id	sid	tid	token	lemma	pos
nz805x24562	1	1	the	the	DET
nz805x24562	1	2	properties	property	NOUN
nz805x24562	1	3	of	of	ADP
nz805x24562	1	4	actinide	actinide	ADJ
nz805x24562	1	5	materials	material	NOUN
nz805x24562	1	6	have	have	AUX
nz805x24562	1	7	been	be	AUX
nz805x24562	1	8	explored	explore	VERB
nz805x24562	1	9	by	by	ADP
nz805x24562	1	10	discriminate	discriminate	NOUN
nz805x24562	1	11	ligand	ligand	NOUN
nz805x24562	1	12	selection	selection	NOUN
nz805x24562	1	13	based	base	VERB
nz805x24562	1	14	on	on	ADP
nz805x24562	1	15	hyperpolarizability	hyperpolarizability	NOUN
nz805x24562	1	16	and	and	CCONJ
nz805x24562	1	17	control	control	NOUN
nz805x24562	1	18	of	of	ADP
nz805x24562	1	19	oxidation	oxidation	NOUN
nz805x24562	1	20	state	state	NOUN
nz805x24562	1	21	.	.	PUNCT
nz805x24562	2	1	this	this	PRON
nz805x24562	2	2	has	have	AUX
nz805x24562	2	3	led	lead	VERB
nz805x24562	2	4	to	to	ADP
nz805x24562	2	5	a	a	DET
nz805x24562	2	6	number	number	NOUN
nz805x24562	2	7	of	of	ADP
nz805x24562	2	8	interesting	interesting	ADJ
nz805x24562	2	9	compounds	compound	NOUN
nz805x24562	2	10	that	that	PRON
nz805x24562	2	11	further	far	ADV
nz805x24562	2	12	the	the	DET
nz805x24562	2	13	chemistry	chemistry	NOUN
nz805x24562	2	14	of	of	ADP
nz805x24562	2	15	the	the	DET
nz805x24562	2	16	underexplored	underexplored	ADJ
nz805x24562	2	17	5f	5f	NUM
nz805x24562	2	18	series	series	NOUN
nz805x24562	2	19	.	.	PUNCT
nz805x24562	3	1	this	this	PRON
nz805x24562	3	2	includes	include	VERB
nz805x24562	3	3	the	the	DET
nz805x24562	3	4	synthesis	synthesis	NOUN
nz805x24562	3	5	and	and	CCONJ
nz805x24562	3	6	isolation	isolation	NOUN
nz805x24562	3	7	of	of	ADP
nz805x24562	3	8	the	the	DET
nz805x24562	3	9	surpisingly	surpisingly	ADV
nz805x24562	3	10	air	air	NOUN
nz805x24562	3	11	stable	stable	ADJ
nz805x24562	3	12	u(iii	u(iii	PROPN
nz805x24562	3	13	)	)	PUNCT
nz805x24562	3	14	and	and	CCONJ
nz805x24562	3	15	np(iii	np(iii	NOUN
nz805x24562	3	16	)	)	PUNCT
nz805x24562	3	17	sulfates	sulfate	NOUN
nz805x24562	3	18	along	along	ADP
nz805x24562	3	19	with	with	ADP
nz805x24562	3	20	the	the	DET
nz805x24562	3	21	synthesis	synthesis	NOUN
nz805x24562	3	22	of	of	ADP
nz805x24562	3	23	pu(iii	pu(iii	NOUN
nz805x24562	3	24	)	)	PUNCT
nz805x24562	3	25	molybdate	molybdate	NOUN
nz805x24562	3	26	and	and	CCONJ
nz805x24562	3	27	pu(iii	pu(iii	ADJ
nz805x24562	3	28	)	)	PUNCT
nz805x24562	3	29	tungstate	tungstate	NOUN
nz805x24562	3	30	,	,	PUNCT
nz805x24562	3	31	which	which	PRON
nz805x24562	3	32	feature	feature	VERB
nz805x24562	3	33	a	a	DET
nz805x24562	3	34	metal	metal	NOUN
nz805x24562	3	35	to	to	ADP
nz805x24562	3	36	metal	metal	NOUN
nz805x24562	3	37	charge	charge	NOUN
nz805x24562	3	38	transfer	transfer	NOUN
