id	sid	tid	token	lemma	pos
tb09j388f51	1	1	this	this	DET
tb09j388f51	1	2	dissertation	dissertation	NOUN
tb09j388f51	1	3	comprises	comprise	VERB
tb09j388f51	1	4	three	three	NUM
tb09j388f51	1	5	major	major	ADJ
tb09j388f51	1	6	components	component	NOUN
tb09j388f51	1	7	that	that	PRON
tb09j388f51	1	8	sequentially	sequentially	ADV
tb09j388f51	1	9	describe	describe	VERB
tb09j388f51	1	10	the	the	DET
tb09j388f51	1	11	development	development	NOUN
tb09j388f51	1	12	of	of	ADP
tb09j388f51	1	13	three	three	NUM
tb09j388f51	1	14	methodologies	methodology	NOUN
tb09j388f51	1	15	for	for	ADP
tb09j388f51	1	16	the	the	DET
tb09j388f51	1	17	formation	formation	NOUN
tb09j388f51	1	18	of	of	ADP
tb09j388f51	1	19	novel	novel	ADJ
tb09j388f51	1	20	methyl	methyl	NOUN
tb09j388f51	1	21	substituted	substitute	VERB
tb09j388f51	1	22	polyketide	polyketide	PROPN
tb09j388f51	1	23	structural	structural	ADJ
tb09j388f51	1	24	units	unit	NOUN
tb09j388f51	1	25	and	and	CCONJ
tb09j388f51	1	26	their	their	PRON
tb09j388f51	1	27	application	application	NOUN
tb09j388f51	1	28	in	in	ADP
tb09j388f51	1	29	complex	complex	ADJ
tb09j388f51	1	30	molecule	molecule	NOUN
tb09j388f51	1	31	synthesis	synthesis	NOUN
tb09j388f51	1	32	.	.	PUNCT
tb09j388f51	2	1	this	this	DET
tb09j388f51	2	2	research	research	NOUN
tb09j388f51	2	3	dissertation	dissertation	NOUN
tb09j388f51	2	4	commences	commence	VERB
tb09j388f51	2	5	with	with	ADP
tb09j388f51	2	6	a	a	DET
tb09j388f51	2	7	literature	literature	NOUN
tb09j388f51	2	8	review	review	NOUN
tb09j388f51	2	9	pertinent	pertinent	ADJ
tb09j388f51	2	10	to	to	ADP
tb09j388f51	2	11	the	the	DET
tb09j388f51	2	12	development	development	NOUN
tb09j388f51	2	13	of	of	ADP
tb09j388f51	2	14	an	an	DET
tb09j388f51	2	15	ether	ether	NOUN
tb09j388f51	2	16	transfer	transfer	NOUN
tb09j388f51	2	17	protocol	protocol	NOUN
tb09j388f51	2	18	,	,	PUNCT
tb09j388f51	2	19	enabling	enable	VERB
tb09j388f51	2	20	a	a	DET
tb09j388f51	2	21	novel	novel	ADJ
tb09j388f51	2	22	access	access	NOUN
tb09j388f51	2	23	to	to	ADP
tb09j388f51	2	24	the	the	DET
tb09j388f51	2	25	formation	formation	NOUN
tb09j388f51	2	26	of	of	ADP
tb09j388f51	2	27	1,3	1,3	PROPN
tb09j388f51	2	28	-	-	PUNCT
tb09j388f51	2	29	syn	syn	NOUN
tb09j388f51	2	30	-	-	PUNCT
tb09j388f51	2	31	diol	diol	NOUN
tb09j388f51	2	32	monoor	monoor	ADJ
tb09j388f51	2	33	diethers	diether	NOUN
tb09j388f51	2	34	through	through	ADP
tb09j388f51	2	35	electrophilic	electrophilic	ADJ
tb09j388f51	2	36	activation	activation	NOUN
