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PrintiMl i.. advance iron, the Associaliuii Number of II,,.. Aiiiericau ^ Naturalist. SALKM : NATURALISTS' AGENCY. 1871. SPECIAL NOTICE. We shall issue a DOUBLE NUMBER OF THE AMERICAN NATURALIST, to be called tlie ASSOCIATIOISr jS^UMBER, as 800U as possible after tlie adjournment of the MEETING OP THE ASSOCIATION. This double number will contain the papers read before the Natural History Sections, and will be furnished to subscribers as Nos. 8 and 9 of Vol. 5. The price of single copies will be FIFTY CENTS. Orders are solicited by the PltOPltlKTOKS OF THJE WAT lilt AXIST, The Geognosy of the Appalachians and the Origin of Crystalline Rooks. ADDRESS TO THE AMERICAN ASSOCIATION FOR THE ADVANCEMENT OF SCIENCE, ERRATUM For foot notes on page 45, read * Pogg. Annal. Ixvili, 319. t Amer. Jour. Sci., II, xvi, 218. Printed In advance from tlie Association Number of the American Naturalist. SALEM : NATURALISTS' AGENCY. 1871. i'a%rwvKT^m SPECIAL NOTICE. We shall issue u DOUBLE NUMBER OF TUB AMERICAN NATURALIST, to be culled the ■ reif'm Association, at the close of our meeting at Salem in August, 18G9, it was already feared that failing health would prevent him from meeting with us at Troy, in .1870. This, as you are aware, was the case, and I was therefore called to preside over the Asso- ciation in his stead. In the ;,atumn of 18G9, he was compelled by illness to resign his position of Chancellor of the Washington Uni- versity of St. Louis, and in December last died at the age of filly years, leaving behind him a record to which science and his country may point with just pride. During his connection of fourteen years with the Naval Academy at Annapolis he was the chief instrument in building up that institution, which he left in 1859 to take the chair of Astronomy and Mathematics at St. Louis, where his re- markable qualities led to his selection, in 18G2, for the post of (3) 4 ADDKESa OK T. STKUKY HINT. cliiuiocllor of the miivcrsitv, wliich he lllletl with «;rout credit nnd UHcriiliicH.s u]) to tlic time of liis i'csier time and piiice iitlempt tlie task. All who knew him can however join with me in testityinj>- to his excellencies as a man, an instructor an,- and perplexing pr()i)lcnis for our ^colopaiacliian nionntaii, chain. Xo- where else in the world has a mountain system of sncii ireo«'rai)hi- eal extent and such fi;eolo<«;ical complexity been studied by such ft nunil)er of zealous and learned investif^ators, and no other, it nuiy be conlidcntiy asserted, has fin'nished such vast and imi)ort!int residts to gcolojiical science. The laws of mountain structure, as revealed in the A])palacliians by the labors of the brothers Henry 1). and William 15. Rogers, of Lesley and of Hall, have given to the world the l)asis of a correct system of orot-raphic ireoIoLrv,* and many of the obscure <>;eolo,u;ical |)rol)lems of Europe become plain when read in the light of our American experience. To discuss even in the most summary manner all of the (juestions which the theme suggests, would be a task too long for the present occasion, but I shall endeaAor to-night in the first place to bring before you certain facts in the history of the physical structure, the mineralogy and the paleontology of the Api)alacliians ; and in the second place to discuss some of the i)hysical, chemical and bioh)gical conditions which have presided over the formation of the ancient crystalline rocks that make ni) so large a portion of our great eastern mountain system. J. The Geofjnosy of the Ax>pahiclnan Si/stem. The age and geological relations of the crystalliiu' stratified rocks of eastern North America have for a long time occupied the at- tention of geologists. A section across northern New Yoi-k, from Ogdensbnrg on the St. Lawi'cnce to Portland in Maine, shows the existence of three distinct regions of nnlike crystalline schists. These are the Adirondacks to the west of Lake ('liami)lain, the Green Mountains of Vermont, and the White IMountains of New Hampshire. The lithological and mineralogical ditlcrences between the rocks of these three regions are such as to have attracted the attention of some of the earlier observers. p:aton, one of the * Amer. Jour. Sci., II, xxx, 406. 6 ADDRESS OF T. STKUUY HUNT. fouiulers of American fjcolofjy, at least as early as IH.'J-J. distin- guisheil in his Cieolojiical Text book (2(1 edition) between the gneiss of the Adirontlacks and that of the Green Monntains. Ailopting the then received divisions of i)rnnary, transition, secondary and tertiar}' rocks, he divided each of these series into three classes, which he named carboniferons, (jnartzose and calcareons ; meaning by the lirst schistose or argillaceous strata such as, according to him, might include carbonaceous matter. These three divisions in fact corresponded to olay, sand, and lime-rocks, and were sui)posed by him to be repeated in the same onler in each series. This was apparently the lirst recognition of that law of cycles in sedimenta- tion upon which I afterwardr- insisted in 180.'$.* Without, so far as 1 am aware, defniing the relations of the Adirondacks, he referred to the lowest or carboniferous division of the primar}- series, the crys- talline schists of the Green Mountains, while tiie quartzites and marbles at their western base were made the (juai'tzose and calca- reous divisions of this primary series. The argillites and sandstones lying still farther westward, but to the east of the Hudson Kiver, were regarded as the fu'st and second divisions of the transition series, and were followed by its calcareous division, which seems to have included the limestones of the Trenton group ; all of these rocks being supposed to dip to the westward, and away from the central axis of the Green Mountains. Eaton does not aj)pear to have studied the AVhite INIountains, or to have considered their geological relations. The^- were, however, clearly distinguished from the former by C. T. Jackson in 1844, when, in his report on the geology of New IIami)shire, he described the White Moun- tains as an axis of primary granite, gneiss and mica-schist, over- laid successively, both to the east and west, by what were designa- ted by him Cambrian and Silurian rocks ; these names having, since the time of Eaton's publication, been introduced by English geol- ogists. While these overlying rocks in IVIaiue were unaltered, he conceived that the corresponding strata in Vermont, on the western side of the granitic axis, !iad been changed by the action of intrusive serpentines and intrusive (juartzites, which had altered the Cam- brian into the Green JNlountain gneiss, and converted a portion of the fossiliferous Silurian limestones of the Champlain valley into white marbles. t Jackson did not institute any comjiarison be- * Amer. Jour. Sci., II. xxxv, 100. t Geology of New H!iinj)t-hire, 1(10-102. ^•'5^, (listin- ' the gneiss Adoi)tiii met with in more recent series. The White jNEonntain rockf^ also include beds of micaceous quartzite. The basic silicates in this series are represented chiefly by dark colored gneisses and schists, in which hornblende takes the place of mica. These pass occi- sionally into beds of dark hornblende-rock, sometimes holding garnets. Beds of crystalline limestone occasicually occur in the GEOGNOSY OF THE APPALACHIANS. 9 Tliev ing the schistH of the Wliite Mountain serins, and are sometimes aeeom- panied by pyroxene, garnet, idoerase, si)hene and grapliite, as in the eorresponding roelvs of the Laurentian, wliieli tliis series, in its more gneissic portions, closely resembles, though apparently dis- tinct geognostieally. The limestones are intimately associated with tiie highly micaceous schists containing staurolite, andalusite, cyanitc and garnet. These schists are sometimes highly phnnl>ag- inous, as seen in the graphitic mica-schist holding garnets in Nelson, New Hampshire, and that associated with cyanite in Corn- wall, Conn. To this third series of crystalline schists belong the eoncretionar}^ granitic veins abounding in ber}'!, tourmaline and lepidolite, and occasionally containing tinstone and columbite. (Iranitic veins in the Laurentian gneisses I'rcHiuently contain tour- maline, but have not, so far as yet known, yielded the other min- eral species just mentioned. * Keei)ing in mind the characteristics of these three series, it will be easy to trace them southward by the aid of the concise and ac- curate descrii)tions which I'rof. II. I). Rogers has given us of the rocks of Pennsylvania. In his report on the geology of this state he has distinguislied three districts of various crj'stalline schists, which are by him included together under the name of gneissic or hypozoic rocks. Of these districts the most northern, or the South Mountain belt, to the northwest of the Mesozoic liasin, is said to be the continuation of the Highlands of New York and New .Tersey, which, crossing the Delaware near P^aston, is continued southward through I'ennsylvania and INIaryland into Virginia, where it appears in the Blue Kidge. Tiie gneiss of this district in I'ennsylvania is described as differing considerably from that of the southernmost district, being massive and granitoid, often horn- blendic, with nmch magnetic iron, but destitute of an}' consider- able beds of micaceous, talcose or chloritic slate, which mark the rocks of the southern district. These characters are suflicient to show that the gneiss of this northern district is lithologically as well as geognostieally identical with that of tlie Highlands, and l)elongs like it to the Adirondack or Laurentian system of crys^tal- linc rocks. The gneiss of the middle district of Pennsylvania, to the south of the Mesozoic. but north of the Chester valley, is de- scribed by Rogers as resembling that of the South Mountain or ♦Hunt. Notes on Granitic Kocks; Amer. Jour. Sci., Ill, i, 182, 10 ADDRESS OF T. STERRY HUNT. northern district, and to consist diiefly of white feldspatliic and dark liornblendic gneiss, with very little mica, and witli cr3'stalline limestones. The gneiss of the third or sontliern district, that lying to the south of the Montgomerj^ and Chester valleys, comes from l)eneath the Mesozoic of New Jersey about six miles northeast of Trenton, and stretching southwestward, occupies tlie southern border of Pennsylvania, extending into Delaware and Maryland. It is sub- divided by Rogers into three belts ; the first or southernmost of these, passing through Philadelphia, consists of alternations of dark hornl)lendic and highly micaceous gneiss, with abundance of mica-slate, sometimes coarse-grained, and at other times so line- grained as to constitute a sort of whet-slate. To the northwest- ward the strata become still more micaceous, with garnets and beds of hornblende slate, till we reach the second subdivision, which consists of a great belt of highly talcose and micaceous schists, with steatite and serpentine, and is in its turn succeeded b}'^ a third, naiTow belt resembling the less micaceous members of the first or southernmost subdivision. The micaceous schists of this region abound in staurolite, gurnet, cj^anite and corundum, and are traversed by numerous irregular granitic veins containing beryl and tourmaline. All of these characters lead us to refer the gneiss of this southern district to the third or White Mountain series, with the exception of the midi.e subdivision, Avhich presents the aspect of the second or Green Mountain series. Above the hypozoic gneisses Rogers has placed his azoic or semi-metamorphic series, Avhich is traceable from the vicinity of Trenton to the Schuylkill, along the northern boundary of the southern hypozoic gneiss district. This series is supposed by Rogers to be an altered form of the primal sandstones and slates, and is described as consisting of a feldspatliic quartzite or eurite, containing in some cases porphyritic beds with crystals of feldspar and hornblende, together with various crystalline schists ; includ- ing in fact tlie whole of the great serpentine belt of Montgomery, Chester and Lancaster counties, with its steatites, hornblendic, dioritic, chloritic, and micaceous schists (often garnet-bearing), together with a band of argillite, affording roofing-slates. With this great series are associated chrolnic and titanic iron, and ores of nickel and copper. Veins of albite with corundum also inter- sect this series near Unionville. We are repeatedly assiu-ed by GEOGNOSY OF TIIK APPALACHIANS. 