nz805x24562	3	39	.	.	PUNCT
nz805x24562	4	1	there	there	PRON
nz805x24562	4	2	are	be	VERB
nz805x24562	4	3	two	two	NUM
nz805x24562	4	4	goals	goal	NOUN
nz805x24562	4	5	of	of	ADP
nz805x24562	4	6	this	this	DET
nz805x24562	4	7	work	work	NOUN
nz805x24562	4	8	.	.	PUNCT
nz805x24562	5	1	the	the	DET
nz805x24562	5	2	first	first	ADJ
nz805x24562	5	3	is	be	AUX
nz805x24562	5	4	to	to	PART
nz805x24562	5	5	explore	explore	VERB
nz805x24562	5	6	the	the	DET
nz805x24562	5	7	bonding	bonding	NOUN
nz805x24562	5	8	in	in	ADP
nz805x24562	5	9	trivalent	trivalent	ADJ
nz805x24562	5	10	5f	5f	NUM
nz805x24562	5	11	complexes	complex	NOUN
nz805x24562	5	12	with	with	ADP
nz805x24562	5	13	oxoanions	oxoanion	NOUN
nz805x24562	5	14	.	.	PUNCT
nz805x24562	6	1	oxoanion	oxoanion	NOUN
nz805x24562	6	2	bonding	bonding	NOUN
nz805x24562	6	3	to	to	ADP
nz805x24562	6	4	the	the	DET
nz805x24562	6	5	5f	5f	NUM
nz805x24562	6	6	elements	element	NOUN
nz805x24562	6	7	can	can	AUX
nz805x24562	6	8	range	range	VERB
nz805x24562	6	9	from	from	ADP
nz805x24562	6	10	completely	completely	ADV
nz805x24562	6	11	ionic	ionic	ADJ
nz805x24562	6	12	to	to	ADP
nz805x24562	6	13	partially	partially	ADV
nz805x24562	6	14	covalent	covalent	NOUN
nz805x24562	6	15	.	.	PUNCT
nz805x24562	7	1	however	however	ADV
nz805x24562	7	2	,	,	PUNCT
nz805x24562	7	3	there	there	PRON
nz805x24562	7	4	is	be	VERB
nz805x24562	7	5	little	little	ADJ
nz805x24562	7	6	indication	indication	NOUN
nz805x24562	7	7	of	of	ADP
nz805x24562	7	8	which	which	PRON
nz805x24562	7	9	ligands	ligand	NOUN
nz805x24562	7	10	will	will	AUX
nz805x24562	7	11	express	express	VERB
nz805x24562	7	12	covalent	covalent	NOUN
nz805x24562	7	13	interactions	interaction	NOUN
nz805x24562	7	14	and	and	CCONJ
nz805x24562	7	15	which	which	PRON
nz805x24562	7	16	will	will	AUX
nz805x24562	7	17	express	express	VERB
nz805x24562	7	18	ionic	ionic	ADJ
nz805x24562	7	19	interactions	interaction	NOUN
nz805x24562	7	20	.	.	PUNCT
nz805x24562	8	1	this	this	DET
nz805x24562	8	2	work	work	NOUN
nz805x24562	8	3	shows	show	VERB
nz805x24562	8	4	that	that	SCONJ
nz805x24562	8	5	the	the	DET
nz805x24562	8	6	hyperpolarizability	hyperpolarizability	NOUN
nz805x24562	8	7	can	can	AUX
nz805x24562	8	8	be	be	AUX
nz805x24562	8	9	used	use	VERB
nz805x24562	8	10	as	as	ADP
nz805x24562	8	11	an	an	DET
nz805x24562	8	12	indication	indication	NOUN
nz805x24562	8	13	of	of	ADP
nz805x24562	8	14	anion	anion	NOUN
nz805x24562	8	15	polarizability	polarizability	NOUN
nz805x24562	8	16	which	which	PRON
nz805x24562	8	17	heavily	heavily	ADV
nz805x24562	8	18	influences	influence	VERB
nz805x24562	8	19	the	the	DET
nz805x24562	8	20	type	type	NOUN
nz805x24562	8	21	of	of	ADP
nz805x24562	8	22	bonding	bonding	NOUN
nz805x24562	8	23	observed	observe	VERB
