FROM THE TRANSACTIONS OF THE ROYAL SOCIETY OF CANADA THIRD SERIES— 1908-1909 VOLUME II SECTION IV The Nepheline and Associated Alkali Syenites of Eastern Ontario By FRANK D. ADAMS, D.Sc., F.R.S. and ALFRED E. BARLOW, M.A., D.Sc. Published by permission of the Director of Qeolosical Survey. OTTAWA PRINTED FOR THE ROYAL SOCIETY OF CANADA. 1909 UCS'E iJBRARy Plate 1 CORUXDUM-SYENITE CRAIGMOXT, ONT. SEcnoN IV., 1908. [ 3 ] Trans. K. S. C. I. — The Nepheline and Associated Alkali Syenites of Eastern Ontario, By Feank D. Adams, D.Sc, F.K.S. and Alfred E. Barlow, M.A., D.Sc. ( Published by permission of the Director of the Geological Survey. ) (Read May 26, 1908.) 1. Introduction. 2. Distribution. 3. Geological Relations. 4. General Petrographical Character. 5. Mineralogical Composition. 6. Description of the several occurrences: (a) The Alkali Syenites of the Township of Lutterworth. (b) The Nepheline and Alkali Syenites of the Township of Monmouth. (c) The Nepheline and Alkali Syenites of the Township of Glamorgan. (d) The Nepheline and Alkali Syenites of the Townships of Harcourt, Cardiff and Wollaston. (e) The Nepheline and AlkaK Syenites of the Township of Methuen. (f) The Nepheline and Alkali Syenites of the Townships of Faraday, Dungannon, Carlow and Monteagle. 7. Summary. Introduction. By far the most extensive development of nepheline syenite which has up to the present time been discovered in North America, or in fact, BO far as can be ascertained, anywhere in the world, is that which occurs in the eastern part of the Province of Ontario, in the counties of Hali- burton, Peterborough, Hastings and Renfrew, in the tract of country whose position is indicated on the accompanying sketch map. The occurrence of nepheline syenite in this district was first re- cognized in 1893, attention having been directed to its probable existence by a specimen of sodalite which was sent in to the Museum of the Geo- logical Survey at Ottawa from the township of Dungannon in the spring of this year, just as Dr. Adams was about to leave for tJiat district to undertake a geological reconnaissance of this part of Eastern Ontario for the Geological Survey of Canada. On visiting the locality from which this sodalite came, the mineral was found to occur in the form of veins traversing a large area of nephe- line syenite in the ancient crystalline rocks of the Laurentian Protaxis. 4 RO^AL SOCIETY OF CANADA A brief description of this area of nepheline syenite was given in a paper which appeared in 1894, and analyses by Dr. B. J. Harrington of the sodalite and certain other nidnerals occurring in the nepheline syenite were published at the same time.' The discovery of corundum in the associated alkali syenite on lot 14, con. XIV of the township of Carlow was made by Mr. W. P. FerrLer, of the Geological Survey of Canada in 1896,=^ and the possibilities of the exploitation of the corundum-bearing varieties of these syenites was subsequently studied by Dr. Barlow^ of the Geological Survey and by Dr. Miller* of the Ontario Bureau of Mines. As a result of these in- vestigations corundum is now being mined on a large scale in the nephe- line and alkali syenites at Craigmont. The sodalite at the original locality, which is a short distance to the east of the town of Bancroft, is also extensively worked as an ornamental stone. Following the geological reconnaissance to which reference has been made, a detailed geological survey of this whole area was undertaken for the Geological Survey of Canada by the writers, which led to the discovery of a large number of additional areas of nepheline syenite, many of them carrying corundum, as well as to an extended study of the relations of these rocks to the other rocks of the Protaxis, in which they occur. The results of this study will appear in the form of a Report to the Geological Survey of Canada, which is now about to go to press and which is accompanied by two geological maps of the area in ques- tion. In the present paper it is proposed to present merely the chief results obtained from the study of the nepheline syenites and the rocks immediately associated with them, the reader being referred to the re- port in question for additional local details if required. Distribution. All the occurrences of nepheline syenite in this region, with the exception of those in the township of Methuen, are found in a com- paratively narrow belt of country which has a general north-easterly ' Adams, F. D. — On the occurrence of a larg-e area of Nepheline Syenite In the township of Dungrannon, Ont. — Amer. Jour, of Science; vol. xlvlll, July 1894. Harrington, B. J. — On Nepheline, Sodalite and Orthoclase from the Nephe- li»ne Syenite of Dnnpannon, liastings Tounty. Ont. — ditto. 'Ann. Rep. Oeol. Surv. Can. Vol. ix. 1896 p. 116. A. •Summary Reports. Geol. Surv. Can. 1896, p. 53; 1897 pp. 48-56; 1898 p. 110; 1899 pp. 130-131; 1900 pp. 127-128; 1901 p. 148; 1903 pp. 142-143; 1904 pp. 190-193. ♦Ann. Rep. Bur. of Mines Ont., Vol. vii. Part III, 1898 pp. 207-238; Ann. Rep. Bur. of Mines Ont., Vol. vlii. Part II, 1899. pp. 205-240. Amer. Geol. Nov. 1899 Vol. xxlv., pp. 276-282; Jour. Can. Min. Mat. Vol. V. 1902 pp. 233-255. DEPARTMENT OF MINES Geological Map CENTRAL ONTARIO CORUNnUM-BEARING ROCKS L [ADAMS A BARLOW] ALKALI SYENITES OF EASTERN ONTARIO S course, as shown on the accompanying map. The most westerly occurr- ence discovered is that in the township of Lutterworth, where a corundum-bearing syenite has been found on lot 12, concession IV. of this township. The next occurrences are those which are situated in the townships of Glamorgan and Monmouth, in which townships some twenty separate areas of the rock have been mapped and studied. The largest and in many respects the most noteworthy of these is a wide belt cf nepheline syenite which surrounds an occurrence of granite inter- vening between this rock and the limestone which forms the country rock of the central portion of the township of Monmouth. Here the nepheline syenite and the granite are clearly seen to be differentiation product? of a common magma. The other occurrences in these townships are smaller and lie for the most part in the limestone. Going to the east from the township of Monmouth a narrow band of nepheline syenite can be traced across the corner of the township of Cardiff into the second range of Harcourt, beyond which, in the north- east corner of Cardiff, occurrences of the closely related white alkali syenite have been noted by Dr. jMiller at Leafield. Beyond this, in the north-west corner of the township of Faraday, what appears to be a continuous belt of nepheline syenite, accompanied sometimes by the closely related red alkali syenite, extends in a south- easterly direction for a distance of about three and a half mile?, cross- ing the Monck road on lot 26 between concessions A and B. Xear this place there is a gradual change in the strike of the rock, the band curv- ing around and running in a direction a little north of east, as far as lot 16 of concession A. It is impossible to trace its further extension east- ward, as occasional outcrops only were found protruded through the deep covering of drift. It seems, however, entirely reasonable to as- sume that the several exposures found, belong to one continuous belt, for as the village of Bancroft is approached there is a very marked in- crease in the area over which these syenite rocks are distributed. At its intersection with the Hastings roiid at the village of Bancroft, be- tween the townships of Dungannon and Faraday, the nepheline syenite measures over half a mile across its strike, which is here nearly east and west. East of Bancroft these syenite rocks increase very rapidly in volume, attaining their maximum development in the vicinity of Bronson, where extended and often nearly continuous outcrops may be found for a distance of over two and a half miles in a north and south direction, underlying most of the area between the eleventh and four- teenth concessions as far as the York river. Along the valley of the York river and extending in a general direction a little east of north from the bridge over the York river in 6 ROYAL SOCIETY OF CANADA the eleventh concession of Dungaunon to the mouth of the Papineau Creek in the township of Carlow, there are a large number of lenticular masses of nepheline syenite and alkali syenite intruded along the strike of the crystalline limestones and amphibolites. Time did not permit of a sufficiently detailed examination of this valley to accurately outline all such masses, even if this were possible with so heavy an accumula- tion of drift as is here found. The position, however, of certain of these occurrences is shown upon the geological map which accompanies the general report on the district to wliich reference has already been made. A little to the east of Papineau Creek, nepheline syenite is met with on both sides of the river, while farther dovra the river a little north of Foster's Eapids, an extremely basic nepheline rock occurs. Still farther to the east Dr. Miller mentions nepheline syenite outcropping on a ridge in the ninth concession of Carlow, about one and a half miles north-west of Campbell's bridge on the York river. No very detailed examination was made of the area between Carlow and Brudenell, but corundum syenites occur in the eighteenth and nineteenth concessions of Eaglan and in the first concession of Eadcliffe, close to Palmer's rapids on the Madawaska river, while nepheline syenite has been found on lot 25 of the nineteenth concession of Eaglan. All these last mentioned occurrences in Eaglan and Eadcliffe be- long to another and parallel band of these syenite rocks, which, starting from lot 14 of concession XIV of the township of Carlow, where corundum was first discovered by Ferrier, extends eastward through the two northern concessions of Eaglan, having been traced a short distance east of the Madawaska river near Palmer's Eapids. The occurrence of nepheline syenite and the closely related red syenite in the fifth and seventh concessions of the eastern part of the township of Brudenell, witli their north-west and south-east strike, cannot be correlated with either of these bands, although they occupy an intermediate position between these and the Algona and Sebastopol occurrences on the east. Extending eastward from Brudenell a very wide belt of rocks of closely related syenite types covers the northern portions of the town- ship of Lyndoch, extending thence into Sebastopol and South Algona, as far as Clear Lake, and probably beyond the Ottawa river into the ad- jacent Province of Quebec. From the township of Tiutterworth where, as above mentioned, the most westerly development of these rocks is found, the occurrences of nepheline syenite, if wo except that in Methuen, are thus confined to a narrow and somewhat sinuous belt of country having a general north-east- erly strike and which reaxjhes the Ottawa river in the township of South [ADAMS 4 BARLOW] ALKALI SYENITES OF EASTERN ONT.^IO 7 Algona. This represents a distance of about 103 miles. Within this belt from the township of Glamorgan north-east to the Ottawa river, over a distance of about eighty-three miles, the nepheline syenites and their associated rocks are represented by very frequent exposures, constituting an almost continuous development. Geological Relations. The area in which the nepheline syenites occur is underlain by the Laurentian System of Logan. According to Logan, this system was composed of the Fundamental Gneiss, with an overlying series of very ancient sediments consisting chiefly of limestones, and which subse- quently came to be known as the Grenville Series. Logan considered both series to be of sedimentary origin, the well defined bedding of the upper series bein^ in the Fundamental Gneiss, represented by a gneissic structure which he regarded as representing an almost obliterated bed- ding. The contact of these two series in the single area which he worked out in detail, namely, the district lying north of Grenville, which is situated about half-way between the cities of Montreal and Ottawa ou the north shore of the St. Lawrence, is of such a character as to lend some colour to this old AVernerian view. A careful examination of the very large areas in which the relations of these two series has since been closely studied, shows, however, that in all cases the so-called Fundamental Gneiss breaks up through the over- lying Grenville Series, the contact being an intrusive one, so that over wide stretches of country in the Province of Quebec and in Eastern On- tario the " Laurentian System " is composed of a great series of sedimen- tary rocks chiefly limestone, invaded and intensely altered by enormous intrusions of the Fundamental Gneiss. In Western Ontario a similar relation is always seen where the oldest stratified series in that part of the Dominion, namely, the Keewatin Series, comes in contact with the Fundamental Gneiss. In fact, the same remarkable relation has been found in all parts of the world where the oldest sediments have been studied. There is no floor to the sedimentary series, no basement of granitic or other roeks on which the oldest sediments of the geological column repose and from which they have been derived, but, instead, the oldest sedimentary series float on enormous intrusions of granite, which break up through them in every direction. It is in such an area that the rocks described in the present paper occur. The limestones with their associated sedimentary gneisses and amphibolites (Grenville Series) are excellently developed, being of great areal extent and of great thickness. Through this Grenville Series the granite batholiths of the Fundamental Gneiss are well up, being often 8 ROYAL SOCIETY OF CANADA completely surrounded by the sedimentary series in question, while going Jiorth, toward the limit of the area at present under discussion, the Fun- damental Gneiss becomes relatively more abundant and finally underlies the whole region, containing, however, everywhere shreds and patches of tlie limestone series which is frayed away into it and partly absorbed by it. The nepheline and their associated alkali syenites are found either along the actual junction of the granite and the limestone, or in the limestone itself near the granite contact. There is only a single excep- tion to tliis in the area under discussion, namely, the nepheline syenite mass in the township of Methuen, which occurs between a great granite intrusion and a body of amphibolite, containing a few small bands of limestone. These nepheline rocks are of the same age as the general complex in which they occur, that is, they belong to the Pre-Cambrian or Pro- terozoic rocks of the Laurentian Protaxis. They are intruded into the crystalline limestones and associated sedimentary rocks of the Grenville Series on one hand, and at several points where they are well exposed, they pass gradually over into the Fundamental Gneiss on the other hand. Elsewhere, however, dykes of the nepheline syenite or associated alkali syenites can be seen to cut the Fundamental Gneiss. A careful study of the whole area shows that the nepheline syenite and its associated alkali syenites represent a peripheral' differentiation phase of the granite (Fundamental Gneiss), and that in the few cases where these rocks are seen to cut the Fundamental Gneiss, they are of the nature of dykes of differentiated material intruded into a more acid phase of the same magma which was already consolidated, very much in the same way as in the occurrence of ordinary granite pegmatite dykes, are found repre- senting the last product of consolidation of a common magma. General Petrogkaphical Character. It wouJd far exceed the scope of the present paper to' describe in detail the exact composition of these syenites at the many localities where they are exposed, for their extreme and rapid variation in com- position is one of the most noteworthy features of their development. In fact, too much emphasis can hardly be given to this fact, for no other rocks show an equally great diversity of types within such short dis- tances. It is quite possible to obtain hand specimens from the same ex- posure, and even from contiguous bands, which exhibit such a wide differ- ence in their mineralogical composition as to be classed as separate and distinct types of rock. All these, however, are differentiation products of one highly alkaline and aluuiinous magma, representing one phase of [ADAMS & BARLOW] ALKALI SYENITES OF EASTERN ONTARIO 9 plutonic activity. They belong to one petrographical province; never- theless for purposes of convenience of description, they may be con- sidered as divisible into four groups, although it must be understood that no arbitrary lines exist in nature between these respective sub- divisions. 1. The Nepheline Syenite. 2. Eocks of the TJrtite and allied groups. 3. The White Alkali Syenite. * 4. The Red Alkali Syenite. 1. The Nepheline Syenite. — This is made up essentially of an acid plagioclase, usually albite, with nepheline and biotite (lepidomelane), hornblende or pyroxene. Orthoclase, microclme and microperthite are occasionally found, but when present rank merely as accessory con- stituents. 2. Rocks of the TJrtite and Allied groups.— The nepheline syenite exhibits extreme variations in the relative proportion of its constituent minerals, passing by a decrease in the amount of plagioclase present into rocks composed exclusively of nepheline and ferro-magnesian minerals, and of these into varieties composed on the one hand, almost exclusively of nepheline (Monmouthite) or, on the other hand, into very basic varieties composed almost exclusively of iron magnesian con- stituents and approaching Jacupirangite in composition. The rocks of groups 1 and 2, in addition to their essential consti- tuents almost invariably contain a certain amount of calcite. Scapolite is aJso a frequent constituent. Some of the less common accessoiy con- stituents are, garnet, sodalite, cancrinite, fluorite, muscovite, corundum, magnetite, pyrite, sphene, zircon, apatite, spinel (automolite), graphite and eudialite. 3. White Alkali Syenite. — This differs from the nepheline syenite in that the nepheline occurs merely as an accessory constituent, or may be entirely lacking. The rock is thus composed of an acid plagioclase and the ferro-magnesian constituents, the latter, however, being present usually in very subordinate amount. 4. Red Alkali Syenite. — This rock is distinguished at once from the preceding syenite by its pinkish or reddish colour. Like the white syenite it contains plagioclase, usually albite, as the predominant feld- spar, but orthoclase and microcline are usually present and are relatively more abundant. Occasionally a little nepheline occurs, but when found is generally decomposed to a reddish or pinkish gieseckite. Magnetite in small irregular crystals and grains is usually present. Biotite is the iron magnesian constituent and is, as a general rule, present in very subordinate amount. When specimens are examined by the unaided eye, lO ROYAL SOCTETY OF CANADA quartz seems to be entirely lacking, but an examination of thin sections under the microscope often reveals this mineral, sometimes in no incon- siderable amount. Tlie rocks of these several gi-oups pass into one another by imper- ceptible graduations. The magmas of all four types were in places supersaturated with alumina, this excess crystallizing out as free alumina in the form of corundum. In those varieties of nepheline syenite which are unusually rich in nepheline and in the rocks of the Urtite group, the corundum is only developed when the iron magnesia minerals do not occur in any appreciable amount. Intimately associated vnth the rocks of these several types and form- ing part of the same igneous complex are certain abnormally coarse phases which are their pegmatitic equivalents. These may occur as parallel or intercalated bands or they may cut across the foliation of the rock in the form of dyke-like masses. The contact of these peg- matites with the parent or normal plutonic rock is sometimes quite sharp, especially in the case of those which intersect the foliation. They usually, however, present a rather abrupt, though quite perceptible, transition into the ordinary medium grain type. The nepheline syenite pegmatite is usually composed altogether of nepheline and albite. Some- times very large individuals of biotite and occasionally of hornblende, apatite and magnetite are present. The pegmatitic form of the red syenite is made up almost exclusively of microperthite, consisting of an irregular intergrowth t)f orthoclase and albite. The term S3''enite as applied to the nepheline syenite, in the north- eastern portions of the syenitic band, is in some cases somewhat of a misnomer, for plagioclase varying from albite through oligoclase to andesine is the prevalent and often the only feldspathic constituent. Dr. Adams^ in his paper announcing the discovery of these occurrences in the townships of Dungannon and Faraday, made reference to this as follows. — " If the distinctive character of the nepheline syenite named Litchfleldite by Bayley be the replacement of the orthoclase by albite, this rock is a more typical Litchfleldite than that from the original local- ity. The propriety of defining nepheline syenite as a rock composed essentially of nepheline and an alkali feldspar, instead of one composed of nepheline and orthoclase is rendered evident, as otherwise it would be necessary to classify this rock as a theralite from typical specimens of which it would differ greatly in composition.'' These various rocks, while sometimes quite massive, possessing a true hypidiomorphic granular structure, usually have a more or less per- ' American Journal of Science, vol. XIA'III, 1894, p. 15. [ADAMS A BARLOW] ALKALI SYENITES OF EASTERN ONTARIO . 