id sid tid token lemma pos sn009w06925 1 1 in in ADP sn009w06925 1 2 this this DET sn009w06925 1 3 dissertation dissertation NOUN sn009w06925 1 4 i i PRON sn009w06925 1 5 present present VERB sn009w06925 1 6 work work NOUN sn009w06925 1 7 on on ADP sn009w06925 1 8 the the DET sn009w06925 1 9 factors factor NOUN sn009w06925 1 10 important important ADJ sn009w06925 1 11 to to PART sn009w06925 1 12 heat heat VERB sn009w06925 1 13 transport transport NOUN sn009w06925 1 14 in in ADP sn009w06925 1 15 gold gold NOUN sn009w06925 1 16 nanostructures nanostructure NOUN sn009w06925 1 17 , , PUNCT sn009w06925 1 18 particularly particularly ADV sn009w06925 1 19 nanoparticles nanoparticle NOUN sn009w06925 1 20 . . PUNCT sn009w06925 2 1 i i PRON sn009w06925 2 2 examine examine VERB sn009w06925 2 3 the the DET sn009w06925 2 4 effect effect NOUN sn009w06925 2 5 of of ADP sn009w06925 2 6 particle particle NOUN sn009w06925 2 7 size size NOUN sn009w06925 2 8 , , PUNCT sn009w06925 2 9 ligand ligand NOUN sn009w06925 2 10 layer layer NOUN sn009w06925 2 11 rigidity rigidity NOUN sn009w06925 2 12 , , PUNCT sn009w06925 2 13 and and CCONJ sn009w06925 2 14 surface surface VERB sn009w06925 2 15 gold gold NOUN sn009w06925 2 16 vibrational vibrational ADJ sn009w06925 2 17 freedom freedom NOUN sn009w06925 2 18 . . PUNCT sn009w06925 3 1 the the DET sn009w06925 3 2 interfacial interfacial ADJ sn009w06925 3 3 thermal thermal ADJ sn009w06925 3 4 conductance conductance NOUN sn009w06925 3 5 of of ADP sn009w06925 3 6 various various ADJ sn009w06925 3 7 particle particle NOUN sn009w06925 3 8 morphologies morphology NOUN sn009w06925 3 9 , , PUNCT sn009w06925 3 10 as as ADV sn009w06925 3 11 well well ADV sn009w06925 3 12 as as ADP sn009w06925 3 13 the the DET sn009w06925 3 14 thermal thermal ADJ sn009w06925 3 15 conductivity conductivity NOUN sn009w06925 3 16 of of ADP sn009w06925 3 17 nanoarrays nanoarray NOUN sn009w06925 3 18 , , PUNCT sn009w06925 3 19 display display NOUN sn009w06925 3 20 trends trend NOUN sn009w06925 3 21 of of ADP sn009w06925 3 22 how how SCONJ sn009w06925 3 23 heat heat NOUN sn009w06925 3 24 transport transport NOUN sn009w06925 3 25 is be AUX sn009w06925 3 26 affected affect VERB sn009w06925 3 27 by by ADP sn009w06925 3 28 particle particle NOUN sn009w06925 3 29 size size NOUN sn009w06925 3 30 , , PUNCT sn009w06925 3 31 shape shape NOUN sn009w06925 3 32 , , PUNCT sn009w06925 3 33 and and CCONJ sn009w06925 3 34 volume volume NOUN sn009w06925 3 35 fraction fraction NOUN sn009w06925 3 36 of of ADP sn009w06925 3 37 a a DET sn009w06925 3 38 system system NOUN sn009w06925 3 39 . . PUNCT sn009w06925 4 1 direct direct ADJ sn009w06925 4 2 simulations simulation NOUN sn009w06925 4 3 of of ADP sn009w06925 4 4 interfacial interfacial ADJ sn009w06925 4 5 thermal thermal ADJ sn009w06925 4 6 conductance conductance NOUN sn009w06925 4 7 of of ADP sn009w06925 4 8 solvated solvate VERB sn009w06925 4 9 gold gold NOUN sn009w06925 4 10 nanoparticles