id sid tid token lemma pos n009w092750 1 1 the the DET n009w092750 1 2 unusual unusual ADJ n009w092750 1 3 and and CCONJ n009w092750 1 4 useful useful ADJ n009w092750 1 5 properties property NOUN n009w092750 1 6 of of ADP n009w092750 1 7 nanostructured nanostructure VERB n009w092750 1 8 materials material NOUN n009w092750 1 9 enable enable VERB n009w092750 1 10 exciting exciting ADJ n009w092750 1 11 applications application NOUN n009w092750 1 12 such such ADJ n009w092750 1 13 as as ADP n009w092750 1 14 color color NOUN n009w092750 1 15 - - PUNCT n009w092750 1 16 changing change VERB n009w092750 1 17 or or CCONJ n009w092750 1 18 adaptive adaptive ADJ n009w092750 1 19 materials material NOUN n009w092750 1 20 , , PUNCT n009w092750 1 21 ultra ultra ADJ n009w092750 1 22 - - ADJ n009w092750 1 23 sensitive sensitive ADJ n009w092750 1 24 chemical chemical NOUN n009w092750 1 25 measurements measurement NOUN n009w092750 1 26 for for ADP n009w092750 1 27 earlier early ADJ n009w092750 1 28 detection detection NOUN n009w092750 1 29 of of ADP n009w092750 1 30 disease disease NOUN n009w092750 1 31 , , PUNCT n009w092750 1 32 and and CCONJ n009w092750 1 33 increased increase VERB n009w092750 1 34 understanding understanding NOUN n009w092750 1 35 of of ADP n009w092750 1 36 chemical chemical ADJ n009w092750 1 37 behavior behavior NOUN n009w092750 1 38 . . PUNCT n009w092750 2 1 laboratory laboratory NOUN n009w092750 2 2 - - PUNCT n009w092750 2 3 scale scale NOUN n009w092750 2 4 experiments experiment NOUN n009w092750 2 5 with with ADP n009w092750 2 6 nanomaterials nanomaterial NOUN n009w092750 2 7 suggest suggest VERB n009w092750 2 8 numerous numerous ADJ n009w092750 2 9 applications application NOUN n009w092750 2 10 , , PUNCT n009w092750 2 11 but but CCONJ n009w092750 2 12 fabrication fabrication NOUN n009w092750 2 13 difficulty difficulty NOUN n009w092750 2 14 remains remain VERB n009w092750 2 15 among among ADP n009w092750 2 16 the the DET n009w092750 2 17 largest large ADJ n009w092750 2 18 barriers barrier NOUN n009w092750 2 19 preventing prevent VERB n009w092750 2 20 widespread widespread ADJ n009w092750 2 21 implementation implementation NOUN n009w092750 2 22 . . PUNCT n009w092750 3 1 electrochemical electrochemical ADJ n009w092750 3 2 fabrication fabrication NOUN n009w092750 3 3 strategies strategy NOUN n009w092750 3 4 offer offer VERB n009w092750 3 5 a a DET n009w092750 3 6 means means NOUN n009w092750 3 7 of of ADP n009w092750 3 8 addressing address VERB n009w092750 3 9 these these DET n009w092750 3 10 problems problem NOUN n009w092750 3 11 by by ADP n009w092750 3 12 manipulating manipulate VERB n009w092750 3 13 nanostructures nanostructure NOUN n009w092750 3 14 after after ADP n009w092750 3 15 reaching reach VERB n009w092750 3 16 the the DET n009w092750 3 17 limits limit NOUN n009w092750 3 18 of of ADP n009w092750 3 19 traditional traditional ADJ n009w092750 3 20 fabrication fabrication NOUN n009w092750 3 21 . . PUNCT n009w092750 4 1 two two NUM n009w092750 4 2 nanostructures nanostructure NOUN