady Mountains. A. Cowles Daley assisted the writer in the field and in the preparation of the maps. GEOLOGY A rapid reconnaissance was made of a part of the Cady Mountains in the vicinity of the celestite deposit in order to obtain a general view of the geology of the district. The map, plate 8, shows only the large lithologic units (37) 38 Special Report 32 and the principal structural features. Careful mapping will be required to fill in the complex structural details that could not be shown on a map of this scale. The rocks of the southeastern part of the Cady Moun- tains are lava flows, tuffs, and lacustrine sediments of Tertiary age, except for an area of granite in the north- western part of the mapped area. The ages of all the rocks can only be inferred by correlation with the more com- plete and better-known section in the Newberry Moun- tains 30 miles to the west. The work of Gardner (1940) in that region is the only general geological study of any nearby area. Stratigraphy Pre-Tertiary Rocks A light-pink, medium-grained biotite granite occurs only in the northwestern part of the area mapped, but extends far to the north and northeast. It is the oldest rock of the area, and though its age is unknown, it is no doubt pre-Cretaceous, possibly Jurassic. The granite is probably equivalent to the "pink granite" in the New- berry Mountains. Tertiary Rocks Basalt. The oldest of the Tertiary rocks, designated as basalt for convenience, is a thick series consisting largely of vesicular and amygdaloidal black to rust- colored olivine basalt flows and flow breccias with green to brown basaltic tuff, tuff -breccia, and agglomerate. Lo- cally, between the strictly volcanic and pyroclastic mem- bers, there are thin units of predominantly red, but in places green, conglomerate, sandstone, and siltstone, com- monly ripple-marked and mud-cracked, that were prob- ably deposited in local basins formed as a result of vol- canic activity. Much of the tuff is silicified, and the series is cut by veins of calcite, manganese oxides, barite, and chalcedony. The relationship of the basalt to the older granite is unknown, as the only observed contacts are faults ; but probably the basalt rests on an erosion surface of the granite, as in the Newberry Mountains. There rocks that have been called the Rosamond series, with which the writer correlates the basalt of the Cady Mountains, rest directly upon the granite, according to Gardner (1940, p. 280). The thickness of the basaltic series is at least 1,000 feet, and perhaps is as much as several thousand feet. Andesite. The basalts and tuffs are overlain by a thick series of reddish and gray hypersthene andesite flows with local intercalations of tuff and tuff-breccia. Along the south side of the range the andesite is a dense rock that is mottled red and green on a fresh surface ; but generally it is weathered distinctly red or purplish gray. Sparse phenocrysts of plagioclase and hypersthene in an aphanitic groundmass are generally aligned in the flow planes. Platy jointing is well developed. In the eastern and northwestern parts of the area, where the series is thickest, the andesite is more massive. Medium-sized phenocrysts of plagioclase and hypersthene are abundant and are unoriented. At several places near the base of the section there is light-gray to black, locally vitrophyric biotite and hornblende andesite. Veins of manganese oxide and chalcedony are abundant in the andesite, and small black nodules of manganese oxide are common in the joints. The andesite rests on the basalt at the depositional co tact that may possibly be an unconformity, as in t Newberry Mountains to the west, where, according Gardner (1940, pp. 281-283), the presumably correlate Red Mountain andesite rests both on the Rosamond seri and on the older granitic rocks. Proof of the unconformi in the Cady Mountains was not obtainable. The original thickness of the andesite is unknown, £ the top is eroded. No section has been accurately measuri because of structural complexities, but the andesite about 600 feet thick near the celestite deposit, and must several times that thick in the eastern part of the are Welded Rhyolite Tuff. Along the western and sout ern margins of the range the andesite is overlain unco formably by a relatively thin welded rhyolite tuff. J places the two types of rock are separated by a sho interval of gravel and breccia composed largely of fra ments of the older andesite and basalt, but with a notab absence of silicified or otherwise mineralized rock. Near the highway northwest of Lavic, and from tl Rowe and Buehler celestite deposit to the Black But manganese mine, the tuff overlaps the andesite and res on the basalt. The tuff is an obscurely bedded rock that contai abundant crystals of quartz and of brilliantly iridesce sanidine. Clastic structure is nearly always evident, b where the tuff has been vitrified, the rock closely sembles a flow. Spherulites have been developed in a i places. Where only slightly altered, as to the east of DuPont deposit, the rock is white to salmon pink, oi poorly consolidated, and contains large fragments pumice. Where