key: cord-0738221-s5fk8rdt
authors: Guo, Chuanyan; Guo, Hongge
title: Progress in the Degradability of Biodegradable Film Materials for Packaging
date: 2022-05-06
journal: Membranes (Basel)
DOI: 10.3390/membranes12050500
sha: bada156fb738e26cd17aa4f3c4c5d53a5721eaf9
doc_id: 738221
cord_uid: s5fk8rdt

In today’s world, the problem of “white pollution” is becoming more and more serious, and many countries have paid special attention to this problem, and it has become one of the most important tasks to reduce polymer waste and to protect the environment. Due to the degradability, safety, economy and practicality of biodegradable packaging film materials, biodegradable packaging film materials have become a major trend in the packaging industry to replace traditional packaging film materials, provided that the packaging performance requirements are met. This paper reviews the degradation mechanisms and performance characteristics of biodegradable packaging film materials, such as photodegradation, hydrodegradation, thermo-oxidative degradation and biodegradation, focuses on the research progress of the modification of biodegradable packaging film materials, and summarizes some challenges and bottlenecks of current biodegradable packaging film materials.

Plastic was once hailed as one of the greatest inventions of the 20th century, because of its light weight, good processing performance, low price and many other advantages that make the global plastic industry has been rapid development [1] . According to statistics, the total global production of plastic products exceeds 300 million tons [2] [3] [4] , with 13 million tons entering the water [5] . However, only 6-26% of plastic products are recycled, which means that at least 74% of plastic waste ends up in landfills or enters the environment every year [3, 6] , of which about 46% comes from the packaging industry, especially food packaging films, which are largely non-recyclable [7] . Since most plastics are now made from non-biodegradable materials, it often takes one to two hundred years to degrade these plastic products [8] [9] [10] [11] [12] [13] .

Plastic is the most commonly used packaging material [14, 15] , especially packaging film material. However, the packaging industry generates about 141 million tons of plastic waste each year [16] , and most of the packaging film materials are composed of non-degradable materials, which obviously leads to many environmental problems, such as "white pollution" [17] [18] [19] . General purpose plastic packaging films such as polyethylene (PE), polypropylene (PP), polystyrene (PS) and polyvinyl chloride (PVC) [20, 21] film materials undergo a long period of aging under the current common waste disposal method of sanitary landfill conditions. Under the action of abiotic factors (such as solar radiation, high temperature, wave impact, gravel abrasion) or biotic factors (such as ingestion, colonization, degradation) [22, 23] , physical or chemical property changes, molecular weight reduction and molecular weight distribution changes, but its decomposition is not complete, the majority of decomposition into microplastics (particle size < 5 mm) or nanosized-plastics (particle size < 0.1 µm) [24, 25] . At present, microplastics have been widely detected in oceans [24, 26] , sediments [27] , rivers [28] [29] [30] , lakes [20] , atmosphere [31] [32] [33] , soil [34, 35] and organisms [36] , disrupting the normal metabolism and energy balance in organisms, thus affecting the normal growth and reproduction of organisms and causing potential harm to human health [37, 38] .

To solve these problems, it has become important for biodegradable packaging film materials to replace traditional packaging film materials [39, 40] . However, biodegradable plastics currently account for less than 1% of total plastics production [41] . Compared with traditional packaging film materials, biodegradable packaging film materials are more expensive to produce and have poor mechanical properties and their barrier properties, which are the main reasons for their limited applications [42] .

This paper reviewed the degradation mechanism of different packaging films and the research progress of biodegradable films, and provided outlook on the future development trend of packaging film materials.

Degraded plastics are plastics that have been subjected to defined environmental conditions for a period of time and contain one or more steps that result in significant changes in the chemical structure of the material resulting in loss of certain properties (such as integrity, molecular mass, structure or mechanical strength) and/or fragmentation [43, 44] . As shown in Table 1 , the degradation degree can be divided into complete and incomplete degradation, and different degradation mechanisms can be divided into photodegradation, water degradation, thermal oxidative degradation and biodegradation [45] . 

Photodegradable materials are degraded to low molecular weight compounds that are relatively safe for the environment by photo-initiated fracture and free radical oxidative fracture reactions under the action of sunlight (mainly UV light) [46] . Photodegradable film materials can be mainly divided into photodegradable materials obtained by copolymerization and photodegradable materials with composite photosensitizers [47] .

