id sid tid token lemma pos np193775f9j 1 1 the the DET np193775f9j 1 2 goal goal NOUN np193775f9j 1 3 of of ADP np193775f9j 1 4 this this DET np193775f9j 1 5 dissertation dissertation NOUN np193775f9j 1 6 is be AUX np193775f9j 1 7 to to PART np193775f9j 1 8 explore explore VERB np193775f9j 1 9 the the DET np193775f9j 1 10 fundamental fundamental ADJ np193775f9j 1 11 chemistry chemistry NOUN np193775f9j 1 12 of of ADP np193775f9j 1 13 various various ADJ np193775f9j 1 14 hexavalent hexavalent NOUN np193775f9j 1 15 uranium uranium NOUN np193775f9j 1 16 and and CCONJ np193775f9j 1 17 neptunium neptunium NOUN np193775f9j 1 18 compounds compound NOUN np193775f9j 1 19 with with ADP np193775f9j 1 20 a a DET np193775f9j 1 21 focus focus NOUN np193775f9j 1 22 on on ADP np193775f9j 1 23 crystal crystal NOUN np193775f9j 1 24 structure structure NOUN np193775f9j 1 25 determination determination NOUN np193775f9j 1 26 to to PART np193775f9j 1 27 better well ADV np193775f9j 1 28 understand understand VERB np193775f9j 1 29 the the DET np193775f9j 1 30 formation formation NOUN np193775f9j 1 31 and and CCONJ np193775f9j 1 32 stabilization stabilization NOUN np193775f9j 1 33 of of ADP np193775f9j 1 34 actinide actinide ADJ np193775f9j 1 35 compounds compound NOUN np193775f9j 1 36 in in ADP np193775f9j 1 37 the the DET np193775f9j 1 38 solid solid ADJ np193775f9j 1 39 - - PUNCT np193775f9j 1 40 state state NOUN np193775f9j 1 41 . . PUNCT np193775f9j 2 1 solvothermal solvothermal ADJ np193775f9j 2 2 synthetic synthetic ADJ np193775f9j 2 3 approaches approach NOUN np193775f9j 2 4 using use VERB np193775f9j 2 5 both both CCONJ np193775f9j 2 6 aqueous aqueous ADJ np193775f9j 2 7 and and CCONJ np193775f9j 2 8 ionic ionic ADJ np193775f9j 2 9 liquid liquid ADJ np193775f9j 2 10 solvents solvent NOUN np193775f9j 2 11 were be AUX np193775f9j 2 12 implemented implement VERB np193775f9j 2 13 to to PART np193775f9j 2 14 grow grow VERB np193775f9j 2 15 crystals crystal NOUN np193775f9j 2 16 yielding yield VERB np193775f9j 2 17 a a DET np193775f9j 2 18 variety variety NOUN np193775f9j 2 19 of of ADP np193775f9j 2 20 different different ADJ np193775f9j 2 21 organic organic ADJ np193775f9j 2 22 - - PUNCT np193775f9j 2 23 inorganic inorganic ADJ np193775f9j 2 24 hybrid hybrid NOUN np193775f9j 2 25 structures structure NOUN np193775f9j 2 26 . . PUNCT np193775f9j 3 1 special special ADJ np193775f9j 3 2 emphasis emphasis NOUN np193775f9j 3 3 is be AUX np193775f9j 3 4 placed place VERB np193775f9j 3 5 on on ADP np193775f9j 3 6 the the DET np193775f9j 3 7 use use NOUN np193775f9j 3 8 of of ADP np193775f9j 3 9 ionic ionic ADJ np193775f9j 3 10 liquids liquid NOUN np193775f9j 3 11 as as ADP np193775f9j 3 12 the the DET np193775f9j 3 13 main main ADJ np193775f9j 3 14 reaction reaction NOUN np193775f9j 3 15 medium medium NOUN np193775f9j 3 16 , , PUNCT np193775f9j 3 17 given give VERB np193775f9j 3 18 the the DET np193775f9j 3 19 relatively relatively ADV np193775f9j 3 20 few few ADJ np193775f9j 3 21 reports