id	sid	tid	token	lemma	pos
p5547p91t3c	1	1	tris(2-(arylamido)-4,6	tris(2-(arylamido)-4,6	PROPN
p5547p91t3c	1	2	-	-	PUNCT
p5547p91t3c	1	3	di	di	PROPN
p5547p91t3c	1	4	-	-	PUNCT
p5547p91t3c	1	5	tert	tert	NOUN
p5547p91t3c	1	6	-	-	PUNCT
p5547p91t3c	1	7	butylphenoxo)molybdenum(vi	butylphenoxo)molybdenum(vi	PROPN
p5547p91t3c	1	8	)	)	PUNCT
p5547p91t3c	1	9	complexes	complex	NOUN
p5547p91t3c	1	10	(	(	PUNCT
p5547p91t3c	1	11	rap)3mo	rap)3mo	ADV
p5547p91t3c	1	12	can	can	AUX
p5547p91t3c	1	13	be	be	AUX
p5547p91t3c	1	14	prepared	prepare	VERB
p5547p91t3c	1	15	either	either	CCONJ
p5547p91t3c	1	16	from	from	ADP
p5547p91t3c	1	17	(	(	PUNCT
p5547p91t3c	1	18	cycloheptatriene)mo(co)3	cycloheptatriene)mo(co)3	PROPN
p5547p91t3c	1	19	and	and	CCONJ
p5547p91t3c	1	20	the	the	DET
p5547p91t3c	1	21	n	n	PROPN
p5547p91t3c	1	22	-	-	PUNCT
p5547p91t3c	1	23	aryliminoquinone	aryliminoquinone	PROPN
p5547p91t3c	1	24	,	,	PUNCT
p5547p91t3c	1	25	or	or	CCONJ
p5547p91t3c	1	26	from	from	ADP
p5547p91t3c	1	27	moo2(acac)2	moo2(acac)2	NOUN
p5547p91t3c	1	28	and	and	CCONJ
p5547p91t3c	1	29	the	the	DET
p5547p91t3c	1	30	aminophenol	aminophenol	NOUN
p5547p91t3c	1	31	.	.	PUNCT
p5547p91t3c	2	1	in	in	ADP
p5547p91t3c	2	2	contrast	contrast	NOUN
p5547p91t3c	2	3	to	to	ADP
p5547p91t3c	2	4	all	all	DET
p5547p91t3c	2	5	other	other	ADJ
p5547p91t3c	2	6	reported	report	VERB
p5547p91t3c	2	7	unconstrained	unconstrained	ADJ
p5547p91t3c	2	8	transition	transition	NOUN
p5547p91t3c	2	9	metal	metal	NOUN
p5547p91t3c	2	10	tris(amidophenoxide	tris(amidophenoxide	NOUN
p5547p91t3c	2	11	)	)	PUNCT
p5547p91t3c	2	12	complexes	complex	NOUN
p5547p91t3c	2	13	,	,	PUNCT
p5547p91t3c	2	14	the	the	DET
p5547p91t3c	2	15	molybdenum	molybdenum	NOUN
p5547p91t3c	2	16	complexes	complex	NOUN
p5547p91t3c	2	17	show	show	VERB
p5547p91t3c	2	18	a	a	DET
p5547p91t3c	2	19	facial	facial	ADJ
p5547p91t3c	2	20	geometry	geometry	NOUN
p5547p91t3c	2	21	in	in	ADP
p5547p91t3c	2	22	the	the	DET
p5547p91t3c	2	23	solid	solid	ADJ
p5547p91t3c	2	24	state	state	NOUN
p5547p91t3c	2	25	.	.	PUNCT
p5547p91t3c	3	1	in	in	ADP
p5547p91t3c	3	2	solution	solution	NOUN
p5547p91t3c	3	3	,	,	PUNCT
p5547p91t3c	3	4	the	the	DET
p5547p91t3c	3	5	fac	fac	PROPN
p5547p91t3c	3	6	isomer	isomer	PROPN
p5547p91t3c	3	7	predominates	predominate	VERB
p5547p91t3c	3	8	,	,	PUNCT
p5547p91t3c	3	9	though	though	SCONJ
p5547p91t3c	3	10	a	a	DET
p5547p91t3c	3	11	small	small	ADJ
p5547p91t3c	3	12	amount	amount	NOUN
p5547p91t3c	3	13	of	of	ADP
p5547p91t3c	3	14	mer	mer	X
p5547p91t3c	3	15	isomer	isomer	PROPN
p5547p91t3c	3	16	is	be	AUX
p5547p91t3c	3	17	detectable	detectable	ADJ
p5547p91t3c	3	18	at	at	ADP
p5547p91t3c	3	19	room	room	NOUN
p5547p91t3c	3	20	temperature	temperature	NOUN
p5547p91t3c	3	21	.	.	PUNCT
p5547p91t3c	4	1	at	at	ADP
p5547p91t3c	4	2	elevated	elevated	ADJ
p5547p91t3c	4	3	temperature	temperature	NOUN
p5547p91t3c	4	4	the	the	DET
p5547p91t3c	4	5	two	two	NUM
p5547p91t3c	4	6	species	specie	NOUN
p5547p91t3c	4	7	interconvert	interconvert	VERB
p5547p91t3c	4	8	through	through	ADP
p5547p91t3c	4	9	rây	rây	NOUN
p5547p91t3c	4	10	-	-	PUNCT
p5547p91t3c	4	11	dutt	dutt	NOUN
p5547p91t3c	4	12	trigonal	trigonal	ADJ
p5547p91t3c	4	13	twists	twist	NOUN
p5547p91t3c	4	14	,	,	PUNCT
p5547p91t3c	4	15	which	which	PRON
p5547p91t3c	4	16	are	be	AUX
