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( Translated from the tierman by Xfinil Xorlan Evana.) OTTAWA PRIXTKD HY S. K. DAWSON, I'KINTKH TO TKK KIMiS MOST KXiKI.LKXT MA.IKSTY 1902 12 o No. 7«3. NOTBS ON CERTAIN ARCH.EAN- ROCKS OF THE OTTAWA VALLKV. Hv A Os\N\, Ml LHAV8RN, AlkaCK. (Tr,n„l.'''"• extending over five weeks, in that part of the province of (^ueliec north and cast of Ottawa, and in thisi I was assisted in the most obli"in« manner by Dr. Dawson, then direitor of the .Survey. Further, upon many of these excursions I wa.s ably directed by l>r. U. W. Kils and by Mr. E. D. Ingall. It is a pier ure in this place to express my warmest thanit in vrry mui'h l«nt •nd ttiUM, im may U- eMily observed on the lurlacoH which huvf lnH-n highly polishinl liv i. Thf miicnwcopic character of thf gni-i"! ri-niimls one »troniily of the horniel* tineiM in ihenouthern Oilen- wttld iiiiii of ii.any xocallwl llfrnK gneiitMi t'l. Blivck Fon>»t ; in hand upe.inn'n'* it in oft»'n iuijxMnilil.' to di«tinKuiitii it from thew. Charao fJii-lic »ign« ftr»« the fiillowiiig : modiTately tine and very even grain, (jreiit abundance i>t' inifii, and a niii'ii schint habitui caunetl tliereby. Further, lack of flivn-r or augen utriutui.! ; the oonstitueiitu are very unit'oimly diMlril.ul' d, the mira plates are all arranffed parallel, iO that th«> iiK-k liroakH fairly well in this din-ction. The retfularity of the MniL'turc is only intirferrd with by nunicroiin (juarti: veins anil mxlulei whi.'h are trf.|upntly as thick n» one'n tinker and thin out to noihinK in Oiort diitaiiceH. Tl*- mica of the normal rock 'i» a re«ldi*h. brown hiiitite, l>ut in many of the IkhI* tlierc occurs also a white mica on thi' whistose iturfacfn ; this is not unit'oriiily di»tril)UteJ but forms rosette-like iijut tlie ilinennioni flncrpa-oe fnmi tlii)i iluwii to nxtmiie Humtl* nMi«. <) it brownUh'Ki'«an : K, coluurli-ii with a touch <>|f rml. ColourloM mien, at Alreiuiy ttnttMl, !» I'urittiDil 'tlnuixt entirely tr- tiw' little itgKrf)i(ntiim'« : in th<* iioniuil nxii it i'l very rirs itml iiiiiki>K up liiru'>'r tliike« in poilciiitie interKniwth witli thr conitituentfi o( the fnck. Quartz, with the uxunl llui>l iriulusiDriN, iMiurs much iinite N|iitrinuiy than fe'dtpiir mill iniiu. Apntiie nnil nrei ar'i ritre : «ii£ ii Tvpiciil h ,,> typical hornfoU ; in p'irtioiit rii-h in luinii, enpecially in m-.tions cut '''' "'""'""' vertical t" the H<'liii«t'mity, it it iimri- or Ic" liiililen .. the |iiiriillel arrangement of thin iiiiiienil. The uniform !r. l>iitrii;h, and i* ;;iven under I. .tid... Tin, . Al., < );, , I'., II, I'll II. Mk<» . Cull . X11.J ( I Ka II . I', " » . (' O, . H,0.. 1. II. .Vl liM .'.: Ml im — tdU 33 Ki l-IIH — R-60 7 74 3 71 .l-.Ml I) .'HI 1 111 1) Xi M lilt K IM ■ » 7« »1 _ 11;-, 151 01 Totttl. urn For comparison there is given undi r II .n »*-«»lyHis of h silliraanite- .\iuilv* • bearing gneiss, rich in biotite, from Treinblii to wtiom we owe very vnhiiiile in -eM from a large area north of Montreal. similar except in the larger i|uantitv of al in.. alkalies in No. II, a peculiarity which i.s e.xfjU the occurrerce of the pure Milieate of alumina, *v. fnnnite. in the gnei.'i* from Trembling lake. No. I show.s the same |*i i\iP <4 -;ilic!), lint •onlii . I,) Ad-imii, "-..ihikimhI. ' the gnei-'.ies 1* ilysps are verv .Her quantity of iianeralogicttlly by * liO.H i.ii i^riiitiui). • e OTTAWA \ ALLEY ! ml 14 s \» puorer in ulutiiin.* and richer in r»ll«i»liw, eorrefipomiing to iu «»n' nl ■>t touriiialini'. Ill given tin- ni'lt^ulnr |>n»twrtiim •>( I rt-tluce*! to liK), «>xi-lu(iinK the w«t« 11 411 1 • •l .■1 !C, 111 |-. K," ti «•.' 1 i;i :i IJ ;i 41 :i ,'4' »•,«' V. VII. with 11 o II WItll II II II.'. Ii» Mull. I'J Itit 1 1. ii7 Sr tl. "7 Miitl. II l.-l .1,1 For both aniily-cH I iind [I the Mimll i|U tntity of lime in prop irtion '' to the Urge i|)inntity of iDii;:neiiu and >iiiiill i|aanttty of Hilii-n in cliarau- teristic Further, the total idknlien and lime are far from duHiiient to form with the alumina the nioU-ciiU's ( K. Na), Al., <>, mid Cn Al.j O,. .Miiieraloaically thin i» expliiineil bv tin- compU-ti^ly unaltered charactei of thi- riKk, and by lh>- sili Hteii of alumina being free from or |Kmr in iilkalin, Hui-h ax Hillimaniti- and tourmaline. A glaiii-e at the anidytii'iil tablen of plutonic rwka arranged uccording to lecular proportion.s (2) whowi tliat sui-h u Miiiili ■ intent of liu:« us tlx-ie iii in III only (Kours in the cam- of highly iioidic granites and a few el.folite- syenite^. In the former ciin^ the .'^i O, (in molecular profiortions) in over HO , in the latter iiluminii iind ulkulii-s are dfciledly higher. For r'liiipurison the following iir • j-iven : — IV. .\iialy"i" "f KiiiiiiiiKramfi' Viiu.m n. V. Syiiiiti' frmii Viiifii I'l'iik. Montana. \'!. ,. (fraiiiti- fnnii l'a|ii' Ann. Ma..«. VII. Klauliti' "Vfiiiti- fMni Litclititlil, Ml . < If thfse, IV. and V. have atjout the xaiw proportion of Si O.^, Al.^ {) ., and alkalies) as III. ; on the other hand the pniporiion of lime ia considerably higher. VI. has about the siime proportion of alkalies and lime ; but alumina, iron and magnesia are lower and silica con- siderably higher. In VII. silica and lime are as in III., tiut alumina and alkalies are more plentiful, magnesia and iron Kuch lower. Uosen- buscli first pointed out that such a small proportion of lime with rela- tively large quantities of iron and raagnrsia are characteristic of normal oilKliwta rHOW Till !IRI<>'l)iI> ■■»' i>IT,\u ( I o cUjr »l«t«a, MX i» iil«<> uounlly th>' {irrnuunL't'il prviiimilfriinrii of ixtttmh ovur Hoiln. Fro\iir|>liu-it, their chfrnic*! cmiipiMitum i» ».'»,»tJ ' oiil> nliKhtly < Iihiikpn >>lMH>rve'v't iiictntiioi |>hu«i« on Mvi-rnI iM'Cii«ioii«, thn itupiMwitiun that rii< Mil ".'IipIIu Kiipiit'< tins lirt-n \|.,tii.U.||ii foiinml !>• Ill • cl»v >.liit«< !■. <|uit«' iiiharmniy with it» rhi-iiiinil ii.iii i"'ii'm.'im,iv IMiKition. It iiiuMl noi luiwuvir Iik fi>rK»tl«ii, thnt im hn« iHrn ofti>n ■ f'""' oljiwrvril in thi- rune of |ilutoiiii' nM'k«, hy nnrumi iltct iii|ui>.itiiin u rnpiil rpiuovnl i)f liiiiti niiil ■unIii ih'<'ui'-<, licri' iilno liui ixiiit' I'lu'inical cimr- i».ai r r«'»iilt' Mmt of tht- olij l'iilif utitnini'il ' 'imteriHl iiiHiniy tniiii fru|iiiM' riM.ki and iTuptivp gnfii-M-x. . ' It » U'«iliini{ out of lime kihI wkIh liy the wcnthirinK 'luriiiK l! i.'iiiii>|»>rt /iik! i.'riiiiliii]u' up i.f tlio oiitfinnl iiutti-iinl inuxt havf taki«n place, wliili- in tlic out ni iilutoiuo rncki lliut havi- iu»l ixTn mil innchaiiicjilly liiHiuti'urati'il. iliis i lieiniritl priHcxH will haw taken plare much iiiorf slowly anil Ii'kh I'liinplfti'ly. Tlit' ((tnenil pri)- ce»» i«, however, the naim- in l«JtH rajti-.. The alMnn nnalywH tliiTefori> furniiih merely a certain prohahility of tin' m (liim-iitaiy diaracter of the Montebello ifnoitn. The ijuartzitu fnini Mouteliello, lon^i t- for the niont part of a coarx- r.,iii|.-.iii..ii «KK'"«"K<»t«'"' nuartz ({rains, which al.ui ii-«iii»t onHanotiiiT wiihirri'Ku )'l/,l"'\l"',''... larly angular and txithtd innrgin*. No iiidicaticn.i whatever of ilaxtir '"H" origin or ..t" later orientateil ifrowtli, ilrc, can lie recoxnizitl ; a ceni''nl In also wantini;. Wiih-iy iliittributed, however, art- the well known evidences of prexsuie such a- umiulose extinction and the lireakiiii! up of larger ;;raiM into a iiuinlier of iinialler oneM of approximately the winie optical orientation. Further the ntnakeil appearance, so ot't«'n de»cribed ns suggestin;; twinning lamellie, is not uticouiuion. The .streaks can lie reeogni/eii in unlinary liijht : in part they are an clear aH water, in pirt dull and tilled with inter|)ositioiis Uniking like dust. Some of these, upon --trong magnification are found to lie ttuid induitions. Among accessory constituents may lie inentioneil somw inuscovitc .•cif»«.iy and graphite, ixith vigilile with the magnifyinp glass, gran f a triclinic "'""''""'""• feldspar, small i|iiaiititieg of carbi>nate8, prol>a)ily rich in iron judging from their brown colour, isolated j-latc of biotite and titanite in rounded grains and elliptical sections The granular limestone of the Monteiiello section is rather coarse in grain, of a dirty grey green colour and characterized by a considerable content of chlorite. It also con lins microscopically some quartz and .eldspar, in part mierocline. ill 8o OTTAWA VALLBV Different type of pieiss. Micf' ile8crii>lioii, |»c • I Structure similar to a plutuniu iiK-k Not far from Montebello, at a place called L«faivre, an opening was made a short time ago in granular limestone in the search for graphite. The limestone is here snow-white, much more coarse- grained (grains up to 1 cm.) and contains light brown mica, some muscovite and rounded plates of graphite (up to 2 mm. diameter). A type of gneiss entirely different from that already described I found north and north-west of Lachute station (76 miles east of Ottawa). Between Lachute, T^kefield, and the mass of syenite which covers a part of Grenville and Chatham Townships (see geol. map accompanying Annual Report Geol. 8urv. Can., vol. V^III., N.S.) this gneiss appears to cover a considerable area. Hand specimens were taken from a num- ber of points and were found to correspond with one another macros, copically as well as microscopically. The uniformly medium-grained rock shows on the cross-fracture a typical stratified structure occasioned by reddish layers composed mainly of potash feldspar and som8 quartz, alternating with layers rich in hornblende and mica. In other specimens this alternation is more or less indistinct and a granular striped structure appears which passes over one almost completely granular. Under the micro- scope the rock is seen to be composed essentially of feldspar and horn- blende with decreasing quantities of quartz and mica. The hornblende is green and transparent and exhibits in .sections parallel to the prism zone a maximum extinction angle (5 : C, 18-20'. Absorption and pleochroism are strong ; 31 is light greenish-yellow, "8 and 6 approxi- mately equally dark grass-green. The outline is in general irregular, but many grains are much elongated in the direction of the (5 axis and sometimes rough crystal outlines are observed corresponding, not only to fac&s of the prism zone but also to terminal faces. The much more rarely occurring brown mica sometimes exhibits six-sided outlines. The allotriouiorphic feldspar is to a small extent pla- gioclase but chiefly orthoclase and microcline. Extremely common and very various in appi'aiance are the microperthitic intergrowths. The orthoclase contains spindle-shaped inclusions or irrejrular patches of a feldspar characterized by a higher refractive index and double refrac- tion. Further the orthoclase grains are sometimes peripherally sur- rounded by a narrow edging of more strongly double-refracting feldspar substance which is certainly of later growth. Apatite and zircon occur as accessory constituents in relatively large quantities. The microscopic structure of the gneiss reminds one strongly of . that of a plutonic rock. This impression is produced particularly by the tendency in the amphibole and mica to regular outlines, their frequent il ■•] ONEIRSES FROM TIIK yEIOIIHOURIIOOri OF OTTAWA 9 O bunchy aggregation and the difiPerence in age of these two niinerals as compared with that of the feldspar and <]uart7. On the otlicr hand the ragged development and fre<{uent inter$;rowth and interpenetra- tion of the contituents so common in other gneisses is entirely wanting. At any rate one may express with great probability the supposition i'r.>l)iiip|y nf that this Liichute gneiss is of eruptive origin ami this is supported ,', by an analysis made by Dr. Dittrich which gave : — riiptivi' SiO,. . Ti( ), . Al.lK . K.-,l >: F.o M)f«i.. Cal). . NajO K.(». I'.O,. H,l>. CO.. !tr>i 71' 1 .-)i; II. •i7 I'.i II ,sl 11 ti.s 4ir S ()4 i; s! 4 17 O (IN w;-2 Under II the corresponding molecular percentjiges are given, neglect- ing the water and COj and calculating all iron as Fe( ). One is struck upon first glance by the distinct difference lietween this and the Montebello gneiss, although both analyses show almost the same content of silica and alumina. The soda iind lime are however quite different. The whole composition of this Lachute gneiss cor- responds with that of an eruptive rock, and for it may be give_ .^ — 111 40 (■ 1 L'S K s .W til . This formula tits in very well with tho.se of syenites rich in liiif.pMiic alkali between the types Umptekite and Hedrumite. There is n ,,'.i'„"'i,7:ii'i(i"" remarkable similarity between its composition and that, for example, l-idnitr of the syenite from Red Hill, New Hampshire, (Analysis III) in molecular proportions. III. Sifl lili 21 TiO OILS ALO:, !•_> INI VM 4 7'.l MiiO o;', Mk<» l-7« C:lO. 2 Wl Nu.jO :m K,<) 3 Ki l i : J ' 1 ^1 ■ ^ -■ i ' .|j[ 10 o OTTAWA VALLEY Eruptive ffiieiaH from Treinbliiik iiinuntain Laketi.M. P. <;. Ull) Mic-roHwtpi Hection. tiieiitH. The high value of Na.^< ) can here be explained only by microscopic and perhaps also cryptoperthitic int«'rgrowth of urthoclaae with a swla feldspar. The average plagioclai^e has a composition Ab, An,, and is therefoi-e an acidic oligoolase ; probably there are present in the rock albite and a basic oligoclase. Adams, in the investigation above mentioned, gives the analysis of Jin eruptive gneiss from Trembling mountain. This rock is more acidic to the extent of about 10 per cent of iSiO.j, and corresponds in its cumposition to a granite. At a place called Laketield, Argenteuil Co., P.Q., a gneiss was collected that does not difl'er essentially from the one just descrilied. It is decidedly more fine-grained, and contain.s " Augen " of feldspar, 5 — 1 cm. diameter, whereby the strwture is rendered somewhat more "flaserig.' The cleavage surfaces of these feldspars are much bent, sometimes are ijuite crushed. Cleavage plates parallel to oP are in some cases without twinning strise, and as tar as their strong undulose extinction will allow of a determination the extinction is parallel. Other cleavage faces exhibit the cross-hatching of microcline. Under the micros- cope the grain is seen to l)e distinctly coarser than that of the gneiss fro-ii Lachute. The principal part of the section is made up of a mos;aic of little feldspar grains, of which the striated and not striated are present in about e'ntione(l in the description of the occurrences of apatite antt graphite. Os THE Occurrence of Apatite am> JIua north of (jttawa :J4I fji Apatite in large deposits of economic value was known in the dis- vir-t <1U- alKitlti-. trict of the Lii'vre river as early as 1829, but was soon forgotti'n. In ihe year 1H4", r»r. Sterry Hunt' descrilied similar occurrences in the province of Ontario, between Kingston and Ottawa, in the counties of North find South Burgess, Lanark, Frontenac, Renfrew, Addington and I^eeds. A regular exploitation was begun in the sixties and was carried on till the beginning of the nineties. .\t this time the Canadian ipatite industry succumbed to the enormous development of the phosphorite industry in Florida, Alabama and neighbouring states. It was mainly in the two districts indicated, one north of the < »ttawa river in the province of Quebec, and one south of the river in (Jntario, that the mines were situated. The observations here recorded refer to the first of these districts, and the principal mines on the Licvre and in the neighl)ourh(H)d of the (iatineau river were the only ones visited. The area in which apatite occurs and is mineii, extends ove.- a Ana cf large part of the townships of Buckingham, Portland East, Portland "l«tit'- '"•ir- West, Templeton, Wakefield, Bowman and neighbouring townships. i.r(.\incciif From the copio s literature upon this subject, it may be said that it was very early rec lized that the apatite was generally associated with rocks which w. e entirely or for the most part cim posed of pyroxene, * >nelM'C. • S \ I \ V > Starry Hunt on I mU' I if < iccuir»'n(.'f. vatioHM ctiii- tiniied. 12 OTTAWA VALLkV .1. \V. I)a«.