TS 637 T5 UC-NRLF SB 31 The Theory of Drying and its Application to the Hew Humid ity-Heg Plated and Reeirculating Dry Kilns aui UNITED STATES DEPARTMENT OF AGRICULTURE BULLETIN No. 509 Contribution from the Forest Service HENRY S. GRAVES, Forester Washington, D. C. PROFESSIONAL PAPER March 17, 1917 THE THEORY OF DRYING AND ITS APPLICATION TO THE NEW HUMIDITY-REGULATED AND RE- CIRCULATING DRY KILN. By HABRY D. TIEMANN, In Charge, Section of Timber Physics, Forest Products ' ' Laboratory. CONTENTS. Introduction Elementary principles of drying Elementary principles of hygrometry. Types of kilns Drying by superheated steam Page. 1 2 5 7 8 Page. Importance of proper piling of lumber 9 Theory and description of the Forest Service kirn 10 Theoretical discussion of evaporation 13 Theoretical analysis of heat quantities 18 INTRODUCTION. The problem of satisfactorily drying lumber without checking, honeycombing, or warping is one of very wide interest. Although an old problem, it has not yet reached an entirely satisfactory solu- tion, especially with hardwood lumber. Even air drying, which is the slowest and what might be called the most conservative method of removing the moisture, is far from satisfactory for some species of wood. The drying of softwoods, or wood from coniferous trees, on the other hand, may be considered as having reached a fairly sat- isfactory solution. With few exceptions, the softwoods present no special difficulty to the lumber drier. The great trouble with the hardwoods lies in their relatively excessive and very unequal shrink- age. This is due largely to the structure of the wood. In soft- woods the vertical elements are all of the same kind, regularly ar- ranged and of approximately the same width (tangentially). The medullary rays also are very fine and regular. In hardwoods, on the other hand, the elements are very complex, varying in diameter in some species in the same section 20 to 30 times, and are often very crooked. Many woods, such as the oak, have large medullary rays, as 70253 Bull. 50917 1 437650 3-7 2 :BtrLLETOjF:5p9; ii.-s. DEPARTMENT OF AGRICULTURE. ^iS yej-r mffftones v irfegularly arranged. Consequently, strains are ; pro the amount of heat given up by the coils, since the air is brought back to its initial state in the cycle and the water evaporated from the wood is added to the spray water. Hence the amount of heat removed in water at a temperature t x is (4) , G(t 2 tj X (c+sd x ) , when G is the weight of dry air in the mixture required to evaporate 1 pound of water, c and s are the specific heats of the air and vapor. Of this the amount G(t 3 tj (c+sdj represents the loss not ac- counted for in the latent heat of the pound of water which has been evaporated and is taken up by the spray water. The maximum possible thermal efficiency is therefore (5), f . 2 ~,^ if just enough air is circulating to give up all its available heat to the evaporation of the water so that it leaves the lumber in a saturated condition. From equation (2) and (3) the value of t 3 is determined for any given values of t and t 2 . These values may be most readily obtained from the tables given by Hausbrand, before referred to. ti and t 2 are arbitrary values determined entirely by the physical conditions of the material to be dried. In actual operation, however, the efficiency will be much leSvS than this maximum, since the air leaving will not be saturated, and a much larger quantity of air will need to pass through the material than the 'minimum indicated by the equation. If no evaporation takes place, all the heat will be used in heating and cooling the cir- culating medium. The total heat used per pound of air will then be (t 2 t x ) (c+sd-J, and this will go simply to heating the spray water. COMPARISON OF EFFICIENCY. Comparing the theoretical efficiency of the condensing with that of the ventilating type of kiln, it will be seen that under identical run- ning conditions its efficiency is much greater, because the initial tem- perature t is very much higher. Let the temperature of the outside air be 32 F., so that the water has to be raised from 32 F. to the tem- perature of evaporation an dthen evaporated. Let the air leaving the lumber be three-fourths saturated, 75 per cent humidity. Also let t 1 =113 and t 2 =140, giving a relative humidity of 48 per cent. Then d for 1 pound of saturated air at 113 is 0.0653 pound. Substituting those values in equation (3) it is found that t 3 =125 and d 3 =0.06889. Since w=d 3 d 15 the number of pounds 1 1 of air required to evaporate 1 pound of water is G= ~= jriig~ = *"^ which contains 279X0.0653=18.2 pounds of vapor. The pressure of the saturated vapor alone at 113 is 71.4 mm. of