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Maps, plates, charts, etc., may be filmed at different reduction ratios. Those too large to be entirely included in one exposure are filmed beginning in the upper left hand corner, left to right and top to bottom, as many frames as required. The following diagrams illustrate the method: Les cartes, planches, tableaux, etc., peuvert itte filmAs A des taux de reduction diffirents. Lorsque le document est trop grand pour etre reproduit en un seul clichi. il est film^ A partir de Tangle supirieur gauche, de gauche i droite, et de haut en bas, en prenant le nombre d'images nicessaire. Les diagrammes suivants illustrent la mAthode. 1 2 3 1 2 3 4 5 6 ■ft if .is O. H. M. S. ^ D«pul^ JfiniHtr. LABORATORY OF THE INLAND REVENUE DEPARTMENT OITAWA, CANADA BULLETINT No. 188 LIQUOR PICIS CARBONIS (SOLUTION OF COAL TAR.) 6675—1 LABORATORY OP THE INLAND REVENUE DEPARTMENT OTfAWA, CANADA BULLETIN Ko. 188 A LIQUOR PICIS CARBONIS (SOLUTION OF COAL TAR.) Ottawa, September 20, 1909. W. J. Gerald, Ksq., Deputy Minister of Inland Revcni- SiB— Ihavethe honour to submit herewith a report upon the examination of twenty four (24) samples purchased by our inspectors as Liquor Pic.s Carbonis (Solution °* ^"rhe British Pharnmcopaia directs this article to be prepared as follows— > Digest for two days at IJO' F., one part by weight of prepared c(«l tar, m five of a Tincture of Ouillaia (1 in 10, alcohol 90 per cent.) Decant, or filter when cold. The finished Liuuor Picis Carbonis should therefore contain about 75 per cent of its weight of 90 per cent alcohol; or approximately 67 • 5 per cent of its weight of absolute aUohol. Allowing for evaporation and loss, it may be rea-sonable to accept 60 per cent by weight, or 67 per cent by volume, in the article as dispensed. Jn all sHnioles containing alcohol, the content of alcohol meets quantitative requirements. An alcoholic solution of coal tar, known as Liqwr Carbmixs Detergent, is much employed in the treatment of skin diseases. This is not official, and is not to be con- founded with Liquor I'icis Carbonis, as above described. , „j „„ Various solutions of coal tar, some of them being proprietary articles, are found on the markPi Five samples of this character have been accepted by our inspectors. In accepting these articles, unless expressly supplied as Liquor Picis Carbonis, our Inspectors '"^ "Tbts^is cUariy the case in Nos. 987 and 988, which are distincUy labelled ' n tor Mrthyl Aloohol. Kafraetiofi. II 1 I Methyl Alcohol, "8 i Ronwrlu, ami Opinion of the rhiof An»ly*t. R. J. WAUGH. INSPECTOR. (I MiS6 U MM p.c 72 70 p.c, 70 27 72 7»i 79-27 1 P.O. »452J 87 00 9676| 30 U 78 3 eg 78 00 !p.e. of Uitall j Alcohol. I +0-8 I none. 1 4173(1 (leniiine. G9H— OH: none | '117:17 " THEO. MOORE, INSPECTOR. II 8814; 66 U9 I 8H64 639G J. 73 380 9406 39 60 71 42,0 97?1 19-88 808 49 6 80 8 49 7 -0 2 38571 (Senuine, 38572 .1. C. FEROUSON, INSPECTOR. U S464 II 8K29 80 79 6&46 8A 15 9394 72 SO 9270 40 10! 75 5 4600 86 7 81 6 87 -6 1 -0 3 14(1 39536 AdiilteraU-d. S«h) Ap-x-ndix A. ; i none ' 3fl6S7]r. Cow. Nkiii*' »iii1 Aildnnu •f the Maiiufac- turiT or Kuniiithfr, ut fri>**n Ity tht? Wndoi. IwiKirt. (In not »ii ex prriwiini »f opinion. ) 1009. a»pt. 1 . 1. DISTRICT OK OTTAWA- l.ii|. I'ii-i» Cnr ihtui* (wiliition of ci«l tar). tl'.TIIiNut. IM'UK ami Cheiii. I Co., Ltluti<.m worth Chem.Co., of coal tar). LUl., Toronto. Sold as Liq. PicinCarboniii .. 