p5547p91t3c	4	17	faster	fast	ADJ
p5547p91t3c	4	18	than	than	SCONJ
p5547p91t3c	4	19	bailar	bailar	VERB
p5547p91t3c	4	20	twists	twist	NOUN
p5547p91t3c	4	21	in	in	ADP
p5547p91t3c	4	22	this	this	DET
p5547p91t3c	4	23	system	system	NOUN
p5547p91t3c	4	24	,	,	PUNCT
p5547p91t3c	4	25	presumably	presumably	ADV
p5547p91t3c	4	26	because	because	SCONJ
p5547p91t3c	4	27	of	of	ADP
p5547p91t3c	4	28	steric	steric	ADJ
p5547p91t3c	4	29	effects	effect	NOUN
p5547p91t3c	4	30	of	of	ADP
p5547p91t3c	4	31	the	the	DET
p5547p91t3c	4	32	n	n	ADJ
p5547p91t3c	4	33	-	-	PUNCT
p5547p91t3c	4	34	aryl	aryl	ADJ
p5547p91t3c	4	35	groups	group	NOUN
p5547p91t3c	4	36	.	.	PUNCT
p5547p91t3c	5	1	substituents	substituent	NOUN
p5547p91t3c	5	2	on	on	ADP
p5547p91t3c	5	3	the	the	DET
p5547p91t3c	5	4	n	n	ADJ
p5547p91t3c	5	5	-	-	PUNCT
p5547p91t3c	5	6	aryl	aryl	ADJ
p5547p91t3c	5	7	ring	ring	NOUN
p5547p91t3c	5	8	shift	shift	NOUN
p5547p91t3c	5	9	the	the	DET
p5547p91t3c	5	10	fac	fac	NOUN
p5547p91t3c	5	11	/	/	SYM
p5547p91t3c	5	12	mer	mer	X
p5547p91t3c	5	13	equilibrium	equilibrium	NOUN
p5547p91t3c	5	14	of	of	ADP
p5547p91t3c	5	15	the	the	DET
p5547p91t3c	5	16	complex	complex	NOUN
p5547p91t3c	5	17	,	,	PUNCT
p5547p91t3c	5	18	with	with	ADP
p5547p91t3c	5	19	more	more	ADJ
p5547p91t3c	5	20	electron	electron	NOUN
p5547p91t3c	5	21	-	-	PUNCT
p5547p91t3c	5	22	withdrawing	withdraw	VERB
p5547p91t3c	5	23	substituents	substituent	NOUN
p5547p91t3c	5	24	generally	generally	ADV
p5547p91t3c	5	25	increasing	increase	VERB
p5547p91t3c	5	26	the	the	DET
p5547p91t3c	5	27	proportion	proportion	NOUN
p5547p91t3c	5	28	of	of	ADP
p5547p91t3c	5	29	the	the	DET
p5547p91t3c	5	30	mer	mer	X
p5547p91t3c	5	31	isomer	isomer	PROPN
p5547p91t3c	5	32	.	.	PUNCT
p5547p91t3c	6	1	the	the	DET
p5547p91t3c	6	2	preference	preference	NOUN
p5547p91t3c	6	3	for	for	ADP
p5547p91t3c	6	4	fac	fac	NOUN
p5547p91t3c	6	5	over	over	ADP
p5547p91t3c	6	6	mer	mer	X
p5547p91t3c	6	7	geometry	geometry	NOUN
p5547p91t3c	6	8	is	be	AUX
p5547p91t3c	6	9	thus	thus	ADV
p5547p91t3c	6	10	suggested	suggest	VERB
p5547p91t3c	6	11	to	to	PART
p5547p91t3c	6	12	be	be	AUX
p5547p91t3c	6	13	due	due	ADJ
p5547p91t3c	6	14	to	to	ADP
p5547p91t3c	6	15	enhanced	enhanced	ADJ
p5547p91t3c	6	16	π	π	NOUN
p5547p91t3c	6	17	bonding	bonding	NOUN
p5547p91t3c	6	18	in	in	ADP
p5547p91t3c	6	19	the	the	DET
p5547p91t3c	6	20	fac	fac	PROPN
p5547p91t3c	6	21	isomer	isomer	PROPN
p5547p91t3c	6	22	.	.	PUNCT
p5547p91t3c	7	1	in	in	ADP
p5547p91t3c	7	2	contrast	contrast	NOUN
p5547p91t3c	7	3	to	to	ADP
p5547p91t3c	7	4	analogous	analogous	ADJ
p5547p91t3c	7	5	catecholate	catecholate	ADJ
p5547p91t3c	7	6	complexes	complex	NOUN
p5547p91t3c	7	7	,	,	PUNCT
p5547p91t3c	7	8	the	the	DET
p5547p91t3c	7	9	tris(amidophenoxide	tris(amidophenoxide	NOUN
p5547p91t3c	7	10	)	)	PUNCT
p5547p91t3c	7	11	complexes	complex	NOUN
p5547p91t3c	7	12	are	be	AUX
p5547p91t3c	7	13	not	not	PART
p5547p91t3c	7	14	lewis	lewis	NOUN
p5547p91t3c	7	15	acidic	acidic	NOUN
p5547p91t3c	7	16	and	and	CCONJ
p5547p91t3c	7	17	are	be	AUX
p5547p91t3c	7	18	inert	inert	ADJ
p5547p91t3c	7	19	to	to	ADP
p5547p91t3c	7	20	nucleophilic	nucleophilic	NOUN
p5547p91t3c	7	21	oxidants	oxidant	NOUN
p5547p91t3c	7	22	such	such	ADJ
p5547p91t3c	7	23	as	as	ADP
p5547p91t3c	7	24	amine-n-oxides.the	amine-n-oxides.the	PROPN
p5547p91t3c	7	25	tris(aminophenol	tris(aminophenol	NOUN