* un lutMle of occurreiicv. and which Sterry Hunt"' called ' pyroxeniie.' Concerning the origin of ••his ' pyroxenite ' and of the apatite, opinion is still very much divided. Stprry Hunt* described in the year 1863 the apatite iis occurring in the Lnurentian rocks, lioth distributed in crystals through carlwnate of liinc and in ' irregular beds running with the stratitication and com- posed of nearly pure cryslallinp phosphate of lime.' In North Burgess the mineral occurs in ' several parallel betls interstratified with the gneiss. Tn the year 1866, the same author says', 'the presence of apatite seemed characteristic of the interstratified pyroxenic roeks, the apatite marks ihe stratification.' Simultaneously, ' true apatite vein-stone* ct'tting the bedded rocks of the country ' were mentioned. These were ' well-defined veins traversing vertically and nearly at right angles the various rocks.' In the year ls84, Hunt" says : ' I have within the past few months exairined with some detail many of the apatite work. inj;s in Ontario, which have served to confirm the early observatiuis and to give additional importance to the fact that the deposits of apatite are in part bedded or interstratified in the pyroxenic rock of the region, and in part true veins of posterior origin The bedded dep of quartz, of carlwnate of lime, of pyrites and of apatite. All of these often show a banded structure not unlike that of the gneiss to wiiich they are evidently posterior and of which they often contain fragments.' J. W. Dawsoi., in 1876, says" : ' It appears from the careful strati- graphical exploration of the Caundian Survey in the districts of Bur- gess and Ainsley, which are especially rich in apatite, that the mineral ir,Afi-. 1 APATITE AND MICA NORTH OK OTTAWA occurs l.ii'gely in beds interstnvtified with tlie other mcuiliors of tht- geriea, though deposits of the nature uf veins liiccwUe occur. It also appeiirs thuc the principal beds are contin- i to certain horizons in the upper part of the Lower liaurentian, abo\i the limestones containing Eozuou, though some les4 important deposits occur in lower jKisitions.' Fu.'ther, he says of the veins ; ' Since these veins are found princi- V.in^ ■.. pally in the same members of the series in which the beds occur, it is )"7ni'Iut "n a fair inference that the former are a secondary formation, dependent on the original deposition of apatite in the latter, wliich must belong to the time when tlie gneisses and limestones were laid down as sedi- ments )ind organic accumulation-.' Dawson further points out that in the Primordial time animals 'with phosphatic crusts and skeletons' predominated, and the calcium fluoride, contained in the apttitu, also occurs in bones e'^jeoially in m.iny fossils. }io lays especial value upon the face of the occurrence of phosphorite r.oii this region (Templeton) are not 1 -Is, is plainly shown by the mani.er i'"''"'- in which they cut across the strik of the rocks containing them.' He turlher mentions the opinion of Bmgger an i Keusch as to the eruptive origin of the apatite veins of Southern Norway, and remarks . ' This idea of an igneous origin cannot bo adopted for our veins, ' points out the fact that the ' pyroxcnite often contains grains of apatite, and adds • no doubt they are the strata from which the apatite of the veins has Ix-en chiefly derived.' In 1883, J. F. Tiirrence'" exprcs.ses the opinion that the apatite de j j-. Xurr<-nci ptisits of Portland and Buckiiisiham are irregular seiireaations from the '".' "ccuriiiui- country i-ock, and that these belong to one or more rock /one^ I'.utl.md aii'l more or less strongly iioprcgii;Ued with (ipiitite which follow a N.N. W. '"' "'^' """' direction along the course of the Lii'vre river. He further remarks ; ' During the past, season I often i>oticed in tlie same pit, patches of apatite ''.it might easily be taken for the contents of a fissure vein if ther ■ ar,y casing rock on either side of it to separate it fiom the cou rock, and patches of tlat-lying apatite that might easily be called befided, if they were of any ,reat extent or approximately uni- form thickness and if the country rock showed any planes of bedding par,il!el to the longest ones of such patches ; or else it might easily Ije assumed that the country rock hafi been more or less tilted and over- turned sit>i-e «he deposition of the apatite and that the vertic;U patches ; il m 14 o OTTAWA VALLEY M Oth>riii.iiiiii un niiidt' nf (Woiirrt'iK't-. SllliIKWHrl cit-ar fvidei of HruptiM' were interbedded and tlie horizontal onea were veins >f their relations to the country rock were Huch as veins and IiedM respectively are wont to maintain, liut unfortunately I failed to perceive these conditionn. ' Further : ' In by far the greatest nunil)er of ''a»es the containing rock of apatite is pyroxenite ; the veins are very irregular, consii^tin^ of large bunches or pockets of ore, yielding hundreedded apatite ' is of organic origin and that the Laurentian strata in which they occur are altered sediments. The ' vein apatite " has Ijcen formed from this by a ' process of segrega- tion.' (»n the other hand, in 1S86, R. Bell'"' says that the apatite comes principally out of the pyroxenite and there are no indications of orga- nic origin. The pyroxenite is jiossibly ' derived froDj igneous sources.' E. Coste' ", in 1887, attributes iht- formation of apatite and a part of the iron ore.s occurring in the Laurentian to eruptive agencies. He says : ' We Iwlieve that we have gathered year after year strong and clear evidence to show that our deposits of irtm ores in the Archiean rocks are of an jruptive or igneous origm, but also that our deposits of phosphate are e.cactly similar and have also the same origin.' Further, ' in the region north of Kingston, in the counties of Frontenac, Leeds, Lanark, Renfrew, Pontiac, and Ottawa many deposits of iron ores and many deposits of phosphate were observed also in the same association with igneous rocks, and both cutting through the Archn'an rocks. In the cose of the phosphate the igneous rock wos often the rock termed by Dr. Hunt " pyroxenite, " but at other times it was a pegmatite or a mica syenite or a pyroxene syenite. ' He further points out that in many localities the iron ores and the apatite occur in the same veins, APATITE ANK MICA NORTH OF OTTAWA 19 O thu« at the filoasington mine in nine different pits ; in tlie summer of 1886, 500-tiOO tons of iron ore and 1,500 ton* of apatite were obtained. ' We should conclude that the iron ores and phosphate to be found in our Archn'an rocks are the result of emanations wliich have accompanied or immediately followed the intrusions through theie rooks of uuiny varied kinds of igneous rocks which are no doubt then.|uivalent of the A'olcanic rocks of to-day. ' Penrose (1888)" verified the freijuent vein nature ..f th- .ipatite iVnrcM- deposits. Concerning the ' pyroxonites ' he says : ' The pyroxrnic rock ''"'• u never found ec anti which therefore is of interest. Starting out from the spotted i^'abliro of Norway as apatite-liearing, Adams has exantined certain pyroxenites with respect to their containing scapolite- The specimens came from Lot 35, Range V., of Portland West, from the McLaurin mine, Templeton, and the Emerald mine. In none of these was scapolite found. Further, two rocks collected by E. Co?ite at the Star Kill mine, Portland West, and the Blessington mine, (»nt., were recognized as granular eruptive rocks and designated as mica syenite and augite mica syenite. On the other hand, Adams found in a series of rocks from Arnprior on the Ottiiwa river, a rock consisting essentially of pyroxene, hornblende and scapolite and which he called scapolite iliorite on account of its granular structure. Snnilarlyin the Museum of the Geological Survey there were some scapolite-bearing rocks from Ont.irio, liesignated as plagioclase scapolite diorite and plagioelase scapolite amphibolite. Apparently these occurrences, as Adams remarks, are not connected with the apatite deposits. Lacroix later examined the same rock from Arnprior--. Unfortunately I have been unable to consult the greater part of the Canadian literature, but it is evident from what has l>een quoted al)Ove that the views with regard to the Canadian apatite are very diverse. Davidson and perhaps a few other geologists deny the occurrence of apatiti; and pyroxenite in true vein.'--. According lu tht-tu the pyroxe APATITK «ND MICA NORTH OK OTTAWA 17 o nite iti of the Mine age hh the gneiitii and atrntit. il conformalily with it. The Apatite has been derived from iin original phosphoric ncitl content of the Laurentian depotitit ; l)y their inetamorphoHis it cryttal- lized out from the ' plantic mafpiiii.' The ureater numljer of Canadian ((cologisti are agrc. I, howevor, A|«iiir. Stth that both 'bedi' and veins of apatite occur, wliich cut the gneiMM th.. itii.i«». strata in all possible directionM. Thfy rejrard the former a« deii I from phosphoric acid in the rocks due to organic remains, the veins being formed from a leaching out of this material, ».»•. by lateral secre- tion. In connection with the organio urigin of the phosphoric acid much weight is laid upon the occurren-'e of graphite in tho neighliour- hood of the apatite and also (the graphite veins in the neighbourhood cf Duckingimm on the Liivre river contain green apatite in compact raa.sses], on tho occurrence of Eozoon fanadeiise in the Liurentian limestones, and of certain iron ores in the Laurentian, the origin of which is also supposed t4) l>e connected with the action of organisms. Selwyn, Cost*', Mis, and also Hell, bring the formation of apatite <;''i.tii ri|»- into genetic relation with that ot baste eruptive rocks {t-.i/. pyroxenite). ,„„| ,,y,,,x,.. Ells speaks directly of a fumarole action which accompanied or fol- """■ lowed their formation anil throui{li llie .iction of which upon the lime of the pyroxene the apatite was formed. This view is very similar to the theory put forwanl liy liroj.'t!er and Vogt to explain the formation of the apatite veins of southern Norway. Unfortunately the opportunities for the study of the occurrences of ivnimiu-cs , , , , , , . II..W (litti( lilt apatite are very much less aiie mine oocupiee but a very Niuall itren. The principal vein ha* boen o|>enMl up hy cutting! to ii length of about 700 feet and in platen to a il»ptli of about 50 feet. uorder plane pyroxene crystals have formed, prismatically developed up to 6 cm. thick and twice an long. The prism zone is almo.-4t perpendicular to the plane of V.iii iiiij er.»l« contact. A second vein mineral is reddiNh-brown phlogopite.aUo usually well crystallized, but sometimes in scaly aggregates filling out the spaces between the pyroxenes. Everywhere one can discern that the pyroxene is the earlier formed and the phlogopite the later formed mineral. In places the two build a regular net-work the interspaces of which are either empty or filled with a coarse-grained aggregate of ren apatite, the relative quantities of the two vary, the former generally predominating. The apatite either exhibits the crys- Ulline form a P | 1010 I P | 1011 [ with rounded edges and corners, oi' forms large irregular lumps. The richer the vein is in calcite the better is the apatite crystallized. Calcite crystals are entirely absent. The sequence of the four vein minerals here is therefore: pyroxene, phlogopite, apatite, calcite. The same relations appear on the opposite edge, the vein is laterally symmetrical. From this vein a narrow vein branches off into the gneiss having a thickness of about 5 m. Its edges are alsi perfectly sharply defined against the gneiss. The vein is symmetrically formed APATITK AWI) MHA NORTH Or OTTAWA 19 anil confiuu an the Mccompanying H«ur»« »ln>ws of two latural /unwi n and l> alinoRt pi|ual in thiilcmxa r"^.- "nd «' a coiilral part < alwiut 23 cm. thick ; (/ ix tlie gneinn. The »wo Ifc-riMii i, lateral zones con,.«t of a verj- ',",',1.1.""'' unifoi'iuly Krnnular iiiixlure of ■ pyroxene, jihlogopite and apatite. The iii/e of the grainii i« alioiit 4^/f-^^-;^i,^_* ♦ t- + ►. ♦ I " 1 — -niui. ry;oxfiieiitii| luirH T "-;:"- -^-^---^^ -_ - present in about i<|uiil <|uiiM "■■"■"" " apatite ii ihown unilt-r the i »co\tti to lie (leridttUy Ics- in . tity. Kvidentiy it ix a uut agtjrejjate of tiniilar origin to that of tlif lateral pe typical scainilit.. gHl,)«,, i„ tin- case of medium and ctmrse-grained varieties, it is a rock of i ! .iraljv massive structurr and con8ist> of ulx.ut e their strike by a vein of apatite. AKain on lot fifteen of the eighth range of Templet..n are three veins, whose courses are respe.tively X. 40' W.. N. fiO W.. and N. 67 W., while that of the county r..ck is N. --'O" W. In «ome instances de|H.Mts which look like interHtratine plac- are here and there seen to give off lau-ral l.i, inches which cut directly across the strike of these rocK. . An example of this wa» notic lint i|ut^liiin iiiii to Im- A' to wh»i th««e ■pyroxraitM' Ml'. A portion <>f th«'in iin- i -1 iikUk mill ilf«iKii'it«'.. 1... II l.-ii,-. Kr..iit.ni. M,„„tx, I Int.; A, :.|..,i,i. ; li.ini -Vi'IilK' ami |ij fiX.'Ii-' m.iii II. |.VI-. Ml": •'. imillliV k'll.l", .-.all 1 ^..,,„j|,,, ||,c..rt,iilirilM'still'l(M k- imli u= T Ifi I. ^ , . 1 • « 1 i'\|M «'.l III till- iiiiiii» Are frr^li . griHTiUly, li-i».vii. lli.'y nil' riiucli nitin";, wliiTi iiy (.nreioulnily i» m>w foiiiiiiti.iii of MaiM.liti', lU tlir .-xi" n»i' "f till- MiK|.iir. Ii.i>< tiiki-n pin..', ^uoh Miipi.liti- uiilioro- oriil roUtoil r'nii" I I'lm- .-..lliiii'il un-l i^;.,;!';:!'!;,,*;;','^ HXiimiuc'd mitriwciipiiiilly fimn liu' N'liviisoiir, bmiliin. Kini'iaUl, Nnrtli n ..t i.i..|.i Star, I'tiinii. lliali K'kU ami fiowi. Hill lllln.•^ ami fnmi ihi- l'ou|Kire poiliilhi', ill >liort, limn aliiio.^t lU tin- apiititi' Ic^iilitii's viMiti-d, Tlit-y fimn nil anulo^'Ui' to llie stciipniite ^jalilim of Hoiitlii-ni Norway, with which also tiir otcuiifiico of apntitu veins iit coiim-cti' I. A tun version of pyroxt-iio into liinwn liornlilendf, as is tlii- ca-f in the Mj-called spotKii tiahl.rii from O.-deKanlcn, litiA not Ih'. n mot with to iny knowledge. The pyroxeiifs ute partly iiltered to yreeii uialile, but the changf seeiin to be indeiieiuleiit of the torination of thf i.ilU. npiitite veina. Another portion of the ' pyroxenite ' hiw farmed in the crack." them- ^J;'_|;™'_"''" selves, and constitutes mineral ag«rei,'ates, which, in general, arc of the Hame aj{e as the apatite. Such a uniformly fjianular asjureanti' o' pyroxene, phlogopite and apatite was mentioned in connection with the small vein at the Vavasour mine. The composition and structure of these masses is very varied. In some cases they can be distiiijjuish- ed from the unalteretl plutonic rock at a first glance ; in other ca«e3 tliey are extraordinarily like these, not only macroscopically. but also microscopically, being rich in scapolite, iVc, so that a dividing line between the two classes of 'pyroxenite' can hardly l)e drawn- This, in the nature of the ca.se, is not surprising. As eyamplefi, two rases from the Emerald mine may here lie mentioned. In the neighbourhood of the Belleau pit, and underneath the smithy, on the ■-!1 i I' 22 o OTTAWA TALLBT »ein». boundary of the Squawhill mine, the gabbro, whicli forms the main hj^m.^ '^"'* "*"' °* **** "''"'^ *''"' '■ intersected by pegmatite veini, which are widely diatributed throughout the whole region. They are granite pegmatites, consisting essentially of quartz and microcline. At both places the pegmatite is cut by narrow apatite veins, which exhibit a symmetrical structure, asin PeOMATITC the accompanying figure. The two outer zone.s about 10-12 cm. thick, sharply defined against the peg- matite, consist of such ' pyroxenite.' The central zone, about 30-40 cm. thick, consists iif calcite and apa- tite. The dividing lines between the ' pyro.xenite ' and the central zone are not sharp ; many crystals of pyroxene, very well formed, penetrate into the calcite, and in some places a gradual transition is found, caused by increase of calcite and decrease of pyrt..umlary between .iltered plut.mic r.xk and later form.-d pyroxenite. Penrose gives a number of .Irawiiig^ wlii.l, illustrate these relations very clearly. Without -oi„g into a special liescription of the individual occurrencs, -ertain i;nportant imImIs b.;aring upon the a.-nesis of these rocks may be itidicated. -Vs is evident from the literature already .[uoted, many authors speak Ap"f I'v.-s of a ' bedd.'il ■ pyrox.Miite ami apatif and deduce from this thec.nclu m!";,;',";!,,!^ sion that they are both of the same age as the Liurentian strata an.l belong to a certain division of these. I have In-en unable in any liM-ality to convince myself of this fact. That many veins are dev,'.