n009w092750 4 3 , , PUNCT n009w092750 4 4 nanoholes nanohole NOUN n009w092750 4 5 and and CCONJ n009w092750 4 6 nanoscale nanoscale NOUN n009w092750 4 7 conductive conductive ADJ n009w092750 4 8 filaments filament NOUN n009w092750 4 9 , , PUNCT n009w092750 4 10 were be AUX n009w092750 4 11 used use VERB n009w092750 4 12 to to PART n009w092750 4 13 study study VERB n009w092750 4 14 simultaneous simultaneous ADJ n009w092750 4 15 optical optical ADJ n009w092750 4 16 and and CCONJ n009w092750 4 17 electrochemical electrochemical ADJ n009w092750 4 18 behavior behavior NOUN n009w092750 4 19 in in ADP n009w092750 4 20 methods method NOUN n009w092750 4 21 described describe VERB n009w092750 4 22 here.disassociated here.disassociate VERB n009w092750 4 23 nanoapertures nanoaperture NOUN n009w092750 4 24 block block NOUN n009w092750 4 25 transmission transmission NOUN n009w092750 4 26 of of ADP n009w092750 4 27 propagating propagate VERB n009w092750 4 28 light light NOUN n009w092750 4 29 , , PUNCT n009w092750 4 30 acting act VERB n009w092750 4 31 as as ADP n009w092750 4 32 zero zero NUM n009w092750 4 33 - - PUNCT n009w092750 4 34 mode mode NOUN n009w092750 4 35 waveguides waveguide NOUN n009w092750 4 36 ( ( PUNCT n009w092750 4 37 zmws zmws NOUN n009w092750 4 38 ) ) PUNCT n009w092750 4 39 . . PUNCT n009w092750 5 1 electrochemical electrochemical ADJ n009w092750 5 2 zmws zmws PROPN n009w092750 5 3 ( ( PUNCT n009w092750 5 4 e e NOUN n009w092750 5 5 - - NOUN n009w092750 5 6 zmws zmws VERB n009w092750 5 7 ) ) PUNCT n009w092750 5 8 enable enable VERB n009w092750 5 9 the the DET n009w092750 5 10 observation observation NOUN n009w092750 5 11 of of ADP n009w092750 5 12 spectro spectro ADJ n009w092750 5 13 - - PUNCT n009w092750 5 14 electrochemical electrochemical ADJ n009w092750 5 15 behavior behavior NOUN n009w092750 5 16 at at ADP n009w092750 5 17 the the DET n009w092750 5 18 single single ADJ n009w092750 5 19 molecule molecule NOUN n009w092750 5 20 level level NOUN n009w092750 5 21 , , PUNCT n009w092750 5 22 which which PRON n009w092750 5 23 was be AUX n009w092750 5 24 exploited exploit VERB n009w092750 5 25 to to PART n009w092750 5 26 implement implement VERB n009w092750 5 27 windowed windowed ADJ n009w092750 5 28 cross cross NOUN n009w092750 5 29 - - NOUN n009w092750 5 30 correlation correlation NOUN n009w092750 5 31 between between ADP n009w092750 5 32 electron electron NOUN n009w092750 5 33 transfer transfer NOUN n009w092750 5 34 and and CCONJ n009w092750 5 35 optical optical ADJ n009w092750 5 36 fluorescence fluorescence ADJ n009w092750 5 37 transients transient NOUN n009w092750 5 38 , , PUNCT n009w092750 5 39 revealing reveal VERB n009w092750 5 40 signatures signature NOUN n009w092750 5 41 of of ADP n009w092750 5 42 single single ADJ n009w092750 5 43 molecule molecule NOUN n009w092750 5 44 population population NOUN n009w092750 5 45 fluctuations fluctuation NOUN n009w092750 5 46 on on ADP n009w092750 5 47 sparsely sparsely ADV n009w092750 5 48 populated populated ADJ n009w092750 5 49 nanopore nanopore PROPN