In sunlight, UV light with a wavelength of 290 nm-400 nm only accounts for about 5%, and it is the UV light that causes photodegradation of the film. Figure 1 shows the photodegradation mechanism. The molecular chains react under certain conditions of oxygen, temperature and humidity, and the long molecular chains are decomposed into peroxides and eventually achieve photodegradation [48] . Christensen et al. [49] investigated the photodegradation properties of polymers with a 1:1 mass ratio of polycaprolactone to polyvinyl chloride by monitoring CO 2 emissions during UV exposure. The results showed that the interaction of the two components in the polymer reduced the photodegradability. Najaf et al. [50] used polyaniline modified TiO 2 as a photocatalyst and then combined it with polyvinyl chloride to make photodegradable films. The results showed that the quality of polyaniline decreased by 67% when the molar ratio of polyaniline to TiO 2 was 10:1 under the condition of 30W UV lamp irradiation for 720 h, decreased by 12% compared with the pure polyvinyl chloride (PVC) film, and its photodegradation performance was greatly improved.

Photodegradable materials must be exposed to light and have a long degradation period, while most film materials are not exposed to natural light for a long time after disposal and it is difficult to ensure the degradation conditions required for photodegradable film materials, which greatly limits the large-scale application of photodegradable film materials.

Hydrodegradable plastic is a kind of plastic that can self-degrade by hydrolysis. The essence is the presence of hydrolyzable covalent bonds in degradable plastics, such as esters, ethers, anhydrides, amides, carbamides or ester-amide groups [45] , which can achieve dissolution when the plastic encounters water [51, 52] . Water activity, temperature, pH and time are the key factors affecting the efficiency of hydrolysis [53] .

Polyvinyl alcohol (PVA) is a water-soluble polymer with a carbon chain as the main chain and a large number of hydroxyl groups on the side chain [54, 55] . It is non-toxic, easily processed, biodegradable, has good mechanical properties [56, 57] , and can be mixed with natural polymeric materials such as polysaccharides and proteins to improve its properties [58] [59] [60] . Mainly used in the packaging of water-soluble products, the buyer can do not touch the product in the process of using the product, safe and at the same time make the use of the product more convenient. However, the resistance of PVA film to water is very low, usually in a very short period of time can be completely dissolved [61] ; therefore, if it is widely used in the field of packaging needs, it needs to be modified for water resistance.

Lv et al. [62] investigated the time-dependent hydrolysis behavior of polylactic acid (PLA) and starch/PLA composites. The results showed that the presence of starch may induce hydrolysis to occur at the interface between starch and PLA. In addition, starch can slightly slow down PLA hydrolysis without affecting the degree of PLA hydrolysis. Table 2 shows the water degradation of several common biodegradable polyesters in different water environments. 

Thermally oxygen degraded plastic is that subjected to heat and/or oxidation over a period of time and contains one or more steps that result in significant changes in the chemical structure of the material, resulting in loss of certain properties (such as integrity, molecular mass, structure or mechanical strength) and/or fragmentation [64, 65] . Heat can change the oxidation mechanism of plastics, and higher temperatures can improve the degradation of plastics [66, 67] . Figure 2 shows the mechanism of thermal oxidative degradation. Thermally oxygen degraded plastic is also very difficult to degrade completely in most cases due to the conditions. Gaurav et al. [69] prepared two high-density polyethylene/polylactic acid blends with and without the addition of a compatibilizer and a pro-oxidant using a melt blending technique. The results showed that the addition of the compatibilizer led to a significant improvement in the mechanical properties of the blends and the addition of the pro-oxidant led to an improvement in their oxidative degradation properties.

Biodegradable plastics are those degraded by naturally occurring microorganisms under natural conditions such as soil and/or sand, and/or specific conditions such as composting or anaerobic digestion or aqueous cultures, and ultimately degrade to environmentally benign biomass, CO 2 , CH 4 and H 2 O [70] [71] [72] . Figure 3 shows the biodegradation mechanism. Biodegradable plastics have stable performance and can be completely degraded and returned to nature in a short period of time under composting conditions [73] . Current research shows that animals, plants, microorganisms and enzymes all have some ability to degrade plastics [74, 75] . Table 3 shows the biodegradation of common plastics. Among the many ways to change the properties of plastics, biodegradation of plastics is one of the inevitable environmental processes for plastics to enter the environment, and it is also an in situ, green, relatively low-cost and low-technology way to treat plastic waste.

