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REPORT ox THB MINERALS OF SO.AIK OF THE APATITF^-BEARLNG VKINS % OF OTTAWA COUNTY, Q., WITH NOTES ON MISCELLANKOUS ROCKS AND MINKJfALS 1878 BY B. J. HARRINGTON, B.A., Pii. I). « -tv. PUBLISHED BY AUTHOIilTY OF PAllLIAMENT. Montreal : r)A.\vso3sr brothers. 1879 i t f *^ •1 I ■! '"a GBOLOOICAL SURVET OF CANADA. ALKKHl) U. C. SKLWYN, K.W.S., F.U.S., I)ikkATlTK-BFAHIN(r VEINS U^ Of OTTAWA COUNTY, Q., WITH NOTES ON MISCJ5LLANW)l'S ROCKS ANIi MINEEALS 1878 BY B. J. HARRINGTON, C.A., Pii. D. 1 PUBLISHED BY AUTHORITY OF PARLIAMENT. • : • • • • .•• ,•• *. ••••1.. •#••• 1879 » * > • • • • • . • • • • •' • - • • • •. t « • f • • ( • • • • ' ♦ . • •• . • . • > > • • • . •• • • • ,• • • • • • ,• • • - • ••* , •.• •,*,, • • • • t • • ( ••• .«. ■^n"**«iii I ** CONTENTS. i\ I'AOE THE APATITE RK(iION OF OTTAWA COUNTY I At kiiowlodgmcnt of iissistamo 1 Ocriirfiicc ot'nimtifo in Norway; galjbro, dioriti-, pyroxonite 2 (Jiicifis, ((uartziti', dolirite 3 LimuHtones, chrysotile, hvdti and veins of upiitite 5 Kxiimpliiw of veins G Dnisy eaviti( s, large apatite crystal 7 Handed stnieturu of veins 8 Inegnlar i haracter of apatite deposits y Origin of apatite veins 11 De])th of apatite depositn 12 THE MINERALS OF THE APATITE DEPOSITS 13 A I'ATITE 14 Calcitk 1 ,5 fh'oii-si'mi, qiaktz ig PVUOXKNE ANJ) UltALlTK 17 Analysis of pyroxene 17 Analyses of pyroxene and malite 21-23 HOUNBLENDK, PlILOtiOl'lTB 24 (■ AUNKT 2G EpiDOTB, IdOCUASE, TOUKMALINE TiTANITE 27 Analysis of Titanite 28 ZiUcoN 28 Ortiioc'lasb, Aluite 30 ScAi'OLiTB — Localities of ; crystalline form 31 An.alysis of scapolite 32 WiLSONITE 33 Chlorite — Analysis of 34 PiiEfiMTE — Analysis of 34 Chauazite, Hematite, HutiijE, Pvuite > :i5 PvKiuioTiTB, Ciialcopyrite, Sphalbiute, Galkna, Molybubnite 3(> GiiAi'UiTB ; loganitc, wollastonitc, barito 37 n CONTENTS. PAiiR MISL'ELLANKOUH ROCKS AND MINEUALS 3rt MANOANiriciiors Calciti — AimlyHlH of 38 On tub oocniiuKNOE or Olivink in Canada 30 Olivino from Hto. Aimi;'H on the Ottawa,— imalysiH of 30 Olivine rock from near Moinit Alliort, P.Q. ; diniito ; origin of olivine roci^H ; microHciipic cliarnctcrH 40 Olivine from Nova Siotia 41 Olivine from liritish Columbia 41 On bomi of ti:b dioritbs of Montkkal -12 AnalyHlH of diorite 44 Analysis of aualcite ; teHchenito ; uge of eruptive rocks of Mont- real 46 Magnetic Ihon Orb — Analysis of wppcimen from British Columbia. , 4G Spathic Ikon Okb 4G Analyt^is of specimen from Hudson Bay 47 Lignites 47 GOLD AND 8ILVEII ASSAYS 40 Cakiboo District, British Columbia 40 Miscellaneous Looalitiks 50 LIST OF ILLUSTRATIONS. PAGE 1 . — Dolerite Dykes cutting Quartzite 4 2. — Branching Apatite Vein in Pyroxenite 6 3. — Apatite Veins in Pyroxenite 7 4. — Vein showing large Apatite Crystal 8 5. — Section across banded Vein 8 6. — Veinstone showing alternate layers of Apatite and Pyroxene 7. — Drawing sliowing irregular i haraeter of Apatite Vein 10 8. — Outlines of Phlogupite Crystals , 25 9. — Sections of Olivine Hock and Serpentine 41 10. — Drawings of Olivine Crystals, mostly altered to Serpentine 42 1 >l- PAtlR 38 38 3'J 39 40 41 41 42 44 4S 46 46 47 47 49 49 60 PAOB 4 6 7 8 8 9 10 25 41 42 (iEoLocacAL Survey Office, M in Hiickinnham, Templeton and otiier town- nhipH of Ottawa (-()unt3% coniprisiiii^ what is sometimes i. X (ieology of Canada, 1866, p. 185. > I OT?TAWA COUNTV, Q. 3 a i^ lenticular patches and veins of a coarsely crystalline aggregate of orthoclase and quartz, with n\ore or le.ss pyroxene, or sometimoa hornblende, may often be observed, and appear to have been separated out from the mass of the rock by some process of segregation. Of other rocks met with in the Ottawa pliosphatc region the most important are the gneisses, quartzites, and crystalline limestones. Gneiss. The gneisses vary much in character, but the predominating variety consists of more or less reddish orthoclase and gi-eyish or white quartz, with little or no mica, and sometimes with garnets.* It is usually coarse or granitoid in texture, anil the bedding often obscure, tliough in other cases it contains numerous beds or layers of quartzite from half an inch to a foot or more in thickness, which render the strike of the rock plaiidy visible. Cineiss wilii these (juartziie layers may be seen on the twelfth lot of the twelfth range ol" Templeton, where it forms the peak overlooking MctJregoi' Lake at the "Fidelity Mines." In other cases mica is abundant, and the gneiss assumes a marked foliated textui'e. It is then sometimes grey, and at others reddish. Many of the gneisses, liowever, which appear reddish, are 'onl}- so from weathering, and on IVesh fi-aclure the leldspar is seen to be white or pa'e grey. The micaceous gneisses are sometimes garnetiferous, and occasionally exhibit the texture of the so-called (luyen-gnths or eye-gneiss. Grey hornblendic gneisses also occui', and in some instances contain epidote. Quai'tzite has already been referred to as forming thin beds interstrati- Quart/Jte and tied in some of the gneissio strata; but indefjendent beds of considerable thickness also occur. A good example of one of these may be seen in the hill behind the little village of Perkins' Mills, in Templeton. it is white and glassy, and in places contains a little orthoclase. Thequail/.ite and adjoining orthoclase rock and hornblentlic gneiss are here traversed by a doleritef dyk«! more than a hundreil feet thick, the course ol' which is N. 75° \V. and S. 75° K., while the strike of the <|uartzite is about north-east and south-west. At the time of the intrusion of the dyke the (luartzite has been curiously split up into numbers of sheets or layeis in a direction approximately parallel to the course of the dyke, anil thedoleritc has tilled the spaces between the layers, thus producing a series of snuiU dykes parallel to the nuvin mass, but of much tiner texture, owing, no doubt, to nu)re rapid cooling. The accompanying * By some writers many of the-io rocks would be termed granulite, but wo prefer to class them hereunder theK'^nenil name of Kiieiss, with the more tvoioal forms of which they are often intimately associated, and into which they pass by insensible gradations. t By many litholofrJDts 'he rocks spoken of here as dolerite would be called diabase cm account ot their freedom troiii " kUiss " unit their itiitiqiiity. It is, however, deemed advisiible to retain here the name dolerite, by which they have hitherto been designated in the Keimrts of the Survey. 4 o OEOLOOICAL SURVEY OP CANADA. iSeries of dolerite dykes. Microscopii! diameter of dolerite. Hkctch wiiows the upi»eiiranfe ])rcsente(l on the .surface by llie alternating layers of qiiarzite and dolerite. The portion with diagonal shading is the quartzite, Avith the strike of which the diagonal iines coincide, while the dolerite in indicated by the vertical shading. Tne dolerite, it will be seen, occasionally includes angular fragments of the quartzite. The area represented in the sketch is twelve feet Icuig and nearly eight ieet wide. Fio. 1. Dol.BKITK DyKKS Cl'TTlNU QiAliTZITK. The dyke just described is but one of a series which are known to traverse the Laurentian strata in the counties of Ottawa and Argen- teuil. l?y some they have been 9uj)posed to have influenced the char- acter of the apatite dejiosits, and it has even been suggested that rich ajiatite veins were most likely to be found in proximity to the dykes. This, howevei', does not seem to be the case. The dykes cut all the Ijaurentian strata of the region indiseriniiiuitely, and considering the ubmidance of the apatite deposits, and also that they were probably formed before the dykes, i* would be strange if the latter did not oecasioiKtIly ]»ass either thr« ugh or close to some of them. Dykes a])]»arentiy ol' similar chara'cer occur in the apatite region of Norway, l»ut have not, so far as I am aware, been su))poseil to be in any way connected with the apatite deposits. Analyses of specimens of some of the Grenville dolerites were made many years ago by HuTit,-i^ and descriptions of their microscopic characters sulise(iuently published by me in the Canadian ^^aturalist.f (^biite I'ecently, also, micros('0|Me sections of dj'kes from Templeton and Wakefield have been studied, but have not been tbund to otter any * Geology of Canada, 18(5.'5, p. 653. t New Series, Volume VIII., Number 6, p. 315. * ■ i^ OTTAWA COUNTY, Q. 5 a h i GHsontial difforencos from those uf the oldest sot of dykes in (Ji-eiiville. With tlie mici'Dscope tlie rocU shows, in thin sections, a perfectly crys- talline textui-e, beini^ made up of a network of striated blades of triclinic feldspar, brownish auajite, black, opaque i^rains of mai^nietite, and com- monly small quantities of a green chloritic mineral. The i-elative proportions of those constituents vary a good deal, and in the case of the dyke near Perkins' Mills, described above, the pro|iortit)n of aiigite appeai-ed to be much lai-ger in the main djdce than in the Mne-giain»'d portions between the Ia3'er8 of quartzite. in the latter a green ser- pentinous mineral was observed, which is probably ]»seudomorphoiis after olivine. Messrs. Brogger and Ileusch state that limestones rarely occur in Limostonea. the regions where they studied the Norwegian apatite deposits; l»ut with us the ease is different, and a immber of bands of crystalline linuv stone are known to exist in the apatite i-egions of both Ontario and Quebec. Those seen by mo in Tem])loton were highly crystalline, and often ser})entinous. In a few localities they were noticed to contain concretionary balls of serpentine several inches in diameter, sometimes envelo[)ed hy a single layer, or containing several more or less concen- tric laj'ers, of white fibrous calcite. Large masses of serpentine also occur in the limest-i.o, consisting of the ordinary yellowish-green variety, traversed by numerous veins of beautiful chrysotilc. Snuill Chrysotilo. quantities of this have been mined as asbestus on the eleventh lot of the seventh range of Templeton. In the Geology of Canada the a])atite dejjosits of tlie Jhirgess region ueds or vein.s were described as beds. Subsequently, however, it was stated by Di-. "f '"^pat'te- Hunt that although the apatite did occasionally occur in beds the workable deposits wei"e, " with few if any exceptions, confined to the veinstones.'"!^ Jjijnestone beds were described by him as containing disseminateil gi-aiiis or crystals of apatite, the pro|M)rtion of which amounted in some cases to two or three per cent,, or even much mcne, and the pyroxenites were stated to contain disseminated gi-ains or small masses of a])atite marking the stratification. (Ijoc. cit., |). 