nz805x24562	8	24	.	.	PUNCT
nz805x24562	9	1	anions	anion	NOUN
nz805x24562	9	2	with	with	ADP
nz805x24562	9	3	low	low	ADJ
nz805x24562	9	4	polarizability	polarizability	NOUN
nz805x24562	9	5	,	,	PUNCT
nz805x24562	9	6	such	such	ADJ
nz805x24562	9	7	as	as	ADP
nz805x24562	9	8	phosphite	phosphite	NOUN
nz805x24562	9	9	,	,	PUNCT
nz805x24562	9	10	will	will	AUX
nz805x24562	9	11	participate	participate	VERB
nz805x24562	9	12	in	in	ADP
nz805x24562	9	13	ionic	ionic	ADJ
nz805x24562	9	14	bonding	bonding	NOUN
nz805x24562	9	15	,	,	PUNCT
nz805x24562	9	16	and	and	CCONJ
nz805x24562	9	17	there	there	PRON
nz805x24562	9	18	will	will	AUX
nz805x24562	9	19	be	be	AUX
nz805x24562	9	20	little	little	ADJ
nz805x24562	9	21	difference	difference	NOUN
nz805x24562	9	22	between	between	ADP
nz805x24562	9	23	the	the	DET
nz805x24562	9	24	lanthanide	lanthanide	NOUN
nz805x24562	9	25	and	and	CCONJ
nz805x24562	9	26	actinide	actinide	ADJ
nz805x24562	9	27	compounds	compound	NOUN
nz805x24562	9	28	.	.	PUNCT
nz805x24562	10	1	anions	anion	NOUN
nz805x24562	10	2	with	with	ADP
nz805x24562	10	3	high	high	ADJ
nz805x24562	10	4	polarizability	polarizability	NOUN
nz805x24562	10	5	,	,	PUNCT
nz805x24562	10	6	such	such	ADJ
nz805x24562	10	7	as	as	ADP
nz805x24562	10	8	molybdate	molybdate	NOUN
nz805x24562	10	9	or	or	CCONJ
nz805x24562	10	10	tungstate	tungstate	NOUN
nz805x24562	10	11	,	,	PUNCT
nz805x24562	10	12	will	will	AUX
nz805x24562	10	13	have	have	VERB
nz805x24562	10	14	partially	partially	ADV
nz805x24562	10	15	covalent	covalent	ADJ
nz805x24562	10	16	bonds	bond	NOUN
nz805x24562	10	17	to	to	ADP
nz805x24562	10	18	the	the	DET
nz805x24562	10	19	actinide	actinide	ADJ
nz805x24562	10	20	leading	lead	VERB
nz805x24562	10	21	to	to	ADP
nz805x24562	10	22	unusual	unusual	ADJ
nz805x24562	10	23	properties	property	NOUN
nz805x24562	10	24	and	and	CCONJ
nz805x24562	10	25	distinct	distinct	ADJ
nz805x24562	10	26	difference	difference	NOUN
nz805x24562	10	27	to	to	ADP
nz805x24562	10	28	the	the	DET
nz805x24562	10	29	lanthanide	lanthanide	NOUN
nz805x24562	10	30	analogues	analogue	NOUN
nz805x24562	10	31	.	.	PUNCT
nz805x24562	11	1	the	the	DET
nz805x24562	11	2	second	second	ADJ
nz805x24562	11	3	goal	goal	NOUN
nz805x24562	11	4	of	of	ADP
nz805x24562	11	5	this	this	DET
nz805x24562	11	6	work	work	NOUN
nz805x24562	11	7	is	be	AUX
nz805x24562	11	8	to	to	PART
nz805x24562	11	9	access	access	VERB
nz805x24562	11	10	and	and	CCONJ
nz805x24562	11	11	stabilize	stabilize	VERB
nz805x24562	11	12	unusually	unusually	ADV
nz805x24562	11	13	low	low	ADJ
nz805x24562	11	14	oxidation	oxidation	NOUN
nz805x24562	11	15	states	state	NOUN
nz805x24562	11	16	using	use	VERB
nz805x24562	11	17	hydrothermal	hydrothermal	ADJ