11 Rogers that these rocks so much resemble the un{lerl,yiiiiu'issic' rocks wliich we have (listinlisiied in 1840, it will be seen that he refers to the gneiss of the Ilighlauds two gucissic aicas in Litchfield county ; the one occupying i)arts of Cornwall and Kllsworth. and the other extending from Torrington, northward through Winchester, Norfolk and Colcbrooke into Berk- shire county, Massachusetts. Farther investigations may confirm the accuracy of Percival's identification, and show the Lam'cntian age of these New England gneisses, a view which isai)))arcntly sup- ported by the mineralogical characters of some of the rocks in this region. Emmons informs ns that priniaiy limestones witli graj)hite, (perhaps Lanrentian), are met with in the Iloosic range in Massa- chusetts east of the Stockbridge (Taconic) limestones. The rocks of the second series are tracealtle from southwestern Connecticut northward to the (ireen INIountains in Vermont, and the micaceous schists and gneisses of the third (n- AVhite Mountain series are found both to the east and the Avest of the Mesozoic val- ley in Connecticut and INIassachnsetts. They also occupy a con- siderable area in eastern Vermont, where they are separated from the White Mountain range by an outcrop of rocks of the second series. To the southeast of the Wliite Mountain!-., along our line of section, the same mica-schists and gneisses, often with very mod- erate dips, extend as far as Portland, Maine, where they are inter- rupted by the ontcropping of greenish chloritic and chromiferous schists, in nearly vertical beds, which appear to belong to the sec- ond series. I find that the strata of the second series appear from beneath the Carboniferous at Newport, Rhode Island, in a nearly Acrtical attitude, and also in the vicinity of Boston and Brighton, Saugus and Lynnfield. Their relations in this region to the gneisses with crj'stalllne limestones of Chelmsford, etc., Avhich I have refeiTcd to the Lanrentian series,* have yet to be determined. We have already mentioned that the crystalline rocks of Penn- sylvania pass into Maryland and Virginia, where, as H. D. Rogers * Ainer. Joui\ Sci., II, xlix, 75. GEOGNOSY OF THE APPALACHIANS. 18 informs us, they appear in the mountains of tlie Blue l?i(l}ijo. It remains to be seen whetlier the tluee types wliich we have pointed out in Pennsylvania are to be recognized in tliis region. A great belt of crystalline schists extends from Virginia through Nortli and Sontli Carolina, and into eastern Tennessee, where, according to Safford, these rocks underlie the Potsdam. It is easy. IVom the reports of Liel)ei- on the geology of South Carolina, to identify in this state the two types of tlie (Jreen Mountain and White Moun- tain series. The former, as described I)}' him, consists of talcose, chloritic and ei)idotic schists, with diorites, steatites, actinolite- rock and serpentines. It may be noted that he still adheres to the notion of the erui)tive origin of the last three rocks, which the ob- servations of Ennnous, Logan and myself in the Clreen Mountains have shown to be untenable. These rocks in South Carolina gen- erally dip at very high angles. The great gneissic area of Anderson and Abbeville districts is described by Lieber as consisting of line- grained grey gneisses with micaceous and liornl)lendic schists, and is cut l»y numerous veins of pcgmutiti', holding garnet, tourmaline and beryl. These rocks, which have the characters of the White Mountain series, appear, from the incidental observations to be fonnd in Lieber's reports, to belong to a higher group than the chloritic and serpcntinic series, and to dip at comparatively mod- erate angles. Professor Ennnous, whose attention was early turned to the ge- ology of western New England, did not distinguish between the three types which we have defined, but, like Rogers in Pennsylva- nia, included all the crystalline rocks of that region in the primary system. It is to him, however, that we owe the first correct no- tions of the geological nature and relations of the Green Moiuitains. These, he has remarked, are often made to include two ranges of hills belonging to different geological series. The eastern range, including the lloosic Mountain in Massachusetts, and Mount Mansfield in Vermont, he referred to the primary ; which he de- scribed as including gneiss, mica-schist, talcose slate and horn- blende, with beds and veins of granite, limestone, serpentine and trap. He declared, moreover, that there is no clear line of de- marcation among the various schistose primary rocks, and cited, as an illustration, the passage into each other of serpentine, stea- tite and talcose schist. His description of the crystalline rocks of this range will be recognized as comprehensive and truthful. 14 ADDRESS OK T. STEKUY HUNT. To the west of tlie hills of pruniuy schist, ho placed his Taconic system, named from the Tacoiiie hills, whieh run from north to south alonjj; the boundary line of New York and Massachusetts and form a ran1), in an elaborate study of tlie Taconic question, Barrande heads a section thus. " lienversemeiit conqu pour tout tin nysteme," and then proceeds to show that the rcnrernement or overturn is only apparent, by explaining, in the language of Emmons, the view alre.idy set forth above. X Geology of the Southern District of New York, p. 438. OEOflNOSY OF THE APPALACHIANS. 17 caiiHcd tlio S thus pro- oir prosoiit II Hpoiikiiif? iconio Hys- lilc l.y Mr. side of fill) ' till' cliuiii, elsewhere iiiinceil by iiti'i'tuined Si/tifcm (p. rn base of il.ying the zoologists. bcCoro the gtoM, crit- )in Stock- H. Rogers losophical le (piartz- rblo iden- tlic asso- igo of the say. pri- tho same isiou was er group, ither was I it, and 427, xxxiii, ein-psented e, without c. IJool. (le iiulc heads Is lo show mgiiage of cluimed that Ilitchoock hold a siiiiilar view. It will bo scon that thoHo geologists thus uiiilod in one groiii), the sohists of the Iloosic range (regarded by Knnnons as primary), with those of the Tu- conio range, and referred both to the age of the Chaniplain divis- ion, the whole of which was supposed to be included in the group. In the same address Professor Uogors raised a very important question. Having referred to the I'otsdam sandstone, which on Lake Chami»lain forms the base of the paleozoic Hysteni, he in- quires, "Is this formation then the lowest limit of our Appalachian masses generally, or is the system expanded downward in other districts by the introduction beneath it of other conformable sed- imentary rocks?" He then proceeded to state that from the Sus- quehanna River, southwostward, a more complex series appears at th'.f base of the lower limestone than to the north of the Schuylkill, and ill some parts of the lUue Ridge he includes in the primal di- vision (beneath the Calciforous saiidrock) "at least four indepen- dent and often very thick deposits, constituting one general group, in which the Potsdam or white sandstone (with Scolithus) is the second in descending order." This sandstone is overlaid by many hundred feet of ai'enaceous and ferriferous fucoidal slate, and un- derlaid by coarse sandy shales and flagstones ; below which, in Virginia and East Tennessee, is a series of heterogeneous con- glomerates, which rest on a great mass of crystalline strata. The accuracy of these statements is confirmed by Salford, who, in his recent report on the geology of Tennessee (1869), places at the base of the column a great series of crystalline schists, apparently representatives of those of southeastern Pennsylvania. Upon these repose what Satford designates as the Potsdam group, in- cluding, in ascending order, the Ococee slates and conglomerates, estimated at 10,000 feet, and the Chilhowee shales and sandstones. 2,000 feet or more, with fucoids, worm-burrows and Scolithus. These are conformably overlaid by the Knoxville division, con- sisting of fucoidal sandstones, shales, and limestones, the latter two holding fossils of the .age of the Calciforous sandrock. It is noteworthy that these rocks are greatly disturbed bj' fixults, and that in Chilhowee Mountain the lower conglomerates are brought on the east against the Carboniferous limestone, by a vertical dis- placement of at least 12,000 feet. The general dip of all these strata, including the basal crystalline schists, is to the southeast. The primal paleozoic rocks of the Blue Ridge were then by Rog- AMER. NAT., ASSOC. NUMBER. 2 IH ADDUKSS OK T. aTKUUV HUNT. orH, lis now by SiiUhnl, lookod upon uh wliolly of I'otsdsim m^c, in eluding tlio ScolitlniH Hiindstonc as ii Hnl)ordin!itt' nioinl)i>r, ho Unit the strata iMMieath tliis wero still rogiirdcd u.s lu'lon«fing to tlu? New York Hystouj. Ilenee, while Rogers inciuires wlu'ther the Taeonie system "iniiy not along the western border of Vermont and Mas- saehiisetts inelude also scjuie of the huikIv and slaty strata here spoken of as lying l»eueath the I'otsdam sandstone"* ho would still embrace these lower strata in the Champlain division. Thus wo see that at an early period tho rocks of the Taconic system were, by Kogers and Mather, referred to the Chauiplain divi- sion of the New York system, a eonchision wliieh 1ms l»een sus- tained by subse(|uent oi»servations. IJcfore diseiissing these, and their somewhat involved history, we may state two (luestions which present themselves in connection with this solution of the problem. First, whether the Taconic system, as defined l)y Kinmons, includes the whole or a part of tlu^ C'liMuiplain division ; and second, wheth- er it embraces any strata older or newer than Ww iniMiibers of this portion of tho New York system. With reference to the tirst question it is to bo remarked that in their attempts to compare the Taconic rocks with those of the CHiampliiln division as seen farther to the west, observers were led by litliological similarities to iden- tity the upper members of the latter with certain portions of the Tac3. fGcol. Northei'u District of New York, pp. 121, 125. (IE0ONO9V OF THE APPALACHIANS. 