204.) Dr. Hunt's reasons for regarding most of the deposits as concretionary veinstones are fully given in the report just referred to, and also in his Chemical and (ieo/ogical Essaijs. They de])end upon such facts as banded structure, the presence of drusy cavities, the manner in which various minerals surround or encrust each other, and the rounded forms of certain crj'stals — indicating "a process of partial solution succeeding that of deposition." As many of the facts obtained last summer in Templeton and » Report of Progress, 1863-66, p. 188. < t; o OfiOLOfliCAL SURVEY OP CANADA. Hi Examples of veins. Branching apatite vein. adjoining townships l>oar upon these points, some of them may now ho stated, Thtit many of the apatite deposits of this region are not beds is plainly shown by the manner in which they cut across the strike of the rocks containing them. As examples of this, may be mentioned an important vein on the seventh lot of the first range of Portland, tlie course of which is N. 15° W., while the strike of the coimtry rocks is N. 45° E. On the nineteenth lot of the ninth range ol" Templeton the i-ocks strike N. 40° E., and are traversed nearly tit right angles to their strike by a vein of aptitite.* Again, on lot fifteen of the eighth range of Templeton, there are three veins whose courses are, respectively, N. 40° W., N. G0° W., and N. G7° W., while that of the country rocks is N. 20° W. In some instances deposits which look like interstratified bods in phices, are here and there seen to give olf latcnil branches, which cut directly across the strike of these rocks. An eximi])ie of this was noticed at Mud Btiy, on the twelfth lot of the eleventh range of Templeton, in the case of an apatite vein occurring in garnet iferouH gneiss. Fig. 2. Figure No. 2 is a vertical section across a branched vein occurring on the same lot in massive py- roxene rock. The latter shows what are probably joints, though p()ssil)ly planes of bedding, lii eithei- case, however, the only possible conclusion, as regards the apatite, is that it forms a vein. The pyroxene rock is indicated BHAN(HlNO Al'ATITK VkIN I.N 1'YKOXKNITE. aOOUt tWO leCt. Figure No. 3 shows ti number of small irregular veins of apatite cutting alight grcenish-grcy "pyroxenitc," on the surface of which * OwiiiK to tlu-Kri'iit irreKuiiirity of tlio uiiutite veins imd the limited extent to which they have been woriicd, it is often diflicult to obtain their lumrses very accurately. The following twenty, however, were ascertained as caretnlly as possible under the circumstances. The first fifteen are the bearings (mag.) of veins in 'I'empleton, the succeeding four in Portland, and the last in Buckingham:— N. 35" E. N. 60" W. N. 30° W. N. 17" E. N. 40" VV. N. 15" W. N. 67° W. N. 40" W. N. 5" W. N. 60° W. N. 56° W. N. 45° E, E. & W. N. 78° K. E. & W. N. 45" E. E. & W. N.45" E. N. 85" E. N. 35° E. t. OtTAWA COUNTY, Q. 7 <» quartz and feldspar woathcr out and inui'k the strati Hcution of the rock. The ai»atite h)()ks as if « rocks. Drusy cavities do not scorn to Drusy cavities, be so abundant in tlie veins of this rc<^i()n as in those of I?uri;ess, but ai-e now and then met with, liiied witii crystals of (|iiai'(z, calcite, a[)atite or pyroxene. Anionic other hK-alities, they were observed ai the Grant Mine in liu('kini>iunu and on lot seventeen in the lunth ranii;e of Templetot or more in diameter. The top of one, which liad been broken off and was lying on the.ground, had the pyramidal planes entire, and was eighteen inches long and eighteen and a-half inches in greatest diameter. Towards its eastern end, a section of the vein, in a cutting, showed it to be largely com- posed ot calcite holding a few large crystals of apatite, and having a thin layer of the latter mineral adjoining the foot-wall. One rude crystal of apatite, which projected from this layer of apatite into the calcite, was two feet nine inches long, and also in diameter. It '" i^rge apatite shown in the accompanying cut (Fig. 4), in which the diagonal shading '^'■ystul. represents the country rock, the arrow-head markings calcite, and the white, apatite. In another opening west of the tirst, the vein 8 a (JEOLOaiCAL SURVEY OP CANADA. Banded strui'ture of veiriH. Fi((. 4 .sliowt'il imu-h loss calcite and a uoimI (lojil of dark green horn- blonde, pyroxene and mica — the hist Homotimes in plates a foot across, und most ahinidant ah)ng the foot-wall, while the hornblende occurred in ifroatOHtqnanlity along the hanging-wall. At tiio surface the vein showed nearly six foot of solid ajtatito, ])artly consisting of large crystals; but at a depth of eighteen feet the total width of the vein was only four feet, and of this only one foot consisted of apatite. This vein hiu afforded interesting examj)les of mineral onvelo])nient and of bi'oken and re- cemented crystals, some of which \ iiN Miii«iN(. i,Aii(;i: Ai'MiiK ('i;vsT\'. will be noticod further on. A> a iiile. llif apatite bearing veins of the Ottawa region are charac- terised rather by a want of i-egnlarity or order in the arrangement of their constituents than by any degree of symmetry. Occasionally, however, instances are met with whci-e the veins show a distinct banded structui'c. An excellent example of this was observed at Mud Bay, on the twelfth lotof the eleventh rangeofTenipleton. The vein was twenty- one and a half inches thick, and occu))ied a well-defined fissure. A section of it is shown in the acc(>ni]»anying figure (Kig. 5). The Grant Mine, on the eighteenth lot of the twelfth range of Buckingham, has also afforded an interesting illus- tration of the alternate deposi- tion of minerals in a vein. The minerals are pyroxene and apatite, and they occur in lay- ers averaging about a quarter of an inch in thickness, alter- nating one with the other with a.. L. II. Oiili'iti' iiiid iiiic:i. Ii. Kiiif frr.iiiicii iiiicii in wavy lini'S. wi'li pyri).\(!iit' ^111(1 ,1 little :i|i.ititc. c. I'yi'oxfiiL', KiiiiHil.ir :i|i.iiit(', mid ii little iiiicii. Ill line sc'iles, :ii-niiiKeil in \v:iv> lines in the direetioii ot'llie vein. U. Micii- pyroxene iiiid thin layers of apatite. Calcite and mica. womlerful regulai'ity for very c )nsi(|erid)le thicknesses, like the liiminte of Eozoon. In OTTAWA COUNTY, Q. 9 O Fi^. 6, which is a tniciiii!; froniiiii ;iotu:il spccimoii the nhiuiod por- tion roprCHontH the pyroxoiio jiiui the wiiiU" ;i|)iititt'. In Ihf ori- ^iiiiil tho lines arc Hcaircly as shnr[) as indicati'd l>y Iho drawing'. In some cases the apatite has been dissolved away, loavini^ tlie layers of pyroxene. 1m(i li. VKINBTUNK SHOWlNli ALTKRNATK l.AYKHS Ol' APAIIIK AM) I'YHOXKM-:. Veins with sharply-delinetl walls, such as are common iis the case of Sharpiy- metalliferous lodes, are i-arely seen, the cunsliUients of the vein and not common. country rock rather nieri^iui^- into one anothe]'. Accordini>; to Dana, " such a blending of a vein with the walls is a natural result, when its fornuition in a fissure takes place at a high temi)erature during the metamori^hism or crystallization of the contaMiing rock."' * Figure 7 is an illustration of the irregulai- iriunner in which the IrroKulur chur- I . ,. , , , • . I • i I i • i. • 1 '^''**"" "f apatite various minerals occur in some or the apatite dei)osits. it is a vertical depositi!. section on a scale of approximately one foot to an inch, sketched in an opening from which considerable ([uantities of apatite had been ex- tracted. Tho uncertainties of mining deposits of this character are cvulent. Such examples Jis those which liavc been given prove incontestably that there are true apatite veins in the region in question ; and as to their mode of formation, we concur with Hunt in regarding many of them as * Manual of Geology, 1875, p. 733. M { ) 10 o QEOLOOICAL SURVEY OF CANADA. RettreRAteil inatisog. fissuroK or cavi*i<»H which have hoon tilliMl hy tho doposition of mnto- rinls derived iVorn the adjucont ntrata. At tho same time, however, wo believe that in inarjy oanos there haw hoen a Hc^i-egation of apatite and other miiieraJK which aceonnpany it from tho Hiirroiindini^ rock into irrc^iihir or lenticidar masscH, without any true cavity oi- crovico ii! Ill c '^ ++•»++ + t + "f -n + + 1- -f 4 +4 ++++++ ++++4+ *• + + + + + ++++++ ++4+++ ++++•4 + + + +• + + + + + +!■ + t +++++ + +■ + + + + +<++•+ + + + + ■*- + •»• + + + + + ■♦• + + •♦■ + * -»• + + •• + + I- + ■♦• + .t ♦ ++ + H- + + + 1■^ + •f-+-v f •( I- > S f L !i 11 //;,; m Orthoclaje. Plily them in Norway, are that tlu^y are of ernntive orii'in, and that there is ''no dclinite relation helwcen the ''lr"i'''.V?""?'" minei'alH of the veins and those of the count ly rock." The veins are stated to traverse inditl'erenlly hoth ern|)tive and sedinu-ntary strata — gahhro, ^ratnte, hornhlendo slate, horidilend*^ ,i,Mieiss, tniea-sehist and ({iiartzite; hut neither apatite nor any ollici- mineral containing phosphoric acid is known to occur in the country rock. 'IMie hande(| arrangement which they have observed in some of tlu< Norwegian veins, they assume io ho due tt» the conditions under wliicli the "magma" has cooled. Often, too, tho veins are said to he tine grained near the walls and coarse in tlu^ centre, a phenomenon reganled us analogous to what is ohsorvahic in many I lap dykes. The crumpled and broken crystals of miea and other minerals are c(»nsidered as best explained by assuming tho eruptive nature of the veins. After the f, (or the s!ik«- ol' cotnpaiisoii, tlinNo cmnnonili'il by Hnii;7^'»'r and Hciiscli, as occiiiTini,Mn Hit- apatite-ltfaring voins »itu«liod by tlioni in Noiway, arc i^ivisn under II. Mincrnl IIMMIII'illlCS lit iil>iilite. I. A|)iititc. Calcitu. FliKii-Hpiir. <./iiiut/, (Hi'vciiil vars.). Pyroxene. Iloriilileiiile. I'lil()p)pite. (Jul net. Epidote. Idorrase. TniumHliiie. Titaiiitf. Zircon. Orthocluse, Albite. S( iipolite. Wilsonite. Tale (Steal ite)? Clilorito. Prehnite. Clialiazitc!. Heiimtito. Untile? Py.i(e. I'yrriiotite. Chalcopyrite, (lulena. SplialtMite. Molylidenite. (iraphite. I! Apatite. C'alcito. (Jiiart/,. Pyroxene. HorMiiJende. l'liloi,'opile. Toiirnialiiie. Titanite. < Irtlioclase. Alliite. S(a|)olito. Tale V Chlorite. Hematite, ilutile. Pyritc. Pyrrhotite. Cliali opyrite. KjeniKin. TNclierniakite (oligodase). Esmarkite (anorthite '■') Enstatite. AHpasiolite. Titanie Iron Ore. Magnetite. It will thuH be seen that of the thirty Hpooies given in oiir list, no lesH than eighteen, or neai-ly two-thirds of the entire number, are m •II 14 ., UKoMirtlCAL SURVEY OF CANAbA. Enstiitite. idt'iiticiil with (lioso in the N()i'\vo«:;ian (le])().sits. The Norway' list, liowovor, contains sovoral minerals not roprosontcd in ours ; but one of those, magnetite, wfurs in a])ati to-bearing veins in Ontario. Enstatite, thougli earefull}' looked for, has not yet been found here, altliough a mineral siipjiosed to be an alten^d enstatito* is one of the most frequent aeeompaiiimeiits of the Norwegian apatite. 