id sid tid token lemma pos w9504x5413z 1 1 the the DET w9504x5413z 1 2 radiolysis radiolysis NOUN w9504x5413z 1 3 of of ADP w9504x5413z 1 4 three three NUM w9504x5413z 1 5 iron iron NOUN w9504x5413z 1 6 oxides oxide NOUN w9504x5413z 1 7 , , PUNCT w9504x5413z 1 8 two two NUM w9504x5413z 1 9 copper copper NOUN w9504x5413z 1 10 oxides oxide NOUN w9504x5413z 1 11 , , PUNCT w9504x5413z 1 12 and and CCONJ w9504x5413z 1 13 aluminum aluminum NOUN w9504x5413z 1 14 oxide oxide NOUN w9504x5413z 1 15 with with ADP w9504x5413z 1 16 varying vary VERB w9504x5413z 1 17 amounts amount NOUN w9504x5413z 1 18 of of ADP w9504x5413z 1 19 water water NOUN w9504x5413z 1 20 were be AUX w9504x5413z 1 21 performed perform VERB w9504x5413z 1 22 using use VERB w9504x5413z 1 23 & & CCONJ w9504x5413z 1 24 # # SYM w9504x5413z 1 25 947;-rays 947;-rays NUM w9504x5413z 1 26 and and CCONJ w9504x5413z 1 27 5 5 NUM w9504x5413z 1 28 mev mev PROPN w9504x5413z 1 29 4he 4he PROPN w9504x5413z 1 30 ions ion NOUN w9504x5413z 1 31 . . PUNCT w9504x5413z 2 1 the the DET w9504x5413z 2 2 adsorbed adsorb VERB w9504x5413z 2 3 water water NOUN w9504x5413z 2 4 on on ADP w9504x5413z 2 5 the the DET w9504x5413z 2 6 surfaces surface NOUN w9504x5413z 2 7 was be AUX w9504x5413z 2 8 characterized characterize VERB w9504x5413z 2 9 using use VERB w9504x5413z 2 10 temperature temperature NOUN w9504x5413z 2 11 programmed program VERB w9504x5413z 2 12 desorption desorption NOUN w9504x5413z 2 13 and and CCONJ w9504x5413z 2 14 diffuse diffuse NOUN w9504x5413z 2 15 reflectance reflectance NOUN w9504x5413z 2 16 infrared infrared ADJ w9504x5413z 2 17 spectroscopy spectroscopy NOUN w9504x5413z 2 18 , , PUNCT w9504x5413z 2 19 which which PRON w9504x5413z 2 20 indicated indicate VERB w9504x5413z 2 21 that that SCONJ w9504x5413z 2 22 all all PRON w9504x5413z 2 23 of of ADP w9504x5413z 2 24 the the DET w9504x5413z 2 25 oxides oxide NOUN w9504x5413z 2 26 had have AUX w9504x5413z 2 27 chemisorbed chemisorb VERB w9504x5413z 2 28 water water NOUN w9504x5413z 2 29 on on ADP w9504x5413z 2 30 the the DET w9504x5413z 2 31 surface surface NOUN w9504x5413z 2 32 . . PUNCT w9504x5413z 3 1 physisorbed physisorbed ADJ w9504x5413z 3 2 water water NOUN w9504x5413z 3 3 was be AUX w9504x5413z 3 4 observed observe VERB w9504x5413z 3 5 on on ADP w9504x5413z 3 6 the the DET w9504x5413z 3 7 fe2o3 fe2o3 ADJ w9504x5413z 3 8 and and CCONJ w9504x5413z 3 9 al2o3 al2o3 NOUN w9504x5413z 3 10 surfaces surface NOUN w9504x5413z 3 11 as as ADV w9504x5413z 3 12 well well ADV w9504x5413z 3 13 . . PUNCT w9504x5413z 4 1 molecular molecular ADJ w9504x5413z 4 2 hydrogen hydrogen NOUN w9504x5413z 4 3 was be AUX w9504x5413z 4 4 produced produce VERB w9504x5413z 4 5 from from ADP w9504x5413z 4 6 adsorbed adsorb VERB