|op,-,i as bedd.'d veins ([.agergange), in part lilling crevices which in strike and dip correspond with th.' gneiss, is correct; it is natural that many cracks should be formed in the direction of least resistance. As pro.>f of these deposits being of the same age as the neighbouring gneiss, a certain parallel structure in the pyroxenite and in the apatite masses oonnectefl with them has been pointed out, and further the fact that I- i; I ffl ■ If ; 2 ■ I.: ., \ f- "- M. ^ 24 OTTAWA VALI.EV never ili^tiiic Uy lieddt'd. no sharp liiiu of deuiarkation exints between these latter and the gneiss, that they pass o\er one into the other. As far as the panillel structure is concerned, T concur exactly in the view expressed by Penrose : 'Tlie pyroxene rock is ne\er fuutid ilistinctly Uddcd,' Ac. A paral- lel structure at all couipHrabie will) that of the ^inei.ss 1 lia\f never found. That many veins ('xliil)it ii laterally ^-yiiimetrical fornintion has already been pointed out in connection with the Vavasour mine. A typical exainjile from .Mud I'ny, Teiii- pletoi. county, as given by Har- rinfiton, is here figured. It i.s a structure wliich is very well known in the case of c a veins. When such a vein is deposited conformably between gneiss stra- ta its own layers must naturally be parallel with the cleavage planes of the gneiss. Another example from the Orant mine, also by Harrington, exhibits very regular alterna- tions of layers of apatite and pyroxene alxjut j-inch thick ; the structure, as Har- rington points out, reminds one strongly of Eozoon. It is ex- pressly stated that the piece conies from a ' vein.' Penrose • " gives the accompany- ing sketch of a pit in Kijf. 5. VeiiiKtone sli.iwiiiR iilteriiat» layers ef aiPiitite the nei"hbourhood of ■i\w\ pyrexellt'. ^ V\)i. 1. ■'. ( 'all-it, ■ ami iiiira. >'. Fine ^.Taiiietl liiit-a ill liialix- line-. « itli |'\ i"- \eiie nnil little apatite. <. l*yri'\»ne. ^'i-aniilai apatite, and a little mica, in tin*' scait-H. anMnp*d in \va\y litM'> in the cliivftien iif the vein. 'I. .Mita-iiyrovtne and tiiin lay, r- ('t' apatite, ealcite an<' niiea. ••] AIAIJIK AXIl MKA NOIMII (il- ollAUA •^.J O the KiiuTaid miiu,'. lltiv iviiit-nlly tlicr.^ iiv- \fitis in thi' |iyioxenilc ttliirli in places ilwiiulli- iiway, uiui in utli.-c iil.ii>s \vi lea out uiul ai(- l-l-i-;- -l-I-W-M-l-l-l-M-l-l-l-l -l-l-l-l-M-l-l-l-l-l-l-l-M-l-l-l-l-l-l-l-i-l-l -l-I-l-lH-l-l-l-i-l-i-l-l-l-l-l-l-l-i-l-l-l-l-l-l .|-l_l-i., _i-i-i-;-i-i-i-:-i-i-i-i-L-i-i-i-i-i-i-'- ■- .i5 ;^l»H,i-i-i-i-i-i-i-i-i-l-i-i-i-i-i-|.|-i J- l-i-l-l-|.i_l_ 1-1,1-1- 1-1-1- 'l-i-l-l-l-l-l-l-l-l-i-l-l-l-l-l ^_|_ 1-1-1-1-1-1- 1- 1- 1. 1-1- l-i-i-i. ' i I I I 1 I I I I I I 1 1 I - V'lif. ti. S*'Cti«'n ill ;( pit iif.ii r' O'lmitv. '.Ii;.-1h !■. ,1. A|i.-ilit' i; fi-.t." V.li' r:'l'! Mini- l!-...l.ilr. '.. l'M..:,.iM-; .. ]■,■]■;■<■:, . ' ltl:i«;. 1 mill ■ filled with apiiliti-. iind ;u' ma-is which was mineii. T ' "^ I, ' i '~ i H 1 I iT^r aia., Kip. 7. 0(i«*iiiiip in wi^t >iAt of a liill iit-uf Smith'?- iiiint-, ()."ii.. FioiitiMiac cniity. Ont. II. ('imiitrv Syi'iiiti- ; If, A]Kltitc, sf;l!i'. 1 llli-il - L'4 f.-.t. • jimnalily coiiiicclPil with a lar;.'e aiiatitc III' parailel dii-fi'tinn nf tlie>«' has nntliiii^' to do witii a stiatiliid u- >chisliise structure- For foiiipaii.soii aticther ligiiri' by Piuin^i- ' of a locality at !Sii;ith':? mine. Kiuatt'nac ci.iuntv, i> <;iv('ii wluiv .such iiaralU'l a|Mtit(' xeins cut the .syenite. In Plate IV. a piece ot' vein from the Vavasour mine is siiown whoso structure at first sight strongly le- minds one of thestieaky structuieof ' Au- gen-gnei.s.'^ From tiie description on |)age 19 it follows that it is essentially ditiV-rent from it, however. The iiuotation froiii Harrington mentioned on page 20 may In- recalled, according to which from such apparent 'beds,' fragments and veins run into the gneiss strata. With respect to the transition of the pvro.Kenite into the neiglihouiing gneiss. .\|„,iii.. lUlllllJ '\'I-Ilil' . 26 o OTTAWA VALLET or 1-Hther the w.mt of sharp tleinarcation liptween the two, the ociunences me veiy variuus. At the Vavasour mines there are veins which cut through the gnoisi and whose holders areabsolutelv sharply I'yrovvii'it'. "' ''*'''"''^- ^" "•;•«"• "O-"^' e.«.p«-Lially where vein formation of the nature iiit . ,'ii.i«>. of 'pyroxenite' iKiider.-i on the gneisii, the boundaries arc indefinite, and there is an app irent transition. This arise.«, as Penrose has already pointed out, from impregnation of the gneiMS with vein material. Later certain typical examples will he mentioned which leave no doubt that such a process has actually taken place. Plate V shows a \ ein granite from the London nune upon the spherical planes of jointing of which pyroxene, ti iiite, pyrite, and apatite have been later d.-posited. Similar ' leopard granite ' is found at Little Kapi.ls and the North Star mine. Plate X fig. II jrives the iriioroscopic appearance of a (luart/itc in which scapolitc, pyroxene, apatite, tte. have been deposited in cracks. It is dillicult to form an idea as to how far such a process h is taken pluce, as in the mines one sees only that part of the gneiss exposed whi-li was directly in contact with the apatiteor the pyrnxenite. At the North .Star, L'uion, and High l!cH;k mines, ,'neiss(.s were col letted wliich \wreall rich in pyro.Kene ; a very curious gneiss lik(,' agranulite an 1 rich in pyroxene, from the I.rt.ndon mine, will be .le.scribed later. 1I,av far this .■■mtent <,f augite is to be attributed to such secondary irapr.-njaion pinoessescan only .; determined when these crystalline sLJiists can W: rnlluwed along their strike to consider- able Jistiinces from t!ie ap.itite deposits. In what follows theref..re only such cases ,ire introduced .is admit of no d.ulit regarding such a process. Still other facts which point to the vein nature of such apatite deposit.'^ have been mentione.i by oilier authors. Thus, angular frag- ments ,,f the country rock are found in the veins. On thodump ..f t'le Murray pit, Ijmerald mine, I f..und fragments .f gabbro, as Luge a.s ones lie.id, entirely encrusted with apatite. The vein mineral, them- selves also exhibit occasionally su< h eticrustations. Plate II shows a vein fragment from the l-".!iierald mine : ,i pyroxene crystal alx)ut 3 cm. long and 2 cm. thick is surrounded by a coating of apatite about :]-i mra. thick, the whole being embedded in coarser crystalline red.lish calcite. Structures are thus produced such as are freipieLtly found in ore veins and which are called cocarden structuie. Further, urusy hollows occur, the walls of which are lined with well crystfiliized vein minerals. Hairington ' gives a .series of such occur- rences and mentions crystals of apatite a foot in length which were collected from su.h druses. At the Vavasour mine the workmen \*' ill llrllilr. ■il ,ll«ltltf l^|...Mt- |.r.. 1.:,1,1h. . !; ■J APATITE AMD MICA 50RTH OF OTTAWA ■27 showe.) me a piece of auoh a druse, the wall of which was lined entirely with little quartz crystals. When Dr. El!!i and I were viaitinR Hrowna' mine, the owner told us of such a drusy cavity which had b.-en cut into a short tirae before. All thesf peculiarities and the similarity in mineral content of all the deposits of ipatit.- in the province of Quebe.; known t<> me. l.a.J tj the lj<-lief that they are all of the same oriitin and younger than iheassofiat8dgnei8«>s. They are iKcordiii«ly true veins which have been formefl in the same way as all other ore \eins, Thi; Vfin .\[iHi'rnl.i. The minerals formin« the principal part of the vein tillini; ar • V, ;..„„iM.,als, pyroxene, mica (piiloijopite), apatite, calcite, and some feid>p,-ir ' )f less importance are amphibole (actinolite), tourmal.ne, scapolite, titanile, and various nietallic sulphides. Further, Harrinj,'ton ^dves a' Ions; list of other minerals, i.e. (luorspar, rincipally in such deposits as may '' " be said to be typically -eins, and which contain much calcite. Tlies. veins best exhibit the order of age as given in connection with the Vavasour mine ; pyroxene mica, and apatite are the best developed and, lK>ing the oldest, are found directly on the border of the vein (the contact). The crystals are usually dark gresn : the surface is rough and dull ; the faces, especially the terminal ones, often appearing Is though corodeJ>,. F.-O 1. ."nix" 4 W 0-97 1 iMi II. 4.S 24 2 ' ."» ;u 15.-1 >tii( ) (II.-. 12 Mk<) fill » Xa ( 1 i.-.w 2»-44 i-j 21 *1 24 HI 2n K..O r.ri)ss on iznition TiO 1 44 n 33 100 411 100(10 Under II are given the molecular proportion-s, calculated to 100, and leaving out the loss on ignition. According to these, the propor- tions are as below : f 'a< ) : (M j? M n Fe) <) 2.* .".S : 24 .S4 i-ik^flil o'****,"! APAIITK AND MICA NOltTII OK OTT.< WA 29 that is, almost exactly 1:1. Further, ((' K.MkMiiIO -•= 4H ;<7 (Al K.'l, »), = 2 H'( (K Xalj o = •):.<> and the molecules falculatn out as follows : 1 (HI (K Nil (Kr. \1 1 Si ( (^ = :i ■'■' ix-r Cfiit 2:l!i M« Al. Si '■I = ■) m; ., 1 .-.8 K.- f.'ii Si - :i sH I-.' Mn «'a Si ^ 4r> lit 17 Mk (\\ Si = 73 HI „ is.-, Ci Ca Si ( ►,, - - 111 .. The tilicii is for this ooiiiposition nlK)Ut 2 i:i luolerulur peiinnt too low. This is, perhaps, caused t)y the fact that titanic acid is present and was weighed with the alumina. .Vt any rate, this pyroxene is very close to diopsido, the pure diopside molecule, Mg Ca Sij O,,, requiring 55 55 iSK),, 20 'J3 Ca(J and 18 52 MgO. I'hlogopite is a second mineral almost invariably accompanying the 'JIJ'^^'I'V' "' "' apatite; many of the mines which wcio formerly worked for apatite iin-'iMiunyini.' beini; now worked for mica. The mineral is of several shades of brown, '''' '" ' varying from light brownish-yellow, through ruddish brown, to dark chestnut-brown: the most common varieties are about the colour nf dark amber. Ci'ystals are e.xtremely common and in part of gigantic dimensions (more than 1 foot in diameter). Plates 10-15 cm. in t'ia. meter are quite common. The peripheral faces arc always very rough and could not l>e determined with the contact gonimctei- with sutli. cient exactness ; sometimes twining forms are very common. Cleavage lamelhi' exhibit no evident pleochroism and in convergent light give a dark cruss which in the specimens examined from V'ava.sour, North Star, Ca.scade, I'nion, lirowns', Fleury's mines and South March did not open up to hyperbolas, at least the axial angle is very small. Also the inclination |fn|>itf fiimi Sinith .1 30 O OTTAWA VAUir filtered off. In the filtrate the Hilica ami alumina were preoipitatetl with ammonium carl«nate, the filtrate acidified with hydrochloric acid, the CO, driven off by boiling, the liquid neutralized with ammo- nia, and the fluorine pretipitated an calciun> fluoride by roeanii of cal- cium chloride. From the micas from Vavasour, Union, Fleury and Nortli .Star mines a heavy flocculent precipitate was obtained which when burned with the filter and treated with concentrated iulphuric acid gave a strong etching reaction on giuw. A mica from the Cas- cade mine gave, on the contrary, only a slight opalescence. The Can- cade mine is at present an abandoned working, that was only worked for mica, while judging frgm the material on the dump, apatite is entirely absent. No analysis of phlojjopite from apatite mines north of the Ottawa river is known to me. On the other hand iin analysis by Clarke and Schneider- ' in published of the phlogopite from South Hurgiss, On:., so well known on account of its inclusions and its beautiful asterism. Under I its composition is given : — I. II. ^'^h ;«• WJ 40 24 I'l'^a "■■•H o-.Vi Ali »-n 7 r,: !'"•■" iiifi 21.-, M|f'» 2ii'4!t Zi-"! B»<> or.2 ^a'» o:i^. ^'"yO irm Kv. '.'.."..'.'..'. tmo Ti't:ll iHCtU) — O !M il'.l IKi Under II is the analysis of a phlogopite from the apatite veins of Oedegarden, Southern Norway. - * Unfortunately it is incomplete, the determination of the alkalies being wantinj;, but lithia and fluorine are probably absent. Analysis I is that of a typical phlogopite, but the silica is just a little low. The small (juantity of iron and the large quantities of magnesia and of fluorine are, however, characteristic. The last allies .XHATl-tE AM> MICA XoliTII (.!■ OIIWVA •M O the mica cicely t-. t).« lluor mic«», /innw^Mite an.l lepicl.,lit*. CUrke and Hchiipider ciikulato for it the t'oiimilii ; AKHio,), Mk K II, . AI,(Si...), M^ K,.\!tfK.i combining tl.e TiO, with the SiO„ th- Fe.r. with tho Al O th. F,-0 and U«0 with the M«( ) ««.! the Na ( . ^ ith tl„. K ..O. The'. „m position calculated from the lonniiltt au'.Tfs with that found upon analyHLs very well. A calculation of analyses I and II for purpose, of comparw-m gave, in nioiwular proportions : I. II. iKv.MK'liaCuM) . WHO II li;-«4 W.l\ (I liTiC II 1741. I) iMs;; Cttl.ulated to molecular percentage,, thf dillireiaos are, ot eour.se NUialler. ' The much discu.«se.l inclusions which cause the l)eautiful asterisn. in In the mica trom .South liurges.s are e.xcellently vei. in the micas from "" ^orth 8tar, Union, Fleury and Cascade mines : the n.ica from the -North Star mine in particular contains them with relatively very large dunenaions and of great l^eauty. These inclusions were fust dcscrilKnl and figured in detail in the mica from South Hurgess l,y ie ini'luitioim uijret'M very well with that of the incluMJoiii ob«prveil nt the Nortli Httir mine. ItoMenliusch- ' mentions in thme Ckinuliun iiiicitt, rutile nn« of M »nd cauin aHteri<.li neeilles were observed more than 1 cu). long, and of a lliickneRH which under a mHKni'iyinK \'ovrr of 70 apjieared to !»• ei|ual to the crosN liairsf in the eye piece (eye piece .1, objective ".', Fuen".). HometinieM thcv Hwell out. i-sjiecinlly towanis the encU, into a we'ini:f'inn' ill APMITK \J»I» MHV4 NOHTH OV oriAtt* 33o illuiiiinatiun with i.itiiriHrjr lixlit t\wy kiv |«aI.' Nfwtoriinn colour. ; Im- UUhI iirul >(u»|)«!mlwl in wnter.tlu- iiitorf«rfii»ll.v the lon^piit ; xoiiietiiurii the «iviiter nnd KiiiietiiiieH tlie lH»»er elMticity in in thindin-ction. Ihw iK.utidiim lin.n »re »'Xtni.»rdin«rily .harp, hut i.ot very l.rcmd, mi thiii ih<' r.'fni.tive index cuniiot \>k much «ri'.itPr thnn timt of the mica. LittI*. ii.edU-H whii'ii bv u nm^'niticiit ion of ;iUO (eye piece .1. ol.jc.tivf 7, Kues. ) appear, ed hardly thicker than one of the cronii h«iiM, were .till tian.parent. It is therefore v.ry unlikely ihni they are nitile, hs i, imunlv .up pix side«l etched li;,'ure« : in place. where the mica ha.s lieen eaten completely thr<.UKli,the needlis r.'inaine.K)n M»r<- the hlnst lamp they Ixcome cloudy and by reflected liKht dull white, and suspended in water exhibit no eflfect upon |Hilari!ii-d lij{ht. Piot. y^ Jannasch in HeidtlberK had U-en gOKl .iiouKh to make the followin!; "' ' report upon an inve.tiKation which he made up_o_3 ' iiiiiiiiatioii noliii-ioiiH cti. I ! S4 e OTTAWA VALLKT iiMeri|itHHi it|«tit)- • ryiataU. of Aiialytaii- 111 I anuiliuii .i|':ititf». I H 1 |i I -Ii :!j H *v\»tmx* U moeh too •niall to chamctorixe tb<- liodic* (ound. K\i- atiiclj • iniMnI conUining miv Mrthn i* prcMnt. A r.iore fXMt in vMti^Mtion with ■ulBoiant uiat«ri»l I consider to b« vtry imporuiit, if you will (uppl^ DM* with this I Khali be n\tA to carry out an auljmii.' I'poa lieioK farther Mked whether the rare earth could nut be Tio.. nlone, he replied that it could not, ax the H,(>, reaction was much tiK> weak. I am now buay iM>lating a larger quantity of incluaion* from udclititional ipeoimena of iiiioa kindly lent to me by Dr. i>aw«on. AiMtlu tryitaU are gi-nerally found in vein* rirh in caloito ; they alway* exhibit a iiimple form « P | 1010 | P | 1011 | : the bainl end fncei I have never Men here, while they teem to be generally pretent in ■•peciroens from Kenfi^w. The edge* and oorneniare very often rounded, which ii referred by many authore to the action of wime Mlvent. I have examined nome luch cryttaU without luccets for i»uhed riijure*. The colour in generally green, light graw-green to (lark blue-green, alio bruwnish-green to brown. The maeaive portions are in part loamely crynUlline (sparry) and exhibit a fairly perfect rieavage. The cryitalu aometime* atuin a length of fievenil fet-t : from ••ome pocketi in 'pyroxenite,' maue8 up to 1,000 tons in wpight have been found. A curiouD variety i« the nugar-granular apatite : it conti.HH of a tini', aimoHt white, aggregate of apatite grainx, in pui't xo .