19 Tliin view of KiiiinonH ns to tho (iu('l»e(! rocks was luloptcd l)y Sir Williiim Loij;iiii, when, u fisw yours iiltcrwanls, Ik* ln'j^iin to study tlu! goolof^y of that rej;H)n. Tho Haiul.stone of Sillory wuh (IcHcribod by him as corrospoiidiiif^ to tlio Onuida or Sluiwaiif^imk eon western base of the Appalach- ians into Vermont and Massaithusetts, they were found to bo a continuation of the Taconic system, which Sir William was thus led to refer to the upper half of the Chumplain division, as had already been done by I'roft'ssor Adams in IMI7.t As retfards the crystalline strata of the Appalachians in this region, he, however, rejected the view of Emmons, and nuuntained that put forward by the Messrs. Rogers in 1841, viz., that these, instead of being older rocks, were but these sanie upper formations of the C'hamplain division in an altered condition; a view which was maintained dur- ing several years in all of the publications of those connected with the geological survey of Canada. This conclusion, so far as regards the ago of the unaltered fos- siliferous rocks from Quebec to Massachusetts, was sui)i)osod to be conlirmed by the evidence of organic remains found in them in Vermont. Mr. Eunnons had described as characteristic (»f the upper part of the Taconic system, two crustaceans, to wiiicli he gave the names of Atojxt trilineatus and EHiidocfphalHs cmiphnidPH ; the other fossils noticed by him being graptolites, fucoids, and what were apparently the marks of annelids. In 1847 I'rofessor James Hall, in the lirst volume of iiis raleontology, declared the Atops of Enunous to l)e identical with Triarthi'iiH {('dliiinoK') liccl-il, a char- acteristic fossil of the Utica slate ; while the EUiptocephalus was referred by him to the genus Olenns, now known to belong to the primordial fauna of Sweden, where it is found in slates lying l)e- neath the orthoceratite limestone, and near the base of the paleo- zoic series. Although, as it now appears, the geological horizon of the Olenus slates was well known to Ilisinger, this author in his classic work, Lcthma Suecica, published in 1837, represents, by some unexphiined error, these slates as overlying the orthoceratite *Gc()l. Survey of Canada, 1S17-18, pp. 27, 57; and Amer. .Tour. Sci., II, ix, 13. t Aincr. Jour. Sci., II, v, lOiJ. 20 ADDUESS OF T. STERRY HUNT. limestone, which is the equivalent of the Trenton limestone of the Champlain division. Ilence, as Mr. Barrande has remarked, Hall was justified by the authority of Hisinger's publislied work in as- signing to the Olenns slates of Vermont a position above tiiat lime- stone, and in placing them, as he then did, on the horizon of the Hudson River or Lorainc shales. The double evidence atfonled by these two fossil forms in the rocks of \'^crmont, served to confirm Sir William Logan in placing in the upper part of the Champlain division the rocks which he regarded as their stratigraphical equiv- alents near Quebec ; and which, as we have seen, had some years before been by Emmons himself assigned to the same horizon. The remarkable compound graptolites which occur in the shales of Pointe Levis, opposite C^uebcc, Avere described b}' Professor James ILall in the report of the Geological Survey of Canada for 1857, and were then referred to the Hudson River group ; nor was it until August, 1860, that Mr. Billings described from the lime- stones of this same series at Pointe Levis a number of trilo])ites, among which were several species of Agnostus, Dikelocophalus, Bathyurus, etc., constituting a fauna whose geological horizon he decided to be in the lower part of the Champlain division. Just previous to this time, in the Report of the Regents of the University of New York for 1859, Professor Hall had described and figui'cd by the name of Olenus, two species of trilobites from the slates of Georgia, Vermont, which Ennnons had wrongly referred to the genus Paradoxides. They were at once recognized by Bar- rande, who called attention to their primordial character, and thus led to a knowledge of their true stratigraphical horizon, and to the detection of the singular error in Hisinger's book, already noticed, by which American geologists had been misled.* Thoy have since been separated from Olenus, and by Professor Hall referred to a new and closely related genus, which he has named Olenellus, and which is now regarded as belonging to tiie horizon of the Pots- dam sandstone, to which we shall presently advert. Farther studies of the fossiliferous rocks near Quebec showed the existence of a nia'is of sediments estimated at about 1200 feet, holding a numerous fauna, and corresponding to a great development of strata about the age of the Calciferous and Chazj* formations, or more exactly to a formation occupj'ing a position *For the correspondence on this matter between Barrande, Logan and Hall, see Amer, Jour. Sci., II, xxxi, 210-2iJ«. GEOGNOSY OF THE APPALACHIANS. 21 between these two, and constituting, as it were, beds of passage between them. In this new formation were inehuled tlie grapto- lites ah'eady described by Hall, and the numerous Crustacea and brachiopoda described by Billings, all of which belong to the Levis slates and limestones. To these and their associated rocks Sir William Logan then gave the name of the Quebec group, including, besides the fossiliferous Levis formation, a great mass of overlying slates, sandstones and magnesiau limestones, hithei'to Avithout fos- sils, which have been named the Lauzon rocks, and the Sillery sandstones and shales, which he supposed to form the summit of the group, and which had attbrded onl}- an 01)olella and two species of Lingula ; * the volume of the whole group being about 7000 feet. The paleoutological evidence thus obtained by Billings and by Hall, ])oth f'om near Quebec and in Vermont, led to the conclusion that the strata of these regions, so much resembling the ui)por members of the Champlain division, were really a great tlcvelop- ment, in a modified form, of some of its lower portions. Their apparent stratigraphical relations were explained by Logan by the supposition of "an overturned anticlinal fold, Avith a crack and a grout dislocation running along tin- suirrrnit. Ivy »iilch ihe (Quebec group is brought to overlie the Hudson Kiver group. Sometnnes it may overlie the overturned Utica formation, and in Vermont points of the overturned Trenton appear occasionall}' to emerge from l)eneath the overlap." lie, at the same time, declared that ■'from the physical structure alone, no person would suspect the lu'Ciik that must exist in the neighborhood of Quebec, and, without the evidence of fossils, every one would be authorized to deny it."t The rocks from western Vermont, which had furnished to Hall the species of Olenellus, have long been known as the Red sand- rock, and as we have seen, were by Emmons, in 1842, referred to the age of the ^Medina sandstone, a view which the late Professor Adams still maintained as late as 1.S47. 1 In the mean time Emmons had, in IS");"), declared this rock to represent the Cal- oiferous and I^)tsdam formations, the brown sandstones of Bur- lington and Charlotte, Vermont, I»eing referred to the latter. § * See Billings, Paleozoic Fossils of Cnnadft, p. C9. tI>ogan'8 letter to narrniKlo, Amer. Jour. Sci.. II. xxxi,2is. The true date of this letter was DeceinlK'r .'!lst, 18110. but, by a misprint, it is made 1831. t Adams, Amer. .Tour. Sci.. II. v, 108. s Enimous. American Geology, II, 128. 22 APDRESS OF T. STERRY HtTNT. This conclusion was confirmed bj^ Billings, who, In 1861, after vis- iting the region and examining the organic remains of the Red sandrock, assigned to it a position near the horizon of the Pots- dam.* Certain trilobites found in this Rod sandrock by Adams in 1847, were by Hall recognized as belonging to the European genus Conocephalns {=. ConocephaUt.es and Conocoryphe), whose geological horizon was then undetermined. t The formation in question consists in great part of a red or mottled granular dolo- mite, associated Avith beds of fucoidal sandstone, conglomerates and slates. These rocks were carefully examined by Logan in Swanton, Vermont, where, according to him, the}' have a thick- ness of 2200 feet, and include toward their base a mass of dark colored shales holding Olenellus Avith Conocephalites, Obolella, etc. ; Conocephalites Teucer, Billings, being common to the shales and the red sandy beds.| IMany of those fossils are also found at Troy and at Bald Mountain, New York, where they accompany the Atops of Emmons, now recognized by Billings as a species of Conocephalites. A similar condition of things extends northeastward along the Appalachian region. On the south side of the St. Lawrence below Quebec a great thickness of limestones, sandstones, and slates, formerly referred to the Quebec group, is now regarded by Billings as, in i^art at least, of the Potsdam formation ; Avhile on the coast of Labrador, and in northern Newfoundland the same formation, characterized by the same fossils as in Vermont, is largely devel- oped, attaining in some parts, according to Murray, a thickness of 3000 feet or more. Along the northern coast of the island it is nearly horizontal, and appears to be conformabl}' overlaid by about 4000 feet of fossiliferous strata representing the Calcifcrous sand- rock and the succeeding Levis formation. Mr. Billings has described a section from the Laurontian of Crown Point, New York, to Cornwall, Vermont, from which it ap- pears that to the eastward of a dislocation which brings up the Potsdam to overlie the higher members of the Champluin division, the Potsdam is itself overlaid, at a small angle, by a great mass of limestones representing the Calcifcrous, and having at the summit some of the characteristic fossils of the Levis formation. Next in * Ainer. Jour. Sci., II, xxxii, 2;!2. tlbiil.. II, xxxiii. ;i74. t Geology of Canada, 1803, p. 261. Aiiier. .Tour. Sci., II, xlvi, 221. GEOGNOSY OF THE APPALACHIANS. 28 of ascending order are not less than 2000 foet of limestones with Trenton fossils (embracing probably the Chazy division) , while to the east of this the Levis again appears, including the white Stock- bridge limestones. * "We have here an evidence that the augmen- tation in volume observed in the lower members of the Champlain division in the Ai)palachian region extends to the Trenton, which to the west of Lake Champlain is represented, the Chazy included, by not more than 500 feet of limestone. The Potsdam, in the latter region, consists of from .'iOO to 700 feet of sandstone holding Cono- cephalites and Liugulella, and overlaid by 300 feet of magncsian limestone, the so-called Calciferous sandrock. In the valley of the Mississippi these two formations in Iowa, Missouri, and Texas. are represented by from 800 to 1 300 feet of sandstones and mag- ncsian limestones, while in the Black Hills of Nebraska, according to Ilaydon, the only representative of those lower formations is about one hundred feet of sandstone holding Potsdam fossils.t In striking contrast to this it has been shown that along the Appalachian range from Newfoundland to Tennessee these lower formations are represented by from 8000 to 15000 feet of fossil- iferous sediments. It has been suggested by Logan that these Avidely dift'ering conditions represent deep-sea accunmlations on the one hand, and the deposits from a shallow soa which covered a submerged continental plateau, on the other ; the sediments in the two areas being characterized by a similar fauna, though ditfering greatly in lithological characters and in thickness. To this we may add that the continental area, being probably submerged and el- evated at interv.als, became ovei'lnid with bods which represent only in a partial and imperfect majiner tlie great succession of strata which Avere being accumulated in the adjacent ocean. | In a paper which I hope to present to the geological section during the present mooting of the Association it will be shown from a study of tlie rocks of the Ottawa l)asin that the typical Champlain division not only presents important paleontological breaks, but evidences of statigraphic.al discordance at more tiian one horizon over the continental area, which, as the result of widely spread movements, might be supposed to be represented in the Appalachian region. In the latter Logan has already observed * Anicr. .Ti)ur. sci.. 227. t Ibid.. H, XXV. 4;i!i, xxxi. 234. : Ibid.. II, xlvi. 225. ,--^-- 24 ADDRESS OF T. STERRY HUNT. HI Hi that the absence of all but the highest beds of the Levis along the eastern limit of the Potsdam, near Swanton, Vermont, while the whole thickness of them appears a little farther westward, makes it probable that there is a want of conformity between the two ; and 1 have in this connection insisted npon the entire absence in this locality of the Calciferous, which is met with a little farther south in Ihe section just mentioned, as another evidence of the same unconformity.