id	sid	tid	token	lemma	pos
ms35t724v5v	1	1	the	the	DET
ms35t724v5v	1	2	primary	primary	ADJ
ms35t724v5v	1	3	goal	goal	NOUN
ms35t724v5v	1	4	of	of	ADP
ms35t724v5v	1	5	this	this	DET
ms35t724v5v	1	6	research	research	NOUN
ms35t724v5v	1	7	project	project	NOUN
ms35t724v5v	1	8	is	be	AUX
ms35t724v5v	1	9	to	to	PART
ms35t724v5v	1	10	develop	develop	VERB
ms35t724v5v	1	11	methodologies	methodology	NOUN
ms35t724v5v	1	12	for	for	ADP
ms35t724v5v	1	13	further	further	ADJ
ms35t724v5v	1	14	functionalization	functionalization	NOUN
ms35t724v5v	1	15	of	of	ADP
ms35t724v5v	1	16	zintl	zintl	PROPN
ms35t724v5v	1	17	clusters	cluster	NOUN
ms35t724v5v	1	18	in	in	ADP
ms35t724v5v	1	19	order	order	NOUN
ms35t724v5v	1	20	to	to	PART
ms35t724v5v	1	21	attach	attach	VERB
ms35t724v5v	1	22	more	more	ADJ
ms35t724v5v	1	23	than	than	ADP
ms35t724v5v	1	24	two	two	NUM
ms35t724v5v	1	25	substituents	substituent	NOUN
ms35t724v5v	1	26	.	.	PUNCT
ms35t724v5v	2	1	progress	progress	NOUN
ms35t724v5v	2	2	was	be	AUX
ms35t724v5v	2	3	made	make	VERB
ms35t724v5v	2	4	in	in	ADP
ms35t724v5v	2	5	a	a	DET
ms35t724v5v	2	6	step	step	NOUN
ms35t724v5v	2	7	by	by	ADP
ms35t724v5v	2	8	step	step	NOUN
ms35t724v5v	2	9	manner	manner	NOUN
ms35t724v5v	2	10	as	as	SCONJ
ms35t724v5v	2	11	follows	follow	VERB
ms35t724v5v	2	12	:	:	PUNCT
ms35t724v5v	2	13	(	(	PUNCT
ms35t724v5v	2	14	a	a	X
ms35t724v5v	2	15	)	)	PUNCT
ms35t724v5v	2	16	develop	develop	VERB
ms35t724v5v	2	17	methodology	methodology	NOUN
ms35t724v5v	2	18	for	for	ADP
ms35t724v5v	2	19	the	the	DET
ms35t724v5v	2	20	synthesis	synthesis	NOUN
ms35t724v5v	2	21	of	of	ADP
ms35t724v5v	2	22	zintl	zintl	PROPN
ms35t724v5v	2	23	clusters	cluster	NOUN
ms35t724v5v	2	24	functionalized	functionalize	VERB
ms35t724v5v	2	25	with	with	ADP
ms35t724v5v	2	26	more	more	ADJ
ms35t724v5v	2	27	than	than	ADP
ms35t724v5v	2	28	two	two	NUM
ms35t724v5v	2	29	substituents	substituent	NOUN
ms35t724v5v	2	30	,	,	PUNCT
ms35t724v5v	2	31	(	(	PUNCT
ms35t724v5v	2	32	b	b	X
ms35t724v5v	2	33	)	)	PUNCT
ms35t724v5v	2	34	carry	carry	VERB
ms35t724v5v	2	35	out	out	ADP
ms35t724v5v	2	36	subsequent	subsequent	ADJ
ms35t724v5v	2	37	studies	study	NOUN
ms35t724v5v	2	38	for	for	ADP
ms35t724v5v	2	39	the	the	DET
ms35t724v5v	2	40	properties	property	NOUN
ms35t724v5v	2	41	of	of	ADP
ms35t724v5v	2	42	the	the	DET
ms35t724v5v	2	43	functionalized	functionalize	VERB
ms35t724v5v	2	44	clusters	cluster	NOUN
ms35t724v5v	2	45	and	and	CCONJ
ms35t724v5v	2	46	their	their	PRON
ms35t724v5v	2	47	reactivity	reactivity	NOUN
ms35t724v5v	2	48	,	,	PUNCT
ms35t724v5v	2	49	and	and	CCONJ
ms35t724v5v	2	50	(	(	PUNCT
ms35t724v5v	2	51	c	c	X
ms35t724v5v	2	52	)	)	PUNCT
ms35t724v5v	2	53	introduce	introduce	VERB
ms35t724v5v	2	54	more	more	ADJ