1 1 feet foliated structure which in many places presents an actual schistose development, the strike of which conforms to that of the adjacent country rock. The foliation has all the characters of an original structure. They vary in texture from medium to coarse grained, while the peg- matitic phases sometimes present nepheline and plagioclase individuals as much as a yard in diameter. The rock is, as a rule, remarkably fresh and unaltered. Evidences of pressure even in the most pronouncedly foliated or schistose varieties are extremely rare. In occasional instances, however, some of the feld- spars show strain shadows and curved or slightly dislocated twinning lamellae. Sections of the rock comprising the narrow part of the band, crossing the J\Ionck road in Faraday township, show quite pronounced granulation and cataclastic structure. The relations of the constituent minerals, especially the feldspa- thoid species, do not indicate the same regular and definite order of succession which is seen in most of the rocks which have crystallized from a molten magma. In general, however, it may be stated that after the crystallization of such minerals as apatite, zircon, sphene, corundum and magnetite, individuals of which usually possess rather good crystal outlines, the hornblende and biotite were formed. Both of these last mentioned minerals, and especially the hornblende, exhibit many sharp and distinct crystallographic boundaries. Plagioclase came next in order, while the remaining interspaces were filled either with potash feldspars when present, or with nepheline. So far as the texture of the rock is concerned, in the great majority of instances nepheline ap- parently plays the same part as quartz in an ordinary granite. Garnet, which is a very frequent and often abundant accessory constituent, is distinctly later than all of these constituents. Sodalite and cancrinite are also distinctly later, filling cracks and fissures. On the other hand many grave exceptions to this general order of crystallization have been noticed, such as the inclusion of rounded in- dividuals of nepheline and microcline in the plagioclase, and of plagio- clase and nepheline in the hornblende. Again albite is frequently found forming poikilitic tntergrowths with hornblende, such included in- dividuals of albite often having direct connection and more or less dis- tinct optical continuity with certain mantles or borders which sometimes surround the hornblende, separating individuals of this mineral from the other constituents of the rock. There is moreover undoubted evi- dence of very pronounced magmatic corrosion, due apparently to pro- gressive changes in the physical constitution and composition of the magma. 12 ROYAL SOCIETY OF CANAUA The shells or mantles ol" muscovite which often enclose the in- dividuals of corinuluin are distinctly and clearly attributable to me in- creased acidity and hydration of the magma in its later stages. The nepheline syenites and the associated alkali syenites occur al- most invariably on the borders of the granite bathyliths where these cut through crystalline limestone. When the actual contact of the two rocks is well exposed, large in- dividuals of nepheline, biotite and other constituents of the syenite can be seen to have developed in the limestone all along the margin of the nepheline syenite body, while masses of the limestone, great and small, can be found scattered through the nepheline syenite along the contact. These masses, furthermore, were evidently in process of replacement by the magma, the various constituents of the nepheline syenite growing into them. They thus become gradually reduced in size, and now survive merely aa separate, irregularly rounded grains of calcite often enclosed in single individuals of perfectly fresh nepheline, hornblende or other minerals of the nepheline syenite, or lying between these, with the fonn of the latter impressed upon them on every side. (See Plates 4 and 10). Every stage of the passage from the solid limestone to the separate calcite grains enclosed in the constituent minerals of the nepheline syenite can be distinctly traced, while the latter is at the same time fresh and free from decomposition products. The phenomenon is well seen in the railway cutting on the outskirts of the village of Bancroft. In some cases an additional proof of the derivation of the calcite from the ad- jacent limestone is afforded by the fact that the calcite grains enclosed in the nepheline syenite show the twisting and the strain shadows to be observed in the constituent individuals of the invaded limestone, while the minerals of the nepheline syenite which enclose them, are absolutely free from all signs of pressure. The calcite in the syenites is therefore undoubtedly foreign to the magma and represents inclusions of the sur- rounding limestones. In the case of the only important body of nepheline syenites which does not have limestone as a wall rock, namely the occur- rence in the township of Methuen, calcite is very rarely found in the rock, and when it does occur, it is lq very small amount, while the mode of its occurrence is entirely different from that above described and is such as to indicate that the mineral is probably secondary or a later infiltration. The presence of calcite has been noted in other occurrences of nepheline syenite. These are like those of the area at present under dis- cussion, associated with ancient metamorphic rocks, but the calcite in them is believed to be primary by the investigators who have studied PL* > (D -^ c in a o £ a, 2 [ADAMS 4 barlow] ALKALI SYENITES OF EASTERN ONTARIO* 13 them. The occurrences in question are the nepheline syenites of the Sivamalai series of India ' and that of the Island of Alno ^ in Sweden. A similar association has been noted in the occurrences at Kussa in the Ural Mountains^ and in the nepheline rocks of the Kaiserstuhi in Baden.* Concerning the calcite in the Indian occurrences, Holland says: — '' 7.'he calcite occurs in granular crystals with apparently as much right as any of the others to be considered a primary constituent. The crys- tals form isolated granules, and there are no signs of secondary decom- position tlie low silica percentage in this group of rock removes the chief theoretical difficulty to its crystallization from a molten magma as a normal constituent of an igneous rock." The Alno rock contains large masses of crystalline limestone as well as scattered granules of calcite and micropegmatitic intergrowths of calcite with nepheline, asgerine or feldspar, and Hoghom believes that the limestone has been fused in the magma without decomposition and was, during the process cf solidification, crystallized out of the magma in precisely the same way as the other minerals. In neither of these cases does limestone now oc- cur in the immediate vicinity of the syenite, but it may, especially in the latter case, have sunk down into it from overlying beds, sines re- moved hy erosion. This is also considered by Graeff to be the true explanation of the origin of the limestone inclusions in the Kaiserstuhi occurrence. Of the crystalline limestone associated with the Kussa nepheline syenite, Arzruni says that its " austreten unaufgeklart geblieben ist." ^Holland, T. H. — The Sivamalai Series of Elaeolite Syenite and Corundum Syenites in the Coimbatore District, Madras Presidency — Mem. Geol. Survey of India, Vol. XXX— part 3, 1901. p. 197. ^ Hogbom, A. G. — Ueber das Nephelinsyenitgebiet auf der Insel Alno — G«ol. Foren i. Stockholm Forh. Bd, 17. Heft 2. 1895, s. 118. Also Abstract in Min. Mag. Vol. XL (1897), p. 250, and Rosenbusch Mikr. Phys. (1896), pp. 169 and 171. •Arzruni, A. — Die Mineralgruben bei Kussa and Miass — (In the Livret — Guide for the Ural Excursion of the International Congress of Geologists, St. Petersburg Meeting, 1900.) * Graeff, — Zur Geologic des Kaiserstuhlgebriges — Mitt, der Bad. Geol. I..andesanst. Bd. II, 1892. Knop, — Der Kaiserstuhi im Breisgau — Leipzig. 1892; also Hogbom, A. G. (loc. cit.) 14 ROYAL SOCIETY OF CANADA Minerals which occur in the Syenites. The following minerals have been found in the nepheline syenite or its associated alkali syenites. Nepheline Corundum Eucolite Sodalite Calcite Molybdenite Cancrinite Garnet Apatite Feldspar Zircon Magnetite Scapolite Sphene Pyrite Biotite Tourmaline Pyrrhotite Hornblende Spinel Chalcopyrite Muscovite Chrysoberyl Graphite Nepheline. — A§ a rule the mineral is quite fresh and glassy, break- ing with a sub-conchoidal or uneven fracture. The freslily broken fragments are often distinguishable with difficulty from the plagioclase. It varies from almost colourless to white or very pale grey. Often it possesses a beautiful pale salmon pink colour, which, on inspection is seen to accompany an incipient decomposition of the mineral. A progressive increase in this alteration is characterized by a gradual deepening of the tint until a bright brick red colour is assumed, representing the extreme stages in the decomposition and hydration of this mineral. The resul- tant products in the primary stage are chiefly minute scales of mus- covite, with very brilliant double refraction, the process extending from certain cracks, and from the margin of the individual or forming " halos " around certain inclusions. Some of the individuals are more or less turbid and opaque as a result of decomposition. In the more highly coloured phases of the mineral an aggregate resembling gieseckite in composition and appearance is produced, giving rise to very brilliant aggregate polarization. It is usually comparatively free from inclusions, although sometimes hornblende, biotite, calcite and even feldspars occur enclosed. The hardness of the nepheline occurring at York river according to Dr. Harrington' is nearly 6. The specific gravity at 17°C.=2.625 as deter- minofl with the bottle and 2.618 by suspension with a hair. Before the blowpipe it fused quietly at about 3.5 to a colourless slightly vesicular gla-os. An analysis of this nepheline by Dr. Harrington gave the follow- ing result? (under T). For comparison an analysis of the yellow variety of nopheline of Coimbatore, Madras, India, is given under II. ^ 'Amer. Jour. Sc. Vol. XLVIII. (1894), p. 17. 'Mem. Geol. Surv. Ind., Vol. XXX, Part III. 1901. p. 187. I. II. 43.51 43.35 33.78 34.32 0.15 1.02 0.16 0.82 tr. 5.40 5.52 16.94 14.62 .40 0.75 [ADAMS & BARLOW] ALKALI SYENITES OF EASTERN ONTARIO IS SiO, AI263 Fe^Os CaO MgO . . . . K2O Na20 •• .. Loss on igjiition • • 100.34 100.40 The appearance of the nepheline on the weathered outcrops of the nepheline syenite is remarkable. When surfaces of the rock, which have been exposed to the action of the atmosphere "are examined, each grain or individual of nepheline will be found to be represented by a depres- sion. At the bottom of this the nepheline grain can be seen with a smooth rounded surface, as if it had been partially dissolved away, the feldspar and iron magnesia constituents standing up above it on all sides. The surface of the nepheline is coated with a mere film of de- composition products and is of a faint bluish grey colour, the feldspar weathering chalk white, and on breaking the rock open the nepheline appears to be perfectly fresh. Evidently the nepheline is destroyed much more readily by the weather than the other constituents of the rock, and the alteration products are of such a character that they are at once removed, leaving the surface of the mineral fresh and hard. This peculiar method of weathering makes it possible to determine the pre- sence or absence of nepheline in any specimen of tbe syenite from a care- ful inspection of the weathered surface of the rock alone. In fact itd presence can be quite as certainly determined in this way as by means of chemical tests or a microscopical examination. This simple method has furthermore the advantage tliat it can be applied to large areas of rock surface. (See Plates 3 and 4.) Sodalite. — This mineral was observed at a large number of widely separated localities along the great belt of these syenite rocks in the townships of Glamorgan, Faraday, Dungannon, Monteagle, Raglan, Brudenell, and as far as Clear Lake near the north-east end of the belt. It usually occurs in ill-defined irregular masses and patches, of comparatively small size, in the nepheline syenite, especially in those portions which are unusually rich in nepheline. It is also developed along and in the immediate vicinity of certain cracks and fissures in the nepheline, with no sharp line of division between the two minerals, the je ROYAL SOCIETY OF CANADA bluish colour gradually fading in passing outward to the white or pale greyish neplieline. In thin sections under the microscope it is seen to occur in in-egular strings or vein-like forms cutting across and among the other constituents. In certain portions of the area it occurs in very large masses, notably on lot 25, concession XIV of Dungannon. The presence of the sodalite at this locality has been proved over a length of some 250 feet with a width of from forty to fifty feet, and it is stated to be even more extensive than the present developments have shown. Suffi- cient quarrying has, however, been done to prove this occurrence to be of distinct economic importance, as it is quite possible to secure blocks of sodalite weighing several tons. In 1906 a shipment was made of 130 tons of what was considered suitable material, to be used in the decora- tion of the residence of Sir Ernest Cassell in Park Lane, Hyde Park, London, England. This property has been known as the "Princess Quarries, " although a company has not yet been incorporated. It is stated to be the intention of the owners to instal a complete plant not only for quarrying the sodalite with channelling machines but sawing it into slabs of suitable thickness. Other exposures showing large masses of beautiiully coloured sodalite also occur on lots 25 and 29, con, XIIl of Dungannon. At the first mentioned locality, preliminary development work consisting of stripping and some blasting has shown the presence of several large patches of the sodalite. At Craigmont in Eaglan town- ship and on lot 34, concession V. of the township of Brudenell, patches of deep blue sodalite occur in a nepheline syenite made up in addition to this sodalite of a beautiful pale salmon nepheline and grey plagioclase, the association producing a rock which has a very pleasing effect. The colour in this mineral varies from a very dark cobalt blue to very pale bluish, the colour fading rapidly when exposed to the action of the weather. It is susceptible of a high polish and is emmently suitable for inside decorative work. It is often associated with more or less magnetite and biotite, and displays veinlets of reddish and whitish feldspar which was shown on analysis by Dr. Harrington to be orthoclase. A sample in the museum of the Geological Survey shows a crystal of hastingsite several inches in length and perfectly terminated, completely enclosed in the sodalite. Most of the material is compact with a multitude of ver\' fine cracks which may bo due to the shocks of blasting. The specimen selected by Dr. Harrington for analysis showed distinct dodeoahcdral cleavage and vitreous lustre. It was translucent and often sub-trans- parent in ordinarily thin fragments, and its hardness was about 5.5. Heated in a closed tube the sodalite became perfectly white, while be- fore the blowpipe ii fui^ed en«ily with intumescence to a colourless glass. ■-^ J ^ c j: — o > IT [ADAMS & BARLowJ ALKALI SYENITES OF EASTERN ONTARIO 17 Under I is given an analysis of tiie sodalite from lot 2i), concession XIV" of Dungannon, by Dr. B. J. Harrington.^ Under 11 an analysis of sodalite from Duugannon by L. McI. Leigher and G. J. \'olckenning." Si02.. . Al,03.. FeO . . . . Na20 . . . K^O.. . CaO ... CL. .. SO3.. .. H^O.. . Insoluble . 1. II. 36.58 37.34 31.05 31.35 .20 24.81 35.01 .79 .74 .38 6.88 G.79 .13 .37 .80 101.50 101.51 1.55 2.395 3.303 Deducting = CI Specific gravity = Gancriniie. — This mineral was first detected in Canada by Dr. Har- ring^ton in the nepheline syenites of Mount Koyal and Beloeil, in the Province of Quebec.^ In the nepheline syenites of Ontario, it usually can only be distinguished by the assistance of the microscope. It occurs in irregular grains or rude radial aggregates, whose outlines are dependent on the surrounding minerals. It is usually at least in immediate associa- tion with the nepheline and sometimes forms a narrow bolder more or less completely surrounding the individuals of this mineral. It also occurs in cracks or fissures traversing the nepheline. Under the micros- cope it is transparent, colourless, and altogether free from inclusions or alteration products. Cancrinite was noticed in considerable amount in the nepheline syenite where it crosses the Monck road in Faraday township, and is also found in the nepheline syenite about two miles east of Bancroft. On lots 85, concessions XIII and XIV" of Dungannon, the cancrinite was found in small irregular masses with rather ill-defined boundaries, and so intimately associated with the nepheline as to be separable only with extreme difficulty. The cancrinite is translucent, of a pale citron-yellow colour, gradually fading on exposure to the ' Am. Jour. Sc. Vol. XLVIII. 1894. pp. 17 and 18. " Am. Jour. Sc. Vol. XLIX. 1895. pp. 465-466. ' Trans. Roy. Soc. Can. Vol. I., Sect., III., 1882-83., p. 81. Sec. IV., 19ns. 2. 18 ROYAL SOCIETY OF CANADA weather. It has a subvitreous and somewhat greasy lustre. It is un- doubtedly an alteration product of the nepheline, the cleavage planes, in eoutiguous masses or areas, being common to both minerals while boundaries between the two are rarely, if ever, sharp or distinct.^ Feldspar. — Plagioclase varying in composition from albite through oligoclase to andesine^ is the prevailing feldspar in all of these syenites. Albite, with a small percentage of lime, seems to be the most coimuon variety. The specfic gravity of the rock near York river is 2.6207 and 2.625, while in a separation of the rock from lot 35, con. XIV of Dun- gannon, it was found to be not greater than 3.623. The specific gravity of the fresh oligoclase from the syenite was about 3.64, although some of it which had undergone partial alteration was considerably lighter. The andesine which is the feldspathic constituent of the nepheline syenite from lot 12, concession XV of Dungannon, was determined by heavy Srolution on fine fragments to be 2.668. An analysis of this feldspar is given on page 67. A noteworthy feature in connection with the development of the feldspar is the frequent occurrence of a thin mantle of plagioclase (al- bite) more or less completely surrounding individuals and even aggre- gates of hornblende and separating these from the surrounding and more . abundant nepheline. It has also been noticed as a border surrounding calcite and between this mineral and the nepheline. This bordering zone of plagioclase is rather variable in width, but shows very marked optical continuity' over long distances, in this respect also being in close agreement with similar feldspathic material which occurs filling up the various inequalities in the hornblende individuals formed as a result of this mineral's imperfect crystallographic development — and also with in- clusions of feldspar in the midst of the hornblende. In some respects this phenomenon resembles certain " reaction rims, " and it is thus ex- plained by Holland;^ but what seems a more reasonable explanation of the Ontario occurrences is that as the plagioclase succeeded and to a certain extent overlapped the crystallization of the hornblende, it would ^ have been attracted to such centres of crj^stallization as had already been formed by the solidification of the earlier and more basic mineral. This curious occurrence is well illustrated in certain of the hornblendic varietii'S of the syonito exposed at the dam at Bancroft and at Egan Chute on the York river. The larger crystals of corundum occurring in the nepheline rich variety of the syenite at Craigmont are also frequently surrounded by a zone of plagioclase, separating the former mineral from the nepheline. ^ Can. Rec. Sc. Vol. VII, No. 4, 1896-97. 