id	sid	tid	token	lemma	pos
v405s754q1d	1	1	broadly	broadly	ADV
v405s754q1d	1	2	speaking	speak	VERB
v405s754q1d	1	3	the	the	DET
v405s754q1d	1	4	objective	objective	NOUN
v405s754q1d	1	5	of	of	ADP
v405s754q1d	1	6	this	this	DET
v405s754q1d	1	7	dissertation	dissertation	NOUN
v405s754q1d	1	8	is	be	AUX
v405s754q1d	1	9	the	the	DET
v405s754q1d	1	10	investigation	investigation	NOUN
v405s754q1d	1	11	of	of	ADP
v405s754q1d	1	12	carbohydrate	carbohydrate	NOUN
v405s754q1d	1	13	structure	structure	NOUN
v405s754q1d	1	14	through	through	ADP
v405s754q1d	1	15	an	an	DET
v405s754q1d	1	16	integrated	integrated	ADJ
v405s754q1d	1	17	theoretical	theoretical	ADJ
v405s754q1d	1	18	and	and	CCONJ
v405s754q1d	1	19	experimental	experimental	ADJ
v405s754q1d	1	20	approach	approach	NOUN
v405s754q1d	1	21	.	.	PUNCT
v405s754q1d	2	1	in	in	ADP
v405s754q1d	2	2	addition	addition	NOUN
v405s754q1d	2	3	to	to	ADP
v405s754q1d	2	4	being	be	AUX
v405s754q1d	2	5	the	the	DET
v405s754q1d	2	6	most	most	ADV
v405s754q1d	2	7	evolutionary	evolutionary	ADJ
v405s754q1d	2	8	ancient	ancient	ADJ
v405s754q1d	2	9	class	class	NOUN
v405s754q1d	2	10	of	of	ADP
v405s754q1d	2	11	biopolymer	biopolymer	NOUN
v405s754q1d	2	12	,	,	PUNCT
v405s754q1d	2	13	carbohydrates	carbohydrate	NOUN
v405s754q1d	2	14	have	have	VERB
v405s754q1d	2	15	the	the	DET
v405s754q1d	2	16	highest	high	ADJ
v405s754q1d	2	17	potential	potential	NOUN
v405s754q1d	2	18	for	for	ADP
v405s754q1d	2	19	structural	structural	ADJ
v405s754q1d	2	20	diversity	diversity	NOUN
v405s754q1d	2	21	.	.	PUNCT
v405s754q1d	3	1	this	this	DET
v405s754q1d	3	2	structural	structural	ADJ
v405s754q1d	3	3	diversity	diversity	NOUN
v405s754q1d	3	4	is	be	AUX
v405s754q1d	3	5	manifest	manif	ADJ
v405s754q1d	3	6	both	both	CCONJ
v405s754q1d	3	7	in	in	ADP
v405s754q1d	3	8	terms	term	NOUN
v405s754q1d	3	9	of	of	ADP
v405s754q1d	3	10	primary	primary	ADJ
v405s754q1d	3	11	sequence	sequence	NOUN
v405s754q1d	3	12	,	,	PUNCT
v405s754q1d	3	13	and	and	CCONJ
v405s754q1d	3	14	in	in	ADP
v405s754q1d	3	15	a	a	DET
v405s754q1d	3	16	very	very	ADV
v405s754q1d	3	17	high	high	ADJ
v405s754q1d	3	18	potential	potential	NOUN
v405s754q1d	3	19	for	for	ADP
v405s754q1d	3	20	conformational	conformational	ADJ
v405s754q1d	3	21	flexibility	flexibility	NOUN
v405s754q1d	3	22	due	due	ADP
v405s754q1d	3	23	to	to	ADP
v405s754q1d	3	24	the	the	DET
v405s754q1d	3	25	high	high	ADJ
v405s754q1d	3	26	concentration	concentration	NOUN
v405s754q1d	3	27	of	of	ADP
v405s754q1d	3	28	geometrically	geometrically	ADV
v405s754q1d	3	29	mobile	mobile	ADJ
v405s754q1d	3	30	dihedrals	dihedral	NOUN
v405s754q1d	3	31	present	present	ADJ
v405s754q1d	3	32	in	in	ADP
v405s754q1d	3	33	saccharides	saccharide	NOUN
v405s754q1d	3	34	.	.	PUNCT
v405s754q1d	4	1	the	the	DET
v405s754q1d	4	2	structural	structural	ADJ
v405s754q1d	4	3	biology	biology	NOUN
v405s754q1d	4	4	of	of	ADP
v405s754q1d	4	5	saccharides	saccharide	NOUN
v405s754q1d	4	6	is	be	AUX
v405s754q1d	4	7	further	far	ADV
v405s754q1d	4	8	complicated	complicate	VERB
