id sid tid token lemma pos vx021c20z0m 1 1 this this DET vx021c20z0m 1 2 thesis thesis NOUN vx021c20z0m 1 3 studies study VERB vx021c20z0m 1 4 the the DET vx021c20z0m 1 5 reactions reaction NOUN vx021c20z0m 1 6 and and CCONJ vx021c20z0m 1 7 structural structural ADJ vx021c20z0m 1 8 changes change NOUN vx021c20z0m 1 9 in in ADP vx021c20z0m 1 10 alkanethiol alkanethiol PROPN vx021c20z0m 1 11 self self NOUN vx021c20z0m 1 12 - - PUNCT vx021c20z0m 1 13 assembled assemble VERB vx021c20z0m 1 14 monolayers monolayer NOUN vx021c20z0m 1 15 ( ( PUNCT vx021c20z0m 1 16 sams sams PROPN vx021c20z0m 1 17 ) ) PUNCT vx021c20z0m 1 18 on on ADP vx021c20z0m 1 19 au(111 au(111 SPACE vx021c20z0m 1 20 ) ) PUNCT vx021c20z0m 1 21 resulting result VERB vx021c20z0m 1 22 from from ADP vx021c20z0m 1 23 exposure exposure NOUN vx021c20z0m 1 24 to to ADP vx021c20z0m 1 25 gas gas NOUN vx021c20z0m 1 26 - - PUNCT vx021c20z0m 1 27 phase phase NOUN vx021c20z0m 1 28 atomic atomic ADJ vx021c20z0m 1 29 hydrogen hydrogen NOUN vx021c20z0m 1 30 . . PUNCT vx021c20z0m 2 1 hydrogen hydrogen NOUN vx021c20z0m 2 2 atoms atom NOUN vx021c20z0m 2 3 remove remove VERB vx021c20z0m 2 4 the the DET vx021c20z0m 2 5 alkanethiol alkanethiol ADJ vx021c20z0m 2 6 molecules molecule NOUN vx021c20z0m 2 7 and and CCONJ vx021c20z0m 2 8 we we PRON vx021c20z0m 2 9 investigate investigate VERB vx021c20z0m 2 10 how how SCONJ vx021c20z0m 2 11 the the DET vx021c20z0m 2 12 local local ADJ vx021c20z0m 2 13 surface surface NOUN vx021c20z0m 2 14 environment environment NOUN vx021c20z0m 2 15 influences influence NOUN vx021c20z0m 2 16 monolayer monolayer NOUN vx021c20z0m 2 17 erosion erosion NOUN vx021c20z0m 2 18 . . PUNCT vx021c20z0m 3 1 a a DET vx021c20z0m 3 2 scanning scan VERB vx021c20z0m 3 3 tunneling tunneling NOUN vx021c20z0m 3 4 microscope microscope NOUN vx021c20z0m 3 5 ( ( PUNCT vx021c20z0m 3 6 stm stm PROPN vx021c20z0m 3 7 ) ) PUNCT vx021c20z0m 3 8 , , PUNCT vx021c20z0m 3 9 attached attach VERB vx021c20z0m 3 10 to to ADP vx021c20z0m 3 11 a a DET vx021c20z0m 3 12 molecular molecular ADJ vx021c20z0m 3 13 beam beam NOUN vx021c20z0m 3 14 chamber chamber NOUN vx021c20z0m 3 15 , , PUNCT vx021c20z0m 3 16 allows allow VERB vx021c20z0m 3 17 us we PRON vx021c20z0m 3 18 to to PART vx021c20z0m 3 19 monitor monitor VERB vx021c20z0m 3 20 in in ADP vx021c20z0m 3 21 situ situ NOUN vx021c20z0m 3 22 the the DET vx021c20z0m 3 23 exact exact ADJ vx021c20z0m 3 24 same same ADJ vx021c20z0m 3 25 area area NOUN vx021c20z0m 3 26 of of ADP vx021c20z0m 3 27 a a DET vx021c20z0m 3 28 surface surface NOUN vx021c20z0m 3 29 before before ADV vx021c20z0m 3 30 , , PUNCT vx021c20z0m 3 31 during during