thoroughly consolidated the tuff is gr to purplish gray and is very hard and brittle. The tuff about 200 feet thick. Lacustrine Sediments. The rhyolite tuff is overla conformably by a sequence of lacustrine sediments th contain the celestite. At the celestite deposits the se ments are greenish-yellow clay, gray tuff, and gr limestone. Coarse clastic sediments are lacking. Abo H miles northwest of the Rowe and Buehler deposit small outcropping of the lake sediments consists of v canic conglomerate and greenish tuff of rhyolitic compo tion. Farther north and extending across the sumir region of the range there is, preserved in the trough a syncline, a sequence of coarse unconsolidated gra-\ composed of fragments of the underlying andesitic roe and the welded tuff. The gravel is probably equivale to the lacustrine sediments at the celestite deposits, overlaps the welded tuff and rests in part on the andesr Probably it is a shore facies, or perhaps a fluviatile gra^ of the same age as the lacustrine sediments. The top of the lacustrine sediments is not expose The thickest section, that at the celestite deposit, is abo 700 feet. All the rocks here called Tertiary probably are Mioeer though the lacustrine sediments might be Pliocene age. Gardner (1940, p. 280) correlated the basaltic roc of the Newberry Mountains with the Rosamond series Rosamond Station and Mojave, and thereby implied th they are Miocene, which is the accepted age of the s called Rosamond series. Baker (1911, pp. 339-341) cc related the beds of the Barstow syncline with the Ros mond series, and the upper part of the 5,000 feet of h Strontium Deposits, Southern California 39 !i lacustrine sediments in that syncline are known to ong in the upper Miocene (Merriam, 1919, p. 454). I us probably the whole section in the Cady Mountains j roughly equivalent to the section in the Barstow syn- : ie, and probably the lacustrine sediments of the Cady I'a are also upper Miocene. Caternary Rocks 31der and younger alluvial deposits are present in the la, but they were not differentiated on the map of the my Mountains, plate 8. The older gravels cap the lower • ges along the south and southeast sides of the range. Ije younger deposits are the gravels and sands of the p;sent stream courses and the alluvial fans of the ad- vent basins. The two groups of deposits are probably a. very different in age, and both are considered to tyong in the Quaternary. The elevation of the older de- bits is probably the result of a slight general uplift of t). range, and in some places it is certainly the result of r«ent faulting, as observed in the area north of the high- ly near Lavic, where the gravel caps low hills of basalt, II also in the low hills on the eastern side of the range ath of Ludlow. Structure Ohe Tertiary rocks of the area have been folded twice ll perhaps three times. Possibly the basalt was folded Wore the eruption of the andesite. Folding took place Bar the eruption of the andesite and before the deposi- ■l of the welded rhyolite tuff, for the tuff rests both )j:he andesite and basalt. This disturbance was probably lompanied by faulting. The lake sediments are prob- ily conformable with the welded tuff, even though tl gravel in the northwest overlaps the edge of the tuff. T u angle of overlap is slight, and the unconformity is p bably local. After the lacustrine sediments were de- puted, the strata were again folded ; this disturbance w-. probably the most intense of all. It is likely that rat of the faulting occurred at this time. Jthough faulting has probably occurred at more than or time it has not been possible to assign any particular fejlt a definite age. The faults within the range fall into ffc >e systems, the most important of which strikes north- 1 1. Most of the faults of this system are reverse faults th dip toward the southwest, but the one shown towai'd th west end of section A-A', plate 8, is a normal fault th dips toward the northeast, The attitude of the fault it he east end of section A-A' is not known. Two sets of I s faults, one of which strikes a little east of north ii the other a little north of east, are of about equal m ortance. Faults of both sets terminate against those I dug northwest, but they also cut off some of the m or faults of that system. he magnitudes of the fault displacements are not well :i Bra, but on some of the larger faults the displacement n t amount to many hundreds of feet. Possibly, how- ■ , the relatively large displacements, such as are indi- "a d on section A-A', plate 9, are really the sum of the li lacements of many small faults that are not shown oni he map but are present. undamentally the structure of the southeastern part f ie range is a northwest-trending anticline, which is SB lgly modified by faulting. The main anticline is ila ted on the southwestern side by the small syncline th contains the gravels. West of this syncline there is probably another anticline that extends from the most westerly outcrops of the welded tuff to the vicinity of the Black Butte manganese mine. The range is probably separated from the adjacent basins by normal faults, for this