ms35t724v5v	2	55	organic	organic	ADJ
ms35t724v5v	2	56	functionalities	functionality	NOUN
ms35t724v5v	2	57	to	to	ADP
ms35t724v5v	2	58	the	the	DET
ms35t724v5v	2	59	cluster	cluster	NOUN
ms35t724v5v	2	60	core	core	NOUN
ms35t724v5v	2	61	.	.	PUNCT
ms35t724v5v	3	1	each	each	PRON
ms35t724v5v	3	2	of	of	ADP
ms35t724v5v	3	3	these	these	DET
ms35t724v5v	3	4	segments	segment	NOUN
ms35t724v5v	3	5	is	be	AUX
ms35t724v5v	3	6	discussed	discuss	VERB
ms35t724v5v	3	7	in	in	ADP
ms35t724v5v	3	8	detail	detail	NOUN
ms35t724v5v	3	9	in	in	ADP
ms35t724v5v	3	10	this	this	DET
ms35t724v5v	3	11	dissertation.after	dissertation.after	NOUN
ms35t724v5v	3	12	introducing	introduce	VERB
ms35t724v5v	3	13	the	the	DET
ms35t724v5v	3	14	background	background	NOUN
ms35t724v5v	3	15	of	of	ADP
ms35t724v5v	3	16	zintl	zintl	NOUN
ms35t724v5v	3	17	ions	ion	NOUN
ms35t724v5v	3	18	and	and	CCONJ
ms35t724v5v	3	19	the	the	DET
ms35t724v5v	3	20	recent	recent	ADJ
ms35t724v5v	3	21	developments	development	NOUN
ms35t724v5v	3	22	on	on	ADP
ms35t724v5v	3	23	the	the	DET
ms35t724v5v	3	24	study	study	NOUN
ms35t724v5v	3	25	of	of	ADP
ms35t724v5v	3	26	nine	nine	NUM
ms35t724v5v	3	27	–	–	PUNCT
ms35t724v5v	3	28	atom	atom	NOUN
ms35t724v5v	3	29	germanium	germanium	NOUN
ms35t724v5v	3	30	clusters	cluster	NOUN
ms35t724v5v	3	31	(	(	PUNCT
ms35t724v5v	3	32	chapter	chapter	NOUN
ms35t724v5v	3	33	1	1	NUM
ms35t724v5v	3	34	)	)	PUNCT
ms35t724v5v	3	35	,	,	PUNCT
ms35t724v5v	3	36	the	the	DET
ms35t724v5v	3	37	rational	rational	ADJ
ms35t724v5v	3	38	synthesis	synthesis	NOUN
ms35t724v5v	3	39	of	of	ADP
ms35t724v5v	3	40	tri	tri	ADJ
ms35t724v5v	3	41	–	–	ADJ
ms35t724v5v	3	42	silylated	silylated	ADJ
ms35t724v5v	3	43	ge9	ge9	NOUN
ms35t724v5v	3	44	clusters	cluster	NOUN
ms35t724v5v	3	45	is	be	AUX
ms35t724v5v	3	46	discussed	discuss	VERB
ms35t724v5v	3	47	(	(	PUNCT
ms35t724v5v	3	48	chapter	chapter	NOUN
ms35t724v5v	3	49	2	2	NUM
ms35t724v5v	3	50	)	)	PUNCT
ms35t724v5v	3	51	.	.	PUNCT
ms35t724v5v	4	1	this	this	DET
ms35t724v5v	4	2	approach	approach	NOUN
ms35t724v5v	4	3	allows	allow	VERB
ms35t724v5v	4	4	for	for	SCONJ
ms35t724v5v	4	5	ge9	ge9	NOUN
ms35t724v5v	4	6	clusters	cluster	NOUN
ms35t724v5v	4	7	with	with	ADP
ms35t724v5v	4	8	more	more	ADJ
ms35t724v5v	4	9	than	than	ADP
ms35t724v5v	4	10	two	two	NUM
ms35t724v5v	4	11	substituents	substituent	NOUN
ms35t724v5v	4	12	to	to	PART
ms35t724v5v	4	13	be	be	AUX
ms35t724v5v	4	14	synthesized	synthesize	VERB
ms35t724v5v	4	15	by	by	ADP
ms35t724v5v	4	16	reacting	react	VERB
ms35t724v5v	4	17	"	"	PUNCT
ms35t724v5v	4	18	hypersilyl	hypersilyl	ADJ
ms35t724v5v	4	19	"	"	PUNCT
ms35t724v5v	4	20	chloride	chloride	PROPN
ms35t724v5v	4	21	(	(	PUNCT
ms35t724v5v	4	22	me3si)3sicl	me3si)3sicl	PROPN