2 Mem. Geol. Surv. Ind. Vol. XXX, Part 3, 1901, pp. 190-191. [ADAMS & BARLOW] ALKALI SYENITES OF EASTERN ONTARIO 1 9 Microcline in rather unusual in the nepheline syenite and much of it presents a somewhat indefinite and distorted mesh which is not dis- tinctive. Much of the microperthite has the veiy fine and interrupted twinning lamellae characteristic of anorthoclase with which it is prob- iably identical. Most of what has been considered to be orthoclase also shows quite a perceptible intergrowth of other feldspars, the potash feld- spar being, however, predominant. A white and reddish mineral, which was proved on analysis by Dr. Harrington to be orthoclase, fills certain little cracks traversing the sodalite on lot 25, concession XIV of Dun- gannon. It is mostly dull, but in places shows cleavage surfaces with a pearly lustre. The reddish portions probably owe their colour to the decomposition of pyrite, occasional grains of which still remain. The mineral is regarded as secondary. The specific gravity at 18° C. was fcund to be 2.555, and analysis gave the following percentage composi- tion: — SiO^ 63.00 AI263 18.93 Fe^O, ' .59 Cab .08 MgO .09 K2O 12.08 ISTa^O 3.67 Loss on ignition 1.00 99.44 An analysis of the microperthite of the corundum-bearing syenite pegmatite of Craigmont in the township of Eaglan is given on page 71. Scapolite. — This mineral is a frequent and often abundant con- stituent of the nepheline syenite, occurring in clear colourless grains which meet the accompanying neplieline and feldspar grains with a per- fectly sharp outline, there being no evidence that the mineral is the re- sult of alteration or weathering. The double refraction is much stronger than in the nepheline and feldspars, the interference colours seen in the thin sections being red, blue, and yellow. In this it resembles cancrinite, from which it can generally be distinguished by its habit, the cancrinite usually filling in cracks and the small interspaces left after the crystalli- zation of the other constituents. Biotite. This is the chief iron-magnesia constituent of these rocks, but it is usually present in subordinate amount. It occurs in the usual small scales and plates, some of wh^ch exhibit good crystal boundaries. The hand specimens show an almost black mica which has usually a dis- 20 ROYAL SOCIETY OF CANADA tinctly greenisli colour in transmitted light. The thin sections under tlie microscope have a very strong pleocliroism I'rom pale greenish yellow- to very deep almost opaque greenish brown. Basal sections are dis- tinctly bisaxial, but with a very small axial angle. In some of the coarser phases of the rock, as well as occupying certain miarolitic cavities, as in the north-west corner of Faraday, some of these biotite cr}'stals are veiy large and well formed. An analysis of the biotite (lepido- melane) occurring in the nephcliue syenite on lot 16, range IX of the township of Monmouth is given on page 35. Hornblende. — Although less common than the biotite this mineral is occasionally the prevailing ferro-magnesian constituent. Dr. Adams, in his first description of the Dungannon occurrences, made mention of the fact that two distinct varieties of hornblende, both green in colour, could often be distinguished in the same hand specimens, and this has been found to be true of outcrops in the south-western and north-eastern extensions of the band. The individuals are, as a rule, much larger than those of the biotite and present a nearer approach to perfection of crystallographic outline. The prismatic cleavages at angles of about 121° are often well seen. The first variety has a large axial angle, with strong pleochroism in tints var\'ing from pale yellow to deep green. Before the blowpipe it fuses with intumescence to a black glass, giving at the* same time a strong soda flame. This variety probably contains a considerable quan- tity of soda, but approaches common hornblende in composition. The second variety, the type specimen of which was obtained from a series of exposures about two miles to the east of the village of Ban- croft in Dungannon township, has a small axial angle with a high ex- tinction angle and a much stronger pleochroism in the bluish tints sug- gestive of arfvedsonite. The mineral occurs in hypidiomorphic grains wliich show the usual hornblende cleavages. It is optically negative, a being the acute bisectrix, but the double refraction is weak. It pos- sesses very strong pleochroism as follows: a=:^ 3'ellowish green, b and c = (looT) bluish green. The absorption is c = b > a, b and c, if not quite ci|ual, are nearly so, hence sections cut at right angles to the acute bisectrix show but litlle pleochroism and are nearly isotropic. c lies nearest the vertical axis, but whether toward the acute angle b or on the opposite side cannot be determined, as the mineral does not pos- sess a good crystalline form; it makes with the vertical axis a large angle, the extinction amounting to 30^. The plane of the optic axis is the clinopinacoid, and there is a strong dispersion — red greater than violet. WIk'T) :i softion, cut at right angles to the acute bisectrix, is ex- [ADAMS 4 barlow] ALKALI SYENITES OF EASTERN ONTARIO 21 amined between crossed nicols in convergent light, a black cross is seen, thickened towards the intersection of the arms. This cross, on revolv- ing the stage, divides into two hyperbolas, but these separate from one another but very little and appear to separate less than they really do, on account of the fact that the low double refraction and deep colour of these sections cause the hyperbolas to be ill-defined, while the whole field is very dark. Tlie dispersion, however, makes itself evident in the varying colours on the sides of the hyperbolas. When, however, a gyp- sum plate giving a red of the first order, is inserted alDove the objective, the hyperbolas become a little better defined, although still not sufficiently definite to allow the axial angle to l)e accurately measured. The axial angle is found to be over 30°, possibly as much as 45°, which, however, is still very small for hornblende, being about one-half the usual value.^ This hornblende resembles a variety intergrown with the augite in the nepheline S3^enite from the Corporation Quarry at ]\Iontreal. It also resembles in some respects the variety described by Hackman under the name " arfvedsonite " occurring intergroAvn with aegirine in the nepheline syenite from Umptek in the Kola Peninsula.^ The Kola hornblende is much lighter in colour than that from either of the Canadian locali- ties. This hornblende was analyzed by Dr. Harrington with the follow- ing results : — SiO^ :j-t.l84 TiO^ 1.527 Al^O. 11.517 Fe.Og 12.6-21 FeO 21.979 MnO .639 CaO 9.867 MgO 1.353 KoO 2.286 Na.0 3.290 H.O .348 99.601 Specific gravity 3.433 lAm. Jour. Sc. Vol. XL VIII, 3rd Series, 1894, p. 13, and Am. Jour. Sc. Vol. 1. 4th Series, 1896, p. 210-218. ^Can. Rec. Sc. Vol. VII. 1896-97, pp. 77-87. 22 ROYAL SOCIETY OF CANADA The name '" Hastingsite "' was suggested by Dr. Harrington as a varietal name for this hornblende, thus connecting it with the region where it occurs. Muscovite. — This mineral seems to occur in two definite and dis- tinct forms. First, in comparatively small individuals, somewhat similar in dimensions and habit to the biotite, which is the usual and more abun- dant mica. In this mode of development it is often intergrown with the biotite. In the second place, the muscovite occurs in much larger plates and aggregates, in more or less intimate association with corundum, in those types of the syenite which have consolidated from a magma supersatu- rated with alumina. It is, therefore, present in greater abundance and is more characteristic of these somewhat unusual types of the nepheline syenite, which mainly by the almost complete failure of the ferromag- nesian minerals, favoured the separation of the excess of alumina in the form of corundum. The mineral, under these conditions of association, has always been described and regarded as secondary, resulting from the alteration of the corundum. The supporters of such a view, argued that every gradation in the process of this alteration may be seen, from those occurrences, in which a comparatively pure crystal has been replaced by muscovite. On the other hand, the peculiar conditions which at- tended and contributed to the replacement have never been satisfactorily explained. Both minerals are developed side by side in perfectly fresh and unaltered rocks, the surrounding constituent minerals having under- gone little or no perceptible change. Moreover, it is well known that corundum is one of the most unalterable of substances when subjected to ordinary processes of atmospheric decay, this fact receiving the strongest support from the Ontario occurrences. The critical and ex- tended study of these Ontario deposits of corundum, both in the field and in thin sections under the microscope, shows that this apparent al- teration is closely connected with some phases of pneimiatolytic or vein action, which immediately preceded the complete solidification of the rock. The extreme phases of this alteration are best seen in the peg- matitic or coarser varieties of the syenite, although examples are not lacking in the more normal grained portions of these rocks. Indeed it seems to belong to the same class of phenomena as the " corona " or " reaction rims " which so frequently surround some of the earlier formed minerals in many plutonic rocks. (See Plate 10.) The alteration in the case of the Ontario corundum is always to muscovite and this mineral may be considered chemically as made up of orthoclase. corundum and water. Morozewicz has shown experimentally that a magma such as that which on cooling gives risa to a soda syenite [ADAMS 4 BARi.ow] ALKALI SYENITES OF EASTERN ONTARIO 23 has the power to dissolve alumina and on cooling to separate out any- excess completely. The conditions laid down by what is known as Moro- zewic^'s law (see page 65) are completely fulfilled by the corundum- bearing nfipheline syenites of Ontario. In all magmas^ those of acidic composition especially, water is believed to be present in consideraljle amount. As the corundum separated out, the magma would tend to ap- proach more nearly to the composition of a mass of fused feldspar to- gether with a certain amount of water. At this stage, and on account of some condition or change of conditions, this residual magma attacked the corundum, the hydrous feldspathetic magma together with the alumina from the dissolved corundum making muscovite, which crystal- lized around or replaced the corundum, according to the following for- mula : — K2O, AI2O3, eSiO^ (:= orthoclase) -f 2AL,03 (= corundum) + 3HoO = K.O, 2H2O, 3AI2O3, 6SiOo = muscovite. This likewise explains the marked prevalence of this altera- 'tion in the pegmatitic fades of the syenite, for it is in these residual dift'erentiated portions of the magma that water plays such an important part in the process of crystallization. Corundum. — The crystals when normally developed are usually six- sided prisms which are sometimes terminated by a six-sided pyramid and not frequently by the basal plane. Many of the ciystals especially those occurring in the nepheline syenite have a tolerably sharp and perfect outline, frequently tapering +,0 either extremity, thus producing the very characteristic barrel-shaped form. The pyramidal and pris- matic faces arc very often more or less deeply striated or grooved horizon- tally. The basal planes or truncated ends of the crystals are frequently striated in three directions, forming equilateral triangles, corresponding with the less perfect rhombohedral partings or pseudo-cleavages. The crystals yavj greatly in size, the lairgest noticed in the nepheline syenite being about eight inches in length by two inches in diameter. Such crystals are comparatively rare, the usual size being about two to three inches and from that sinking to those of microscopic dimensions. The larger crystals as well as the very small ones are usually inclined to have an irregidar or imperfect outline. The conmdum is in many in- stances somewhat brittle, breaking with an uneven or conchoidal fracture, but when in large masses it is exceedingly tough. The lustre is in general vitreous, but in the translucent light green variety noticed in Brudenell township the lustre is somewhat pearly. The colour of the corundum in the nepheline syenite is in general of varying shades of blue to white. It is sometimes of a distinct rose-red colour. Many of the crystals, especially those present in the nepheline syenite exposures in the vicinity of York river, show an irregular or cloud-like arrangement 24 ROYAL SOCIETY OF CANADA of the colour material, shading ofT from deep azure blue through pale blue to colourless. Occasionally crystals exhibit a very decided and beau- tiful zonal arrangement. The hardness of the mineral is a = 9. The specific gravity of the blue corundum from the nepheline syenite of Dungannon ranges from 3.i)3 to 4.01, Avith an average of 3.95. A microscopical exajiiination of the thin sections of the rock shows that in addition to the larger and more perfect crystals which are visible to the naked eye, there are often innumerable small, usually exceedingly iri-egular individuals distributed through the rock. Corundum under the microscope has a high index of refraction but a low double refraction, and in good thin sections the interference colours do not exceed a red of the first order. Such sections are, how- ever, difficult to obtain on account of the relatively much greater hard- ness of corundum as compared with the surrounding minerals. When these latter have been ground sufficiently thin the corundum grains, as may be seen in sections from which the cover glass has been removed, stand out in relief, the result of their resistance to the grinding operations. As a consequence, therefore, the corundum seems to have a higher double refraction than it actually possesses, and the mineral in most thin sections shows \ery brilliant polarization colours between crossed nicols. The pronounced relief, the dark borders of total reflection, the rough surface and the parting planes or pseudo-cleavages are very strongly marked, as is also the nega- tive character of the double refraction. The following localities show corundum in the nepheline syenite, most of which are of economic im- portance: — Lot 12, cons. XI and XII; lot 18, con. XI; lot 12, con. XIV . and XV; lots 6 and 7, con. XV; lots 6 and 7, con. XVI, Dungannon township. Lot 4, con. I, Monteagle; lots 2 and 3, con. II, Monteagle. Lot 34, con. V., lot 25, con. VI, and lot 32, con. VII of BrudencU town- ship. (See Plates 10 and 12.) An analysis of the corundum from lot 12, con. XV, of Dungannon is given on page 68, and an analysis of the corundum from Craigmont. in the township of Kaglan, on page 72. CaJcitr. — This mineral is very frequently present and is especially abundant in those exposures which are in immediate contact with crys- talline limestone. Its unexpected presence in the rock has already been explained elsewhere (see page 12). That the mineral is foreign to the magma and represents included fragments of the neighbouring crystalline limestones is in dii'cct agreement with all the phenomena so far observed. Its mode of occurrence is essentially that of an original constituent, be- ing found in eompnratively large, well defined, unusually rounded grains, sometimes completely enclosed by the other constituents, or in other cases lying between them. The line of separation is quite sliarp and CD < P4 [ADAMS A BARLOW] ALKALI SYENITES OF EASTERN ONTARIO 2S distinct, with no hint of decomposition in any of the sun-ounding minerals. The individual grains show the nsual perfect rhomhohedral cleavages often with well marked twinning lamellae. Comparatively largo individuals occur in the pegmatitic phases as noticed in the ex- posures west of the bridge over the York river in Dungannon township. Garnet. — This mineral is of common occurrence and is occasionally so abundant, especially at certain exposures near the York river in the northern part of Dungannon, as to characterize the rock. In the hand specimen it exhibits a dark reddish l^rown colour. In thin sections it is, of course, much paler in tint, assuming a deep brownish tint, fading to a yellowish towards the interior of the larger grains. It shows the usual high index of refraction and coiisequent very pronounced relief. It is quite isotropic. The individuals and especially the larger grains usually possess a ver\- irregular outline, with irregular arms and intricate in- dentations and hold abundant inclusions of most, if not of all, of the other constituent minerals of the rock. In some instances it exhibits well developed crystallographic boundaries. It is especially abundant in those varieties of the syenite which contain hornblende, and is for the most part developed in immediate n^soeiation with this mineral. It resembles a garnet found in small amount in the nepheline syenite of the Corpora- tion Quari'v at Alontreal, and also the melanite in the nepheline syenite of Alno.^ A chemical analysis by Dr. B. J. Harrington- of the variety asso- ciated with Hastingsite about two miies east of the town of Bancroft in the township of Dvmgannon afforded the following results, showing the garnet to be a titaniferous andradite: — SiO, 36.604 TiO, 1.078 A1,0, 9.771 Fe./)., 15.996 FeO 3.852 MnO 1.301 CaO 29.306 MgO 1.384 Loss on ignition .285 99.577 Specific gravity at 16° C 3.730 1 Geol. Foren. i. Stockholm, Forh. 1895. p. 144. = Can. Rec. Sc, Vol. VI., 1894-95, pp. 480-481; also Vol. VII., 1896-97, pp. 87-88. 26 ROYAL SOCIETY OF CANADA Zircon. — This mineral is quite commonly seen in thin sections under the microscope. The microscopic individuals have a rather short pris- matic form and are as a rule somewhat rounded. In some of the coarser phases of the rock, noticeably at the York river in Dungannon and at Craigmont in Eaglan. crystals are not uncommon which would measure from a quarter to half an inch in length. On lot 32 of con. II of Glamorgan, crystals of zircon over an inch in. diameter are found in dykes of nepheline syenite, each of these crystals displaying a double tetragonal pyramid. One short stout crj'-stal at present in the Museum of the Geological Survey measures an inch in length by three-quarters of in inch across. These crystals " show two quite different habits : one in which by the development of two opposite pairs of the pyramidal faces, together with a pair of the prisms of the second order, the crystal becomes columnar in this direction and mimics a hexagonal prism of the second order terminated by rhombohedral faces. In the second habit the pyramidal faces are strongly developed, while the prism faces are short or lacking altogether."