id sid tid token lemma pos n296ww74n4g 1 1 base base NOUN n296ww74n4g 1 2 metal metal NOUN n296ww74n4g 1 3 oxides oxide NOUN n296ww74n4g 1 4 are be AUX n296ww74n4g 1 5 of of ADP n296ww74n4g 1 6 interest interest NOUN n296ww74n4g 1 7 as as ADP n296ww74n4g 1 8 low low ADJ n296ww74n4g 1 9 - - PUNCT n296ww74n4g 1 10 cost cost NOUN n296ww74n4g 1 11 replacements replacement NOUN n296ww74n4g 1 12 for for ADP n296ww74n4g 1 13 pt pt PROPN n296ww74n4g 1 14 - - PUNCT n296ww74n4g 1 15 based base VERB n296ww74n4g 1 16 no no DET n296ww74n4g 1 17 oxidation oxidation NOUN n296ww74n4g 1 18 catalysts catalyst NOUN n296ww74n4g 1 19 . . PUNCT n296ww74n4g 2 1 while while SCONJ n296ww74n4g 2 2 the the DET n296ww74n4g 2 3 mechanism mechanism NOUN n296ww74n4g 2 4 of of ADP n296ww74n4g 2 5 pt pt PROPN n296ww74n4g 2 6 - - PUNCT n296ww74n4g 2 7 catalyzed catalyze VERB n296ww74n4g 2 8 no no DET n296ww74n4g 2 9 oxidation oxidation NOUN n296ww74n4g 2 10 is be AUX n296ww74n4g 2 11 fairly fairly ADV n296ww74n4g 2 12 well well ADV n296ww74n4g 2 13 understood understand VERB n296ww74n4g 2 14 , , PUNCT n296ww74n4g 2 15 such such ADJ n296ww74n4g 2 16 is be AUX n296ww74n4g 2 17 not not PART n296ww74n4g 2 18 the the DET n296ww74n4g 2 19 case case NOUN n296ww74n4g 2 20 for for ADP n296ww74n4g 2 21 the the DET n296ww74n4g 2 22 oxides oxide NOUN n296ww74n4g 2 23 . . PUNCT n296ww74n4g 3 1 in in ADP n296ww74n4g 3 2 this this DET n296ww74n4g 3 3 work work NOUN n296ww74n4g 3 4 , , PUNCT n296ww74n4g 3 5 we we PRON n296ww74n4g 3 6 report report VERB n296ww74n4g 3 7 density density NOUN n296ww74n4g 3 8 functional functional ADJ n296ww74n4g 3 9 theory theory NOUN n296ww74n4g 3 10 ( ( PUNCT n296ww74n4g 3 11 dft dft NOUN n296ww74n4g 3 12 ) ) PUNCT n296ww74n4g 3 13 and and CCONJ n296ww74n4g 3 14 kinetic kinetic ADJ n296ww74n4g 3 15 modeling modeling NOUN n296ww74n4g 3 16 results result NOUN n296ww74n4g 3 17 for for ADP n296ww74n4g 3 18 one one NUM n296ww74n4g 3 19 class class NOUN n296ww74n4g 3 20 of of ADP n296ww74n4g 3 21 potential potential ADJ n296ww74n4g 3 22 oxide oxide NOUN n296ww74n4g 3 23 catalysts catalyst NOUN n296ww74n4g 3 24 , , PUNCT n296ww74n4g 3 25 the the DET n296ww74n4g 3 26 perovskites perovskite NOUN n296ww74n4g 3 27 . . PUNCT n296ww74n4g 4 1 the the DET n296ww74n4g 4 2 perovskite perovskite PROPN n296ww74n4g 4 3 lacoo3 lacoo3 PROPN n296ww74n4g 4 4 itself itself PRON n296ww74n4g 4 5 has have AUX n296ww74n4g 4 6 been be AUX n296ww74n4g 4 7 shown show VERB n296ww74n4g 4 8 to to PART n296ww74n4g 4 9 have have VERB n296ww74n4g 4 10 good good ADJ n296ww74n4g 4 11 no no DET n296ww74n4g 4 12 oxidation oxidation NOUN n296ww74n4g 4 13 activity activity NOUN n296ww74n4g 4 14 , , PUNCT n296ww74n4g 4 15 and and CCONJ n296ww74n4g 4 16 sr sr PROPN n296ww74n4g 4 17 substitution substitution NOUN n296ww74n4g 4 18 improves improve VERB n296ww74n4g 4 19 no no DET n296ww74n4g 4 20 oxidation oxidation NOUN