13. 41^45 Hargn-avin Hn»., 162 l-iuvon St. We.t, To- ronto. B .. . ! 26 t 1 Lyman, Knox ft Clarkaon, To- ronto. .Sold at Liq. Pi- cia Carbonit. DISTRICT OK LONDON- .Tuly 23. .. 2!). Liq. Pici» Car 306!«C. E. Na.sinith ft Co., [3 bot.j 60 E. B. Shuttleworthi Inmis (wilution | Stratford. I & Co., Toronto. I of coal tar). I ! Liq. Carbonis dp ,30809 .T. E. Hovey, Clinton... 's oz.. 25'.). A'lm-r A Co., Liq. Carbonis tt-rgi-na. i | Hiuiiiltoii. Detcrgen*. DISTRICT OK WINDSOa- ,Tiily 28. . Liq. Piclii Car- 3.59!t3 'x)ni» (solution! of coal tar). ; .. 28. . Solut. of coal tari35999 .\ndt'rt»on ft N**llt-», Ijon- 6 oje don. 60 |Nat. Drug Co., Montreal. W. T. Strong, London. . 6 ., . .! 60 Vendor ! I lARBONia (SOLUTION OF COAL TAR). Rraikrkii, kim) Opinion >•( the Chinf Anklyit. .1. A. BICKKV. INSPECTOR p.0. p.c. ! p.c. p.0. 1 •oUl Alcohol. 1 1)8)02 73 71 8» Ifi 9342 42 67 84 3 839 + 04 none 41279 (ieniiine. II 8472 80 46 86 87 09118 53 77 994 92 1 + 08 none 41280 " ,IAS. HOGAN, INSPECrOK 1 1930( none 1 16M none 41170 I» not Lii|Uor Vicii (;»rtHini«. I See App. B. 41171! " " . " >^^ U tolution Ot CCMtl tMt. H. J. DAOER, INSPECTOR. 1) 8953 1 0211 flO IS none 67 810 9419 38 83 485 80 00! -36 5 T. KIDD, INSPECTOR. 8545 8632 73 71 83'43;0-9242 47 27 80 15 0-9486 35 20 428 39 6 88 76 1 -452 -36 6 J NO. TALBOT, INSPECTOR. 8707 KJ79 70 56 8412 77-39;0 9168 88 790 9234 5061 47-64 91-0; 90-8 46-05 88 35 +0-2 -42 3 86 1 41344 Ii not Liq. Pici» Curbonii. I The f»ct of b»in(j mmde w.th I methyl alcohi '.iihiinld be iit«- 41.'M5 ted on the label. i4ee>Vpp.C. U not Liquor Picii Carbonis. See App. D. 93-4 90 6 30695 Adulterated. ConUin* methyl alcohol. See App. E. 30809' Ifi adulterated and not Liq. Picia Carbonia. The fact of beinff made with methyl alcohol Hhould be stated on the Ubel. See. App. F. none 86 7 36998 35999 Genuine. Adulterated. Contain* methyl alcohol. See App. G. 8 BULLETIN No. 188— LIQUOR PICIS Date of Collec- tion. Nature of Sample. Name and Addrew of Vendor. Cost. Nauie and Address of the Manufac- turer or Furnisher, as given by the Vendor. Inspector's Report. (Is nut an ex- pression of opinion. ) DISTRICT OF CALGARY - 1909; Aug. ll.Liq. PiciH Car- 35598 A. Archibald, Kdmon Umifl (solution ton. of coal tar). I. 11 35699 D. W. Macdonald, Ed I I monton. Wright k Co., Sonthwark, Lon- don, Eng. Unknown DISTRICT OF VANCOUVER- •luly I.ii). Picis Car- 37710 Wiluon's Drug Store, 6 oz. l)oni8 (solution: Vanjonver. of coal tar). 37717. Lralie (J. Henderson, |6 oz. Vancouver. 60 1 SO Vendor W. V. Wright ft Co., South wark, London. CARBONIS (SOLUTION OF COAL TAR). RlSl'LTS or ANALTBia. a. B 1 Auproxiiiwte Alcohol, p.c. I 3 Gxaminktiun for Methyl Alcohol & 1 Refrsction. 1^ ' -i I" i i I •< I i. j H Methyl Alcohol. I Reiukrkit and Opinion of th* Chief Analyrt. K. W. FLETCHER, INSPECTOR. 8876 8567 p.c, 63 43 76-58 p.c. 70 93 82 6.5 9709 0-9296 p.c. 20 68 515 ! 44 73; 63 7 54 6 86 -323 ; p.c. of total —0-1 none 35598! Genuine. I I 36699! Adulterated. Contain! methyl \ alcohol. J. F. POWER, INSPECTOR. 8568 8863 76 %' 82 97iO 9768: 16 83 42 6 64 43! 71 860 9452 37 00 77 90 I I I 42 2 +0 4 780 ; -0 1 sni6 3ni7 Genuine. 