ADP vx021c20z0m 3 32 and and CCONJ vx021c20z0m 3 33 after after ADP vx021c20z0m 3 34 exposure exposure NOUN vx021c20z0m 3 35 . . PUNCT vx021c20z0m 4 1 initially initially ADV vx021c20z0m 4 2 extensive extensive ADJ vx021c20z0m 4 3 damage damage NOUN vx021c20z0m 4 4 to to ADP vx021c20z0m 4 5 the the DET vx021c20z0m 4 6 monolayer monolayer NOUN vx021c20z0m 4 7 is be AUX vx021c20z0m 4 8 observed observe VERB vx021c20z0m 4 9 in in ADP vx021c20z0m 4 10 the the DET vx021c20z0m 4 11 form form NOUN vx021c20z0m 4 12 of of ADP vx021c20z0m 4 13 both both CCONJ vx021c20z0m 4 14 dark dark ADJ vx021c20z0m 4 15 and and CCONJ vx021c20z0m 4 16 bright bright ADJ vx021c20z0m 4 17 features feature NOUN vx021c20z0m 4 18 in in ADP vx021c20z0m 4 19 stm stm NOUN vx021c20z0m 4 20 images image NOUN vx021c20z0m 4 21 . . PUNCT vx021c20z0m 5 1 molecules molecule NOUN vx021c20z0m 5 2 positioned position VERB vx021c20z0m 5 3 along along ADP vx021c20z0m 5 4 surface surface NOUN vx021c20z0m 5 5 defects defect NOUN vx021c20z0m 5 6 ( ( PUNCT vx021c20z0m 5 7 domain domain NOUN vx021c20z0m 5 8 boundaries boundary NOUN vx021c20z0m 5 9 , , PUNCT vx021c20z0m 5 10 gold gold NOUN vx021c20z0m 5 11 - - PUNCT vx021c20z0m 5 12 terrace terrace NOUN vx021c20z0m 5 13 step step NOUN vx021c20z0m 5 14 edges edge NOUN vx021c20z0m 5 15 ) ) PUNCT vx021c20z0m 5 16 are be AUX vx021c20z0m 5 17 preferentially preferentially ADV vx021c20z0m 5 18 removed remove VERB vx021c20z0m 5 19 before before ADP vx021c20z0m 5 20 molecules molecule NOUN vx021c20z0m 5 21 located locate VERB vx021c20z0m 5 22 in in ADP vx021c20z0m 5 23 close close ADV vx021c20z0m 5 24 - - PUNCT vx021c20z0m 5 25 packed pack VERB vx021c20z0m 5 26 areas area NOUN vx021c20z0m 5 27 . . PUNCT vx021c20z0m 6 1 while while SCONJ vx021c20z0m 6 2 the the DET vx021c20z0m 6 3 overall overall ADJ vx021c20z0m 6 4 net net ADJ vx021c20z0m 6 5 reaction reaction NOUN vx021c20z0m 6 6 is be AUX vx021c20z0m 6 7 to to PART vx021c20z0m 6 8 remove remove VERB vx021c20z0m 6 9 the the DET vx021c20z0m 6 10 octanethiol octanethiol PROPN vx021c20z0m 6 11 sam sam PROPN vx021c20z0m 6 12 , , PUNCT vx021c20z0m 6 13 molecules molecule NOUN vx021c20z0m 6 14 remaining remain VERB vx021c20z0m 6 15 on on ADP vx021c20z0m 6 16 the the DET vx021c20z0m 6 17 gold gold NOUN vx021c20z0m 6 18 surface surface NOUN vx021c20z0m 6 19 undergo undergo VERB vx021c20z0m 6 20 significant significant ADJ vx021c20z0m 6 21 rearrangement rearrangement NOUN vx021c20z0m 6 22 : : PUNCT vx021c20z0m 6 23 domain domain NOUN vx021c20z0m 6 24 boundaries boundary NOUN vx021c20z0m 6 25 anneal anneal ADJ vx021c20z0m 6 26 into into ADP vx021c20z0m 6 27 close close