id	sid	tid	token	lemma	pos
td96k071q2h	1	1	the	the	DET
td96k071q2h	1	2	state	state	NOUN
td96k071q2h	1	3	of	of	ADP
td96k071q2h	1	4	the	the	DET
td96k071q2h	1	5	catalytic	catalytic	ADJ
td96k071q2h	1	6	surface	surface	NOUN
td96k071q2h	1	7	during	during	ADP
td96k071q2h	1	8	oxidation	oxidation	NOUN
td96k071q2h	1	9	reactions	reaction	NOUN
td96k071q2h	1	10	on	on	ADP
td96k071q2h	1	11	supported	support	VERB
td96k071q2h	1	12	pt	pt	PROPN
td96k071q2h	1	13	catalysts	catalyst	NOUN
td96k071q2h	1	14	has	have	AUX
td96k071q2h	1	15	been	be	AUX
td96k071q2h	1	16	investigated	investigate	VERB
td96k071q2h	1	17	by	by	ADP
td96k071q2h	1	18	kinetic	kinetic	ADJ
td96k071q2h	1	19	studies	study	NOUN
td96k071q2h	1	20	and	and	CCONJ
td96k071q2h	1	21	in	in	ADP
td96k071q2h	1	22	-	-	PUNCT
td96k071q2h	1	23	situ	situ	NOUN
td96k071q2h	1	24	infrared	infrared	ADJ
td96k071q2h	1	25	(	(	PUNCT
td96k071q2h	1	26	ir	ir	NOUN
td96k071q2h	1	27	)	)	PUNCT
td96k071q2h	1	28	and	and	CCONJ
td96k071q2h	1	29	extended	extend	VERB
td96k071q2h	2	1	x	x	ADJ
td96k071q2h	2	2	-	-	NOUN
td96k071q2h	2	3	ray	ray	NOUN
td96k071q2h	2	4	absorption	absorption	NOUN
td96k071q2h	2	5	fine	fine	ADJ
td96k071q2h	2	6	structure	structure	NOUN
td96k071q2h	2	7	(	(	PUNCT
td96k071q2h	2	8	exafs	exafs	PROPN
td96k071q2h	2	9	)	)	PUNCT
td96k071q2h	2	10	spectroscopies	spectroscopy	NOUN
td96k071q2h	2	11	.	.	PUNCT
td96k071q2h	3	1	the	the	DET
td96k071q2h	3	2	results	result	NOUN
td96k071q2h	3	3	of	of	ADP
td96k071q2h	3	4	this	this	DET
td96k071q2h	3	5	work	work	NOUN
td96k071q2h	3	6	show	show	VERB
td96k071q2h	3	7	the	the	DET
td96k071q2h	3	8	effect	effect	NOUN
td96k071q2h	3	9	of	of	ADP
td96k071q2h	3	10	the	the	DET
td96k071q2h	3	11	preparation	preparation	NOUN
td96k071q2h	3	12	method	method	NOUN
td96k071q2h	3	13	,	,	PUNCT
td96k071q2h	3	14	the	the	DET
td96k071q2h	3	15	pretreatment	pretreatment	NOUN
td96k071q2h	3	16	,	,	PUNCT
td96k071q2h	3	17	and	and	CCONJ
td96k071q2h	3	18	most	most	ADV
td96k071q2h	3	19	significantly	significantly	ADV
td96k071q2h	3	20	of	of	ADP
td96k071q2h	3	21	the	the	DET
td96k071q2h	3	22	reaction	reaction	NOUN
td96k071q2h	3	23	atmosphere	atmosphere	NOUN
td96k071q2h	3	24	on	on	ADP
td96k071q2h	3	25	the	the	DET
td96k071q2h	3	26	co	co	NOUN
td96k071q2h	3	27	oxidation	oxidation	NOUN
td96k071q2h	3	28	activity	activity	NOUN
td96k071q2h	3	29	.	.	PUNCT