mercury; hence that of the air alone is 76071.4=688.6 mm. of mercury. The HUMIDITY-REGULATED AND RECIRCULATING DRY KILN. 25 volume occupied by 1 pound of dry air at 113 and a pressure of 688.6 mm. of mercury is 16 cubic feet (more exactly 15.921), which must be the same as that occupied by the 0.0654 pound of vapor present in the pound of air. As 279 pounds of air are required with its inherent 18.2 pounds of vapor, the volume of air, or com- bined air and vapor, is 15.921X279=4,442 cubic feet at 113. At 125 this will occupy 4,535 cubic feet. The total heat consumed is 279 (0.237+0.0653X0.475) X (140-113) =2,019 B. t. u., 1 of which the useful work has been the total latent heat of 1 pound of vapor above 32 F. evaporated at 116 F. (the wet-bulb temperature) and superheated to 125 F.= 1,122 B. t. u. This should be the same as the heat given out by the air and superheated vapor in cooling from 140 F. to 125 F., 279 (0.237+ 0.0653X0.475) X (140125) =1,122. The thermal efficiency is *^*= to - ^1 =55 ' 6 per cent Also =55 - 6 per cent Compare this first with a ventilating kiln in which the air enters saturated at 32 F., is heated to 140 F., and leaves at 75 per cent hu- midity, escaping to the outer air. We then have ^=32, d!=.00387 pound per pound of air t,=140 t 3 =calculated=80.2, and d 3 at 75 per cent humidity=.01692. The quantity of air required to evaporate 1 pound of water is : G= .01692-.00387 = 76 ' 6 P Unds ' This air contains 76.6X-00387=0.296 pound of vapor. The total heat consumed is: 76.6 (.237+.00387X-475) (140-32) =1,969 B. t. u. The thermal efficiency is ~ =55.6 per cent, which happens to be 14(J o the same as in the condensing kiln, but examination will show at once that the two cases are not analogous. In the condensing kiln the 1 Another way of arriving at this result is to compare the total heats ; thus, in the vapor at 125 and 75 per cent saturation : Total heat in the air alone at 125=279X 0.237 (125 32) equals ______________ 6, 149 Total heat in saturate vapor at the dew point of 115 (75 per cent humidity at 125) =279X0.06889 XI 117 equals _______________________________________ 21, 491 Superheating this vapor from its dew point of 115 to 125=279 X 0.06889 X 0.475X10 equals _______________________________________________________ 91 Total at 125 27,731 At the initial stage, 113 : Total heat in air=279 X 0.237 (113 32) equals 5,356 Total heat in saturate vapor at 1 13=279X 0.0653 X 1116.4 equals 20, 339 Total heat at 113 25,695 The difference, 27,731-25,695=2,036 B. t. u., is the heat added to the air. This should be the same as before, namely, 2,019, the difference being in inaccuracy of the constants used. 26 BULLETIN 509, U. S. DEPARTMENT OF AGRICULTURE. humidity after heating to 140 F. was 48 per cent ; in the other kiln it is only 3 per cent, an extremely low amount. For a correct comparison, the condition of the air entering the lumber should be the same in both cases, namely, it is necessary to raise the humidity in the ventilating kiln from 3 per cent to 48 per cent. This can be done by allowing live steam to escape into the heated air sufficient to saturate it at 113 F., the dew point for 48 per cent humidity. Now, if 1 pound of dry air saturated at 32 F. is heated to 113 F. it will still contain its original weight of vapor, namely, 0.00387 pound; but to saturate a pound of air at 113 F. re- quires 0.0653 pound of vapor; consequently, the difference between this and 0.00387 or 0.06143 pound of vapor must be added for each pound of air at 113 F., in order to make the two cases comparable ; they are then exactly alike, and we shall have for our kiln, to re- capitulate, as before ^=113 saturated t 2 =140 humidity 48 per cent t 3 =125 humidity 75 per cent. Number of pounds of air required to evaporate 1 pound of water at 115 from initial temperature of 32 =279 Total heat required=2,019 B. t. u. Heat lost * 2,019 1,122=897 B. t. u. In the ventilating kiln, on the other hand, we shall have by com- parison : ^=32 saturated. t 2 =140 at 3 per cent humidity. t 3 =125 humidity 75 per cent. h 2 =heat in vapor added to raise the humidity to saturation at 113 F. ; 0.0614 pound are required per pound of air. The total heat in saturate vapor at 113 above 32 =1,117 B. t. u. per pound; 1,117X.0614=68.58 B. t. u. required per pound of air. There are 279 pounds of dry air required as in the other case. 68.5X279=19,134 B. t. u., which must be added as vapor. K 2 =heat required to raise temperature of the air and vapor from 32 to 113=279 (.237+.00387X.475) (113-32) =5,396 B. t. u. Therefore, in this case the total heat which must be given to the air to evaporate 1 pound of water is B. t. u. Heat given by coils to raise the air from 32 to 113 equals 5, 39G Heat given by coils to raise saturate air from 113 to 140 as before equals 2, 019 Heat supplied in vapor equals 19, 134 Total heat required 26, 549 Heat lost (provided it all escaped to the air) 26,549 minus 1,122 equals. 