area is a part of the province characterized by basin and range structure. No faults of this type have been found, probably because erosion has cut deeply into the range and any such boundary faults are concealed beneath the resulting al- luvial deposits. The low hills north of Lavic (pi. 8) afford a clue to the fault system, for basalt is here exposed at the surface, and is partly capped by alluvial deposits that have been up- lifted above the general level of the surrounding fans. The absence of andesite may result from earlier faulting and erosion, but the elevation of the hills was certainly pro- duced by a more recent dislocation. The southwest-dip- ping beds northwest of the Rowe and Buehler celestite de- posit pass beneath alluvium toward a northeast-facing scarp in the alluvium that is nearly 100 feet high. An- other scarp in the alluvium that does not show clearly on the map extends from a little west of Lavic station nearly to the Rowe and Buehler deposit. While this scarp is prob- ably no longer on the fault, it marks the approximate fault line. The fault shown along the south base of the range extending toward Ludlow is inferred on the basis of the relationships described above. Mineral Deposits Veins of manganese oxides, calcite, and barite are pres- ent in the region, in addition to the celestite deposits de- scribed below. Manganese oxide has been mined at both the Black Butte and the Lavic Mountain mine properties (pi. 8). Considerable ore has been shipped from the Black Butte, and the property was being worked in a small way at the time of the field work (1945). The Lavic Mountain manganese mine was inactive. Small veins of calcite are abundant in the basalt, and several attempts have been made to work them. A little calcite has been marketed for chemical uses, but none of optical quality has been found. Barite in thin veins is also present over the area, but only the Hansen barite deposit (pi. 8) has been mined. The manganese mineralization was younger than the andesite, for veins at both mines are in that unit. The absence of manganese stains, chalcedony, and silicified rocks in general from the volcanic conglomerate beneath the welded tuff indicates that the mineralization is younger than the volcanic conglomerate. The barite min- eralization cannot be easily dated, but it is probably of the same general age. The calcite veins may be as old as the basalt, for they are found only in that unit and the amyg- dules in the basalt are dominantly of calcite. GEOLOGY OF THE CELESTITE DEPOSITS The geology in the immediate vicinity of the celestite deposits is shown on plate 9. All outcrops of the beds as- sociated with the celestite are included on the map. There are small and isolated outcrops of the several zones involved, but contact surfaces between the units are rarely exposed. Therefore the contacts were extrapolated in order to obtain a view of the distribution of the several units, and to help in determining the positions and char- acter of a number of significant but unexposed faults. 40 Special Report 32 Stratigraphy Tertiary Rocks Basalt. Basalt enters the north-central and north- western parts of the mapped area and is the oldest Terti- ary rock exposed. The four small outcrops at the north- west end of the area consist of fine-grained black porphyritic olivine basalt with phenocrysts of plagioclase, augite, and olivine. The olivine is mostly altered to iddingsite. A pronounced platy jointing is present. The olivine basalts of the north-central part of the area are reddish brown on fresh surfaces, but they weather black. In many places olivine in large phenocrysts is altered to iddingsite and iron oxide. The rocks are highly vesicular and amygdaloidal, and contain amygdules of calcite and chlorite. The andesite at the north quarter corner of section 30 (pi. 9) seems to be interbedded with the basalt. The ande- site is a massive brownish-green rock with abundant un- oriented small phenocrysts of plagioclase set in a dense aphanitic groundmass. It is similar to the later andesite, and, because it is near the top of the basaltic series, it may represent an early flow of the magma type from which the succeeding andesite series was derived. Andesite. The andesite, which appears to rest con- formably on the basalt, consists of an indeterminate number of flows with pronounced platy jointing. Sparse, small, tabular phenocrysts of plagioclase are oriented in the flow planes parallel to the platy jointing. Small phenocrysts of hypersthene are everywhere present, and in some places there are a few of olivine. Most of the groundmass is dull green, much of it streaked with pink. The rock weathers purplish gray and reddish brown. Zones of breccia are abundant ; they probably originated both from flowage and from later tectonic disturbances. The attitudes shown on the map, though measured on flow banding and platy jointing, were carefully selected so as to be representative of the general position of the flows. The thickness of the andesite is about 600 feet. Volcanic Conglomerate. The volcanic conglomerate, so-called because its constituents are mostly volcanic