«oft i.« to I* rubbed olT by the hand. Under the micmscope a variety from the Little Ilapids mine exbibitH irregular angular or rounded forun, pretty evenly nized, and among them there is n very little pyroxene :ind calcite. A o'liesi of analysis of Canadian apatites have been puliiislieil l)v Hoffmann ■", Carnoi ■", and Voelcker-''^ : 1. II. III. IV. V. VI. VII Mil. l.\ '■."• ♦ti .t; 41 IIN :t!i II.-. II 11 •0 s7 (II .•■'.' 411 M • 1 .--1 11 lit 1 ■ . . . . n m :< IT ;< 7'.i :t .sti :i 7;t :< : 1 ill 1 17 (•! II II n -.111 II IS i: i'l II 4;< II if.i II m II ;t7 4-.' Cm.. II ii^< ii:iT II Id II '.•.; 11 II Sli II w> ■•■.•m •-• :i! ( '.»' '. . 47 .h:! 411 Hi 4ti :w 4!t :m «.>< 4H 4!l >M 111 10 .V.' mi .V.> IK) (■( . . :i ::t 3 MO 4 Lll 4 -.Ii 4 17 A liO .•i 7ii — .M,f<'. II 15 •» rr. (I .Vi I.H ii; II L'l II iiL> TniCf TI-..C" \^" (1 lii II 71 1 I'.l II .-.7 X* 0-.'7 II .-.7 r - 1 » 111.-. i:i 1 •.II noil II '.11 II IM II i:i II L".'" :*)> h - .;. . :i .<:i II ;t7 ;i I'.t iim; 1 i."i 1 r,:i II K\ II :.i U, r»i>ir> li, l..Hii.|ii|, ,,f ,Hi..rriMi(H.i, ||.>|f.„iiim. in IV. V. VI. vn Vill i\ liratil mini, t>>Hn«lii|>ii( lliii:kiiiKli,iiii \"i lii, riiiiK' 3, t'i»o»hit>i>( X,.tfh IturK... .. Kili'liir liiitH. tlii|iiil I'oiilniirl l"I Itl.fHlllCi' I'l, t.i»li«hi|i..f Irf.MKdl. 111.1111(1 • Watt- until-. tnHii.|ii|.i.r r..rtliiriil • il-ctor ■ I'll. Imhii»IiI|> i.( Tiiii|.li'l..ii Inn.r (wrl i>( u clurk gpni \:< II '.I*! 1 ri' .1 .1- lt«» 1;. tlltl :,n \ VI \ll VIM IN \. " Ik; It '1;; T ;*• -J \s L' HI 1 ."il 1 (17 11 i;< II m; II .'.N II *>t; •1 It lU! *.ts !i».t s-» Ml .,- Kviiieiitly all the analyxe^ liuve not l»««en iimiie upon iiiatfriul fiei- m fiom inclusions. Thf difteicnce in t\\<- amount of tluorim- in the first '"_ >even Hnalyne* to that shown in thoiw followint; in reinai-kulile. ("er- >!' taiiily in these fir»t ones the detvriuinations are too hiKti. Since pure tluorii|iutite tontains only .'t-TT I', it is inijKjssible that :» 79 F in analysis III witli an insolulile residue of .'I^U can be correct. From the 4Uiintitie.s of F and CI present may I*' calculated : I II III l\ V VI \ II VIM IN \. \| • 'iiK. li sii 7 1:1 T Ts 7 '.';t CiCI, ... 11 lili II 41 11 71 (• 'M< f'iiK.iii m '.i."i !i| '.Ni The Canadian apatiie.s arc therefore distinf'ui^'hed by a very high pro- portion ofHuorine ; in part they are almost pure tluorapatite : the {■ropurtion of fluorine moletulf to chlorine molecule is always i;reater than 4:1. The same is true of the apatite in tin ore veins and of the apatite and phosphorit«> which are also vein formations, partly in granite, in the province of Estreinadura, in Spain. In contrast with this are the vein apatites of southern Norway, almost free from tluurine. In twenty crystals from Kr.isjrr.H', Voolcker couid not r.-toi^iiiat- fluorine. 1 2— 0-3J Ulltllv>f'»MOt ■•* fr.»iii ill i»i'>n-. A: 1 i i; j * ■ s I ' 'i' 36 o OTTAWA VALLEY Vnlcit>- is,ii8 has already been stated, always the latest formed iiiiiieial in the veins ; 1 have never seen crystals, the mineral forming a coar>e- grained moat!y reddish coloured aggregate in the central part of tiie veins in which the finest apatite crystals oc i:r. . It is peculiar that many apatite crystals possess a nut-' os ,,-; . nioite. This may be explained by the former mineral havin . a s!>rt of sk^'letu,' growth and the resulting cavities having been fillp'. up i iter witli c« oite. Kel' pi'ncnces of apatite. It "Irm'u" witli '" ^^P^^'^^'y * grey-coloured microcline, forming coarsely crystalline aiuitit*'. aggregates which in many places cover large surfaces nf the walls of mines. At the Cascade mine I found crystals of a plagioclase exhil)it- ing the facs OP | 001 I ocPX | 010 I y. ?' I 110 | y. ' ? I 110 I crPj I 130 I ^ 'P3 I liTo X 'P' 5E I 101 1 P, 111 \ 111 ^ Cleavage plates parallel to OP and r. PvS give extinction angles of .V and ll-Iii re- spectively; it is there- fore an andesine of the composition Ab , An... The cry.stals are elongated in the direc- tion of the a axis. They are about o cm long with very rough surfaces. Fig. 10. They are supportetl {>ai'tly upon compact pyroxen- ite, partly upon a net- work of small pyroxene crystals. At the Vava- sour mine I collected masses which consisted of a coarsely crystalline microcline, a light-green plagioclase, and green pyroxene. The single individuals are some- Flc. 10. -Feldspar friim the OiscikIi- .Miin\ ^- a „■ j- times over 8 cm in dia- meter. The plagioclase has on OP an extinction angle of almost U . and "*""■" APATITK AND MICA VORHI OK OTTAWA 37 O b therefore andesine. Harrington ' mentions also ortiiociase and allute from the apatite reins. Am))/iil>ole was sefn principally at the Little Rapids mine in masses compose■> ^:, V> .<):> 411 MiiO tn..v. Call !i i«i \a,.(J s :i: K,6 1 l:; CI 2 41 SO., (1 sc. H.^i) (riiliibil»il) .... . . T- H_,(> (li.\(fni«'cipic) II 14 I'NI 4i< <> II :,:i 'riiiiriLialiiit' ulllllllllUlt. ScaiH.liti- iTy»tal». I.! ill This ^-capolite corresponds pretty closely to the composition Me, Ma.. to Me^.Ma.,. Microscopically the mineral is found to lie •■.xtraordinarih widely distributed in the ' pyroxenite.' M'laUlr miwrn/.y are represented by pyrite, chalcopyritp and .M.-talliomii pyrrhotite. In many pits of the Kmi-rald mine the pyroxenite is r.il" penetrated through and through with pyrrhotite and pyrite, and the niaterial on the dump is coloureage parallel to oo P, there is a less perfect one parallel to « Pi ; the lamellar structure of diallage, however, is absent. Small leaves of mica have formed in the cleavage crack.s of the second order above mentioned. A slight alteration into uraKte, beginning at the edges, has taken place. The rhombic pyroxene is less abundant than the monoclinic. Its sec tions often have a rude prismatic development. It is colourless and transparent, but in thicker sectionsexhibits a slight pleochroism between reddish and greenish tones. A high relief, due. perhaps, to its fibrous nature, its very low interference colours, and parallel extinction in . sections trora the prism zone, enable it to l,e easily distinguished from the monoclinic augite. An alteration into a green serpentine-like mineral, perhaps bastite, has taken place along rough irregular cross- cracks. Inclusions of little opaque rods are verv common, and are arrangetl in rows parallel to the c. axis of the host. The mica is transparent with a reddish-brown colour, and in con- xergent light appears to be uniaxial : the pleochroism is b,.tween straw.yellow and red-brown. The detection of Huorine in this mica was of special interest ; if its formation is secondary and connected with that of the apatite and phlogopite of the veins, it was to be expected that it also should contain fluorine. In fact, the carefully puiiried mineral gave a strong Huorine reaction. Apatif in rounded grain'* i^ fairly abundantly present in the rock. IV. Dittrich made an analysis of this enstutit^-gal)l)ro. Material was chosen for this purpose which was free from tlie above mentioned o».«.1 APATITE AXD MICA XOHTII OF OTTAWA 41 o mica reins, und which, tlierefore, containe.J mica only iti verv snmll quantities : '■ II la. «'•>= v.'-.:-: x^n; -,,,- T;"; " '^ :iT"im,|.,„..) n:y ^'^ " '•'•« y-^-^-' s,,, »•••<» 77.; i" ■•■' 7.;^ >'"•> II 1." 7 -• 17-. t''"'^ n 7:< i; ii" ,.'.,'- ^■''■" :; 1-' I 70 ■' ,-. *^'* II-' (.:«! 07^ [>"' "•"'• . . ,..« "■*' '"'•< "71 ll..",.„i::.) LO.; SI) !•!' ■■'J IK.Ii-, For compaiison the analysis of „n olivin? liyperite froi.i Lofthus in a„ u .Snaruin has been given under 11., asatype of thegabbroaccompanyii.j.' ''■•"l-"'i""n.' the apatite veins in southern Norway. la. gives analysis I. in molecu- lar proportions, calculated to 100. From it may be calculated -^ '• y ■■< r f ^11!' 2 Mi ^■-^ :ir(il i :, -j ■ „, ;, and the formula s, , a,.,, c.,., f, n,.,. Tlie rock therefore belongs ijetween the types Molkenhaus Subiteluia and Keewenaw. •.viih which the silica agrees in a satisfactory manner. It is on the boundary of the '/ and /.' serie.s. As a\ erage plagioclase we obtain Ab,.,.. An or almost Ab, An,, which agrees verv well wit' the specific aravitv L'-694. ■ f rt J Another very fresh gabbro was obtained from the smithy, of the,;.,,,,,, ,, Kmerald mine, lot IS, range XII. This uniform rather coarse rock ^yni'tiiv a"" al.so consists of almo.st equal quan, < of very fresh pl.igioclase and ''■""'■''''"""• pyro.xene, but mica and rhombic pyro.xene are entirely wantin;;. The leld.spar commonly exhibits undulose extinction, with bent and cracked twinning lanielli.', probably pressure phenomena. The augite is completely dusted through with tiny inclusions, which l)y employing an immersion objective are seen to be liquid inclusions with movable bubbles. The formation of uralili' has gone .somewhat farther than in the gabbro I. ^.n Murray's pit. Sulphides and ipatite are scarce. A gabbro from the dump of the Squaw Hill mine contains large (juantities of red-brown niicii : these works are on the same hill as the Kiueraid mine. It is distributed very evenly thn.sigli tjiis wmewhitt if i ie seen with the unaided eye, fresh feldspar with twinning striie, some brown mica and a good deal of augite. PlagiuclaKe and augite are present in about equal ijuantities. The hand specimens which were collected from the mine on the contact against the later-formed ' pyroxenite ' and other vein fillings exhibit a somewhat gneiss-like appearance. Augite and plagioclase are arranged in lenticular masses, so that the surface on the main fracture has a light and dark spotted appearance, the cross fracture lieing somewhat streaky owing to the alternation of the lenticles ; the grain is also somewhat finer. At the contact with the pyroxenite the rock is completely penetrated liy honey -brown titanite crystals and grains and is very rich in pyrite. The rock from the railway line shows under the microscope an absolutely irregular structure, neither plagioclase nor pyroxene show ci-ystalline boundarie.s. Cleaxage lamellae of the former give an extinc- tion which on P varies from 3 — 13° and on M from 7 — 2.i' ; it therefore belongs tu the andosine-labradorite series. Even with the magnifying glass it is seen that many of the cleavage faces are bent. Under the microscope, undulose extinction, bent and broken twinning lamellie are very common. The rock has certainly sufiFered great pressure. The pyroxene is transparent, of a light •rifen-gray colour ; pleocliro- ism is hardly perceptible. Sections normal to c exhibit, besides the cleavage parallel to the prism, well developed cracks parallel to x Px and very numerous fine cracks, parallel to x Pi , running only short distances, so that a fibrous appearance is developed. (Jne optic axis is almost perpendicular to this section. Polysyiithetic twinning according to oP is very common. The formation of uralite has gone quite fari proceeding from the cracks parallel to x Px and those connected with the tormation of the aljove mentioned twins. Lamelhe converted into uralite often alternate with others of the unaltered mineral. The uralite is green and shows relativelyweakdifferencesof absorption, the pleochro- ism varies from light greenish-yellow to light grass-green. In a section iiimost parallel to x Px l\>v augite shows an extinction an^ic of 39 — liu M'ATITK ASl) MICA \ORTH Of OITAWA to O 40 , the uralile 15' ami in lx»tli <• differs from c in the same sunse. In the cleavage CMcks and the separation cracks p.iralU'1 to oP the siiiiu- rod and plate-like inclusions are found as is the case of the hyperstliei.e of St. PiiuU island, only here tliey are scarcer and not so remularly dis- tributed. The mica forma little plates which collect into small knohs or are .Min...,..| arrange ' «""■ f'"' ' have b.!en derived from the uralite. Small plates of mica are groiipeil """"' as a fringe around the hornblende roome- what darker in colijur and more strongly pleoeliroic than in the rock from the railway cutting. It contains the same opaque or red-lirown transparent inclusions. Besides an alteration to hornblende, epidot«! is also widely distributed. As has already l)een mentioned in the macroscopic description, titanite occurs very abundantly, the pymxene slightly predominating over it. It is strongly pleochroic in al- most colourless and reddish-yellow tints and frequently shows (lolysyn. thetic twinning. The very coTiimon pyrite has also Ijeen mentioned above. Evidently pyrite and titanite, and perhaps also part of the feldspar, are here alterii*ion products, whose origin is connected with the formation of the ' pyroxenite.' vvn Hill mini'. MiiTOHcopif tinh. .1- III. 44 c OTTAWA VALLEY one nnotlier. Tlieir tliklcnesa u so Hmali that they are usually truniparent. In isolated thick ones high doublt- refraction and parxllrl extinction are evident, and it is not improlMtble that they are rut le. The pyroxene, transparent with very lixtit green-gray colour, is to H larjie extent converted intouralite ; the uralite has, in placet, l>een converted into luica. Opaijue metallic grains are surrounded by ieu- coxene edges ami are prolxibly titanic iron ore. ishnnhiHxt'- from ihe Crown Hill miw. — This rock which differs chemically considerably from the pluton-'c rocks already described, is found in a small prospect hole on the river side of the slope on the line of the wire rope tramway, built to transport apatite from the Union mine to the Lii-vrt' river. The uniform, medium to coarse-gruined, unaltered rock is very rich in dark-coloured constituents, in which dark-gray pyroxene and to a less extent brown mica can be lecognized macroscopically. Feldspar is present in very much smaller quantity. The structure is that of a typical plutonic rock : all puruUel structure is completely absent. ()ne would conclude from the macroscopic appearance that it was a micaceous gabbro or basic monzonite. Under the microscope none of the principal mnstituents exhibit idiomorphic outlines. The feldspar is almost absolutely free from twinning lamellii' ami is u typical microperthite ; extinction was deter- mined on some cleavage lamclhc, on OP parallel, on x P ob as 7". The little plates between crossed iiicols get uniformly dark, probably on account of the extraordinary fineness of the intergrown lamellii-. The optical liehaviour, and the strong predominance of potash over soda in the general analysis make it certain that the principal part of the feld- spiir is oi'thoclase. < in cleavage faces parallel to ac P ot the inclina' tion of the very regularly penetrating reads to the cleavage cracks parallel to OP was 74-7o' ; on oP they lie normal to the cleavage parallel to a P v.. The plane of interposition is therefore an ortho- dome, which, as in murchisonite, corresponds approximately to 7 P ^ . .Many feldspar grains upon strong magnification exhibit in their peripheral portions an extremely tine twinning striation : perhaps this is an anorthooiftse. A lime-soda feldspir is present only in very small (|uantities. It is, unlike the unaltered microperthite, always filled with alteration pro- ducts in the foi-ni of stronjdy double-refracting threads and plates. Tiie augite, transparent with a very light green colour, do«>s not ex- hibit ;inythins reiuarkalile : it is in the first stage ot uralitisation. Part APATITK AMU MICA yOKTII OF oriAW A f. of the green weakly pleochroitie Imniljli-nili' is (.ertninlj- juinmry. llie micii is fre.|uentiy intergrown ri-gul,irly with the hornblen.ie mul then no doubt partially d«rive(l from it. If h larije hornhieiKJe section in rotated till it is dark, a number of fine lamelh.-, strongly doublv refract ing are seen parallel to the cleavage cracks, which imiy, ufx.ii hi^h magniticatiori, Ikj recogniml ax micii. The mio.i iilsci surrounQ> the hornblen-Jp and extends into tiie cleavng,. cracks and fnictures. Un the other hand, larger mica plates arc certainly primary. As acces-oiy constituents titanite and nietallie minerals may b.- mcnti.imil, the latter on account of their behavi.iur in rellecte.l light seem to c.jnsist essentially of pyrite. An analysis of the rock was made by Dr. Ditti ich. In spite of the An.ilv-w ..i fact that almost all th.' deterniin.iti..i,s were m,ule in duplicate with it" h'un.l* nearly identical results, the total came to '.INCO only. At my re.niest examinations were made for fluorine and clilorlne ; tlii'rine wasab^icnt, and chlorine present only in traces (not more than 01 ». Wheiv the loss is cannot be guessed. I. III. .SiU- ,s Titl^ „ Al^r |;t hV.O -2 K.it t Mk<» s <'a(» |.., I so. 0- l:ll 17 s.