n009w092750 5 50 electrode electrode NOUN n009w092750 5 51 arrays array NOUN n009w092750 5 52 . . PUNCT n009w092750 6 1 these these DET n009w092750 6 2 measurements measurement NOUN n009w092750 6 3 constitute constitute VERB n009w092750 6 4 true true ADJ n009w092750 6 5 unamplified unamplified ADJ n009w092750 6 6 studies study NOUN n009w092750 6 7 into into ADP n009w092750 6 8 single single ADJ n009w092750 6 9 molecule molecule NOUN n009w092750 6 10 electron electron NOUN n009w092750 6 11 transfer transfer NOUN n009w092750 6 12 events event NOUN n009w092750 6 13 and and CCONJ n009w092750 6 14 thus thus ADV n009w092750 6 15 may may AUX n009w092750 6 16 direct direct VERB n009w092750 6 17 future future ADJ n009w092750 6 18 study study NOUN n009w092750 6 19 of of ADP n009w092750 6 20 fundamental fundamental ADJ n009w092750 6 21 electrochemical electrochemical ADJ n009w092750 6 22 reaction reaction NOUN n009w092750 6 23 events.closely events.closely ADV n009w092750 6 24 - - PUNCT n009w092750 6 25 spaced space VERB n009w092750 6 26 nanoaperatures nanoaperature NOUN n009w092750 6 27 behave behave VERB n009w092750 6 28 not not PART n009w092750 6 29 as as ADP n009w092750 6 30 individual individual ADJ n009w092750 6 31 e e NOUN n009w092750 6 32 - - NOUN n009w092750 6 33 zmws zmws VERB n009w092750 6 34 but but CCONJ n009w092750 6 35 in in ADP n009w092750 6 36 aggregate aggregate NOUN n009w092750 6 37 as as ADP n009w092750 6 38 a a DET n009w092750 6 39 plasmonic plasmonic ADJ n009w092750 6 40 metamaterial metamaterial NOUN n009w092750 6 41 , , PUNCT n009w092750 6 42 selectively selectively ADV n009w092750 6 43 transmitting transmit VERB n009w092750 6 44 light light NOUN n009w092750 6 45 as as ADP n009w092750 6 46 a a DET n009w092750 6 47 function function NOUN n009w092750 6 48 of of ADP n009w092750 6 49 pore pore NOUN n009w092750 6 50 spacing spacing NOUN n009w092750 6 51 and and CCONJ n009w092750 6 52 geometry geometry NOUN n009w092750 6 53 . . PUNCT n009w092750 7 1 electrodeposition electrodeposition NOUN n009w092750 7 2 of of ADP n009w092750 7 3 a a DET n009w092750 7 4 dissimilar dissimilar ADJ n009w092750 7 5 metal metal NOUN n009w092750 7 6 onto onto ADP n009w092750 7 7 the the DET n009w092750 7 8 conductive conductive ADJ n009w092750 7 9 nanohole nanohole NOUN n009w092750 7 10 film film NOUN n009w092750 7 11 , , PUNCT n009w092750 7 12 acting act VERB n009w092750 7 13 an an DET n009w092750 7 14 electrode electrode NOUN n009w092750 7 15 , , PUNCT n009w092750 7 16 creates create VERB n009w092750 7 17 a a DET n009w092750 7 18 metamaterial metamaterial NOUN n009w092750 7 19 with with ADP n009w092750 7 20 a a DET n009w092750 7 21 tunable tunable ADJ n009w092750 7 22 optical optical ADJ n009w092750 7 23 response response NOUN n009w092750 7 24 proportional proportional ADJ n009w092750 7 25 to to PART n009w092750 7 26 charge charge VERB n009w092750 7 27 transfer transfer NOUN n009w092750 7 28 by by ADP n009w092750 7 29 decreasing decrease VERB n009w092750 7 30 hole hole NOUN n009w092750 7 31 size size