ADV vx021c20z0m 6 28 - - PUNCT vx021c20z0m 6 29 packed pack VERB vx021c20z0m 6 30 areas area NOUN vx021c20z0m 6 31 , , PUNCT vx021c20z0m 6 32 film film NOUN vx021c20z0m 6 33 defects defect NOUN vx021c20z0m 6 34 diffuse diffuse VERB vx021c20z0m 6 35 to to ADP vx021c20z0m 6 36 monolayer monolayer NOUN vx021c20z0m 6 37 edges edge NOUN vx021c20z0m 6 38 , , PUNCT vx021c20z0m 6 39 and and CCONJ vx021c20z0m 6 40 molecules molecule NOUN vx021c20z0m 6 41 located locate VERB vx021c20z0m 6 42 along along ADP vx021c20z0m 6 43 the the DET vx021c20z0m 6 44 edge edge NOUN vx021c20z0m 6 45 of of ADP vx021c20z0m 6 46 close close ADV vx021c20z0m 6 47 - - PUNCT vx021c20z0m 6 48 packed pack VERB vx021c20z0m 6 49 features feature NOUN vx021c20z0m 6 50 reorganize reorganize VERB vx021c20z0m 6 51 and and CCONJ vx021c20z0m 6 52 change change VERB vx021c20z0m 6 53 the the DET vx021c20z0m 6 54 shape shape NOUN vx021c20z0m 6 55 of of ADP vx021c20z0m 6 56 the the DET vx021c20z0m 6 57 remaining remain VERB vx021c20z0m 6 58 monolayer monolayer NOUN vx021c20z0m 6 59 . . PUNCT vx021c20z0m 7 1 this this DET vx021c20z0m 7 2 annealing annealing NOUN vx021c20z0m 7 3 and and CCONJ vx021c20z0m 7 4 restructuring restructure VERB vx021c20z0m 7 5 likely likely ADV vx021c20z0m 7 6 results result NOUN vx021c20z0m 7 7 from from ADP vx021c20z0m 7 8 increased increase VERB vx021c20z0m 7 9 mobility mobility NOUN vx021c20z0m 7 10 of of ADP vx021c20z0m 7 11 surface surface NOUN vx021c20z0m 7 12 - - PUNCT vx021c20z0m 7 13 bound bind VERB vx021c20z0m 7 14 alkanethiolates alkanethiolate NOUN vx021c20z0m 7 15 in in ADP vx021c20z0m 7 16 the the DET vx021c20z0m 7 17 vicinity vicinity NOUN vx021c20z0m 7 18 of of ADP vx021c20z0m 7 19 monolayer monolayer NOUN vx021c20z0m 7 20 defects defect NOUN vx021c20z0m 7 21 , , PUNCT vx021c20z0m 7 22 or or CCONJ vx021c20z0m 7 23 from from ADP vx021c20z0m 7 24 diffusion diffusion NOUN vx021c20z0m 7 25 and and CCONJ vx021c20z0m 7 26 readsorption readsorption NOUN vx021c20z0m 7 27 of of ADP vx021c20z0m 7 28 transiently transiently ADV vx021c20z0m 7 29 formed form VERB vx021c20z0m 7 30 alkanethiol alkanethiol ADJ vx021c20z0m 7 31 molecules molecule NOUN vx021c20z0m 7 32 . . PUNCT vx021c20z0m 8 1 increasing increase VERB vx021c20z0m 8 2 exposure exposure NOUN vx021c20z0m 8 3 also also ADV vx021c20z0m 8 4 results result VERB vx021c20z0m 8 5 in in ADP vx021c20z0m 8 6 an an DET vx021c20z0m 8 7 accelerated accelerated ADJ vx021c20z0m 8 8 rate rate NOUN vx021c20z0m 8 9 of of ADP vx021c20z0m 8 10 observed observed ADJ vx021c20z0m 8 11 surface surface NOUN vx021c20z0m 8 12 changes change NOUN vx021c20z0m 8 13 , , PUNCT vx021c20z0m 