and pyroclastic rocks, rests unconf ormably on the andesite ; it overlaps onto the basalt at the western end of the area (pi. 9). The unit consists of 50 to 200 feet of coarse, poorly sorted boulder conglomerate and a few thin tuf- faceous pebbly sand beds. The boulders, as much as 4 feet in diameter, are poorly rounded blocks of the underlying andesite, olivine basalt, and associated tuff ; but, as noted above, chalcedony and manganiferous and silicified rocks are absent. Welded Rhyolite Tuff. The welded rhyolite tuff rests on the volcanic conglomerate and maintains a nearly uni- form thickness of about 200 feet, though it may be some- what thicker at the west end. Most of the welded tuff is light salmon pink but weathers to purplish gray. This is a well-indurated phase that breaks with a conchoidal fracture. It is characterized by abundant sanidine crys- tals that show a brilliant blue iridescence. A clastic struc- ture can be seen with the hand lens. Near the base of the two prominent hills at the west end of the area (pi. 9) is a few feet of dense, black, completely vitrified tuff. Some of the tuff at the east end of the deposit is poorly indurated, porous, and contains pumice fragments as much as 4 inches in diameter. Just east of the mapped area a part of the tuff is entirely unindurated. Here is white to cream colored and contains large pumi fragments in a powdery matrix. Lacustrine Sediments. The rhyolite tuff is overlain 1 the lacustrine sediments that contain the celestite. Tl exposed thickness along section A- A' (pi. 9) is about 7i feet, but the top is concealed by alluvium. The sequen is divided on the map into several units of differing lithe ogy, but it changes rapidly along the strike so that generalized sequence for the several units could not established. The base of the section at the Jasper and Redfi claims and to the east consists of dark yellow-green tin faceous clay and tuff that contains a few thin beds brown to gray limestone 2 to 4 inches thick. From 10 30 percent of the beds of the unit have been replac< by dark-red, green, yellow, brown, and variegated cl cedony. The chalcedony is in sheets an inch to 2 feet th which lie parallel to the bedding of the adjacent se ments. Single sheets of chalcedony can be followed distances of as much as 300 feet, and then they are ter nated only by the limit of exposure'. The thickness of unit in the Jasper claim is about 120 feet. It contains celestite there. In section 29, east of the Jasper claim, the green cl with chalcedony are very much thicker and contain, alo section 1 (pi. 9), about 30 feet of celestite-bearing be and still farther east, five thin beds of celestite. Many of the beds of chalcedony are associated "w iron-rich, partly silicified ocherous clays that are bri red to bright yellow. Evidently ferric oxide was in duced with the silica. The large pit shown at the east < of the mapped area is in a body of red ocher that mined there about 1927. The green clay and chalcedony at the Jasper and R fire claims are overlain by gray, cream, and light-gr tuff and clay that contain the celestite. The lar celestite-bearing and celestite-free zones are shown plate 9. Details of the sequence are given below in s tions 3, 4, and 5. Several thin zones of silicified clay a;l tuff are also in this sequence. The thickness of t] celestite-bearing sequence is 372 feet in section 4 and 4| feet in section 5. Although sections 4 and 5 are only abet 1,000 feet apart, it is not possible to correlate them i detail. The celestite, tuff, and clay are overlain by limestone i beds from 2 inches to 2 feet thick. The limestone unit? very poorly exposed, and possibly other types of se- ments are interbedded with it. The thickness of fl limestone unit is not known for the top is conceal , but approximately 200 feet of beds is exposed in sectii A-A', plate 8. The limestone is mostly gray, fine grain . and porous, but a few of the beds are pink and bu; stains and nodules of manganese oxide are common. The celestite-bearing beds thin rapidly east of l| Jasper claim, and there the limestone rests directly i the green clay and chalcedony. At the Rowe and Buehler deposit, tuffs such as the interbedded with the celestite at the DuPont deposit e present at the base of the lacustrine sediments. Celesle occurs above the tuff and is interbedded with green ai purplish-red silicified clay and ocher. The limestone u t is not exposed there. Strontium Deposits, Southern California 41 laternary Rocks ;The older alluvium, consisting of sand and gravel, oc- rjpies a terrace-like position near the north edge of the ripped area, but merges into the younger alluvium along h: south edge. The older alluvium rises as high as 60 feet B3ve the present stream courses and is subject to erosion i the higher levels. In places it is probably nearly 100 fi't thick. Its present position is probably due to a slight i lift of the range in recent times. The younger alluvium is the sand and gravel of the pres- et stream courses. ■Wind-blown sand is found everywhere over the area, b! has been separately mapped in three places where i effectively obscures the older rocks. Structure The Tertiary rocks strike nearly east and dip toward ft south, except for minor reversals in the lake sediments. • The andesite swings southward at the west end of the ft'a (pi. 9) and is overlapped by the volcanic conglom- e te. The welded tuff and the lower part of the lacustrine sed- iijmts dip at angles of 40° to 60°. At the east end higher b'ls dip more gently, but the dip in the highest beds is 5j'. In general, the dips are steeper near the base of the siiments; they flatten a little toward the south, and then si ;i pen again as shown in section A-A', plate 8. 