nz805x24562	11	18	techniques	technique	NOUN
nz805x24562	11	19	.	.	PUNCT
nz805x24562	12	1	as	as	SCONJ
nz805x24562	12	2	the	the	DET
nz805x24562	12	3	electronic	electronic	ADJ
nz805x24562	12	4	properties	property	NOUN
nz805x24562	12	5	of	of	ADP
nz805x24562	12	6	actinides	actinide	NOUN
nz805x24562	12	7	are	be	AUX
nz805x24562	12	8	dependent	dependent	ADJ
nz805x24562	12	9	on	on	ADP
nz805x24562	12	10	oxidation	oxidation	NOUN
nz805x24562	12	11	state	state	NOUN
nz805x24562	12	12	,	,	PUNCT
nz805x24562	12	13	the	the	DET
nz805x24562	12	14	ability	ability	NOUN
nz805x24562	12	15	to	to	PART
nz805x24562	12	16	access	access	VERB
nz805x24562	12	17	and	and	CCONJ
nz805x24562	12	18	stabilize	stabilize	VERB
nz805x24562	12	19	different	different	ADJ
nz805x24562	12	20	oxidation	oxidation	NOUN
nz805x24562	12	21	states	state	NOUN
nz805x24562	12	22	is	be	AUX
nz805x24562	12	23	of	of	ADP
nz805x24562	12	24	utmost	utmost	ADJ
nz805x24562	12	25	importance	importance	NOUN
nz805x24562	12	26	.	.	PUNCT
nz805x24562	13	1	oxoanion	oxoanion	NOUN
nz805x24562	13	2	complexes	complex	NOUN
nz805x24562	13	3	of	of	ADP
nz805x24562	13	4	u(iii	u(iii	PROPN
nz805x24562	13	5	)	)	PUNCT
nz805x24562	13	6	and	and	CCONJ
nz805x24562	13	7	np(iii	np(iii	NOUN
nz805x24562	13	8	)	)	PUNCT
nz805x24562	13	9	are	be	AUX
nz805x24562	13	10	exceedingly	exceedingly	ADV
nz805x24562	13	11	rare	rare	ADJ
nz805x24562	13	12	,	,	PUNCT
nz805x24562	13	13	leaving	leave	VERB
nz805x24562	13	14	many	many	ADJ
nz805x24562	13	15	of	of	ADP
nz805x24562	13	16	their	their	PRON
nz805x24562	13	17	properties	property	NOUN
nz805x24562	13	18	underexplored	underexplored	ADJ
nz805x24562	13	19	.	.	PUNCT
nz805x24562	14	1	it	it	PRON
nz805x24562	14	2	is	be	AUX
nz805x24562	14	3	shown	show	VERB
nz805x24562	14	4	that	that	SCONJ
nz805x24562	14	5	u(iii	u(iii	PROPN
nz805x24562	14	6	)	)	PUNCT
nz805x24562	14	7	and	and	CCONJ
nz805x24562	14	8	np(iii	np(iii	PROPN
nz805x24562	14	9	)	)	PUNCT
nz805x24562	14	10	can	can	AUX
nz805x24562	14	11	be	be	AUX
nz805x24562	14	12	obtained	obtain	VERB
nz805x24562	14	13	hydrothermally	hydrothermally	ADV
nz805x24562	14	14	from	from	ADP
nz805x24562	14	15	higher	high	ADJ
nz805x24562	14	16	valent	valent	ADJ
nz805x24562	14	17	starting	start	VERB
nz805x24562	14	18	materials	material	NOUN
nz805x24562	14	19	.	.	PUNCT
nz805x24562	15	1	these	these	DET
nz805x24562	15	2	products	product	NOUN
nz805x24562	15	3	are	be	AUX
nz805x24562	15	4	isolated	isolate	VERB
nz805x24562	15	5	using	use	VERB
nz805x24562	15	6	znhg	znhg	PROPN
nz805x24562	15	7	amalgam	amalgam	NOUN
nz805x24562	15	8	hydrothermally	hydrothermally	ADV
nz805x24562	15	9	,	,	PUNCT
nz805x24562	15	10	with	with	ADP
nz805x24562	15	11	no	no	DET