n296ww74n4g 4 21 rates rate NOUN n296ww74n4g 4 22 and and CCONJ n296ww74n4g 4 23 reduces reduce VERB n296ww74n4g 4 24 no2 no2 NOUN n296ww74n4g 4 25 inhibition inhibition NOUN n296ww74n4g 4 26 . . PUNCT n296ww74n4g 5 1 we we PRON n296ww74n4g 5 2 used use VERB n296ww74n4g 5 3 periodic periodic ADJ n296ww74n4g 5 4 dft dft ADJ n296ww74n4g 5 5 calculations calculation NOUN n296ww74n4g 5 6 in in ADP n296ww74n4g 5 7 the the DET n296ww74n4g 5 8 vienna vienna PROPN n296ww74n4g 5 9 ab ab PROPN n296ww74n4g 5 10 initio initio PROPN n296ww74n4g 5 11 simulation simulation PROPN n296ww74n4g 5 12 package package NOUN n296ww74n4g 5 13 to to PART n296ww74n4g 5 14 compute compute VERB n296ww74n4g 5 15 the the DET n296ww74n4g 5 16 energies energy NOUN n296ww74n4g 5 17 of of ADP n296ww74n4g 5 18 vacancies vacancy NOUN n296ww74n4g 5 19 , , PUNCT n296ww74n4g 5 20 o o PROPN n296ww74n4g 5 21 , , PUNCT n296ww74n4g 5 22 o2 o2 PROPN n296ww74n4g 5 23 , , PUNCT n296ww74n4g 5 24 no no INTJ n296ww74n4g 5 25 , , PUNCT n296ww74n4g 5 26 no2 no2 NOUN n296ww74n4g 5 27 , , PUNCT n296ww74n4g 5 28 and and CCONJ n296ww74n4g 5 29 no3 no3 NOUN n296ww74n4g 5 30 on on ADP n296ww74n4g 5 31 the the DET n296ww74n4g 5 32 ( ( PUNCT n296ww74n4g 5 33 100)-lao 100)-lao NUM n296ww74n4g 5 34 and and CCONJ n296ww74n4g 5 35 ( ( PUNCT n296ww74n4g 5 36 100)-coo2 100)-coo2 NUM n296ww74n4g 5 37 terminations termination NOUN n296ww74n4g 5 38 of of ADP n296ww74n4g 5 39 the the DET n296ww74n4g 5 40 parent parent NOUN n296ww74n4g 5 41 lacoo3 lacoo3 PROPN n296ww74n4g 5 42 and and CCONJ n296ww74n4g 5 43 8%-doped 8%-dope VERB n296ww74n4g 5 44 sr sr PROPN n296ww74n4g 5 45 - - PUNCT n296ww74n4g 5 46 substituted substitute VERB n296ww74n4g 5 47 material material NOUN n296ww74n4g 5 48 . . PUNCT n296ww74n4g 6 1 further far ADV n296ww74n4g 6 2 , , PUNCT n296ww74n4g 6 3 we we PRON n296ww74n4g 6 4 used use VERB n296ww74n4g 6 5 first first ADJ n296ww74n4g 6 6 - - PUNCT n296ww74n4g 6 7 principles principle NOUN n296ww74n4g 6 8 thermodynamic thermodynamic ADJ n296ww74n4g 6 9 models model NOUN n296ww74n4g 6 10 to to PART n296ww74n4g 6 11 determine determine VERB n296ww74n4g 6 12 the the DET n296ww74n4g 6 13 most most ADV n296ww74n4g 6 14 common common ADJ n296ww74n4g 6 15 surface surface NOUN n296ww74n4g 6 16 species specie NOUN n296ww74n4g 6 17 under under ADP n296ww74n4g 6 18 no no DET n296ww74n4g 6 19 oxidation oxidation NOUN n296ww74n4g 6 20 conditions condition NOUN n296ww74n4g 6 21 . . PUNCT n296ww74n4g 7 1 experimental experimental ADJ n296ww74n4g 7 2 tpd tpd PROPN n296ww74n4g 7 3 suggest suggest VERB n296ww74n4g 7 4 o o INTJ n296ww74n4g 7 5 , , PUNCT n296ww74n4g 7 6 no no INTJ n296ww74n4g 7 7 , , PUNCT n296ww74n4g 7 8 and and CCONJ n296ww74n4g 7 9 no2 no2 PROPN n296ww74n4g 7 10 species specie NOUN n296ww74n4g 7 11 are be AUX n296ww74n4g 7 12 present present ADJ n296ww74n4g 7 13 on on ADP n296ww74n4g 7 14 the the DET n296ww74n4g 7 15 