'n the limestone southeast of the Jasper claim, several ■ill folds are present on both sides of the inferred fault ; b' they are probably only local in occurrence and are p sibly related in origin to movement on the fault. Relatively few faults in the area of detailed mapping w/e located by direct observation. The andesite includes ir umerable zones of brecciation, but none could be traced in the sediments, possibly for lack of exposure and prob- m in part because they are older than the sediments. TJ3 faults are shown in the andesite north of the Jasper em (pi. 9). Il small fault that offsets the base of the limestone beds isrly exposed. Gray and green celestite float and eds of dark green celestite as much as 0.1 foot Slick. Much silicified clay and celestite. Esti- lated 25 percent celestite 14.5 3.6 Ik yellow-green celestite with partings of green lay. Estimated 98 percent celestite 1.7 1.7 In-bedded green celestite with partings of green ay 0.8 0.8 I k yellow-green, gray, and white celestite, partly licified, in beds as much as 0.1 foot thick. Fi- rous celestite near the base 3.0 3.0 In-bedded green and gray celestite, green clay, ad gray tuff. Estimated 30 percent celestite___ 7.9 2.6 [ se of celestite-bearing zone] Total 372.0 111.0 Percent celestite 29.8 Section 5 Redfire claim. concealed hin-bedded nodular gray limestone with part- gs of green shale 12.0 k red and yellow chalcedony, probably silici- :d tuffaceous clay 2.6 ow-green tuffaceous clay with pink siliceous id maganiferous limestone beds, the largest 0.2 ot thick 13.7 9 of celestite-bearing beds] l-bedded gray tuff with beds of celestite from 1 to 0.3 foot thick. Estimated 75 percent celes- :e 1.8 i-bedded to massive white celestite 11.7 )w-green tuffaceous clay and green, pink and own celestite in nodules and in beds as uch as 1.1 feet thick. Estimated 50 percent lestite 44 t gray tuff nodules and thin beds of celestite d very small nodules of manganese oxide 4.2 te celestite in beds as much as 1.0 foot thick ntaining streaks and small nodules of manga- se oxide, separated by partings of gray tuff d gray-green tuffaceous clay. Estimated 95 rcent celestite 10.4 t gray tuff and gray-green clay. Very poorly posed. Contains a little celestite 23.7 te celestite in beds, the largest 1.0 foot thick. orly exposed. Estimated 75 percent celestite 29.1 Thickness in feet Member Celestite Not included in total 1.3 11.7 2.2 9.9 21.8 Section 5. Redfire claim — continued. Thickness in feet Member Celestite Thin-bedded gray tuff and gray-green clay con- taining very little celestite 9.8 Light pink and white celestite in beds as much as 0.6 foot thick interbedded with gray gypsifer- ous tuff and powdery white gypsum. Estimated 60 percent celestite 9.3 5.0 Gray gypsiferous tuff and white powdery gypsum that contain nodules of celestite mostly less than 0.1 foot in diameter 4.3 White celestite in beds as much as 0.2 foot thick. Poorly exposed. Estimated 75 percent celestite 13.4 10.3 Dark green clay and nodules of green and red chal- cedony and green celestite 1.7 Gray tuff, gray-green gypsiferous clay, and powdery white gypsum 33.0 White celestite in beds as much as 0.3 foot thick. Estimated 85 percent celestite 8.3 7.0 Unexposed. Probably gray tuff without celestite 11.1 White celestite in beds, the largest 0.6 foot thick. Estimated 90 percent celestite 7.0 6.3 Gray tuff 10.8 Dark green shale, partly silicified 1.4 White celestite in beds as much as 0.8 foot thick and partings of gray-green clay. Estimated 98 percent celestite 4.2 4.1 Thin-bedded gray tuff and gray-green shale. Poorly exposed 18.2 Poorly exposed. Probably mostly dark green tuf- faceous clay 25.5 Red chalcedony 3.5 Dark to light green tuffaceous clay 4.0 Poorly exposed. Mostly dark green partly silicified tuffaceous clay and beds of celestite about 0.1 foot thick at intervals of 1 to 2 feet. Nodules of w T hite celestite, as much as 0.2 foot in diameter and mostly coated with chaledony, occur at several places. Amount of celestite is negligible 40.0 Light gray and pink tuff and beds of white celes- tite ; the largest are 0.2 foot thick. Estimated 10 percent celestite 15.6 1.6 Thin-bedded white celestite. Estimated 75 percent celestite 2.5 1.9 Poorly exposed. Gray tuff and some celestite 16.5 White celestite in beds as much as 0.2 foot thick. Partly silicified. Estimated 75 percent celestite 9.0 6.7 Light gray tuff containing a little celestite 24.0 Thin-bedded white and gray siliceous celestite. Estimated 50 percent celestite 9.5 4.7 Poorly exposed. White celestite in beds