id	sid	tid	token	lemma	pos
qr46qz23722	1	1	this	this	DET
qr46qz23722	1	2	thesis	thesis	NOUN
qr46qz23722	1	3	describes	describe	VERB
qr46qz23722	1	4	the	the	DET
qr46qz23722	1	5	progress	progress	NOUN
qr46qz23722	1	6	on	on	ADP
qr46qz23722	1	7	three	three	NUM
qr46qz23722	1	8	different	different	ADJ
qr46qz23722	1	9	methodology	methodology	NOUN
qr46qz23722	1	10	projects	project	NOUN
qr46qz23722	1	11	and	and	CCONJ
qr46qz23722	1	12	two	two	NUM
qr46qz23722	1	13	multistep	multistep	ADJ
qr46qz23722	1	14	syntheses	synthesis	NOUN
qr46qz23722	1	15	of	of	ADP
qr46qz23722	1	16	a	a	DET
qr46qz23722	1	17	complex	complex	ADJ
qr46qz23722	1	18	molecule	molecule	NOUN
qr46qz23722	1	19	.	.	PUNCT
qr46qz23722	2	1	specifically	specifically	ADV
qr46qz23722	2	2	,	,	PUNCT
qr46qz23722	2	3	we	we	PRON
qr46qz23722	2	4	have	have	AUX
qr46qz23722	2	5	synthesized	synthesize	VERB
qr46qz23722	2	6	a	a	DET
qr46qz23722	2	7	single	single	ADJ
qr46qz23722	2	8	isomer	isomer	NOUN
qr46qz23722	2	9	of	of	ADP
qr46qz23722	2	10	a	a	DET
qr46qz23722	2	11	bis(siloxy)diene	bis(siloxy)diene	NUM
qr46qz23722	2	12	.	.	PUNCT
qr46qz23722	3	1	to	to	PART
qr46qz23722	3	2	accomplish	accomplish	VERB
qr46qz23722	3	3	the	the	DET
qr46qz23722	3	4	synthesis	synthesis	NOUN
qr46qz23722	3	5	of	of	ADP
qr46qz23722	3	6	bis(siloxy)diene	bis(siloxy)diene	NUM
qr46qz23722	3	7	,	,	PUNCT
qr46qz23722	3	8	we	we	PRON
qr46qz23722	3	9	had	have	VERB
qr46qz23722	3	10	to	to	PART
qr46qz23722	3	11	screen	screen	VERB
qr46qz23722	3	12	for	for	ADP
qr46qz23722	3	13	conditions	condition	NOUN
qr46qz23722	3	14	to	to	PART
qr46qz23722	3	15	produce	produce	VERB
qr46qz23722	3	16	a	a	DET
qr46qz23722	3	17	single	single	ADJ
qr46qz23722	3	18	isomer	isomer	NOUN
qr46qz23722	3	19	of	of	ADP
qr46qz23722	3	20	its	its	PRON
qr46qz23722	3	21	mono(silyl)enol	mono(silyl)enol	PROPN
qr46qz23722	3	22	ether	ether	NOUN
qr46qz23722	3	23	.	.	PUNCT
qr46qz23722	4	1	additionally	additionally	ADV
qr46qz23722	4	2	,	,	PUNCT
qr46qz23722	4	3	a	a	DET
qr46qz23722	4	4	vinylogous	vinylogous	ADJ
qr46qz23722	4	5	horner	horner	NOUN
qr46qz23722	4	6	-	-	PUNCT
qr46qz23722	4	7	wadsworth	wadsworth	NOUN
qr46qz23722	4	8	-	-	PUNCT
qr46qz23722	4	9	emmons	emmon	NOUN
qr46qz23722	4	10	(	(	PUNCT
qr46qz23722	4	11	hwe	hwe	PROPN
qr46qz23722	4	12	)	)	PUNCT
qr46qz23722	4	13	reagent	reagent	NOUN
qr46qz23722	4	14	was	be	AUX
qr46qz23722	4	15	developed	develop	VERB
qr46qz23722	4	16	,	,	PUNCT
qr46qz23722	4	17	which	which	PRON
qr46qz23722	4	18	can	can	AUX
qr46qz23722	4	19	be	be	AUX
qr46qz23722	4	20	used	use	VERB
qr46qz23722	4	21	to	to	PART
qr46qz23722	4	22	provide	provide	VERB
qr46qz23722	4	23	4	4	NUM
qr46qz23722	4	24	-	-	PUNCT
qr46qz23722	4	25	methyldienoates	methyldienoate	NOUN
qr46qz23722	4	26	from	from	ADP
qr46qz23722	4	27	an	an	DET
qr46qz23722	4	28	aldehyde	aldehyde	NOUN
qr46qz23722	4	29	starting	start	VERB
qr46qz23722	4	30	material	material	NOUN
qr46qz23722	4	31	.	.	PUNCT
qr46qz23722	5	1	with	with	ADP