11 \ I Large iipiiti crystals. Al'ATITK. The varieties of this mineral ocuri-ing in the Ottawa region are so numerous that no attempt will bo made to describe theni all in detail, but simply to give a few general statements with regard to some of their more im])()rtant cliaracteristics.f C-rystals of the mineral are of common occurrence, and sometimes attain to lai'go dimensions, measuring afoot or mure in diameter and several feet in length, and weighing hundreds of pounds. The form, likt^ that of the so-called moroxite from Arondal in Norway, is a hexagDual ])rism terminated (often at both ends) by a hexagonal })vramid (x P.P.); and in no case, so far as I am aware, has the l)asal plane oP., so ci)mmoii in crystals from man}' regions, been observed. The I'dges of the crystals are sometimes shai-p, but moi-e frt>(pietitly rounded. The s|>ecitic gravity vai-ies sliglitly in ditVerent varieties; but that ol'a dark green, glassy crystal from the(Jrant Mine in Buckingham was found to be 0.2115. The colour of the mineral varies greatly, including gre^'u of various shades (sea-green, olive-green, grass-green, asparagus-green, groyish-gr; en, »\:c.), sky-blue, I'cd and brown of ditVerenI shades, yellow and winto. The lustre varies from vitreous to i'csiiioiis or fatty, and while the minoj'al in its more glassy forms is subtransparont, it is more froijuently subtranslucent anil often opa(iui'. I'hough at some localities the a)>atito occurs chietly in crystalii, at others it is wholly or almost altogether massive, varying from com- pact or erypto-crystalline to coarse granular. Frequently, also, it * It is Kft'cn oi' Breenisli-Krcy in colour, unil somoti'i^js I'ccur.s in vi-ry liirKo crystals. The hardness is only 2-'t, and tlu! sin'oiliu univity 'J.'i -"..'.S. In fine splinti-rs the mineral fuses to a black glass. Tho following are two anal>ses cited by Uriij^ger and Reusch :— OedcKiirden. .Sniiruni. Silica :i~A'>:; r>ii.,')i Alumina ].(»;> 0.97 Musinesia. ;)ll.,'f7 ;!0.89 l-'errous o.xide i.W 2 95 liinie (t.;)7 Water 7.21 C.Ol 101.22 100.70 After examining a lartfc number ot crystals, the conclusion of these gentlemen is that the mineral is rhombic, luthough the crystals are very near to pyroxene in form, and had previously been described as pseudomorpha of steatite after augite. t For fuller particulars, as well tia for detailed analyses of a number of Canadian apatites, see Mr. Christian Hott'mann's Report- OTTAWA COliNTV, Q. 15 (J Iho xly Bee Oxliibits a (listiiu't lamolhir toxture. A iVialdo, saccliaroidal variety is voiy common, and otlen loi-niod ".suiijar |)li()s])hak'." Wiien white, it is sonu'limes ditlicult to distini:;iiisli liy thi' i' ye from n^nw i'orms oi'(|uar(/. sandstone. On account of its IVialiilily it is, no doubt, much easiei' to i^rind than some of the moiv coinj)act i'orms, l)ut, at the same time, it is more apt to underj^o loss in the operations of mining and transjior- tation. Crystals arc sometimes imbedded in this i;-raindar apatite, and IVeipHMitly also rounded masses of aptditi' of all sizes up to many inches in diameter. Similar masses of pyroxene, as well as crystals, are also sometimes imbt'dh's of the tine "granu- lar or saccliaroidal a]iatite occur at several of the openiui^s on the twelfth lot of the twell'lh i-am^'c of Templeton. On this lot also, at Mr. Miller's " J)octor Pit," a curious translucent variety occurs, somewhat resendilinj;' serpentine in apjicarance. At the Ifitcdiie Mine, on the seventh lot i>f the seventh rani;e of Portland, a beautiful example of the vitreous sea-i!;reen variety was seen. The mass, as c.rpoml, measured nearly twenty feet across, and in the whole of this thickness was a]>pari'ntly free from other minerals, with the exception of a few ciystals of pyroxene and mica. As already stated, apatite crystals are sonn'times found imbedded in the ifranular form of the same mineral ; the best crystals, however, usually (H'cur in calcite — as at Mr. Miller's '-Crystal Pit." Other minerals in which they have been toinid ai-e pyroxene, hornblende, phloi;opite, orthoclase, scapolite, steatite and |»yrile. LiUe the crystals from other rei^ions, they frequently enclose other miniMals, amonatite, pyroxene, phloi;(>pite, zircon, «S:c. ; and still more freciucntly contains other mine rals, as apatite, pyroxene, ]>hloalite. calcite oi- other constituents of the dei)0sit, or lining drusy cavities. The (juartz in these cavities is sometimes colourless, at others smoky or amethy.stine, and occasionallj' red or brown, and more or less ojwujue from included oxide of iron. The amethystine (Uiartz is commonly pale, but fairly coloured crystals have been I'diind on the seventeenth lot of the ninth range of Templelon. At this locality chaleedonic (|uart/. has been depositeil in crevices in the vein, producing agate when there has been an alterna- tion of dirteri'iit colours. In some specimens, layers of vitreous (juartz alternate with tlu' chalcedony. The surfaces of the agate are often covered with little scalenohedral crystals, which are apjwrentl}' jiseu- domorphs of (piarlz aCler dog-looth spar. Most of them are iindei- an eighth of an inch in lengtli, and fie(piently they are hollow. Ocea- sioJial grains of copper ])yrites are imbedded in the chalcedony, while zinc blende occurs in vitreous (piartz at the same locality. In a specimen said to have come from the (Jrant Mini^ in Bucking- ham, glassy (|uarlz was imbedded in a mass of mountain leather. In one or two instances also, veins of ]»ale blue subtransliicent quart/, were observed (mttiiig a niixtui'e of granular apatite and jiyroxene. The occurrence of quartz in some of the stratified rocks of the region is elsewhei-e referred to. OTTAWA COUNTY, (I. 17 U PVKOXENE AM) UrALITE. Of all tlie rninoral associutcs ol' apatite in {\\r Ottawa n'i;i()ii, iivrox- eno is the most coiifstaiit and tlu' most alxiiidaiit. in one tunii or another it is }»rol)al)ly j)r('seiil in all I lie ajiatite (le|)osils, oxcoj)tin;:;, perhaps, some of llic calcareous veins with imhediliMl apatite ci-ystais. The mosteomnion variety appears to he an alnminoiis sahlite or lime- magnesia-iron j)yroxeiie, hut a lii;'lit-eoloiire(l variety, prohahly iliop^iilo p^'nlxl'ne." or malacolite, is also common. Less I'reqiiently a heaiilitiil Mack kind may he ohserved, excellent examples of which have hcen ol)tainod from the thirteenth lot of the eleventh range oi'TiMnpleton. it is here associated with green apatite, white orthoclase, sca]»olile, graphiti' and small gi'ains of titanite. The pyroxeni^ crystals often contain little round or irregidar masses of the orthoclasc> as well ;is scales el" graph- ite, and their surfaces are sometimes coati'd hy hroad ])lates of the last-named minei'al. The crystals dill-.M- from those ol the more oidi- narily occurring sahlite not only in colour, hut also, t(» a ct'rtain extent, in chemical composititHi and form, having the faces of the inclined rhojnhic prism usually much more fully developed than the eliiio- ])inacoid, and presenting iather ditferent pyramidal terminations. The ohserved planes are those of the inclined rhomhie ami rectangulai- prisms CO P. 00 Poo . [oo Poo ], comhined with {\\o pyiviniidal liices I'. 2 P.-P. and the clinodome [2 Poo]. The iaces of tin- rhomhie prism are often develo[»ed almost to the exclusion of the ortho- and clinopina- coi pyramidal jilant-s aic^ prettj- e(|ually developed, hut in otlu'rs much distorted. In the specimens examined the hasal {)lane oP. is ahscnt,hut there is a vei-y distinct hasal cleavage. The fracture varies from uneven to contdioidal. The colour is mostly hiack, hut in somt^ s])ecimens hlackish-green. On the edgt-s or in thin splinters the mineral is Iranshu'cnt, ami hy transmitted light appt'ars deep hottle-green. The lustre is vitreous, and sometinu'r. almost splen- dent. The hardiu'ss is ahoul six, and a crystal, of whiih the following is an analysis, was found to have a specilie gravity of 3-.'{Sr) : M'li'k p.vio.\ene Silica T)! -JTr) Alnmiiiii JH'J I Feiiic oxido 1 .'U 7 Fcrions oxide .iHi I Miiiigfinoiifi oxide (t :i2;i Lim.' Ti:\M Magnesia 11 t> 1 2 Loss on ignition o 1 7 I Tht) analyais shows that this is an aluminous lime-magnesia-iron 1 18 o OEOLOOIfAL SURVEY OF CANADA. in yellow sea- polite Large cr.vstnl.-^ Forms (if crystals. pyroxene, and its compoHitioii and other charuclcrK sconi to conneot it with the variety sometimeH called I'assaite. Kxajnj)Ie.s of other varieties of pyroxene may he met with at almost any of the a|)atite mines. They vary miieh in colour, usually heiiii;' of .some shade of i^reen or i^rey, hut scmctimes white or hi'i>wn. I^owcr Lilac pynixonc down tile Ottawa, in the augmentat'on of (Jrenville, a hoautiful lilac pyroxene oecui-s, tlie crystals of which arc somotimcs imbedded in a ])ale lemon-yellow scapolite. Now and then crystals of lar_^;e diiuv-nsions are obtained. Oik', for exampK', from the towjishiii of Templetoii is eleven and a half inches in circiimfereiico, nine inciies lonj:;, and weii^hs eiufht and one-third ]>ounds. Lai'ge ciystals have also hceii t(»und on the sixth lot of the lirst ram^e of Portland township, and a portion of one now in the museum of the (ieoloii'ical Sui'vey weiii'lis ahout twelve ]tounds. Some of them, lhoui,di dull outwardly, are .glassy within, and of a j)ale hotlle- green colour. The simj)lest iorms observed are crystals of sahlite sliowiny; the followini:^ combination: x Poo . oo 1*. [oo Poo ]. Poo, P. Other ])lanes are, liowever, fref|uently present, and amonsi: them 2 I'. 3 P.-!'. and oP. 8(jmetimes the crystals of sahlite are striatied longitudinally, and they ai'c often much fhittened in the direction of the ortliodiagonal. One, for example, having a width of an inch and eight-tenths, measured only seven-tenths of an inch in thickness; another, an inch and a hall' wide, was tivc-eigiiths of an inch thick, while a third measured two and a quarter inelies by eigbi-lenths ot' an inch — giving an avei-age width ol'over Iwoand a half times that of the thickness. In the tt)wnsiiip of Tem])leton well crystallised pyroxene is often found in veins unaccompanietl by apatite, for which mineral, liowever, it has free] uently been mistaken. As atfording a gooil example of this, a vein occun-ing on the tweiity-lourlh lot of the ninth range may be mentioned. (Jood crystals of more or less glassy, subtraiisliicent green pyroxene arc hero imbeilded in a pale flesh-coloured calcite. They vary in length from a couide of inches downwai'ds, and ai'e often well termijiated at both ends. They are almost iiuariably flattened in the dii'ection of the clinodiagonal, and sliow the following ])lanes : x P. [oc Poo]. ooPco. Poo. P. 2 P.