id	sid	tid	token	lemma	pos
x633dz03j6s	1	1	this	this	DET
x633dz03j6s	1	2	dissertation	dissertation	NOUN
x633dz03j6s	1	3	describes	describe	VERB
x633dz03j6s	1	4	studies	study	NOUN
x633dz03j6s	1	5	encompassing	encompass	VERB
x633dz03j6s	1	6	a	a	DET
x633dz03j6s	1	7	variety	variety	NOUN
x633dz03j6s	1	8	of	of	ADP
x633dz03j6s	1	9	areas	area	NOUN
x633dz03j6s	1	10	of	of	ADP
x633dz03j6s	1	11	carbocation	carbocation	ADJ
x633dz03j6s	1	12	chemistry	chemistry	NOUN
x633dz03j6s	1	13	.	.	PUNCT
x633dz03j6s	2	1	carbocation	carbocation	NOUN
x633dz03j6s	2	2	formation	formation	NOUN
x633dz03j6s	2	3	in	in	ADP
x633dz03j6s	2	4	ionic	ionic	ADJ
x633dz03j6s	2	5	liquids	liquid	NOUN
x633dz03j6s	2	6	,	,	PUNCT
x633dz03j6s	2	7	which	which	PRON
x633dz03j6s	2	8	are	be	AUX
x633dz03j6s	2	9	polar	polar	ADJ
x633dz03j6s	2	10	aprotic	aprotic	ADJ
x633dz03j6s	2	11	solvents	solvent	NOUN
x633dz03j6s	2	12	,	,	PUNCT
x633dz03j6s	2	13	was	be	AUX
x633dz03j6s	2	14	studied	study	VERB
x633dz03j6s	2	15	.	.	PUNCT
x633dz03j6s	3	1	the	the	DET
x633dz03j6s	3	2	chemistry	chemistry	NOUN
x633dz03j6s	3	3	of	of	ADP
x633dz03j6s	3	4	some	some	DET
x633dz03j6s	3	5	unusual	unusual	ADJ
x633dz03j6s	3	6	silicon	silicon	NOUN
x633dz03j6s	3	7	substituted	substitute	VERB
x633dz03j6s	3	8	carbocations	carbocation	NOUN
x633dz03j6s	3	9	was	be	AUX
x633dz03j6s	3	10	also	also	ADV
x633dz03j6s	3	11	investigated	investigate	VERB
x633dz03j6s	3	12	.	.	PUNCT
x633dz03j6s	4	1	reactions	reaction	NOUN
x633dz03j6s	4	2	of	of	ADP
x633dz03j6s	4	3	a	a	DET
x633dz03j6s	4	4	number	number	NOUN
x633dz03j6s	4	5	of	of	ADP
x633dz03j6s	4	6	triflates	triflate	NOUN
x633dz03j6s	4	7	,	,	PUNCT
x633dz03j6s	4	8	mesylates	mesylate	NOUN
x633dz03j6s	4	9	and	and	CCONJ
x633dz03j6s	4	10	trifluoroacetates	trifluoroacetate	NOUN
x633dz03j6s	4	11	in	in	ADP
x633dz03j6s	4	12	ionic	ionic	ADJ
x633dz03j6s	4	13	liquids	liquid	NOUN
x633dz03j6s	4	14	have	have	AUX
x633dz03j6s	4	15	been	be	AUX
x633dz03j6s	4	16	investigated	investigate	VERB
x633dz03j6s	4	17	.	.	PUNCT
x633dz03j6s	5	1	it	it	PRON
x633dz03j6s	5	2	was	be	AUX
x633dz03j6s	5	3	concluded	conclude	VERB
x633dz03j6s	5	4	that	that	SCONJ
x633dz03j6s	5	5	these	these	DET
x633dz03j6s	5	6	substrates	substrate	NOUN
x633dz03j6s	5	7	all	all	PRON
x633dz03j6s	5	8	react	react	VERB
x633dz03j6s	5	9	via	via	ADP
x633dz03j6s	5	10	carbocationic	carbocationic	ADJ
x633dz03j6s	5	11	intermediates	intermediate	NOUN
x633dz03j6s	5	12	.	.	PUNCT
x633dz03j6s	6	1	in	in	ADP
x633dz03j6s	6	2	fact	fact	NOUN