w9504x5413z 4 7 water water NOUN w9504x5413z 4 8 only only ADV w9504x5413z 4 9 on on ADP w9504x5413z 4 10 fe2o3 fe2o3 NOUN w9504x5413z 4 11 and and CCONJ w9504x5413z 4 12 al2o3 al2o3 ADJ w9504x5413z 4 13 , , PUNCT w9504x5413z 4 14 while while SCONJ w9504x5413z 4 15 the the DET w9504x5413z 4 16 other other ADJ w9504x5413z 4 17 compounds compound NOUN w9504x5413z 4 18 did do AUX w9504x5413z 4 19 not not PART w9504x5413z 4 20 show show VERB w9504x5413z 4 21 any any DET w9504x5413z 4 22 hydrogen hydrogen NOUN w9504x5413z 4 23 production production NOUN w9504x5413z 4 24 due due ADP w9504x5413z 4 25 to to ADP w9504x5413z 4 26 the the DET w9504x5413z 4 27 low low ADJ w9504x5413z 4 28 amounts amount NOUN w9504x5413z 4 29 of of ADP w9504x5413z 4 30 water water NOUN w9504x5413z 4 31 on on ADP w9504x5413z 4 32 the the DET w9504x5413z 4 33 surfaces surface NOUN w9504x5413z 4 34 . . PUNCT w9504x5413z 5 1 slurries slurry NOUN w9504x5413z 5 2 of of ADP w9504x5413z 5 3 varying vary VERB w9504x5413z 5 4 amounts amount NOUN w9504x5413z 5 5 of of ADP w9504x5413z 5 6 water water NOUN w9504x5413z 5 7 were be AUX w9504x5413z 5 8 also also ADV w9504x5413z 5 9 examined examine VERB w9504x5413z 5 10 for for ADP w9504x5413z 5 11 hydrogen hydrogen NOUN w9504x5413z 5 12 production production NOUN w9504x5413z 5 13 , , PUNCT w9504x5413z 5 14 and and CCONJ w9504x5413z 5 15 they they PRON w9504x5413z 5 16 showed show VERB w9504x5413z 5 17 yields yield NOUN w9504x5413z 5 18 that that PRON w9504x5413z 5 19 were be AUX w9504x5413z 5 20 greater great ADJ w9504x5413z 5 21 than than ADP w9504x5413z 5 22 the the DET w9504x5413z 5 23 yield yield NOUN w9504x5413z 5 24 for for ADP w9504x5413z 5 25 bulk bulk ADJ w9504x5413z 5 26 water water NOUN w9504x5413z 5 27 . . PUNCT w9504x5413z 6 1 however however ADV w9504x5413z 6 2 , , PUNCT w9504x5413z 6 3 the the DET w9504x5413z 6 4 yields yield NOUN w9504x5413z 6 5 of of ADP w9504x5413z 6 6 hydrogen hydrogen NOUN w9504x5413z 6 7 from from ADP w9504x5413z 6 8 the the DET w9504x5413z 6 9 copper copper NOUN w9504x5413z 6 10 compounds compound NOUN w9504x5413z 6 11 were be AUX w9504x5413z 6 12 much much ADV w9504x5413z 6 13 lower low ADJ w9504x5413z 6 14 than than ADP w9504x5413z 6 15 those those PRON w9504x5413z 6 16 of of ADP w9504x5413z 6 17 the the DET w9504x5413z 6 18 iron iron NOUN w9504x5413z 6 19 suggesting suggest VERB w9504x5413z 6 20 that that SCONJ w9504x5413z 6 21 the the DET w9504x5413z 6 22 copper copper NOUN w9504x5413z 6 23 oxides oxide NOUN w9504x5413z 6 24 are be AUX w9504x5413z 6 25 relatively relatively ADV w9504x5413z 6 26 inert inert ADJ w9504x5413z 6 27 to to ADP w9504x5413z 6 28 radiation radiation NOUN w9504x5413z 6 29 induced induce VERB w9504x5413z 6 30 damage damage NOUN