qr46qz23722	5	2	this	this	DET
qr46qz23722	5	3	hwe	hwe	PROPN
qr46qz23722	5	4	reagent	reagent	NOUN
qr46qz23722	5	5	,	,	PUNCT
qr46qz23722	5	6	we	we	PRON
qr46qz23722	5	7	have	have	AUX
qr46qz23722	5	8	synthesized	synthesize	VERB
qr46qz23722	5	9	trichostatic	trichostatic	ADJ
qr46qz23722	5	10	acid	acid	NOUN
qr46qz23722	5	11	through	through	ADP
qr46qz23722	5	12	an	an	DET
qr46qz23722	5	13	improved	improved	ADJ
qr46qz23722	5	14	method	method	NOUN
qr46qz23722	5	15	where	where	SCONJ
qr46qz23722	5	16	the	the	DET
qr46qz23722	5	17	diene	diene	NOUN
qr46qz23722	5	18	unit	unit	NOUN
qr46qz23722	5	19	is	be	AUX
qr46qz23722	5	20	installed	instal	VERB
qr46qz23722	5	21	in	in	ADP
qr46qz23722	5	22	one	one	NUM
qr46qz23722	5	23	step	step	NOUN
qr46qz23722	5	24	.	.	PUNCT
qr46qz23722	6	1	additionally	additionally	ADV
qr46qz23722	6	2	we	we	PRON
qr46qz23722	6	3	have	have	AUX
qr46qz23722	6	4	used	use	VERB
qr46qz23722	6	5	an	an	DET
qr46qz23722	6	6	analogous	analogous	ADJ
qr46qz23722	6	7	step	step	NOUN
qr46qz23722	6	8	-	-	PUNCT
qr46qz23722	6	9	wise	wise	ADJ
qr46qz23722	6	10	version	version	NOUN
qr46qz23722	6	11	of	of	ADP
qr46qz23722	6	12	this	this	DET
qr46qz23722	6	13	synthesis	synthesis	NOUN
qr46qz23722	6	14	to	to	PART
qr46qz23722	6	15	prepare	prepare	VERB
qr46qz23722	6	16	trichostatin	trichostatin	PROPN
qr46qz23722	6	17	a.	a.	NOUN
qr46qz23722	7	1	we	we	PRON
qr46qz23722	7	2	have	have	AUX
qr46qz23722	7	3	developed	develop	VERB
qr46qz23722	7	4	an	an	DET
qr46qz23722	7	5	efficient	efficient	ADJ
qr46qz23722	7	6	synthesis	synthesis	NOUN
qr46qz23722	7	7	of	of	ADP
qr46qz23722	7	8	1	1	NUM
qr46qz23722	7	9	-	-	PUNCT
qr46qz23722	7	10	a-13	a-13	PROPN
qr46qz23722	7	11	,	,	PUNCT
qr46qz23722	7	12	which	which	PRON
qr46qz23722	7	13	allowed	allow	VERB
qr46qz23722	7	14	us	we	PRON
qr46qz23722	7	15	to	to	PART
qr46qz23722	7	16	provide	provide	VERB
qr46qz23722	7	17	gram	gram	NOUN
qr46qz23722	7	18	quantities	quantity	NOUN
qr46qz23722	7	19	of	of	ADP
qr46qz23722	7	20	this	this	DET
qr46qz23722	7	21	pyrrolinone	pyrrolinone	NOUN
qr46qz23722	7	22	to	to	ADP
qr46qz23722	7	23	our	our	PRON
qr46qz23722	7	24	collaborators	collaborator	NOUN
qr46qz23722	7	25	for	for	ADP
qr46qz23722	7	26	biological	biological	ADJ
qr46qz23722	7	27	evaluation	evaluation	NOUN
qr46qz23722	7	28	as	as	ADP
qr46qz23722	7	29	a	a	DET
qr46qz23722	7	30	niemann	niemann	NOUN
qr46qz23722	7	31	-	-	PUNCT
qr46qz23722	7	32	pick	pick	NOUN
qr46qz23722	7	33	type	type	NOUN
qr46qz23722	7	34	c	c	NOUN
qr46qz23722	7	35	disease	disease	NOUN
qr46qz23722	7	36	(	(	PUNCT
qr46qz23722	7	37	np	np	PROPN
qr46qz23722	7	38	-	-	PUNCT
qr46qz23722	7	39	c	c	PROPN
qr46qz23722	7	40	)	)	PUNCT
qr46qz23722	7	41	therapeutic	therapeutic	NOUN
qr46qz23722	7	42	.	.	PUNCT
qr46qz23722	8	1	we	we	PRON
qr46qz23722	8	2	also	also	ADV
qr46qz23722	8	3	discuss	discuss	VERB
qr46qz23722	8	4	the	the	DET
qr46qz23722	8	5	synthesis	synthesis	NOUN
qr46qz23722	8	6	of	of	ADP
qr46qz23722	8	7	triazine	triazine	NOUN