td96k071q2h	4	1	experimental	experimental	ADJ
td96k071q2h	4	2	data	datum	NOUN
td96k071q2h	4	3	are	be	AUX
td96k071q2h	4	4	compared	compare	VERB
td96k071q2h	4	5	with	with	ADP
td96k071q2h	4	6	theoretical	theoretical	ADJ
td96k071q2h	4	7	results	result	NOUN
td96k071q2h	4	8	obtained	obtain	VERB
td96k071q2h	4	9	with	with	ADP
td96k071q2h	4	10	dynamic	dynamic	PROPN
td96k071q2h	4	11	monte	monte	PROPN
td96k071q2h	4	12	carlo	carlo	PROPN
td96k071q2h	4	13	(	(	PUNCT
td96k071q2h	4	14	dmc	dmc	PROPN
td96k071q2h	4	15	)	)	PUNCT
td96k071q2h	4	16	simulations	simulation	NOUN
td96k071q2h	4	17	.	.	PUNCT
td96k071q2h	5	1	kinetic	kinetic	ADJ
td96k071q2h	5	2	results	result	NOUN
td96k071q2h	5	3	indicate	indicate	VERB
td96k071q2h	5	4	that	that	SCONJ
td96k071q2h	5	5	,	,	PUNCT
td96k071q2h	5	6	under	under	ADP
td96k071q2h	5	7	oxidizing	oxidize	VERB
td96k071q2h	5	8	conditions	condition	NOUN
td96k071q2h	5	9	,	,	PUNCT
td96k071q2h	5	10	the	the	DET
td96k071q2h	5	11	specific	specific	ADJ
td96k071q2h	5	12	rate	rate	NOUN
td96k071q2h	5	13	of	of	ADP
td96k071q2h	5	14	co	co	NOUN
td96k071q2h	5	15	oxidation	oxidation	NOUN
td96k071q2h	5	16	on	on	ADP
td96k071q2h	5	17	pt	pt	PROPN
td96k071q2h	5	18	/	/	SYM
td96k071q2h	5	19	sio2	sio2	PROPN
td96k071q2h	5	20	catalysts	catalyst	NOUN
td96k071q2h	5	21	increases	increase	VERB
td96k071q2h	5	22	with	with	ADP
td96k071q2h	5	23	increasing	increase	VERB
td96k071q2h	5	24	particle	particle	NOUN
td96k071q2h	5	25	size	size	NOUN
td96k071q2h	5	26	.	.	PUNCT
td96k071q2h	6	1	dmc	dmc	PROPN
td96k071q2h	6	2	simulation	simulation	PROPN
td96k071q2h	6	3	results	result	NOUN
td96k071q2h	6	4	suggest	suggest	VERB
td96k071q2h	6	5	that	that	SCONJ
td96k071q2h	6	6	these	these	DET
td96k071q2h	6	7	differences	difference	NOUN
td96k071q2h	6	8	are	be	AUX
td96k071q2h	6	9	due	due	ADJ
td96k071q2h	6	10	to	to	ADP
td96k071q2h	6	11	the	the	DET
td96k071q2h	6	12	variation	variation	NOUN
td96k071q2h	6	13	on	on	ADP
td96k071q2h	6	14	the	the	DET
td96k071q2h	6	15	activity	activity	NOUN
td96k071q2h	6	16	of	of	ADP
td96k071q2h	6	17	the	the	DET
td96k071q2h	6	18	various	various	ADJ
td96k071q2h	6	19	types	type	NOUN
td96k071q2h	6	20	of	of	ADP
td96k071q2h	6	21	sites	site	NOUN
td96k071q2h	6	22	present	present	ADJ
td96k071q2h	6	23	in	in	ADP
td96k071q2h	6	24	a	a	DET
td96k071q2h	6	25	crystallite	crystallite	NOUN