Among various degradable mechanisms, biodegradation is more complete and faster than other degradation mechanisms, and the degradation products are harmless. Biodegradable plastics can be composted together with organic waste, thus eliminating the manual sorting step compared to general plastic waste, greatly facilitating waste collection and disposal, thus making composting and harmless disposal of organic waste into reality [80] .

Biodegradable packaging film materials are green, environment-friendly and resourcesaving compared with traditional film materials, thus gradually becoming a research hotspot in the packaging industry, the development of biodegradable packaging film is an effective way to fundamentally solve "white pollution". 

Biodegradable film materials can be divided into three categories according to raw materials and processing methods: natural polymer-based films, petroleum-based film materials and bio-based film materials.

Starch is a natural degradable polymer [81] , available from a wide range of plant species [82] , the long chain molecules can be broken into glucose monosaccharides and other small molecules by the action of microorganisms, and eventually metabolized to CO 2 and H 2 O [83] . Starch-based films are one of the most productive biodegradable films in the world, with high flexibility, good oxygen barrier, colorless, environmentally friendly and other characteristics [84] , but its film also has a difficult to process, physical properties and poor water resistance as well as other disadvantages [85] , so in practical use, they usually need to be modified [86] . Surface modification [87, 88] , blending with reinforcement fillers [89] [90] [91] , and blending with other polymers [92, 93] are the three most commonly applied reinforcement strategies. Table 4 shows the different modifications of starch-based film materials. 

Blending with other polymers

Modified starch-based film materials with natural fibers in blends

Tensile strength and modulus of elasticity were improved, but the elongation at break was not as good as that of ordinary starch-based films [92] Blending with other polymers

Modified barley hulls (BH) by grafting palmitic acid and then blended with cross-linked polyvinyl alcohol (PVA)/starch

The physical properties of the composite film could be effectively improved, and the air and water resistance were substantially enhanced [93] Surface modification Acetylated corn starch (AS), acetylated sugarcane fiber (AcSF) and glycerol were used to make biodegradable film materials Mechanical properties and water resistance have been improved [87] Blending with reinforcement fillers Different contents of metakaolin were blended with cassava starch to make film materials

The mechanical tensile strength and properties increased significantly and the elongation at break decreased [91] 3.

Cellulose is a highly reactive biopolymer with a large amount of hydroxyl group in its structure [94] [95] [96] [97] , which can be chemically modified through various reactions such as esterification, etherification and oxidation to give cellulose new properties while ensuring its degradable properties [98, 99] . As a packaging material, cellulose also has good biodegradability and excellent physical and mechanical properties, which makes it one of the most suitable natural polymers for use in films [98, 100] . However, cellulose also has some limitations, such as high water absorption and poor interfacial adhesion [101] . Cellulose is also converted into various derivatives, which can be mainly classified as: cellulose acetate (CA), cellulose sulfate (CS), cellulose nitrate (CN), carboxymethyl cellulose (CMC), ethyl cellulose (EC), methyl cellulose (MC), cellulose nanocrystals (CNC) and nanocellulose (NC) [98] . Table 5 shows examples of cellulose derivatives film formation. 

As the second most abundant polysaccharide in nature after cellulose [106, 107] , chitosan (CS) is not only widely available and biodegradable, but also has good film-forming, biocompatible and antibacterial properties [108, 109] , and is one of the ideal materials for packaging films. However, its poor mechanical properties, weak water resistance and poor thermal stability also limit the application in packaging [110, 111] . Properties can be improved by cross-linking [112, 113] , graft copolymerization [114, 115] , blending with reinforcement fillers [116] and blending with other polymers [117] . Table 6 shows the different modifications of chitosan-based film materials. 

Preparation of a chitosan/bacterial cellulose membrane treated by multiple cross-linking methods Mechanical strength and elongation at break increase, but its antimicrobial efficiency decreases [112] Graft copolymerization Chitosan (CS) was grafted with caffeic acid (CA-g-CS) through carbodiimide coupling and cast into films CA-g-CS films have higher tensile strength, elongation at break and oxidation activity, and better barrier properties to water vapor and oxygen [114] Blending with reinforcement fillers Nickel oxide nanoparticles (NiONPs) were doped into chitosan-based films to fabricate composite films

The composite film has improved water resistance, tensile strength, thermal properties and surface hydrophobicity, and has ideal photocatalytic and antibacterial activity [116] Blending with other polymers

