id sid tid token lemma pos x346d221071 1 1 this this DET x346d221071 1 2 dissertation dissertation NOUN x346d221071 1 3 focuses focus VERB x346d221071 1 4 on on ADP x346d221071 1 5 exploring explore VERB x346d221071 1 6 the the DET x346d221071 1 7 fundamental fundamental ADJ x346d221071 1 8 chemistry chemistry NOUN x346d221071 1 9 of of ADP x346d221071 1 10 solid solid ADJ x346d221071 1 11 - - PUNCT x346d221071 1 12 state state NOUN x346d221071 1 13 uranyl uranyl NOUN x346d221071 1 14 and and CCONJ x346d221071 1 15 neptunyl neptunyl ADJ x346d221071 1 16 coordination coordination NOUN x346d221071 1 17 complexes complex NOUN x346d221071 1 18 to to PART x346d221071 1 19 better well ADV x346d221071 1 20 understand understand VERB x346d221071 1 21 actinyl actinyl PROPN x346d221071 1 22 crystal crystal PROPN x346d221071 1 23 chemistry chemistry PROPN x346d221071 1 24 and and CCONJ x346d221071 1 25 probe probe VERB x346d221071 1 26 the the DET x346d221071 1 27 nature nature NOUN x346d221071 1 28 of of ADP x346d221071 1 29 structure structure NOUN x346d221071 1 30 directing direct VERB x346d221071 1 31 factors factor NOUN x346d221071 1 32 leading lead VERB x346d221071 1 33 to to ADP x346d221071 1 34 their their PRON x346d221071 1 35 formation formation NOUN x346d221071 1 36 . . PUNCT x346d221071 2 1 the the DET x346d221071 2 2 goal goal NOUN x346d221071 2 3 of of ADP x346d221071 2 4 this this DET x346d221071 2 5 research research NOUN x346d221071 2 6 is be AUX x346d221071 2 7 to to PART x346d221071 2 8 design design VERB x346d221071 2 9 and and CCONJ x346d221071 2 10 synthesize synthesize VERB x346d221071 2 11 coordination coordination NOUN x346d221071 2 12 complexes complex NOUN x346d221071 2 13 that that PRON x346d221071 2 14 demonstrate demonstrate VERB x346d221071 2 15 rich rich ADJ x346d221071 2 16 chemical chemical NOUN x346d221071 2 17 and and CCONJ x346d221071 2 18 structural structural ADJ x346d221071 2 19 diversity diversity NOUN x346d221071 2 20 of of ADP x346d221071 2 21 the the DET x346d221071 2 22 5f 5f NUM x346d221071 2 23 - - PUNCT x346d221071 2 24 elements element NOUN x346d221071 2 25 at at ADP x346d221071 2 26 a a DET x346d221071 2 27 nexus nexus NOUN x346d221071 2 28 with with ADP x346d221071 2 29 ionic ionic ADJ x346d221071 2 30 liquids liquid NOUN x346d221071 2 31 , , PUNCT x346d221071 2 32 protonated protonate VERB x346d221071 2 33 amines amine NOUN x346d221071 2 34 , , PUNCT x346d221071 2 35 and and CCONJ x346d221071 2 36 a a DET x346d221071 2 37 variety variety NOUN x346d221071 2 38 of of ADP x346d221071 2 39 n- n- X x346d221071 2 40 , , PUNCT x346d221071 2 41 oand oand PROPN x346d221071 2 42 h2-(n h2-(n SPACE x346d221071 2 43 - - PUNCT x346d221071 2 44 o o NOUN x346d221071 2 45 ) ) PUNCT x346d221071 2 46 donor donor NOUN x346d221071 2 47 ligands ligand NOUN x346d221071 2 48 . . PUNCT x346d221071 3 1 the the DET x346d221071 3 2 principle principle ADJ x346d221071 3 3 theme theme NOUN x346d221071 3 4 explores explore VERB x346d221071 3 5 the the DET x346d221071 3 6 use use NOUN x346d221071 3 7 of of ADP x346d221071 3 8 