^ Sphene (Titanite). — This mineral is sometimes present although l)y no means abundant, and so far as observed, it occurs in microscopic crystals only. It is often in characteristic wedge-shaped though some- what rounded forms, but also occurs in irregular grains. It is more iibundant in the hornblendic varieties, Avhere it is often quite an im- portant accessory constituent. Tourmaline. — This mineral is seen occasionally and in only small amount. It occurs in characteristic crj^stals, which are black in colour. Spinel (Auiomolite) . — A dark green spinel evidently closely allied if not identical with automolite is occasionally found in the nepheline syenite, although it is more abundant in the red alkali syenite. Chrysoheryl. This mineral is occasionally met with in the alkali syenite at Craigmont, associated with the corundum. Eucolite. — A mineral with the characters of eucolite occurs rather abundantly in the hornblendic variety of the nepheline syenite at Egan chute on the York river as w^ell as at another locality a little lower down on the same stream. It has a yellow colour and usually displays an im- perfect crystallographic form. It is intimately associated with horn- blende and garnet, frequently enclosed in the former and resembling the latter closely in appearance. It has, however, when examined m tbin sections, a distinct, though low double refraction with negative sign, but a high index of refraction with decided relief, a rough surface and paral- lel extinction. It is further distinguished from the garnet by a decided >Amer. Jour, Sc. Vol. XLVIII., 1894, p. 215. [ADAMS A barlow] ALKALI SYENITES OF EASTERN ONTARIO 27 difference in colour, the garnet being brownish or reddish brown in thin sections, while the eucolite is pale yellowish. In a heavy solution, euco- lite falls with the hornblende and garnet and can only be separated with •the greatest difficulty from these minerals. By magnetic separation several times repeated, fairly pure material is obtained, but hardly pure enough for purposes of chemical analysis. It is likely that further and more careful search in this region will show a larger and more abun- dant supply of this mineral. Molybdenite. — This mineral is occasionally found and occurs usually in small plates and scales and less frequently in crystals. Apatite. — This mineral is a very common constituent of the nephe- line syenite, but it is usually present as a very subordinate accessory con- stituent and in very small, often microscopic, crystals. In some locali- ties, especially in association v/ith the magnetite on lot 30, con. XIII of Dungannon, comparatively large crystals of apatite may be obtained, while in the north-west comer of Faraday, similarly large and well de- fined hexagonal prisms, terminated by planes of two pyramids, have been collected. Occasionally these crystals were noticed growing together in parallel position, the resulting individual simulating a twin crystal. Magnetite. — This mineral has a very general distribution through- out the whole mass of the nepheline syenite, although its complete and unexpected absence from occasional outcrops representing even the more basic phases of the rock is noteworthy. It is usually present, however, and is certainly one of the more important of the accessory con- stituents. Individuals in thin sections under the microscope often show fairly good crystalline form, but the grains are usually somewhat rounded and irregular in outline. The mineral is most conspicuous and abun- dant in the more feldspathic variety, especially the red syenite. In many places the magnetite has differentiated out from the rest of the rock and forms large and important masses of this mineral, much of which is free from any other admixture. Attempts have sometimes been made to work some of these masses in the hope that they would ultimately become producing mines. At one locality on lot 30, con. XIII of Dungannon, considerable development work, consisting chiefly of stripping and blasting, has revealed the presence of considerable bodies of very pure magnetite which, however, judging from analogous occurrences accompanving the red syenite and which have been analyzed, would in all probability contain titanium. The mineral here has a very perfect octahedral cleavage. In certain localities in Dungannon, and especially in the north-west corner of Faraday, perfect octahedrons of ma^gnetite can be occasionally secured weighing several pounds. (See 28 ROYAL SOCIETY OF CANADA Plate 8.) An analysis of the iiiagnetiti' oceiirriiii: in the syenite peg- matite at rrai?iiinnt. in the township of Hadrian, is given on page 72. Pyrite, ri/rrhotitr and Chalcoininic — All three of these minerals have been fount! as constituents of the neplieline syenite. Pyrite is the most common. Under the microscope it is occasionally ])resent in small well defined cubes, but usually it occurs in rounded or irregular grains. Graphite. — This mineral is not, so far as observed, a frequent or an abundant constituent, but it has been noticed in the coarse phase of the neplieline syenite exposed to the east of the York river in Dungannon township. It occurs very pure, in small rounded shot-like forms con- sisting of minute scales of the mineral arranged in a radiating or plumose manner. In certain poiiions of the rock at this locality, gra- phite in this form is quite abundantly distributed. It has been noticed as an important and characteristic mineral in a certain variety of the nepheline syenite of Sivamalai m India, described by Holland, where it constitutes 0.58 per cent of considerable masses of the rock.^ Holland explains its presence in this rock as due to its crystalliza- tion from fusion, and regards it as a primary constituent and older than the feldspar. This conclusion may be taken as applying also to the graphite in the York river nepheline syenite. Description of the Several Occurrences. For purposes of description it will be most convenient to group the several occurrences by townships, as follows: — I. The alkali syenites of the township of Lutterworth. II. The nepheline and associated alkali syenites of the township of Monmouth. III. The nepheline and associated alkali syenite's of the township of Glamorgan. IV. Tlie nepheline and associated alkali syenites of the townships of Harcourt, Carditf and Wollaston. V. The nepheline and associated alkali syenites of the township of Methuen. A'T. The nepheline and associated alkali syenites of the townships of Faraday, Dungannon, Carlow and Monteagle. I. The Alkali Syenites of the iov)nship of Lutterworth. — The corundum-bearing syenite was discovered on lot 12, con. IV, in this township, by Mr. Tett, v/hen acting as assistant to W. A. Johnson, Esq., of the Geological Survey of Canada, in the summer of 1905. This rock is said to occupy an area from thirty to forty acres in extent and to cut Mem. Geol. Surv. Ind., Vol. XXX, part 3, pp. 174 and llo. [ADAMS A barlow] ALKALI SYENITES OF EASTERN ONTARIO 29 the gneissic granite of the district. Mucli of the rock contains over ten per cent of corundum.^ II. The Nepheline and associated Alkali syenites of the tov:n- sliip of MoTWiouth. — The largest and most important occurrence of nepheline syenite in this township, is that which is found as a border around the body of pegmatitic granite which runs through the centre of the township stretching in a direction about N.30°E. from con. VII to con. XIV, a distance of about six miles. This granite mass has a maximum width of a little over a mile. The border of nepheline syen- ite varies from one-eighth to half a mile in width. Fine transverse sections from the limestones on either side through the nepheline border to the central mass of granite can be obtained on the several roads which cross this occurrence. The rock which has been referred to as granite, is pink or red in colour and is usually of medium grain. It shows in many places that irregular and often rapid variation in size of grain which is seen in pegmatite. At the north-eastern end of the mass on lot 29, con. XIII, it has a distinctly foliated structure. Farther south the foliation becomes less distinct, although the rock still retains a streaked appearance. This granite is never rich in quartz, although in the north-eastern part of the mass and as far south as con. XI, this mineral is present in considerable amount. Farther to the south-east the quartz decreases in quantity and the rock passes into a syenitic phase. The rock as ex- posed on lot 26, con. XII of Monmouth, in the middle of the granite mass, is a medium grained granite, red m colour and with a rude folia- tion. The quartz is light gray and glassy. The feldspar is red on the fresh surface of fracture and shows a good cleavage and high lustre, but weathers to a pale red or pink colour. The iron-magnesian constituent is present only in small amount. Under the microscope the rock is seen to be composed of the follov/ing minerals : — albite, microcline, ortho- clase, microperthite, quartz, hornblende, biotite, sphene, apatite and magnetite. Jt was found by making a separation with Thoulet's solu- tion that the amount of albite and microperthite taken together was about double the sum of the amounts of orthoclase and microcline pre- sent in the rock. Quartz is about equal in amount to the potash feld- spars. The ferro-magnesian constituents occur in aggregates of in- dividuals which have a rather frayed or irregular outline. Very few of these approach an idiomorphic development. Two varieties of horn- blende are present : one green and the other blue in colour. The former is evidently ordinary hornblende, showing a pleochroism in yellow and green tints with an extinction of 20°. The blue variety of hornblende * Geological Survey of Canada, Summary Report, 1905, p. 93. so ROYAL SOCIETY OF CANADA is intergrown with that just mentioned, and presents absorption colours ranging from deep lavender blue to light green. Biotite is present in insignificant amount. The syenite phase of this rock is red in colour and composed almost exclusively of feldspar, which is for the most part micropcrthite, the iron-magnesian constituent occurring in occasional dashes with a rudely parallel arrangement. It differs from the granite, not only in the fact tliat no quartz is visible in the sections, but also in the absence of horn- blende. The rock contains a small amount of biotite, while a little mus- covite and calcite are also present. The latter may be secondary. The soda feldspar preponderates over the potash feldspar, as shown by the analysis given below. An analysis of this rock was made by Prof. Norton-Evans, with the following result : — SiO,. Al.O, Fe',0', Feb.. MnO. CaO. MgO. K.O. Na,,0 , PA- CO,.. HoO. per cent. 64.15 19.04 1.03 93 .16 1.37 .37 7.10 5.37 .10 .70 .37 100.58 If the norm of this rock be calculated, it will be found to be as follows. The omitted. calcite is considered to be secondary and is therefore Quartz 1.86 per cent Orthoclase 43.36 " Albite 45.59 " Anorthite 5.84 " Corundum .30 " Hypersthene 3.09 " Magnetite 1.39 " Apatite .34 " 99.67 [ADAMS A BARLOW] ALKALI SYENITES OF EASTERN ONTARIO 31 The position of the rock in the Quantitative Classification is accord- ingly as follows: — Class 1 Persalane. Order 5 Canadare. Rang 1 Normarkose. Sub-rang 3 Phlegrose. It is a question whether the calcite should be considered as an al- teration product or as representing little inclusions of the surrounding limestone, as in the case of the nepheline syenites described below. If, as above, all the lime be considered as belonging to the magma, the rock lies near the line between phlegrose and pulaskose. The mode of the rock, that is to say, its actual mineralogical com- position, is found on calculation to be as follows : — Quartz 4.20 per cent. Orthoclase 37.25 Albite 45.59 \ 47 26 Anorthite 1.67 J Muscovite 4.78 Biotite 3.93 Magnetite 1.39 Apatite 27 Calcite 1.60 100.68 This syenitic phase c^f the granite passes imperceptibly into the nepheline syenite on either side by the disappearance of the quartz with the concomitant increase of soda feldspar at the expense of the potash feldspars, together with the increase in the proportion of iron-magnesia constituents and the appearance of some nepheline. An albitic phase of the nepheline syenite thus results. This transition is excellently seen on lot 26, con. XII of Monmouth, tiie transitional rock being rather coarse in grain and dark in colour, having a faint red tinge and show- ing on the weathered surface a little nepheline and in one or two places small crystals of corundum. Rather large grains of magnetite are also scattered through the rock. It has a distinct foliation, due chiefly to the approximately parallel arrangement of the biotite, of M^hich a large amount is present. Under the microscope this rock is seen to consist of albite, ortho- clase, microcline and a little microperthite with nepheline, biotite and calcite. As accessory constituents magnetite and apatite are present in the thin sections. A separation by means of Thoulet's solution shows that there is about eighteen times as much albite as potash feldspar pre- sent in the rock. 32 ROYAL SOCIETY OF CANADA The transition between the syenitic phase of the granite and the nepheline syenite is also well seen at the southern end of lot 15, con. VIII of Jlonmouth. The nepheline syenite here, has a schliercn struc- ture caused by a variation in the relative amount of the constituent minerals in the different streaks. Some of these schlieren consist of red syenite and others are intermediate in composition between the red syenite and the nepheline syenite. There is thus represented in these schlieren a complete transition from the red syenite to the normal white or gray nepheline syenite. The nepheline syenite which forms the border of the mass, has a distinctly foliated structure and is coarse in grain. It is white to dark gray in colour, according to the proportion of the iron-magnesia con- stituents which it contains. In a few places, as, for instance, on lot 23, con. XI, it is pale pinkish, owing to the presence of a pink geiseckite- like alteration product of the nepheline. The rock is by no means uni- fonn in composition, but usually possesses a rudely banded or schlieren structure which conforms to the direction of the foliation, the different schlieren being marked by a variation of the relative percentage of the several minerals present. Thus, in some schlieren, the rock will be rich in nepheline, while, in the adjacent ones, the nepheline will almost or entirely disappear; again, there may be a variation in the relative pro- portion of the iron-magnesia constituents, which will give rise to a change in character. As a place where the rock is locally very rich in nepheline, lot 24, con. XII, may be cited, the nepheline rock hero in some places containing much magnetite m large grains scattered through it. These respective schlieren or bands are usually of considerable dimensions, being several feer to many yards in widtli, and, of course, are not sharply defined, but fade away into one another, although rather abruptly. Occasionally the grain of the rock will suddenly become iinuli coarser, the rock passing into a pegmatitic facies, this ])eing most com- mon in those places where nepheline is abundant. A detailed study was made of a variety of the nepheline syenite rich in albite and poor in nepheline, w^hich occurs on lot 16, con. IX of Monmouth, and forms part of this belt of nepheline syenite surrounding the granite. It was collected on the east side of the road between McCue lake and Hotspur, about one third of the way soutli of the north- ern limit of the band. The rock is coarse in grain and pos:^osses a distinc^t foliation. Under the microscope it is seen to possess a hypidomorphie structure and to consist of the following minerals: — Albite, mifroclino, microper- thite, nepheline, lepidomelane, magnetite and on kite. Jn some few schlieren a dark green hornblende (probably hastingsite) replaces a portion of the biotite. Albite and lepidomelane are the chief con- lADAMS & barlow] ALKALI SYENITES OF EASTERN ONTARIO 33 etituents. The albite is well twinned and must be a variety approach- ing the pure soda molecule, as it has a specific gravity of 2.618 and shows a maximum extinction against the line of the twinning lamellae ©f 15°. In a single slide a few grains having an extinction as high as 20° were observed, showing that a plagioclase somewhat more basic than albite is also occasionally present in very small amount. The microcline presents its usual characters and is frequently intergrown with albite, forming microperthite. The nepheline is in the form of large individuals similar in shape and dimensions to those of the albite. Smaller in- dividuals of it are sometimes seen to be included in the albite, while, in other cases, it includes individuals of albite. It is very fresh and free from alteration products. The lepidomelane is the same dark brown highly pleochroic variety of biotite which occurs in the transitional rock lying between the granite and the nepheline syenite (p. 32) and has the form of short laths. A lighter coloured mica is also present in, smaller amount. The calcite occiirs in large single individuals, often of a rounded form, sometimes enclosed in the feldspars, nepheline or lepi- domelane, but usually lying between the other constituents. The en- closing minerals show no signs of alteration and the calcite shows no signs of secondary origin. The magnetite is in large sub-angular or more or less rounded grains. There seems to be no definite order of succession in the crystallization, seeing that the various minerals en- close and penetrate one another. The lepidomelane, however, has a much better form than the other constituents and would thus seem to have crys- tallized earlier. An analysis of the biotite-bearing variety of this nepheline syenite was made by M. F. Connor, B.Sc, and gave the following results : — SiOa 51.58 per cent. TiO^ .35 AI2O3 19.40 Fe^O^ 4.26 FeO 5.25 MnO .20 CaO • 3.64 MgO .49 K2O 4.23 Na^O 7.49 PA -15 CO2 1.53 H2O 1.02 99.59 Sec. IV., 1907. 3. 34 ROYAL SOCIETY OF CANADA The norm of the rock is as follows : — Orthoclase 25.02 per cent. Albite 34.84 Anorthite 6.67 Nepheline 15.50 " Diopside .90 Olivine 5-05 Ilmenite .73 Magnetite 6.15 " Apatite .34 Calcite 3.45 98.65 Water 1.02 99.67 The rock has thus the following position in the Quantitative Clas- sification: — Class II Dosalane. Order 6 Norgare. Rang 2 Essexase. Sub-rang 4 Essexose. If the calcite be regarded as representing inclusions (and reasons will be given for thus considering it later on), the rock will lie just on the line between Essexose and Laurdalose. The calculation of the mode of the rock, that is to say the percen- tage proportion of the minerals actually present in it, cannot be made with absolute accuracy, since the precise composition of both micas pre- sent is not known. If, however, the micas be taken to have the samc^ average composition as the lepidomelane from the nepheline syenite of Litchfield, .Me., (see Bull. 168, U.S. Geol. Survey, p. 31), except that one per cent of alumina replaces an equivalent amount of ferric oxide, as is frequently the case in these minerals, the mode will he as follows : — Orthoclase 4.45 per cent. f^'^'f^.- ^^0.83 \ 52.08 " Anorthite 1.24 j Nepheline 8.05 " Biotite. . 29.61 " Iron Ore .73 Apatite .34 Calcite 3.45 Water t.02 • 99.73 ADAMS 4 BARLOW] ALKALI SYENITES OF EASTERN ONTARIO 35 This gives a plagioclase of the albite series having a composition Abio-g An., which is the proper composition as shown by the Ihoulet separation. The composition assumed for the nepheline is that of the nepheline of the Dimgannon nepheline syenite, the analysis of wliich is given on page 15. This arrangement of results leaves an excess of 1.25 per cent of lime and a deficit of 1.40 per cent of ferric oxide. The dark brown or black lepidomelane present in the rock was iso- lated by means of a Wetheral Electric Separator, followed by the use of Thoulet's solution, and was analysed by J. C. Egleson, M.Sc, of McGill University. It was found to have the following composition: — (^) SiO^ 31.48 TiO, 2.50 AI2O3 17.23 Fe^Oa 5.85 FeO 27.96 MnO l.Gl CaO 1.33 MgO 2.99 K2O 4.17 Na,0 1.68 Li,0 .00 Water (combined) ■. .. 3.94 Fl. .. .00 100.74 The specific gravity of this mica is 3.25. Another very interesting occurrence in this township is that pre- sented by the lenticular shaped mass of nepheline rocks, occupying por- tions of lots 9, 10, 11 and 12, cons. VI and VIII. This consists of nepheline syenite associated with rocks of the urtite group. The in- trusion breaks through the crystalline limestone of the Grenville Series, by which it is entirely surrounded, and of which it holds many inclu- sions. These included masses of the limestone are coarsely crystalline and have a variety of silicates developed in them. The nepheline syenite presents the appearance of eating into these masses. It might be sup- posed that the limestone was in course of solution by the magma, but there is no sign of an increase of lime-bearing silicates near the contact, for while in some places the nepheline syenite near the contact is rich in hastingsite, elsewhere about the border of the mass this and» other lime-bearing minerals are absent. Scapolite in this occurrence is com- paratively rare. It is probable that the mass of the limestone was carried 'An Examination of some Canadian Micas— Trans. Roy. Sec. of Canada, 2nd Ser., Vol. X, Sec. 3, p. 57 (1904). 