p5547p91t3c	7	26	)	)	PUNCT
p5547p91t3c	7	27	ligand	ligand	NOUN
p5547p91t3c	7	28	meclamph6	meclamph6	PROPN
p5547p91t3c	7	29	(	(	PUNCT
p5547p91t3c	7	30	tris(2-(3',5'-di	tris(2-(3',5'-di	PROPN
p5547p91t3c	7	31	-	-	PUNCT
p5547p91t3c	7	32	tert	tert	PROPN
p5547p91t3c	7	33	-	-	PUNCT
p5547p91t3c	7	34	butyl-2'-hydroxyphenyl)amino-4	butyl-2'-hydroxyphenyl)amino-4	NUM
p5547p91t3c	7	35	-	-	PUNCT
p5547p91t3c	7	36	methylphenyl)amine	methylphenyl)amine	NOUN
p5547p91t3c	7	37	)	)	PUNCT
p5547p91t3c	7	38	reacts	react	VERB
p5547p91t3c	7	39	with	with	ADP
p5547p91t3c	7	40	cr(thf)3cl3	cr(thf)3cl3	X
p5547p91t3c	7	41	to	to	PART
p5547p91t3c	7	42	make	make	VERB
p5547p91t3c	7	43	the	the	DET
p5547p91t3c	7	44	octahedral	octahedral	NOUN
p5547p91t3c	7	45	(	(	PUNCT
p5547p91t3c	7	46	meclamp)cr	meclamp)cr	PROPN
p5547p91t3c	7	47	complex	complex	NOUN
p5547p91t3c	7	48	.	.	PUNCT
p5547p91t3c	8	1	x	x	X
p5547p91t3c	8	2	-	-	NOUN
p5547p91t3c	8	3	ray	ray	NOUN
p5547p91t3c	8	4	crystallography	crystallography	NOUN
p5547p91t3c	8	5	shows	show	VERB
p5547p91t3c	8	6	that	that	SCONJ
p5547p91t3c	8	7	(	(	PUNCT
p5547p91t3c	8	8	meclamp)cr	meclamp)cr	PROPN
p5547p91t3c	8	9	is	be	AUX
p5547p91t3c	8	10	octahedral	octahedral	ADJ
p5547p91t3c	8	11	,	,	PUNCT
p5547p91t3c	8	12	and	and	CCONJ
p5547p91t3c	8	13	has	have	VERB
p5547p91t3c	8	14	little	little	ADJ
p5547p91t3c	8	15	interaction	interaction	NOUN
p5547p91t3c	8	16	between	between	ADP
p5547p91t3c	8	17	the	the	DET
p5547p91t3c	8	18	metal	metal	NOUN
p5547p91t3c	8	19	and	and	CCONJ
p5547p91t3c	8	20	the	the	DET
p5547p91t3c	8	21	central	central	ADJ
p5547p91t3c	8	22	triarylamine	triarylamine	PROPN
p5547p91t3c	8	23	nitrogen	nitrogen	NOUN
p5547p91t3c	8	24	(	(	PUNCT
p5547p91t3c	8	25	cr	cr	NOUN
p5547p91t3c	8	26	–	–	PUNCT
p5547p91t3c	8	27	nar3	nar3	PROPN
p5547p91t3c	8	28	=	=	PUNCT
p5547p91t3c	8	29	3.32	3.32	NUM
p5547p91t3c	8	30	å	å	PROPN
p5547p91t3c	8	31	)	)	PUNCT
p5547p91t3c	8	32	.	.	PUNCT
p5547p91t3c	9	1	through	through	ADP
p5547p91t3c	9	2	the	the	DET
p5547p91t3c	9	3	use	use	NOUN
p5547p91t3c	9	4	of	of	ADP
p5547p91t3c	9	5	variable	variable	ADJ
p5547p91t3c	9	6	-	-	PUNCT
p5547p91t3c	9	7	temperature	temperature	NOUN
p5547p91t3c	9	8	nmr	nmr	NOUN
p5547p91t3c	9	9	the	the	DET
p5547p91t3c	9	10	singlet	singlet	NOUN
p5547p91t3c	9	11	-	-	PUNCT
p5547p91t3c	9	12	triplet	triplet	NOUN
p5547p91t3c	9	13	energy	energy	NOUN
p5547p91t3c	9	14	gaps	gap	NOUN
p5547p91t3c	9	15	for	for	ADP
p5547p91t3c	9	16	(	(	PUNCT
p5547p91t3c	9	17	meclamp)cr	meclamp)cr	PROPN
p5547p91t3c	9	18	and	and	CCONJ
p5547p91t3c	9	19	cr(phnc6h2tbu2o)3	cr(phnc6h2tbu2o)3	PROPN
p5547p91t3c	9	20	,	,	PUNCT
p5547p91t3c	9	21	its	its	PRON
p5547p91t3c	9	22	meridonal	meridonal	ADJ
p5547p91t3c	9	23	tris(chelate	tris(chelate	ADJ
p5547p91t3c	9	24	)	)	PUNCT
p5547p91t3c	9	25	equivalent	equivalent	NOUN
p5547p91t3c	9	26	,	,	PUNCT
p5547p91t3c	9	27	were	be	AUX
p5547p91t3c	9	28	determined	determined	ADJ
p5547p91t3c	9	29	to	to	PART
p5547p91t3c	9	30	be	be	AUX
p5547p91t3c	9	31	4.28	4.28	NUM
p5547p91t3c	9	32	±	±	NOUN
p5547p91t3c	9	33	0.10	0.10	NUM
p5547p91t3c	9	34	kcal	kcal	ADJ
p5547p91t3c	9	35	mol-1	mol-1	ADP
p5547p91t3c	9	36	and	and	CCONJ
p5547p91t3c	9	37	3.26	3.26	NUM
p5547p91t3c	9	38	±	±	NOUN
p5547p91t3c	9	39	0.04	0.04	NUM
p5547p91t3c	9	40	kcal	kcal	ADJ
