id	sid	tid	token	lemma	pos
sx61dj56777	1	1	the	the	DET
sx61dj56777	1	2	reactivity	reactivity	NOUN
sx61dj56777	1	3	and	and	CCONJ
sx61dj56777	1	4	stability	stability	NOUN
sx61dj56777	1	5	of	of	ADP
sx61dj56777	1	6	homogenous	homogenous	ADJ
sx61dj56777	1	7	transition	transition	NOUN
sx61dj56777	1	8	metal	metal	NOUN
sx61dj56777	1	9	catalysts	catalyst	NOUN
sx61dj56777	1	10	largely	largely	ADV
sx61dj56777	1	11	depends	depend	VERB
sx61dj56777	1	12	on	on	ADP
sx61dj56777	1	13	the	the	DET
sx61dj56777	1	14	supporting	support	VERB
sx61dj56777	1	15	ligand	ligand	NOUN
sx61dj56777	1	16	system	system	NOUN
sx61dj56777	1	17	.	.	PUNCT
sx61dj56777	2	1	thus	thus	ADV
sx61dj56777	2	2	,	,	PUNCT
sx61dj56777	2	3	ligand	ligand	NOUN
sx61dj56777	2	4	design	design	NOUN
sx61dj56777	2	5	is	be	AUX
sx61dj56777	2	6	a	a	DET
sx61dj56777	2	7	crucial	crucial	ADJ
sx61dj56777	2	8	component	component	NOUN
sx61dj56777	2	9	to	to	ADP
sx61dj56777	2	10	reactivity	reactivity	NOUN
sx61dj56777	2	11	modulation	modulation	NOUN
sx61dj56777	2	12	and	and	CCONJ
sx61dj56777	2	13	optimization	optimization	NOUN
sx61dj56777	2	14	of	of	ADP
sx61dj56777	2	15	catalysts	catalyst	NOUN
sx61dj56777	2	16	.	.	PUNCT
sx61dj56777	3	1	in	in	ADP
sx61dj56777	3	2	particular	particular	ADJ
sx61dj56777	3	3	,	,	PUNCT
sx61dj56777	3	4	the	the	DET
sx61dj56777	3	5	development	development	NOUN
sx61dj56777	3	6	of	of	ADP
sx61dj56777	3	7	ligand	ligand	NOUN
sx61dj56777	3	8	systems	system	NOUN
sx61dj56777	3	9	capable	capable	ADJ
sx61dj56777	3	10	of	of	ADP
sx61dj56777	3	11	participating	participate	VERB
sx61dj56777	3	12	in	in	ADP
sx61dj56777	3	13	metal	metal	NOUN
sx61dj56777	3	14	ligand	ligand	NOUN
sx61dj56777	3	15	cooperativity	cooperativity	NOUN
sx61dj56777	3	16	(	(	PUNCT
sx61dj56777	3	17	mlc	mlc	PROPN
sx61dj56777	3	18	)	)	PUNCT
sx61dj56777	3	19	has	have	AUX
sx61dj56777	3	20	become	become	VERB
sx61dj56777	3	21	a	a	DET
sx61dj56777	3	22	popular	popular	ADJ
sx61dj56777	3	23	area	area	NOUN
sx61dj56777	3	24	of	of	ADP
sx61dj56777	3	25	research	research	NOUN
sx61dj56777	3	26	in	in	ADP
sx61dj56777	3	27	the	the	DET
sx61dj56777	3	28	organometallic	organometallic	ADJ
sx61dj56777	3	29	community	community	NOUN
sx61dj56777	3	30	.	.	PUNCT
sx61dj56777	4	1	complexes	complex	NOUN
sx61dj56777	4	2	of	of	ADP
sx61dj56777	4	3	this	this	DET
sx61dj56777	4	4	nature	nature	NOUN
sx61dj56777	4	5	promote	promote	VERB
sx61dj56777	4	6	participation	participation	NOUN
sx61dj56777	4	7	from	from	ADP
sx61dj56777	4	8	the	the	DET
sx61dj56777	4	9	supporting	support	VERB
sx61dj56777	4	10	ligand	ligand	NOUN
sx61dj56777	4	11	and	and	CCONJ
sx61dj56777	4	12	the	the	DET
sx61dj56777	4	13	metal	metal	NOUN
sx61dj56777	4	14	center	center	NOUN
sx61dj56777	4	15	throughout	throughout	ADP
sx61dj56777	4	16	a	a	DET
sx61dj56777	4	17	chemical	chemical	NOUN
sx61dj56777	4	18	process	process	NOUN
sx61dj56777	4	19	.	.	PUNCT
sx61dj56777	5	1	credited	credit	VERB
sx61dj56777	5	2	for	for	ADP
sx61dj56777	5	3	their	their	PRON
sx61dj56777	5	4	tunability	tunability	NOUN
sx61dj56777	5	5	,	,	PUNCT
sx61dj56777	5	6	tridentate	tridentate	ADJ
sx61dj56777	5	7	,	,	PUNCT
sx61dj56777	5	8	chelating	chelate	VERB
sx61dj56777	5	9	pincer	pincer	NOUN
sx61dj56777	5	10	ligands	ligand	NOUN
sx61dj56777	5	11	are	be	AUX
sx61dj56777	5	12	well	well	ADV
sx61dj56777	5	13	-	-	PUNCT
sx61dj56777	5	14	known	know	VERB
sx61dj56777	5	15	for	for	ADP
sx61dj56777	5	16	their	their	PRON
sx61dj56777	5	17	ability	ability	NOUN
sx61dj56777	5	18	to	to	PART
sx61dj56777	5	19	participate	participate	VERB
sx61dj56777	5	20	in	in	ADP
sx61dj56777	5	21	mlc	mlc	ADJ
sx61dj56777	5	22	-	-	PUNCT
sx61dj56777	5	23	type	type	NOUN
sx61dj56777	5	24	reactivity	reactivity	NOUN
sx61dj56777	5	25	on	on	ADP
sx61dj56777	5	26	a	a	DET
sx61dj56777	5	27	variety	variety	NOUN
sx61dj56777	5	28	of	of	ADP
sx61dj56777	5	29	different	different	ADJ
sx61dj56777	5	30	metal	metal	NOUN
sx61dj56777	5	31	centers	center	NOUN
sx61dj56777	5	32	.	.	PUNCT
sx61dj56777	6	1	more	more	ADV
sx61dj56777	6	2	specifically	specifically	ADV
sx61dj56777	6	3	,	,	PUNCT
sx61dj56777	6	4	transition	transition	NOUN
sx61dj56777	6	5	metal	metal	NOUN
sx61dj56777	6	6	carbenes	carbene	NOUN
sx61dj56777	6	7	bearing	bear	VERB
sx61dj56777	6	8	the	the	DET
sx61dj56777	6	9	[	[	X
sx61dj56777	6	10	pc(sp2)p	pc(sp2)p	NOUN
sx61dj56777	6	11	]	]	X
sx61dj56777	6	12	pincer	pincer	NOUN
sx61dj56777	6	13	framework	framework	NOUN
sx61dj56777	6	14	exhibit	exhibit	VERB
sx61dj56777	6	15	unique	unique	ADJ
sx61dj56777	6	16	reactivity	reactivity	NOUN
sx61dj56777	6	17	,	,	PUNCT
sx61dj56777	6	18	including	include	VERB
sx61dj56777	6	19	cooperative	cooperative	ADJ
sx61dj56777	6	20	1,2	1,2	NOUN
sx61dj56777	6	21	-	-	PUNCT
sx61dj56777	6	22	additions	addition	NOUN
sx61dj56777	6	23	across	across	ADP
sx61dj56777	6	24	the	the	DET
sx61dj56777	6	25	m	m	NOUN
sx61dj56777	6	26	-	-	PUNCT
sx61dj56777	6	27	ccarbene	ccarbene	ADJ
sx61dj56777	6	28	bond	bond	NOUN
sx61dj56777	6	29	when	when	SCONJ
sx61dj56777	6	30	treated	treat	VERB
sx61dj56777	6	31	with	with	ADP
sx61dj56777	6	32	polar	polar	ADJ
sx61dj56777	6	33	substrates.this	substrates.this	DET
sx61dj56777	6	34	work	work	NOUN
sx61dj56777	6	35	in	in	ADP
sx61dj56777	6	36	mind	mind	NOUN
sx61dj56777	6	37	,	,	PUNCT
sx61dj56777	6	38	efforts	effort	NOUN
sx61dj56777	6	39	towards	towards	ADP
sx61dj56777	6	40	expanding	expand	VERB
sx61dj56777	6	41	the	the	DET
sx61dj56777	6	42	[	[	X
sx61dj56777	6	43	pc(sp2)p	pc(sp2)p	NOUN
sx61dj56777	6	44	]	]	X
sx61dj56777	6	45	ligand	ligand	NOUN
sx61dj56777	6	46	system	system	NOUN
sx61dj56777	6	47	to	to	ADP
sx61dj56777	6	48	an	an	DET
sx61dj56777	6	49	iron	iron	NOUN
sx61dj56777	6	50	metal	metal	NOUN
sx61dj56777	6	51	center	center	NOUN
sx61dj56777	6	52	were	be	AUX