* There are also, I think, reasons for sus- pecting anotiier stratigraphical break at the summit of the C^nebec group, in which case many problems in the geological structure of this region will be nuich simplified. It should be remembered that the conditions of deposition in some areas have been such that accumulations of strata, corres- ponding to long geologic periods, and elsewhere marked by strati- grai)hical ])reaks, are arranged in conformable superposition ; and moreover that movements of elevation and depression have even caused great paleontologlcal breaks, which over considerable areas are not marked by any apparent discordance. Thus the remarka- ble break in the fauna between the Calciferous and the Chazy is not accompanied by any noticeable discordance in the Ottawa basin, and in Nel)raska, according to llayden, the Potsdam, Carbonifer- ous, Jurassic and Cretaceous formations are all represented in about 1200 feet of conformable strata.! In Sweden the whole series from the base of the Cambririu to the sunnnit of the Upper Silurian appears as a conformable sequence, while in North Wales, altiiough tiiere is no apparent discordance from the base of the Cambrian to the sunnnit of the Lingula flags, stratigraphical breaks, according to Kamsay, probably occur both at the base and the summit of the Tremadoc slates, I Avhich are considered equiva- lent to the Levis formation. We have seen that, according to Logan, a dislocation a little to the north of Lake Champlain causes tlie (Quebec group to overlie the higher members of the Cha-ni)lain division. The same uplift, according to him, brings up, farther south, the Red sandrock of Vermont, which to the west of the dislocation rests upon the up- turned and inverted strata of various formations from the Calcif- erous sandrock to the Utica and Hudson River shales. These * Anier. Jour, Sci., II, xlvi, 225. t Ibid., II. XXV, 440. i Quai'. Geol. Journal, xix, page xxxvi. GEOGNOSY OP THE APPALACHIANS. 25 latter, according to him, are seen to pass for considcraljle distances beneath nearly horizontal laycr.s of the lied sandrock, the Utica slate, in one case, holding its characteristic fossil, Triarthrns lieckil. This relation, which is well shown in a section at St, Albans, fig- nred by Hitchcock,* was looked upon by Eninions and by Adams as evidence that the Red sandrock was the representative of the Me- dina sandstone of the* New York system. AVhen, however, the former had recognized the Potsdam age of the sandrock, with its Olenollus. Avliich ho supposed to be Paradoxides, this conditi(m of things was conceived to be an evidence of the existence beneath the Potsdam of an older and unconformable fossiliferous series already mentioned. The objections made bj-^ Emmons to Pogers's view of the Cham- plain iige of the Taconic rocks were three-fold : first, the great dif- ferences in lithological characters, succession and thickness, be- tween these and the rocks of the Cliamplain division as previously known in New York ; second, the supposed unconformable infra- position of a fossiliferous series to the Potsdam ; and third, the dis- tinct fauna which the Taconic rocks were supposed to contain. The first of these is met by the fact now established that in the Appa- lachian region, the Champlain division is represented by rocks having, with the same organic remains, very different lithological characters, and a tliickness ten-fold greater than in the tj'pical Chami^lain region of northern New York. The second objection has already been answei'ed l)y showing that the rocks which pass beneath the Potsdam Jire really newer strata belonging to the upper part of the division, and contain a characteristic fossil of the Uti- ca slate. As to the third point, it has also been met, so far as regards the Atops and EUiptocephalus, by showing these two genera to belong to the Potsdam formation. If we inquire farther into the Taconic fauna we find that the Stockbridge limestone (the Eolian limestone of Hitchcock), which was placed by Emmons near the base of the Lower Taconic, (while the Olenellus slates are near the summit of the Upper Taconic), is also fossiliferous, and contains, according to the determinations of Professor Hall, species belonging to the genera Euomphalus, Zai)h. ontis, Stromatopora, Ciiaetetes and Stictopora.f Huch a fauna would lead to the cou- * Geology of Vermont, p. 374. t Geology of Vermont, 419, and Amer. Jour. Sci., 11, xxxiii, 419. 26 ADDRESS OF T. STERRY HUNT. elusion that these limestones instead of being older, wei-e really newer than the Olenellus beds, and that the apparent order of suc- cession was, contrary to the supimsition of Emmons, the true one. This eonohision was still farther confirmed by the evidence ob- tained in 1H(\H by IMr, IJillings, who found in that region a great number of characteristic species of the Levis formation, many of them in beds immediately above or beloAT the white marl ties,* which latter, from the recent observations of tiic Rev. Augustus Wing in the vicinity of Jutland, A''ermont. would seem to l)e among the upper l)eds of the I'otsdam formation. Thus wliile some of the Taconic fossils belong to the Potsdam and Utica formations, the greater number of them, derived from beds sup- posed to be low down in the system, are shown to be of the age of the Levis formation. Tliere is, therefore, at present, no evi- dence of the existence, among tlie unaltered sedimentary rocks of the western base of the AppMlachiaus in Canada or New England, of any strata more ancient than those of the Champlain division, to which, from their organic remains, the fossiliferous Taconic rocks are shown to belong. Mr. Billings lias, it is true, distiuguislied provisionally wliat he has designated an upper and a lower division of the I'otsdam, and has referred to the latter the Ked sandrock with the Olenellus slates of Vermont, together with beds holding simihii- fossils at Troy, New York, and along the straits of Bellisle in Labrador and Newfoundland ; the upi)er division of the Potsdam being repre- sented by the basal sandstones of the Ottawa basin and of the Mississi2)pi valley .f In the present state of our knowledge of the local variations in sediments and in their fauna dependent on depth, temperature and ocean currents, Billings, however, con- ceives that it would be i)rematui"e to assert that these two types of the Potsdam do not rej)resent synchronous deposits. The base of the Champlain division, as known in the Potsdam formation of New York, of the Mississippi valley and the Appa- lachian belt, does not, however, represent the base of the paleozoic series in Europe. Tlie Alum slates in Sweden are divided into two parts, an upper or Oleuus zone, and a lower or Conocoryphe zone, as distinguished by Angelin. The latter is characterized by * Arier. Jour. Sci., II, xlvi.227. t Report Geol. of Canada, ISfiS-Ofi, p. 230. GEOGNOSY OK THE ArrALACIlIANS. 27 age the goniis Paradoxides, wliicli also occupies a lower division in the primordial paleozoic rocks of IJoheniia (Barraude's stage C), the greater part of which are regarded as tlie equivalent of the Olenus zone of Sweden and tiie Potsdam of North America. The Lingula flags of Wales belong to the same horizon, and it is at their Ijase, in strata once referred to the Lower Lingula flags, that the Paradoxides is met with. These strata, for which Hicks and Salter, in 1H0;>, proposed the name of the Menevian groni). are regarded as corresponding to the lower division of the Alum slates, and, like it, contain a fauna not yet recognized in the basal rocks of the New York S3'stem. Wc here approach the debatable land between the Cambrian and the Silurian of the British geologists. The Cambrian, as originally claimed l»y Sedgwick, inclu(le(l in its upper division the Middle and Upper Lingula flags, with the over- lying Tremadoc slates, to the base of the Llaudeilo rocks, and may be regarded as equivalent to the Potsdam, C'alciferous and Levis formations ; while in the Lower Cambrian were embraced the Lower Lingula flags and the Upper and Lower Longmynd rocks, corres- ponding respectively' to the Harlech grits and the Llanberis slates. A portion of the Cambrian has, however, l)een claimed for the Silurian by Murchison, who draws the dividing line at the top of the Longmynd rocks, leaving the three divisions of the Lingula flags in the Silurian. Lj-ell, on the contrary, remarks that the .Menevian beds, which were, on lithological grounds, made by Sedgwick a part of the Lower Lingula flags, have been sliown by Hicks and Salter to be ver}' distinct from these paleoutologi- cally ; and, while he includes the Menevian in the Lower Cam- brian, refers the whole of the Lingula flags to the Upper Cambrian. Lyell therefore admits the Avhole of the Cambrian system as oriijinally defined by Sedgwick, and the same classification is noAV adopteil by Linarsson, in Sweden, where in Westrogothia, the Cam- brian rocks, (resting unconformably on the crystalline schists to be noticed farther on), ai'e overlaid conformably by the orthoceratite lime&tones, which are by him regarded as forming the base of the Siluri'iu, and as the equivalent of the Llandeilo rocks of Wales. The total thickness of these lower rocks in Sweden, including the representatives of the Lingula flags, the JNIenevian beds and an underlying fucoidal (Eophyton) sandstone, is only three hundred feet, while the first two divisions in Wales have a thickness of five to six thousand, and the Harlech grits and Llanberis slates i 28 ADDUKSS OV T. STKUUY HUNT. ili 11 (including the Welsh roollng-slivtes beneath) amount to eight thou- sand feet additional. Recent researches show that these lower rocks in Wales contain an altundant launa, extending downward soinc^ 2S()() I'eet from the JNIeneviau to the very base of strata re- garded as the representatives of tiie Ilarledi grits. The brachio- poda of the Harlech beds appear identical with those of the Men- evian, but new species of Conoccphalites^ Micwdiscits and Para- doxidcs are met with, besides a new genus, Phitonia, allied to the last mentioned. Mr. Hicks, to whom wc owe these discoveries,* remarks, tliat the Menevian gives us, for the present, a well marked paleontological horizon for the summit of the Cambrian, corres])onding with the Lower Cambrian as defined by Sedgwick. The Upper Cambrian in North America would thus include the lower half of the Champlain division from the base of the Potsdam to the sunnnit of the Levis (including perliaj)s the Chazy), while the Lower Cambrian, (the Caml)rian of Murchison and liicUs) is represented by the strata holding Paradoxides in Newfoundland, New Brunswick and eastern Massachusetts. Although no strata marked l»y these fossils have yet been found in the Appalachians, it is not improbable that such may yet be met with. In May, 1861, I called attention to the fact tliat beds of (piartzose con- glomerate at the base of the Potsdam in llemniingford, near the outlet of Lake Champlain on its western side, contain fragments of green and black slates, "showing the existence of argillaceous slates before the dtiposition of the Potsdam sandstone." f The more ancient strata, which furnished these slat}- fragments to the Potsdam conglomerate, have perhaps been destroyed, or are concealed, but they or their equivalents ma}- yet be discovered in some part of the great Appalachian region. They should not, however, be called Taconic, l)ut receive the prior designation of Cambrian, unless, indeetl, it shall appear that the source of these slate fragments was the more argillaceous beds of the still older Huronian schists. Emmons regarded his Taconic sj'stem as the e([uivalent of t)ie Lower Cambrian of Sedgwick, but when iu 1842, Murchison announced that the name of Cambrian had ceased to have any zoological significance, l)eing identical with Lower Silurian,} Emmons, conceiving, as he tells us, that all *Geol. M:(g., V, 30(!; jmil Hep. Brit. Assoc, ]8(58, i). 09; also Hiukness uuU Hicks in Nature, Proc. Gcol. Soc, May 10, 1871. t Amer. Jour. Sci., IF, xxxi. 404. t Proc. Geol. Soc, London, HI, 042. GE0(JN08Y OF TIIK AI'I'ALACIIIANS. 29 Cambrian rockH were not Silurian, instead of niaintaiiiinly Canihrian," and states as a reason for that opinion, that tliey are connected by certain hi'ds of interniediato litholojiical characters with strata of uiulonhted Cambrian a<;c.