Biodegradable chitosan-based film containing micro ramie fiber and lignin was prepared by the casting method Significant improvement in mechanical, water resistance, thermal and oxidation resistance properties [117] 

Poly (butylene succinate) (PBS or PBSu), an aliphatic polyester, can be contained in petrochemical-based biodegradable polymers [118, 119] , but the important novelty is that PBS can be produced from renewable resources such as sugarcane, cassava and corn [120, 121] . PBS has similar properties to PE, so it is often compared to PE and appears as a biodegradable alternative [122] . PBS has excellent properties, such as elongation at break of over 200% and good barrier properties [7, 123] . However, the relatively high cost still limits its application. Therefore, many strategies are being developed to reduce costs, on the one hand, and improve its performance to meet the specific requirements of packaging, on the other. Blending with other polymers [124] [125] [126] [127] , synthetic copolymers [128, 129] and blending with reinforcement fillers [130, 131] are commonly used to improve their properties. Table 7 shows the different modifications of PBS film materials. 

Blending with other polymers

The PBS and plasticized whey protein (PWP) blend makes the film Significant increase in modulus of elasticity, tensile strength and elongation at break [124] Blending with other polymers

Improved hydrophilicity and biodegradability, in addition to higher pollution inhibition index [127] Synthetic copolymers Synthetic poly (butylene succinate-co-diethylene glycol succinate) (P(BS-co-DEGS)) copolymer Crystallinity, tensile modulus, thermal stability slightly reduced and water degradation rate increased.

[129]

Blending with reinforcement fillers

Improved barrier properties to water and oxygen [131] 3.

Poly (butyleneadipate-co-terephthalate) (PBAT) is an aliphatic-aromatic copolyester mainly made by condensation of benzodimethyl (C 8 H 6 O 4 ), adipic acid (C 6 H 10 O 4 ) and butylene glycol (C 4 H 10 O 2 ), etc. [132] [133] [134] . In addition to biodegradability, PBAT has high flexibility, high strength and good tear resistance, and is widely used in various industries, especially in food packaging [135, 136] . Pure PBAT films have higher costs and lower mechanical properties than traditional film materials [133, 137, 138] , so blending with reinforcement fillers [139] [140] [141] [142] or blending with other polymers [134, 143] is an effective way to reduce prices and improve performance. Table 8 shows the different modifications of PBAT film materials. The addition of TiO 2 leads to the improvement of the overall barrier properties, thermal stability and tensile strength of PBAT composite film materials, but its elongation at break decreases [142] 

Polycaprolactone (PCL) is a green, non-toxic synthetic aliphatic polyester material [144] with numerous advantages, including: (1) faster crystallization rate and higher crystallization [145] ; (2) rubbery state at room temperature, elongation at break hundreds of times higher than PLA [146, 147] ; (3) better rheology, viscoelasticity, good flexibility and processability [148] ; (4) outstanding resistance to UV radiation, wear resistance, anti-aging properties, longer degradation half-life than PLA [127, 149] ; (5) excellent biocompatible and biodegradable, non-toxic and harmless, EU and FDA certified for implantation into human body [150] ; (6) strong hydrophobicity and drug passage [151] . However, it has the characteristics of poor water solubility, slow degradation, low melting point and poor mechanical strength, so it needs to be modified in the actual use process. Table 9 shows the different modifications of PCL film materials. Table 9 . The different modifications of PCL film materials.

Cross-linking Polycaprolactone (PCL) was cross-linked by adding different amounts of organic peroxides, such as di-(2-tert-butylperoxyisopropyl)benzene (BIB) PCL branching and cross-linking have significant effects on the mechanical properties of PCL 0.5 pbw (part by weight) BIB-modified PCL has better mechanical properties, and higher BIB content can lead to degradation and excessive cross-linking of PCL [152] Compound modification Prepared PCL/polyvinyl chloride (PVC)/organoclay nanobioblends film Enhanced mechanical and barrier properties, exhibiting some antibacterial activity [153] Blending with other polymers PCL/PLA is mixed and green tea extract (GTE) is used as an antioxidant to make the film Reduced hydrophilicity and enhanced barrier and mechanical properties [154] 3.3. Bio-Based Film Materials 3.