NOUN n009w092750 7 32 . . PUNCT n009w092750 8 1 used use VERB n009w092750 8 2 as as ADP n009w092750 8 3 a a DET n009w092750 8 4 reporter reporter NOUN n009w092750 8 5 in in ADP n009w092750 8 6 a a DET n009w092750 8 7 closed closed ADJ n009w092750 8 8 - - PUNCT n009w092750 8 9 bipolar bipolar ADJ n009w092750 8 10 electrode electrode ADJ n009w092750 8 11 configuration configuration NOUN n009w092750 8 12 , , PUNCT n009w092750 8 13 detection detection NOUN n009w092750 8 14 of of ADP n009w092750 8 15 analyte analyte NOUN n009w092750 8 16 in in ADP n009w092750 8 17 a a DET n009w092750 8 18 separate separate ADJ n009w092750 8 19 electrochemically electrochemically ADV n009w092750 8 20 - - PUNCT n009w092750 8 21 coupled couple VERB n009w092750 8 22 cell cell NOUN n009w092750 8 23 was be AUX n009w092750 8 24 demonstrated demonstrate VERB n009w092750 8 25 with with ADP n009w092750 8 26 the the DET n009w092750 8 27 metamaterial metamaterial ADJ n009w092750 8 28 acting acting NOUN n009w092750 8 29 as as ADP n009w092750 8 30 an an DET n009w092750 8 31 optical optical ADJ n009w092750 8 32 readout readout NOUN n009w092750 8 33 of of ADP n009w092750 8 34 charge charge NOUN n009w092750 8 35 transfer transfer NOUN n009w092750 8 36 , , PUNCT n009w092750 8 37 a a DET n009w092750 8 38 capability capability NOUN n009w092750 8 39 which which PRON n009w092750 8 40 may may AUX n009w092750 8 41 enhance enhance VERB n009w092750 8 42 future future ADJ n009w092750 8 43 point point NOUN n009w092750 8 44 - - PUNCT n009w092750 8 45 of of ADP n009w092750 8 46 - - PUNCT n009w092750 8 47 care care NOUN n009w092750 8 48 medical medical ADJ n009w092750 8 49 diagnostics diagnostic NOUN n009w092750 8 50 . . PUNCT n009w092750 9 1 nanoscale nanoscale PROPN n009w092750 9 2 conductive conductive ADJ n009w092750 9 3 filaments filament NOUN n009w092750 9 4 may may AUX n009w092750 9 5 be be AUX n009w092750 9 6 formed form VERB n009w092750 9 7 and and CCONJ n009w092750 9 8 dissolved dissolve VERB n009w092750 9 9 at at ADP n009w092750 9 10 specified specify VERB n009w092750 9 11 spatial spatial ADJ n009w092750 9 12 coordinates coordinate NOUN n009w092750 9 13 in in ADP n009w092750 9 14 an an DET n009w092750 9 15 ion ion NOUN n009w092750 9 16 - - PUNCT n009w092750 9 17 conducting conduct VERB n009w092750 9 18 solid solid ADJ n009w092750 9 19 polymer polymer NOUN n009w092750 9 20 electrolyte electrolyte NOUN n009w092750 9 21 using use VERB n009w092750 9 22 a a DET n009w092750 9 23 conductive conductive ADJ n009w092750 9 24 atomic atomic ADJ n009w092750 9 25 - - PUNCT n009w092750 9 26 force force NOUN n009w092750 9 27 microscope microscope NOUN n009w092750 9 28 ( ( PUNCT n009w092750 9 29 c c NOUN n009w092750 9 30 - - PUNCT n009w092750 9 31 afm afm X n009w092750 9 32 ) ) PUNCT n009w092750 9 33 . . PUNCT n009w092750 10 1 this this DET n009w092750 10 2 c c PROPN n009w092750 10 3 - - PUNCT n009w092750 10 4 afm afm NOUN n009w092750 10 5 method method NOUN n009w092750 10 6 was be AUX n009w092750 10 7 employed employ VERB n009w092750 10 8 to to PART