id sid tid token lemma pos x059c537159 1 1 this this DET x059c537159 1 2 thesis thesis NOUN x059c537159 1 3 examines examine VERB x059c537159 1 4 the the DET x059c537159 1 5 formation formation NOUN x059c537159 1 6 of of ADP x059c537159 1 7 multicomponent multicomponent NOUN x059c537159 1 8 self self NOUN x059c537159 1 9 - - PUNCT x059c537159 1 10 assembled assemble VERB x059c537159 1 11 monolayers monolayer NOUN x059c537159 1 12 ( ( PUNCT x059c537159 1 13 sams sams PROPN x059c537159 1 14 ) ) PUNCT x059c537159 1 15 on on ADP x059c537159 1 16 the the DET x059c537159 1 17 au(111 au(111 SPACE x059c537159 1 18 ) ) PUNCT x059c537159 1 19 surface surface NOUN x059c537159 1 20 using use VERB x059c537159 1 21 scanning scan VERB x059c537159 1 22 tunneling tunneling NOUN x059c537159 1 23 microscopy microscopy NOUN x059c537159 1 24 . . PUNCT x059c537159 2 1 two two NUM x059c537159 2 2 methods method NOUN x059c537159 2 3 , , PUNCT x059c537159 2 4 sequential sequential ADJ x059c537159 2 5 adsorption adsorption NOUN x059c537159 2 6 and and CCONJ x059c537159 2 7 coadsorption coadsorption NOUN x059c537159 2 8 , , PUNCT x059c537159 2 9 are be AUX x059c537159 2 10 used use VERB x059c537159 2 11 to to PART x059c537159 2 12 create create VERB x059c537159 2 13 these these DET x059c537159 2 14 mixed mixed ADJ x059c537159 2 15 sams sam NOUN x059c537159 2 16 . . PUNCT x059c537159 3 1 in in ADP x059c537159 3 2 the the DET x059c537159 3 3 sequential sequential ADJ x059c537159 3 4 adsorption adsorption NOUN x059c537159 3 5 experiments experiment NOUN x059c537159 3 6 , , PUNCT x059c537159 3 7 a a DET x059c537159 3 8 clean clean ADJ x059c537159 3 9 au(111)-on au(111)-on NOUN x059c537159 3 10 - - PUNCT x059c537159 3 11 mica mica NOUN x059c537159 3 12 substrate substrate NOUN x059c537159 3 13 is be AUX x059c537159 3 14 exposed expose VERB x059c537159 3 15 to to ADP x059c537159 3 16 the the DET x059c537159 3 17 first first ADJ x059c537159 3 18 molecular molecular ADJ x059c537159 3 19 species specie NOUN x059c537159 3 20 and and CCONJ x059c537159 3 21 then then ADV x059c537159 3 22 this this DET x059c537159 3 23 adsorbate adsorbate NOUN x059c537159 3 24 - - PUNCT x059c537159 3 25 covered cover VERB x059c537159 3 26 sample sample NOUN x059c537159 3 27 is be AUX x059c537159 3 28 exposed expose VERB x059c537159 3 29 to to ADP x059c537159 3 30 the the DET x059c537159 3 31 second second ADJ x059c537159 3 32 molecular molecular ADJ x059c537159 3 33 species specie NOUN x059c537159 3 34 . . PUNCT x059c537159 4 1 alternately alternately ADV x059c537159 4 2 , , PUNCT x059c537159 4 3 in in ADP x059c537159 4 4 the the DET x059c537159 4 5 coadsorption coadsorption NOUN x059c537159 4 6 experiments experiment NOUN x059c537159 4 7 , , PUNCT x059c537159 4 8 a a DET x059c537159 4 9 gold gold ADJ x059c537159 4 10 surface surface NOUN x059c537159 4 11 is be AUX x059c537159 4 12 exposed expose VERB x059c537159 4 13 to to ADP x059c537159 4 14 both both DET x059c537159 4 15 adsorbates adsorbate NOUN x059c537159 4 16 simultaneously simultaneously ADV x059c537159 4 17 . . PUNCT x059c537159 5 1 exposing expose VERB x059c537159 5 2 a a DET x059c537159 5 3 coroneneor coroneneor NOUN x059c537159 5 4 dithiocarbamate dithiocarbamate