Polyhydroxyalkanoate (PHA) is a general term for a class of biopolyester produced by microbial fermentation engineering technology, which has good biocompatibility and biodegradability [155, 156] , and has the thermoplastic processability of petrochemical resins, which can be processed by injection molding, extrusion blow molding film, extrusion calendering, extrusion hollow molding, compression molding, etc., and manufactured into films and containers that are widely used in packaging [157, 158] . PHAs are classified into short chain length and medium chain length PHAs, which depend on the amount of carbon in the monomeric fraction [159, 160] . Its main varieties are poly-β-hydroxybutyric acid (PHB), poly-β-hydroxyvalerate (PHV) and their copolymers poly (β-hydroxybutyrate-βhydroxyvalerate) (PHBV), etc. [161] . Besides having some advantages, it is limited by poor mechanical properties, high susceptibility to thermal degradation and high production cost in practical applications [162] , so it needs to be modified. Table 10 shows the different modifications of PHA film materials. 

Four cross-linkers (citric acid, adipic acid, borax and boric acid) with polycarboxyl or polyhydroxy structures were used in the preparation of the starch/polyhydroxyalkanoate (PHA) films

With higher relative crystallinity, but hinders the formation of intercalation structures in the polymer matrix, improving light transmission and barrier properties [163] Blending with reinforcement fillers Lignin nanoparticles homogeneously dispersed in poly-β-hydroxybutyric acid (PHB) matrix to form nanocomposites with improved properties using oil-in-water emulsion method Improved mechanical properties, lower crystallinity, higher glass transition temperature and better barrier properties [164] Compound modification Preparation of PHA/PLA nanocomposite films under different levels of montmorillonite

Better thermal stability and electrical conductivity [165] 3.

Polylactic acid (PLA) is a type of degradable polymer material with lactic acid as raw material [166, 167] , which is renewable and has the characteristics of non-toxicity, nonirritation, good biocompatibility, processability, excellent mechanical properties, complete biodegradability and environmental friendliness [168, 169] , and is considered as the main alternative to petroleum-based plastics [170] .

The degradation of PLA in nature occurs first by water degradation and then by biodegradation, and the hydrolysis of PLA films is mainly caused by the hydrolysis of the ester bond of the main chain into molecules of low relative molecular mass [171] [172] [173] [174] , and the hydrolysis process is shown in Figure 4 [175] . The biodegradation of PLA is greatly influenced by environmental factors [176] . The start of hydrolysis at room temperature takes six months, while biodegradation takes one year, and microorganisms play almost no role in the beginning of hydrolysis, which is one of the characteristics of PLA [176, 177] .

PLA is one of several biodegradable plastics with large global production, PLA has sufficient raw material sources, is renewable and has good hardness, gloss and thermoplasticity, as well as good tensile strength and processing properties, but it also has deficiencies such as poor blending properties and expensive [178] . Currently, the comprehensive performance of PLA is mainly improved by copolymerization modification, blending with reinforcement fillers, blending with other polymers and compound modification [179] [180] [181] . Table 11 shows the different modifications of PLA film materials. 

Blending with reinforcement fillers Add bamboo cellulose nanowhiskers (BCNW) to PLA as a filler and make a film by solution casting method Mechanical properties, glass transition temperature, cold crystallinity increase and microcrystal size increase significantly [180] Compound modification Introduction of glass fibers (GF) modified with silane coupling agent (GF-S) into PLA to make PLA-based composites Improved mechanical and thermodynamic properties [179] Blending with reinforcement fillers

Halloysite nanotubes (HNT) and chitosan as fillers were blended with PLA to make films Mechanical strength and mechanical properties have been improved, with excellent barrier to water and UV light, and some antibacterial ability [166] Blending with other polymers Cinnamic acid (CA)/PLA films obtained by casting or thermal processing Greatly improves the mechanical properties of the film and improves the barrier to oxygen and water [182] copolymerization modification PLA is blended with polydecalactone (PDL)-grafted cellulose copolymer (CgPD) and made into films Improved mechanical properties and mechanical properties [183] PLA film is the most cost-effective biodegradable film material. Its mechanical properties and transparency are similar to those of polystyrene (PS) or polyethylene terephthalate (PET) films, and it has good processability and stable performance, making it a promising biodegradable film. Compared with other materials, there are many PLA materials that are already used in business. R. J. Reynolds Tobacco Products (US) has developed a new tobacco packaging film coated with a metal oxide layer consisting of aluminum oxide, titanium oxide and/or aluminum-titanium oxide that retains some moisture barrier capability at the fold after folding [184] . Suzhou Xinghuo Fengying Environment Prot Package Co Ltd. has developed a blown film process using PLA, PBAT, antioxidants and poly (N-propionylethylenimine) blended extrusion, according to which the garbage bags produced by this process have high elongation at break [185] . Perak Biochemicals has developed a method for producing polylactic acid (PLA)-shaped products by thermoforming and such thermoformed PLA products. Purac Biochem Bv (NL) Perak Biochemicals has developed a method for producing polylactic acid (PLA)-shaped products by thermoforming and such thermoformed PLA products [186] .

