THE CONSERVATION OF TEXTILES LAUNDRYOWNERS NATIONAL ASSOCIATION DEPARTMENT OF CHEMICAL ENGINEERING THE CONSERVATION OF TEXTILES . . . BY . . . HARVEY GERALD ELLEDGE AND ALICE LUCILLE WAKEFIELD INDUSTRIAL FELLOWS OF The MELLON INSTITUTE o/ INDUSTRIAL RESEARCH OF THE UNIVERSITY OF PITTSBURGH PUBLISHED BY LAUNDRYOWNERS NATIONAL ASSOCIATION LA SALLE, ILLINOIS Extra copies of this Book may be had for $1.00 per copy upon application to W. E. FITCH, Manager of the Laundryowners National Association, Drawer No. 202, La Salle, Illinois COPYRIGHT, 1921, BY LAUNDRYOWNERS NATIONAL ASSOCIATION LA SALLE, ILLINOIS Applications for permission to 'use any of the material in this Book should be addressed to W. E. Fitch, Manager of thelLaundryowners National Association, Drawer Ko. 202, La Salle, Illinois. Mlrdoch-Kerr Press Pittsburgh, Pa. Contents PAGE Preface 7 The Development of the Power Laundry Industry — Textile Work of the Department of Chemical Engineering — Causes of Wear in Fabrics — Attitude of Laundry Industry to Damages — Failure of Curtains — Impartiality of the Department of Chemical Engineering. CHAPTER I. Fibers 13 History of Clothing — Skins — Rushes — Development of Fabrics — Development of Spinning — Cotton — Mercerized Cotton — Schreiner Finish — Linen— Wool — Silk — Artificial Silk and True Silk— Test for Vegetable Fibers— Differen- tiation of Artificial Silk — Test for Animal Fibers — Use of the Microscope — Identification of Fibers by Physical Appear- ances. CHAPTER II. Weaves ^^ Plain — Fancy — Use of "Floats" — Advantages and Disadvan- tages Accruing from Use of Floats — Ideal Fabric — Variations from the Ideal — Loose Spinning — Long Floats — Relation Between Fiber Lengths and Float Lengths — Satin Weave — Short Fibers and Loose Spinning — Pile Fabrics — Weaving Flaws — Use of Poor Materials — Influence of the Finishing Process on Fabrics. CHAPTER III. Mechanical Sources of Damage 82 Snagging — Knives — Razor Blades — Bed Springs — Mice — Poor Tailoring. CHAPTER IV. Colored Garments 90 Types of Dyes — Classification of Dyes — Direct — Acid — Basic — Salt — Mordant — Vat — Sulfur — Aniline. CHAPTER V. Corrosive Materials 98 Claim Adjuster — Settlement of Claims — Identification of Type of Damage — Chemical Tendering — Tendering by Launderer — Tendering by Wearer — Table of Materials Cor- rosive to Fabrics (Table I.)— Table of Corrosives Encountered in Various Professions and Employments (Table II.) — Dis- cussion of Tables — Tendering by Manufacturers. Contents — Cont. CHAPTER VI. PAGE The Treatment of Stains 129 Treatment of Stained Fabrics — Need of Trained Employee for this Work — Equipment — Table of Reagents Used in Stain Removal — Oxalic Acid — Acetic Acid — Hydrochloric Acid — Caustic Soda — Ammonia — Javelle Water — Hydrogen Di- oxide — Potassium Permanganate — Sodium Perborate — Sodium Bisulfite — Oleic Acid — Sodium Thiosulfate — Potas- sium Cyanide — Removal of Stains (following L N. A. Pro- cedure Chart, See insert, page 135). CHAPTER VII. The Conservation of Fabrics 142 Length of Life of Fabrics — Hotel Fabrics — Collars — Mechani- cal Effect of Power Machinery — Effect of Standard Wash- room Reagents — the Model Laundry of the American Insti- tute of Laundering — Work of the Salvage Branch of the U. S. Army — Agencies of Responsibility — Retail Merchant — Dyes — Styles — Education of the Public — Abuse of Fabrics by the User — Responsiblity of the Laundry. CHAPTER VIII. Pure Fabric Legislation and the Department of Chemical Engineering, J. Clair Stone 153 The Creation of the Committee on Legislation for the Correct Labeling of Fabrics — Purposes of the Committee — Protec- tive Legislation — The Interest of the Laundry Industry in this Endeavor — Educational Responsibilities of the Com- mittee — The Study of Textile Conservation — 1917 National Textile Conference — Co-operation of Department of Chemical Engineering with the Textile Committee — The Laundr>'- owner's Knowledge of Textiles — Present Activities of the Committee on Legislation for the Correct Labeling of Fab- rics — Assistance Required of the Individual Laundryowners. Foreword THE chapters in the succeeding pages of this book present the results of five years of painstaking re- search into a subject that is of the keenest interest to laundryowners. The authors of this book have not only handled their subject from an analytical and scientific standpoint, but they have succeeded in putting it together in a truly readable and interesting literary style. The subject "The Conservation of Textiles" is one with which every laundryowner should be familiar. Our knowledge of textiles has been more of an intuitional nature than of one of positive understanding of their origin, compositiop and peculiarities. A positive and sympathetic understanding of the goods we are called upon to renovate is of the greatest importance to ourselves and to the public. We all are or should be deeply concerned with the "conservation of textiles." Our reputations as launderers are at stake — not only that but the reputation and ad- vancement of our industry are greatly influenced by the degree of accuracy with which we classify the goods we are to launder, and by the degree of accuracy with which we prescribe the treatment they are to receive. The Department of Chemical Engineering, the Director and Associate Director of which Department are the authors of this treatise on textiles, has already given to the members of this Association its Standard Formulas for Washroom Practice. It is most fitting now that we should be told of the nature of the goods to which these formulas are to be applied. In fact, it seems that many of us would have understood the formulas better if we had studied the "conservation of textiles" first. Science is not something to be afraid of or ridiculed or classed as "high-brow stuff." It is nothing more or less than "organized knowledge and classified common sense." Through its use and application to social, in- dustrial and agricultural problems, our greatest progress as a nation is being brought about. And so, then, let us take this little book at even more than its face value. It will help us to know more about the goods we are handling. It will familiarize us with certain practices on the part of certain textile manu- facturers, which practices are detrimental to the interests of the public and to our interests and cause many of the claims that are presented to us for payment through failure of some of these goods. Let us learn how to use this book intelligently in the adjustment of claims. Let us read it thoroughly and preserve it carefully, remembering that there is no similar book in the world, and that, while it is not a large book, its preparation represents extensive study on the part of its authors; and last, but not least, let us remember that the book comes to you as an enduring testimonial to the value of organized effort through our membership in the Laundryowners National Association. W. E. Fitch. La Salle, Illinois. Preface THE development of the power laundry industry has been, until comparatively recent times, coincident with the popularity of the starched, detachable collar. The time is well within the memory of many men, today actively engaged in the laundry business, when white, stiff-bosomed shirts, white cuffs and collars constituted the chief articles laundered. Conditions have been, and still are, rapidly changing. In the early periods of the development of the industry the laundry manager was required to know the characteristics of few fabrics; one grade of cotton and one grade of linen, both of plain weave, were encountered. Dyes did not concern him. Later, he was required to wash and iron colored shirts and collars; still later silk and fine flannels. Today, with the variety of styles in men's shirts and with the laundry catering to family service, a knowledge of textiles and dyes is needed by everyone interested in good laundering. Some suggestions which will prove helpful in securing this desired knowledge appear in the following pages. The phase of the activities of the Department of Chemical Engineering of the Laundryowners National Association Service Bureau that has attracted the greatest interest during the period of the last year or so, has been in connection with textile articles for which claims for damage have been made against the laundry for one cause or another. Some of these exhibits show the failure of the fabric in the typical manner of the natural wearing function. The fact that textiles are perishable cannot be too strongly impressed on the minds of the patron of the The Conserz'ation of Textiles laundry, the management of laundries, and the owners of laundries. It is true that under some circumstances cloth may be and has been preserved through long periods of time. Such incidents, however, are rather the excep- tions that prove the rule. Textile fabrics wear out. Sunlight, some dyeing materials, water and friction are their natural enemies. In addition to these natural enemies, there are incidental enemies which are acquired by accident or rather by uncommon incident during the designated use of the fabric. Medicines, household toilet articles and cosmetics, and industrial materials are acci- dentally acquired during the ordinary use of the cloth, which, according to fairly well understood chemical laws, cause weakening of the individual fibres and a consequent shortening of the serviceable life of the fabric. Through correspondence with various members of the Association and other communications from this Department, discussion has been presented on many specific examples of the type of cases mentioned above. The general interest which has been attracted by the diagnosis of the cause and responsibility for the condition exhibited by the many cases of textile failures and the special interest of some of the members of the Association have prompted the preparation of this book on the subject of textile defects and failures.* The attitude of mind entertained by the management and personnel of the laundry industry toward these problems is reflected to the patronage of the industry. Recognition of the truth of this proposition constitutes the actuating motive for the elimination of words and expressions of objectionable connotation from the trade language. It likewise constitutes the incentive toward research on problems that are only qualitatively under- stood. Every thoughtful person knows that the useful period of service to be had from any textile article is ♦Some of the material pres;nted herein was induded in a paper on this same sub- ject delivered before the Chicago Convention and published in the 1918 "L. N. A. Year Book." Preface limited. Just how long a period constitutes a reasonable expectancy for various grades of materials is an un- answered question. This Department is making an effort to place at the disposal of the industry some definite knowledge concerning the wearing qualities of cloth. Even a casual inspection of any back-yard on washday noon affords a clear demonstration of the qualitative facts. Do clothes wear out, is not so much the question as is, how rapidly should fabrics of a certain quality wear out under ideal conditions of wearing and washing? The experience of the housewife who does not send any of her work to the power laundry has taught her that lace curtains fail more quickly when the window-shades are left up, exposing the curtains to sunlight. She has also observed that the line of failure is determined by the position of the window-shades and she is therefore very apt to keep the shades down most of the time in order to protect her lace curtains. If, however, she is a patron of a power laundry, she is inclined to forget about the effect of sunlight on fabrics and, in case the curtain has failed, she is inclined — not always with intentional dishonesty, but through prejudice against power laundries — to want an adjustment with the laundry for alleged damage done the fabric in washing. The experiments conducted by the Department have shown just how much tendering a certain amount of exposure to summer sunlight does to a fabric in a certain length of time. An interesting contri- bution to the knowledge of the effect of sunlight is had from the experience of the British Army with airplane fabrics when exposed to the tropical sun.* It is a part of the favorable publicity campaign for the laundry industry to make the people engaged therein understand more thor- oughly the facts. Knowledge of the truth is good for all concerned and especially will a correct understanding of textile knowledge be beneficial to the salesmen and pro- ducers of laundry service. ♦Charles Doree and Joseph W. W. Dyer, Journal of the Society of Dyers and Colour ists, January, 1919. Tlic Conservation of Textiles Successful salesmen usually know something concern- ing the production of their commodity. It is the practice of the United States Steel Corporation to give their sales- men a brief course of instruction in the chemistry and technology of steel. Progressive automobile distributors make it a practice to send their salesmen to the factories to learn something of the construction of the machine they have to sell. It was with the idea of furnishing some of the information suggested above, and, if possible, of providing a stimulus to careful study of the production and sale of laundry service, that the writing of this book was undertaken. If the purpose is accomplished in the broader sense, it will be done through the sympathetic co- operation of its readers. The readers that the authors have had in mind during the preparation of the text are first of all the members of the Laundryowners National Association. In addition to these, it has been the aim to interest the foremen of the washrooms and other departments of the laundry plant organization and especially those persons who come in contact with the customers, the salesmen and claim adjusters. In the accumulation of the information which the authors have endeavored to present, they have come in contact with the most progressive men of the industry. This progressiveness is evidenced by the fact that they have taken the time and trouble to file their data with the Department of Chemical Engineering, where it is available to every member of the Association. In view of this fact, no feeling of self-complacency should be inspired in the minds of the thoughtful men of the laundry industiy to know that, of the exhibits submitted to the authors' Department, less than five per cent, have represented cases wherein the laundry has been at fault. 10 Preface It should be pointed out in this connection that the industry is being watched, not only by the patrons but also by the textile manufacturers, the fabricators of garments and some of the larger dealers in fabrics. Many of these maintain their own research departments. Through these agencies the L. N. A. ofificials, and this Department in particular, are learning of undeniable instances of the shortcomings of the industry. The most flagrant cases of the violation of the rules of good laundry practice are from the less progressive plants and from those outside the National Association. These conditions should stimulate the management of the better plants to more consistent consideration of helpful advice, not only in the application of it to their own work, but also in an endeavor to interest the less progressive. It is quite obvious, as has been called to the attention of all so many times, that the good laundry suffers the bad effect caused by the poor quality of service rendered by the nonprogressive. In the analyses of textile exhibits this Department has always maintained an impartial stand, considering only such evidence as would be acceptable in a court of law. No attempt has been made to shield the laundryowner when the evidence submitted showed that he had been at fault. If, on the other hand, the evidence indicated the fault of the fabric or abuse of the fabric by the user, it has been the pleasure of the Department to help the laundryowner to convince the patron of the facts and thereby ultimately to increase the store of good will toward the industry. Some of the facts presented in the first few chapters may appear to the busy launderer to be of academic rather than of practical interest. However, these par- ticulars are furnished in view of the conviction enter- 11 The Conservation of Textiles tained by the authors that the information contained therein constitutes a helpful background for the appli- cation of the facts brought out in the technical portion of the book. Harvey Gerald Elledge, Alice Lucille Wakefield. Mellon Institute of Industrial Research, University of Pittsburgh, September, 1920. 12 CHAPTER I. Fibers A SHORT review of the history of clothing will not be wholly out of place here. The records obtained by archeologists date back as far as 2600 B.C. and show the arts of spinning and weaving to be in a late stage of de- velopment at this time. Beyond this date nothing definite is known because no records have been found; in fact, no records are expected of the very earliest stages since these arts appeared long before man began to express himself by means of writing. However, from our present knowledge of man and the progress of his ideas and intellect from infancy to manhood, it has been possible to imagine the first steps taken by primitive man in the evolution of the art of cloth manufacture. When the first desire or need for body covering arose, our ancestors took what lay nearest at hand and clothed themselves with the robes which nature had furnished their less highly endowed brothers, the four-footed, fur-bearing animals. To do this, imple- ments for obtaining the skins were necessary, and the cleverness displayed in their preparation soon found expression in another way. Rushes and fibrous grasses were plaited or woven into mats that were found to be much lighter and more suitable for purposes of clothing in certain climates and seasons than were the animal skins. Continued use of the grasses demonstrated that an exceedingly wide field of application of heretofore useless materials had been opened to ingenious minds. Experience proved that for purposes of covering or decorating the 13 The Conservation of Textiles body some plants were more desirable than others. The desirable features of these plants were found to be confined to one section of the stalk, the section lying between the bark and the woody portion ; these features were toughness, pliability and greater ease of bleaching. Primitive man was even more prone to personal decoration than civilized man and early realized that white cloth gave him clearer and more brilliant colors than gray or cream cloth did. The fibers that resulted from the manipulation of rushes and reeds by the ancients are the linen fibers of today, and by virtue of their descent from reed weaving, and the fact that reed weaving goes back beyond any other type of weaving, linen fibers may be called the oldest of the textile fibers. Long after grass fibers were first used, but before their use had reached any great degree of perfection, the pos- session of herds had brought a knowledge of wool. Wool originally did duty as a body covering in the natural form of an undipped skin, and the real value of wool fibers became apparent only after the discovery was made (by accident rather than by intent) that by simultaneously pulling and twisting the clipped wool a long continuous strand could be obtained. This process of pulling and twisting (later called spinning) was quickly applied to other fibers, and, by means of it, many fibers, hitherto useless for weaving, by reason of their extreme shortness, were added to the list of useful natural products. Cotton was the most important of these later additions, but, like silk, was not used extensively for a long period and was regarded as a rare luxury. Today, however, the relative economic values have changed so that cotton heads the list as the one fiber used most universally and in largest quantity, while linen, wool and silk take their places in the order named. It is interesting to note that these four fibers, known now for ages, still remain the best and most useful aids to 14 Fibers man's physical comfort. They are also the ones in which the laundry industry is most interested and for that reason we must know them so well that we will recognize them wherever we meet them. They are grouped as vegetable fibers (cotton and linen) and animal fibers (wool and silk), on account of the sources from which they are derived. The vegetable fibers are further differentiated as seed and bast fibers; i. e., fibers from the seed pod and fibers from that portion of the stalk known as the bast region, lying between the outer bark and the inner woody portion. Cotton. — This fiber (which is useful only when ripe) belongs to the class of seed fibers and is disclosed in the ripe burst seed pod as numerous white hairs or fibers at- tached to the seeds. Before spinning, these fibers must be removed from the seed and, previous to the invention of the cotton gin by Eli Whitney, this was done by hand. Microscopic examination shows the individual fiber to be a long, slender, flat tube, spirally twisted about its axis. Figure 1 is a photomicrograph (a photograph taken through a high power microscope) of cotton showing the details of its structure. One end will be found closed and pointed; this is the loose end of the fiber as it grew within the seed pod. The other end will be«found blunt and ragged where it has been torn from the seed. The fibers vary con- siderably both in length and width, the longer ones being best suited for spinning and weaving because when spun greater intertwining of the individual fibers occurs, resulting in a yarn of greater strength than that spun from shorter fibers. Actual measurements show the variation in length of the fibers to be, on the average, from eight-tenths of an inch to one and eight-tenths inches, although some fibers come as short as one-half inch. These extremely short fibers are usually combined with longer fibers to insure for the finished yarn a reason- 15 The Conservation of Textiles Fig. 1. — Cotton,* approximately, x 300 diameters. The appear- ance of cotton fibers, which is said to be like a "twisted ribbon," is shown very clearly in this photomicrograph. The middle fiber is an especially good illustration of this description, although the other two fibers are of value as demonstrating the fact that all fibers do not twist to the same degree. ♦Copied from the "Encyclopedia Britannica." i6 Fibers Fig. 2. — Cotton, Mercerized Under Tension,* approximately, X 300 diameters. By treatment with hot caustic soda solution while under tension, cotton fibers are changed into untwisted cylinders that reflect the light to a greater degree than the untreated fibers do and, consequently, possess a higher gloss. ♦Copied from "A Manual of Dyeing," by Knecht, Rawson and Loewenthal. 17 The Conservation of Textiles able tensile strength. Such is not always the case, how- ever, and many damages exhibited by fabrics submitted to the Laundryowners National Association's Department of Chemical Engineering for examination are the direct result of the use of these short fibers alone, without the reinforcement of a percentage of longer fibers. Mercerized Cotton. — A variation of the natural cotton is mercerized cotton. The difference between the two is physical rather than chemical, although it is brought about through the action of caustic soda. Mercerization causes the fiber to become transparent and to lose its flat spiral form to become a nearly straight cylinder having an increased power of light reflection and consequently a higher gloss. This change in form is illustrated by Figure 2. The mercerized fiber is even stronger than the raw fiber when the conditions of mercerization have been carefully guarded and overtreatment avoided. The only part of the change that is apparent to the eye, unaided by a magnifying instrument, is the increased gloss. Schreiner Finish for Cotton. — A high luster, simi- lar to that appearing on mercerized cotton, can be given to a piece of cotton cloth by subjecting it to a process called calendering. This process consists of passing the cloth between rollers under heavy pressure. One of the rolls is engraved with obliquely set lines, ruled fiom 125 to 600 to the inch; these lines produce a great number of parallel, flat surfaces on the cloth, which cause it to acquire a high luster. If the rollers are heated during the process, a finish is produced that closely resembles mercerized cot- ton, and is quite permanent. This finish, however, is lost to a large degree on washing. Linen. — Linen is a representative of the bast fibers and is obtained by fermentation of the whole flax plant. This process prepares those parts of the stalk that are undesirable as textile fibers so that further treatment by i8 Fibers Fig. 3. — Linen,* approximately, x 210 diameters. The jointed structure that suggests the description of "bamboo-like" is (juite ev'ident in the above photomicrograph. ♦Copied from "A Manual of Modern .'^team Laundry Work," by E. Clayton. 19 The Conservation of Textiles Fig. 4. — Wool,* approximately, x 210 diameters. The over- lapping scales that characterize the wool fiber are clearly defined in this photomicrograph. This feature is not so apparent on used wool as on the virgin wool. *Copied from "A Manual of Modern Steam Laundry Work," by E. Clayton. 