25,427 1 In the spray kiln this is not in reality lost, since part is utilized in producing the circulation and all the remainder is recovered in the spray water. It is simply a transfer of heat from lumber to spray water. HUMIDITY-REGULATED AND RECIRCULATING DRY KILN. 27 Compared to the loss in the Forest Service kiln, as just shown, of only 897 B. t. u., this would be enormous. It would mean an effi- 1122 ciency of only 05X27 = 4>41 P er cent - ^he assum ption, however, that it all escapes to the outside air is not carried out in practice in moist air kilns, but instead a large proportion of this is returned by inter- nal circulation, and only a small amount escapes into the air. It is not possible in the latter case to calculate the theoretical efficiency, since there is no means of knowing what portion of the heat is re- turned in the recirculation within the kiln. The analysis is instruc- tive, however, in showing what enormous heat losses are possible in a ventilating kiln. In no case can the theoretical efficiency of the ventilating equal that of the Forest Service kiln when operating under identical conditions within the drying chamber. INCREASE IN DENSITY PRODUCED BY EVAPORATION. TABLE 3. Increase in density of mixture of air and vapor produced ly the spontaneous cooling of the mixture from the evaporation of moisture as it through the lumber. Entering air. After heating before entering lumber. Leaving lumber. Weight of 1 c. c. of mix- ture in grams. ti. hi. t. h s . Dew point. t 3 . ha. Entering at t*j. Leaving at tshs. F. Percent. F. P.ct. F. o p Percent. 32 100 158 1.8 32 78.8 100 0.0010264 0.0011658 32 100 158 1.8 32 110.5 25 .0010264 .0011057 86 100 158 13 86 99.5 100 .0010126 .0011094 86 100 158 13 86 140.5 25 .0010126 . 0010394 140 100 158 64 140 140.9 100 .0009525 .0009779 140 100 158 64 140 151.7 75 .0009525 .0010154 86 100 212 14 86 105.8 100 .0009310 .0010915 86 100 212 14 86 146.3 25 .0009310 .0010255 176 100 212 47 176 176.5 100 .0007820 .0008221 The weights are given in grams per cubic centimeter of the mix- ture. The independent variables which may be assumed at choice are (1) the temperature of the entering air t ; (2) the relative hu- midity of the entering air h^; (3) the temperature to which the air is heated before it enters the lumber t 2 ; and (4) the degree of satu- ration of the air leaving the lumber, h 3 . From these, h 2 , t 3 , and the volumes and weights of the air and vapor are determined. METHOD USED IN CALCULATING TABLE 3. 1. The temperature, t" 3 , of the air leaving the lumber is determined first, as for Table 1. The dew point must also be determined in order to determine the vapor pressure. 28 BULLETIN 509, U. S. DEPARTMENT OF AGRICULTURE. 2. The following equation gives the value of the density (grams per c. c. ) of the mixture of air and vapor : j_B 0.3T8.e .00129305 * 760 X l+.003670t' B= total barometric pressure in millimeters of mercury. e= pressure of the vapor in the mixture. t=temperature Centigrade of the mixture. .00129305 is the weight in grams of 1 c. c. of dry air at C. pressure 760 mm. under gravity at 45 latitude and sea level. The figure .003670 is the coefficient of ther- mal expansion of air at 760 mm. The first fractional expression may be explained as follows: Let di=density of dry air at B-e mm. pressure. d v = density of vapor at e mm. pressure. Then d=d 1 -fd v . The air pressure alone is B-e and , B-e di a d v =.622 X d X j. when .622 is the density of vapor compared to air at 760 pressure. Knowing the values t 2 and t 3 and the vapor pressures at these two points (pressures at the dew points) the values of d 2 and d 3 are obtained from the above equation. It will be noted that in every case chosen in Table 3 the density increases due to the evaporation, hence the tendency of the air is to descend as it passes through the pile of lumber. 1 See Smithsonian Meteorological Tables, Tables 83 to 86. ADDITIONAL COPIES OP THIS PUBLICATION MAY BE PROCURED FROM THE SUPERINTENDENT OF DOCUMENTS GOVERNMENT PRINTING OFFICE WASHINGTON, D. C. AT 5 CENTS PER COPY WASHINGTON : GOVERNMENT PRINTING OFFICE : 1917 THIS BOOK IS DUE ON THE LAST DATE STAMPED BELOW AN INITIAL FINE OF 25 CENTS WILL BE ASSESSED FOR FAILURE TO RETURN THIS BOOK ON THE DATE DUE. THE PENALTY WILL INCREASE TO 5O CENTS ON THE FOURTH DAY AND TO $1.OO ON THE SEVENTH DAY OVERDUE. JAN 31 1936 LD 21-100m-7,'33 Caylord Bros. Makers Syracuse, N Y. PAr.J4M.21, 19M 437650 TS 337 UNIVERSITY OF CALIFORNIA LIBRARY