86 ROYAL SOCIETY OF CANADA off in solution by the magmatic waters contained in the invading magma and given off by it as it solidified. On the weathered surface of the syenite, the limestone fragments, Tvhich in many places are thickly scattered through the rock, are dissolved away, leaving little pits and cavities into which the individuals of the nepheline and other constituents of the rock project, often with rude crystallographic forms. The intrusion has a marked foliation or gneissic structure, and is irregular in composition, consisting of a series of thick bands or schlieren running parallel to one another and to the strike of the surrounding lime- stones. Some of these schlieren are very highly feldspathic and hold but little nepheline. Much of the rock, however, is rich in nepheline, while in some of it, nepheline replaces the feldspar almost entirely. Bands as much as six feet in width can be found, which consist almost exclusively of nepheline. Usually those streaks which are rich in nepheline are also rich in hornblende, often with red garnet as an accessory constituent. Elsewhere the rock consists of nepheline and albite. In the latter variety small individuals of white mica sometimes occur which exactly resemble the crystals of this mineral which in other parts of the area are formed by the alteration of corundum. The highly feldspathic type which resembles those already described does not require further mention, but three tpyical varieties of the rock in which nepheline is more abundant were selected for study, Nepheline Syenite — Township of Monmouth — Lot 11, Con. VIII. (First variety). This is a variety rich in hornblende. It is coarse in grain, dark in colour, and possesses a distinct gneissic structure. Under the microscope it is seen to consist of nepheline, albite, horn- blende and calcite, Avith a small amount of apatite as an accessory con- stituent. These minerals, with the exception of the apatite, are all in large individuals, and like most of the nepheline syenites of this area, have a peculiar structure which approaches an allotrimorphic struc- ture in character. JSTone of the minerals have good crystalline forms, but all have a tendency to occur with more or less rounded outlines and to come against one another in curved lines. In- clusions of one mineral in another are common, no definite order of succession can be observed in the crystallization, and the structure in some respects approaches the ''mosaic" structure feen in the metamor- phic rocks when a complete recrystallization has taken place. The nepheline is considerably altered to a very fine grained turbid aggregate resembling kaolin, but in places it is quite fresh and shows ADAMS 4 barlow] ALKALI SYENITES OF EASTERN ONTARIO 37 its usual optical properties. It frequently holds rounded inclusions of albite and of calcite. The albite is well twinned and possesses the usual characters. The hornblende is the most abundant constituent, and, if not hastingsite, is a variety closely resembling it. It is deep gi-een in colour, looks black on the fractured surface of the rock. Although the rock is so basic, it contains no iron ore, which is elsewhere common as ani accessory constituent in such rocks. The calcite, as usual occurs aa rounded inclusions in the albite, nephcline or hornblende, or filling spaces between the grains of these minerals. No microcline nor micro- perthite is present in the sections. Analysis of the jock by Prof. Norton-Evans shows it to have the following composition : — SiO, 43.67 per cent. TiOo .78 AI263 20.91 Fe^Og 3.54 FeO 8.01 MnO .05 CaO 7.37 MgO 1.46 K2O 2.25 NaoO 6.73 P2O5 11 " CO2 2.37 H,0 2.52 99.77 'i'he norm of the rock will then be as follows : — Orthoclase 12.79 per cent. Albite 22.01 Anorthite 20.29 Nepheline 19.03 Olivine 10.58 Ilmenite 1.52 Magnetite 5.10 " Apatite .34 " Calcite 5.41 97.07 Water 2.52 " 99.59 38 ROYAL SOCIETY OF CANADA Its pot^ition in the Quantitative Classification is as follows : — Class III Dosalane. Order 6 Norgare. Rang 2 Essexase (very near Salemase). Sub-rang 4 Essexose. Its mode or actual niineralogical composition is as follows: — Orthoclase 2.78 per cent. Albite 22.27 \ 23.94 " Anorthite 1.67 / Nepheline 15.91 \ 26 23 "' Kaolin 10.32/ Hornblende 39.75 " Apatite .34 ■(^alcite 5.50 " 98.54 Water 1.10 " 99.64 Nepheline syenite — Township of Monmouth — Lot 11, Con. VIII. {Second Variety). This is rich in nepheline and contains a large percentage of py- roxene. It is much lighter in colour, but otherwise bears a general re- semblance to the variety just described. Under the microscope all the constituents are seen to be fresh, but they frequently show signs of hav- ing been submitted to pressure, as shown by the presence of a more or less uneven extinction. This is especially marked in the case of the calcite, and the albite can in some few instances be seen to have been not only bent but actually fractured. The nepheline also occasionally shows strain shadows. As before, no microcline nor microperthite is present in the sections and a Thoulet separation shows that the rock contains no potash feldspar. The albite has a specific gravity of verv- nearly 2.61. The pyroxene is very deep green in colour and somewhat pleochroic. Around the individuals of this mineral and occasionally about the cal- cite grains, there is sometimes a narrow border of garnet. The pyro.xene is evidently very rich in iron and holds rounded inclusions of calcite and nepheline. [ADAMS A BARLOW] ALKALI SYENITES OF EASTERN ONTARIO 39 An analysis of the rock by Prof. Norton-Evans shows it to have the following chemical composition : — SiO. 42.72 per cent. TiO^ .38 AI2O3 25.08 FcaOa 2.00 FeO 4.36 MnO .16 CaO 6.92 MgO .97 K2O S-69 NaoO 11.02 PA .19 CO2 2.99 H^O 88 100.36 lis norm is as follows: — Orthoclase 15.57 per cent. Albite 7.34 Anorthite 10.80 Nepheline 46.58 Diopside 3.08 Olivine 5.10 Ilmenite .76 Magnetite 2.78 Apatite .34 Calcite 6.80 99.15 Water .88 100.03 Its position in the Quantitative Classification is: — Class II Dosalane (very near Persalane). Order 7 Italare. Rang 2 Vulturase. Sub-rang 4 Vulturose. 40 ROYAL SOCIETY OF CANADA If thi^; rock posses.-!e(l about one-half of one per cent less iron-mag- nesia constituents, it would fall into the class of persalanes and would constitute the first dosodic domalkalic tasmanare known. The mode or actual mineralogical composition of the rock is a8 follows : — Albite ... Nepheline Pyroxene Garnet Iron Ore Apatite Calcite Water. 19.39 per cent, 50.57 a 18.35 ii 1.45 a 1.8G u .34 a 6.80 a 98.76 .88 a 99.64 NepheUne Rock (MonmoutJiite) — Township of Monmouth — Lot 19, Con. VIII. (Third Variety). This consists essentially of nepheline and hornblende, the rock be- ing practically free from feldspar. It is found in bands six feet or more in width, which bands may be traced for long distances on the strike. The rock is coar.ee in grain, the white nepheline and black hornblende being strongly contrasted on the surface of fracture. The hornblende in the case of the nepheline syenite has a tendency to run in streaks parallel to the course of the bands. On the weathered surface the rock is pale grey in colour and presents the smooth surface assumed by nephe- line whsn exposed to the weather, ih^ black hornblende standing out from it. Tinder the microscope the rock is seen to consist esseixtially of nepheline and hornblende, with plagioclase, cancrinite, and calcite as accessory constituents, as well as sodalite, apatite, sphcne, biotite, pyrite and iron ores, these latter minerals being present in extremely small amipunts.^ The nepheline occurs in large well-defined grains, presenting the usual characters displayed by the species. It is clear and fresh. ' F. D. Adams. — On a New Nepheline Rock from the Province of Ontario, Canada. Am. Jour, of Sci., April, 1904. AUAMS A BARLOW] ALKALI SYENITES OF EASTERN ONTARIO 41 The hornblende is green in colour, the pleochroism and absorption being as follows: — Ci = pale greenish yellow, b and C = very deep green. The absorption is C = b > a. The maximum extinction ob- served in the sections of the rock was 19°. It is an alkali hornblende, containing less iron than hastingsite, but like it, as shown by the cal- culation of the analysis of the rock, belonging to the division of the syntagmatites. The plagioclase is present only in very small amount and is in some cases untwinned, while in other case.? it shows a faint, polysynthetic twinning. In thin sections it bears a very close resemblance to the nepheline, and when untwinned it is difficult in all cases to distinguish the two minerals. When a section is treated with acid and etched, how- ever, the plagioclase is seen to occur in individuals of a more or less rounded form, or with curving outlines, lying between the nepheline grains or enclosed in the latter. The feldspar isolated from another variety of the rock in the same occurrence was found to be albite, and this feldspar has, therefore, been taken as albite in calculating the mode of the rock. The amount of cancrinite present varies very considerably in dif- ferent specimens of the rock. In the specimen analyzed about 5 per cent was found. In other specimens more is found, although in no case is it very abundant. It is clear and colourless, but is at once distin- guished from the nepheline when examined between crossed nicols by its much higher polarization colours, which in thin sections frequently rise to a blue of the second order. It is free from interpositions, and in con- vergent light is seen to be uniaxial and negative. It also shows a slight but distinct dispersion of the bisectrices, giving a brownish and a bluish tint on either side of the position of maximum extinction. When separ- ated by Thoulet's solution, the mineral was found to have a specific gravity between 2.44 and 2.48, and to be readily decomposed when heated with dilute hydrochloric acid, with the evolution of carbonic dioxide, and with subsequent gelatinization. The cancrinite occurs in the nepheline in the form of narrow strings or more rarely in little bunches of grains. These usually follow the course of minute cracks or cleavage lines, but also are frequently seen to follow the boundaries of individual grains of nepheline on their contact with grains or other minerals. Thus be- tween crossed nicols they appear as a brilliant edging about hornblende individuals or about calcite inclusions m the nepheline, the small pris- matic individuals of cancrinite being arranged with their longer axes at right angles to the contact or to the course of the crack, as the case 42 ROYAL SOCIETY OF CANADA may bo. The cancrinite has the appearance of being an alteration pro- duct of the nepheline. Calcite occurs in large single individuals, which are found as in- clusions in both the hornblende and the nepheline. The single in- dividuals are often perfectly circular in outline, and the enclosing mineral is perfectly fresh arid unaltered and is sharply defined against them. In ether cases the same large calcite individuals lie between the other con- stituents of the rock, in all cases having the character of inclusions. They generally show very marked strain shadows, while the other con- Btituents show but little or no evidence of pressure phenomena. The apatite is found as occasional more or less rounded individuals, enclosed in the nepheline or hornblende, but, like the other accessory constituents, merits no special description. An andysis of tjie rock made Mr. M. F. Connor, B.Sc, gave the following results : — SiO, 39.74 TiO, .13 AI2O3 30.59 FeA .44 FeO 2.19 MnO .03 CaO 5.75 MgO .60 K2O 3.8S NaoO 13.25 CO, 2.17 SO3 trace CI 02 S 07 H2O 1.00 99.86 Tf following the methods of the Quantitative Classification, the norm of the rock be calcidatt>d, that is to say the proportion of standard minerals which would give a magma of this composition, or in the form of which the rock under other conditions of cooling might have solidified, this is found to be as follows: — :t ■*-..■■•% m *%^:i ^M- \<* ■?. :,:& ^^ WM^- ^vr ;^ > ^ o C nJ S .-2 o < Q. QJ O o ■" x: [ADAMSABARLowj ALKALI SYENITES OF EASTERN ONTARIO 43 Anorthite 13.51 Xepheline 67.72 Leucite 8,28 Olivine 3. 70 Akermanite .40 Magnetite .70 * Ilmenite .30 Pyrite .14 Calcite 4.93 98.67 Water 1.00 99^7 This gives the rock the following position in the Quantitative Clas- wfieation : — Class I Persalane. Order 8 Ontarare. Rang 2 . (Domalkahc). Sub-rang 4 (Dosodic) . As this is the first Ontarare which has been described, the rangs and sub-rangs have received no names as yet. It is proposed, therefore, to call rang 2 Monmouthase, and sub-rang 4 Monmouthose, from the township of Monmouth in which this rock is found, while, as an ordinary designation, the name Monmouthite may be applied. The mode, or actual mineralogical composition of the rock, is quite different from the norm, as given above, no leucite, anorthite, olivine, or akermanite being actually present. The mode is abnormative to a strik- ing degree. The mode is as follows : — Albite 1.83 Nepheline 72.20 Sodalite .28 Cancrinite 5-14 Hornblende 15.09 Hematite .50 Calcite 3.12 Pyrite -14 98^0 Water .50 Excess of ALO, 1.30 100.00 ' See Quantitative Classification (loc. cit.), p. 150. 44 ROYAL SOCIETY OF CANADA In calculating this mode the nepheline is taken as consisting of Boda nepheline and kaliophyllite, in the proportions of 5 to 1, which is the composition of the nepheline of the nepheline syenite, occurring further to the west, in the area of the township of Dungannon.^ One- half of the water founj in the analysis is considered as being present in the cancriilite, the remainder being regarded as belonging in part to the hornblende and as existing in part as hygroscopic water. This gives cancrinite in about the proportion in which it seems to be present in the thin sections of the specimens analyzed. The various bases not required by the other minerals and remain- ing over to form the hornblende, are present in the proportions required to form syntagmatite, which are the proportions in which these bases are found in the Hastingsite of the Dungannon nepheline syenite. The horn- blende has accordingly been calculated as syntagmatite, using the theore- tical values given by Zirkel.- This accounts for the existing percentages of all the constituents of the rock, with the exception of an excess of 1.20 per cent of alumina. Of the rocks hitherto described, those which bear the closest re- semblance to Momnouthite are the urtites of the Peninsula of Kola.' These, however, belong to the class of the dosalanes. Another variety of the rock from lot 11, con. Vllf, when examined vmder the microscope, was found to contain scapolite in addition to al- bite and nepheline, together Mdth a brown hornblende, instead of hast- ingsite, and a little biotite. The scapolite, which occurs in large amount, shows good prismatic cleavages and is usually quite fresh. ,It has a specific gravity of 2.711, showing that it is near the meionite end of the scapolite series and is accordingly rich in lime. III. Nepheline and Alkali Syenites of the Township of Glamorgan. The township of Glamorgan lies immediately to the west of IVIon- mouth, and the nepheline and alkali syenites which occur in it have a very marked resemblance to those of the township of Monmouth just described. Tliey all lie in the south-eastern corner of the township, and as in ^lonmouth, they occur intimately associated with limestones. There is, however, one feature presented by the Glamorgan occurrences which is of special interest, namely, the frequent occurrence in them of enormously coarse grained developments of the rock in the form of nepheline syenite pegmatites. The occurrences which protrude through the drift in the middle of lot 32, con. Ill, and also further soutli, on the north end of lot 32, * B. J- Harrington : loc. cit. ' Lehrbuch der Petrographie, vol. 1, p. 303. 8W. Ramsay: Das Nephelinsyenltgebiet auf der Halbinsel Kola, Fennia, 15, No. 2, p. 22. m Eh < m£o [ADAMS A barlow] ALKALI SYENITES OF EASTERN ONTARIO 4S con. 11, have this coarse pegmatitic development and consist of albite, nepheline and black mica. Their exact mode of occurrence cannot in all cases be seen on account of the drift which surrounds them, but on the north half of lot 32, con. III, this same development -of the rock is seen cutting the limestone in the form of great dykes; while on lot 32, con. II, it is seen in dykes of the same character, penetrating the gabbro and cutting abruptly across the course of its foliation. These dykes on lot 32, con. Ill, hold included masses of limestone, very coarse in grain, crystals of zircon, dark reddish brown in colour, over an inch in dia- meter and each consisting of a double tetragonal pyramid, were also found in these dykes, as well as crystals of apatite. The dykes on lot 32, con. II, in some cases become extremely coarse in gi-ain. A specimen obtained from one of them consisted of a pyra- midal mass of nearly pure nepheline, which measured 14 inches on the side and was composed of individuals of this mineral from three to five inches in diameter. The nepheline is in places slightly streaked with sodalite, and on the weathered surface shows in places irregular-shaped cavities which represent spaces from which masses of calcify have been dissolved. An important area of nepheline syenite is that which runs across con IV, from lot 27 to lot 32. It is very well exposed on lot 30, con. IV, on the property of Mr. Archibald McColl. The greater part of this mass consists of a light grey, well foliated nepheline syenite, containing a hornblende resembling hastingsite. A specimen of this rock, which was examined microscopically, was found to be composed of microcline, albite, nepheline and hastingsite, with a little microperthite. Both microcline and albite are present in large amount. Inclusions of the former were observed in the nepheline. The rock is quite fresh and has the almost allotriomorphic structure usually seen in these foliated nepheline syenites. In addition to this, which may be called the normal development of the rock, there are on the same lot other varieties. One of these is a very coarse pegmatitic phase of the rock like that forming dykes on lot 32, con. II, but even coarser in grain. One exposure of this is seen not far from Mr. SIcColl's house and has been opened up by blasting. Here the rock consists essentially of nepheline and albite, with occasional individuals or small masses of coarsely crystalline cal- cite. The iron-magnesia constituents are present in very small amount, and are over large surfaces entirely absent. They are represented chiefly by a black mica. A black hornblende, probably hastingsite, as well as a white mica and a little pyrrhotite were also observed. The rock con- tains masses of pure nepheline as much as a yard in diameter. 