20 Fibers drying and rolling removes them, leaving the long tough fibers to be used for spinning. When examined micro- scopically (see Fig. 3), a linen fiber presents a more or less bamboo-like structure, caused by the occurrence of several cells in sequence, with nodes or knots at irregular intervals where two cells are joined at the ends. An individual cell measures in length from twenty to forty millimeters (7/lOOths to 15 lOOths of an inch); conse- quently the long fibers of combed flax linen consist of a large number of cells attached end to end. These fibers, by virtue of their greater length, furnish a much stronger yarn than does cotton. Wool. — Wool and silk, though grouped together as animal fibers, are produced in entirely different ways. The term wool is usually taken to mean the hair of the sheep, although the hair of certain goats (Cashmere, Mohair, etc.) and of the camel are classed under the same name. The kind of animal from which it is obtained and the location on the body determine the quality character- istics of the wool, which may be short or long, coarse or fine, dull or lustrous. A long stapled wool fiber is one that measures over one and one-half inches in length, and its diameter is usually proportional to its length. Long stapled wool is generally combed and spun into worsted yarn and used for the best qualities of coatings, dress goods, etc., while the short fibers are carded and spun into woolen yarn, which is subjected to a fulling process subse- quent to being woven into fabrics, in order to impart thicker and fuller feel to the fabric. A close microscopical examination of wool reveals a cylindrical fiber covered with flattened, horny scales, which are funnel-like and which overlap each other in the manner of fish scales (see Fig. 4). The dimensions, uni- formity and compactness of these scales are generally conceded to determine the luster and strength of the wool. 21 The Conservation of Textiles Wool differs from the vegetable fibers in several important respects. It possesses greater elasticity and strength and is more lustrous; it is curly and has the property of becoming felted under certain conditions, which are outlined in the L. N. A. charts of Standard Procedure for Washroom Practice as including the use of too low a bath with too little soap. This property, while being useful in certain ways, is a nuisance in others, and it is well for launderers to keep this fact in mind when handling woolen articles. The exact physical change that takes place during the process of felting is still under discussion, but experiments carried out by the Department of Chemical Engineering have proved that it is the result of hard pounding in the wheel rather than of changes in temperature, which was first given as the cause of the phenomenon and was said to cause contraction of the fiber and an interlocking of the scales. The observation made by this Department upon the cause of felting is substantiated by the research findings of the United States Government workers on this problem.* Silk. — Silk is a substance secreted by several species of caterpillar for the purpose of forming a cocoon in which the change from the caterpillar stage to the moth stage of existence occurs. It is produced by two glands, situated one on each side of the body, and is carried by ducts to the head of the caterpillar where the spinneret is located. Here on coming in contact with the air the two gelatinous streams solidify and are cemeted together by another secretion which is produced by glands located near the spinneret. While all caterpillars spin cocoons in this manner, the secretions of only a few species form strands of sufficient strength to make them of value as textile fibers. When recovering these fibers for spinning, the cocoons are placed in water at a temperature of 60°C. to *A full report of this work is to be found in the laundry trade journals for the early part of 1919. 22 Fibers Fig. 5. — Raw Silk,* approximately, x 150 diameters. The above photomicrograph shows the silk fiber as it is obtained from the cocoon, before the gum is removed by boiling. Each strand is really two fibers, the gum serving to cover this double nature. ♦Copied from "A Manual of Dyeing," by Knecht, Rawson and Loewenthal. 23 The Conservation of Textiles Fig. 6. — "Boiled-off" Silk,* approximately, x 150 diameters. The true silk fiber as it appears after the gum has been removed. The natural high gloss that is developed or uncovered by this process is not as evident in a photograph as in the fibers themselves. ♦Copied from "A Manual of Dyeing," by Knecht, Rawson and^Loewenthal. 24 Fibers soften the cement which binds the two fibers together. When this softening has taken place the fibers are reeled onto spools, several strands being reeled together to form a thread. Raw silk (unreeled silk or the cocoon proper) is of a creamy or yellowish color and has very little luster. When examined under the microscope it appears as two straight, transparent fibers, absolutely lacking in cellular structure, cemented together along their whole length (Fig. 5). When boiled with soap solution, theouter layer of cementis removed, and the true luster of the fiber is revealed (Fig. 6). A silk fiber varies from 500 to 1500 yards in length and in diameter from 0.01 to 0.02 millimeters (4/1000 to 8/1000 inch). Besides the advantage afforded by such ex- ceptional length, silk is extremely elastic and is the strongest and most lustrous of the natural fibers. The best silk is produced by silk-worms reared under artificial environ- ment and carefully cultivated, and is finer, whiter and more lustrous than the so-called "wild" silks obtained from the cocoons of uncultivated worms. Artificial Silk. — The demand for silk has reached such proportions that efforts to supply its beauty at a popular price have led to the manufacture of artificial silks. The most_important varieties of these fibers are prepared by the same fundamental formula, which calls for a solution of some chemical product of cellulose in an appropriate liquid. Of the two types of artificial silk on the market, the better known is made from cellulose hydrate, more commonly called viscose. The other type is manufactured from cellulose acetate, and sold under the trade-name of "Lustron." Viscose and cellulose acetate "silks" differ materially chemically but the physical differences are not marked. However, the identification of the type to which an artificial silk belongs may be readily accom- plished in the laboratory. 25 The Conservation of Textiles The process of manufacture of artificial silk is briefly as follows: A solution of v^iscose (or of cellulose acetate) in a suitable solvent and of desired concentration is ex- truded by appropriate mechanical devices in such a way as to convert the viscous solution into filament form. These filaments or threads are placed into some medium that causes immediate coagulation or hardening, and are reeled from this coagulating material and prepared for weaving in the same manner as silk, per se. None of the varieties of cellulose silk possesses the strength and elasticity of real silk nor its resistance to the process of washing; they all have to be handled with considerable care and even with such treatment the results obtained are often not entirely satisfactory. This product of the chemical laboratory can hardly be dififerentiated from real silk by microscopical examin- ation because of the absolute lack of physical character- istics that exists in both types of fiber; it happens, however, that the one physical point of difference lies in the greater luster of the artificial silk, which shows such an increase over that of real silk that identification can be made merely from an inspection of the fabrics. In case any doubt remains in the mind of the inspector recourse may be had to simple chemical tests that are infallible. Differentiation of Artificial and True Silk. — The sim- plest of these tests is burning and identifying the odor that results; an odor as of burning feathers indicates real silk, an odor as of burning wood indicates artificial silk. Another test, that improves on this test by replacing the factor of personal judgment with one of purely chemical character, is conducted by heating a portion of the fibers under examination in a dry test tube and testing the reaction of the volatile matter driven off by this treatment with a piece of moist neutral litmus paper placed at the mouth of the test tube. If the litmus paper becomes red, the 26 Fibers fumes are acid and prove the fibers to be artificial silk; if the litmus paper becomes blue, the fumes are alkaline with ammonia and prove the fibers to be real silk. These are two of the few reliable tests recommended for the identification of textile fibers. Textile literature is filled with tests that are said to be good and that have been praised beyond their actual merits. It is often quite possible that these tests deserve their reputation for great delicacy of indication, provided we consider one important factor, i. e., the relation of the manipulator to the results. If the delicacy of the test is greater than the degree of d iicacy of technic that lies within the possi- bilities of tht average manipulator, the chances are that the test will fail when applied by other than the man who has worked it out. The process of evolution has gained for the originator of the test a knowledge of the reactions involved and a fineness of technic that is denied to others who may attempt to use it. It is deemed advisable to include in this chapter a discussion of the tests that have the full endorsement of the authors. Tests for Vegetable Fibers in Mixtiires.—li the presence of cotton or linen is suspected in a wool or silk fabric, proof can be obtained by boiling a small piece of the cloth in a 5% solution of caustic soda for five minutes. At the end of this period the wool or silk will be entirely dissolved and any cotton or linen that may be present will remain unaffected by this treatment. Tests for Animal Fibers. — If, on the other hand, it is desired to remove the cotton or linen and leave the wool or silk, the cloth may be saturated with a 2% solution of sulfuric acid (H2SO4) and then dried in an oven at 100°C. for an hour. This treatment chars cotton and linen fibers and they can be readily removed by rubbing the cloth gently between the palms of the hands. The wool and silk 27 The Conservation of Textiles successfully resist the action of the acid. These tests may be made quantitative by using weighed samples, carefully washing, drying and weighing the residue. The weight of the residue divided by the weight of the sample and multi- plied by 100 equals the percentage of wool or silk in the case of treatment with sulfuric acid, and of cotton or linen in the case of treatment with caustic soda. Figs. 7, 8 and 9 illustrate the application of these treatments to a fabric of cotton and wool mixture. Fig. 7 shows a piece of the whole cloth that has been dyed with an acid dye and later bleached to differentiate between the cotton and the wool. The cotton is bleached white while the wool retains its color. Fig. 8 shows the cotton threads that have resisted the action of boiling caustic solution, the open spaces having been occupied by the wool that was dis- solved out by this treatment. Fig. 9 shows the condition of the fabric after treatment with sulfuric acid, and pre- sents the unaffected wool fibers with the cotton removed. It is possible to differentiate between the two animal fibers by chemical analysis, but the procedure is too complex and the apparatus required too bulky to be at the command of everyone. There is no chemical means of differentiating between the vegetable fibers in spite of the oft-repeated statement that such differentiation may be made by treating a mixed cotton and linen cloth with concentrated sulfuric acid for one or two minutes, drying and washing. The statement is made that the linen will survive this treatment while the cotton will not. The degree of solubility of cotton in sulfuric acid approximates that of linen too closely to permit a separation by this method. For these reasons, in cases that prove difficult to decide, it is often desirable to conduct final tests with the microscope. Although the examination of a fiber with the micro- scope is the quickest and most reliable method of identify- 28 Fibers P'ig. 7. Wool and Cotton Mixture. This mixture was dyed to differentiate between the wool and the cotton in the photograph. The dark portion is the wool and the light portion is the cotton. 29 The Conservation of Textiles ."I'v' ..'-■^^&^iUiS,Ji mm ■;:iKiBi Fig. 8. Cotton that has Survived Treatment with Caustic Soda. A piece of the fabric pictured in Fig. 7 was boiled in a 5 per cent, solution of caustic soda for five minutes. This treatment dissolved the wool and left the cotton as it appears in the above photograph. 30 Fibers fjCAjm«.''< 2QU<r,r Fig. 9. Wool that has Sl kvivkd Treatment with Sulfuric Acid. A piece of the fabric pictured in Fig. 7 was dipped in a 2 per cent, solution of sulfuric acid and dried for one hour at 212 degrees Fahrenheit. It was then rubbed between the palms of the hands. The cotton was charred by the action of the acid at 212 degrees Fahrenheit and was removed b\- the rubbing. 31 The Conservation of Textiles ing it, there are times when the microscope is inaccessible and when we must be prepared to recognize fibers from their characteristic appearance when spun and woven into fabrics. The characteristic appearance of the four fibers considered here, as observed without chemical or physical aids, are distinct, yet the best way to acquire a knowledge of their differences is to obtain pieces of material, pick them apart, feel them, and examine them closely for distinguishing features. There are certain statements which can be incorporated into such a book as this, like the fact that mercerized cotton is glossier than natural cotton, and that silk is glossier than cither natural or mercerized cotton; that linen has a gloss, but that it is not so hard or high as that of silk or even mercerized cotton ; that wool is crinkly and elastic, etc. But what we cannot do is to describe accurately the difference between the several glosses or between the crinkle due to the nature of the wool fiber and that which is acquired in the fabric as the result of the strain exerted by the crossed threads, so that the reader may judge all cases unerringly. There are things that the eye can perceive quickly and the mind retain readily, but which are difficult of description. The time required to train the eye and mind to accurate differ- entiation through observation is actually less than the time required to make the most accurate, skilled descrip- tion possible, which at its best would be inadequate because of the limitations of the written language. So our advice to a laundry claim adjuster is, not to go to books for word pictures, l)ut to go to the fabrics themselves for original pictures. This may mean "shop- ping" for samples of known quality and construction to be used as standards, or it may merely mean the exten- sion of interest to all fabrics that are received at the laundry; in any case it means keen observation and accurate memory, combined with a strict avoidance of "snap" judgments. 32 CHAPTER II. Weaves. WEAVING, by which means rpun fibers are con- verted into fabrics, consists of intertwining at least two systems of threads in such a manner that each individual thread maintains a definite position to the rest of the threads and the two systems are locked in their respective positions. The threads running length- wise of the cloth, parallel to the selvedge, are known as the "warp," while those running at right angles to the selvedge are termed the "filling." Plain Weaves. — In the simplest form of weaving (what is known as the plain weave) no two adjacent filling threads cross one warp thread on the same side of the cloth. While the odd filling threads are going under one warp thread the even filling threads are going over it. This order is changed for the next warp thread, the odd filling threads going over and the even going under. (See Fig. 10 for details of this construction.) A homely ex- ample of this method of weaving, and one ' with which the most of us are familiar, is the "darning" stitch used in mending. In this process the hole to be mended is filled with parallel threads placed rather close together; after this is accomplished, the needle is started across the hole at right angles to the threads already there, in its passage picking up every other thread. To return to the other side of the hole those threads that were not taken up the last time are "picked up," with the result that both systems are locked together and a "woven" fabric fills the hole. The very first weaving was done in this simple manner, the first system of threads (the warp) being 33 The Conservation of Textiles ^'-r -i' O, •*^ -i-^^' W^"^***'' if -^1^. «^ Fig. 10. Plain Weave. A portion of a piece of fabric made by the "plain weave" pattern. The regular "over one-under one" course of both warp and the filling is made plain here by enlargement with the microscope. 34 Weaves Fig. 11. "Satin" Stitch. The "under one-over four" stitch, known as the satin stitch, is used in weaving satins to give the smooth unbroken surface finish and in fancy fabrics of all kinds to facilitate the change from background to pattern. 35 The Couscrvation of Textiles strung between two poles. It was learned, however, that the process could be hastened by certain mechanical improvements that are represented in their highest degree of perfection by our present-day power looms that weave so rapidly that one is not able to follow the separate motions. Fancy Weaves. — There are many variations of the fundamental plan, or plain weave, possible, but the two ideas upon which these variations are based are (1) an increase in the number of systems of threads involved, and (2) a lengthening of the "floats." A "float" is that portion of any thread of one system that crosses another thread or other threads of the second system. In the plain weave the floats are only one thread-diameter in length because the threads of this weave are carried over only one thread at a time (see Fig. 10). Where the threads are carried over two or more threads in succession the floats are two or more thread-diameters in length (see Fig. 11). The advantage of longer floats is an increased reflection of light and a consequent increase of gloss. This advantage is desirable in itself as increasing the esthetic value of the fabric, but by means of it another advantage is obtained, that is, the possibility of producing "patterns" in fabric in solid colors by carrying the floats in opposite directions in adjacent areas. A comparison of a plain weave cloth with a damask pattern illustrates the advantages to be gained by the use of the long floats. But with the advantages gained by the use of long floats and by the use of several systems of threads come many disadvantages as the result of the law of compensation that governs this world and exacts from us pay for everything. This law and its rule are evidenced in fabrics by a definite relation between the fibers employed, the degree of spin- ning, the type of weave and the strength of the fabric; this relation is not to be ignored in our consideration of claims 36 / leaves Fig. 12. Uneven Distribution of W.arp and Filling. The heavy white threads are of cotton and represent the filling of a so-called silk shirt. The fine threads are silk and are the warp threads. Such a great difference in weight of the two systems is undesirable from the standpoint of utility, but enables the manufacturer to offer the fabric at a much lower price than if enough silk were used to make the fabric strong. 37 The Conservation of Textiles for damage. By all rights the buyer should be cognizant of this law of compensation and its application to fabrics, and should know what type of cloth to purchase and how much wear to expect of it when applied to different uses. This is not the case, however, and, since it is not, the laundryowner must acquire the knowledge, in order to protect himself and incidentally to assist in the move toward more general enlightenment. If the laundry- owner is able to accompany his decision of a claim with a clear simple explanation of the limits of his responsibility and to point out without prejudice where the responsi- bility really lies, the average patron will welcome the information and make use of it in the future. The Ideal Fabric. — In considering the several factors that combine to produce the "quality" of a fabric, first attention goes most logically to the individual threads involved. These may be heavy or fine, strong or weak, tightly spun or loosly spun, but in combination as the warp and filling of a fabric they should be of equal quality to meet ideal conditions. Ideal conditions are threads that are composed of fibers of good length (standard of length varies for each fiber, as indicated in Chapter II) that have been well spun to give a smooth, even thread of uniform strength; such well prepared threads combine so that the warp and filling are of equal size and strength,* occur in equal numbers per inch and are interlocked to the greatest degree. These conditions guarantee a fabric of highest tensile strength, greatest firmness and best wearing qualities, that can be obtained with the v/eight of thread chosen. They do not, however, guarantee a fabric of greatest beauty, as judged by our modern standards. Beauty"and decorativeness are acquired at the sacrifice of a portion of one or all of the qualities previously mentioned. *It is seldom found expedient to follow the specifications for the ideal fabric to the point of choosing the warp and the filling threads of equal weight. On account of the strain exerted on the warp that the filling is not called upon to stand, the warp threads are usually a little stronger than the filling. 38 Weaves Variations from the "Ideal." — The ideal cloth may be made of heavy or of fine threads, the difiference showing in the weight and strength of the fabric; these quaUties being uniform for each piece. Variations of this ideal cloth are produced by combining loosely spun warp with tightly spun filling (or vice versa) ; by combining heavy warp with fine filling; by introducing a heavy thread at given intervals to produce a corded effect, or by omitting one occasionally to obtain the effect of a "drawn" thread; by floating the threads more than one thread-diameter; by decreasing the number of threads per inch in one system without a corresponding decrease in the other sys- tem; or by a combination of two or more of these methods to produce the more extreme "patterns." Each variation exacts its compensation for added beauty by causing a reduction of the tensile strength or of the firmness and consequently of the wearing qualities of the fabric, the reduction being proportional to the degree of variation. The loss in wearing qualities is brought about by the actual reduction of the strength of the individual threads, as in the case of loosely spun threads or of fine threads; by the greater friction exerted by one thread on a second than the second is able to return, as in a combination of heavy and fine threads or of tight spun and loosely spun threads; by the increased friction that a long float must stand as a consequence of its more exposed position; and by the loss of unity where threads are omitted. Loose Spinning. — Some illustrations of the consequen- ces of these variations have been received at the authors' laboratory from time to time and some interesting results have been gathered in the form of photographs. Fig. 12 is an extreme example of the use of a heavy filling and a weak warp, and was taken from a half silk shirt which had failed to stand careful hand laundering. The warp is of real silk, which has previously been declared to be the 39 The Conservation of Textiles ... IM Fig. 13. A Low Priced Silk Collar. This grade of collar, that sold at a very popular price, ha.s been found to fail in laundering much too soon for the amount of wear received. Examination showed it to be a cotton, real-silk combination, but the silk represented only 20 per cent, of the weight of the fabric. 40 Weaves Fig. 14. Photomicrograph ok Fig. 13. This enlargement of a portion of Fig. 13 shows the manner in which the manufacturer was able to make 20 per cent, of silk cover 80 per cent, of cotton to give a high luster. The silk is absolutely unspun so that it can be spread over as much surface as possible. The silk fibers as they pass over the cotton warp threads, are placed in a position of greatest exposure to friction and are soon worn through. 41 The Conservation of Textiles strongest natural fiber, but in this case the natural strength was sacrificed in an endeavor to save silk by omitting the throwing* so that a given amount of silk would cover a greater surface. By carrying the silk fibers parallel over the heavy cotton filling threads more surface is covered and a greater luster is obtained than would be possible with any other treatment of the same amount of silk. The advantage gained in this direction was entirely counter- balanced, however, by the great loss in the wearing qualities of the material. Had the same amount of cotton and silk been combined so that the tensile strength of the two systems and the friction of one system on the other would be more nearly equal, a fabric of greater strength, but of less sheen, would have been produced. A similar combination of silk and cotton, which was made for appearance rather than for wear, is illustrated in Figs. 13 and 14. The same condition of unthrown fibers, in this case of artificial silk filling and cotton warp, occurred in another shirt submitted at about the same time. The condition of this fabric is shown in Fig. 15. Such deliberate sacri- fice of quality for appearance suggests intention on the part of the manufacturer of deceiving the public. It may, however, be the natural result of a demand on the part of the public for a fabric of high luster and silky appearance at an extremely low price. But, whatever the cause, if the consumer can not or will not see that no gain is made without an equal or often greater accompanying loss, he must continue to see his clothes drop to pieces through wear or laundering and should receive no recompense from the blameless laundryman. Long Floats. — Figs. 16 and 17 are illustrative of one of the disadvantages that accompany the long float. Fig. 16 *Silk is "thrown," or only slightly spun, together when fibers of good quality and length are used. The short lengths are "spun," to make the sewing and embroidery threads. 