perovskites perovskite NOUN n296ww74n4g 7 16 . . PUNCT n296ww74n4g 8 1 thermodynamic thermodynamic ADJ n296ww74n4g 8 2 models model NOUN n296ww74n4g 8 3 show show VERB n296ww74n4g 8 4 nitrates nitrate NOUN n296ww74n4g 8 5 and and CCONJ n296ww74n4g 8 6 adsorbed adsorb VERB n296ww74n4g 8 7 no2 no2 PRON n296ww74n4g 8 8 as as ADP n296ww74n4g 8 9 the the DET n296ww74n4g 8 10 most most ADV n296ww74n4g 8 11 stable stable ADJ n296ww74n4g 8 12 species specie NOUN n296ww74n4g 8 13 on on ADP n296ww74n4g 8 14 the the DET n296ww74n4g 8 15 lao lao NOUN n296ww74n4g 8 16 and and CCONJ n296ww74n4g 8 17 coo2 coo2 NOUN n296ww74n4g 8 18 terminations termination NOUN n296ww74n4g 8 19 , , PUNCT n296ww74n4g 8 20 respectively respectively ADV n296ww74n4g 8 21 . . PUNCT n296ww74n4g 9 1 based base VERB n296ww74n4g 9 2 on on ADP n296ww74n4g 9 3 the the DET n296ww74n4g 9 4 results result NOUN n296ww74n4g 9 5 above above ADV n296ww74n4g 9 6 , , PUNCT n296ww74n4g 9 7 we we PRON n296ww74n4g 9 8 performed perform VERB n296ww74n4g 9 9 a a DET n296ww74n4g 9 10 dft dft NOUN n296ww74n4g 9 11 screening screening NOUN n296ww74n4g 9 12 of of ADP n296ww74n4g 9 13 vacancies vacancy NOUN n296ww74n4g 9 14 , , PUNCT n296ww74n4g 9 15 o o INTJ n296ww74n4g 9 16 , , PUNCT n296ww74n4g 9 17 no no INTJ n296ww74n4g 9 18 , , PUNCT n296ww74n4g 9 19 no2 no2 NOUN n296ww74n4g 9 20 , , PUNCT n296ww74n4g 9 21 and and CCONJ n296ww74n4g 9 22 no3 no3 NOUN n296ww74n4g 9 23 intermediates intermediate NOUN n296ww74n4g 9 24 on on ADP n296ww74n4g 9 25 the the DET n296ww74n4g 9 26 ( ( PUNCT n296ww74n4g 9 27 100)-lao 100)-lao NUM n296ww74n4g 9 28 and and CCONJ n296ww74n4g 9 29 ( ( PUNCT n296ww74n4g 9 30 100)-mo2 100)-mo2 NUM n296ww74n4g 9 31 terminations termination NOUN n296ww74n4g 9 32 of of ADP n296ww74n4g 9 33 the the DET n296ww74n4g 9 34 entire entire ADJ n296ww74n4g 9 35 first first ADJ n296ww74n4g 9 36 row row NOUN n296ww74n4g 9 37 perovskite perovskite PROPN n296ww74n4g 9 38 series series PROPN n296ww74n4g 9 39 , , PUNCT n296ww74n4g 9 40 lamo3 lamo3 PROPN n296ww74n4g 9 41 ( ( PUNCT n296ww74n4g 9 42 m m NOUN n296ww74n4g 9 43 = = SYM n296ww74n4g 9 44 sc sc PROPN n296ww74n4g 9 45 - - PUNCT n296ww74n4g 9 46 cu cu PROPN n296ww74n4g 9 47 ) ) PUNCT n296ww74n4g 9 48 . . PUNCT n296ww74n4g 10 1 vacancy vacancy NOUN n296ww74n4g 10 2 and and CCONJ n296ww74n4g 10 3 o o INTJ n296ww74n4g 10 4 energies energy NOUN n296ww74n4g 10 5 vary vary VERB n296ww74n4g 10 6 nearly nearly ADV n296ww74n4g 10 7 linearly linearly ADV n296ww74n4g 10 8 across across ADP n296ww74n4g 10 9 the the DET n296ww74n4g 10 10 series series NOUN n296ww74n4g 10 11 , , PUNCT n296ww74n4g 10 12 while while SCONJ n296ww74n4g 10 13 nox nox NOUN n296ww74n4g 10 14 adsorption adsorption NOUN n296ww74n4g 10 15 energies energy NOUN n296ww74n4g 10 16 show show VERB n296ww74n4g 10 17 less less ADJ n296ww74n4g 10 18 variability variability NOUN n296ww74n4g 10 19 . . PUNCT