id sid tid token lemma pos tb09j389j88 1 1 metallic metallic ADJ tb09j389j88 1 2 structures structure NOUN tb09j389j88 1 3 at at ADP tb09j389j88 1 4 the the DET tb09j389j88 1 5 nanoscale nanoscale ADJ tb09j389j88 1 6 exhibit exhibit NOUN tb09j389j88 1 7 numerous numerous ADJ tb09j389j88 1 8 properties property NOUN tb09j389j88 1 9 which which PRON tb09j389j88 1 10 enable enable VERB tb09j389j88 1 11 fascinating fascinating ADJ tb09j389j88 1 12 uses use NOUN tb09j389j88 1 13 . . PUNCT tb09j389j88 2 1 plasmonic plasmonic ADJ tb09j389j88 2 2 responses response NOUN tb09j389j88 2 3 , , PUNCT tb09j389j88 2 4 electromagnetic electromagnetic ADJ tb09j389j88 2 5 field field NOUN tb09j389j88 2 6 generation generation NOUN tb09j389j88 2 7 , , PUNCT tb09j389j88 2 8 chemical chemical NOUN tb09j389j88 2 9 sensing sensing NOUN tb09j389j88 2 10 and and CCONJ tb09j389j88 2 11 catalytic catalytic ADJ tb09j389j88 2 12 capabilities capability NOUN tb09j389j88 2 13 are be AUX tb09j389j88 2 14 facilitated facilitate VERB tb09j389j88 2 15 by by ADP tb09j389j88 2 16 the the DET tb09j389j88 2 17 appropriate appropriate ADJ tb09j389j88 2 18 implementation implementation NOUN tb09j389j88 2 19 of of ADP tb09j389j88 2 20 metallic metallic ADJ tb09j389j88 2 21 nanoparticles nanoparticle NOUN tb09j389j88 2 22 . . PUNCT tb09j389j88 3 1 these these DET tb09j389j88 3 2 properties property NOUN tb09j389j88 3 3 can can AUX tb09j389j88 3 4 be be AUX tb09j389j88 3 5 enhanced enhance VERB tb09j389j88 3 6 significantly significantly ADV tb09j389j88 3 7 by by ADP tb09j389j88 3 8 strategic strategic ADJ tb09j389j88 3 9 morphology morphology NOUN tb09j389j88 3 10 and and CCONJ tb09j389j88 3 11 placement placement NOUN tb09j389j88 3 12 control control NOUN tb09j389j88 3 13 ; ; PUNCT tb09j389j88 3 14 namely namely ADV tb09j389j88 3 15 selective selective ADJ tb09j389j88 3 16 faceting faceting NOUN tb09j389j88 3 17 , , PUNCT tb09j389j88 3 18 and and CCONJ tb09j389j88 3 19 nanogap nanogap ADJ tb09j389j88 3 20 formation formation NOUN tb09j389j88 3 21 . . PUNCT tb09j389j88 4 1 while while SCONJ tb09j389j88 4 2 colloidal colloidal ADJ tb09j389j88 4 3 syntheses synthesis NOUN tb09j389j88 4 4 have have AUX tb09j389j88 4 5 been be AUX tb09j389j88 4 6 explored explore VERB tb09j389j88 4 7 in in ADP tb09j389j88 4 8 great great ADJ tb09j389j88 4 9 detail detail NOUN tb09j389j88 4 10 throughout throughout ADP tb09j389j88 4 11 the the DET tb09j389j88 4 12 literature literature NOUN tb09j389j88 4 13 , , PUNCT tb09j389j88 4 14 providing provide VERB tb09j389j88 4 15 a a DET tb09j389j88 4 16 vast vast ADJ tb09j389j88 4 17 selection selection NOUN tb09j389j88 4 18 of of ADP tb09j389j88 4 19 available available ADJ tb09j389j88 4 20 morphologies morphology NOUN tb09j389j88 4 21 which which PRON tb09j389j88 4 22 enable enable VERB tb09j389j88 4 23 facet facet NOUN tb09j389j88 4 24 selection selection NOUN tb09j389j88 4 25 , , PUNCT tb09j389j88 4 26 controllable controllable ADJ tb09j389j88 4 27 placement placement NOUN tb09j389j88 4 28 of of ADP tb09j389j88 4 29 the the DET tb09j389j88 4 30 structures structure NOUN tb09j389j88 4 31 remains remain VERB