46 ROYAL SOCIETY OF CANADA In fact, so far as can be ascertained no nepheline rock so coarse in grain has hitherto been discovered anywhere. Sodalite is also present in the rock in places, occurring in irregular shaped masses sometimes as much as two inches in diameter, included in the large masses of nepheline and having apparently been derived from them by some pro- cess of alteration. The relation of this pegraatitic development to the normal variety of the rock cannot be ascertained with certainty, as the contact is covered by drift. A true quartz orthoclase pegmatite, how- ever, occurs protruding through the drift in the immediate vicinity of the occurrence just described and in such a position as to suggest that it is a differentiation product of the same magma. A reddish syenite containing some biotite, and similar to that found in so many parts of the area in association with the nepheline syenites is also exposed in the immediate vicinity. Another important and interesting occurrence is that which in the form of a comparatively narrow band is exposed at intervals along the Monck road to the east of the village of Gooderham on cons. V. and VI from lot 29 to lot 35, and then curving north with the strike of the couatry rock extends to the front of con. VIII. Just to the north of the road, on lot 29, con. V, the rock is seen as a pale gray granular syen- ite containing in places a little nepheline and also holding a small amount of black mica. So closely does it resemble the crystalline limestone through which it cuts and to whose strike it conforms, that the two rocks are with difficulty distinguished from one another by their ap- pearance. On lot 31, con. VI, it is seen intimately associated with, and occurring as schlieren in, the great quartz pegmatite masses which here border and probably cut the granite gneiss. In places on this lot, it holds nepheline, although never in large amount. IV. The Nepheline and Alkali Syenites of the Townships of Harcourt, Cardiff and WoUaston. The occurrences in these townships are of comparatively small ex- tent. In the township of Harcouri, on lot 15, of concession I, there is a fine exposure of the nepheline rock in a cutting on the Irondale, Ban- croft and Ottawa railway. It is bounded on the north by the heavy band of crystalline limestone which sweeps around the northern end of the Cardiff bathylith, the limestone being seen just north of the railway track in large exposures consisting of nearly horizontal beds. The lime- stone here is nearly pure and free from admixture of silicates, but in some bands is dolomitic. The nepheline rock appears to form a narrow ADAMS 4 barlow] ALKALI SYENITES OF EASTERN ONTARIO 47 selvage along the southern side of the limestone and can be traced to the west across the neighbouring lots. To the south the relations of the syenite to tlie granite of the bathyliths are obscured by drift. The nepheline syenite has a banded structure, some bands consisting of al- most pure nepheline, while in others the iron-magnesia constituents preponderate; there is also in many cases a variation m size of grain in different bands. Masses of coarsely crystalline calcite, evidently frag- ments from the adjacent limestones, are occasionally found as in- clusions in the nepheline syenite, the nepheline and other constituent minerals of the syenite growing into these inclusions, as if the lime- stone was being replaced by them. Under the microscope the rock is seen to be composed essentially of nepheline and a deep green hornblende allied to hastingsite. The relative proportions of these two minerals vary in different slides. A considerable amount of calcite is present in large individuals with irregular and usually curved outlines, which lie between the other constituents of the rock. A plagioclase feldspar and microperthite are present in very subordinate amount, together with a few rounded grains of spliene. The structure of the rock is allotrimor- phic. None of the constituents possess any approach to good crystalline form, but come together along curved or straight lines and are quite irregular in shape. About four miles to tlie east of this occurrence and associated with the same band of limestone, Pr. Miller (^) has observed a mass of white syenite carrying brown corundum. The rock is stated to form a hill about half a mile east of Lea field Post Office in the north-east comer of thei township of Cardiff, and was also found at the roadside about half a mile south-east of the same point. Some of the syenite in the hill has a quite strongly marked porphyritic structure. No description of this rock is given, but it is apparently free from nepheline and allied to the alkali syenites associated with the nepheline syenites in the township of Methuen and elsewhere in the area. This occurrence was not visited, but its position, as indicated by Dr. Miller, has been shown on the Ban- croft sheet. In the township of Wollaston, only a single occurrence of nepheMne syenite is known, and this is a small one. It is foxmd on the road which runs on the line between the townships of Wollaston and Faraday, on lot 9. On account of the fact that the country here is rough, the road does not follow the exact line on which it is supposed to bo laid out. but winds to and fro across the boundary. On lot 9, at the point where the nepheline syenite occurs, it bends to the south and is almost exactly on ^ Report of the Ontario Bureau of Mines, Vol. VIII, page 216. 48 ROYAL SOCIETY OF CANADA the boundary. The occurrence, therefore, probably lies partly in Fara- day and partly in Wollaston. Its position, however, is here taken as lot 9 of con. XVI of Wollaston. . The mass is peculiarly situated, form- ing as it does a solitary exposure only twenty feet across, surrounded by gabbro diorite. (') The nepheline syenite has a more or less well marked banded character and is usually coarse in grain. The relative abundance of the constituents varies more or less in different parts of the mass. Under the microscope the rock is seen to consist essentially of nephe- line, plagioclase and biotite, while microcline, calcite, magnetite, pyrite, apatite and zircon (?) occur as accessory constituents. The biotite usually occurs in rather large irregular-shaped individuals which are strongly pleochroic in colours, ranging from a pale yellow to a very deep brown, basal sections being nearly black. It is sometimes found ad- joining or partially surrounded by magnetite or chlorite, this latter mineral clearly showing its derivation from the biotite. The plates of biotit*? are frequently twisted. The prevailing feldspar is an albite, which, with the nepheline, in some places makes up the entire rock. As a rule it is fresh, occurring as large individuals and smaller grains, often showing fine polysynthetic twinning, the lamellae being distinctly bent in some cases and the mineral often showing strain shadows. Microcline is present in small amount and microperthite intergrowths are common. The nepheline forms large irregular individuals, frequently cracked and very turbid, this turbidity being due to incipient decomposition. In- clusions of small rounded grains of plagioclase and untwinned feldspar. as well as of calcite and biotite, are frequently found in the nepheline. Oalcite is always present and is often abundant, occurring in large in- dividuals. The shape of the grains indicates that it is derived from limestone inclusions. The twinning lines of the calcite are often curved in a striking manner. Both magnetite and pyrite occur in small amounts, the former being much more abundant. The pyrite in one or two cases is found partially altered to hematite, while magnetite forms a border around it. Little zircons < ?) and a few grains of apatite pos- sessing good crystallographic outlines are present in the sections. The curved individuals of biotite, plagioclase and calcite, and strain shadows, suggest that the rock has been subjected to great pressure. A separation of the constituents of the rock was made by means of Thoulet's solution, which showed that the feldspar present was almost exclusively al])ite, the potash feldspar present being quite subordinate in amount but white in colour like the albite, and thus not to * A somewhat similar occurrence has been described by Ransome in the case of a nepheline syenite at Broclcville, N.J., Am. Jour, of Sci., 1899, p. 426. ADAMS A BARLOW] ALKALI SYENITES OF EASTERN ONTARIO 49 be distinguished from it in hand specimens of the rock. One curious fact in connection with this rock is that, while the nepheline syenite con- tains numerous large grains of calcite, which from analogy with other occurrences would naturally be regarded as derived from the disintegra- tion of included masses of limestone, no limestone was found within a mile of the exposure. So that, while there may be inclusions of lime- stone hidden by the forest which mantles much of the surrounding dis- tnct, the small body of nepheline syenite seems to occur as an isolated mass within the great body of diorite which underlies the north-eastern comer of Wollaston. V. The Nepheline and Alkali Syenites of the Township of Methuen. These rocks in Methuen are confined to a single occurrence which however, is large, and forms the most striking topographical feature in the township. This is what is known as the Blue Mountain, a ridge which, rising abruptly from the level country about the middle of the township, stretches away to the south-west nearly to the Burleigh line, where it gradually sinks again to the level of the plain. It has an average height of somewhat over 300 feet above the waters of the Kaslia- bog Lake which lies immediately to the south of it, but at its northern end becomes considerably bolder, reaching a height of 300 feet above the waters of the lake. The ridge is formed of nepheline syenite associated with both the white and \he reddish varieties of alkali syenite, while the surrounding country, as shown in the accompanying map, is underlain by amphi- bolites containing thin interstratified bands of crystalline limestone, both of which are cut by the granite-gneiss of the Methuen batholitli. The intrusive mass of the Blue mountain thus possesses a slender pear-shaped outline, being eight miles long and one and a half wide at its widest part, near the north-east end, while the narrow south-western part of the mass, where it runs through the township of Burleigh, has a width of only about 200 yards. The Nepheline Syenite. — The normal nepheline syenite of this occurrence is best exposed on the north-east half of the Blue Mountain. It is light grey or white in colour and of medium grain, being characterized like all the syenites of this occurrence by a very low content of iron-magnesia constituents. In the central and highest portion of this north-eastern part, the rock is massive in character, but on either side the rock develops a more or less well marked foliation or parallelism of constituent minerals, which, how- Sec. IV., 1907. 4. BO ROYAL SOCIETY OF CANADA ever, is not very striking on account of the small proportion of iron- magnesia constituents which the rock contains. The foliated appearance is accompanied by a streaked or schlieren structure in the rock, which coincides with the strike of the foliation, that is with the direction of the longer axis of the ridge. The streaks consist of portions of the rock, which are coarser in grain than the normal rock or which contain some constituents more abundantly developed. Under the microscope the rock is seen to be very fresh and to con- sist of albite, microcline and nepheline, with which are associated in very subordinate amount magnetite, biotite, hornblende, or very rarely P3rroxene. In some cases, but not usually, these two latter minerals oc- cur together. Occasionally muscovite occurs associated with and par- tially replacing the biotite. As accessory constituents garnet, scapo- lite(?) and zircon (?) were observed in very small amounts and each in but a single specimen. The nepheline syenite in this township pre- sents a variety which is highly feldspathic and rather poor in nepheline. The feldspar is chiefly albite. This mineral is always well twinned according to the albite law, and occasionally this mode of twinning is combined with that according to the Carlsbad law, A series of measure- ments of the extinction of this feldspar in sections in the zone of the macropinacoid were made in slides of the rock from the highest point of the Blue mountain, and it was found that the maximum extinction on either side of the twinning line was 16°. A separation of the consti- tuents by Thoulet's solution showed the feldspar to have a specific gravity of very nearly 2.60. The feldspar is therefore albite. Similar separa- tions carried out on specimens collected on lot 18, con. VI and on specimens of the various varietal diiierentiation products of the rock to be mentioned below, show that the plagioclase present in the rock is al- ways albite and that no feldspar more basic than this specimen (that is, having a specific gravity greater than 2.60) occurs in the rock. The microcline is much less abundant than the albite, although it always occurs in considerable amount. There is, as a rule, from two to four times as much albite as microcline present. The nepheline is usually quite fresh, but occasionally shows traces of alteration. It oc- curs in large, irregular shaped grains. It is on the whole about equal to the microcline in amount, but locally becomes the preponderating constituent in the rock. The biotite is a very strongly pleochroic variety, a = dark greenish brown, nearly black. C = pale yellow. Ab- sorption a > c. The axial angle is very small. The hornblende is hastingsite. The small individuals possess a fairly good crystalline form, but the larger are irregular in shape, sometimes lying between the [ADAMS 4 BARLOW] ALKALI SYENITES OF EASTERN ONTARIO 31 feldspathic elements of the rock and sometimes enclosing them. It has an intense colour and a very strong pleochroism, as follows : — a = green with yellowish tinge, h = deep green with bluish tinge. C = deep green. The absorption is C ~ b > a. The dispersion is very strong and sections at right angles to the optic axes are nearly opaque. The extinction is high, probably about 30°. The magnetite occurs chiefly in large individuals scattered sparingly through the rock and usually possessing a rude crystalline form. The garnet, which was found in small amount in one specimen of the rock holding hornblende, is pale yellowish brown in colour and identical in all its characters with that occurring associated with the hastingsite in the Dungannon nephe- line syenite from which the latter mineral was originally described. (') As has been mentioned, the rock often possesses a streaked or schlieren structure. The more coarsely crystalline streaks are usually composed of albite and nepheline — individuals of the latter mineral seven inches in diameter having been observed in one case. Sodalite was observed in association with this coarsely crystalline nepheline in a few places. The rock has a granular texture uith which the faint gneissic and the schlieren structures are combined — blocks of the rock thus resembling a somewhat impure crystalline limestone or marble. Under the micros- cope the structure is seen to be essentially allotriomorphic. In one case a minutely miarolitic structure was observed. A fine development of the nepheline syenite is seen forming high white cliffs at the western end of Mountain Lake, on the north side of the lake, on lots 13 and 14, con. X of Methuen, The rock consists of about one-third nepheline and two-thirds feldspar and is almost free from iron-magnesia constituents. In a rather more micaceous specimen of the nepheline syenite from the Blue Mountain, a short distance further east, on lot 15, con. IX of Methuen, a small quantity of spinel in little rounded individuals was observed in the thin sections. The occurrence of this mineral is of in- terest in showing that the magma here contained a slight excess of alumina, which separated in combination with magnesia as spinel, while, as mentioned below, the much larger excess of alumina in other parts of the mass separates out as corundum. The White Alkali Syenite. — 'The nepheline syenite in places be- comes rather fine in grain and poorer in nepheline, passing into a white syenite. ^ Adams, F. D. and Harring^ton, B. J. — On a new alkali Hornblende and a titaniferous Andradite from the Nepheline Syenite of Dung-annon, Hastings County, Ontario. — Am. Jr. of Science, March, 1896. 62 ROYAL SOCIETY OF CANADA One of the best developments of tliis wliite syenite is to be found on the summit of the ridge of the Blue ^Mountain, about the middle of lots 13 and 14, con. X of Methuen, where it is seen in large exposures. Under the microscope it is seen to be composed chiefly of albite, with a considerable admixture of microcline and a very small amount of nephe- line. Muscovite and magnetite, both very subordinate in amount, are the only other constituents. Its structure and the character of its con- stituent minerals is identical with that of the nepheline syenite already described. A chemical analysis of a specimen of this rock which, however, still contains a considerable amount of accessory nepheline, by Professor Norton-Evans of McGill University, gave the following results: — SiO^ 59.68 TiOj none AI2O3 23.48 Fe^Og .59 FeO .37 MnO none CaO .26 MgO .21 K2O 4.68 Na20 9.52 P2O5 none CO2 .04 H,0 .66 99.49 The norm of the rock when calculated is found to be as follows Orthoclase 27.80 per cent. Albite 49.25 " Anorthite 1.25 " Nepheline 16.76 " Olivine .45 " Corundum 2.24 " Magnetite .93 " 98.68 Water .66 " 99.34 ADAMS A BARLOW] ALKALI SYENITES OF EASTERN ONTARIO 83 The rock thus has the following position in the Quantitative Clas- sification : — Class I Persalane. Order 6 Russare. Rang 1 Miaskase. Sub-rang 4 Miaskose. i The mode of the rock, that is to say, its actual quantitative mineralo- gical composition when calculated out is found to be as follows: — Orthoclase 16.12 percent. Albite 53.45 \ r.A jo Anorthite. .. 1.25/ Nepheline 18.18 Biotite 1.27 Muscovite 7.95 Magnetite .93 99.15 Water 28 99.43 The Reddish Alhdi Syenite. — The reddish syenite is typically developed about a quarter of a mile to the west of the locality from which the v/hite syenite, whose analysis has been given above, was obtained. The syenite is here traversed by the veins which are being worked for corundum. It is first seen to occur as streaks or sclilieren in the white syenite, and then on going west it replaces the latter. The syenite here has a pale reddish or pinkish colour and is rather fine and even in grain. The iron-magnesia con- stituents, which are very subordinate in amount, occur in the form of little elongated dashes, giving a species of foliation to the rock. It is chiefly confined to the sides of the Blue Mountain mass, although not continuously developed about it. Under the microscope the rock is seen to be composed essentially of albite and microcline. The twinning of the microcline is very narrow, and there is some untwinned feldspar which is apparently orthoclase. The only other minerals present are biotite, magnetite, pyrite, calcite and quartz. These occur intimately associated and form the little dark coloured dashes seen on the surface of fracture. They are all present in small amount, the magnetite often having a rude crystalline form. The calcite occurs in irregular-shaped individuals and is occasionally seen away from the dashes, lying between the feldspar grains. The quartz, like the calcite, does not occur in all sections, and when present, is found with the calcite in the form of rather large irregular-shaped grains. These two constituents may be secondary, although not ordinary decomposition products, for the rock is very fresh. 