This review focuses on the degradation mechanism of packaging films and the properties and performance of several common biodegradable film materials available today. This includes natural polymer-based film materials, petroleum-based film materials and bio-based film materials. With the global "plastic ban", the development of biodegradable packaging films is one of the important research directions to solve the resource and environmental problems. However, biodegradable packaging films also have poorer performance than traditional packaging films, insufficient degradation controllability and higher production costs. How to reduce the material production cost by improving the synthesis and process is an urgent issue for the massive use of biodegradable films. In response to the disadvantages of poor performance of biodegradable films, the development of modification technologies such as cross-linking modification, hybrid modification, copolymer modification and composite modification has become one of the key research directions at present. The degradation performance of biodegradable packaging film is also an important factor affecting its use, and either too fast or too slow degradation will limit its use. To master the degradation mechanism of biodegradable packaging films and then realize the controlled degradation of packaging films is a challenge that needs to be overcome by the efforts of researchers.

At present, the misuse of biodegradable film materials in the market places a great burden on the environment. Since they are expensive, some manufacturers usually add some petroleum-based plastics to biodegradable products to improve durability as well as reduce cost. However, this can lead to "pseudo-degradation" and can result in microplastics entering the environment, causing a greater burden on the environment. Therefore, developing biodegradable standards for the packaging industry will also be a priority. The global outbreak of the coronavirus disease (COVID-19) in 2019 has gradually started to bring antibacterial and antiviral packaging films into the limelight, and food safety issues have become too important to ignore, and the development of antibacterial and antiviral biodegradable packaging films will be an important research direction. Research and development of biodegradable packaging films with better performance, economy and convenience is the main task of the packaging industry all over the world, replacing traditional packaging films with biodegradable packaging films to achieve green development in the packaging field. 

The authors declare no conflict of interest.

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Highly Efficient Preparation of Functional and Thermostable Cellulose Nanocrystals via H 2 SO 4 Intensified Acetic Acid Hydrolysis

Recent Development and Environmental Applications of Nanocellulose-Based Membranes

A Review of Cellulose and Its Derivatives in Biopolymer-Based for Food Packaging Application

Green Encapsulation of LDH(Zn/Al)-5-Fu with Carboxymethyl Cellulose Biopolymer; New Nanovehicle for Oral Colorectal Cancer Treatment

Recent Advances in Polymers and Polymer Composites for Food Packaging

Angellier-Coussy, H. Mitigating the Impact of Cellulose Particles on the Performance of Biopolyester-Based Composites by Gas-Phase Esterification

Fabrication of Improved Cellulose Acetate-Based Biodegradable Films for Food Packaging Applications

Oil Palm Biomass Cellulose-Fabricated Polylactic Acid Composites for Packaging Applications

Preparation and Characterization of Carboxymethyl Cellulose-Based Composite Films Reinforced by Cellulose Nanocrystals Derived from Pea Hull Waste for Food Packaging Applications

Preparation and Functional Properties of Poly(Vinyl Alcohol)/Ethyl Cellulose/Tea Polyphenol Electrospun Nanofibrous Films for Active Packaging Material

Chitosan Based Nanocomposite Films and Coatings: Emerging Antimicrobial Food Packaging Alternatives

Graphene Oxide, and Cerium Oxide Composite Blended Films: Structural, Physical, and Functional Properties

Preparation and Characterization of Chitosan/Nano-ZnO Composite Film with Antimicrobial Activity

Application Status and Technical Analysis of Chitosan-Based Medical Dressings: A Review

Development of Functional Chitosan-Based Composite Films Incorporated with Hemicelluloses: Effect on Physicochemical Properties

Antimicrobial Food Packaging Based on Sustainable Bio-Based Materials for Reducing Foodborne Pathogens: A Review