tb09j389j88 4 32 challenging challenge VERB tb09j389j88 4 33 for for ADP tb09j389j88 4 34 colloidally colloidally ADV tb09j389j88 4 35 synthesized synthesized ADJ tb09j389j88 4 36 particles particle NOUN tb09j389j88 4 37 . . PUNCT tb09j389j88 5 1 conversely conversely ADV tb09j389j88 5 2 , , PUNCT tb09j389j88 5 3 substrate substrate NOUN tb09j389j88 5 4 - - PUNCT tb09j389j88 5 5 immobilized immobilize VERB tb09j389j88 5 6 structures structure NOUN tb09j389j88 5 7 such such ADJ tb09j389j88 5 8 as as ADP tb09j389j88 5 9 those those PRON tb09j389j88 5 10 achieved achieve VERB tb09j389j88 5 11 through through ADP tb09j389j88 5 12 thin thin ADJ tb09j389j88 5 13 film film NOUN tb09j389j88 5 14 dewetting dewette VERB tb09j389j88 5 15 can can AUX tb09j389j88 5 16 provide provide VERB tb09j389j88 5 17 excellent excellent ADJ tb09j389j88 5 18 placement placement NOUN tb09j389j88 5 19 capabilities capability NOUN tb09j389j88 5 20 , , PUNCT tb09j389j88 5 21 through through ADP tb09j389j88 5 22 lithography lithography NOUN tb09j389j88 5 23 processes process NOUN tb09j389j88 5 24 , , PUNCT tb09j389j88 5 25 though though SCONJ tb09j389j88 5 26 the the DET tb09j389j88 5 27 ability ability NOUN tb09j389j88 5 28 to to PART tb09j389j88 5 29 control control VERB tb09j389j88 5 30 morphology morphology NOUN tb09j389j88 5 31 remains remain VERB tb09j389j88 5 32 underdeveloped underdeveloped ADJ tb09j389j88 5 33 . . PUNCT tb09j389j88 6 1 even even ADV tb09j389j88 6 2 provided provide VERB tb09j389j88 6 3 acceptable acceptable ADJ tb09j389j88 6 4 syntheses synthesis NOUN tb09j389j88 6 5 , , PUNCT tb09j389j88 6 6 the the DET tb09j389j88 6 7 challenge challenge NOUN tb09j389j88 6 8 of of ADP tb09j389j88 6 9 preserving preserve VERB tb09j389j88 6 10 such such ADJ tb09j389j88 6 11 structures structure NOUN tb09j389j88 6 12 remains remain VERB tb09j389j88 6 13 , , PUNCT tb09j389j88 6 14 as as SCONJ tb09j389j88 6 15 material material ADJ tb09j389j88 6 16 properties property NOUN tb09j389j88 6 17 of of ADP tb09j389j88 6 18 nano nano NOUN tb09j389j88 6 19 - - PUNCT tb09j389j88 6 20 dimensioned dimension VERB tb09j389j88 6 21 structures structure NOUN tb09j389j88 6 22 differ differ VERB tb09j389j88 6 23 significantly significantly ADV tb09j389j88 6 24 from from ADP tb09j389j88 6 25 our our PRON tb09j389j88 6 26 understanding understanding NOUN tb09j389j88 6 27 of of ADP tb09j389j88 6 28 those those PRON tb09j389j88 6 29 in in ADP tb09j389j88 6 30 bulk bulk ADJ tb09j389j88 6 31 materials material NOUN tb09j389j88 6 32 . . PUNCT tb09j389j88 7 1 thermal thermal ADJ tb09j389j88 7 2 degradation degradation NOUN tb09j389j88 7 3 , , PUNCT tb09j389j88 7 4 as as ADV tb09j389j88 7 5 well well ADV tb09j389j88 7 6 as as ADP tb09j389j88 7 7 oxidation oxidation NOUN tb09j389j88 7 8 and and CCONJ tb09j389j88 7 9 other other ADJ tb09j389j88 7 10 chemical chemical ADJ tb09j389j88 7 11 reactions reaction NOUN tb09j389j88 7 12 tend tend VERB tb09j389j88 7 13 to to PART tb09j389j88 7 14 alter alter VERB tb09j389j88 7 15 the the DET tb09j389j88 7 16 nanostructures nanostructure NOUN tb09j389j88 7 17 much much ADV tb09j389j88 7 18 more more ADV