tb09j388f51	2	37	of	of	ADP
tb09j388f51	2	38	homoallylic	homoallylic	ADJ
tb09j388f51	2	39	alkoxymethyl	alkoxymethyl	NOUN
tb09j388f51	2	40	ethers	ether	NOUN
tb09j388f51	2	41	.	.	PUNCT
tb09j388f51	3	1	starting	start	VERB
tb09j388f51	3	2	from	from	ADP
tb09j388f51	3	3	1,1	1,1	PROPN
tb09j388f51	3	4	-	-	PUNCT
tb09j388f51	3	5	disubstituted	disubstitute	VERB
tb09j388f51	3	6	alkenes	alkene	NOUN
tb09j388f51	3	7	,	,	PUNCT
tb09j388f51	3	8	this	this	DET
tb09j388f51	3	9	transformation	transformation	NOUN
tb09j388f51	3	10	enabled	enable	VERB
tb09j388f51	3	11	us	we	PRON
tb09j388f51	3	12	to	to	PART
tb09j388f51	3	13	stereoselectively	stereoselectively	ADV
tb09j388f51	3	14	access	access	VERB
tb09j388f51	3	15	tertiary	tertiary	ADJ
tb09j388f51	3	16	ethers	ether	NOUN
tb09j388f51	3	17	.	.	PUNCT
tb09j388f51	4	1	the	the	DET
tb09j388f51	4	2	use	use	NOUN
tb09j388f51	4	3	of	of	ADP
tb09j388f51	4	4	iodine	iodine	NOUN
tb09j388f51	4	5	monochloride	monochloride	PROPN
tb09j388f51	4	6	proved	prove	VERB
tb09j388f51	4	7	critical	critical	ADJ
tb09j388f51	4	8	for	for	ADP
tb09j388f51	4	9	a	a	DET
tb09j388f51	4	10	selective	selective	ADJ
tb09j388f51	4	11	process	process	NOUN
tb09j388f51	4	12	,	,	PUNCT
tb09j388f51	4	13	but	but	CCONJ
tb09j388f51	4	14	other	other	ADJ
tb09j388f51	4	15	reagents	reagent	NOUN
tb09j388f51	4	16	such	such	ADJ
tb09j388f51	4	17	as	as	ADP
tb09j388f51	4	18	idsi	idsi	PROPN
tb09j388f51	4	19	and	and	CCONJ
tb09j388f51	4	20	bdsb	bdsb	NOUN
tb09j388f51	4	21	have	have	AUX
tb09j388f51	4	22	shown	show	VERB
tb09j388f51	4	23	to	to	PART
tb09j388f51	4	24	be	be	AUX
tb09j388f51	4	25	as	as	ADV
tb09j388f51	4	26	efficient	efficient	ADJ
tb09j388f51	4	27	.	.	PUNCT
tb09j388f51	5	1	additional	additional	ADJ
tb09j388f51	5	2	advancements	advancement	NOUN
tb09j388f51	5	3	have	have	AUX
tb09j388f51	5	4	led	lead	VERB
tb09j388f51	5	5	to	to	ADP
tb09j388f51	5	6	the	the	DET
tb09j388f51	5	7	discovery	discovery	NOUN
tb09j388f51	5	8	of	of	ADP
tb09j388f51	5	9	2	2	NUM
tb09j388f51	5	10	-	-	PUNCT
tb09j388f51	5	11	naphthylmethyl	naphthylmethyl	NOUN
tb09j388f51	5	12	ether	ether	NOUN
tb09j388f51	5	13	which	which	PRON
tb09j388f51	5	14	proceeded	proceed	VERB
tb09j388f51	5	15	smoothly	smoothly	ADV
tb09j388f51	5	16	through	through	ADP
tb09j388f51	5	17	ether	ether	NOUN
tb09j388f51	5	18	transfer	transfer	NOUN
tb09j388f51	5	19	and	and	CCONJ
tb09j388f51	5	20	was	be	AUX
tb09j388f51	5	21	easily	easily	ADV
tb09j388f51	5	22	cleaved	cleave	VERB