as much as 0.4 foot thick. Estimated 75 percent celestite 10.5 7.9 Partly silicified clay shale and orange chalcedony, and thin beds of celestite. Estimated 20 percent celestite 9.5 1.9 White celestite in beds as much as 0.4 foot thick. Estimated 75 percent celestite 5.0 3.7 Dark green party silicified shale and some celes- tite 5.2 White celestite in beds, the largest 0.3 foot thick. Estimated 80 percent celestite 3.2 2.6 Gray tuff and gray-green clay 3.5 Thin-bedded light green celestite, green clay, and gray tuff. Estimated 50 percent celestite 4.0 2.0 Dark green clay shale and dark green chalcedony 2.0 (Base of celestite-bearing zone) Total 410.8 112.6 Percent celestite 27.4 44 Special Report 32 Section G. Bone and Buckler deposit. Thickness in feet Member Celestite Top concealed Dark blackish-green and purplish-red gypsiferous shale 2.9 Platy gray tuff, partly silicified 0.7 Dark blackish-green and purplish-red gypsiferous clay 2.3 Thin, platy porcellaneous celestite and partings of dark green clay. Estimated 98 percent celestite 0.8 0.8 Blackish-green clay 3.3 Dark green and dark red ocherous clay and beds of dark green and red chalcedony 35.1 Light to dark green tuffaceous clay and pale green to white tuff 3.4 Light green tuffaceous clay and a few thin beds of light green celestite 1.4 Thin-bedded nodular pale green to white celestite 2.7 2.7 Light green tuffaceous shale and tuff with nodules and thin beds of celestite. Estimated 40 percent celestite 2.2 0.9 Dark to light green tuffaceous clay 6.6 Platy green chalcedony 0.3 Lower beds poorly exposed, but probably do not contain celestite Total 61.7 4.4 Percent celestite 7.1 The bedded celestite has various aspects depending on color, which is largely controlled by impurities, and on the grain form and size. Most of it is light gray to white, and much is light green. The latter color is evidently due to small amounts of green clay between the grains of celes- tite. Lesser amounts are light to dark brown, dark gray, and pink. The maximum grain size of the celestite is about 1 mm, but only a very little is that coarse. Most of it is obviously granular, with equidimensional grains, but some is so fine grained as to be porcelaneous. A little of the celestite at the east end of the area consists of acicular crystals, so disposed that their length is parallel to the bedding planes. The commonest impurity is light- to dark-green clay. Gray and pink chalcedony has replaced a part of the celes- tite in some beds, and Moore (Hewett, et al., 1936, p. 156) reports it to be in small amounts in all of the celestite. Stains of manganese oxide are common, and small nodules of manganese oxide 1 to 3 mm in diameter are abundant in some beds, and are also found attached to the surfaces of beds. Most of the celestite is interbedded with sandy gray tuff and light- to dark-greenish-yellow clay. The beds of celestite range in thickness from mere films to 2 feet. Units 10 to 12 feet thick are composed almost entirely of celestite, but they are bedded and weather into homo- geneous slabs mostly between 0.1 and 0.5 foot thick. The bedding planes in less-pure celestite are marked by layers of impure material or by films and thin beds of clay or tuff. Some of the less-pure celestite is shaly; it splits readily into laminae 1 to 2 mm thick. Most of the celestite is granular and some consists of aggregates of needles. Celestite cements some of the sandy tuffs. The beds of celestite seemingly have sharp contacts with the adjacent sediments, but in detail, particularly where celestite beds are in tuff, there is a transition zone 1 to 10 mm thick. The surfaces of the beds are usually gently wavy to strongly nodular. Beds thin and thicker rapidly and terminate either by tapering out or by a grad- ual transition from celestite to sediment. In the first typt of termination the decrease in thickness of celestite i< compensated by a thickening of the sedimentary material Concretions of celestite are sometimes present at the sam( horizon beyond the ends of beds. Concretions of celestite in sandy tuff are exposed in th< highest bed described in section 3, in the face and soutl wall of the large cut at the east end of the Jasper #3 claim Concretions 0.2 foot thick and as much as 0.8 foot in di ameter are present in a tuff bed 0.2 foot thick. They ari quite pure at the center, but impurities increase towart the margin so that they grade completely and gradually into tuff. Tuff, weakly cemented with celestite, extend beyond the surface of the hard firm body of the concre tions. Concretions are separated in the bed by a few inche to a few feet of tuff. The thickness of the concretions i controlled and limited by the thickness of the bed in whicl they lie. The concretions in the clay are somewhat different frou those in the tuff for they are more sharply defined at th margins and consist of dense fine-grained white or grep) celestite. They are more irregular in form and resembl knobby potatoes in both size and shape. Their maxinvur diameter is about 0.3 foot. In some places they are parti; to wholly replaced by chalcedony, and a few are coate* with chalcedony. Some