id sid tid token lemma pos pg15bc41r6k 1 1 in in ADP pg15bc41r6k 1 2 this this DET pg15bc41r6k 1 3 dissertation dissertation NOUN pg15bc41r6k 1 4 , , PUNCT pg15bc41r6k 1 5 a a DET pg15bc41r6k 1 6 new new ADJ pg15bc41r6k 1 7 molecular molecular ADJ pg15bc41r6k 1 8 level level NOUN pg15bc41r6k 1 9 platform platform NOUN pg15bc41r6k 1 10 that that PRON pg15bc41r6k 1 11 can can AUX pg15bc41r6k 1 12 bear bear VERB pg15bc41r6k 1 13 single single ADJ pg15bc41r6k 1 14 transition transition NOUN pg15bc41r6k 1 15 metal metal NOUN pg15bc41r6k 1 16 active active ADJ pg15bc41r6k 1 17 sites site NOUN pg15bc41r6k 1 18 was be AUX pg15bc41r6k 1 19 introduced introduce VERB pg15bc41r6k 1 20 . . PUNCT pg15bc41r6k 2 1 the the DET pg15bc41r6k 2 2 new new ADJ pg15bc41r6k 2 3 platform platform NOUN pg15bc41r6k 2 4 was be AUX pg15bc41r6k 2 5 developed develop VERB pg15bc41r6k 2 6 by by ADP pg15bc41r6k 2 7 utilizing utilize VERB pg15bc41r6k 2 8 a a DET pg15bc41r6k 2 9 known know VERB pg15bc41r6k 2 10 synthetic synthetic ADJ pg15bc41r6k 2 11 method method NOUN pg15bc41r6k 2 12 of of ADP pg15bc41r6k 2 13 lacunary lacunary ADJ pg15bc41r6k 2 14 defect defect NOUN pg15bc41r6k 2 15 formation formation NOUN pg15bc41r6k 2 16 on on ADP pg15bc41r6k 2 17 well well ADV pg15bc41r6k 2 18 - - PUNCT pg15bc41r6k 2 19 defined define VERB pg15bc41r6k 2 20 polyoxometalate polyoxometalate NOUN pg15bc41r6k 2 21 ( ( PUNCT pg15bc41r6k 2 22 pom pom NOUN pg15bc41r6k 2 23 ) ) PUNCT pg15bc41r6k 2 24 structures structure NOUN pg15bc41r6k 2 25 and and CCONJ pg15bc41r6k 2 26 subsequent subsequent ADJ pg15bc41r6k 2 27 metalation metalation NOUN pg15bc41r6k 2 28 of of ADP pg15bc41r6k 2 29 formed form VERB pg15bc41r6k 2 30 defective defective ADJ pg15bc41r6k 2 31 vacancy vacancy NOUN pg15bc41r6k 2 32 . . PUNCT pg15bc41r6k 3 1 on on ADP pg15bc41r6k 3 2 the the DET pg15bc41r6k 3 3 lacunary lacunary ADJ pg15bc41r6k 3 4 defects defect NOUN pg15bc41r6k 3 5 of of ADP pg15bc41r6k 3 6 wells wells PROPN pg15bc41r6k 3 7 dawson dawson PROPN pg15bc41r6k 3 8 phosphor phosphor PROPN pg15bc41r6k 3 9 - - PUNCT pg15bc41r6k 3 10 tungstate tungstate NOUN pg15bc41r6k 3 11 structures structure NOUN pg15bc41r6k 3 12 , , PUNCT pg15bc41r6k 3 13 single single ADJ pg15bc41r6k 3 14 ni2 ni2 ADP pg15bc41r6k 3 15 + + NOUN pg15bc41r6k 3 16 active active ADJ pg15bc41r6k 3 17 sites site NOUN pg15bc41r6k 3 18 were be AUX pg15bc41r6k 3 19 isolated isolate VERB pg15bc41r6k 3 20 . . PUNCT pg15bc41r6k 4 1 upon upon SCONJ pg15bc41r6k 4 2 dispersion dispersion NOUN pg15bc41r6k 4 3 of of ADP pg15bc41r6k 4 4 ni ni PROPN pg15bc41r6k 4 5 substituted