functionalized functionalize VERB x346d221071 3 9 ionic ionic ADJ x346d221071 3 10 liquids liquid NOUN x346d221071 3 11 as as ADP x346d221071 3 12 unconventional unconventional ADJ x346d221071 3 13 solvents solvent NOUN x346d221071 3 14 that that PRON x346d221071 3 15 may may AUX x346d221071 3 16 act act VERB x346d221071 3 17 as as ADP x346d221071 3 18 a a DET x346d221071 3 19 ligand ligand NOUN x346d221071 3 20 , , PUNCT x346d221071 3 21 charge charge NOUN x346d221071 3 22 balance balance NOUN x346d221071 3 23 specie specie NOUN x346d221071 3 24 , , PUNCT x346d221071 3 25 or or CCONJ x346d221071 3 26 as as ADP x346d221071 3 27 an an DET x346d221071 3 28 aqueous aqueous NOUN x346d221071 3 29 - - PUNCT x346d221071 3 30 less less ADJ x346d221071 3 31 reaction reaction NOUN x346d221071 3 32 medium medium NOUN x346d221071 3 33 . . PUNCT x346d221071 4 1 several several ADJ x346d221071 4 2 classes class NOUN x346d221071 4 3 of of ADP x346d221071 4 4 ionic ionic ADJ x346d221071 4 5 liquids liquid NOUN x346d221071 4 6 were be AUX x346d221071 4 7 employed employ VERB x346d221071 4 8 to to PART x346d221071 4 9 develop develop VERB x346d221071 4 10 coordination coordination NOUN x346d221071 4 11 compounds compound NOUN x346d221071 4 12 and and CCONJ x346d221071 4 13 hybrid hybrid ADJ x346d221071 4 14 materials material NOUN x346d221071 4 15 that that PRON x346d221071 4 16 expand expand VERB x346d221071 4 17 on on ADP x346d221071 4 18 the the DET x346d221071 4 19 topological topological ADJ x346d221071 4 20 diversity diversity NOUN x346d221071 4 21 of of ADP x346d221071 4 22 solid solid ADJ x346d221071 4 23 - - PUNCT x346d221071 4 24 state state NOUN x346d221071 4 25 uranyl uranyl NOUN x346d221071 4 26 structures structure NOUN x346d221071 4 27 and and CCONJ x346d221071 4 28 systematically systematically ADV x346d221071 4 29 investigate investigate VERB x346d221071 4 30 , , PUNCT x346d221071 4 31 through through ADP x346d221071 4 32 judicious judicious ADJ x346d221071 4 33 selection selection NOUN x346d221071 4 34 of of ADP x346d221071 4 35 incorporated incorporated ADJ x346d221071 4 36 moieties moiety NOUN x346d221071 4 37 , , PUNCT x346d221071 4 38 the the DET x346d221071 4 39 importance importance NOUN x346d221071 4 40 and and CCONJ x346d221071 4 41 role role NOUN x346d221071 4 42 of of ADP x346d221071 4 43 various various ADJ x346d221071 4 44 structure structure NOUN x346d221071 4 45 directing direct VERB x346d221071 4 46 factors factor NOUN x346d221071 4 47 ( ( PUNCT x346d221071 4 48 i.e. i.e. X x346d221071 4 49 steric steric ADJ x346d221071 4 50 affects affect VERB x346d221071 4 51 , , PUNCT x346d221071 4 52 hydrogen hydrogen NOUN x346d221071 4 53 bonding bonding NOUN x346d221071 4 54 , , PUNCT x346d221071 4 55 ph ph NOUN x346d221071 4 56 , , PUNCT x346d221071 4 57 temperature temperature NOUN x346d221071 4 58 , , PUNCT x346d221071 4 59 etc.)a etc.)a NOUN x346d221071 4 60 second second ADJ x346d221071 4 61 area area NOUN x346d221071 4 62 of of ADP x346d221071 4 63 research research NOUN x346d221071 4 64 investigates investigate VERB x346d221071 