* These, iiowever, as he achnits, present great local variations, and, after carefully scannin<>; tlu^ whoh^ of the (nidencc; adduced, 1 am inclined to see in it nothiiifj; more than the existence, in this rej^ioii, of Cambrian strata made up from the ruins from the great mass of pre-Cambrian schists, which are the crystalline rocks of Anglesea. Such a phenomenon is repeated in numerous instances in our North American rocks, and is the true explanation of many supposed examples of passage from crystalline sciiists to uncrys- talline setliuients. The Anglesea rocks are a highly inclined and much contorted series of (juart/ose, micaceous, ehloritic and epi- dotic schists, with diorites and dark coloreil chromiferouH serpen- tines, all of which, alter a careful examination of them in the colh'ctions of the (icological Survey of Great Britain, appear to me identical with the rocks of the (ireen jMonntain or Iluronian series. A similar view of their age is shared by riiillips and b\' Sedgwick, in opposition to the opinion of the British survey. The former asserts that the crystalline schists of Anglesea are '• below all the Cambrian rocks ;"■)■ while Sedgwick expresses the opinion that they are of '' a distinct epoch from the other rocks of the dis- trict, and evidently older."]: Associated with the fossiliferons Devonian rocks of .the lihine, is a series of crystalline schists, similar to those just noticed, seen in the Taunus, the Ilundsriick and the Ardennes. These, in opi)0- sition to Dumoiit, who regarded them as belonging to an older system, are declared by Kiinier to have resulted from a subse(iucnt alteration of a portion of the Devonian sediments. § Turning now to the Highlands of Scotland, Ave have a similar series of crystalline schists, presenting all the mineralogical char- acters of those of Norway and of Anglesea, Avhich, according to Murehison and Giekie, are neither of Cambrian nor pre-Cambrian age, but are ^younger than the fossiliferons limestones of the west- *Geol. of N'oitli AVilles, pp. 145, 175. t Jlunual of Cieology (18r>3) 89. t (ieol. .Touinal fur 1815, WO. § Naumauu, Geoguosie, 2d edition, II, 38.3. OKOUNOSV OK TIIK Al'l'ALACIIIANS. 31 ir era coiiHt (iihoiit Ww horizon ol tlif L«^vi.s roniiiitioii) whicli hccui to pass lH>iu>iitli tliein. Profossor Nifol,on (he coiitniry, iiiaintiiiiiH that tills uppurcnt supor-poHition is *hie to iipiiftN, uiul that these crystal lino schists iirc really older than either Caiiil)ri!iii or Silurian, both of which :ii)pear to the west of them as uncryHtalliiie .sedi- ments, resting on the Lanrentian. lie does not, however, con- i'onnd tliesi' crvHtalline seliists of the Scottish l!i;j;iilands with the Laurentian, from whi(rh they dilfer uiineraloards them as a distinct series.* In the presenct; of the ditferences of opinion which have been shown in this controversy, we may be permitted to ask whether, in such a ease, strati<>;ra|»hical evidence alone is to be relied upon. Ki'peated examples have shown that the most skilful strati^rai)liists may be misled in studyiufj; the structure of a disturlx'd re<>ion where there arc no organic remains to guide them, or where unexpected faults and overslides may deceive even the most sajfacious. I am convinced that in the study of the crystalline schists, the persistence of certain mineral characters nuist be relieKK8S OF T. HTKUUY IIl'NT. I nm ooiniiiood thiit tliOHc crvHtnlliiio schlslm of riormniiy, Aii<^lo- Hoa, iiiid the Scolcli IIi<{liliiii(ls, will ho round, like those of Nor- wiiy, to holonjj; to ii period anterior to the deposition of the Canihrian sediments, and will eoi'ros[)ond with the newer fi;neissie series of our ApiJuhieliian ree(lded miea- schists with andalusit*', stainolite and cyaniti'. which are met with in Arj;;yleshii'e, Alierdeenshire, Hanll'shire and the Shetland Isles. Rocks rej^arded hy Ilarkness us identical with these of the Scottish Ilitfhiands also occur in l)onean jnsstily still farther this comi)arison,for not only the more schistose beds of the Green Monn- taiji series, bnt even the mica-schists of the third or White jNIonntain series, with stanrolito and garnet, are represented in Michigan, as appears by the recent collections of Major li rooks, of the Geolog- ical Survey of Michigan, kindly placed in mj' hands for examina- tion, lie informs me that tliese latter scliists are the highest of the crystalline strata in the northern peninsula. To the north of Lake Superior, as I have already shown else- where, the schists of this third series, which, as early as 1861, 1 compared to those of the Appalachians, are widely spread ; while in Hastings County, forty miles nortli of Lake Ontario, rocks nav- ing the mineralogical and lithological characters both of the second and third series are found resting on the first or Laureu- tian, the three apparently unconformable, and all in turn overlaid by horizontal Trenton limestone.* We have shown, that in Pennsylvania, while some of these schists of the second and tliird series were regardey (1- i;ir fo led + + From the part which the ruins of these rocks play in the produc- tion of succeeding sediments it is not always easy to define the limits between the ancient mica-schists and the Camln-ian strata in these northeastern regions. It is not impossible that the two may grad- uate into each other, as some have supposed, in Newfoundland and Nova Scotia, but until farther lij^'ht is thrown upon the sultject I am disposed to regard the relation between the two as one of der- ivation rather than of passage. We have already alluded to the history of the rocks of the White Mountains, formerly looked upon as primary, and b}-^ Jack- son described as an old granitic and gneissic axis uplifting the more recent (Jreen Mountain rocks. Their manifest differences from the more ancient gneiss of the Adirondacks, and their apparent super- position to the Green Mountain series, then regarded by the Messrs. Rogers as belonging to the Champlain division, led them in 1H4(! to look upon the White Mountains as altered strata be- longing to the Levant division of their classification, correspond- ing to the Oneida, Medina and Clinton of the New York system. In 1848 Sir William Logan came to a somewhat similar conclusion. Accepting, as we have seen, the view of Emmons that the strata about Quebec included a portion of the Levant division, and re- garding the Green INIountain gneisses as the equivalents of these, he was induced to place the AVhite Mountain rocks still higher in the geological series than the Messrs. Rogers had done, and ex- pressed his belief that they might be the altered repi*esentatives of the New York system from the base of the Lower Helderberg to the top of the Chemung ; in other Avords, that they were not Middle Silurian, but Upper Silurian and Devonian. This view, adopted and enforced by me,* Avas farther sui)ported by Lesley in 18. . 40 AI>I)UKSS OF T. STEURY HUNT. soda, leaving ])chin(l silica, alumina and potasli — tlie elomonts of granitic, gneissic and tracliytic rocks. Tlic liner and more alumi- nous sediments, including the ruins of the soft and easily al)raded silicates of tlie pyroxene group, resisting the penetration of the water, will, on the contrary, retain their alkalies, lime, magnesia and iron, and tlnis will have the composition of the more basic rocks. * A little cousideration will, however, show that tliis process, al- tliough doubtless a true t;auHe of dirt'erences in the composition of sedimentary rocks, is not the only one, and is inadequate to ex- plain the production of many of the varieties of stratified silicated rocks. Such are serpentine, steatite, hornl)lende, diallage, chlorite, pimte and labradorite, all of which mineral species form rock-masses b}"" themselves, frequently almost without admixture. No geologi- cal student will now (juesticm that all of these rocks occur as mem])ers of stratified formations. Moreover, the manner in which serpentines are found interstratifled with steatite, chlorite, argillite, diorite, hornblende and feldspar rocks, and these, in their turn, with(|uartzites and orthoclase rocks, is such as to forbid the notion that these various materials have been deposited, with their present composition, as mechanical sediments from the ruins of preexist- ing rocks ; a hypothesis as luitenable as that ancient one which supposed them to be the direct results of plutonic action. There are, however, two other h3'potheses which have been pro- posed to explain the origin of these A'arious silicated rocks, and especially of the less abundant, and, as it were, ex<'Oi)tional species just mentioned. The first of these supposes that the minerals of which thej'^ are composed, have resulted from an alteration ot pre- viously existing minerals, often very unlike in composition to the I^resent, ])y the taking away of certain elements and the addition of certain others. This is the theory of metamorphism b}' pseu- domorphic changes, as they are called, and is the one taught bj' the now reigning school of chemical geologists, of which the learned and laborious Bischof," whose recent death science deplores, maj' be regarded as the great exponent. The second hj'pothesis supposes that the elements of these various rocks were originally deposited as, for the most part, chemicallj^ formed sediments, or precipitates ; and that the subsequent changes have been simply Quar. Jouv. Geol. Soc, xv, 489; also, Aiiiei'. Jour. Sci., II, xxx, 133. OUIOIN Oy CRYSTALLINE KOCKS. 41 molecular, or, at most, confined in certain cases to reactions be- tween the mingled elements of the sediments, with the elimination of water and carbonic acid. It is proposed to consider briefly, these two opposite theories, which seek to explain the ori' the crystallization of aqueous sediments, for the most part chemically formed precipitates. Mineral pseudomorphism, that is to say, the assumption by one mineral substance of the crystalline form of another, may arise in several ways. First of these is the fillinfi; up of a mould left by the solution or decomposition of an imbedded crystal, a process which sometimes takes place in mineral veins, wliere the processes of solution and dejiosition can be freel}^ carried on. Allied to this, is the mineralization of organic remains, where carbonate of lime or silica, for example, fills the pores of wood. When sub- setiucnt decay removes the woody tissue, the vacant spaces may, in tlieir turn, be filled by the same or another species. * In the second place, we may consider pseudomorphs from alteration, which are the result of a gradual change in the composition of a mineral species. This process is exemplified in the conversion of feldspar into kaolin l)y the loss of its alkali and a portion of sil- ica, and the fixation of water, or in the change of clialybite into limonite by the loss of carbonic acid and the absorption of water and oxygen. The doctrine of pseudomorphism by alteration as taught by Gus- taf Rose, llaidinger, lilum, Volger, Rammelsberg, Dana, Bischof, and many others, leads them, however, to admit still greater and more remarkal)le changes than those, and to maintain the possl- bilit)^ of converting almost any silicate into any othei . Tims, by referring to the pages of Bischof 's Lehrl)uch der Geognosie, it will be found that serpentine is said to exist as a pseudomorph after au- gite, hornblende, olivine, cliondrodite, garnet, mica, and i)robably also after labradorite, and even ortlioclase. Serpentine rock or oph- iolite is supposed to have resulted, in different cases, from the al- teration of hornblende-rock, diorite, granulite and even granite. Not only silicates of protoxyds and aluminous silicates are con- ceived to be capal)le of this transformation, but probabl}' also quartz itself ; at least, Blum asserts that meerschaum, a closely re- * Hunt oil the Siliciflcutioii of Fossils, Cauadiau Naturalist, uew series, I, 40. 