substitute VERB pg15bc41r6k 4 6 wells wells PROPN pg15bc41r6k 4 7 dawson dawson PROPN pg15bc41r6k 4 8 polyoxometalate polyoxometalate PROPN pg15bc41r6k 4 9 ( ( PUNCT pg15bc41r6k 4 10 ni ni PROPN pg15bc41r6k 4 11 - - PUNCT pg15bc41r6k 4 12 pom pom NOUN pg15bc41r6k 4 13 - - PUNCT pg15bc41r6k 4 14 wd wd NOUN pg15bc41r6k 4 15 ) ) PUNCT pg15bc41r6k 4 16 on on ADP pg15bc41r6k 4 17 sba-15 sba-15 PROPN pg15bc41r6k 4 18 , , PUNCT pg15bc41r6k 4 19 substituted substitute VERB pg15bc41r6k 4 20 ni ni PROPN pg15bc41r6k 4 21 sites site NOUN pg15bc41r6k 4 22 successfully successfully ADV pg15bc41r6k 4 23 converted convert VERB pg15bc41r6k 4 24 ethylene ethylene NOUN pg15bc41r6k 4 25 to to ADP pg15bc41r6k 4 26 linear linear VERB pg15bc41r6k 4 27 butene butene NOUN pg15bc41r6k 4 28 species specie NOUN pg15bc41r6k 4 29 and and CCONJ pg15bc41r6k 4 30 heavier heavy ADJ pg15bc41r6k 4 31 oligomers oligomer NOUN pg15bc41r6k 4 32 . . PUNCT pg15bc41r6k 5 1 ni ni PROPN pg15bc41r6k 5 2 - - PUNCT pg15bc41r6k 5 3 pom pom NOUN pg15bc41r6k 5 4 - - PUNCT pg15bc41r6k 5 5 wd wd NOUN pg15bc41r6k 5 6 catalysts catalyst NOUN pg15bc41r6k 5 7 yielded yield VERB pg15bc41r6k 5 8 resembling resemble VERB pg15bc41r6k 5 9 kinetic kinetic ADJ pg15bc41r6k 5 10 parameters parameter NOUN pg15bc41r6k 5 11 to to ADP pg15bc41r6k 5 12 those those PRON pg15bc41r6k 5 13 of of ADP pg15bc41r6k 5 14 other other ADJ pg15bc41r6k 5 15 solid solid ADJ pg15bc41r6k 5 16 nickel nickel NOUN pg15bc41r6k 5 17 catalysts catalyst NOUN pg15bc41r6k 5 18 such such ADJ pg15bc41r6k 5 19 as as ADP pg15bc41r6k 5 20 ni2 ni2 ADP pg15bc41r6k 5 21 + + NOUN pg15bc41r6k 5 22 exchanged exchange VERB pg15bc41r6k 5 23 zeolites zeolite NOUN pg15bc41r6k 5 24 . . PUNCT pg15bc41r6k 6 1 the the DET pg15bc41r6k 6 2 robust robust ADJ pg15bc41r6k 6 3 stability stability NOUN pg15bc41r6k 6 4 of of ADP pg15bc41r6k 6 5 ni ni PROPN pg15bc41r6k 6 6 - - PUNCT pg15bc41r6k 6 7 pom pom NOUN pg15bc41r6k 6 8 - - PUNCT pg15bc41r6k 6 9 wd wd NOUN pg15bc41r6k 6 10 catalysts catalyst NOUN pg15bc41r6k 6 11 was be AUX pg15bc41r6k 6 12 shown show VERB pg15bc41r6k 6 13 by by ADP pg15bc41r6k 6 14 multiple multiple ADJ pg15bc41r6k 6 15 regenerated regenerate VERB pg15bc41r6k 6 16 cycles cycle NOUN pg15bc41r6k 6 17 ethylene ethylene NOUN pg15bc41r6k 6 18 oligomerization oligomerization NOUN pg15bc41r6k 6 19 without without ADP pg15bc41r6k 6 20 structural structural ADJ pg15bc41r6k 6 21 degradation degradation NOUN pg15bc41r6k 6 22 . . PUNCT pg15bc41r6k 7 1 we we PRON pg15bc41r6k 7 2 investigated investigate VERB pg15bc41r6k 7 3 the the DET pg15bc41r6k 