The Impact of Cross-Linking Mode on the Physical and Antimicrobial Properties of a Chitosan/Bacterial Cellulose Composite

Viscoelastic Properties of Crosslinked Chitosan Films. Processes

Characterization of the Physical Properties and Biological Activity of Chitosan Films Grafted with Gallic Acid and Caffeic Acid: A Comparison Study

Chitosan Derivatives: Introducing New Functionalities with a Controlled Molecular Architecture for Innovative Materials

Chitosan-Based Nanocomposite Films Incorporated with NiO Nanoparticles: Physicochemical, Photocatalytic and Antimicrobial Properties

Chitosan-Based Composite Film Reinforced by Ramie Fibre and Lignin for Food Packaging

A Review on Current Strategies for the Modulation of Thermomechanical, Barrier, and Biodegradation Properties of Poly (Butylene Succinate) (PBS) and Its Random Copolymers

Biodegradability of Bio-Flour Filled Biodegradable Poly(Butylene Succinate) Bio-Composites in Natural and Compost Soil

Butylene Succinate) (PBS) and Its Main Copolymers: Synthesis, Blends, Composites, Biodegradability, and Applications. Polymers 2022

Green Composites: An Overview

Bio-Based Poly (Butylene Succinate): Recent Progress, Challenges and Future Opportunities

How Do Cellulose Nanocrystals Affect the Overall Properties of Biodegradable Polymer Nanocomposites: A Comprehensive Review

Preparation and Compatibilization of PBS/Whey Protein Isolate Based Blends

PLA) and Its Blends with Poly(Butylene Succinate) (PBS): A Brief Review

Thermoforming of Compostable PLA/PBS Blends Reinforced with Highly Hygroscopic Calcium Carbonate

Biodegradable Membrane Based on Polycaprolactone/Polybutylene Succinate: Characterization and Performance Evaluation in Wastewater Treatment

Improving Polylactide Toughness by Plasticizing with Low Molecular Weight Polylactide-Poly(Butylene Succinate) Copolymer

Synthesis and Properties of Biodegradable Poly(Butylene Succinate-Co-Diethylene Glycol Succinate) Copolymers

A Review on Green Composites Based on Natural Fiber-Reinforced Polybutylene Succinate (PBS)

Improvement of Barrier Properties of Biodegradable Polybutylene Succinate/Graphene Nanoplatelets Nanocomposites Prepared by Melt Process

Polyhydroxybutyrate Blends: A Solution for Biodegradable Packaging?

An Overview on Synthesis, Properties and Applications of Poly(Butylene-Adipate-Co-Terephthalate)-PBAT

Binary Green Blends of Poly(Lactic Acid) with Poly(Butylene Adipate-Co-Butylene Terephthalate) and Poly(Butylene Succinate-Co-Butylene Adipate) and Their Nanocomposites

Eco-Friendly Polymer Composites for Green Packaging: Future Vision and Challenges

Influence of Low Contents of Superhydrophilic MWCNT on the Properties and Cell Viability of Electrospun Poly (Butylene Adipate-Co-Terephthalate) Fibers

A Critical Review on the Progress and Challenges to a More Sustainable, Cost Competitive Synthesis of Adipic Acid

Tailoring the Structure, Morphology, and Crystallization of Isodimorphic Poly(Butylene Succinate-Ran-Butylene Adipate) Random Copolymers by Changing Composition and Thermal History

Mechanical and Morphological Properties of Poly(Butylene Adipate-Co-Terephthalate)/Thermoplastic Starch Blends and Its Biocomposite with Babassu Mesocarp

Economically Competitive Biodegradable PBAT/Lignin Composites: Effect of Lignin Methylation and Compatibilizer

Effects of High Starch Content on the Physicochemical Properties of Starch/PBAT Nanocomposite Films Prepared by Extrusion Blowing

TiO 2 Nanoparticles/Poly(Butylene Adipate-co-terephthalate) Bionanocomposite Films for Packaging Applications

Properties of Biodegradable Films Based on Poly(Butylene Succinate) (PBS) and Poly(Butylene Adipate-Co-Terephthalate) (PBAT) Blends

Synthesis of Polycaprolactone: A Review

The Return of a Forgotten Polymer-Polycaprolactone in the 21 st Century

The Physical Characterization of a Thermoplastic Polymer for Endodontic Obturation