42 Weaves Fig. 15. Photomicrograph of a Shirt Fabric. This photo- micrograph shows a portion of an artificial silic and cotton shirt. This fabric is weak for the same reason that the fabric pictured in Fig. 12 is weak, but the difference in weight between the warp and filling of this fabric is not so great as in the other cas2. 43 The Conservation of Textiles % *i Fig. 16. Photomicrogr.\ph Showing Long Floats. The area pictured here shows floats of varying length, some being as long as 18 thread-diameters. Such great length exposes the threads to undue friction that causes the fabric to fail much sooner than is economically desirable. 44 J V eaves ^ ipi. i f. i Fig. 17. DisPL.vcED Floats. The reason for presenting this photomicrograph is to demonstrate the looseness of a fabric in which long floats occur and the ease with which they are displaced during wear. 45 The Conservation of Textiles Fig. 18. Damask Pattern in Cotton. This is a portion of the fabric that furnished the photomicrographs of Figures 16 and 17. The long floats occurred in the floral pattern, which was the part of the fabric that first showed the effects of wear. 46 Weaves Fig. 19. A Worn Portion of the F"abric Pictured in Fig. 18. When this damage appeared in a pair of pajamas, the owner claimed abuse by the laundry. The series of photographs, Figures 16, 17 and 18, demonstrates why the launderer was justified in refusing payment of this claim on the grounds that the fabric had not been wisely chosen for the wear it was to receive. 47 The Conservation of Textiles shows a portion of a fabric that contains some unusually long floats, some of which were 18 thread-diameters or one- fourth inch in length. Fig. 17 shows the looseness of weave that results when so many long floats occur at one place, and the distance that each float can "slip" from its posi- tion. This slipping was accompanied by such friction that the fabric gave way at the spots where these floats occurred, while the remainder of the fabric, which was of plain weave, retained its original strength. Fig. 18 is a photograph of a portion of this fabric that showed no damages but pos- sessed all the inherent weaknesses described and waited only for the requisite friction or strain to demonstrate them. Fig. 19 is a photograph of an area that failed in several places, and showed the damages to follow the design. An interesting and illuminating observation to be made in con- nection with these photographs is that this material was made up into pajamas. The wear to which it was subjected in this role was out of all proportion to the wear that it could stand. In such a case, it is difficult to decide whether the manufacturer of the cloth, the designer of the garment or the purchaser is to be blamed for the failure of the fabric. This type of failure is aggravated when the fabric is made from all cotton fibers. In this connection it is well to remember that the threads used in fabrics are composed of numerous short lengths twisted together. The action of friction is, therefore, less a matter of wearing through the individual fibers than it is a matter of rubbing these fibers apart. In linen fabrics the fibers are comparatively long furnishing fewer fiber ends per inch of finished thread and reducing the possibility of their being rubbed apart during use. Cotton fibers are, on the contrary, short and many more are included in an inch of spun thread. Therefore, when a portion of a cotton thread is exposed to extra fric- tion, the time required to sever the thread is greatly re- duced. Figs. 20 and 21 are photographs of failures in cot- ton damask that are to be accounted for only by the fact 48 JVeaves Fig. 20. K.MLUKK IN Table Linen Due to the Use of Short Fibers in Long Floats. When short fibers are used in spun threads, the number of fiber ends per inch is greater than when long fibers are used. By weaving short fibers in a plain weave pattern the greatest wearirlg quality is obtained from them. Long floats permit the fiber ends to be rubbed apart, eventually causing a break in the thread. 49 The Conservation of Textiles Fig. 21. Failure in Tablecloth. This failure is also due to the use of short fibers and is explained under Fig. 20. It is given a special place in this book, however, because it is typical of the failures that occur along the border of cotton damasks. 50 Weaves that the floats were too long in comparison to the length of the fibers that were used in preparing the fabric. Fig. 22 illustrates the ease with which the "satin" weave slips out of place. This is a common occurrence in shirts that are made with stripes produced by this method of weaving, and results from the looseness that is incident to the "over four-under one" method of combining the warp and the filling. Where the filling is of cotton this slipping does not occur quite so readily because the surface of the filling threads ofTer a higher friction to the silk threads due to their rougher finish. Similar slipping will occur even in a plain weave, all-silk fabric wherein the number of filling threads per inch is too low to produce a firm fabric. Such slipping is not a true damage, since no threads are broken or even stretched during the change of position; it can often be remedied by gently rubbing the fabric between the fingers, all motions being planned to return the indi- vidual threads to their original positions. Short Fibers and Loose Spinning. — Another example of weakness due to the method of weaving, this time oc- curring in a woolen fabric, presents itself in the form of a pair of blankets. The process of laundering, which the laundryowner claimed was carefully conducted along approved methods (this claim was fully substantiated by the soft, unfelted appearance of the blankets), had reduced the blankets to shreds, the damaged portions showing the filling gone and only the warp remaining, as illustrated by Fig. 23. Close examination showed that the exhibit had presented an appearance of great weight and softness to someone not acquainted with the tricks of the weaving trade. To the initiated, however, it appeared as it actually was, — a fabric composed of a three-ply cotton thread, with which enough wool had been spun to partially cover its identity, as the warp and a loosely spun woolen thread as the filling. Woolen is here used in the light of the expla- 51 The Conservation of Textiles Fig. 22. The Satin Stitch in Silk F.vbrics. This photomicro- graph illustrates a source of wear and a type of damage that is quite common in silk fabrics that have satin stripes in them. The extremely smooth surface of the silk threads offer no great resistance to each other so that they slip out of position with the application of very little force. 52 IV eaves nation given in a foregoing chapter tiiat woolen yarn is made of the shorter fibers. Further than this the carding process which raises the nap and gives the blanket its soft, fuzzy appearance had of necessity reduced the actual weight of the filling yarn so that it was extremely weak. The expression "of necessity" is used advisedly since the amount of wool contained in the warp was so small as to be practically negligible. The appearance of the true fabric of the blankets is shown in Fig. 24, in which the nap has been clipped to expose the details of structure. Such a procedure is denied the prospective purchaser, but there are ways of examining a fabric that will furnish conclusive evidence, without injury to the article, which everyone should apply. "Pile" Fabrics. — "Terry" or loop-pile fabrics offer an- other possibility for damage (see Fig. 25), that is quite often said to be the launderer's fault by the uninformed patron. The bath towel is the one member of this class of fabrics that we are most often asked to renovate, but other members that are handled less often are bath mats, counter- panes and other piled fabrics of domestic application. These fabrics are produced from two separate systems of warp threads, (a) the ground warp threads that go to form the true fabric, and (b) the pile warp threads that form the loops on the surface of the fabric which are placed on sepa- rate warp beams. The usual method of weaving employs the ground and pile warp in equal proportions, arranged in the loom alternately or in alternate pairs. In each case the final result is the same to all practical purposes. Dur- ing weaving the ground warp is held tight, but the pile warp is permitted to be quite loose so that it may be looped up to form the pile with great ease. Terry fabrics are said to be one, three, four, five or six-thread terry fabrics, ac-. cording to the number of filling threads that are inserted for each cross row of loops. 53 The Conservation of Textiles Fig. 23. Failure in Blanket. This blanket, claimed to be worth S12.00 at the time when this amount of money should have bought a really good blanket, was laundered after a season's use by a power laundry with the result that it was reduced to shreads as illus- trated in this picture. Examination showed the blame for this condition to fall to the construction of the fabric rather than to the laundering. Fig. 24 displays the details of this fabric. 54 J V eaves A <? «*y Fig. 24. Photomicrograph of Failure in Blanket. In order to obtain this photograph the nap was clipped from a portion of the blanket that had not been damaged. This made it possible to observe the condition of the threads that had been used in weaving the fabric. The warp, which runs across the page, was found to be a well spun, three-ply, cotton thread with a small amount of wool spun with it to mask its identity. The filling was a loosely spun wool thread made from short fibers. The nap had been combed from this portion of the fabric and had left a much weakened filling which had broken under the weight of the whole fabric when wet. The diagram in the upper right hand corner shows the degree of twisting that the two systems of threads had been given. The warp and 'filling threads were super- imposed along the line A-B, and the lines C-D and C-E were obtained by paralleling the course of the fibers of the threads. The angle BCD represents the degree of twist in the filling; the angle BCE, the degree of twist in the warp. :)0 The Conservation of Textiles Fig. 26 represents a Terry fabric of the simplest con- struction possible. Here the ground and pile warp threads are alternated and are woven with the filling in the plain weave manner. The result is that a minimum of contact be- tween the pile warp and the ground fabric occurs. When the ground fabric is more closely beaten up than that which furnished this figure, the pile threads are held a little more closely, but this type of weaving is not designed to pro- duce a good firm Terry fabric; it is used only in the very poorest grade of toweling. The better grades of toweling are woven on the three, four, five or six-thread plan, of which the 6-thread plan is the best because of the increased contact between the pile warp and the ground fabric. The six-thread plan is, indeed, excellent because in it the pile warp actually is woven into the ground fabric, not merely looped into it. Figs. 27 and 28 present samples of the three-thread Terry fabric. The plan necessitates the individual threads traveling "over two-under one." Consecutive ground threads weave in contrary manner to each other as do consecutive pile threads; that is, while one thread (of ground or pile warp) is going over two-under one, its next neighbor is going under two-over one. In this way the ground fabric is regularly woven and the pile threads alternate in looping on the face and the. back of the fabric, producing a double piled cloth. Variations of the arrangement of the warp threads — that is, alternating them singly or in groups — make differences in the desirability of the finished fabric. Fig. 27 is arranged so that a pair of pile warp threadsalter- nate with a single ground warp thread, making the pile loops of double threads instead of single as in Fig. 28, where the ground and pile warp threads alternate singly. Fig. 29 shows even a greater grouping of pile warp than does either of the other two illustrations. Here the pile warp occurs in groups of six which are placed with the 56 Weaves 1 ^^^R??!^ i 1 1 I 1 ■ ■ ^HB^ . N 1 ^ H H 1 ^ - li 1 ^^^K ^ <••," f '9 ^^^^B> *■ -^ if tt'^H^B ■' *l J- 1 Fig. 25. Typical F.mlure of Bath Toweling. Loops of the pile are caught and the pile warp is pulled out for some distance, giving long threads that becoinc intertwined and knotted on the surface of the towel as illustrated, 57 The Conservation of Textiles ■ •iwtiKi,; '•Mifi.i;,; * '■- IIH»I,,, <>' •■ ■ >t iikI . 1 1*1 " .,.. ']^^\]v^h c ""'.r,',',',v ,'i'i'.i'n'>> <I4I Fig. 26. Poor Grade Bath Toweling. (Terry Fabric.) The background weave is the simple plain weave. This is a very poor foundation for pile fabrics at the very best, but when it is as loosely woven as in this exhibit, the result is that the pile "pulls" and the towel assumes the appearance of Fig. 25. The pile warp threads have been removed so that their relation to the whole fabric can be observed. 58 Weaves Fig. 27. Medium Grade of Terry Fabric. This towel was submitted for examination to the Department of Chemical Engineer- ing because of damages similar to that shown in Fig. 25. The reason for its appearance is that it is woven on what is known as the "three- pick" Terry pattern. In this pattern the warp threads are carried over two-under one, with the result that the pile loops are held in place by single filling threads only. A good firm pile can be obtained by weaving the pile warp threads into the ground fabric for a distance of three or four filling threads. This plan is followed in the true Turkish or Osman toweling. 59 The Conservation of Textiles ht Fig. 28. "Martex" Toweling. This fabric was purchased for the purpose of comparing a "Marte.x" fabric, said by the retail merchant to be the best grade of bath toweling, with the fabric shown in Fig. 27. Although the fabric as a whole was finer in this sample, the same method of weaving had been used to produce the two. 60 IVeai'es Fig. 29. A V'erv Good Type of Three-pick Terry Fabric. This fabric was also purchased to compare with that of Fig. 27. The ground fabric was found to be woYen on the same three-pick plan, but the distribution of the pile warp threads ditTered. In this exhibit they are introduced in groups of six, at intervals of six ground warp threads. This results in ridges of pile that parallel the warp. "Pulling" is avoided by the fact that the six loops become so entangled that they form a knot, making withdrawal impossible. 61 The Conservation of Textiles ground warp in the following oider: The face-pile waip threads, one ground warp thread; the back-pile warp threads, four ground warp threads. This causes the pile to occur in ridges that run lengthwise of the fabric. An advantage that is gained in this grouping of six-pile warp threads together is that the six loops formed at each point become entangled so that withdrawal of the thread is impossible. The beauty of the finished fabric is greatest in Figs. 27 and 28, but the utility and length of life of Fig. 29 are very much the greatest. Weaving Flaws. — Knots or heavy threads constitute another fault that occurs quite frequently in the cheaper fabrics or "seconds," ofifering a starting point for very serious damages. A knot may result from a break that has occurred in the weaving process and has been repaired by tying the two ends together; oi it may result from an entanglement of the yarn. Whatever the cause, it will stand out on the surface of the fabric (as in Fig. 30) and receive a great deal more hard usage than the threads about it in their less prominent positions. Eventually it will be rubbed off accidentally or picked off deliberately; in which case it leaves behind it a broken thread. One broken thread does not sound like a great misfortune but it upsets the nice balance of stress that has obtained in the fabric and the neighboring threads are forced to bear a greater burden in consequence. The final result is an ever enlarging number of broken threads which present the appearance of Fig. 31. It always happens that these broken threads are confined for some time to one system, paralleling the thread that originally con- tained the knot and first gave way. Fig. 32 is an enlarge- ment of one of the small holes to be seen in Fig. 31; it shows one of the threads of the other system broken, illustrating the beginning of enlargement in the remaining direction. 62 Weaves Fig. 30. Common Flaw in Fabrics. Knots similar to the one shown in this photograph are the cause of many damages that appear in fabrics. When this knot is rubbed or picked off a thread is broken and a hole is started. 63 The Conservation of Textiles Fig. 31. Typical Wear in Sheeting. Such holes as these will result from the. removal of knots from the surface of a fabric. 64 Weaves Fig. 32. Photomicrogr.vph of Damage Exhibited in Fig. 31. This photomicrograph illustrates the development of a hole from a small inception like that suggested under Fig. 30. The damage proceeded for some time in one system only, but finally began to affect the second system. This photograph shows the first break in the second system in the development of this hole. 65 The Conservation of Textiles Heavy threads — that is, threads that are spun un- evenly so that occasionally a thickened, loosely-spun length is encountered — (see Fig. Z2) — are seen very often in the ess expensive, coarser table linens. One of the chief 'ndoor sports of the diner (of which he is quite unconscious) is to pull out these heavy portions as he sits at the table and converses. This move is, it is judged, actuated by a desire to improve the looks of the cloth, to change it from a coarse, uneven thing to a fine, even piece of workmanship. But, alas, this subconscious urge toward improvement merely places the opening wedge of destruction. The damage that results from the broken thread is the same in a table cover as in a bed sheet, which is the fabric pictured in Fig. 31. Figures 34 and 35 present another type of flaw met with in fabrics and the effect that washing has exerted upon it. Fig. 34 shows a weaving defect in a handker- chief, after the sizing has been removed. Just how serious this defect was, is demonstrated by Fig. 35, taken after the handkerchief had been laundered eleven times. This handkerchief, having been bought for experimental pur- poses only, was not used between washings; had it received normal wear between trips to the laundry the efifect of laundering would have been exaggerated. Fig. 36 illustrates the beginning stages of a damage resulting from another very common defect in damask patterns, both cotton and linen; that is, long floats that are unconnected with the development of the pattern. The tablecloth that furnished this illustration was in very good condition, apparently in every place except the spot in Fig. 36 that appeared as a "thin" spot. Examination disclosed the ends of threads on either side of this thin spot, which indicated broken threads. Very close ex- amination established the fact that the "thin" effect was produced by the removal of those threads that corre- 66 Weaves Fig. 33. The "Heavy Thread" Flaw in Fabrics. The heavy thread that occurs in fabrics as a result of uneven spinning and which is unrelated to the development of the pattern or design is a flaw and, as such, is unsightly and undesirable. It may cause damage by wear- ing out the finer threads which cross it or by being pulled out of the fabric itself, causing a break therein. 67 The Conservation of Textiles Handkerchief sold as a Second Note defect after removal of sizing Fig. 34. A Tvpic.vL Weaving Flaw. A flaw such as is pictured in this figure places the fabric bearing it among the "seconds." These flaws are often small and hidden by the sizing, but they always con- stitute a weak spot that will give way before any other portion of the fabric does. What happens to such flaws in the laundering is shown in Fig 35. 68 Weaves Handkerchief sold as a Second Appearance of defect after eleven washings Fig. 35. The Effect of Laundering on a Weaving Flaw. The fabric pictured in Fig. 34 was purchased for the purpose of de- termining the effect of laundering on weaving defects. After being laundered eleven times, without being used between trips through the laundry, the defect had assumed the appearance shown above. Had the handkerchief received customary usage between launderings, the damage would have enlarged with greater rapidity. 69 The Conservation of Textiles Fig. 36. Damaged Table Linen. This damage showed up as a "thin" spot. Examination demonstrated this thinness to result from the fact that every fifth thread had been removed for a distance of half an inch. The reason that these threads had been removed proved to be that they had never been incorporated into the fabric at the spot, but had been "floated" for a space. The thread at the upper part of the spot is the last one to withstand the wear and connects the former condition of this area of fabric with its present condition. 70 Weaves l«ii||RPRPI^iPpni|WPPPTiPf^^ ' A. .i f- * ' ' ' ' Fig. 37. Damaged Table Linen. This is a smaller "thin" spot that occurred in the same cloth with that shown in Fig. 36. The thin spot in this photograph is not such important data as are the long floats that occur in several areas about it. This evidence substantiated the story suggested by the one remaining float in Fig. 36. 71 The Conservation of Textiles sponded to the broken ends, which allowed more light to filter through the cloth. The reason why these threads were broken and why none of the others was, is explained by the one thread that remains at the upper part of the spot. It is nearly worn through by friction but it still remains as a continuous thread and offers proof of the conclusion that originally these threads had been "floated" for a distance of one-third inch or 32 thread diameters, instead of covering that distance in the regular "over-four- under-one" stitch used in the cloth. This mistake is quite patently due to a moment of poor operation on the part of the loom. Fig. 37 shows another spot that was found in support of this conclusion. The thin spot itself furnished very little contributing evidence, but the surrounding areas of long unnecessary floats were just the proof that was most desired. Flaws of this type are watched for as the fabric is woven and material that contains them is considered of inferior quality and classed as "seconds." Legitimately the "seconds" do not command as high a price as "firsts," but the dressing that is given damasks is of a type to render these flaws practically unnoticeable. This state- ment is not meant to imply that the manufacturer de- liberately covers them up. It merely states that they are covered up and suggests that this is done by a process that we demand to be given the fabrics we purchase, and that it may be an aid to dishonest selling or indifTerent pur- chasing. Fig. 38 represents a type of damage that is, at first glance, hard to recognize as the result of improper weaving. This type of damage can occur in any grade of fabric and is not dependent upon the length or kind of fiber used, the degree of spinning, the weight of fabric produced, or any other of the faults that have been found to be due to the intimate parts of the fabric itself. Instead, the fault lies 72 Weaves mtm Fig. 38. Shrink.\ge in Table Linen. The shrinkage is confined in this exhibit to a group of warp threads near the selvedge. Such localized damage can not be regarded as the result of improper launder- ing even when one is ignorant of the real cause. The real cause is that the affected threads have been held under greater tension on the warp beam than the other warp threads have. This tension was continued during the finishing process until the sizing had dried and a straight fabric was insured. Laundering has merely removed this tension and has permitted the threads to assume their normal positions. 73 The Conservation of Textiles ^i '♦^T7 ^^'V^l^r "l^ ^f 3:i '3! Fig. 39. A "Scratch-up." The thread end appearing in this figure is one end of a warp thread that has broken during weaving. The original course of this thread is that taken across the page; after breaking, the thread end was carried across the fabric with the filling. Such a condition constitutes the damage known to the fabric manu- facturer as a "scratch-up." It will be seen that the affected warp thread has been removed beyond the point where the break occurred. 