4 65 transuranic transuranic ADJ x346d221071 4 66 cyanometallates cyanometallate NOUN x346d221071 4 67 , , PUNCT x346d221071 4 68 and and CCONJ x346d221071 4 69 demonstrates demonstrate VERB x346d221071 4 70 marked marked ADJ x346d221071 4 71 differences difference NOUN x346d221071 4 72 between between ADP x346d221071 4 73 pentavalent pentavalent ADJ x346d221071 4 74 neptunium neptunium NOUN x346d221071 4 75 and and CCONJ x346d221071 4 76 hexavalent hexavalent NOUN x346d221071 4 77 uranium uranium NOUN x346d221071 4 78 chemistry chemistry NOUN x346d221071 4 79 . . PUNCT x346d221071 5 1 notably notably ADV x346d221071 5 2 , , PUNCT x346d221071 5 3 the the DET x346d221071 5 4 work work NOUN x346d221071 5 5 demonstrates demonstrate VERB x346d221071 5 6 important important ADJ x346d221071 5 7 differences difference NOUN x346d221071 5 8 relating relate VERB x346d221071 5 9 to to ADP x346d221071 5 10 redox redox ADJ x346d221071 5 11 chemistry chemistry NOUN x346d221071 5 12 and and CCONJ x346d221071 5 13 so so ADV x346d221071 5 14 - - PUNCT x346d221071 5 15 called call VERB x346d221071 5 16 cation cation NOUN x346d221071 5 17 - - PUNCT x346d221071 5 18 cation cation NOUN x346d221071 5 19 interactions interaction NOUN x346d221071 5 20 prevalent prevalent ADJ x346d221071 5 21 in in ADP x346d221071 5 22 np(v np(v PROPN x346d221071 5 23 ) ) PUNCT x346d221071 5 24 coordination coordination NOUN x346d221071 5 25 chemistry chemistry NOUN x346d221071 5 26 . . PUNCT x346d221071 6 1 furthermore furthermore ADV x346d221071 6 2 , , PUNCT x346d221071 6 3 the the DET x346d221071 6 4 work work NOUN x346d221071 6 5 also also ADV x346d221071 6 6 demonstrates demonstrate VERB x346d221071 6 7 a a DET x346d221071 6 8 novel novel ADJ x346d221071 6 9 system system NOUN x346d221071 6 10 for for ADP x346d221071 6 11 exploring explore VERB x346d221071 6 12 mixed mixed ADJ x346d221071 6 13 - - PUNCT x346d221071 6 14 valent valent ADJ x346d221071 6 15 tetracyanoplatinate tetracyanoplatinate ADJ x346d221071 6 16 complexes complex NOUN x346d221071 6 17 , , PUNCT x346d221071 6 18 with with SCONJ x346d221071 6 19 the the DET x346d221071 6 20 potential potential NOUN x346d221071 6 21 for for ADP x346d221071 6 22 chemical chemical ADJ x346d221071 6 23 fine fine ADJ x346d221071 6 24 tuning tuning NOUN x346d221071 6 25 of of ADP x346d221071 6 26 their their PRON x346d221071 6 27 magnetic magnetic ADJ x346d221071 6 28 and and CCONJ x346d221071 6 29 electronic electronic ADJ x346d221071 6 30 properties.a properties.a NOUN x346d221071 6 31 third third ADJ x346d221071 6 32 area area NOUN x346d221071 6 33 of of ADP x346d221071 6 34 research research NOUN x346d221071 6 35 explores explore VERB x346d221071 6 36 the the DET x346d221071 6 37 importance importance NOUN x346d221071 6 38 of of ADP x346d221071 6 39 structural structural ADJ x346d221071 6 40 unit unit NOUN x346d221071 6 41 charge charge NOUN x346d221071 6 42 density density NOUN x346d221071 6 43 matching matching NOUN x346d221071 6 44 and and CCONJ x346d221071 6 45 hydrogen hydrogen NOUN x346d221071 6 46 bonding bonding