w9504x5413z 6 31 to to ADP w9504x5413z 6 32 nearby nearby ADJ w9504x5413z 6 33 water water NOUN w9504x5413z 6 34 . . PUNCT w9504x5413z 7 1 x x X w9504x5413z 7 2 - - NOUN w9504x5413z 7 3 ray ray NOUN w9504x5413z 7 4 diffraction diffraction NOUN w9504x5413z 7 5 measurements measurement NOUN w9504x5413z 7 6 did do AUX w9504x5413z 7 7 not not PART w9504x5413z 7 8 show show VERB w9504x5413z 7 9 any any DET w9504x5413z 7 10 indication indication NOUN w9504x5413z 7 11 of of ADP w9504x5413z 7 12 changes change NOUN w9504x5413z 7 13 to to ADP w9504x5413z 7 14 the the DET w9504x5413z 7 15 bulk bulk ADJ w9504x5413z 7 16 crystal crystal NOUN w9504x5413z 7 17 structure structure NOUN w9504x5413z 7 18 due due ADP w9504x5413z 7 19 to to ADP w9504x5413z 7 20 radiolysis radiolysis NOUN w9504x5413z 7 21 for for ADP w9504x5413z 7 22 any any PRON w9504x5413z 7 23 of of ADP w9504x5413z 7 24 the the DET w9504x5413z 7 25 oxides oxide NOUN w9504x5413z 7 26 . . PUNCT w9504x5413z 8 1 the the DET w9504x5413z 8 2 surfaces surface NOUN w9504x5413z 8 3 of of ADP w9504x5413z 8 4 the the DET w9504x5413z 8 5 oxides oxide NOUN w9504x5413z 8 6 were be AUX w9504x5413z 8 7 analyzed analyze VERB w9504x5413z 8 8 using use VERB w9504x5413z 8 9 raman raman NOUN w9504x5413z 8 10 spectroscopy spectroscopy NOUN w9504x5413z 8 11 and and CCONJ w9504x5413z 8 12 x x NOUN w9504x5413z 8 13 - - NOUN w9504x5413z 8 14 ray ray NOUN w9504x5413z 8 15 photoelectron photoelectron NOUN w9504x5413z 8 16 spectroscopy spectroscopy PROPN w9504x5413z 8 17 ( ( PUNCT w9504x5413z 8 18 xps xps PROPN w9504x5413z 8 19 ) ) PUNCT w9504x5413z 8 20 . . PUNCT w9504x5413z 9 1 for for ADP w9504x5413z 9 2 the the DET w9504x5413z 9 3 iron iron NOUN w9504x5413z 9 4 samples sample NOUN w9504x5413z 9 5 , , PUNCT w9504x5413z 9 6 feo feo PROPN w9504x5413z 9 7 and and CCONJ w9504x5413z 9 8 fe3o4 fe3o4 ADV w9504x5413z 9 9 , , PUNCT w9504x5413z 9 10 raman raman ADJ w9504x5413z 9 11 spectroscopy spectroscopy NOUN w9504x5413z 9 12 revealed reveal VERB w9504x5413z 9 13 areas area NOUN w9504x5413z 9 14 of of ADP w9504x5413z 9 15 fe2o3 fe2o3 NOUN w9504x5413z 9 16 had have AUX w9504x5413z 9 17 formed form VERB w9504x5413z 9 18 following follow VERB w9504x5413z 9 19 irradiation irradiation NOUN w9504x5413z 9 20 with with ADP w9504x5413z 9 21 he he PRON w9504x5413z 9 22 ions ion NOUN w9504x5413z 9 23 . . PUNCT w9504x5413z 10 1 xps xps PROPN w9504x5413z 10 2 indicated indicate VERB w9504x5413z 10 3 the the DET w9504x5413z 10 4 formation formation NOUN w9504x5413z 10 5 of of ADP w9504x5413z 10 6 a a DET w9504x5413z 10 7 new new ADJ w9504x5413z 10 8 oxygen oxygen NOUN w9504x5413z 10 9 species specie NOUN w9504x5413z 10 10 on on ADP w9504x5413z 10 11 the the DET w9504x5413z 10 12 iron iron NOUN w9504x5413z 