qr46qz23722	8	8	2	2	NUM
qr46qz23722	8	9	-	-	SYM
qr46qz23722	8	10	a-1	a-1	PROPN
qr46qz23722	8	11	,	,	PUNCT
qr46qz23722	8	12	which	which	PRON
qr46qz23722	8	13	was	be	AUX
qr46qz23722	8	14	another	another	DET
qr46qz23722	8	15	np	np	ADJ
qr46qz23722	8	16	-	-	PUNCT
qr46qz23722	8	17	c	c	PROPN
qr46qz23722	8	18	drug	drug	NOUN
qr46qz23722	8	19	candidate	candidate	NOUN
qr46qz23722	8	20	.	.	PUNCT
qr46qz23722	9	1	we	we	PRON
qr46qz23722	9	2	also	also	ADV
qr46qz23722	9	3	report	report	VERB
qr46qz23722	9	4	on	on	ADP
qr46qz23722	9	5	the	the	DET
qr46qz23722	9	6	development	development	NOUN
qr46qz23722	9	7	of	of	ADP
qr46qz23722	9	8	a	a	DET
qr46qz23722	9	9	new	new	ADJ
qr46qz23722	9	10	aryl	aryl	ADJ
qr46qz23722	9	11	amination	amination	NOUN
qr46qz23722	9	12	protocol	protocol	NOUN
qr46qz23722	9	13	,	,	PUNCT
qr46qz23722	9	14	which	which	PRON
qr46qz23722	9	15	is	be	AUX
qr46qz23722	9	16	able	able	ADJ
qr46qz23722	9	17	to	to	PART
qr46qz23722	9	18	transform	transform	VERB
qr46qz23722	9	19	aryl	aryl	NOUN
qr46qz23722	9	20	iodides	iodide	NOUN
qr46qz23722	9	21	,	,	PUNCT
qr46qz23722	9	22	bromide	bromide	NOUN
qr46qz23722	9	23	,	,	PUNCT
qr46qz23722	9	24	chloride	chloride	PROPN
qr46qz23722	9	25	,	,	PUNCT
qr46qz23722	9	26	azides	azide	NOUN
qr46qz23722	9	27	,	,	PUNCT
qr46qz23722	9	28	and	and	CCONJ
qr46qz23722	9	29	nitro	nitro	PROPN
qr46qz23722	9	30	compounds	compound	VERB
qr46qz23722	9	31	into	into	ADP
qr46qz23722	9	32	the	the	DET
qr46qz23722	9	33	corresponding	corresponding	ADJ
qr46qz23722	9	34	aryl	aryl	NOUN
qr46qz23722	9	35	amines	amine	NOUN
qr46qz23722	9	36	.	.	PUNCT
qr46qz23722	10	1	with	with	ADP
qr46qz23722	10	2	this	this	DET
qr46qz23722	10	3	new	new	ADJ
qr46qz23722	10	4	method	method	NOUN
qr46qz23722	10	5	,	,	PUNCT
qr46qz23722	10	6	we	we	PRON
qr46qz23722	10	7	transformed	transform	VERB
qr46qz23722	10	8	1	1	NUM
qr46qz23722	10	9	-	-	PUNCT
qr46qz23722	10	10	a-13	a-13	PROPN
qr46qz23722	10	11	into	into	ADP
qr46qz23722	10	12	the	the	DET
qr46qz23722	10	13	corresponding	correspond	VERB
qr46qz23722	10	14	amine	amine	NOUN
qr46qz23722	10	15	to	to	PART
qr46qz23722	10	16	establish	establish	VERB
qr46qz23722	10	17	an	an	DET
qr46qz23722	10	18	sar	sar	NOUN
qr46qz23722	10	19	for	for	ADP
qr46qz23722	10	20	the	the	DET
qr46qz23722	10	21	pyrrolinones	pyrrolinone	NOUN
qr46qz23722	10	22	.	.	PUNCT
qr46qz23722	11	1	this	this	DET
qr46qz23722	11	2	amine	amine	NOUN
qr46qz23722	11	3	was	be	AUX
qr46qz23722	11	4	converted	convert	VERB
qr46qz23722	11	5	into	into	ADP
qr46qz23722	11	6	the	the	DET
qr46qz23722	11	7	corresponding	correspond	VERB
qr46qz23722	11	8	azide	azide	NOUN
qr46qz23722	11	9	1	1	NUM
qr46qz23722	11	10	-	-	PUNCT
qr46qz23722	11	11	a-13	a-13	PROPN
qr46qz23722	11	12	-	-	PUNCT
qr46qz23722	11	13	n3	n3	PROPN
qr46qz23722	11	14	for	for	ADP
qr46qz23722	11	15	a	a	DET
qr46qz23722	11	16	photoaffinity	photoaffinity	NOUN
qr46qz23722	11	17	labeling	labeling	NOUN
qr46qz23722	11	18	study	study	NOUN
qr46qz23722	11	19	.	.	PUNCT