id sid tid token lemma pos v979v121868 1 1 despite despite SCONJ v979v121868 1 2 decades decade NOUN v979v121868 1 3 of of ADP v979v121868 1 4 research research NOUN v979v121868 1 5 , , PUNCT v979v121868 1 6 the the DET v979v121868 1 7 origins origin NOUN v979v121868 1 8 of of ADP v979v121868 1 9 spatially spatially ADV v979v121868 1 10 heterogeneous heterogeneous ADJ v979v121868 1 11 dynamics dynamic NOUN v979v121868 1 12 in in ADP v979v121868 1 13 proximity proximity NOUN v979v121868 1 14 to to ADP v979v121868 1 15 the the DET v979v121868 1 16 glass glass NOUN v979v121868 1 17 transition transition NOUN v979v121868 1 18 as as ADV v979v121868 1 19 well well ADV v979v121868 1 20 as as ADP v979v121868 1 21 the the DET v979v121868 1 22 length length NOUN v979v121868 1 23 scales scale NOUN v979v121868 1 24 associated associate VERB v979v121868 1 25 with with ADP v979v121868 1 26 these these DET v979v121868 1 27 heterogeneities heterogeneity NOUN v979v121868 1 28 , , PUNCT v979v121868 1 29 remains remains AUX v979v121868 1 30 hotly hotly ADV v979v121868 1 31 debated debate VERB v979v121868 1 32 as as SCONJ v979v121868 1 33 it it PRON v979v121868 1 34 is be AUX v979v121868 1 35 rather rather ADV v979v121868 1 36 difficult difficult ADJ v979v121868 1 37 extract extract VERB v979v121868 1 38 them they PRON v979v121868 1 39 from from ADP v979v121868 1 40 experiments experiment NOUN v979v121868 1 41 [ [ PUNCT v979v121868 1 42 1 1 NUM v979v121868 1 43 - - SYM v979v121868 1 44 4 4 NUM v979v121868 1 45 ] ] PUNCT v979v121868 1 46 . . PUNCT v979v121868 2 1 however however ADV v979v121868 2 2 , , PUNCT v979v121868 2 3 in in ADP v979v121868 2 4 recent recent ADJ v979v121868 2 5 years year NOUN v979v121868 2 6 direct direct ADJ v979v121868 2 7 visualization visualization NOUN v979v121868 2 8 of of ADP v979v121868 2 9 model model ADJ v979v121868 2 10 colloidal colloidal ADJ v979v121868 2 11 systems system NOUN v979v121868 2 12 via via ADP v979v121868 2 13 confocal confocal ADJ v979v121868 2 14 microscopy microscopy NOUN v979v121868 2 15 has have AUX v979v121868 2 16 become become VERB v979v121868 2 17 popular popular ADJ v979v121868 2 18 and and CCONJ v979v121868 2 19 provided provide VERB v979v121868 2 20 key key ADJ v979v121868 2 21 insights insight NOUN v979v121868 2 22 into into ADP v979v121868 2 23 the the DET v979v121868 2 24 glass glass NOUN v979v121868 2 25 transition transition NOUN v979v121868 2 26 in in ADP v979v121868 2 27 bulk bulk NOUN v979v121868 2 28 domains domain NOUN v979v121868 3 1 [ [ PUNCT v979v121868 3 2 3 3 NUM v979v121868 3 3 , , PUNCT v979v121868 3 4 4 4 NUM v979v121868 3 5 ] ] PUNCT v979v121868 3 6 . . PUNCT v979v121868 4 1 in in ADP v979v121868 4 2 this this DET v979v121868 4 3 thesis thesis NOUN v979v121868 4 4 , , PUNCT v979v121868 4 5 we we PRON v979v121868 4 6 use use VERB v979v121868 4 7 confinement confinement NOUN v979v121868 4 8 to to PART v979v121868 4 9 probe probe VERB v979v121868 4 10 how how SCONJ v979v121868 4 11 spatial spatial ADJ v979v121868 4 12 cooperativity cooperativity NOUN v979v121868 4 13 