p5547p91t3c	9	41	mol-1	mol-1	X
p5547p91t3c	9	42	respectively	respectively	ADV
p5547p91t3c	9	43	.	.	PUNCT
p5547p91t3c	10	1	neutral	neutral	ADJ
p5547p91t3c	10	2	(	(	PUNCT
p5547p91t3c	10	3	meclamp)cr	meclamp)cr	PROPN
p5547p91t3c	10	4	can	can	AUX
p5547p91t3c	10	5	be	be	AUX
p5547p91t3c	10	6	oxidized	oxidize	VERB
p5547p91t3c	10	7	by	by	ADP
p5547p91t3c	10	8	one	one	NUM
p5547p91t3c	10	9	electron	electron	NOUN
p5547p91t3c	10	10	which	which	PRON
p5547p91t3c	10	11	gives	give	VERB
p5547p91t3c	10	12	an	an	DET
p5547p91t3c	10	13	epr	epr	ADJ
p5547p91t3c	10	14	signal	signal	NOUN
p5547p91t3c	10	15	diagnostic	diagnostic	NOUN
p5547p91t3c	10	16	of	of	ADP
p5547p91t3c	10	17	a	a	DET
p5547p91t3c	10	18	ligand	ligand	NOUN
p5547p91t3c	10	19	centered	center	VERB
p5547p91t3c	10	20	radical	radical	ADJ
p5547p91t3c	10	21	.	.	PUNCT
p5547p91t3c	11	1	(	(	PUNCT
p5547p91t3c	11	2	meclamp)v	meclamp)v	X
p5547p91t3c	11	3	is	be	AUX
p5547p91t3c	11	4	prepared	prepare	VERB
p5547p91t3c	11	5	by	by	ADP
p5547p91t3c	11	6	reacting	react	VERB
p5547p91t3c	11	7	meclamph6	meclamph6	PROPN
p5547p91t3c	11	8	and	and	CCONJ
p5547p91t3c	11	9	vanadium(v	vanadium(v	PROPN
p5547p91t3c	11	10	)	)	PUNCT
p5547p91t3c	11	11	oxytriisopropoxide	oxytriisopropoxide	NOUN
p5547p91t3c	11	12	.	.	PUNCT
p5547p91t3c	12	1	the	the	DET
p5547p91t3c	12	2	neutral	neutral	ADJ
p5547p91t3c	12	3	complex	complex	NOUN
p5547p91t3c	12	4	is	be	AUX
p5547p91t3c	12	5	seven	seven	NUM
p5547p91t3c	12	6	coordinate	coordinate	NOUN
p5547p91t3c	12	7	in	in	ADP
p5547p91t3c	12	8	the	the	DET
p5547p91t3c	12	9	solid	solid	ADJ
p5547p91t3c	12	10	state	state	NOUN
p5547p91t3c	12	11	(	(	PUNCT
p5547p91t3c	12	12	v	v	NOUN
p5547p91t3c	12	13	–	–	PUNCT
p5547p91t3c	12	14	nar3	nar3	PROPN
p5547p91t3c	12	15	=	=	PRON
p5547p91t3c	12	16	2.38	2.38	NUM
p5547p91t3c	12	17	å	å	PROPN
p5547p91t3c	12	18	)	)	PUNCT
p5547p91t3c	12	19	but	but	CCONJ
p5547p91t3c	12	20	the	the	DET
p5547p91t3c	12	21	optical	optical	ADJ
p5547p91t3c	12	22	spectrum	spectrum	NOUN
p5547p91t3c	12	23	gives	give	VERB
p5547p91t3c	12	24	evidence	evidence	NOUN
p5547p91t3c	12	25	to	to	PART
p5547p91t3c	12	26	suggest	suggest	VERB
p5547p91t3c	12	27	it	it	PRON
p5547p91t3c	12	28	is	be	AUX
p5547p91t3c	12	29	six	six	NUM
p5547p91t3c	12	30	-	-	PUNCT
p5547p91t3c	12	31	coordinate	coordinate	NOUN
p5547p91t3c	12	32	while	while	NOUN
p5547p91t3c	12	33	in	in	ADP
p5547p91t3c	12	34	solution	solution	NOUN
p5547p91t3c	12	35	.	.	PUNCT
p5547p91t3c	13	1	neutral	neutral	ADJ
p5547p91t3c	13	2	(	(	PUNCT
p5547p91t3c	13	3	meclamp)v	meclamp)v	PROPN
p5547p91t3c	13	4	can	can	AUX
p5547p91t3c	13	5	be	be	AUX
p5547p91t3c	13	6	reduced	reduce	VERB
p5547p91t3c	13	7	or	or	CCONJ
p5547p91t3c	13	8	oxidized	oxidize	VERB
p5547p91t3c	13	9	by	by	ADP
p5547p91t3c	13	10	one	one	NUM
p5547p91t3c	13	11	electron	electron	NOUN
p5547p91t3c	13	12	with	with	ADP
p5547p91t3c	13	13	redox	redox	ADJ
p5547p91t3c	13	14	titrations	titration	NOUN
p5547p91t3c	13	15	showing	show	VERB
p5547p91t3c	13	16	isosbestic	isosbestic	ADJ
p5547p91t3c	13	17	points	point	NOUN
p5547p91t3c	13	18	indicative	indicative	ADJ
p5547p91t3c	13	19	of	of	ADP
p5547p91t3c	13	20	a	a	DET
p5547p91t3c	13	21	clean	clean	ADJ
p5547p91t3c	13	22	conversion	conversion	NOUN
p5547p91t3c	13	23	from	from	ADP
p5547p91t3c	13	24	one	one	NUM