8 14 indicating indicate VERB vx021c20z0m 8 15 that that SCONJ vx021c20z0m 8 16 the the DET vx021c20z0m 8 17 reactivity reactivity NOUN vx021c20z0m 8 18 of of ADP vx021c20z0m 8 19 the the DET vx021c20z0m 8 20 surface surface NOUN vx021c20z0m 8 21 increases increase VERB vx021c20z0m 8 22 as as ADP vx021c20z0m 8 23 a a DET vx021c20z0m 8 24 result result NOUN vx021c20z0m 8 25 of of ADP vx021c20z0m 8 26 gas gas NOUN vx021c20z0m 8 27 - - PUNCT vx021c20z0m 8 28 surface surface NOUN vx021c20z0m 8 29 reactions reaction NOUN vx021c20z0m 8 30 . . PUNCT vx021c20z0m 9 1 we we PRON vx021c20z0m 9 2 compare compare VERB vx021c20z0m 9 3 our our PRON vx021c20z0m 9 4 results result NOUN vx021c20z0m 9 5 with with ADP vx021c20z0m 9 6 kinetic kinetic PROPN vx021c20z0m 9 7 monte monte PROPN vx021c20z0m 9 8 carlo carlo PROPN vx021c20z0m 9 9 simulations simulation NOUN vx021c20z0m 9 10 to to PART vx021c20z0m 9 11 determine determine VERB vx021c20z0m 9 12 that that SCONJ vx021c20z0m 9 13 the the DET vx021c20z0m 9 14 edge edge NOUN vx021c20z0m 9 15 of of ADP vx021c20z0m 9 16 defect defect NOUN vx021c20z0m 9 17 sites site NOUN vx021c20z0m 9 18 are be AUX vx021c20z0m 9 19 upwards upwards ADV vx021c20z0m 9 20 to to ADP vx021c20z0m 9 21 100 100 NUM vx021c20z0m 9 22 times time NOUN vx021c20z0m 9 23 more more ADV vx021c20z0m 9 24 reactive reactive ADJ vx021c20z0m 9 25 than than ADP vx021c20z0m 9 26 close close ADV vx021c20z0m 9 27 - - PUNCT vx021c20z0m 9 28 packed pack VERB vx021c20z0m 9 29 monolayer monolayer NOUN vx021c20z0m 9 30 areas area NOUN vx021c20z0m 9 31 . . PUNCT vx021c20z0m 10 1 monolayer monolayer NOUN vx021c20z0m 10 2 erosion erosion NOUN vx021c20z0m 10 3 also also ADV vx021c20z0m 10 4 revealed reveal VERB vx021c20z0m 10 5 the the DET vx021c20z0m 10 6 formation formation NOUN vx021c20z0m 10 7 of of ADP vx021c20z0m 10 8 bright bright ADJ vx021c20z0m 10 9 gold gold NOUN vx021c20z0m 10 10 islands island NOUN vx021c20z0m 10 11 . . PUNCT vx021c20z0m 11 1 recent recent ADJ vx021c20z0m 11 2 theoretical theoretical ADJ vx021c20z0m 11 3 and and CCONJ vx021c20z0m 11 4 experimental experimental ADJ vx021c20z0m 11 5 studies study NOUN vx021c20z0m 11 6 have have AUX vx021c20z0m 11 7 suggested suggest VERB vx021c20z0m 11 8 gold gold ADJ vx021c20z0m 11 9 adatoms adatom NOUN vx021c20z0m 11 10 are be AUX vx021c20z0m 11 11 incorporated incorporate VERB vx021c20z0m 11 12 into into ADP vx021c20z0m 11 13 the the DET vx021c20z0m 11 14 alkanethiol alkanethiol ADJ vx021c20z0m 11 15 -- -- PUNCT vx021c20z0m 11 16 gold gold NOUN vx021c20z0m 11 17 interface interface NOUN vx021c20z0m 11 18 . . PUNCT vx021c20z0m 12 1 the the DET vx021c20z0m 12 2 gold