^%,- 1/ H DYER'S ASSISTANT IN THE ART OF DYING WOOL AND WOOLLEN GOODS. EXTRACTED FHOM The Philofcphical and Chymical Works of thofe MOST IMINENT AUTHORS) FERGUSON; DUFAY ; IIELLOT; GEOFFERY ; COLBERT ; And that reputable French Dyer, MoNs. DF. JULIENNE. TRANSLATED FROM THE FRENCH, WITH Additioss a>ul Pp.actlcal Explrime::^. By JAMES HAIGH, Late Silk and Muslin Dyer, Leeds, A NEW EDITION. PRINTED For J. Mawman, (SuccefTar to Mr. Duly} in the Poultry, LONDON: And for T.Wjlson & R. Spence, the Frmtsrs, F]i^h-Ouf?g,:;e, YORK. Jwjo 1800. THE PREFACE. HERE are very few arts fo extenfive as that of dvinsf ; and althoudi thofe principal comnioditie.-, clotliing and furni- ture, receive their chief iniprovement and value therefrom, it is neverthelefs very far from being brought to perfe6lion. A long pra^iice, found judgment, and great atten- tion, will form a good and expert Dyer. ^lany Dyers can work with fuccefs in a number- of colours only which depend on each other, and are entirely ignorant of the rell, or have but a very imperfect idea of them. A Philofopher, who ftudies the art of dying, is in fome meafure afionilhed at the multiplicity of new objefts which it affords^ every (lep prefents new difficulties and ob- fcurities, without hopes of any inftrutlion from the common workmen, who feldom know more than fafts and culiom. Their manner of explaining themfelves, and their common terms, only afford more darknefs, which the uncommon and often ufeleiscir- A 2 cumftartce IV PREFACE. cumiLances of their proceedings render more obfcure. Before we enter into the particulars of dying v.'ool, it is neccfl'ary to give an idea . XIII. Of the Coccus Polonicus, a colouring Infeft 126 XIV. OftheRedofMa7 XXVII. Of the Manner of mixing Wool of dif- ferent Colour?, for Cloths, or mixed Colours, (Colours mixed in the Loom) 169 XXVIII. Of CONTENTS. XVU CHAP. PAGE XXVIII. Of the Method of preparing the Pattern Felts, or Mixture for an Eflay 171 XXIX. OfPoIilhRed ■ ■ HS PART II. ON THE LESSER DYE. I. Of the dying of Wool by the Lefler Dye 175 11. Of the dying of Flock or Goats' Hair 177 Sulphuring of Wool ' 183 The Theory of the Dilfolution of Flock ib. III. Of the Manner of ufing Archil IS? Baftard Scarlet by Archil 1S9 IV. Of Logwood or Canipeachy ■ 191 The Raven Grey ■ 195 V. Of Saxon Blue and Green ib. Blue on Cloth, Stuff, or Yarn 196 Chyniic for Green » " 197 VI. Of Brazil Wood 198 VII. OfFuftic . 201 VIII. OfRoucou 203 IX. Of the Grains of Avignon ■ 204< X. Of Turmeric 205 XI. Of Silver Grey 20G Another excellent Silver Dye 207 Inftrudions on the Proof of dyed Wool ^ and Woollen StufFs ■■ ». PART III. ADDITIONAL ARTICLES. I, Of Flowers —— . — 217 Of Blud^Iowers — ■ - . 218 Of Red and Yellow Flowers 219, 220 Of White Flowers i . 221 II. Of XVUl - CONTENTS. CHAP. PACE II. Of Fruits 2-22 III. Ot Leaves 226 JV. Mr. Lewis's Hiftory of Madder, and Man- ner of treating it ■< ■ i ■ 2C3 V. OfFuftic 231 VI. Of Nephritic Wood . , 232 VII. Mr. Fergufon's Hiftory of Logwood as a colouring Drug ■ ■ ■ 233 VIII. The Procefs of Pruffian Blue 254 IX. Of Alkanet Root . 237 X, Of Alum 238 XI. Chjniical Hiftcrj of Saunders, end its Diii'erence from other Red- Woods 259 XII. OfVerdign/e 240 TItE THE dyer's assistant. PART I. CHAP, I. OF BLue. WOOL and woollen ftuffs of all kinds, are dyed blue without any other preparation than wetting them well in luke-warm water, fqueezing them well afterwards, or letting them drain: this precaution is nectflarv, that the colour may the moreeafily infinuate itfelt into the body of the wc«l, that it may be equally difperfed through- out ; nor is this to be O'nitted in any kind of co- lours, whether ihe fubjetSt be wool or cloth. As to wool in the fleece, which is ufed in ma- rufadturing cloth, as well the mixt as ctner forts, and which they are obliged to dye before ttiey are fpun, they are prepared in another manner, viz. they are fcoured, and thereby diveiled of the natural 20 THE DYERS ASSISTANT. natural fat they had when on the body of the ani- mal *, As this operation is properly the Dyer's, and is indifpenfable in wool which is to be dyed before it is fpun, let the colour be what it will, 1 fliall give the proper procefs. This operation is not every where alike, but this is the method followed in the manufadlory ot Audly in Normandy, where cloths are moft beau- tifully manufadured. A copper containing twenty pails is ufed for this purpofe j they put twelve pails of water, and four of urine, (which is generally fermented) the copper is headed, and when tlie liquor is^fo hot as to bear the hand without fcsrldiiSg, ten or t A'elve pouiids of wool, that ftill continues its natural fa-t, are put in and Itft in tlie copper about a qi>3rter of an hour, flirring from time to time with flicks j. it is then taken out and put to drain on a fcray ; from thence it is carried in a large fquare bafket» and placed in running v/ater, two men (iirring it to and fro for a confidcrabie time with long poles, till it is entirely cleanfed of its fat ; then it is talcen out and placed in a bafket to drain : while this wool is thus preparing, a like quantity may be put into the copper, and thus proceed till the whole is fcoured. If the liquor is too much wafted, frefli is to be added, made up of one part urine and three parts water. They generally fcour a bale of wool at once; if it weighed 25Clb. in the' fat, it generally iofes 6olb. in fcouring; but this diminu- tion of weight varies in proportion to the wool be- ing more or lefs fcoured, and in proportion to the more or lefs fat contained therein. Too much at- tention cannot be paid to the fcouring, as it is thereby better difpofed for the reception of the dye. The * The natural fat adhering to tlie wool preferves it in the wart- houffj and alio from moths. THE DYER S ASSISTANT. 21 The fat, which is an oily tranfudation, and flightly partaking of th« quahty of urine retained by the fleece, which is too tiuck to let it out, is foluble in water, ccnfequently, as water alone could not feparate it, a fourth pnrt of urine is put into the copper, which nriuft have been kept fome days, in order to feparate its volatile falts. by fer- mentation ; (I mean tliat it is necefiary this urine iliould begin to acquire a ftrong fmell) this volatile fait, being an alkali, forms with the fat a kind of foap, which is always the refult of all oils and al- kalis whatfoever mixed to?;ether. As foon as foap is formed by the combination of thefe two princi- ples, it becomes foluble in water, and is confe- quently eafily carried off. A proof that a true foap has been formed in this operation, is, that the water which carries it away, whitens as long as any fat is feparated from the wool : if there was a ■fufficient quantity of fermented urine in the copper, the wool will be well fcoured ; if it was not, all the fat would net be changed into foap, and con- fequently the \yool will remain greafy. The fame operation might be performed with fixed alkalis, as with 'the .lee of pot-a(h or pearl-afhes: but as this lee would not only come dearer than urine, it might alfo damage the wool, if the exaft propor- tion was not applied. I am convinced by feveral experiments, that thefe cauftic falts do eafily de- ftroy all animal fubftances, as wool, fi'.k, &c. 1 beg the reader may take notice, that though in the fequel I do not mention tiiis operation of fcour- ing, it is neverthelefs neceffary for all wool that is to be dyed before it is fpun, as alfo that it is necef- fary to wet thofe that are fpun, and fluffs of all kinds, that the colour may be the more equally diffufed throughout. 0( 22 THE dyer's ASSISTANT. Of the five primary colours mentioned in the Preface, two ot them require a preparation given by roncolcuring ingre-'ients, which, by the acidity and hnenefs of their earth, difpofe the pores of the •wool to receive the colour. This is called the preparation i it varies according to the nature of fnades and colours : the red, the yellow, and the colours derived from them muft be fo treated ; black muft have a preparation peculiar to itfelf ; blue and brown require none ; it is iufHcient that the wool be thoroughly fcoured and wetted ; and even for blue, it fuffices to dip it into the vat, flir- ring it well, and letting it remain, more or lefs, according as the ground of the colour is wanted. For this reafon, and ajib that many colours previ- ouily require a blue ihade to be given to the wool, I fliall begin with it, and give thereon the moft exa£t rules in my power. It is an eafy matter to dye wool blue, when the vat is once prepared, but it is not fo eafy to prepare the vat, which is the moil difficult part of the Dyer's art. ]n ail the other prccefTes, it is fufhcient to follow the fimple operations tranfmitted from mafters to apprentices. Three ingredients arc ufed in the blue dye, viz. garden-woad or pafte), the woad, and the indigo. I (hall give the preparation of eacl), beginning with the garden-woad. CHAP. II. OF THE GARDEN-WOAD, OR PASTEL- V^^OAD. THE garden-woad is a plant cultivated in many parts of Holland and France, and fDight be in Frgiand or Ireland, to the great ad- vantage of the hufbandoian ; it is made up in bales, generally THE DYER S ASSISTANT. 1^ generally weighing from one hundred and fifty pounds to two hundred ; it refembles little clods of dried earth, interwoven with the fibres of plants; it is gathered at a proper feafon, and laid up to rot, and then made into fmall balls to dry. Several circumftances are to be obferved in this preparation; on this you may fee the regulations of Monf. Colber t on Dyes ; the beft prepared comes from thediocefe of Alby in France. 7 he Vatfet to TVork. A copper, as near as pofTible to the vat is filled with water that has ftood fome time, or, if fuch water is not at hand, a handful of Dyer's woad or hay is added to the water, with eight pounds of cruft of fat madder. If the old liquor from a vat that has been ufed in dying from madder can be procured, it will fave the madder, and produce a better effedl. The copper being filled, and the fire lighted about three in the morning, it muft boil an hour and a quarter, (fome Dyers boil it from two hours and a half to three ; it is then conveyed by a fpout into the woad vat, in which has been previoufly put a peck of wheaten bran. Whilft the boiling liquor is emptying into the vat, the balls of woad niuft be put one after another into the vat, that they may be the eafier broken, raked, and ftirred ; this is to be continued till all the hot liquor from the copper is run into the vat, which, when little more than half full, muft be covered with cloths fomewhat larger than its circumference, fo that it may be covered as clofe as polfible, and left in this ftate for four hours. Then it muft be aired, that is, uncovered to be raked, and frefli air let into it; and to each bale of v^'oad, a good meafure of ware fiung 24- THE dyer's assistant. flung In ; this is a concealed name for lime that has been fljcked. This meafure is a kind of wooden fhoveJ, which ferves to meafure the lime grofsly j it is five inches broad and three inches and a half long, containing near a good handful ; the lime being fcattered in, and the vat well raked, ii mufl be again covered, leaving a little fpace of about four fingers open, to let in air. Four hours after, ihe muft be raked, without ferving her with lime j the cover is then put on, leaving, as before, an opening for the air ; in this manner fhe muft be let to ftand for two or three hours. Then fhe may be raked well again, if fhe is not j-et come to work ; that is, if file does not cafl blue at her fur- face, and that fhe works or ferments flili, which may be known by raking and plunging with the flat of the rake in the vat ; being well raked, (he is to remain fiill for one hour and a half more, carefully obferving v;hether fhe cafts blue. She is then to be ferved with v.ater, and the quantity of indigo judged necefifary is to be put in : it is com- monly ufed in a liquid f^ate, the full of a d\e- houfe kettle for each bale of woad ; the vat being filled within fix finger-breadths of her brim, is to be raked and covered as before; an hour after filling her with water, fhe muft be ferved with lime, viz. two meafures of lime for each bale of woad, giving more or lefs according to the quality of the word, and what may be judged it will fpend or take of lime. I hope the reader will excufe my plainnefs ; this Treatife being wrote for the Dyer, I muft fpeak the language he is ufed to; the Philofopher will eafily fubflitute proper terms, which perhaps the v^'ork- man would not underf^and. There are kinds of woad readier prepared than others, fo that general and precife rules cannot be given en this head. It 2 mi " % THE dyer's assistant. 25 muft alfo be remarked, that the lime is not to be put into the vat till rtie has been well raked. The vat being again covered, three hours after a pattern niuft be put in, and kept entirely covered for an hour ; it is then taken out to judge if (he be fit to work. If fhe is, the pattern muft come out green, and on being expofed a minute to the air, acquire a blue colour. If the vat gives a good green to the pattern, ihe muft be raked, fcrved with one Of two meafures of lime, and covered. Three hours after, 'fhe muft be raked, and ferved with what hme may be judged neceffary ; fhe is then to be covered, and one hour and a half after, the vat being pitched or fettled, a pattern is put in, which muft remain an hour to fee the ef- tcifts of the vvoad. If the pattern is of a fine green, and that it turns to a deep blue in the air, another muft be dipt in to be certain of the tf^tO: of the vat. If this pattern is deep enough in colour, let the vat be fiJed up with hot water, or if at hand, with old liquor of madder, and rake her well. Should th.e vat ftiU want lime, ferve her with fuch a quan- tity as you may judge fufticient by the fmell and handling. This done, fhe muft be again covered, and one hour after put in your ftuffs, and make your overture. This is the term ufed for the firft working of wool or ftuffs in a new vat. J Marks by which you may know hoh.v io conducl a Vat regularly, A. vat is fit to Work when the grounds are of a green brown, when it changes, on its being taken out of the vat, when the flurry is of a fine Turkifli or deep blue, and when the pattern, which has been dipt in it for an hour, comes cut of a fine deep grafs green. When ftie is fit to work, the B bever •26 TK£ dyer's assistant. tever has a good appearance, clear and reddiQi, ard the drops and edges that are formed under the rake in lifting up the bever are brown, txamin- ing the appearance of the bever, is lifting up the liquor with the hand or rake, to fee what colcur the iiquor of the vat has under its furface. The fcdiment cr grounds n:,uft change colour (as has been already obferved ) at being taken out of the bever, and muft grew brown by being expofed to the external air. The bever or liquor tnuft fe^t neither too rough nor too greafy, and murt not fn.ell either of lime or lee. Thefe are the d;uin- guilhing marks of a vat that is ht to work. Hoiu to know when a Vat is crcclid by too gnat or too fmall a Quantity of Lime ; Extremes wijich nH0 be avoided. When more lime has been put in than was fuf- ficier.t fcr the woad, it is esfily perceived by dip- ping in a pattern, which, inftead cf turning to a beaucl.'Ui grafs green, is only daubed with a fteely green. The grounds do not change, the vat gives fcarcely any fiurry, and the bever has a Arong odor of quick lime, or its lees. This error is rectified by thinning the vat, in which the Dyers differ ; fome ufe tartar, others bran, of which they throw a bufhel into the vat, more or lefs i9;proportion to the quantity of lime uied, ethers a pail of urine. In feme places a large iron channg-diih is made ufe of, Icng enough to reach from the ground to the top of the vat, this chatin2;-.dilh or furnace has a grate at a foot diftance frcm its bottom, and a funnel coming from under this grate, and afccnding to the top of the chafing- difh, .which is to give a;r to, and kindle the coais Vthich are placed en the grate. This furnace is funk THE dyer's assistant. 2/ funk in the vat, near to the furface of the grounds, fo as not to touch them, and is faftened with iron bars to prevent its rifing. By this method the Hme is raifed to the furface of the hquor, which gives an opportunity to take off" with a fieve what is thought fuperfluous; but when this is taken out, the neceflary quantity of ware mufi: be carefully ret^ored to the vat. Others again thin the vat with pearl alhes, or tartar boiled in ftale urine ; but the befl: cure, when fhe is too hard, is, to put in bran and madder at difcretion ; and if fhe be but a little too hard, it will fufiice to let her remain quiet four, five, or fix hours, or more, putting in only two hats full of bran and three or four pounds of mad- der, which are to be lightly ftrewed on the vat, after which it is to be covered. Four or five hours after, flie is to be raked and plunged, and accord- ing to the colour, that the flurry which arifes from this motion, aillimes and imprints on the whole liquor, a fre(h proof is tnade by putting in a pattern. If file is cracked, and cafls blue only when fne is cold, fhe mufl be left undillurbed, fometimes whole days without raking ; wlien fhe begins to flrike a tolerable pattern, her liquor mufl: be re-- heated "or warmed; then commonly, the lime, which feemed lo have loft all power to excite a fer- rrientation, acquires new ftrength, and prevents the vat from yielding its dye fo foon. If flie is to be haftened, fome bran and madder are to be thrown on, as alfo one or two bafkets of new woad, which helps the liquor that has been re- heated to fpend its lime. Care mufl be taken to put patterns in each hour, in order to judge, by the green colour which they acquire, how the lime is worked on. By thefe trials fhe may be conduced with more exactnefs, B 2 for 28 THE dyer's assistant. for when once a vat is crackedv by too great or too fmall a quantity of lime, (he is brought to bear with much more difficulty. If while you are en- deavouring to bring her to work, the bevcr grows a little too cold, it muft be heated by taking off fome of the clear, and inftead thereof, adding fome warm water ; for when the bever is cold, the woad fpends little or no li^ne ; when it is too hot, it retards the action of the woad, and prevents it from fpending ihe lime.; therefore it is better to wait a little, than to haften the vats to come to work when they are cracked . A vat is known not to have been fufHciently ferved with lime, and that (he is cracked, when the bcver gives no flurry, but infiead thereof gives only a fcum, and when (he is plunged or raked, (lie only works, ferments and hi(res, (this noife is made by a great number of air bubbles that burft as foon as they form) the li- quor has alfo the fmell of a common fewer oriink, or rotten eggs ; it is harfh and dry to the touch : tlie grounds when taken out do not change, which ge- nerally happens when a vat is cracked for want of lime. This accident is chiefiy to be apprehended when a vat is opened and a dip made in her ; for if her ftate has not been looked into, both in regard to the fmell as well as raking and plunging, and that the Ruffs be imprudently put in when the woad has fpent its lime, it is to be feared the vat may be loft ; for tl^.e fluffs being put in, the fmall quantity of lime that fli!I remains in a ftate to ae in the new vat. This vat heated again, is con- cluded in the fame manner, that is, three rakings are made the firfl day, obferving at each raking, whether fhe wants iime ; for in this cafe, the quantity judged neceffary muft be given. Blue made of woad alone, according to the opinion of fome perfons prejudiced in the favour of old cuftoms, is much better than that wliich the woad gives with the addition of indigo. But then this blue would be much dearer, beoaufe woad gives much lefs dye than indigo, and it has been found by repeated experience, that four pounds of fine indigo from Guatimala, produced as much as a bale of Albigeois woad or paftel ; and five pounds as much as a bale from L'Auragais, which generally weighs two hundred and ten pounds. So the ufmg of the indigo with the woad is a great faving, as one vat with indigo fhall dye as much as three without it. Indigo is generally put into new vats after the woad yields its blue, and a quarter or half after fhe is to be ferved with lime; as this folution of indigo is already impregnated with fome of its difTolution^ the lime mufl be given with a more fparing hand than where the woad is ufed alone. At the re-heat- ing, the indigo is put in on Saturday night, that it may incorporate with the bever, and that it may ferve as garnifh by its lime. The indigo that is brought from Guatinvala in ^ America is the befl ; it is brought over in the fhape of fmall flones, and B4 ©f 32 THE dyer's assistant. of a deep blue ; it muft be of a deep violet colour within, and when rubbed on the nail, have a copper hue ; the lighteft is the beft. It is neceffary to ob- ferve, that for the better conducting of a woad vat, and to prevent accidents, a manufacflurer ought to have a good woadman, this is the name given to the Journeyman Dyer, whofe principal buiinefs is to conducl the woad, practice has taught him more than this treatife can furnifn. I Ihall make ibme refiedions neceflary to attain a more perfect knowledge of this procefs. The woad vat mull never be re-heated but when fit for working ; that is, fhe muft have neither too much nor too little lime, but be in fuch a ftate as only to want heating to com.e to work. It is known file has too m.uch lime (as has been before obferved) by the quick fmell ; on the contrary, a want is known by t])e fwsetiili fmell, and by the fcum which rifes on the furface by raking, being of a pale blue. Care muft be taken when a vat is intended to be re-heated, not to ferve her with lime in the evening, (unlefs in great want of it) for if flie was too much ferved wirli it, (lie might next day be too hard, as the Dyers term it ; for by heating her again, a greater action is given to the lime, and makes her fpend it the quicker. Frefti indigo is commonly put into tlie vat, each time flie is re-heated, in pro- portion to the quantity to be dyed. It would be r.eedlefs to put in any, if there was but little work to do, or only light colours wanted. It was not per- mitted by the ancient regulations of France, to put more than ftx pounds of indigo to eacli b^le of v.oad, becaufe the colour of the indigo was thought not lafting, and that it was only the great quantity of woad v.hich cculd fecure and render it good ; but it is now afcertained, both by tlie experiments of Moniieur Dufay, and thofe which 1 have fmce made THE dyer's assistant. 33 made, that the colour of indigo, even ufed alone, is full as good, and refifts as much the adion of the air, fun, and rain, as that of paftel or woad. When a vat has been heated two or three times, and a good part has been worked off, the fame li- quor is often preferved, but part of the grounds are taken our, which is replaced by. new woad j (this is called vamping); the quantity cannot be pre- fcribed on this occafion, for it depends upon the work the Dyer has to do. Practice will teach all that can be wiflied for on this head. There are Dyers who preferve liquor in their vats feveral years, renewing them with woad and indigo in propor- tion as they work them ; others empty the vat en- tirely, and change the liquor when the vat has been heated fix or feven times, and that (he gives no more dye. A feries of pradice alone will Ihow which of thefe is preferable. It is however more reafonable to think, that by renewing it now and then, more lively and beautiful colours may be obtained, and the beft Dyers follow this method. In Holland they have vats v.'hich do not require to be fo often heated. Mr. Van Robbais had iome of thefe made fome years fince for their royal ma- nufadtory at Abbeville. The upper parts of thefe vats, to the height of three feet, are of copper, and the reft lead : They are alio furrounded with a fmall brick wall, at feven or eight inches from the copper ; in thi'j interval embers are put, wh.ich keep up the heat of the vat a long time, fo that fhe remains feveral days together in a condition to be worked, without the trouble of heating her over again. Thefe vats are much more coftly than the others, but they are very convenient, efpeciaily for the dipping of very light colours ; becaufe the vat is always lit to work, though fhe be very weak ;, this is not the cafe of the others, which oencrally p ^ • < 34- THE DYER S ASSISTANT. m:.k.e the colour a E-^eat deal deeper than required, unlefs they are fet to cool confiderably, and then it happens that the colour is not fo g^od, nor has it the fame bnghtnefs. To make t ii:fe light colours in common vats, it is better to work fome pui pofely that are ftrong with woad and weak of i."dii:o ; fuch give their colours flower, and light colours are made with greater eafe. As to the vats made after the Dutch fafhion, and vvr.icii have already been mentioneJ, the four w'l.ich Mr. Van !<.^b'oais has in his manutaclory, are fix feet in depth, of which three feet and a half in the upper pan are copper, and the two feet and a half of the bottom are lead. Fhe diameter at the bottom is four feet and a half, and that at the top live feer four inches. To return to the obfervations on heating the common vats. If the vat was heatel when cracked, that is, when (he has- net quit? lime enough, rtie would turi. in the heating without being perceived, and perchance be entirely loft, as the- beat vve-uld foon finifh the fpcnding of the lirr.e. which was in too fmnli a quantity. If this is perceived in time, it muft be helped by pouring it back into tl,e vat without more heatmg ; then feed her v.ith lime, and not heat her till {he is come to work. On the re-p.esting. fome of the grounds muft be put into the crpper with the liquor or beverj and irreat care muft be taken not to boil it, becaufe the volatile neceffary in this operation would evaporate. There are fome Dyers, who, in heating their vats, do not pat in the in./igo immediately after the liquor is pour^c" from the c pper into the var, but wait fome hr urs till they fee her come to work : (his they do z^ a precautiun, left tlie vat ftiouid fail, and the indigo be left ; but by this method, the indigo does not fo freely yield its colour, as they are obliged THE dyer's assistant. 35 obliged to work her as foon as (he is fit, that (he may not cool, lb thAt the indigo, not being entirely diflblved, nor altogether incorporated, has no effect:. Jt is therefore better to put it into the vat at the /ame time the liquor is caft in, and rake her well after. If th3 vat is heated over again without her cofning to work, fhe muft not be fcummed as in the common heatings, as the indigo would be car- ried off thereby, whereas, when Ihe has worked, this fcum is formed of the earthy part of the indigo and woad, united with a portion of lime. When too much lime is put into a vat, you muft wait for her till fuch time as fhe has fpent it, or it may be accelerated by heating it, or by putting in ingredients which deftroy in part the a£tion of the lime, fuch as tartar, vinegar, honey, bran,fome mine- ral acid, or any matter that will become four; but all thefe correctors wear out the dye of the indigo and woad, fo that the befl method is", to let it fpend of its own accord. A vat is not commonly fed with lime, but on the firft, fecond, and fometimes the third day, and it is a!fo remarked, not to dip the violets, purples, or any other wool or fluffs which have previously a colour that may beeafily damaged; the fucceedmg day after its being fed with lime, as it is then too aftive, it dulls the drft colour ; the firth or fixth day the crimfon may be dipt to give them a violet, and the yellows for green ; foilowmg this rule, the colours will always be bright. When a vat has been re- heated, (hz pnufl: come to work before fhe is ferved with lime; if this was done a little too foon, (he would be cracked ; the fame thing would happen if fome of the grounds were put into the copper. The moft efFectual me- tl)od in this i-afe is to let her relt before (he is worked, until (he comes to, whicti often happens ■ in two, three, or fdur hours, and fometimes a day. B6 Byy 36 THE dyer's assistant. By ufing light or weak, lime, (he grows too hard ; becaufe this light lime remains in the liquor, and does not incorporate with the grounds. This is known by the ftrong fmell of the liquor, and on the contrary the grounds have a fweetifh fmell, whereas the fmell ought to be equal in both. The beft way then is, to let it fpend itfelf, by raking her often, in order to mix the lime with the grounds, until the fmell of the vat is reftored, and the flurry becomes blue. A woad vat may be fet without the addition of indigo, but then fne yields but little colour, and only dyes a fmall quantity of wool or fluffs ; for one pound of indigo, as has already been obferved, affords as much dye as fifteen or fixteen pounds of woad. J fet one of this kind to try the qualities of v.'oad by itfelf, and I could not find that indigo was any way inferior to it, either for the beauty or fo- lldity of the colour. As lime is alwaysufed, and fometimes four liquors, in the fetting of a vat, this is the proper place to fpeak of their preparation. Preparation of Lime. That the lime may be properly flacked for the Dyer's ufe, feveral pieces are immerfed in water, one after another, and when each has remained till it begins to crackle, they are taken out to put in others, and after this manner they are caft into an empty vefTel, where the lime finifhes flacking, and reduces itfelf to powder, confiderably augmenting its bulk ; it is afterwards fifted through a canvas, and kept in a dry hogfhead. Sour liquors are not only neceffary in fome cir- cumftances of fetting a woad vat, but alfo in fome of the preparations given to wool and fluffs pre- vio\:s THE dyer's assistant. 37 vlous to their being dyed ; they are prepared after the following manner. Preparation 0/ ^our Liquors, ■ •" ,-< ; :,{\r\ ' '.^- • A copper of the fize required is filled with r^^ver water, and when it boils, it is flung into a hog- Ihead, where a fufficient quantity of bran has been put, and ftirred with a ftick three or four times a- day. The proportion of bran and water is not very material ; I have made a good liquor by put- ting three buHiels of bran into a veffel containing two hundred and fourfcore quarts. Four or five days after, this water becomes four, and confe- quently fit for ufe in all cafes, where it will not be detrimental to the preparations of wool that are independent of dying. For it may happen, that wool in the fleece which has been dyed in a liquor where too great a quan- tity of fourwater has been pur, will be harder to fpin, as the fediment of the bran forms a fort of ftarch that glues the fibres of the wool, and pre- vents their forming an even thread. I-muft here take noticeof the bad cuftom of letting fourliqucrs re- main in copper- vefliels, as I have feen in fomeeminent dye-houfes; for this liquor being an acid, corrodes the copper, and if it remains long enough to take in a portion of this metal, it will caufe a defect both in the dye and in the quality of the fluff: in the dye, becaufe the diflblved copper gives a greenifli caft; in the quality of the ftufi^, becaufe the copper diflblved preys on all animal fubftances. The Dyers are often ignorant of the caufe of thefe de- fers. I flatter myfelf to have omitted no effential point on the woad vat : if any difficulties or accidents, which I have mentioned, are not found in the prac- tice- 38 THE dyer's assistant. tice t'ey are not cot;fiderabie, and an eafy remedy' v;ill be found by thofe who make thcmfelves fami- liar with the working part. 1 he reai-iers who hj" ".no idea of this work, may , . , ,. Is ho, • ' 1 / think me too prohx, ano nr.d repetitions ; but thole who intend to make ufe of what I have taug!;t in this chapter, will perhaps reproach me foTnot hav- ing faid enough on the fubj:61:. Thole that read this chapter with attention, will not be furprized that the mafter-pi'sce for appren- tices to Dyers of the great dye, is, to fet the woad vat and work her. CHAP. in. OF THE FIELD WOAD VAT. I HAVE but little to fay on this woad vat, dif- fer en r^frdrh' that wl'iich hag been related of the -paftel or garden woad. The woad is a plant cul- tivated in Nor. randy, arid prepare- after the Ta-ne manner the garden woad is m Languedoc. The method of cultivatii:g it may be fceh in the French ''General Irllruiftions on Dy.'s," of the '28th of March, 1671, from the article 259 to 288, where it treats of the culture and preparation of the paf^el and woad. The woad vat is fet at work after the fame manner as that of paftcl ; all the difference is that it has Icfs flrergth and yields lefs dye. There follows a dcfcription of the woad vat, which I car- ried on in fii:all, and in a bath heat fimilar to that of the psi^ei in the foregoine chapter. I placed in a copper a fmall vefle! containing fifty quarts, and filled two-thirds with a liquor made of river water, one ounce of madder, and a little weld, putting in at the fame time a good handful THE dyer's assistant. 39 handful of wheaten bran and live pounds of woad. The vat was well rnkcd anc: covered ; it was then five in the evening ; it W\\s agam rake.i at feven, nine, twelve, two, and four o'clock j the woad was then working, that is, the vat was flovviy coming to work, as i have already related of that of the paftel. Pretty large air bubbles forined theinfelves, but in a faiall quantity and had fcarcelv a!;y colour. She was then ferved with two ounces of linie and raked. At five o'clock a pattern was put in; v/hich was taken out at fix, raking her; this pattet'n be- gan to have fome culour ; another was put in at feven, at ei.;ht flie was raked, and the pattern came out pretty bright ; aii evince of indigo wa? then put in ; at nine another pattern, at ten (he was raked, and one ounce of lime was added, becauf'e (he began to have a Iwtetilh fmell ; at eleven a pattern, at twelve flie was raked ; it was thus con- tinued till five, then three ounces of indigo were put in, at fix a pattern, at feven (he was raked. It would then have been proper to have ferved her with water., as ihe was at that time perfeclly come to work, the pattern that was taken out being very green, and turning' of a bright blue. But befidcs that I was fatigued, having fat up the whole night, 1 chofe rather to put her back to the next day, to fee her efFe<5l by day-light , and for that purpofe, I put one ounce of lime, which kept her up till nine in the morning: from time to tiire patterns wefe put in, the laft that w;;s taken out was very beauti- ful ; file v^'3s ferved with a liquor compofed of water, and a fmall handful of bran. She was raked, and patterns put in from hour to hour ; at five fhe was come to work ; ihe was afterwards ferved with lime, and raked to prefcrve her till fhe was to be re- heated. Some 40 THE dyer's ASSISTAN-T. Some time after I fet another with the woad alone without indigo, that I might be able to judge of the lafting of the dye of the woad, which, upon trial, I found to be as good as the paftel or garden woad. Thus all the fuperiority the paftel has on the woad, is, that the latter yields iefs dye than the former. The little varieties that may be obferved in fet- ting thefe different vats at work, prove, that there are many circumftances in thefe procefTes that are not abfolutely necefTary. It appears to me, that the only important point, and that to which the great- eft attention is to be given, is, in the condudling the fermentation with care, and not to ferve her with lime, but when judged neceflary by the indi- cations I have laid do\Nn. As to tb.e indigo being put in at twice, or altogether, a little fooner or later, it appears very indifferent. The fame may be faid of the weld, which I made ufe of twice, and fupprefied the two other times, and of pearl- alhes, which I added in a fmall quantity in the fmall paftel vat, and fupprefled in the woad vat. In fhort, I believe, and it appears to me to a de- monftration, that the greateft regard is to be had to the proper diftribution of the lime, throughout the whole ccurfe of the working of the vats, either to fet them at work, or to re-heat tliem. I muftr alfo add, tliat wlien a wcad vat \k fet to work, fhe cannot be too often infpeited into to know her ftate ; for if there are fome that are backward (which is attributed to the weaknefs of the woad) there are alfo others that very quickly come to- work. I have feen a middling one of feventy pounds of woad, poifoned j becaufe the woad man neglecled to infpefl her as often as Ihe required, and file had been two hours fit to work before he difcovered it ; the grounds were entirely com.e up to the furface of the liquor, and ths whole had a very. THE dyer's assistant. 