nanoparticle NOUN sn009w06925 4 11 were be AUX sn009w06925 4 12 carried carry VERB sn009w06925 4 13 out out ADP sn009w06925 4 14 using use VERB sn009w06925 4 15 molecular molecular ADJ sn009w06925 4 16 dynamics.nanoparticles dynamics.nanoparticle NOUN sn009w06925 4 17 created create VERB sn009w06925 4 18 in in ADP sn009w06925 4 19 vitro vitro X sn009w06925 4 20 contain contain VERB sn009w06925 4 21 a a DET sn009w06925 4 22 ligand ligand NOUN sn009w06925 4 23 layer layer NOUN sn009w06925 4 24 at at ADP sn009w06925 4 25 the the DET sn009w06925 4 26 surface surface NOUN sn009w06925 4 27 of of ADP sn009w06925 4 28 each each DET sn009w06925 4 29 particle particle NOUN sn009w06925 4 30 that that PRON sn009w06925 4 31 prevents prevent VERB sn009w06925 4 32 aggregation aggregation NOUN sn009w06925 4 33 and and CCONJ sn009w06925 4 34 is be AUX sn009w06925 4 35 a a DET sn009w06925 4 36 result result NOUN sn009w06925 4 37 of of ADP sn009w06925 4 38 the the DET sn009w06925 4 39 method method NOUN sn009w06925 4 40 used use VERB sn009w06925 4 41 in in ADP sn009w06925 4 42 the the DET sn009w06925 4 43 synthesis synthesis NOUN sn009w06925 4 44 of of ADP sn009w06925 4 45 the the DET sn009w06925 4 46 particles particle NOUN sn009w06925 4 47 . . PUNCT sn009w06925 5 1 this this DET sn009w06925 5 2 moiety moiety NOUN sn009w06925 5 3 controls control VERB sn009w06925 5 4 the the DET sn009w06925 5 5 movement movement NOUN sn009w06925 5 6 of of ADP sn009w06925 5 7 heat heat NOUN sn009w06925 5 8 from from ADP sn009w06925 5 9 a a DET sn009w06925 5 10 particle particle NOUN sn009w06925 5 11 to to ADP sn009w06925 5 12 the the DET sn009w06925 5 13 surrounding surround VERB sn009w06925 5 14 media medium NOUN sn009w06925 5 15 . . PUNCT sn009w06925 6 1 in in ADP sn009w06925 6 2 particular particular ADJ sn009w06925 6 3 , , PUNCT sn009w06925 6 4 looking look VERB sn009w06925 6 5 closely closely ADV sn009w06925 6 6 at at ADP sn009w06925 6 7 how how SCONJ sn009w06925 6 8 the the DET sn009w06925 6 9 rigidity rigidity NOUN sn009w06925 6 10 of of ADP sn009w06925 6 11 this this DET sn009w06925 6 12 ligand ligand NOUN sn009w06925 6 13 layer layer NOUN sn009w06925 6 14 ( ( PUNCT sn009w06925 6 15 and and CCONJ sn009w06925 6 16 the the DET sn009w06925 6 17 length length NOUN sn009w06925 6 18 of of ADP sn009w06925 6 19 the the DET sn009w06925 6 20 ligand ligand NOUN sn009w06925 6 21 ) ) PUNCT sn009w06925 6 22 change change VERB sn009w06925 6 23 thermal thermal ADJ sn009w06925 6 24 transport transport NOUN sn009w06925 6 25 across across ADP sn009w06925 6 26 the the DET sn009w06925 6 27 solvent solvent ADJ sn009w06925 6 28 - - PUNCT sn009w06925 6 29 particle particle NOUN sn009w06925 6 30 interface interface NOUN sn009w06925 6 31 . . PUNCT sn009w06925 7 1 this this PRON sn009w06925 7 2 provides provide VERB sn009w06925 7 3 further further ADJ sn009w06925 7 4 insight insight NOUN sn009w06925 7 5 into into ADP sn009w06925 7 6 the the DET sn009w06925 