tb09j389j88 7 19 significantly significantly ADV tb09j389j88 7 20 , , PUNCT tb09j389j88 7 21 rendering render VERB tb09j389j88 7 22 many many ADJ tb09j389j88 7 23 materials material NOUN tb09j389j88 7 24 unfeasible unfeasible ADJ tb09j389j88 7 25 for for ADP tb09j389j88 7 26 the the DET tb09j389j88 7 27 applications application NOUN tb09j389j88 7 28 for for ADP tb09j389j88 7 29 which which PRON tb09j389j88 7 30 they they PRON tb09j389j88 7 31 may may AUX tb09j389j88 7 32 otherwise otherwise ADV tb09j389j88 7 33 be be AUX tb09j389j88 7 34 selected select VERB tb09j389j88 7 35 . . PUNCT tb09j389j88 8 1 this this DET tb09j389j88 8 2 dissertation dissertation NOUN tb09j389j88 8 3 provides provide VERB tb09j389j88 8 4 means mean NOUN tb09j389j88 8 5 by by ADP tb09j389j88 8 6 which which PRON tb09j389j88 8 7 each each PRON tb09j389j88 8 8 of of ADP tb09j389j88 8 9 these these DET tb09j389j88 8 10 challenges challenge NOUN tb09j389j88 8 11 can can AUX tb09j389j88 8 12 be be AUX tb09j389j88 8 13 addressed.it addressed.it NUM tb09j389j88 8 14 is be AUX tb09j389j88 8 15 demonstrated demonstrate VERB tb09j389j88 8 16 that that SCONJ tb09j389j88 8 17 the the DET tb09j389j88 8 18 faceting faceting NOUN tb09j389j88 8 19 of of ADP tb09j389j88 8 20 dewetted dewette VERB tb09j389j88 8 21 metallic metallic ADJ tb09j389j88 8 22 structures structure NOUN tb09j389j88 8 23 can can AUX tb09j389j88 8 24 be be AUX tb09j389j88 8 25 enhanced enhance VERB tb09j389j88 8 26 by by ADP tb09j389j88 8 27 subjecting subject VERB tb09j389j88 8 28 them they PRON tb09j389j88 8 29 to to ADP tb09j389j88 8 30 a a DET tb09j389j88 8 31 liquid liquid ADJ tb09j389j88 8 32 - - PUNCT tb09j389j88 8 33 phase phase NOUN tb09j389j88 8 34 chemical chemical NOUN tb09j389j88 8 35 environment environment NOUN tb09j389j88 8 36 in in ADP tb09j389j88 8 37 which which PRON tb09j389j88 8 38 metal metal NOUN tb09j389j88 8 39 ions ion NOUN tb09j389j88 8 40 are be AUX tb09j389j88 8 41 reduced reduce VERB tb09j389j88 8 42 and and CCONJ tb09j389j88 8 43 deposited deposit VERB tb09j389j88 8 44 on on ADP tb09j389j88 8 45 the the DET tb09j389j88 8 46 nanostructure nanostructure ADJ tb09j389j88 8 47 surface surface NOUN tb09j389j88 8 48 in in ADP tb09j389j88 8 49 a a DET tb09j389j88 8 50 manner manner NOUN tb09j389j88 8 51 that that PRON tb09j389j88 8 52 leads lead VERB tb09j389j88 8 53 to to ADP tb09j389j88 8 54 facet facet NOUN tb09j389j88 8 55 formation formation NOUN tb09j389j88 8 56 . . PUNCT tb09j389j88 9 1 the the DET tb09j389j88 9 2 resultant resultant ADJ tb09j389j88 9 3 structures structure NOUN tb09j389j88 9 4 exhibit exhibit VERB tb09j389j88 9 5 sharper sharp ADJ tb09j389j88 9 6 corners corner NOUN tb09j389j88 9 7 which which PRON tb09j389j88 9 8 far far ADV tb09j389j88 9 9 surpass surpass VERB tb09j389j88 9 10 those those PRON tb09j389j88 9 11 which which PRON tb09j389j88 9 12 can can AUX tb09j389j88 9 13 be be AUX tb09j389j88 9 14 produced produce VERB tb09j389j88 9 15 by by ADP tb09j389j88 9 16 thermal thermal ADJ tb09j389j88 9 17 routes route NOUN tb09j389j88 9 18 alone alone ADV tb09j389j88 9 19 . . PUNCT tb09j389j88 10 1 the the DET tb09j389j88 10 2 