4I a very four fmell ; It was not pofllble to bring her back, and they were obliged to fling her away, as fhe would in a fhort time have dontradled a fcctid fsnell. The retarding of the adion of the vat may alfo proceed from the temperature of the air ; for the vat cools a great deal fooner in winter than in fummer; tlierefore it becomes neceffary to watcli it attentively, though commonly they are fourteen or fifteen hours before they come to work. I fhall endeavour to explain, in the fequel, how the colouring part of this ingredient, fo neceffary in dying, difplays itfelf; but I mufl: firft of ail fpealc ot vats which are prepared from indigo. CHAP. IV. THE INDIGO VAT. Procefs of making the Indigo in America. INDIGO is the fecula of a plant named 7//// or anil; to make it, three vats are placed the one over the other, in form of a cafcade ; in the firft, called the ffeeper, the plant is put in with its leaves, •bark, and flowers *, and filled with water; fome time after, the whole ferments, the water grows intenfely hot, thickens, and becomes of a blue colour bordering on the violet; the plant, accord- ing to the opinion of fome, depofmg all its lalts, and,^ according to others, all its fubftance. In this ftate, the cocks of the fleeper are turned, and all the water let out ftained with the colouring * In the village of SarguJTa, near the town of Amadabat, the Imljans only iife tlie leaves of the anil ; they fling away the reft of the plant. The bell indigo comes from thence. parts 42 THE DYER S ASSISTANT. parts of the plant into the fecond, called the beater j becaufe this water is beat by a mill or machine that has long iVicks, to condenfe the fubftance of the indigo, and precipitate it to the bottom. By this means the water becomes clear and colourlefs, Hke common water; then the cocks are turned, that the water may run off from the furface of the blue fediment ; after which, other cocks are turned that are at the bottom, that all the fecula may fall into the third vat, called the repofer; for it is there the indigo remains to dry ; it is then taken out to be made into cakes, &c. See, en this fubjeift, Hif-oire des Antilles^ pare le Pert Labett. At Pondicherry, on the coaft of Coromande], tliere are two kinds of indigo, the one a great deal finer than X.\\t other ; the beft is feldom ufcd but to lufrre their filks, the inferior in dying. They augment in price according to their quality; there is fo-.ne which coft from jf pagcdas the bar (which weighs 48 pounds) to 2C0 pagodas. The moft beautiful is prepared nigh Agra. There is alfo a very good kind tiiat comes from MafiJupatan and Ayanon, where the Eaft-Tndia Company have a fsclory. At Chandernagcr it is called nil! when it is prepared and cut to pieces. The indigo of Java is the beft of &11 ; it is alfo the r^eareft, and confequently few Dyers ufe it. Good indigo ought to be fo light as to float on the_ water; the more it finks, the more it may be fufpeiled of being adul- terated by a mixture of eartn, cinders, or pouiided fiates. It muft be of a deep blue, bordering on the violet, brilliant, lively, and ihining ; it muft be finer within, and appear of a Ihining hue. Its goodncfs is tried by diffolving it in a giais of water ; if it be unmixed and well prepared, it wiiidilTolve entirely J if fophiftlcated, the foreign matter will fink to the botto>n. Another method of trying it THE dyer's assistant. 43 it is by burning ; good indigo burns entirely away, and when adulterated, the mixture remains after the indigo Is ccnfumed. Powdered indigo is much more fubje£t to adul- teration than that which is in cakes : for it is a dif- ficult matter that fand, powdered Hates, &c. fhould unite fo as not to form together in different places layers of different matters j and, in this cafe, by breaking the lump indigo, it is eafily difcovered. Alethod of working the Indigo Vet. There are feveral methods of preparing the in- digo vat } I fried all tliofe I knew, and they all fuccecded. I (hall defcribe them after the mcft exait manner, beginning v.'ith that which is the moft in ufe, and ahncfl: the only one known ar Paris. It is a vat which is about five feet in height, two feet diameter, and becomes narrow towards the bottom ; fhe is furrounded with a wall that Jeaives a fpace round her, which ferves to hold embers. Jn a vat of this fize, two pounds of in- digo may at leaft be ufed, and five or fix for the greateft proportion. To fet a vat of two pounds of indigo in fuch a veiTel that may contain about fourfcore quarts, about fixty quarts of river water are fet to boil in a copper for the fpace of half an hour, with two pounds of pearl afhes, two ounces of madder, and a handful of bran j during this, the indigo is prepared after the following manner : ', Two pounds of it are weighed out, and caft into a pail of cold water to feparate the earthy parts. The water is afterwards poured off by in- clination, and the indigo well ground ; a little warm water is put into it, (baking it from fide to fide ; it is poured by inclination into another veffei; what remains is ftill ground, and frefh water put in, 44 THE DYER S ASSISTANT. in to carry off the fineft parts, and thus continued till all the indigo is reduced into a powder, fine enough to be raifed by the water. This is all the preparation it undergoes. Then the liquor which has boiled in the copper with the grounds are pour- ed into the high and narrow vat, as ilkewire the indigo; the whole is then raked with a fmall rake, the vat is covered, and eir.bers placed round her. If this work was begun in the afternoon, a few embers are added at night ; the fame is repeated the next day morning and night. The vat is alfo lightly raked twice the fecond day; the third day, the embers are continued to be put round, to keep up the heat of the vat ; {he is raked twice in the day: about this time, a fhining copper-coloured fkin begins to appear on the furface of the liquor, and appears as if it was broken or cracked in fe- veral places. The fourth day, by continuing the fire, this fkin or pelicle is more formed and clofer ; the flurry, which rifes in raking the vat, appears, and the liquor becomes of a deep green. When the liquor is in this (late, it is a lign that it is time to h.l che vat. For this purpofe a frefli liquor is made, by putting into a copper about twenty quarts of water, with one pound of pearl afhes, a handful of bran, and half an ounce of madder. This is boiled a quarter of an hour, and the vat is ferved with it ; (lie is then raked, and caufes a great quantity of flurry to rife, and the vat comes to work the next day ; this is known by the quantity cf flurry with which fhe is covered by the fkin or copper-fcaly cruft which fwims on the liquor, which, although it .appears of a blue- brown, is never thelefs green underneath. This vat wa-, much longer coming to its colour than the others, becaufe the fire was too ftrong the fecond day, oiherwire fee would have been fit to THE dyer's assistant. 45 to work two days fooner. This did no other damage but retarded her, and the day (he came to work, we dipt in ferges weighing thirteen or four- teen pounds. As this caufed her to lofe her ftrength, and the liquor being diinin.ifhed by the pieces of ftufF that had been dyed in her, Ihe was ferved in the afternoon with frefh liquor, made with one pound of pearl afhes, half an ounce of madder, and a handful of bran ; the whole was boiled together in a copper for a quarter of an hour; the vat being ferved with it the was raked, covered, and a few embers put round. She may be pre- ferved after this manner feveral days, and when fhe is wanted to work, flie niuft be raked over night, and a little fire placed about her. When there is occaflon to re-heat, and add in- digo to this kind of vat, two thirds of the liquor (which then is no more green, but oi a blue-brown and almoft black) is put into a copper ; when it is ready to boil, all the fcum that is formed at the top is taken off with a fieve ; it is afterwards made to boil, and two handfuls of bran, a quarter of a pound of madder, and two pounds of pearl aHies are added. The fire is then removed from the copper, and a little cold water caft into it to ftop the boil ; after which the v/hole is put into the vat, with one pound of powdered indigo, diluted in a portion of the liquor as before related ; after this the vat is raked, covered, and fome fire put round ; the next day flie is fit to work. When the indigo vat has been re-heated feveral times, it is neceflary to empty her entirely, and to fet a frefh one, or fhe will not give a lively dye ; when fhc is too old and flale, the liquor is not of fo fine a green as at firft. I put feveral other vats to work after the fame method, with different quantities of indigo, from one 46 THE dyer's assistant. one pound to fix ; always obfervin^ to augment or diminilh the other ingredients in propcrtion, but always one pound cf pearl afhes to each pound of indigo. 1 have fince made other experiments, which proved to me that this proportion was not abfolutely neceiTar}' ; and I make no doubt but that feveral other means might be found to make the indigo come to as perfedl a colour. I fliall, nevertlielefs 5 proceed to Tome ether obfervations on this vat. Of ail thcfe I fct to work, after the manner de- fcribed, one only failed me, and that by neglect- ing to put fire round her the tecond day. She never came to a proper colour ; pov/dered arfnic was put in to no effect; red-hot bricks were alio plunged in at different times ; the liquor turned of a green- ilh hue, but never came to the proper colour ; and having attempted feveral other means without fuc- cefs, or without being able to find out the caufe of her not fucceeding; I caufed the liquor to be emp- tied and ca{\ away. All the other accidents that have Iiappened me in conducting ihe indigo vat, have only lengthen- ed the operation ; fo that this procefs may te look- ed upon as very eafy when compared to that of the woad vQt. I have alfo made feveral^ experiments on both, in which my chief view was to ihorten the time of the common preparation ; but not meeting with the delired fuccsfs, I fhall not relate them. The liquor of the incigo vat is not ex^dlly like that of the woad ; its furface is cf a blue- brown, covered with coppery fcales, and the under part of a beautiful green. I he ftuff or wool dyed in this is green when taken out, and becomes blue a mo- ment after. — ^Ve have already feen that the fame happens 10 the fluff dyed in the woad vat; but it is remaikable, THE DYER S ASSISTANT. 47 remarkable, that the liquor of the laft is not green, and yet produces on the wool the fame effed: as the other. It muft alfo be obferved, that if the liquor of the indigo vat be removed out of the , veflel in which it was contained, and if too long expofed to the air, it lofes its green and all its qua- lity, fo that, although it gives a blue colour, that colour is not lafting. I (hall examine this more particularly in the fe- quel, and endeavour to give the chymical theory of this change. C H A P. V. THE COLD VAT WITH URINE. A VAT is alfo prepared with urine, which yields its colour cold, and is worked cold : for this purpofe four pounds of indigo are powder- ed, which is to be digefted on warm afhes twenty- four hours, in four quarts of vinegar ; if it is not then well difTolved, it muft be ground again with the liquor, and urine is to be added little by little, with half a pound of madder, which muft be well dikjted by ftirring the liquor with a ftick ; when this preparation is made, it is poured into a veflel filled witli 250 quarts of urine ; it matters not whether it be frelh or ftale ; the whole is well flir- red and raked together night and morning for eight days, or till the vat appears green at the furface when raked, or that (lie m.akes flurry as the com- mon vat ; (he is il^en fit to work, without more trouble than pievioufly raking her two or three hours before. This kind of vat is extremely con- venient, for when once fet to work, Ihe remains good till fhe be entirely drawn, that is, till the in- digo 4? THE dyer's assistant. digo has given all its colour ; thus fhe may be' v.orked at all times, whereas the common vat muft be prepared the day before. This vat may at pleafure be made more or lefs confiderable by augmenting or diminilhing the in- gredients in proportion to the indigo intended to be made ufe of; fo that to each pound of indigo add a quart of vinegar, two ounces of madder, and fixty or feventy quarts of urine. This vat comes fooner to work in fummer than in winter, and may be brought fooner to work by warming fome of the liquor without boiling, and returning it into the vat; this procels is fo fimple that it is almoft impofTible to fail. When the indigo is quite fpent, and gives no more dye, the vat may be charged again without fetting a new one. For this purpofe, indigo muft be difiuived in vinegar, adding madder in propor- tion to the indigo, pouring the whole into the v::t, and raking her night, and morning, and evening as at firft, {he will be as good as cefcre ; however fhe muft not be charged this way above four cr five times, for tlie ground of the madcier and iniligo would cuil the liquor, and in confeqoence render the colour Isfs bright. I did not try tliis metiiod, and therefore do not anfwer for the fuccefs ; but here fellows another with urine wir.ch gives a very lafting blue, and which 1 prepared. Hot Vat with Urine. A pound of Indigo was lleeped twenty-four hours in four quarts of clear urine, and when the urine became very blue, it was run through a fine fieve into a pail, and the indigo which could not pafs, and which remained in theHeve, was put with four quarts of frefh urine 5 this was fo continued THE DYER S ASSISTANT. 49 till all the indigo had parted through the ficve vviih the urine ; this lafted about two hours. At four in the afterncon three hoj^fheads of urine were put into the copper, and it was made as hot as could be without boiling. The urine cart up a thick fcum, which was taken up with a broom and caft out of the copper. It was thus fcummed at dif- ferent times, till the-e only remained a white and ligjit fcum ; the urine, by this means fufRciencIy purified and ready to boil, was poured into the wooden vat, and tlie indigo prepared as above, put in ; the vat was then raked, the better to mix the indigo with the urine: fo on after, a liqucr was put into the vat, made of two quarts of urine, a pound of roach-alum, and a jiound of red tartar. To make this liquor, the alum and tartar were firft put into the mortar, and reduced to a tine powder, ' upon which the two quarts of urine were poured, and the whole rubbed together, till this mixture, which rofe all of a fudden, ceafed to ftrment : it was then put into the vat, which was ftrongly raked; and being covered with its wooden cover, (he was left in that ftate all night ; the next morning the liquor was of a very green colour ; this was a flgn rtie was come to work, and that (he might have been worked if thought proper, but not!un whereas dyin^^ it at twice, it takes eight or ten hours. 2. At t'iC end of three hours, in which time the wool vould be dyed, taken out, and the green taken cfF, the vat being yet very hot; after raking and letting her reft a couple of hours, the fame wool might be returned into her, which would heighten the colour very much ; for all wool that has been dyed, aired, and' the green taken cfT, always takes a finer colour thjn new or white wool, which might remain iwer.ty hours in the vat. Great care mufl be tsken to air and take off the preen of the dyed parcels of wool that are taken cut cf tlv€ vat haftily, that the air may ftiike them eqaa'ly, without which the blue colour will not be u'ifcrm thrcughcut the wool. There are manu'aciurtrs who fay that cloths, w)-cfe wool has received this ground cf blue with urine, cannot be perftQly fcoured at the fulling rr.ill, even at twice; others vouch the contrary, 2:-d'l am of opinion the laft fpeak the truth ; yet, it the fiifl are right, it might be fufpecled tl.at the a imal oil of the urine becoming r-finous by dry- i:r2 on the wool, or by uniting with th.e oil with v.hivh the wool is moifttned ; for its other prepara- tions mere ftrongly refift the fuller's earth and foap, than a fimple oiF by expreflion. To remedy this, the wool ought to be well wafhed in a running water after it is dved, twifted, aired, the green taken off and cooled. 'Be it as it may, the woad vat will aiv'avs be preferred in the great dye-houfes to thole kii.d's of indigo vats made with urine or otherwife ; a- d for this'^reafon, that with a good woad vat, ar^d an ingenious woad man, much more work is dtfpatched than with all the other blue vats. '^ 1 have THE DYERS ASSISTANT. 53 I have defcribed the indigo vats in this treatife, not with a defign to introduce them in the hrg,e manufat^lories, but to procure- eafy means to the Dyers in fmall, and fmall manufadtories, to whom I wirti this work, may be of as much advantage as to the others. I fhall t'nerefore here defcribe a cold vat, which may be ufed with advantage by thole who dye fmall ftuffs, in whofe compofition thread and cotton enter. The colour is lafting, but ca:.- not be made ufe of for wool. C H A P. VI. OF THE COLD INDIGO VAT WIHOUT URINE. Ir is cuftomary nt Rouen, and in fome other cities of France, to dye in a cold indigo vat, different from that defcribed in the foregoing chap- ter, and more covenicnt, as flia comes to work. fooner, and has no bad fmell. She is prepared after the following manner: Diffjlve three pounds of indigo powdered fine- ly, in a glazed earthen pot, with three pints o£ ftrong foap- boiler's lees, which is a ftrong Ice of foda and quick lime. The indigo takes abouc twenty- four hours diffolving, and when perfedlly fo, remains fufpended in the liquor, thickens it, and gives it the coafulence of an extradl. At the fame time, three pounds of fifted flacked liir.e muft be put into another vefTe], with fix quarts of water, and boiled together for a quarter of an hour ; when fettled, the clear is poured off by inclination. Then three pounds of green copperas are to be dif- folved in this clear litiie- water, and the whole let to reft till the next day. Three hundred quarts < f water are then put in a large deal-vefifel (no other C 3 wood 54 THE DYER S ASSISTANT. wood but deal will do, for it would dull and blacken the dye, efpecially if if was oak.) The two folu- tions which were maie the day before are put in, the vat, is well raked, and AiiFered to reft. 1 have leen her come to colour in two hours after, but this never tails to happen the next day at farihert. She makes a ereat deal of flurry, and the liquor becomes ur" a tine green colour, but a little more orv the yellow than the green of the common vat. When this vat begins to fpend herfcif, Hie is to be qu ckened without putting in frefh indigo, by making a fmall liquor with two pounds cf green copperas, diiTolved in a fulBcient quantity of lime- water; but when the indigo has fpent all its colour, (he ir.uft t;e re-charged by putting in frelh, dilTolved in fucli a iee as has been defcribed. IVater af Old Iron. Some Dyers put into this vat a little water of old iron, it is a mixture of vinegar and water, in which fome old iron nails have been put to ruit. 'J hey lay thi< makes the colour more hiling, but I have experienced, that it is fufHciently fo without this, and ss good as ah the other blues, of wliich I havf: bttore given the prqjaration. I fet feveral fmali vats ; t ofe that required to be licaied were put in a bath or fand heat, in fmall eiafs bodies j and thrfe that are worked cold were left v;ithout doing any thing to them. 1 hefe laft are eafy, being fuJiicient to diminilh the quantity of liquor, and of all the ciher ingredients, in pro- p.rrion to the vefTei that is to be fet, and it is ai- xnoft impofiihle to rail. As to that which 1 firft defcribed, which is fet hot, as it is fomewhat more difficult, and that fe- veral mi^ht be willing to try the e'xperiment, which in THE dyer's assistant. 55 in itfelf is curious, and neither requires expence ror apparatus to perform in fmall, 1 fliaH give the procefs of one which fuccceded perfectly, and in which 1 had delignedly put a greater quantity of indigo than ufuallyis done in the common propor- tion. I boiled two quarts of water Vv'ith two fcruples of madder and tour ounces of pearl-afhes ; after boiling a quarter of an hour, I !>ul it into a body, which held about four quarts, and had been pre- vioully heata^i with warsn water,- atul in wliich I had put a quarter of a handful of bran. The whole was well ftirred with a deal fpatula, the glafs body put on a very gentle fand-heat, which only kept it warm, and pretty near the fame degree of heat that is required for the common indigo vat. The fire was kept all night, and the ne.xt day under the fand-heat, without any feniible change happening; it was only ftirred twice a-day. The next clay fome flurry began to rife, and a copper- Coloured fkin formed on the furface, and tlie liquor was of a green-brown ; it was then filled up with a liquor made of a quart of water, two ounces of pearl-aflies, and a little bran. I mixed the whole together, ther. let it reft. It c^mie perfedHy well to colour, and the next day I dyed feveral middling pieces of ftuiTs and wool. Thefe fmall vef- fels may be re-heated and charged again as cafily as a large one. 1 think i have nothing more to fay concerning -the method of fetting to woik all thefe kinds of blue vats ; yet I am perfuaded that there are feveral other means pradifed in different places, and that it is even eafy to contrive new ones ; liowevcr, I can affirm that all thofe which ] have defcribed are very fure, and th^t- they have all been worked feveral times with tlie fame fuccefs. C4. CHAP. 56 THE dyer's assistant, CHAP. vn. OF THE METHOD OF DVING BLUf. 'HEN the vat is once prepared and come to work, the dying of wool or ftufFs is eafy. Wet ihem we!) in clear warin water, wring- iiig and dipping them in the vat, and keeping them in more or iefs time, according as the colour is re- t;uTed in fliade. From time to time the fluff is aired, tiiat is, taken out of the vat and wrung, fo that the liquor may fall back into the vat, and ex- pofed a little to the air, which takes off the green in one or two minutes ; tor let what vat foever be ufed, the fluff is always green at its coming our, and only takes the blue colour in pr >portion as the air adls upon it. Jt is al'b very necciliry to let the green go off' before it is returned into the liquor to receive a fecond (hade, as being then better able to judge of its colour, and knov/ if it is requifite to give what is c.iUed one or feveral returnings. It is an ancient cuHom among Dyers to reckon thirteen ftiades of blue from the deepeft to the Jight(ff. Although their denominations be fome- what arbitrary, and that it is impoiTible exactly to iix the juft pafTi^ge from Oi.e to the other, I fliail r.otwlthllandlng give tlie names. They are as fol- low, beginning with the lighted:: miik-blue, pearl- blue, pale blue, fijt-blte, middling- blue, (ky blue, queen's blue, turkilh-blue, watchet-blue, g?.ner- blue, mszare-n-blue, deep-bine, and very deep blue, 'i hefe diftiniftions are not equally received by all Dyers, nor in all provinces, but the mcft part are known ; and it is the only method that can be taken to give an idea of the fame colour, whgfe only difference is in being more or iefs deep. Ir THE dyer's assistant. 57 It Is esfy to make deep blues. I have already faid, that to effed this, the wool or fluffs are to be returned feveral times into the vat j but it is not (o in refpe£l to light blues ; for when the vat is rightly co ne to work, the wool can feldom be left in fliort time enough, but that it takes more than the fhade required. It often happens when a cer- tain quantity of wool is to be dipped, and that it cannot ^11 be put in at the fame time, that what goes in at {v(i is deeper than the other. There are fome Dyers who, to obviate this inconveniency in making very light blues, which they call milk and water, take fome of the liquor of the indigo vat, and dilute it in a very great quantity of luke- warm water ; but this method is a bad one, for tha wool dye-i in this mixture has not near fo lading a colour as that dyed in the vat; as the altering iii- gredients which are put into the vat with the in- digo, ferves as much to difpofe the pores oi" tiie fubje6V which is dipped in, as to the opening of the colouring facula which is to dye it, their con- courfe being necefTary for the adheflon.of the co- lour. The befl method of making thefe very light blues, is to pafs them either ina woad or in- digo vat, out of which the colour has been work- ed, and begins to cool. Fhe woad vat is Aill preferable to thatof the indigo, as it does not dye fo foon. The blues made in vats that have been workel are duller than the others ; but they nay be pretty fenlibly roufed by pafTing the wool or fluffs in boil- ing water. This prcidice is even neceflary to the perfeition of all blueMh^des; by this the colour is not only made brighter, but alfo rendered more fecure, by taking off all that is not well incorpo- rated with the wool ; it alfo prevents its fpoiting the hands or linen, which commonly happens, and C 5 the 5? THE dyer's assistant. the Dyers, to gain time, negle6l this precaution. After the wool is taken out of the warm water, it is necelBry to walh it again in the river, or at leaft in a furiicient quantity of water for the earring off all the fuperfiuous loofe dye. The bell method to render the blue dye trlghter, is by tiling them with a thin hquor of melted foap, and arterwards clcanfmg them from the foap by warm water, and, if convenient, by rinfing them in an old cochineal liquor. This meihod is to be Tsken with deep blues ; but if the fame was taken with very hght blues, the)^ v/ould lofe their bright blue luftre, and incline to grey. 1 hope to have removed all difficulties on the preparation cf blue, and in the method of dying it. Some Dyers, for tliC fake of gain, fpaie the woad and indigo,- and ufe for blue, orchei or logAOcd, and bra-^il jthis ought to be e::prefs!y forbid, though this adulterfated blue is often brighter than a laP.ing and legitimate blue. 1 fha'l take notice of this in the chapters treating; on the lelVer dye. 1 iiijli now explain the theory of the invllibis change cf the blue dye. This colour, which I Ihall here only confider in relation to its ufe in the dying of ftufFs cf what kind foever, has hitherio been exrraded cniy from the vegetable world, and it does not appear that we can hope to ufe in tliis art the blues the psinters employ : fuch are the Pruflian blue, which holds of tiie animal and mi- neral kind*; the azure, which is a vitrihed mi- neral fublhnce ; the ultrattiarine, which is pre- pared from a hard itonej the earths that have_a blue colour, &c. Thefe, matters cannot, without lofing their colour in whole or in parr, be reduced into * T74?, Monf. Macquer, of the Royal Academy of Sc'e.-irtr* four-« the means of uli ig the PruflTian falae to rfye filk and c!oth» ;". i bl'at wholj brightnei'i /ccsirid nl :hc blues hitherto kncvo. THE dyer's ASSISTAN'T. ^ into atorrs fufficiently minute, fo as to be fufpended in the faline liquid, v;hich mud penetrate the fibres of the aniina! and vegetable fubflances of which fluffs are mannfa61:ured ; for under this name linea and cotton cloths muft be comprehended, as well as thofe wove of fiik and woul. Hitherto we know but of two plants that yield blue after their preparation : the one is viie iiatis or glauflum, which is called pafccl in Languedoc, and woad in Normandy. Their preparation confifts in a fermentation continued even to the putrefac- .tion of all the parts of the plar.t, the root excepted ; and ccnfequently in the unfolding of al! their prin- ciples into a new combination, and freih order of iheie faine principles, from whence follows an union of infinite tine particles, which, applied to any ibbjefl whatever, reflects the light on thera very difrerent from what it would be, if thcfe lame particles were fliil joined to thofe which the fer- jvieatation has feparatcd. The other plant is the anil, whicli is cuklvpted in the £all and Well Indies, out of .which they prepare that fecula that is fent to Eijrope under the rinsne of incHgo. In the preparation of this plant the Indians and Americans, more induilrious than ouriflves, liave found out the art of feparating only the colouring paits of the plant frotn the ufelefs ones ; and the French and Spanifh colonies have imitated them, and thereby made a confiderable in- crer.fe of commerce. That the indieo, fuch as is imported from Ame- rica, fhouid' depofit on the wool or fluffs the co- louring parts required >;v: the Dyer, it is infuied fc- veral v;ays, the procffles of which we have already • given. They may be reduced to tliree ; the coJd indigo vat may ferve for thread and cotton ; thciic that are made ufc of hot, are fit for fluffs of any .kind whatever. C 6 6o THE dyer's assistant. In the cold vat, the indigo is mixed with pearl- a(hes, coppera-i cr green vitriol, lime, madder, snd bran. The hot vats are either prepared with water or urine j it with water, pearl- aihes, and a littie madder muft be added ; if with urine, alum and tartar muft be joined to the indigo. Both of thefe vats, principally intended for wool, require a rro- derate degree of heat, but at the fame time ftrong enough for the wool to take a hfting dye, 1 mean fuch £3 will withftand the deftroying a£\ion of the air and fjn, the proof rf dyes. I l^^ve prepared, as I faid before, thefe three vats in fmall, in cylindrical glafs veflels, expofed to the light, in order to fee what psfied before the infufion came to a colour* thst is, whether it was green beneath tl.e f!urry at the furface, which is a fign of inttrnal fermentation. I have faid that tlie green co.cur of the liqaor is a condition abfolutely eflen- tia!, and without which^ the colour the fluff would ttkt would not be a gocd dye, and would ahr^oft entirely difappcar on the leaft proofs. I fhall now give a dcfcription of the cold indigD vat in fmall, for the changes are much better feen in her, and for this reafon, that what happens in the two others is not very eflcntially different. It is proper to take notice, that whai 1 friall call par:^ in this Obfervation of Experiments, is a mcafure of the weight of four drachms, of all matter either liquid cr folid, and that it will be this quantity that muft be fuppcfed, each time that I ufe that word in the detail cf thei'e experiments. I put three hvmdred parts of water into a veffe!, containing five hundred and twelve, cr eight quarts, in which I dilfo'ved fix parts of copperas, which gave the liquor a yellow dye. Six parts of pot- aflies were alio difiblved by themfelves in thirty-fix pans of water. The folution made, I digefted in it THE dyer's assistant. 6 I It fix parts, or three ounces, of inoigo of St. Do- mingo well ground ; it was left over a very gentle fire three hours. The inciigo fwelled, and t^-.klng up a larger fpace, rofe from the bottom of this al- kaline liquor, with which it formed a kind of thick fyrup, which was blue. This was a proof that the indigo was only divided, but not dilToIved i for had its folution been perfefl, that thick liquor would have been green ioftead of blue ; for all liquor that has been tinged blue by a vegetable of any kind, grows green on the admixion of an alkaline fair, either concrete or in a liquid form, whether it be a fixed or volatile. From hence the reafon is difccvered why indigo does not dye a fluff of a lalVing blue when its li- quor is not green ; for its folution not being com- plete, the alkali cannot z6i upon thefe firft ele- trentary panicles ; as for example, it a6ts on the tinifiure ot violets, which is a perfect folution of the colouring parts of thofe flowers, which it turns green in an inftant, and on the firft contact. I poured this thick blue liquor into the folution of vitriol, and after well (baking the mixture, I added fix parts of lime that had been flacked in the air; it was cold weather when this experiment was made ; the thermometer was at two degrees undtr the freezing point, v/hich was the caufe that this was near four days coming to a colour, and the fermentation, which mufl naturally enfue in all vitriolic liquor, where an alkaline fait has been put in, fuch as pot-afhes, and an alkaline earth, was carried on with fo much flownefs that very little fcum appeared on the furface of the liquor. In a hot feafon, and by making ufe of lime newly cal- cined, thefe kind of vats are fometimes fit to dye in four hours. £acb 62 THE DY£R*S ASSISTANT. Each time I ftirred the, mixture with a fparula, I obferved tliat the iron of the vitriol or copperas was the tirft thst precipitated to the bottom of th;-vi{re!> and thit the alkaht.e fait had precipitated it, to join itfeir to the acid. TliUS in this proctfs of the cold indigo vat, a rartsr of vitriol after the onanner of Tachenius is ff.nxied; wh.erea'j by ihecoiTiinon me- thod of preparing this neutral fait, the acid of vitriol is poured on a true alkalii e fait, fach as fait of tartar or pot-allics. This again is a circuni- ftance that leads infer.fibly to the theory of tlie good dye. 1 deSre the reader to take notice of this, as ir will occur in t! e fequel of this obferva- tiou, as we]) as in other chapters. 'Ihc earthy, parts of the iixe precipitate next after the iron -, they are eafi'v difiinauifned by the whitenefs, which aife-yct difficult to diltinguifli v^heri the colouring parts cf the indigo are fuffi- cier.tly ioo'.e.ied. in Ihort, under this wl'.ite ecrth ■ the lecu.a of the indigo cepofits itfelf, and by de- grees rarilie; in fuch a n'-anner, tl.at this fubftance, which the firfl d2y was only the eighth of an inch above the precipitated lirre, rofe infennbly within half an inch of the furface of the liquor, and the third day grew fo opaque and muddy, that nothing fuiiher could be difiinguifhcd. Th.is rarcf.:(5t!on of the inJiio, flow in winter, quick in fummer, and which may be accelerated m winter by heating the liquor to hi teen or tixteea degrees, is a proof that a real fermentation hap- pens in the mixture, -which opens ti.e little iump3 of indigo, and divides them into particles of an ex- treme finenels; then their furfaces being multiplied almoft ad injinitum, they are fo much the more equally diftributed in the iiquor, which depodts them equally on the fubje^b d'pp-d in to i^ke liis dye. THE dyer's assistant. 