-P. oP., and sometimes [2 Poo ]. The siieeific gravity of a crystal was found to be 3"232. Scales of mica sometimes coat the crystals, or arc enclosed in them. On lot thirteen in tlie eighth range of Templetoii a white to greyish- white or greenish-white jiyroxene occurs, small (piantities (»f which were at one time mineil under the sujtposition that the mineral was apatite. The crystals exhibit the same planes as those just described, but are Iosh imiueully tluttencd in the direction of the clinopinacoid. Flat cry.'tals. OTTAWA COUNTY, Q. lit The enc'l()8iire of mica in pj'roxone ciystals, which ha.s already hcoii Mica in alhided to, may frequoiiUy he ohservcd, and iii some iiislamos tiio '"'^"^"^ HcaloH or cryHltils of mica may be seen to be more or loss s^'mmotrically arranged Avith reference to the phines of the pyroxene. On the f-even- tcenth lot of the nintli range of Templcton hirgc crystals were observed, showing a central portion of dai'k green pyroxene siirronnde(l by a zone of minute scales of jnica, while the outi'r portion of the crystal was pale green pyroxene. Other inclusions also are common, and among them calcite, apatite and orthoclase. Not infrequently also pyroxene crystals are rouiKied us if by the action of some solvent, but this is much less common than in the ease of aiiatite. Sometimes they have been cracked or broken in two; and the spaces l>etween the pieces tilled up with calcite, apatite?, or some other mineral. In one case, a crystal four inches in diameter was observed which h.. • bein fractured and re-cemented with apatite. The most interesting peculiarity observed, however, is the tendency i mlitp. which the pyroxene in some localities exhibits to become altert>(l into a kind of uralite. This name was long ago given by (iusluv Rose to crystals possessing the I'orm of j)yroxene but eh'avage and other char- acters of hornblende, and tirst observetl by him in certain rocks tiom the Urals, which he termed uralite por[)hyries. 'i'lie larger crystals wore found to freqently contain a kernel of pyroxene, which in the smallrtv ones had entirely disappeared. In the case of pyroxene from Arendal in Xorway also. Hose observed a perfect transition from lus- trous crystals showing no apparent trace of hoi-nblendt' within to others with drusy surfaces, in which no trace of augite eoiild be detected.-*^ Crystals of pyroxene from Travei-sella atl'oril another example ot' a change t)f this kind. The unaltered crystals are described as transpar- ent and glassy, but on being altered become opa(|ue, and often assunu? a silky lustre. In this opa(iue porti(jn fine fibres running [)arallel to the principal axis begin to be devoloj)ed, and, as the change advances, unaltered, others have been converted into hornldende for a greaver or less depth Ircmi the sur- face; others, again, are entirely changed to hornblende, and show no trace of pyi-oxene even when sliced and examined microscopicidly. In the first stage of alteration the ])yroxene, which in ilsoriginal condition is glassy and of a gi'cy colour, becomes more or lesxlull and greenish or i>reyish-wdiite, still, howevei-, retaining the cleavage of pyroxene. In this jtale portion acicular prisms of green horid)lende begin to be deve- lo])ed, gradually increasing until, in some cases, all trace of j)yr(ixeno is obliterated. The t'hange aj)peai's (o have always begun at the sur- face of (he ciystals, extending inwards more rapidly in some ])arts of the crystals than in others, liut although the hornblende ]>risms at the surface appear to be mostly parallel with the |)rinci|)al axis, within they are seen to run in evi-ry diivction, or in some cases to be arranged in i-adiating groups. IntcM-mingled with the horidtlende prisms a little calcite occurs in ))laees. Kven when the crystals have been i-ntirely cliangi'd to hornbh'mb^ the ]»yroxene angles remain perfecti}' distiiu-t, and one crystal with * Forotlier intori'stintr dctnils (MnrpriiiiiK uriilite pco Zirl«el, Mil,', IhxihdO', il, Uliii. n. (l,ni. p. ITS. Also llosiMibuscli. Mil:, riii/nliiii. il. Mill., p. .'!!(>. .In the oiuic of ail '"iiimito syoiiitc," IVoui .liicksoii, N.ll., Mr. (J. W. Ilawos ha.-* oliscrved jin alu ration of nunitc into conipHct brown hornblende insteiid of into the usuiil llbrous green uralitio luafS.— O'w/'W ot.Xtw Jliiiiijinliin , I'art IV., 1878 ; p. 205. ) OTTAWA rOUNTY, Q. 21 O terminal ])lanes sIiowm tlu' tollowiiii; combination : x J'x . co P. [qo P 00 ]. Pco .-I'. 2 P. The rrystal is an inch and scvcn-oiniiths wide and a littlc! over iialt'an i^cii tliicU. The rcmainini^ portion ol'another crystal, which has lost its terminal |ilanes, is thrci- inches wide and an inch thick, and apparently wholly iiralite. The crystal which siip- |)lied (h«> material lor the t'ollowini;' analyses was ahoiit an inch and three-y an aii'i^re^ation of hornblende })risnis. These three portions may be called respect- ively A., B. and {\ A. resembled in appearance much ol'llu' ortlinary pyroxene of the re^^ion, from which also it piobably does not diller much in comiMtsition. The s|)ecilic i;iavily was I'ound to be iMSl and Aimiysfsoi it gave on analysis t'le t()llowin 100 -IS I "^I'liiH is the composition of an aliiminons diopside or malacolite, and, except in !h(^ larger pi-oportion ol iron, r»>sembles that of pyroxcuio fronv (irenville and Hathnrsl.-''- The flillowino,' analysis of li.. the white j)ortion of i1h> crystal, shows that, chenii'205) was also about the same as that of A : — B. Silica :.0-8'.>8 Aliuniiia •. I -825 Foiiic oxide 1 ■ T 1 1 FclTons oxide I -SCtH iMaiigaiiotiN oxide 152 Lime 24 • :?92 Magnesia l5-2t;a I'otash ()-ir)(i Soda (I • ()7(> I.OKfi on ignition 1 • 200 100 -0(50 * Sec analysis, Rciutrt of Progress, 1874-75, p. :J02, and Ooology of Canada, ISft), p. 407. I:, I 22 O flEOLOOirAL SURVKY OF CANADA. It will lie ohscrvcd Unit althoii^^li the toUil siinount of iron in A. and J>. is aliiiosi idonticul, more ol" it oxiHts as ferric oxide in H. thnu in A. TIh! (|iiaiitity of alkalies \h also only about oiio-third ol llie amount iuund in A. If now we ])ass to ('., the uralitic portion of the crystal, the chani^es are nuicli more strikinj^, as will he seen from the following analysis : C. Sili( a 52 •H2;i Aiiiniiiiii ;{-2ir) Feiiif oxide J- 007 (""(•nous oxido 2 • 7()'J Maiigaiious oxide i)-2T(> Lime 15- ;;•!'.» MaK'iiesifi 1 i) • 042 I'otiish •(■.«(! Soda o-H'JH Loss on ignition 2 ■ lO;} 'J9-r.08 The s])eeiHe ^'ravity in this eas»^ was only IJ-OO;}. (\»m|>aring C with A. and Ji. we find that the lime is diminishevllici- with tiiialysos of pyroxono IVinii (lifiivillt- (D.) and Malliiirst (Vj.), and al.so of hornltlcudi) I'roni tlu' lli.i^li Kails of tlic Mudawa^ka, in Ontario (F.), and from EdonvilK- in Now York Stale ((J). K. and F. aro Ity Jlnnt. and (i. l)y KanMmdslu'i'!,^. |). i.s tVom llic K'cpoit i>i Progro.ss for 1871-7;'), p. ;j()2 : — Aniil> '(■.•< of l'.vni.\rnr. >Vr, A. TiOSCH ■t-adS ()-!l70 (IMS 2i-i:i8 J r)-:{72 o-l'J7 0-2 IS i-i;n> lOO.lSI B. C. 52-82;{ ;< 2 1 r. 2-0(i7 2-7ii'.i (1-27(1 1 5-;iS!l I'.i-or.' o-osi; 0-8!)S 2-lo:i 9.1 lOS !). .-.1-27 .1-110 10 25-27 17- Mi 0-11 (12 iMiH 51-50 (i-15 0-35 2 3 8(1 i7-(;',i 1-10 55(15 4-.')0 .')-85 i;mi 20 115 ;i5 lOdlt (i. Silita no s'.)8 1-825 1-711 1-;!")S (It, 52 2t-;i'.i2 1 ")-2(:s (i-ino o-o7() 1 -200 loo'OCO 1 •-, 1 -nv Aiiiniiiia Ki'iricd.xidc Fcri(Mi.s»)xi{lc. . . . WHiij;fUM)U8(t.\ide. I,iino 5-75 2 SC 1 ■' r' Magnesia rota.sh 2:-.-:;7 (IS 1 Soda 0-75 Ijiiiitioii (!• k; loo-l'j IOO'5'.I 08 1 2 Tlu! uralitic ]tortioii ot' tlic crystal, it will 1h' sfoii, docs not ditfiT greatly in coinposit ion Iroin the hornlilciKU' (par^asilc) of llic lli^ii Fall.s of the MadawasUa, nor from the so-calli'd i'(lcnitt' of Kdcnvillc. Tlic ])yroxene, too, somewhat ve.semhles tlio uliiminous diojisidcs (I). F.) ot'(ironvillc and Bathurst. The Ibrmalion of uralite is spoken of liy sonic writers as tlioiii;li if I'lu.imdiphi.-i wroduet of ]iyroxeiu\ ? • Almndanco of iitiloBopito iu Norwa.y. PlILOGOPITE, According to Broggcr and KeuH(h, phlogopite is an (>xceedingiy abundant mineral in the veins of Oedegarden, in the Hamh> district, Morway, and, Judging iVom their descrij)tion, its mode of oecurretu-e is in man.y resjieds very siuiilar to that of the miea found in the ajiatite regions oi' this country. They state that " a brown magnesia-mica is in many veins almost the only mineral, but fre(pu!ntly aceomjianied hy green enstatite, together with small masses of a|)atite. As the quantity of mica decreases and that of the a])atite increases, tlic char- acter ol the veins changes. The richer veins are distinguished by the fact that mica almost exclusively occiH)ies the sides of the veins and a}»atite the centre." Adjoining the wall-rock the mica is said to occur mostly in small scales, while in the middle of the veins it is in large plates. The veins in wdiich mica is the predominant constituent are termed by Brogger and Iveusch "a])atitc-bearing mii-a veins." Few, if Ottawa district, any, of tlie veins which I have seen in the Ottawa district could properly have this designation applied to them, notwithstanding that phlogopite is one of the most common of the minerals accompanying T*" OTTAWA COIJNTV, Q. 25 ,1 tli(! iipatitc; hut :ih an oxninplc oCoiu- which is vciy iiifj^i-ly cuiniiosfii of mica, may hn incnlioiUMl u vein in tlic first raii^c ol' I'di'tland townshij). It is altout twent^'-foiir toot tliick, and contains niimci'oiis I'.Miticnhvi- massos of n|)atito, Homotimos Hoveral foot in diamotor, imhod- dod in ])ido^n)|»ito and pyroxono. Tho mica is ))ai'tly in tino scalos, hut soniotimos in platos moro tlian lift con inches wide, l-'rom an oponiny; at this hK-aht}-, ah(»ut thirty live fci-t di'cp, several hundred tons of very lino a])atiti' havc^ l)oon I'xtractcd. In some instancos mica linos tho walls of veins, while the conli'o is nilod with a])atito. As in Norwu}' also, mica in line scalos is suinotitnos found adjoining; tho walls, while lar<^e < rystals occur in tho central por tions of tlio v*'in. Larn'o crystals ai'i', howevoi-. (|uile as often found near the walls, and in some oases are scattered indiscriniiiuifely throUi^h all ])arts of tho vein. Anion^' the minei-als in wliicli j»Idoii-o|)ite is found imlu'dded arc; Minerals apatite, calcite, pyroxene, hornblende, scapolito, and zircon. On the pUogopiu-."'*^ other hand, the phloi^opito olteii contains calcite and apatite, lho.se minerals occiipint;" cavitii-s whose lorms fre(pientl_>' have soiuo relation to the prismatic faces (»f tho mica cryslals. Or the calcite, and more rarely tho apatite, may form thin tihns between the layers of mica. In a few instanoos, small prisms of apatite were obsorvod ponolrating phlogopito crystals. Pit;-. K. OUTLINKS Oh' PhI.OOOI'ITK CUYSTAI.S. The phloi^opite crystals^*"' fi'om many localities in Ti-nipleton and the adjoiinng townshij)s are, as in the Burgess region, often of groat beauty. * Auourdintc to the latest ob^tervHtiuii!