v405s754q1d	4	9	by	by	ADP
v405s754q1d	4	10	a	a	DET
v405s754q1d	4	11	dearth	dearth	NOUN
v405s754q1d	4	12	of	of	ADP
v405s754q1d	4	13	robust	robust	ADJ
v405s754q1d	4	14	experimental	experimental	ADJ
v405s754q1d	4	15	and	and	CCONJ
v405s754q1d	4	16	theoretical	theoretical	ADJ
v405s754q1d	4	17	techniques	technique	NOUN
v405s754q1d	4	18	.	.	PUNCT
v405s754q1d	5	1	a	a	DET
v405s754q1d	5	2	large	large	ADJ
v405s754q1d	5	3	component	component	NOUN
v405s754q1d	5	4	of	of	ADP
v405s754q1d	5	5	this	this	DET
v405s754q1d	5	6	work	work	NOUN
v405s754q1d	5	7	involved	involve	VERB
v405s754q1d	5	8	developing	develop	VERB
v405s754q1d	5	9	experimental	experimental	ADJ
v405s754q1d	5	10	and	and	CCONJ
v405s754q1d	5	11	theoretical	theoretical	ADJ
v405s754q1d	5	12	tools	tool	NOUN
v405s754q1d	5	13	for	for	ADP
v405s754q1d	5	14	the	the	DET
v405s754q1d	5	15	conformational	conformational	ADJ
v405s754q1d	5	16	analysis	analysis	NOUN
v405s754q1d	5	17	of	of	ADP
v405s754q1d	5	18	carbohydrates	carbohydrate	NOUN
v405s754q1d	5	19	,	,	PUNCT
v405s754q1d	5	20	specifically	specifically	ADV
v405s754q1d	5	21	parameterizing	parameterize	VERB
v405s754q1d	5	22	the	the	DET
v405s754q1d	5	23	conformational	conformational	ADJ
v405s754q1d	5	24	dependence	dependence	NOUN
v405s754q1d	5	25	of	of	ADP
v405s754q1d	5	26	nmr	nmr	ADJ
v405s754q1d	5	27	spin	spin	NOUN
v405s754q1d	5	28	-	-	PUNCT
v405s754q1d	5	29	spin	spin	NOUN
v405s754q1d	5	30	couplings	coupling	NOUN
v405s754q1d	5	31	for	for	ADP
v405s754q1d	5	32	the	the	DET
v405s754q1d	5	33	interpretation	interpretation	NOUN
v405s754q1d	5	34	of	of	ADP
v405s754q1d	5	35	experimental	experimental	ADJ
v405s754q1d	5	36	couplings	coupling	NOUN
v405s754q1d	5	37	in	in	ADP
v405s754q1d	5	38	structural	structural	ADJ
v405s754q1d	5	39	terms	term	NOUN
v405s754q1d	5	40	.	.	PUNCT
v405s754q1d	6	1	on	on	ADP
v405s754q1d	6	2	the	the	DET
v405s754q1d	6	3	experimental	experimental	ADJ
v405s754q1d	6	4	side	side	NOUN
v405s754q1d	6	5	measurement	measurement	NOUN
v405s754q1d	6	6	of	of	ADP
v405s754q1d	6	7	13c	13c	NUM
v405s754q1d	6	8	-	-	PUNCT
v405s754q1d	6	9	based	base	VERB
v405s754q1d	6	10	spin	spin	NOUN
v405s754q1d	6	11	-	-	PUNCT
v405s754q1d	6	12	spin	spin	NOUN
v405s754q1d	6	13	couplings	coupling	NOUN
v405s754q1d	6	14	necessitated	necessitate	VERB
v405s754q1d	6	15	the	the	DET
v405s754q1d	6	16	development	development	NOUN
v405s754q1d	6	17	of	of	ADP
v405s754q1d	6	18	technologies	technology	NOUN
v405s754q1d	6	19	for	for	ADP
v405s754q1d	6	20	strategic	strategic	ADJ
v405s754q1d	6	21	isotopic	isotopic	ADJ
v405s754q1d	6	22	enrichment	enrichment	NOUN
v405s754q1d	6	23	.	.	PUNCT
v405s754q1d	7	1	the	the	DET
v405s754q1d	7	2	couplings	coupling	NOUN
v405s754q1d	7	3	measured	measure	VERB
v405s754q1d	7	4	in	in	ADP
v405s754q1d	7	5	these	these	DET
v405s754q1d	7	6	compounds	compound	NOUN
v405s754q1d	7	7	are	be	AUX
v405s754q1d	7	8	interpreted	interpret	VERB
v405s754q1d	7	9	using	use	VERB
v405s754q1d	7	10	theoretically	theoretically	ADV