6} If fermentation comes on hafti'y, or in a feW hours, whether on account ot -the heat of the air, or by the help of a fmall fire, a great quantity of flurry appears j it is blue, and its reflection they have alfo named coppery, becaufe the colours of the rainbow appear in it, and the red and yellow here predominate ; however this phsenomenon is not peculiar to indigo, fince the fame reflection is perceived in all mixtures that are in actual fermenta- tion, and particularly in thofe which contain fat particles blen>-^ed wit!! falts, urine, foot, and feveral other bodies put into fermentation, (how on their furface the fa;jie variegated colours. The flurry of the indigo vat appears blue, be- caufe expofed t J tf.e external air ; but if a fmail portion ot the liquor which is under it be taktn up with a fpoon, it appears more or lefs neen in pro- portion as it is filled with colouring particks. In the courfe of this obfervation, 1 (hall fnow the rea- fon of this -difrerence, or, at iealf, a probable ex- plication of this change of blue, which, as I have faid before, is abfolufely neceflfary for fucceeding'ia the procefs dcfcrifced. VVhen the vat is in this flate, it has already ^eea faid that cotton, thread, cloths wove from then, -Sec. may be dyed in her, and the colours whichi they take are of the good dye; that is, this cotton and thread will nnaintain then), even after remaining a fuitable time in a folution of white foap, acfualiy boiling. This is the proof given theai prrterafele to any othei^, becaufe the linen and cotton clollis "Vinuft be wafhed with foap when dirty. Though the indigo liquor which is in this ftate can make a lafting dye without the addition of any other ingredient ; the Dyers who ufe this cold va£ add, as in the other hot vats, a deccdlion of mad- , (Ser and bran inxrommon water run through a fieve j " this 64 THE dyer's assistant. this is what they call bever. They put madder to infure, as they fay, tlie colour of the indigo, be- caufe this root affords a cole ur \o adhefive that it {lands all proofs ; they put the bran to foften the water, which they imagine generally to contain foTie portion of an acid fat, which, according to their opinion, muil be deadened. This was the opinion of the French Dyers againft indigo in the days of Monfieur Colbert ; and as this minifter could not fpare lime to fee the ex- periments performed in his prefence, on ihe foun- dation of this report, he forbad indigo to be ufed alone. But fince the Government has been con- vinced, by new ex()€riments naae by the late Mr. Dufay, that the {lability of t'.e blue dye of this in- gredient was fuch as could be defired ; the new re- gulation of 1^37 licenfes the Dyers to ufe it alone, or mixed with woad ; fo thst if they continue to ufe the madder, it is rather becaufe this root giving a pretty deep xt&^ and this red mixing with the blue of the indigo, gives it a tint which approaches- the viclet, and a!fo a fine hue. As to the bran, its ufe is not to deaden the pretended acid fairs, but to difperfe throughout a quantity of fizey matter j for the fmall portion of flour which remains in it, dividing itfelf into the liquor, mu{l diminifli in fome nieafure its fluidity,, and confequently prevent the colouring particles which are fufpcnded m it, being precipitated too quick, in a liquor which had not acquired a certain degree of tiiickne^s. Notwithflandmg this diflributed throughout the liquor, as well from the bran as the madder, which alfo affords fomething glutinous, the colouring par- ticles will fubfide if the liquor remait.s fome days without being flirred ; then the top of the liquor gives but a feeble tint to the body dipped in, and if a flrong THE DVER'S assistant. 65 a ftrong one is wanted, the mixture muft be raked, and left to reft an hour or two, that the iron in the copperas, and the grofs parts of the lime may fall to the bottom, which oiherwife would mix with the true colouriiig panicles, and prejudice their dye, by (^epofiting on the body to be dyed a fub- ftance that would have but little adhefion, which in drying would become friable, and of which each minute part would occupy a fpace, where the true colouring particle could neither introduce nor de- pofit itfelf by an imniediate contacSt on the fubjc(5l. Not to deviate from the method followed by the Dyers, I boiled one part of grape-madder and one of bran, in 174 parts of water : this proportion of water is not neceflary, more or lefs may be put, but 1 wanted to fill my vefTel, which contained 512 parts. I palTed this bever through a cloth and fqueezed it, putting this liquor, ftiil hot, and which was of a blood-red, into the imligo liquor, obferv- ing the neceflary precautions to prevent the break- ing of the glafs vefl'ej* The whole was well ftirred, and two hours after the liquor was green, and confequenlly fit for dying. It dyed cotton of a lafting blue, fomewhat brighter than it was be- fore the addition of the red of madder. I Ihall now endeavour to find out the particular caufe of the folidity of this colour; perhaps it may be the general caufe of the tenacity of all the reft ; for it appears already, from the experiments above related, that this tenacity depeitds on the choice of falts, which are added to the decoctions of the co- louring ingredients, when the fame ingredients contain none in themfelvcs. It from the confe- quences which fliall refult from the choice of thefe falts, of their nature, and of their properties, it be admitted (and it cannot be fairly denied) that they afford more or lefs tenuity in the homogeneous colouring 66 THE dyer's assistant. colcuHn^ parts of the dying ingredients, the whole theoiy of this art will be difcovered, without hav- ing recourfe to uncertain or contefted caufes. One may eafiiy conceive that the falts added to the indigo vats not only open the natural pores of the luhje£t to be dyed, but alfo unfold the colcur- ing atoms of the indigo. In the other preparations'of dyes (ro be men- tioned hereafter) the v.'ool'.en fluffs are boiled in a folution of fairs, v.hich the Dye?;; call preparation. In this preparation tart?.r ani nhim are generally ufed. In fotne liours the fluff is taken out, iTight- ly fqueeztd, and kept da"np f rfome days in a cool place, that the faline liquor wLiich remains in it may •ftill ad, and prepare it for the reception of the dye of thefe ifigredients, in the decoction of which it is plunged to boil again. Without this prepara- tion, experience fliuws that the colours'will not be lafting, at leaft for -he greateft part -, for it mufl: be owr.ed that there are fome ingredients which yield laAing colours, though the (haff has not pre- viouily undergone this preparation, becaufe the in- gredient contains in itlelf thefe falts. It IS therefore necefTjty, that the natural pores of the fibres of the wool thould be erihuged and cleanfed by the help of thofe falts, which are aU. ways fomewhat corroding, and perhaps il'.ey open new pores for the reception of tiie colouring atoms contained in the ingredients. The boiling of this liquor drives in the atoms by repeated ftrokeSi The pores already enlarged by thefe falts, are fur- ther dilated by the best of the boiling water ; they are afterwards contrafled by the external cold when the dyed matter is taken cut of the copper, when it is expofed to the external air, or when it is plunged i.nto cold water. Thus the colouring atom is taken in, and detained in the pores or fifiures of * the THE dyer's assistant. 67 the dyed body, by thefpringinefs of its fibres, which have contradted and reftored themfelves tb their firft ftate, and have re-aflunned their primary ftifF- nefs upon being expofed to the cold. If, befides this fpring of the fides, of the pore, it be fuppofed that thefe fides have been plaillered inwardly with a layer of the faline liquor, it will appear plainly that this is another means employ- ed by art to detain the colouring atom ; for this atom, having entered into the pore, while the faline cement of the fides was yet in a ftate of fo- lution, and confequently fluid ; and this cement being afterwards congealed by the external cold, the atom is thereby detained ; by the fpring which has been mentioned, and by this faline cement, which by cryflalization is become hard, forms a kind of maftic which is not eafily removed. If the coloured atom, (which is as fmall as the little eminence that appears at the entrance of the pore, and v>'ithout which the fubjedl would not ap- pear dyed) be fufiiciently protuberant to be expofed to more powerful fhocks than the refiftance of the fides of the cement that retains it, then the dye re- fuliing from all thefe atoms fufficiently retained, will be extremely lafiing, and in the rank of the good dye, provided the faline coat can neither be car- ried off by cold water, fuch as rain, nor calcined or reduced to powder by the rays of -the fun; for every lafting colour, or colour belonging to the good dye, mufi withfiand thefe two proofs. No other can reafonably be expedled in ftuffs defigned for apparel or furniture. I know but of two falts in chymifiry, which-, being once cryfializ.-d, can be moifiened with cold water without diflolving; and there are few befides thefe that can remain fcveral days expofed to the fun, without being reduced to a flour or white 68 THE dyer's assistant. white powder. Thefe are tartar, either as taken from the wine veffels, or purified, and tartar of vitriol. The tartar of vitriol may be made by mix- ing a fait already alkalized, (or that may become fuch when the acid is drove out with a fait whole acid is vitriolic, as copperas and alum); this is eafily efFecled \i it be weaker than the acid of vitriol, and fuch is the acid of all effential falts extracted from vegetables. In the procels of the blue vat, whicli I tried in fmall, to difcover the caufe of its efFe£ls, cop- peras and pot-a(h, (which is a prepared alkalij are mixed together; as foon as rheie fol«tions are united, the alkali precipitates the iron of the cop- peras in form of powder almofl black ; the vitriolic acid of the copperas, divcftevi of its metallic bafis by its union with the alkali, forms a neutral fait, called tartar of vitriol^ as when matJe with the fait of tarrtar and the vitriolic acid already feparatei from its bafis; for all alkalis, from whatever ve- getables they are extracted, are perfecflly alike, pro- vided they have been equally calcined. More difficulties will occur with regard to the water for the preparation of other colours, fuch as reds and yellows. It may be denied that a tartar of vitriol can refult from the mixture of alum and crude tartar boiled -together ; yet the theory is the fame, and I do not know that it can be otherwife conceived. The alum is a fair, confifling of the vitriolic acid united with an earth ; by adding an alkali, the earth is immediately precipitated, and the tartar foon forms ; but inftead of this alkaline fait, alum is boiled with the crude tartar, which is the effential fait of v;ine, that is, a fait compofed of the vinous acid, (which is more volatile than the vitriolic) and of oil, both concentrated in a fmall portion of e^rth. Thi« TiiE dyer's assistant. 6iJ This fait, as is kn iwn to .chymi(!«, becomes alkali by diverting it of its acid. Thus when the alum and crude tnrtar are boiled together, befides the imprelTion which the fibres of the fluff to be dyed receive from the firft of thefe falts, which is fomewhat corrofive, the tartar is alfo purified, and by tlie addition of the earth, which is feparated from the alum, (and wl^ich has near the fame ef- fe<5V upon the tartar, as the earth of Mervie/fy which is ufed at Montpellier in manufaduring cream of tartar) it becomes clear and tranfparent. It may very probably happen, that the vitriolic acid of the alum, driving out a part of the vegetable acid of the tartar, a tartar of vitriol may be formed as hard and tranfparent as the cryflal of tartar. Admitting one or other of thefe fuppofitions, con- fequently there is in the open pores of the wool a faline cement which cryftalizes as foon as the ftufF which comes out of the dye is expofed to the cold air, which cannot be calcined by heat, nor is fo- luble in cold water. I could not avoid making this digreffion. This theory is common to the indigo vat, where urine is ufed inllead of water ; alum and crude tartar in the place of vitriol and pot-a(hes. This urine vat gives a lafling dye only when ufed hot, and then the wool mufl remain in an hour or two to take the dye equally. As foon as the vat is cold, {he f^rikes no more dye; the reafon of this would be difficult to difcover in an opaque metal vat, but in a glafs vciTel it is eafily ken. 1 let this little glafs proof vat cool, and all the green colour, which was fufpended in it while hot, precipitated little by little to the bottom ; tor then the tartar crjflalizing itfelf, and reuniting in heavier mafTes than its moculas were during the heat of the liquor, and its folution, it funk to the bottom 70 THE DYERS ASSISTANT. bottom of the veffel, and carried with it the co- louring particles. When I reftored this liquor to its former degree of heat, after fhaking it, and letting it fettle a while, I dipped a piece of cloth, which I took out one hour after, with as lafting a dye as the firft ; fo that when this vat is ufcd and fit to work, the tartar is to "be kept in a ftate of folution, which cannot be done but by a pretty ftrong heat. The alkali of the urine greens it, the alum prepares the fibres of the wool, and the cryftal of tartar fecures the dye by cementing the colouring atoms depofited in the pores. There ftill remains a difficulty with refpedtto the indigo vat, in which, neither vitriol, alum, or tartar are ufed, but only pearl-aflies in equal quan- tity with the indigo, and which is pretty brifkly lieated to dye the wool and ftuflPs. But before I enter into the caufe of the folidity of its dye, which is equal to that of the other blue vats where the other falts already mentioned enter, I mufl examine into the nature of pearl-afhes, which are the lees of wine dried and calcined : it is therefore an alka- line fait,, of the nature of fait of tarcar, but lefs pure, as proceeding from the heavieft parts of the dregs of wine, and confequently the moft earthy ; befides, the. alkali of the pearl-aflies is never as homogeneous as ihe alkaline fait of tartar well cal- cined, and there are fcarcely any pearl-aflies not purified, from wi.ich a confiderable quantity of tar- tar of vitriol may not be obtained : it is even pro- bable by an experiment which I have related, that it might at length be entirely converted into this neutral fait; the fame may be faid of pot-afhes, and of all other alkaline falts, whQle bafis are not that of the marine fait. 2 The THE DYER S ASSISTANT. 7 1 The want of this homogeneous quality, is the caufe that pearl-aOies never fall entirely into deli- quium in the air; therefore iince experience fliows that there is a tartar of vitriol already fornrted in the pearl-alhcs, it is evident that this indigo vat, which does not give a good dye until the liquor has been fo bri&iy heated as not to fufF.f the hand without fcalding, will difl";lve the fmall portion of tartar of •vitriol thnt is contained in it, and confequently this fait will introduce itfelf into the pores of the wool to cleanfe and cement them, and will coagu- late therein on the wool being taken out of the li- quor, and expofed to the air to cool. I mufl: now give the reafon why the indigo vat is green under the firft furface of the liquor; why this liquor muft be green that the blue dye may l^e lading, and why the fluff that is taken green out of the liquor becomes blue as foon as it is aired. All thefe conditions being of necefiity common to all indigo vats either cold or hot, the fame explica- tion will ferve for them all. X. The flurry which rifes on the furface of the indigo liquor when it is fit to dye is blue, and the under part of this fcum is green ; thefe two cir- cumflances prove the perfedt folution of the indigo, and that the alkaline ialt is united to its colouring atoms fince it greens them, for without they v/ould remain, blue. 2. Thefe circumftances prove that there is alfo in the indigo a volatile urinous alkali, which the fixt alkali of the pct-afh, or the alkaline earth of the lime difplays, and which evaporates very fhortly after the expofition of this fcum to the air. The exiftence of this urinous volatile appears plainly by the fmell of the vat during the fermentation ; when ftirred, or when heated, the fmell is (harp, and refembles that of ftinking meatroafted. 3. In 72 THE DYER S ASSISTANT. 3. In the preparation of the anil, in order to feparate the fecula, a fermentation is continued to putrefadlion. All rotten plants are urinous. This volatile urinous quality is produced by the intimate union of fahs with the vegetable oil, or is owing to a prodigious quantity of infers falling on all tides of fermenting planks, and attra<5led by the fmell exhaling from them, where they live, multiply, and die in them, and confequently depoilt a number of dead bodies ; therefore to this vege- table fubftance an animal one is united, whofe fait is always an urinous volatile. This fame urinous quality exifts alfo in the woad, which is prepared after the fame manner, viz. by fermentation and putrefaction, and which will be fun her explained in the abridged narrative of its preparation. "4. And laftly, if indigo or woad be diftiUed in a retort, either alone, or (which is much better) with fome fixed faline or earthy alkali added to ir, a liquor will be obtained, which, by all chymical effays, produces the fame effeds as volatile fpirits of urine. Why does not this volatile urinous quality in the indigo caufe it to appear green, fince it muft be equally diftributed through all its parts ? And why does indigo, being difTolved in plain boiling water, tinge it t'ue and not green ? It is becaufe this volatile urinous fait is not concreted ; that it requires another body more atJElly di- ftributed, the liquor contained in the vat would net D be 74 T^£ DY£R S ASSISTANT. be equally faline : the bottom cf this liquor would contain all the fait ; tie upper would be inlipid. In this cafe, the ftuff dipped in would neither be prepared to receive the dye, nor to retain it ; but when it is taken out green at the end of a quarter ^f an hour's dipping, it is a proof that the ]iquor wcs equal]}' faline, and equally loaded with colour- ing atoms ; it is alfo a fign, that the alkaline falts have infinuated themfelves into the pores of the fibres of the fluff and enlarged them, as has been obferved, and perhaps hive formed new ones. Now there can be no doubt that an alkaline fait may have this effe£l on a woollen ftufF, when it is evi- deut that a very fharp alkaline ley burns and dif- /o'ves almcfl in an inflant a flock of wool Or a feather. A procefs in dying called, by the French, fsvie ie Icurre^ that is, the melting or dilTolving of flock cr hair, is ftill a further example. The hair, which is ufed and boiled in a folution of pearl-afhes in urine, is fo perfedlly difTolved as not to leave the leaft fibre remaining. Therefore if a lixivium, ext:en>ejy fharp, entirely deftroys the wool, a ley which fliall have but a quantity of alkaline fait fuf- ficicTit to acl on the wool without defl^roying it, wiii prepare the pores to receive and preferve the cclc'c:ring aroms of the indigo. The fluff is aired after being taken green out of the vat, and after wringing it becomes blue. What is done by airing ? it is cooled ; if it is the urinous volatile detached from the indigo which gave it this ereen colour, it evaporates, and the blue ap- pears again ; if it is the fixed alkaline that caufes this ereen, not only the greatefl part is carried off by the ftrcng exprellion cf the fluff, but what re- inains can have no more action on the colouring parr, lecaufe the fmall atom cf tartar of vitriol, whkb THE dyer's assistant. -75 which contains a coloured atom ftill Icfs than itf^lf, is cryftalized the iniknt of its expoiitlon to the cold air, and contrading this farne colouriniT atom by the help of the fpring at the fides of the oore, it ^ entirely preffes out the remainder of the' alkali, which does not cryftalizeas a neutral fait. The blue is roufed, that is, it becomes brighter and finer by fcaking the tained in July ; rain ar dry weather advances or retards it eight days. I 'he third crop- is at the lat- ter end of Auguft ; a fourtii the latter eivd of Sep- tember ; and the fifth and lail about the tenth of November. This lafl crop is the mcil confider- able, the interval being longer. The plant at this crop is cut at the root from Whence the leaves fpring. This woad is not good, and the laft crop is forbid by the regulations. The. woad is not to be gathered in foggy or rainy weather, but in ferene weather, when the fun has been out fome time. At each crop the leaves are brought to the mill to be ground, and reduced ta a fine pafle ; tliis is to be done fpeedily, for the leaves when left in a heap ferment, and foon rot with an intolerable ftench. Theie mills are like the oil or bark- mills, that is, a mill-fl:one turns round a perpendicular pivot in a circular grove or trough, pretty deep, in ,which the woad is ground. The leaves thus mafhed and reduced to a pafle, are kept up in the galleries of the mil!, or in the open air. After preffing the pafte well with the hands and feet, it is beat down and made finooth with a fiiovel. This is called the woad piled. An outward cruft forms, which becomes blackifli; when it cracks, great care muft be taken to clofe it again. Little worms will generate in thefe crevices and fpoil it. The pile is opened in a fortnight, well worked between the hands, and the cruft well mixed with theinfide; fometimes this cruft requires to be beat with a mallet to knead it with the reft. This pafte is then made into fmall loaves or round balls, which, according to the regulations, D 4. luuft So THE dyer's assistant. muft weigh a pound and a quarter. Thefe balls are well prcfied in the making, anH are tb.en given to another, who kneacs them again in a wooden ci){h, lengthens them at both ends, mak-ng them oval znd fc'-'t oth. Laftiy, they are given to a third, who finifhes 'them in a leffer bowl difh, by prefling and perfedily uniting them. The parte] or woad thus prepared is called Paflel tn Cccaigne\ whence arifes the provtrb. Pan de Cicaigm ; which fignifies a rich couniry, bccaufe this coui try * where the woad grows, enriched it- feif forrr;erly by the ccrarDerce of this drug. Thefe balis f are fpreid en hurdks, and expofcd to the fun in 6ne weather j in bad weather they are put at the top of the mill. The woad that has been expofed fome hours to the fun, becomes black on the ouiiide, whereas that which has been kept within doors is generally yellowifli, particularly it the Wcsther has bren rainy. The merchants pre- fer ti^;e former ; this makes little diftcrence as to its xiit; it is in general always yeilowifli, as the pecfants mollly work it in rainy weather, when they cannot attend their rural employments. In fummer, thefe balls are commonly dry in fif- teen or twenty daySj whereas in autumn thofe of ihc ]3il crop are Ion? in drying. The good balls v. lien broke are of a violet co- lour within, and have an agreeable fmell ; wl.creas thofe that arc of an earthy colour and a bad Imell, are not good : this proceeds from the ga- thering of the woad during the rain, when the leaves were filled with earth. Their goodnefs is alfo * UAhigeuh & Laurag is. + There is a place in Indie, the name I fio not recollea, where the anil is prepared after the manner of the woad, and the indigo conr.«» frorti it in lumps, containing all the ufclefs parts of ihc .plant. - It is very dificult to prepare a blue va: with it. THE dyer's assistant. Si alfo known by their .weight, being light when they have taken too much air, or rotten by not having been fufticientiy preft. Poivder of Woad, Of thefe balls well prepared, the powder of woad is to be made ; for this purpofe a hundred thoufand at leaft are required. A diftant uara or a warehoufe niuft be procured, larger or finalier according to the quantity intended to be made. It mufl be paved with bricks and lined with the fame, to the height of four or five feet ; the walls would be better to be or ftone to that height, yet often the walls are only coated with earth j this coat breaking off and mixing with the woad is a great prejudice to it. In this place the balls are reduced to a grofs powder with large wooJen inulitts. This pt/Wder is heaped up to the height of four feet, referving a fpace to go round, and is moiften- ed with water; that which is flnny*'is beft, pro- vided it be clear J the woad thus moiftened, fer- ments, heats, and emits a very thick ftinking vapour. it is f^irred every day for twelve days, flinging it by fh.jvels full from one (ide to the other, and moiflenmg it every ^day during that time; a'ter which no more water is liung on, but only ftirred every fecond day; then every third, fourth, and filth; it is then heaped up m the middle of the place, and looked at from time to time to air it in D 5 cafe * 1 can fee no reafon why (limy water, and yet to he r'ear, is - prtlerrtci. it appears lo n.e rlui cltnr river waiei would be more ffcurej with thik they would &void the iiu-«)nvenitnses that n;uft atteo'l a ftahcing water, always filled with h'tl)j or of a muddy wattr, which contains uukfa^rth, and which n;uft make the . dje uneven. 82 THE dyer's assistant. cale it (hculd heat. This is the paflel or garden woad powder tA fcr fale to the Dyers. Air. Aftruc, to prove that the fale of woad fcr- fnerly enriched ihe higher Languedoc, quotes the fol- lowing palTage from a book entitled Le Alarchand. " Forrr.erly they tranfported from Toulouze to BourJeaux, by the river Garonne, each year a hundred thoufand bales of woad, v/hich on the fpot are worth at leaft fifteen livres a bale, which amounts to 1.500.000 livres ; -frooi whence pro- ceeded the abundance of money and riches of that country." CaHel in his Msmoirs de V Hijio'ire du Languedoc^ in 1633, P- 49* The comparing -of thefe two methods of pre- paring the woad and indigo may be fufficient to a perfon of underitandi.-.g, who mi^ht be appointed to try, by experi.nents, the pofllbiiity of extracting a fecula from the ifatis of Languedoc like that of the anil. It is neither tlie Dyer or Manutaclurer that ought be applied to for that purpofe ; both would condemn the |;rrje6l as a novelty, and it would re- quire many experiments, which in general they are not accudomed to. 1 could wiih tliis experiment was tried in gre^t, fo that at lealt fifty pounds of this fecula might be get, that fevsral vats might be fet in cafe the firfl fliuuld fail. Whoever does try it, fhould be very careful to defcribe all the circumilances of the pro- cefs. Perhaps it mia,ht not fucceed at the firfl crop of the leaves of the "t^Oidi^ becaufe the heat in June is not fufficient, but probably he m.ight meet with fuccefa in Augufl. If this fucceens, there are without douht feveral ot^^er plants of the fame quality as the ifatis, and wli.ch yielas a like fecula. It is alfo probable that the dark green of feverul plants is coropofcd of yellw^v, srld blue parts ; if by fermentaticn THE dyer's assistant. S^ fermentation the yellow could be deftroyed, the blue would remain. ^ Tins is not a chimerical idea, and it is eafy to prove that fome ufe might be de- rived from fuch an experiment. CHAP. viir. OF RED. RED, as has been faid, is one of the primary or mother colours of the Dyers, in ihe great dye there are four principal reds, which are the ba(is of the reft. Thefc aie, I. Scarlet of grain. 2. The fcarlet, now in ufe, or flame-coloured fcarlet, formerly called l^utch fcarlet. 3. Thecrixr.fon red. Axid, 4.. The mad- der red. 1 here are alfo the bailard fcarlet and the baftard crimfon ; but as thefe are only mixtures of the principal reds, they ought not to be coufidered as particular colours. The red, or nncaret of bourre *. was formerly permitted in the great dye. All theie different reds have their particular fhades from the deeped to the llghte'l, but they furm feparjte cLifTes, as the fnades of the one never fall into thofe ol' the other. The reds are worked in a different manner from the blues, the wool or ftuffs not beinj; immediately dipped in the dye, but previouily receivinj^ a prepa- ration which gives them no colour, but prepares them to receive that of the colouring in without alum, and as much of tliC ccrnpofition as wonld be ufed for the makins a Icarlet with co- cliineal, you have in one liquor an exceeding bright cinnamon, tor nrthinij but"tiie acid entering in the iLixmre, the red parts of the kermes become fo minute that they almoft eJ'cape the fight. But if this cinnamon colour he pafTed through a liquor of Roman alum, part of tiiis red appears again ; whether it be by the addition or the a.um that drives out a part of the acid of the comp.fi'. ion, or the earth of the alum precipitated by the aftriction of the kermes, which has the efFedl ofgalls^ I know not ; but this red thus reftored is not tine. With cream of tartar (the cortipofition for fcar^ let) and alum, in greater quantity than tartar, the kermes gives a lilac colour, which varies according as the proportion of ingredients are changed. If in the place of alum and tartar, ready pre- pired tartar of vitriol is fubftituted, v.hich is a very hard fait, refulting from tJic mixture of the vitriolic acid and a fixed alkali, fuch as the oil of tartar, pot-aflies, &c. an.i if, I fay, after boiling the kermes in a folution of a fmail quantity of this fait, the fluff be dipped in and boiled one hour, it acquires a tolerable handfome agath grey, and in which very little red is feen, for the acid of the compofitioa bavins too much divided the red of the kermes, and the tartar of vitriol, not containing the earth of the alum. THE DYER S ASSISTANT. 93 •alum, it could not re- unite thefe rerl atoms, dif- perled by precipitation. Ti^efe agath -reys are of , the good dye, for, as I have obferved in the chapter treating of indigo, the tartar of vitriol is a hard fait, which is not calcined by the fun, and is indif- foluble in rain water. Glauber faits mixed with the kermes entirely de- ftroy its red, and give an earthy grey that does not ftand the proof, for this fait neither refifts cold w.^ter nor the rays of tlie fun, which reduce it into powder. Vitriol or green copperas, and blue vitriol feparated fubftituted for alum, but jjined to th.e cryftal of tartar, equally deftroy or veil the red of the kermes, which in thefe two experiments pro- duce the fame efFeit as if galls or fumach had been made ufe of; for it precipitates the iron of the green vitriol, and dyes the cloth of a grey brown, and the copper of the blue vitriol dyes it of an olive. Inftead of blue vitriol, I ufed a folution of cop- per* in aqua fcrtis, which alfo produced an olive colour ; a convincing proof that the kermes has the precipitating quality of the galls, fince it precipi- tates the copper of the vitriol as a decodlion of gall- nut would. There is great probability that what renders the red of tiie kermes as holding as that of madder, is from the infedts feeding on an aftringent fhrub, which, notwithftanding the changes made by the digeftion of the juices of the plant, ftill retains the aftringent quality of the vegetable, and confequently the virtue, and fo gives a greater fpring to the pores of the wool to contract themfelves quicker and with greater ftrength, when it comes out of the boiling water, and is expofed to the cold air j for I have obferved * Verdigrife, 94 THE dyer's assistant. obferved that a'l barks, roots, weeds, fruits, and other matters that have forae allriclicn, yield colcuis of the good dye. Violets zuithout Blue. The white vitriol of goflar, whofe bafis is the zkick, being joined with the cryftal cf tartar, changes the red of the kermes into a violet. Thus v.ith one colouring ingredient, and fimple changes, violets are made without a blue ground ; for tnis compound cclcur, hitherto only obtained by putting a blue on a red, or a red on a blue, is made as well with cochineal, or even ^ith madder, as (hall be fhov.'n treating of thefe two ingredients. Vv'hite vitriol being extracted from a mine, containing lead, arl'enic, and feveral other natters, whcfe re- crements melted afterwards with fand and alkaline falts, vitrifies into a blue mafs, called /^^v. I fuf- pe£led the white vitriol might contain a portion of this blue, which, with the red of the kermes, might have changed to a violet, and confequently that the mine of i]\e bifmuth, which really contains this blue matter, znd the biimuth itfeif, would produce tlie fame effect as wl ite vitriol ; neither was I mif- tsken in my conjeciure; for having put fotne of the extract of the mine of bifmuth in the liquor of kermes, and fcn-je of the folution of the bifmuth itfeif, upon another decodlion of the fame ingre- dient, they both dyed cloth of a violet colour. I fhall not here give the procefs of extracting the mine of bifmuth, for it is a cifficuk operation for a Dyer. However, if the reader is defirous to know what I mean by the extraction of the mine of bif- muth, he will find the prccefs in the Royal Aca- demy of Sciences for the year ly^Jt where there is a menicir on fvmpathetic inks. As to the folution of THE DYER S ASSISTANT. 95 of bifmuth, which produces almoft the fame effe£l, it is made after the following manner : Take four parts of fpirits of nitre, and four parts of very clear water, which mix together, and dif- folve therein one part of bifmuth, or tin glafs, broken in fmail pieces, put the laft little by little into the liquor, left they fliould occafion too violent a fer- mentation. Acids put in too great abundance in the liquor of the kermes, whether it be fpirits of vitriol, aqua fortis, vinegar, lemon juice, even four water, fo greatly divide the red colouring particles, that the cloth receives but a cinnamon colour, bor- dering on the aurora, if there is too much acid, and a little redder if there is lefs. Fixed alkaline falts, mixed with four water and cream of tartar, in the place of alum, do not de- ftroy the red of the kermes as acids do, but faddens and muds it if too much be put in, fo that the cloth receives only a faded lilac colour. Other experiments, ftill more diverfified than thofe here related, prefented an infinite variety cf colours, but nothing more beautiful than what may be done with cheaper drugs than the kermes i I Ihall therefore pafs them over. CHAP. X. OF FLAME-COLOURED SCARLET. FLAME-coloured fcarlet, that is, bright- colour- ed fcarlet, known formerly under the name of Dutch fcarlet, (the difcovery of which Kunkel at- tributes to Kufter, a German chymili) is the fineft and brighteft colour of the dye. It is alfo the mod an the fine or cultivated ; the colour is more holding and better, bvi- has not the fame brightnefs, neither is it profitable to. uie it, fi^ice it requires four parts, and fometimes more, to do what may be done with cne of fine. 2 Sometirr.es THE DYtR's ASSISTANT. 