p5547p91t3c	13	25	complex	complex	NOUN
p5547p91t3c	13	26	to	to	ADP
p5547p91t3c	13	27	the	the	DET
p5547p91t3c	13	28	other	other	ADJ
p5547p91t3c	13	29	.	.	PUNCT
p5547p91t3c	14	1	the	the	DET
p5547p91t3c	14	2	electronic	electronic	ADJ
p5547p91t3c	14	3	structure	structure	NOUN
p5547p91t3c	14	4	of	of	ADP
p5547p91t3c	14	5	both	both	PRON
p5547p91t3c	14	6	(	(	PUNCT
p5547p91t3c	14	7	meclamp)cr	meclamp)cr	PROPN
p5547p91t3c	14	8	and	and	CCONJ
p5547p91t3c	14	9	(	(	PUNCT
p5547p91t3c	14	10	meclamp)v	meclamp)v	ADJ
p5547p91t3c	14	11	is	be	AUX
p5547p91t3c	14	12	best	well	ADV
p5547p91t3c	14	13	described	describe	VERB
p5547p91t3c	14	14	using	use	VERB
p5547p91t3c	14	15	a	a	DET
p5547p91t3c	14	16	covalent	covalent	NOUN
p5547p91t3c	14	17	model	model	NOUN
p5547p91t3c	14	18	in	in	ADP
p5547p91t3c	14	19	which	which	PRON
p5547p91t3c	14	20	the	the	DET
p5547p91t3c	14	21	metal	metal	NOUN
p5547p91t3c	14	22	center	center	NOUN
p5547p91t3c	14	23	is	be	AUX
p5547p91t3c	14	24	supported	support	VERB
p5547p91t3c	14	25	by	by	ADP
p5547p91t3c	14	26	iminoxolene	iminoxolene	NOUN
p5547p91t3c	14	27	ligands	ligand	NOUN
p5547p91t3c	14	28	with	with	ADP
p5547p91t3c	14	29	substantial	substantial	ADJ
p5547p91t3c	14	30	π	π	PROPN
p5547p91t3c	14	31	donation.oxobis(iminoxolene)osmium(vi	donation.oxobis(iminoxolene)osmium(vi	PROPN
p5547p91t3c	14	32	)	)	PUNCT
p5547p91t3c	14	33	compounds	compound	NOUN
p5547p91t3c	14	34	(	(	PUNCT
p5547p91t3c	14	35	rap)2oso	rap)2oso	NOUN
p5547p91t3c	14	36	(	(	PUNCT
p5547p91t3c	14	37	rap	rap	NOUN
p5547p91t3c	14	38	=	=	SYM
p5547p91t3c	14	39	2-(4	2-(4	NUM
p5547p91t3c	14	40	-	-	PUNCT
p5547p91t3c	14	41	rc6h4n)-4,6	rc6h4n)-4,6	NOUN
p5547p91t3c	14	42	-	-	PUNCT
p5547p91t3c	14	43	tbu2c6h2o	tbu2c6h2o	PROPN
p5547p91t3c	14	44	)	)	PUNCT
p5547p91t3c	14	45	are	be	AUX
p5547p91t3c	14	46	deoxygenated	deoxygenate	VERB
p5547p91t3c	14	47	by	by	ADP
p5547p91t3c	14	48	phosphines	phosphine	NOUN
p5547p91t3c	14	49	and	and	CCONJ
p5547p91t3c	14	50	phosphites	phosphite	NOUN
p5547p91t3c	14	51	to	to	PART
p5547p91t3c	14	52	give	give	VERB
p5547p91t3c	14	53	five	five	NUM
p5547p91t3c	14	54	-	-	PUNCT
p5547p91t3c	14	55	coordinate	coordinate	NOUN
p5547p91t3c	14	56	(	(	PUNCT
p5547p91t3c	14	57	rap)2os(pr′3	rap)2os(pr′3	NUM
p5547p91t3c	14	58	)	)	PUNCT
p5547p91t3c	14	59	or	or	CCONJ
p5547p91t3c	14	60	six	six	NUM
p5547p91t3c	14	61	-	-	PUNCT
p5547p91t3c	14	62	coordinate	coordinate	NOUN
p5547p91t3c	14	63	(	(	PUNCT
p5547p91t3c	14	64	rap)2os(pr′3)2	rap)2os(pr′3)2	ADJ
p5547p91t3c	14	65	complexes	complex	NOUN
p5547p91t3c	14	66	.	.	PUNCT
p5547p91t3c	15	1	analysis	analysis	NOUN
p5547p91t3c	15	2	of	of	ADP
p5547p91t3c	15	3	the	the	DET
p5547p91t3c	15	4	intraligand	intraligand	NOUN
p5547p91t3c	15	5	distances	distance	NOUN
p5547p91t3c	15	6	indicates	indicate	VERB
p5547p91t3c	15	7	that	that	SCONJ
p5547p91t3c	15	8	this	this	DET
p5547p91t3c	15	9	net	net	ADJ
p5547p91t3c	15	10	two	two	NUM
p5547p91t3c	15	11	-	-	PUNCT
p5547p91t3c	15	12	electron	electron	NOUN
p5547p91t3c	15	13	reduction	reduction	NOUN
p5547p91t3c	15	14	is	be	AUX
p5547p91t3c	15	15	accompanied	accompany	VERB
p5547p91t3c	15	16	by	by	ADP
p5547p91t3c	15	17	the	the	DET
p5547p91t3c	15	18	apparent	apparent	ADJ
p5547p91t3c	15	19	oxidation	oxidation	NOUN
p5547p91t3c	15	20	of	of	ADP
p5547p91t3c	15	21	the	the	DET
