id sid tid token lemma pos t435gb21x12 1 1 the the DET t435gb21x12 1 2 calculation calculation NOUN t435gb21x12 1 3 of of ADP t435gb21x12 1 4 phase phase NOUN t435gb21x12 1 5 equilibrium equilibrium NOUN t435gb21x12 1 6 is be AUX t435gb21x12 1 7 a a DET t435gb21x12 1 8 fundamental fundamental ADJ t435gb21x12 1 9 and and CCONJ t435gb21x12 1 10 reoccurring reoccurring ADJ t435gb21x12 1 11 problem problem NOUN t435gb21x12 1 12 in in ADP t435gb21x12 1 13 modeling modeling NOUN t435gb21x12 1 14 of of ADP t435gb21x12 1 15 chemical chemical ADJ t435gb21x12 1 16 engineering engineering NOUN t435gb21x12 1 17 phenomena phenomenon NOUN t435gb21x12 1 18 . . PUNCT t435gb21x12 2 1 a a DET t435gb21x12 2 2 key key ADJ t435gb21x12 2 3 step step NOUN t435gb21x12 2 4 in in ADP t435gb21x12 2 5 the the DET t435gb21x12 2 6 computation computation NOUN t435gb21x12 2 7 of of ADP t435gb21x12 2 8 multiphase multiphase ADJ t435gb21x12 2 9 equilibrium equilibrium NOUN t435gb21x12 2 10 is be AUX t435gb21x12 2 11 phase phase NOUN t435gb21x12 2 12 stability stability NOUN t435gb21x12 2 13 analysis analysis NOUN t435gb21x12 2 14 . . PUNCT t435gb21x12 3 1 a a DET t435gb21x12 3 2 reliable reliable ADJ t435gb21x12 3 3 technique technique NOUN t435gb21x12 3 4 for for ADP t435gb21x12 3 5 phase phase NOUN t435gb21x12 3 6 stability stability NOUN t435gb21x12 3 7 analysis analysis NOUN t435gb21x12 3 8 will will AUX t435gb21x12 3 9 assure assure VERB t435gb21x12 3 10 both both PRON t435gb21x12 3 11 that that SCONJ t435gb21x12 3 12 the the DET t435gb21x12 3 13 correct correct ADJ t435gb21x12 3 14 number number NOUN t435gb21x12 3 15 of of ADP t435gb21x12 3 16 phases phase NOUN t435gb21x12 3 17 is be AUX t435gb21x12 3 18 found find VERB t435gb21x12 3 19 , , PUNCT t435gb21x12 3 20 and and CCONJ t435gb21x12 3 21 that that SCONJ t435gb21x12 3 22 the the DET t435gb21x12 3 23 phase phase NOUN t435gb21x12 3 24 split split NOUN t435gb21x12 3 25 computed compute VERB t435gb21x12 3 26 corresponds correspond NOUN t435gb21x12 3 27 to to ADP t435gb21x12 3 28 a a DET t435gb21x12 3 29 global global ADJ t435gb21x12 3 30 minimum minimum NOUN t435gb21x12 3 31 in in ADP t435gb21x12 3 32 the the DET t435gb21x12 3 33 total total ADJ t435gb21x12 3 34 gibbs gibbs PROPN t435gb21x12 3 35 energy energy NOUN t435gb21x12 3 36 . . PUNCT t435gb21x12 4 1 that that ADV t435gb21x12 4 2 is is ADV t435gb21x12 4 3 , , PUNCT t435gb21x12 4 4 phase phase NOUN t435gb21x12 4 5 stability stability NOUN t435gb21x12 4 6 analysis analysis NOUN t435gb21x12 4 7 serves serve VERB t435gb21x12 4 8 as as ADP t435gb21x12 4 9 a a DET t435gb21x12 4 10 global global ADJ t435gb21x12 4 11 optimality optimality NOUN t435gb21x12 4 12 test test NOUN t435gb21x12 4 13 in in ADP t435gb21x12 4 14 solving solve VERB t435gb21x12 4 15 the the DET t435gb21x12 4 16 global global ADJ t435gb21x12 4 17 optimization optimization NOUN t435gb21x12 4 18 problem problem NOUN t435gb21x12 4 19 that that PRON t435gb21x12 4 20 determines determine VERB t435gb21x12 4 21 phase phase NOUN t435gb21x12 4 22 equilibrium equilibrium NOUN t435gb21x12 4 23 at at ADP t435gb21x12 4 24 constant constant ADJ t435gb21x12 