10 13 oxide oxide NOUN w9504x5413z 10 14 surfaces surface NOUN w9504x5413z 10 15 . . PUNCT w9504x5413z 11 1 raman raman ADJ w9504x5413z 11 2 spectroscopy spectroscopy NOUN w9504x5413z 11 3 of of ADP w9504x5413z 11 4 the the DET w9504x5413z 11 5 copper copper NOUN w9504x5413z 11 6 oxides oxide NOUN w9504x5413z 11 7 did do AUX w9504x5413z 11 8 not not PART w9504x5413z 11 9 reveal reveal VERB w9504x5413z 11 10 any any DET w9504x5413z 11 11 changes change NOUN w9504x5413z 11 12 in in ADP w9504x5413z 11 13 the the DET w9504x5413z 11 14 surface surface NOUN w9504x5413z 11 15 composition composition NOUN w9504x5413z 11 16 , , PUNCT w9504x5413z 11 17 however however ADV w9504x5413z 11 18 , , PUNCT w9504x5413z 11 19 xps xps PROPN w9504x5413z 11 20 measurements measurement NOUN w9504x5413z 11 21 showed show VERB w9504x5413z 11 22 a a DET w9504x5413z 11 23 decrease decrease NOUN w9504x5413z 11 24 in in ADP w9504x5413z 11 25 the the DET w9504x5413z 11 26 amount amount NOUN w9504x5413z 11 27 of of ADP w9504x5413z 11 28 oh oh INTJ w9504x5413z 11 29 groups group NOUN w9504x5413z 11 30 on on ADP w9504x5413z 11 31 the the DET w9504x5413z 11 32 surface surface NOUN w9504x5413z 11 33 of of ADP w9504x5413z 11 34 cu2o cu2o SPACE w9504x5413z 11 35 , , PUNCT w9504x5413z 11 36 while while SCONJ w9504x5413z 11 37 for for ADP w9504x5413z 11 38 the the DET w9504x5413z 11 39 cuo cuo PROPN w9504x5413z 11 40 samples sample NOUN w9504x5413z 11 41 the the DET w9504x5413z 11 42 amount amount NOUN w9504x5413z 11 43 of of ADP w9504x5413z 11 44 oh oh INTJ w9504x5413z 11 45 groups group NOUN w9504x5413z 11 46 were be AUX w9504x5413z 11 47 found find VERB w9504x5413z 11 48 to to PART w9504x5413z 11 49 increase increase VERB w9504x5413z 11 50 following follow VERB w9504x5413z 11 51 radiolysis radiolysis NOUN w9504x5413z 11 52 . . PUNCT w9504x5413z 12 1 pristine pristine ADJ w9504x5413z 12 2 al2o3 al2o3 NOUN w9504x5413z 12 3 showed show VERB w9504x5413z 12 4 the the DET w9504x5413z 12 5 presence presence NOUN w9504x5413z 12 6 of of ADP w9504x5413z 12 7 a a DET w9504x5413z 12 8 surface surface NOUN w9504x5413z 12 9 oxyhydroxide oxyhydroxide ADJ w9504x5413z 12 10 layer layer NOUN w9504x5413z 12 11 which which PRON w9504x5413z 12 12 was be AUX w9504x5413z 12 13 observed observe VERB w9504x5413z 12 14 to to PART w9504x5413z 12 15 decrease decrease VERB w9504x5413z 12 16 following follow VERB w9504x5413z 12 17 radiolysis radiolysis NOUN w9504x5413z 12 18 , , PUNCT w9504x5413z 12 19 consistent consistent ADJ w9504x5413z 12 20 with with ADP w9504x5413z 12 21 the the DET w9504x5413z 12 22 formation formation NOUN w9504x5413z 12 23 of of ADP w9504x5413z 12 24 molecular molecular ADJ w9504x5413z 12 25 hydrogen hydrogen NOUN w9504x5413z 12 26 . . PUNCT