tb09j388f51	5	23	by	by	ADP
tb09j388f51	5	24	ddq	ddq	PROPN
tb09j388f51	5	25	oxidation	oxidation	NOUN
tb09j388f51	5	26	.	.	PUNCT
tb09j388f51	6	1	this	this	DET
tb09j388f51	6	2	new	new	ADJ
tb09j388f51	6	3	method	method	NOUN
tb09j388f51	6	4	to	to	PART
tb09j388f51	6	5	access	access	VERB
tb09j388f51	6	6	structural	structural	ADJ
tb09j388f51	6	7	units	unit	NOUN
tb09j388f51	6	8	containing	contain	VERB
tb09j388f51	6	9	tertiary	tertiary	ADJ
tb09j388f51	6	10	ethers	ether	NOUN
tb09j388f51	6	11	was	be	AUX
tb09j388f51	6	12	applied	apply	VERB
tb09j388f51	6	13	in	in	ADP
tb09j388f51	6	14	the	the	DET
tb09j388f51	6	15	synthesis	synthesis	NOUN
tb09j388f51	6	16	of	of	ADP
tb09j388f51	6	17	the	the	DET
tb09j388f51	6	18	c9	c9	NOUN
tb09j388f51	6	19	-	-	PUNCT
tb09j388f51	6	20	c19	c19	NOUN
tb09j388f51	6	21	fragment	fragment	NOUN
tb09j388f51	6	22	of	of	ADP
tb09j388f51	6	23	lyngbyaloside	lyngbyaloside	PROPN
tb09j388f51	6	24	b	b	PROPN
tb09j388f51	6	25	and	and	CCONJ
tb09j388f51	6	26	c.	c.	PROPN
tb09j388f51	6	27	in	in	ADP
tb09j388f51	6	28	several	several	ADJ
tb09j388f51	6	29	cases	case	NOUN
tb09j388f51	6	30	,	,	PUNCT
tb09j388f51	6	31	we	we	PRON
tb09j388f51	6	32	observed	observe	VERB
tb09j388f51	6	33	the	the	DET
tb09j388f51	6	34	failure	failure	NOUN
tb09j388f51	6	35	of	of	ADP
tb09j388f51	6	36	the	the	DET
tb09j388f51	6	37	ether	ether	NOUN
tb09j388f51	6	38	transfer	transfer	NOUN
tb09j388f51	6	39	methodology	methodology	NOUN
tb09j388f51	6	40	to	to	PART
tb09j388f51	6	41	provide	provide	VERB
tb09j388f51	6	42	the	the	DET
tb09j388f51	6	43	desired	desire	VERB
tb09j388f51	6	44	reactivity	reactivity	NOUN
tb09j388f51	6	45	.	.	PUNCT
tb09j388f51	7	1	this	this	PRON
tb09j388f51	7	2	was	be	AUX
tb09j388f51	7	3	particularly	particularly	ADV
tb09j388f51	7	4	true	true	ADJ
tb09j388f51	7	5	when	when	SCONJ
tb09j388f51	7	6	sp2	sp2	NOUN
tb09j388f51	7	7	-	-	PUNCT
tb09j388f51	7	8	hybridized	hybridize	VERB
tb09j388f51	7	9	substituents	substituent	NOUN
tb09j388f51	7	10	were	be	AUX
tb09j388f51	7	11	adjacent	adjacent	ADJ
tb09j388f51	7	12	to	to	ADP
tb09j388f51	7	13	the	the	DET
tb09j388f51	7	14	reacting	react	VERB
tb09j388f51	7	15	alkoxymethyl	alkoxymethyl	NOUN
tb09j388f51	7	16	ether	ether	NOUN
tb09j388f51	7	17	,	,	PUNCT
tb09j388f51	7	18	resulting	result	VERB
tb09j388f51	7	19	in	in	ADP
tb09j388f51	7	20	the	the	DET
tb09j388f51	7	21	formation	formation	NOUN
tb09j388f51	7	22	of	of	ADP
tb09j388f51	7	23	dihalogenated	dihalogenated	ADJ
