id	sid	tid	token	lemma	pos
n583xs57z1t	1	1	alkyne	alkyne	PROPN
n583xs57z1t	1	2	substituent	substituent	NOUN
n583xs57z1t	1	3	effects	effect	NOUN
n583xs57z1t	1	4	in	in	ADP
n583xs57z1t	1	5	the	the	DET
n583xs57z1t	1	6	methylenecyclopropane	methylenecyclopropane	NOUN
n583xs57z1t	1	7	rearrangement	rearrangement	NOUN
n583xs57z1t	1	8	as	as	ADV
n583xs57z1t	1	9	well	well	ADV
n583xs57z1t	1	10	as	as	ADP
n583xs57z1t	1	11	solvolysis	solvolysis	NOUN
n583xs57z1t	1	12	studies	study	NOUN
n583xs57z1t	1	13	of	of	ADP
n583xs57z1t	1	14	the	the	DET
n583xs57z1t	1	15	structurally	structurally	ADV
n583xs57z1t	1	16	similar	similar	ADJ
n583xs57z1t	1	17	trifluoroacetates	trifluoroacetate	NOUN
n583xs57z1t	1	18	were	be	AUX
n583xs57z1t	1	19	determined	determine	VERB
n583xs57z1t	1	20	.	.	PUNCT
n583xs57z1t	2	1	the	the	DET
n583xs57z1t	2	2	results	result	NOUN
n583xs57z1t	2	3	of	of	ADP
n583xs57z1t	2	4	these	these	DET
n583xs57z1t	2	5	kinetic	kinetic	ADJ
n583xs57z1t	2	6	studies	study	NOUN
n583xs57z1t	2	7	fell	fall	VERB
n583xs57z1t	2	8	into	into	ADP
n583xs57z1t	2	9	a	a	DET
n583xs57z1t	2	10	range	range	NOUN
n583xs57z1t	2	11	that	that	PRON
n583xs57z1t	2	12	was	be	AUX
n583xs57z1t	2	13	expected	expect	VERB
n583xs57z1t	2	14	.	.	PUNCT
n583xs57z1t	3	1	in	in	ADP
n583xs57z1t	3	2	the	the	DET
n583xs57z1t	3	3	methylenecyclopropane	methylenecyclopropane	NOUN
n583xs57z1t	3	4	rearrangement	rearrangement	NOUN
n583xs57z1t	3	5	all	all	DET
n583xs57z1t	3	6	studied	study	VERB
n583xs57z1t	3	7	systems	system	NOUN
n583xs57z1t	3	8	are	be	AUX
n583xs57z1t	3	9	moderate	moderate	ADJ
n583xs57z1t	3	10	radical	radical	ADJ
n583xs57z1t	3	11	stabilizers	stabilizer	NOUN
n583xs57z1t	3	12	,	,	PUNCT
n583xs57z1t	3	13	rearranging	rearrange	VERB
n583xs57z1t	3	14	more	more	ADV
n583xs57z1t	3	15	quickly	quickly	ADV
n583xs57z1t	3	16	than	than	ADP
n583xs57z1t	3	17	the	the	DET
n583xs57z1t	3	18	parent	parent	NOUN
n583xs57z1t	3	19	system	system	NOUN
n583xs57z1t	3	20	.	.	PUNCT
n583xs57z1t	4	1	solvolytic	solvolytic	PROPN
n583xs57z1t	4	2	studies	study	NOUN
n583xs57z1t	4	3	showed	show	VERB
n583xs57z1t	4	4	that	that	SCONJ
n583xs57z1t	4	5	the	the	DET
n583xs57z1t	4	6	sigma	sigma	PROPN
n583xs57z1t	4	7	+	+	CCONJ
n583xs57z1t	4	8	values	value	NOUN
n583xs57z1t	4	9	for	for	ADP
n583xs57z1t	4	10	the	the	DET
n583xs57z1t	4	11	para	para	NOUN
n583xs57z1t	4	12	-	-	PUNCT