v405s754q1d	7	11	derived	derive	VERB
v405s754q1d	7	12	relationships	relationship	NOUN
v405s754q1d	7	13	between	between	ADP
v405s754q1d	7	14	molecular	molecular	ADJ
v405s754q1d	7	15	conformation	conformation	NOUN
v405s754q1d	7	16	and	and	CCONJ
v405s754q1d	7	17	coupling	coupling	NOUN
v405s754q1d	7	18	magnitude	magnitude	NOUN
v405s754q1d	7	19	.	.	PUNCT
v405s754q1d	8	1	these	these	DET
v405s754q1d	8	2	karplus	karplus	ADJ
v405s754q1d	8	3	relationships	relationship	NOUN
v405s754q1d	8	4	are	be	AUX
v405s754q1d	8	5	based	base	VERB
v405s754q1d	8	6	upon	upon	SCONJ
v405s754q1d	8	7	quantum	quantum	ADJ
v405s754q1d	8	8	mechanical	mechanical	ADJ
v405s754q1d	8	9	density	density	NOUN
v405s754q1d	8	10	functional	functional	ADJ
v405s754q1d	8	11	theory	theory	NOUN
v405s754q1d	8	12	(	(	PUNCT
v405s754q1d	8	13	dft	dft	NOUN
v405s754q1d	8	14	)	)	PUNCT
v405s754q1d	8	15	calculations	calculation	NOUN
v405s754q1d	8	16	of	of	ADP
v405s754q1d	8	17	spin	spin	NOUN
v405s754q1d	8	18	-	-	PUNCT
v405s754q1d	8	19	spin	spin	NOUN
v405s754q1d	8	20	couplings	coupling	NOUN
v405s754q1d	8	21	on	on	ADP
v405s754q1d	8	22	energetically	energetically	ADV
v405s754q1d	8	23	optimized	optimize	VERB
v405s754q1d	8	24	model	model	NOUN
v405s754q1d	8	25	compounds	compound	NOUN
v405s754q1d	8	26	in	in	ADP
v405s754q1d	8	27	which	which	PRON
v405s754q1d	8	28	a	a	DET
v405s754q1d	8	29	particular	particular	ADJ
v405s754q1d	8	30	geometric	geometric	ADJ
v405s754q1d	8	31	feature	feature	NOUN
v405s754q1d	8	32	such	such	ADJ
v405s754q1d	8	33	as	as	ADP
v405s754q1d	8	34	a	a	DET
v405s754q1d	8	35	dihedral	dihedral	NOUN
v405s754q1d	8	36	is	be	AUX
v405s754q1d	8	37	varied	varied	ADJ
v405s754q1d	8	38	.	.	PUNCT
v405s754q1d	9	1	the	the	DET
v405s754q1d	9	2	structural	structural	ADJ
v405s754q1d	9	3	interpretations	interpretation	NOUN
v405s754q1d	9	4	of	of	ADP
v405s754q1d	9	5	these	these	DET
v405s754q1d	9	6	couplings	coupling	NOUN
v405s754q1d	9	7	takes	take	VERB
v405s754q1d	9	8	the	the	DET
v405s754q1d	9	9	form	form	NOUN
v405s754q1d	9	10	of	of	ADP
v405s754q1d	9	11	populational	populational	ADJ
v405s754q1d	9	12	distributions	distribution	NOUN
v405s754q1d	9	13	about	about	ADP
v405s754q1d	9	14	the	the	DET
v405s754q1d	9	15	relevant	relevant	ADJ
v405s754q1d	9	16	molecular	molecular	ADJ
v405s754q1d	9	17	dihedrals	dihedral	NOUN
v405s754q1d	9	18	.	.	PUNCT
v405s754q1d	10	1	this	this	PRON
v405s754q1d	10	2	is	be	AUX
v405s754q1d	10	3	applied	apply	VERB
v405s754q1d	10	4	in	in	ADP
v405s754q1d	10	5	a	a	DET
v405s754q1d	10	6	modular	modular	ADJ
v405s754q1d	10	7	fashion	fashion	NOUN
v405s754q1d	10	8	to	to	ADP
v405s754q1d	10	9	various	various	ADJ
v405s754q1d	10	10	molecular	molecular	ADJ
v405s754q1d	10	11	fragments	fragment	NOUN
v405s754q1d	10	12	of	of	ADP
v405s754q1d	10	13	biologically	biologically	ADV
v405s754q1d	10	14	significant	significant	ADJ
v405s754q1d	10	15	monosaccharides	monosaccharide	NOUN
v405s754q1d	10	16	.	.	PUNCT
v405s754q1d	11	1	the	the	DET
v405s754q1d	11	2	natural	natural	ADJ