74 Weaves with the mechanical setting-up of the threads from which the fabric has been w^oven. The warp threads, indicated by the arrow, and which are several inches shorter than the others in the tablecloth, have shrunken because they had been held under greater tension than the unshrunken warp threads duiing the weaving process. When removed from the loom, the cloth was sized and finished so that they appeared as long as the whole cloth; but, on laundering, the strain that had been exerted on them was removed and they were permitted to resume their true proportions. This shrinkage occurs legitimately in all fabrics to a slight extent; but where it occurs to the extent demonstrated in the photograph under discussion, it is a condition that could have been avoided by the manufacturer and is, there- fore, his responsibility. Another fabric that has caused considerable worry for the launderer is the heavy cotton material called Bedford cord. This cloth is formed of cords or welts that lie side by side, parallel to the selvedge. These welts are made to stand out in relatively high relief by the employment of padding threads which are held in place by certain of the fillingthreads that are carried across behind them. The so- called damage that appears in this material occurs in the padding threads which loop out between the threads which pass behind them. Such a condition can not be avoided in a heavily loaded commercial wash wheel when a fabric of this type is being washed. Had the padding threads been backed by a true fabric, made like the facing, or in other words had the material been made "double-faced" by the introduction of extra warp threads to engage the filling threads that cross behind tKe padding, such a condition would have been impossible. Double-faced fabrics are, however, expensive; more expensive than the average person can afford for an everyday wash fabric. Therefore, the trouble with Bed' 75 The Conservation of Textiles Fig. 40. Towel Crash. This is a portion of a crash towel that appeared to be a good grade of unbleached linen crash. Seven hundred of these towels, owned by a linen supply company, were laundered be- fore distribution and failed to survive the process. The failure was con- fined to the filling threads which, on examination, proved to be made of paper stock. This material, when spun into threads, has the appear- ance of coarse linen and is quite strong when dry, but has practically no strength when wet. 76 Weaves ford cords will continue to occur unless the launderer changes the method used in handling this type of fabric. It is possible, and also advisable, to wash gar- ments made from Bedford cord by hand or in small vacuum-type washers wherein the mechanical rubbing is reduced to a minimum. Use of Poor Materials. — The damages so far discussed have been due to weaknesses in construction rather than to weaknesses of material. That weakness of material does occur, however, is evidenced by Figs. 40 and 41. Fig. 40 is a reproduction of what appears to be a good grade of crash. But 700 towels made from this material fell to pieces when laundered for the first time in preparation for distribution by a towel supply company. On examination the failures proved to be confined to the filling only. It was found that the warp was a good three-ply cotton thread that would stand heavy wear, but that the filling was noth- ing more than "cooked rope" or paper stock. Cooked rope is a term used by paper manufacturers to designate the material that results from cooking jute and hemp fibers in an alkaline bath. Jute and hemp fibers are strong but when untreated or "uncooked" are quite harsh. This characteristic is very evident in burlap, a fabric made from these untreated fibers, and is due to the large amount of resinous material present in the fibers. Cooking with an alkaline material removes the resin content, but in doing so it also reduces the strength of the fibers. There seems to be a definite relation between the amount of resin pres- ent and the strength of the fiber, because complete removal of this material leaves the fibers worthless as textile ma- terial. The weakness of the threads made from "cooked rope" or paper stock is not evident when they are dry but is immediately apparent in the presence of moisture. This is a phenomenon that has been made familiar to us all in our experiences with heavy wrapping papers. 77 The Conservation of Textiles Fig. 41. Failure in Artificial Silk. This shirt, in cotton warp and artificial silk filling, shows a failure in the sleeve only. No accom- panying tenderness appears in any other part of the shirt to suggest that the damage has occurred during laundering. The tenderness has been caused by mistreatment of the fabric while it was still in the piece at some time during the finishing process. The fact that the tenderness is confined to the left sleeve is explained as the result of using two pieces of cloth to cut the garment. One piece was good, the other was weak. 78 JVeaves Supplementing this towel exhibit and further exem- plifying the tendency of the manufacturers of textiles to- wards adulteration, is a bath rug. This rug, gieen and white and brown, in a rather pleasing mottled effect, was evidently bought for a cotton and wool mixture. Launder- ing, however, had reduced it to a sad state of disintegra- tion, the cause of which lay not in the laundry or in the laundering process but rather in the composition of the article itself, as discovered through a critical examination. Such examination demonstrated the fact that the warp was cotton, but that the filling which at first glance appeared to be composed of three-fourths and cotton one-fourth wool was really three-fourths twisted paper and one-fourth wool. The paper was of a soft unglazed grade which twisted readily into an even pliable rope, giving an effect quite similar to that of loosely spun cotton thread when woven into a fabric and examined only perfunctorily by the pur- chaser. It was entirely in keeping with the quality of this material that the wool content should be introduced in the form of loosely spun shoddy yarn. In a manner the per- spicacity exhibited by the manufacturer in taking this action is admirable — it can at least be said that no good wool was wasted in the production of these articles. Fig. 41 shows a shirt, of which only one sleeve is dam- aged, but which has been reduced to shreds in this portion during the laundering process. No other portion of the shirt is affected, not even the cuff on the damaged sleeve. Examination showed that the fabric of the garment that had remained whole was a good piece of material of cotton warp and artificial silk filling, and showed no evidence of chemical action. The damaged sleeve, on the contrary, although of similar construction (that is, of cotton warp and artificial silk filling, in the same pattern) showed evi- dence of chemical action. There is no method known to the chemist by which complete destruction of one definite 79 The Conservation of Textiles portion of a garment can be brought about without some small area of damage appearing in some other portion of the garment. In this case, had chemical action taken place after the garment had been assembled, traces of this action would have been found at the left shoulder and cufif. On the contrary, such evidence was confined completely to the fabric of the sleeve proper. The explanation for this dam- age is mistreatment of the yarn or of the pieces in the fac- tory. Two pieces of the same pattern have been used to make the garment, one being good and strong, and the other being poor and weak. In connection with this discussion it is well to state that the launderer may readily ascertain the extent of a damage of this type by testing the tensile strength of the fabric at various parts of the garment. This test can be made qualitatively by grasping the fabric firmly between the fore-finger and thumb of both hands and applying a steady strain to the threads by pulling the hands apart, keeping the threads straight during the process. Such a test was all that was needed to establish the fact that the damage in Fig. 41 was confined to the fabric of the left sleeve. The finish that is applied to a fabric by the manu- facturer before he permits it to be marketed is a factor that is of greatest importance to the consumer and the launderer. By means of the art of finishing, a fabric may be made to appear decidedly more desirable than it actually is. Cotton and linen fabrics are loaded with excess starch or even clay to give them weight and body; this weighting is removed in the first laundering and the impression is left with the owner of the article that the laundering process is hard on fabrics. Similar methods are used with silk fabrics, but in this type of fabric the weighting material is more often a salt of tin than any other compound. When excessive amounts of tin salts 80 IV eaves are used the threads lose their pHabiUty and break very quickly under the stress of wear. The heavy silk dresses of our grandmothers, that stood alone and wore a lifetime, are not duplicated today at popular prices. The reduction of the cost of silk fabrics means an equal reduction of the amount of silk used; the resultant loss of weight is made up in weighting material. Therefore, when a modern silk fabric splits, it is necessary to consider the original cost and the length and degree of service it has rendered before placing the blame for damage to the credit of any one influence. 81 CHAPTER III. Mechanical Sources of Damage. A PERUSAL of the preceding chapter might lead one to the beUef that all the troubles of the laundry were due to flaws in weaving and mistakes of the manufacturer and that claims could be readily disposed of by referring them to the manufacturer. Such is not the case, how- ever, because the user of the garment and the launderer must each come in for his share of the responsibility in the conservation of the handiwork of the textile producer. There are innumerable ways in which a garment may be damaged both by chemical and mechanical action, during use and laundering. This chapter will be confined to a discussion of the mechanical possibilities of damage. The chemical possibilites are considered later in detail in Chapter V (page 98). During wear many things are apt to occur of which the wearer may or may not be aware and which soon slip the memory. The use of pins in garments offers many opportunities for introducing rents; the clothing may be snagged on any roughness of furniture. Maybe the cloth is only caught by a few threads which are carefully re- moved before they are completely severed, but at the least estimation the damage done is great. It will require only a little strain, such as the weight of the fabric itself when wet, to break the weakened threads. Table linens are subject to cuts, which may occur from cutting bread at the table without using a bread board. (This is not, of course, the general practice, but it occurs in every home in moments of haste or carelessness.) Or the table knives may be used to draw line-pictures on 82 Mechanical Sources of Damage the soft padded surface of the dinner table, in which case the damage done may not be intense enough to show up immediately, but will always be present. Reckless chil- dren can cause damages in many ways that cannot be proved on countless occasions because of the absolute ignorance of the occurrence in which their elders remain. Another source of cuts in linens, this time in toilet towels, is razor blades. Many men who shave themselves use a towel to dry their razor blades on after the operation is over. In spite of careful manipulation, this use of a fabric exposes it to the danger of being cut, and in nine cases out of ten a cut of some degree is made. This practice has caused so much trouble in hotel linens that many hotels have begun to furnish special cloths for this purpose with the request that they be used in preference to the face towels. Figs. 42, 43, 44 and 45 illustrate the appearance of cuts in fabric both while still distinct and after they have been laundered. In Fig. 42 the cut has affected only one system of threads; Fig. 43 shows a diagonal cut that affects both warp and filling. After laundering. Fig. 42, will appear like Fig. 44, while Fig. 43 will appear like Fig. 45. It is quite apparent from even a casual obser- vation of these photographs that laundering merely accentuates this type of damage as it does in all cases of failures that are not corrected before delivery to the launderer. Bed springs, finished with sharp ends protruding and provided with no covering to protect them from dust or the bed clothes from being snagged; clothes chutes not as smooth of finish as is desirable; mice, having, as they do, free access to every part of the house ; these are only a few of the ways in which fabrics may receive the damage which only appears after the clothes have been returned from the laundry, and for which the user is to blame rather than the launderer or the laundry process. Care 83 The Conservation of Textiles K r • * • « ^..•^ »> f ■ * "%. IV .41 ^- -» iht-^i|r 1 • ^ Fig. 42. A Cut, Running Parallel to O^ne System of Threads. This photomicrograph shows the characteristics of a cut in which only one system of threads is implicated. The blunt, even ends of the threads are very typical of a damage that has resulted from the action of a sharp edge. 84 Mechanical Sources of Damage Fig. 43. A Diagonal Cut. The diagonal direction of this damage places it immediately in the class of mechanical damages. The blunt, clean cut ends of the threads modifies this general classification to the extent that the damage is specifically called a cut without hesitation. 85 The Conservation of Textiles taken on the part of the housewife to mend everything before sending thQ goods to a commercial plant would eliminate many of the complaints to which the launderer has to give audience. Another type of failure in garments that the laundry is usually unjustly blamed for results from poor tailoring methods. One of the most interesting cases of this type of damage ever submitted to the Department of Chemical Engineering for examination was a Palm Beach suit of a heavy grade of pongee in which the only damages ap- peared along the seams where the fabric had pulled out of the stitching in many places. Examination disclosed that the reason this pulling had occurred was that not sufficient seam allowance had been made. Pongee is easily frayed and if permanence is desired for seams made in it, the raw edges must be reinforced against fraying by binding or overcasting, or unusually big seam allowances must be made so that fraying will not endanger the seam. The suit under consideration, wherever pulling had occurred, showed seam allowances of one-fourth inch, with no attempt made to prevent fraying. In the laundry the possibilities of mechanical damage lie in the chance of buttons being caught in crevices of the cylinder of both the washing machine and the drying tumbler; of snagging on pins that have become caught in these machines; or on rough places in the wheels that result from unfinished cutting of the parts, or from wear of the wooden parts that has exposed sharp corners of metal parts; and by careless handling of the garments. Every one knows that carelessness is possible and probable under present labor conditions, in every plant; therefore, the greatest care on the part of the laundryowner to instill respect for fabrics into the individual employee and in- sistance on the observation of care in handling them is the only remedy for this group of damages, which is in truth, a group of avoidable damages. 86 Mechanical Sources of Damage *tf^0$^ Fig. 44. The Result of Laundering a Cut Affecting One System of Threads. The sharply characteristic features of a cut are no longer present in this photomicrograph which presents the same damage that appears in Fig. 46. The difference that occurs in the two figures is due to the fact that the fabric has been washed between photographs. 87 The Conservation of Textiles Fig. 45. The Result of Laundering a Diagonal Cut. This figure shows that laundering is nearly as effective in removing the characteristic features of a diagonal cut as it is in removing them from a cut that parallels the threads. It is often possible to hold such a spot to the light, however, and discover traces of its diagonal character that are still too evident to dispute. Mechanical Sources of Damage Mechanical damages of any source are characterized by features that are readily distinguished from the features of chemical damages in the laboratory and it is an easy task for one to learn these characteristic features and apply them to the cases of damage as they arise within the plant. If the cooperation for which we hope is extended by those who receive copies of this book, claims of this type may be equitably handled and an important objective of the laundrv industrv will have been attained. 89 CHAPTER IV. Colored Garments. The Relationship Between Dyes and Laundering* OOME familiarity with dyes, with their manufacture and ^ appUcation to fabrics, is of the utmost importance if launderers hope to handle colored garments successfully in the power laundry. Of course, a man may trust to luck and success may attend his efforts for a fair percentage of the time, but the day always comes when the combination presaging failure obtains and he is unable to prevent its occurrence because he does not recognize his danger. And one mistake or failure on the part of the launderer always overshadows in the mind of the public several successes; which is the way of human nature. No industry stands absolutely alone without some alliance to other industries, and the man who is well informed concerning all things related to his business will be able to realize his limitations in all directions and so avoid disaster. The expression "well informed" does not presuppose knowledge to the degree of expertness; it merely suggests such information as is necessary to an adequate appreciation of the application of all minor interests to one major interest. It is our endeavor to set forth in this chapter that portion of the vast subject of dyes and dyeing which is pertinent to the laundry industry. *The authors desire to acknowledge their indebtedness to Professor L. A. Olney, of the Lowell Textile School, and Dr. J. Merritt Matthews, of the Grasselli Chemical Com- pany, for help received in connection with this chapter; their ability to present the sub- ject of dyes in so simple and readable a manner is largely due to the clearness of per- ception gained through contact with these men. They are also indebted to the Ameri- can Dyes Institute, which, by its generous co-operation, made possible a criticism of this work before publication, thus ensuring accuracy as well as simplicity of statement. 90 Colored Garments There are two general types of dyes, viz., natural and artificial. Natural dyes are coloring materials that are produced by the natural functioning and growth of certain plants and animals and comprise the first dyes known to man. Artificial dyes are the result of increased chemical knowledge and can be manufactured with so much greater ease and accuracy to produce such a greater variety of colors that they have come to replace the natural dyes almost completely. There are two ways of classifying dyes, each of which is of interest and use to a certain group of men. The one that the chemists use, which is based upon the color-producing groups present in dyestuffs, is the one most recently developed and is admitted to be the better because it is more logical and can be applied to the present day mass of dyeing materials with less confusion; however, the use of this classification requires a very intimate knowledge of chemistry that can be acquired only by long and arduous study. The second classification, which is based upon the affinities of the dyes for and the methods of their application to animal and vegetable fibers, is much more intelligible to the layman, in spite of the fact that under this classification one dye may appear in more than one group, due to its capacity for being applied to different fibers under diff^erent conditions. This classification divides the dyestuffs according to their reactions and methods of application in the following manner : — Direct dyes. Mordant dyes. Vat dyes. Sulfur dyes. Aniline dyes. Direct Dyes. — The dyes of this class are taken out of the dye bath directly onto the fiber. According to the 91 The Conservation of Textiles character of the fiber being dyed the dye bath may be acid, alkaUne or neutral, but in any case the process of dyeing is brought about by the actual absorption of the dye by the fiber. These dyes are all "salts" in the chemical sense that they are products of chemical action between acid and alkali groups, but their nature is more complex than the ordinary salt with which we are familiar and many of these salts possess acid or alkaline radicals in addition to the ones that are involved in the reactions that produce the dyes. Those "salts" or dyes that possess an acid radical or group of this kind are called acid dyestuffs; those that possess an alkaline gioup are called basic dye- stuffs; those that possess neither an acid nor an alkaline group are called salt dyestuffs. The acid dyestuffs dye animal fibers directly from an acidified bath, forming direct chemical combinations with the fiber material. Silk and wool, being nitrogenous or protein materials, are characterized by both an acid and a basic group. The acid group of acid dyestuffs reacts with the basic group of the fibers just as the acid group of any simple acid reacts with the basic group of a simple alkali to form a salt. In the case of reaction between wool and a dyestuff, the product of reaction is insoluble in acid or neu- tral solutions, but in alkaline solutions the attraction between the dyestuff and the alkali of the bath is greater than the attraction between the dyestuff and the alkaline group of the fiber and a loosening of the dye results. This is true because the alkaline group of the fiber possesses less defi- nite alkaline characteristics than the alkaline group of the solution. Vegetable fibers do not possess the complexity of form that enables the animal fibers to produce insoluble compounds with the acid dyestuffs, so where washing is desirable this type of dye should not be chosen to dye cotton and linen fabrics; the use of acid dyestuffs on cotton explains why some of the cheaper fabrics loose their color on being placed into water. 92 Colored Garments The basic dyestuffs, possessing an alkaline group, react with the acid group of animal fibers to form a compound that is insoluble in neutral or alkaline baths but which are stripped from the fibers to some extent by treatment with an acid solution. This stripping is accomplished in the same manner as the stripping of an acid dyestuff with an alkaline solution, through the greater attraction of the acid of the solution for the dyestuff than the attraction of the acid radical of the fiber. This class of dyestuffs is also undesirable for dyeing vegetable fibers, only staining theni in a superficial manner that is corrected by simple treat- ment with water. The action of basic dyestuffs on cotton and silk is to be seen in the laundry quite often when the silk ribbons used as trimmings for lingerie all come out of the blueing bath irrevocably blue, w^hile the cotton fabric is still a pure snowy white. The salt dyestuff differs from the acid and basic dye- stuffs in that they dye a vegetable fiber direct from a neu- tral or alkaline solution. They also dye animal fibers in acid, neutral or alkaline solutions. The chemical reason for this difference in action toward vegetable fibers has not been satisfactorily determined as yet, so we who are mainly interested in the action need only accept the fact as it stands. Whether dyed upon animal or vegetable fibers this class of dye tends to "run" or "bleed" in slightly alkaline solutions. The whole class of direct dyes is unsatisfactory for use on wash goods, (where this term signifies cotton and linen fabrics), and will cause trouble in varying degrees for the launderer when encountered. There is some little conso- lation, however, in the fact that they are seldom used today on other than the cheapest fabrics, and such fabrics are still more seldom purchased by the class of people who patronize the power laundry. When they are encountered on cotton fabrics there is no method of laundering that will not affect them. It sometimes happens that the addition 93 The Conservation of Textiles of some salt to the water makes them less soluble, but the salts that are accessible are seldom of very great assistance in this manner and those salts that are of assistance are too hard to use to make them desirable for the launderer. When these dyes appear on wool or silk fabrics they should be laundered with neutral soap and warm water, the stand- ard process recommended by the Department of Chemical Engineering of the Laundr>'owners National Association. Therefore, if the recommendations of this Department are carried out the trouble experienced with this class of dyes will be reduced to a minimum. It has been stated earlier in this chapter that one dye- stuflf may be listed under more than one class-heading, according to the method of application used and the affin- ity that the dyestufif exhibits for the fiber under the existing conditions. Some of the dyestufifs, notably the basic dye- stuffs, that under the conditions described for direct dyes are not fast on the vegetable fibers become exceedingly fast and desirable when the fabric is given a "mordanting" treatment before dyeing. A mordant is a material that reacts with the dye to form an insoluble compound; when a fabric, with which no reaction occurs by direct dyeing, is first impregnated with a mordant and then treated with the dye, the insoluble compound is formed on the fabric. The mordants used in the application of these dyes are albumin; acids and acid salts, which include the iron, aluminum and chromium salts of the strong acids (hydro- chloric and sulfuric). The mordant used often has a de- cided effect on the color produced; for instance, alizerine gives a red color with aluminum mordant and a purple color with an iron mordant, while certain other red dyes are changed to dark blue or black by chromium salts. In cases where whole pieces of material are dyed a solid color the mordant may be applied in a "first bath," the dyestuff being applied separately; or through later developments, the mordant may be added to the dyebath itself and the 94 Colored Garments dyeing process completed in one