4 25 temperature temperature NOUN t435gb21x12 4 26 and and CCONJ t435gb21x12 4 27 pressure pressure NOUN t435gb21x12 4 28 . . PUNCT t435gb21x12 5 1 however however ADV t435gb21x12 5 2 , , PUNCT t435gb21x12 5 3 phase phase NOUN t435gb21x12 5 4 stability stability NOUN t435gb21x12 5 5 analysis analysis NOUN t435gb21x12 5 6 is be AUX t435gb21x12 5 7 itself itself PRON t435gb21x12 5 8 a a DET t435gb21x12 5 9 global global ADJ t435gb21x12 5 10 optimization optimization NOUN t435gb21x12 5 11 problem problem NOUN t435gb21x12 5 12 that that PRON t435gb21x12 5 13 can can AUX t435gb21x12 5 14 be be AUX t435gb21x12 5 15 very very ADV t435gb21x12 5 16 difficult difficult ADJ t435gb21x12 5 17 to to PART t435gb21x12 5 18 solve solve VERB t435gb21x12 5 19 reliably reliably ADV t435gb21x12 5 20 . . PUNCT t435gb21x12 6 1 stochastic stochastic ADJ t435gb21x12 6 2 global global ADJ t435gb21x12 6 3 optimization optimization NOUN t435gb21x12 6 4 methods method NOUN t435gb21x12 6 5 ( ( PUNCT t435gb21x12 6 6 e.g. e.g. ADV t435gb21x12 6 7 , , PUNCT t435gb21x12 6 8 simulated simulated ADJ t435gb21x12 6 9 annealing annealing NOUN t435gb21x12 6 10 , , PUNCT t435gb21x12 6 11 genetic genetic ADJ t435gb21x12 6 12 algorithms algorithm NOUN t435gb21x12 6 13 , , PUNCT t435gb21x12 6 14 etc etc X t435gb21x12 6 15 . . X t435gb21x12 6 16 ) ) PUNCT t435gb21x12 6 17 have have AUX t435gb21x12 6 18 been be AUX t435gb21x12 6 19 frequently frequently ADV t435gb21x12 6 20 proposed propose VERB t435gb21x12 6 21 in in ADP t435gb21x12 6 22 this this DET t435gb21x12 6 23 context context NOUN t435gb21x12 6 24 . . PUNCT t435gb21x12 7 1 however however ADV t435gb21x12 7 2 , , PUNCT t435gb21x12 7 3 none none NOUN t435gb21x12 7 4 of of ADP t435gb21x12 7 5 these these DET t435gb21x12 7 6 techniques technique NOUN t435gb21x12 7 7 is be AUX t435gb21x12 7 8 actually actually ADV t435gb21x12 7 9 guaranteed guarantee VERB t435gb21x12 7 10 to to PART t435gb21x12 7 11 produce produce VERB t435gb21x12 7 12 the the DET t435gb21x12 7 13 correct correct ADJ t435gb21x12 7 14 results result NOUN t435gb21x12 7 15 . . PUNCT t435gb21x12 8 1 thus thus ADV t435gb21x12 8 2 , , PUNCT t435gb21x12 8 3 there there PRON t435gb21x12 8 4 has have AUX t435gb21x12 8 5 been be AUX t435gb21x12 8 6 significant significant ADJ t435gb21x12 8 7 interest interest NOUN t435gb21x12 8 8 in in ADP t435gb21x12 8 9 the the DET t435gb21x12 8 10 development development NOUN t435gb21x12 8 11 of of ADP t435gb21x12 8 12 deterministic deterministic ADJ t435gb21x12 8 13 techniques technique NOUN t435gb21x12 8 14 that that PRON t435gb21x12 8 15 guarantee guarantee VERB t435gb21x12 8 16 the the DET t435gb21x12 8 17 correct correct ADJ t435gb21x12 8 18 solution solution NOUN t435gb21x12 8 19 of of ADP t435gb21x12 8 20 the the DET t435gb21x12 8 21 phase phase NOUN t435gb21x12 8 22 stability stability NOUN t435gb21x12 8 23 problem problem NOUN t435gb21x12 8 24 . . PUNCT t435gb21x12 9 1 these these DET t435gb21x12 9 2 efforts effort NOUN t435gb21x12 9 3 have have AUX t435gb21x12 9 4 been be AUX t435gb21x12 9 5 focused focus VERB t435gb21x12 9 6 primarily primarily ADV t435gb21x12 9 7 on on