arises arise VERB v979v121868 4 14 when when SCONJ v979v121868 4 15 a a DET v979v121868 4 16 colloidal colloidal ADJ v979v121868 4 17 liquid liquid NOUN v979v121868 4 18 is be AUX v979v121868 4 19 constrained constrain VERB v979v121868 4 20 to to ADP v979v121868 4 21 progressively progressively ADV v979v121868 4 22 smaller small ADJ v979v121868 4 23 dimensions dimension NOUN v979v121868 4 24 and and CCONJ v979v121868 4 25 measure measure VERB v979v121868 4 26 the the DET v979v121868 4 27 length length NOUN v979v121868 4 28 scales scale NOUN v979v121868 4 29 associated associate VERB v979v121868 4 30 with with ADP v979v121868 4 31 such such ADJ v979v121868 4 32 motions motion NOUN v979v121868 4 33 . . PUNCT v979v121868 5 1 additionally additionally ADV v979v121868 5 2 , , PUNCT v979v121868 5 3 we we PRON v979v121868 5 4 examine examine VERB v979v121868 5 5 how how SCONJ v979v121868 5 6 sensitivity sensitivity NOUN v979v121868 5 7 to to ADP v979v121868 5 8 dynamic dynamic ADJ v979v121868 5 9 length length NOUN v979v121868 5 10 scales scale NOUN v979v121868 5 11 is be AUX v979v121868 5 12 dependent dependent ADJ v979v121868 5 13 on on ADP v979v121868 5 14 the the DET v979v121868 5 15 sizes size NOUN v979v121868 5 16 of of ADP v979v121868 5 17 tracers tracer NOUN v979v121868 5 18 embedded embed VERB v979v121868 5 19 in in ADP v979v121868 5 20 matrix matrix NOUN v979v121868 5 21 suspensions suspension NOUN v979v121868 5 22 that that PRON v979v121868 5 23 are be AUX v979v121868 5 24 close close ADJ v979v121868 5 25 to to ADP v979v121868 5 26 the the DET v979v121868 5 27 colloidal colloidal ADJ v979v121868 5 28 glass glass NOUN v979v121868 5 29 transition transition NOUN v979v121868 5 30 . . PUNCT v979v121868 6 1 these these DET v979v121868 6 2 studies study NOUN v979v121868 6 3 are be AUX v979v121868 6 4 not not PART v979v121868 6 5 only only ADV v979v121868 6 6 of of ADP v979v121868 6 7 fundamental fundamental ADJ v979v121868 6 8 interest interest NOUN v979v121868 6 9 , , PUNCT v979v121868 6 10 but but CCONJ v979v121868 6 11 they they PRON v979v121868 6 12 have have VERB v979v121868 6 13 wide wide ADJ v979v121868 6 14 ranging range VERB v979v121868 6 15 applications application NOUN v979v121868 6 16 that that PRON v979v121868 6 17 crosses cross VERB v979v121868 6 18 disciplines discipline NOUN v979v121868 6 19 ranging range VERB v979v121868 6 20 from from ADP v979v121868 6 21 the the DET v979v121868 6 22 instability instability NOUN v979v121868 6 23 of of ADP v979v121868 6 24 sub-100 sub-100 ADJ v979v121868 6 25 nm nm NOUN v979v121868 6 26 polymer polymer NOUN v979v121868 6 27 nanostructures nanostructure NOUN v979v121868 6 28 used use VERB v979v121868 6 29 in in ADP v979v121868 6 30 nanolithography nanolithography NOUN v979v121868 6 31 and and CCONJ v979v121868 6 32 data datum NOUN v979v121868 6 33 storage storage NOUN v979v121868 6 34 applications application NOUN v979v121868 6 35 to to AUX v979v121868 6 36 protein protein NOUN v979v121868 6 37 folding fold VERB v979v121868 6 38 [ [ PUNCT v979v121868 6 39 1 1 NUM v979v121868 6 