97 Sometimes they have damaged cochineal at Ca- diz; this is line cochineal that has been wetted with fait water, occafioned by fome (hipwrcck or leakage. 'Thefe accidentrs confukrably dinninifii the price, the fea fait faddening the dye. This kind ferves only to make purples, and even thofe are not the bed. However, a perfqn in 1735 found the fecret to turn this to almoft as mucfi advantage for fcarlet as the fined cochineal. The difcovery of this fecret is eafy, but let him that poffefTes it enjoy it, I fhall not deprive him of the advantage he might have in it. Every Dyer has a particular receipt for dying fcarlet, and each is fully perfuaded that his own is preferable to all others ; yet the fuccefs depends on the choice of the cochineal, of the water ufed in the dye, and on the manner of preparing the folution of tin, which the Dyers call compofition for fcarlet. As it is this compofition which gives the bright flaiiie colour to the cochineal dye, and v.'hich without this acid liquor would naturally be of a crimfon colour, I (hall defcribe the preparation that fucceeded beft with me. Compofitian for Scarlet, Take eight ounces of fpirit of nitre, (which Is always purer than the common aqua fortis mortly ufed by the Dyers) and * be certain that it con- £ tains * Diflblve in a fjr.all quantity of fpirit of nitre as much filrer as it will take J put a few drops of this into fome of the fpirit cf nitre that is to be proved ; if this fpirit remains tranfparenr, it is pure; tut if a white cloud be perceived, which will afterwards form a fediment, it is a fign that there is a commixture of vitriol or fpirit of fait. In order therefore to rentier the fpirit t f nine ab- . folaiely pure; drop the folution of filter gradually into it, fo long §8 THE dyer's assistant. tains no vitriolic acid ; weaken this nitrous zad by puttins into it eight ounces of filtered river water; difToIve in it, little b\ liit'e. half an ounce o( very white lalt amn^oniac, to make it an aqua regia, becaufe fpirits of nitre akne wa i ct dif- folve b!jck-tin. Laftly, add two drachms or Talt- petre ; this might be omitted, but J Lbierved that it was of uie in nr.nking :he dye f-r.coth and equal. In this squa r^gia thus weakened, ciiloive one ounce of the beft hl:ck-tin, which is firft granul- ated cr made roiaii while mieltcd Dy caft.ng ir irom a iieight into a veflel of cold-water. Tl.efc fmall grains of tin are put into tlic difiblvent one by one, letting the .firft d;ffol\'e bttore putting in others j this prevents the Icis of the red vapcurs, which would rife in great abuncance, and be loft if the diiTolution of tne rretal was rnac'e too haiVily ; it is necefTarv to prekrve thefe vapours, and, as Kunkel cbferved, they greatly ».ontribu'e towaiv's the brightneis of the colour, e.ther becaufe thefe vapours are acids that evaporate and are loft, or contain a fulphur peculiar to faiipetre, which giveg a brightnefs to the colour. This method is indeed much longer than that ufed by the Dyers, who im- mediately pcur the aqua fortis upon the tin reduced to fmall piece?, and wait till a ilrcng fermentstion enfues, and a great quantity evaporates before they weaken it with common water. When the tin is thus diiTcived, this fcsriet compofition is made, and the liquor is of the beautiful colour of diiTolved gold, without any dirt or black .fediment, as as It O-.aH produce the leaft turbidr.efs, time being given for the ipirit to beccme clesr betwixt each addiricn. The {-/.Tit c( nitre b£Jnf then po'jred cff from t e fedin.ent, will be perfefUy pure } a:>.d if this fediir.er.f, which is the Giver precipitated, he evapo- ratid to dryrefs, jud then infofed in a crucibie with a fnriail ^•jar.tiry of any fcxed alkaline fa^t, i; wUi be reduced to i:» pr^- *ii D,eta:!.r.e flste. THE dyer's assistant. 99 as I ufed very pure tin without allay, and fuch as runs from the firft melting of the furnaces of , Cornwall. This folutionof tin is very tranfparent when newly made, and becomes miiky and opaque during the great heat of fummer; the greateft part of the Dyers are of opinion, that it is then changed and good for nothing; yet mine, notwithltanding this defe£^, made as bright fcarlet as if it had re- mained clear ; befides, in cold weather, what I made recovered its firft tranfparency. It muft be kept in a glafs bottle with a ftopper, to prevent the evaporation of the volatile pans. As the Dyers do not attend to this, their com- pofition often becomes ufelefs at the end of twelve or fifteen days. I have laid down the beft method, and, if they feek perfedion, they will abandon their old practice, which is imperfed:. The Dyers in France firft put into a ftone vefiel, with a large opening, two pounds of fait am- moniac, two ounces of refined faltpetre, and two pounds of tin reduced to grains by water, or, which is ftill preferable, the filings of tin; for when it has been melted and granulated, there is always a fmall portion converted into a calx which does not diffolve. They weigh four pounds of water in a feparate veftel, of which thev pour about two ounces upon the mixture in the ftone vefTel ; they then add to it a pound and a half of common aqua fortis, which produces a violent fermentation. When the ebullition crafes, they put in the fame quantity of aqua fortis, and an inftant after they add one pound more. They then put in the re- mainder of the four pounds of water they had fet £fide; the vefiel is then clofe covered, and the com- pofition let to ftand till the next day. The fait petre and fait ammoniac are fometitnes tlifiblved in the aqua fortis before the tin is put in ; E 2 ' thev 100 THE dyer's assistant. they pradice both methods indilcriminately, though it is certain that this laft method is beft. Others mix the water and aqua fortis together, and pour this mixture on the tin and fah ammoniac. In ihorr, every Dyer follows his own method. [Voter for the Preparation of Scarlet. The day after preparing the compofition, the water for the preparation of fcarlet is made, which differs from that made in the preceding chapter. Clear the water well. For each pound of fpim wool, put twenty quarts of very clear river water (hard fpring water will not do J into a fmal! copper. When the water is a little more than lukewarm, two ounces of cream of tartar finely powdered, and one drachm and a half of powdered and fifted cochineal is added. The fire is then made a httie Wronger, and when the liquor is ready to boil, two ounces of the compofition are put in. This acid iiiftantly changes tlie colour of the liquor, which, from a cri'Tifon, becomes of the colour of blood. As foon as this liquor begins to boil, the wool is dipped in, which muil have been previoufly wetted in warm water and wrung. The wool is conti- nually worked in this liquor, and left to boil an hour and a half; it is then taken out, flightly wrung, and waftied in frefli water. The wool coming out of the liquor is of a lively fle^ colour, cr even fome fhades deeper, according to the good- nefs of the cochineal, and the ftrength of the com- pofition. The colour of the liquor is then entirely pafTed into the wool, remaining almofl as clear as common water. Tals is called the water of preparation for fcar- ler, and the firfl: jJreparation it goes through before it is dyed j a preparation abfolutely necefiary, without THE DY£R*S ASSISTANT. lOI without vihich the dye of the cochineal would not be fo good. Reddening. To finifh it, a frefh liquor is prepared with clear water, the goodnefs of the water being of the greateft importance towards the perfeilion of the leaflet. An ounce and a half of ftarch is put in *, and when the liquor is a little more than luke- warm, fix drachms and a half of cochineal finely powdered and fifted is thrown in. A little before the Hquor boils, two ounces of the compofition is poured in, and the liquor changes its colour as in the former. It muft boil, and then the wool is put into the copper, and continually ftirred as in the former. It is likewife boiled an hour and a half J it is then taken out, wrung, and walhed. The fcarlet is then in its perfe£l:ion. One ounce of cochineal is fuf£cient for a pound of wool, provided it be worked with attention, and after the manner laid down, and that no dye re- Hiains in the liquor. For coarfe cloth lefs v/ould do, or half as much for worfted. However, if it was required to be deeper of cochineal, a drachm or two might be added, but not more, for it would then lofe its luftre and brightnefs. Though I have mentioned the quantity of the cornpofition, both in the water of the preparation and the dye, yet this proportion is not to be taken as a fixed rule. The aqua fortis, ufed by the Dyers, is feldom of an equal ftrength ; if, therefore, it be always mixed with an equal quantity of water, the com- pofition would not produce the fame eflfeit ; but tlicre is a method of afcertaining the degree of E 3 acidity * Starch foftens it, JG2 THE DYER S ASSISTANT. acidity of aqua fortis. For example, to ufe that only, two otnces of which would diffolve one ounce of filver. This would produce a compo- fition that would be always equal, but the quality of the cochineal would then produce new varieties,, and the trifling difference tliat this commonly caufcs in the fliade of fcarlei is of no great fignihcaticn, as more or lefs may be ufed to bring it precifely to tlie colour defired. If the compofiuon be -weak, and the aforefaid quantity not put in, the fcarlet will be a little deeper and fuller in colour. On the contrary, if a little more is added, it will be more on thcvorange, and have what is called more fire j to rectify v;hich, add a little of the compofition, ftirring it well in the copper, having firfl taken out tht v/ool ; for if it was to touch any part before it was thoroughly mixed, it would blot it. If, en the contrary, the fcarlet has too much fire, that is, too iTiUch on the orange, or too much rouzed, it mufk be paficd through clear warm water; when finiftjed, this I'addens it a little, that is, diminifhes its bright, crange ; if there ftill remained too much, a little Pvoman alur. muft be mixed with the hot water. For fpun wool that is to have all the various Ihades of fcarlet, about half the cochineal, and half the compofition for full fcarlet is fufficient. The cream of tartar muft: alfo be diminifhed propor- tionabiy in the water of preparation. J he wool riiufi be divided into as many hanks or Hcains as there are to be Ciades, and when the liquor is pre- pared, the (kains that are to be lighteft are firft to be dipped, and to remain in but a very Ihort fpace of time; then thofe that are to be aJittle deeper, which mull: remain in fomewhat longer, and thus pro- ceeding to the deepefl ; the wool is then to be walhed, and the liquor prepared to finifli them. In this liquor, each of thefe Ihades are to be boiled one THE dyer's assistant. lOJ one after the other, beginning always with the lighteft, and if any are perceived nor to be of the proper (hide, they muft be pafTed again through the iiquor. The eye of a Dyer will readily judge of the (hades, and a little pratStice will bring this to perfection. The Dyers are divided in opinion of what metal the boiler (houIJ be made In Languedoc they ufe thofe made of the fineft block-tin, and fcveral Dyers in Paris follow the (ame method. Yet that great Dyer, M. de Julienne, whofe fcarlets are ia high repute, ufes brafs. The fame is ufed in the great manufadtory at St. Dennis. M. de Julienne, to keep the ftuifs from touching the boiler, makes ufe of a large rope-net with clofe ma(hes. At St. Dennis, in(\ead of a rope- net, they have large bafVets, made of willov/llripped of the bark, and not too clofe worked. As fo much had been faid concerning the metal of the boiler, I tried the experiment. I took two eils of white (edan cloth, which I dyed in two fepa- rate boilers of equal fize ; one was of brafs^ futed with a rope- net, the other of block- tin. The co- chineal, the compofition, and other ingredients, were weighed with tl'ie utmoiV accuracy, and boiled precifely the fame time. In fhort, I took all pof- iible care that the procefs fhould be the fame in both, that if any difference arofe it might only be attributed to the difrerent metals of the boiler.^ After the firft liquor, the two pieces of cloth were abfolutely alike, only that which had been boiled in the tin veffel appeared a little more ftreaked and uneven, which, in all likelihood, proceeded from thefe two ells of cloth being lefs fcoured at theinill than the two others; the two pieces were tinifhed each in the feparate boilers, and both turned out veiy tinei but that which had been made in the tin i-' 4 boikr 104 THE dyer's assistant. boiler bad a little mere fire than the other, and th« 1 jft v/as a little more faddeiied. h would have beea an eafy matter to have brought them both to the fame (hade, but that was not my intention. From this experiment, i conclude, that when a brafs boiler is ufcd, it requires a little more of the cornpofiiion than the tin one ; but this addition of ti»e compcfition mskes the clcth feel rough; to avoid this defecl, the Dyers who ufe brafs veffels put in a little turmeric, a drug of the Dye, but wiiich gives to fcarlct that ihade which is now in - faihion ; I mean that flame- colour, which the eye is fcarce able to bear. This adulteration is eafily difccvered by cutting a piece of the cloth ; if there is no turmeric, the web will be of a fine v/hite, but yellow if there is. \Vljen the web is dyed the fan;e as the furface, it is fiid that colour is webbed, and the contrary, when the middle of the weaving remains white. The lawful fcarlet is never dyed in the web : the adul- terated, where the turmeric or furtic has been made ufe cf, is more liable to change its colour in the air than the other. Eut as tiic brighteft fcarlets are i:iow in fafliion, and muft have a yellow caft, it is better to tolerate the ufe of turmeric, than to ufe too great a quantity of thecompofition to bring the fcar'et to ti.is fhade ; for in this laft cafe, the cloth would be damiaged by it, would be fooner fpotted by dirt from the quality of ilie acid, and would be more eaCly torn, becaufe acids ftifien the fibres of the wool, and render them brittle. 1 muft alfo take notice, that if a copper veflel is ufed it cannot be kept too clean. 1 have failed fcveral times with my patterns of fcarlet, by not having the copper fcoured. I cannot help condemning the common pradlice of fome Dyers, even the mofl eminent, who pre- pare THE dyer's assistant. IO5 pare their liquor over-night, and keep it hot till next morning, when the)^ dip in their fluffs ; this they do not to lofe time, but it is certain that the liquor corrodes the copper in that fpace, and by in- troducing particles of copper in the cloth, preju- dices the beauty of the fcarlet. They may fay they only put in their compofition juft at the time when tiie cloth is ready to be dipt in the copper ; but the cream of tartar, or the white tartar, which they put in over- night, is an acid fait fufficient to cor- rode the copper of the veflel, and form a verdigrife, although it dilutes itfelf as it forms, ftill has not a lefs effe£^. It would therefore be better to make ufe of tin boilers, a boiler of this metal mud contribtfte to the beauty of fcarlet ; but thefe boilers of a fufficient fize coft much, and may be melted by the negli- gence of the workmen, and there is a difficulty in carting them of fo great a fize without fand-flaws, which mud be filled^ Now if thefe fand-holes are filled with folder, there muft of neceffity be places in the boiler thai contain lead ; this lead in time being corroded by the acid of the compofition, •will tarnifh the fcarlet. But if fuch a boiler could be csft without any fand-holes, it is certain iuch a one would be preferable to all others, as it con- trades no ruft, and if the acid of the liquor detaches fome parts, they cannot be hurtful. Having laid down the manner of dying fpun wool in fcarlet, and its various fhades, 'which are fo necelTary for tapeftry and other work, it is proper to give an idea of the dying of feveral pieces of ftuff at one time. I fhall relate this operation as it is pradlifed in Languedoc. I made the trial on fome ells of fluff, which fucceeded very well, but this fcarlet was not fo fine as the flame-coloured, E.5 Th':T§ 106 THE DYER'iS ASSrSTAWT. There are two reafons why the wool Is not dyed before ic is ipun (tor fine colours) firi^ in th.e courfe of the manufadturing, that is, either in the fpinnhig, carcing, or weoviog, it would be almofl: iir^pofTible in a large workfhop, where there are many work- men, nut that fome particles of white wool, or fome: other colour would mix, which v;ouId fpoil that of the ftuff by blotting it ever fo little j for that reafon, the reds, the blues, the yeliows, the greens, and all other colours that are to be perfc£lly uniform, are never dyed before they are manufa6fured. The fecond reafon, which is peculiar to I'carler, or rather to ccehineal, is, that it will not ffand the nulling, and as the greateft part of high fiufFs muft be ir.ilied after they are taken from the loom, the cochineal would lofe part of its colour, or at leaft. would be greatly faddened by thsfoap, which pro- duces this eit^iEt by the alkaline fait which deftroys ■the brightnefs given to the red by the acid. Thefe are t!ie reafons that the cloths and fluffs are not dyed in icarlet, light red, crlmfon, violet, purple, and other light colours, but after being entirely milled and drefied. To dve, for example, f>ve pieces of cloth at one time of five quarters breadth, and containing fifteen or fixreen eiis eacli, the following proportsoiis are to be obferved. Put into a {tone or gljzed earthen pot tvjulve pounds of aqua fortis, and twenty pounds of water, to wh;d"i add a pound and a half of tin,, inside in grains by running it in water, or nled. The diiToiution is msde quicker or flower, accord- ing to the greater or lefTer acidity of the aqua fortis. Trie whole is left to refl twelve liours at leaff, duriiig which time a kind of black mud fettles at the bottom of tlie vt-lTel ; what fwinis over this fe- diii.eiit li poured off by incliintion y this liquor is ciear THE dyer's assistant. 10/ clear and yellow, and is the compofition which is to be kept by itfelf. This prccefs differs from the finl in the quan- tity of water mixt with the aqua fortis, and in the final! quantity of tin, httle of which^mufl remain in the liquor, fince aqua fortis alone cannot dilToIve it, but only corrodes it, and reduces it to a calx, as there is neither fait petre, nor fait ammoniac which would form an aqua regia. However, the effevSl of this compolition differs from the firft only to the eyes accuflomed to judge of that colour. This compofition made without fait ammoniac, and which has been of long ufe amongft a great- number of manufavSlurers at Carcaffone, who cer- tainly imagined that its effecSt was owing to the fulphur of the tin, can only keep thirty-fix hours in ^winter without fpoiling, and twenty-four hours in furamer j at the expiration, of which it grows muddy, and a cloud precipitates to the bottom of the veffel, which changes to a white fediment.. This is the fmall quantity of tin, which was fufpended in the acid, but an acid not prepared for that metal j the compofition which ought to be yellow becomes at that time as clear as water, and if ufed in that ftate v/ould not fucceed ; it would have the fame effect as that which would become milky. The late M. Baron pretended to have been the firft difcoverer at Carcaffone of the neceffity of adding fait ammoniac to hinder the tin from pre- cipitating. U fo, there was no one in that town that knew that tin cannot be really diffolved but by aqua regia. Having prepared the compofition as I have de- fcribed it after M. de Fondriers, about fixty cubi- cal icet of water arc put into a large copper for the ii/e pieces of cloth before mentioned, and wiica tiie water grov.'s warm, a bag with bran is £ 6 UUt; 10% THE dyer's assistant. put in, fjmetimes alfo four waters are ufed : the one and the other ferve to correct tl-.e water, that is. to abforb the eartlw and alkaline matters which may be in it, and which, as I have already faid^ fsddens the dye cf the cochineal, for the efFccl of the water ought to be well known, and experience will teach whether fuch expedients ihould be ufed, cr whetlier the water, being very pure and denulated of falts and earthy particles, can be ufed without fu:h helps. Be tliat as it will, as loon as the water begins to 1)5 little more than lukewarm, ten pounds of pow- dered cream of tartar is flung in, that is two pounds for each piece of clnh. T!ie Tquor is then raked flrongly, and when it grows a little hotter, half a pound of powdered cochineal is caft in, which is well mixt with flicks ; immediately a^ter, twenty- feven pounds of the compof^tion very cTesr is poured in, which is alfo well ftirred, and as f'on as the liqi^or begins to boil, the cloths are put in, wMch are made to boil flrongly for tvvo hours, furring them continually by the he'p cf the wynch ; they are then taken cut upon the fcray, and ■well handled three cr four times from end to end, by pafling the lirts between the hands to air and ccoi them. Thev jre afterwards walhed. Af:er the cloth has been wafhtd, the copper is emptied and a frefii lii^unr prepared, to which, if r.eceilary, a bag with bran cr fome four water is acded ; bur if the water i<: o^ a good quality, thele sre to be omitred y when the liquor is ready to boil, elihr pounds ai^d a quarter of powdered and. fifted cochineal is put in, which is to be mixed as equal- ly as pcluble th.-ou';:hout the liquor, and having left off ftirrine, it is t > be obforved when the cochineal rift^s en the furfsce of the water, and forms a cruft ot the colour of the le.s of the wine i the inllant tills THE DYER S ASSISTANT. IQ9 this cruft opens of itfelf in feveral places, eighteen or twenty pounds of the compofition is to be added. A veflel with cold water muft be at hand to caft on the liquor in cafe it fhould rife, as it fometin^eff does, after the compofition is put in. As foon as the compofition is in the copper, and equally diftributed throughout the whole, the cloth is caft in, and the wynch ftrongly turned two or three times, that all the pieces may equally take the dye of the cochineal. Afterwards it is turned fiowly to let the water boil, which it muft do very faft for one hour, always turning the wynch, and finking the cloth in the liquor with flicks, when by boiling it rifes too much on the fijrface. The cloth is then taken out, and the lifts pafTed between the hands to air and cool it ; it is then wafned, after which it is to be dyed and dreiTed. In each piece of the Langueooc fcarlet cloth there is ufed, as has been fhown, one pound and three quarters of cochineal in the dye and prepara- tion ; this quantity is fufRcient to give the cloth a very beautiful colour. If more cochineal was added, and a deeper orange-colour required, the quantity of the compofition muft be augmented. When a great quantity of fluffs are to be dyed .in fcarlet, a confiderable profit arifes by doing them together, for the fame liquor ferves for the fecond dip which was ufed for the firft. For example : when the five firfl pieces are finiflied, there always remains in the liquor a certain quan- tity of cochineal, which in hven. pounds may amount to twelve ounces ; fo tliat if this liquor be ufed to dye other fluffs, the cloths dipped in it will have the fame fhade of rofe colour as if • they had been dyed in a frefh liquor with twelve ounces of cochineal ; yet this quantity may vary pretty much, according to the quality or choice of 110 THE dyer's assistant. ©f the cochineal, or according to the finenefs it- has been reduced to when powdered. 1 fnall fay no more of this before I ftnifh this chapter ; but whatever colour may remain in the liquor, it de- ferves fome attention on account of the high price ©f this drug. The fame liquor is then made ufe of for other five pieces^ and lefs cochineal and compo- fition are put in proportion to\vhat may be judged to remain ; fire and time are aifo faved by this, and roft- colour and fltfli-colour may aifo be produced from it ; but if the Dyers have no leifure to make thefe different liquors in twenty four hours, the colour of the liquor corrupts, grows turbid, and lofes the rofe-colour entirely. To prevent this cor- ruption fome put in Roman alum, but the fcarlets which are prepared after that manner are all fad- dened. When cloths of different qualities, or any other fluffs are to be dyed, the furefts method is to weigh them, and for each hundred weight of cloth add about fix pounds of cryfial or cream of tartar, eighteen pounds of compofition in the water of preparation, as much for the reddening, and fix pounds and a quarter of cochineal. Thus in pro- poition for one pound of ftuff ufe one ounce of cream of tartar, lix ounces of compofition, and one ounce of cochineal ; fome eminent Dyers at. Paris put two- thirds of the compofition r.:.J a fourth of the cocluneal in the water of preparation, and the other third of tlie compolition with three- fourths of the cochineal in reddening. It is not cuftomary to put cream of tartar in the reddenitig, yet I am certain, by experience, that it does not hurt, provided the quantity does not ex- ceed hair the weiuht ot the cochineal, and it ap- peared to 'ne t.) make a more hllmg colour. Soiiie Overs nave made fcarlet with three dippings ; THE DYERS ASSISTANT. I If namely, a firfl: and fecond water for preparation,, and then the reddening ; but ftill the fame quantity of drugs is always ufed. 1 obferved, in the foregoing chapter, that the little ufe made cf kermes for the brown or Vene- tian fcarlets, obliges moft Dyers to make them with cochineal j for this purpofe a water of prepa- ration is made as ufual ; and for the reddening,, eight pounds of alum are added for each hundred weight of fluff; this alum is diflblved by itfelf in a kettle, with a fufEcient quantity of water, thea poured into the liquor before the cochineal is put in. The remainder is performed exadlly as in the common fcarlet ; this is the Venetian fcarlet, but it has not near the fame folidity as if made with, the kermea. Tiiere are no alkaline falts which do not fadden fcarlet; of this number are the fait of tartar, pot- aflij pearl- aflies calcined, and nitre fixed by fire; therefore alum is more generally ufed ; and if thefe aikalire falts be boiled with the fluffs, they would confiderably damage them, for they diffolve all animal fubftances. if the alum be calcined, it is i^iil the more fecure. The redder the fcarlet Is, the more it has been faddened ; from thence it appears tliat thefe co- lours lofe in tlie liquor that browns them-a part of their ground ; however one cannot brown in the good dye but with falts. The late M. Baron ob- ferves, in a memoir he gave fome time ago to the Koyal Academy of Sciences, that all the falts he had made ufe of tor browning, making the colour fmooih, and preferving its brightnefs and deepnefs, he h.-i.i fuccccdcd belt with fait of urine, but, as he ohicrvcs, it is too troubldbme to make this fait in any quantity,- I faid. 112 THE dyer's assistant. I faid, in the beginning of this chapter, that the choice of the water for dying of fcarlet was very material, ss the greateft part of common water faddens it, for they moftly contain a chalky, cal- caneus earth, and fometimes a futphureous or vi- tric'ic acid ; thefe are commonly called hard waters, that is, they will not difloive foap or boil vegeta- bles well. By finding a method of abforbing or precipitating thefe hurtful matters, all waters may be equally good for this kind c{ dye : thus, if al- kaline matters are to be renvDved, a little four water produces this effect; for if five or fix buckets of thefe four waters are mixed with fixty or feventy of the hard water befcre it comes to boil, thefe alkaline earths rife in a fcum, which is eaiily taken off the liquor. All that I have hitherto faid in this chapter is for the inflru£lion of Dyers ; I fhall new make an attempt to fatisfy the philcfopher how thefe dif- ferent effefts are produced. Cochineal, infufed or boiled by itfelf Jn pure water, gives a crimfon colour bordering on the purple; this is its natural colour; put it into a glaf?, and drop en it fpirits of nitre ; this colour will becom? yellow, and if you itill add more, you wVil fcarcely perceive that there was originally any red in the liquor ; thus the acid dtflroys the red by diffoiving it and dividing its parts fo minutely that they efcape the fight. If in this experiment a vi- triolic, inf^ead of a nitrous acid be ufed, the firft. changes of the colour will be purple, then purpled lilac, after that a light lilac, then flelh-colour, and laf^iy, colourlefs. This bluifh fubftance, which mixes with the red to form a purple, may proceed from that fmall portion of iron, from which oil of vitriol is rarely exempt. In the liquor of prepa- ration for fcadetj rto other fait but cream of tartar is THE dyer's assistant. II3 is ufed, no alum is added as in tlie common pre- paring water for other colours, becaufe it would t'adden the dye by its vitriolic acid ; yet a calx or lime is required, which, with the red parts of the cochineal, may form a kind of lake like that the painters ufe, which may fet in the pores of the wool by the help of the cryftal of tartar. This white calx is found in the folution of very pure tin, and if the experiment of the dye is tnade in any fmall glazed earthen veflcl, immediately oa the cochineal's communicating its tin£lure to the water, and then adding the compolition drop by drop, each drop may be perceived with a glafs or lens, to form a fmall circle, in which a brifk fer- mentation is carried on ; the calx of the tin will be feen to feparate, and inftantaneoufly to take the bright dye, which the cloth will receive ia the fe- quel of the operation. A further proof that this white calx of tin is ne- ceflary in this operation, is, that if cochineal was ufed with aqua fortis, or fpirits of nitre alone, a very ugly crimfon would be obtained ; if a folution of any other metal was made ufe of in fpirits of nitre, as of iron or mercury, from the firft would be had a deep cinder-grey, and from the fecond, a chef- nut colour with green ftreaks, without being able to trace in the one or other any remains of the red of the cochineal. Therefore, by what 1 have laid down, it may be reafonable to fuppofe, that the white calx of the tin, having been dyed by the colouring parts of the cochineal, rouzed by the acid of the diffolvent of this metal, has formed this kind of earthy lake, whofe atoms have introduced them- felves into the pores of the wool, which were opened by the boiling water, that they are there plaiftered by the cryftal of tartar, and thefe pores, fuddenly contrading by the immediate cold" the cloth was expofed 114 "^^^ dyer's assistant. expofed to by airing, that thefe colouring particles are found fufficiently fet in to be of the good dye, and that the air will take off the priaiitive bright- nefs, in proportion to the various matters with which it is impregnated. In the country, for ex- ample, and particularly if the fituation be high, a fcarlet cloth preferves its brightnel's much longer than in great cities, where the urinous and alkaline Tspours ai e more abundant. For the fame reafon, the country mud, which in roads is generally hut an earth diluted by rain water, does not ftain fcarlet as the mud of towns where there are urinous mat- ters, and often a great deal of dilTolved iron, as in the flreets of great cities, for it is well known that any alkaline matter deftrcys the eitecl which an acid has produced on any colour whatfoever. And for the like reafon, if a piece of fcarlet is boiled in a ley of pot-afli, this colour becomes purple, and by a continuation of boiling it is entirely taken out j thus from this fixed alkali, and the crynal of tartar, a fblubie tartar is made, which the water diflolves and eafily detaches from the pores of the wool: all the maftic of the colouring parts is then deftroyed, and they enter into the leys of the fairs. 1 have tried feveral experiments on the dye of cochineal, to ditcover v.'hat might be produced from the union of its red with other different matters, which generally are not efleemed colouring ; but I fhall only relate here fuch as had the moft fingular cfFeds. Experiments on Cochineal Liquor. Zinc difTolved in fpirit of nitre changes the red of cochineal to a llatey violet-colour. The fait of lead, ufed inrtead of cream of tartar, makes a liUc fomewhat faded j a proof that fome portion- THE dyer's assistant. 