td96k071q2h	6	26	.	.	PUNCT
td96k071q2h	7	1	ir	ir	NOUN
td96k071q2h	7	2	results	result	NOUN
td96k071q2h	7	3	clearly	clearly	ADV
td96k071q2h	7	4	show	show	VERB
td96k071q2h	7	5	that	that	SCONJ
td96k071q2h	7	6	the	the	DET
td96k071q2h	7	7	active	active	ADJ
td96k071q2h	7	8	surface	surface	NOUN
td96k071q2h	7	9	of	of	ADP
td96k071q2h	7	10	pt	pt	PROPN
td96k071q2h	7	11	/	/	SYM
td96k071q2h	7	12	sio2	sio2	PROPN
td96k071q2h	7	13	catalysts	catalyst	NOUN
td96k071q2h	7	14	during	during	ADP
td96k071q2h	7	15	co	co	NOUN
td96k071q2h	7	16	oxidation	oxidation	NOUN
td96k071q2h	7	17	is	be	AUX
td96k071q2h	7	18	the	the	DET
td96k071q2h	7	19	metallic	metallic	ADJ
td96k071q2h	7	20	pt	pt	PROPN
td96k071q2h	7	21	.	.	PUNCT
td96k071q2h	8	1	the	the	DET
td96k071q2h	8	2	presence	presence	NOUN
td96k071q2h	8	3	of	of	ADP
td96k071q2h	8	4	residual	residual	ADJ
td96k071q2h	8	5	cl	cl	PROPN
td96k071q2h	8	6	on	on	ADP
td96k071q2h	8	7	pt	pt	PROPN
td96k071q2h	8	8	/	/	SYM
td96k071q2h	8	9	al2o3	al2o3	PROPN
td96k071q2h	8	10	and	and	CCONJ
td96k071q2h	8	11	pt	pt	PROPN
td96k071q2h	8	12	/	/	SYM
td96k071q2h	8	13	sio2	sio2	PROPN
td96k071q2h	8	14	catalysts	catalyst	NOUN
td96k071q2h	8	15	affects	affect	VERB
td96k071q2h	8	16	their	their	PRON
td96k071q2h	8	17	activity	activity	NOUN
td96k071q2h	8	18	during	during	ADP
td96k071q2h	8	19	co	co	NOUN
td96k071q2h	8	20	,	,	PUNCT
td96k071q2h	8	21	methane	methane	NOUN
td96k071q2h	8	22	and	and	CCONJ
td96k071q2h	8	23	ethane	ethane	NOUN
td96k071q2h	8	24	oxidation	oxidation	NOUN
td96k071q2h	8	25	.	.	PUNCT
td96k071q2h	9	1	on	on	ADP
td96k071q2h	9	2	the	the	DET
td96k071q2h	9	3	cl	cl	NOUN
td96k071q2h	9	4	-	-	PUNCT
td96k071q2h	9	5	containing	contain	VERB
td96k071q2h	9	6	catalyst	catalyst	NOUN
td96k071q2h	9	7	,	,	PUNCT
td96k071q2h	9	8	pt	pt	PROPN
td96k071q2h	9	9	-	-	PUNCT
td96k071q2h	9	10	cl	cl	PROPN
td96k071q2h	9	11	as	as	ADV
td96k071q2h	9	12	well	well	ADV
td96k071q2h	9	13	as	as	ADP
td96k071q2h	9	14	pt	pt	PROPN
td96k071q2h	9	15	-	-	PUNCT
td96k071q2h	9	16	pt	pt	PROPN
td96k071q2h	9	17	and	and	CCONJ
td96k071q2h	9	18	pt	pt	PROPN
td96k071q2h	9	19	-	-	PUNCT
td96k071q2h	9	20	o	o	PROPN
td96k071q2h	9	21	bonds	bond	NOUN
td96k071q2h	9	22	were	be	AUX
td96k071q2h	9	23	detected	detect	VERB
td96k071q2h	9	24	using	use	VERB
td96k071q2h	9	25	exafs	exafs	PROPN
td96k071q2h	9	26	.	.	PUNCT