operation. Printed calicos are prepared by printing the dyestuff on the fabric in the form of a thick paste, which is then steamed into the cloth. The cloth may be treated with a solution of the mordant either before or after this process. Several exhibits of striped shirts in which the color has faded only in spots and has been unaccompanied by tendering even in the slightest degree, have been examined in the laboratory of the authors. The cause of this uneven fading has been that the mordant has been unevenly applied to the printed fabric and only portions of the pattern have been properly "fixed" on the fibers. The salts used as mordants are all salts of strong acids and under certain conditions decompose to give the free acids which are capable of tendering the fabric. Proper dyeing methods recognize these possibilities and so far as possible eliminate the provocative conditions; it often hap- pens that even in the best of plants some slips will occur that will pass unnoticed, and a piece of cloth will be put on the market that is markedly defective. Figs. 51 and 52 demonstrate a case where this is true. The black threads used in this shirting cloth were dyed in the yarn and later woven into the fabric. The dyeing process, through im- proper or careless application, affected the tendering of these threads to the extent that the friction of wear alone was sufficient to remove them. Laundering proved fatal to all the tendered portions, as is shown in Fig. 52, which presents the condition of the fabric that suggested the damage claim against the laundry. Strange to relate the owner of this garment was a superintendent of a large textile mill. The mordant dyes, when properly applied, will give the launderer no trouble under ordinary conditions of laundering. They are, furthermore, as a rule hard to strip from the fabric, but certain ones are affected by oxidizing bleach and others by reducing bleach. The standard wash- 95 The Conservation of Textiles room foimulas of the Laundryowners National As- sociation do not recommend the use of bleach on colored fabrics, and the only occasion on which the launderer will be called upon to apply an oxidizing or reducing material to the mordant dyed cloth is when some fabric, dyed with one of the direct dyes, has "bled." In such cases it is well to test the action of the bleaching material on some portion of the fabric that is hidden from general observation. It is considered pertinent to introduce at this point a discussion of the pro- prietary compounds that are recommended as removing all stains. It should be recognized that the process of oxi- dation is the exact opposite to the process of reduction and that one compound cannot combine the advantages of both processes, and therefore can not be expected to per- form the impossible task of removing stains of every chem- ical type. Vat Dyes. — The vat dyes are a class of color materials that are themselves insoluble in water and to be applied to the fabrics have to be changed to a soluble form by the process of reduction. After the fabric is evenly treated with the soluble reduced form, it is exposed to the air so that reoxidation may take place, forming a coating of the insoluble color on the fibers themselves. This type of dye is fast to water, soap, alkalies and acids, and to light and bleaching, and cause no trouble to the launderer. Sulfur Dyes. — The sulfide or sulfur dyes are charac- terized by the ability to dye vegetable fibers direct from a bath containing sodium sulfide. The resulting colored fabrics are remarkably fast to washing and offer little cause for worry on the part of the launderer. The one exception to this statement is when the fabric is subjected to the action of javelle water, which acts on the dyestuffs even in weak solutions destroying their color. One source of annoyance to 96 Colored Garments the launderer that is pecuHar to this class of dyes is their tendency to oxidize with the formation of free sulfuric acid, which exerts a tendering effect on fibers of vegetable origin. The results of experimental work on these dyes, planned to obtain data that would be of assistance in over- coming this tendency, show that the sulfur content that is oxidizable to form free sulfuric acid is the sulfur upon which the dyeing powers of the compounds are dependent. Therefore, the sulfur dyes are used with all precautions in the eflfort to avoid the formation of sulfuric acid, but the dye can not be guaranteed to retain its original state. Printed striped shirtings that become tendered along the line of the stripes are frequently dyed with sulfur dyes. This is another type of damage that is not to be credited to the launderer. Aniline Dyes. — Anilineblack is given a special classifica- tion becauseof its great importance as adyestuff and because of a slightly different technicof application. It is a material that forms an insoluble compound on the surface of the fiber by an oxidation process, but the oxidation is not brought about by the simple method of exposing the treated fabric to the air. Instead, chemical reaction of compounds that do not enter into the final product of reaction except as occluded material, is necessary to the production of the oxygen that brings about the conversion of the aniline black to an insoluble compound. This color is the most difficultly removed of all dyes; in fact complete stripping from the fabric is impossible without detriment to the fabric. 97 CHAPTER V. Corrosive Materials. Damage to Fabrics Due to Chemical Action of Corrosive Materials. NO person in the laundry plant organization has a greater opportunity for the application of common sense, supported by broad information, to his task than has the claim adjuster. His mental ecjuipment should consist of an understanding of human nature, a knowledge of the funda- mentals of applied psychology, in addition to thorough information as to what normally goes on in the plant and as to what may, with a degree of probability, happen by accident to influence the quality of laundry service ren- dered by the establishment employing him. The laundry claim adjuster has an important function to perform, and it is the wish of this Department of Chemical Engineering to help him. It should be realized that in adjusting a claim for damage a great deal more than the money involved in the transaction is at stake. Good will is created and fostered by the proficiency of the entire laundry being kept on such a high plane that there will be the minimum num- ber of occasions for claims for damage. This high ideal may be approached, never quite realized, by good man- agement and careful co-operation between the various de- partments of the laundry. Next to this ideal condition as a means of removing prejudice and maintaining favor is the equitable adjustment of the claims that do inadvertently occur. Adjusting claims to please the patron regardless of the merits of the case on the fallacious policy that the patron is always right, tends only to accentuate the prejudice that exists against the power laundry and in many instances 98 Corrosive Materials encourages the dishonest patron to take advantage of the laundry. The claim adjuster can not be urged too strongly to exert his influence for careful examination of articles as they are received at the plant. When he once realizes the great amount of interesting and important data that can be lost between the time of arrival and the time of sorting for delivery he will begin to insist on finding every article that presents a possiblity of developing a damage while it still bears the deciding evidence. If the laundry is not at fault in a given case it is better for the industry in general, if not immediately, for the individual laundry to spend twenty dollars in time, thought and effort to convince the patron of the facts than to spend ten dollars to dispose of the case in the easier way by paying the claim. In addition to sacrificing a generous portion of good will, paying an unjust claim deprives the laundry of just that much resource which could be ex- pended in improving the quality of the service it has to sell. The efforts required in applying the suggestions herein presented should not be denied, therefore, on the score of time economy. Where it is considered advisable to satisfy the patron's ideas of just settlement, payment should be made only after the greatest effort has been put forth to convince the patron of the true facts in the case. One laundry- owner, with whom one of the authors has discussed this very point, handles matters of this kind in the following manner. When Mrs. X presents a claim for a damaged dresser scarf Mr. Laundryowner submits the exhibit to the Department of Chemical Engineering. Upon the receipt of a report that the tendered spot has resulted from the action of a certain medicine that had been spilled on the scarf, he presents the report to Mrs. X. If she is reluctant to accept this explanation and if he desires to retain her patronage, he pays her claim, making it clear to 99 The Conservation of Textiles Fig. 46. Corrosion by Acid. The damage exhibited in this photograph effects several layers of the fabric. The sheet, when re- ceived, was folded as it had been on coming from the flat work ironer, the damage extending through almost all the layers of the fabric. The definite relation of the several holes was enough evidence that the damage had occurred subsequent to folding in the laundrj'. The presence of sulfuric acid in the fabric supported this conclusion and indicated that the damage had occurred subsequent to the occasion of the last laundering. 100 Corrosive Materials Fig. 47. Corrosion by Acid. This photograph shows the dam- age exhibited in Fig. 46 as it appeared when the sheet was opened. In deciding where the responsibility for damage lies, the space relation of the damages is considered. If exhibits are received after they have been unfolded and folded along new creases, the first folding may be reconstructed. In many cases such procedure superimposes the damages and demonstrates the time of damage as subsequent to laundering. If no such relationship is observed the conclusion may be drawn that the damage occurred during use or at some other period when the article is not folded for storage. 101 The Conservation of Textiles her, however, that payment does not indicate that he accepts the responsibihty of the damage. He explains that he makes adjustment according to her ideas to show that it is not the money consideration, but the principle of fair dealing involved, that has influenced him to exert such effort to ascertain the true cause of damage. It has been shown in previous chapters how defective weaving or mechanical abuse may be the cause of a pre- mature failure of a fabric. Information accompanied by photographs of actual exhibits of chemical corrosion examined by the authors, helpful in arriving at the correct conclusions, is presented in this chapter. In cases of doubt the services of the Department of Chemical Engineer- ing are at the disposal of any member of the Laundry- owners National Association. In the laboratory it is a comparatively simple matter to decide quickly and definitely whether a certain textile failure has resulted from chemical or mechanical action. It is not always possible, however, to identify the corroding material. This limitation will be understood when one considers that the damage is not usually brought to the chemist's attention until after the fabric has been laundered and the corroding substance if soluble is thereby removed and the ev^idence which would lead to the identification is destroyed. Sometimes the corroding material is also a staining material and leaves unmistakable evidence for the chemist to employ. In the absence of chemical evi- dence as to the identity of the corroding material, recourse is had to the knowledge of common household and industrial materials that will produce tendering on textiles. Some of these, by way of suggestion, are presented later. There are also many facts to be observed in examining a corroded fabric which may be helpfully applied as cir- cumstantial evidence. Such facts pertain to the outline and relative location of the holes or tendered areas of the fabrics. (See Figures 46, 47, 48 49 and 50.) If the fabric 102 Corrosive Materials Fig. 48. Circular Corrosions. Another type of corrosion is illustrated here. In this case the corrosion has occurred in a ring, the enclosed and surrounding areas of fabric being less definitely damaged. Such ring damages can occur only by placing a bottle or similar vessel on the fabric without cleaning the outside to prevent the corrosive material from running down onto the fabric. This article was laundered between the time of damaging and the time of photographing; the fact that the damage was very limited in area is proved by the fact that the fabric immediately within the ring was strong enough to withstand laundering. 103 The Conservation of Textiles is of the same material, both in warp and filling, and the corroding material a thin fluid and the fabric dry or nearly so when the corrosive is acquired, the resulting hole or tendered area will be nearly circular in outline. If, on the other hand, the corroding material is of a pasty consis- tency, the hole or tendered area will have a position and shape corresponding to the original smear. That is to say, the application of a pasty corrosive material to a fabric will usually result in a tendered area of an irregular outline. If the holes, in case there are more than one in the piece, are located so that by folding the fabric in a certain way the holes may be superimposed so that each area will be concentric with the next underlying area, this fact of itself constitutes evidence that the corroding material was acquired while the fabric was folded in just the manner required to superimpose the holes. Such cases are of common occurrence and are illustrated by Figures 46 and 47. Evidence of this character has often been of assistance in determining at whose hands the damage was acquired, as for instance, in one case a bed sheet was folded just as it is usually folded when received from the flatwork ironer, and in another a table cloth was folded in a careless manner as it might have been folded w^hen removed soiled from the table. The first case indicated that the damage was done after the piece left the ironer and before it was used by the patron. The second case indicated that the damage was done after the article has been soiled, before it had the last laundering and not while the cloth was spread for use. Yet another table cloth showed numerous holes without any symmetrical relation to each other, indicat- ing that each hole was the result of an individual drop of the corrosive while the cloth was spread out, perhaps in course of use. When a fabric is composed of wool warp and cotton filling, or vice versa, and the cotton is tendered in limited 104 Corrosive Materials Fig. 49. CiRCUL.\R Corrosion. The article in Fig. 48 is shown folded in the position in which the damage occurred. This photograph has been taken of the article spread out so that the extent of the damage may be observed. The most definite damages occur in the upper left hand quarter of the picture, but breaks that indicate a circular tendered area are to be seen in both right hand quarters. 105 The Conservation of Textiles areas, while the wool is unchanged, wc know at once that the corroding material was an acid because acids have little effect on wool and a pronounced effect on cotton. Or, if in such a combination of warp and filling the wool has been tendered and the cotton unaffected, we would know that the tendering agent had been of a strong alkaline na- ture because alkalies dissolve wool and scarcely affect cot- ton. (See Figures 7, 8 and 9, Chapter I.) In a combination such as described for these two cases, linen may be substi- tuted for cotton and silk for wool, the effect of acid being the same on linen as on cotton and the effect of alkalies on silk the same as on wool. The manifestation of this sort of chemical tendering is a tendency to slitting and often one set of yarn disappears entirely leaving an appearance of drawn work as shown in figures 8 and 9. Chemical tendering, as is true of all mistreatments that work against the possibility of the greatest service of a fabric, may be due to the errors or mistakes of the manu- facturer, the user, or the launderer. F"ollowing a modifica- tion of a biblical injunction, we will first consider the motes that are in our own eyes and then proceed to the beams that obscure the correct vision of the other two agencies of responsibility. The Launderer. — If the tendering is in local spots or areas, the possibility that the regular laundering process is to be blamed is at once precluded, because it is impossi- ble to produce such results while the fabric is in a bath in the wheel. Contrary^ to a popularly expressed belief not even particles of undisintegrated bleaching powder from the bleach jar when applied in the wheel can make a ten- dered area that can be detected without the aid of careful laboratory tests. This statement must not be construed as a license for the use of improperly prepared bleach liquor, because the effect of such a liquor is accumulative and does in time shorten the life of a fabric. 106 Corrosive Materials Caustic soda or strong acids will not produce local ten- dered areas when applied to goods in the wheel. Progres- siv-e lessening of the tensile strength of fabrics may be caused by the use of these materials in the wheel, but the damage does not appear in the form of local well defined tendered areas or holes. It should be remembered in this connection that the findings of the authors indicate that the prudent laundryowner will keep caustic soda, sul- furic acid and sodium bisulfate out of his plant or, if special conditions require the use of caustic soda or sodium bisul- fate, the quantities should be carefully controlled and thorough rinsing be rigidly employed after their use. Sul- furic acid has no legitimate place in any laundry. While a consideration of these established facts shows that the source of a hole of chemical origin or a local tendered spot can not be attributed to the careless use of these materials in the wheel, complete exoneration of the washroom cannot be given on the basis of them alone. We will look further. It is a common fault to be observed in many laundries that garments of odd character, not sufficiently extensive in numbers to make a washing load for each lot, are thrown in a corner on the washroom fioor until there is an accumu- lation of volume to suit the washman's convenience or his fancy as to what constitutes a load of economically wash- able size. Pieces awaiting individual attention (hand wash) are likewise often thrown aside on the floor. When in such a location these goods are subject to dam^ige not only by the possibility of being ground between an iron castor wheel and the cement floor, but in many instances they receive spatterings from the bleach jar or sour container or from the washman's pail as he is transferring these reagents to the wheel. Sours other than acetic acid if spilled on cotton or linen and allowed to dry thereon will always produce tendering and in most cases holes. Bleach solution of the strength usually employed in the laundry for a stock solu- tion, if spilled on any fabric and allowed to concentrate by 107 The Conservation of Textiles normal evaporation, will usually produce tendering. Strong soda solutions if spilled on silk or wool and allowed to dry thereon will cause tendering. Eliminate these possibilities and the washroom may be cleared from all blame as far as holes caused by direct chemical action are concerned. The policy of using the washroom floor for the recep- tion of this class of goods cannot be too strongly condemned. In order to minimize these possibilities, bins should be pro- vided for the reception of the class of articles mentioned above which accumulate in the washroom for deferred attention, and the laundry management should insist upon the use of these bins for the purpose for which they were designed. Instances of holes being caused in fabrics during their sojourn in the laundry have come to our attention. These have sometimes resulted from the excessive use of stain removers and at other times from the failure to properly rinse the fabric after the treatment with these reagents. There exists also the possibility of the stain removing reagents being spilled on goods that are lying about on the table used for the stain removal treatment. If a special bench for this work is not available, care should be taken to see that no customers' goods are adjacent to the working place at the time. Of the stain removal materials prescribed in the chart (see insert in Chap. VI of this book, also L. N. A. charts), javelle water, potassium permanganate and oxalic acid, if not properly handled, are corrosive to cotton and linen. Javelle water should not be used on wool or silk. Potassium permanganate in concentrated solution, or if not properly rinsed after having been applied, is corrosive to silk and wool. The proprietary outfits of stain removing materials often contain solutions of hydrochloric and hydrofluoric acids. These are corrosive to cotton and linen if left to dry on the fabric. As a general proposition, fabrics should be 108 Corrosive Materials well rinsed with pure water after having been treated with any stain removing material. While the authors feel that the two possible sources of chemical damage just discussed, carelessness in the washroom and the improper manipulation of stain re- movers, are usually guarded against in most laundries, it is considered in place that emphasis should be laid on them as possible contingencies against which to be pro- vided. Carefulness in the plant will support the claim adjuster and give him an attitude of confidence which will be reflected to the patron. Notwitstanding the fact, as stated elsewhere, that less than five per cent, of all exhibits of all kinds of damage to fabrics that have been submitted to us have represented cases in which the laundry has been at fault, we feel that the strength of this statement should be taken with some reservation because of the high probability that we have to deal in these matters with only the more progressive plants. It is to the interest of every individual laundryowner that the faults of the entire industry should be eliminated as nearly as possible. In this alone lies an incentive for every member of the Laundryowners National Association to be a booster for the extension of the membership. The higher the standard of perfection attained by the average laundry, the better it will be for the industry ; by such accomplishment adver- tising becomes more eflfective, and existing prejudices become more easily displaced by the facts in the patron's mind. Holes of a chemical source or local tendered spots in fabrics may be compared to acute diseases of the human body, while conditions in the plant under which progressive depreciation of the tensile strength occurs, due to incorrect laundry methods, are not unlike chronic diseases of the human body. Instances of the first example are forced upon our attention while the causes of the second con- dition go unnoticed for a time, the cause persisting and 109 The Conservation of Textiles finally, unless remedied in time, leading to disastrous results. As an index of the presence of conditions causing the progressive but untimely failure of fabrics, every laundry should keep up the practice of continually running control pieces through with each typical class of work. A set of specially marked collars, for instance, should be kept continually going through the process and suitable record kept of the number of treatments they survive. Similar arrangements should be contriv-ed with big com- mercial flat work contracts. The procedure here sug- gested is not unduly expensive when properly organized, and is many times repaid by the feeling of confidence it affords the management if the laundry methods are good and, what is more important, by the help it offers in detecting violations of good practice when they do occur. The price of producing laundry service satisfactory as to appearance, sanitation and coordinate conservation of the life of the patron's goods, is eternal vigilance. THE wearer's responsibility. As the reader has already been led to see, the larger number of instances of damaged fabrics bearing holes or local tendered spots constitute those wherein the wearer or user is to blame for the exhibited condition. In these cases the patron must be, if possible, convinced of his responsibility. The claim adjuster must not only feel secure, yet withal open minded, in his conviction that the laundry is not at fault, but he should also be familiar with the possible sources of damage to which the owner may have submitted the fabric. If there is any doubt in the mind of the claim adjuster as to whether the damage is of chemical or mechanical source, he should first of all avail himself of the Laundryowners National Association's Department of Chemical Engineering. Having the infor- mation that the case represents a chemical corrosion, the following tables will be found useful. 