NOUN x059c537159 5 5 - - PUNCT x059c537159 5 6 covered cover VERB x059c537159 5 7 surface surface NOUN x059c537159 5 8 to to ADP x059c537159 5 9 excess excess ADJ x059c537159 5 10 thiol thiol NOUN x059c537159 5 11 in in ADP x059c537159 5 12 the the DET x059c537159 5 13 vapor vapor NOUN x059c537159 5 14 phase phase NOUN x059c537159 5 15 results result VERB x059c537159 5 16 in in ADP x059c537159 5 17 a a DET x059c537159 5 18 drastic drastic ADJ x059c537159 5 19 restructuring restructuring NOUN x059c537159 5 20 of of ADP x059c537159 5 21 the the DET x059c537159 5 22 initial initial ADJ x059c537159 5 23 surface surface NOUN x059c537159 5 24 . . PUNCT x059c537159 6 1 this this PRON x059c537159 6 2 is be AUX x059c537159 6 3 primarily primarily ADV x059c537159 6 4 driven drive VERB x059c537159 6 5 by by ADP x059c537159 6 6 the the DET x059c537159 6 7 kinetics kinetic NOUN x059c537159 6 8 of of ADP x059c537159 6 9 the the DET x059c537159 6 10 octanethiol octanethiol PROPN x059c537159 6 11 monolayer monolayer NOUN x059c537159 6 12 formation formation NOUN x059c537159 6 13 process process NOUN x059c537159 6 14 , , PUNCT x059c537159 6 15 but but CCONJ x059c537159 6 16 the the DET x059c537159 6 17 extent extent NOUN x059c537159 6 18 to to PART x059c537159 6 19 which which PRON x059c537159 6 20 this this PRON x059c537159 6 21 happens happen VERB x059c537159 6 22 is be AUX x059c537159 6 23 dependent dependent ADJ x059c537159 6 24 on on ADP x059c537159 6 25 the the DET x059c537159 6 26 molecule molecule NOUN x059c537159 6 27 - - PUNCT x059c537159 6 28 molecule molecule NOUN x059c537159 6 29 and and CCONJ x059c537159 6 30 molecule molecule NOUN x059c537159 6 31 - - PUNCT x059c537159 6 32 surface surface NOUN x059c537159 6 33 interactions interaction NOUN x059c537159 6 34 of of ADP x059c537159 6 35 the the DET x059c537159 6 36 adsorbate adsorbate NOUN x059c537159 6 37 due due ADP x059c537159 6 38 to to ADP x059c537159 6 39 the the DET x059c537159 6 40 initial initial ADJ x059c537159 6 41 coverage coverage NOUN x059c537159 6 42 and and CCONJ x059c537159 6 43 order order NOUN x059c537159 6 44 of of ADP x059c537159 6 45 the the DET x059c537159 6 46 monolayer monolayer NOUN x059c537159 6 47 . . PUNCT x059c537159 7 1 an an DET x059c537159 7 2 octanethiolate octanethiolate ADJ x059c537159 7 3 monolayer monolayer NOUN x059c537159 7 4 is be AUX x059c537159 7 5 also also ADV x059c537159 7 6 substantially substantially ADV x059c537159 7 7 modified modify VERB x059c537159 7 8 when when SCONJ x059c537159 7 9 immersed immerse VERB x059c537159 7 10 in in ADP x059c537159 7 11 a a DET x059c537159 7 12 solution solution NOUN x059c537159 7 13 containing contain VERB x059c537159 7 14 dithiocarbamate dithiocarbamate NOUN x059c537159 7 15 ( ( PUNCT x059c537159 7 16 dtc dtc PROPN x059c537159 7 17 ) ) PUNCT x059c537159 7 18 . . PUNCT x059c537159 8 1 defects defect NOUN x059c537159 8 2 in in ADP x059c537159 8 3 the the DET x059c537159 8 4 octanethiol octanethiol ADJ x059c537159 8 5 monolayer monolayer NOUN x059c537159 8 6 are be AUX x059c537159 8 7 prime prime ADJ x059c537159 8 8 sites site NOUN x059c537159 8 9 for for ADP x059c537159 8 10 molecular molecular ADJ x059c537159 8 11 exchange exchange NOUN x059c537159 