x633dz03j6s	6	3	,	,	PUNCT
x633dz03j6s	6	4	some	some	PRON
x633dz03j6s	6	5	of	of	ADP
x633dz03j6s	6	6	the	the	DET
x633dz03j6s	6	7	ionic	ionic	ADJ
x633dz03j6s	6	8	liquids	liquid	NOUN
x633dz03j6s	6	9	under	under	ADP
x633dz03j6s	6	10	investigation	investigation	NOUN
x633dz03j6s	6	11	were	be	AUX
x633dz03j6s	6	12	found	find	VERB
x633dz03j6s	6	13	to	to	PART
x633dz03j6s	6	14	have	have	VERB
x633dz03j6s	6	15	an	an	DET
x633dz03j6s	6	16	ionizing	ionize	VERB
x633dz03j6s	6	17	power	power	NOUN
x633dz03j6s	6	18	similar	similar	ADJ
x633dz03j6s	6	19	to	to	ADP
x633dz03j6s	6	20	that	that	PRON
x633dz03j6s	6	21	of	of	ADP
x633dz03j6s	6	22	cf3ch2oh	cf3ch2oh	PROPN
x633dz03j6s	6	23	,	,	PUNCT
x633dz03j6s	6	24	a	a	DET
x633dz03j6s	6	25	commonly	commonly	ADV
x633dz03j6s	6	26	used	use	VERB
x633dz03j6s	6	27	solvent	solvent	NOUN
x633dz03j6s	6	28	for	for	ADP
x633dz03j6s	6	29	carbocation	carbocation	ADJ
x633dz03j6s	6	30	formation	formation	NOUN
x633dz03j6s	6	31	.	.	PUNCT
x633dz03j6s	7	1	evidence	evidence	NOUN
x633dz03j6s	7	2	in	in	ADP
x633dz03j6s	7	3	support	support	NOUN
x633dz03j6s	7	4	of	of	ADP
x633dz03j6s	7	5	this	this	DET
x633dz03j6s	7	6	conclusion	conclusion	NOUN
x633dz03j6s	7	7	include	include	VERB
x633dz03j6s	7	8	the	the	DET
x633dz03j6s	7	9	observation	observation	NOUN
x633dz03j6s	7	10	of	of	ADP
x633dz03j6s	7	11	carbocationic	carbocationic	ADJ
x633dz03j6s	7	12	rearrangements	rearrangement	NOUN
x633dz03j6s	7	13	in	in	ADP
x633dz03j6s	7	14	a	a	DET
x633dz03j6s	7	15	variety	variety	NOUN
x633dz03j6s	7	16	of	of	ADP
x633dz03j6s	7	17	substrates	substrate	NOUN
x633dz03j6s	7	18	,	,	PUNCT
x633dz03j6s	7	19	a	a	DET
x633dz03j6s	7	20	hammett	hammett	NOUN
x633dz03j6s	7	21	-	-	PUNCT
x633dz03j6s	7	22	brown	brown	ADJ
x633dz03j6s	7	23	rho+	rho+	ADJ
x633dz03j6s	7	24	value	value	NOUN
x633dz03j6s	7	25	of	of	ADP
x633dz03j6s	7	26	ì¢	ì¢	NUM
x633dz03j6s	7	27	ââ'7.1	ââ'7.1	ADJ
x633dz03j6s	7	28	for	for	ADP
x633dz03j6s	7	29	the	the	DET
x633dz03j6s	7	30	solvolyses	solvolyse	NOUN
x633dz03j6s	7	31	of	of	ADP
x633dz03j6s	7	32	1	1	NUM
x633dz03j6s	7	33	-	-	PUNCT
x633dz03j6s	7	34	aryl-2,2,2	aryl-2,2,2	ADJ
x633dz03j6s	7	35	-	-	PUNCT
x633dz03j6s	7	36	trifluoroethyl	trifluoroethyl	NOUN
x633dz03j6s	7	37	triflates	triflate	NOUN
x633dz03j6s	7	38	,	,	PUNCT
x633dz03j6s	7	39	and	and	CCONJ
x633dz03j6s	7	40	the	the	DET
x633dz03j6s	7	41	facile	facile	NOUN
x633dz03j6s	7	42	solvolysis	solvolysis	NOUN
x633dz03j6s	7	43	of	of	ADP
x633dz03j6s	7	44	1	1	NUM
x633dz03j6s	7	45	-	-	PUNCT
x633dz03j6s	7	46	adamantyl	adamantyl	ADJ