40 - - SYM v979v121868 6 41 5 5 NUM v979v121868 6 42 ] ] PUNCT v979v121868 6 43 . . PUNCT v979v121868 7 1 in in ADP v979v121868 7 2 chapter chapter NOUN v979v121868 7 3 3 3 NUM v979v121868 7 4 , , PUNCT v979v121868 7 5 we we PRON v979v121868 7 6 find find VERB v979v121868 7 7 impeded impede VERB v979v121868 7 8 structural structural ADJ v979v121868 7 9 relaxation relaxation NOUN v979v121868 7 10 of of ADP v979v121868 7 11 hard hard ADJ v979v121868 7 12 - - PUNCT v979v121868 7 13 sphere sphere NOUN v979v121868 7 14 colloidal colloidal ADJ v979v121868 7 15 suspensions suspension NOUN v979v121868 7 16 in in ADP v979v121868 7 17 confinement confinement NOUN v979v121868 7 18 . . PUNCT v979v121868 8 1 interestingly interestingly ADV v979v121868 8 2 , , PUNCT v979v121868 8 3 we we PRON v979v121868 8 4 find find VERB v979v121868 8 5 similar similar ADJ v979v121868 8 6 behavior behavior NOUN v979v121868 8 7 in in ADP v979v121868 8 8 a a DET v979v121868 8 9 suspension suspension NOUN v979v121868 8 10 of of ADP v979v121868 8 11 soft soft ADJ v979v121868 8 12 , , PUNCT v979v121868 8 13 deformable deformable NOUN v979v121868 8 14 spheres sphere NOUN v979v121868 8 15 in in ADP v979v121868 8 16 chapter chapter NOUN v979v121868 8 17 4 4 NUM v979v121868 8 18 where where SCONJ v979v121868 8 19 we we PRON v979v121868 8 20 examine examine VERB v979v121868 8 21 colloidal colloidal ADJ v979v121868 8 22 gelation gelation NOUN v979v121868 8 23 in in ADP v979v121868 8 24 confinement confinement NOUN v979v121868 8 25 as as ADV v979v121868 8 26 well well ADV v979v121868 8 27 as as ADP v979v121868 8 28 the the DET v979v121868 8 29 emergence emergence NOUN v979v121868 8 30 of of ADP v979v121868 8 31 spatially spatially ADV v979v121868 8 32 heterogeneous heterogeneous ADJ v979v121868 8 33 dynamics dynamic NOUN v979v121868 8 34 that that PRON v979v121868 8 35 has have VERB v979v121868 8 36 a a DET v979v121868 8 37 distinct distinct ADJ v979v121868 8 38 structural structural ADJ v979v121868 8 39 origin origin NOUN v979v121868 8 40 . . PUNCT v979v121868 9 1 in in ADP v979v121868 9 2 the the DET v979v121868 9 3 second second ADJ v979v121868 9 4 part part NOUN v979v121868 9 5 of of ADP v979v121868 9 6 this this DET v979v121868 9 7 work work NOUN v979v121868 9 8 , , PUNCT v979v121868 9 9 we we PRON v979v121868 9 10 focus focus VERB v979v121868 9 11 exclusively exclusively ADV v979v121868 9 12 on on ADP v979v121868 9 13 heterogeneous heterogeneous ADJ v979v121868 9 14 dynamics dynamic NOUN v979v121868 9 15 and and CCONJ v979v121868 9 16 methods method NOUN v979v121868 9 17 to to PART v979v121868 9 18 extract extract VERB v979v121868 9 19 dynamic dynamic ADJ v979v121868 9 20 length length NOUN v979v121868 9 21 scales scale NOUN v979v121868 9 22 associated associate VERB v979v121868 9 23 with with ADP v979v121868 9 24 spatially spatially ADV v979v121868 9 25 heterogeneous heterogeneous ADJ v979v121868 9 26 dynamics dynamic NOUN v979v121868 9 27 . . PUNCT v979v121868 10 1 in in ADP v979v121868 10 2 chapter chapter NOUN v979v121868 10 3 5 5 NUM v979v121868 10 4 , , PUNCT v979v121868 10 5 we we PRON v979v121868 10 6 study study VERB v979v121868 10 7 the the DET v979v121868 10 8 tracer tracer NOUN v979v121868 10 9 size size NOUN v979v121868 10 10 sensitivity sensitivity NOUN v979v121868 10 11 to to ADP v979v121868 10 12 spatially spatially ADV v979v121868 10 13 heterogeneous heterogeneous ADJ v979v121868 10 14 dynamics dynamic NOUN v979v121868 10 15 in in ADP v979v121868 10 16 matrix matrix NOUN v979v121868 10 17 suspensions suspension NOUN v979v121868 10 18 that that PRON v979v121868 10 19 are be AUX v979v121868 10 20 close close ADJ v979v121868 10 21 to to ADP v979v121868 10 22 the the DET v979v121868 10 23 colloidal colloidal ADJ v979v121868 10 24 glass glass NOUN v979v121868 10 25 transition transition NOUN v979v121868 10 26 . . PUNCT v979v121868 11 1 in in ADP v979v121868 11 2 chapter chapter NOUN v979v121868 11 3 6 6 NUM v979v121868 11 4 , , PUNCT v979v121868 11 5 we we PRON v979v121868 11 6 confine confine VERB v979v121868 11 7 hard hard ADJ v979v121868 11 8 - - PUNCT v979v121868 11 9 sphere sphere NOUN v979v121868 11 10 suspensions suspension NOUN v979v121868 11 11 to to PART v979v121868 11 12 progressively progressively ADV v979v121868 11 13 smaller small ADJ v979v121868 11 14 dimensions dimension NOUN v979v121868 11 15 to to PART v979v121868 11 16 probe probe VERB v979v121868 11 17 the the DET v979v121868 11 18 confinement confinement ADJ v979v121868 11 19 effect effect NOUN v979v121868 11 20 on on ADP v979v121868 11 21 the the DET v979v121868 11 22 growth growth NOUN v979v121868 11 23 of of ADP v979v121868 11 24 dynamic dynamic ADJ v979v121868 11 25 heterogeneities heterogeneity NOUN v979v121868 11 26 via via ADP v979v121868 11 27 confocal confocal ADJ v979v121868 11 28 microscopy microscopy NOUN v979v121868 11 29 . . PUNCT v979v121868 12 1 heterogeneous heterogeneous ADJ v979v121868 12 2 dynamics dynamic NOUN v979v121868 12 3 abruptly abruptly ADV v979v121868 12 4 increases increase VERB v979v121868 12 5 as as SCONJ v979v121868 12 6 the the DET v979v121868 12 7 gap gap NOUN v979v121868 12 8 is be AUX v979v121868 12 9 reduced reduce VERB v979v121868 12 10 below below ADP v979v121868 12 11 a a DET v979v121868 12 12 critical critical ADJ v979v121868 12 13 spacing spacing NOUN v979v121868 12 14 , , PUNCT v979v121868 12 15 defining define VERB v979v121868 12 16 the the DET v979v121868 12 17 confinement confinement ADJ v979v121868 12 18 length length NOUN v979v121868 12 19 scale scale NOUN v979v121868 12 20 . . PUNCT v979v121868 13 1 in in ADP v979v121868 13 2 chapter chapter NOUN v979v121868 13 3 7 7 NUM v979v121868 13 4 we we PRON v979v121868 13 5 examine examine VERB v979v121868 13 6 spatially spatially ADV v979v121868 13 7 heterogeneous heterogeneous ADJ v979v121868 13 8 dynamics dynamic NOUN v979v121868 13 9 in in ADP v979v121868 13 10 confined confine VERB v979v121868 13 11 colloidal colloidal ADJ v979v121868 13 12 liquids liquid NOUN v979v121868 13 13 under under ADP v979v121868 13 14 oscillatory oscillatory ADJ v979v121868 13 15 shear shear NOUN v979v121868 13 16 . . PUNCT