td96k071q2h	10	1	this	this	DET
td96k071q2h	10	2	catalyst	catalyst	NOUN
td96k071q2h	10	3	,	,	PUNCT
td96k071q2h	10	4	however	however	ADV
td96k071q2h	10	5	,	,	PUNCT
td96k071q2h	10	6	does	do	AUX
td96k071q2h	10	7	not	not	PART
td96k071q2h	10	8	chemisorb	chemisorb	VERB
td96k071q2h	10	9	co	co	PROPN
td96k071q2h	10	10	,	,	PUNCT
td96k071q2h	10	11	indicating	indicate	VERB
td96k071q2h	10	12	that	that	SCONJ
td96k071q2h	10	13	there	there	PRON
td96k071q2h	10	14	are	be	VERB
td96k071q2h	10	15	no	no	DET
td96k071q2h	10	16	reduced	reduced	ADJ
td96k071q2h	10	17	surface	surface	NOUN
td96k071q2h	10	18	pt	pt	PROPN
td96k071q2h	10	19	atoms	atom	NOUN
td96k071q2h	10	20	.	.	PUNCT
td96k071q2h	11	1	ir	ir	PROPN
td96k071q2h	11	2	results	result	NOUN
td96k071q2h	11	3	show	show	VERB
td96k071q2h	11	4	that	that	SCONJ
td96k071q2h	11	5	chlorine	chlorine	NOUN
td96k071q2h	11	6	significantly	significantly	ADV
td96k071q2h	11	7	reduces	reduce	VERB
td96k071q2h	11	8	the	the	DET
td96k071q2h	11	9	amount	amount	NOUN
td96k071q2h	11	10	of	of	ADP
td96k071q2h	11	11	co	co	NOUN
td96k071q2h	11	12	adsorbed	adsorb	VERB
td96k071q2h	11	13	on	on	ADP
td96k071q2h	11	14	metallic	metallic	ADJ
td96k071q2h	11	15	pt	pt	PROPN
td96k071q2h	11	16	sites	site	NOUN
td96k071q2h	11	17	.	.	PUNCT
td96k071q2h	12	1	the	the	DET
td96k071q2h	12	2	mechanism	mechanism	NOUN
td96k071q2h	12	3	of	of	ADP
td96k071q2h	12	4	chlorine	chlorine	NOUN
td96k071q2h	12	5	poisoning	poisoning	NOUN
td96k071q2h	12	6	occurs	occur	VERB
td96k071q2h	12	7	mainly	mainly	ADV
td96k071q2h	12	8	by	by	ADP
td96k071q2h	12	9	site	site	NOUN
td96k071q2h	12	10	blocking	blocking	NOUN
td96k071q2h	12	11	.	.	PUNCT
td96k071q2h	13	1	the	the	DET
td96k071q2h	13	2	state	state	NOUN
td96k071q2h	13	3	of	of	ADP
td96k071q2h	13	4	the	the	DET
td96k071q2h	13	5	working	work	VERB
td96k071q2h	13	6	surface	surface	NOUN
td96k071q2h	13	7	of	of	ADP
td96k071q2h	13	8	pt	pt	PROPN
td96k071q2h	13	9	/	/	SYM
td96k071q2h	13	10	sio2	sio2	PROPN
td96k071q2h	13	11	and	and	CCONJ
td96k071q2h	13	12	pt	pt	PROPN
td96k071q2h	13	13	/	/	SYM
td96k071q2h	13	14	al2o3	al2o3	NOUN
td96k071q2h	13	15	catalysts	catalyst	NOUN
td96k071q2h	13	16	were	be	AUX
td96k071q2h	13	17	also	also	ADV
td96k071q2h	13	18	studied	study	VERB
td96k071q2h	13	19	in	in	ADP
td96k071q2h	13	20	the	the	DET
td96k071q2h	13	21	presence	presence	NOUN