x633dz03j6s	7	47	mesylate	mesylate	NOUN
x633dz03j6s	7	48	which	which	PRON
x633dz03j6s	7	49	necessarily	necessarily	ADV
x633dz03j6s	7	50	proceeds	proceed	VERB
x633dz03j6s	7	51	via	via	ADP
x633dz03j6s	7	52	a	a	DET
x633dz03j6s	7	53	carbocationic	carbocationic	ADJ
x633dz03j6s	7	54	intermediate	intermediate	NOUN
x633dz03j6s	7	55	.	.	PUNCT
x633dz03j6s	8	1	some	some	DET
x633dz03j6s	8	2	unusual	unusual	ADJ
x633dz03j6s	8	3	reactivity	reactivity	NOUN
x633dz03j6s	8	4	was	be	AUX
x633dz03j6s	8	5	seen	see	VERB
x633dz03j6s	8	6	in	in	ADP
x633dz03j6s	8	7	ionic	ionic	ADJ
x633dz03j6s	8	8	liquids	liquid	NOUN
x633dz03j6s	8	9	as	as	ADV
x633dz03j6s	8	10	well	well	ADV
x633dz03j6s	8	11	.	.	PUNCT
x633dz03j6s	9	1	for	for	ADP
x633dz03j6s	9	2	example	example	NOUN
x633dz03j6s	9	3	,	,	PUNCT
x633dz03j6s	9	4	it	it	PRON
x633dz03j6s	9	5	was	be	AUX
x633dz03j6s	9	6	found	find	VERB
x633dz03j6s	9	7	that	that	SCONJ
x633dz03j6s	9	8	small	small	ADJ
x633dz03j6s	9	9	concentrations	concentration	NOUN
x633dz03j6s	9	10	of	of	ADP
x633dz03j6s	9	11	water	water	NOUN
x633dz03j6s	9	12	in	in	ADP
x633dz03j6s	9	13	the	the	DET
x633dz03j6s	9	14	ionic	ionic	ADJ
x633dz03j6s	9	15	liquids	liquid	NOUN
x633dz03j6s	9	16	have	have	VERB
x633dz03j6s	9	17	a	a	DET
x633dz03j6s	9	18	significant	significant	ADJ
x633dz03j6s	9	19	impact	impact	NOUN
x633dz03j6s	9	20	on	on	ADP
x633dz03j6s	9	21	the	the	DET
x633dz03j6s	9	22	rates	rate	NOUN
x633dz03j6s	9	23	of	of	ADP
x633dz03j6s	9	24	solvolyses	solvolyse	NOUN
x633dz03j6s	9	25	of	of	ADP
x633dz03j6s	9	26	mesylates	mesylate	NOUN
x633dz03j6s	9	27	.	.	PUNCT
x633dz03j6s	10	1	the	the	DET
x633dz03j6s	10	2	effect	effect	NOUN
x633dz03j6s	10	3	of	of	ADP
x633dz03j6s	10	4	water	water	NOUN
x633dz03j6s	10	5	on	on	ADP
x633dz03j6s	10	6	triflate	triflate	NOUN
x633dz03j6s	10	7	solvolyses	solvolyse	NOUN
x633dz03j6s	10	8	however	however	ADV
x633dz03j6s	10	9	,	,	PUNCT
x633dz03j6s	10	10	was	be	AUX
x633dz03j6s	10	11	negligible	negligible	ADJ
x633dz03j6s	10	12	.	.	PUNCT
x633dz03j6s	11	1	additionally	additionally	ADV
x633dz03j6s	11	2	,	,	PUNCT
x633dz03j6s	11	3	a	a	DET
x633dz03j6s	11	4	novel	novel	NOUN
x633dz03j6s	11	5	oxidation	oxidation	NOUN
x633dz03j6s	11	6	process	process	NOUN
x633dz03j6s	11	7	of	of	ADP
x633dz03j6s	11	8	triflates	triflate	NOUN
x633dz03j6s	11	9	involving	involve	VERB
x633dz03j6s	11	10	loss	loss	NOUN
x633dz03j6s	11	11	of	of	ADP
x633dz03j6s	11	12	sulfinate	sulfinate	NOUN
x633dz03j6s	11	13	was	be	AUX
x633dz03j6s	11	14	found	find	VERB