tb09j388f51	7	24	byproducts	byproduct	NOUN
tb09j388f51	7	25	upon	upon	SCONJ
tb09j388f51	7	26	activation	activation	NOUN
tb09j388f51	7	27	with	with	ADP
tb09j388f51	7	28	iodine	iodine	NOUN
tb09j388f51	7	29	monochloride	monochloride	PROPN
tb09j388f51	7	30	.	.	PUNCT
tb09j388f51	8	1	we	we	PRON
tb09j388f51	8	2	therefore	therefore	ADV
tb09j388f51	8	3	developed	develop	VERB
tb09j388f51	8	4	a	a	DET
tb09j388f51	8	5	second	second	ADJ
tb09j388f51	8	6	generation	generation	NOUN
tb09j388f51	8	7	of	of	ADP
tb09j388f51	8	8	activating	activate	VERB
tb09j388f51	8	9	conditions	condition	NOUN
tb09j388f51	8	10	,	,	PUNCT
tb09j388f51	8	11	using	use	VERB
tb09j388f51	8	12	n	n	NOUN
tb09j388f51	8	13	-	-	PUNCT
tb09j388f51	8	14	iodosuccinimide	iodosuccinimide	NOUN
tb09j388f51	8	15	in	in	ADP
tb09j388f51	8	16	wet	wet	ADJ
tb09j388f51	8	17	nitromethane	nitromethane	NOUN
tb09j388f51	8	18	,	,	PUNCT
tb09j388f51	8	19	to	to	PART
tb09j388f51	8	20	resolve	resolve	VERB
tb09j388f51	8	21	this	this	DET
tb09j388f51	8	22	lack	lack	NOUN
tb09j388f51	8	23	of	of	ADP
tb09j388f51	8	24	selectivity	selectivity	NOUN
tb09j388f51	8	25	.	.	PUNCT
tb09j388f51	9	1	this	this	DET
tb09j388f51	9	2	new	new	ADJ
tb09j388f51	9	3	,	,	PUNCT
tb09j388f51	9	4	stereoselective	stereoselective	ADJ
tb09j388f51	9	5	route	route	NOUN
tb09j388f51	9	6	to	to	PART
tb09j388f51	9	7	access	access	VERB
tb09j388f51	9	8	1,3	1,3	NUM
tb09j388f51	9	9	-	-	PUNCT
tb09j388f51	9	10	syn	syn	NOUN
tb09j388f51	9	11	-	-	PUNCT
tb09j388f51	9	12	diol	diol	NOUN
tb09j388f51	9	13	monoor	monoor	ADJ
tb09j388f51	9	14	diethers	diether	NOUN
tb09j388f51	9	15	was	be	AUX
tb09j388f51	9	16	successfully	successfully	ADV
tb09j388f51	9	17	applied	apply	VERB
tb09j388f51	9	18	to	to	ADP
tb09j388f51	9	19	the	the	DET
tb09j388f51	9	20	syntheses	synthesis	NOUN
tb09j388f51	9	21	of	of	ADP
tb09j388f51	9	22	diospongins	diospongin	NOUN
tb09j388f51	9	23	a	a	PRON
tb09j388f51	9	24	and	and	CCONJ
tb09j388f51	9	25	b.	b.	PROPN
tb09j388f51	9	26	the	the	DET
tb09j388f51	9	27	final	final	ADJ
tb09j388f51	9	28	section	section	NOUN
tb09j388f51	9	29	describes	describe	VERB
tb09j388f51	9	30	a	a	DET
tb09j388f51	9	31	method	method	NOUN
tb09j388f51	9	32	that	that	PRON
tb09j388f51	9	33	enabled	enable	VERB
tb09j388f51	9	34	sp3	sp3	DET
tb09j388f51	9	35	c	c	NOUN
tb09j388f51	9	36	-	-	PUNCT
tb09j388f51	9	37	h	h	NOUN
tb09j388f51	9	38	bond	bond	NOUN
tb09j388f51	9	39	functionalization	functionalization	NOUN
tb09j388f51	9	40	by	by	ADP