report NOUN np193775f9j 3 22 of of ADP np193775f9j 3 23 their their PRON np193775f9j 3 24 use use NOUN np193775f9j 3 25 in in ADP np193775f9j 3 26 the the DET np193775f9j 3 27 synthesis synthesis NOUN np193775f9j 3 28 of of ADP np193775f9j 3 29 actinide actinide ADJ np193775f9j 3 30 - - PUNCT np193775f9j 3 31 bearing bear VERB np193775f9j 3 32 compounds.projects compounds.project NOUN np193775f9j 3 33 were be AUX np193775f9j 3 34 developed develop VERB np193775f9j 3 35 to to PART np193775f9j 3 36 further further ADJ np193775f9j 3 37 study study NOUN np193775f9j 3 38 organically organically ADV np193775f9j 3 39 stabilized stabilize VERB np193775f9j 3 40 uranyl uranyl ADJ np193775f9j 3 41 sulfate sulfate NOUN np193775f9j 3 42 materials material NOUN np193775f9j 3 43 , , PUNCT np193775f9j 3 44 which which PRON np193775f9j 3 45 are be AUX np193775f9j 3 46 known know VERB np193775f9j 3 47 for for ADP np193775f9j 3 48 their their PRON np193775f9j 3 49 rich rich ADJ np193775f9j 3 50 structural structural ADJ np193775f9j 3 51 diversity diversity NOUN np193775f9j 3 52 . . PUNCT np193775f9j 4 1 the the DET np193775f9j 4 2 goal goal NOUN np193775f9j 4 3 of of ADP np193775f9j 4 4 the the DET np193775f9j 4 5 first first ADJ np193775f9j 4 6 of of ADP np193775f9j 4 7 these these PRON np193775f9j 4 8 is be AUX np193775f9j 4 9 systematically systematically ADV np193775f9j 4 10 changing change VERB np193775f9j 4 11 solvothermal solvothermal ADJ np193775f9j 4 12 synthetic synthetic ADJ np193775f9j 4 13 parameters parameter NOUN np193775f9j 4 14 to to PART np193775f9j 4 15 better well ADV np193775f9j 4 16 understand understand VERB np193775f9j 4 17 how how SCONJ np193775f9j 4 18 the the DET np193775f9j 4 19 chemical chemical ADJ np193775f9j 4 20 and and CCONJ np193775f9j 4 21 heat heat NOUN np193775f9j 4 22 treatment treatment NOUN np193775f9j 4 23 variables variable NOUN np193775f9j 4 24 influence influence VERB np193775f9j 4 25 the the DET np193775f9j 4 26 resultant resultant ADJ np193775f9j 4 27 crystal crystal NOUN np193775f9j 4 28 structures structure NOUN np193775f9j 4 29 . . PUNCT np193775f9j 5 1 the the DET np193775f9j 5 2 second second ADJ np193775f9j 5 3 study study NOUN np193775f9j 5 4 investigates investigate VERB np193775f9j 5 5 the the DET np193775f9j 5 6 way way NOUN np193775f9j 5 7 in in ADP np193775f9j 5 8 which which PRON np193775f9j 5 9 the the DET np193775f9j 5 10 organic organic ADJ np193775f9j 5 11 cations cation NOUN np193775f9j 5 12 and and CCONJ np193775f9j 5 13 interstitial interstitial ADJ np193775f9j 5 14 species specie NOUN np193775f9j 5 15 coordinate coordinate VERB np193775f9j 5 16 to to PART np193775f9j 5 17 and and CCONJ np193775f9j 5 18 stabilize stabilize VERB np193775f9j 5 19 uranyl uranyl ADJ np193775f9j 5 20 sulfate sulfate NOUN np193775f9j 5 21 structural structural ADJ np193775f9j 5 22 units.projects units.project NOUN np193775f9j 5 23 were be AUX np193775f9j 5 24 also also ADV np193775f9j 5 25 developed develop VERB np193775f9j 5 26 to to PART