115^ portion of lead is joined to the colour of the cochi- neal. Vitriolated tartar made with pot-afh and vitriol dertroys its red, and there only remains an agath grey. Dif.'Yiuth diflblved in fpirit of nitre, weakened by an equal part of common water, and poured on the liquor of cochineal, gives the cloth a dove-grey, very beautiful and very bright. A folution of copper in fpirit of nitre not weak- ened, gives to the cocliineal a dirty crimfon, Cupullated filver, a cinnamon colour, a little on . the brown. Arfenic added to the liquor of cochineal, gives a brighter cinna;non than the preceding. Gold diffolved in aqua regia gave a flreaked chefnut, which made the cloth appear as it it had betn manufaf^ured with wool of different colours. Mercury diflolved with fpirit of nitre, produces pretty near the fame effed. Glauber's falts alone deftroys the red, like the vitriolated tartar, and produces like that an agath grey, but not of the good dye ; becaufe this fait ealily diffolvcs even in cold v/ater, and befides it calcines in the air. The fixed fait of urine gives a cinder-grey co* lour, where nor the leaft tindlurc of red is per- ceived, and like the foregoing is not of a good dye^ for it is a fait that cannot form a folid cement iu the pores of the wool, as it is folubk by the moii^ure^ of the air. Violet without Blue, Laftly, the extra£l of bufmuth changes the cochi- neal red to a purple, almoft violet, as beautiful as if this red had been put on a cloth that had beei^ previoully dyed of a Iky- blue. Il6 THE dyer's assistant. From thefe experiments it is evident, that the falls and metallic folutions yield particles which unite themfelves with the particles of the colouring ingredients ufed in dying, and which faits and par- ticles contribute greatly to the tenacity of colours. Before I finifh this chapter on fcarlet, I mufl add fome obfervations which perhaps the reader may be glad to know. Neither the mud of the ftreets nor feveral acrid matters can ftain fcarlet, if the fpotted part is im- mediately wafhed with plain clean water and a clean cloth j but if the mud has had time to dry, then the fpot appears of a violet black ; this cannot be taken off but by a vegetable acid, fuch as vine- gar, lemon-juice, or a warm folution of white tar- tar flightly loaded with falts ; but if thefe acids are not made ufe of with precaution and /kill in taking off" the black fpot, a yellow one will fucceed ; be- caufe, as has been faid before, the acids roufe and even deflroy the red of the cochineal. But there are fome for which the colour muH be difcharged, and the ftuff dyed again. There are other falts, befides alkalis which will difcharge the colour of fcarlet ; for if a piece of fcarlet cloth be. put into the water of preparation for that colour, it will lofe a great part of its colour, infomuch, that if it w'as fewed with two or three pieces of white cloth, it would be difficult after one hour's boiling to dif- tinguifh which was the fcarlet from the otl.ers ; but if it was boiled afrefh in a liquor, of cochineal or in the reddening, it would regain its firff colour. Scarlets always lofe {ovnc part of their brightncfs in the drelHng, for the drefling lays the hair, and forces the fibres to be almoft parallel to the web. In this cafe the cloth has numerically lefs furface, and confequently lefs rays of light are re- fleded from it. Befides the exiremity of the hair is THE dyer's assistant. II 7 is always moft penetrated with the dye which caufes the bright'^.efs, and when it is laid on the cloth, the greateft part of thefe points appear no more. c C H A p. X[. OF CRIMSON. RLVISON, as I have already obferved, is the natural colour of th= cochineal, or rather, that which it gives to wool boiled with aivrn and tartar, which is the ufual water of preparation for all colours. This is the method which is com- monly pradifed for fpun wool ; it is almoft the fame for cloths, as will be feen hereafter. For each pound of wool, two ounces and a half of alum, and an ounce and a half of white tartar, are put into the copper. When the whole boils, the wool is put in, well ftirred, and left to boil ^or ^wo hours ; it is afterwards taken out, flightly wrung, put into a bag, and left thus with its water, as for ihe fcarlet in grain, and for all other colours. For the dye a freHi liquor is made, in which three- fourtlis of an ounce of cochineal is added for each pound of wool. When the liquor is little more than luke-warm, the cochineal is put in, and when it begins to boil, the wool is caft in, which h to be well ftirred with fticks ; it is to remain thus for an hour j when taken out, wrung and wafhed. If degrees of (hades are required, (whofe names are merely arbitrary) proceed, as has been already related for the fcarlet, ufing but half the cochineal at firft, and beginning with the lighteft. The Il8 THE dyer's assistant. TliC besuty of crimfon ccnRfts in its bordering -as much as pcffible on the grifdelin, a colour be- tween a grey and a violet, I made feveral trials to bring criir.fon to a b.igher perfection than moft X)yers have hitherto done, and indeed I fucceeded fo as to mske it as fine as the falfe crimfon, which is -always brighter than the fine. This is the principle on which I worked. As all alkalis fsdden cochineal, I tried foap, barilla, pot-afb, pearl afiies ; all thefe falts brought the crimfon to rhe fhade I wanted, but at the fame time, they ttrnifhed and dirniniflied its brightnefs. I then betliou^ht myfelf to make ufe of volatile alkalis, and I found thst the volatile fpirit of fait ammoniac produced a ver}' good efFe£l ; but this fpirit inftantly evaporated, and a pretty confiderable quantity was ufed in the liquor, which greatly aug- mented the pri:e of the dye. I then had recourfe to another expedient vrhich fucceeded better, the ex pence of which is trifling. This was to make the volatile alkali of the fait am- moniac enter into the liquor, at the very inflant that it comes out of its bafis ; and to efteci this, after my crimfon was made after the ufual manner, I pafied through a freJh liqucr, in which 1 had dif- folved a little of the fait aTimoniac, As foon as the liquor was a little tnore than luke-warm, I flung in as much pot-sfh as I had before of fait ammoniac, and my wool immediately took a very brilliant colcur. This method even fpares the cochineal ; fcr this new liquor makes it rife, and then lefs may be ufed than in the common procefs ; but the greateft pirt of Dyers, even the moil eminent, fadden their crlmfons with archil, a drug of the fa'.fe dye. \'ery beautiful crimfons are alfo made by boiling the wool as for the common fcarlet, a.nd then boil- ing THE dyer's assistant, H^ It In a fecond liquor, whith two ounces of alutn and one ounce of tartar, for each pound of wool, leaviDg it one hour in the hquor. A frelh liquor is then prep-red, in which fix drachms of cochineal is put for every pound ■:>( wool. After it has re- mained an hour in this liquor, it is taken out, and paflec) imintdjately tarough a liquor of barilla and ialt ammoniav. By this method, gradations of very be uiiful crimfon ftiades are made by diminilhing the quantity or the cochineal. It is to be obferved, that in this procefs there are but fix drachms of cochineal to dy each pound of wool, becaufe in the firft liquor a drachm and a halt of coch'tieal is ■ufed tor each pound. It is alfo neceflaty to remark, that, to fadden thefe crimfons, the liquor of the alkaline fait and fait ammoi.iac be not made too hot, becaufe the feparation of the volatile fpirit of this la it fait would be too quick, and the cryrtal of tartar of the iirft liquor would lofe its proper efFedt by being changed, as I have already faid into a foluble tartar. The fame operation may be done by ufing one part of the cochineal fylveftre inflead of the fine cochineal, and the colour is not lefs beautifol, for commonly four parts of fylveflre have not more effect in dying than one part of fine cochineal. The fylvefire may alfo be ufed in dying fcarlet, but with great precaution ; it fliould only be ufed in baftard fcariets and half crimfons. I (hall fpeak of this when I treat of thefe colours in particular. When a fcarlet is fpotted or fpoiled in the ope- ration by fome unforefeen accident, or even when the dye has failed, the common remedy is to make it a crimfon, and for that purpofe, it is dipt in a Jiquor where about two pounds of alum are added for each hundred weight of wool. It is imme- diately 120 THE dyer's ASSISTANT. diately plunged in this liquor, and left there until it has acquired the (hade of the crimfon defired. Languedoc Crimfon, I fliall now fhow the method they follow in Lan- guedoc to make a very beautiful fort of crimfon, or the cloths exported to the Levant, but which is not fo much faddened as that which I have juft fpoken of, and which refembles much more the Venetian fcarlet. For five pieces of cloth the -hquor io prepared as ufual, putting bran if necefl'ary. When it is more than lukewarm, ten pounds of fea-falt are put, inftead of cryftal of tartar, and when it is ready to boil, twenty-feven pounds of the fcarlet cumpofition, made after the manner of carcafline already defcribed, are poured in, and without adding cochineal the cloth is paffed through this liquor for tv^o hours, keeping it always turn- ing with the wynch, and continually boiling. It is afterwards taken out, aired and wafhed ; then a frefh liquor is made, with eight pounds and three quarters of cochineal powdered and fifted, and when it is ready to boil, twenty-one pounds of compofition are added ; the cloth is boiled for three quarters of an hour with the common precautions, after which it is taken out, aired and waflied : It is of a very fine crimfon, but very little faddened ; if it is required to be more faddened, a greater quantity of alum is put into the firft liquor of pre- paration, and in the fecond lefs of the compofition, the fea-falt is alfo added to this fecond liquor; a little pravSlice in this method will foon teach the Dyer to make all the ftiades that can properly be derived from crimfon., Whenever cochineal has been ufed, there is found at the bottom of the reddening liquor a quantity THE DVER S ASSISTANT. 121 quantity of very brown fediment, wl^'ch Is flung away with the liquor as ufelefs. I examined it and ound, that the liquor for the reddening of fcarlct contained a precipitated calx of tin : I united tb.is metal with a great deal of trouble; the remaining parts of this fediment are the drofs of the white tartar, or of the cream of tartar, united with the grofs parts of the bodies of the cochineal, which is, as has already been faid, a finall infe61. I walhed thofe little animal parts in cold water, and, by fhaking this water, I colled^ed, with a Imnll fieve, what the agitation caufed to rife on the furface. At'ter this manner I feparated tliefe light parts from tl-e earthy and metallic; I dried tliem fepj- rately, then levigited them with equal weight of frefh cryftal of tartar ; I boiled a portion with a little alum, and put in a pattern of white cloth, which boiled for three quarters of an hour, at the end of which it was dyed of a very beauniu! crim- fon. This experirrent having convinced me, that by powdering and fiftmg the cochineal as is commnnly pra'difed, all the profit that might be extiaded from this dear drug is not obtained, i thouc/ht propf^r to communicate this difccvery to the Dyers, that they might avail thcmfelves of it by the me- thod following. Take one ounce of cochineal powdered and fifted as ufual ; mix with it a quarter of its weight of very white cream of tartar very cryllalline a'nd very airy ; put the whule en a hard levigating flone, and levigate this mixture till it is reduced to an impalpabh powder; make ufe of this cociii- mal thus preparec. in the liquor, and in the redden- ing, fubtrsfting frcm the crejm of tartar, which is to be ufed in the liquor, \h.Q fmall quantity before ^^ ufed 122 THE dyer's ASSISTANT. ufed with the cochineal. What is put to the red- dening, although mixed with a fourth of the fame fait, does not prejudice its colour, it even appeared to me that it was more folid. Thofe that will fol- low this method will find that there is about a fourth naore profit to be obtained by it. The Natural Crmfon in Grain. In proportion for every pound of cloth or other things, take two ounces of tartar pure, and two ounces of alum ; boil them with the goods an hour and a half; then rince the goods very well from the boiling. The kettle muft be filled again with clear water and a few handfuls of bran put in, in order to take out the filth of the water, as well as to foften it. Scum the fcurf off when it begins to boil, and put in an »unce of well powdered grain, with one dram of red arfenic and onefpoon- ful of burnt wine lees ; this gives a pretty luflre ; then wafli and rince it well, and you have a moft beautiful colour. CHAP. XII. SCARLET OF GUM-LACQUE. THE red part of the gum-lacque -may be alfo ufed for the dying of fcarlet, and if this fear- let has not all the brightnefs of that made of fine cochineal alone, it has the advantage of being more lading. The gum-lacque, which is in branches or fmall fticks and full of animal parts, is the fitteft for dy- ingo THE dyer's ASSrsTAN'T. I23 I'ng. It muft be red within, and its cxlernal parts of a blackifti brown ; it appears, by a particular examination made of it by M. Geoffrey fome years fince, that it is a fort of hive, fomewhat like that of bees, wafps, &c. Some Dyers make ufe of it powdered snd tied in a linen bag; but this is a bad method, for ihere always paffes throui2;h the cloth fome refi.o'is por- tion of the gum, which melts in the boiling water of the copper, and flicks to the cloth, where it be- comes fo ad;-,erent wiien cold, that it mud be fcraped off with a knife. Others reduce it to powder, boil it in water, and after it has given ail its colour, let it cool, and the refinous parts fall to the bottom. The water is poured out, and evaporated by the air, vdiere it of- ten becomes fliriking, and wlien it has acquired t!;e confiftence of thick honey, it is put up into voffels for ufe. Under this form it is pretty c'ifikult jUilly to determine the quantity that is ufed; tl is induced me to feek the means of obtaining this tinfiure fe- parated from its refinous gu;», without being obliged to evaporate Co great a qu3ntity of water to have it dry, and to reduce it to powder. I tried it with weak iime water, with a decc6^ion of the heart of agaric, w'ith a decoclion of com- frey-foot, recommended in an. ancient book of phyfic; in all thefe the water leaves a part of the dye, and it ilill pafles too full of colour, and it ought to be evaporated to get all tl'.e dye; this evaporation I wanted to avoid, therefore 1 made ufe of mucilaginous or llimy roots, which, of thetn- felves gave no colour, but whofe mucilage might retain the colouring pnrts, fo that ttiey might re- main with it on the fil^^er. The great comfrey-root has, as yet, the bell anfwcred my intention : 1 ufe it dry and in a grofs ■F 2 powder, 124- THE DVER S AiSI^TAKT. powder, putting half a dram to each quart of wa- ter, which is boiled a quarter of 311 hour, pafTin^ it through a hair lleve. It immediately extracts from it a beautitu! crimfon tinclure; put the vefTel to (i\2t(\ in a nioderate heat for twelve hours, (bak- ing it feven or eight tirres to mix it with tiie gum that remains at the bottom, then pour eft the wa- ter that is loaded with colour in a \t{U:l fufficientJv large, that three-fourths may remain empty, and nil it v\ith cold water : then pour a very Imail quantity of f^rorg fclutio:^. ct R.oman alum on the tincture; the mucilagincu? or llimy dye precipitates 3!l"e!f, and if the W2ttr which appears on the top ap- pears ftiil coloured, add Tome drops of the folutioa of alum to finifh the precipitation, and this re- peat till the water becoir.cs as clezr as common water. When the crifr:!rafled by cominor. r.vtr water, by ir.akir.g it a lit;;.- more than la!:s-warm, and inclcErs the pcwdcr^d l&cqae in a coa?fe wcoUsobsg. THE dyer's assistant. 12/ Having feparatcd the coccus from the earth, which they do by a riddle made for that purpofe,. their chief care is, that it fnould not change into a fmaii worm ; tor this purpofe they fprinkle it with vinegar, and fometimes with very cold wa- ter ; they then brinst them to a warm place, or elfe expofe them to the fun to dry j without thi^, thefe inieils would dcftroy thsmfelves, and if they were dryed too precipitately, they would lofe their beautiful colour. Sometimes they feparate tiicfc fmall infe£^s from their veficles or bladders with the ends of their fingers by a gentle preflbre, whicii they form into final! round cakes. The Dyers pay dearer for this dye when in lump than wi^en it is in grain. Bernard de Bernitz, from whofe book I have taken this, adds, that the great marechal Konitf- poliki, and fome other Pohfli noblemen, who had lands in the Ukrania, fet this gathering of the coc- cus to the Jews at a confiderable profit, and caufed it to be gathered by their vafi^ls ; that the Turks and Arminians, who bought this drug of the Jews, vfed it tor the dying of wool, fiik, the manes and tails of their horfes ; that the Turki(h womerv made ufe of it to paint their fingers' ends of a beautiful carnation colour ; and that formerly the Dutch ufed to buy the coccus at a high price, and mixed it with an equal quantity of cochineal ; that with the dye of this infed and chalk, a lacque for the painters might be made as fine as the Florence lacque ; and that a beautiful red W'as prepared from it for the toilet of the ladies in Fraiice and Spain. F 4 ^ CHAF. 128 THE dyer's assistant, CHAP. IV. 0? THE RED CF MADDER. THE root cf madder is the only part cf this _^ plant which is uTed in dying. Of all the rers this is the moil laHine, v.hen it is put on a cloth 1. r Auft that is thcrcughly fc-ured, then pre- pared with the falts with which it is to be boiled two or three hours, without which, this red, fo tenacious after the preparation of the fubjecl, would fcarceiy relift inore the proofs of tl.e reds than any other i gredients of the tdlfe dye. This is a proof ti.at the pores cf the fibres of the wool ouglit not orJy to be w.U fcoureu from the yolk or un^^uous trsnfpiration ot the animal, wnich iTiay have re;T)ained, notwithftanding the fcouring of tiie wool after the comm.-.n manner with water and urine ; bu: it is alfo necefiary, that thefe fame pores be plaillered inwardly \Mth fotne of thofe falts which are called hard, hecaufe they do not calcine in the air, and cannot be dilTjlved by rain wattr, or by the moiAure or the air in rainy weather. Such is, as has been faid before, the white trude t-rtar, the red and the cryftal of tartar, ot w'nich, according to common cuftom, about a fourth is put into the preparing liquor, with two- ihirds or three- fourths of alum. The beft madder roots come ^nerally from Zealand, where this plant is cultivated in the illands of Ter{^:e«, Zerzee, Sommerdyke, and Thoo'en. That from tiie tiiH of thefe iflands is elteeined the beft; the foil is ciay, fat, and fomewhat fait. The lands that are deemed the bed for the cultivation of this p'ant are new lands, that only ferved for pailure, which are always ftefhtr and moifter than cihers. The Zealar.dcrs are beholden to the re- fugees thj: dyer's assistant. 129 /"ugees of Flanders for the cultivation and great commerce o( this root. It is known in trade and dying under the names of grape- madJerj bunch madder, &c. It is how- ever the fame root ; ail the difference in regard to its quality is, that the one kind contains pith and roof, and the other has the fmall fibres from its principal root adhering to it. Both are prepared by the fame work, which I (hall not relate the particulars of here, as it would only ferve to lengthen this treatife to no purpofe. They chooie the fineli roots for the fiift fort, drying them with care, grinding them and feparat- ing the rind at the mill, and prefcrving the middle of the root ground in hogfheads, where it remains for two or three years ; for after this time, it is belter for dying than it would have been coming from the mill ; for if madder was not kept clofe after this manner, the air would fpoil it, and the colour would be lefs bright. It is at fird yellow, but it reddens and grows brown by age ; the hcf\ is of a fafFron colour, in hard lumps, of a ftrong fmell, and yet not difagree.ible. It is alia culti- vated about Lifle in Flanders, and feveral other places of the kingdom, where it v/as found to grow fpontaneouily. The madders which are made ufe of in the Le= vant and in India, for the dying of cottons, are fomewhat different from the kinds ufed in Europe,- it is named chat on the coail of Coroinandel. This' plant thus caiied, grows abundantly in the woods' on the coaft of Malabar, and this ch:dt is the wilcF fort. The cultivated comes from Vafur and 'Fuc- corin, and the mofl efteemed of all is the chat of Perfia, named dtwias. They alfo gather on the coaft of CoromaiJel the root of another plant called ra^ de chaye, or F 5 root 13^ THE DYZR's assist AKT. root cf colcur, srid which was thought to be a kind of ruh':a tinSiirum, but is the root of a kind oi gallium fijre albo.^ as it appeared by obfervations fent from India in 1748. It has a Icng (lender root, U'liich dyes cotton of a tolerable handrcme red, when it has received all the preparations previous to the dye. At Kurder, in the neighbourhood of Smyrna, and in the countries of AkilTar and of Yordas, they cultivate another kind of madder, which is called in tlie country ckioc-lsya ek'im kaz^'.a. This of all the madders is the befl: for the red dye, by the proofs that have been made of it, and tar mere efteemed in the Levant than the nneft Zealand madder the Dutch bring there. This madder fo much valued is called by the modern Greeks lizari, and by the Arabs /ij/'m *. There is another kind of msdder in Canada called iYjTa-voyana. It is a very fmall roDt, which produces pretty near the fame effect as our Euro- pean madder. The water of preparation f-Dr madder red :. pretty near the fame as for kerme?, that is cctn- pofed of alum and tartar. The Dyers do not agree as to the proportions ; but the beft appears to be four ounces of alum and one of red tartar to eacH- pound of fpun wool, and about one- tVrelith part of four wate.'", and let the wool boil in it for two hours. If it is fpun wool, leave it for feven or eight days, that it may be well moiilened by ths diflblution of thefe faits j and if it is cloth, finilh it the fourth day. To dye wool with madder, prepare a freia li- quor, and when the water is come to a heat to bear the ♦ Thefe kinds of inadders give brighrer red; than tfae fceft grape nsadcer of Zealand, for tisev are dyed in the air aiw noi ia a ftovs. The msdder of Lanjue-cc, even that of Poitcu. fuc- cceds 33 well as that of iLzari, ^en it is dri'id without £:c. THE dyer's assistant. I3I the hand, put in half a pound of the finefl: grape madder for each pound of wool ; let it be well raked and mixed in the copper before the wool goes in,, keep the wool in an hour, during which time it muft not boil *. Shades from madder are obtained after the manner laid down for other co- lours, but thefe Ihades are little ufed, except in a mixture of feveral colours. When feveral pieces of cloth are to be dyed at once in madder red, the operation is the fame, only augmenting the ingredients in proportion -, and let it be remarked that in fmall operations the quantity of ingredients muft be fomewhat greater than in great, not only in madder red> but in all other colours. Thefe reds are never fo beautiful as thofe of the- kermes, and much lefs io than thofe of the lacque or cochineal, but they cofl lefs, and are made ufe- of for common fiufFs whofe low prices would not allow a dearer dye. Moft of the reds fur the army are of madder, faddened with archil or brazil, (though thefe drugs be of the fafe dye) to make them finer, and more on the velvet, which perfec- tion -could not be procured to them even with- cochineal, without confiderably augmenting the price. I have already faid that madder put on fluffs not being prepared to receive it by the alum and tar- tar-water, did in fact give its red colour, but that which it dyed was blotted and net lairing, it is. therefore the faitsthat fecure the dye; this is com- mon to all other colours red or yellow, which can- not be made without a preparing liquor. Now tbs qucftion is, whether t^.ef€ a£t by taking off the re* mams of the oily and fat traniplration of the Caeep^^, F 6 ct; * If madder is bollec', its rid becomes obfcure, and cf a bv.ck. cobur. 132. THE DVEH's ASilSTAMT. or whether thst of the two falts, particuisriy that which even cannot be carried by iuke-warm wa- ter, remains tocatch, feiz.- and cement the colour- ing atone-, openea or dilated by the heat of water to receive it, and contrai^ted by the cold to retain it. To determine which, ufe any alkaline fairs, fuch as pctalTi, the clarified lays of oak-afhes, or any other pure lixivial fait inftead of alum and tartar, put in a due proportion fo as not to dilTolve ths woo!, and afcerwards dip the fluff in madder li- quor. This ftuff will come out coloured, but will not hft, even boiling water will carry off three- fourths of the colour. Now it cannot be faid that a lixed alkaline fait is unfit to extract from tlie pores of the wool the yolk or fat of the (heep, fince lixivijl falts are ufed with fuccefs in feveral cafes, to take the greafe cut of tluffs of what kind foever they be, vi'hich water alone could not take off. It is alfo well kr.own, that with fats foreign to tiie i^uff, and an a.kaline fait, a kind of foap is formed which water eafily carries off. Again, take a piece of ftuff dyed in madder red, according; to the ufual method, boil it fome time in a folution of fixv alkaline falts, a fmall quantity v/ill alfo deftroy the colour, for the fixt alkali, at- tacking the fmall atoms of the cryftal of ^artar or crude tartar, which lines the pores of the woo), forms a foluble tartar, which water difiblves very eafily, and confequently the pores being opened in the hot vk'ater of the experiment, the col curing atom cam.e out with the faline atom that fheathed it. This fluff being wadied in water, the remain- ing red colour is diluted, and a colour half browrt snd half dirty remains. If, infiead of an alkaline fait, foap is fuhfiituted, (which is an akaline fair, mitigated by oil) and another piece of cioth dyed alfo in madder, be boiled for a few minutes, the red THE DYERS ASSISTANT. I 33 red will become finer, becaufe the alkali whicli is in the foap being ftieathed with oil, it could not at- tack the vesetable acid, and the boiling on'y car- ried off the colouring parts ill ftuck together, and their numbers diminilhing, what remains muft ap- pear deeper or clearer. 1 mull aiib add, for further proof of the aflual exiilerice of falts in the. pores of a fluff prepared with alum and tartar, betorc dying it with madder, that more or lefs tartar gives an infinite variety of iliades with this root only ; for if the quantity of alum be diirunifhed, and thst of the tartar aug- mented, a cinnamon will be had, and ev? n if no- thing but tartar alone be put into the liquor, the red is loft, and a dt-ep cinnamon or brown-root colour is obtained, though of a very good dye ; for the crude tartar, which is an acid fait, has fo much diff^lved the part which rtiould have pro- duced the red colour, that there onlv remained a very finall quantity, with the ligneous fibres of the root, which, like all other common roots, does then yield but a brown colour, more or lefs deep accord- ing to the quantity ufed. I have already proved that the acid which brightens the red, diffolves them if too much is ufed, and divides them into particles fo extremely minute, that they are not perceptible. If in the place of tartar, any fait which is eafily diffolved be put will- rhe alum in the liquor, to prepare the fluff for the madder dye, fuch as fait petre, the greater part of the maddtir red becomes ufelefs, it difappears, or does not ftick on, and nothing is got but a very bright cinnamon, which will not fufficicntly fland the proof, becaufe the two falts ufed in the preparing liquor are not of the harcinefs of the tartar. Velatile I.34- THE DYER S ASSISTANT. Volatile urinous alkalis which are obtained from certain plants, fuch as the perllla, the archil of the Canaries, and other nr>oiTes or lichens, deftroy alfo the madder red, but at the fame time communicate anotlier to it, for on experiment, madder prepared after the manner of archil with fermented urme and quick lime, produced only nut colours, but whicli neverthelefs are lairing; becaufe there entered into the liquor only the little portion of urinous volatile that moiftened the madder which the boiling was fufScient ro evaporate, ana tefides, the cloth was fufficientiy furnifned with the falts of the liquor made as ufual, to retain the colouring parts of the dye. When a pure red, that for cochineal an exam- ple, is l:id upon a c'.oth firft dyed in blue, and af- terwards prepared with the liquor of tartar, and alum to receive and retain this red, a purple cr vio- let is produced according to the quantity of blue cy red. The no of madder has not this efie(5l, for it is not a pure red like that of the cochineal, and a» I faid above, it is altered by the brown ligneous fibres of its root, and makes on the blue a cHefnat colour, more or lefs deep according to the preced- ing:, i:uenfity of the blue lirft laid on. If this chef- Fiut colour is wanted to have purple cau, a little cochineal muft be added. In order to avoid this brown of the root, the Dyers who make the beft reds of madder take great heed t.^ ufe the liquor of madder a little mere tiian lukewarm J the madder tarnifhes confiderably by the heat of the vsater, extracting tlie particles which dye brown, and unite themfeives with the red. This inconveniency might be remedied, if at tlie tinrie that the madder root is frefh a means cOuJd be found to feparate from tl>e reft of this root the led circle which is underneath its brown pelicle, and THE dyer's assistant. I J9 and which furrounds the middle pith ; but this ^vork would augment its price, and even then it would not afford fo good a red as cochineal. How- ever, it might be attempted to dye cottons red, whofe price might bear the expences of this pre- paration. Madder being of all ingredients the cheapeft of any that dye red and of the good dye, it is mixt with others to diminifh the price. It is with mad- der and kermes that the bailard fcarlets of grain are dyed, othcrwife called half- grain fcarlets, ;ind with inadder and cochineal the half-common fcar- lets, and the half-crimfons are made. To make the half- grain fcarlet, the water of preparation, and all the reft of the operation is to be performed after the fame manner as fcarlet made of the grain of kt-rmes, or the common Vene- tian, only the fecond liquor is compcfed of halt kermes and half grape madder. For the half-fcarlet and flame-colour, the cona- poUtion and preparation is as ufual, nothing but pure cochineal being put in, but in the reddening, half cochineal and half madder is ufed : here al fo the fylveftre may be made ufe of, for alter having made the preparation with cochineal, for redden- ing, ufe half a pound of cochineal, a pound and 3 half of fylveftre, and one pound of madder infiead of cochineal alone, That the wool and fluffs may be dyed as equally as poffible, it is necefTary that the two kinds of co- chineal be well rubbed or lifted, as alfo the madder, with which they muft be well incorporated before ihey are put into the liquor. This mufl be ob- fcrved in all colours where feveral ingredients are rnixt together. I his half fcarlet is finifhed like the common fcarlet, and it may be faddened after the 136 THE DY£R's assistant. the fame manner, either with boiling v/ater or alum. The balf-criinfon is made like the common crimfon, only ufing half madder, and half cochin- eal, the cochineal fyiveilre tray be ufed here alfo, obferving only to retrench half of the common cochineal, and to replace it with three times as much of the fylvcftre. U a p;reater quantity of the fylveftre was ufed, and more of the otiiei taken off, the colour would not be fo fine. Various (hades may be produced by augmenting or IfiTening the ' madder or cochineal. Purple with Madder wit I out Blue. I fliall finilh this cliapter with an experiment •jvhich afforded a pretty fine purple without cochin- eal, or without the cloth being firft dyed blue. I boiled a piece of cloth weighing half an ounce, with ten grains of Roman a'utn, and fix grains of cry- iial of tartar ; hair an hour after, I took it out, Wrung it, and let it cool ; then added to the fime liquor twenty-four grains of grape madder; after it hatl furnifiied its dye to this liquor, fiill im- pregnated witli fait?, 1 dropt in twenty-fcur drop? of a folution of bifnfVJth, iriade with equalpans of water and fpirit ot nitre, and then dipt my cloth again. Hnlf an hour af;er, T took rt out, wrung and wnfhed it; it was alnioft as fin"e a crimuni as if it had been done vinh. cochineal, it had even a fufficient ground to have remained in that fiate. I dipt it again in the fame liquor, and boiled it for a quarter of an hcur, it cartre out a pretty brig^ht purple ; this purple, tried by tlie proof of a- lum, rf^ufesand embelliAies itfelf, and by the proof of foap it remained of a much finer red than the common reds of madder. If THE dyer's assistant. J 37 If the doth be kept for feveral days moidened in its liquor of tartar and alum, and afterwards dyed in frefh madder liquor, plain and without falts, according to the common method, till it has ta- ken a bright cinnamon colour, and to this liquor be added the fame folution of bifmuth, a chefnut colour, and no purple will be obtained. This Ihows what exadtn.efs is required in defcribing the procefles of dying, for want of which, all books hitherto publifhed on this art have been ufelefs, as they ntglecled to point out the neccflary circum- flan'-es tor the fuccefs of the d( fired colour. In this fecond experi-rent, ths cloth did at fird take too much falts, they remained top long in ir, and there was none in the liquor of the dye ; for want of alum the purple did not appear, becaufe the white earth of this fait could not precipitate it- M( with the diffolved pans of the bifmuth, which, as has been faid in the chapter of the kermes, carry with them the blue parss of the fmalt, which is always found in the mine of bifmuth, and a portion of which very probably unites itfelt to this half r«ietal during the melting. TWis mutual precipitation is performed in operation of dying, by the help of the aftringent parts of the ligneous fibres of the mad- der root. CHAP. XV. OF yr.LLJW, "Ithrrto ten forts of drugs have been named for dyinj yellow, but by the proofs that )iave been made it is certain there are but five that are fufficiently lafting to be ufed in the good dye. Several more might be added to ihefe five, as yel- lows 138 THE dyer's assistant. lows are eaCly ohtslned. I fliall therefore firft fpeak of thefe five, which are t*anner as the other ingredi- ents for dying brown, and in feveral places is even tolerated in the good dye, as. it refills the fun and air as well as t;ie others, I thought it would not be improper here to give the method of wotkip.;^ it ; for the fame re?.fon I fliaH now defcribe the method of dying with foot, though permitted only in the lefler dye, having lefs folidlty than the reir, befides hardening the wool, and giving a difagree-* able fmell to the ftufTs. The foot * is commonly put into the copper the fame time as the water, and the whole is v.ell boiled together; th.e ftuir is then dipt in, which is to boil more or lefs, according to the iliadc re- quired ; after v^hich it is taken out and aired, and thofe put in wliich are to be lighter; they are then to be well wafhed and dried, but it is better to boil the foot in the water for two hours then let it fettle, and empty the liquor into another copper, Vvfitliout mixing the foot ; the wool and {luffs are put into this liquor, and are lefs hardened and dried tliau when they have been mixt with the foot itfelf, but the colour is riot folid, and it is better not to m^ke life of it for dying fluffs that bear a price, and G more * * Wood foot. 146 THE DYLR's assistant. ir.ore fo as all its flia.'es may be had by the fcre^ going ingredients, which are better, more lafting, and aifo fotten the woo!. The Dvers of he lelTer dye ufually employ the rlnc's of the nut and the root of the wahnn-trec for thciT hrown colours ; the working of thffe two ingredients bein? comtron to Dyers or the greater and itfler dye ; but there are places where it is dif- ficult to ohtain them, and then the faunders and even foot are obliged to be ufed in their ftead. What I have hitherto faid to account for the foiidity ot the colours of t'ne good dye, may feem nr:t fet in with foiidity, but by the hr-ip of a fait capable of ceuenting the colouring atoms, 1 he foot does not give lo lafting a brow n, be- caufe it O'lv contains a v latile and an earthy fait eafily difTolved, and in fa»5t the foot being only cciri.iof%l of the lighTefl and mofl volatile parts of comhuftible bo'ies, which hjve ferved as food few the fire, it could not raife tartar of vitriol along with THE dyer's assistant. I47 with it, viiiich is a fait that does not rife by heat, and which is alfo feldoin (ound in the wood whicii we comitioniy burn in our chimnies. As 1 am not wilHng to omit any living within the limits of my knowledge, on the article of woi Hen dying, 1 fliall give two or three hmts on the acid of vitriol. if you would have a beautiful claret on wool, fluffs, or cloth, boil in a copper ot a good fize, redwood or faunders in proportion to the (haJe you want, and two pou>ds ot logwo'-d, for forty pounds of wool previoufly fc-^ured. When the in- gred.ents h ve boiled iialt an h( ur, put a pi,,t of oil of vitriol into a pail of cold water, and add it to the liquor, when the wool inuft be put m, and gently boiled for two or three hours. It it then to be taken up on a fcray, that is, let acrcfs the cop- per to drain, and five or fix pails of water poured over it, l>.e copper muft be tlien run down and filled as before with fair water, and when it is lior, ten pounds of copperas and tour ounces of pearl- alhcs muft be adc'ed, and the v.'ool returned and well worked with a long pole to n.ake it even The alhes (which are a fixed alkali) a6i upon the logwood, and give- it a tire luftre ac the faaie time. It weakens the a^id of the vitriol, and makes way for the copperas to do its part, which would ot er- wife be kept at a diflance ; the vitriol d es not obftrudf the cloth in the fulling mili, fur thf- vi:rioI, which fome fuppoie to be a great enei.y ir, the mill, is divef^eu ot it.s acid by the (ir 'ng alkali contained in the chamberley in fcouring, and the colour remains pertedily vivid. If f r torry pounds or wool, &c. ten pcu.ds of nut-^alls were bruifed' and boiled with the above ingredients, the acid therein contained woul produce as biliiant a colour, andj if pofTible, more hcldiog than the G 2 former j 148 THE dyer's assistant. former ; but if galls are ufcd, the fame liquor will do the faiTie buiii efs when the copperns is added without 2(hes 2s a frefli water would when vitriol js ufed. It ferry pounds of cloth, ftuff, or wcrfted were boiled in a fufficient quantity of redwood or iaunders, and one pint of prepared aquafortis be added to the liquor after the g( ods have boiled aa hour and a half, and then turned well for half an hour, the colour will be vivid and fine ; the cop- per muft be well cooled when tlie fpirits are put in. When cloth or fluffs are dyed claret with oil of -vitriol, great care muft be taken to turn them cot\- tinually over the wench, and particularly in taking out, obferve the inftant the laft end comes up to take off into a large tub of cold water, that all parts may cool alike, or the colour will be very uneven, as the vitriol when hot will not bear the air. Oil of vitriol is fo ufcful a thing in dying, that any colour, fave woaded blue or green, may, by the help of its acid, be brought to a fine claret, black not excepted. CHAP. XVIi. OF BLACK. BLACK is the fifth of the primary colours. To dye the beft and the mcft lively fhade, a velTel fuficiently large muft be filled with foft water, and for every hundred weight of cloth, thirty pounds of logwood in chips muft be put in, with half a pail ot'^elder bark and fix pounds of fumach ; boil thefe ingredients together half an hour, when the cloth may be entered (the copper being firft cooled by ■^ the THE dyer's assistant, I49 the addition of cold water), and boiled an hour and a half, being inftantly turned on the wynch to pre- vent an unevennefs of dye. This operation being ended, which is called a preparation or (luffing the blacks, I (hall proceed to the finhhing. A, fiTiall tub is to be placed at the (ide of the copper, out of which it muft be iilled with hot li- quor, in which put ten or fourteen pounds or cop- peras to diilblve ; the cloth is then kept turning, whilil a man with a piggin h ladiiig the copperas water into the copper; the cloth is turned here at 3 boilinw heat one hour, then taken out and coo'ed wdl in all parts alike ; when thoroughly cold,, re- turn it into the copper, v/ith two haadfuls of cop- peras, and boil it gently as bef jre for two hourSj then cool it again. Wliilil the fecond coo'.ing is carrying en, (ix pounds of logwood, ten pounds of bark, 'and two pounds of argil, with ten pounds of foda or co nmoa afhes, and three pounds of copperas, muft be added to the liquor ; thefe ingredients muft be made to boil one hour, when the goods mull be turned and workrd one hour. Kep the v/ynch continually turning, always obfervmg that the fmall portion of air which the goods receive by turning on the wynch, contributes much to the beauty of the co- lour. Some Dyers inftead of aihes ufe chaiiiberley, but this is a bad cuftom. If they would become good black Dyers, tiiey muft abandon their old pradice, and by mixing their natural genius with reafon and good fenfe, they, will f lon find by ex- perience, that the acid of the argil ads only on the vitriolic acid of th? copperas, and prevents a broAfn or rufty hue that will un:iypidably proceed from the )ogwju(t be fo weak, that it is only a miik and water colour, which is very difficult to give fmoot'.i and equal. When this fhide h.as been happily hit, it is eaiier to give the yellow dye that fuits it, w'lih the virga au?