NOUN x346d221071 6 47 between between ADP x346d221071 6 48 an an DET x346d221071 6 49 interlayer interlayer NOUN x346d221071 6 50 complex complex NOUN x346d221071 6 51 and and CCONJ x346d221071 6 52 anionic anionic ADJ x346d221071 6 53 structural structural ADJ x346d221071 6 54 unit unit NOUN x346d221071 6 55 in in ADP x346d221071 6 56 the the DET x346d221071 6 57 formation formation NOUN x346d221071 6 58 of of ADP x346d221071 6 59 two two NUM x346d221071 6 60 - - PUNCT x346d221071 6 61 dimensional dimensional ADJ x346d221071 6 62 uranyl uranyl ADJ x346d221071 6 63 sulfate sulfate NOUN x346d221071 6 64 compounds compound NOUN x346d221071 6 65 . . PUNCT x346d221071 7 1 here here ADV x346d221071 7 2 , , PUNCT x346d221071 7 3 a a DET x346d221071 7 4 literature literature NOUN x346d221071 7 5 review review NOUN x346d221071 7 6 and and CCONJ x346d221071 7 7 analysis analysis NOUN x346d221071 7 8 of of ADP x346d221071 7 9 structural structural ADJ x346d221071 7 10 data datum NOUN x346d221071 7 11 is be AUX x346d221071 7 12 used use VERB x346d221071 7 13 to to PART x346d221071 7 14 elucidate elucidate VERB x346d221071 7 15 aspects aspect NOUN x346d221071 7 16 of of ADP x346d221071 7 17 structure structure NOUN x346d221071 7 18 directing direct VERB x346d221071 7 19 properties property NOUN x346d221071 7 20 to to PART x346d221071 7 21 better well ADV x346d221071 7 22 inform inform VERB x346d221071 7 23 on on ADP x346d221071 7 24 and and CCONJ x346d221071 7 25 provide provide VERB x346d221071 7 26 clarity clarity NOUN x346d221071 7 27 in in ADP x346d221071 7 28 their their PRON x346d221071 7 29 descriptions description NOUN x346d221071 7 30 within within ADP x346d221071 7 31 the the DET x346d221071 7 32 literature literature NOUN x346d221071 7 33 . . PUNCT x346d221071 8 1 this this DET x346d221071 8 2 work work NOUN x346d221071 8 3 provides provide VERB x346d221071 8 4 a a DET x346d221071 8 5 qualitative qualitative ADJ x346d221071 8 6 framework framework NOUN x346d221071 8 7 for for ADP x346d221071 8 8 understanding understand VERB x346d221071 8 9 orientational orientational ADJ x346d221071 8 10 geometric geometric ADJ x346d221071 8 11 isomerism isomerism NOUN x346d221071 8 12 , , PUNCT x346d221071 8 13 interlayer interlayer NOUN x346d221071 8 14 stacking stack VERB x346d221071 8 15 interactions interaction NOUN x346d221071 8 16 and and CCONJ x346d221071 8 17 interlayer interlayer NOUN x346d221071 8 18 distance distance NOUN x346d221071 8 19 dependence dependence NOUN x346d221071 8 20 for for ADP x346d221071 8 21 two two NUM x346d221071 8 22 - - PUNCT x346d221071 8 23 dimensional dimensional ADJ x346d221071 8 24 uranyl uranyl NOUN x346d221071 8 25 sulfate sulfate NOUN x346d221071 8 26 compounds compound NOUN x346d221071 8 27 incorporating incorporate VERB x346d221071 8 28 protonated protonate VERB x346d221071 8 29 cyclic cyclic NOUN x346d221071 8 30 and and CCONJ x346d221071 8 31 alkylamines alkylamine NOUN x346d221071 8 32 via via ADP x346d221071 8 33 templating templating NOUN x346d221071 8 34 effects effect NOUN x346d221071 8 35 . . PUNCT