np193775f9j 5 27 investigate investigate VERB np193775f9j 5 28 uranyl uranyl ADJ np193775f9j 5 29 phosphate phosphate NOUN np193775f9j 5 30 chemistry chemistry NOUN np193775f9j 5 31 , , PUNCT np193775f9j 5 32 which which PRON np193775f9j 5 33 has have VERB np193775f9j 5 34 importance importance NOUN np193775f9j 5 35 to to ADP np193775f9j 5 36 separations separation NOUN np193775f9j 5 37 and and CCONJ np193775f9j 5 38 environmental environmental ADJ np193775f9j 5 39 remediation remediation NOUN np193775f9j 5 40 strategies strategy NOUN np193775f9j 5 41 . . PUNCT np193775f9j 6 1 the the DET np193775f9j 6 2 first first ADV np193775f9j 6 3 produced produce VERB np193775f9j 6 4 four four NUM np193775f9j 6 5 novel novel ADJ np193775f9j 6 6 uranyl uranyl NOUN np193775f9j 6 7 phosphate phosphate NOUN np193775f9j 6 8 crystal crystal NOUN np193775f9j 6 9 structures structure NOUN np193775f9j 6 10 with with ADP np193775f9j 6 11 unique unique ADJ np193775f9j 6 12 topologies topology NOUN np193775f9j 6 13 influenced influence VERB np193775f9j 6 14 by by ADP np193775f9j 6 15 the the DET np193775f9j 6 16 incorporation incorporation NOUN np193775f9j 6 17 of of ADP np193775f9j 6 18 the the DET np193775f9j 6 19 diethyl diethyl PROPN np193775f9j 6 20 phosphate phosphate NOUN np193775f9j 6 21 anion anion NOUN np193775f9j 6 22 from from ADP np193775f9j 6 23 the the DET np193775f9j 6 24 ionic ionic ADJ np193775f9j 6 25 liquid liquid NOUN np193775f9j 6 26 . . PUNCT np193775f9j 7 1 the the DET np193775f9j 7 2 role role NOUN np193775f9j 7 3 the the DET np193775f9j 7 4 organic organic NOUN np193775f9j 7 5 on on ADP np193775f9j 7 6 the the DET np193775f9j 7 7 organophosphate organophosphate NOUN np193775f9j 7 8 anion anion NOUN np193775f9j 7 9 is be AUX np193775f9j 7 10 further far ADV np193775f9j 7 11 investigated investigate VERB np193775f9j 7 12 by by ADP np193775f9j 7 13 replacing replace VERB np193775f9j 7 14 the the DET np193775f9j 7 15 diethyl diethyl PROPN np193775f9j 7 16 phosphate phosphate NOUN np193775f9j 7 17 with with ADP np193775f9j 7 18 dimethyl dimethyl NOUN np193775f9j 7 19 and and CCONJ np193775f9j 7 20 dibutyl dibutyl NOUN np193775f9j 7 21 phosphate phosphate NOUN np193775f9j 7 22 to to PART np193775f9j 7 23 see see VERB np193775f9j 7 24 how how SCONJ np193775f9j 7 25 the the DET np193775f9j 7 26 chemical chemical NOUN np193775f9j 7 27 system system NOUN np193775f9j 7 28 and and CCONJ np193775f9j 7 29 the the DET np193775f9j 7 30 resulting result VERB np193775f9j 7 31 crystal crystal NOUN np193775f9j 7 32 structures structure NOUN np193775f9j 7 33 change.the change.the DET np193775f9j 7 34 third third ADJ np193775f9j 7 35 set set NOUN np193775f9j 7 36 of of ADP np193775f9j 7 37 projects project NOUN np193775f9j 7 38 explores explore VERB np193775f9j 7 39 more more ADJ np193775f9j 7 40 complex complex ADJ np193775f9j 7 41 chemical chemical NOUN np193775f9j 7 42 systems system NOUN np193775f9j 7 43 , , PUNCT np193775f9j 7 44 namely namely ADV np193775f9j 7 45 the the DET