7 4 influence influence NOUN pg15bc41r6k 7 5 of of ADP pg15bc41r6k 7 6 molecular molecular ADJ pg15bc41r6k 7 7 surroundings surrounding NOUN pg15bc41r6k 7 8 on on ADP pg15bc41r6k 7 9 substituted substitute VERB pg15bc41r6k 7 10 ni ni PROPN pg15bc41r6k 7 11 sites site NOUN pg15bc41r6k 7 12 by by ADP pg15bc41r6k 7 13 changing change VERB pg15bc41r6k 7 14 the the DET pg15bc41r6k 7 15 size size NOUN pg15bc41r6k 7 16 and and CCONJ pg15bc41r6k 7 17 elemental elemental ADJ pg15bc41r6k 7 18 compositions composition NOUN pg15bc41r6k 7 19 of of ADP pg15bc41r6k 7 20 site site NOUN pg15bc41r6k 7 21 bearing bear VERB pg15bc41r6k 7 22 polyoxometalates polyoxometalate NOUN pg15bc41r6k 7 23 . . PUNCT pg15bc41r6k 8 1 it it PRON pg15bc41r6k 8 2 was be AUX pg15bc41r6k 8 3 shown show VERB pg15bc41r6k 8 4 that that SCONJ pg15bc41r6k 8 5 the the DET pg15bc41r6k 8 6 size size NOUN pg15bc41r6k 8 7 of of ADP pg15bc41r6k 8 8 polyoxometalate polyoxometalate NOUN pg15bc41r6k 8 9 structure structure NOUN pg15bc41r6k 8 10 does do AUX pg15bc41r6k 8 11 not not PART pg15bc41r6k 8 12 perturb perturb VERB pg15bc41r6k 8 13 the the DET pg15bc41r6k 8 14 kinetic kinetic ADJ pg15bc41r6k 8 15 nature nature NOUN pg15bc41r6k 8 16 of of ADP pg15bc41r6k 8 17 substituted substitute VERB pg15bc41r6k 8 18 ni ni PROPN pg15bc41r6k 8 19 sites site NOUN pg15bc41r6k 8 20 . . PUNCT pg15bc41r6k 9 1 on on ADP pg15bc41r6k 9 2 the the DET pg15bc41r6k 9 3 other other ADJ pg15bc41r6k 9 4 hand hand NOUN pg15bc41r6k 9 5 , , PUNCT pg15bc41r6k 9 6 the the DET pg15bc41r6k 9 7 activation activation NOUN pg15bc41r6k 9 8 energy energy NOUN pg15bc41r6k 9 9 of of ADP pg15bc41r6k 9 10 ni ni PROPN pg15bc41r6k 9 11 sites site NOUN pg15bc41r6k 9 12 was be AUX pg15bc41r6k 9 13 found find VERB pg15bc41r6k 9 14 to to PART pg15bc41r6k 9 15 be be AUX pg15bc41r6k 9 16 correlated correlate VERB pg15bc41r6k 9 17 with with ADP pg15bc41r6k 9 18 the the DET pg15bc41r6k 9 19 electronegativity electronegativity NOUN pg15bc41r6k 9 20 of of ADP pg15bc41r6k 9 21 internal internal ADJ pg15bc41r6k 9 22 heteroatoms heteroatom NOUN pg15bc41r6k 9 23 . . PUNCT pg15bc41r6k 10 1 moreover moreover ADV pg15bc41r6k 10 2 , , PUNCT pg15bc41r6k 10 3 three three NUM pg15bc41r6k 10 4 ni ni PROPN pg15bc41r6k 10 5 sites site NOUN pg15bc41r6k 10 6 were be AUX pg15bc41r6k 10 7 isolated isolate VERB pg15bc41r6k 10 8 on on ADP pg15bc41r6k 10 9 one one NUM pg15bc41r6k 10 10 polyoxometalate polyoxometalate NOUN pg15bc41r6k 10 11 structure structure NOUN pg15bc41r6k 10 12 . . PUNCT pg15bc41r6k 11 1 mass mass NOUN pg15bc41r6k 11 2 normalized normalize VERB