-| 111 .\; i« 711 . •J W 1 I'lii !:t L't 11 ;tl K' ;«) •-' 71 ;i 'il •.' '■>' 2 ti."» > 1 .*( ,'( 7!l .'» tis ti .*i»: M 1)11 14 -M 1-.' l:) u 4L' ;; -.» i 2 .'► *'.*> 1 :,x 1 1!) ■J l-J II til !• 71 II L'll II •-•:! Mm Hi '.-.'.Mndii TA . . . r.iiheline-pyroxene-malignite from Poobah lake, VnalyM, i.n Rainy River district ; No. Ill, theralite from Kunjokthal, ri.iptek '■""'''•"■'■""■ Kola ; and No. IV, shonkinite, from Yogo Peak, Little Belt Mountains, .Montana, have been introduced for comparison. No. IV agrees liest with No. I both in alkalies and the proportion of CaO to MgO and FeO. No. II is poorer in FeO and MgiJ, but richer in CaO. In III the proportions of alkalies are reversed. Undoubtedly the rook from Crown Hill mine belongs to this family. A reduction to mol.cular perctintJige.s (all iron calculated ns FeO) gives : Hi 1 i ,. I: in 46 OITAttA VALLrV sin Btt 4H TiO «) A'> Al,0 !• ft' K.(» •1 ;)M Mtrn . 14 :» <•«<» ... II i;.'' N:lj«> .. 1 v K U . ."i '.••• I'.O. » (•» tim ID) Consequently A y.id : C = .SaO ; F Jl»06 ; a -> .» : c > n ^ '.''4 giving the formula «..-. A:. C.-, V,.-, N..-.. i:. ; f l.--.^; The rock i* very .similar to the theralite type Kunjoktiial, tlif> Hilioa agreeing very well also. Th** pro|iflrtion of nikaliea places it in the E series. While the rcicks descrilied contain much feldspar, ^eini occur in the t;neist near the l^undoii mine which are very poor in feldspar, and which, I believe, in part at least lx>long to the same category of plu- tonic rocks. Tltey consist estientially of augite a;>^ri>.>'«n t7e« in th«! sernte of the petrographic nomenclature {irrhgterxte). The colourles.s and sometimes al8o weakly pleochroic en.statite forms roughly outlined prismatic crystals and is always older than the monoclinic augite. It exhibits the usual tibrous te.xture, parallel to the c axis, across which run irregular wide cracks in which the alteratiun into a green alteration product begins. The aui^ite iloes not show any peculiarities wortli mentioning. The sparse plagioclase tills up the vacancies between the pyroxenes. The red-brown mica is, jml^'in^ from the whole manner of its occurrence, a new foruiatiiin. It de>el : 1. Pure pyroxene tiggregutf*. 2. Pyro'xenephlugopite Bugn-gates. 3. Fyroxene-iiptititv aggregatei. 4. Pyroxenp'Hcapolite nggrngatev. Ilctween theiie groups there exitt, ot voune, all iioxHJble tranoitionH. I'ur. ,,\,..^,;, Hen-, therefore, only certain type* can be d.alt with. .min-u;.!.- Almost piii-f jn/ro."!w agijr'ijatt, hiixe lieen olitained from the Brown. Vavawiur, Kittle Kapids and Sijuaw Hill minen. They , 'e rather coarse, i|uite irrt^ularly arranged raanses of light Kreen. '.ray. or re4. also at the C/ascaue mine ; they contain almost equal quantities of mica and pyroxene. In the .specimens from the V'avasour mine, the latter is gra.ssgreeii, alK)ut the colour of chrome diopside, and tonus a loose granular mass, partly crumbling Ijetween the fingers, 111 this occur yellow-brown phlogopite plates, mostly arranged in u parallel manner. Contact .sjiecimens show that the cleavage planes are normal to the Iwriier of the viin. From the gneiss in which m IM o OTTAWA VAt.l.KV Wl Aii^itc ('III' KU|Mt.-., ? 11 ^VIn^.||;t. fiuiit Inluii iniikt'. thn vein oci-ui-M, tliU iiia«i» it loiiiti At<-m that HUch a Immliil structure hni nothing to do with the piirallpl itruoture of the uneUn ; farther, the contact with tlm KneiaN iii abwilutely nharp. The iti/n of the graini "f thit pyroxeno phio|{i>pite mixture is very uniform, rtliout O.") cm. diameter. The nugitf in the apecimen from the Cawiidc luine it ttoniewlmt lUrker, but in mi-tionn ii aInuMt colourless and trsniparent. K\ery wheiH it iM iM-en, frtini the way thi' |ihl(iK<'ptt<' plittea are wpdijed in Iwtween the pyroxeni-. that they are youn«i«r than the latter. other augitc phlogophite n){gregates from the Viivnitour mine exhibit a very peculiar itructun*. The light grey-green pyroxerif forniH large, roandes (augen) several centimeter!) long and generally muoh eIongiktepite, and Nome Hne grained uugite. Platf I v. ahowH such ii vein masv. The lonticulitr -augen' are all arrang- ihI with their longer axex parallel, to that upon tirst glance there scemn to be a similarity to the structure of a foliated augen-gneiM. The pbli> gopite plates of the interp(«en it lies, with fairly well derined Ihiuu- ilary, the central portion of the vein material rich in calcite. Another peculiar structure is exhibitel by pyroxenite.s from the Fleury mine. In the main mass consisting of pyroxene, are embedded at distances of 2 3 cm., roundish lumps rich in phlogupite and also con- taining some calcite. A tranfition to the next group is repi-esented by the widely distri- buted fiyroi-'w-phttHjojiititajiatite aggregates of the Vavasour mine. A type of a ' pyroxenite ' consisting of inujit- and n/mlile I obtained from the I'nion mine. Plate III shows that the pyroxene is without sharp cry.stallographic outline.s, and forms rough prisms arranged parallel, about 5 cm. long, among which is a granular aggregate of green apal.:*e : the whole arrangement reminds one of flow structure. In sections, the apatite grains are seen to be penetrated by dark stripes which upon higher magnification are »een to be closely aggregated tube-like fluid inclusions. In what relation the position of the pyrox- ene stoo OTTAW \ 40 />■».>•,....,•»/..,/,<«. „;,y,.y.,f...—T\n» i.,u.i|. !.n.K „\..r int., ih,. „1. ISr.A.,,, te,H,| ;(*t,t.ro«. A .l.«r|. .iiwM..,, l,^t««.i. tim t«.. „, ,„ Im* iil.e.wly :;;,',Vl;';,'. . I.»pn |,..inle.l (Mil, imfK«,il,le, », » lnr«». |»,rtioii ol thp i.irtti-rinl ha.l fo l>»..illeae.l In.m 'lie .lump*. rnt..,i k f..r «uoli ii .livi-i.,,, „iiul,t ,m xoiiijlil in thi- method ol' «Kviiri»'iic»' .in.l in tli.- iiiiii.,..-.,|(ii-,,l ,tiu.iur<- ■>f til.' pyn.x.'rip, (if ..nn ini;:lir [....tulat.- timt l,y i|,.- Mafx.lili.inj; ,,t" tli.. j{nl.l,r.. tiiJH niiiutral Imil ii..t i^nn . ....ntiallv clmitg.'.! . ,„„i i,|>., in h,. MmL'tun-fif the whol.. i.ih--.. |!.,ih .■„i„i,lt.ii»tinii-, howevri, U'li.i t.. no (Icrtiiito rPHulfN. In nio,t ,«..s mi-icc Mri w«s th.. nine witli tlic iiiitfit.' iin.i |.|.i;.'i.Klii»f in thsalM.ve n)..nti.iiir.l |,lut..nii lo.k.. Oofftsjon lUy wIimi scnp.!it« .- li.lily r.'i.ivM'nt.-.l thiTe in ,|.-\,.1.,|)..,| ii Imn.-yo.ml) like siru.tur.- wlii.h in aobenuiifully.)lMerve .iit pcyniatit.' whiiji in it- tuiii iwcurs as veins in L'al.hi'o an.l itn.'iss. Th.' .■onlni't of the oiiur /on.'s ,'ij,'ainit the peymatife is ah,«.lutely sharp. lioth a«i;r.'L.iites i«.!.Hess a li^ht i eddish -ray ciour a.iij .'xhihil nil. ro-i.'..pieally, hesi.ies the aui.'it.', only s„mii- ;r;,en apatite grains iinil soni.' pyritp. The s.ip.,iiie is (irst seen under the micros, ope. Mere th.' distrihuti.m of the tw.i prinoij al c-.mstitiientH is set.,, to he very irrejj'ular. Some portion- of th.' se.-tion .-..n.sist almost .-ntirely of the c'olourl.'Hs transparent auu'i"' with littl.- s.npt.lite, in other.'* the latter distinctly pre.|. rainatev. |-r.'.|u.nt!y it forms iar«e n.d like individuals in \^•hioh aui.'ite grains are p..ikiiitically . level. .p.d. I itiier portions of the sections exhibit l...th inin.rals in almost e«|ual .|u.intities in the form of e.jually larj.'e ;.'rains Koimd.,1 l.y straight lines, so that a lioneycoml) pavement-like structure is pr.duced. The s« I I I III V, 1/ piutooic rucks. Scapotite nbbro itom Vavaaour mine. 90 o OTTAWA VALLEY sections and the optical oriR'itation of the longitudinal sections enable one to distinguish it eoxi) , from this mineral, however. Phlogopite is also found in varying quantities in this augite scapolite mixture. Altered plulonic rocks and ' pyroxeniUa, ' in part, cQtuuting ensentialfj/ of augite and scapolite. To the above described mixtures which on account of their geolo- gical occurrence are certainly to be characterized as vein formations, must be added a large number of hand specimens collected at almost all the mines visited. They are dark-gray medium to coarse-grained mixtures of augite and scapolite of completely massive appearance which mocroscopically exhibit the greatest similarity to gabbros. Under the magnifying gloss one sees that the colourless constituent does not possess the good cleavage and the twinning striu' of plagio- I'laso. The fracture is irregular, often fibrous, the lustre more greasy, so that this is probably the reason why many authors mention the frequent occurrence of quartz in the pyroxenite. Generally, as has already been pointed out, the microscopic examination reveals no traces whatever of the genesis of these masses. As everywhere the same relations are repeated, only certain occurrences, which I hold to be undoubtedly altered plutonic rocks, need be here described. Scapolite gahbrofrom the Vavasour mine. — This is a somewhat coarse- >{rained rock. An)ong the darker constituents hornblende may be recognized by its good cleavage. The colourless ivineral may without ditiicalty be distinguished from plagioclase under the magnifying glass. Its poor cleavage, and a somewhat greasy lustre remind one of nepheliiic ; it is frequently fibrous in structure. Pyrite is widely scattered through the rock ; brown mica is found only here and there, but in plates nearly a, centimetre across. Some epidote can also be seen raacroscopically. I'nder the microscope the light green-grey transparent pyroxene is seen to form irregular or roughly prismatically outlined grains wliioli, as in gabbro, are often collected together into little lump.s. Kxterr>ally and along the cracks, the augite lias become altered into uralite and here and there into epidote. It is also very noticeable here how it is eiitcn out like a sieve, and everywhere scapolite and phlogopite have been formed in thfe holes. The latter is "een by fairly high magnification to \m wedged in between the augite in the cleavage cracks in long thin plates. Fig. I., Plate X. APATITB AND MICA NORTH OF O-TAWA 51 O The quantity of the scapolit(> seems much greater under the micro- scope, because alteration having liegun and the mineral having thereby become opaque and dirty-looking it is difficult to dixtinguish it macro- acopically from the augite. Cleavage and optical behaviour in parallel and convergent light, easily prevent its being mistaken for other miner- als. In places which are rich in facapolite the at>ove mentioned pavement- like structure is very distinct ; see Fig. I., Plate V'lII. Cross settions as well as longitudinal ones often exhibit very regular hexagonal contours. The specific gravity of the unaltered scapolite was determined as 2 64 by means of the pyknoraeter ; according to Tschermak's data this corre- sponds to a mixture of about 30-40% Me to 60-64 ; Ma. Primary hornblende is entirely wanting. Similar relations are found in the other hand-specimens examined. The pyroxene is generally very fresh. The scapolite usually exhibits the little rod-like or six-sided opaque inclusions ( Fig. 4, Plate X. ) which are probably titanic iron. It is much more subject to decomposition than the pyroxene, and thereby becomes tibrous and dark-coloured by a substance, not determinable, being scattered through it like dust. Then it passes over into the laminated aggregate .so often referred to. The proportions of pyroxene iiiul scapolite vary very much ; usually the former predominates. The pyroxene sometimes shows rough crystal- lographic outlines, the scapolite never. Phlogopite occurs in many of the rocks, but always exhibits relations which point to its secondary origin, which is certainly connected with the formation of the apatite. The content of metallic^minnrals is very variable : in most cases it is very small, in others pyrite, pyrrhotite and also some chalcopyrite may be distinguished macroscopicaily ; these are unmistakablv impre<;- nations. Apatite is also found abundantly, many sections are com- pletely covered by a network of little veins of it ; its formation here is also secondary. A scapolitized gabbro from Poupore post office is very rich in tremo- Transition of lite and epidote. An old apatite opening there is altered into a light- fj'siue'"'*' green coloured ' pyroxenite,' which, macroscopicaily, is seen to contain abundant colourless hornblende. (■ reen actinolite, in company with cal- cite, forms the filling of veins which traverse the rock in all directions. At one place in the cut, the transition of the ' pyroxenite ' into a dark blue-gray, medium to tine-grained rock, is visible, which, with a com. pletely massive hal)itus, has the appearance of a diorite or gabbro poor in feldspar. It is richly powdered all through with particles of secondary pyrite. Under the microscope, the constituents are seen to 12— o— 4J ill t: i| u ^lll :l i- Mil Sijuavv Hill IllllU- • I'lurt/.itf. 62 o OTTAWA VALLEY and + P X I Toi I . Cleavage be <|uartz, triclinic feldspar, very abundant green hornblende, epidote and Bcapolite. The quantities of quartz and feUUpar are very different in different specimens ; in many they are almost entirely wanting, while in others they constitute almost a ijuarter of the whole rock. Aiuphibole and scapolite are poorly outlined iry^tallographically ; they form irregular grains, the former also often rod-like forms. The amphibole is very light-green or quite colourless and transparent, in tho former case with weak pleochroism ; and, is probably a form inter- mediate between treinolite and actinolite. Scapolite, with the usual pro- perties, is much altered. The epidote mast be a secondary product, and forms crystals elongated parallel to the b axis, and usually well ami shbrply outlined. 8ectiops perpendicular to h are six-sided boundeello quartzite. This aggregate is traversed by strings and veins formed of a mixture of light-green augite, dark-green hornblende, abundant scapolite with its characteristic in- clusions, titanite, epidote and some calcite. Plate X., Fig. II.. shows ib APATITK AMI MICA NORTH OK OTTAWA 53 O such a jwrtion moderntely magnified. On the right and left sides of tlie the figure is tlie colourless (|uartz ; through the middle runs such a vein whose contacts with the quartz are very sharply defined. At other places the (luartzite mass in the neighbourluxxl of such veins is interpenetrated with grains of these minerals. This is doubtless another typicil example of secondary formation, caused by impregna- tion with solutions or vapours. iSiniil.ir relations are observed in the quartzite from the Crown Hill mine. As to how far jineis.ses in the neiifhlwurhood of the apatite veins Konnatiun . have been altered by such impregnations, or how far in particular ^;,',^J,''^|^,',,.,| the content of pyroxene is to be attributed to such causes, it is »i''' difficult to say : on the one hand, because pyroxene-bearing gneisses |I.iiHi«."'" " have been found abundantly in other parts of Canada, e.g., by Adams, east of the apatite region : and on the other hand, because of the short time which I could devote to the examination and the lack of good exposures, it was not pussible to follow such augite gneisses to any great distance from the apatite veins. But I certainly believe that such alterations are in many cases connected with the formation of the apatite. GarnetgilUinnnile-giteis^ from I'onpnre poxt ojKc. — In the opening '■■""'' ,11., . , , .... >illiln:uiitii- already reterred to many times, there occur alternating with the nii,ipar wliile quartz is distinctly inferior in quantity. Of the feld>pai-, plagioclase predominates over microcline and unstriated feldspar. Unly biotite is present as a dark-coloured constituent. The garnet is of a very light rosy-red colour, and is transparent and optically isotropic. Sillimanite needles are found only in the garnet but literally till it in places. Rarely there are found in the garnet i.sotropie grains of daik green colour and stronger refrac- ll "itl ■■iBiii r>^ OTTAWA VALLBT if;:! ^H Peciiliar i'ry»t»Iline HcnistK in London mint-. Hi lion which are probably a spinel, very likely hercynite or pleonast. Kutile, in the form of little crystals and twins, is a relatively abun- dant constituent. The structure in section.