-ea than with the weld, rhe virga aurea is not known to the D) ers of Lan- guedoc, who make moft of thefe kind of colours, and as the neceffary blue (hades are diflicult to dye, they are fomctimes permitted to dye celadons with verdigrife, alihougli this colour be in the rank of the lelTer dye. The Dutch make this' colour perfe<2:Iy, and render it more bfting than it commonly is with the verdigrife. Here follows their method. Two coppers are fet a little diftance the one from the other. In the firft is put for two pieces of cloth of forty. Eve or fiity elis long, eight or ten 15S THE dv;r's ass::tant. ten pounc's of white f:ap cut hr-all and perfectly iTielted. When the liquor is ready to boil, rhe cloths are dipt in, and boil for lialf an h^ur. Another liquor is prepared in the next copper, and whtn it is I'calding hot a clcth bag is put in con- taining eight or ten pounds of Cyprus or blue v>rif)l, and ten or twelve pounds of iime, botli powr'ered and we 1 mixt j this mixture rrtuii be as equal z- polFible. The bag is moved about in the hot water, but not boiling, till all the blue vitriol is dilToAed in the liquor ; then a wynch is pur up, fiirrounded hv a clesn linen cloth, and weli taltened on ; one end ot the two cloths is put i)n the vvvnch, which is turned iwiftly th-t the cl ths may quickly p^ls thrcugli the foap liquor to that of the vitriol ; then the wynch ss worlced more gently, that the cloth may have time to charge itfclf with the parts o* copper, which the li ne has fcattercd in the .iquor, by feparatinjj ar :d precipitating them from the vitriol w \:n contained them. The cloths are left in t' is l.quor, wluch nhuit not bit until thev hdve taken t e (hac^e ot the celadon that was wanted ; then they are taken out an i well aired : they muft be entirely cold refore they are walhed, and muft touch no wood befr.re they aie, for the wood fpots them ; for this reafon the wynch z?A thrC hoile are furiounded with cioth. CHAP. XX. OF THE ^5IXTL'RE OF BLUE AN"t» BRO'.VI^. Ln^TLE ufe is made of the (hade which arifes from the mixture cf blue and brown : thefc £re ■^reenjfh gieys, or a kind or Oiives, wiiich are ciily fi: to match fhades fcr tapsftries; thefe colours THE dyer's assistant. 159 colours are eafily made when wanted, and it is equal to begin by the blue or the brown colour to the fpun wool ; but care muft be taken that it be well fcoured, as is done for the blue and the com- pound colours which are fimfhed by dipping them in the vat. Any fubflance that dyes brown inay be equally made ufe of for thefe colours, and ioinc give the (hade required better than others. CHAP. xxr. OF THE MIXTURE OF BLUE AND BLACK. 'O particular fha:!e arifes fronn this mixture, ^ , except by the mixture of blue and grey, (which are fhades of the black). In this cafe the blue muft not be very deep, and is afterwards worked the fame as the black, excepting', that the colour not beina; fo dark lefs copperas enters in ; but I repeat again tliat this colour ou'iht only to be efteemed a fhade of the black Thus it may be laid that no fhades are made from olue and black ufcd by themfelves, and very few trom blue and brown. CHAP. XXII. OF THE MIXTURE OF RED AND YELLOW. FROM fcarlet of grain or kermes and the yel- low are formed the aurora, ttie marigold, and the orange. The v;ool is firrt boiled m alum and tartar, and dyed in cne of theie colours, and then dipped in the fecond, or by mixing in the fame li- quor i6o THE dvcr's assistant. quor the kernies, the weld, the favory, Sec. and fa dyit.2; it at once. Yet it is eaiier to attain the exact (hades bv dyin^ it at twice ; for this reafon, tlie wool or the itutF ir.ay be alternately paiTed in the one or other Uquor, tili it be precifeiy ot the defired colour. The lobfter and pomegranate colours are done exadly as fcarlet is, that is, boiled with cream of tartar, cochineal, and the compofition, after which thev are taken out, aired, and waihed. For the finiihing, a frefli liquor is prepared as lor the Larlet, ► ut without cr chineal ; in its ftead, a little yeKovv \^'ooj ground is fubftitute;! -, this depends on the colour the ftuff is intended to be of. The more it borders on the orange, the more yellow Viced is added, diminifhing the quantity ot the co-> chineal. i endeavoured to make this colour after three different n.ethods, and lucceeded in ail j the firft- is that which I have cefcnbed ; the fecond is by putting tuilic inilead ot veLow weed, and this laves a gre^t deal of cochineal, and the (h^de ot the fuftic is a great deal more on the orange than the yellow wood, but thefe ingredients are n-, t lafting, and ought not to be u!ed but in the f iTer dye. The method is with cochineal alone, by augment- ing the quantity of the compofition, winch roufes the coctMncal. and turns it to orange as nuch as is ciefired ; but this is attended with verv great in- convenience, jft, The Colour bcco.i es ver) ex- penfive, becaufc it requires more cochineal than common fcarlet, as the great quantity of the com- poiiti'jn, which is an acid, makes it lofe part or its ground. 2d, For the fame reafon tlie colour al- ways ] oks ftarvcd, it appears as if the cochineal had been fpared, the compofui n having difToived part of it. 3dj This large quantity of compofition hardens THK dyer's assistant. i6i hardens the wool, and makes it more liable to be fpotted by dirt and (harp liquor, and confequently this method is the worft, 1 mentioned that the Inconveniency of the fecond was ufing the fuftic, which is a wood forbid in the good dye ; confe- quently the firft ought to have the preference, if it give the lobfter colour as bright as the fecond. But this colour made by the yellow wood has not all the folidity that might be deiired, as I have tried by expofing it to the fun ; this at tirft appesrs ex- traordinary, fince the ingredients ufed have all the folidity poffible. But the reafon why they are not fo good in the prefent cafe is, that the cochineal ufeci in the fcarlet compofition and the cream of tartar are too folid ; thun the lobfter colour lofes nothing in the air. But the cafe is otherwife with the yellow wood, though it be very lafling on the wool boiled in alum and tsrtar, efpecially when a little alum is added to the liquor of its dye; it is not the fame as when the wool or fluff has received the water fcr the fcarlet preparation in which no alum can enter, and confequently when thefe fort of colours are expofed to the air, they fadden in a fliort time, that is, they Ici'e part of their orange colour, produced by the mixture of the yellow with the red, and the effcdt of the air upon this colour is the fame, though it appears different from that on all others, &c. that it commonly turns them pale ; yet this one darkens and browns them by taking away part of its bright orange. For it is demotiflrated by fevera! chynVical experiments, that there is a vitriolic acid in ti^ air like unto that which may be extracled from alum. Now if a fluif dyed lobller colour was to be pafTed through a jiglit foiution of alum, the acid of the fait would i:nmediately fadden it, and the red of the cochineal would cclipre the orange dye ; the fame thing muft then l62 THE dyer's assistant. then happen when fuch a colour is expofed to the air, Vv'hich is itDpregnated with the fame acid. Very tew (hades are made from the crimfonand yellc w, bccaufe of the price of the liiA, and that pretty near the fame fhades are made with madder and kermes, yellow and half fcarlet of grain, as well as from ihe yellow and halt crju^fon. It is with thefe difFer^nt mixtures, that marigold, orange, gold yellow, and other like (hades are made, which are fimply produced hy the mixture of tlie yeli0\« and red, and fometirries by yellow alone. CflAP. XXI II. OF THE -MIXTURE OF RED AND BROWN. THE reds of the kermes and cochineal are nor ufed in this mixture, for madder has as gcod an effctfl on thofe which cannot become briglu, becaufe of the dark obfcure col. ur uf the brown, but after they are maddered, they are dipt in the old liquors of cochinal or kermes ; yet a liqu- r in thofe ingredients is felriom purpofely pre- pared, being too dear for fuch common colours which are as eafily made with madder. The ftufF is to be boiled with a qyantity of alum and t rtar, proportioned to the red fhade of mad 'er intended ; it is then paflVd through a liquor of this root, and afterwarrfs dipped and worked in a liquor ot walnut roots or walnut rinds ; the following colours will be produced, viz. cinnamon, tobacco, chefnut, mufic, bear's h.alr, and numherhfs oihrs, by vary- ing the ground of the madder froai the brownell to the lighteil, and keeping then longer or fh.rter in t!ie liquor of the roct. The proccfs m.ay bcgia, witliin any one of tliefe colours, but the red isx:om.-> monly THE dyer's assistant. 163 monly dyed firft, as the liquor proper for the mad- der might hurt the brjvvn, therelore they are not to be mixt as the red-and yellow are foiBeiimes. CHAP. XXIV. OF THE MIXTURE OF YELLOW AND BROWN. FROM this mixture are produced the {hades of feulemort and bear's hair. Soot is commonly ufed in thefe colours inftead of the rinds 61' walnuts, or the root of the walnut tree, as it makes them finer, but care muft be taken tl^at the wool or ftufF be well fcoured after it is dyed, to take off the bad fmell of the liquor; for only the clear hqu r of the foot is to be ufed, as has already been faid. I he walnut rinds are preferable to the foot, unlefs obliged to match a pattern of fc'ulemf}rt with the greateft exadnefs, and which may fonetiines be done with the walnut. Thefe are the only two browns refulting from thefe fha'les, the fu nach and the alder bark not givin;^ fufficient ground. Wool muft be boiled in alum and tartar to dye it yellow before it is made brown , but it itfh ^uld not hive a fufficient ground ot yellow, it might be pafTed atrelh tnrough the yellow dye, notwithftand- ing it has been browned, though m fadt this method of feeking exadly the ihade does not make fo laft- ing a colour as when the yellow was at firft fuffi- ciently dye 1 ; for wl.en the yellow is dyed firft, the brown is a great deal brighter. CHAP 164 THE DY£R's assistant. CHAP. XXV. OF THE MIXTURE OF BROWN AND ELACK. FROM this rrixlure a great number of colours may be extruded, as cofFre, chefnur, prune, mufk, thorn, and feveral Hke (hades, wiv^fe num- bers are almoir infinite, and of great ufe. The method of working them is this : After the wool or fttfls have been made brown, as already defcribed, and that feyeral fliades have previoufly been given ; as for example, a ftronger brown tor the ccit'ee, chefnur, &c. gails, fumach, and elder bark are put into a copper in proportion to the quantities of ftufF to be dyed; the whole is- boilcd fur one hour, after which green copperas is to added. 7 he fluffs that are to be ligfitell, as tlie thorn, are firfl dipped in this liquor, then taken cur, and others that are to be browner are put in, obferving to add copperas to the liquor each time, and as occaficn may require, which is known by its not browning the ftuff quickly, thus continuing until ail the fluits are browned : the. liquor mufl not boil, nor be of a greater degree of heat than the hanJ can bear. When the galls and other ingredients are boiled, cr Id water is added to refrefh the livjuor before the ftufF is put in: this is a precaution that-is abfolutely neceffary, as I have often faid. The ftufFs are firft to be dipped in luke-w?rm water before they are put info the copper, leil fince they v/ere browned they fhould have dried ; and they mufi be aireJ when they have remained fome time in the brown- ing, by palling thC'Ti between the hands bythehiis, without which they would perhi;ps fpoil, blot, and be unequally dyed, and the brown, for want of airing. THE dyer's assistant. 165 airing, would not be laftins:, as there would not be a fucceflive congelation of the faline parts of the vitriol. I have now fliown all the neceflary colours or fhades wliich may be produced by the mixture of the primitive colours taken two by two, and have given a minute defcription both of their efFetSfs and the method of producing them. There being but few colours which may not be greatly varied, it depends on the judgment of the Dyer to choofe the eafieft, provided the colour be equally jfine. CHAP. XXVI. GF THE MIXTURE OF THE PRIMITIVE COLOURS, TAKEN THREE BY THREE. FROM blue, red, and yellow, the red olives and grcenifh greys are made, and fome other like ihades of little ufe only for fpun wool defigned for tapeftry. It would be a repetition to give the method of ufing thefe colours, having fufHciently explained it in the preceding pages. In the mixture, > where blue is a (hade, it is ufual to begin with it ; the ftuflp is afterwards boiled to give it the other colours, in which it is dipped alternately one after the other ; notwiih- flanding they are fometimes mixed together, and are as good, provided they are colours which re- quire the fame preparation ; for example, the mad- der-red and the yellow. As to the cochineal and kermes, they are feldom ufed in thefe common colours, but only light colours which have a bloom or vinous hue, and which muft be bright and bril- liant, and then they are not ufed in the laft liquor, that i66 THE dyer's assistant. that is, the fluff is only dipped in when it has re- ceived the riher colours, unltfs they are to be greyed a little, which is laflly done by pafling them throucrh the browning. It is i^i pcflible to give any precife rules for this work, and the it aft pradtice of ihefe rules will teach more than 1 could fay in many volumes. Olives are made from blue, red, and brown, from the deepeft to ihe li hteft, and by giving a little fhade of re.<, the flatcd greys, the lavender greys, and fuch like. From the blue, the red, and the black, an in- finite nu:Tiber ot grty of all (hares are made, as the fage erey, the pi-eon grey, the flate grey, the lead grey, the kir.g's and pnrKe's col( ur, browner than ufual, and a variety or other colours almofl iirnurrierable. From sellow, blue, and brown, are made the greens, goofe dung, and olives of all kinds. From brown, blue, and black, are produced the brown olives and the green greys. From the red, yellow, and brown, proceed the oranee, g<.ld colour, rriarigold, ftulemrirt, old car- nations, burnt cinnam- n, and tobacco of all kinds. From the red, yellow, and biack pretty near the fame as the laft, and the deep feu'emort ; as alfo the ox hair and brown nut, and others of the like kind. I give this lif^ of colours only as a table to fhow in general what ingredients are made ufe of to make thele forts of colours, which alfo partake of feveral others F(jur or five of thefe colours may be mixed to- gether ; however this is rarely done: a n)ii:ufe detail on this fubje6t would be ufelefs, becaufe all that may be done is ottentimes fuptrf^uous. 1 fhall new only relate the manner in which I have feen ;ibout THE dyer's assistant. 167 about forty different fhades of carnations made in fpun wool i this fxnrTiple will fh)w what may be done in all other cafes. Thre were none of thofe bnght (hades ot fcarlet in thefe which are made as in the chapter on that colour. Variety of Carnation Colours, All thefe flefh or carnations were old carnations, or (hades of it, fo that they were all obliged to he taken from the mixture of the red of kermes, yel- low, brown, and bUvk. An un-qual preparation was firft given to the wool, referving tor^he lighter (hades thofe whofe preparing liquors had been weakert. When they had remained as ufual four or tive days in the liquor, the li^jhter (ha^^es were dyed ; thefe colours were difpofed in f mr different veffels, which were always kept fufnciently hot without boiling. A fkain of wool was immediately dipped in the liquor of the kermes for a minute, it was taken out, wrung, and paffed through a liquor of weld, and an irtftant after through a brown one, and it became of the colour required by the Dyer \ he immediately dipped anbther, which remained a litle longer in each liquor: he went on after this manner, and when, after being ftDngly wrung, and feeined to want a little red or any other colour, he dipped it in the liquor which it appeared to want. By this niethod he brought all his colours to the defired fhade, and pafT^d through the brown thofe that were required to be deeper. I was fully perfuaded by this method of working, that only pjtience and pradiice were wanting to make all the colours which can be conceived. Too much caution cannot be given in this kind of work, to begin always with the li^hteft Ihades ^ for i68 THE dyer's assistant. for it often happens that they are kept too long in fome of thefe liquors, and then that Ikain inuft be made into a darker fliade. But when once the hghter fhades are matched, and in a right degrada- tion, the reft are eafily made. What I have been fp^aking of, relates only to 'vs'ool intended for tapeftry, when it is neceffsry that the fnades be carried on with tiie greateft degree of precifion, without which it would be impoffible to imitate the flefh colours of the painter. With regard to (luffs, it feldom or never hap- pens, tliat they are made in thefe gradations of (hades, or that (o many colours are mixed together; two or three are generally fufncient, fince it has been fiiown what a variety of colours arofe from their combination, that even names cannot be found for them. I think I have omitted nothing regarding the dying of wool or woollen (ix^ffs in the great and good dye, and I make no doubt but that by exactly following wliat I have laid down, each colour and all the Ihades may he executed to the greateft per- feiilion, as well in fleece wool, fpun wool, as on fluffs mianufa^lured in white. 1 think it yet neceflary to add Something in re- gard to mixed fluffs, that is, v/hofe wool is mixed before the ma.tufailuring ot the fruff, and to teach the method by .which this mixture of dyed wool is performed, to be afterwards carded an(! fpun to form a colour refuiting from thofe dif- ferent wools. It may he objefled, that this article rather re- lates to tt.e manufaduring of ftuffs than their dyes ; but to ihis 1 anfwer, that fometimes colours aie made by mixing wool of different fhades, whofe cclours would not e^^fily be imitated by dy- ing the fluff of a compound colour ; fome of thele , 2 . - r different THE dyer's assistant. 169 different (hades compofed of ingredients which would require a different preparation ; whereas by dying every part ot the wool feparately, the mixture is made without any difficulty ; it cannot tlierefore be improper here to give the manner of mixing together wool of different colouis, and I fnall alfo give the manner of making mixtures for an effay or proof in fmall, (which is always recef- fary; to choofe tliat which produces the moft agree- able effedl. CHAP. XXVIL OF THE MANNER OF MIXING WOOL OF DIFFFRENT COLOURS FOR CLOTHS OR MIXUD COLOURS. Colours 77iix£d in the Loom. ONE example of the method of mixing (af- ter the moft ex3(5t manner pcffibic) uool of different colours, will be fufficient, and it will be eafily applied in all other cafes required. Sup- pofe a mixed cloth of a coffee colour to be made, the following is the method of the manufadurers of Languedoc, and pr.'ity near the fame is prac- tifed in all other manufactories. Three hundred and fifty pounds of wool are firft dyed coffee colour, which is called the ground wool, that is, that which prevails in the fiuffs ; after which are taken five pounds of wool dyed in madder- red or kcrmes, and two pounds dyed in king's blue; thefe laft are called the wool of mixture. This wool is diftributed to different perfons placed in a ring in a large room. The fador, or he that has the care of the mixture, H ftands 1^0 THE dyer's AS5ISTANT. -ftands with a flick in his hand in the centre of this circle, the iricn being at fix tee t diftance from himj eight or ten are generaily employed at this work, snd all tl^.e wool is piven to them. In the prefent cafe, for example, fix will be eoiployed in bearing the prevailirg wool or coffee colour, oie the blue, snd another the red ; but they muft be fo fituated that there may be three toge:her who have the ccfTee co.oured wool, then he that has the red, then three with the coffee colour, and iaflJy lie that has the blue. When there is a greater nuirber of colours, they are thus equally diftributed, cbferving to di^dc them, as much a^ poflible, the one from the other. The nen thus difpofed walk flowly round the faclor, keepit ii an equal diftance, and each flep they tske they caft at tlie feet of tlie faflor a fmall lock of the wool they carry, with this difference, that thofe tiiat h^ve the red or the blue, having but a firall quantity to diftribute, fling but little each time, whereas the others muft fling much more. The faiior (tirs the wool with his flick whilfl the n:en a'-e flinging it, and tiut the mixture f^iould be perfedi, they muft all have diilributed their wool at one and the fame time. The fatSlor then mixes it again, and gives it to the carders. The carding makes a perfe«5l mixture, (o »hat r.o particular colour is to. be diftinguilhed, ar.d it appears of one uniform colour; it is afterwards fpun, the cloth manufactured, and brought to the mill. The i'r.portance of this mixture being exactly made is ealily conceived, for if thefe colours were unequally ciflriLuted, the cloth would appear full of blots. As in the compofiiion of thefe mixtures it is not pcffible to judge exactly of the effetl which niay be produced by the combination of all thefe colours THE dyer's assistant. lyr colours In different proportions, I fliall give a method of making a proof in fniali, that a colour formed after this manner by a known proportional mixture, it may be executed in great, and be cer- tain that the colour of the fluff will be equal to that of the pattern. CHAP, xxviir. OF THE METHOD OF PREPARING THE PATTERN FELTS, OR MIXTURE FOR AN ESSAY. THIS little work is very fimple and very ufe- ful, as it will fiiovvT in an hour what a mixt cloth will be after it is m2nufa6tured, and even when it is entirely drcfled. For this purpofe, wool of different colours are taken, and after having weighed each exactly, the mixture is made with the fingers in the proportion which is judged fuf- licient, but the whole in a very fmali quantity; fo that the mixture being made, it mny not exceed the hignefs of the fill. This wool is then moifien- ed with a little oil, and carded feveral titr.es with ft^nail cards, till all thefe colours are well incorpo- rated together and perfcdly well mixt. This wool, which is extremely open and of the fquare form of the card, is folded four times, and gently prefied be- tween the hands. It is then plunged into a flrong foap water, and putting it again between the hands, it is ftrongly preffed at different times, ftriking fornetimes one hand on the other. It is then gently rubbed betwixt the two hands, which hardens the wool by contrading it 2II manner of ways, and making it occupy lefs fpace. It is then dipped again in the foap water, a!;d continued to be felted, until it hiS acquired fQtne confidence, and that it becom.es H 2 like I'Z THE dyer's ASSISTAN'T. like felt, and pretty near the fame confiftence as the corrtmon cloth. This felt is then a true copy of what tlie cloth will be after its manufacturing ; for vhen it h:s been well felted, that is, that the wool has been equall)' and caremijy extended un- der the hand con.ii g from the card, it is as equal and as fmcoih as the cloth itfelf czn be. To finifh it alfo as perfectly as the cloth, after it has been wafhed to take oft the foap, it is dried and put between two papers, and preft with an iron fome- what hot: by this means it acquires a luftre which n-;akes it appear like a cloih which has been entirely creiTed. If the colour of the felt is approved of, the mix- ture in great is made for the cicih, by following the fame proportions exactly, and it will cer- tainly be like the pattern, for not only the wool of different colours are as entirely miixt and clofed one to the other in the felt as in the cloth, but the foap which has been made ufe of to felt it, has pro- duced th^ fame cffcci as that which happens to the cloth in the fulling-mill, for there are feveral colours, and particularly thofe that have been browned, that 15, in whofe compoHtions there are fliades of black and grey, which Icfe in the mill part of their brown- ing, fo'that it muft always be d)ed of a deeper colour than intended to be after finiftiing : this de- fect of foiidity in the browning does not hinder it from ftanding very well the acVion of the air, but it is eafily fpotted by acid liquors, as has been be- fore {aid. The colours that have been faddened in the woad or indigo vat are not liable to this, they fcarce !ofe any thing in the mill. The felt produces the f:ime effect, and it Is certain that the fluff will not !• fe more in great at the mill than the felt did with foap; confequently this preliminary operation oi the felt may be looked upon as a furc guide THE DYER*S ASSISTANT. 1 73 guide for the choice and aflbrtment of wool In mixt cloths. Thefe patterns are made ftill better with black foap, but it gives them a difagreeable fmeil, which is not eafily taken off by repeated wafliings. The felts, when made, may be dyed for fluffs, in which it is required that one colour fhould cover the other, for then, after the ftuff fliould have been mixt with the fame colours as the feit, it might be dipt in the fame dye through which that had beea paffed, and by this means it would be of the fame colour as the felt ; but this is not to be done to the ftufF till it comes from the mill, has been Ihecred, and nothing remains but to drefs it. This method will be of great ufe when it is a mixt cloth in whicii cochineal has been ufed, for it faddens too much and fpoiis at the mill ; fo that when it is ufed in mixt rtufls, a frelh liq^uor muft be made, in which the cloth muft be dipt, when it requires no more drefling than that which is given to cloth dyed white after it is come out of the dye. CHAP. XXIX. POLISH RED. BEFORE I enter upon the colours of the leffcr dye, I fhall give the procefs of a very excel- lent colour, called Pollfh red. If you would dye forty pounds of wool this bright and holding colour, boil ten pounds of nut galls, in a copper fufficiently large, an hour and a half i then cool the liquor with cold water about ten degrees under a boiling heat, becaufe the mad- der fliould not boil, and add beft madder in pro- portion to the fhade required, from fourteen to H 3 twenty i;4 THE dyer's assistant. twenty pounds. V.'ork thefe ingredients with the wool for two hours with long poles, that it may dye in ali parts ahke. Rince it well, and you have the true polifti red. If you would have a dark colour, ufe a little aflies. Obferve to have the wool well fcoured. This procefs v/iil hold good In cloth and other things. THE THE DYER'S ASSISTANT, PART IL CHAP. I. OF THE DYING OF WOOL BY THE LESSEH DYE.- Obferved in the beginning of this Treatife, that the ciying of woo), or woo'lea ftuffs manu- fadured from it, wese c'lftinguifhed by the great and lefTer dye. The French regulations have fixed what the quahty of the wool and fluffs are to be, which are to be dyed by the great or lefTer dye. This diftinftion has been founded on this principle, that fluffs of a certain value, and which generally conflitute the upper part of clothing, fhould receive a more folid and lafting colour than fluffs of a low price, which would be dearer and become lefs faleable, were they obliged to be dyed by the good dye, as the good dye is a great deal more ex- penfivetban the leifer, and that ftuffs of low price, which are permitted to be dyed by the lefTer dyr, are generally ufed to make linings, fo that they are little expofed to the action of the air, and if th.ey are put to other ufes they are Toon worn out, on ac- H 4 count, 176 THE DVEK's assistant. count of the wesknefs of their texture ; and cofi- fequently t!\ere is no neceffi'v for their colours being fo ialting as th^t ct a iluff of 2 rr.uch longer duration. I have related in the prtceciing treaiife, v.ith the greateft exaclrefs and precifion in my power, the method of executing by the good dye all in-aginable colours ; I (hall do the fame in that which concerns the ;e;Ter dye, and fha.l lay down the ir.ethod of making the lame colours with other ingredients th.an I have hitherto fpcken of, and which, though tliey have not the foJidity of the iiril, often have the advantage of yielding mere lively colours j beSdes which, the greater part give a fnaocther colour, and are worked with greater facility than the irgredients of the good dye. Th.ei'e are the advantages cf thefe fubftances which are called falfe ingrec.ents, and thcugh it is to be vvifhed that their ufe was not fo general, it iruil be agreed that they have their utility for Auffs lei's txpcfed to the air, or whofe colour does not flard in. need of a long duration. I might alfo add, that the colcurs are naoft comrrcnly forted with greater eafe, and with more expedition, in the leiTr dye th'n can be dene in the great. I ih'-ll n^t follow the fan:e order fcr this kind of dve as I did for the good, ilnce in this no primary colours are known. Few ferve as a grourid fcr ethers : the greatefl part do not srife from a com- bination cf two or feverai fixple colours, in fhort, th.ere are colours, fuch as the b'ue^&c. which are feidom or never made i.i ihe lefler dye. This is the crc'er which I propcfeto follow, and ihali firll: fet forth the names cf ail the ingrecienrs which rar-iculariy belong to the ielTer dye, and then give the method of ufmg each of t'-.efe ingredients, and ihe extradicn of ail the co-ours they can yield. It THE dyer's assistant. I77 It win be found that feveral of thefe ingredients produce fimilar colours, (o that it would have beea impoflible to have treated of them feparately, with- out tiring the reader with tedious and troublefome repetitions. The ingredients are flock or goat's hair mad- dered, archil, logwood, brafil, fuftic, roncou, grains of Jvignon, turmeric, or terra merrita. t Ihall not here fpeak of the fanders or loot, though thefe ingredients particularly belong to the lefler dye ; I have already given the manner of ufing thefe laft. GHAP. IT. OF THE BYING OF FLOCK OR GOAT's HAIR. THERE are two preparations very different- one from the other in the dying of flock : the firft is with madder, and belongs to the great and good dye; the fecond is to diflblve it and make ufe of it ; this belongs to the leffer dye The dying with flock was formerly permitted in the good dye, but was rather on account of its being- extradled from madder, than by any experiment that had been made concerning its durability, I tried it with great attention, and found it beyond any doubt that there is no colour that reufts the air lefs. It is certainly fcr this reafon that it >vas reftrained to the lellerdye in the nev>^ regulation of France in 1737. Yer, as by the fame regulation, it is not permitted to the Dyers of the lelTer dye to ufe madder, nor even to keep it in their houfes ; it has been enaded, that only the Dyers of the great dye fliould be fuftered to madder flock, and thefe of the leffer dye to diffolve and ufe ir. H 5 This. Iy8 TK£ DYER S ASSISTANT. This maddering of fiock ought to have found z place in the foregoing Treatife, but that 1 chofe rather to clafs together all operations that have any necelTary connection, than to ftick too fcrupuloufly to that difTinction of the great and lefTer dye, which is the particular obje£l of the civil government of that art, and which upon fomeoccafions might have made me fall into fome obfcurities, or run into continual repetitions j befides, the government of dying is not the arc confidered iti itfelf. To madder the flock or goat's hair, four pounds cf either of them is cut and well feparated, that the dye may penetrate the better. It is boiled two hours in a fufficient quantity of four water ; then it is drained for an hour, and put into a middling copper, halt filled with water, with four pounds of roach alum, two pounds of red tartar, and one pound of madder. The v.hole is boiled for fix hours, putting in hot water as the liquor waftes ; it is left all night and next day in this liquor ; the third day it is taken out and drained in a ba&et. Some Dyers let it remain eight days, but it often happens that by this delay in a copper vefTel it is tarnilhed by the liquors corroding a part of the copper J a middling copper is then filled to the two- thirds with hah four water and half common water, and when the liquor is ready to boil, eight pounds of m.adder, v.