* on tim subject, pliloKOpite \a luonuuliuic iu oryatallisatiuu. tti tl L'C ) I) (iKoI,(MlI('AI- SIUJVKV (>V (!ANAI»A. Hiiiit mill riirniKiitiMl cryMtiilc. Miiscovitt' Tlioy vary in lustre IVniu pearly to alnio.st na'tallic, and in eoluiir IVoiii yellowiMli or reddish-hrown !•• alinosi black, The prisms are usually taperiuir, and llu' lateral jtlanes often perfectly smooth <)r polished. ('ompouiin have curious outlines, such as aiv sli«)\vn in tlu' aceompanyinij li<^urt!. (I*'i^. S. Out I incH traced from th(! crystals themselves and reduced to one-l'our(h natural si/.e.) IkiMuarkalile oxamph's of lu'nt and corrut^att'd or \vriidy no means common. A dark I'cd specimen from lot twelve in tlu! twelfth rant^o of 'i'cniplcton is pndiahl}- almandint" or common ^arnot. It was imhedded in orthoclase. in the townships of Wakctitdd and Portland HjH'cimens of essonile or cinnamon-stone have l)een found, and in some cases mistaken for apatite. This variety is found both massive and cryslallist'd in rhomhic dodecahcilrons. Amoni;- the minerals imme- diately associatt'd with it, besides apatite thort^ ai'c cpuirtz, feldspai', calcite, and idocrase — prisms of the Inst beinii" imbedded in the i^ai-nct. A more or less smoky and»er-yellow garnet has been found in the townshiji of Hull, but whether assoeiated with apatite oi- not 1 am un.'uvare. The ci'vstals are hiijhlv lustrous, and sh()\v i)lanes of the dodecahedron and trapi'zohcdron. Cliroine-Karnetv A beautiful cmcrald-i;reen chromiferous mineral occurs in the town- shi|) of Wakctield, associated with apatite, ])yroxene and toui-malinc. In colour and lustre it closely rcsendtlcs ouvarovite or chrome-i>;ariiet. Althoii!j;h one s]»ccimen seems to exhibit jirismatic stiiicturc, another shows faces a|»]iarently of a rhombic dodecahedi'on — thrive ))lanes meet- inii^ at 120°. As the ]U'esence of chi'omium does not seem to have been hitherto recognised with certainty in any of our Laurentian minerals, this one n\ust be roi^arded as f)f pai'ticular interest, and a quantitative analysis of it will slK)i"tly be made. As we have already seen, garnets aiv common in some of the gneisses of the region, and have also been observed, though rarely, in the pyroxenites. niTAWA COirNTV, (j. 2"? «l RniioTK. In udditinn t(» its occuiTonco in moiuo of tlio slralifuMl roclcs of ll.o Ei'i«l<>tc. ivii^iof), t'|»i(|(»|<« lifts, in a Tew cast's, Im'imi met with as a coiistiliKMit of till! apaliU' (ii'jKwits. One localily is on lot nine of tin' tciilli, anotlicr on lot twenty tliivtf of tlu' Ihiid'fntli ran^^f of 'IVnipit'ton. At the fornuM" it is ussociad'tl willi dai'k ,i,n'i't'M jtyroxiMic, |»yi"i(t' ami caiciti' ; at tho Inttor willi hornMondc, |iyn»xoin', orllioclasi". sca|toliif, pyi-ito and calcitc. In hotli cases tlu' niincral is yellowish-^j^recn, and fuses with niuc.li intiiineseence to a lilack sJaiT- In the closed tidie it uives, m i.s usually the case with epidotc, a little water. InoCKASK OR \ K.SIN lAMTK. Heautiful ci-ystals of hrownish red idocrase, ucaily an inch in diMiii idoiTiise etor, have l»eon found in lln^ township of'l'enipleton, hut whethei- from one of tho apatito veins 1 iuivo heen unahie to aseerlain. Small prisms of ^reon idocvaso inihedded in cinnamon-stone have also heen nhtained from the township of Wakeliehl, hciiit:; in this case associated with aj)atite. ToUHMAI-INE. The oidy variety of this minei-al noticed in aii^' of the apatite l>e:irinL;" l?lii>-k tomnm- veiuH is the ordinary hlaclc tourmaline, hut this is of <|iiite common occurronci'. The ht'st crystals ai-e usually indicdded in calcitc. Iml they are hrittle and not oflt'u ohtaiiied with terminations, in one cast- a ti'iani;ular ])rism, ahout an inch and a half loiii;- and lu^Mrly half an inch across thci facoH of tlui prism, hail heen hrol". I ■ JWSJUI'WWWtVfl"** IW'WJ' : S ; i. 28 a (iK()L()at(^\L survey ov ('anada. vaiy in sizo Irom merely iiiiii-()sc()|iii' onos to others moasui-iii^ several inches across. As a rule, however, they are very l)rittle, and (.liUicnlt to obtain in a perfect eondition. ^fany of them eonlain rounded i;-rains of calcite liki' thoso found in crystals oi' ajtatite and jiyroxene. In Anulysisol' <*oni|)osil ion they prohaldy resi'mhle the sphene of (Jrenville, an up leiie. analysis of wliich — made many years ago, but never piiblisiied — gave ine the following results: — Silica ;?2-();» Titiinic mill 37 "Oti Ferrous oxiiie 1-16 l,iiiic 28-50 Loss (111 i,t;riiti(»n O-Ci! ;t9-47 Specimens of sphene may he I'ound at almost any ol (he a])atite mines, hut the largest which I have seen occur at Breekon's Mine on lot twenty-three of the thirteenth range of Templeton. They were here, however, very brittle, and no good specimens were obtaiiUMl. in the museum there ai'e fairly good crystals collectt'd by Mr. Frank Adams on thi^ south-east half of lot eight in the I'ourteenth i-ange of Hull. ZlHCON. This interesting mineral is oiu' of lre([uent occui'renee in the apatite veins of Templeton and the atljoining townships, and is sometimes Forms of zircon |;„„k1 in crvstals of i^ri'at bcautv. Tin- crvslals almost always consist of a sre.«s, Ontario, said to como from a ffranilic voiii, show the oom liiiiHtioii cc (• :!|'. 1'. .ll'.'i , and occasioiiall.v havi- I'acfH of the st'comlary orisiii or l>x . Many of thiMii have 'U*. ik'volopt'd to a much groatcr uxtoul than P.i and thorcforo uav cherry-red in colour, but others are reildish-brown and more raiely grejish. A crystal I'rom the " Bis'iop Pit," on the twenty-tirst lot of the thirteenth range of Templeton, resembles somewhat in i-oloui- the greyish crystals from Buncondje County in North Carolina, but has a pinkish tinge at the extremity. Its siiecilic gravity is only 4-4S2, while that of one of the .Spociilo gravity 1 i" • i" 1.1 .11 I't zircon. dark red crystals from lot twelve m the tweilth range was tound to l)e 4'G14.* Many of the crystals are subtransparent, but they range from this to ahuost opat^ue. Though tlay commoidy have a high lustre, few, if any, could be used as gems, for (hey are usually brittle and full of flaws. They are also apt (o contain inclusions t»f other minoi-als, among which are a])atitc, calcite and mica, the last being prol>ably the most common. The calcite occurs in little rounded masses analogous to those which are so common in the a])atite and pyroxene crystals. The minerals in which the zircons have been found imbedded are a])a- tite, calcite, orthocl.nse, pyroxene, |)hlogopite, black tourmaline, and prohnite. The apatite conlai.iing the zircons is usually a tine-granular variety, but in one instance a small prism of zircon was found imbed- ded in a large crystal of green apatitt\ Zircon is now known (o be a far more \videl3- ditVused mineral than PrBquent was ormerly supposed, its presence having been detected in many or/Jr(.o',','^^n cry tal'inr i-ocks both in Kui-opc and America.f The crystals arc J!oJ,'|*"""'* soni3 inies macr()scoj)ic, as in the so-called zircon syenite of Norway, but more fre(j[uently can oidy be seen with the microsco]H'. Among * Tliis is utmost exactly llio density of the (Ironville zircon, wliicli, iicconlinR (o Hunt, is 4-()25-4'CK)'J. by liydrotiuorio acid. The occurroiico ol' zircon in Home of tlie Kninitc.i iind Knci.sscH of Now Iliimpthire is dcscriljuU bylMr. U. Uawus in his report on the (iooIoKy and Litholugy of that Statu, IW«»i.Vi' -Jl- 30 o GEOLOaiCAL SURVEY OP CANADA. tho rockH in which it has been observed are granite, syenite, gneiss, mica-schist, felsite, eklogite, basalt, hypersthenite, &c. Orthoclase. Orthoclase. We have already referred to orthoclase as a constituent of tho gneisses and pyroxenites; but in addition to its occurrence in these stratified rocks it is also common in veins cutting them, including many of the apatite-bearing veins. The orthoclase of these veins is very often white, but at other times flesh-coloured, grey, lavender, green and other colours. The green has been found in both Temploton and Hull ; in the latter to^'vnship in masses of considerable size. Ortho- clase crystals are sometimes found in cavities, but more frequently the mineral is massive an 1 often coarse-crystalline in texture. Masses with broad cleavage si rfaces are often imbedded in a ground-mass of paler colour and finer texture, also consisting of orfihoclase or ortho- clase and quartz. Eude crystals and masses presenting broad cleavage surfaces have been found by Mr. Miller on lot thirteen of the eleventh range of Templeton, which appear to have been acted upon by some solvent which has eaten the feldspar into curious corrugated channels or cavities, while the black pyroxene accompanying the felds])ar has been but little affected. Among the minerals imbedded in the ortho- clase of many of the veins, besides quartz, there are apatite, pyroxene, hornblende, sphene (very common, and sometimes in large crystals), zircon, mica, tourmaline, and calcite. In a few cases granitic veins, or possibly true dykes, were observed cutting sharply across the apatite veins, and therefore of more recent origin. One of them, occurring on lot twelve in the twelfth range of Templeton, is eighteen inches thick, and bears S. 18° E. Another, on lot eight in the tenth range of the same tov,rnship, is two feet thick, and bears north and south.* Occurrence of albite. Albite. This species of feldspar' has been found in a few localities in the township of Templeton, associated with apatite, sphene, pyroxene, &c. Cavities or crevices in the last-named minerals have drusy linings of albite crystals, which, on analysis, have been found to contain — Potash 2-75 Soda 8 -90 11-71 p.c. •For analyses of orthoclase from BuckinKham townshi|i,— lussociated with graphite, but similar in appearance to much of wliat occurs with the apatite— see Mr- Christian Hoffmann's Report published last yea,!.— Report of Piogretn, 1876-77» p. 611. T^ OTTAWA COUNTY, Q. :^i ift SCAPOLITE. This name is now made by many mincraloKi«t8 to include a group Scaimiiteirroup of closely related minerals, all of which are teti-ai^'ona! in crystallisation, and consist of silicates of alumina and lime, with, or in some cases without, soda. The most important member of the group is wernerite, and to this species much of our scapolile probably belongs, but until more analyses have been made the general term scapolite must be used. Scaiwlite is a common mineral in the Laurentian, and has hitherto s^appi'te been observed at a number of localities, including Hunterstown, Gren- ville, Calumet Island, Golden Lake (Jvenfrew County), &c.