^ parallel to the schituwity is perfectly irregular. Feldspar and quartz everywhere exhibit marked signs of pressure, which develope an incipient mortar-structure. Large pla- gioclasea are often crushed ; the individual fragments, displaced with respect to one another a ; still recognizable as lielonging to one another: Undulose extinction and the Imnding and breaking of twin- ning lamellif are very common. The biotite exhibits an irregular rag- ged form. In sections at right angles to the schistosity a parallel struc- ture is develojied chiefly by the alternation of layers rich and poor in mica. Quartz and feldspar contribute but little to the parallel struc- ture, a few large quartz grains have been s(|ueezed out in the direc- tion of the schistosity. No rt>gular arrangement of the constituents around the garntt. is observable. In all probability the rock is an altered sediment ; the alternation with quartzite and the mineralogical and chemical composition favour this opinion to a certain ext''* •" "^ course most clearly seen in sections parallel to the prism zone and the extinction is parallel ; the plane of the optic axis lies parallel to this. Hornbleuue is relatively rare but generally well outlined and often enclosed in augite. Sections at right angles to the c axis exhibit only the prism faces on their out- lint as is often the case with actinolite. Constituents which are very characteristic for granulite, such as garnet and also cyanite, andalusite, and hypersthene, are here entirely wanting. Microper- thitic intergrowths also play a very unimportant part. The rocks are perhaps best designated as granulite gneisses. With regard to their origin, it is almost impossilile to make a guess. At any rate, a further Kurtlirr study of their distribution and their position with reuard to the other "''"'y / ^ . n'-ceiwary. gneisses is necessary in order to form any opinion upon this point. Moreover, the question as to whether a part of the pyroxene and amphibole, and particularly the abundant titanite and apatite, are not in some way connected genetically with the apatite veins can only be answered when these rocks have been traced out farther along their strike. Hornblende gneisses containing pyroxene were also met with at the High Rock and North Star mines. Here again it must be left to later investigations to show whether the pyroxene is not in some fei i i n ,! -if I t J; Kriiptivc rockn near a|iutitt- vein iiG o OTTAWA VALLEV way connected with the apatite veins. They are both medium-utained rocks rich in red orthoclase, and the darker constituents predominate in certain layers without actually producing a distinct schistosity. They may he best descril)ed as granular-streaky. The lighter layers contain much microcline, and the only dark coloured constituent present is mica which posses^et a strong pleoi-hroism Ix'tween straw-yellow and dark greenish-brown. This mica can lie distinguished at a glance from that of the apatite veins. In the darker layers the mica decreases and green hornblende and green-gray pyroxene increase. Both in hand specimens and under the microscope this gneiss is very similar to that described from the neighbourhood of Lachute and probably possesses the sunie origin. Eruptiiv rcrk.1 which occur in (hi- neighbourhood of the ajHilili' veint, hut irhich hair nothing to do with their f'onnalion. Along with coarse-grained pegmatites which are widely distributed in the neij^hbourhood of the apatite-bearing vein.«, another type of granite veins occurs,which is characterized by a very even medium to fine grain and an almost complete lack of darker constituents ; the rocks consist almost entirely of quartz and feidsi '\r which is mainly microcline. Such a vein about 0-5— 1 m. thick has : een cut into in the upper workings of the London mine. The normal verv- light colourefl rock is here cut by dark gray-green veins, which often exliibit a regular round or elliptical outline. The rock thus 1ms a ver}- peculiar ap|)earance and is known in Canada as ' leopard giaiiite." Siiuilar masses were found on the dumps of the Little Rapids, North Star, High Rock and Union mines. A very typical blockof thisleopard aranite was shownat the Paris Exhibition, in 1000. Plate V shows a piece from the London mine. With the magnifying glass one easily sees that these veins are caused by an increased quantity of pyroxene, with which in places much pyrite is associated. L'nder the microscope they consist of light-green pyroxene, dark sap-green hornblende, epidote, very almndant titanite, apatite, and small quantities of carbonates. Apophyses frequently branch off from the larger veins and after a short course thin out. These minerals have penetrated sparingly in the immediate neighbourhood into the mass of the rock itself. The whole appearance leaves no doubt that one is dealing with secondary structures, which have been formed upon more or less spherical jointing faces. The identity of the minerals occurring here with the essential ones of the apatite veins makes it (certain that impregnation has occurred here and that this process is connected with AFAUTE AM) MICA NORTH OF OTTAWA 57 o the formation of the apatite and the raineraU acenrapanving it. It is analagous to the .secondary formation of phlo.'opite on the i<.inf planes of the yabbro from Murray'i pit already de-scrilied. Diabiiee and augil-- porphyry both occur in the fo.ai of veins. In I'i.i'a-w- the neighbourhood of the Little Rapids mine two dialmve.lykes occur, jlfin'^r'"""'' each at least 10-12 m. in thickness, and having; a .strike ulniost east and west : they thus cut the gneisses and <|uart/ite:s, whicli here have a strike X.N.E und S.S.W , almost at right angles. One of these veins is cut by the tramway south of the Little Rapids mine on the slope towards the Lievre river, and the other north of the main building ami the smithy. Both dykes cut not only the gnei-is and quart/.ite but aUo the pegmatite occurring in them, the northern dia- base vein also cuts the pyroxenite, so that they are the youngest dykes in the '.istrict. Both diabases are somewhat coarse-grained, ijuite fresh, and exhibit macroscopically typical ophitic structure. Under the micro- scope the plagioclase always e.xhibits sharply defined forms elongated in the direction of one axis, the interstic-s l;eiug fi'led with allotrio- raorphic augitc. Not infrequently the lattr;r exhibits tor cousiderabley stretches uniform orientation and is then poifci'i'i.ally penetrated by the feldspar forms. Sections of the lat.er normal to P and M gave extinction of 3G.38 with the trace of M; the plagioclase telongs therefore to the labradorite series and has approximately the composition Ab., An ;. Two such .sections with a nearly square outline were ob;;erved, which fell into two twin halves along a diagonal. They are probably Baveno twins. The augite is transparent and of a gray-brown co'.our ; it is a typical diabase augite. Some •■'ivines are completely converted into serpentine. Titanic iron in irrf gular forms is present in abundance. f P An (iH'jite porphyrite from the (Jrotrn lliU mini' is seeti in an o!d opening us a vein 05 — 1 m. thick, cutting i.yroxenitfs and apatite veins. It is a black very tine-grained unaltered rock without anv pheno crysts. Under the microscope the feldspars are distinguished fjoiu the other constituents by somewhat greater out Oo m. thick with ,a strike east and west, north of the London mine. The groundmuss of this black .■Vui.Mt>- ["Uphvi-ite. f ! ii If II i - it II' if : 1 1 'I pi KralilU u( invmtJKtt- tJiinH. 88 AsM)ci;itt d vein niinerAlH, OTTAWA VALIIT and almoat compnct rock has a distinct intersertal structure. In it there are large nodule*) mode up of a collection of irregular augite grains with scattered feldspar particlef. Evidently these dialiases and augite porphyrites Iwlong to one and the same younger dyke for ination : the thicker dykes are made up of diabases, the thinner of augite porphyritei*. The eruption to which they l>eluiig oocurr«z the discovery of the apatite III answering tU« fjuestion at to the origin of the apatite \einH, one Clin sat'ely concir in the view put forth by If rugger, Keusch and ^'^lgt, and for the Canadian occurrences in general outlineil by EIIh (»«e Itefer- ence'4) that the formation of the vein minerals has l>een caused by o fuuiarole process which acciimpnnied the eruption of the basic iimgmas or directly followM) it. The material from which the veins were formed, particularly the abundant elements CI, F, Ti, P, B (in tour- maline), Li (in phlogopite) and sulphur canant \te considere.li in dark con- stituents, micii a II d pyroxene. The feldspar i-. .seen by the naked eye to l>e pUgio- clasi', on account of the lwiiiaiii>i striie. In accord- Fi. . II. Kozc^i, CaiuulenH.-. AfATITB AXD MICA NOWTH OP OTTAWA 61 O ante with the «n»ly>.i>t given Inter, tli.- rock is Im-si (|.»imi,»te>( the hill is •t b»'tw»en the nMmi iiml the Eoze giiiiaeil l).«..ii.-; f (grains 4 ."> nun incliain.) ami shows nmtroaco[)i.'aliy l.rownish coloured "'""'"'' "*''• roii/iy lustre, which i- shown l>y the uiitroHcope to \te partly rhoniliic and partly nionoclinio. These pyroxenes have le«t their lustre along their eilfes on account of the formation of uralite. Under the microscope the plagioclas*- exhibits the usual twinning lamellae nCLording to the all.ite and, in part, peridiiie law. It contains many inclusions, as is so frequently the case in Irnsic eruptive rock-, in the form of u tine dust, which, with a high power, is icscUe.l into tiny rtxls and plates ; the latter have hexagonal outlines and are transparent and of a gray-biown colour: they aie prolmhly titanic iron. The extinction angle wa.s measured on plates paiallel to < »l> and found to U^ 2-4J , on plates parallel to x P 5, l:.'li; ; a 'ieternii- nation of speeifie gravity with the picnometer u'ave 267'>. It i-. therefore, a feldspai lielonging to the oligoclase andesini- series ; the specific gravity corresponds very nearly to a mixture Ab . An, and the extinction angle t-i a somewhat more basic one. Probably on account of the freshness of the mineral, the .specific gravity is a better "uide than the few extinction angles. The monoclinic pyroxene is trasparent and of a light green-grav colour, and exhibits almost no pleochroisni. In sertions parallel to r. P ^ the extinction (5 : c wis 12 . Itesidethe normal cleavage parallel to or- P there was one parallel to -x Y-j wir,h few cracks but strong and running strai.'ht, and a grt-at many short but sharp cracks parallel to -x P ^ causing a tine fibrous structure. These relations are Ijest oliserved, especially the tegular intergrowth with the rhombic pyroxene on sec- tions at right angles to c. The central portion of such a seition is formetl of rhombic pyroxene with distinct p!eochroi.sm between rel to « P ^ »o common in rhouibic pjruxenoi. Tin* peripheral |ii>rtiun of the lection iacoMpoMd ol augit*. In convergent light one axia appmuw »t the edge of the »^d. the plani> nf the optic »«ii in p«r»llel to the •Im>v-« mentioned tibrouii erackii the laittr l>etng nuted patrhfH in the interior. All three minernU exhibit ximultaneoua •-litinction. The rhi^mkic pyruxeue alwayn eeemi to be older than tl»e tiiuiMX'linic. Iktth, eepeciallT the fonn>>r, C)intain incluNion« of littl* rods and plutea iiiniilar to tli-xe in the f>lagiiutituent», and it fflox'ly certainly primary. A »mall pui aeema to h«ve lieen derived from tli- uralile. The dark constuupntN are ir -gularly outlined, only the rhombic au);ite exhibita ii. part rou){li |>f i!«niatic forma, it is undoubtedly the oldest of all. Itesidea apatite and isolated metallic grains, then* is some quartz in v<*ry xmall grains Ijetwoea the tVldspara. FresHure phenomena are hardly present. An analysis by Dr. Dittrichgave the composition under I ; under II the curresponilin^ molecular proportions have l)een calculated to 100, leaving out the H.^O and COj. I Tin, . Al,t)„ Fe,(), Fe«). MnO . MgO.. CaO. Na,<) K,0 P,o. H,0.. CO, . . r>2 I'.p t: U 5-' :i 1 1 (i 21' trace, f, .-,7 8 SH 3 (1- 1 Kt I 43 53 m M U15 H 111 Kcll 10 .'HJ IIP •-•(I a 711 1 (>-, II IM ITOOS 4| AfATITK AMD <•»* K">HTH or OIT.tWA «3 1> Fn>iu 11 may tw cnlcuiitni : A-4H4;C 4 31 ; P = 24 no, (1=3; c •,' 6; f 14 B n • 7 *< •nd th« forniul* : * j« . 3 *j •^i .1 'i 1 • • "; . •• A glance iit the Ubltj of plutonie nxk« ( •.') "how- thm tlif riH;lt hnlda •bout th)> ■•tne position an the DiiuagablirofioiiiHuri icaii l(iili(e, Wlluw atone Park, described by hidings, and thiii the luineriiln-^ii-'itl i.'unttUu tion of both roolcM i« very niinilur. The latter conbiinH augiti', hy|ier ittheue, biotite, platjioclup, «)uih niUioolitiie, i|uart/., iinil oiivini-. The potition of tb«> ('Aiiadiuii rlkenhaus (uiuler a - M). In the diorite table, on account of its a c i ratio it would tit in betwifn the typea Montrom> and Cuinpo major . t'or this poiltion it< |HTi'Hutiigi> of silica Ih It littlH low. It it therefore d><«iKnati-il ax inii-ahyiMTstlii-ni* Mi™ *'>|"t»- gabliro. It IS amo ciieinically v>-ry similar to tn>' enMexitu lyfx; rair view ; here, however, the pro| rtion of alkalies is in general Honie- what hi;;her, the value for i i slinctly lower. The type point in table VIII (loc. cit. i conies near the points ■''"> (Montnwe) an'l 07 (C'abo Frio). I rom the numliers for A and C we obtain an average plagio close Ao „ An^. I . The value for Ali is ii toubledly, on account of the considerable quantity of mici. -.omewhat i.iuli. and in .spite of this the value varies but little from that calcul.iti'd trmi the specific gravity. A con>(Miri8on wiUi the gaiibro fion. Murray n pit shows that the rock from C(^te St. Pierre is somewhat more acidic and corre'-pondingly richer in alkalie- andalumin i. but poorer inbiMilent metiils ; eM|H'cially the 'Hiantity ot magnesia, in spite of the mica content, is distinctly lower. Murray s pit is lower and more tl»>iulc may be uralite. Tt i* alsi) rich in apatite and titanite. The foriiier seems to nie uinioiibtedly to l)e a marginal facies of the gabbro, but I am not sure of tlii-i. A decision la,. iie made only after a further study of the field relations. Difpc'coiitiut As has already been stated, the direct contact between the lime>toiii' not exiKiwd. ,^^^j ^^^^ gabbro, b on the profile, is not exposed, liut in many places it was possible to uncover rock-: whieli undoubtedly fame from very close by it. It is characteristic of the s|:)eciinetis tlus cullected that feiiispar and quartz were completi-ly wanting, and that their coarseness and composition varied very niu ■li at points but a little distance apart. One of them is exceedingly touyi', linr-,'rained, of darjv greenish-brown colour, and in which may ba detected inacroscnpically isolated large plates of mica and cleavage surfaces of green lioi-nblende up to a centi- metre across, irregularly outlined and interpenetrated poikilitically by other minerals. Under the microscrip", the main mass of the rock is seen to consist of light-gray transparent augite and green faintly weakly pleo- chroitic hornblende. Mica is only rarely present, and there is also some calcite, a green transparent spinel and abundant titanite. Feld- spars and quartz are altogether ab-enf. The hornblende is very irregularly distributed : in certain portions of the section it forms large shreds which are poikilitically penetrated by other minerals. Whero it is wanliiip, the structure is tliat of a typical lime silicate APATITE AND MICA \0R1 II OF OTTAWA 1)0 O hornstoiie of relatively coarse Rrain. Plate VIII., fig. 2 gives a repre- sentation of this structure. Another ona of these rocks is distinguished liy the tact that, inairo- scopically, tesides green pyroxene and very abundant titanite, it contains large grains of a white mineral that, in lustre and cleavage, is similar to tht jcapolite of the apatite veins. .Mica is al.so very abundant in spots. I'nder the microscope, this undoubted contact product consists in part of a very uniform mixture of pyroxene, scapolite and titanite. Plate XI., fig. 3, is uktn from such a place. ( Hher parts of the same section are made up almost entirely of scapolite, which is coarsely fibrous, the indivirlual fibres having a tendency to arrange themselves radially. Piute XI, Fig. 4. From still another place in the neighbourhood of the contact comes Ma.»iv, a black-green ma.s»ive serpentine, cut by cracks a centimetre wide, h,','"'',',''.'';' fillrni with some calcite and large mica crystals. Under the micro- """""• scope, the serpentine exhibits in some places distinct ci-oss hutching, caused by two fibrous systems crossing one another at right angles. There are isolated grains of carljonates and mica plates in the serpen- tine. The mica which fills the cracks has an axial angle of about 30', and ' filled with redbi-own inclusi(ms. At another point near the contact is a very coarse diopside rock. The whole rock consists of coarsely crystalline grains of -J-.'