sx61dj56777	6	53	explored	explore	VERB
sx61dj56777	6	54	and	and	CCONJ
sx61dj56777	6	55	the	the	DET
sx61dj56777	6	56	optimal	optimal	ADJ
sx61dj56777	6	57	synthetic	synthetic	ADJ
sx61dj56777	6	58	route	route	NOUN
sx61dj56777	6	59	was	be	AUX
sx61dj56777	6	60	discovered	discover	VERB
sx61dj56777	6	61	.	.	PUNCT
sx61dj56777	7	1	reactivity	reactivity	NOUN
sx61dj56777	7	2	studies	study	NOUN
sx61dj56777	7	3	of	of	ADP
sx61dj56777	7	4	the	the	DET
sx61dj56777	7	5	resulting[{pc(sp2)p}fe(pme3)(n2	resulting[{pc(sp2)p}fe(pme3)(n2	PROPN
sx61dj56777	7	6	)	)	PUNCT
sx61dj56777	7	7	]	]	PUNCT
sx61dj56777	7	8	complex	complex	NOUN
sx61dj56777	7	9	with	with	ADP
sx61dj56777	7	10	styrene	styrene	NOUN
sx61dj56777	7	11	and	and	CCONJ
sx61dj56777	7	12	select	select	ADJ
sx61dj56777	7	13	alkynes	alkyne	NOUN
sx61dj56777	7	14	were	be	AUX
sx61dj56777	7	15	investigated	investigate	VERB
sx61dj56777	7	16	.	.	PUNCT
sx61dj56777	8	1	the	the	DET
sx61dj56777	8	2	reactivity	reactivity	NOUN
sx61dj56777	8	3	displayed	display	VERB
sx61dj56777	8	4	in	in	ADP
sx61dj56777	8	5	the	the	DET
sx61dj56777	8	6	presence	presence	NOUN
sx61dj56777	8	7	of	of	ADP
sx61dj56777	8	8	substrates	substrate	NOUN
sx61dj56777	8	9	containing	contain	VERB
sx61dj56777	8	10	π	π	PROPN
sx61dj56777	8	11	character	character	NOUN
sx61dj56777	8	12	is	be	AUX
sx61dj56777	8	13	not	not	PART
sx61dj56777	8	14	only	only	ADV
sx61dj56777	8	15	novel	novel	ADJ
sx61dj56777	8	16	to	to	ADP
sx61dj56777	8	17	the	the	DET
sx61dj56777	8	18	reactivity	reactivity	NOUN
sx61dj56777	8	19	exhibited	exhibit	VERB
sx61dj56777	8	20	by	by	ADP
sx61dj56777	8	21	other	other	ADJ
sx61dj56777	8	22	[	[	PUNCT
sx61dj56777	8	23	pc(sp2)p	pc(sp2)p	ADJ
sx61dj56777	8	24	]	]	PUNCT
sx61dj56777	8	25	complexes	complex	NOUN
sx61dj56777	8	26	,	,	PUNCT
sx61dj56777	8	27	but	but	CCONJ
sx61dj56777	8	28	also	also	ADV
sx61dj56777	8	29	,	,	PUNCT
sx61dj56777	8	30	all	all	DET
sx61dj56777	8	31	previously	previously	ADV
sx61dj56777	8	32	synthesized	synthesize	VERB
sx61dj56777	8	33	iron	iron	NOUN
sx61dj56777	8	34	carbene	carbene	NOUN
sx61dj56777	8	35	complexes	complex	NOUN
sx61dj56777	8	36	.	.	PUNCT
sx61dj56777	9	1	furthermore	furthermore	ADV
sx61dj56777	9	2	,	,	PUNCT
sx61dj56777	9	3	the	the	DET
sx61dj56777	9	4	iluc	iluc	NOUN
sx61dj56777	9	5	lab	lab	NOUN
sx61dj56777	9	6	has	have	AUX
sx61dj56777	9	7	extensively	extensively	ADV
sx61dj56777	9	8	studied	study	VERB
sx61dj56777	9	9	the	the	DET
sx61dj56777	9	10	reactivity	reactivity	NOUN
sx61dj56777	9	11	of	of	ADP
sx61dj56777	9	12	a	a	DET
sx61dj56777	9	13	nucleophilic	nucleophilic	ADJ
sx61dj56777	9	14	palladium(ii	palladium(ii	PROPN
sx61dj56777	9	15	)	)	PUNCT
sx61dj56777	9	16	carbene	carbene	NOUN
sx61dj56777	9	17	complex	complex	NOUN
sx61dj56777	9	18	,	,	PUNCT
sx61dj56777	9	19	[	[	X
sx61dj56777	9	20	{	{	PUNCT
sx61dj56777	9	21	pc(sp2)p}pd(pme3	pc(sp2)p}pd(pme3	PROPN