42 ADDUKSS OK T. STKKHV HUNT. luted 8iliciite of mjigiipsiu, which somotiincs accompanios Horpen- tino, roHiilts from tho altenitioii of flint ; wliilc accord iiifi to lio.se, Herpoiitinc may even Ite produced I'rom (lolomite, wliicii we are told is itself produced l»y the alteration of limestone. IJut this is not all, — feldspar may replace carlionatc of lime, and carbonate of lime, feldspar, so that, according to Volger, some gneissoid lime- stones are probalily formed from gneiss by the substitution of calcite for orthocluse. In this way, we are led fmni gi\eiss or granite to limestone, from limestone to dolomite, and from dolo- mite to serpentine, or more directly from granite, granulite or diorite to serpentine at once, without passing through the inter- mediate stages of limestone and dolomite, till we are ready to exclaim in the worils of Goethe : — '• >ricli iiiiffstifft iliii^ VerliiiiKliche Iiii widriKt'ii (ii's<;li\vittz, Wo Nichts veilianet. Alios llielit. Wo sclioii vcrsclnvundon was man siclit,"* which we ma}- thus translate : — "I am vexed with the sophistry in their contrary jargon, where nothing endures, but all is fugitive, and where Avhat we see has already passed awaj'." By far the greater number of cases on which this general theory of pseudomorphism by a slow process of alteration in minerals, has been based are, as I shall endeavor to show, cxiimples of the phe- nomenon of mineral enveloitment, so well studied by Delesse in his essay on Pseudomorphs,t and maj' be considered under two heads: — first, that of symmetrical envelopment, in which one mineral species is so enclosed within the other that the two appear to form a single crystalline individual. Examples of this are seen when prisms of cyanite are surroumled by staurolite, or staurolite crystals completely enveloped in those of cyanite, the vertical axes of the two prisms corresponding. Similar cases are seen in the enclosure of a prism of red in an enveloi)e of green tourmaline, of allanite in epidote, and of various minerals of the pyroxene group in one another. The occurrence of nmscovite in lepidolite, and of margarotlite in Icpidomelane, or the in\erse, are well-known examples, and, according to Scheerer, the crystallization of serpen- tine around a nucleus of olivine is a similar case. This phenome- non of sj'mmetrical envelopment, as remarked by Delesse, shows *Chinesisch-DeiitscIie Jnhres und Tages Zcitcn, xi. t Annalos dos Mines, V, xvi, ;!17-302. OBIOIN OF CRYSTALLINE ROCKS. 48 itself with species wliich tiro fj^enerally isoniorphoius or homa?oinor- phous, and of related eiieinical c(>ini)o.sition. Allied to tiiis is the repeated alternation of erystalline laniiiiu' of related species, as in perthite, the crystalline cleavable masses of which consist of thin, altornatinjif layers of orthodasc and albite. Very unlike to the above arc tlujsc cases of envdopnicnt lu which no relations of crystalline synnnetry nor of siniihir chemi- cal constitution can be traced. Examples of this kind are seen in garnet crystals, the walls of which are shells, sometimes no thicker than jtaper, enclosing in dilferent cases, crystalline carbon- ate of lime, epidote, chlorite or (juartz. In like manner, crystal- line shells of leucitc enclose feldspar, hollow })risms of tourmaline are tilled with crystals of mica or with hydrous peroxyd of iron, and crystals of beryl with a granular mixture of orthoclase and quartz, hohling small crystals of garnet and tourmaline, a compo- sition identical with the enclosing granitic veinstone. * Similar shells of galenite and of zircon, having the external forms of these species, are also found tilled with ealcite. In many of these cases the process seems to have been first the formation of a hol- low mould or skeleton-crystal (a phenomenon sometimes observed in salts crystallizing from solutions), the cavity being subsecjuently tilled with other matters. Such a })rocess is conceivalile in free crystals found in veins, as for example, galenite, zircon, tourmaline, beryl and some examples of garnet, but is not so intelligible in the case of those garnets imbedded in mica-schist, studied by Delesse, which enclosed within their crystalline shells irregidar masses of white (pKirtz, with some little admixture of garnet. Delesse con- ceives these and similar cases t()l)e ))ro(lueed by a process analogous to that seen in the crystallization of ealcite in the Fontainebleau sandstone ; where the (juartz grains, mechanically enclosed in wc.'ll- delinetl rhombohedral crystals, equal, according to him, sixty-five per cent., of the mass. Ver3^ similar to these are the crystalloiils with the form of orthoclase, which sometimes consist in large i)art of a granular mixture of quartz, mica and orthoclase, with a little cassiterite, and in other cases, contain two-thirds their weight of the latter mineral, with an admixture of orthoclase and (piartz. Crystals with the form of scapoUte, but made up, in a great part, of mica, seem to be like cases of envelopment, in which a small i)ro- portion of one substance in the act of crystallization, compels in- ♦ Rei)ort (jJeol. Survey of Canada, 18(i(;. page 18!). 44 ADDRK88 Ol' T. STKIUIY HUNT. to its own crystalline form a hiryro portion of .some foroi;iiile, luis Iteen (lescrilx'd as an al- tered spinel, isfoinid l>y analysis to he an adniixtnre of viillkni'rito witli a variable proportion of spinel, wliicli. in some specimens, does not exceed ei<;ht per cent., hnt to which, nevertheU'ss, tlu'se crystal- loids appear to owe their more or less complete oetohedral form.* The nl»ove characteristic exami)les of synnnetrical and asynnnct- rical enveloimient arc cited from a <^reat nnmher of others which mi;j;ht have been mentioned. Very nnmy of these arc by the pseu- domorphists rcfj^arded as resnlts of partial alteration. Tims, in the case of associated ciystals of andalusite and cyanite, IJischof does not hesitate to maintain tlie di'rivation of andalnsite from the latter species by an elimination of (pnirtz ; more than this, as the andalnsite in (picstion occnrs in a ;(). lie hence rejected the view of (iustaf Hose that these seri)entine crystals were results of tiic alteration of olivine, and supported his own by reasons drawn from the con- ditions in which the crystals occur. In 1853 I took up this (jues- tion and endeavored to show that these cases of isomorphism described by Scheerer, entered into a more general law of isomor- phism pointed out by me among homologous compounds ditl'ering in their formulas by /(INLC)^ (jNI = h3(lrogen or a metal). I in- sisted, moreover, on its bearing upon the received views of the alteration of minerals, and remarked, "The generally admitted no- tions of pseudomorphism seem to have originated in a too exclu- sive plutonism, and require such varied hypotheses to explain the different cases, that we ai'e led to seek for some more simple ex- planation and to find it, in man}' instances, in the association and crystallizing together of homologous and isoniorphons species." f Subseijuentl}', in IHOO, I coni1)ated the view of Bischof, adopted by Dana, that " regional metamorphism is pseudomorphism on a grand scale," in the following terms : — " The ingenious speculations of IJischof and others, on the pos- sible alteration of mineral species by the action of various saline and alkaline solutions, may pass for what they arc worth, although we are satisfied that by far the greater part of the so-called cases of pseudomorphism in silicates are purely imaginary, and. when * VopK. Annal.. Ixviii, 319. fl'ogg. Anual., Ixvlii, 311). IG ADUItK88 OF T. STKllHY HUNT. rpiil, nro Imt local ami accidciHal plicnoiiu'iia. lliscliofH notion ol" till' psi'iKlonioiplilMiii of wilifalt's liko tt'l(lsi)ais ami |)vro\('ue«, pi'i'HU|)|)o.st'H tlio I'xif+tt'iico of cryHtallino rockH, whose gi'iu'ration this iicittiinist never atteniptu to explain, hnt takes his stailing- point from u plntunic hasis." I then asserted that the problem to he solved in reji'ional metu- morphism is the conversion of sedin I'ntary strata, "derived by chemical and mechanical aj^encies from the oceau-wuters and pre- existinjf crystalline rocks into aggrej^ations of crystullim! silicates. These nvetaniorphic rocks, onco formed, are liiiblo to alteration only by local ami su[)erlicial aiicncies, and are not, like tlu' tissnes of a living organism, subject to incessant transformations, the psiiiidomorphism of IJischof."* 1 had not, tit that time, seen the essay by Delessc on Pseudo- morphs already referred to, published in IHol), in which he nudn- taijied views similar to those set forth by me ii IH;').'! and iHCiO, declaring that much of what had been regarded as pseudomor- phism had no other l)asis than the observed associations of miner- als, and that often " the so-called metainorphism tlnds its natural explanation in envelo[)ment." These views he ably and iugeid- ously defended by a careful discussion of the whole range of facts belonging to the history of the subject. My own expression of opinion on this question, in IHi')'.), had been privately criticised, and 1 had been charged with a want of comprehension of the (piestion. It was, therefore, with no small pleasure, that 1 not oidy saw my views so ably supported by Di'lesse, but read the lang 'xc of Carl Friedrich Naumann, who in I'SCil wrote to Dclesse a ollows, leferring to his essay just noticed : — "You have rendered u veritable service to science in restricting pseudomorphs to their true limits, and separating what had been erroneously united to them. As you have remarkecl, enveloi)- nients have, for the most part, nothing in common with pseudo- m()r[)hs, and it is inconceivable that they have been united bj' so many mineralogists and geologists. It ai)pears to nic. moreover, that they connnit an analogous error, when they regard gneisses, amphibolites, etc., as being, all of them, the ri.'sults of metamor- phic epigenesis, and not original rocks. It is precisely because pseudomorphism has been so often confounded with metamori)hism that this error has found acceptance. I only admit a pseuchMuorph * Amer. Jouv. Sci.. II. xxx, 1;>5. OKKilN Of CIIY8TALLINK UOt'KH. 47 wluTo tluu'o Ih Homo crywtiil tlie form of which has boon preaorved. Th(M'o lU'e vory umiiy iiictiiniorphic Miilistjiiiccs which arc, in no hcuhg of tlic wonl, p.HciKloiiioipiis. ihitl the iiitiiic of fri/sfo/hiid hccn chosen, instcml of pHcinloiiiorph, tiiiM conriisioii woiijii ccrtniiily Imvc never found its way into the Hcienco. I think, with yon, that tlie enveh)pnu'nt of two niinerals in most nfcnerally i'xpiiiined hy a coiifi'iii/xirdticoii!