x633dz03j6s	11	15	to	to	PART
x633dz03j6s	11	16	occur	occur	VERB
x633dz03j6s	11	17	in	in	ADP
x633dz03j6s	11	18	certain	certain	ADJ
x633dz03j6s	11	19	ionic	ionic	ADJ
x633dz03j6s	11	20	liquids	liquid	NOUN
x633dz03j6s	11	21	.	.	PUNCT
x633dz03j6s	12	1	an	an	DET
x633dz03j6s	12	2	investigation	investigation	NOUN
x633dz03j6s	12	3	of	of	ADP
x633dz03j6s	12	4	the	the	DET
x633dz03j6s	12	5	stabilizing	stabilize	VERB
x633dz03j6s	12	6	effect	effect	NOUN
x633dz03j6s	12	7	of	of	ADP
x633dz03j6s	12	8	beta	beta	NOUN
x633dz03j6s	12	9	-	-	PUNCT
x633dz03j6s	12	10	silyl	silyl	NOUN
x633dz03j6s	12	11	groups	group	NOUN
x633dz03j6s	12	12	on	on	ADP
x633dz03j6s	12	13	cyclopropyl	cyclopropyl	PROPN
x633dz03j6s	12	14	carbocations	carbocation	NOUN
x633dz03j6s	12	15	was	be	AUX
x633dz03j6s	12	16	also	also	ADV
x633dz03j6s	12	17	undertaken	undertake	VERB
x633dz03j6s	12	18	.	.	PUNCT
x633dz03j6s	13	1	the	the	DET
x633dz03j6s	13	2	normally	normally	ADV
x633dz03j6s	13	3	large	large	ADJ
x633dz03j6s	13	4	effect	effect	NOUN
x633dz03j6s	13	5	of	of	ADP
x633dz03j6s	13	6	a	a	DET
x633dz03j6s	13	7	beta	beta	NOUN
x633dz03j6s	13	8	-	-	PUNCT
x633dz03j6s	13	9	silyl	silyl	NOUN
x633dz03j6s	13	10	group	group	NOUN
x633dz03j6s	13	11	(	(	PUNCT
x633dz03j6s	13	12	which	which	PRON
x633dz03j6s	13	13	can	can	AUX
x633dz03j6s	13	14	cause	cause	VERB
x633dz03j6s	13	15	solvolysis	solvolysis	NOUN
x633dz03j6s	13	16	rate	rate	NOUN
x633dz03j6s	13	17	enhancements	enhancement	NOUN
x633dz03j6s	13	18	of	of	ADP
x633dz03j6s	13	19	up	up	ADP
x633dz03j6s	13	20	to	to	PART
x633dz03j6s	13	21	1012	1012	NUM
x633dz03j6s	13	22	)	)	PUNCT
x633dz03j6s	13	23	was	be	AUX
x633dz03j6s	13	24	found	find	VERB
x633dz03j6s	13	25	to	to	PART
x633dz03j6s	13	26	be	be	AUX
x633dz03j6s	13	27	greatly	greatly	ADV
x633dz03j6s	13	28	repressed	repress	VERB
x633dz03j6s	13	29	in	in	ADP
x633dz03j6s	13	30	cyclopropyl	cyclopropyl	PROPN
x633dz03j6s	13	31	systems	system	NOUN
x633dz03j6s	13	32	.	.	PUNCT
x633dz03j6s	14	1	computational	computational	ADJ
x633dz03j6s	14	2	studies	study	NOUN
x633dz03j6s	14	3	agreed	agree	VERB
x633dz03j6s	14	4	with	with	ADP
x633dz03j6s	14	5	this	this	DET
x633dz03j6s	14	6	conclusion	conclusion	NOUN
x633dz03j6s	14	7	.	.	PUNCT
x633dz03j6s	15	1	the	the	DET
x633dz03j6s	15	2	intermediate	intermediate	ADJ
x633dz03j6s	15	3	silyl	silyl	NOUN
x633dz03j6s	15	4	-	-	PUNCT
x633dz03j6s	15	5	substituted	substitute	VERB
x633dz03j6s	15	6	cyclopropyl	cyclopropyl	PROPN
x633dz03j6s	15	7	cations	cation	NOUN