110 Corrosive Materials TABLE No. 1. TABLE OF MATERIALS CORROSIVE TO FABRICS. Chemical Name. Acids Chloracetic Dichloracetic Trichloracetic Chromic Hydrochloric Common Name. Muriatic acid Nitric Oxalic Sulfuric Aqua fortis Oil of vitriol Use. Dentists and chiropodists. In dyeing, tanning, metal pol- ishes, veterinary practice and to some extent in medicine as an escharotic. Widely used in arts and indus- tries. In medicine, certain cases of dyspepsia. On farm and dairy in doing the Bab- cock test for butterfat in milk. In soldering. Many other uses. Often a household material. In manufacture of certain ex- plosives and dyes. In medical and veterinary practice in treating warts, malignant growths, etc. In metal polishes, stain re- movers, ink eradicators. To some extent in medicine. Common industrial material. In dilute form in many med- ical preparations. For gastro- indigestion, treatment of goiter. Exciting liquid in lead storage battery. Pick- ling of steel and iron in prepa- ration for galvanizing, tin plating and porcelain enam- eling. Many other uses. See next table Even most dilute solutions if allowed to dry on 111 The Conservation of Textiles TABLE No. 1— Continued. TABLE OF MATERIALS CORROSIVE TO FABRICS. Chemical Name. Common Name. Use. cotton and linen will produce tendering. Used in carbon- izing wool, a process whereby wool is freed of burrs, woody splinters and vegetable fibres. Alkalies Potassium hydroxide Caustic potash In making soap. Sodium Hydroxide Caustic soda In making soap. A solution of caustic soda is the exciting liquid in the nickel iron stor- age batteries which are popu- larly used on electric trucks. Salts — Aluminum chloride In treating petroleum. As a disinfectant. Aluminum nitrate In the leather industry. Aluminum sulfate Coagulant for treating and clarifying muddy water. In leather and paper indus- tries. In medicine and veter- inary practice as a powerful astringent, treating ulcers, en- larged tonsils, in treating na- sal tumors (polypi). Antimony trichloride In making patent leather, in bronzing metal for gun bar- rels, in blackening zinc sur- faces. A remedy for snake bites. In treating poisoned wounds. Copper sulfate Blue vitriol Exciting material in galvanic battery. As a preservative for wood. Treating water in swimming pools. In dyeing, manufacturing green and blue 112 Corrosive Materials TABLE No. 1.— Continued. TABLE OF MATERIALS CORROSIVE TO FABRICS. Chemical Name. Common Name. Iron chloride Ferric chloride solution, tincture of iron Iron nitrate Iron sulfate Copperas or green vitriol Lead nitrate Potassium aluminum Alum sulfate Use. pigment. In medical practice treating chronic diarrhea, and externally for treatment of callous wounds. Household for treating warts, hair dye, etc. Much used in veterinary practice. In photo-engraving. Mordant in dyeing. To be found in most accident kits to be used to stop hemorrhages (styptic). As an astringent in many gargles for sore throat. Often a constituent of tonics. Used by dentists, chiropodists, bar- bers and manicurists, to in- hibit bleeding. As mordant in dyeing and calico printing, for weighting silk and dyeing it black. Used to some extent in medi- cal and veterinary practice. In dyeing, tanning and pho- tography. In medicine as tonic. Externally in treating skin diseases. A common medicine given to chickens and hogs. Used in patent preparations for chapped hands and cracked lips. In dyeing and printing, in manufacturing dyes, paper, vegetable glues, marble ce- ment, porcelain cement and 113 The Conservation of Textiles TABLE No. 1.— Continued. TABLE OK MATERIALS CORROSIVE TO FABRICS. Chemical Name. Common Name. Potassium perman- ganate Sodium bisulfate Nitre cake Sodium bifluoride Stannic chloride Silver nitrate Zinc chloride Salt of tin Tin chloride Lunar caustic Use. in tanning. Common house- hold material. Dried or burnt alum is used by barbers as caustic and styptic. Bleaching and stain removing. A common household antisep- tic and prophylactic. A rem- edy for snake bites and anti- dote for other organic poisons. Common household material usually purchased under trade name, such as "sani-flush," used for cleansing porcelain sanitary fixtures. For pick- ling iron and steel preparatory to enameling, galvanizing or tin plating. Substitute for sulfuric acid. Has been used in drinking water to prevent typhoid fever in the field. Preservative, glass. For etching In dyeing, tanning and weighting silk. In photography, and in prepa- ration of other silver salts. In medicine, antiseptic in treat- ment of ulcers and morbid growths. In dental cement, preserva- tive for wood, flux for solder- ing, etching metals, and in oil refining. Used in proprie- tary preparations sold for checking excessive perspira- 114 Corrosive Materials TABLE No. 1.— Continued. TABLE OF MATERIALS CORROSIVE TO FABRICS. Chemical Name, Zinc sulfate Common Name. White vitriol Pharmaceuticals. Astringent and caustic mixture Antiseptic solution of pepsin Aqua Hydrogen dioxide Compjound infusion of rose Fluid extract of senega Fluid extract of taraxacum Hydrogen peroxide Use. tion under armpits. Used in treating scrofula, and other diseases. Antiseptic in medical and vet- erinary practice. Note: — Statements apply- ing to pharmaceutical prepa- rations must not be construed as being recommended by the authors. Corrosive components are zinc sulfate and copper sul- fate. Applied locally to ma- lignant growths. Corrosive component is hy- drochloric acid. Adminis- tered in some cases of indi- gestion. Corrosive component is sul- furic acid. Used as antisep- tic, prophylactic and deodor- ant. Corrosive component is sul- furic acid. Used in throat gargles and as a masking fla- vor and colorant in many preparations. Corrosive component to silk and wool is caustic potash. Used as a cathartic. Corrosive component to silk and wool is caustic soda. Used as cathartic. 115 The Conservation of Textiles TABLE No. 1.— Continued. TABLE OF MATERIALS CORROSIVE TO FABRICS. Chemical Name. Liquor cresoli compositus "Lysol" Common Name. A proprietary Use. Corrosive component to silk and' wool is caustic potash. Used as germicide. Similar to liquor cresoli com- positus. Liquor picis alkalinus Corrosive component is caus- tic potash. Used in treatment of eczema and other affections of the skin. Liquor acidi arsenosi Hydrochloric acid solution of arsenic Corrosive component is hy- drochloric acid. In intermit- tent fevers and in skin dis- eases. Liquor chlori com- Compound so- Corrosive components are free positus lution of chlorine chlorine and hydrochloric acid. Gargle. Liquor hydrargyri nitras Solution of mer- Corrosive component is nitric curie nitrate acid. In treating cancer, chancres, acne and boils. Liquor sodae chlorinatae Javelle water or Dakin-Carrol solution Corrosive component is sodi- um hypochlorite. Treatment of wounds. Used mostly in severe hospital cases. Some- times in treatment of sore throat. Refrigerants Fever drops Often contain one or more of the following acids: Sulfuric, nitric, phosphoric or hydro- chloric. Administered in cases of fever to reduce body tem- perature. 116 Corrosive Materials TABLE No. 1.— Continued. TABLE OF MATERIALS CORROSIVE TO FABRICS. Chemical Name. Common Natne. Use. Syrup of phosphate Corrosive component is iron iron, quinine and sulfate or iron chloride. Tonic strychnine commonly administered in convalescence. Other Preparations. Cleansers for porce- See under sodium bisulfate. lain toilet fixtures Corn and Wart These preparations usually removers contain one or more of the fol- lowing acids; trichloracetic, nitric or chromic. Cuticle acid Manicurist Corrosive component is oxalic preparation acid. Cuticle remover Trade name Corrosive component is caus- "Cutex" tic soda. Foot ease Tiz, Allen's Corrosive components are Foot Ease, etc. alum or zinc chloride or other astringent materials. Metal polishes Corrosive components are ox- alic acid, sodium bisulfate, ni- tric or sulfuric acids. Wrinkle cradicators Corrosive components are alum, zinc chloride, zinc sul- fate and other astringent salts. 117 The Conservation of Textiles TABLE No. 2. TABLE OF CORROSIVES ENCOUNTERED IN VARIOUS PROFESSIONS AND EMPLOYMENTS. Industry, Profession or Trade in Which Claimant is Engaged. Automobile manufacturing Barbers Canning factory. Coke (By-product recovery process) Chemical Industries Chemist Chiropodist Dentist Detinning plants Doctor (medical or veterinary) including hospital employees and nurses Corroding Materials Which Might Be Encountered. Sulfuric acid in storage batteries. Caus- tic soda in nickel iron batteries. Pick- ling baths for preparing metals for nickel plating, silver plating, etc. Antimony trichloride for making gun metal finish. Soldering fluxes, etc. Silver nitrate for antiseptic, alum and ferric chloride to inhibit bleeding. Fluxing materials for soldering, such as zinc chloride and hydrochloric acid. Sulfuric acid for the recovery of am- monium sulfate, also laboratory rea- gents. Products produced, all the mineral acids and the salts mentioned in pre- ceding table. Also the mineral acids are used in the manufacture of such acids as acetic, oxalic, formic and others of the organic acids. Many laboratory reagents. Trichloracetic acid, nitric acid and any of the styptics as ferric chloride, alum, etc. Trichloracetic acid for treating cases of pyorrhea, ferric chloride to inhibit bleeding, phenolsulfonic acid, sulfuric acid and silver nitrate, etc. Hydrochloric acid is used in dissolving tin and zinc from scrap metal. Any of the pharmaceuticals mentioned in previous table. 118 Corrosive Materials TABLE No. 2.— Continued. TABLE OF CORROSIVES ENCOUNTERED IN VARIOUS PROFESSIONS AND EMPLOYMENTS. Industry, Profession or Trade in Which Claimant is Engaged Dyeing, Textile finishing trades Electrical machinery Embalmer Engraving Explosives Farmer Fertilizer factory Flour mills Funeral Director Corroding Materials Which Might Be Encountered Bleaching materials, Mordants and stripping salts. Fluids for storage batteries, fluxing materials for soldering and brazing, also various metal polishing materials. Mercuric chloride, zinc chloride, zinc sulfate and aluminum sulfate are used in the embalming fluids. Sulfuric, nitric and hydrochloric acids and ferric chloride. Sulfuric and nitric acids. Medical and veterinary preparations, insecticides, etc. Sulfuric acid in making superphosphate. Sulfuric acid for treating fish scrap. Nitric acid as a source of nitric oxide fumes for bleaching, also bleaching powders and mineral acid as source of chlorine for bleaching flour. See Embalmer. Gas plant (artificial or coal gas) Sulfuric acid for reclaiming ammonium sulfate. Glass factory Glucose and starch Hotels Sulfuric and hydrofluoric acids for etching designs and finishing cut glass. Hydrochloric and sulfuric acids in making glucose and corn syrup. Ordinary household hazards. Strongly acid cleaning solutions for sanitary porcelain fixtures. Metal polishes. Caustic soda for the mechanical dish- 119 The Conservation of Textiles TABLE No. 2.— Continued. TABLE OF CORROSIVES ENCOUNTERED IN VARIOUS PROFESSIONS AND EMPLOYMENTS. Industry, Profession or Trade in Which Claimant is Engaged Iron and steel galvanizing, tin plating, porcelain enameling Leather Mortician Musical instruments Paper and wood pulp Petroleum Refineries Plumbers Photographers Restaurants Smelters Soap factories Soap Trade and Transportation Dis- pensers, in drug and other stores handling materials men- tioned in previous table, freight handlers. Undertaker Corroding Materials Which Might Be Encountered washer. The medicines and toilet ma- terials of the guests as listed in previous table. Sulfuric acid and sodium bisulfate for pickling. Corrosive mineral salts such as alumi- num nitrate, antimony trichloride, iron sulfate, chromic acid, etc. See Embalmer. Metal polishes, soldering fluxes, etc. Bleaching powders, caustic soda, and sodium bisulfate. Aluminum chloride, sulfuric and nitric acids, zinc chloride. Mineral acids and soldering fluxes. Iron sulfate, o.xalic acid, silver nitrate. Caustic soda for the mechanical dish- washer, metal polishes. Many of the smelters of the sulfide ores of lead, zinc and copper produce sulfuric acid as a by-product. Also in bleaching ores, chlorine, strong mineral acids, and sodium cyanide. Caustic soda and caustic potash. Also reagents in analytical laboratories. From spilling of corrosive materials from broken or leaking containers. See Embalming. 120 Corrosive Materials In table number one is presented a list of materials that are corrosive to fabrics. The materials placed in the first column are suggestive of those which may be en- countered in the industries, arts, medicine and in the house- hold. A comprehensive enumeration of all such materials would be beyond the scope of this book, but if the ones pre- sented are carefully studied an adequate idea of the clothes hazard in every day life must be impressed on the reader. The laundry salesman and claim adjuster, fortified with this information, will have a tremendous advantage in representing the interests of the industry. It is thought also that the data collected therein may be used to advan- tage in the preparation of dignified constructive publicity and advertising material. The second column gives the common name, while the third gives the uses of the ma- terials. Table number two presents an alphabetic arrangement of the various professions, trades and employments with the corrosive materials which constitute the clothes haz- ards in each particular one. Having found in any par- ticular case the employment or activities of the owner of the fabric under consideration, reference to this table will furnish suggestions as to the probable source of the corro- sion. In these included in the industrial occupations it should be pointed out that it is not the actual workers that are so frequently involved in laundry claims. Such per- sons are usually conscious of the clothes hazard of their occupation and therefore are less apt to entertain prejudice against the laundry in the event of a failure of the fabric in garments worn in their work. It is rather those persons who are engaged in these industries in supervisory capacity, or who only incidentally or occasionally are about the works where the corrosive materials are exposed, that the laundry claim adjuster has to deal. By such a person the corroding material will be acquired by accident, the ten- dering will develop slowly, not showing till after the laun- 121 The Conservation of Textiles Fig. 50. Corrosion' by Acid. This photograph shows a damage similar to that in Figs. 46 and 47. In this case methyl orange indi- cator has been put on the fabric to test for the presence of acid. The presence of acid is indicated by the dark stain which was red in actuality. The action of the acid has removed a portion of the fabric and tendered adjacent areas as. is indicated by the slits that occur near the edges of the holes. Washing will remove this tendered area. The photograph shows that four layers of cloth have been affected, each one as we descend showing a smaller damaged area. This is in accord with the principle that each layer receives less liquid than the one preceding it and is affected to a correspondingly less degree. 122 Corrosive Materials dering. at which time he will have forgotten the incident and as a natural consequence will likely blame the laundry. The extent of the sources of possible damage to fabrics during the course of wear and use is not generally appreci- ated by the laundry patron. Herein lies an opportunity for progressive instructional publicity among the patrons and especially and first among the laundry employees. The Manufacturer. — Local holes or tendered spots due to the chemical action of corrosives employed by the man- ufacturer are not of frequent occurrence. According to the experience in the authors' laboratory the greater num- ber of cases in which the manufacturer has been found to be responsible for exhibited unsatisfactory service from a fabric have been of the nature of spinning and weaving defects such as those described in Chapter III. The cases of chemical corrosion for which the manufacturer has been found to be responsible have been in cases of over-bleaching white goods, including the souring treatment, the excessive or improper use of mordants, in the corrosive action of certain dyes and in the failure to thoroughly treat printed goods in which the figures of the design have been effected by the use of stripping salts. In the bleaching of piece goods the bleacher employs much more drastic treatment than is accorded the fabrics in the power laundry process. He must of necessity employ stronger souring bath than is permissible in the laundry. He has some advantages not possessed by the operator of a power laundry plant. He is not required to repeat the process; his bleaching is done in equipment that allows the exclusion of air during the boiling in the alkaline bath while such precaution though desirable cannot be exer- cised by the commercial laundry. In spite of these advan- tages exhibits of cotton goods tendered in the bleachery are sometimes encountered. In such cases the tendering is usually evenly distributed and, without chemical or tensile 123 The Conservation of Textiles Fig. 51. Texdering Due to the Dyeing. The dyeing process used on the black yarn in this fabric resulted in a tendering of the yarn. The black threads were readily removed by rubbing between the fingers, and wear and laundering resulted in the removal of the stripes. 124 Corrosive Materials 4- f ^^ k ft. i *■ I ') » Fig. 52. Tendering Due to Dyeing. This photograph shows the same fabric that appears in Fig. 51 after the black stripe had been removed by laundering or rubbing. Such damages can not be credited to the laundry process. 125 The Conservation of Textiles strength tests, the true condition of the fabric is not easily detected. There is one way, however, in which such con- dition is evidenced in the course of laundering. That is in the case of ready-made white garments, usually white shirts in which one piece of the pattern of the garment shows failure while the remaining portions of the garment are in good condition. This comes about by the use of one bolt of cloth for one portion of the garment and of another bolt for the remainder, one of the bolts being of good cloth while the other (of the same design, of course) has been tendered during the bleaching process. For instance, we examined a shirt recently which showed failure in one sleeve and the section forming the right front, while the re- maining sections were sound. Chemical tests showed that all the cloth in the affected sleeve and right front section was evenly tendered. Tensile strength tests also showed even tendering on the sleeve and right front section. There could be no condition under which these results could have been brought about other than the treatment of these two pieces of the garment before the shirt had been sewed to- gether. Cases similar to this one are occasionally encoun- tered in the authors' laboratory. The improper use of mordants are more frequently en- countered. Generally this character of failure will be found in striped goods such as shown in Figure 51, wherein the stripe is effected by means of colored warp which has been dyed in the yarn. In the case represented by this figure, the black yarn had been tendered in the dyeing pro- cess before the cloth was woven. The remaining warp and all the filling was of good quality. No laundry process could have produced such an exhibit because all the yarn was of cotton and any reagent that would have affected one set of yarns would have had a similar effect on the other set. The black stripe yarn was so friable that the first washing of the garment produced the appearance of drawn work shown in Figure 52. The same effect could be pro- 126 Corrosive Materials • « • * •** * # # f # ♦ r ^^•i* ^.» % •># # . * •«••»•♦♦'.'* • * * * .** ^*>^ * 17 • » « • % * • « « * • • • ♦ • • • • 'Ate ««[^ « * X X V Ik « Ik Fig. 53. CoRROSiox by Stripping Salts. The improperly governed action of stripping salts on fabrics is demonstrated in this photograph. This fabric possessed a blue background and a pattern in white dots. The whole fabric had been dyed blue and the white dots made by stamping on stripping salts. These salts were not removed after the desired decoloration had taken place and extended their activities to the fabric itself. The tendered areas were dissolved in the first laundering, leaving the fabric in this condition. The responsibility in this case lies wholly with the dyer. 127 The Conservation of Textiles duced on any of the black stripes by simply rubbing the goods between the fingers. Such tendering of dyes in the yarn warp may be caused by the use of excessively strong mordant solution, by failure to sufficiently rinse the yarn at the end of the dyeing operation, or by the use of certain dyes, notably the sulfur dyes that have an inherent ten- dency to produce tendering which under some conditions becomes more pronounced. The figures in some printed goods, such as bandana handkerchiefs and the star field of cheaper grades of our national flag, are produced by first dyeing the piece for the background color and later printing on in pasty form certain so-called stripping salts which will discharge the background color leaving the figure white. The stripping salts are of a corrosive nature and soon tendering of the figure areas will at best occur, and if, as sometimes happens, the stripping salts are too strong or are not thoroughly removed after having served the purpose for which they were applied, pronounced tendering will result and the white figures will crumble away leaving holes in the cloth where the white figures ought to be. Such a case is pictured in Figure 53. This fabric was a blue handker- chief with white figures. After the first laundering the blue portion of the cloth was as strong as it was originally, but the white figures had almost entirely disappeared. 128 CHAPTER VI. The Treatment of Stains. IT IS thought advisable to include in this book the Procedure Chart for the Removal of Stains from Wash Goods, together with a more complete discussion of the preparation of the solutions involved and their application than was possible to present in the limited space of the wall chart. Our best advice to the laundryowner is that he choose one of his employees who shall handle all stained fabrics which require special treatment. Such a procedure can not be urged too strongly because the propei treatment of stains is dependent upon an intimate knowledge of their physical and chemical characteristics and a thorough training in the technic of the application of this knowledge. The physical characteristics of stains are differentiated by such slight degrees in so many cases that word-pictures make an impossible medium for instruction; rather a keen- ness of perception and a large power of retention, combined with the consistent application of these faculties are nec- essary for the development of a good "stain identifier." Having provided oneself with a trained observer, or with a person capable of being trained to observe, the thing to do is to provide a special work bench for the application of the specific knowledge of stain treatment. Only a small bench will be necessary, say the size of an ordinary kitchen table, but it should be given up entirely to the work under discussion and should be specially equipped. It would be well to remember, when choosing the location of this bench, that at times inflammable materials will be used and that no flames should be in the vicinity. 129 The Conservation of Textiles In the first place it should be placed in the best light obtainable. This is desirable that slight color differences may be noted and that final results may be accurately judged as complete or partial removal. If only partial removal has been effected, efforts may be renewed along different lines until the stain is completely removed or until the worker is convinced that the only results possible have been obtained. The equipment should include all the reagents used in the identification and removal of stains and any apparatus that will facilitate their application. The reagents to be desired are presented in the table on page 131. There should be "stock" bottles of each reagent; that is, bottles in which the reagent is kept in its original condition and strength. These will be handled only when the solutions to be used in stain treatment are made up. There should be the bottles of solution that are to be kept on hand as "indicators" and as "testors." The solutions should be carefully prepared. There is no need for using excessively strong solutions because the lessening of the time factor by this method means a cor- responding increase in the tendency of the solution to tender the fabric. It is just as profitable for the person who is removing stains "to increase the dose" as it was for the man who increased the dose of headache tablets, and died as a consequence. In both cases the physical condition of the object under treatment is made worse instead of better. Oxalic Acid. — One ounce of oxalic acid crystals are dissolved in a gallon of water. This solution works more rapidly when warm. Always rinse carefully in clear water after using this acid; if traces of it are left in the fabric it becomes concentrated as the moisture evaporates and tenders the cloth. 130 The Treatment of Stains K S 3 en ti3 "^i rt 5^ 1 C 3 a. rt g ^.^ >5 ^iro-g- n 03 rt- o r "■ > 3 03 =1 W 3- H s-'^. ^'^ ^ n> c !" n> 2. e/5 3 2. 3 > a o xali ydr ceti > Don n o 3- VI O "1 o' >i2 > in n austic so oda ash mmonia otassium > n p. r ^ p 5 03 (J) 3 D- ft> Jave Hyd Pota m; Sodi :lle wa rogen ssium angan um pe ^ § cr c "o 3: m O f* 0) o '^ ;;i 7 X P3 1 N-. ri- D- fD n C/5 C/l c/) o c o o D. 55 CL CL C Q, C C ^ ?o 3^33 > — ■ -J en en d 9 N c c 2: 5 en ij, .— • ►— • C^ 3 31 3^ (/I P^ " f? (? r* rt o o p^ W O n > > n > m ^.