n296ww74n4g 11 1 we we PRON n296ww74n4g 11 2 constructed construct VERB n296ww74n4g 11 3 relative relative ADJ n296ww74n4g 11 4 energy energy NOUN n296ww74n4g 11 5 diagrams diagram NOUN n296ww74n4g 11 6 combining combine VERB n296ww74n4g 11 7 these these DET n296ww74n4g 11 8 results result NOUN n296ww74n4g 11 9 with with ADP n296ww74n4g 11 10 both both DET n296ww74n4g 11 11 langmuir langmuir PROPN n296ww74n4g 11 12 hinshelwood hinshelwood PROPN n296ww74n4g 11 13 ( ( PUNCT n296ww74n4g 11 14 lh lh INTJ n296ww74n4g 11 15 , , PUNCT n296ww74n4g 11 16 competitive competitive ADJ n296ww74n4g 11 17 surface surface NOUN n296ww74n4g 11 18 adsorption adsorption NOUN n296ww74n4g 11 19 ) ) PUNCT n296ww74n4g 11 20 and and CCONJ n296ww74n4g 11 21 mars mars PROPN n296ww74n4g 11 22 van van PROPN n296ww74n4g 11 23 krevelen krevelen PROPN n296ww74n4g 11 24 ( ( PUNCT n296ww74n4g 11 25 mvk mvk PROPN n296ww74n4g 11 26 , , PUNCT n296ww74n4g 11 27 vacancy vacancy NOUN n296ww74n4g 11 28 - - PUNCT n296ww74n4g 11 29 mediated mediate VERB n296ww74n4g 11 30 ) ) PUNCT n296ww74n4g 11 31 reaction reaction NOUN n296ww74n4g 11 32 mechanisms mechanism NOUN n296ww74n4g 11 33 . . PUNCT n296ww74n4g 12 1 these these DET n296ww74n4g 12 2 models model NOUN n296ww74n4g 12 3 show show VERB n296ww74n4g 12 4 that that SCONJ n296ww74n4g 12 5 the the DET n296ww74n4g 12 6 reaction reaction NOUN n296ww74n4g 12 7 mechanism mechanism NOUN n296ww74n4g 12 8 is be AUX n296ww74n4g 12 9 sensitive sensitive ADJ n296ww74n4g 12 10 to to ADP n296ww74n4g 12 11 the the DET n296ww74n4g 12 12 material material NOUN n296ww74n4g 12 13 , , PUNCT n296ww74n4g 12 14 termination termination NOUN n296ww74n4g 12 15 , , PUNCT n296ww74n4g 12 16 and and CCONJ n296ww74n4g 12 17 temperature temperature NOUN n296ww74n4g 12 18 . . PUNCT n296ww74n4g 13 1 surface surface NOUN n296ww74n4g 13 2 pathway pathway NOUN n296ww74n4g 13 3 microkinetic microkinetic ADJ n296ww74n4g 13 4 models model NOUN n296ww74n4g 13 5 predict predict VERB n296ww74n4g 13 6 rates rate NOUN n296ww74n4g 13 7 of of ADP n296ww74n4g 13 8 the the DET n296ww74n4g 13 9 lh lh INTJ n296ww74n4g 13 10 mo2>lao mo2>lao NOUN n296ww74n4g 13 11 pathway pathway NOUN n296ww74n4g 13 12 with with ADP n296ww74n4g 13 13 mn mn PROPN n296ww74n4g 13 14 having have VERB n296ww74n4g 13 15 the the DET n296ww74n4g 13 16 highest high ADJ n296ww74n4g 13 17 tof tof NOUN n296ww74n4g 13 18 . . PUNCT n296ww74n4g 14 1 finally finally ADV n296ww74n4g 14 2 , , PUNCT n296ww74n4g 14 3 sulfur sulfur NOUN n296ww74n4g 14 4 deactivation deactivation NOUN n296ww74n4g 14 5 is be AUX n296ww74n4g 14 6 a a DET n296ww74n4g 14 7 practical practical ADJ n296ww74n4g 14 8 challenge challenge NOUN n296ww74n4g 14 9 for for ADP n296ww74n4g 14 10 the the DET n296ww74n4g 14 11 application application NOUN n296ww74n4g 14 12 of of ADP n296ww74n4g 14 13 perovskites perovskite NOUN n296ww74n4g 14 14 as as ADP n296ww74n4g 14 15 no no