faceting faceting NOUN tb09j389j88 10 3 procedure procedure NOUN tb09j389j88 10 4 , , PUNCT tb09j389j88 10 5 which which PRON tb09j389j88 10 6 can can AUX tb09j389j88 10 7 be be AUX tb09j389j88 10 8 carried carry VERB tb09j389j88 10 9 out out ADP tb09j389j88 10 10 in in ADP tb09j389j88 10 11 minutes minute NOUN tb09j389j88 10 12 , , PUNCT tb09j389j88 10 13 is be AUX tb09j389j88 10 14 also also ADV tb09j389j88 10 15 shown show VERB tb09j389j88 10 16 to to PART tb09j389j88 10 17 be be AUX tb09j389j88 10 18 amenable amenable ADJ tb09j389j88 10 19 to to ADP tb09j389j88 10 20 a a DET tb09j389j88 10 21 templated template VERB tb09j389j88 10 22 dewetting dewette VERB tb09j389j88 10 23 approach approach NOUN tb09j389j88 10 24 in in ADP tb09j389j88 10 25 which which PRON tb09j389j88 10 26 arrays array NOUN tb09j389j88 10 27 of of ADP tb09j389j88 10 28 lithographically lithographically ADV tb09j389j88 10 29 defined define VERB tb09j389j88 10 30 nanostructures nanostructure NOUN tb09j389j88 10 31 are be AUX tb09j389j88 10 32 formed form VERB tb09j389j88 10 33 . . PUNCT tb09j389j88 11 1 the the DET tb09j389j88 11 2 work work NOUN tb09j389j88 11 3 has have VERB tb09j389j88 11 4 the the DET tb09j389j88 11 5 potential potential NOUN tb09j389j88 11 6 to to PART tb09j389j88 11 7 increase increase VERB tb09j389j88 11 8 the the DET tb09j389j88 11 9 functionality functionality NOUN tb09j389j88 11 10 of of ADP tb09j389j88 11 11 dewetted dewette VERB tb09j389j88 11 12 nanostructures nanostructure NOUN tb09j389j88 11 13 by by ADP tb09j389j88 11 14 enabling enable VERB tb09j389j88 11 15 facet facet NOUN tb09j389j88 11 16 dependent dependent ADJ tb09j389j88 11 17 chemical chemical ADJ tb09j389j88 11 18 reactivity reactivity NOUN tb09j389j88 11 19 and and CCONJ tb09j389j88 11 20 enhanced enhanced ADJ tb09j389j88 11 21 plasmonic plasmonic ADJ tb09j389j88 11 22 hot hot ADJ tb09j389j88 11 23 spots.the spots.the DET tb09j389j88 11 24 functionality functionality NOUN tb09j389j88 11 25 of of ADP tb09j389j88 11 26 such such ADJ tb09j389j88 11 27 well well ADV tb09j389j88 11 28 - - PUNCT tb09j389j88 11 29 tailored tailor VERB tb09j389j88 11 30 nanomaterials nanomaterial NOUN tb09j389j88 11 31 can can AUX tb09j389j88 11 32 only only ADV tb09j389j88 11 33 be be AUX tb09j389j88 11 34 retained retain VERB tb09j389j88 11 35 if if SCONJ tb09j389j88 11 36 they they PRON tb09j389j88 11 37 are be AUX tb09j389j88 11 38 robust robust ADJ tb09j389j88 11 39 to to ADP tb09j389j88 11 40 the the DET tb09j389j88 11 41 environmental environmental ADJ tb09j389j88 11 42 factors factor NOUN tb09j389j88 11 43 in in ADP tb09j389j88 11 44 which which PRON tb09j389j88 11 45 they they PRON tb09j389j88 11 46 operate operate VERB tb09j389j88 11 47 . . PUNCT tb09j389j88 12 1 herein herein ADV tb09j389j88 12 2 , , PUNCT tb09j389j88 12 3 it it PRON tb09j389j88 12 4 is be AUX tb09j389j88 12 5 demonstrated demonstrate VERB tb09j389j88 12 6 that that SCONJ tb09j389j88 12 7 atomic atomic ADJ tb09j389j88 12 8 layer layer NOUN tb09j389j88 12 9 deposition deposition NOUN tb09j389j88 12 10 can can AUX tb09j389j88 12 11 be be AUX tb09j389j88 12 12 used use VERB