% ^ <^ w _. e; 3:3,8 ^3 5- 3 -1 Q. o o o N cr m Q- 3: rr- ><: "<^ v; .. =•. en z,- o ::^ 3 -I- — ^ C/) ene ine acid 3 3 alcohc alcoho ether ne e oform n tetra r < CO* 2: 5 3- "" H n> -1 > w r m o > O M "Z H CO M O o < > r 131 The Conservation of Textiles Acetic Acid. — This acid is usually found in the laundry as commercial 56 per cent, acetic. It can be used in this strength without damage to the fabric, but it is preferable to dilute it with an equal amount of water. As this acid is volatile, that is, as it evaporates with the water, concen- tration does not occur with drying and tendering does not result from insufficient rinsing. Hydrochloric Acid. This acid should be used in weak solutions, not exceeding a 10 per cent, solution. This per- centage may be purchased from the drug store, and care should be taken to express the percentage desired as it is prepared for pharmaceutical purposes in 10 per cent., 25 per cent, and 37 per cent, strengths. Careful rinsing is urged with this acid for the same reason that is given under oxalic acid. Caustic Soda. — A 5 per cent, solution is prepared by dissolving an ounce of the solid in a pint of water. This solution is to be used on cotton and linen fabrics only and followed by a good rinsing. The concentration of the 5 per cent, solution is not detrimental to these fibers but in greater concentrations tendering is effected. Ammonia. — The ammonia sold by druggists is about a 10 per cent, solution. It will never be found necessary to use it in this strength and dilution with ten times its volume of water is advised. Javelle Water.— This reagent is so well known in the laundry that no other discussion will be given than that it is prepared as directed in the L. N. A. "Standard Formulas for Washroom Practice," Chart No. 1. The stock solution resulting from this formula should be diluted at least fifty times before using on fabrics. If rinsing is done with dilute acetic acid water the activity of the bleaching solution will be killed. 132 The Trcatmcni of Stains Hydrogen Dioxide. — Commonly called hydrogen per- oxide, and purchased at the drug store, this reagent may be used full strength. The commercial grade of hydrogen dioxide usually contains a considerable percentage of free sulfuric acid; for this reason great care should be used in rinsing after this reagent has been used. Due to the presence of this small amount of acid that has produced corrosion when used ignorantly, the idea has sprung up that hydrogen dioxide itself is corrosive. This is not the case, however, and no hesitancy should be felt in using it as a stain remover. Potassium Permanganate. — One ounce of the crystals is dissoK^ed in a gallon of water. A stronger solution is capable of burning the fabric as effectively as a flame, so should never be used. Sodium Perborate. — This reagent may be used in so- lutions of any strength, or made into a paste with water and spread on the fabric to be treated. Sodium Bisulfite.- — ^A saturated solution of this reagent is prepared by adding it to the water until no more will go into solution. Sodium bisulfite is used alone and in con- nection with powdered zinc. When zinc is used it should be put into small bags so that it will not settle on the fabric and leave a stain that can only be removed with an accompanying damage to the fabric. Oleic Acid. — This reagent may be purchased under the trade name of "Red Oil," but an effective substitute for it can be prepared in the plant by dissolving some soap in hot water, precipitating the fatty acids by acidifying with strong acid, heating till separation is complete and then cooling. After cooling, the fatty acid will be found as a solid cake on the surface of the water. 133 The Conservation of Textiles Sodium Thiosuljate. — Used in saturated solution, pre- pared by adding crystals to water until no more can be dis- solved. Potassium Cyanide. — One ounce of the crystals is dis- solved in a gallon of water. This reagent is one of the most deadly poisons known; therefore great care is to be observed in its use. If any is gotten on the hands they should be kept away from the rest of the body and from the clothing until they can be washed well. The solution should be thrown out immediately after the treatment is completed, the utensils used with it washed thoroughly, and the bench cleaned of any splashings it may have received. If these precautions are observed no fear need be entertained concerning the use of this reagent. The successful application of these solutions requires a few common utensils that are listed herewith: Hotplate (electric or gas), Nest of enameled bowls, Scales, Glass rods (with rounded ends). White blotting paper. The actual discussion of the treatment of stains had best be made to follow the Procedure Chart for the Removal of Stains from Wash Goods, and will occupy the remainder of this chapter. Albumin. — The regular standard washing process in- cludes a lukewarm first bath for the purpose of dissolving any albuminous materials that may be present. Blood. — The albuminous portion of this stain is re- moved in the first bath of lukewarm water; the stain 134 Procedure Chart for the Removal of Stains From Wash Goods K,™or^*,N 1 corroN | Lm.» | wool ^ COLORED CABMH^ ALBUMIN. R.rT.ov«l in th. .l>ndiud •■■.hint pro«». ™.™.0,«l.™™,.„d. BLOOD. Romo.«linlh.)t.nd«rd«..hinep«c.... Th. .lainof th.h.minlobm 1 R.mov.d in Ih. .t«nd«d •■"h'n« Pro«". TTi. .lain ol h.mof lohln fRov;sES'TKlr?Bi'i& :^"'"^ p„.^;7K:;^tr„t^";""^L"r^u,r■;vsr'£o;^ Betin with th. •ImpL.t COCOA AND CHOCOIATE. R,m«v«l in Ih. .t«,d«d w..hir., pr«.... pro COFFEE. CREAM AND ICE CREAM. „.„.... ,„,H. ........ ...M.„™... MULTICOLORED ECC. ^ K™„..,„.H. ...... ...K,.„^„.. FRUIT. — — ,,;b^eB'^^^-^^^ CRASS. ^.Xz::ij^t^j::^^'xv::.." - •'-—■— ..^Kr^^j-i^a;^" - — -■ - — - -•■ - ^^^Mmi^SiMH :^^^^;b^^^---^^'^ CUM OR RESIN. ..^^yi'z^is;ip^z^^::^;^r^s^;i:^iS:iS^s^ WRITING. INDELIBLE PENCIL. =;S'!{HHHH;^s:S^3t=2i^1| ................................... .o,so.. IRON. 5«lNKSIIRONi. IEAT«ER. .u,»';'X'S'sj,';:i's;r,™ir. t".-,.;"""-' — '""■ '— ■■■ ''"'•■ | -<• ■^•'^ <■ ■». — k^* <• >—■... .. u,. ,.«.. MACHINE OIL ..h.r'™*.'5;rdrr.i:.rs:r'-VS":.™r«'"^^^^^ " • '~'"'' — " ™'— ■'- —• '"- » iH^^W MILDEW. ..£•;;lJ*;^:v£^=•i,Hfc;?-;^;t:S;:^s'=..3K| MUD. o,.,^?,:v;:is^^3,:^-:;xr;:;.:r:l^;?^i';r':;s -.,.'i r.,7^^^■;..^„,i''i;nr.;;^^^':L!;'Kax^::i!■. i™."- 1 ,.„.';.'j';;^.':„;r,r' -" °- - -"'""■ -""•"«■-• "'"-" iiSS-SrJ^^S h-,"!''.' .'"^^."1^ """"', '" "" ■""''■"' "■■'''"■ ■"°""' '"' SYRUP. TAR OR TARRY. TEA. TA»»V_.MS,DUI! ,j^-^£^-^.::£z^vSsL':^^ mM^mB&SM [Edgpss^s ««»■<=»- ""^"""" .u.«..ful, ".»n.n. 1. not .iw.y. ssimK;*^. :::SiiHS:-=SS^:£^— -— --^^ Preparation of Solutions Recommended for Use Above The Treatment of Stains proper, which is due to the hemoglobin or coloring matter of the blood, is removed in the bleach bath. If the fabric is of the kind that can not be treated with javelle water the stain may be treated with hydrogen dioxide. Bluing. — Bluing is of three kinds, ultramarine blue that gives the desired color by depositing small insoluble particles of blue on the fabric; prussian blue that dyes the fabric with a soluble dye; and aniline blue that dyes the fabric with an insoluble dye. Ultramarine blue, which only gives trouble by being used too heavily, may be removed by simple washing; Prussian blue, which in an alkaline bath is changed to iron oxide and gives a rust stain, has to be treated with oxalic acid solution. The aniline blues, if used too freely, dye the fabric permanently as far as the ordinary solvent, water, is concerned, and must be removed by treatment with oxidizing or reducing agents, according to the nature of the dye used. Javelle water or potassium permanganate solution is used to oxidize these blues on cotton or linen fabrics, while potassium permanganate solution or hydrogen dioxide is used on silk and wool. Sodium bisulfite solution and zinc may be used on both the animal and vegetable fibers as a reducing agent. The potassium permanganate solution treatment is not complete in itself, as it leaves a brown stain of manganese dioxide in the cloth which must be removed by treatment with oxalic acid solution. If it is found necessary to repeat the treatment the excess oxalic acid should be washed from the fabric before more permanganate solution is applied. It is always well to observe the precaution of rinsing from the fabric any excess of solution when two solutions are alternated, because the excess of solution present reacts to neutralize the effect of the other solution in a manner that has no effect in the removal of the stain. There is no need for such useless reactions. 135 The Conservation of Textiles Cocoa and Chocolate. — These stains occur in most cases on white table linens and, when too deep to be removed by the water and soap, are removed by the bleach bath. Coffee. — Javelle water, applied in the bleach bath, removes this stain effectively. Cream and Ice Cream. — The principal ingredient that causes trouble in this type of stains is the butter fat present. When this is removed with hot water and soap the stain is usually gone completely. In the case of an ice cream that has fresh fruit juice or a food dye present as coloring matter the stain will be removed by javelle water. Dyes. — The treatment for a dye stain has always to be determined by a few tests on some portion of the stained fabric. The first trial may be made with javelle water; then with permanganate solution, then with sodium bisulfite solution and zinc. The kind of material involved and the dye itself have to be taken into consideration for the successful treatment of this type of a stain. The removal of hat dyes is facilitated by treatment with 95 per cent, ethyl alcohol, in which the greater portion of the dye is soluble. A residual stain may have to be treated with one of the oxidizing or reducing agents prescribed on the chart. Egg. — This stain is partly albuminous, partly fatty, and, in most cases, will be removed by a formula that includes a lukewarm first bath and hot suds. Fruit. — Fruit stains can readily be removed by treat- ment with javelle water; for that reason the stains appear- ing in cotton and linen garments are said to be removed in the standard washing process. Silks and wools are to be treated with the reagents given in the chart that are not detrimental to them. 136 The Treatment of Stains Grass. — This stain is also removed from cotton and linen by treatment with javelle water. Silks and wools are treated with a mixture of equal parts of ethyl alcohol and ethyl ether. This is a solvent for the green dye present in grass. Grease. — The av^erage grease stain is removed in the standard washing process. Any stain that survives this treatment may be softened with oleic acid and lard and washed in a hot solution of soda ash. If the grease has contained a mineral staining agent like iron or some type of dyestuff it can be treated specially as described under these headings. The best treatment to be accorded to silks and wools is with one of the many grease solvents given on the chart. The solubilities of the different types of grease vary with the different solvents, and it is often necessary to experiment with several solvents before the more efficacious is found. Gum or Resin. — The type of the gum or resin decides the solvent that should be used. Common chewing gum is soluble in carbon tetrachloride; varnish is soluble in alcohol; resins are soluble in ether, alcohol and tur- pentine, the source of the resin determining which solvent is best. Since there is no way to decide which resin is present, the method of trial and error must be applied to discover which solvent is to be used. Ink. — Iron inks are best removed by treatment with warm oxalic acid. If such treatment does not remove the stain completely it is possible that the ink has been a mixture of iron ink and an aniline dye, in which case a second treatment with javelle water is necessary. India ink and printers ink are both suspensions of carbon in a gum-like medium, and should be removed in the regular laundering process. If such treatment is not effective the 137 The Conservation of Textiles stain may be loosened with lard and laundered again. Silver nitrate inks have to be treated with sodium thio- sulfate or with javelle water. Javelle water converts the silver to an insoluable colorless salt that has to be removed by treatment with dilute ammonia water. If this pre- caution is not taken the silver may again oxidize to the colored salt and the stain reappear. Indelible pencils contain both graphite and an aniline dye; the dye can be removed by treatment with javelle water, while the graphite will be washed away mechanically. Iron. — The specific treatment for iron stains is warm oxalic acid solution. Leather. — Javelle water has been found to remove these stains from the cotton and linen fabrics, but in the case of silks and wools the stain is permanent. Medicines. — The medicines containing organic ma- terials are usually removed in the regular laundry process; any stain surviving this treatment can be treated with javelle water. The medicines containing salts of the heavy metals, like iron, silver, etc., may be treated with potassium cyanide. The cyanides of these metals are water soluble and are removed by means of this solvent after conversion has taken place. Mildew. — These stains are usually removed in the standard washing process, but heavy stains may have to be treated alternately with javelle water and oxalic acid. Mud. — ^The mud itself is removed in the regular water washing but a residual stain of iron is often encountered. This is treated as all iron stains are, with warm oxalic acid. Paint and Varnish. — These stains are best removed before laundering. They may be loosened by treatment 138 " The Treatment of Stains with oleic acid and then laundered or they may be treated with one of the solvents that are given in the table of reagents. The character of the paint determines the treatment applied. Paints are composed of some vehicle and a pigment; the vehicle hardens or sets by the evapora- tion of some volatile ingredient or by the absorption of oxygen from the air, depending upon its chemical nature. The pigment can be removed mechanically after the vehicle carrying it is dissolved again. Perspiration. — This stain, being water borne, is usually removed by simple soap and water washing. If it is con- nected with the running of a dye, treatment for the dye must be applied. Colored goods that have been discolored by perspiration may sometimes be restored by sponging with weak acid or alkaline solutions. Scorch. — Scorched cotton or linen may be restored by treatment with javelle water alternated with oxalic acid solution, provided the scorch has not completely destrpyed some of the fabric. The same results may also be obtained with potassium permanganate and sodium bisulfite solutions. Light scorches on silk and wool may be partially restored by treatment with permanganate solution, but nothing can be done for heavy scorches on these fabrics. Syrup. — -Syrup stains are usually removed in the standard washing process because the medium of the stain, the sugar, is removed. If a fruit juice has been present, some stain may survive this process but the treatment described under Fruit will remove it satis- factorily. Tar and Tarry. — See treatment of paint. Tea. — Tea stains are usually removed in the washing process, but the occasional heavy one should be treated 139 The Conscrvaiion of Textiles with javelle water when it appears on cotton and Hnen and with potassium permanganate or hydrogen dioxide when it appears on silk or wool. This stain is, in most cases, the result of the tannin present in the tea but in some cases is due to a dye that is added to give a darker color to the infusion. Tobacco. — The stains from tobacco are usually soluble in the standard washing process, but occasionally stains that require longer treatment are encountered. They may be treated with the oxidizing agents that are permissible with the type of fabric involved or they may, in case of the tarry residue from pipes, be treated with ethyl alcohol. Turmeric. — This is oneof the seven dyes permitted by the U. S. Pure Food law to be used in food stuffs. They are usually to be removed by treatment with javelle water or permanganate solution, but in cases that do not respond to this treatment amyl alcohol will be found efTective. Verdigris or Copper Stains. — This stain, if not removed by the usual laundry process, has to be treated quite drastically with dilute hydrochloric acid. If only a weak solution of acid is used and care is taken to remove all traces of it afterwards, no ill results will be noticed. Walnut. — This stain is one of the worst encountered on fabrics. It can usually be reduced to a light gray color on cotton and linen by treatment with javelle water, but when it appears on silk and wool no treatment can be recommended. Wax. — The most satisfactory method of removing waxes from fabrics is to place the spot on a piece of blotting paper and apply a warm iron. The heat liquifies the wax and the blotting paper absorbs it. If traces remain after this treatment they may be sponged away with one of the organic solvents. 140 The Treatment of Stains In conclusion, it is appropriate to suggest that inspec- tion of garments for stains be rigidly maintained in the receiving room. Many times stains are set in laundering and offer a much greater problem for removal then they otherwise would. 141 CHAPTER VII. The Conservation of Fabrics. ADEQUATE, definite information regarding the length of time a fabric should last under normal conditions of use is almost entirely lacking. This is true in the first place because of the infinite variation in the quality of cloth and in the second place because of no accepted meaning of the expression "normal conditions of use." A number of observations on the life of certain hotel linen supplies have been recorded in various reports from the authors' laboratory. We have, also, a series of observa- tions of the life of standard brands of collars, and compara- tive tests of the effect of power laundry practice compared with that of the housewife and the Chinese laundry. We have observed and recorded the effects of the various processes in laundering, such as the mechanical effect of the power washing machine operated under conditions outlined in the Manual of Standard Washroom Formulas published in May, 1918, number of the Bulletin of the Laundryowners National Associaion. We have deter- mined the effect of each of the standard washroom reagents under the best conditions and under the less favorable conditions. It is a discouraging observation resulting from a recent test, that the membership of the Association has not made a very marked success in the endeavor toward standardization of washroom methods. In the test referred to a number of the same brand of new soft collars were sent to a number of different laundries over the country and upon their return the shrinkage was measured. The results were distinctly at wide variance. This is, by the way, to illustrate that complete protection of 142 The Conservation of Fabrics laundries from unjust claims can not be had until plant operation methods in general are placed on a better plane. The old saying that the good suffer with the evil is truly applicable to laundries. In the October, 1918, number of the Bulletin of the Laundryowners National Association, and in Chapter V of this contribution, a method was proposed wherein all laundries of the association could assist in the collection of the needed data as to the expectancy (to borrow an expression from life insurance literature) of various standard fabrics and garments. There has been little response to this suggestion up to the present time, very likely due to the difficulties involved in mixing research work of this character with the commercial plant operation. Obviously these data cannot all be obtained in the laboratory. The most marked progress in this direction awaits the establish- ment of the Model Laundry of the American Institute of Laundering. Some useful information regarding the life of certain fabric articles worn by soldiers may be secured later through some observations that have been started by the Salvage branch of the U. S. Army. It will be a marked achievement when we can say that a cloth weighing so many ounces per square yard and having so many "ends" and so many "picks" and such and such tensile strength when used for a certain purpose will survive so many launderings. We will then be in a position to give recom- mendations to some of the large users of textiles and to assist hotel managers in preparing specifications for the linen supply of their establishments. Having all the information that it will be possible to get regarding what does constitute a good textile fabric, the laundryowner will still further need a means of pro- tecting himself against articles which appear to be of good quality, but which, as a matter of fact, are defective in one way or another as described in previous chapters. This means will be found in bringing about a greater discrimin- 143 The Conservation of Textiles ation in purchasing on the part of the users of textile fabrics. The thought also suggests legislation for the correct labeling of fabrics, but this will be discussed else- where The Three Agencies of Responsibility. — Evidence af- forded by a large number of exhibits that from time to time have been submitted to the authors' Department, show conclusively that if the textile articles were purchased wisely, with the adaptibility to the proposed use definitely in mind, and that if these fabrics honestly repiesented the quality they appear to represent, and if the fabrics were not abused during the course of use or wear, claims for damage against the laundry would be reduced ninety-five per cent. That is to say that less than five per cent, of the damage claims with which the authors have had to do are attributable to causes for which the laundry held direct responsibility. This statement should be taken in the light of the fact that in cases wherein the laundry is obviously responsible the exhibit would seldom be sub- mitted to the authors. When we find evidence, as we sometimes do, that the responsibility is probably charge- able to the laundry, the laundryowner is plainly advised to that effect. At the same time are presented any suggestions that we may be able to ofifer, the consistent application of which would tend to preclude the recurrence of the trouble. The three agencies of responsiblity for the satisfactory conservation of textile fabrics are plainly the manufacturer, including the manufacturer of the cloth as well as the fabricator of the garment; the owner of the article whose responsibility includes the exercising of discretion in making the purchase, in which responsibility, to some extent the retailer shares, as well as in the exercising of due precaution in protecting the article from severe mechanical strains and from strong alkaline and oxidizing materials if it be of animal fiber, and from acids and oxidizers if it be of vege- 144 The Conservation of Fabrics table fiber; and the launderer whose duty, obviously, is to renov^ate the textile with the least possible depreciation of tensile strength consistent with the standard of quality of work demanded by the trade. This responsibility of the launderer is implied by the mere acceptance of the soiled linen. The authors again feel constrained to urge careful examination of fabrics on their arrival at the laundry plant so that the limits of the responsibility of the launderer may be accurately defined. To obtain the harmonious functioning of these three agencies is an objective worthy of the efforts of a great trade organization. If we, as members of the trade, are sincere in our expressed belief that the industry constitutes a public utility and that the only commodity distributed is service, it follows without argument that the conserva- tion of the life of the fabric laundered is the matter of prime importance. If this matter is cared for persistently the questions of the success of any individual enterprise and of adequate profits will be automatically included and the advancement of the industry to a more comprehensive contact with the homes will be assured. Certainly we should coordinate the scientific knowledge concerning the other aspects of the service so that adequate but fair revenue will be secured to sustain the business on a sound financial basis. Leaving out for the present the con- sideration of financial features, as important as they are, let us consider in what way we, as an Association, may be able to improve the conditions over which the two agencies other than ourselves have the more direct control. This means the exertion of cooperative influences on the organi- zations and individuals controlling the factors outside the laundry that affect the life of fabrics. In this we will con- sider the retailer as merely an agent of the producer, textile manufacturer and garment fabricator. Emphasis should be placed on the responsibilities of the garment 145 The Conservation of Textiles maker, for the laundryowner has suffered quite as much on account of his shortcomings as on account of those of the spinners and weavers. This is notably true in the case of palm beach suits, wherein cases of poor tailoring are as frequently evident as are cases of poor quality of cloth. The producers of textiles are not usually accessible to the users or laundryowners while the retailer is. It would therefore appear that the sympathetic understanding of the retailers should be cultivated. The Retail Merchant. — There is a national association of retail dry goods merchants. Some of the membership of the Laundry Association in every town and city are in contact with members of the retailers' associations through Rotary Clubs and other organizations nearly every day. It is the business of the retailer to serve the same clientelle that is served by the laundry. He should, therefore, be shown just wherein his interests overlap those of the laundryowner. Such mutual under- standing that is sure to result from the right kind of contact will assist in the movement for legislation for the correct labeling of fabrics. It is our purpose in the following paragraphs to