-ell cut and crufhed between the hands, is added. When the madder is well iriixed in the liquor, four pounds of flock or hair is put in and boiled for fix hours ; it is then well wafhed, and the next day it is maddered a lecond time after the fame manner, only putting in tour pounds of madder infiead of eight, which were before ufed. After this fecond maddering, jt is 'veil wa(hed and dried i it is then almoil black j^rj fit for ufe. It THE dyer's assistant. 1 79 It appears by this operation, that four p:5undsof flock or hair is loaded wich thirteen pounds of the: dye of madder, yet there ftili remains fome Dye in the liquor, which is then called an old maddering, and which is preferved for ufe on certain occafions, as in tobacco, cinnamon colour, and feveral others. When the flock is thus maddered by the Dyer o^ the great dye he felis it to Dyers of the lefl^r, who have (hen the liberty to difTjlve and ufe it ; this is; liTe common method, which has many diffecultieSj and is known but to few Dyers. Madder is here- by made fine. 'About half an hour after fsven in the morning,., fix pails full of clear water are put into a middling, copper, and when the water is lukewarm, five pounds of pearl-afhes are put in :.. the whole is boiled tiil eleven, and the. liquor is then confider- ably diminifhed, (o as to be held in a lefTer copper, , into which it is emptied, obferving firft to let the dregs of the pearl- aflies fubfide, that none but the clear may be ufed. A pail fuM of t'lis liquor is afterv^ards put into the middling copper, having firrt fcoured it well,. and a little fire made under it; the four pounds of maddered flock are fcattered in by degrees, and- at the fame time a little of the lukewarm and faline liquor of the fmall copper is added to keep down the boiling, which rifes from time to lime to the top of the copper, in which the operation is : performing. Wlien all the flock and the liquor of the little - copper are put into the middling one, a p-ai! fail of v clear water is put on the dregs of the pearl-aihes remaining in tr.e little copper. This water ferves to fill the middling one as the liquor in it evapo- rates. All this flock melts, or is diiTjlved by the actijn of the pearl- a'hes, and after the firil half H.6. hour iBo THE DYEk's ASSISTANT. hour, not the leaft hair is to be perceived. The liquor is -then of a very deep red. The whole is then boiled without any addition, ti,l three in the arrerncon, thst tl:e whcle diffoluiion of the flocks may be the more exacily performed. Then a llick is plscetl upcn the copper, and upon this ftick is placeJ a pail of fermented urine, in which pail a I'mall hole has been previoufly made towards its lower part, and a little ftraw put into ir, that the Drine may very ilowly run into the copper ; whilft it is running, the liquor is made to boil flrongly, and this urine makes good what may be loft by evaporsticn. This operation continues five hours, during which time three paiis fuil of urine are dif- charged into the copper, being made to run fafter when the boil is (Wronger, than when moderate. It is here to be obferved, that, on account of the iinall quantity of fiock in the experiment which I lay down here, five pounds only of pearl- alhes are ordered ; for when thirty pounds of fiock are dif- Ibived at ore time, which is the common cuftonv of the French Dyers, they put twelve ounces of pear!-2(hes to each pound or flock. During the whole time of this operation, a ftrong volatile Imell of urine is emitted, and there fwims en the furface of the liquor a brown fcum, but much more fo after the addition of the urine. The liquor is known to be fufficient'y done when this xifes no more, and that the boil rifes but gently, that is what happened to the operation now related, at eight in the evening. The fire is then raked our, the copper covered, and thus left to the next day. Patterns had been taken at different times of the colours of the liquor from three to eight in the evening, by dipping in fmall pieces of paper : the firrt were very brown, and they became continually lighter, and united themfeives more and more, in proportion THE dyer's assistant. i8| proportion as the volatile part of the urine a£led on the colouring parts of the liquor. Nothing now remained but to dye the wool ia the liquor thus prepared, and which is called melt- ing of flock ; this is the eadeft work belonging to the Dyer. A quarter of an hour before the dying is begun, a little piece of very clean roach alum is' put in, and the copper is well raked to melt it. As this liquor which was in the middling copper had been covered the whole night, and the firi" had not been put out, the liquor was ftill fo hot as not to fuffer the hand. The cleareft was taken out and brought into a fmall copper, with a fufficient quantity of lukewarm water, fome wool dyed yellow with weld was dipped in it ; it immediately became of a fine orange, bordering on the flame colour, that is of the colour called nacarety and known to the Dyers by the name of nacaret of flock, becaufe it is commonly made with melted flock. Twenty hanks of white wool were dipped one after the other in the fame liquor, beginning by thofe that were to have the deepefl: ground, and leaving them longer or ftiorter in the liquor ac- cording to the fllade required. An affortment was made after this manner from the nacaret, or bright orange red, to the cherry colour. It ought to be obferved, that in proportion as the liquor was con- famed, frefli was taken from the middle-fized cop- per, great care being taken not to ftlr the fediment St the bottom ; a little fire was alfo kept under the fmall copper, to keep the liquor always in the fame degree of heat. The wool is thus dipped until the whole liquor is ufed, and all the colour drawn out. But the lighter colours could not be dyed in it ; for when the colour of the liquor is once weakened, as it ought to be for thefe colours, it is generally loaded with filth, which would take off the brightnefs required in thefe fhades. The 1^2 THE DYIR's assistant. The following is the method of msking fhades lighter tlisn the cherry colour. A cojjper is filled with clear water, and five or fsx hanks of wool d\ed of lije deepeft dye from the flock, that is, from the fiiade that immediately follows the nacarat, are put in. As foon as the water boils, it takes out all the colour, the wool had, and it is' in this frelh liquor that the other wool that is to be dyed is dipped, from tliC cherry colour to the paleft ficfh rolour, obferving always to begin by the deeped (hides. I^.Ioft of the Dyers who do not knov7 how to melt the fiock, or who will not give themfelves that trouble, buy fome pounds of this fcarlet of flock, which they ufe after this mjnner, to make all the liihter ih^des, which, as hiS been faid, is dene with much eafe. This operation (hows what little dependence can be put on the felicity of a colour that pafles fo qui:kly in boiling warer. And in fa<5>, it is one of the worft colours there is in dyi.ig, and on that account the new. regulation has taken it from the great dye, and permits it in the leiler for the re^fons above rsentioned- Thus a very bad colour n.ry be had from an insredient which, of all thofe tliat are ufed in dying, is perhaps the bei^ and the mcfl curable ; yet when this hair, dyed with ail the neceffary precautions to infure the colour as much as poiTible, ccmes to be ciSblved or melted in a liquor of pearl-sfhes, its colour, by acquiring a new luflre, lofes all i;s foii- dity, and can only be ranked in the number of the, faifell dyes. it may appear that the little foiidity of this cclour proceeded from the woo! !ia\ing no prepa- ration, and retaining no f-lt be/ore its being dipped in the diiTolved fleck ; but I found that this was iiQt the caufe : for 1 dipped in this liquor woo] boiied THE dyer's assistant. 1 83- boiled as ufual, and other woo! differently prepared, without finding that the colour of tiie latter had. acquired any more folidity; the luftre was iefs, that. is, it came cut more faddcned than the wool that had been dyed in.it without any preparation. Though i have faid that wcio! receives no prepa- ration before its being dyed in a difTolution of flock, it is ncverthelefs neceflary to fulphur thofe that are to make clear Ihades, for that gives them a great brightnefs and luflre, as the difTolved flock is applied on a ground a great deal whiter than it would be without the vapour of the fulphur, which cleanfes it of all its hhh. The fame thing is done for the light blues, and for fome other colours j but this operation is feldom made ufe of but for wool intended for famples or tapeftry. Sulphu7'big of Wcol. The Dyers do not do this, becaufe of the flink- of the fulphur, or rather to avoid the trouble. Ncverthelefs, to give an idea of it, the white wool is fufpended on hoops or perches in a clofe room, and under this wool chafHng-diflies are placed with lighted coals, on which powdered fulphur is caft. The room- door is afterwards fhur, that the fmoke may be the longer retained and acl on the wool, which is to remain till it is entirely whitened; it. ie then called fulpliured wool; and this is thie pre- paration it muft receive to give a brightnefs to the rofe, cherry, and fle(h colours, which are made from the difiblution of flocks. ^he Theory of the Dljfoiution of Flock. The reafon why from an ingredient, fuch ?,s the root of madder, perifhable colours are produced. from 184 THE over's assistant. from diflblved flock, Is not difficult to affign. In the firfk operation of maddering the flock, the red of the madder was fixed in the hair by the prepa- ration of alum and tartar as much as pofTible, but as it is overloaded with this colour, it is eafy to conceive that the fuperfluous colouring atoms being only applied on thofc which already filled the pores of this hair, thefe alone are really re- tained in the pores, and are cemented by the falts. The hair thus reddened by the madder fo as to be- come almoft black, would lofe a great deal of the intenfity of its colour, if it was boiled in any liquor, was it even common water ; but to this water, pearl-aflies are added in equal weight with the flock already dyed, which is to be melted in it; confequently there is a very ftrong lixivium of fixed alkaline falts made. I have already faid in another place, in the foregoing Treatife, that very flrong alkaline leys deftroy the natural texture of almoft all animal fubftancc-s, as alfo gums and reflns ;- in (hort, that an alkaline fait is their difTolvent. In the prefent operation, the lixivium of the pearl- aflies is very concentrated, and very acrid, and confequently in a flate to melt the hair, which is an animal fubftance, which it does very quickly, and with a ftrong fermentation, which fliows itfelf by the flrong and violent elevation of the liquor ; confequently it deftroys the natural texture of each cf thefe hairs, and the fides of the pores being at the fame time broken and reduced to very minute parts, thefe fides having neither confidence nor fpring to retain thefe falts, and the colouring particles that were llicking to them. Therefore the animal par- ticles of the hair, the colouring parts of the mad- der, the faline parts of tiie liquor, and the alkali cf the pearl-aflies, are all confounded together, and form a new mixture, which cannot afford a laf^ing THE dyer's assistant. 185 dye, becaufe from thefe faline parts mixed toge- ther there cannot be formed a fufficient quantity of falts capable of cryftalization, and producing moleculas, which can refift cold water and the rays of the fun. In (hort, it could not form a tartar of vitriol, becaufe the alkaline fait is in too great a proportion. To rouze the deep and overloaded dye of the madder firft applied on the flock, and after con- founded by the melting of this hair in the mixture already fpoken of, putrified urine is added in a con- fiderable quantity ; this is a further obftacle to cryftalization ; confequertly wool not prepared by other faits, and dippe j in a liquor thus compofed, can only be covered by a fuperficial colour, which finds no prepared pores, or any thing faline in thofe pores, which may ce'.nent the colouring atoms ; therefore fuch a dye muft quit its fubjedl: on the leaft effort of what nature ibever it be. But wool prepared by the liquor of tartar and alum, does not take a more lafting colour, in the liquor of the meki.'d flock, than wool nut prepared by thefe falts ; for a liquor which abounds with fixt alkaline falts attacks the tartar left of the pre- ceding preparation in the pores of the wool. This tartar changes its nature, and from being hard to diffolve, as It was Ipefore, it becomes a foluble tartar, that is, a fait that difiblves very eafily in the coldeft water. It may perhaps be objedled, that particles of alum remain in the pores of the prepared wool, that from thefe particles of alum, as well as from a portion of the fame fait which is put mto the liquor, reddened by the melting of the flock, the alkali of the pearl-afhes mulT: fornr\ a tartar of vitriol, which, according to my principles, ought to fecure the dye. Tq i86 THE dyer's assistant. To this T anfver, that the urine i)inders the co.Tibination of thefe two falts, which is r.eceffary for the foriT.aricn cf the tartar of vitriol ; if even this hindrance did not exill, the quantity of this fa!t, which I have named bard in another place, could not be fufficient to ccnient the colour m the pores of the wool, or put them in a itate to retain the colouring atoms. Further, tlie (bsrpnefs of the alkaline falts in this liquor, which is cspabJe of entirely diiTolving the hair boiled in it, would equally be able to diflblve the wool, were it boiled as the fiCrck wys. But yer, though a degree of I.eat is not given to the liquor, which would be neceflary for this total deftruction, it is eafily con- ceived, that if the fum of the deftroying aciicn is not the fame, at leiil a psit exifts, which is iliH fufficient to corrode the fides of the pores of the wool, to enhrge thetn greatly, and to render them unfit to reuii-. the cclsuring atoms; to this may be added, that the hair is melted in the liquor, and confequently mixt with the colouring parts of ths madder in a great quantity j that ihefe are hetero-^ geneous parts, which prevent the immediate con- ta(Sl of the fame colouring parts, and that from all thefe obftacles taken together, the colour muft be rendered lefs durable and lefs holding than any of the lelTcr dye. This, experience fufficiently proves, for if a f^ain of red wool dyed in this manner, be put into boiling water, the colour will be taken cS. entirely. CHAP. THE dyer's assistant. 187 CHAP. III. OF THE MANNER OF USING ARCHIL. ARCHIL is a foft parte, of a deep red, which being fimply diluted in hot water affords a number of different fhades ; there are two kinds, the moft common which is not fo fine or fo good, is generally made in Auvergne, of a lichen or fort of mofs, very common on the rocks of that province: it is known under the name of Archil of Auvergne, or Land Archil. The other is a great deal finer and better ; it is called the Archi! of Herb, or of the Canaries, cr Cape Verd Archil ; it is prepared in France, England, Holland, and other places. The workmen who prepare this herb Archil, make a fecret of the preparation, but the particu- jars may be found well related in a Treatife of M. Pierre Antoine Mkhsli^ which bears for title, Al^ya Plantarum Genera^ therefore I fliall upt hejre\ givtj the method of preparing it. When a Dyer wants to afTure himfelf that the Archil will produce a beautiful effetSt, he mufl extend a piece of this pafte on the back of his hand ryid let it dry, afterwards wafhing his hand with cold water. \i this fpot remains with only a little; of its colour difcharged, he may judge the Archil to be good, and be afTured it will fucceed. I ftiall now give the method of ufmg the pre- pared archil, but I fliall only, treat of that of thei Canaries, and juft mention the difference between, it and that of Auvergne. A copper is filled with clear water, and when it bepns to be luke-warm, the proper quantity of archil is put in and v;ell ftirred: the liquor is afterwards heated almoft to foiling, and the wool or ftuffs are dipt without any preparation i88 THE dyer's assistant. preparation, only keeping thore longer in that are to be deeper. When the archil yields no more colour at this degree of iieat, the l:quor is made to boil to extract the remainder; but it it is archil of Auvergne, the colours drawn after this manner will be fadder than the firft, on account of the boiling of the liquor. The Canary archil, on the contrary, will lofe nothing of its brightnefs, if even the liquor boiled from the beginning. This lafV, though dearer, yields much mere dye, fo thst tr.ere is mere profit in making ufe of it, befides its fuperiority over the other in beauty and eoodr.efs cf colour. The natural colour which is drawn both from the one and the other archil, is a fine gris-deJin, border- ing on the violet. The violet, the panfy, the amaranth, and fevera! like colours are obtained from it, by giving the ft'jft' a grounJ of blue more or lefs deep before it is palled through the archil. It muft here be cbfcrved, that to have the clear fhades of* thefe colours as bright as they ought to be, the wool ought to be fulphured, as was faid iti the foregoing chapter, either before it is dipped in the archil, for the gris~de-lin^ or before it is dyed blue for the violet and other like colours This way of uHng archil is the fimplef^, but the colours that proceed from it are not lafting. It may be imagined that the colours would be better by giving a preparation to the wool previous to its being dyed, as is practifed in the great dye, when madder, cochineal, weld, &cz. are ufed ; but ex- perience fhows the contrary, and I have ufed the archil on v/ool boiled in alum and tartar, which did not refill the air more than that vJhich had re- ceived no preparation. There is, notwithftandirg, a method of uling the Canary archil, and giving it almoft as much duration THE dyer's assistant. iSq duration as the moft part of the ingredients of the good dye ; but then its natural colour of gris-deJm is taken off, and it acquires a red or fcarlet, or rather a colour known under the name of baftard fcarlet. The colours of the kermes or Venetian fcarlet, and feveral other fhades that border on the red and the orange, may alfo be drawn from it, Tliefe colours are extradted from the archil by tlie means of acids, .and all thofe that are thus made may be looked upon as much more hfting than the others, though ftridly fpeaking, they are not of the good dye. There are two methods of extracting thefe red colours from the archil. The firft is by incor- porating fomc acid in the compofition itfelf that is made ufe of to reduce this plant to a pafte (fuch as is known to the Dyers under the name of archil). I have been afTured that it may be made violet and even blue, which probably is done by tlie mixture of fome alkalis, but 1 muft confefs I could not fucceed in it, although I made above twenty trials for that purpofe. I fhall now proceed to the fecond method of extradling from archil a beautiful and pretty lailing red, and which 1 executed four times with fuccefs. Bajlard Scarlet by Archil. Prepared archil from the Canaries is diluted as ufual in warm water, and a faiall quantity of the aommon compodtion for fcarlet is added, which is as has been ihown in the preceding treatife, a folu- tion of tin in aqua-regia^ weakened with water ; this acid clears the liquor immediately and gives ic a fcarlet colour. The wool or fluff is then to be dipped in this liquor, and left till it has received the (hade required. If the colour (hould not have brightnefs IQO THE dyer's ASSISTANT. brigbtnefs enough, a little tnore of the compcntion muft be put in, and pretty near the fame method riiuft be followed zs in ^be dying of common fcarlet : I tried to muke it in two liquors as the fcariet, that is, to boil the ftuff with the compo* fition, and a fmall quantity or archil, and alter- wards to fini'h it wish a greater quantity of both, and I fu7ceedcd equally; but the operation is longer after this manner, and I have fomeiimes made as fine a colour in one liquor. Thus the Dyer may take his choice of either of thefe methods. I cannot exadlly fix the quantity of ingredients in this operation. Firfl, As it depends on the fhade that is to be eiven to the ilaiJ. Second, As it is a new procefs in dying, I have not had fufficient experiirents to know with exacVncfs the quantity of archil and compofition which ought to be ufed : the fuccefs z'Co depends on the greater or lefi'er acidity of the compcfition. In fliort, this method of dying with archil is fo eafy, that by making tv^o or three trials in fmall, more know- ledge will be acquired from it th.an I could teach in a large volume: I muft only add, that tlie more the colour drawn from this ingredient approaches the fcarlet, the more Isfting it is. I have made a great number of (liades from the farr.e archil, and which confequently oniy differed by the greater or ]efs quantity of tiiC compc fition, and I always fouiid that the more tl;e arcliil went from the natural colour, the more lading it became, fo thst when 1 brought it to the fliade known by the name of bsflard fcarlet, it withliood the action of the air and elTay proof almoft ss well as that which is commoi^ly made vith cochineal or madder. U too much compofition be put in the liquor, the wool will become of an orange colour, and difatrei;abie. THE DYER S ASSISTANT. I9I x!ifagreeable. The fame thing alfo happens with cochineal, io that this is not an inconvenience peculiar to this dye; befides it is eafily avoided by proceeding gradually in the addition of the compo- fition, ar.d by putting a fmall quantity at firft. I have tried the different acids in this fcarlet con:ipcrition, but none fucceedcd well ; vinegar did not give a fufficient rednefs to the liquor, and the fluff dyed in it only took a colour of lees of wine, which even was not more lafting in the air than tliat of the archil in its natural flate, and other acids faddened the colour. In (hort, it appears that (as in fcarlet with cochineal) a metallic bafe extremely white muft be united to the red of the archil, 2nd this bafis is the ca'x of tin. I have re- peated the fame operation with the archil of Auvergne, but the colours were not near fo fine or fo good. CHAP. IV. OF LOGWOOD OR CAMPEACHY. TiIEcampeachy wood, known under the name of logwood, is of grest ufe in the lefTer dye, and it were to be v.ilheJ that it was not ufsvi in tl^.e good dye, for the colour which that wood produces lofes its brightnefs in a fhort time, and even dif- appears in fome places oi^ being; expofcd to the air ; the low price of this drug in fome meafure tolerates its ufe ; but the principal reafon of uiing it is, that by the means of different preparations and falts it affords a gr^at number of colours and ihades, which ate not eafily made by the ingredients of the good dye alone. Yet it is pollible, as I have faid before, to make all thefe colours without the help of 192 THH dyer's assistant. of logwood ; therefore it was proper to forbid the ufe of this ingredient in the good dye. Logwood js neccfiary to foften and velvet the blacks ; it is this velvet hue that gives that excel- lency to the Sedan blacks. I fhall now add fome little matter concerning the other colours in which this wood is ufed, and I Ihall obferve, that when any wood v.hatfoever is ufed in dying, it muft be cut into fmall fliavings or chips, and put into a bag, that it may not ftick to the wool or fluffs j for the rough chips will not only tear the gocds, but blot them in thofe places to which they ftick. Logwood is ufed with galls and copperas for all the ftiades of grey which border en the flate or lavender, the pigeon grey, the lead grey, and fuch like. To make thefe, a copper is filled with clear water, and a proper quantity of galls is added ; this mull be proporiioned to the quantity of fluffs to be dyed, and to the depth of tlie ihade required. A bag of logwood is put into this liquor, 2nd when the whole has boi'ed and cooled, the fluff is dipped in it, adding by little and little fome copperas )ire- vioufly difToived in water. I cannot fix any exact proportion of ingredients, as the Dyers of the leffer dye are not accuftomed to weigh theai , they work by the eye, and their bufinefs being to match low-priced iluffs for linings of cloths for which they have the patterns, they firfl make them lighter than is wanted, and fadden them by adding copperas till they are come to the fhade required. If thty find there is not loowood fufficient, they add more ; they do the fame when they have feveral fluffs to pafs through tlie fame liquor, when they find the wood they have given has yielded all its dye. This work is not difficult, and only requires practice to judge pretty nearly the quantity of ingredients to be ufed, and to judge by the fluff, while svet, whether, when THE dyer's assistant. I93 when dry, it would have the intended colour, which is done by ftrongly wringing the end, and blowing on it ftrongly : by this means, the greateft part of the humidity, which has by twirting been brought to the furface of the ftuff, is driven off; then for an inftant the colour is feen pretty nearly fuch as it will be when dry ; but this muft be done by a quick eye, for in a moment after the adjacent moifture is communicated to this dry place, and then you mky, be deceived. A pretty fine violet is alfo made "with logwood, by firft boiling the wool as ufual with alum and tartar, and afterwards, pafllng it through a liquor of logwood in which a little alum is diflblved. But it is made much finer by bluing and alwming the fluff firft, then dipping it in a liquor of Brazil mixt with a little logwood j this violet, though of the ieffer dye, is much better than the former, be- caufe the blue ground always fuftains the colour, and makes it more holding. The logwood alfo affords a blue colour, but it lafts fo ill that this wood is feldom u fed for dying blue. Yet if from curiofity you wifti to make a trial, you need only prepare a liquor with log- wood, and mix a little Cyprus or blue vitriol in it, and dip the fluffs in this without any other prepa- ration, and you have a fine blue. By the fame means, green may be made in the fame liquor. For this purpofe, logwood, French berries or grains of Avignon and verdigrife are put into a copper ; this mixture gives the liquor a beautiful green colour ; the wool may be then dipt to the height defired, and may be of any defired fhade, by putting in more or lefs of the logwood and Avignon grains. But this colour is not better than the blue, and both ought to be excluded .^ art of dying : I have given the procefs, merelner in. 1 of, and ia 194- THE DYER S ASSISTANT. I might omit nothing which came to my knoA'- iedpe concerning the art. The u/e to which logwood is mcft commonly applied in the ieflcr dye is lor plumb, prune colours, purpies and their (hades. This wood joined with gails, readily gives all its colours to wool that has a ground of blue ; it is faddened with a little green copperas, which browns them, and by this means fome Ihades may be eafily obtained which are much more difficult to hit in the great dye, as the different degrees of faridening are much more diiEcuit to match in a blue vat, than by the help of the iron of the copperas. But thei'e colours fade away very foon in the air, and in a few days a great difference is feen between the pans that were expofed to the air and thofe that vrere covered. Having experienced, as I faid in the preceding chapter, that the fcar.et compofition changed the coicur of the archil, and made it more lafting, I tried what eife<5i it might produce on the logwood; but what appeared (insular to me was, that what- foever quantity of compofition I put into this liquor, it rever loft its violet colour. Being deiircus to put this to a further trial, 1 dyed a piece of cloth with logwood, and put into the liquor a quantity of compofition, pretty near equal to that which I would have put for an equal dofe of archil : the clot . took a pretty good violet colour. This cloth was put in the weainer for twelve fuinmer days, and the colour proved no better than if no compofiion had been ufed. By adding a fmall quantity of cr)ftals of tartar to another liquor comp fed as the rormer, I had a mere lafting co- jour, but confiuerably different. ana Jhi THE dyer's assistant. . i.g$ The Raven Grey. The raven grey on worfted or fluffs Is perfornned in the foliowing manner. In a copper fufficiently large for fixty pound weight, diffolve eight ounces of alum, and work the worfted on fticks very quick for the fpace of half an hour at a boiling heat ; then take it up, and add to the fame liquor three or four pounds of cop- peras, and work it at a boiling heat for half an hour longer ; while this is performing, the worfted muft be wafhed, and one pail full of logwood chips muft be boiled in another copper about twenty minutes ; the worfted muft then be turned very quick in the logwood decodion about half an hour, when it muft be taken out, and returned about ten or fifteen minutes in the deco£lion of alum and copperas, as at firft. This laft operation is abfo- lutely neceftary, as it contributes much to the beauty and luftre of the colour, by difcharging the gTofs particles of the logwood, and leaves a beauti- ful raven grey. This procefs will hold good for thin goods and coarfc cloth, but a lefs proportion •of logwood will do. CHAP. V. OF SAXON BLUE AND GR£EM. I Place here among the lefler dyes that called Saxon blue and green, which has been for fome time greatly in fafhion, being finer and brighter than any blue or green hitherto kn'^- the greater or lelTer dye, b"^ — wn either In -J -« bears no proof, and in J96 THE dyer's assistant. in twelve days expofition to the fun, it lofes a great part of its colour. Blue on C/othj Stuj^y or yarn. Put into a glazed earthen-pot four pounds of good oil of vitriol, with twelve ounces of choice indigo, very finely ground and fitted j ftir this chy- mical mixture very haftily and frequently in order to excite a fermentation, and break the lumps with a ftick vvhofe bark has been ftript off". It is cuflomary with fome Dyers to put into this com- pcfiticn a little antimony or faltpetre, tartar, chalk, alum, or other things j but I find it fufficient to mix the oil and indigo alone, and the colours will be finer, for thofe neutral falts deflrcy the acid of the vitriol and fully the colcur. In twenty- four hours it is fit for ufe ; then a copper of a good fize is to be filled with fair water, (into which one peck of bran is put in a bag) and made pretty warm ; the bran, after yielding its flour, muft be taken our, and the chymic mixed well with water, in a piggin, is put in according to the (bade required, having- firfl put in a handful of powdered tartar j the cloth, &c. is to be well wet, ^nd worked very quick over the wynch for half an hour. The liquor mu(\ be not be made hotter than that for madc'cr red. Obferve, the hot acid ot the vitriol would caufe the blue to incline to green if too much heat was given. The cloth, fiufF, or yarn muft be turned in this liquor very quick for half an hour, and having been previcully very well fccured, the colour will be brilliant and fir.e ; it is belt after walhing to dry this colour in the (hade. Chymic TH^ Desk's assistant. '97 Chymicfor Grteiti Eight ounces of m(jigo is fufficient for four pounds of oil for green, becaufe this mixture works green (and would even dye a pea- green if ufcd very hot) and therefore would not do for blue. The indigo is better fufpended ia this mixture thaa in the former, and is fuppofed to go further in green. The goods, being well fcoured are to be aluined ; for every twenty pound weight, two pounds of alum is to be put into a copper with fair water, and the goods boiled gently an hour and a half; whilft this is performing, another cop- per is got ready, in which fuHic chips are put to Isoil ; if there are any to dye pea-green it is befl: to ^hich have a caft of the red, a great deal rrcre i? uf d. Sometimes cn!y, a fmal! quantity or gs )s js fut with the Brazil, and it is faddened with corp ras ; oftrn a)fo with logwood, archil, or fcoif oilier mgredient, it is added according to the ih?de, frcm whence it is rot pcC:^!e to give any fixt ;u!e t r this kmd cf wo'k, en accrunt of the inSi.ite var^ty ct (hades which are obtained frotn thefe different mixrures. Tne aturi^i col ur of the Brazil, and for which it is m ft ufed, is the fiile fear et, which appears f.r.e ^rd brivhi, but ;sr interior to the bnghtnefsof the ccc> inea! cr gum lacque. To extra*^ the colour from this wood, the harceft water, fuch as wij! n-'t diflbKe fcap, muft be raade ufe of tor river water has not nearly fo gcoii an effccij it cvR. be cut into chips and boUed THE dyer's assistant. I99 boiled for three hours; th? water is then taken out and put into a large veflel, and frefh well-water put on the wo 'd and boiled again for three hours; this water is added to the firft ' ■ This liquor, which is called juice of Brazil, muft be old and fermented, and rope like an oily wine before it is fit for ufe. To extrafl a bright red from it, the fluff mud be filled with the falts of the common liquor of preparation, but the alum muft predommate, for the tartar alone, and alfo four water, greatly fpoils the beauty of this colour: in (hort, acids are hurtful to it, and difTolve its red colouring part. Four ounces of alum for each pound of ftufF is to be added to the liquor,^ and only two ounces of tartar^ or even lefs. The wool is to be boiled in it for three hours ; it is then taken out and gently wrung, and thus kept moift for eight days at leaft, that by the falts being retained it may be fufficiently prepared to receive the dye. To dye with this, one or two pails full of the old juice of Brazil is put into a convenient copper, and well fcummed. Dip the ftufF which has remained eight or ten days moiftened in the preparing liquor, and it mufl be well worked in it without making the liquor boil too ftrongly, until it be fmoothly and equally dyed. Care muft be taken to wring a corner of this fluff now and then, as I have already faid, to judge of its colour, for, whilft wet, it appears at leaft three fhades deeper than when dry. By this method, which is fome- what tedious, very bright reds are made, perfeftly imitating certain colours the Englifh fell under the name of Campeachy fcarlets, which, by the proof of dyes, are not found to be better than this, only that they feem to have been lightly maddered. This red, of which I have given the procefs, and which is no where elfe defcribed, withftands 1 4 the 20« THE dyer's ASSISTANT. the weather three or four months in the vBJnter, "^'ithcut lofing an^ of its ihade; en the contrary, it faddsns, and tfecns to acquire a ground, but it does not ftand the proof of tartar. Some Dyer$ of the grear oye ufe Brazil to heighten the red of madder, either to fave this root, or make its red more bright than ufual. This is done by dipping in a Brazil liquor a fluff, begun with the madder, but this kind of fraudulent dye is exprefsly forbid by the French regulations, as well as any mixture of the great dye with the \^:U hecaufe it can only ferve to cheat, and to pafs for a fine madder red, a colour whi.h in a few days ioles all its brightnefs along with the (hstie, which has been drawn from the Brazil, prepared in the common manner. The lirft colour extracted from this wood is not cf agGod dye, probably becaufe it is an indigefted fap, and whofe colouring partjcles have not been fufiiciemly attenuated to be retiined and fuiEcienfly fixt in the pores of the wool dyed in it. Whea thefe firft grcfs parts of the colour have been car» ried ofF, thofe that remain in fmall quantity are :l|ner, and mixing themfelves to the yeJiow partSi which are furniftied by the pure woody parts, the red refulting from it is more iafting. By the means of acids, of" wh^t kind {oev(^, all the red colour of this w.