nz805x24562	15	12	regards	regard	NOUN
nz805x24562	15	13	to	to	ADP
nz805x24562	15	14	o2	o2	ADJ
nz805x24562	15	15	exclusion	exclusion	NOUN
nz805x24562	15	16	.	.	PUNCT
nz805x24562	16	1	this	this	DET
nz805x24562	16	2	work	work	NOUN
nz805x24562	16	3	also	also	ADV
nz805x24562	16	4	shows	show	VERB
nz805x24562	16	5	that	that	SCONJ
nz805x24562	16	6	this	this	DET
nz805x24562	16	7	chemistry	chemistry	NOUN
nz805x24562	16	8	is	be	AUX
nz805x24562	16	9	useful	useful	ADJ
nz805x24562	16	10	outside	outside	ADV
nz805x24562	16	11	of	of	ADP
nz805x24562	16	12	the	the	DET
nz805x24562	16	13	actinides	actinide	NOUN
nz805x24562	16	14	with	with	ADP
nz805x24562	16	15	the	the	DET
nz805x24562	16	16	production	production	NOUN
nz805x24562	16	17	of	of	ADP
nz805x24562	16	18	eu(ii	eu(ii	PROPN
nz805x24562	16	19	)	)	PUNCT
nz805x24562	16	20	,	,	PUNCT
nz805x24562	16	21	v(ii	v(ii	PROPN
nz805x24562	16	22	)	)	PUNCT
nz805x24562	16	23	,	,	PUNCT
nz805x24562	16	24	and	and	CCONJ
nz805x24562	16	25	cr(ii	cr(ii	VERB
nz805x24562	16	26	)	)	PUNCT
nz805x24562	16	27	compounds	compound	VERB
nz805x24562	16	28	in	in	ADP
nz805x24562	16	29	a	a	DET
nz805x24562	16	30	similar	similar	ADJ
nz805x24562	16	31	manner	manner	NOUN
nz805x24562	16	32	.	.	PUNCT
nz805x24562	17	1	this	this	DET
nz805x24562	17	2	dissertation	dissertation	NOUN
nz805x24562	17	3	is	be	AUX
nz805x24562	17	4	focused	focus	VERB
nz805x24562	17	5	on	on	ADP
nz805x24562	17	6	synthesis	synthesis	NOUN
nz805x24562	17	7	and	and	CCONJ
nz805x24562	17	8	characterization	characterization	NOUN
nz805x24562	17	9	on	on	ADP
nz805x24562	17	10	a	a	DET
nz805x24562	17	11	number	number	NOUN
nz805x24562	17	12	of	of	ADP
nz805x24562	17	13	lanthanide	lanthanide	NOUN
nz805x24562	17	14	,	,	PUNCT
nz805x24562	17	15	actinide	actinide	ADJ
nz805x24562	17	16	,	,	PUNCT
nz805x24562	17	17	and	and	CCONJ
nz805x24562	17	18	transition	transition	NOUN
nz805x24562	17	19	metal	metal	NOUN
nz805x24562	17	20	complexes	complex	NOUN
nz805x24562	17	21	.	.	PUNCT
nz805x24562	18	1	chapters	chapter	NOUN
nz805x24562	18	2	3	3	NUM
nz805x24562	18	3	&	&	CCONJ
nz805x24562	18	4	8211	8211	NUM
nz805x24562	18	5	;	;	PUNCT
nz805x24562	18	6	6	6	NUM
nz805x24562	18	7	focus	focus	NOUN
nz805x24562	18	8	on	on	ADP
nz805x24562	18	9	the	the	DET
nz805x24562	18	10	bonding	bonding	NOUN
nz805x24562	18	11	of	of	ADP
nz805x24562	18	12	ligands	ligand	NOUN
nz805x24562	18	13	with	with	ADP
nz805x24562	18	14	low	low	ADJ
nz805x24562	18	15	versus	versus	ADP
nz805x24562	18	16	high	high	ADJ
nz805x24562	18	17	hyperpolarizability	hyperpolarizability	NOUN
nz805x24562	18	18	when	when	SCONJ
nz805x24562	18	19	complexed	complexe	VERB
nz805x24562	18	20	with	with	ADP
nz805x24562	18	21	lanthanides	lanthanide	NOUN
nz805x24562	18	22	and	and	CCONJ