of the nodules have a "brea< crust" surface on one side, formed of polygonal craefo The nodules are widely scattered in some beds, but i many beds they constitute 30 to 50 percent of the mass In a few places they are so closely spaced that only film of clay remain between them. The general appearance c nodules when crowded together suggests that some of th highly nodular beds were formed by the coalescence c nodules localized in a particular zone. Two layers of fibrous pale blue translucent celestii occur near the base of section 4, and a layer is preser. near the top of the lowest celestite-bearing unit shown o the map a little west of section 5. All three layers consi; of fibers or columns of celestite with their length norm; to the margins of the layers, which range in thickne; from 0.05 to 0.2 foot. Though uncertain because of poc exposure, one of the layers near the base of section seems to strike at an angle of about 15° from the strike i the beds. The other two layers are parallel to the beddin The structure of the layers is like that so commonly fovu in gypsum, which suggests that the celestite may ha replaced and pseudomorphed gypsum. Separate celestite crystals and rosettes of crystals occi in green clay in the ravine about 90 feet northeast of i strument station T in the NWj sec. 29. The lowest be< exposed here are dark green poorly consolidated Ian nated clay-rich celestite rocks consisting of short prisr and needles of celestite 1 to 3 mm long, which are a ranged with their length parallel to the bedding plane About 5 feet of this rock is overlain by about 10 feet < dark green clay without celestite ; and this clay, in tur is overlain by alternate beds, about a foot thick, of barn clay, and of clay that contains separate celestite crysta The crystals are rough prisms, some of which have poor developed terminal faces. They are mostly 5 to 10 m Strontium Deposits, Southern California Table 1. Analyses of celestite rock. 45 (Number SiOj AhOs Fe 2 Oa CaO MgO SO s C0 2 H 2 SrO BaO MnO SrSO* calculated from SrO 1 2.05 2.80 7.05 0.45 . 55 1.80 0.15 1.55 0.75 1.65 40.80 41.20 37.30 34.34 38.33 34.49 35.85 41.41 29.88 31.52 36.89 31.49 36.88 41.08 Little Little Little None Trace 0.03 None 0.70 Trace 7.90 1.40 0.27 4.05 0.30 0.50 0.55 1.10 50.50 51.55 47.75 43.35 48.53 44.35 44.39 50.53 36.16 39.52 45.29 40.55 47.73 52.35 0.13 0.63 0.26 0.64 0.73 0.09 None 0.005 0.02 Trace Trace None None None Trace 0.17 0.05 Trace 0.02 Trace 89.5 91.4 3 4 5 6 7 8 9 10 11 12 13 14 rage SrSO 1 84.6 76.8 86.0 18.02 0.66 0.05 0.96 78.5 78.6 89.6 1.70 0.76 0.51 1.19 1.14 1.07 64. 1 70.0 80.3 17.86 2.20 1.53 0.98 0.21 0.92 0.38 0.46 0.54 2.81 5 . 34 0.97 0.17 0.08 0.11 1.60 0.03 0.56 72.0 84.6 92.6 81.3 ysts: 1 to 3, It. K. Bailey; 4, 5, 9, 10, 11, R. C. Wells: 12 to 14, C. Milton: 6 to 8, R. E. Stevens. pses 1 to 5 are Moore's samples 1, 3, 4, 5, and 6, from his section 1, analyses 6 to 14 are his samples 1 to 9 from his section 2. . F., Moore, B. N., Callaghan, E., Nolan, T. B., Rubey, W. W., and Schaller, \Y. T. (1936), Mineral resources of the region around Boulder Dam: U. S. Geol. Survey Bull. S71, 197 pp. Merriam. J. C. (1919), Tertiary mammalian faunas of the Mojs Desert: California Univ., Dept. Geol. Sci. Bull. 11, pp. 438-5: Moore, B. N. (1935), Some strontium deposits of southeast* California and western Arizona : Am. Inst. Mm. Met. Eng. Te Pub. 599, pp. 1-24. Tucker, W. B., and Sampson, R. J. (1930), Los Angeles & division : California Jour. Mines and Geology, vol. 26, pp. 202-3: Tucker, W. B., and Sampson, R. J. (1943), Mineral resources San Bernardino County, California : California Jour. Mines a Geology, vol. 39, pp. 427-549. 74750 2-53 2M printed in California state printing office BSfiW&L UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY grophic bose ffom J.0 Lewis, July 31, 1911 SECTION A-A ' "Toe : ->: .. '* m ™_i rbr C ""■ mSM SECTION C-C SECTION D-0 EXPLANATION Terroce deposits Contoct Indefinite contoct ', red sondstone ond cloys, reccio.Trs, soil beds with (Giant breccia) Fault, showing dip Proboble toult, or fault plunge of oxis (Dost approximately loc< dotted where cone Syocl.ne, showing troce of oxiol plane. (Dashed where opproiimately located; doited where concealed) Strike ond dip of beds Q Cr T « 'vWRTgc GEOLOGIC MAP OF CELESTITE DEPOSITS NEAR THE SOUTHERN END OF DEATH VALLEY SAN BERNARDINO COUNTY, CALIFORNIA i •>5>.:- sr;S„. i '■■ -.'mi I C.I&* i Cordell Ourrell ond A C Dol DIVISION OF MINES OLAF P. JENKINS, CHIEF STATE OF CALIFORNIA DEPARTMENT OF NATURAL RESOURCES UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY Topography by Cordell Durrell and A.C.Daley, November 1944 Geology by Cordell- Durrell and A. C. Doley, November 1944 SPECIAL REPORT 32 PLATE 2 EXPLANATION Terrace gravel /////////// Clay, limestone, tuff beds Calcareous tuff bed Strontiamte bearing clays showing individual strontianite beds Sandstone ond conglomerate Contact Indefinite contact i 77 Fault, showing dip U,upthrown side; D.downthrown side Fault, proboble or location uncertain Concealed fault Strike and dip of beds GEOLOGIC MAP OF THE ROSS STRONTIANITE DEPOSIT, MUD HILLS, SAN BERNARDINO COUNTY, CALIFORNIA Contour interval 10 feet Datum is approximate sea level DIVISION OF MINES QLAFP. JENKINS, CHIEF STATE OF CALIFORNIA DEPARTMENT OF NATURAL RESOURCES UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY SPECIAL REPORT 32 PLATE 3 SECTION A-A SECTION C-C SECTION B-B' Note! Location of sections shown on Figure 12. These sections prepared by stadia survey. Geology by Cordell Durrell and A. C. Daley, December 1944 STRUCTURE SECTIONS, EAST END OF MUD HILLS, SAN BERNARDINO COUNTY, CALIFORNIA 2400 FEET O o •J°UH,?