present some suggestions which, if carefully and tactfully put into execution by the laundry- owners in the various communities, would lead to im- provements in both trades and finally would result in a great benefit to the public. If the laundryowner would have the sympathetic interest of the retailer he must give sympathic hearing to the troubles of the retailer. Always there are two sides to every question. We must realize that all the materials that enter into a textile fabric cannot be invariably of the best quality. Furthermore, the fallibility of human hands is a condition obtaining in the textile and garment indus- tries as well as in the laundry industry. We must be fair and open minded. We know that large quantities of shoddy must be used or, otherwise, there would not be 146 The Conservation of Fabrics enough wool to meet the demands. We know that the cotton that must be made into cloth cannot all be grown in the Mississippi Delta. Some of it must be grown on the uplands of our Southern states where nature does not produce the long staple variety. In spite of these facts, however, we should, by vividly portraying the reasons, bring it about that the short staple should be used in the tightly spun and tighly woven fabrics in which its use is, from a conservation standpoint, satisfactory, instead of in other designs of cloth in which its use, for reasons pointed out in Chapter II, constitutes almost criminal waste. Also we must realize that the operations of spinning, weaving, bleaching, and dyeing in the textile mills are not without their difficulties. Mistakes will occur to some extent in these operations. It, therefore, follows that in order to avoid an unbearable loss or a prohibitive price for the perfect product of the mills some defective fabrics must be marketed. Our Committee on Legislation for the Correct Labelling of Fabrics has realized this circum- stance all along. The Committee does not wish to restrict the honest producer. Its object is rather to bring about conditions under which deceptions could be less readily perpetrated on the dealers and in turn on the buying public so that the laundryowner as a consequence would be relieved from the blame that is unjustly attributed to him from these sources. Elsewhere we have pictured a "scratch up." (See figure 39.) "Scratch ups" occur in seconds which are sold over the bargain counters. If it were required that seconds be labeled as seconds so that the buyer would know that the cloth contained some defect or other a great measure of protection would be afforded the purchaser. Protecting the purchaser in this case would also be protecting the laundryowner. Some dyes, as has been pointed out in Chapters IV and V, are known to have a marked tendency to tender fibers. It should be the laundryowner 's endeavor to 147 The Conservation of Textiles familiarize the retailer as well as his own employees and the laundry patrons with these facts. Styles in fabrics constitute a factor influencing con- servation, which under present conditions, is even more than any of the other factors without the range of our control. The buyers for the large dry goods stores, however, are able to mitigate to a large extent some of the evils resulting from ill adaption of cloth to the purpose of the garment. For instance, through the accumulated effect of constructive advertising on the part of the laundry- owners and other general public — education on textile matters, which by the way, has already acquired con- siderable momentum through such instrumentalities as the domestic science schools and popular journals devoted to the household arts, — combined with the sort of cooperation between the laundryowners and the retailers as suggested herein and in the July, 1920, number of the Laundryowners National Association Bulletin, the buyers for the retail store could be lead to select for their stocks fewer jacquard designs in light mercerized cotton cloth for pajamas. (See figures 16, 17, 18 and 19.) Also, through such instru- mentalities as are suggested here the purchasers of table fabrics would come to the realization that jacquard designs in cotton and mercerized cotton table cloths must, to be serviceable, be made of yarn tightly spun from long staple cotton and be woven in patterns requiring comparatively short floats. When the managers of homes, hotels and restaurants come to be more descriminating in the pur- chase of table fabrics a great source of annoyance will be removed from the laundryowners. To help spread popular interest in discriminative buying of textiles is a privilege which should be exercised by every man in the laundry industry. He should not neglect the opportunities afforded by his membership in business men's organizations. The illustrations contained in this book are available to members of the Laundry- 148 TJic Conservation of Fabrics owners National Association in the form of lantern slides. They should be used for the good influence that the infor- mation therein portrayed will have on both the sellers and users of fabrics. When this is done the avowed ideal of the industry to effectively serve their patrons will be more quickly attained. The tune must be raised by the laundryowners themselves, then others will sing their praises. In association work, however, we are repeatedly re- minded that we must deal with people and conditions largely as they are and that perhaps we can afford to spend only a comparatively small portion of our efforts in trying to promote the ideal. Our first interest, therefore, is to fortify the laundry management and the plant personnel with the facts presented in the preceding chapters, so that in case of unjust damage claims it will be more easy to point out to the patron just why the responsibility is his or that of the manufacturer of the fabric or garment. Abuse of Fabrics by Users.— Difficulties in the way of the attainment of ideals should not deter the conscientious from persistent effort. The adjustment of claims on the basis of accurately determined evidence will lead, in time, to a better understanding on the part of the users of fabrics, of the ordinary and accidental hazards. It is not within the scope of this book to discuss the advertising and publicity needs of the laundry industry but some phase of the requirements, if not the details of the methods to be employed, can not escape our attention. Certainly the industry could profit by receiving better cooperation from the patrons. It is distinctly to its advantage to have spread a better knowledge regarding the proper care of fabrics in use. This is true not only of fabrics that are included in the family wash but especially so con- cerning the so-called commercial work. Restaurant, small hotel and linen supply goods are notably abused. 149 The Conservation of Textiles The use of dish towels for general mopping purposes in the kitchen after they have become too soiled for their further use for the purpose for which they were made, thereby rendering necessary drastic treatment in the washing process, shortens the life of this particular article more than any other one factor. Likewise the transference of slightly soiled table napkins (notably cheap restaurant practice) to the use of common wiping rags is one of the great causes of short life for this article. The use of toilet supply towels for wiping shoes curtails their maximum length of service. The autombile storage battery, certain toilet articles and medicines which are enemies to textiles are enumerated in Tables I and II in Chapter V. Re- gardless of the advertising or publicity methods to be employed, it is the duty of the laundry trade to acquaint the patrons regarding these factors outside the laundry that operate against the maximum life of garments and household linens. In households wherein the laundering is done in the home it has been observed that greater care is usually taken to avoid severe staining and exposure to other wearing hazards. The fact that the responsibility of laundering is taken from the home seems to prove conducive to carelessness in the use of household textiles. Responsibility of the Laundry. — The experiments of the authors to determine the best methods of washroom pro- cedure,, the results of which were published in the May, 1918, number of the Bulletin of the Laundryowners National Association, were conducted with the idea con- stantly in mind of causing the least wear and tear to the fabrics consistent with the quality of work demanded by the patrons. The summation and suggested application of all this work was presented in the Bulletin but some features were given more detailed account elsewhere, especially in the June 14, 1917, number of the Scientific 150 The Conservation of Fabrics American Supplement. Some things, however, will bear repeating here. The greatest degree of selective treatment consistent with commercial plant operation should be made with respect to strength and texture of the cloth to be laundered and with respect to the extent of soiling they bear. In this point lies the greatest advantage which the washwoman has over the power laundry. Our experience shows, however, that she has compensating disadvantages. In respect to selective treatment the power laundry can only approach the latitude enjoyed by the laundress, if indeed she be a good laundress. When a good laundress picks up a fragile garment she handles it with special care and as a result she is able to get from a fabric that is nearly worn out a few more periods of service than if the same garment were washed as it would have to be washed in a commercial laundry. For the consolation of the trade it may be well to state that such good laundresses are hard to find. In the case of fine goods most laundries now make careful selection and accord the fabric the treatment it requires. The selection with respect to the dirtiness of the fabric to be laundered is not, according to the authors' observations, so thoroughly carried out in the power laundry as is usually the case with a careful washwomen. The extended use of the home washing machine is taking away from home laundering even this advantage, excepting to the degree, as pointed out above, that in such households the incentive to care for the clothes in use is generally accentuated. We have urged that commercial fiat work that is slightly soiled should be given a shorter treatment than is necessary for the regular run of flat work. In addition to correct washing formulas, proper classification for selective treatment and rigid inspection for defects and corrosions detectable on the soiled goods before they are laundered, good laundry management also implies the selection of dependable workmen. We have 151 TJic Conservation of Textiles all observed damages which were the results of careless handling of the goods in transferring them from the washer to the extractor and from the extractor to the truck. Slipping driving-belts on the washing machine that cause the tangling of the goods should be guarded against. Improper loading of the extractors often results in torn fabrics. Some cases of tearing by too vigorous a pull of the garment over the press, especially on the shirt bosom press, have come to the authors' attention. Exposed or projecting bolt or screw heads, lodged nails and pins and the catching of marking pins are sources of occasional damage to fabrics that should be looked for and avoided in the wheels and tumblers. These are details that should never be overlooked. The magnitude of the job of running a laundry successfully is recognized, but we believe all the suggestions herein presented are pertinent to the production of good laundry service, the only kind of service that is worthy of merit and that will receive praise from the patrons. 152 CHAPTER VIII. Pure Fabric Legislation and the Department of Chemical Engineering. At the Twenty-ninth Convention of the Laundry- owners National Association, held in Detroit in 1912, by action of the Executive Committee, there was created a standing Committee on Legislation for the Correct Labeling of Fabrics. The contributor of this chapter has served as Chairman of this Committee since its establishment. The purposes, both primary and incidental, are on record in the various numbers of the L. N. A. Year Book*, to which those readers who are interested in the detailed history of the efforts toward pure fabric legislation are referred, but it is in place to point out here some of the salient features of the progress of the work. As the designation of the Committee implies, the primary objective of the work undertaken was to secure protective legislation which should result in minimizing the possibility of deceptive practices in the manufacturing and distribution of textiles and garments. While the interest of the laundry industry in such an endeavor would appear to be quite obvious, it developed that the committee had to assume an incidental function, certain educational responsibilities, not only in its relations with the public and members of Con- gress, but also in connection with the Laundryowners National Association membership. So that, as often hap- pens in a pioneering enterprise, the incidental or secondary purpose attracted the major efforts, which were productive of the most substantial benefits. The work of this committee ♦Especially 1916 number L. N. A. Year Book, Page 74. 153 The Conservation of Textiles on textile defects marked the beginning of the study of textile conservation by the Laundryowners National Asso- ciation. When in May, 1917, the Laundryowners National Association was invited to send a representative to partici- pate in the National Textile Conference, held under the auspices of the U. S. Bureau of Standards, the files of the Committee were turned over to the Department of Chemical Engineering of the L. N. A. Service Bureau, the Director of which was appointed to represent the laundry industry in the Textile Conference. Since textile research is essentially, though not entirely, of a chemical nature, to turn the re- search work of the Committee over to the Department of Chemical Engineering seemed to be the logical procedure. The results of the continuation of this work are pre- sented in the preceding chapters. This does not mean that the work is finished, but w^e have in this book, for the first time, a comprehensive and usable presentment of the avail- able information on the subject of conservation of textiles. An assimilation of the information by the personnel of the industry, and from them a diffusion of the knowledge to the general public through the medium of advertising and that other great medium of publicity, personal contact, will be of inestimable value to the users of textiles, a group as com- prehensive in extent as society itself. The indirect benefit which will accrue to the industry through the spread of the habit of the discriminative purchasing and using of fabrics cannot be over-estimated. The Laundryowner and his employees must know textiles in order to properly perform the duties he has assumed from the public. He must also know textiles in order to protect the industry from the impositions that might be placed by the uninformed or dishonest among the users, manufacturers and distributors of fabrics. Many ways in which the information herein presented may be used to the ends indicated have been pointed out in the pre- 154 Pure Fabric Legislation ceding pages. Others will be suggested to the minds of the careful reader. Books are helpful only when they are carefully read and the information obtainable from them is thoughtfully applied. While the Committee on Legislation for the Correct Labeling of Fabrics has been relieved of its research respon- sibilities, it is still alive to its original primary purpose. The interests of the public, the honest producer and dis- tributor of textiles, as well as the interests of the laundry industry, still demand legislation of some sort that will pro- mote the use of truth in selling fabrics. Every laundry- owner in every community can help to bring this legisla- tion about. First, he must, through his associations with the re- tailers and the public, let it be known in a modest way that he possesses information on the subject of textiles; that he knows good textiles and how to launder them, and furthermore, that he recognizes faults in fabrics and some of the commonly practiced deceptive tricks. The matter of deceptive practices in the making and selling of fabrics should not, however, be emphasized to the extent of distracting attention from the more common defects in textiles which are naturally incident to manufacturing processes. The impression should be conveyed to the public, as well as to representatives in Congress whose aid in the furtherance of this matter is sought, that there is no intention on the part of the supporters of the proposed textile law to restrict the market or to hamper the honest producer or dealer. The object of the legislation sought is to promote greater care in the weaving and dyeing of fabrics and to protect the interest of the honest producer and dealer as well as the consumer and launderer by re- quiring a label on all textiles sold under interstate commerce regulation and that this label must state the truth and only the truth. 155 The Couscri'ation of Textiles The Textile Committee welcomes this splendid book and asks for the co-operation on the part of the Laundryowners National Association which the use of the information contained herein will unquestionably facilitate. J. Clair Stone, Chairman, Committee on Legislation for the Correct Labeling of Fabrics, Laundryowners National Association. Elk Laundry Co. St. Paul, Minnesota. 156 Index PAGE Abuse of fabrics by users 149 Acid corrosion of fabrics 100, 101, 103, 104, 122 Acid dyes 92 Aniline dves 97 Animal fibers 27, 30, 31 Artificial and true silk, differentiation of 26 Artificial dyes 91 Artificial silk 25 Artificial silk, indentification of 25 Artificial silk, manufacture of 25, 26 Artificial silk, physical characteristics of 26 B Basic dyes 93 Bedford cords 75 "Boiled-off" silk, structure of 24, 25 Cellulose acetate 25 Cellulose hydrate 25 Chemical Engineering:, department of 7, 154 Circular corrosion of "fabrics 100, 101, 103, 104, 105, 122 Claims, settlement of 98, 99 Classification of dyes 91 Classification of fibers 15 Clothing, history of 13 Committee on fabric legislation, relation to the Department of Chemical Engineering 154 Committee on legislation for pure fabrics 153, 156 Committee on pure fabric legislation, chairman of 156 Committee on pure fabric legislation, duties of 153, 154 Conservation of fabrics 142 to 152 Conservation of fabrics, by user 149 Conservation of fabrics, responsibility of laundry 150 Conservation of fabrics, retail merchant in 146 Corrosion by dyes 95, 124, 125 Corrosion of fabrics, responsibility of launderer for 106-110 Corrosion in fabrics, responsibility of manufacturer for 123-128 Corrosion in fabrics, responsibility of wearer for 110, 11 1-120 Corrosion of fabrics 98-128 Corrosion of fabrics by acid 100, 101, 103, 104, 122 Corrosion of fabrics by stripping salts 127, 128 Corrosion of fabrics, circular 100, 101, 103, 104, 105, 122 Corrosive materials 98-128 Corrosive materials to fabrics Ill 157 Index — Cont. PAGE Corrosives encountered in various professions 118 Cotton 15-18, 80 Cotton fibers 14, 15, ' 16 Cotton, mercerized 17, 18 Cotton, origin of 15 Cotton, schreiner finish on 18 Cotton, sizing of 80 Cuts 82, 84, 85, 87, 88 Damages 62-75 Damages, detection of cause of 102, 104, 106, 122 Damages in Bedford cords 75 Damages in pile fabrics 53, 57 Damage in terry fabrics 53, 57 Damages, mechanical 82-89 Department of Chemical Engineering 7, 154 Department of Chemical Engineering, relation to Committee on Fabric Legislation 154 Detection of causes of damages 102, 104, 106, 122 Development of power laundry industry 7 Differentation of artificial and true silk 26 Direct dyes 91 Duties of committee on pure fabric legislation 153, 154 Dyes, acid 92 Dyes, aniline 97 Dyes, artificial 91 Dyes, basic 93 Dyes, classification of 91 Dyes, corrosion by 95, 124, 125 Dyes, direct 91 Dyes, mordant 95 Dyes, natural 91 Dyes, relation to laundry industry 90 Dyes, salt 93 Dyes, sulfur 96 Dyes, vat 96 Fabrics, abuse, by users 149 Fabrics, action of sunlight on 9 Fabrics, agencies of responsibilitiy in conservation of 144 Fabrics, circular corrosion of 100, 101, 103, 104, 105, 122 Fabrics, conservation of 142-152 Fabrics, corrosion of 98-128 Fabrics, corrosion of, by acid. 100, 101, 103, 104, 122 Fabrics, corrosion of, by stripping salts 127, 128 Fabrics, damage in terry 53, 57 Fabrics, damages in pile 53, 57 Fabrics, finish of 80 158 Index — Cont. PAGE Fabric, ideal 38 Fabric, legislation for pure 153, 154, 155, 156 Fabrics, materials corrosive to Ill Fabrics, mixed 29 Fabrics, paper 76, 77, 79 Fabrics, pile 53 Fabrics, structure of pile 53, 56, 58, 59, 60, 61 Fabrics, structure of terry 53, 56, 58, 59, 60, 61 Fabrics, terry 53 Fabrics, three-thread pile 56, 59, 60, 61 Fabrics, three-thread terry 56, 59, 60, 61 Fabric, variations from the ideal 39 Failures in textiles, responsibility for 8, 9 Fancy weaves 36 Felting of wool 22 Fibers, animal 27, 30, 31 Fibers, classification of 15 Fibers, cotton 14, 15, 16 Fibers, effect of length 48, 49, 50, 51, 54, 55 Fibers, linen 14 Fibers, origin of 13 Fibers, preparation of linen 18 Fibers, silk 22, 23, 24, 25 Fibers, vegetable 27, 30, 31 Fibers, wool 14 Finish of fabrics 80 Finish, schreiner on cotton 18 Flaws in weaving 66, 68, 69 Floats, advantages of 36 Floats, disadvantages of 36 Floats, long 70, 71 H Heavy threads 66, 67 History of clothing 13 I Ideal fabric 38, 39 Identification of artificial silk 25 K Knots 62, 63, 64, 65 L I.aunderer's responsibility for corrosion in fabrics 106-110 Laundry industry, relation to dyes 90 Laundry, responsibility for conservation of fabrics 150 Legislation for pure fabrics 153, 154, 155, 156 Length of fibers, effect of 48, 49, 50, 51, 54, 55 159 Index — Cont. PAGE Linen fibers 14 Linen, origin of 13 Linen, preparation of fibers 18 Linen, sizing of 80 Loose spinning 39, 51, 54, 55 Linen, structure of 19, 21 Long floats 70, 71 "Lustron" 25 M Manufacturer's responsibility for corrosion in fabrics 123-128 Materials corrosive to fabrics Ill Mechanical damages 82-89 Mercerized cotton 17, 18 Mordant dyes 95 Mordants 94, 95 Mordants, improper use of 124^, 125, 126 N Natural dyes 91 O Overbleaching 123 Paper in fabrics 76, 77, 79 Perishability of textiles 7 Physical characteristics of artificial silk 26 Physical characteristics of wool 22 Pile fabrics 53 Pile fabrics, damages in 53, 57 Pile fabrics, structure of 53, 56, 58, 59, 60, 61 Pile fabrics, three-thread 56, 59, 60, 61 Plain weave 33, 34 Power laundry industry, development of 7 Professions, corrosives encountered in various 118 Pure fabric legislation 153, 154, 155, 156 Pure fabric legislation, duties of committee on 153, 154 Pure fabrics, committee on legislation for 153, 156 R Raw silk, structure of 23, 2^ Removal of stains, procedure chart 13"* Research in textiles, importance of ' Research in textiles, incentive toward ° Responsibility for conservation of fabrics 14^ Responsibility for failures in textiles 8, 9 Responsibility of launderer for corrosion in fabrics 106-110 160 Index — Cont. PAGE Responsibility of laundry in conservation of fabrics 150 Responsibility of manufacturer for corrosion in fabrics 123-128 Responsibility of wearer for corrosion in fabrics 110, 111-120 Retail merchant in conservation of fabrics 146 s Salt dyes 93 Satin weave 35 Satin weave, slipping of 51, 52 Schreiner finish on co ton 18 "Scratch-up" 74 Settlement of claims 98, 99 Shrinkage 72, 73 Silk, artificial 25 Silk, difi"erentation of artificial and true 26 Silk fibers 15, 22, 23, 24 Silk, manufacture of artificial 25, 26 Silk, origin of 22 Silk, preparation for spinning 22 Silk, structure of "boiled-off" 24, 25 Silk, structure of raw 23, 25 Silk, weighting of 80 Sizing of cotton 80 Sizing of linen 80 Slipping of satin weave 51, 52 Snags in fabric 82, 83, 86 Spinning, early stages of 13 Spinning, loose 39, 51, 54. 55 Spinning of silk, preparation for 22 Stains, procedure chart for the removal of (insert) 134 Stripping salts, corrosion of fabrics by 127, 128 Structure of linen 19, 21 Structure of pile fabrics 53, 56, 58, 59, 60, 61 Structure of silk, "boiled-off" 24, 25 Structure of silk, raw 23, 25 Structure of terry fabrics 53, 56, 58, 59, 60, 61 Structure of wool 20, 21 Sulfur dyes 96 Sunlight, action on fabrics 9 T Tensile strength 80 Terry fabrics 53 Terry fabrics, damage in 53, 57 Terry fabrics, structure of 53, 56, 58, 59, 60, 61 Terry fabrics, three-thread 56, 59, 60, 61 Textile research, activities of the Department of Chemical En- gineering in 7 Textile research, importance of 7 Textile research, incentive toward 8 Textiles, ideal in 38 161 Index — Cont. PAGE Textiles, importance of research in 7 Textiles, incentive toward research in 8 Textiles, perishability of 7 Textiles, responsibility for failures in 8, 9 Textiles, uneven shrinkage in 72, 73 Textiles, use of poor materials in 76, 77, 78, 79 Three-thread pile fabrics 56, 59, 60, 61 Three-thread Terry fabrics 56, 59, 60, 61 U Uneven shrinkage 72, 73 Users abuse of fabrics 149 Vat dyes 96 Vegetable fibers 27, 30, 31 Viscose 25 W Washing of wool 22 Wearer's responsibility for corrosion in fabrics .110, 111-120 Weaves, fancy 36 Weaves, plain 33, 34 Weaves, satin 35 Weaves, slipping of satin 51, 52 W^eaving, early stages of 13 Weaving flaws 66, 68, 69 Weighting of silk 80 Wool, comprehensiveness of term 21 W'ool, early use of 14 Wool, felting of 22 Wool fibers 14 Wool, origin of 21 Wool, physical characteristics of 22 Wool, structure of 20, 21 W^ool, washing of 22 162 THE LIBRARY UNIVERSITY OF CALIFORNIA Santa Barbara THIS BOOK IS DUE ON THE LAST DATE STAMPED BELOW. Series 9482 UC SOUTHERN REGIONAL LIBRARY FACILITY A 000 580 650