ADP t435gb21x12 9 8 the the DET t435gb21x12 9 9 case case NOUN t435gb21x12 9 10 of of ADP t435gb21x12 9 11 symmetric symmetric ADJ t435gb21x12 9 12 models model NOUN t435gb21x12 9 13 ( ( PUNCT t435gb21x12 9 14 same same ADJ t435gb21x12 9 15 thermodynamic thermodynamic ADJ t435gb21x12 9 16 model model NOUN t435gb21x12 9 17 used use VERB t435gb21x12 9 18 for for ADP t435gb21x12 9 19 all all DET t435gb21x12 9 20 phases phase NOUN t435gb21x12 9 21 ) ) PUNCT t435gb21x12 9 22 . . PUNCT t435gb21x12 10 1 work work VERB t435gb21x12 10 2 on on ADP t435gb21x12 10 3 deterministic deterministic ADJ t435gb21x12 10 4 stability stability NOUN t435gb21x12 10 5 analysis analysis NOUN t435gb21x12 10 6 for for ADP t435gb21x12 10 7 the the DET t435gb21x12 10 8 asymmetric asymmetric ADJ t435gb21x12 10 9 case case NOUN t435gb21x12 10 10 ( ( PUNCT t435gb21x12 10 11 different different ADJ t435gb21x12 10 12 models model NOUN t435gb21x12 10 13 used use VERB t435gb21x12 10 14 for for ADP t435gb21x12 10 15 different different ADJ t435gb21x12 10 16 phases phase NOUN t435gb21x12 10 17 ) ) PUNCT t435gb21x12 10 18 has have AUX t435gb21x12 10 19 been be AUX t435gb21x12 10 20 limited limit VERB t435gb21x12 10 21 to to ADP t435gb21x12 10 22 cases case NOUN t435gb21x12 10 23 involving involve VERB t435gb21x12 10 24 either either CCONJ t435gb21x12 10 25 an an DET t435gb21x12 10 26 ideal ideal ADJ t435gb21x12 10 27 gas gas NOUN t435gb21x12 10 28 vapor vapor NOUN t435gb21x12 10 29 phase phase NOUN t435gb21x12 10 30 or or CCONJ t435gb21x12 10 31 a a DET t435gb21x12 10 32 pure pure ADJ t435gb21x12 10 33 solid solid ADJ t435gb21x12 10 34 phase phase NOUN t435gb21x12 10 35 . . PUNCT t435gb21x12 11 1 in in ADP t435gb21x12 11 2 this this DET t435gb21x12 11 3 thesis thesis NOUN t435gb21x12 11 4 , , PUNCT t435gb21x12 11 5 a a DET t435gb21x12 11 6 deterministic deterministic ADJ t435gb21x12 11 7 method method NOUN t435gb21x12 11 8 for for ADP t435gb21x12 11 9 the the DET t435gb21x12 11 10 more more ADV t435gb21x12 11 11 general general ADJ t435gb21x12 11 12 asymmetric asymmetric ADJ t435gb21x12 11 13 case case NOUN t435gb21x12 11 14 will will AUX t435gb21x12 11 15 be be AUX t435gb21x12 11 16 presented present VERB t435gb21x12 11 17 , , PUNCT t435gb21x12 11 18 focusing focus VERB t435gb21x12 11 19 on on ADP t435gb21x12 11 20 the the DET t435gb21x12 11 21 common common ADJ t435gb21x12 11 22 situation situation NOUN t435gb21x12 11 23 in in ADP t435gb21x12 11 24 modeling model VERB t435gb21x12 11 25 vapor vapor NOUN t435gb21x12 11 26 - - PUNCT t435gb21x12 11 27 liquid liquid ADJ t435gb21x12 11 28 equilibrium equilibrium NOUN t435gb21x12 11 29 in in ADP t435gb21x12 11 30 which which PRON t435gb21x12 11 31 nonidealities nonidealitie NOUN t435gb21x12 11 32 are be AUX t435gb21x12 11 33 represented represent VERB t435gb21x12 11 34 in in ADP t435gb21x12 11 35 the the DET t435gb21x12 11 36 vapor vapor NOUN t435gb21x12 11 37 phase phase NOUN t435gb21x12 11 38 by by ADP t435gb21x12 11 39 an an DET t435gb21x12 11 40 equation equation NOUN t435gb21x12 11 41 of of ADP t435gb21x12 11 42 state state NOUN t435gb21x12 11 43 and and CCONJ t435gb21x12 11 