* and iiriijiiinl crvHtalli/ation. Secomhiry envel- opments, however, exist, and such nuiy bo caile(l pscn(h)mor|)hH O" civstalloids, if tli«'v repr(i of a reaction which formerly generated beds of chlorite in the same way as those of sepiolite or talc." Delesse, subsequently, in 1861. in his essay on Rock-Metamorphism insisted upon the sepio- lites or so-called magnesian marls, as probably the source of steatite, and suggested the derivation of serpentine, chlorite, and other related minerals of the crystalline schists, from deposits approaching these marls in composition.! He recalled, also, the occurrence of chromic oxyd, a frequent accompaniment of these magnesian minerals, in the hydrated iron ores of the same geo- logical horizon with the magnesian marls in France. Delesse did not, however, attempt to account for the origin of these deposits of magnesian marls, in explanation of which I afterwards verified Bischof's observations on the sparing solubility of silicate of magnesia, and showed that silicate of soda, or even artificial hy- drated silicate of lime, when added to waters containing magne- sian chlorid or sulphate, gives rise, by double decomposition, to a very insoluble magnesian silicate. | To explain the generation of silicates like labradoritc. scapo- llte, garnet, and saussurite, I suggested that double aluminous silicates allied to the zeolites might luive been formed, and subse- quently rendered anhydrous. The production of zcolitic minerals observed by Daubrce at Tlombieres and Luxeuil by the action of a silicated alkaline water on the masonry of ancient Roman baths, was appealed to by way of illustration. It had there been shown * Pogg. Annal., Ixxi, 288. t Etudes surle Metamorphlsme, quarto, pp. 91. Paris, 1861. i Anier. Jour. Sci., II, xl, 49. ^ ^ AMER. NAT., ASSOC. NUMBER. "' f ^ 50 ADDUESS OF T. STEKRY HUNT. by Daubrec that the elements of the zeolites had been, derived in part from the waters, and in part from the mortar and even the clay of the bricks, which had been attacked, and had entered into combination with the soluble matters of the water to form chaba- zite. I, however, at the same time pointed out another source of silicated minerals, upon ^vhich I had insisted since 1857, viz. : the reaction between silicious or argil'-neoous matters and earthy carbonates in the presence of alkalire solutions. Numerous ex- periments showed that when solutions of an alkaline carbonate were heated with a mixture of silica and carbonate of magnesia, the alkaline silicate formed acted upon the latter, yielding a sili- cate of magnesia, and regenerating the alkaline carbonate ; which, without entering into permanent combination, was the medium through which the union of the silic" and the magnesia was ef- fected. In this way I endeavored t . explain the alteration, in the vicinity of a gi'eat intrusive mass of dolerite, of a gray Silurian limestone, which contained, besides a little carbonate of magne- sia and iron-oxj'^d, a portion of very silicious matter, consisting apparently of comminuted orthoclase and quartz. In place of this, there had been developed in the limestone, near its contact with the dolerite, an amorphous greenish basic silicate, which had seemingly resulted from the union of the silica and alumina with the iron-oxyd, the magnesia and a portion of lime. By the crys- tallization of the products thus generated it was conceived that minerals like hornblende, garnet and epidote might be developed in earthy sediments, and many cases of local alteration explained. Inasnnich as the reaction described required the intervention of alkaline solutions, rocks from which these were excluded would escape change, althougli the other conditions might not be want- ing. The natural associations of minei*als, moreover, led me to suggest that alkaline solutions might favor the crystallization of aluminous silicates, and thus convert mechanical sediments into gneisses and mica-schists. The ingenious experiments of Dau- bree on the part whicli solutions of alkaline silicates, at elevated temperatures may play in the formation of crystallized minerals, such as feldspar and p3'roxene, Avere posterior to my early publi- cations on the subject, and fully justilied the importance wliich, early in 1857, I attributed to the intervention of alkaline silicates in the formation of crystalline silicated minerals. * * Proc. Koyal Soc, May 7, ISTiT. Amer. Jour. Sci., 11, xxili, 438, and xxv, 28"J and 435. OUIGIN OF CHYSTALLINE UOCKS. 51 While, however, there is good reason to believe that solutions of alkaline silicates or carbonates have been elllcient agents in the crystallization and molecular re-arrangement of ancient sediments, and have also played an important part in that local alteration of sedimentary strata which is often observed in the vicinity of intru- sive rocks, it is clear to me that the agency of these solutions is less universal than once supposed by Daubree and myself, and will not account for the formation of various silicated rocks found among crj'stalline schists, such as serpentine, hornblende, steatite and chlorite. When I commenced the study of these crystalline strata I was led, in accordance with the almost universally received opinion of geologists, to regard them as resulting from a sul)se- quent alteration of paleozoic sediments, which, according to differ- ent authorities, were of Cambrian, Silurian or Devonian age. Thus in the Appalachian region, as we have already seen, they have, on supposed strati graphical evidence, been successivcl}^ placed at the base, at the summit, and in the middle of the Lower Silurian or Champlain division of the New York system. A carefid chemical examination among the unaltered paleozoic sediments, which in Canada Avere looked upon as the stratigraphical equivalents of the bands of magnesian silicates in these crystalline schists, showed me, however, no magnesian rocks except certain silicious and ferruginous dolomites. From a consideration of reactions which I had observed to take place in such admixtures in presence of heater^, alkaline solutions, and from the composition of the basic silicates Avhich I had found to be formed in silicious limestones near their contact with eruptive rocks, I was led to suppose that similar actions, on a grand scale, might transform these silicious dolomites of the unaltered strata into crystalline magnesian sili- cates. Farther researches, however, convinced me that this view was inapplicable to the crj'stalline schists of the Appalachians, since, apart from the geognostical considerations set forth in the previous pai't of this paper, I found that those same crystalline strata hold beds of quartzose dolomite and niiignesian carbonate, associated in such intimate relations with beds of serpentine, diallngo and stea- tite, as to forbid the notion that these silicates could have been generated by any transformations or chemical re-arrangement of mixtures like the accompanying beds of (juartzose magnesian car- bonates. Hence it was that already, in 18G0, as shown above, I 52 ADDRESS OF T. STERUY HUNT. annoiinced mj' conclusion that seqientinc, chlorite aurl steatite had been derived from silicates like sepiolite, directly foniicd in waters at the eartli's surface, and that the crystalline schists hail resulted from the consolidation of previously formed sediments, partly chemical and partlj'^ mechanical in their origin. The latter being chiefly silico-ahuninous, took, in part, the forms of gneiss and mica- schists, while from the more argillaceous strata, poorer in alkali, much of the aluminous silicate crystallized as andalusitc, stauro- lite, cyanite and garnet. These views Avere reiterated in 1«G3,* and farther in 1864, in the following language, as regards the chemically-formed sediments: "steatite, serpentine, pyroxene, hornblende, and in many cases, garnet, epidote and other silicated minerals are formed by a crystallization and molecular re-arrange- ment of silicates generated by chemical processes in waters at the earth's surface."! Their alteration and crystallization was com- pared to that of the mechanically formed feldspathic, silicious and argillaceous sediments just mentioned. The direct formation of the cr3-stalline schists from an aqueous magma is a notion which belongs to an early period in geological theory, Delabechc in 1834 1 conceived that they were thrown down as chemical deposits from the waters of the heated ocean, after Its reaction on the crust of the cooling globe, and l)efore the appearance of organic life. This view Avas revived by Daul)ree in 18fi0. Having sought to explain the tdteration of paleozoic strata of mechanical origin, by the action of heated waters, l;e proceeds to discuss the origin of the still more ancient cryst.illine schists. The first precipitated Avaters, according to him, acting on the anhy- drous silicates of the earth's crust, at a very elevated temperature, and at a great pressure, Avhich he estimated at tAvo hundred and fifty atmospheres, formed a magma, from Avhich, as it cooled, Avere successively deposited the various strata of the crj'stalline schists, § This hj'pothesis, violating, as it does, all the notions which sound theory teaches Avith regard to the chemistry of a cooling globe, has, moreover, to encounter grave geognostical difficulties. The pre-Silurian crj'stalline rocks belong to tAvo or more distinct sys- tems of different ages, succeeding each other in discordant strat- *Geol. of Canada, pp. .^77 — 581. t Amer. Jour. Sci., II, xxxvii, 2(56, and xxxviii, 183. t Researches in Theoretical Geology, pp. 297-300. § Etudes et experiences synthetiques sur le Metamorphisnie, pp. 119-121. ORIGIN OV CRYSTALLINE ROCKS. 58 ification. The whole history of tlieso rocks, moreover, shows that their various alternatin<>' strata were deposited, not as precipi- tates from a seething sohition, biit under conditions of sedimen- tation very like those of more recent times. In the oldest known of them, the Laurentian sj'stom, great limestone formations are interstratified with gneisses, quartzites and even with conglom- erates. All analogy, moreover, leads us to conclude that even at this early period, life existed at the surface of the planet. ( Jreat accunudations of iron-oxyd, ])eds of metallic sulphids and of graphite, exist in these oldest strata, and we know of no other agency than that of organic matter, cai)able of generating these products. IJischof had already arrived at the conclusion, which in the present state of our knowlodge seems inevitable, that "all the car- bon yet known to occur in a free state, can only be regarded as a product of the decom])osition of carbonic acid, and as derived from the vegetable kingdom." He farther adds, "living plants decompose carbonic acid ; dead organic matters decompose sul- phates, so that, like carbon, sulpluir appears to OAve its existence in a free state to the organic kingdom."* As a decom])osition (deoxidation) of suli>hatcs is necessary to the production of me- tallic sulpliids, the presence of the latter, not less than that of free sulphnr and free carlion, depends on organic bodies ; the part which tliese pla}^ in reducing and rendering soluble the peroxyd of iron, and in t'.ie production of iron ores is, moreover, well known. It was, therefore, that, after a careful study of tliese ancient rocks, I declared in May, 18.58, that a great mass of evidence "points to the existence of organic life, even during the Laurentian or so- called azoic period." t This prediction was soon verified in the discovery of the Eozonn Canadenne, of Dawson, the organic character of which is now ad- mitted by all zoologists and geologists of authority. But with this discovery, appeared another fact, which afforded a signal veri- fication of my theory as to the origin and mode of deposition of serpentine and pyroxene. The microscopic and chemical i"c- searches of Dawson and myself showed that the calcareous skel- eton of this foraminiferal organism was filled with tlie one or the other of these silicates in such a manner as to make it evident that * lUschof, Lelubuch, Ist. eil., II, i>5. Euglli^h ed., I, 252, iU. t Amer. Jour. Science, II, XXV, 430. . : 54 ADDRESS OF T. STKRUY HUNT. they had r('i)hicc(l the sarcode of the animal, precisely as glauco- nito and simihir silicates have, from the Silurian times to the pres- ent, filled and injected more recent foraminiferal skeletons. 