tb09j388f51	9	41	means	mean	NOUN
tb09j388f51	9	42	of	of	ADP
tb09j388f51	9	43	a	a	DET
tb09j388f51	9	44	hydride	hydride	NOUN
tb09j388f51	9	45	shift	shift	NOUN
tb09j388f51	9	46	.	.	PUNCT
tb09j388f51	10	1	we	we	PRON
tb09j388f51	10	2	discovered	discover	VERB
tb09j388f51	10	3	that	that	SCONJ
tb09j388f51	10	4	protonation	protonation	NOUN
tb09j388f51	10	5	of	of	ADP
tb09j388f51	10	6	an	an	DET
tb09j388f51	10	7	alkene	alkene	NOUN
tb09j388f51	10	8	with	with	ADP
tb09j388f51	10	9	a	a	DET
tb09j388f51	10	10	strong	strong	ADJ
tb09j388f51	10	11	br?nsted	br?nsted	ADJ
tb09j388f51	10	12	acid	acid	NOUN
tb09j388f51	10	13	initiated	initiate	VERB
tb09j388f51	10	14	a	a	DET
tb09j388f51	10	15	1,5	1,5	NUM
tb09j388f51	10	16	-	-	PUNCT
tb09j388f51	10	17	hydride	hydride	NOUN
tb09j388f51	10	18	shift	shift	NOUN
tb09j388f51	10	19	through	through	ADP
tb09j388f51	10	20	reduction	reduction	NOUN
tb09j388f51	10	21	of	of	ADP
tb09j388f51	10	22	a	a	DET
tb09j388f51	10	23	tertiary	tertiary	ADJ
tb09j388f51	10	24	carbocation	carbocation	NOUN
tb09j388f51	10	25	by	by	ADP
tb09j388f51	10	26	an	an	DET
tb09j388f51	10	27	appropriately	appropriately	ADV
tb09j388f51	10	28	positioned	position	VERB
tb09j388f51	10	29	benzyl	benzyl	NOUN
tb09j388f51	10	30	ether	ether	NOUN
tb09j388f51	10	31	.	.	PUNCT
tb09j388f51	11	1	modifications	modification	NOUN
tb09j388f51	11	2	to	to	ADP
tb09j388f51	11	3	the	the	DET
tb09j388f51	11	4	starting	starting	NOUN
tb09j388f51	11	5	material	material	NOUN
tb09j388f51	11	6	or	or	CCONJ
tb09j388f51	11	7	to	to	ADP
tb09j388f51	11	8	the	the	DET
tb09j388f51	11	9	activating	activating	NOUN
tb09j388f51	11	10	conditions	condition	NOUN
tb09j388f51	11	11	allowed	allow	VERB
tb09j388f51	11	12	the	the	DET
tb09j388f51	11	13	formation	formation	NOUN
tb09j388f51	11	14	of	of	ADP
tb09j388f51	11	15	a	a	DET
tb09j388f51	11	16	variety	variety	NOUN
tb09j388f51	11	17	of	of	ADP
tb09j388f51	11	18	synthetically	synthetically	ADV
tb09j388f51	11	19	useful	useful	ADJ
tb09j388f51	11	20	motifs	motif	NOUN
tb09j388f51	11	21	that	that	PRON
tb09j388f51	11	22	could	could	AUX
tb09j388f51	11	23	be	be	AUX
tb09j388f51	11	24	potentially	potentially	ADV
tb09j388f51	11	25	employed	employ	VERB
tb09j388f51	11	26	in	in	ADP
tb09j388f51	11	27	the	the	DET
tb09j388f51	11	28	synthesis	synthesis	NOUN
tb09j388f51	11	29	of	of	ADP
tb09j388f51	11	30	complex	complex	ADJ
tb09j388f51	11	31	natural	natural	ADJ
tb09j388f51	11	32	products	product	NOUN
tb09j388f51	11	33	.	.	PUNCT