v405s754q1d	11	3	bonding	bonding	NOUN
v405s754q1d	11	4	orbital	orbital	ADJ
v405s754q1d	11	5	(	(	PUNCT
v405s754q1d	11	6	nbo	nbo	PROPN
v405s754q1d	11	7	)	)	PUNCT
v405s754q1d	11	8	method	method	NOUN
v405s754q1d	11	9	is	be	AUX
v405s754q1d	11	10	used	use	VERB
v405s754q1d	11	11	to	to	PART
v405s754q1d	11	12	dissect	dissect	VERB
v405s754q1d	11	13	spin	spin	NOUN
v405s754q1d	11	14	-	-	PUNCT
v405s754q1d	11	15	spin	spin	NOUN
v405s754q1d	11	16	coupling	coupling	NOUN
v405s754q1d	11	17	mechanisms	mechanism	NOUN
v405s754q1d	11	18	based	base	VERB
v405s754q1d	11	19	upon	upon	SCONJ
v405s754q1d	11	20	discreet	discreet	ADJ
v405s754q1d	11	21	through	through	ADP
v405s754q1d	11	22	space	space	NOUN
v405s754q1d	11	23	and	and	CCONJ
v405s754q1d	11	24	through	through	ADP
v405s754q1d	11	25	bond	bond	NOUN
v405s754q1d	11	26	orbital	orbital	ADJ
v405s754q1d	11	27	interactions	interaction	NOUN
v405s754q1d	11	28	.	.	PUNCT
v405s754q1d	12	1	lastly	lastly	ADV
v405s754q1d	12	2	,	,	PUNCT
v405s754q1d	12	3	an	an	DET
v405s754q1d	12	4	x	x	ADJ
v405s754q1d	12	5	-	-	NOUN
v405s754q1d	12	6	ray	ray	NOUN
v405s754q1d	12	7	crystal	crystal	NOUN
v405s754q1d	12	8	structure	structure	NOUN
v405s754q1d	12	9	of	of	ADP
v405s754q1d	12	10	methyl	methyl	PROPN
v405s754q1d	12	11	-	-	PUNCT
v405s754q1d	12	12	allolactoside	allolactoside	PROPN
v405s754q1d	12	13	is	be	AUX
v405s754q1d	12	14	presented	present	VERB
v405s754q1d	12	15	with	with	ADP
v405s754q1d	12	16	a	a	DET
v405s754q1d	12	17	complete	complete	ADJ
v405s754q1d	12	18	structural	structural	ADJ
v405s754q1d	12	19	analysis	analysis	NOUN
v405s754q1d	12	20	including	include	VERB
v405s754q1d	12	21	a	a	DET
v405s754q1d	12	22	discussion	discussion	NOUN
v405s754q1d	12	23	of	of	ADP
v405s754q1d	12	24	ring	ring	NOUN
v405s754q1d	12	25	-	-	PUNCT
v405s754q1d	12	26	puckering	pucker	VERB
v405s754q1d	12	27	behaviour	behaviour	NOUN
v405s754q1d	12	28	.	.	PUNCT
v405s754q1d	13	1	the	the	DET
v405s754q1d	13	2	battery	battery	NOUN
v405s754q1d	13	3	of	of	ADP
v405s754q1d	13	4	experimental	experimental	ADJ
v405s754q1d	13	5	and	and	CCONJ
v405s754q1d	13	6	theoretical	theoretical	ADJ
v405s754q1d	13	7	techniques	technique	NOUN
v405s754q1d	13	8	presented	present	VERB
v405s754q1d	13	9	in	in	ADP
v405s754q1d	13	10	this	this	DET
v405s754q1d	13	11	dissertation	dissertation	NOUN
v405s754q1d	13	12	set	set	VERB
v405s754q1d	13	13	the	the	DET
v405s754q1d	13	14	ground	ground	NOUN
v405s754q1d	13	15	work	work	NOUN
v405s754q1d	13	16	for	for	ADP
v405s754q1d	13	17	application	application	NOUN
v405s754q1d	13	18	to	to	ADP
v405s754q1d	13	19	a	a	DET
v405s754q1d	13	20	broad	broad	ADJ
v405s754q1d	13	21	spectrum	spectrum	NOUN
v405s754q1d	13	22	of	of	ADP
v405s754q1d	13	23	biological	biological	ADJ
v405s754q1d	13	24	investigations	investigation	NOUN
v405s754q1d	13	25	involving	involve	VERB
v405s754q1d	13	26	carbohydrate	carbohydrate	NOUN
v405s754q1d	13	27	structure	structure	NOUN
v405s754q1d	13	28	and	and	CCONJ
v405s754q1d	13	29	function	function	NOUN
v405s754q1d	13	30	.	.	PUNCT