td96k071q2h	13	22	of	of	ADP
td96k071q2h	13	23	sulfur	sulfur	NOUN
td96k071q2h	13	24	.	.	PUNCT
td96k071q2h	14	1	the	the	DET
td96k071q2h	14	2	activity	activity	NOUN
td96k071q2h	14	3	results	result	NOUN
td96k071q2h	14	4	show	show	VERB
td96k071q2h	14	5	that	that	SCONJ
td96k071q2h	14	6	the	the	DET
td96k071q2h	14	7	light	light	ADJ
td96k071q2h	14	8	-	-	PUNCT
td96k071q2h	14	9	off	off	ADP
td96k071q2h	14	10	temperature	temperature	NOUN
td96k071q2h	14	11	for	for	ADP
td96k071q2h	14	12	co	co	NOUN
td96k071q2h	14	13	oxidation	oxidation	NOUN
td96k071q2h	14	14	increases	increase	NOUN
td96k071q2h	14	15	with	with	ADP
td96k071q2h	14	16	ex	ex	ADJ
td96k071q2h	14	17	-	-	ADJ
td96k071q2h	14	18	situ	situ	ADJ
td96k071q2h	14	19	h2s	h2s	ADJ
td96k071q2h	14	20	addition	addition	NOUN
td96k071q2h	14	21	.	.	PUNCT
td96k071q2h	15	1	in	in	ADP
td96k071q2h	15	2	-	-	PUNCT
td96k071q2h	15	3	situ	situ	NOUN
td96k071q2h	15	4	ir	ir	NOUN
td96k071q2h	15	5	results	result	NOUN
td96k071q2h	15	6	show	show	VERB
td96k071q2h	15	7	a	a	DET
td96k071q2h	15	8	shift	shift	NOUN
td96k071q2h	15	9	of	of	ADP
td96k071q2h	15	10	the	the	DET
td96k071q2h	15	11	linear	linear	PROPN
td96k071q2h	15	12	co	co	NOUN
td96k071q2h	15	13	band	band	NOUN
td96k071q2h	15	14	indicating	indicate	VERB
td96k071q2h	15	15	a	a	DET
td96k071q2h	15	16	change	change	NOUN
td96k071q2h	15	17	in	in	ADP
td96k071q2h	15	18	the	the	DET
td96k071q2h	15	19	bonding	bonding	NOUN
td96k071q2h	15	20	of	of	ADP
td96k071q2h	15	21	adsorbed	adsorb	VERB
td96k071q2h	15	22	co	co	NOUN
td96k071q2h	15	23	due	due	ADP
td96k071q2h	15	24	to	to	ADP
td96k071q2h	15	25	the	the	DET
td96k071q2h	15	26	presence	presence	NOUN
td96k071q2h	15	27	of	of	ADP
td96k071q2h	15	28	sulfur	sulfur	NOUN
td96k071q2h	15	29	.	.	PUNCT
td96k071q2h	16	1	continuous	continuous	ADJ
td96k071q2h	16	2	addition	addition	NOUN
td96k071q2h	16	3	of	of	ADP
td96k071q2h	16	4	20	20	NUM
td96k071q2h	16	5	ppm	ppm	NOUN
td96k071q2h	16	6	of	of	ADP
td96k071q2h	16	7	so2	so2	NOUN
td96k071q2h	16	8	to	to	ADP
td96k071q2h	16	9	the	the	DET
td96k071q2h	16	10	reactant	reactant	ADJ
td96k071q2h	16	11	mixture	mixture	NOUN
td96k071q2h	16	12	also	also	ADV
td96k071q2h	16	13	increases	increase	VERB
td96k071q2h	16	14	the	the	DET
td96k071q2h	16	15	light	light	ADJ
td96k071q2h	16	16	-	-	PUNCT
td96k071q2h	16	17	off	off	ADP
td96k071q2h	16	18	temperature	temperature	NOUN