44 in in ADP t435gb21x12 11 45 the the DET t435gb21x12 11 46 liquid liquid ADJ t435gb21x12 11 47 phase phase NOUN t435gb21x12 11 48 by by ADP t435gb21x12 11 49 an an DET t435gb21x12 11 50 excess excess ADJ t435gb21x12 11 51 gibbs gibbs PROPN t435gb21x12 11 52 energy energy NOUN t435gb21x12 11 53 model model NOUN t435gb21x12 11 54 . . PUNCT t435gb21x12 12 1 in in ADP t435gb21x12 12 2 comparison comparison NOUN t435gb21x12 12 3 to to ADP t435gb21x12 12 4 the the DET t435gb21x12 12 5 symmetric symmetric ADJ t435gb21x12 12 6 model model NOUN t435gb21x12 12 7 case case NOUN t435gb21x12 12 8 , , PUNCT t435gb21x12 12 9 the the DET t435gb21x12 12 10 use use NOUN t435gb21x12 12 11 of of ADP t435gb21x12 12 12 multiple multiple ADJ t435gb21x12 12 13 thermodynamic thermodynamic ADJ t435gb21x12 12 14 models model NOUN t435gb21x12 12 15 in in ADP t435gb21x12 12 16 the the DET t435gb21x12 12 17 asymmetric asymmetric ADJ t435gb21x12 12 18 case case NOUN t435gb21x12 12 19 adds add VERB t435gb21x12 12 20 an an DET t435gb21x12 12 21 additional additional ADJ t435gb21x12 12 22 layer layer NOUN t435gb21x12 12 23 of of ADP t435gb21x12 12 24 complexity complexity NOUN t435gb21x12 12 25 to to ADP t435gb21x12 12 26 the the DET t435gb21x12 12 27 phase phase NOUN t435gb21x12 12 28 stability stability NOUN t435gb21x12 12 29 problem problem NOUN t435gb21x12 12 30 . . PUNCT t435gb21x12 13 1 to to PART t435gb21x12 13 2 deal deal VERB t435gb21x12 13 3 with with ADP t435gb21x12 13 4 this this DET t435gb21x12 13 5 additional additional ADJ t435gb21x12 13 6 complexity complexity NOUN t435gb21x12 13 7 the the DET t435gb21x12 13 8 phase phase NOUN t435gb21x12 13 9 stability stability NOUN t435gb21x12 13 10 problem problem NOUN t435gb21x12 13 11 is be AUX t435gb21x12 13 12 formulated formulate VERB t435gb21x12 13 13 in in ADP t435gb21x12 13 14 terms term NOUN t435gb21x12 13 15 of of ADP t435gb21x12 13 16 a a DET t435gb21x12 13 17 new new ADJ t435gb21x12 13 18 type type NOUN t435gb21x12 13 19 of of ADP t435gb21x12 13 20 tangent tangent ADJ t435gb21x12 13 21 plane plane NOUN t435gb21x12 13 22 distance distance NOUN t435gb21x12 13 23 function function NOUN t435gb21x12 13 24 , , PUNCT t435gb21x12 13 25 which which PRON t435gb21x12 13 26 uses use VERB t435gb21x12 13 27 a a DET t435gb21x12 13 28 binary binary ADJ t435gb21x12 13 29 variable variable NOUN t435gb21x12 13 30 to to PART t435gb21x12 13 31 account account VERB t435gb21x12 13 32 for for ADP t435gb21x12 13 33 the the DET t435gb21x12 13 34 presence presence NOUN t435gb21x12 13 35 of of ADP t435gb21x12 13 36 different different ADJ t435gb21x12 13 37 liquidand liquidand NOUN t435gb21x12 13 38 vapor vapor NOUN t435gb21x12 13 39 - - PUNCT t435gb21x12 13 40 phase phase NOUN t435gb21x12 13 41 models model NOUN t435gb21x12 13 42 . . PUNCT t435gb21x12 14 1 to to PART t435gb21x12 14 2 then then ADV t435gb21x12 14 3 solve solve VERB t435gb21x12 14 4 the the DET t435gb21x12 14 5 problem problem NOUN t435gb21x12 14 6 deterministically deterministically ADV t435gb21x12 14 7 , , PUNCT t435gb21x12 14 8 an an DET t435gb21x12 14 9 interval interval NOUN t435gb21x12 14 10 - - PUNCT t435gb21x12 