DET n296ww74n4g 14 16 oxidation oxidation NOUN n296ww74n4g 14 17 catalysts catalyst NOUN n296ww74n4g 14 18 . . PUNCT n296ww74n4g 15 1 however however ADV n296ww74n4g 15 2 , , PUNCT n296ww74n4g 15 3 recent recent ADJ n296ww74n4g 15 4 reports report NOUN n296ww74n4g 15 5 have have AUX n296ww74n4g 15 6 determined determine VERB n296ww74n4g 15 7 that that SCONJ n296ww74n4g 15 8 depositing deposit VERB n296ww74n4g 15 9 pd pd PROPN n296ww74n4g 15 10 onto onto ADP n296ww74n4g 15 11 lacoo3 lacoo3 PROPN n296ww74n4g 15 12 can can AUX n296ww74n4g 15 13 increase increase VERB n296ww74n4g 15 14 the the DET n296ww74n4g 15 15 sulfur sulfur NOUN n296ww74n4g 15 16 tolerance tolerance NOUN n296ww74n4g 15 17 . . PUNCT n296ww74n4g 16 1 we we PRON n296ww74n4g 16 2 explore explore VERB n296ww74n4g 16 3 the the DET n296ww74n4g 16 4 binding binding NOUN n296ww74n4g 16 5 of of ADP n296ww74n4g 16 6 sox sox X n296ww74n4g 16 7 on on ADP n296ww74n4g 16 8 lacoo3 lacoo3 PROPN n296ww74n4g 16 9 and and CCONJ n296ww74n4g 16 10 various various ADJ n296ww74n4g 16 11 models model NOUN n296ww74n4g 16 12 of of ADP n296ww74n4g 16 13 pd pd PROPN n296ww74n4g 16 14 deposition deposition PROPN n296ww74n4g 16 15 . . PUNCT n296ww74n4g 17 1 the the DET n296ww74n4g 17 2 increasing increase VERB n296ww74n4g 17 3 pd pd PROPN n296ww74n4g 17 4 content content NOUN n296ww74n4g 17 5 in in ADP n296ww74n4g 17 6 general general ADJ n296ww74n4g 17 7 decreases decrease VERB n296ww74n4g 17 8 the the DET n296ww74n4g 17 9 binding binding NOUN n296ww74n4g 17 10 of of ADP n296ww74n4g 17 11 sulfur sulfur NOUN n296ww74n4g 17 12 to to ADP n296ww74n4g 17 13 the the DET n296ww74n4g 17 14 lao lao NOUN n296ww74n4g 17 15 termination termination NOUN n296ww74n4g 17 16 . . PUNCT n296ww74n4g 18 1 we we PRON n296ww74n4g 18 2 also also ADV n296ww74n4g 18 3 use use VERB n296ww74n4g 18 4 thermodynamic thermodynamic ADJ n296ww74n4g 18 5 modeling modeling NOUN n296ww74n4g 18 6 to to PART n296ww74n4g 18 7 explore explore VERB n296ww74n4g 18 8 the the DET n296ww74n4g 18 9 phase phase NOUN n296ww74n4g 18 10 degradation degradation NOUN n296ww74n4g 18 11 in in ADP n296ww74n4g 18 12 of of ADP n296ww74n4g 18 13 lacoo3 lacoo3 NOUN n296ww74n4g 18 14 in in ADP n296ww74n4g 18 15 the the DET n296ww74n4g 18 16 presence presence NOUN n296ww74n4g 18 17 of of ADP n296ww74n4g 18 18 sulfur sulfur NOUN n296ww74n4g 18 19 . . PUNCT n296ww74n4g 19 1 the the DET n296ww74n4g 19 2 la2o2so4 la2o2so4 NOUN n296ww74n4g 19 3 is be AUX n296ww74n4g 19 4 the the DET n296ww74n4g 19 5 lowest low ADJ n296ww74n4g 19 6 energy energy NOUN n296ww74n4g 19 7 phase phase NOUN n296ww74n4g 19 8 of of ADP n296ww74n4g 19 9 la2o3 la2o3 PROPN n296ww74n4g 19 10 , , PUNCT n296ww74n4g 19 11 coo2 coo2 NOUN n296ww74n4g 19 12 , , PUNCT n296ww74n4g 19 13 co2o3 co2o3 SPACE n296ww74n4g 19 14 , , PUNCT n296ww74n4g 19 15 and and CCONJ n296ww74n4g 19 16 lacoo3 lacoo3 PROPN n296ww74n4g 19 17 . . PUNCT