6675—3 10 APPENDICES. A —Referring to sample 39536 :— This sample was carefully cheokeu, and the presence of methyl alcohol e.toblished. It would appear that the maaufacturers were not airare that wood alcohol had been used in its preparation, and the sm"!! amount of methyl alcohol present may have been added through some oversight m manufacture. Tiie vendors write, under date 4th October -'Our laboratory man still claims that he uses nothing but pure alcohol in the manufacture of Liq Carbonu-j Detergens ; but at the same time I have no doubt that your analysis is correct, and I will Imvo what we have on hand, destroyed, and will see that our new lot contains nothing but pure gram *'"" B°-In regard to sample 41170, the following letter of 22 September, has been received from the vendors. ' Your advance notice re Liquor Picis Carbonis is duly to hand, and your observation noted. We have to thank you for the information. It is information to us On inquiry we find that this preparation was taken over by this Company from their pretlecessors, Henry Skinner A Co. On further inquiry we are informed that this was made by Henry Skinner & Co., probably 15 years ago, before the propara- tion became official. What Iktle we had in stock (less than a gallon) has been ^* 'c^l-Sample 41344 was apparently tendered as Liiiuor Carbonis Detergens, and invoiced as Liquor Picis Carbonis, by our Inspector in a mist tke. The vendor writes under date 21 September :-' Your collector received samp^ ^'T. ,"! f ^T"'' ^^-^ bonis Detergens, one of the ...t official preparations by E B^ Shuttleworth. This preparation is made from an o1cl. Ho asked for Liquor Picis Carbonis, and we showed him that the preparation we had was not the official one '. Our inspector's account of the transaction is as follows :—' Ihe clerk serving me a.sked if Detergens was what I wanted. I said Liquor Picis Carbonis was what I wanted. He asked proprietor about it. Proprietor said it was all right, and tne clerk then filled the bottle '. While it is true that Liquor Carlwnis Detergens fills many ot the requirements of Liquor Picis Carbonis, the preparations are not identical, and should not be dispensed as being so. , . . , . ^. .i r< d ai..,»fi„ Recarding the presence of methyl alcohol in this preparation, the E B. Shuttle- worth Co. writes under date 25th September :-' We are in receipt of your favour of the 24th instant, with inclosure of Inland Revenue Act, for which accept our thanks This is the first intimation we have had, that preparations containing Methyl. Alcohol should be labelled as such, and we will immediately comply with that condition, although it will not afifect us materially as we believe we have only one or two prepara,tions m which we use it ; this particular preparation (Liq. Carbonis Detergens) is used almost exclusively as a disinfectant'. , . . .ia^i a >■ ™ D -In the matter of sample 4134.5, the vendors write, under date 20th Septem- ber — ' We should explain in fairness to the manufacturer whose name is attached to the container, that the title on the conUiner is Liquor Carbonis Detergens. Our custom has l>een to treat 'Liquor Carbonis Detergens' and ' Liquor P.cis Carbonis as identically one and the same. From any information at hand, we have felt justitied in this conclusion and in regard to the nonalcoholic adulteration, authorities state bo^ contain alcohol '. Also under date 25th September :-' Reply.rg to yours date.1 23rd instant, we presume we must accept responsibility for the article sold to Inspector Daeer We woi ' \ however point out in justification of our custom, that in 1888 some years previous to the adoption by B. P. revision committee of any formula for Liquor Picis Carbonis, we prepared a Li