14 11 newton newton NOUN t435gb21x12 14 12 approach approach NOUN t435gb21x12 14 13 is be AUX t435gb21x12 14 14 used use VERB t435gb21x12 14 15 . . PUNCT t435gb21x12 15 1 the the DET t435gb21x12 15 2 new new ADJ t435gb21x12 15 3 methodology methodology NOUN t435gb21x12 15 4 is be AUX t435gb21x12 15 5 tested test VERB t435gb21x12 15 6 using use VERB t435gb21x12 15 7 several several ADJ t435gb21x12 15 8 examples example NOUN t435gb21x12 15 9 with with ADP t435gb21x12 15 10 nrtl nrtl PROPN t435gb21x12 15 11 as as ADP t435gb21x12 15 12 the the DET t435gb21x12 15 13 liquid liquid NOUN t435gb21x12 15 14 - - PUNCT t435gb21x12 15 15 phase phase NOUN t435gb21x12 15 16 model model NOUN t435gb21x12 15 17 and and CCONJ t435gb21x12 15 18 a a DET t435gb21x12 15 19 cubic cubic ADJ t435gb21x12 15 20 equation equation NOUN t435gb21x12 15 21 of of ADP t435gb21x12 15 22 state state NOUN t435gb21x12 15 23 as as ADP t435gb21x12 15 24 the the DET t435gb21x12 15 25 vapor vapor NOUN t435gb21x12 15 26 - - PUNCT t435gb21x12 15 27 phase phase NOUN t435gb21x12 15 28 model model NOUN t435gb21x12 15 29 . . PUNCT t435gb21x12 16 1 in in ADP t435gb21x12 16 2 three three NUM t435gb21x12 16 3 cases case NOUN t435gb21x12 16 4 , , PUNCT t435gb21x12 16 5 published publish VERB t435gb21x12 16 6 phase phase NOUN t435gb21x12 16 7 equilibrium equilibrium NOUN t435gb21x12 16 8 computations computation NOUN t435gb21x12 16 9 were be AUX t435gb21x12 16 10 found find VERB t435gb21x12 16 11 to to PART t435gb21x12 16 12 be be AUX t435gb21x12 16 13 incorrect incorrect ADJ t435gb21x12 16 14 ( ( PUNCT t435gb21x12 16 15 not not PART t435gb21x12 16 16 stable stable ADJ t435gb21x12 16 17 ) ) PUNCT t435gb21x12 16 18 . . PUNCT t435gb21x12 17 1 procedures procedure NOUN t435gb21x12 17 2 for for ADP t435gb21x12 17 3 deterministic deterministic ADJ t435gb21x12 17 4 phase phase NOUN t435gb21x12 17 5 stability stability NOUN t435gb21x12 17 6 analysis analysis NOUN t435gb21x12 17 7 , , PUNCT t435gb21x12 17 8 such such ADJ t435gb21x12 17 9 as as ADP t435gb21x12 17 10 described describe VERB t435gb21x12 17 11 here here ADV t435gb21x12 17 12 , , PUNCT t435gb21x12 17 13 can can AUX t435gb21x12 17 14 be be AUX t435gb21x12 17 15 used use VERB t435gb21x12 17 16 in in ADP t435gb21x12 17 17 connection connection NOUN t435gb21x12 17 18 with with ADP t435gb21x12 17 19 any any DET t435gb21x12 17 20 algorithm algorithm NOUN t435gb21x12 17 21 or or CCONJ t435gb21x12 17 22 software software NOUN t435gb21x12 17 23 package package NOUN t435gb21x12 17 24 for for ADP t435gb21x12 17 25 computing compute VERB t435gb21x12 17 26 phase phase NOUN t435gb21x12 17 27 equilibrium equilibrium NOUN t435gb21x12 17 28 , , PUNCT t435gb21x12 17 29 to to PART t435gb21x12 17 30 validate validate VERB t435gb21x12 17 31 the the DET t435gb21x12 17 32 computed compute VERB t435gb21x12 17 33 results result NOUN t435gb21x12 17 34 and and CCONJ t435gb21x12 17 35 to to PART t435gb21x12 17 36 provide provide VERB t435gb21x12 17 37 corrective corrective ADJ t435gb21x12 17 38 feedback feedback NOUN t435gb21x12 17 39 if if SCONJ t435gb21x12 17 40 needed need VERB t435gb21x12 17 41 . . PUNCT