gold ADJ vx021c20z0m 12 3 adatoms adatom NOUN vx021c20z0m 12 4 remain remain VERB vx021c20z0m 12 5 on on ADP vx021c20z0m 12 6 the the DET vx021c20z0m 12 7 surface surface NOUN vx021c20z0m 12 8 after after SCONJ vx021c20z0m 12 9 alkanethiol alkanethiol PROPN vx021c20z0m 12 10 monolayer monolayer PROPN vx021c20z0m 12 11 removal removal NOUN vx021c20z0m 12 12 and and CCONJ vx021c20z0m 12 13 form form NOUN vx021c20z0m 12 14 features feature VERB vx021c20z0m 12 15 that that PRON vx021c20z0m 12 16 we we PRON vx021c20z0m 12 17 can can AUX vx021c20z0m 12 18 observe observe VERB vx021c20z0m 12 19 using use VERB vx021c20z0m 12 20 stm stm NOUN vx021c20z0m 12 21 : : PUNCT vx021c20z0m 12 22 formation formation NOUN vx021c20z0m 12 23 of of ADP vx021c20z0m 12 24 single single ADJ vx021c20z0m 12 25 - - PUNCT vx021c20z0m 12 26 atom atom NOUN vx021c20z0m 12 27 thick thick ADJ vx021c20z0m 12 28 gold gold PROPN vx021c20z0m 12 29 islands island NOUN vx021c20z0m 12 30 , , PUNCT vx021c20z0m 12 31 decreasing decrease VERB vx021c20z0m 12 32 size size NOUN vx021c20z0m 12 33 of of ADP vx021c20z0m 12 34 surface surface NOUN vx021c20z0m 12 35 vacancy vacancy NOUN vx021c20z0m 12 36 pits pit NOUN vx021c20z0m 12 37 , , PUNCT vx021c20z0m 12 38 and and CCONJ vx021c20z0m 12 39 faceting faceting NOUN vx021c20z0m 12 40 of of ADP vx021c20z0m 12 41 terrace terrace NOUN vx021c20z0m 12 42 step step NOUN vx021c20z0m 12 43 edges edge NOUN vx021c20z0m 12 44 . . PUNCT vx021c20z0m 13 1 compared compare VERB vx021c20z0m 13 2 to to ADP vx021c20z0m 13 3 the the DET vx021c20z0m 13 4 alkanethiol alkanethiol ADJ vx021c20z0m 13 5 - - PUNCT vx021c20z0m 13 6 terminated terminate VERB vx021c20z0m 13 7 surface surface NOUN vx021c20z0m 13 8 , , PUNCT vx021c20z0m 13 9 these these DET vx021c20z0m 13 10 features feature NOUN vx021c20z0m 13 11 indicate indicate VERB vx021c20z0m 13 12 a a DET vx021c20z0m 13 13 net net ADJ vx021c20z0m 13 14 increase increase NOUN vx021c20z0m 13 15 in in ADP vx021c20z0m 13 16 the the DET vx021c20z0m 13 17 amount amount NOUN vx021c20z0m 13 18 of of ADP vx021c20z0m 13 19 gold gold NOUN vx021c20z0m 13 20 present present ADJ vx021c20z0m 13 21 on on ADP vx021c20z0m 13 22 the the DET vx021c20z0m 13 23 surface surface NOUN vx021c20z0m 13 24 , , PUNCT vx021c20z0m 13 25 compared compare VERB vx021c20z0m 13 26 to to ADP vx021c20z0m 13 27 the the DET vx021c20z0m 13 28 alkanethiol alkanethiol ADV vx021c20z0m 13 29 - - PUNCT vx021c20z0m 13 30 terminated terminate VERB vx021c20z0m 13 31 bulk bulk ADJ vx021c20z0m 13 32 structure structure NOUN vx021c20z0m 13 33 . . PUNCT vx021c20z0m 14 1 varying vary VERB vx021c20z0m 14 2 the the DET vx021c20z0m 