='= In the region more particularlj^ referred to at present, it has been found as a constituent of the apatite-bearing veins in many localities, among which the following may be mentioned: Templotoii — Lot 13, Knnge XI. Templeton — Lot 21, Range XIL " — " 12, " Xn. " — " 23, " XIIL " — " 14, " XII. Portlaiul — '' C, '• I. Hull— Lot 8, Range XIV. The best crystals which 1 have seen are from lot fourteen in the twelftii range of Templeton. Very large ones (sometimes more than a foot in length), but of i-ude form, have been found on the twent^'-third lot of the thirteenth range, where an etiorinous vein of massive scapolite occurs. The crystals from the different localities are, on thi^ whole, very Form of similar, but occasionally pi-esent points ol' difference. Usually they ory.lstals*^ are short and thick, l)ut sometimes slender. The simj)lest forms observetl consist of a comltinalion of fhe two S(|uare ])risms — the faces of the secondary greatly j)redomina(ing — Avith the unit octahedron or square pyramid (oo i'co . cc P. !*.). Hood exam])les of these were seen at a small opening on the twenty-third lot of the thirteenth range of Templeton, the cr^'stals being unusually long for their thickness. The more commonly occurring ciystals, however, exhibit a much larger numbei- of j)lanes. Some of those, for example, from the fourteenth lot of the twelfth range of Templeton show the following: r 3P. Pyramidal < Pec. JJasal, oP. All these are sometimes found in single crysfals, but x P2 and .'JP.'J, as is frequently the case with crystals from other i'Ogi(»ns, are hemihe- r CO Poo Prismatic -| oo P. / 00 P 2. * See Geology of Caniida, 1863i p. 473. Also Chapmau, Minerals and Geology of Central Canada, Toronto, 1871, p. 113. ll'?»l',Wl«,'f.lf,W.''\W»' "T !I""^WV.W»W»' ' ) 'Ai- 1* i'i 32 a GEOLOGICAL SURVEY OP CANADA. dral in arrangement. OccaHionally the fiiccs oo P. are more fully developed than oo Poo , but the reverse is usually true. The colour of the Hcapolite varies mostly from white to grey or greenish-grey, but sometimes there is a pinkish tinge. A massive vai-iety fi-om further down the Ottawa, in the augmentation of (Ji-euville, is of a pale lemon- yellow colour, and holds imbedded crystals of liUic pyroxene. The surfaces of the scapolite cr^'stals are often dull, owing, no doubt, to })artial decomi)osition, and sometimes much stained with oxide of iron. The dccom[)Osed ])ortion, however, usually i'orms (mly a thin crust, beneath which the mineral appears white and exhibits its characteristic fibrous texture and cleavage. Not infreqtiently the crystals look as if they had been submitted to pressure while in a soft or plastic state, and have had their faces curved, or have been bidged out at the base where attached to the rock. In other cases they have been too hard to yield readily to the pressure, and have been cracked or broken, the spaces being sometimes filled with other minerals. Many of the best scapolite crystals are imbedded in calcite, and they are very often accompanied by pyroxene. Apatite, titanite, tour- maline and other minerals are frequently imbedded in the sca])olite. During the ])ast summer Mr. Fi-ank 1). Adams, while engaged on one of the survey parties in tracing out some of the trap dykes north of the Ottawa, found specimens of scapolite on lot thirteen of the FmlrAdMns'^' *^i^li^li range of Ripon, one of which he subsequently analj'sed at the Sheffield Scientific School, New Haven, with the following results :* Silica .54-859 Alumina 22-448 Ferric oxide 0-48(> Lime 9 092 Magnesia traio Potash 1127 Soda 8-365 Chlorine 2-41 1 Sulphuric acid (SO,) 0-796 Water (combined) 0-722 Water (hygroscopic) 0141 100-447 Deductiou^for replaced by chlorine .59 99-857 Chlorine in The presence of chlorine in scapolites xeems to have been previously "'"^ ' ^ ' almost entirely overlooked, and its detecticm, as well as that of sul- • On tho Presence of Chlorine in Scapolites ; by Frank D. Adams. Contributions from the LaborutotTof the Sheffield Soientific School.— .-4 mfrtcan Juurnid uf Science, April, 187i*, p. 315. T^ OTTAWA COUNTY, Q. 33 o phuric acid, in tlie present instance, is a fact of much interest. In order to ascertain wliether this was an exceptional case, fourteen other Hpeciniens of scapolite wore examined by Mr. A(huns, and chlorine found in thorn all, although in some cases the amount was small. The above analysis shows the scapolite fromKipon to be more liighly acidic than mosti of the members of the scapolite family. WiLSONITE. This name was many years ago given by Dr. Hunt to a mineral occui-ring in the township of Bathurst, where it was tirst observed by Dr. Wilson, formerly of Perth. By some mineralogists it is regarded Wilsonitean as an altered scapolite, with which mineral Chapman has shown it to scapolite. agree in cleavage. Hunt, on the other hand, i-egards it as a variety' of gicseckite, and discards the idea of its being an alteration product of scapolite. (Geology of Canada, 1803, p. 483.) In the townships of Templeton and Hull, a mineral with the rose-red colour and other characters of wilsonite occurs at many of the apatite mines, and certainly appears to be an alteration product of scapolite. In all the specimens seen the two minerals occurred together, and appeared to merge one into the other, the cleavage of the two minerals being continuous. Aniong the localities in which the wilsonite has been found are Templeton, lots twelve and twenty-three in the thirteenth, and twenty-one in the twelfth range, and Hull, lot four, range ten. Steatite. A soft (11= 2 - 2A) sleatitic minei-al of grey or greenish-grey colour occurs in some of the apatite veins, ami is, perha])s, in some cases of the tuiture of pyrallolite. Specimens from Mr. Miller's "Old Eed Pit," at the Fidelity Mines in Templeton, are subtranslucent, veiy compact, soapy in feel, and have a distinct conchoidal fracture. The mass is here and there penetrated by a prismatic mineral, which looks as if it had originally been hornblende, but which is now quite as sott as the material in Avhich it is imbedded. In some cases bright green prisms of apatite are imbedded in a grey steatitic mineral, which iti one instance looks as if it were pseudomorphous after mica. Chlorite. Under this general name mineralogists include a number of foliated minerals, which, though ditfering considerably' in the relative propor- tions of their constitueJits, are, for the most part, hydrous silicates of magnesia, ferrous oxide, and alumina. At several of the apatite mines Pyrallolite. 7 riT ' I Analysis of chlorite. Analysis of prehnite. 34 O GEOLOGICAL SURVEY OF CANADA. of Templeton a green chlorite-Iike mineral han been observed, and a specimen from the north-wcHt half of lot eighteen in the ninth range of that township has been examined. The chloritic mineral in this case was associated with apatite, quartz, iron pyrites and calcite, and occurred in uneven folia, mostly of an olive-green colour, and with a pearly lustre. The hardness was 2^, and specific gravity 2-61. Folia flexible, but scarcely elastic. An analysiH gave the following results : Silica 35-80 Alumina 1318 Ferric oxide 428 Ferrous oxide 1018 Magnesia 22-80 Water 1 2-64 98'88 This, it will be seen, is approximately the composition of ripidolite, with part of the alumina ref)laced by ferric oxide and part of the magnesia by ferrous oxide. The silica is higher than in ripidolite, but this is probably due to the presence of a little quartz, which was difficult to separate perfectly. The quantivalent ratio for R : Eg : Si : II, deduced from the above figures, is 5 : 3 : 8 : 4^, while for ri])idolite it is 5 : 3 : 6 : 4. Prehnite. This mineral, which . of frequent occurrence in connection with the copper- bearing rocks of Lake Superior, has not heretofore been found in the Laurontian of Canada. I am indebted to Mr. J. G. Miller for a specimen from lot sixteen in the twelfth range of Templeton. The mineral is translucent and of a yellowish-white colour, with a greenish tinge in places. It seems to have occurred in a cavity, and shows rounded surfaces made up of an aggregation of crystals. The hai'dnoss is a little above 6, and specific gravity 2-891. Analysis gave the following results : Silica 42-82 Alumina 23-86 Ferric oxide 1-42 Manganous oxide 0-10 Lime 27-64 Magnesia 009 Water 4-82 100-75 Before the blow-pipe the mineral fuses easily and with much intumescence. 'I ^TTfT ' OTTAWA COUNTY, Q. 35 a The hardness of prehuite serves to distinguish it reiuUly from members of the zeolite family, with some of which it might be confounded. Chabazite. ^ " Zeolitic" minerals are said to have been observed in some of the apatite-beailng veins of North Burgess, but no i)articular species seems to have been identitied. Among minerals collected last summer at the '* Bishop Pit," on tbo twcnty-Hrst lot of the twelfth range of Tonipleton, chabazite has been detected. It occurs in small colourless Chabazite ... 1 • • . . . , , identihed. or white, glassy crystals, in irregular cavities in scapohte and pyroxene. The crystals, which are mostly under an eighth of an inch in diameter, are obtuse rhombohedrons, and many of them penetration twins. The chabazite, like the last mineral described, is evidently of secondary origin, and possibly derived from the scapolite.* Hematite. Peroxide of iron occasionally occurs enclosed in quartz in some of Hematite, the apatite veins, and is also the colouring matter of the ordinary red apatite. In a crystalline condition it has not been met with in the Ottawa phosphate region, though sometimes associated with apatite in Ontario. Rdtile. This mineral is reported to occur ii some of the apatite-bearing veins, but I was not successful in linding any. Specimens of supposed rutile from Templeton prove to be only peroxide of iron enclosed in glassy quartz. In Norway rutile is said to be one of the most charac- j^utjjg ;„ teristic minerals of the apatite veins, and Brogger and Eeusch state Norway. that if it were of any economic value it could be obtained in largo quantity. One crystal found by them weighed no less than ll-lO grammes.f Pyrite. Though not usually a very abundant constituent of the apatite veins, pyrite is nevertheless of frequent occurrence. It is commonly massive. * Since the above notes were in type, Mr. Miller has kindly forwarded me a number of inter- esting specimens. AuionBthom is oneof prehnite from lot twenty-tliree in the thirteenth ranRO of Temiileton, occurrinR in a cavity in apatitei a crystal of the latter mineral being imbedded in the prennite, Also a specimen of chabazite from a new locality (Portland West, lot twenty-one, range twelve), and other zeolitio minerals) one of which is evidently natrolite. t Small crystals of rutile have been found, since the above was written, in an apatite voiq on the tenth lot of the tenth range of Templeton. 