8 12 . . PUNCT x059c537159 9 1 a a DET x059c537159 9 2 surplus surplus NOUN x059c537159 9 3 of of ADP x059c537159 9 4 dtc dtc NOUN x059c537159 9 5 in in ADP x059c537159 9 6 the the DET x059c537159 9 7 solution solution NOUN x059c537159 9 8 drives drive VERB x059c537159 9 9 substitution substitution NOUN x059c537159 9 10 that that PRON x059c537159 9 11 can can AUX x059c537159 9 12 lead lead VERB x059c537159 9 13 to to ADP x059c537159 9 14 the the DET x059c537159 9 15 complete complete ADJ x059c537159 9 16 removal removal NOUN x059c537159 9 17 of of ADP x059c537159 9 18 thiol thiol NOUN x059c537159 9 19 from from ADP x059c537159 9 20 the the DET x059c537159 9 21 surface surface NOUN x059c537159 9 22 . . PUNCT x059c537159 10 1 when when SCONJ x059c537159 10 2 a a DET x059c537159 10 3 au(111 au(111 SPACE x059c537159 10 4 ) ) PUNCT x059c537159 10 5 surface surface NOUN x059c537159 10 6 is be AUX x059c537159 10 7 exposed expose VERB x059c537159 10 8 to to ADP x059c537159 10 9 solutions solution NOUN x059c537159 10 10 containing contain VERB x059c537159 10 11 both both CCONJ x059c537159 10 12 octanethiol octanethiol NOUN x059c537159 10 13 and and CCONJ x059c537159 10 14 dithiocarbamate dithiocarbamate NOUN x059c537159 10 15 ( ( PUNCT x059c537159 10 16 dtc dtc PROPN x059c537159 10 17 ) ) PUNCT x059c537159 10 18 , , PUNCT x059c537159 10 19 both both DET x059c537159 10 20 molecular molecular ADJ x059c537159 10 21 species specie NOUN x059c537159 10 22 compete compete VERB x059c537159 10 23 for for ADP x059c537159 10 24 available available ADJ x059c537159 10 25 adsorption adsorption NOUN x059c537159 10 26 sites site NOUN x059c537159 10 27 . . PUNCT x059c537159 11 1 at at ADP x059c537159 11 2 equal equal ADJ x059c537159 11 3 octanethiol octanethiol NOUN x059c537159 11 4 - - PUNCT x059c537159 11 5 to to ADP x059c537159 11 6 - - PUNCT x059c537159 11 7 dtc dtc NOUN x059c537159 11 8 ratios ratio NOUN x059c537159 11 9 , , PUNCT x059c537159 11 10 molecular molecular ADJ x059c537159 11 11 exchange exchange NOUN x059c537159 11 12 hinders hinder VERB x059c537159 11 13 octanethiol octanethiol NOUN x059c537159 11 14 monolayer monolayer NOUN x059c537159 11 15 formation formation NOUN x059c537159 11 16 . . PUNCT x059c537159 12 1 higher high ADJ x059c537159 12 2 octanethiol octanethiol ADJ x059c537159 12 3 concentration concentration NOUN x059c537159 12 4 in in ADP x059c537159 12 5 solution solution NOUN x059c537159 12 6 results result NOUN x059c537159 12 7 in in ADP x059c537159 12 8 the the DET x059c537159 12 9 incorporation incorporation NOUN x059c537159 12 10 of of ADP x059c537159 12 11 thiol thiol NOUN x059c537159 12 12 into into ADP x059c537159 12 13 the the DET x059c537159 12 14 resulting result VERB x059c537159 12 15 monolayer monolayer NOUN x059c537159 12 16 , , PUNCT x059c537159 12 17 with with ADP x059c537159 12 18 a a DET x059c537159 12 19 strong strong ADJ x059c537159 12 20 dependence dependence NOUN x059c537159 12 21 on on ADP x059c537159 12 22 the the DET x059c537159 12 23 chain chain NOUN x059c537159 12 24 length length NOUN x059c537159 12 25 of of ADP x059c537159 12 26 the the DET x059c537159 12 27 dtc dtc NOUN x059c537159 12 28 molecules molecule NOUN x059c537159 12 29 . . PUNCT