sx61dj56777	9	22	)	)	PUNCT
sx61dj56777	9	23	]	]	PUNCT
sx61dj56777	9	24	.	.	PUNCT
sx61dj56777	10	1	as	as	ADP
sx61dj56777	10	2	a	a	DET
sx61dj56777	10	3	continuation	continuation	NOUN
sx61dj56777	10	4	of	of	ADP
sx61dj56777	10	5	this	this	DET
sx61dj56777	10	6	work	work	NOUN
sx61dj56777	10	7	,	,	PUNCT
sx61dj56777	10	8	[	[	X
sx61dj56777	10	9	{	{	PUNCT
sx61dj56777	10	10	pc(sp2)p}pd(pme3	pc(sp2)p}pd(pme3	PROPN
sx61dj56777	10	11	)	)	PUNCT
sx61dj56777	10	12	]	]	PUNCT
sx61dj56777	10	13	was	be	AUX
sx61dj56777	10	14	treated	treat	VERB
sx61dj56777	10	15	with	with	ADP
sx61dj56777	10	16	h2o	h2o	PRON
sx61dj56777	10	17	to	to	PART
sx61dj56777	10	18	further	far	ADV
sx61dj56777	10	19	elucidate	elucidate	VERB
sx61dj56777	10	20	its	its	PRON
sx61dj56777	10	21	small	small	ADJ
sx61dj56777	10	22	molecule	molecule	NOUN
sx61dj56777	10	23	activation	activation	NOUN
sx61dj56777	10	24	competencies	competency	NOUN
sx61dj56777	10	25	.	.	PUNCT
sx61dj56777	11	1	results	result	NOUN
sx61dj56777	11	2	indicated	indicate	VERB
sx61dj56777	11	3	that	that	SCONJ
sx61dj56777	11	4	the	the	DET
sx61dj56777	11	5	second	second	ADJ
sx61dj56777	11	6	activation	activation	NOUN
sx61dj56777	11	7	of	of	ADP
sx61dj56777	11	8	water	water	NOUN
sx61dj56777	11	9	proceeded	proceed	VERB
sx61dj56777	11	10	through	through	ADP
sx61dj56777	11	11	µ-oxo	µ-oxo	PROPN
sx61dj56777	11	12	species	specie	NOUN
sx61dj56777	11	13	and	and	CCONJ
sx61dj56777	11	14	prompted	prompt	VERB
sx61dj56777	11	15	the	the	DET
sx61dj56777	11	16	synthesis	synthesis	NOUN
sx61dj56777	11	17	of	of	ADP
sx61dj56777	11	18	a	a	DET
sx61dj56777	11	19	µ-sulfide	µ-sulfide	NOUN
sx61dj56777	11	20	dimer	dimer	NOUN
sx61dj56777	11	21	through	through	ADP
sx61dj56777	11	22	treatment	treatment	NOUN
sx61dj56777	11	23	of	of	ADP
sx61dj56777	11	24	the	the	DET
sx61dj56777	11	25	palladium	palladium	NOUN
sx61dj56777	11	26	carbene	carbene	NOUN
sx61dj56777	11	27	with	with	ADP
sx61dj56777	11	28	h2s	h2s	PROPN
sx61dj56777	11	29	.	.	PUNCT
sx61dj56777	12	1	additional	additional	ADJ
sx61dj56777	12	2	work	work	NOUN
sx61dj56777	12	3	with	with	ADP
sx61dj56777	12	4	[	[	X
sx61dj56777	12	5	{	{	PUNCT
sx61dj56777	12	6	pc(sp2)p}pd(pme3	pc(sp2)p}pd(pme3	PROPN
sx61dj56777	12	7	)	)	PUNCT
sx61dj56777	12	8	]	]	PUNCT
sx61dj56777	12	9	focused	focus	VERB
sx61dj56777	12	10	on	on	ADP
sx61dj56777	12	11	the	the	DET
sx61dj56777	12	12	ancillary	ancillary	ADJ
sx61dj56777	12	13	ligands	ligand	NOUN
sx61dj56777	12	14	effect	effect	NOUN
sx61dj56777	12	15	on	on	ADP
sx61dj56777	12	16	reactivity	reactivity	NOUN
sx61dj56777	12	17	and	and	CCONJ
sx61dj56777	12	18	stability	stability	NOUN
sx61dj56777	12	19	of	of	ADP
sx61dj56777	12	20	the	the	DET
sx61dj56777	12	21	4	4	NUM
sx61dj56777	12	22	-	-	PUNCT
sx61dj56777	12	23	coordinate	coordinate	NOUN
sx61dj56777	12	24	carbene	carbene	NOUN
sx61dj56777	12	25	system	system	NOUN
sx61dj56777	12	26	.	.	PUNCT