36 o OEOLOOICAL SURVEY OF CANADA. Crystals of pyrito. but Horaetimes occurH in wcll-definod cryHtulM (cubes, octahedronH, or oombinationH of theso forms). In some cases pyrito in imbedded apatite, but, on the other hand, rounded crystals of green apatite r imbelorHtioiis of Mr. llidiardson during tho pjwt season have sliown that it tliere forms Important i-oek-massos close to the sorpontines of Mount Albert, which have evidently boon produced by tho ultorution of tho olivine. A 8j)e- cimoM of tho rock collected by Mr. Richanlson is fine-granulai-, slightly friable, and [)ale yellowish to greyish-green in colour. It shows u few minute black grains, probably of chromite, and rarely a little of a fibrous mineral which resembles enstatite. Altogether, tho rock hjoks remarkably like one variety of that from Ncu-th Carolina, which was many years ago described by Geiith, and regarded by him as tho source of tho serpentine and talc of tho same region.* An aggregate of olivino and chromite occurs at Dun Mountain in New Zealand, and henco the luimo dunite, by wliich the rock is now com- monly known. There, also, it is accompanied by serpentine, llocks of somewhat similar character also occur at a number of localities in Euroj)0. The dunitc of New Zealand is slated to bo an eruptive rock, while the olivine rock of North (/arolina, according to Dana, is " meta- morphic." Concerning tho relations of the olivino rock from near Mount Albert little is known, but it is probably not erjiptivo. Tho origin of such olivino rocks as those of Carolina and IVFount Albert is a dilficult and disputed question, but one which still remains, whether we believe tliat the Horpentines which accompany thom were derived from thom or not. Jn opposition to tho view that they owe their origin to chemical precipitation, Clarence King suggests that they may represent accumulations of olivino sands like those now occurring on the shores of the Hawaiian islands. f Wliotlier such accumulations did take place in the earlier geological formations wo do not know, but there is certaiidy nothing unreasonable or unlikely in the view that magnesian precipitates may then, as in later times, have boon formed and subsequently altered .to olivine. A thin section of tho olivino rock or dunite from near Mount Alhert, when examined with tho microscope, presents the appearance shown in Fig. 9 a. It is seen to consist almost entirely of granular olivine, with occasional hlack grains of chromic iron. Owing to an alternation of layers with finer and coarser texture, it shows a more ml' mi * Ammcan Journal of Science, Vol. XXXIII.; 1862, p. 199. t United Slates Geological Exploration of the Fortieth Parallel. Vol. I., p. 117. OCClfRRENCK OF Ot.rVINE. 41 U or lc88 hiindod Htnicturo. Ah okscM-vtMl uhovo, tu\ i-iiHtatiU'-like iiiiiuMul may oceaHicjually bo booh in tlio hand spocinien, l»iit iionu of il hap- pened to oeciir in the jtortiun HJicod. Fia. y. Fig. !• h is (li-awn from a Hection of one of the Ho-called sor])ontinos occurring near the diinite. Its rehition to tlio latter hi evident, for it atili contains numerous grains of unaltered olivine. In some speci- mens the change has not advanced so far as hero, but in other cases the olivine has almost, if not entirely, disapj)eared. The chromite, however, always remains. Another example of the occurnuice of olivint^ is to be tound in the case of a dark-grey dolerite occurring near Houth Lake, in Antigonish County, Nova Scotia. When a section of the rock is examined with the microscope, it is seen to consist of u beautifully banded Iriclinic feldspai", brownish augite, magnetite, and veiy numerous irregular grains, or occasionally rude crystals, of olivine. The olivint; resembles that sometimes seen in gabbro. It is traversed by the usual cracks or rifts, which in this case appear very broad and black, and also contains great quantities of black and opaque microlites, which are probably magnetite, and which are sometimes so abundant as to render the mineral almost opaque. Some of them are arranged in parallel rod- like forms, while others are occasionally grouped in star-like or other more or less symmetrical shapes. Olivine has also been detected in several of the oru])tive rocks of British Columbia. One of these, of Tertiary age, from Kamloops, aftbrds most beautiful examples of the alteration of olivine to serpen- tine. It is massive, rather tine-grained, and of a very dai-k olive-green colour. The examination of a slide with the microscope shows that originally the rock must have consisted of crystals and grains of olivine, augite (mostly in crystals) and a small proportion of plagioclase feldspar and magnetite. But while tlie augite mostly remains fresh, u Herjjentine (lorivod from duiiitu. Olivine in Nova Scotia. Olivine in British Columbia. Alteration of olivine to serpentine. Serpentineij of tno Eastern Townships. yt'i 42 a GEOLOGICAL SUR\ x',Y OF CANADA. largo part of the olivine, which appears to be the moat abundant constituent of the roclc, has been altered to serpentine. Most of the olivine crystals and grains retain a nucleus of the unaltered mineral, showing the characteristic rifts, and the outlines of many crystals which are partly or entirely converted into serpentine are still perfectly sharp. In the accompanying figure (l^'ig. 10) a represents a group of crystals which arc mainlj' composcil of serpentine, but show nuclei of olivine and a few opaque grains probably of magnetite; b is an irregu- lar mass also partly changed to serpentine ; c represents a crystal which has been entirely converted into serpentine; while d is an almost perfectly fresh crystal of olivine. Fiu. 10. On further alteration such a rock might be almost entirely converted into sei-pentine. Such a change lias been observed elsewhere, as, for example, in the case of man}' of the Wurtemberg basalts, which arc said to be "little more than serpentine rocks containing some mag- netite, since the olivine and aiigite which composed the basalt are changed into serpentine." * In this country we have other examples than those already given of the production of serpentines by the alteration of other rocks. That such is the origin of man}' of the serpentines of the Kastorn Townships there can be little doubt. The fact of their being commonly chromi- ferous suggestH that they may have been derived from such peridotic rocks as Iherzolite, dunite, olivine-gabbro, &c. f On Some op the Diorites op Montreal. There are probably few regions of such limited extent that furnish • Rutley, on authority of Dr. M. U. R. Fritzgiirtner. The Stndu »f W.-oA-s, 18T(t. p. 117. t ConcerninK these roc^ks and the chanprea wiiioh they have undergone, see Rosenbuauh, MauiifH' Getli'ine, pp. ri25-.'VW. Al.so, Honnoy, On the iSorpentine and Associated Rocks of the 4iKard District.— (i>uar(eWv Journal of the Oeolouieul iSueictu, Vol. XXXIIL, p. 884. DIORITES OP MONTREAL. 43 a a greater variety of interesting eruptive rockn than Montreal and its vicinity. This fact, long ago, attracted the attention of Dr. Hunt, and though many of the rocks were ably described by him, there still remains a wide field for investigation, both as regards the character of the rocks and their relative ages. Numerous facts bearing u[K)n tlieso points have recently been accumulated, but many additional details are required before the subject can be fully discussed. In the Geology of Canada the intrusive rocks of Montreal are described as doleritos, trachytes and phonolites, the first of these constituting the main mass of Mount Royal as well as numerous dykes, while the others occui- only in dykes, which are stated in some instances to cut the dolerites. No mention is, however, made of the numerous dykes of diorite which occur, and which, in some cases, have also been Diorite dykes, observed to cut the doler.te of the mountain. These diorites vary considerably in their characters, ranging in colour from light to dark grey, and in specific gravity from 275 to over 3.* They are usually medium to fine-grained in texture, and often porpliyritic with crystals of hornblende. Sometimes, too, they are amj'gdaloidal, the cavities containing calcite, zeolitic minerals, and rarely epidote. They all appear to contain carbonates, the ([uantity of which, however, varies in different cases. Their principal constituents are hornblende, a triclinic feldspar, and titanii; iron; but they commonly contain other minerals, the most important of which is, perhaps, mica. Augite is also sometimes present. The mica is occasionally so abundant that the rock becomes the mica-diorite of some lithologists. A dyke occurring in the reservoir extension consists of what may probably l)e regarded as a typical variety of the diorites referred to above. It is dark grey in colour, rather fine-grained, but still showing, without the lens, quantities of acicular prisms of a black mineral which proves to be hornblende. The dyke was about two feet thick and very homogeneous, showing neither porjdiyritic nor amygdaloiual texture. Specimens sliced and examined with the microscope are seen to consist essentially of hornblende, a triclinic feldspar, and numerous opaque grains of titanic iron. Mica, apatite, calcite, and a little of a green chloritic mineral, are also commonly pi'esent. The hornblende appears mostly fresh, though in ])lace8 slightly altered to the chloritic mineral Just mentioned. It is of a rich brown colour and strongly dichroic. In cross sections the cleavage of the prisms is often beautifully displayed. The feldspar is in part * The following are the specific gravities of a number of specimens:— 2749 2-94 2P23 3-005 2-889 2'07 4S)47 2'8()5 8-W 2-927 Analyses of diorito. 44 O GKOLOQICAL SURVEY OP CANADA. .altered, but in places fresh. It is tricliaic, and, judging from the unusujvlly basic character of the diorite, must be a feldspar low in eilica. The black mineral occurs mostly in irregular grains, but hei'o and there in curious fantastic forms after the manner of titanic iron ore. That it consists mainly of this mineral, and not of magnetite, is evident from the considerable proportion of titanium dioxide shown by the analysis, and also from the fact that when the rock is pulverised the magnet removes almost nothing. The specific gravity of different fragments of the rock varied from 2'92'7 to 3-005. An analysis was made some time ago, and, as the comj)()sition .appeared unusual, search was made for descriptions of similar rocks from other localities, but none could be found. Since then, however, Mr. G. W. Ilawes has described rocks of wonderful similarity from Campton, in the State of New Hampshire.* An analysis, by Mr. Hawes, of one of these dioritos is given under II. for comparison with I., which is an analysis of the diorite from Montreal just described: — I. II. Silica 40-95 41-94 Alumiua 16-45 15-3G Ferric oxidef 13-47 3-27 Ferrous oxide 9-89 Manganous oxide - 33t ■ 25 Titanium dioxide 3-39 4 15 Lime 10-53 9-47 Magnesia G ■ 1 5 01 Potash 1-28 0-19 Soda 4 00 5-15 Phosjihoric acid 0-29 Carbon dioxide . . 2.47 Lobs on ignition. 