-od is carried olf or dii- appears ; then the ftuft that is dyed by it takes a hind colour, rnore or Jeis deep in proportion to the time it is kept in the liquor, and this colour is of a vtrygood dye. . . it is faid that the Dyers of Ambolfe have a raethod of binding the Brazil colour in this man* r.cr j after their ftufTs lightly maudtrei.have been pafied through a liquor of. weld, and conlequently boiied twice in ajum and tartar, they put arienic and THE dyer's assistant, 201 and pearl-afhes in the juice of Brazil, and it is aflerted that this colour then refifts the proofs ; I tried this procefs, but it did not fucceed. When a very bright red is required from the Brazil, I know by experience that it is polTible to infure the colour drawn from it after fuch a man- ner that, having expofed it thirty days to the rays of the futntner's fun, it will not cliange ; but thsrfe kind of colours are coffee and chefnut purples, i To make thefe, I keep the fluff moiflened in its liquor in a cellar for fifteen days ; this liquor is prepared as for the reds, of wJuch 1 have heretofore fpoken J I fill a copper to two-thirds with well ■water, and the remaining third up with Brazil juice, to which I add about one ounce of Aleppo galls in very fine powder to every pound of fluff, and tlien boil it one or two hours, as I want the fhade to be in deepnefs ; the ftuff is aired from, time to time, and when it has taken the colour defired, it is well cooled before it is walhed. This fluff being brufhed, the nap layed, and cold-prelTed, comes out very fine and very fmooth. CHAP. VIL . OF FUSTIC^ . THE fuftic gives an orange colour that is not ■ lafling; it is. commonly ufed in the lefTer dye, like the roots or huiTss or walnuts, v/ithoiu boiling the ftuff, fo that it is cifily managed. It is often mixed with waiiiut hu(ks.and weld, to make ; to'^acco and ciniia nan colours, and other • like : fhades. But this wood is a very bad ingrediear, . for its. colour being expofed to the air fora very I 5 _, fhort £ 202 THE DYER S ASSISTANT. fhcrt tirre lofes all its biightnefs and the greateft part of its yellow fhade. If a fluff dyed with fuftic is dipt in the woad vat, a difagreeable olive enfues, which does not refift the air, but fcon lofes its colour. I have already faid that fuftic was made ufe of in Langueiioc for making of lobfter colours for foreign markets, as it greatly faves cochineal. For this purpofe they mix weld, fuftic, and cochineal, vith a little cream of tartar, in the fame liquor, and the ftuff boiled in this liquor comes out of a lobfter co'our, and accordingly, to the quantity of thefe different ingredients, it becomes more or lefs red, tending to tre orange. Alti-iough the method of mixing together ingredients of the good with thcfe of the Kffer dye ought to be condemned, yet in this cafe, and for this colour only, which is in ccnfiderable demand in the Mediterranean, it ap- pears that the fuftic may be tolerated ; for having attempted to make the fame colour, with only the ingredients of the good dye, I did not get a mosc lafting colour* The change which the air produces in the lobfter colour made wih fuftic is very fenfiVile, but it is not fo difagreeable as the changes incident to feversl other colours j for all the fhade goes off and weakens at once, fo that it is rather a diminution- than a change of colour; whereas the lobfter colour made with the yellow wood becomes of a 'ZhsTTj colour. CHAP. THE dyer's assistant. 2.03 CHAP. VIII. OF. ROUCOU. THE roucou or racourt is a kind of dry paffe brought from America ; this ingredient gives an orange colour pretty near the fame as the fuftic, and the dye is not more lading. However it is not by the proof alum that the quality of the roucou is to be judged, for this does not in the leaft alrer its colour ; on the contrary, it becomes finer and brighter, but the air carries it off, and effaces it in a fhort time ; foap has the fame effef^> and if is by this it muft be tried according to the inftrudtions on thefe kind of proofs The place of this ingredient is eafily fupplied in the good dye by weld and madder mixt together, but roucou is made ufe of in the JeiTer dye after the following, manner. Pearl -afhes are diffolved in a copper with a fuf- ficient quantity of water ; it is well boiled for one hour, that the aflies maybe totally diffolved ; then as many pounds of rou ou as there are of afhes, are added ; tiie liquor is well raked and fuffered to boil tor a quarter of an hour; the wool or ftuffs that are to be dyed are then dipt without any pre- paration^ except dipping thegn in luke-warm water, that the colour may fpread itfelf equally. They are left in this liquor, working, them con- tinually, until they are; come to the defu^ed fhadCi, after which they sre.waflied and dried.. The roucou is often mixt with other ingredients of the leffer dye, but I cannot give any inftruc- tions on thefe mixtures, as they depend on the fhades you wifh to make, and are in themfelves attended with no difficulty, 16 IJuy* . 204 THE dyer's ASSISTANT. I bsve boiled the (luff in alum and tartar before I dyed It with roucou, but though the colour was more lafting it was not fufficientlyfo to be deemed of the good dye. On the who'e, the rcucou is a very bad ingredient for dying of wool, and is not made much ufe of, for it is dear, and other ingre- dients, that are cheaper and hold better, are ufed in its ftead. Wool dyed with roucou, and afterwards dipt in the indigo or woad vat, takes a reddifh olive^ which in a very (hort time becomes almoft blue in the air, the colour given by the roucou difap- pearing. CHAP. IX. OF THE GRAINS OF AVIGNON, THE grains of Avignon are but little ufed in dying, they give a pretty good yellow, but net iafting, no mere than the green, produced by dipping in the fame liquor a fluff.that has a ground of blue. To work it, the fluff muft be boiled in alum and tartar as for weld. Then a frcfh liquor is made with thefe grains, and the fluff is dipt^ and mufl lie in it longer or fhorter, according to the fhade that is wanted. There is no difnculty in working of it, fo I need only obferve that it ought never to be ufed but when all other ingre- emfelves perfectly, and the falfe ones were carried cff more or lefs according to their bad quality ; and as a colour is only to be accounted good inafmuch as ii refirts the adlion of the air and fun, this proof (erved 33 a rule to decide the goodnefs of different colours. After this, feveral proofs were made on the fame wool whofe patterns had been expcfed to tl.e air and fun, and it was in-. mediately found that the fame trials could not be indifferently ufed i'l prov- ing of all colours ; for it often happened that one colour, known to be good by expofi!ion to the air, was confiderab'y changed by the effay proof, and that a falfe colour ftood the fame prcct. Thefc experiments exploded leiVion juice, vine- gar, four waters, and ftrong waters, as it was im- poflible to afcertain the degree of acidity of thefe liquors ; and it appeared that the fureft method is to ufe ingredients with common watefj whofe ef- fects are always equal. In following th:s plan, it has been judged necef- lary to divide into three claffes ail the colours in which wool is dyed, either m the great or JeiTer , dye, and to fix the ingredients that are to be made ufe of in the effay proo's of the c>. lours, compre- hended in each of t{:efe three claffes. T he colours comprehended in the firft clafs ar« to undergo the proot of Romati alum, thofe of the fecond w.iih while foap, and thofe of the third with led tartar^ But THjB dyer's Assistant. 20:9 But It is not fufficient to be afTured of the good- nefs of a colour by ufingin the proof, ingredients vwhofe efFed^ may always be equal ; it is alfo necef- fary, that not only the duration of this trial be exacStly determined, but even the quantity of water fixed ; for the proportion of water confiderably augments or dimimlhes the adivity of the ingre- dietits which are put into it. The method of pro- ceeding m thefe different proofs fliall be fet forth in the foHowing articles : Article I. The proof of Roman Alummufihe made as follows: Qnt? pound of wator and half an ounce of alum are to be put in an earths rnveffel or pan. Tliie veflel is to be placed on the fire, and when the water boils ftrongly, tlxe wool is put in and left to l>9il for iiye minuies, after which it is to be taken out and waflaed in cold water j the weight of tlije pattern of wool muft be a drachm cr thereabouts, II. When feveral patterns are to undergo the proof together, the quantity of water and aluai is to be doubled, or even trippled, which will no ways change the ftrength or effedt of the proof, if you ohferve the fame proportion of water and aluin, fo that for each pound of water there may be one ounce of alum. III. To render the effecSl of the proof more certain, care muft be taken not to try together wool of dif- ferent colours. 2IO THE DYERS ASSISTANT. IV. The Proof with White Soap is to be made after the following Manner. ' To one pound of water add two drachms of white fcap, and place the vefiel on the fire; ftir. it with a ftick that the fo^p may be thoroutihly rtif- folved , when it is fo, and the water boils ftrongly, the woollen pattern is put in, which is to boil for five minutes. V. When feveral patterns are to undergo this proof, the fame method is to be obftrved as in the fecond article, that is, to put to each a pound of water two drachms of foap. VI. The proof with red tartar muft be exactly the fame, with the fame proportions as the proof with alum, taking care that the tartar rs finely powdered and well diffolved in the water before the pattern is put in. VII. The follov/ing colours are to be proved with Roman alum, viz. crimfon of all fhades, Vene- tian fcarlet, flame colour or common fcarlet, cherry- colour and other fhades of fcarlet, violets and ^;,r- de-lin of all (hades, purples, lobfter, pomegranate, flate greys, lavender creys, violet greys, vinous greys, and all other like fhades. VIII. If, contrary to the orders of the regulations on dying, any ingredients of the falfe dye have been made THE dyer's assistant. 211 made ufe of for fine wool dyed in crimfon, the cheat will be eafiiy found out by the proof of alum, for it changes the fine crimfon a little on the vio- let, tliat is, makes it border a little on the gris-de- lin, but it deftroys the higheft (hades of the baftard crimfon ; thus this proof is a fure method to dif- tinguifh falfe crimfon from fine. IX. Scarlet of kermes or grain, commonly called Venetian f arlet, is no wife prejudiced by this proof ; it raifes the fire-colour fcarlet to a purple, and gives a violet colour to the lighter (hades, fo that they border on the gris-de-lin^ but it carries off the greate(t part of the falfe Brazil fcarlet, and brings it to an onion- peel colour; it has yet a more fenfible effea on the lighter fhades of this falfe colour. The fame proof carries off almoft entirely the fcarlet of flock and its fliade. X. Though the violet is not a fimple colour, but formed of blue and red (hades, it is'tieverihelefs of fo much confequence as to merit a particular in- quiry. Tht fame proof with Roman alum has fcarcely any effedt on the fine violet, whereas it confider- ably alters the falfe ; but it mufi be obferved, that It does not always equally carry off a great part of the (hade of the falfe violet, becaufe this colour has fometimes a ground of woad or indigo: now this ground being of the good dye, is not carried off by the proof, but the rednefs goes off, and the brown (hades become ,ahnoi\ blue, and the pale ones of the colour of lees of wine. XI 112 THE dyer's assistant, XT. With regard to half fine violets, forbidden fcy the prefent regulations, they muft be ranked in the dafs of falfe violets, and do not ftand the proof. XII. The fine grls-di-lin may be known from the fialfe by the lame method, the difference is but trifling] the gris-de'lin of tnegood dye lofes a little lets tiian that ot the falfe. XIII. Fine purples entirely refift the proof with alum, whereas the falfe entirely lofe the greaieft part of their colour. XIV. Lobfter colours and pomegranate ftrike on the purple after the proof, if thev have been made with cochineal, whereas they will pale greatly if fuftic has been ufed j the ufe of which is prohi- bited. XV. Blues of tlie good dye will lofe nothing in the proo*^, whether of woad or indigo; but thofe of the lefler dye will lofe the greateft part of their colour. XVI. The flate greys, lavender greys, violet greys, and vinous greys, lofe ahnoft all their colour if they are of the falfe dye; whereas they psrfeClly maintain it, if of the good. XVII. THE oyer's assistant, 213 xvir. The proofs of the following colours are to be made with white fcap; yellow, jonquiH or lemon colour, orange, and all the fliades of yellow ; all green (hades from the yellow green or light green, to the cabbage or parrot green » the reds of madder, cinnamon, tobacco, and fuch like. XVIII. This proof perfe£lly (hows if the yellows and other (hades derived from it are of a good or falfe dye ; for it carries off the greateft part of their colour if they have been made with grains of Avignon, roucou, turmeric, fuftic, or faffron, whofe ufe is prohibited for fin« dyes, but it po ways impairs the yellows made with favory, Dyers' wood, yellow wood, weld, or fenugreek. XIX. The fame proof will alfo (how the goodnefs of -greens, as thofe of the falfe dye lofe mo(\ of their colour, or become blue if they have a ground of woad or indigo ; whereas thofe of the good dye lofe almoft nothing of their (hade, but remain green. XX. The reds of pure madder lofe nothing by the foap proof, on the contrary become (iner, but if Brazil wood has been ufed, they lofe their colour \n proportion to the quantity of it in the compo- fition of the dye. XXI. Cinnamon, (n\iff colours, and others of this caft, are fcarcely altered by this proof, if of the 3 good 214 "^"^ dyer's assistant. good dye, but they Icfe confiderably if roucou, fuf- tic, or diffolved flock has been made ufe of. XXII. The proof of alum would be of no ufe, and might even lead us into errors with regard to feve- ral colours belonging to this fecond clafs, for it no ways alters the fuftic nor the roncou, which never- thelefs do not withftand the adlion of the air ; on the other hand, it carries off a great part of the favory and of the Dyers' wood, which are very good jellows and greens. XXIII. All the brown or root colours Ihould undergo the proof with red tartar. The Dyers call by this name all colours that are not derived from the five primary colours; they are made with rinds and roots of walnut, alder-bark, fumach or roudoul, fantal and foot ; each of thefe ingredients gives a great variety of (hades, which are all comprehended under the general name of brown or root colour. XXIV. The above-namtd ingredients in the preceding article are good, except the fantal and foot, which are not quite fo good, and make the woi 1 ftifF when too great a quantity is ufed, fo that all this proof can (how on thefe kind of coiouis, is, whe- ther t'lo much fantal or foe)t has been put into them ; in this cafe they Icfe cot fiderably by the pr< o. with tartar; but if made with other ingre- dients, W' h only a moderate quantity ot fantal or foot, they Ibnd a Rreat deal better. XXV. THE dyer's assistant. 11^ XXV. Black IS the only colour which cannot be com- prehended in any of the three clafles above-men- tioned, and a much more active proof muft be made ufe of. To know if the wool has had a deep ground of blue, conformable to the regula- tions, the proof is to be maie in the following manner : take a pint or pound ot water, one ounce of tartar, and the fame quantity of Roman alum well powdered ; boil ir, and then put in the pattern; let it boil ftrongly for a quarter of an hour, and af- terwards wafh it in cold water; you will thea eafily know if it has had the proper blue ground, for if fo, the wool will remain of a dark blue almoft black i if not, it will turn very grey. XXVI. It is common to brown certain colours with galls and copperas ; this operation is called brown- ing, which is to be permitted in the good dye; but as this may caufe a particular efre6i in proving of thefe colours, it is to be obferved that although the proof liquor appears loaded with dye as the browninti is carried off, the wool muft be reputed of a good dye if it ftiil prelerves its ground ; if on the contrary it lofes it, it is then deemed to be of the falfe eye. XXVII. Al'hough the brownmp, which is made of galls and topper s, if ot the good dye, yet, as it hardens the wu I, «t IS brtter to make ufe of the indieo or woad vat in uicierence. XXVIJL 2l6 THE dyer's assistant. XXVIII. Common greys made with galls and copperas are not, to undergo any of thefe proofs, becaufe thefe colours are of the good dye, and are not otherways made ; but it is to be obferved, that they are firft lobepaffed through the liquor of galls, and afterwards through a fecond liquor, containing the copperas, which muft be much cooler than the firft, for by this ihethod they are made finer and more lafling. TH€ THE DYER'S ASSISTANT. PART III. ADDITIONAL ARTICLES. CHAP. I. OF FLOWERS. MONG the infinite variety of colours which glow in the flowers of plants, there are very few which have any durability, or wliofe fugitive beauty can be arreted by art, fo as to be applied to any valuable purpofes. The only permanent ones are the yellow. The red, the blue, and all the intermediate (hades of purples, crimfons, violets, &c. are extremely perilhable. Many of thefe flowers lofe their colour on being barely dried ; efpeciiliy if they are dried flowly, as has been ufuaily directed, in a Hiady and not warm place. The colours of all of them peri(h, on keeping, even in the clofeft vefleis. The more haflily they are dried, and the more perfectly thiiy are fecured from the air, the longer they retain their beauty. The colourmg matter, extracted and applied on certain bodies, is ftill more peri Chable : oftentimes it is changed or defiroyed in the hands of the operator. K Of 2l8 THE dyer's assistant. Of Blue Flowers. The colour of many blue flowers is exJ^cS^ed by infufion in water, but there are feme from which water gains only a reddifli or a purplifh hue. Of ihofe that hsve heai tried, there is not one wjiich gives any blue tincture to fpiritu us liquors : fome give no col 'ur at all, and fome a red( ilh one T he juice prefl out from the frelh fit wers is for the mft part blue. The blue juices and ir.fufions are changed red by al! acids ; the inarine acid feems to llrike the moft finid red Th.e flowers themfefves, macer- . ated in acid liquors, impart alfo a deep red tinifiurc. Alkalis, both hxt and volatile, and lime water, change them to a green. Thofe inl'ufions or juices, which have notlang of the native colour of the flower, TufTer the fame changes from the addition of acid and alkaline liquors j even when the flowers have been kfpt till their colour is loil, infufions made from them acquire flill a red colour from the cne, and a green from the other, though in a lefs degree than when the lowers were frefh. The red colour proouced by acids is Scarcely mere durable than the original blue, applied upon other bodies, and expofed to the air, it gradually def.enpraTes into a faint purplish, and at iengih f if- appears, leaving hardly ^^ny fiain behind. The green produced by alknlis changes to a yellc«%-, vhicn dots not fade fo foon. The green by lime water is more pernianent and mor« beautiful. Green lakes, prepared from thefe flowers by lime water, have been uled as pigiricnts by ihe painter. The flowers cf cyar.ub have DCs-n greatly re- comnienv;ed, as aflfv^rding elec!ant and durable blue pigments ; but i nave never been able tn extrift from ihem any blue colour at ai). They retain their colour indeed, when haftily drie^i, longer than fome THE dyer's assistant. llQ fome other blue flowers, but ihey cooimunicate nothing of it to any kind ot menftruu.n. Infu- fions ot them in watery, fpiritunus, and oily liquors, are all more or lefs of a reddilh cad, withrur any tendency to blue. Alum, which is laid to hei^^htea and prcferve their blue cclour, changfs it like th?.t of other blue fiuwers, to a purplifti red ; acids to a -deep red ; alkalis and lime water to a green. Solution of tin, added to the watery infufion^ turns it to a fine crinifon ; on (landing, a beautiful red fecula fubfides, but it lofes all its colour by the time it is dry. The wattry infufion, infpir.ffared to the confidence of an extrat^t made with redinei fpirit, is of a purplilh colour. The colour of both extra6ts, fpread ihin and expofed to the air, quickly fades. The flowers employed in thefe experiments were thofe ot the common blue bottle oi the corn-fields; cyanus fegetum C. B. centauria calycibus ferratis ; foliolis linearibus integerrimis ; irfimis dcntatis linn, fpcc. Red Flowers. Red flowers readily communicate their own red colour to watery menilrua j among thofe that have been tried the^' is not one exception. Thofe of a full red colour, give to redtified fpirit a'fo a .cep red tincture, brighter, though fomowhat paler thaa the watery infufion ; but the lighter red flowers, and thofe thst have a tendency to purplifh, imparc very little colour to fpirit, and feem to partake fi'ore of the nature of the blue flowers thm of the pure red. Infufions of red flowers are fuppofcd to be heightened by acids^ and turned green by alkalis, like thofe of tlie blue ; but this is far f'roa) being univtrfal. Among thofe I l!2ve exainined, ti)e rofe colours and purpiifh reds were all chaneed K 2 nearly 220 THE dyer's ASSISTANT. nearly in the fame manner as the blues, but the full deep reds were not. The deep infufion cf red poppies is turned by alkalis, not to a green but to a dufky purple. Yellow Flowers. The colours of yellow flowers, whether pale or deep, are in general durable. Many of them are as much fo perhaps as any of the native colours of vegetables. The colour is extrailed both by water and by fpirit ; the watery infufions are the deepeft. Neither acids nor alkalis alter the fpecies of colour, though both of them vary its fhades j acids render- ing it paler, and alkalis deeper : alum likewife confiderably heightens it, though not fo much as alkalis. Wool or fiik impregnated with a folution of alum and tartar, receives, on being boiled with the watery infufion, or decoftion, a durable yellow dye, more or lefs deep according as the liquor is more or lefs faturated with the colouring matter. An infufion of the flowers made in alkaline ley, precipitated by alum, gives a durable yellow lake. Some of thefe flowers, particularly thofe of the chryfanthemum, or corn- marigold, appear (from" the An Tin£icra Fundamental'! i. publifhed by Stahl) to be made ufe of by the Germaii Uyers. In fome of the deep redd fh yeliow, or orange- coloured flowers, the yell w mattei feems to be of the fan e kmd with that of the pure yellow flowers, but the red to be of a different kind trom the pure red ones : watery menftrua take up only the yellow and leave the red, which may afterwards be ex- tracted by recfitied fpirit of wine, or by water adluated v.ith fixed alkaline fait. Such particularly are the f^ffron- coloured flowers of carthamus. Thefe, after tiie yellow matter has becii extracted by water, are faid to give a red tincture to ley ; from THE dyer's assistant. 221 from which, on ftanding at reft for feme time, a deep bright red fecula fubfides, called, from one of the natnes of the plant which produces it, faf- flower, and from the countries whence it is com- monly brought to us, Spanifh red, and China lake ; this pigment impregnates fpirits of wine with a beautiful red tindure, but communicates no colour to water. I have endeavourrd to feparate by the fame treat- ment, the red matter of fome of the other reddifli yellow flowers, as thnfe of the garden marigold, but without fuccefs. Plain water extracted a yel- low colour, and alkaline ley extracted afierwnrds only a paler yellow ; though the digeflions were continued till the flowers had loft their colour, the tindures were nocther than yellow, and not h deep as thofe obtained from the pure yellow flowers. The little yellow flofculi, which in fome kinds of flowers are collected into a compact round difc, as in the daify and corn- marigold, a^ree fo far as they have been examined with the expanded yellow petala. Their colour is affeded in the fame man- ner by acids, by alkali;, and by alum, and equally extracted by water and by fpirit But the yellow farina or fine duft lodged on the tips of the ftamina of flowers, appears to be of a diiferent kind. It gives a fine bright yellow to fpirit, and a duller yellow to water; the undiflbived part proving, in both cafes, of a pale yellowifh white. Both the watery and fpirituous tindures were brightened by alkaline liquors, turned red by acids, and asain a deep yellow on adding more of the alkali. 1 know no other vegetable yellow that is changed red by acids. TFkiie Flowers. White flowers are by no means deflitute of colouring matter. Alkaline lixivia cxtrad from K 3 fome 222 THE dyer's ASSISTANT. fome of them a green tinfrure, and change their C' louriefs expreiTed juices to cne fame colour. But ] have not ohferved that they are turnele green tincture to fpirit than thofc of any other herb, i^lkalis heighten the col(5ur both of the tinctures and green juices. Acids weaken, deflroy, or change it to a br» and boil them about 2s long as h is cuftomary to boil fifli. The THE dyer's assistant. 22; The whole is fufFered to ftand in the veflel for a night. The wool, taken out in the morning, does not appear to l^ave received any colour. The pot is again made i^ot, and the yarn hun^ over it upon a Hick, covered with an inverted A\(h t > con- fine the fteam, for this fteain is l'upp')led to be efiential to the colour. The yarn is afterwiids wrung, the leaves taken out of the. boiung .iqujr, a littie treili water added to the decoction, and the wool frequer.tiy dipt therein, till it appears fuf- ficiently coloured. The ieav s of many kinds of herbs and trees give a yellow dye to woo! or woo len cloth that has been previoufly boiied with a folution of alu n and tartar: weld in particuiar afford- a fine ye. low, and is commonly made ufe-uf for this nurpofe by the Dyers, and cultivated in large quaiitities in fome parts of England. There is no co;aur for w-hich we have fuch plenty of materials as for yellow. Mr. Hel'jt obferves in h:s 4rt cie Tcindre^ that all leaves, barks, atid roots whi.h on being chewed difcover a flight allring-ncy, as the le.ives of the almond, peach, and pear-trees, afh-bark, fefpecially that taken '.■ ft' after the lirit nfing ot tne fap in fpringj the roots of wild patience, &c. yield durable yellows, more or lefs- beautiful ace jrding to the length of time that the borling is ■ continued, and the proportions of alum and rartar in the pre- paratory liqu.r: tliat a lar^e quantity oi alu a makes thefe yellows approach to tne elegant yellow of v/eld: that if the tartar is nade ro pre\'ail, it in- clines them to an orange: that if the roots, barksy or leaves be too long boile I, th^ yeiiow proves tarnifhed, and acquires (hades of brown : t'lat f t dying with weld, the bell proportions of th.^ fa ts are, four parts of aium and one of tartar t> iix- teen of the wool : and that the vvjol prepared with thefe is to be boiled again with tive or fix li nes its K 6 quanti:y 22S THE dyer's ASSISTANT. quantity of weld : that for light (hades, it is cuftomary to diminifh the alum and oniit the tar- tar; and that in this cafe the colour is more ilosvly imbibed, and proves Jefs durable. Of all the colours or" the Dyer, we have the fe. veil materials for blue; the mineral and animal kingc^oms afF^rd none, excepting perlups PrufTiaa b!ue, whicli Mr. Macquer has lately attempted to introduce in this" art. The veeetable yields but two, which are both produced from the leaves of plants, indjgo and woad. CHAP. IV. MR. lewis's history Of MADDER, AND MAN- NER OF TRtATiSG IT. MADDER (Ruria Un£iorutn fctiva, C. B.) i cne of the afpcrifoiious lleiiated plants, cr of thcfe which have rough narrow leaves, fet i:i form of a Itar at the joints of the ftalks. Ths roct, which is the only part :nace ufe of, is Jong and flender, of a red colour both on tiie outiide and v.i:!i n, excepting a whitiih pith which runs along the middle. This piant was formerly cultivated among us in great quantity for the u^e of the Dyers, who for fome time paft have ^een fupp.ied from H haiid and Zea- land. Its culture is now aeain fet on foot in this kingdom, unc:er the laudabic encoi:ratemenr oi a public fcciety. lA'^idex is not like alkanet, and other exotic plants, thee- lour of which degenerates in our ciiT»a'e*, for tr.gJfh madder is equal to the bell that is brought trom abroad. Aladdcr root gives out its colour both to water and to rectified fpirit ; the watery tincture is of a dark, dull red, the fpiritucus of a deep bright cne. T^aken interrally (for it has f mstin.es been uled u-.edicinaiiy as an aperient and diuretic; it tinges the urine THE dyer's assistant. 229 urine red. In the Philofophical Tranfafiions, and in the Memoirs of the French Acade^iiy, there are accounts of its producing a Hke effedl upon the bones of animals, to whom it had been given with their food. All the bones, particularly the more folid ones, were changed horh externally and in- ternally ta a deep red, but neither the cartilaginous nor fleOiy part fufFered any alteration. Sotne of thofe bones, macerated In water for many weeks togetiier, and afterwards rteepe i and boiled in fpiric of viK'e, loft nothing of their colour, nor com- municated any tinge to the liquors. T he dealers in this commodity make three forts of it ; madcer in the branch, madder in the bunch or in the bundle, and madder unbundled. Madder in the branch is the entire root dried. This grouted in milis to a grofs pjwJer is the un- buniUed madder. The bundled or bunch madder is a powder ot the fi:;er roots, freed from the outer bark and from tlie pith. It is faid that by keeping for two or three years in clofe cafks the colour is improved •, in open veflVls it decays. Madder imprarts to woollen cloth, prepared with alu n and tartar, a very durable, though not a very beautiful red Jye. As it is the cheapeft of all the red-i-rugs that give a durable colour, it is the prin- cipal one commo'iy made ufe of for ordinary ItuiTs. Someti i;es its dye is heightened by the addition of Brazil wood; and fometimesit is emplojed in con- junction with the dearer reds, as cochineal, for demi-fcarlcts and demi-crimfons, Mr. Hellot in- forms us, that thofe who dye the beft madder reds are particuiarly careful to keep the liquor of a heat confiderably below boiling, increafing the lire only towards the endy fo as to make it boil for a minute or twojuft ojtoro the cloth is taken out to confirm the iiye ; a boilmg heat enables water to extract not only the red, but a tawny or brown;ih matter, which debafes the red to a dull brick colour. The 230 THE DYER S ASSISTANT. The proportion of madder is about half thff we ght or the cloth. The beft: proportion of falts for preparing the cloth to receive tlie dye, feems to be five parts of alum and one of red tartar for fixt.en of the ftuffj which is to be boiled with thefe for two hours or longer, then kept moift for fome days, and afterwards digtfted with the mad- der. A variation in the proportion of the falts, varies the colour cmmunic ted by the madvler, and not only ihe (hade, bur the Ipecies of colour. Ir the alum be dininifhed, and the tartar in- creafed, the r'ye pr-ves a red cinnairion ; if the. alum be entirely omtited, the red is deftroyed, and a very durable tawny cinnamon is produced. On boiling the dyed cloth in weak alkaline ley, great part of rhe colour is c'elVoyed, and the re- mainoer appears of a dirty or a kind or fallow hue. Solution of f'ap, on the oth^r hand, difcharges a part, and leaves the remaining red more lively than before. V' latile alkalis heighten the red colour of mad- der, but at the fime time render* it fugitive like, thenifelves Madder prepared with line and urine, after the manner praciifed for archil, loft its red colour on attempting to dye with it, and commu- nicated to the cloth only permanent nur- colours. If a pure red, as that c cochmea!, be applied on cloth which has been previoufly dyed blue, and afterwards prepared tnr receivn;g this red by boil- ing with aluin and tartar, a purpie or violet will be produced, according as tht blue or the red pre- vail. The madoer red has !.•! tins rfT-6f, for as its colour is not a pure red, but is 'arndhed by the tawny matter which its woody fi^^res nave in com- mon with oilier roots, it gives upon blue only a chelrut dye, more or iefs deep according to the deepnefs of the blue applied firft. There THE dyer's assistant. 231 There are, however, means of obtaining from madder a fine purple, without the addition of jny other Colouring f'rug. A piece of white woollen cloth, weighing half an ounce, was boiled tor half an hour with ten grains of Roman alum and fix grains ot cryftals of tartar, and then taken out, fqueezev, and fuffi.red to cool. Twe ty-four grams ot bunch madder were added to the fame liquur ; and artcr the madder harl given out iis colour, twenty drops of a folurion of bifmuih (made in fpirit of nitre, diluted with equil its weight of water; Wi-re dropped in. The cloth was now dippe.t again, and in halt an hour taken out, fqueeze