tb09j389j88 12 13 as as ADP tb09j389j88 12 14 a a DET tb09j389j88 12 15 pliable pliable ADJ tb09j389j88 12 16 technique technique NOUN tb09j389j88 12 17 for for ADP tb09j389j88 12 18 the the DET tb09j389j88 12 19 application application NOUN tb09j389j88 12 20 of of ADP tb09j389j88 12 21 oxide oxide NOUN tb09j389j88 12 22 coatings coating NOUN tb09j389j88 12 23 to to ADP tb09j389j88 12 24 substrate substrate NOUN tb09j389j88 12 25 - - PUNCT tb09j389j88 12 26 based base VERB tb09j389j88 12 27 metallic metallic ADJ tb09j389j88 12 28 nanostructures nanostructure NOUN tb09j389j88 12 29 . . PUNCT tb09j389j88 13 1 emphasis emphasis NOUN tb09j389j88 13 2 is be AUX tb09j389j88 13 3 placed place VERB tb09j389j88 13 4 on on ADP tb09j389j88 13 5 cu cu PROPN tb09j389j88 13 6 , , PUNCT tb09j389j88 13 7 which which PRON tb09j389j88 13 8 is be AUX tb09j389j88 13 9 typically typically ADV tb09j389j88 13 10 rejected reject VERB tb09j389j88 13 11 as as ADP tb09j389j88 13 12 a a DET tb09j389j88 13 13 feasible feasible ADJ tb09j389j88 13 14 material material NOUN tb09j389j88 13 15 despite despite SCONJ tb09j389j88 13 16 having have VERB tb09j389j88 13 17 favorable favorable ADJ tb09j389j88 13 18 plasmonic plasmonic ADJ tb09j389j88 13 19 and and CCONJ tb09j389j88 13 20 electronic electronic ADJ tb09j389j88 13 21 properties property NOUN tb09j389j88 13 22 at at ADP tb09j389j88 13 23 low low ADJ tb09j389j88 13 24 cost cost NOUN tb09j389j88 13 25 . . PUNCT tb09j389j88 14 1 it it PRON tb09j389j88 14 2 is be AUX tb09j389j88 14 3 shown show VERB tb09j389j88 14 4 that that SCONJ tb09j389j88 14 5 suitably suitably ADV tb09j389j88 14 6 protected protect VERB tb09j389j88 14 7 structures structure NOUN tb09j389j88 14 8 become become VERB tb09j389j88 14 9 robust robust ADJ tb09j389j88 14 10 to to ADP tb09j389j88 14 11 oxidation oxidation NOUN tb09j389j88 14 12 , , PUNCT tb09j389j88 14 13 high high ADJ tb09j389j88 14 14 temperatures temperature NOUN tb09j389j88 14 15 , , PUNCT tb09j389j88 14 16 and and CCONJ tb09j389j88 14 17 aqueous aqueous ADJ tb09j389j88 14 18 , , PUNCT tb09j389j88 14 19 acidic acidic ADJ tb09j389j88 14 20 , , PUNCT tb09j389j88 14 21 and and CCONJ tb09j389j88 14 22 alkaline alkaline NOUN tb09j389j88 14 23 solutions solution NOUN tb09j389j88 14 24 without without ADP tb09j389j88 14 25 unduly unduly ADV tb09j389j88 14 26 influencing influence VERB tb09j389j88 14 27 important important ADJ tb09j389j88 14 28 plasmonic plasmonic ADJ tb09j389j88 14 29 properties property NOUN tb09j389j88 14 30 . . PUNCT tb09j389j88 15 1 moreover moreover ADV tb09j389j88 15 2 , , PUNCT tb09j389j88 15 3 strategies strategy NOUN tb09j389j88 15 4 are be AUX tb09j389j88 15 5 presented present VERB tb09j389j88 15 6 for for ADP tb09j389j88 15 7 maximizing maximize VERB tb09j389j88 15 8 plasmonic plasmonic NOUN tb09j389j88 15 9 near near ADP tb09j389j88 15 10 - - PUNCT tb09j389j88 15 11 fields field NOUN tb09j389j88 15 12 and and CCONJ tb09j389j88 15 13 allowing allow VERB tb09j389j88 15 14 for for ADP tb09j389j88 15 15 the the DET tb09j389j88 15 16 transport transport NOUN tb09j389j88 15 17 of of ADP tb09j389j88 15 18 hot hot ADJ tb09j389j88 