n583xs57z1t	4	13	substituted	substitute	VERB
n583xs57z1t	4	14	trifluoroacetates	trifluoroacetate	NOUN
n583xs57z1t	4	15	are	be	AUX
n583xs57z1t	4	16	relatively	relatively	ADV
n583xs57z1t	4	17	similar	similar	ADJ
n583xs57z1t	4	18	,	,	PUNCT
n583xs57z1t	4	19	with	with	ADP
n583xs57z1t	4	20	the	the	DET
n583xs57z1t	4	21	para	para	PROPN
n583xs57z1t	4	22	-	-	PUNCT
n583xs57z1t	4	23	acetylene	acetylene	PROPN
n583xs57z1t	4	24	group	group	NOUN
n583xs57z1t	4	25	the	the	DET
n583xs57z1t	4	26	only	only	ADJ
n583xs57z1t	4	27	system	system	NOUN
n583xs57z1t	4	28	that	that	PRON
n583xs57z1t	4	29	showed	show	VERB
n583xs57z1t	4	30	rate	rate	NOUN
n583xs57z1t	4	31	retardation	retardation	NOUN
n583xs57z1t	4	32	in	in	ADP
n583xs57z1t	4	33	reference	reference	NOUN
n583xs57z1t	4	34	to	to	ADP
n583xs57z1t	4	35	the	the	DET
n583xs57z1t	4	36	parent	parent	NOUN
n583xs57z1t	4	37	para	para	PROPN
n583xs57z1t	4	38	-	-	PUNCT
n583xs57z1t	4	39	hydrogen	hydrogen	NOUN
n583xs57z1t	4	40	system	system	NOUN
n583xs57z1t	4	41	.	.	PUNCT
n583xs57z1t	5	1	the	the	DET
n583xs57z1t	5	2	studies	study	NOUN
n583xs57z1t	5	3	also	also	ADV
n583xs57z1t	5	4	showed	show	VERB
n583xs57z1t	5	5	the	the	DET
n583xs57z1t	5	6	gamma	gamma	NOUN
n583xs57z1t	5	7	+	+	CCONJ
n583xs57z1t	5	8	value	value	NOUN
n583xs57z1t	5	9	of	of	ADP
n583xs57z1t	5	10	the	the	DET
n583xs57z1t	5	11	1,2,3	1,2,3	NUM
n583xs57z1t	5	12	-	-	PUNCT
n583xs57z1t	5	13	triazole	triazole	NOUN
n583xs57z1t	5	14	system	system	NOUN
n583xs57z1t	5	15	is	be	AUX
n583xs57z1t	5	16	better	well	ADJ
n583xs57z1t	5	17	at	at	ADP
n583xs57z1t	5	18	stabilizing	stabilize	VERB
n583xs57z1t	5	19	a	a	DET
n583xs57z1t	5	20	developing	develop	VERB
n583xs57z1t	5	21	carbocation	carbocation	NOUN
n583xs57z1t	5	22	by	by	ADP
n583xs57z1t	5	23	a	a	DET
n583xs57z1t	5	24	factor	factor	NOUN
n583xs57z1t	5	25	of	of	ADP
n583xs57z1t	5	26	39	39	NUM
n583xs57z1t	5	27	than	than	ADP
n583xs57z1t	5	28	a	a	DET
n583xs57z1t	5	29	phenyl	phenyl	NOUN
n583xs57z1t	5	30	ring	ring	NOUN
n583xs57z1t	5	31	.	.	PUNCT
n583xs57z1t	6	1	this	this	PRON
n583xs57z1t	6	2	is	be	AUX
n583xs57z1t	6	3	due	due	ADJ
n583xs57z1t	6	4	to	to	ADP
n583xs57z1t	6	5	further	further	ADJ
n583xs57z1t	6	6	delocalization	delocalization	NOUN
n583xs57z1t	6	7	of	of	ADP
n583xs57z1t	6	8	the	the	DET
n583xs57z1t	6	9	carbocation	carbocation	NOUN
n583xs57z1t	6	10	.	.	PUNCT