7 7 factors factor NOUN sn009w06925 7 8 that that PRON sn009w06925 7 9 govern govern VERB sn009w06925 7 10 heat heat NOUN sn009w06925 7 11 flow flow NOUN sn009w06925 7 12 . . PUNCT sn009w06925 8 1 proposed propose VERB sn009w06925 8 2 mechanisms mechanism NOUN sn009w06925 8 3 for for ADP sn009w06925 8 4 heat heat NOUN sn009w06925 8 5 transfer transfer NOUN sn009w06925 8 6 rely rely VERB sn009w06925 8 7 on on ADP sn009w06925 8 8 two two NUM sn009w06925 8 9 effects effect NOUN sn009w06925 8 10 : : PUNCT sn009w06925 8 11 the the DET sn009w06925 8 12 vibrational vibrational ADJ sn009w06925 8 13 spectral spectral ADJ sn009w06925 8 14 overlap overlap NOUN sn009w06925 8 15 of of ADP sn009w06925 8 16 the the DET sn009w06925 8 17 materials material NOUN sn009w06925 8 18 at at ADP sn009w06925 8 19 the the DET sn009w06925 8 20 interface interface NOUN sn009w06925 8 21 and and CCONJ sn009w06925 8 22 the the DET sn009w06925 8 23 physical physical ADJ sn009w06925 8 24 contact contact NOUN sn009w06925 8 25 between between ADP sn009w06925 8 26 the the DET sn009w06925 8 27 same same ADJ sn009w06925 8 28 materials.finding materials.finde VERB sn009w06925 8 29 no no DET sn009w06925 8 30 direct direct ADJ sn009w06925 8 31 relationship relationship NOUN sn009w06925 8 32 between between ADP sn009w06925 8 33 particle particle NOUN sn009w06925 8 34 size size NOUN sn009w06925 8 35 with with ADP sn009w06925 8 36 the the DET sn009w06925 8 37 ligand ligand NOUN sn009w06925 8 38 layer layer NOUN sn009w06925 8 39 and and CCONJ sn009w06925 8 40 the the DET sn009w06925 8 41 thermal thermal ADJ sn009w06925 8 42 transport transport NOUN sn009w06925 8 43 , , PUNCT sn009w06925 8 44 a a DET sn009w06925 8 45 simpler simple ADJ sn009w06925 8 46 system system NOUN sn009w06925 8 47 was be AUX sn009w06925 8 48 examined examine VERB sn009w06925 8 49 : : PUNCT sn009w06925 8 50 bare bare ADJ sn009w06925 8 51 nanoparticles nanoparticle NOUN sn009w06925 8 52 in in ADP sn009w06925 8 53 a a DET sn009w06925 8 54 non non ADJ sn009w06925 8 55 - - ADJ sn009w06925 8 56 polar polar ADJ sn009w06925 8 57 solvent solvent NOUN sn009w06925 8 58 . . PUNCT sn009w06925 9 1 the the DET sn009w06925 9 2 particles particle NOUN sn009w06925 9 3 consist consist VERB sn009w06925 9 4 of of ADP sn009w06925 9 5 nanospheres nanosphere NOUN sn009w06925 9 6 , , PUNCT sn009w06925 9 7 icosahedra icosahedron NOUN sn009w06925 9 8 , , PUNCT sn009w06925 9 9 and and CCONJ sn009w06925 9 10 cuboctahedra cuboctahedra NOUN sn009w06925 9 11 . . PUNCT sn009w06925 10 1 the the DET sn009w06925 10 2 latter latter ADJ sn009w06925 10 3 two two NUM sn009w06925 10 4 structures structure NOUN sn009w06925 10 5 display display NOUN sn009w06925 10 6 facets facet NOUN sn009w06925 10 7 that that PRON sn009w06925 10 8 are be AUX sn009w06925 10 9 common common ADJ sn009w06925 10 10 in in ADP sn009w06925 10 11 many many ADJ sn009w06925 10 12 nanostructures nanostructure NOUN sn009w06925 10 13 due due ADJ sn009w06925 10 14 to to ADP sn009w06925 10 15 their their PRON sn009w06925 10 16 stability stability NOUN sn009w06925 10 17 . . PUNCT sn009w06925 11 1 the the DET sn009w06925 11 2 interfacial interfacial ADJ sn009w06925 11 3 thermal thermal ADJ sn009w06925 11 4 conductance conductance NOUN sn009w06925 11 5 ( ( PUNCT sn009w06925 11 6 g g NOUN sn009w06925 11 7 ) ) PUNCT sn009w06925 11 8 of of ADP sn009w06925 11 9 the the DET sn009w06925 11 10 particles particle NOUN sn009w06925 11 11 was be AUX sn009w06925 11 12 examined examine VERB sn009w06925 11 13 as as ADP sn009w06925 11 14 a a DET sn009w06925 11 15 function function NOUN sn009w06925 11 16 of of ADP sn009w06925 11 17 particle particle NOUN sn009w06925 11 18 radius radius NOUN sn009w06925 11 19 and and CCONJ sn009w06925 11 20 morphology morphology NOUN sn009w06925 11 21 . . PUNCT sn009w06925 12 1 the the DET sn009w06925 12 2 coordination coordination NOUN sn009w06925 12 3 of of ADP sn009w06925 12 4 gold gold NOUN sn009w06925 12 5 atoms atom NOUN sn009w06925 12 6 at at ADP sn009w06925 12 7 the the DET sn009w06925 12 8 particle particle NOUN sn009w06925 12 9 surface surface NOUN sn009w06925 12 10 , , PUNCT sn009w06925 12 11 which which PRON sn009w06925 12 12 provides provide VERB sn009w06925 12 13 information information NOUN sn009w06925 12 14 about about ADP sn009w06925 12 15 the the DET sn009w06925 12 16 vibrational vibrational ADJ sn009w06925 12 17 spectrum spectrum NOUN sn009w06925 12 18 , , PUNCT sn009w06925 12 19 displayed display VERB sn009w06925 12 20 a a DET sn009w06925 12 21 small small ADJ sn009w06925 12 22 correlation correlation NOUN sn009w06925 12 23 with with ADP sn009w06925 12 24 g. g. NOUN sn009w06925 12 25 this this PRON sn009w06925 12 26 lends lend VERB sn009w06925 12 27 support support NOUN sn009w06925 12 28 to to ADP sn009w06925 12 29 the the DET sn009w06925 12 30 proposed propose VERB sn009w06925 12 31 factors factor NOUN sn009w06925 12 32 for for ADP sn009w06925 12 33 heat heat NOUN sn009w06925 12 34 transport transport NOUN sn009w06925 12 35 that that PRON sn009w06925 12 36 were be AUX sn009w06925 12 37 discovered discover VERB sn009w06925 12 38 while while SCONJ sn009w06925 12 39 investigating investigate VERB sn009w06925 12 40 ligands.the ligands.the DET sn009w06925 12 41 ideas idea NOUN sn009w06925 12 42 from from ADP sn009w06925 12 43 both both DET sn009w06925 12 44 previous previous ADJ sn009w06925 12 45 chapters chapter NOUN sn009w06925 12 46 are be AUX sn009w06925 12 47 combined combine VERB sn009w06925 12 48 to to PART sn009w06925 12 49 study study VERB sn009w06925 12 50 au<sub>144>/sub>pet<sub>60</sub> au<sub>144>/sub>pet<sub>60</sub> ADJ sn009w06925 12 51 ; ; PUNCT sn009w06925 12 52 particles particle NOUN sn009w06925 12 53 , , PUNCT sn009w06925 12 54 in in ADP sn009w06925 12 55 both both DET sn009w06925 12 56 isolation isolation NOUN sn009w06925 12 57 , , PUNCT sn009w06925 12 58 and and CCONJ sn009w06925 12 59 in in ADP sn009w06925 