nz805x24562	18	23	actinides	actinide	NOUN
nz805x24562	18	24	.	.	PUNCT
nz805x24562	19	1	chapters	chapter	NOUN
nz805x24562	19	2	7	7	NUM
nz805x24562	19	3	&	&	CCONJ
nz805x24562	19	4	8211	8211	NUM
nz805x24562	19	5	;	;	PUNCT
nz805x24562	19	6	11	11	NUM
nz805x24562	19	7	focus	focus	NOUN
nz805x24562	19	8	on	on	ADP
nz805x24562	19	9	the	the	DET
nz805x24562	19	10	use	use	NOUN
nz805x24562	19	11	of	of	ADP
nz805x24562	19	12	znhg	znhg	PROPN
nz805x24562	19	13	as	as	ADP
nz805x24562	19	14	an	an	PRON
nz805x24562	19	15	in	in	ADP
nz805x24562	19	16	situ	situ	ADJ
nz805x24562	19	17	reductant	reductant	NOUN
nz805x24562	19	18	.	.	PUNCT
nz805x24562	20	1	this	this	DET
nz805x24562	20	2	work	work	NOUN
nz805x24562	20	3	has	have	VERB
nz805x24562	20	4	implications	implication	NOUN
nz805x24562	20	5	for	for	ADP
nz805x24562	20	6	actinide	actinide	ADJ
nz805x24562	20	7	chemistry	chemistry	NOUN
nz805x24562	20	8	through	through	ADP
nz805x24562	20	9	a	a	DET
nz805x24562	20	10	method	method	NOUN
nz805x24562	20	11	of	of	ADP
nz805x24562	20	12	ligand	ligand	NOUN
nz805x24562	20	13	discrimination	discrimination	NOUN
nz805x24562	20	14	to	to	PART
nz805x24562	20	15	affect	affect	VERB
nz805x24562	20	16	actinide	actinide	ADJ
nz805x24562	20	17	properties	property	NOUN
nz805x24562	20	18	.	.	PUNCT
nz805x24562	21	1	this	this	DET
nz805x24562	21	2	work	work	NOUN
nz805x24562	21	3	also	also	ADV
nz805x24562	21	4	has	have	VERB
nz805x24562	21	5	general	general	ADJ
nz805x24562	21	6	implications	implication	NOUN
nz805x24562	21	7	through	through	ADP
nz805x24562	21	8	the	the	DET
nz805x24562	21	9	metal	metal	NOUN
nz805x24562	21	10	-	-	PUNCT
nz805x24562	21	11	to	to	ADP
nz805x24562	21	12	-	-	PUNCT
nz805x24562	21	13	metal	metal	NOUN
nz805x24562	21	14	charge	charge	NOUN
nz805x24562	21	15	transfer	transfer	NOUN
nz805x24562	21	16	of	of	ADP
nz805x24562	21	17	f	f	NOUN
nz805x24562	21	18	-	-	PUNCT
nz805x24562	21	19	elements	element	NOUN
nz805x24562	21	20	which	which	PRON
nz805x24562	21	21	could	could	AUX
nz805x24562	21	22	impact	impact	VERB
nz805x24562	21	23	the	the	DET
nz805x24562	21	24	development	development	NOUN
nz805x24562	21	25	of	of	ADP
nz805x24562	21	26	materials	material	NOUN
nz805x24562	21	27	as	as	ADV
nz805x24562	21	28	well	well	ADV
nz805x24562	21	29	as	as	ADP
nz805x24562	21	30	the	the	DET
nz805x24562	21	31	isolation	isolation	NOUN
nz805x24562	21	32	of	of	ADP
nz805x24562	21	33	v(ii	v(ii	PROPN
nz805x24562	21	34	)	)	PUNCT
nz805x24562	21	35	and	and	CCONJ
nz805x24562	21	36	cr(ii	cr(ii	VERB
nz805x24562	21	37	)	)	PUNCT
nz805x24562	21	38	through	through	ADP
nz805x24562	21	39	hydrothermal	hydrothermal	ADJ
nz805x24562	21	40	synthesis	synthesis	NOUN
nz805x24562	21	41	.	.	PUNCT