14 3 length length NOUN vx021c20z0m 14 4 of of ADP vx021c20z0m 14 5 the the DET vx021c20z0m 14 6 alkane alkane NOUN vx021c20z0m 14 7 chain chain NOUN vx021c20z0m 14 8 does do AUX vx021c20z0m 14 9 not not PART vx021c20z0m 14 10 affect affect VERB vx021c20z0m 14 11 the the DET vx021c20z0m 14 12 total total ADJ vx021c20z0m 14 13 adatom adatom ADJ vx021c20z0m 14 14 coverage coverage NOUN vx021c20z0m 14 15 , , PUNCT vx021c20z0m 14 16 as as ADP vx021c20z0m 14 17 adatom adatom ADJ vx021c20z0m 14 18 coverage coverage NOUN vx021c20z0m 14 19 for for ADP vx021c20z0m 14 20 ethanethiol ethanethiol NOUN vx021c20z0m 14 21 ( ( PUNCT vx021c20z0m 14 22 0.172 0.172 NUM vx021c20z0m 14 23 & & CCONJ vx021c20z0m 14 24 177 177 NUM vx021c20z0m 14 25 ; ; PUNCT vx021c20z0m 14 26 0.039 0.039 NUM vx021c20z0m 14 27 ) ) PUNCT vx021c20z0m 14 28 , , PUNCT vx021c20z0m 14 29 octanethiol octanethiol NOUN vx021c20z0m 14 30 ( ( PUNCT vx021c20z0m 14 31 0.143 0.143 NUM vx021c20z0m 14 32 & & CCONJ vx021c20z0m 14 33 177 177 NUM vx021c20z0m 14 34 ; ; PUNCT vx021c20z0m 14 35 0.033 0.033 NUM vx021c20z0m 14 36 ) ) PUNCT vx021c20z0m 14 37 , , PUNCT vx021c20z0m 14 38 and and CCONJ vx021c20z0m 14 39 dodecanethiol dodecanethiol PROPN vx021c20z0m 14 40 ( ( PUNCT vx021c20z0m 14 41 0.154 0.154 NUM vx021c20z0m 14 42 & & CCONJ vx021c20z0m 14 43 177 177 NUM vx021c20z0m 14 44 ; ; PUNCT vx021c20z0m 14 45 0.024 0.024 NUM vx021c20z0m 14 46 ) ) PUNCT vx021c20z0m 14 47 sams sam NOUN vx021c20z0m 14 48 are be AUX vx021c20z0m 14 49 within within ADP vx021c20z0m 14 50 experimental experimental ADJ vx021c20z0m 14 51 error error NOUN vx021c20z0m 14 52 of of ADP vx021c20z0m 14 53 one one NOUN vx021c20z0m 14 54 another another DET vx021c20z0m 14 55 . . PUNCT vx021c20z0m 15 1 this this PRON vx021c20z0m 15 2 corresponds correspond VERB vx021c20z0m 15 3 to to ADP vx021c20z0m 15 4 one one NUM vx021c20z0m 15 5 gold gold NOUN vx021c20z0m 15 6 adatom adatom NOUN vx021c20z0m 15 7 for for ADP vx021c20z0m 15 8 every every DET vx021c20z0m 15 9 six six NUM vx021c20z0m 15 10 atoms atom NOUN vx021c20z0m 15 11 in in ADP vx021c20z0m 15 12 the the DET vx021c20z0m 15 13 bulk bulk ADV vx021c20z0m 15 14 - - PUNCT vx021c20z0m 15 15 terminated terminate VERB vx021c20z0m 15 16 surface surface NOUN vx021c20z0m 15 17 , , PUNCT vx021c20z0m 15 18 and and CCONJ vx021c20z0m 15 19 thus thus ADV vx021c20z0m 15 20 one one NUM vx021c20z0m 15 21 gold gold NOUN vx021c20z0m 15 22 adatom adatom NOUN vx021c20z0m 15 23 for for ADP vx021c20z0m 15 24 every every DET vx021c20z0m 15 25 two two NUM vx021c20z0m 15 26 alkanethiol alkanethiol ADJ vx021c20z0m 15 27 molecules molecule NOUN vx021c20z0m 15 28 . . PUNCT