12 60 a a DET sn009w06925 12 61 nanoarray nanoarray NOUN sn009w06925 12 62 . . PUNCT sn009w06925 13 1 these these DET sn009w06925 13 2 small small ADJ sn009w06925 13 3 particles particle NOUN sn009w06925 13 4 ( ( PUNCT sn009w06925 13 5 r r X sn009w06925 13 6 & & CCONJ sn009w06925 13 7 amp;asymp amp;asymp SPACE sn009w06925 13 8 ; ; PUNCT sn009w06925 13 9 10 10 NUM sn009w06925 13 10 a a X sn009w06925 13 11 ) ) PUNCT sn009w06925 13 12 have have VERB sn009w06925 13 13 highly highly ADV sn009w06925 13 14 undercoordinated undercoordinated ADJ sn009w06925 13 15 gold gold NOUN sn009w06925 13 16 atoms atom NOUN sn009w06925 13 17 in in ADP sn009w06925 13 18 the the DET sn009w06925 13 19 ligand ligand NOUN sn009w06925 13 20 layer layer NOUN sn009w06925 13 21 . . PUNCT sn009w06925 14 1 the the DET sn009w06925 14 2 thermal thermal ADJ sn009w06925 14 3 conductivity conductivity NOUN sn009w06925 14 4 of of ADP sn009w06925 14 5 the the DET sn009w06925 14 6 composite composite ADJ sn009w06925 14 7 material material NOUN sn009w06925 14 8 is be AUX sn009w06925 14 9 predicted predict VERB sn009w06925 14 10 using use VERB sn009w06925 14 11 bulk bulk ADJ sn009w06925 14 12 properties property NOUN sn009w06925 14 13 and and CCONJ sn009w06925 14 14 an an DET sn009w06925 14 15 estimation estimation NOUN sn009w06925 14 16 of of ADP sn009w06925 14 17 boundary boundary ADJ sn009w06925 14 18 resistance resistance NOUN sn009w06925 14 19 . . PUNCT sn009w06925 15 1 this this DET sn009w06925 15 2 prediction prediction NOUN sn009w06925 15 3 uses use VERB sn009w06925 15 4 individual individual ADJ sn009w06925 15 5 components component NOUN sn009w06925 15 6 of of ADP sn009w06925 15 7 the the DET sn009w06925 15 8 composite composite ADJ sn009w06925 15 9 systems system NOUN sn009w06925 15 10 , , PUNCT sn009w06925 15 11 and and CCONJ sn009w06925 15 12 is be AUX sn009w06925 15 13 compared compare VERB sn009w06925 15 14 to to ADP sn009w06925 15 15 results result NOUN sn009w06925 15 16 for for ADP sn009w06925 15 17 simulated simulated ADJ sn009w06925 15 18 nanoarrays nanoarray NOUN sn009w06925 15 19 . . PUNCT sn009w06925 16 1 in in ADP sn009w06925 16 2 the the DET sn009w06925 16 3 predicted predict VERB sn009w06925 16 4 conductivity conductivity NOUN sn009w06925 16 5 , , PUNCT sn009w06925 16 6 the the DET sn009w06925 16 7 nanoarray nanoarray ADJ sn009w06925 16 8 thermal thermal ADJ sn009w06925 16 9 conductivity conductivity NOUN sn009w06925 16 10 depends depend VERB sn009w06925 16 11 mostly mostly ADV sn009w06925 16 12 on on ADP sn009w06925 16 13 the the DET sn009w06925 16 14 geometric geometric ADJ sn009w06925 16 15 feature feature NOUN sn009w06925 16 16 , , PUNCT sn009w06925 16 17 v<sub>p</sub> v<sub>p</sub> PROPN sn009w06925 16 18 ; ; PUNCT sn009w06925 16 19 , , PUNCT sn009w06925 16 20 the the DET sn009w06925 16 21 particle particle NOUN sn009w06925 16 22 volume volume NOUN sn009w06925 16 23 fraction fraction NOUN sn009w06925 16 24 . . PUNCT