15 19 electrons electron NOUN tb09j389j88 15 20 while while SCONJ tb09j389j88 15 21 maintaining maintain VERB tb09j389j88 15 22 coating coating NOUN tb09j389j88 15 23 integrity integrity NOUN tb09j389j88 15 24 . . PUNCT tb09j389j88 16 1 within within ADP tb09j389j88 16 2 the the DET tb09j389j88 16 3 scope scope NOUN tb09j389j88 16 4 of of ADP tb09j389j88 16 5 the the DET tb09j389j88 16 6 investigation investigation NOUN tb09j389j88 16 7 , , PUNCT tb09j389j88 16 8 alumina alumina PROPN tb09j389j88 16 9 , , PUNCT tb09j389j88 16 10 hafnia hafnia PROPN tb09j389j88 16 11 , , PUNCT tb09j389j88 16 12 titania titania PROPN tb09j389j88 16 13 , , PUNCT tb09j389j88 16 14 and and CCONJ tb09j389j88 16 15 combinations combination NOUN tb09j389j88 16 16 thereof thereof ADV tb09j389j88 16 17 are be AUX tb09j389j88 16 18 all all PRON tb09j389j88 16 19 shown show VERB tb09j389j88 16 20 to to PART tb09j389j88 16 21 be be AUX tb09j389j88 16 22 effective effective ADJ tb09j389j88 16 23 under under ADP tb09j389j88 16 24 certain certain ADJ tb09j389j88 16 25 conditions condition NOUN tb09j389j88 16 26 , , PUNCT tb09j389j88 16 27 but but CCONJ tb09j389j88 16 28 where where SCONJ tb09j389j88 16 29 hafnia hafnia PROPN tb09j389j88 16 30 shows show VERB tb09j389j88 16 31 the the DET tb09j389j88 16 32 greatest great ADJ tb09j389j88 16 33 durability durability NOUN tb09j389j88 16 34 in in ADP tb09j389j88 16 35 extreme extreme ADJ tb09j389j88 16 36 ph ph NOUN tb09j389j88 16 37 environments environment NOUN tb09j389j88 16 38 , , PUNCT tb09j389j88 16 39 enabling enable VERB tb09j389j88 16 40 lspr lspr ADJ tb09j389j88 16 41 preservation preservation NOUN tb09j389j88 16 42 for for ADP tb09j389j88 16 43 over over ADP tb09j389j88 16 44 100 100 NUM tb09j389j88 16 45 days day NOUN tb09j389j88 16 46 in in ADP tb09j389j88 16 47 1 1 NUM tb09j389j88 16 48 m m NOUN tb09j389j88 16 49 hno3 hno3 ADJ tb09j389j88 16 50 or or CCONJ tb09j389j88 16 51 naoh naoh NOUN tb09j389j88 16 52 . . PUNCT tb09j389j88 17 1 alumina alumina PROPN tb09j389j88 17 2 - - PUNCT tb09j389j88 17 3 hafnia hafnia PROPN tb09j389j88 17 4 laminates laminate NOUN tb09j389j88 17 5 provide provide VERB tb09j389j88 17 6 optimal optimal ADJ tb09j389j88 17 7 thermal thermal ADJ tb09j389j88 17 8 protection protection NOUN tb09j389j88 17 9 against against ADP tb09j389j88 17 10 oxidation oxidation NOUN tb09j389j88 17 11 and and CCONJ tb09j389j88 17 12 morphology morphology NOUN tb09j389j88 17 13 altering alter VERB tb09j389j88 17 14 surface surface NOUN tb09j389j88 17 15 diffusion diffusion NOUN tb09j389j88 17 16 , , PUNCT tb09j389j88 17 17 to to SCONJ tb09j389j88 17 18 temperatures temperature NOUN tb09j389j88 17 19 as as ADV tb09j389j88 17 20 high high ADJ tb09j389j88 17 21 as as ADP tb09j389j88 17 22 600 600 NUM tb09j389j88 17 23 ° ° NOUN tb09j389j88 17 24 c.strategic c.strategic ADJ tb09j389j88 17 25 application application NOUN tb09j389j88 17 26 and and CCONJ tb09j389j88 17 27 removal removal NOUN tb09j389j88 17 28 of of ADP tb09j389j88 17 29 ald ald PROPN tb09j389j88 17 30 alumina alumina PROPN tb09j389j88 17 31 is be AUX tb09j389j88 17 32 then then ADV tb09j389j88 17 33 used