Pillin, I. Organomontmorillonite/Graphene-PLA/PCL Nanofilled Blends: New Strategy to Enhance the Functional Properties of PLA/PCL Blend

In-Depth Study from Gluten/PCL-Based Food Packaging Films Obtained under Reactive Extrusion Conditions Using Chrome Octanoate as a Potential Food Grade Catalyst

A Review on the Recent Research of Polycaprolactone (PCL)

Poly(ε-Caprolactone): A Potential Polymer for Biodegradable Food Packaging Applications

Study on Hydrophilicity and Degradability of Chitosan/Polylactide-Co-Polycaprolactone Nanofibre Blend Electrospun Membrane

Structural and Thermo-Mechanical Properties of Poly(ε-Caprolactone) Modified by Various Peroxide Initiators

Performances of PCL/PVC/Organoclay Nanobioblends Films for Packaging Applications

Fabrication and Characterization of Biodegradable Active Films with Modified Morphology Based on Polycaprolactone-Polylactic Acid-Green Tea Extract

PHB Produced by Bacteria Present in the Argan Field Soil: A New Perspective for the Synthesis of the Bio-Based Polymer

Microbial Polyhydroxyalkanoates (PHAs): Efficient Replacement of Synthetic Polymers

Polyhydroxyalkanoate (PHA): Properties and Modifications

Hydrothermal Treatment of Lignocellulose Waste for the Production of Polyhydroxyalkanoates Copolymer with Potential Application in Food Packaging

Blends and Composites of Polyhydroxyalkanoates (PHAs) and Their Applications

Polyhydroxyalkanoates: Characteristics, Production, Recent Developments and Applications

Development of Polyhydroxyalkanoates Production from Waste Feedstocks and Applications

Grand Challenges for Industrializing Polyhydroxyalkanoates (PHAs)

Effects of Various Cross-Linking Agents on the Physicochemical Properties of Starch/PHA Composite Films Produced by Extrusion Blowing

Fabrication of Lignin/Poly(3-Hydroxybutyrate) Nanocomposites with Enhanced Properties via a Pickering Emulsion Approach

Nanofiller Reinforced Biodegradable PHA/PLA Composites: Physico-Chemical, Thermal and Dielectric Properties

Modulating the Properties of Polylactic Acid for Packaging Applications Using Biobased Plasticizers and Naturally Obtained Fillers

Evaluation of Nanofiltration Membranes for Pure Lactic Acid Permeability

Development of Active Packaging Film Made from Poly (Lactic Acid) Incorporated Essential Oil

Biodegradable PLA/PBS Multinanolayer Membrane with Enhanced Barrier Performances

Lactic Acid) Blends: Processing, Properties and Applications

Physicochemical Evolutions of Starch/Poly (Lactic Acid) Composite Biodegraded in Real Soil

Lactic Acid)-Based Nanobiocomposites with Modulated Degradation Rates

Hydrolytic Degradation and Lifetime Prediction of Poly(Lactic Acid) Modified with a Multifunctional Epoxy-Based Chain Extender

Degradation Behavior and Mechanism of Poly(1actic Acid)Based Composites

Chemical Recycling of PLA: A Great Opportunity Towards the Sustainable Development?

Do Poly(Lactic Acid) Microplastics Instigate a Threat? A Perception for Their Dynamic towards Environmental Pollution and Toxicity

Enhancement of Gas Barrier Properties of Graphene Oxide/Poly (Lactic Acid) Films Using a Solvent-Free Method

The Effect of Surface Modification of Glass Fiber on the Performance of Poly(Lactic Acid) Composites: Graphene Oxide vs

Effects of Bamboo Cellulose Nanowhisker Content on the Morphology, Crystallization, Mechanical, and Thermal Properties of PLA Matrix Biocomposites

Emerging Materials and Technologies of Multi-Layer Film for Food Packaging Application: A Review

Properties of PLA Films with Cinnamic Acid: Effect of the Processing Method

Enhancement of Tensile Toughness of Poly(Lactic Acid) (PLA) through Blending of a Polydecalactone-Grafted Cellulose Copolymer: The Effect of Mesophase Transition on Mechanical Properties

Package Wrapping Including PLA Film with Moisture Barrier by Atomic Layer Deposition. WO2018013367A1

Biodegradable Material, Preparation Method and Use Thereof

Process for Producing Active Food Packaging Based on Polylactic Acid Modified with Nanocomposite. Romania Patent RO134492A0