3-84 3-29§ 100-03 100-44 On boiling T. with hydrochloric acid for several hours, and filtering, the insoluble residue after ignition anjounted to only 51-80 percent. Although the amount of carbon dioxide was not determined, it must constitute a large proportion of the loss which the rock sustains on ignition; for acetic .acid dissolves 4-02 per cent, of lime and 0-G7 of ferrous oxide, and these bases, if calculated as carbonates, would require 3-57 per cent, of carbon dioxide. The basic character ol' the rock, and the extent to which it is dissolved by hydrochloric acid, ♦ Gioloffu ti/ NfW Ihxmpiliiri-, Part IV., p, 100. , American Journal of ^('inieet 1879, |>. 148. t All the iron is calouliitcd lis ferric oxide, the ferrous oxide not hiiving been determined. t With u little cobalt. § Water. €> M> I DI0RITE8 OP MONTREAL. 45 G seem to indicate n feldspar of the natui-e of anorthite. In that case a considerable proportion of the allvalies must belong to the hornblende ; but this is not improbable, as some varieties of hornblende are known to contain several per cent, of alkalies. Aiioihci' dyke, occurring within a few yards of that just described, intereBting •' ' ^' , '' . ' dyke- is also of much interest. It is dark grey in colour, and, like Ihe last. shows numerous aeicular prisms of hornblende penetrating the mass in all directions. Here and there macrosco[)ic scales of dark brown mica are seen, and the rock is dotted witli numerous spots — occasionally as much as a quai'tcr of an inch across — of a glassy, colourless to white mineral, which, on analysis, proves to be aiialcilc. The specific Analysis of „,, 1 •, . A ^,i-r 1 ., • • ,.11 analcite. gravity oi the analcite is li-z5o, and its composition as tollovvs : — ISilica 5;? -29 Alumiiui l!;5 • 3:i l'\'riic «).\i(ie trace. I-imc • (54 Wagnusia trace. Soda 14-54 Water 8-47 100 -27 The mineral was examined for ]"»otasli, but none found. Before the blow-[)ipe it fuses easily to a colourless glass. When thin sections of the rock are examined Avith the microscope the analcite appears very transparent and shows but few inclusions. It is traversed by numerous reticulaiing cracks, but displays no characteristic clcav^age. The feld- spar is mostly iliill, but here and there is sufticiciitly transparent to show its triclinit' cliaraclcr with polarize! light. The hornblende and titanic iron aj)pear exactly similar to what occurs in the ordinary diorites of the locality. No augite has been observed, but one slide shows numerous green crystals, which arc evidently pseudoinor])hs of serpentine af'tt'r olivine. J n so far as its constituents are concerned, this rock appears to be somewhat similar to that which Tschermak, many j-ears ago. called tesehenitc, after Teschen in Austria. Tschermak regarded the analcite Tesclionite. as one of the normal constituents of the rock, and this it may possibly l)e in the present instance. On the other hand, the general similarity of the other constituents of the rock to those of the ordinary diorites of the vicinity would lead one to infer that the analcite is a secondary niineral, and that the rock is sim])ly an altered diorite. The diorites described above traverse not only the Lower Silurian Age of eruptive *' rooks. limestones, but also the dolerite of Blount Eoyal. Rounded masses of the diorite of precisely similar character occur in the Lower 1 1 elder- berg conglomerate or breccia of St, Helen's Island. Those, therefore, 46 o GEOLOGICAL SURVEY OP CANADA. :t;' who would classify eruptive rocks according to age, would say that Mount Eoyal is a tliahasc and not a dolerite. Admitting such to bo the case, liow is it, the (|uesti<)n may he asked, that dykes of photwlitc are ahru))tly cut off by the diahase, wlien phunolite, according to the chronological theory, ought to be of Tertiary or more recent age? It maybe that future investigations will solves the ditticulty, hut, in the meantime, the eruptive rocks of Montreal d(» not seem to fall into their proper jjlacc in a elassitication based upon age. Analysis of magnetite. Maonetio Iron Ore. According to Dr. (i. M. Dawson, deposits of magnetic iron ore occur near the west end of Cherry Hiutf, on Iviimloops Lake, British ('olumbia. The ore forms irregular veins varying from the thickness of ti sheet of paper up to three feet or more in a sort of diorite, and is often associated with e]»idote. A specimen which has been tmalysed was bluish-black in colour, and showed in places a curious sub-columnar structure. The only gangu(> visil)le was a little 1-85 Ferrous oxide 27-57 Rlangiinous oxide ito'.t IJme 1 ^(J Alagnesia , 0-78 Phosiilioric acid 0-2,'? Siiiphmic acid '. <».it7 ( 'arl)onie acid <>:ir, Water (K!7 Insoluble matter I«'o- Ft'iroTis iiui)oiiate .TJ-To Maiiganous ciirhonato 2 1 tl4 Ciilciiiiu carboniiti' traies. Wagiicsiiiin lailionatt' I I SI IiisoIuIpIl' rosuliic l()-9t l0(l-09 Metallic iron •JS-lt It was brownish-grey in colour, and liad a sjti'citic gravity of 3'4n. The insoluble mattei- was white and mainly silica. The ore is interest- ing on account of the I'ather unii>ually large |)i-o|iorli(in of manganese which it contains, and which would make it valuahle for thr manufacture of spiegeleisei\. Ores of the kind have long heon mined at a uumbei- of localities in Europe, but there the most important deposits arc of Devonian and Permian age. Another specimen from Flint island was little more than a tine- grained <|uai'tzite charged with carbonates of iron and manganese. It containetl ll}'(12 j)er cent, of iron. On the same island coai'sely crystal- line siderite occurs in veins, associated with i|uart/, though not in snlHcient (luantity to be C(uisidered economically ini]H)rtant. Davieau's Island, on the east coast of Hudson Hay, is iinothcr locality in which Dr. IJell has found spathic iron ore. A specimen collected . by him is distinctly crystalline in texture, and contains liT'S.'! per cent, of iron. The |)roportion of manganese has not lieen detei'mined. but is }trobaI)ly high. Fuller details concerning the localities of these spathic ores are given by Dv. Bell in his report. •i LioNiTE, ou Brown (V>ai,. J/r. r. Fast cokinff. Water (at lOO"-! IU'V.) HGO 8fi() Volatile coinbuKtible matter 3')-r>l 41-42 Fixed carlion 4(;-84 40-9.'5 Ash (white) 905 9-05 lOO'OO KIO-IIO The powder showed no disposition to cok'e. When healed with a solution of caustic potash, it coloured tlie solution intensely brown. Junction of Nicola and Coldwafer Bioers, British Columbia. — Proximate analj'ses of coals from this region were given in last yeai''s report, but since then an(>ther si)ecimen has been examinetl which came from the uppermost seam (rifteen feet four inches) of the section given in Dr. Dawson's report (p. 125). It was black, somewhat ])itchy in lustre, and showetl distinct planes of bedding. The powder was brownish- black, and coloured a solution of caustic potash brown, though not veiy intensely. Slow and ftxst coking gave the following residts: Slow cokinf?. Fast pokinK. Water (at 10()"-115°C.) 5-78 ,0-78 Volatile combufitible matter 27-(;5 :i:v72 Fixed carbon 52G9 4062 Ash (reddiah-white) 1 3'88 1 :t-88 10000 100-00 The powder was not fritted even by ra])id heating. Kohasganlio Stream, British Columbia. — This specimen was lu-ought by Dr. G. M. Dawson from a seam of lignite occurring on the above named stream.* It was dull brown to black, and on drying fell into small iragments, often with highly liisti-ous surfaces. it shoAved distinct lamination and a good deal of mineral charcoal between the layers. The powder was blackish-brown and coloured the potash solution very strongly. By slow and rapid heating the following results were obtained : Slow cokinK- Riipid (.-okiner. Water (at lOO'-lir)" C) 9-90 9- 90 Volatile combustible matter 37.71 42-Gl Fixed carbon :i8-85 33-9') Ash (pale giey) 1354 13-54 1000(» 100-00 Belly River, N'orth-Wcst Territori/ — A specimen of »'oal from near Belly Eiver, recently received for examination from the Surveyor- ^n i * See Report of Progress, 1876-77, p. 76. I GOLD AND 8ILVER ASSAYS. 4!) (1 Genoml, Mr. L. A. Kus.sell, proved to l»e of excellent quulity. In a})]»earaiK'o it rosomhled a true bitiiniinous coal from the ('arboniferous, tiioiii,Hi really ol' Cretaceous or possibly Tertiary a^^e. It contained a little mineral charcoal and occasional- thin tilms of calcite in joints, ('oloiir black and fVacture uneven to sub-conclioidal. Analyse-^ by slow and fast coUin<^ ,i;-ave the followini!; : Slow cukinu'. Hygroscopic water r>'V!) Volatile comliiistible matter 41 -'J,") BMxed earlion 47''.M Asli (reiUlisli-fjrcy) . Sm*") l'";isl I'okillfi nii'.ir, 5-0,"> lOO-OO Ratio of volatile eomluistilile mat- ter to fixed carbon 1 1.16 lodoo 1 : 1.5n The powder was sliizlilly sintered by rapid heatiiii;-. it also colouivd a potash solution brown, but not so deeply as the lignites just described. GOi.D AND SILV1':R ASSAYS. Cariboo District, British Coi.umria. Tn the Eeport of Progress for ISTC-'IT a series of assays was pnblished of samples taken from a number of (piartz veins in (he Cariboo district, British Columbia; but in almost cvvA-y instance the proportions of g-ohl and silver found were very tritling. Subse(iuently, other samples were sent I'or examination by the Deputy Minister of Mines. They were assayed, and the results, which were forwarded to Victoria in Juno last, showed a much larger (]uantity of gold than in the specimens previously examined. The residts nniy be given in tabular form, as follow^s: (ioi.ii. Sii.vraf. ()/,. tn ten of Oz. to ton of :2,0(iO 11)>. ;i,lllK.lll»,-'. No. 1 i-i-i:! '••l:<4 u 2 O-SO'J tl-24!t u 3 0- 1 1»; oTx: u 4 :!-24r) i)'Ji:5 ti 5 2 • 450 . 3r)'.> u 6 -"'CS 0-374 l oiiiH'fS to tln^ tun. Silver 1-079 " " •< " *7. — Oros Cap, Luke Superior {Broun 6 Si/rer Mine). A s[)ecimen received trom Dr. II, IJell, and consisting of lallier fine granular galena and /,ine blonde in a gangue ot' caleile ami cpiartz . Silver 0-ori8 ounces to the ton. The proportion of gaU'na and hlende \v:is small ; but even taking this into consideration, it is evident that ncitlier of these minerals contains much silver. 8. — Victoria Mine, (lanhn River. Coarse cryHtalline galena -i^ with enrveil faci's, It was carefully freed from gangue, and found to contain, Silver 30-623 ounces lo the ton. Another sample received at tlie same time, but from which the gangue was not separated, gave, Silver 21 • 1 10 ounces to the ton. 9. — Lake Teinisedinin;/, Ontario. Specimens ■>*' ^.^nlena from a locality discovered in 1877 by Mr. Arncmifcrous Edward VVrig „, of Ottawa. The galena is coarse crystalline, uko" '■""'" and resembles in appearance much of that from the Victoria 'i'c"»i8caming. * For other assays of galena from this locality, see lloport of Progress, 1876-77, j). -180. Tctrahcdrilp t'roiii Ciiiii'llon, Copper pyrites, Oiilcim from New Bruiifwick. 62 O OEOLOOICAL SURVEY OF CANADA. Mine, iiojif (i;ir