n009w092750 10 9 gather gather VERB n009w092750 10 10 statistics statistic NOUN n009w092750 10 11 of of ADP n009w092750 10 12 filament filament NOUN n009w092750 10 13 formation formation NOUN n009w092750 10 14 and and CCONJ n009w092750 10 15 dissolution dissolution NOUN n009w092750 10 16 times time NOUN n009w092750 10 17 , , PUNCT n009w092750 10 18 granting grant VERB n009w092750 10 19 insight insight NOUN n009w092750 10 20 into into ADP n009w092750 10 21 the the DET n009w092750 10 22 kinetics kinetic NOUN n009w092750 10 23 of of ADP n009w092750 10 24 ion ion NOUN n009w092750 10 25 transport transport NOUN n009w092750 10 26 within within ADP n009w092750 10 27 the the DET n009w092750 10 28 electrolyte electrolyte NOUN n009w092750 10 29 . . PUNCT n009w092750 11 1 experimentation experimentation NOUN n009w092750 11 2 and and CCONJ n009w092750 11 3 simulation simulation NOUN n009w092750 11 4 showed show VERB n009w092750 11 5 that that SCONJ n009w092750 11 6 nanoparticles nanoparticle NOUN n009w092750 11 7 , , PUNCT n009w092750 11 8 otherwise otherwise ADV n009w092750 11 9 electrically electrically ADV n009w092750 11 10 inaccessible inaccessible ADJ n009w092750 11 11 within within ADP n009w092750 11 12 the the DET n009w092750 11 13 electrolyte electrolyte NOUN n009w092750 11 14 , , PUNCT n009w092750 11 15 act act VERB n009w092750 11 16 as as ADP n009w092750 11 17 bipolar bipolar ADJ n009w092750 11 18 electrodes electrode NOUN n009w092750 11 19 and and CCONJ n009w092750 11 20 influence influence NOUN n009w092750 11 21 filament filament NOUN n009w092750 11 22 behavior behavior NOUN n009w092750 11 23 within within ADP n009w092750 11 24 a a DET n009w092750 11 25 large large ADJ n009w092750 11 26 area area NOUN n009w092750 11 27 of of ADP n009w092750 11 28 the the DET n009w092750 11 29 electrolyte electrolyte NOUN n009w092750 11 30 . . PUNCT n009w092750 12 1 fabrication fabrication NOUN n009w092750 12 2 of of ADP n009w092750 12 3 self self NOUN n009w092750 12 4 - - PUNCT n009w092750 12 5 assembled assemble VERB n009w092750 12 6 nanoparticle nanoparticle NOUN n009w092750 12 7 stacks stack NOUN n009w092750 12 8 was be AUX n009w092750 12 9 demonstrated demonstrate VERB n009w092750 12 10 by by ADP n009w092750 12 11 a a DET n009w092750 12 12 novel novel ADJ n009w092750 12 13 nanopore nanopore NOUN n009w092750 12 14 templating templating NOUN n009w092750 12 15 method method NOUN n009w092750 12 16 and and CCONJ n009w092750 12 17 used use VERB n009w092750 12 18 with with ADP n009w092750 12 19 an an DET n009w092750 12 20 auto auto NOUN n009w092750 12 21 - - PUNCT n009w092750 12 22 aligned align VERB n009w092750 12 23 c c PROPN n009w092750 12 24 - - PUNCT n009w092750 12 25 afm afm NOUN n009w092750 12 26 program program NOUN n009w092750 12 27 to to PART n009w092750 12 28 form form VERB n009w092750 12 29 filaments filament NOUN n009w092750 12 30 through through ADP n009w092750 12 31 stacks stack NOUN n009w092750 12 32 of of ADP n009w092750 12 33 nanoparticles nanoparticle NOUN n009w092750 12 34 . . PUNCT