use VERB tb09j389j88 17 34 to to PART tb09j389j88 17 35 facilitate facilitate VERB tb09j389j88 17 36 the the DET tb09j389j88 17 37 synthesis synthesis NOUN tb09j389j88 17 38 of of ADP tb09j389j88 17 39 advanced advanced ADJ tb09j389j88 17 40 nanogap nanogap ADJ tb09j389j88 17 41 structures structure NOUN tb09j389j88 17 42 . . PUNCT tb09j389j88 18 1 the the DET tb09j389j88 18 2 fabrication fabrication NOUN tb09j389j88 18 3 method method NOUN tb09j389j88 18 4 enables enable VERB tb09j389j88 18 5 an an DET tb09j389j88 18 6 easily easily ADV tb09j389j88 18 7 tunable tunable ADJ tb09j389j88 18 8 nanogap nanogap PROPN tb09j389j88 18 9 width width NOUN tb09j389j88 18 10 , , PUNCT tb09j389j88 18 11 at at ADP tb09j389j88 18 12 angstrom angstrom PROPN tb09j389j88 18 13 level level NOUN tb09j389j88 18 14 precision precision NOUN tb09j389j88 18 15 . . PUNCT tb09j389j88 19 1 the the DET tb09j389j88 19 2 resultant resultant ADJ tb09j389j88 19 3 trimer trimer NOUN tb09j389j88 19 4 structures structure NOUN tb09j389j88 19 5 form form NOUN tb09j389j88 19 6 parallel parallel ADJ tb09j389j88 19 7 to to ADP tb09j389j88 19 8 the the DET tb09j389j88 19 9 substrate substrate NOUN tb09j389j88 19 10 and and CCONJ tb09j389j88 19 11 show show VERB tb09j389j88 19 12 preferred preferred ADJ tb09j389j88 19 13 alignment alignment NOUN tb09j389j88 19 14 , , PUNCT tb09j389j88 19 15 which which PRON tb09j389j88 19 16 enables enable VERB tb09j389j88 19 17 optimal optimal ADJ tb09j389j88 19 18 coupling coupling NOUN tb09j389j88 19 19 under under ADP tb09j389j88 19 20 surface surface NOUN tb09j389j88 19 21 - - PUNCT tb09j389j88 19 22 normal normal ADJ tb09j389j88 19 23 light light NOUN tb09j389j88 19 24 , , PUNCT tb09j389j88 19 25 and and CCONJ tb09j389j88 19 26 polarization polarization VERB tb09j389j88 19 27 dependent dependent ADJ tb09j389j88 19 28 lspr lspr ADJ tb09j389j88 19 29 spectra spectra NOUN tb09j389j88 19 30 , , PUNCT tb09j389j88 19 31 which which PRON tb09j389j88 19 32 are be AUX tb09j389j88 19 33 of of ADP tb09j389j88 19 34 importance importance NOUN tb09j389j88 19 35 to to ADP tb09j389j88 19 36 various various ADJ tb09j389j88 19 37 optical optical ADJ tb09j389j88 19 38 sensing sense VERB tb09j389j88 19 39 modalities modality NOUN tb09j389j88 19 40 . . PUNCT tb09j389j88 20 1 the the DET tb09j389j88 20 2 trimer trimer NOUN tb09j389j88 20 3 geometry geometry NOUN tb09j389j88 20 4 enables enable VERB tb09j389j88 20 5 high high ADJ tb09j389j88 20 6 density density NOUN tb09j389j88 20 7 of of ADP tb09j389j88 20 8 nanogaps nanogap NOUN tb09j389j88 20 9 on on ADP tb09j389j88 20 10 the the DET tb09j389j88 20 11 substrate substrate NOUN tb09j389j88 20 12 , , PUNCT tb09j389j88 20 13 at at ADP tb09j389j88 20 14 4.9 4.9 NUM tb09j389j88 20 15 billion billion NUM tb09j389j88 20 16 gaps gap NOUN tb09j389j88 20 17 per per ADP tb09j389j88 20 18 square square ADJ tb09j389j88 20 19 centimeter centimeter NOUN tb09j389j88 20 20 , , PUNCT tb09j389j88 20 21 a a DET tb09j389j88 20 22 feature feature NOUN tb09j389j88 20 23 of of ADP tb09j389j88 20 24 great great ADJ tb09j389j88 20 25 importance importance NOUN tb09j389j88 20 26 to to ADP