& • :- *.'; :'.]'■. ".1:-' ----I ••: " * :-J .' WiM ii!il/ifl!iiMiBiii™i!M ~^:y ,' --:.-jr O r '•Tm :S"tf s»! o»j. •• : -; I l\ \ II 1 Mill! 1 ' S^/^v ^r-^L- + £2 o> H o. w w _ 3 (i. Q. to CO °1 w _ q q o O CT C o H z m o "n c/) m o ^■ Q -'^ 3 |I| 1 "1 a 1 1 Is a. ui 1 Si 11 ■ ">° s I| E reen clay with limestone bee Thin brown be near top c * J f 3fl - g * k a. H O z o S o a «° IV * -r 3 =r 3 « ■ ' s " s si 1° 1 S 3 o- f W ° *£. o * :v 3 Si. « °- " «l "S S3 £ Q- 3 1 I I S3 \ ; J.llliii » £> . A & * & c^ $£% ^ .> it- : '■ % i l,l_ to ID ->j s m - / no W o. si 10_ o -4 aj x o ;o -nil o 3) -g _, H Ci -1 e is » 5 S" s^ II m* * o 4 i 1.3 s Is* i s I — S. O Q. O S, [D 5, □■ S ^, m ™ 3 ■ ^jjO O ^.o a cr Q- ^ s 3^5 k S " 5" J t !! i Is 1 1 111 11} I 1 Q- n ^"O 1 > II Ik if i ■■ ■■; ,H" Whit 1 f III 1 ^ "^-' Sill 111 ran I II 1 1 ;ot;:! : S^::|-;*l hi 1': = Pu o n™ q s -^s o en o °l 0> a> Oi ^ 3 o Strontionife-bearmg beds. Yellow .ond green cloy, thin limestone loyers, and white and groy tuff Green ond groy tutfoceous sondstone White colcoreous tuff Green and groy futfoceous sondstone and conglomerate with thin algal limestone Thin-bedded sandstones ond green clay Gray tuff bed Yellow ond green cloy, thin-bedded sandstone at too Alternoting thin-bedded green ond gray sandstone, green ond buff cloy with sondy limestone, ond limestone near the top and bottom Green cloy with white calcareous nodules Mossive brown bentonite Green cloy with white-weathering nodulor limestones and calcareous nodules ai i 2 £ £ 3 » - m o £ Limestone Sandstone ond tuff White rhyolite tuff Sandstone, tuff, limestone and cloy Mossive brown bentonite Thin-bedded sondstone and green clay 11 1°- nivlSION OF MINES Ri af Tj ENKINS, CHIEF STATE OF CALIFORNIA DEPARTMENT OF NATURAL RESOURCES \ ■ ■%fe£$W& EXPLANATION tamte bearing beds M conglomerate, Tlit, white colcoteou toff; Ttjsr.strontionite-beoring sond stone indefinite contact Fault, shewing dip Conceded fault Strike and dip of be< O' +- ^BPP>* "''I'^I^SIIiillSlI I mmmr Geology by Cordell Durrell ond A. C Daley, November 194 GEOLOGIC MAP OF THE SOLOMON STRONTIANITE DEPOSIT MUD HILLS, SAN BERNARDINO COUNTY, CALIFORNIA DIVISION OF MINES OLAFP. JENKINS, CHIEF STATE OF CALIFORNIA DEPARTMENT OF NATURAL RESOURCES UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY SPECIAL REPORT 32 PLATE 6 ' 1 SECTION A-A' SOUTH 3400'- SECTION B-B SOUTH 3400'- SECTION C-C NOfiTH - 3400' EXPLANATION Terroce grovels To, upper cloys including some sand; Tut, gray tuff bed ; r,., . Upper sfronfionite- bearing beds Yellow lominoted cloy with thin limestone layers SECTION D-0' Lower stronfionife - beonng beds Tts, tuffoceous sondstone ond congiomerote, Tts t, white calcareous tuff; Ttssr, strontianite- bearing sandstone Geology by Cordell Durrell ond A. C. Daley, November 1944 Contoct indefinite contact STRUCTURE SECTIONS, SOLOMON STRONTIANITE DEPOSIT MUD HILLS, SAN BERNARDINO COUNTY, CALIFORNIA Fault, showing relative movement Umsion of mines K f P. JENKINS, CHIEF EXPLANATION + ESTIMATED VOLUME PERCENTAGE QF STRONTIANITE ROCK IN OUTCROPS \ Ik X 2 ; \ ' '•: \ " ' i v. \ \ \ .._ Amount indetermmote LIMITS OF STR0NTIANITE-6EARING BEOS \ \ \ Upper strontionite-beonng beds containing 10% or more by uotume tl il Upper strontianite-bearing beds of strontionrte rock r Lower strontmnite-beoring beds i Ex. Excluded areos within outer limits of lower stfonfionite-beoring bed 1 NOTE-. The most southerly limit is fixed by outcrops or faults Contact indefinite contact Fouit, showing dip Survey by Cordell Durrell and A C Dole AP SHOWING ABUNDANCE OF STRONTIANITE, SOLOMON STRONTIANITE DEPOSIT MUD HILLS, SAN BERNARDINO COUNTY, CALIFORNIA DIVISION OF MINES OLAF P. JENKINS, CHIEF STATE OF CALIFORNIA DEPARTMENT OF NATURAL RESOURCES UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY ' Topography by the Metropolitan Water District of Southern California Geology by Cordell Durrell and A. C. Daley, April 1945 Tb""^ ^"""- M — •-*- ■■ ■ '■ :'.■ '.'• ■ S ea level l — I I — IE Contour i nterval 200 feet Datum is sea level SECTION A- A' SPECIAL REPORT 32 PLATE 8 EXPLANATION Qal Alluvium UNCONFORMITY mm Lacustrine sediments Rhyolite welded tuff UNCONFORMITY >P illiTO j:;:::;; Andesite Basalt tuff, etc. UNCONFORMITY - * * * * J 9 r ,%* *** + *< H < i o: Granite a 3 CL Contact 1 n F definite conta ct dip + 55 suit, showing Fault, probable or location uncert am Concealed fault Strike and dip of beds Horizontal beds General direction of dip Mines and mineral deposits 5 Miles GEOLOGIC MAP OF THE SOUTHEASTERN PART OF THE CADY MOUNTAINS, SAN BERNARDINO COUNTY, CALIFORNIA