p5547p91t3c	15	22	iminoxolene	iminoxolene	NOUN
p5547p91t3c	15	23	ligands	ligand	NOUN
p5547p91t3c	15	24	.	.	PUNCT
p5547p91t3c	16	1	this	this	DET
p5547p91t3c	16	2	change	change	NOUN
p5547p91t3c	16	3	is	be	AUX
p5547p91t3c	16	4	due	due	ADJ
p5547p91t3c	16	5	to	to	ADP
p5547p91t3c	16	6	the	the	DET
p5547p91t3c	16	7	increased	increase	VERB
p5547p91t3c	16	8	ability	ability	NOUN
p5547p91t3c	16	9	of	of	ADP
p5547p91t3c	16	10	the	the	DET
p5547p91t3c	16	11	iminoxolene	iminoxolene	NOUN
p5547p91t3c	16	12	ligands	ligand	NOUN
p5547p91t3c	16	13	to	to	PART
p5547p91t3c	16	14	engage	engage	VERB
p5547p91t3c	16	15	in	in	ADP
p5547p91t3c	16	16	π	π	PROPN
p5547p91t3c	16	17	donation	donation	NOUN
p5547p91t3c	16	18	to	to	ADP
p5547p91t3c	16	19	the	the	DET
p5547p91t3c	16	20	reduced	reduce	VERB
p5547p91t3c	16	21	form	form	NOUN
p5547p91t3c	16	22	of	of	ADP
p5547p91t3c	16	23	the	the	DET
p5547p91t3c	16	24	osmium	osmium	NOUN
p5547p91t3c	16	25	complex	complex	NOUN
p5547p91t3c	16	26	.	.	PUNCT
p5547p91t3c	17	1	kinetic	kinetic	ADJ
p5547p91t3c	17	2	studies	study	NOUN
p5547p91t3c	17	3	indicate	indicate	VERB
p5547p91t3c	17	4	that	that	SCONJ
p5547p91t3c	17	5	the	the	DET
p5547p91t3c	17	6	rate	rate	NOUN
p5547p91t3c	17	7	-	-	PUNCT
p5547p91t3c	17	8	determining	determine	VERB
p5547p91t3c	17	9	step	step	NOUN
p5547p91t3c	17	10	is	be	AUX
p5547p91t3c	17	11	the	the	DET
p5547p91t3c	17	12	attack	attack	NOUN
p5547p91t3c	17	13	of	of	ADP
p5547p91t3c	17	14	the	the	DET
p5547p91t3c	17	15	phosphorus(iii	phosphorus(iii	NOUN
p5547p91t3c	17	16	)	)	PUNCT
p5547p91t3c	17	17	reagent	reagent	NOUN
p5547p91t3c	17	18	on	on	ADP
p5547p91t3c	17	19	the	the	DET
p5547p91t3c	17	20	five	five	NUM
p5547p91t3c	17	21	-	-	PUNCT
p5547p91t3c	17	22	coordinate	coordinate	NOUN
p5547p91t3c	17	23	oxo	oxo	NOUN
p5547p91t3c	17	24	complexes	complex	NOUN
p5547p91t3c	17	25	.	.	PUNCT
p5547p91t3c	18	1	while	while	SCONJ
p5547p91t3c	18	2	varying	vary	VERB
p5547p91t3c	18	3	the	the	DET
p5547p91t3c	18	4	substituents	substituent	NOUN
p5547p91t3c	18	5	of	of	ADP
p5547p91t3c	18	6	the	the	DET
p5547p91t3c	18	7	aryl	aryl	ADJ
p5547p91t3c	18	8	groups	group	NOUN
p5547p91t3c	18	9	on	on	ADP
p5547p91t3c	18	10	the	the	DET
p5547p91t3c	18	11	iminoxolene	iminoxolene	NOUN
p5547p91t3c	18	12	ligands	ligand	NOUN
p5547p91t3c	18	13	or	or	CCONJ
p5547p91t3c	18	14	on	on	ADP
p5547p91t3c	18	15	the	the	DET
p5547p91t3c	18	16	triarylphosphines	triarylphosphine	NOUN
p5547p91t3c	18	17	has	have	VERB
p5547p91t3c	18	18	little	little	ADJ
p5547p91t3c	18	19	effect	effect	NOUN
p5547p91t3c	18	20	on	on	ADP
p5547p91t3c	18	21	the	the	DET
p5547p91t3c	18	22	rate	rate	NOUN
p5547p91t3c	18	23	of	of	ADP
p5547p91t3c	18	24	oxygen	oxygen	NOUN
p5547p91t3c	18	25	atom	atom	NOUN
p5547p91t3c	18	26	transfer	transfer	NOUN
p5547p91t3c	18	27	,	,	PUNCT
p5547p91t3c	18	28	the	the	DET
p5547p91t3c	18	29	best	good	ADJ
p5547p91t3c	18	30	correlation	correlation	NOUN
p5547p91t3c	18	31	of	of	ADP
p5547p91t3c	18	32	the	the	DET
p5547p91t3c	18	33	data	datum	NOUN
p5547p91t3c	18	34	is	be	AUX
p5547p91t3c	18	35	shown	show	VERB
p5547p91t3c	18	36	between	between	ADP
p5547p91t3c	18	37	the	the	DET
p5547p91t3c	18	38	rates	rate	NOUN
p5547p91t3c	18	39	of	of	ADP
p5547p91t3c	18	40	oxygen	oxygen	NOUN
p5547p91t3c	18	41	atom	atom	NOUN
p5547p91t3c	18	42	transfer	transfer	NOUN