x633dz03j6s	15	8	instead	instead	ADV
x633dz03j6s	15	9	tended	tend	VERB
x633dz03j6s	15	10	to	to	PART
x633dz03j6s	15	11	undergo	undergo	VERB
x633dz03j6s	15	12	ring	ring	NOUN
x633dz03j6s	15	13	opening	opening	NOUN
x633dz03j6s	15	14	since	since	SCONJ
x633dz03j6s	15	15	silyl	silyl	PROPN
x633dz03j6s	15	16	stabilization	stabilization	PROPN
x633dz03j6s	15	17	is	be	AUX
x633dz03j6s	15	18	reduced	reduce	VERB
x633dz03j6s	15	19	.	.	PUNCT
x633dz03j6s	16	1	a	a	DET
x633dz03j6s	16	2	similar	similar	ADJ
x633dz03j6s	16	3	study	study	NOUN
x633dz03j6s	16	4	was	be	AUX
x633dz03j6s	16	5	undertaken	undertake	VERB
x633dz03j6s	16	6	involving	involve	VERB
x633dz03j6s	16	7	cyclobutyl	cyclobutyl	ADJ
x633dz03j6s	16	8	carbocations	carbocation	NOUN
x633dz03j6s	16	9	.	.	PUNCT
x633dz03j6s	17	1	incorporation	incorporation	NOUN
x633dz03j6s	17	2	of	of	ADP
x633dz03j6s	17	3	a	a	DET
x633dz03j6s	17	4	beta	beta	NOUN
x633dz03j6s	17	5	-	-	PUNCT
x633dz03j6s	17	6	silyl	silyl	NOUN
x633dz03j6s	17	7	group	group	NOUN
x633dz03j6s	17	8	into	into	ADP
x633dz03j6s	17	9	cyclobutyl	cyclobutyl	ADJ
x633dz03j6s	17	10	carbocations	carbocation	NOUN
x633dz03j6s	17	11	led	lead	VERB
x633dz03j6s	17	12	again	again	ADV
x633dz03j6s	17	13	to	to	ADP
x633dz03j6s	17	14	a	a	DET
x633dz03j6s	17	15	smaller	small	ADJ
x633dz03j6s	17	16	than	than	ADP
x633dz03j6s	17	17	expected	expect	VERB
x633dz03j6s	17	18	b	b	X
x633dz03j6s	17	19	-	-	PUNCT
x633dz03j6s	17	20	silyl	silyl	NOUN
x633dz03j6s	17	21	stabilization	stabilization	NOUN
x633dz03j6s	17	22	.	.	PUNCT
x633dz03j6s	18	1	in	in	ADP
x633dz03j6s	18	2	fact	fact	NOUN
x633dz03j6s	18	3	,	,	PUNCT
x633dz03j6s	18	4	the	the	DET
x633dz03j6s	18	5	effect	effect	NOUN
x633dz03j6s	18	6	was	be	AUX
x633dz03j6s	18	7	successfully	successfully	ADV
x633dz03j6s	18	8	quashed	quash	VERB
x633dz03j6s	18	9	in	in	ADP
x633dz03j6s	18	10	a	a	DET
x633dz03j6s	18	11	beta	beta	NOUN
x633dz03j6s	18	12	-	-	PUNCT
x633dz03j6s	18	13	silyl	silyl	NOUN
x633dz03j6s	18	14	benzocyclobutenyl	benzocyclobutenyl	NOUN
x633dz03j6s	18	15	carbocation	carbocation	NOUN
x633dz03j6s	18	16	in	in	ADP
x633dz03j6s	18	17	which	which	PRON
x633dz03j6s	18	18	beta	beta	NOUN
x633dz03j6s	18	19	-	-	PUNCT
x633dz03j6s	18	20	silyl	silyl	NOUN
x633dz03j6s	18	21	stabilization	stabilization	NOUN
x633dz03j6s	18	22	would	would	AUX
x633dz03j6s	18	23	have	have	AUX
x633dz03j6s	18	24	led	lead	VERB
x633dz03j6s	18	25	to	to	ADP
x633dz03j6s	18	26	antiaromatic	antiaromatic	ADJ
x633dz03j6s	18	27	character	character	NOUN
x633dz03j6s	18	28	in	in	ADP