pg15bc41r6k 11 3 ethylene ethylene NOUN pg15bc41r6k 11 4 consumption consumption NOUN pg15bc41r6k 11 5 rate rate NOUN pg15bc41r6k 11 6 was be AUX pg15bc41r6k 11 7 increased increase VERB pg15bc41r6k 11 8 due due ADP pg15bc41r6k 11 9 to to ADP pg15bc41r6k 11 10 the the DET pg15bc41r6k 11 11 increased increase VERB pg15bc41r6k 11 12 per per ADP pg15bc41r6k 11 13 pom pom NOUN pg15bc41r6k 11 14 ni ni PROPN pg15bc41r6k 11 15 concentration concentration NOUN pg15bc41r6k 11 16 . . PUNCT pg15bc41r6k 12 1 more more ADV pg15bc41r6k 12 2 interestingly interestingly ADV pg15bc41r6k 12 3 , , PUNCT pg15bc41r6k 12 4 the the DET pg15bc41r6k 12 5 ratio ratio NOUN pg15bc41r6k 12 6 of of ADP pg15bc41r6k 12 7 1 1 NUM pg15bc41r6k 12 8 - - PUNCT pg15bc41r6k 12 9 butene/2 butene/2 NUM pg15bc41r6k 12 10 - - PUNCT pg15bc41r6k 12 11 butene butene NOUN pg15bc41r6k 12 12 was be AUX pg15bc41r6k 12 13 able able ADJ pg15bc41r6k 12 14 to to PART pg15bc41r6k 12 15 be be AUX pg15bc41r6k 12 16 changed change VERB pg15bc41r6k 12 17 by by ADP pg15bc41r6k 12 18 facilitating facilitate VERB pg15bc41r6k 12 19 re re NOUN pg15bc41r6k 12 20 - - NOUN pg15bc41r6k 12 21 adsorption adsorption NOUN pg15bc41r6k 12 22 and and CCONJ pg15bc41r6k 12 23 isomerization isomerization NOUN pg15bc41r6k 12 24 of of ADP pg15bc41r6k 12 25 1 1 NUM pg15bc41r6k 12 26 - - PUNCT pg15bc41r6k 12 27 butene butene NOUN pg15bc41r6k 12 28 with with ADP pg15bc41r6k 12 29 structurally structurally ADV pg15bc41r6k 12 30 controlled control VERB pg15bc41r6k 12 31 ni ni PROPN pg15bc41r6k 12 32 site site NOUN pg15bc41r6k 12 33 proximity proximity NOUN pg15bc41r6k 12 34 . . PUNCT pg15bc41r6k 13 1 other other ADJ pg15bc41r6k 13 2 known know VERB pg15bc41r6k 13 3 transition transition NOUN pg15bc41r6k 13 4 metal metal NOUN pg15bc41r6k 13 5 active active ADJ pg15bc41r6k 13 6 sites site NOUN pg15bc41r6k 13 7 ( ( PUNCT pg15bc41r6k 13 8 cr cr X pg15bc41r6k 13 9 , , PUNCT pg15bc41r6k 13 10 co co PROPN pg15bc41r6k 13 11 ) ) PUNCT pg15bc41r6k 13 12 for for ADP pg15bc41r6k 13 13 light light ADJ pg15bc41r6k 13 14 olefin olefin NOUN pg15bc41r6k 13 15 coupling coupling NOUN pg15bc41r6k 13 16 reaction reaction NOUN pg15bc41r6k 13 17 were be AUX pg15bc41r6k 13 18 isolated isolate VERB pg15bc41r6k 13 19 on on ADP pg15bc41r6k 13 20 lacunary lacunary ADJ pg15bc41r6k 13 21 defects defect NOUN pg15bc41r6k 13 22 and and CCONJ pg15bc41r6k 13 23 their their PRON pg15bc41r6k 13 24 catalytic catalytic ADJ pg15bc41r6k 13 25 performance performance NOUN pg15bc41r6k 13 26 was be AUX pg15bc41r6k 13 27 evaluated evaluate VERB pg15bc41r6k 13 28 . . PUNCT