p5547p91t3c	18	43	and	and	CCONJ
p5547p91t3c	18	44	the	the	DET
p5547p91t3c	18	45	homo−lumo	homo−lumo	NUM
p5547p91t3c	18	46	gap	gap	NOUN
p5547p91t3c	18	47	of	of	ADP
p5547p91t3c	18	48	the	the	DET
p5547p91t3c	18	49	oxo	oxo	NOUN
p5547p91t3c	18	50	complexes	complex	NOUN
p5547p91t3c	18	51	.	.	PUNCT
p5547p91t3c	19	1	this	this	DET
p5547p91t3c	19	2	correlation	correlation	NOUN
p5547p91t3c	19	3	suggests	suggest	VERB
p5547p91t3c	19	4	that	that	SCONJ
p5547p91t3c	19	5	the	the	DET
p5547p91t3c	19	6	osmium	osmium	NOUN
p5547p91t3c	19	7	oxo	oxo	PROPN
p5547p91t3c	19	8	group	group	NOUN
p5547p91t3c	19	9	shows	show	VERB
p5547p91t3c	19	10	a	a	DET
p5547p91t3c	19	11	balance	balance	NOUN
p5547p91t3c	19	12	between	between	ADP
p5547p91t3c	19	13	both	both	CCONJ
p5547p91t3c	19	14	electrophilic	electrophilic	ADJ
p5547p91t3c	19	15	and	and	CCONJ
p5547p91t3c	19	16	nucleophilic	nucleophilic	ADJ
p5547p91t3c	19	17	character	character	NOUN
p5547p91t3c	19	18	in	in	ADP
p5547p91t3c	19	19	the	the	DET
p5547p91t3c	19	20	oxygen	oxygen	NOUN
p5547p91t3c	19	21	atom	atom	NOUN
p5547p91t3c	19	22	transfer	transfer	NOUN
p5547p91t3c	19	23	reactions	reaction	NOUN
p5547p91t3c	19	24	with	with	ADP
p5547p91t3c	19	25	phosphorus(iii	phosphorus(iii	PROPN
p5547p91t3c	19	26	)	)	PUNCT
p5547p91t3c	19	27	reagents.(hap)2os(l	reagents.(hap)2os(l	SPACE
p5547p91t3c	19	28	)	)	PUNCT
p5547p91t3c	19	29	complexes	complex	NOUN
p5547p91t3c	19	30	react	react	VERB
p5547p91t3c	19	31	with	with	ADP
p5547p91t3c	19	32	substrates	substrate	NOUN
p5547p91t3c	19	33	such	such	ADJ
p5547p91t3c	19	34	as	as	ADP
p5547p91t3c	19	35	styrene	styrene	NOUN
p5547p91t3c	19	36	oxide	oxide	NOUN
p5547p91t3c	19	37	.	.	PUNCT
p5547p91t3c	20	1	when	when	SCONJ
p5547p91t3c	20	2	l	l	PRON
p5547p91t3c	20	3	=	=	VERB
p5547p91t3c	20	4	pph3	pph3	NOUN
p5547p91t3c	20	5	,	,	PUNCT
p5547p91t3c	20	6	the	the	DET
p5547p91t3c	20	7	reaction	reaction	NOUN
p5547p91t3c	20	8	proceeds	proceed	VERB
p5547p91t3c	20	9	rapidly	rapidly	ADV
p5547p91t3c	20	10	at	at	ADP
p5547p91t3c	20	11	room	room	NOUN
p5547p91t3c	20	12	temperature	temperature	NOUN
p5547p91t3c	20	13	to	to	PART
p5547p91t3c	20	14	form	form	VERB
p5547p91t3c	20	15	products	product	NOUN
p5547p91t3c	20	16	where	where	SCONJ
p5547p91t3c	20	17	the	the	DET
p5547p91t3c	20	18	epoxide	epoxide	NOUN
p5547p91t3c	20	19	has	have	AUX
p5547p91t3c	20	20	opened	open	VERB
p5547p91t3c	20	21	and	and	CCONJ
p5547p91t3c	20	22	formed	form	VERB
p5547p91t3c	20	23	a	a	DET
p5547p91t3c	20	24	new	new	ADJ
p5547p91t3c	20	25	c	c	NOUN
p5547p91t3c	20	26	-	-	PUNCT
p5547p91t3c	20	27	n	n	NOUN
p5547p91t3c	20	28	bond	bond	NOUN
p5547p91t3c	20	29	to	to	ADP
p5547p91t3c	20	30	the	the	DET
p5547p91t3c	20	31	iminoxolene	iminoxolene	PROPN
p5547p91t3c	20	32	ligand	ligand	PROPN
p5547p91t3c	20	33	.	.	PUNCT
p5547p91t3c	21	1	the	the	DET
p5547p91t3c	21	2	complexes	complex	NOUN
p5547p91t3c	21	3	are	be	AUX
p5547p91t3c	21	4	capable	capable	ADJ
p5547p91t3c	21	5	of	of	ADP
p5547p91t3c	21	6	catalytic	catalytic	ADJ
p5547p91t3c	21	7	reduction	reduction	NOUN
p5547p91t3c	21	8	of	of	ADP
p5547p91t3c	21	9	aryland	aryland	NOUN
p5547p91t3c	21	10	vinyl	vinyl	NOUN
p5547p91t3c	21	11	-	-	PUNCT
p5547p91t3c	21	12	substituted	substitute	VERB
p5547p91t3c	21	13	epoxides	epoxide	NOUN
p5547p91t3c	21	14	to	to	ADP