64 ROYAL SOCIETY OF CANADA The rock has an allotriomorphic structure, approaching nearly in character to the " mosaic " or " pavement " structure seen in meta- morpliic rocks. The reddish colour is apparently due to very minute reddish in- clusions which occur in both feldspars indiscriminately, and whose pre- sence in the 'other occurrences of the rock seems to be accompanied by the alteration of any nepheline which may be present to a peculiar gie- seckite-like aggregate. The reddish colour, in fact, seems to be due to an incipient alteration of the rock, which is chiefly seen about the sides of the mass. A chemical analysis of the rock by Professor Norton-Evans gave the following results: — SiOa 65.89 TiOa none AI2O3 19.73 Fe.Og 2.03 FeO .75 MnO trace. CaO .46 MgO .27 K,0 3.95 Na20 6.59 PgOr, none S undet. CO2 44 CO3 .44 H,0 34 100.45 The norm of the rock i;^ as follows : — Orthoclase 23.35 per cent. Albite 55.54 " Anorthite 2.22 " Quartz 11.22 Corundum 3.77 " Hyperstheno .70 " Magnetite 2.32 " Pyrite .48 '' 99.60 Carbonic acid and water .78 100.38 [ADAMS 4 barlow] ALKALI SYENITES OF EASTERN ONTARIO 35 The amount of pyrite is calculated by assuming that the excess of ferric iron over the amount required to form magnetite Avith the fer- rous oxide, is united with sulphur. The position of this rock in the Quantitative Classification is as follows : — Class I Persalane. Order 4 Britannare. Sub-rang 4 Kallenidose. Sub-rang 4 Kallerudose. (near Nordmarkase). If, however, the calcite be regarded as secondary and its lime be calculated as anorthite, on the supposition that it was really present in the original magma while the carbonate acid was not, this increase of salic lime will be just sufficient to carry the rock over into Order 5, and thus make it a Canadare with the sub-rang ISTordmarkose. Mineralo- gically it differs from the white syenite just described in containing no nepheline or muscovite, but in holding a little quartz. The mode of this rock is nearly normative — that is, the actual mineral composition is nearly that set forth in the norm. The hypersthene of the norm belongs to the biotite of the rock, the former mineral not being actually present. The calculation shows that there is really relatively more al- bite present in proportion to the orthoclase than would be supposed from a study of the thin sections. It also shows that there is rather more quartz present than would be expected from an examination of the hand specimens or the slides, and also that the rock must contain some free alumina in the form of corundum, although this mineral does not hap- pen to occur in any of the thin sections of the rock from this particular locality, which have been prepared. As has been mentioned, however, corundum is found abundantly in the veins or dykes of syenite peg- matite which cut the rock at this locality. The occurrence of free quartz and corundum in the same igneous rock appears to be an anomaly. If, however, the quartz be secondary, the anomaly disappears. Where this reddish syenite, a mile and a quarter to the south-west of the locality just described, crosses the road running from liake Kasha- bog to Jack's Lake, on lot 6, con. XII of the township of Burleigh, it in places holds corundum in large amount. Under the microscope the rock' is seen to consist of albite, microcline, orthoclase, biotite, mus- covite and corundum. The albite preponderates largely in amount over the potash feldspars. Biotite is present only in very small amount, but there is a considerable percentage of muscovite in irregular-shaped in- dividuals which have a tendency to a lath-shaped development and which, if they occur in groups, frequently penetrate one another and also pene- S6 ROYAL tiOCIETY OF CANADA trate the feldspars. The corundum occurs as individuals about half an inch long which are especially abundant in streaks following the strike of the rock. In the thin sections it is invariably seen to lie embedded in the muscovite, in the form of very irregular-shaped grains, rounded or corroded in appearance. Each corundum grain has a single large in- dividual or muscovite enclosing it, or occasionally there are two or more smaller grains of corundum within the single muscovite individual which look as if they had originally fonned part of a larger indi\idual. The muscovite outline often in a general way conforms to that of the corun- dum core which it contains, as shown in figure. The corundum has the usual high index of refraction and a double refraction, which usually gives yellows and reds of the first order, but in Bome cases, even in good sections, gives a blue of the second order. As has been mentioned elsewhere, the colours which the mineral gives in thin sections are usually higher than would be expected, on account of the fact that, owing to its hardness, it always remains thicker in the finished section, than the minerals with which it is associated and can be seen distinctly standing up from the surface, if the slide is examined before the cover glass is placed upon it. It often contains minute opaque black inclusions, which, in the basal sections, appear as irregularly round- ed plates, but in sections parallel to the vertical axis of the crystal as rods. In the last mentioned sections the extinction of the corundum is parallel to) the direction of the rods, so that the latter are inlaid parallel to the base. It is impossible to determine from the thin sections whether there is a constant orientation in the case of the corundum and mus- covite. In one case, however, the basal plane of the corundum, marked by the inclusions, lay in the direction of the vertical axis of the enclos- ing muscovite individual. In addition to the inclusions just mentioned, the corundum occasionally encloses minute grains of a deep green iso- tropic mineral which have the characters of spinel. And in one or two cases, larger grains of this mineral are seen associated with the corundum. Along the south-eastern side of the Blue Mountain, the reddish syenite crosses an arm of Kashal)og Lake, and in most places holds a small amount of a mineral which is now completely changed to a gieseckite-like alteration product. This is yellow on the weathered surface, but in fresh surfaces of the rock it has a pale green or a pink colour. It has a hardness of four and is quite dull and lustreless. A rough quantita- tive analysis of a specimen by. Prof. 0. E. Leroy, M.Sc, showed it to pos- sess the following chemical composition: — SiOa, 45 p.c; AI2O3 (with a little Fe.O,), 38 p.c. ; MgO, 3.6 p.c. ; CaO, 2.8 p.c; HoO, 7.8 p.c; KjO, not determined. [ADAMS & BARLOW] ALKALI SYENITES OF EASTERN ONTARIO PLATE XL CORUNDUM IN MUSCOVITE (blue mountain, methuen township, Ontario) Corundum IS Often Surrounded by a "Corona' OR Mantle of Muscovite. 0. E. PRUDHOMME, Del [ADAMS 4 BARLOW] ALKALI SYENITES OF EASTERN ONTARIO B7 This represents the chemical composition of the aggregate known as gieseckite, which is an alteration product of nepheline commonly found in other parts of the world. Here also it evidently represents altered nepheline, for although in the pink syenite the change is always com- plete, no unaltered nepheline remaining in the rock, in the white variety of the syenite in a few places the nepheline can be seen in pro- cess of alteration into such an aggregate. A similar material is also produced by the alteration of the nepheline in a nepheline syenite in the township of Monmouth (see page 36). As has been mentioned, both the nepheline syenite and the reddish alkali syenite frequently contain coarser-grained streaks or schlieren. In this respect they resemble many of the granites of other parts of this area. These coarser streaks usually coincide in direction with the foliation of the rock, but in some cases they are seen to cross the folia- tion of the syenite and even to penetrate the rock of the surround- ing country. They are, in fact, the pegmatite phases of this nepheline syenite magma. These pegmatites are composed of the same constituents as the normal rock, and in several places on and about the Blue Mountain they have been opened up by mining operations, in order to obtain the mus- covite or corundum which they contain. The muscovite, which is a com- mon constituent of the syenite, in some of these pegmatite dykes occurs in plates several inches in diameter; while the corundum which is often as has been mentioned, an accessory constituent in the syenite, in several of these dykes occurs in considerable amount. In these cases there must have been a concentration of alumina in the residual magma represented by the pegmatites in question. Those pegmatites, which are worked for muscovite and corundum, however, do not as a general rule here contain nepheline, or if this mineral be present, it is only a fmall amount and is often represented by gieseckite, and they are thus for the most part the pegmatitic developments of the alkali syenite, and usually have syenite for the wall rock. The coarse corundum-bearing pegmatitic segregations worked for this mineral on the Blue Mountain vary in width from one to four or more feet. A striking feature presented by them is the form in which the corundum occurs, being usually found in rounded indivi(hials, each having an irregular, though smooth, surface resembling that which might have been produced by solution. Each of these rounded indivi- duals is found in the middle of a large individual of muscovite, both minerals being perfectly fresh and unaltered. Eeference has already been made to this mode of occurrence on page 32. S8 ROYAL SOCIETY OF CANADA The corundum is of a greenish-grey colour, often changing to blue in the centre of the crystal. The colour suggests sapphire, but the mineral is opaque or at best only translucent. \1. The Nepheline and associated Alkali Syenites of the townships of Faraday, Dungannon, Carlow and Monteagle. It is unnecessary to describe in detail the numerous and often more or less isolated occurrences of the nepheline and alkali syenites in this portion of the belt. They, however, present one point of especial in- terest, namely, the presence in them in many places and often in large amount of the mineral corundujn. This mineral, while known to occur in considerable quantity in several localities, has been actually worked in two places only, of which the more important is Craigmont. This occurrence, therefore, merits a special reference. Craigmont (formerly Eobillard Mountain) is a well marked topo- graphical feature rising abruptly from Campbell's marsh (an expansion of the York river) and extending as far west as the post road between Combermere and Fort Stewart. It covers most of the first four lots in the eighteenth and nineteenth concessions of the township of Eaglan in the county of Renfrew, the line between these two concessions running along the southern slope of the mountain. According to the mean of eeveral observations with two aneroid barometers, the " mountain " rises to a height of 500 feet above the dam at the old mill on the creek, which latter is ninety-five feet above Campbell's Marsh. Tliis, added to 931 feet, the height given by White^ for the junction of the Yoik and Madawaska rivers, gives 1426 feet as the height of the top of Craig- mont above mean tide-level. The rock composing the mass of the mountain is a rather dark coloured homblende-granitite-gnciss, evidently representative of the gneisses of the great Laurentian bathylith. The corundum-bearing rocks form a layer or mass of comparatively small thickness which occupies the whole face of the hill lying on the barren gneiss of the Laurentian and coinciding in strike and dip with the direction of the hilFs face. This strike is N75°E with a southerly dip at an angle of 10° to 12°. The main body of the hill behind this layer is therefore 'Altitudes In Canada, 1901, p. 199. [ADAMS A barlow] ALKALI SYENITES OF EASTERN ONTARIO 39 the ordinary fundamental gneiss presenting the usual characters. This layer of corundum-bearing rock consists of : — (1) Xepheline syenite, in places passing into an almost pure nephe- line rock ; (2) White or grey alkali syenite; (3) Fine grained pinkish alkali syenite like that found in the township of Mjethuen and elsewhere, frequently having a streaked character. These three rocks often occur interbanded with one another and fre- quently pass into one another. In some places the red syenite can be seen to cut across the nepheline syenite. All these rocks locally hold corundum in abundance. In some places bands of a dark micaceous rock conforming to the dip and strike are seen associated with the syenite; these, however, in certain occur- rences can be distinctly seen to consist of altered basic dykes. It is also to be noted that the sloping face of the corundum-bearing rock dips to the south beneath the sandy plain at its foot, through which runs a branch of the York river. Along this stream and elsewhere lime- stone is exposed at several places, showing that in all probability these corundum-bearing rocks here as elsewhere lie at the contact of the in- trusive bathyliths of gneiss with the limestones of t]ie Grenville series. The corundum workings at Craigmont take the form of five cuts or trenches running up the face of the hill in parallel lines. The mill in which the corundum is concentrated from these syenites was producing 305 tons of corundum per month in the summer of 1906. Nephelme Syenite. Typical specimens of two extreme phases of the nepheline syenite from this locality were selected for analysis, one of these being very rich in nepheline and the other being rich in plagioclase and contain- ing proportionately less nepheline. Both varieties contain corundum in well defined crystals, often having a barrel shape, the long axes of which lie at right angles to the foliation of the nepheline syenite. Corundum-'b earing nepheline syenite {rich in nepheline). — When examined in thin sections this rock is seen to be composed of nepheline, oligoclase, muscovite, biotite, calcite, magnetite and corundum. Some of the nepheline is comparatively fresh, but most of it has undergone more or less alteration, the resultant products consisting of a brilliantly polarizing aggregate of minute scales of muscovite, developed along cer- tain irregular lines and cracks. The plagioclase is likewise somewhat eo ROYAL SOCIETY OF CANADA turbid from incipient alteration. Only occasional very small scales of biotite were noticed and still more rarely small grains of magnetite. The corundum in the thin sections consists of irregular shaped ap- parently corroded individuals embedded in plates and scales of muscovite. An analysis of the nepheline rich variety by Mr. M. F. Connor, B.Sc, of the Geological Survey, shows it to have the following com- position : — SiOj 48.38 TiO, trace ALOg 30.54 FcoOa 0.40 FeO O.OG MnO trace CuO trace CaO 1.87 MgO 0.19 K,0 3.70 Na,0 13.94 PoOg trace CO, 0.62 H,0 0.50 100.20 If the norm of this rock be calculated, it will be found to lie as follows : — Orthoclase 21.68 Albite 10.48 Anorthite 5.56 Nepheline 57.94 Corundum 1.63 Calcite ].42 Hematite 40 Fosterite 35 99.46 Water 50 99.96 ADAMS dk barlow] alkali syenites OF EASTERN ONTARIO 61 This gives the rock the following position in the quantitative classi- fication : — Class I Persalane. Order VII Tasmanare (near Ontarare). Rang I Laugenase. Sub-rang II Craigmontose. It is a new type for which we propose the name Craigmontose (Craigmontite). The mode or actual mineralogical composition of the rock is somewhat different from the norm as given above. It is as follows : — Nepheline 63.18 , Oligoclase. . . . : 29.66 Muscovite 4.39 Calcite 1.42 Corundum .50 Biotite .50 JIagnetite .10 99.75 Corundum-bearing nephelinc syenite {poor in nepheline). — An analysis of the second phase of the nepheline syenite, namely that rich in plagiociase and corundum, but containmg less nepheline than that just described, was also made by Mr. M. F. Connor, B.Sc, and was found to have the following composition: — Corundum (determined separately) . . 4.45 SiOo •• 55.45 Tio'2 0.30 AlA 21.65 FeA 0.81 FeO 0.49 MnO 0.01 CaO 3.65 MgO 0.13 K,0 1-62 Na,0 9.31 p 0.01 CO. 0.88 H,6 1-64 100.40 62 ROYAL SOCIETY OF CANADA If the norm of this rock be calculated it will he as follows Orthoclase 9.45 Albite 56.59 Anorthite 12.51 Nepheline 11.93 Corundum 4.45 Calcite 1.98 Magnetite .70 Ilmenite .61 Hematite .30 Fosterite .31 98.73 Water 1.64 100.37 This gives the rock the following position in the quantitative clas- sification : — Class I Persalane. Order VI Russare (near Tasraanare). Rang II Viezzenase. Sub-rang V Raglanose. This is a new type for which we propose the name Raglanose (Raglanite), The mode or actual mineralogical composition of this rock, is some- what different from the norm — the difference being represented chiefly in the grouping of the feldspar molecules and in the modal presence of micas. The rock is actually composed of oligoclase, nepheline, corundum (4.45 per cent), with small amounts of muscovite, biotite, calcite, mag- netite and apatite. White Alkali Syenite. This syenite consists essentially of plagioclase and passes on one hand into the nepheline syenite of the ordinary type, and on the other hand into the reddish variety of alkali syenite. It may therefore be re- garded as a rock of intermediate type marking a transition between the two, although rather more closely related to the former. The con- stituient minerals in cluiracler are identical with those present in the nepheline syenite. Sodalite and cancrinite are absent. The plagio- clase present, varies somewhat in character in different occurrences al- [ADAMS A BARLOW] ALKALI SYENITES OF EASTERN ONTARIO 63 bite, oligoclase and andesine having been found. As in the case of the nepheline syenite, separate occurrences of the rock seem to be charac- terized by the presence of one variety of plagioclase to the almost com- plete exclusion of another. Plagioclase often makes up from 75 to 95 per cent of the whole rock, the other constituents being biotite, muscovite, calcite, magnetite, and occasionally corundum, scapolite and nepheline. Some extreme phases of this rock are made up almost entirely of plagio- clase with little or no ferromagnesian minerals. When such rocks con- tain an excess of alumina which has crystallized out as corundum, they are very closely related to, if not identical with, the rock pulmasite de- scribed by Lawson.' The specimen selected for examination as typical of this variety of rock was obtained, not from Craigmont, but from a large exposure of the rock on lot 12, con. XV of the township of Dungannon. It is worked for corundum at this locality, although some varieties of the corundum " ore " are richer in corundum. The rock is well foliated. The corundum is by no means uniformly disti'ibuted through this rock, and large portions are completely barren of this mineral, while cer- tain rather ill-defined areas on the other hand contain a very high per- centage. In outcrops exposed to the weather the corundum is very con- spicuous, weathering out with pronounced relief from the surrounding matrix. It occurs for the most part in small imperfect crystals and grains, although occasional, characteristic barrel-shaped hexagonal crys- tals are several inches in length. In freshly broken rock the corundum is scarcely noticeable, unless it assumes the prevailing and characteristic bluish colour. Many of the individuals have exceedingly rough and jagged outlines due no doubt to the removal of much of the associated micaceous material. Some of the individuals show rather perfect crys- tallographic development, but, for the most part, the mineral occurs in imperfect crystals or irregular grains. Much of the corundum shows the peculiar parting planes or pseudo-cleavage, especially those parallel to the faces of the rhombohedron and the base, both of which are per- fectly developed. The colour is not uniformly distributed, but indefinite patches of white, blue and brown are often noticed. Most of the mineral has quite a distinct and often pronounced sapphire blue colour. Oc- casional fragments show a comparatively deep brownish colour arrangerl in parallel bands with well defined straight lines as boundaries. These brownish streaks alternate with others, which are nearly, if not 'quite colourless under the microscope. Some of the individuals have little • Bull. Geol. Dept. of the University of California, Vol. Ill, No. 8, pp. 219-229. 64 ROYAL SOCIETY OF CANADA or none of the rauscovite " corona ' surrounding them, while others, manifestly imperfect and much corroded, have quite a wide mantle of this so-called alteration product surrounding them. Under the micros- cope the thin sections show the rock to be made up largely of plagioclase. The extinction angles are those characteristic of andesine. This optical determination is subsequently confirmed by its separation with the heavy solution, and c-hemical analysis of the material thus obtained. Corundum is quite plentiful in the thin sections examined. Scapolite is also present usually in comparatively small amount, the larger individuals occupying the interspaces between the feldspars, with little to suggest its derivation from them. Some smaller grains enclosed in the feldspar may be secondary. The mineral shows the characteristic cleavages with parallel extinction and strong double refrac- tion. Biotite is present in occasional small individuals, showing very marked pleochroism from yellowish to very dark greenish brown and very pronounced absorption. Muscovite occurs both intergrown with the biotite and as zones or mantles of variable width surrounding most of the corundum individuals. It is regarded as a primary constituent formed as aready explained at a time immediately preceding the com- plete solidification of the magma. Occasional grains and imperfect crys- tals! of magnetite and a still smaller amount of calcite complete the list of minerals noticed in the thin sections. An analysis of this rock from this locality was made by Prof. "Norton-Evans, with the following results (under I) : — II. SiO^. Al,03 FeO. CaO. MgO. K2O. Na^O CO,.. H,6. 