np193775f9j 7 46 addition addition NOUN np193775f9j 7 47 of of ADP np193775f9j 7 48 vanadium vanadium NOUN np193775f9j 7 49 into into ADP np193775f9j 7 50 the the DET np193775f9j 7 51 uranyl uranyl ADJ np193775f9j 7 52 phosphate phosphate NOUN np193775f9j 7 53 system system NOUN np193775f9j 7 54 and and CCONJ np193775f9j 7 55 neptunium neptunium NOUN np193775f9j 7 56 with with ADP np193775f9j 7 57 ionic ionic ADJ np193775f9j 7 58 liquids liquid NOUN np193775f9j 7 59 . . PUNCT np193775f9j 8 1 the the DET np193775f9j 8 2 addition addition NOUN np193775f9j 8 3 of of ADP np193775f9j 8 4 vanadium vanadium NOUN np193775f9j 8 5 precursors precursor NOUN np193775f9j 8 6 promotes promote VERB np193775f9j 8 7 the the DET np193775f9j 8 8 crystallization crystallization NOUN np193775f9j 8 9 of of ADP np193775f9j 8 10 novel novel ADJ np193775f9j 8 11 uranyl uranyl NOUN np193775f9j 8 12 vanadate vanadate NOUN np193775f9j 8 13 clusters cluster NOUN np193775f9j 8 14 with with ADP np193775f9j 8 15 unusual unusual ADJ np193775f9j 8 16 shell shell NOUN np193775f9j 8 17 architectures architecture NOUN np193775f9j 8 18 that that PRON np193775f9j 8 19 are be AUX np193775f9j 8 20 described describe VERB np193775f9j 8 21 and and CCONJ np193775f9j 8 22 the the DET np193775f9j 8 23 solution solution NOUN np193775f9j 8 24 speciation speciation NOUN np193775f9j 8 25 was be AUX np193775f9j 8 26 analyzed analyze VERB np193775f9j 8 27 . . PUNCT np193775f9j 9 1 in in ADP np193775f9j 9 2 the the DET np193775f9j 9 3 final final ADJ np193775f9j 9 4 study study NOUN np193775f9j 9 5 , , PUNCT np193775f9j 9 6 isostructural isostructural ADJ np193775f9j 9 7 uranyl uranyl NOUN np193775f9j 9 8 and and CCONJ np193775f9j 9 9 neptunyl neptunyl ADJ np193775f9j 9 10 compounds compound NOUN np193775f9j 9 11 are be AUX np193775f9j 9 12 synthesized synthesize VERB np193775f9j 9 13 to to PART np193775f9j 9 14 compare compare VERB np193775f9j 9 15 spectroscopic spectroscopic ADJ np193775f9j 9 16 details detail NOUN np193775f9j 9 17 to to PART np193775f9j 9 18 understand understand VERB np193775f9j 9 19 differences difference NOUN np193775f9j 9 20 between between ADP np193775f9j 9 21 the the DET np193775f9j 9 22 uranyl uranyl NOUN np193775f9j 9 23 and and CCONJ np193775f9j 9 24 neptunyl neptunyl ADJ np193775f9j 9 25 ions ion NOUN np193775f9j 9 26 . . PUNCT np193775f9j 10 1 overall overall ADV np193775f9j 10 2 , , PUNCT np193775f9j 10 3 these these DET np193775f9j 10 4 studies study NOUN np193775f9j 10 5 highlight highlight VERB np193775f9j 10 6 the the DET np193775f9j 10 7 use use NOUN np193775f9j 10 8 of of ADP np193775f9j 10 9 ionic ionic ADJ np193775f9j 10 10 liquids liquid NOUN np193775f9j 10 11 in in ADP np193775f9j 10 12 the the DET np193775f9j 10 13 synthesis synthesis NOUN np193775f9j 10 14 of of ADP np193775f9j 10 15 novel novel ADJ np193775f9j 10 16 uranyl uranyl NOUN np193775f9j 10 17 and and CCONJ np193775f9j 10 18 neptunyl neptunyl ADJ np193775f9j 10 19 compounds compound NOUN np193775f9j 10 20 . . PUNCT