p5547p91t3c	21	15	the	the	DET
p5547p91t3c	21	16	corresponding	correspond	VERB
p5547p91t3c	21	17	alkenes	alkene	NOUN
p5547p91t3c	21	18	using	use	VERB
p5547p91t3c	21	19	triphenylphosphine	triphenylphosphine	NOUN
p5547p91t3c	21	20	at	at	ADP
p5547p91t3c	21	21	50	50	NUM
p5547p91t3c	21	22	°	°	NOUN
p5547p91t3c	21	23	c	c	NOUN
p5547p91t3c	21	24	.	.	PROPN
p5547p91t3c	21	25	when	when	SCONJ
p5547p91t3c	21	26	cis	cis	NOUN
p5547p91t3c	21	27	-	-	PUNCT
p5547p91t3c	21	28	stilbene	stilbene	NOUN
p5547p91t3c	21	29	oxide	oxide	NOUN
p5547p91t3c	21	30	is	be	AUX
p5547p91t3c	21	31	used	use	VERB
p5547p91t3c	21	32	,	,	PUNCT
p5547p91t3c	21	33	isomerization	isomerization	NOUN
p5547p91t3c	21	34	of	of	ADP
p5547p91t3c	21	35	the	the	DET
p5547p91t3c	21	36	epoxide	epoxide	NOUN
p5547p91t3c	21	37	is	be	AUX
p5547p91t3c	21	38	observed	observe	VERB
p5547p91t3c	21	39	in	in	ADP
p5547p91t3c	21	40	addition	addition	NOUN
p5547p91t3c	21	41	to	to	ADP
p5547p91t3c	21	42	formation	formation	NOUN
p5547p91t3c	21	43	of	of	ADP
p5547p91t3c	21	44	stilbene	stilbene	NOUN
p5547p91t3c	21	45	.	.	PUNCT
p5547p91t3c	22	1	changing	change	VERB
p5547p91t3c	22	2	the	the	DET
p5547p91t3c	22	3	aryl	aryl	ADJ
p5547p91t3c	22	4	substituents	substituent	NOUN
p5547p91t3c	22	5	on	on	ADP
p5547p91t3c	22	6	the	the	DET
p5547p91t3c	22	7	phosphines	phosphine	NOUN
p5547p91t3c	22	8	has	have	VERB
p5547p91t3c	22	9	small	small	ADJ
p5547p91t3c	22	10	effects	effect	NOUN
p5547p91t3c	22	11	on	on	ADP
p5547p91t3c	22	12	rates	rate	NOUN
p5547p91t3c	22	13	and	and	CCONJ
p5547p91t3c	22	14	product	product	NOUN
p5547p91t3c	22	15	distributions	distribution	NOUN
p5547p91t3c	22	16	,	,	PUNCT
p5547p91t3c	22	17	while	while	SCONJ
p5547p91t3c	22	18	changing	change	VERB
p5547p91t3c	22	19	to	to	ADP
p5547p91t3c	22	20	pcy3	pcy3	PROPN
p5547p91t3c	22	21	or	or	CCONJ
p5547p91t3c	22	22	imes	imes	PROPN
p5547p91t3c	22	23	has	have	VERB
p5547p91t3c	22	24	dramatic	dramatic	ADJ
p5547p91t3c	22	25	effects	effect	NOUN
p5547p91t3c	22	26	on	on	ADP
p5547p91t3c	22	27	the	the	DET
p5547p91t3c	22	28	relative	relative	ADJ
p5547p91t3c	22	29	amounts	amount	NOUN
p5547p91t3c	22	30	of	of	ADP
p5547p91t3c	22	31	deoxygenation	deoxygenation	NOUN
p5547p91t3c	22	32	vs.	vs.	ADP
p5547p91t3c	22	33	isomerization	isomerization	NOUN
p5547p91t3c	22	34	observed	observe	VERB
p5547p91t3c	22	35	.	.	PUNCT
p5547p91t3c	23	1	epoxide	epoxide	NOUN
p5547p91t3c	23	2	isomerization	isomerization	NOUN
p5547p91t3c	23	3	as	as	ADV
p5547p91t3c	23	4	well	well	ADV
p5547p91t3c	23	5	as	as	ADP
p5547p91t3c	23	6	iminoxolene	iminoxolene	PROPN
p5547p91t3c	23	7	ligand	ligand	PROPN
p5547p91t3c	23	8	modification	modification	NOUN
p5547p91t3c	23	9	suggests	suggest	VERB
p5547p91t3c	23	10	a	a	DET
p5547p91t3c	23	11	radical	radical	ADJ
p5547p91t3c	23	12	mechanism	mechanism	NOUN
p5547p91t3c	23	13	where	where	SCONJ
p5547p91t3c	23	14	the	the	DET
p5547p91t3c	23	15	ligand	ligand	NOUN
p5547p91t3c	23	16	-	-	PUNCT
p5547p91t3c	23	17	modified	modify	VERB
p5547p91t3c	23	18	products	product	NOUN
p5547p91t3c	23	19	are	be	AUX
p5547p91t3c	23	20	the	the	DET
p5547p91t3c	23	21	resting	rest	VERB
p5547p91t3c	23	22	state	state	NOUN
p5547p91t3c	23	23	of	of	ADP
p5547p91t3c	23	24	the	the	DET
p5547p91t3c	23	25	active	active	ADJ
p5547p91t3c	23	26	catalyst	catalyst	NOUN
p5547p91t3c	23	27	.	.	PUNCT