n009w092750 13 1 unexpected unexpected ADJ n009w092750 13 2 behavior behavior NOUN n009w092750 13 3 in in ADP n009w092750 13 4 formation formation NOUN n009w092750 13 5 / / SYM n009w092750 13 6 dissolution dissolution ADJ n009w092750 13 7 time time NOUN n009w092750 13 8 as as ADV n009w092750 13 9 well well ADV n009w092750 13 10 as as ADP n009w092750 13 11 filament filament NOUN n009w092750 13 12 morphology morphology NOUN n009w092750 13 13 suggests suggest VERB n009w092750 13 14 exceptionally exceptionally ADV n009w092750 13 15 altered alter VERB n009w092750 13 16 ion ion NOUN n009w092750 13 17 transport transport NOUN n009w092750 13 18 behavior behavior NOUN n009w092750 13 19 in in ADP n009w092750 13 20 confined confined ADJ n009w092750 13 21 electrolytes electrolyte NOUN n009w092750 13 22 . . PUNCT n009w092750 14 1 this this DET n009w092750 14 2 technique technique NOUN n009w092750 14 3 provides provide VERB n009w092750 14 4 valuable valuable ADJ n009w092750 14 5 examination examination NOUN n009w092750 14 6 of of ADP n009w092750 14 7 ionic ionic ADJ n009w092750 14 8 whole whole ADJ n009w092750 14 9 - - PUNCT n009w092750 14 10 system system NOUN n009w092750 14 11 behavior behavior NOUN n009w092750 14 12 , , PUNCT n009w092750 14 13 indicating indicate VERB n009w092750 14 14 avenues avenue NOUN n009w092750 14 15 for for ADP n009w092750 14 16 future future ADJ n009w092750 14 17 research research NOUN n009w092750 14 18 with with ADP n009w092750 14 19 similar similar ADJ n009w092750 14 20 systems system NOUN n009w092750 14 21 such such ADJ n009w092750 14 22 as as ADP n009w092750 14 23 batteries battery NOUN n009w092750 14 24 , , PUNCT n009w092750 14 25 resistive resistive NOUN n009w092750 14 26 memory memory NOUN n009w092750 14 27 , , PUNCT n009w092750 14 28 and and CCONJ n009w092750 14 29 ionic ionic ADJ n009w092750 14 30 membranes.nanoelectrochemistry membranes.nanoelectrochemistry NOUN n009w092750 14 31 thus thus ADV n009w092750 14 32 provides provide VERB n009w092750 14 33 a a DET n009w092750 14 34 valuable valuable ADJ n009w092750 14 35 glimpse glimpse NOUN n009w092750 14 36 into into ADP n009w092750 14 37 the the DET n009w092750 14 38 underlying underlie VERB n009w092750 14 39 principles principle NOUN n009w092750 14 40 and and CCONJ n009w092750 14 41 kinetics kinetic NOUN n009w092750 14 42 that that PRON n009w092750 14 43 govern govern VERB n009w092750 14 44 electrochemical electrochemical ADJ n009w092750 14 45 systems system NOUN n009w092750 14 46 , , PUNCT n009w092750 14 47 as as ADV n009w092750 14 48 well well ADV n009w092750 14 49 as as ADP n009w092750 14 50 promising promising ADJ n009w092750 14 51 capabilities capability NOUN n009w092750 14 52 in in ADP n009w092750 14 53 the the DET n009w092750 14 54 nanofabrication nanofabrication NOUN n009w092750 14 55 of of ADP n009w092750 14 56 optical optical ADJ n009w092750 14 57 metamaterials metamaterial NOUN n009w092750 14 58 and and CCONJ n009w092750 14 59 advanced advanced ADJ n009w092750 14 60 devices device NOUN n009w092750 14 61 . . PUNCT