td96k071q2h	16	19	.	.	PUNCT
td96k071q2h	17	1	activity	activity	NOUN
td96k071q2h	17	2	and	and	CCONJ
td96k071q2h	17	3	ir	ir	PROPN
td96k071q2h	17	4	results	result	NOUN
td96k071q2h	17	5	demonstrate	demonstrate	VERB
td96k071q2h	17	6	that	that	SCONJ
td96k071q2h	17	7	alumina	alumina	PROPN
td96k071q2h	17	8	acts	act	VERB
td96k071q2h	17	9	as	as	ADP
td96k071q2h	17	10	a	a	DET
td96k071q2h	17	11	sulfur	sulfur	NOUN
td96k071q2h	17	12	storage	storage	NOUN
td96k071q2h	17	13	reservoir	reservoir	PROPN
td96k071q2h	17	14	.	.	PUNCT
td96k071q2h	18	1	this	this	PRON
td96k071q2h	18	2	delays	delay	VERB
td96k071q2h	18	3	the	the	DET
td96k071q2h	18	4	initial	initial	ADJ
td96k071q2h	18	5	deactivation	deactivation	NOUN
td96k071q2h	18	6	but	but	CCONJ
td96k071q2h	18	7	after	after	ADP
td96k071q2h	18	8	extended	extend	VERB
td96k071q2h	18	9	time	time	NOUN
td96k071q2h	18	10	on	on	ADP
td96k071q2h	18	11	stream	stream	NOUN
td96k071q2h	18	12	in	in	ADP
td96k071q2h	18	13	presence	presence	NOUN
td96k071q2h	18	14	of	of	ADP
td96k071q2h	18	15	so2	so2	NOUN
td96k071q2h	18	16	the	the	DET
td96k071q2h	18	17	activity	activity	NOUN
td96k071q2h	18	18	of	of	ADP
td96k071q2h	18	19	the	the	DET
td96k071q2h	18	20	silicaand	silicaand	PROPN
td96k071q2h	18	21	alumina	alumina	PROPN
td96k071q2h	18	22	-	-	PUNCT
td96k071q2h	18	23	supported	support	VERB
td96k071q2h	18	24	catalysts	catalyst	NOUN
td96k071q2h	18	25	is	be	AUX
td96k071q2h	18	26	similar	similar	ADJ
td96k071q2h	18	27	.	.	PUNCT
td96k071q2h	19	1	the	the	DET
td96k071q2h	19	2	results	result	NOUN
td96k071q2h	19	3	indicate	indicate	VERB
td96k071q2h	19	4	that	that	SCONJ
td96k071q2h	19	5	sulfur	sulfur	NOUN
td96k071q2h	19	6	poisoning	poisoning	NOUN
td96k071q2h	19	7	is	be	AUX
td96k071q2h	19	8	not	not	PART
td96k071q2h	19	9	only	only	ADV
td96k071q2h	19	10	due	due	ADJ
td96k071q2h	19	11	to	to	ADP
td96k071q2h	19	12	site	site	NOUN
td96k071q2h	19	13	blocking	blocking	NOUN
td96k071q2h	19	14	but	but	CCONJ
td96k071q2h	19	15	also	also	ADV
td96k071q2h	19	16	because	because	SCONJ
td96k071q2h	19	17	of	of	ADP
td96k071q2h	19	18	modification	modification	NOUN
td96k071q2h	19	19	of	of	ADP
td96k071q2h	19	20	the	the	DET
td96k071q2h	19	21	pt	pt	PROPN
td96k071q2h	19	22	-	-	PUNCT
td96k071q2h	19	23	co	co	NOUN
td96k071q2h	19	24	bonding	bonding	NOUN
td96k071q2h	19	25	.	.	PUNCT