id sid tid token lemma pos tb09j388n2v 1 1 the the DET tb09j388n2v 1 2 improvement improvement NOUN tb09j388n2v 1 3 and and CCONJ tb09j388n2v 1 4 discovery discovery NOUN tb09j388n2v 1 5 of of ADP tb09j388n2v 1 6 new new ADJ tb09j388n2v 1 7 chemical chemical ADJ tb09j388n2v 1 8 reactions reaction NOUN tb09j388n2v 1 9 can can AUX tb09j388n2v 1 10 provide provide VERB tb09j388n2v 1 11 a a DET tb09j388n2v 1 12 way way NOUN tb09j388n2v 1 13 to to PART tb09j388n2v 1 14 more more ADV tb09j388n2v 1 15 rapidly rapidly ADV tb09j388n2v 1 16 access access NOUN tb09j388n2v 1 17 fine fine ADJ tb09j388n2v 1 18 chemicals chemical NOUN tb09j388n2v 1 19 . . PUNCT tb09j388n2v 2 1 these these DET tb09j388n2v 2 2 reactions reaction NOUN tb09j388n2v 2 3 are be AUX tb09j388n2v 2 4 especially especially ADV tb09j388n2v 2 5 desirable desirable ADJ tb09j388n2v 2 6 if if SCONJ tb09j388n2v 2 7 they they PRON tb09j388n2v 2 8 can can AUX tb09j388n2v 2 9 be be AUX tb09j388n2v 2 10 conducted conduct VERB tb09j388n2v 2 11 catalytically catalytically ADV tb09j388n2v 2 12 and/or and/or CCONJ tb09j388n2v 2 13 in in ADP tb09j388n2v 2 14 a a DET tb09j388n2v 2 15 multicomponent multicomponent ADJ tb09j388n2v 2 16 fashion fashion NOUN tb09j388n2v 2 17 . . PUNCT tb09j388n2v 3 1 herein herein ADV tb09j388n2v 3 2 , , PUNCT tb09j388n2v 3 3 different different ADJ tb09j388n2v 3 4 reactions reaction NOUN tb09j388n2v 3 5 based base VERB tb09j388n2v 3 6 on on ADP tb09j388n2v 3 7 transition transition NOUN tb09j388n2v 3 8 metal metal NOUN tb09j388n2v 3 9 - - PUNCT tb09j388n2v 3 10 catalyzed catalyze VERB tb09j388n2v 3 11 a a DET tb09j388n2v 3 12 - - PUNCT tb09j388n2v 3 13 alkenylation alkenylation NOUN tb09j388n2v 3 14 of of ADP tb09j388n2v 3 15 enolate enolate ADJ tb09j388n2v 3 16 couplings coupling NOUN tb09j388n2v 3 17 were be AUX tb09j388n2v 3 18 developed develop VERB tb09j388n2v 3 19 utilizing utilize VERB tb09j388n2v 3 20 either either CCONJ tb09j388n2v 3 21 twoor twoor NOUN tb09j388n2v 3 22 three three NUM tb09j388n2v 3 23 - - PUNCT tb09j388n2v 3 24 components component NOUN tb09j388n2v 3 25 . . PUNCT tb09j388n2v 4 1 both both PRON tb09j388n2v 4 2 a a DET tb09j388n2v 4 3 pdand pdand PROPN tb09j388n2v 4 4 a a DET tb09j388n2v 4 5 ni ni NOUN tb09j388n2v 4 6 - - ADJ tb09j388n2v 4 7 catalyzed catalyze VERB tb09j388n2v 4 8 a a DET tb09j388n2v 4 9 - - PUNCT tb09j388n2v 4 10 alkenylation alkenylation NOUN tb09j388n2v 4 11 procedures procedure NOUN tb09j388n2v 4 12 that that PRON tb09j388n2v 4 13 operate operate VERB tb09j388n2v 4 14 under under ADP tb09j388n2v 4 15 mild mild ADJ tb09j388n2v 4 16 conditions condition NOUN tb09j388n2v 4 17 were be AUX tb09j388n2v 4 18 established establish VERB tb09j388n2v 4 19 . . PUNCT tb09j388n2v 5 1 the the DET tb09j388n2v 5 2 pd pd PROPN tb09j388n2v 5 3 - - PUNCT tb09j388n2v 5 4 catalyzed catalyze VERB tb09j388n2v 5 5 procedure procedure NOUN tb09j388n2v 5 6 was be AUX tb09j388n2v 5 7 used use VERB tb09j388n2v 5 8 as as ADP tb09j388n2v 5 9 a a DET tb09j388n2v 5 10 platform platform NOUN tb09j388n2v 5 11 to to PART tb09j388n2v 5 12 develop develop VERB tb09j388n2v 5 13 new new ADJ tb09j388n2v 5 14 multicomponent multicomponent NOUN tb09j388n2v 5 15 reactions reaction NOUN tb09j388n2v 5 16 to to ADP tb09j388n2v 5 17 rapidly rapidly ADV tb09j388n2v 5 18 access access NOUN tb09j388n2v 5 19 complex complex ADJ tb09j388n2v 5 20 molecules molecule NOUN tb09j388n2v 5 21 from from ADP tb09j388n2v 5 22 readily readily ADV tb09j388n2v 5 23 available available ADJ tb09j388n2v 5 24 starting start VERB tb09j388n2v 5 25 materials.the materials.the DET tb09j388n2v 5 26 developed develop VERB tb09j388n2v 5 27 reactions reaction NOUN tb09j388n2v 5 28 were be AUX tb09j388n2v 5 29 then then ADV tb09j388n2v 5 30 applied apply VERB tb09j388n2v 5 31 to to PART tb09j388n2v 5 32 synthesize synthesize VERB tb09j388n2v 5 33 potential potential ADJ tb09j388n2v 5 34 therapeutics therapeutic NOUN tb09j388n2v 5 35 for for ADP tb09j388n2v 5 36 the the DET tb09j388n2v 5 37 treatment treatment NOUN tb09j388n2v 5 38 of of ADP tb09j388n2v 5 39 niemann niemann PROPN tb09j388n2v 5 40 - - PUNCT tb09j388n2v 5 41 pick pick NOUN tb09j388n2v 5 42 type type NOUN tb09j388n2v 5 43 c c NOUN tb09j388n2v 5 44 disease disease NOUN tb09j388n2v 5 45 and and CCONJ tb09j388n2v 5 46 towards towards ADP tb09j388n2v 5 47 the the DET tb09j388n2v 5 48 synthesis synthesis NOUN tb09j388n2v 5 49 of of ADP tb09j388n2v 5 50 a a DET tb09j388n2v 5 51 fluorescent fluorescent ADJ tb09j388n2v 5 52 cholesterol cholesterol NOUN tb09j388n2v 5 53 mimic mimic NOUN tb09j388n2v 5 54 . . PUNCT