} cm. diam- eter of a light green to almost colourless diopside. r obtained some hand specimens from Prof. Schmidt in lUscI, who I.i,„.>t..ii.. had cc.llected them on u former excursion to this place, and which con. | '"I"'''''"'-' sist of alx)Ut equal quantities of diopside and calcite. The latter forms "h f^iin.., a coarsely crystalline marble, in which the diopside is developerl as verv '''"""' well formed crystals over a centimetre long. The crystals are short prisms, the two vertical piiiacoids occur only as narrow truiicutions of the prism ed-es. The terminations consist ofOPand various pvruniids. The latter are usually very rough and unsuitable for measurements, while the faces of the prism /.one and OP give very g.nxl rdiections. All crystals exhibit a perfect parting parallel to OP probably on account of a fine twinning. The extinction angle in one section parallel to r P x^, determined with Na light, wa.s 37 . I'ndoubtedly we have here a limestone exhibiting contact metainor- phism ; the whole paragenesis of minerals, the great variety in the grain of the rocks in such a short distance, and the typical contact structure aie uxlraurdiniirily cliaractcristic. At a somewhat greater 12—0—5 11" ,. r : 66 o OTTAWA VALLEV Origin of KuZtKHI. distance trom the contact the carbonates still prevail, in them the diopside has developed in the form of ciystals, and irregular concre- tionary masses, or with the structure j)eculiar to Ehzooh. Dawson says ' sometimes (not usually) pyroxene is the silicious part of Eozooii.' The diopside is very frequently altered to serpentine. When Dawson says ' Further the white pyroxene of the Laurentian limestones and the lo;,'anite and dolomite are all known to have heen produced by aqueous dejiosition,' it certainly does not apply t«i the augite here : it is in this place a product of contact metaniorpliisra. The normal granular lime- stones of Canada also very often contain green pyroxene, as has already been fKiinted out. The rocks here descril>ed cannot, however, be mistaken for them ; they are recognized as ditterent upon the first glance. With regard to the question as to the organic origin of Eozoon, this is in no way connected with the above facts and their explanation. If Eozoon was an organic being, its hard parts which are still preserved certainly did not consist originally of diopside or 8er])entine but were first converted to the former by an act of metamorphosis. It may here be pointed out that Johnston-I^vis and Gregory'"' have recently obtained pieces of lime silicate, ejections from Monte Somma, in which the typical structure of Eozoon is present. According to these two authors, this structure is not originally organic, but is produced by metamorphosis. In the Monte S)mma specimens augite is subordinate to the basic lime and Miagnesia silicates olivine and monticellite : there also occur mica and spinels, as is the case at Cote iSt. Pierre. TWO CANADIAN OCCVBRF.SCE.S OF GRAPHITE. Occurr»*nc;f f ^rajtliite' wi«le!*i»rc:MJ. I. On the occurrence <,f draphit" nt Graphite City, Toirmhip of Bncliitighnm. According to the older reports of the Geological Survey, of which I have been unable to make a through study the occurrence of graphite in Buckingham and the adjoining townships is very widespread. In the first township it is reported fi-oni many points in lots 18 — 28 and ranges V — VIII. In most ca.ses work seems to have been confined to small openings, in only a few has the graphite actually been worked, and even here this has been done very sporadically and witl long delays intervening. In this whole area, as far as is known to me, work is carried on only at Graphite City, and there on a small scale. '■] TWO CAXADIAN OCCLKKESCKM OK GRAPHITE C: .Milling ('u. In the Kej)ort for l>73-74 Mr. \ enuor ha» given some information witii respect to the way in which the ifrapliite oiiurs. iinil according to this the mineral i.s found 'in three distinct forms : 1. As disseminaterl scales or plates in the limestones, gneisses, pyrox- enites and quartzites, and even in some of the iron ores, as at Hull. -. As lenticular or disseminated masses eml)edded in the limestone, or at the junction of these and the adjoinin<; gneiss and pyro.venite. 3. In the form of true fissure veins cutting the incloseominion of Canada Plumbago Co., as can be seen from the d^pth of the working and the dumps. What is gi\en l)elow refers for the most part to these two localities. Only a few other openings were visited ; many were vainly looked for in the thick woods. (In this account, and the shorl time of I'lj' stay, my observations must necessarily be of a veiy fragmentary charaotor. Of special interest are the following points : — 1. In all the pits I have seen, with Imt one exception which will be (irapliitt- mentioned later, the graphite occurs as the iiliing of veins and cracks tillintfuf Mins. in gneiss, granular limestone, pegmatite, and granular eruptive rocks. The direction of these veins is independent of the strike of the rocks traversed. Thus in a small opening between the Main pit and Ne.iy's pit the gneiss has a strike N. 70 E. and a relatively Hat dip. It is cut by four graphite veins all parallel and about 4 /> cm. thick, whose strike is N. 120 W. and dip almost perpendicular. Near Nelly's pit there is a pegmatite vein in the gneiss several meters thick. In this, in a relatively small space, there are several graphite veins which have been exposed in openings, and which are as broad as one's hand in places but usually only a few centimetres. In Nelly's pit itself the veins are collected on the boundaries of the granular limestone, the gnei.ss and a phitonic rock, which, as far as one can see, furuis ji large dike. Some of these veins have a thickness of over 20 cm. One 12_o_5i rp G8 o OTTAWA VALLKV Kxcption to vfiiifdniHttiou Ht Main (lit. Mnit-ral !•' lilt. 'lit of u'rapliite vt'iii!' ^iiiijiU'. can see very well from the abundant material on the dumps how narrow apophyBes and branches have run out from the large graphite veins lietween the layern of gneiss, how thest^ dwindle away, and how along their line of continuation inolat*^! plates and knobs of graphite are depooited. See Plate VII. The granular limestone is strongly impregnat.f alternate bands """ of a dark and li.'ht gneiss-like rock— it is a hypersthene liiotite iralibro- Winiilar, thoU;,'h more altered, plutonii' rucks consisting' essentially of plaj,'ioclase, augite, and mica occur at the Main pit .ind Nelly's |iit. Whether they are parts oi a large ma>.s or are unrelated muUl not be determined from the {KXir exjiosures. The hand specimens from the two last mentionet localities do not show any evidence of parallel structure and are similar eiiouirh to be mistaken for one another. As far as I could see on my short visit, the occurrence of the graphite is connected with tlic contact of this <'ruptive rock with gneiss and granular limestone. The limestone is in these places very much altered , there has been especially a large jiroduction of .scajjolite, pyro.xene and titanite. 8uch altered limestones are so like the scapolite pyroxene rock from the ncighl)OUrlKxxl of the apatite vein*, as to he mistaken for it. Of the riKjks from the iieighWirh.jtMl of the graphite veins, the eruptive rocks will he now described. Hui"'riit/ii'ni' I'intilf imlihto from the neighbourhood of Walker's hoii-e. Hv|»-rstlii m !/' •' . ,, . ,., i.i..f;t..,r.i.i.. This ck, as already jMuntcd out, has niacroscopicaily a v'l^eiss like appe.< nee; microscopically there are seen very strongly ileveioped signs of pressure passing into rudimentary moriar structure. P.irticu larly the feldspar, which is almost entirely plagi'iclase, exhibits undulose extinction, bending and breaking of twins, and similar pressure phenomena in a wonderfully Ijeautiful manner. Ahmg with a mono- clinic augite is less abundantly a stronsjly pleochroic hypersthene. liath are allotriomorphic, the hypersthene in great part converted into a green alteration pnnluct. The monoclinic very faintly pleochroic lliiitit.-;,'.iliK|. J 70 o OTTAWA VALI.ET Amither xiniilar rork iiU>Vf Main |.it. (/nart/ int*ivr«»\vtli III ft-M^'|l.1l uiiil i|iiartz. auRite shows in sectionn ftt riRht angles to c along witli the prismatic cleavages, short sharp cracks which are visible only by considerable magnification and very good lighting, and which correspond to the orthopinacoid ; theplaneof the optic axes is normal to them. Mica is also abundant. The rock must come very close chemically to that from CMe St. Pierre as it does mineralogically, only it is distinctly tiner grained. A rock which I found above the Main pit in large blocks near the graphite vein already described and which must occur very clo.se by, is very similar to the one just described. The rhombic pyroxene is here much less abundant. Of light-coloured constituents, besides plagio- clase, a microperthite is very abundant and also some ([uartz. The structure is completely irregular and that of a normal plutonic r(K;k. Pressure phenomena are less distinct. A few paces north of the entrance of the Main pit the sauie rock occurs again. Macroscopically, it cannot Ik; distinguished from the one last described, irnder the microscope, it exhibiu very peculiar appearances. Here again by far the greater part of the feldspar is plagioi-lase. This plagioclase is completely intergrown with quartz. All those phenomena described iis quar- '/<■ i-m-rnsifm, i/uarz irrmicule, kc, may here be studied in peculiar lieauty. From the edges of the feld- spar sections there run inwards lube and worm-like developments of ([uartz which frequently unite and form :i regular netwoik. Fig. '2, plate XI., shows a typical example of this latter variety ; the isolated plagioclase particles are much rounded, as though roughly broken up and in part somewhat displacet-, U-.--'n-!.. N^>. le-s. !s!H>. . iiiiRiii Skan(!ina\ ischfs Hia TWO CANAIHAN OCCUHIlKXrEM OF GRAPHITE 71 o tized : it i^ eaten nway iimi Klled witli little micu pl«te!< and particles of iiuartz, similarly to what was observed in the scapolitized gnbliro from ttie Vavasour mine. The l)rown mica ni-ver forms large plates, but invarinbly a lot of lirtle vpan^les and irre;;uln»ly boundiHl knol« which grou{i themselves radially, preferably about the pyroxenes and metallic miui-rals or are arranged in parallel swarms. In a short distanse such a group of panillel-arranged micas break up into a sort of soot, so that its arrangcnu-nt looks like that of the microlites having a tluidal :irran(.'enient in glas.sy rocks. Apatite is not an abundant accessory constituent. Uicroix'-- descrilies and liguri's very similar conditions in iiiiiphibole pyroxene gneisses from the graphite district of Ceylon and from Salem. It is possible that these corrosion and alteration phenomena are connected with the formation of the graphite Veins. The gneiss which occurs a few paces from the Main pit contains i on... ntar but little graphite. It is a iliinly-bidded nx^k whose cross section is ,".,,iJJ'||],'l,' ij,,],, seen to Im- essentially a granular mixture of n-ddish feldspar and i-tii''"''- Huartz with some graphite. Mica is much less abundant. On the principal fracture are mainly ^mall plates of light brown mica. I'nder the micriiscope, the rock consists principally of an allotrio- morpluc mixture of unstriated feldspar with a little ([uartz. Plagio- cla.se stems to be extraordinarily scarce. The feldspars are tilleur an irregularly granular. In the portions rich in mica, and freiiuently intimately intergrown with it, there occurs graphite, and in the hand specimens examined these two nnnerals are about eijual in e cassiteritc. In order to make sure the following test was Oxiileiif till, made : The heavies', constituents of the rock were isolated by heavy solutions and sev.wai times treated with hydrofluoric acid ; a smiill )|uaiitity of a black jiowder was obtained. It was dissolved in a Ixirax liead coloured slightly Mue by CuO : the bead assumed a ruby colour or became opaque, resembling red sealing wax. This very characteristic reaction provod beyond a doubt, that SnO- was present. So that though possibly occuring only sparingly, there can be no doubt as to the presence of cassiterite in this gneiss. iMMiaii MHfli -J TWO CANADIAN OrcL'KRKNCKS OK (iHAFIIITB 73 O The mivutes employed (orolitainiiijc f^iitphite from the m.iiniiite do not exhiliit macrosodpicully anything; Imt ^.Tuphitf. rnder t)i<- ndcnitciipe they are found to contain iilnmdunt calcite in Inr^e much t wini'd );rninf>, abundant monoclinic augitu in irregularly outlined grains partly pnssinu over into a dirty green lerpt'ntine-likc altfnitiim priMluct, further quartz grains, abundant titaniti- with strong pleouliniisin and a colourlcsM mineral in radiating tibroux ajtgrpgates that could not In- exactly determined hut is iierhaps trcmolitt- or woliiistonitc. Tin- graphite occurs us in the alwvt- ileiicrilicd ;jneiss in irn-gularly outlined much elongated lumpx. Its intcrgrowth with pyrite has ulrfiidy U-en mentioned. As shown by tlifir composition and by the fact that the transition can Iib followed, these masses have lieen deri\ed from the granuiai' limestone. Itbas already l>eeri mentioned that iheie has been a d(>\ elopement uf ••ccumiKi' ' scapolite at the contact of these urapliite veins, and partly upoti tliein. ..iiitii'i t ,.t Two of such rocks may here lie mentioned. The first comes directiv "''I'''"'' - M'lll". from the contact with the graphite vein which has been opened about r>0 paces alwve the Main pit. It is medium to tine-grained with pyrite abundantly scattered through it and under the magnifying gla«s has the greatest similarity to contact metamorphosed lime silicate rock ; its structure is quiti' irregular and granular. I'nder the microscope it consists of .about pi|ual uarts of colourless pyroxene and scapolite which in part has undergone the alteration desorilieil alnive. Ajiatite in largp grains and titanite are rel.itively ubunti- tuents are augite and scup.ilite, with microcline and a little re mini) it in tlie Cranulai' liiiie^ttune. in In lf*l"i tfi ijrnpliito t'roiii tlio ^ninuiHi- iinieittoni* of •Irenvilli- wan '" mentioi:«l hy L*! "f *1'« Collection ot' Kconouiic Minerals of Cuiiadapri'parrd for the Exhihition in I'hiladeiphia, lX7t>, it is referred to an fulloWH : ' < »n thin lot Ave IhmIm or veins of mure or lesa pure graphite occur in a lielt varyinsif fi-om rtve to i-l^jht feel in width. Tliey range from tive to twenty-two inchen in thicUiieH* and are incliwed iu a g«iij;ue from which the graphite luay be readily separated This gangue conniHtH of pyroxene, wollastonite, feldspar and oiiartz with Hinaller t|U«iitities of spliene, phlogopite, zireon, garnet and idoorase. The country rock eonsists of white limestone. The deposit has lieen o[»"ned to a depth of thirty feet iilong Mxty feet of its course s.' Itecently work seems to have l)een taken up again actively. At the lime of my visit new liuildiug- were lieing put up and new stamps were lieing introi|ui«nlity of tht-gr»nu)ar lirnfHtonufroiii Lachutn .Station hIiouI tpn milox wwi >,t (irttiivilli-, wan dissolvetl in diliitj? liydnM-hloric acid. Tlio Uiiiegtiint of iiliurdant <|Uiirt/ and n, triciiiiic ("idiipiir nlon^ with the iiiinpraiN alrfuly nnm'Hi. All p<>»(iesH a Miort< or \omh rounded surfarp lis llK>ugh fu'<«l. The ffid-ninr Pxhil'iN (B'lyjtyntlii'.ii' twi'ining Iiuit-lln', and uii clonvii!.'i> vnrfiii'f.s parallel to ol* alinoNt pariillel cxtinflioii, *< an olit;m'liiv. Thus tlic normal liinesione fmrii 'lie (irenville griipliite iiiitif< ^'howH no unusual ci>in|o>iition. The !;ra|ihitc wliicii is worth mining ot'cur.s in tlii' lime^t< n<> an utiilouhtctwten the ({rajihitc veins in vorv much altered, and particularly rich in quartz. Thii forms grains of over J mm. diameter, and UMM.nies in places so .nbundHiil as to imparl to the nick the app<>araMce of a <|uart/itic saii'i.stime ; in other places a large part of t!ie calcite grains have lH*come altered to tilirous wollas- tonite. At the same time there has occurred a strong impregnation i>f graphite, so that in the neiglilKnirliiHxl of the cracks the rock lias liecotne almost hiack. These alterations ilecrease in intensity with the distance from the gnipliile veins. In the veins tlninsehes ami in jiiaoes ui>on them theie are masses of pure tihrons wollnstonile, iireen |)yroxene, an-i titanite, a culiic foot in si/e. Here iilso giaphite occurs in he\a gtmal plates more than a I'cntimcter across. If oti the other haul a crack is filled completely with grapliiteit forms ap[)arently a "tructmless muss or a lihrous aggregate. l*'rec|iiently the calcite in the neigh- liorlnw"! of the veins ha.s l«'Conie coarsely crystalline and of .1 lilup Colour, as is the case in contact rocks from Mon/oni and the llanal. The wollastonite of the \eins and their immediate neighhonrhiMxl \v,,l|,i.t,initi' consists either of snow-white parallel fibrous aggregates of |(j — l'O cm. length of libre, and then generally almost quite pure, or an irregular coarsely columnar aggiegate and is then abundantly intergrown with pyroxene and titanite. Microscopically the apparently pure mineral contains small augite lamell:c. The c axis of the latter is parallel to the fibres or b axis of the former. Otn\ hile and pyrite frequently occur in irregular cross cracks, and they are therefore in part youngi'r than the wollnstonite. 