49.56 58.32 33.70 23.80 .93 1.09 1.42 1.67 5.89 6.67 .97 1.14 1.33 1.44 4.95 5.83 .17 .84 99.66 Deducting the excess of alumina present as corundum, which was determined by trial, neglecting the loss on ignition (HoO) and deduct- ing the amount of lime (CaO) necessary to form the calcite with the [ADAMS & barlow] ALKALI SYENITES OF EASTERN ONTARIO 65 CO2 in the rock, the results given under II are obtained. This is the composition of the residual or alumina saturated magma. Morozewicz^ has shown by direct experiment that in supersaturated alumino-silicate magmas, whose general composition is EO, m AI2O3, n SiOa (where R = K2, Nag or Ca, and n ^ 2), the whole of the excess of alumina separates out — (1) as corundum, if no considerable amount of MgO or FeO is present; and if n is less than 6. (2) as sillimanite and corundum; if n is greater than 6. (3) when the magma is rich in magnesia, as spinel or spinel and corundum; if n is less than 6. (4) as cordierite, or cordierite with one or more of the other minerals, if n is greater than 6. The absence of corundum in the nepheline syenites of India is explained by Holland as due to the fact that these rocks, as shown by analysis, contain too much MgO and FeO ; and he refers to the abundance of iron magnesia minerals in the nepheline syenite and the scarcity of such minerals in the corundum syenite as amply accounting for the abuudanc.e of free alumina in the latter and its absence in the former. A similar low content of iron and magnesia is noticeable in the Canadian corundum syenites, and, together with the high percentage of alumina in the magma, probably explains the development of corundum in them. The ratio of the molecular values of (CaO, K^O, !N"a20) : ALO., : Si02 in the rock at present under consideration are as follows : — .228 .233 .972 1 : 1 : .42 The ratio of K^O : Xa20=1.6 and that of alumina to the bases is a little in excess of 1 :1. As a magma for the solution of alumina and its complete separation as corundum on crystallization, it is therefore in per- fect agreement with ]\Iorozewicz's law. Of the alkalis, soda largely pre- dominates, this lending the necessary assistance in the solution of the alumina. Tliere is an excess of ferrous iron and magnesia, above what has been thought permissible (0.05 per cent) by Morozewicz's law, but these amounts have been necessary to assist in the formation of the comparatively small quantities of, magnetite and biotite present in the rock. It is therefore evident that Morozewicz's law, as remarked by Holland,^ does not represent the whole truth, for it might be expected, with this excess of ferrous iron and magnesia, that spinel would be ^Tscher. Mitt. Band XVIII (1898)— pp. 1-90 and 105-240. 'Mem. Geol. Surv. Ind. Vol. XXX, part 3. (1901) p. 208. Sfc. IV.. 1908. 5. 66 ROYAL SOCIETY OF CANADA formed in addition to the corundum. This mineral was, however, not seen in the tliin sections, nor was it found in any of the outcrops where this rock specimen was collected. The norm of the rock is as follows : — Quartz 1.26 Orthoclase 7.23 Albite 41.93 Anorthite 29.19 Corundum 13.46 Hypcrsthene 4.12 Magnetite 1.39 Calcite .37 98.94 Water .84 99.78 In calculating this norm from the chemical analysis, there was a« shown an excess of 1.26 per cent of silica above that required and whicli appears in the norm as quartz. By direct evperiment it was subse- quently shown that most, if not all, of this silica was derived from the agate mortar and pestle which was used in grinding the sample. There is no free silica or quartz shown in the thin sections, nor was any of this mineral found in the separation of the rock by means of the heavy solu- tion. The mode or actual mineralogical composition cannot be calculated with certainty on account of the presence of the two micas and the Bcapolite, the latter having about the same formula as the feldspar. The corundum, magnetite and calcite are normative, i.e., they are present essentially in the percentages given in the norm. From an inspection of the slides the following would seem to be a very close approximation to the mineralogical composition of the rock: — Andesine (near z\.b,An,) 72.00 Nepheline 3 . 00 Scapolite 2.00 Corundum (by trial) 13.24 Biotite 5.00 Muscovite 3 . 00 Magnetite 1.39 Calcite .37 100.00 05 [ADAMS A BARLOW] ALKALI SYENITES OF EASTERN ONTARIO 67 Owing to the large percentage of corundum present, the rock is a very peculiar and unusual one, and represents a new sub-class, order, rang and sub-rang in the Quantitative Classification. We accordingly propose the following names for the new order and rang, and the name Dungannonite for the rock itself : Class I Persalane Sub-class II (Section I) Dosalone Order 5 Indare Eang 3 Dungannonase Sub-rang 4 Dungannonose An analysis of the andesine occurring in the rock was made by Mr. M. F. Connor, B.Sc. This is given under I. The material for the analysis was obtained by separating the feldspar with Thoulet's solution. It was somewhat impure, owing mainly to the admixture of a small amount of biotite. This accounts for the iron, potash and magnesia found in the analysis. Neglecting these, the composition corresponds rather closely to that of an andesine with the formula AbgAug. The •specific gravity of a feldspar with this formula should be 2.68, while that of the andesine separated from the rock was 2.668. For purposes of comparison the theoretical composition of andesine cor- responding with the generally accepted formula for plagioclase with the ratio of the soda to the lime of 1:1 (Ab„AnJ is given under II, while under III the composition of andesine made up of albite and anorthite in the ratio of 3 :2 is shown. I II III SiOj . . 57.15 26.74 0.25 trace 6.66 0.59 0.38 6.83 0.90 59.84 25.46 6.97 7.73 58.11 ALO,. . 26.62 Fe,,03+FeO.. .. MnO CaO MgO .: K^O 8.34 N"a,0 . 6.93 Loss of ignition. . gravity. . Specify 99.50 2.668 100.00 2.671 100.00 2 . 680 68 ROYAL SOCIETY OF CANADA An analysis of the blue corundum which occurs associated with this rock, wae made by Mr. M. F. Connor, B.Sc, witli the following re- sults : — SiOo none AloOa (dili) 96.90 FeoO,+lV() 0.76 CaO.. • 0.46 MgO 1.00 H,0 0.88 100.00 Red AlJcali Syenite. Associated with the white or grey variety of the alkali syenite, as well as with the nepheline syenite, and passing into these some- times by an abrupt, though usually by a gradual transition, are cer- tain highly feldspathic rocks, often occurring as very extensive in- dependent masses which are distinguished in the field mainly by their reddisli colour and the marked scarcity or entire absence of quartz. They differ from the white and grey varieties in that ortho- clase, microcline and microperthite (the latter confined mostly to the pegmatitic phases) are quite abundant and sometimes the predominant feldspars. Plagioclase is also very plentiful, sometimes equalling in amount, if not exceeding the potash feldspars. A comparatively large area representative of this variety of syenite occurs intimately associated with the nepheline syenite near the York river and is referred to in the first published descriptions as " a reddish biotite granite resembling aplite in appearance." ^ Thi^; rock is exposed on both sides of the York river extending from the eleventh to tlie fiftecntli concession. N"epheline syenite occurs on both sides of tliis bathylitli. and if the outcrops of this rock could be traced and foimd continuous would doubtless form an asso- ciation closely analogous to that described a^; occurrinix i'l the township of Monmouth. The rock is essentially a quartz mica syenite made up almost wliolly of oi'tliocla'^o, itiicroclinc. albite. nuaitz. hintito. and in places hornblende. The biotite is in veiy small and exceedingly ir- 'Am. Jour. Sc. Vol. XLVIII, 1894, p. 11. [ADAMS & BARLOW] ALKALI SYENITES OF EASTERN ONTARIO PLATE XIII. O. E. PRUDHOMME, Del. Crystal of Corundum in Syenite Pegmatite. The Syenite Pegmatite or Feldspar Matrix Fills in the basal Cracks. CRAIGMONT, RAGLAN TOWNSHIP, ONTARIO. [ADAMS & BAKLow] ALKALI SYENITES OF EASTERN ONTARIO 69 regular or ragged scales, with strongly marked pleochroism and absorp- tion. This brownish biotite has a distinct greenish tinge. The various cracks and fissures are filled with reddish brown iron oxide which also stains the orthoelase and microcline. The rock is youn2:er than the nepheline syenite which it sometimes intersects, and decidedly later than the surrounding crystalline limestone. Its association with the nephe- line syenite, however, strongly suggests that both are the products of the differentiation of a single magma. A similar type of rock prevails along the southern slope of the hill at Craigmont in Eaglan township. Its mode of occurrence, association and relations to the Laurentian gneisses as well as to the nepheline syenite have already been described. This reddish or pinkish rock frequently contains bands of a dark coloured, highly micaceous rock which may represent deformed and altered dykes of basic composition. In places masses and patches of almost pure hornblende occur. A specbnen of the reddish highly feldspathic variety of the rock, with a distinct streaked appearance, owing to small ragged scales of biotite with more or less parallel arrangement, was analyzed by Mr. M. F. Connor, B.Sc, with the following results: — SiOo 56.05 TiO, 0.47 AlA 17.03 PeA 9.10 FeO i.20 MnO 0.08 CaO 0.72. MgO 0.13 K,0 5.18 Na^O 6.10 PA ^-^^ H..0 0.36 99.38 The ratio of (CaO+K^O+Xa.O) : ALO3 : SiO; .163 : .165 .934 1 : 1 : 5.7 70 ROYAL SOCIETY OF CANADA If the norm of this rocl< be calculated, it will be found to be as follows : — Orthoclase 30.02 Albite 51.35 Anorthite " 3.62 Corundum .20 Magnetite 12.30 Ilmenite .91 Hematite .64 Olivine .31 99.35 Phosphoric Acid .04 Water .36 99.75 Deficit in Silica .27 99.48 The position of the rock in the Quantitative Classification is accord- ingly as follows : — Class II Dosalane Order V Germanare Rang 1 Umptekase Sub-rang TV Umptekose The mode of the rock, that is to sa}-, its actual mineralogical com- position, does not differ essentially from the norm, the rock being made up of orthoclase, microcline, albite (aboxit Ab.AnJ and magnetite, with a little biotite, which latter mineral in the norm is represented by other mineral combinations. No quartz is present, .27 per cent of additional silica being required to satisfy the feldspars in the norm. The rock, which contains the largest and most abundant crystals and masses of corundum at Craigmont, and thus the richest " ore " of this mineral, is the corundum-syenite-pegmatite, which occurs in the form of dykes or veins, varying from six to eighteen feet in widtli. These dykes intersect the medium grained or normal type of red syenite just described, which also contains corundum although in less abundance and in smaller individuals. They are made up almost wholly of a deep flesh- red to very pale salmon-pink feldspar, which, in thin sections under the [.\DAMs & BARLOW] ALIvALI SYENITES OF EASTERN ONTARIO 71 microscope, is seen to be an irregular intergrowth of ortlioclase and al- bite, the former feldspar being the more abundant. Associated with this niicroperthite are corundum, biotite, scapolite, calcite, magnetite, hematite (micaceous iron ore), molybdenite, pyrrhotite, chalcopyrite, chrysobery], spinel, and quartz. All these, with the exception of the first mentioned, occur as accessory constituents in certain places and are usually present in small amount. Although quartz and corundum are commonly supposed to be mutually exclusive, specimens have been found in which small quantities of both of these minerals are present. An analysis of a typical specimen of the corundum syenite pegmatite from Craigmont was made by Mr. M. F. Connor, B.Sc, the results ad- justed to a basis of 100 are given under I. For purposes of comparison the analyses of the corundum syenite pegmatite and of the corundum syenite from Kikolskaja Ssopka in the Urals, Eussia, are included under II and III. (Tschermak's Min. und Petr. Mittheil., XVIII, 1898, p. 219). Under I (a.) is given the analysis of I, omitting the corundum and recalculating it to a basis of 100. Under II (a) and III (a) are similarly included analyses of II and III, in which the corundum i> omitted and the remaining constituents recalculated to a basis of 100. Under IV is an analysis of the separated microperthite from the corun- dum syenite pegmatite of Craigmont, Ont. Under V is an analysis of a similar feldspar from the corundum syenite pegmatite from Sivamalai, India (Mem. Geol. Surv., India, Vol. XXX, Part 3, 1901, p. 202). i; II. III. la. Ila. Ilia. IV. V. Corun- dum 34.62 35.40 18.55 SiO^ 40.53 40.06 52.34 62.30 62.71 64.65 63.43 63.26 AiPa 13.62 13.65 16.05 20.93 21.37 19.83 20.78 21.87 FeA 0.19 0.35 0.45 0.29 0.55 0.56 0.29 0.22 FeO 0.04 0.06 CaO 0.67 0.30 0.20 1.02 0.47 0.25 1.00 0.21 MgO 0.15 0.16 0.23 0.19 0.07 Kfi .5.92 5.20 6.58 9.10 8.14 8.14 8.00 3.09 NaP 3.40 3.71 4.77 5.23 5.81 5.89 5.20 10.25 H^O 1.01 0.46 0.40 1.07 0.72 0.49 1.00 0.78 100.00 99.28 99.50 100.00 100 00 100.00 99.79 99.68 72 ROYAL SOCIETY OF CANADA An examination of these analyses will show at a glance the remark- able similarity jn chemical composition of these corundum-bearing rocks, occurring at such widely separated localities as Canada and Eussia. The specimens of the Canadian and Russian occurrences are practically identical. Xo analysis of the corundum syenite froju India is avail- able. The analysis of the feldspar from the Indian rock is very closely analogous in composition to that of the other syenites free from corun- dum, the only substantial difference being in the relative amounts of soda and potash present. Taking into consideration the molecular values of soda and potash, the ratio of the soda to the potash in the Indian feld- spar is 5 :1, while in the Canadian and Russian occurrences the soda is only slightly in evcess, and in the separated feldspar is practically the same. The following are the molecular ratios in the corundum syenites a=: above : — CaO + K.O + Xa.O Analysis I (a) = 1 Analysis II (a) ^ 1 Analysis III (a) = 1 AL03 : SiOo 1 : 5.2 = Ontario 1.1 : 5.5 = Eussia 1.1 : 5.9 = Eussia Mr. M. F. Connor, B.Sc, has also made analyses of the brown corundum and the magnetite which are present in the syenite pegmatite. These are given under I and II respectively. The material in both cases was selected as free as possible from impurities or alteration products. II. SiOj . AljO, (diff.) .. Oxide of iron CaO MgO H.O none 95. 5S 2.10 0.48 1.00 0.84 100.00 Silica and silicates FeA FeO TiO^ HjO Sp. Or. 1.40 65.04 30.60 2.50 0.57 100.11 3.95 (average four determinations.) The occurrence of the corundum in association with absolutely fresh and unaltered minerals, in rocks of undoubted igneous origin and [ADAMS & BARLOW] ALKALI SYENITES OF EASTERN ONTARIO 73 behaviour, at once removes all doubt as to the pyrogonetic origin of tlie mineral, showing clearly, that it is one of the first products of the crystal- lization of a magma supersaturated with alumina and very poor in ferromagnesian minerals. The chemical analyses, a« given above, arc in remarkably close agreement with the law formulated by Morozewicz, as a result of direct experiments with artificial magmas, not only as to the conditions essential to the solution of alumina in sucli alumino-sili- cate magmas, but also with regard to the subsequent separation of all excess of alumina as corundum, as these solidify on cooling. SUMMARY. 1. The nepheline and associated alkali syenites of this district present one of the most extensive developments of these rocks which is known. They form part of the Pre-Cambrian complex of the Canadian Shield, and occur along the border of the batholiths of Laurentian gneissic granite, where these cut the crystalline limestones of the Gren- ville series. 2. They differ from most occurrences of these rocks which have been described from other parts of the world, in that they have not usually the massive character of ordinary intrusives, but possess a dis- tinct gneissic structure. The gneissic or foliated structure which they usually display is combined with a schlieren or streaked structure, which gives rise in small exposures, to a banded appearance, the several bands dif- fering in the relative proportion of constituents present. The foliation is not such as would be produced by the direct crushing of a massive rock. Cataclastic structures are very seldom seen, and the rock very rarely shows any distinct evidence of pressure. The arrangement of the component minerals, with their longer axes in the same direction, pro- duces the foliation, while their variation in amount from band to band serves to emphasize it. The rock is, as a general rule, poor in iron mag- nesia constituents, and its appearance on the weathered surface so closely resembles that of the crystalline limestones of the Laurentian, which are often more or less impure from the development of secondary sili- cates in streaks and bands through them, thJit it is often impossible to tell the two rocks apart at a distance of a few yards. 3. The nepheline syenite magma throughout the area is one which was relatively very rich in soda. The plagioclase present is in most cases albite, but sometimes oligoclase or even andesine. and these felds- pars preponderate largelv over the orthoelase and are frequently the only feldspars which the rock contains. Tho rnr-k fnrtbennnrc rlifTors from 74 KOYAL SOCIETY OF CANADA the great majority of other occurrences in that instead of augite, which usually occurs in tliese rocks, it contains either biotite (lepidomelane) or liornblende, as the iron magnesia constituent; augite being seldom present and wlien it occurs, being always in very subordinate amount. In this respect it resembles the Indian occurrences as well as those at Miass, in which biotite is the prevailing dark constituent. ■i. The nepheline syenites of this area show a fine series of differ- entiation products. These range from granite at the acid end of the series, through alkali syenites rich in soda, corundum syenites and allied rocks and nepheline syenites, to nepheline rocks, and with increase in the quantity of iron magnesia constituents to varieties having the com- position of Essexites, and even to more basic forms. As a result of this abundance of soda in the magma is the frequent occurrence of varieties of the nepheline syenite which are extremely rich in nepheline, and which, by the disappearance of the feldspar, pass over into rocks which are composed almost exclusively of nepheline and iron magnesia constituents. These rocks are closely allied to the Urtite ^ described by Eamsay from Finland, but contain hastingsite instead of aegerine as the prevailing dark constituent and when the norm is cal- culated, are found to be relatively richer in the salic components, so that they fall into class I (Persalane) of the Quantitative System, while the TJrtite belongs to class II (Dosalane). These rocks thus constitute a new group, the type whose analysis is given on page 42, belonging to a new rang which has been called Monmouthose of the order Ontarare. It is proposed to call this rock Monmouthite. In the terminology of the Quantitative Classification, the various differentiation products which have been analyzed are embraced by rangs 1, 2 and 3 of orders 4, 5, 6, 7 and 8, of the Persalanes and Dosalanes, Sub-class I, with the exception of one of the new t3^es which is a Dosa- lone. A somewhat similar, though les ■* t^ (N ^ •juomSi^jQ »o CO o> •f 9 'trepBjj •lunpuiuoQ 'S CO ""• - qiiA a^t^eaiascj a^maXg CO CO 10 t^ (M on (N (N Tf CO X •jUOUiaiKJJ 'UBJ T CI t- '— « >— ' -iv\i (ssoy[sl<\Mii) 'innp r^ 05 •^ iC 05 -aiuoj qjiAi ajiU'SAS ][^A[V »c 05 •ST 50T CO (N C5 r- 00 10 t^ T)< CD 'AX '"'^O 'nouuB8unQ iC t^ 05 Tf O) Cl Oi CT> ■-< X CD^-^ (dsouounuaunci) lunp 05 CO ^ lO rt ■^ -xnuoo qii-vs. ajiuaXg IIUHIV ■^ • CO CT> ■ jiioni >o * 10 05 10 CO (N 00 Tf -311! JQ 'ubi8bj{ (aso •# iC •*■!-£ I ?OT CO 0) c t^ t-- •* (N Oi IC C ■* CO 'X '""0 'uanqiaiv (asop 10 05 C^ CO CO c -naaiic^i) 'ajmaAg ]\v^iy c H C5 GO 00 t^ ^ X CI •^ CO I'l-L'I CO 0) ■^ 10 CO C (M C r)< t^ CO X c^ •—I x^ •noQ 'qjnoumoi^ (dsoqj Oi (M 10 CO CO CI .—1 OlC -nouiuojv) aiiqjnoiuuoj^ CO CO '^ I0 CO t^ CJ t^ H JOT 'IIIA CO t^ 05 10 CO "* CI t^ ■—1 CO 10 t- •nog 'qinouiuoj^ (asoxas CO CO GO t^ ^ (M C) CM 05 -sg) -a^iuaXg auijaqdaj^ Tf< O) C5 00 10 CD Id •* a> CO 05 10 CO CM OB •9T 1"T 'XI 10 CO ■* (N o CO Tf t^ ^ ^ C5 ^a) -ajraaAg auiiaqdafj iC 05 iC ■* (M CO CO t^ r- t^ t^ X •loq 'uoQ 'qjnoui C5 CO CO CO t^ C^) CO -aojt (asojaajqj) 'a^iuaA;,' CO C5 ^~* ^^ t^ >o d 0" 0" 1 s W 0^ o si THE LIBRARY UNIVERSITY OF CALIFORNIA Santa Barbara THIS BOOK IS DUE ON THE LAST DATE STAMPED BELOW. UTTSSLIBRAFY LOANS '/'"'"vliRSlTI OF CALi.^uENlA SA..TA BAHBASA, bA 9310 2/92 Scnes 9482 i *^'':'i^'':'^t. %?') ^ V-^-,^.; r^j^] 1