x633dz03j6s	18	29	the	the	DET
x633dz03j6s	18	30	carbocation	carbocation	NOUN
x633dz03j6s	18	31	.	.	PUNCT
x633dz03j6s	19	1	the	the	DET
x633dz03j6s	19	2	gamma	gamma	PROPN
x633dz03j6s	19	3	-	-	PUNCT
x633dz03j6s	19	4	silyl	silyl	PROPN
x633dz03j6s	19	5	effect	effect	NOUN
x633dz03j6s	19	6	was	be	AUX
x633dz03j6s	19	7	also	also	ADV
x633dz03j6s	19	8	investigated	investigate	VERB
x633dz03j6s	19	9	in	in	ADP
x633dz03j6s	19	10	cyclobutyl	cyclobutyl	PROPN
x633dz03j6s	19	11	systems	system	NOUN
x633dz03j6s	19	12	.	.	PUNCT
x633dz03j6s	20	1	experimental	experimental	ADJ
x633dz03j6s	20	2	and	and	CCONJ
x633dz03j6s	20	3	computational	computational	ADJ
x633dz03j6s	20	4	studies	study	NOUN
x633dz03j6s	20	5	showed	show	VERB
x633dz03j6s	20	6	that	that	SCONJ
x633dz03j6s	20	7	gamma	gamma	PROPN
x633dz03j6s	20	8	-	-	PUNCT
x633dz03j6s	20	9	silyl	silyl	PROPN
x633dz03j6s	20	10	stabilization	stabilization	NOUN
x633dz03j6s	20	11	can	can	AUX
x633dz03j6s	20	12	occur	occur	VERB
x633dz03j6s	20	13	via	via	ADP
x633dz03j6s	20	14	two	two	NUM
x633dz03j6s	20	15	distinct	distinct	ADJ
x633dz03j6s	20	16	modes	mode	NOUN
x633dz03j6s	20	17	.	.	PUNCT
x633dz03j6s	21	1	either	either	CCONJ
x633dz03j6s	21	2	the	the	DET
x633dz03j6s	21	3	front	front	NOUN
x633dz03j6s	21	4	,	,	PUNCT
x633dz03j6s	21	5	or	or	CCONJ
x633dz03j6s	21	6	the	the	DET
x633dz03j6s	21	7	rear	rear	ADJ
x633dz03j6s	21	8	lobe	lobe	NOUN
x633dz03j6s	21	9	of	of	ADP
x633dz03j6s	21	10	the	the	DET
x633dz03j6s	21	11	gamma	gamma	PROPN
x633dz03j6s	21	12	-	-	PUNCT
x633dz03j6s	21	13	silyl	silyl	PROPN
x633dz03j6s	21	14	group	group	NOUN
x633dz03j6s	21	15	can	can	AUX
x633dz03j6s	21	16	donate	donate	VERB
x633dz03j6s	21	17	electron	electron	NOUN
x633dz03j6s	21	18	density	density	NOUN
x633dz03j6s	21	19	into	into	ADP
x633dz03j6s	21	20	the	the	DET
x633dz03j6s	21	21	empty	empty	ADJ
x633dz03j6s	21	22	p	p	NOUN
x633dz03j6s	21	23	-	-	PUNCT
x633dz03j6s	21	24	orbital	orbital	NOUN
x633dz03j6s	21	25	of	of	ADP
x633dz03j6s	21	26	the	the	DET
x633dz03j6s	21	27	carbocation	carbocation	NOUN
x633dz03j6s	21	28	.	.	PUNCT
x633dz03j6s	22	1	this	this	DET
x633dz03j6s	22	2	effect	effect	NOUN
x633dz03j6s	22	3	was	be	AUX
x633dz03j6s	22	4	also	also	ADV
x633dz03j6s	22	5	found	find	VERB
x633dz03j6s	22	6	to	to	PART
x633dz03j6s	22	7	be	be	AUX
x633dz03j6s	22	8	much	much	ADV
x633dz03j6s	22	9	larger	large	ADJ
x633dz03j6s	22	10	than	than	SCONJ
x633dz03j6s	22	11	previously	previously	ADV
x633dz03j6s	22	12	recorded	record	VERB
x633dz03j6s	22	13	.	.	PUNCT