1 re- called, in connection witli this discovery the observations of Ehrenbertf, Mantell and Hailey, and the more recent ones of Tour- tales, to the ertect that glauconite or some similar substance occa- sionally tills the spines of Echini, the cavities of corals and mille- pores, the canals in the shells of lialanus, and even forms casts of the holes made by burrowing sponges (C'lionia) and worms. The significance of these facts was fartlicr illustrated by showing that the so-called glauconites dilfer considerably in composition, some of them containing more or less alumina or magnesia, and one from the tertiary limestones near Paris being, according to Berthier, a true serpentine. * These facts in the history of Eozoon, were ilrst made known by me in oMay, ls;5.'5. Credner, moreover, as he tells us,f had already from his mincralogical and lithological studies, been led to admit my views as to the original formation of serpen- tine, pyroxene and similar silicates (which he cites from my paper of 18()0, above referred to J), when he fonnd that Giimbel had ar- rived at similar conclusions. The views of the latter, as cited by Credner IVom the work Just referred to, are in substance as fol- lows : — The crystalline schists, with their interstratilied layers, have all the characters rf altered sedimentary deposits, and from their mode of occurrence cannot be of igneous origin, nor the result of epigenic action. The originally Ibrmed sediments are conceived to have been amor])hous. and under moderate heat and pressure to have arranged themselves, and crystallized, generating various mineral species in their midst by a change, which, to distinguish it from metamorphism by an epigenic process, Giimbel lia[)pily des- ignates (h'agenesfs. It is unnecessary to remark, that these views, the conclusions from the recent studies of Giimliel in Germany and Credner in North America, are identical with those put forth by me in 18(50. * Amer. .Toiir. Sci., HI, i. :t7n. t llenuaiin C'rccliier; die Gleiilerung der Eozoischen Forinntionsgrnppe Nord Amer- ikap. Iliille 180!). | That in the Quar. Guol. Jour., XXI, (i". . 56 ADDRESS OP T. STEUUY lUTNT. At the early periods in whie-h (ho iniiteriulH of the ancioiit crys- talline schists were accunnilated, it cannot be (hjulttod that the chemical processes wliicii f2;cii('ratcd silicates were nuicli more ac- tive tiian in more recent limes. The heat of the earth's crnst was probably thi'n far greater than at present, while a high tem- perature prevailed at comparatively small depths, and thermal waters abounded. A denser atmosplicre, charged with carbonic acid gas, nuist also have contributed to maintain, at the earth's surface, a greater degree of heat, though one not incompatible with the existence of organic life. * These conditions nuist have favored man}'- chemical processes, Avhich, in later times, have nearl\' ceased to operate. Hence we find that subse(inently to the eozoic times, silicatcd rocks of clearly marked chemical ori- gin are comparatively rare. In the mechanical sediments of later periods certain crystalline minerals may be developed by a process of molecular re-arrangement — diagenesis. These are, in the feld- spathic and :iluminous sediments, orthoclase, nuiscovite, garnet, staurolite, cyanite and chiastolite, and in the more basic sedi- ments, liornblendic minerals. It is possible that these latter and similar silicates may sometimes be generated by reactions l)etween silica on the one hand, and carb(niates and oxyds, on the other, as already pointed out in some cases of local alteration. Such a case ma}'^ tvpply to more or less hornblendic gneissea, for example, but no sediments, not of direct chemical origin, are pure enough to have given rise to the great beds of serpentine, pyroxene, stea- tite, labrad(mte, etc., which abound in the ancient crystalline schists. Thus, while the materials for producing, by diagenesis, the aluminous silicates just mentioned, are to be met with in the nnid and clay-rocks of all ages, the chemically formed silicates, capable of crystallizing into pyroxene, talc, serpentine, etc., have only l)een formed under special conditions. The same reasoning which led me to maintain the theory of an original formation of the mineral silicates of the crj'stallinc schists, induced me to question the received notion of the epigenic origin of gypsums annesia is liberated in this reaction, not bein<; favorable to its union with the carbonate of lime to form the double salt which constitutes dolo- mite. The experiment of IMarijiiiac, who thouffht to form dolomite by substitutin<>" a solution of chlorid of maiiucKium for the sul- phate, I found to yield similar results, the •greater part of tlu' mag- nesian carbonate produced passing at once into the insoluble condition, without (combining with the excess of carbonate of lime present. The process for the production of the double carbonate described by Ch. Deville, namely, the action of vapors of anhy- drous magnesian chlorid on heated carbonate of lime, in accord- ance with Von Jhich's strange theory of dolomitization, I have not thought necessary to submit to the test of experiment, since the conditions reciuired are scarcely conceivable in nature. Multiplied geognostical observations show that the notion of the epigenic l^roduction of dolomite from limestone is untenable, although its resolution and deposition in veins, cavities, or pores in other rocks is a phenomenon of frcfiuent occurrence. The dolomites or magnesian limestones ma}' be convenientlj' considered in two classes ; first, those which are found with gyp- sxnns at various geological horizons; and second, the more abun- dant and widel}' distributed rocks of the samc^ kind, which are not associated -with deposits of gypsum. The i)ro(biction of the first class is dei)endent upon the decomposition of sulphate of magne- sia by solutions of bicarbonate of lime, while those of the second class owe their origin to the decomposition of magnesian chlorid or sulphate by solutions of alkaline bicarbonates. In both cases, however, the bicarbonate of magnesia, which the carbonated ■waters generally contain, contributes a more or less important part to the generation of the magnesian sediments. The carbon- ated alkaline waters of deep-seated springs often contain, as is «>UiaiN OK CRY8TAI.MNK HOCKS. 09 well known, l)osi(loH tho hicurhoniiU'a of soda, limo, nml mafinc- sia, I'onipoiMKls of iron, niiinjfiinosi", nnd nmny «)!" tin' niriT metals in Holulioii, and tlms tlio nictullitVrous ciiaraclcr of n)any of the doloniitt's of the .socond class is oxplainod. Tho siinultanoons oocniiToncc of alkaline silicates in sneli mineral waters, wonld give rise, as already pointed out, to the production of insolulde silicates of ma}j;nesia, and tiuis the fre(|uent association of such silicates with dolomites and malt»KS« or T. STKUUY lIlfNT. by Iho lU'tion of carbonates of inajfiusia and soda, iTinaiiiM at llrst diHHolvod aH bicarbonato, and is only soparatod in n solid form, wluMi In excess, or when roiiiiircd for the needs of living plants or animals; which an* dependent for their snpply of calcareous matter, on tlu' Iticarbonate of lime prodncod, in pint by the proc- ess just described, and in part by the action of (■ail)()nic acid on insoluble lime-coni[>()iinds of the earth's solid crust. So many limestones are made up of calcareous orpuiic remains, that a notion exists anion}? nmny writers on geolojiy that all limestones ar<', in some way. of organic origin. At the bottom of this lies the idea of an analogy l»etw<'cn (he chemical relations of vege- table and animal life. As plants give rise to beds of coal, so ani- mals are supposed to produce limestones. In fact, however, the synthetic process by which the growing plant, from the elements of water, carbonic acid and ammonia, generates h^-drocarbonace- ons and azoti/eil matters, has no analogy with the assimilative process by which the growing animal a[)pro|)riates alike these or- ganic matters and the carl)onat(! and i)hosphatc of lime. Without the plant, the synthesis of the hydrocarbons would not take place, while independently of the existence of coral or mollusk, the car- bonate of lime would still be generated l)y chemical reactions, and would accumulate in the waters until, these being saturated, its excess would be deposited as gypsum or rock-salt arc deposited. Hence in such waters, where, from any causes, life is excluded, accunndations of pure carbonate of lime maybe formed. In 18r>l I called attention to the white marl ties of V^ermont, which occur intercalated among imi)ure and fossilifcrous beds, as apparently examples of such a process.* It is by a fallacy similar to that which prevails as to the or- ganic origin of limestones, that Daubeny and Murchison were led to appeal to the absence of phosphates from certain old strata as evidence of the absence of organic life at the time of their accu- midation.f Phosphates, like silica and iron-oxyd, were doubtless constituents of the primitive earth's ci'ust, and the production of apatite crystals in granitic veins, or in crystalline schists, is a proc- ess as independent of life as the formation of crystals of quartz or of hematite. Growing plants, it is true, take u\) from the soil or the waters dissolved phosphates, which pass into the skeletons * Ainer. Jour. Sci., II, xxxi, 402. , t Siluria, 4Ui eil., pp. 28 luul 537. ORIGIN OF CRYSTALLINE HOCKS. 61 of aniiiialM, n procoHH which has been active from very roinoto po- riocU. 1 HhovvHMl in IH.'ti tliat tlie Hhetln of Liii^uUi and Orliiciihi, both those from the liase of the i)ah'o/oie roeks and those of the present (inie, liave (lik(r Coiiuhiria and Serpniiles) a clieinieal com- position siniihir to the skeletons of vertebrati' animals.* The relations of l)otli carbonate and |)hosphate of lime to or<>'ani/ed beinjrs nre similar to those of siliea, whieh, like them, is held in watery sohition, and by processes independent of lif(^ is deposited b(jth in aniorphons and cr^'stalline forms, l)nt in certain eases is appropriated by diatoms and sponj^es. and made to assinne or<;an- ized shapes. In a word, the assimilation of silica, like that of phosphate and carbonate of lime, is a pnrcly secondary and acci- dental process, and where life is absent, all of these substances are deposited in mineral and inorganic forms. 1 have thus endeavored to sketch, in a c(»ncise and rapiti man- ner, the history of the earlier rock-formations of eastern North America, and of our [)rop. 8 . . ■.>() cents. Volcanoes and Eavthiiuakes. (Ainer. Geograpli. See. IS(ii)) pp. 12 p) .. Probable Seat of Volcanic Action. ((Jeol. 3Iag. 1800) pp.8 10 •• Some Points in Chemical (ieology. (Can. Xatinallst 1800; reprinted with addi- tions from Quar. Jour. (ieol. Soc. ]s-)!i) p]). m •>.->" Chemistry and Mineralogy of Metamorphlc Uocks. (Dublin Quar. .Tour. 1««0)1'1'-16 ■ j„ .. Chemistry of the Primeval Earth. (Proc. itoyal Inst. 1807) pp. 8 10 ■• Chemical Geology; replies to David Forbes. (Geol. Mag. and Chem. News, Feb. 1808) pp. ;U _'._,,, „ Chemistry of the Globe. (Smithsonian Report 1809) iip. -20 ..>.-, >• Contributions to Lithology; Kruptive Uocks. (Sill. ,7„„r. 18(lt) pp. r.l . . . .-,0 « llist(ny of Ophiolitcs; parti. Sill. .Tour. I8.-.I)) pp. lo j„ .. Euphotide and Saussurite. (Sill. Jour. 18.-)i)) pp. i,") ,„ ., On some Fehlspathic Uocks iXorites). IMiilos. Mag. LsTw) pp. 10 ..... 10 •■ Norite or Labradorite Rock. (sill. Jour. 180!)) pp. 7 I„ .. Notes on Granitic Uocks; parts I and 11. (Sill. Jour. 1871) pp. 20 20 '• History of Kozoon Canadense; with plate. Sill. -Jour, hsor,) i)p. 20 .... 2,'i " Mineralogy of Lauientian Limestones. Geol. Survey Canada 18(;0 ; reprinted with additions. Uop. Uegents- Univ. N. York. 180!)) PI., to go " Chemistry and (Jeology of Natural Waters, (sill. Jour. 18ir.; pp. (17. . . . ,-,„ .. Chemistry of Gypsums and Dob. mites. (Sdl. Jour. 18.1!)) pp. ,!7 25 " *' continued. (Sill. Jour. Isoo) pp. li) . . jo " Siliclllcation of Fossils. (Can. Xatunillst. I80t) p|i. 4 I„ .. Notes on the IILstory of Petroleum. (Can. Xaturali-st, 1801) pp. 1,5 ._,,r, .. Chemistry and Geology of Hitunu'ns and Pyroschists. Sill. -Tour. 180;j) pp. |.-, p, .. Oil-be.u-ing Limestone of Chicago. (Sill. Jour. 1871.) pp. .-i p, .. Geology of the .Vlps. (Sill. Jour. 18'i0) pp. 7 I„ .. Progress of American Geology. (.Sill. Joui\ 1801) pp. J.") •>.-, .< < ieology of South western Ontaiio. (Sill, .|„iir. isos) pp. 10 ]„ ., Laurentian Uocks of Eastei-n Massachnsotts. (Sill. Jour. Is70) pp. ;! . . . p» •• Geology of Eastern New Enuland. (sill. , Jour. 1870.) pp. 7 ]o " Gc(dogy of the Vichiily of IJoston. (Uoston X;it. Hist. Soc. 1870) jjp. s . . pi ••