76 OTTAWA VALLIT An HnalynU l)> Hunoe (Daiis'i Mtii«-raU>gy, li<50; kbvb : Ml. CM). I. II M'lM wCW 1 ait )> i>MI* 4:. 74 HUM I i Titallitf I'ndt-r II. tlie molecular |ii'op<>rtioni> are given. The composition i* : 0-0107 1(*5 FeSiO. Thori' n>maiii« un excesii of 00670 SiO, which is periiaps cau»'' (|uart;f! incluxions. Tlio au)(itp hii« 11 dark hottle-^'ifn^n colour and exhibitN alunK «< ith the cleivaue ciackii parallel to » P, a parting; parallel Id ol'. l*ar«IU'l to thmc fiio's of parting iiiioiwicopic liquid inclusions art- .-jrr^iiigi'u in hand.t. Tituniti' i« al*j very abuiulunt in pii'i'es up to the si/n .>! tii,.''s h.au Buiiz ( ' " ) deMcrilrtw two iTystaLs I'rom here which were al>uut 1 1 ui. 1 iiiik and 4ciu. lonj{. The hahitus is exactly that of the well known ir\-!, il- fioni Renfrew, the observed faces U-ini; Pii | TOl > ^'-'i "' ' ;-■ p"i J I'J.'J V and :;*'-] 1-1 [ according! to Nauniiuin's orienta- tion. I found oaly mii-sive pieces of a resin brown colour. A parting parallel to two faces is very clmraeteri»tic and cotnpleti and gives with the goniometer very good retlections from surfaies iiiakiiig an angle of .")-J' ~0'. 'Ihi-s Is ulinost identical with those found l>y llus/ for the titaidte from Renfrew (')i 'M)). Kroni the.-.e he calculates a parting parallel to ? P4. In consequeme of this parting the mineral is very crumbly mid fragile. Zircon is decidedly more -carce than the three minerals de-cribeii aliove. I was able lo find only two small crystals In the material col- lected, and these were somewhat over 05 cm. long and alxmt 1 mm. thick. They exhibit the forms x P | 110 | 3 P | 331 I 3 P .! •I 311 y and P •! Ill \ The lennination of the cry.stiil is .sharp, a.s in the accompanying iigure, on ticcount of the preponderance of 3 P and 3 P 3. The colour is light violet gray. TW«> i'A^AUIA!* OCCUMBKNCI-.H OK iilHPlHTK lluviaiiiti' nnil i{»r- n«t iiN iiiiiiHrul* If CO in (xtnytiix Uc- gr»{iUit«> »' ( i It'll- ville ; iliirinu tht- nhort limn ol fiiy xtny I WAN unalili' '<) timl tlll'-M". In one of tht itiL,"« tilt' liniextoiH* in cut liv a voin of erupt i VI' r it is -(eeii to U' muili ulteii'il, only ii fi-w vstiils ■ eiiij; iiuite t'resh. In llu- ^roundinass oiii- '■: altered plui^ioclusc and sections of a pri.smatica!ly vi,. *, i« ootnpletely it part of tiny I i/.e roiVact ill, .[.Tains which are proliibly alteration pnxluctx of a ^la.ss. IVol.iWy itie rock is closely relaieil to the auiiite porpliy. rites alrewJy descrilied from the neijjhliouriu!; apatite rc-jion. Hoftnianii ('-) has inmle a seri's of analyses of jiraphite, both from \iK,lv«i-.ir various localities in the tcvnships of Grenville and lluckingham, the |'('."J^,;|','„„'^ results of which are given in the report here referred to. The most iin|xirtant results which have lieen derived from the iiivisti.;iitioii of the 'iccurrences of K'apl'it* "t (iienville and (iraphite City, may be summed up as follows : !. Tij b--'th o?ci!rrenr'>- the grfvphit- app<>jirH an m.itter fiUins; vein.s and cracks, and is therefore youmjer than the containing rook. The strike of these veins is indeiieiidcnt of that of the crysi.-.lline scliiets cut ir* o OTTAWA VALLEY Ctiiiiitry riK'k im|>re| veins. At Urenville this was not possible (Vis augite porphyrite there occurring in veinst certitinly has nothing to do with such a process) : however it must not l)e forgotten that nothing is known geologically of the region even immediately around the graphite works. Perhaps the immense mass of syenite whose boundary is only al)OUt a mile to the east should be considered in this connection. I am thoroughly convinced that the graphite veins at Urenville are not of isolated occurrence, as is the case at Graphite City, but that the wooded character of the country has preventted further discoveries of graphite in the neighbourhood. i.'ni|iii!tr II hTiaiiiil.ii liUlf-lMllf. TWO CASAUIAX OCCCKKENCEtt OK (.liAI'linK 71' O In one respeot these two occurreni-es differ, for in that lU (ira(iliite City the plutonic rock itself is cut by graphite veins. ( tne must, therefore, herp suppose a process conditioned, as in the case of the tin ore and apatite veino, by fuuiarole action after the cooling or solidifyini; of the eruptive rock. The occurrence of npatite and graphite veins in such close proximity in ilie province of Quebec aeul exhibiting so mucli in couinion niineralogicaliy and j,'ooloi{icttlly shows that they have had a similar or analogous urigiii. < »ne needs only to I* n-mindtd of the i>ccurri'ncp of graphite in apatite ^eins, and conversely of a(i«tite in graphite veins. The latter i.s reported from Ceylon in all geological descriptions. Graphite is widely distributed in the granular limestone of Canada, but is aji far as my knowledge goes, however, present only in snwiil cpian- titie.s. That this graphite has been derived from carbon originally pre- sent in the limestone and prol>ablyof organic origin, seems to me to lie witiiuut doubt. By the same process of iiKtamorphism by which the limestone was converted into marble, iliis graphite has also been formed. Tiie graphite ol' the veins which hive been de.scriljed lias, however, certainly nothing to do genetically with this other graphite sparsely and evenly distributed. A short time ago Weinschenk (■'')cami' to the same conclusion in regard to the graphite veins of Ceylon. According to this theory the source of the carbon forming the graphite must be sought deep down in the eartli. As to the chemical form in which it was present as a constituent of volcanic fumaroles. we know at present very little. Weinschenk supposes that it was in the form of cyanogen coiuiKiunds. It may be pointed out that quite n»cently Cohen has found in the nickel-iron of < >vifak and Niakomak, which is now supposed by all to be of terrestrial origin, the sjime iron carbide which under the name of cohenite has been known for a long time as a constituent of meteoric iron. Fuither the inclusions of li(|iiid eartx>n dioxide especially in the ijuartz of eruptive rocks, can only be supposed to have originate from an original content of carbon in the fused masses of the earth's crust. 'It was only while correcting this report that I became aware C.I <.< lord,. ii,'» of Mr. C. H. (Jordon's pajier on the .syenite gneis.s (leopardrock) l'v,'"ii't."Jii..n« from the apatite region of Ottawa county, Canaila.* The investi- gations of the author are essentially confined to the occurences at tlie High Rock mine. The results of his work which have for us a particular interest for us are as follows : ~ • Bull. (;e..l.H,n'. Am.. V,.l. VII.. 1s;h;. It m ~? 80 o OTTAWA VAI.I.BY IntiunivH (;*TtHin. iiiiiiTai-. ,a) The .syenite gneiss occur, in dyke form in pyroxenite. gm-i*. and iartzite and cutH across tl.e latter iu p«t at nght angles to the ^tlrCre" n therefore be no douWt a, t. its intrusive nature, and its younger age in relation to the later rocks. ,A , The syenite gneiss occn.rs in three structurally diffei-ent mo tndi;;;^, which are separate-! from one ..nother by a network of fine- grained mineral aggregates. o Tn the ellipsoidal syenite gneiss these coarse-gvaine.1 blocks are no'longer irregular but are round^i ellipsoidal, or egg.shape modifications are of like composition. pJldparl'tlterpart micr-^line,, «reen pyroxene, and ,uarU an- Feldspar (ui -^«* ' ^^^^^^,y to these are titanite. apatite (m ? T:: ml^ro t o„e 1 1 m .iLmeter,. pynt... .ai.-a. hornblende tp rrl^cT plluct from pyroxene, .alcite, and sparingly a so ^::^ nierals are n.ore strongly developed. The Vy^^^^;^ ZLeed\.. are hen- in part re,ularly arranged ; they he w.th the, lot It normal totheil contact with theenclosed coarse n.asses (rf.) The whole rock shows pressure effects which are partu^uUd inJenl in Mo.lification 3, the sUeaked syemte g-u-.-sn. Acco-d n oTwhole description, the lenticular structure has been produ ;::;;h the crushing together with perh-ps .Uso ^^^^^^ ^ coarse constituents of Modifications 1 an.l - ^''^ ««;';'" ^^^.^, of pressure is in the network whose structure ,s to be d.rectl clesignate OF ( ..:A11I ITK -1 O (..) Witl. ro-iK-ct U. the origin ..t-ti,.".se jicoullir .tiu. lunil n-lMion NhijM. the .luti.or < forth th.- folDwiii;' h_\ lioth".-i> JiH the limst luoljablH ; (1 ) Th.- structure .harnctfrizin;; th.' '.cr.par! rock i- , int.-rme.liat- -tas- in the .K'v.-.op- m.-Mt ..f H slr<-Hk.Ml nupt« s)vnt.- iineis. out -i an aU'^it. -svenUc whi.h WM. ,li,ti„;;«ish,.i 1.V a coar>*.l.v ,r.vstalli/,e.l Xructur.- and l.y a s..>u...vh.„ irregular a«,re.al.m -f pyroxe.,-. The character ..t the ori=,'itt:il ... .pna »,ay hav.. ;..vn .uo-lill.-.l s..,nevvhat hy the ah«..pt.on ot' inclinl.i! t'ntniu.'Ut^ .>f pyr.>xeuile. .o ) The .listrihuti f the pvn.x.-t.e has l.- .. eftV t..! pre.utnahly l,v the s..luii'm..f portions of the..ri«ii.alc-.n.tituentsin.l their cry,ta.. lii-atioti al..ii- liii.'s tii.ukirif; the location of .racks. (:j , Wiih .ontinu.'.! pressure these lumps (ti,.' carse-Krained l.lock.) h.,v.- l.een .....re a,-.d nt.ae ^rau n -ut. the process hein;,' accon>pa,...-.l hy r..,.rystalii/.atioo until the rock assu.n..! the streaked ,.'ne.sso,.i forai." Ti.e rocks which I had an opportunity of stu-lyinu' \>e\on'^ to Gordon s Mo.i •■ the coarsc-..;r«ii.ed b!.M;ks Ihm..;: in part cmplelely spherical. The houndarv iHHwecn these and th« fine-rained tuatcr.al ts s.-en t.> !„. con,liti.,.r;d through original ...ore or less spherical jo.nt.ng. It such r..oks are st,-.mglv s.,uce....l these spherical u.asse, hecotne n.ore an,; .nore rtaitennl an.l con.e.,ue...ly a ht.ticular structure .s .nduced. At the san.e ti.ne elTects of pre«.u.e. su.h as the crushing of the constituents, ;he pro,lucti.m of a n.ortar structure, .Vc, a.-e ...or.- pronounced ..h.ng joint phuu-s in which the --"tu.. .s w^k^ L.1 .....re ope., than i.. c.mpact coarse l.i..cks, therefore the p.es. u.-..eflects are n.o.- p.-onou..ce" tl.|- "ther K^;; I," hunl 1 a.n .■o..vi..ce. Steny Hunt. Tlieai.,ititedepoMt.~of Can.ida Transact. Anier. Inst, of Min. Kngin., 1884. Steny Hunt. Note <.n the apatite region of Canada. Transact. Aiiier. Inst, of .Min. Engin., IfS-"). .1. \y. Haw son. Notes .,ii the phosphate of the f-aurentian and Cambrian rocks. (Juart. Journ. (ieol. .Soc., 32, 1876. B. .1. Harrington. Report on the iiiiri.Mals of some of the apatite-bearing veins of Ottawa Co Report of Progress, (Jeol. Surv. Can., 1877-78. .(. F. Tonance Report ..n apatite deposits, Ottawa Co., Quebec. Report of Progre.s.s, Ueol. Surv. Can., 1S82 >!4. W. B. I)awkins. On some depo-its of .ipatite near Ottawa, Canada. Trans. Manchester (Jeol. Soc., 18, 1 s8,'». O. H. Kinahan. On a possible genesis of the Canadian apatite. Trans. Manchester Oeol. Soc, 18, 18s."). G. M. Daw.son. On the occurrence of pho-sphate in nature. Trans. Ottawa Field Club, I'^SI. itBtfl LITEKATUKE rOSSfLTKD 8:J ) u. J. 15. U. l*i. E. 17. R lf<. A 19. AV 20. U 21. F. •j:i. 24. \V 2r.. o. 2(i. (J. 27. F. A H C. 28. 29. 30. F. Fall inij. On notes on Canatliuu tlii^i- niiatite, Ac. Engin. and Miii. Journ., ISSO. ■Bell. <>n the mi»do of occurrence ut' apatit- in Ca.iJida. Engin. and Min. Journ., 18S6. Coste. Heport on the raining and mineriit statistics }f Cinada. Annual Report Ueol. Surv., Can., Vol. HI., (N.S.) 1S87-H8. A. F. Penrose. Nature anil origin of deposits uf i^lvisv'"**" of lime. Hull. U. S G.-ol. Surv., No. 40, 188s. H. C. Selwyn. Annual Heport. (ieol. Surv. Can. V.)l. IV, (N.S.) 1888-89. . B. M. Davidson. Notes on the geological origin of phosptinte of lime in the United States and Canada. Trans. An;. I.t^*. .Min. Eng., 1892. W. Ells. The phosphate deposits of the t)ftii\v.!. !>htrvt. Canad. Min. Review, XII., 1893. 1». Adams and A. C. Lawson. On aoine Ciinadiiin rjclts containing sciipolite. with a few notes on sime lo-ks associated with the apatite depasits. Can. Record of S.ri., 1S8S. . Lacroix. Contril)Uti;itits ;n Norwpgen. /eitsclir. il. dcutsch. geol. Geo., 27, ls;,"i. Rose. ll>er die rcgelmassigeii Verwii.-hsun^jen der ve.-^ li e- denen Uliininerarten unter einunder sowie rait Penin iir.i Ei>englanz. Her lierl. Akad., 1 162 und IS69. Tschermak. Die (ilimraergruppe. Zeitsclir. f. Krysta!', 2, 1S78. Sandlwrger. I ber Rutil in Phlogopit, Asterisiiius l' s !etz teren, etc. X. Jahrl.. Min., 1882. II. Lacn ix. Sur les inclusions de la phlogopite de Te^iplet-in (Canada). Bull. Soc. Mineral., S, 1885. , Rosenbuscli. MikrfiscojHsche Physiographie der petro- graphistch wichtigen .Mineralien, 1892. Hotfniann. Chemical contributions to the geology of Caniida. RejHirt of Progress, (Jeol. Surv. Can., 1877-7'*. 84 u OTTAWA VALI.KV 31. A. Ciiiiot. rbertlie in der /uiianiiiu-i)»et/un); ilt-s Apatits bed biiilitetei; Vei'scliicdenlieiten. Kull. Si.c. Miii , I'.t, l." Aiiiilyswii. Her clieiii. (JeBt'llnch., iG, i)?tta. ^.I. .1. H, L. Vogt. Heitruu*" zur genetischcn Clashiliration der (liii'ch magnintische DitferviitiatiimsprozcHse uml iltT durcli Priciimatolyse fintstnndenen Erzviirkoiimit'ii. /eit. priikt. (ire!., lf.') :lt. J. V\'. haw^oii. Spt»<;iinoii!* of l'2u/.(>oii Caniidenso and their j;pii!o)j;k-.i1 ami other relatiiiiiM. McUill I'liiverbity, I8SH. ;>'). H. .1. .Ii-.hn«ton-Ijiivi.s and .1. W. Orfgory. Kuzoonal structure of tl.e ejected blocks of Munte Somiiia. Trans. Hoy. I>ul)linSoc., 5, l,s94. 'M'k V. fS'indljerijer. Heitraj; /ur KenntiiiHS de» (iraphits von Ceylon und neiner Bogluifer. Neues Jahrl). .Min., 1HS7, TI. .H7. I'r. (ininlinjj. I'ljer die Minernlvorkomnien von Ceylon. Zeit. nir Kry.itall, :!n, I'JOO. .'i". K. Weinsclienk. Die (Jraj)hitla;;<'rsUitti'ii der in-el Ceylon. Abli. liayr. Akad. Wis.s. 21, 11)00. "1». B. .T. HarrinRton. Notes on a few Canadian minerals and rut!a. K. CoIiPii. riierdes Vorkoniinen von Kisencarbid (Cohenit) ini terre.-trisclien Niokeleisen von Niakoinak bei .Sakobshavn in Nord (iririiland. Meddtlel.ser om Gr.'nland, XV. d^ B i^^t£m^m tiKiH.oiiii .\i. Srn\m <>» ('AK4MA. Vi.i., XII., Mani n. I'MT*; III. l'VHiiXKNKlA|-ATITK'"l'VMl))lKXrr«:." TlIK I.IUIITKll ll.imoN CONSIST!! IIKtiHKICN Al'ATlTK, THK li.VHkKK !■► KriiKI.< I'lllsMATIl Al i.lTK. I'miiX MIXK. (SkK I'AOK 4H|. MKROCOPV IBOWTION TBT CHART (ANSI and ISO TEST CHART No. 2) x IPPLIED IM/CE In 1653 East Mam Street Roctieater. New York 14609 Ui* (716) 482 - 0300 - Phone (716) 288- 5989 -Fox t : !i «iieiii.iK.ii VI. Si lun Mt Cwaha. V"l. Ml., I'AKI O, I I \n Vll. Graphite STKiMiicRs pinchixc oct in (Jhanihh IJxiiiss krom a Orai'Hite vkin — Xkli.vs Pit, Crai'Hitk Citv. 1^ «llM>U»,lrM HlH\»:» l.» (ANAIA. Vol, XII. I'AKI U, I'HTK VIM. 11 Kl... I. S.M'i.l.lTKi.XhIill... \'av,\»i.1 II MINK. .S< \li .ill >; .\M . Al ,. 1 1 K IV MAliT IKMITI/H. ISKK I'.M.t. .•.(I|. Kl... II. LiMK Sll.|r.',TK-llOK\KKI.-i. IKS'slsTlS.. OK I'VIIOXKXK. SOMK AMI'llMiOl.K TrMXlTK. i, ItKiil.lHK )| MlN«ltt .!► I'wjin. N"i Ml . fiHi n. I'l III l\ Kli;*. I. AMI II. L(n{|i'.\l Si'HVKv nr Panaiia. Vol.. XII., I'akt O, 1'i.atk .v. > A»ASI'IIVRI(' COHKOSION VKIN, CRAI'HITK ClTV. (SKK I'Ai:K 70). Flli. III. -ScAPOr.lTE PVIIOXKN-:, lONTACT ROCK, Kli:. IV. - ScAPOLlTE SPMKRfUTK, rONTAfT CV>TK St. I'lKRIIK. (.SkK I'ACiK ImI, RfH'K OK WtK St. I'lKRRK. (SkK P.ViK ti.'i).