tb09j389j88 20 27 photocatalysis photocatalysis NOUN tb09j389j88 20 28 and and CCONJ tb09j389j88 20 29 sers ser NOUN tb09j389j88 20 30 . . PUNCT tb09j389j88 21 1 the the DET tb09j389j88 21 2 superior superior ADJ tb09j389j88 21 3 crystallinity crystallinity NOUN tb09j389j88 21 4 of of ADP tb09j389j88 21 5 these these DET tb09j389j88 21 6 trimer trimer NOUN tb09j389j88 21 7 structures structure NOUN tb09j389j88 21 8 is be AUX tb09j389j88 21 9 also also ADV tb09j389j88 21 10 notable notable ADJ tb09j389j88 21 11 , , PUNCT tb09j389j88 21 12 as as SCONJ tb09j389j88 21 13 many many ADJ tb09j389j88 21 14 other other ADJ tb09j389j88 21 15 nanogap nanogap NOUN tb09j389j88 21 16 syntheses synthesis NOUN tb09j389j88 21 17 produce produce VERB tb09j389j88 21 18 only only ADV tb09j389j88 21 19 polycrystalline polycrystalline NOUN tb09j389j88 21 20 structures.the structures.the DET tb09j389j88 21 21 combined combine VERB tb09j389j88 21 22 scientific scientific ADJ tb09j389j88 21 23 achievements achievement NOUN tb09j389j88 21 24 demonstrated demonstrate VERB tb09j389j88 21 25 in in ADP tb09j389j88 21 26 this this DET tb09j389j88 21 27 dissertation dissertation NOUN tb09j389j88 21 28 serve serve VERB tb09j389j88 21 29 to to PART tb09j389j88 21 30 further further VERB tb09j389j88 21 31 the the DET tb09j389j88 21 32 capabilities capability NOUN tb09j389j88 21 33 of of ADP tb09j389j88 21 34 nanoparticles nanoparticle NOUN tb09j389j88 21 35 for for ADP tb09j389j88 21 36 real real ADJ tb09j389j88 21 37 - - PUNCT tb09j389j88 21 38 world world NOUN tb09j389j88 21 39 applications application NOUN tb09j389j88 21 40 : : PUNCT tb09j389j88 21 41 greater great ADJ tb09j389j88 21 42 morphology morphology NOUN tb09j389j88 21 43 control control NOUN tb09j389j88 21 44 over over ADP tb09j389j88 21 45 substrate substrate NOUN tb09j389j88 21 46 - - PUNCT tb09j389j88 21 47 immobilized immobilize VERB tb09j389j88 21 48 nanostructures nanostructure NOUN tb09j389j88 21 49 , , PUNCT tb09j389j88 21 50 preservation preservation NOUN tb09j389j88 21 51 of of ADP tb09j389j88 21 52 the the DET tb09j389j88 21 53 shape shape NOUN tb09j389j88 21 54 - - PUNCT tb09j389j88 21 55 engineered engineer VERB tb09j389j88 21 56 structures structure NOUN tb09j389j88 21 57 , , PUNCT tb09j389j88 21 58 and and CCONJ tb09j389j88 21 59 advanced advanced ADJ tb09j389j88 21 60 synthesis synthesis NOUN tb09j389j88 21 61 methods method NOUN tb09j389j88 21 62 are be AUX tb09j389j88 21 63 developed develop VERB tb09j389j88 21 64 , , PUNCT tb09j389j88 21 65 each each PRON tb09j389j88 21 66 of of ADP tb09j389j88 21 67 which which PRON tb09j389j88 21 68 may may AUX tb09j389j88 21 69 serve serve VERB tb09j389j88 21 70 independently independently ADV tb09j389j88 21 71 or or CCONJ tb09j389j88 21 72 in in ADP tb09j389j88 21 73 tandem tandem NOUN tb09j389j88 21 74 to to PART tb09j389j88 21 75 greatly greatly ADV tb09j389j88 21 76 advance advance VERB tb09j389j88 21 77 the the DET tb09j389j88 21 78 capabilities capability NOUN tb09j389j88 21 79 of of ADP tb09j389j88 21 80 applied apply VERB tb09j389j88 21 81 nanotechnology nanotechnology PROPN tb09j389j88 21 82 . . PUNCT