ms35t724v5v	4	23	with	with	ADP
ms35t724v5v	4	24	acetonitrile	acetonitrile	ADJ
ms35t724v5v	4	25	suspension	suspension	NOUN
ms35t724v5v	4	26	of	of	ADP
ms35t724v5v	4	27	the	the	DET
ms35t724v5v	4	28	intermetallic	intermetallic	ADJ
ms35t724v5v	4	29	precursor	precursor	NOUN
ms35t724v5v	4	30	k4ge9	k4ge9	NOUN
ms35t724v5v	4	31	to	to	PART
ms35t724v5v	4	32	form	form	VERB
ms35t724v5v	4	33	[	[	PUNCT
ms35t724v5v	4	34	ge9(si(sime3)3)3]–.	ge9(si(sime3)3)3]–.	PROPN
ms35t724v5v	4	35	our	our	PRON
ms35t724v5v	4	36	investigations	investigation	NOUN
ms35t724v5v	4	37	show	show	VERB
ms35t724v5v	4	38	this	this	DET
ms35t724v5v	4	39	route	route	NOUN
ms35t724v5v	4	40	to	to	PART
ms35t724v5v	4	41	be	be	AUX
ms35t724v5v	4	42	general	general	ADJ
ms35t724v5v	4	43	and	and	CCONJ
ms35t724v5v	4	44	applicable	applicable	ADJ
ms35t724v5v	4	45	to	to	ADP
ms35t724v5v	4	46	a	a	DET
ms35t724v5v	4	47	variety	variety	NOUN
ms35t724v5v	4	48	of	of	ADP
ms35t724v5v	4	49	r3sicl	r3sicl	NOUN
ms35t724v5v	4	50	,	,	PUNCT
ms35t724v5v	4	51	with	with	ADP
ms35t724v5v	4	52	r	r	NOUN
ms35t724v5v	4	53	=	=	X
ms35t724v5v	4	54	et	et	PROPN
ms35t724v5v	4	55	,	,	PUNCT
ms35t724v5v	4	56	ipr	ipr	PROPN
ms35t724v5v	4	57	,	,	PUNCT
ms35t724v5v	4	58	nbu	nbu	PROPN
ms35t724v5v	4	59	and	and	CCONJ
ms35t724v5v	4	60	ph	ph	PROPN
ms35t724v5v	4	61	,	,	PUNCT
ms35t724v5v	4	62	etc	etc	X
ms35t724v5v	4	63	.	.	X
ms35t724v5v	5	1	following	follow	VERB
ms35t724v5v	5	2	the	the	DET
ms35t724v5v	5	3	rational	rational	ADJ
ms35t724v5v	5	4	synthesis	synthesis	NOUN
ms35t724v5v	5	5	of	of	ADP
ms35t724v5v	5	6	[	[	X
ms35t724v5v	5	7	ge9(si(sime3)3)3	ge9(si(sime3)3)3	X
ms35t724v5v	5	8	]	]	X
ms35t724v5v	5	9	–	–	PUNCT
ms35t724v5v	5	10	,	,	PUNCT
ms35t724v5v	5	11	the	the	DET
ms35t724v5v	5	12	preparation	preparation	NOUN
ms35t724v5v	5	13	of	of	ADP
ms35t724v5v	5	14	tetra	tetra	PROPN
ms35t724v5v	5	15	–	–	PUNCT
ms35t724v5v	5	16	substituted	substitute	VERB
ms35t724v5v	5	17	ge9	ge9	NOUN
ms35t724v5v	5	18	clusters	cluster	NOUN
ms35t724v5v	5	19	was	be	AUX
ms35t724v5v	5	20	studied	study	VERB
ms35t724v5v	5	21	next	next	ADV
ms35t724v5v	5	22	,	,	PUNCT
ms35t724v5v	5	23	and	and	CCONJ
ms35t724v5v	5	24	this	this	PRON
ms35t724v5v	5	25	is	be	AUX
ms35t724v5v	5	26	discussed	discuss	VERB
ms35t724v5v	5	27	in	in	ADP
ms35t724v5v	5	28	detail	detail	NOUN
ms35t724v5v	5	29	in	in	ADP
ms35t724v5v	5	30	chapter	chapter	NOUN
ms35t724v5v	5	31	3	3	NUM
ms35t724v5v	5	32	.	.	PUNCT
ms35t724v5v	6	1	reactions	reaction	NOUN
ms35t724v5v	6	2	between	between	ADP
ms35t724v5v	6	3	k[ge9(si(sime3)3)3	k[ge9(si(sime3)3)3	PROPN
ms35t724v5v	6	4	]	]	PUNCT
ms35t724v5v	6	5	and	and	CCONJ
ms35t724v5v	6	6	r3sncl	r3sncl	NOUN
ms35t724v5v	6	7	(	(	PUNCT
ms35t724v5v	6	8	r	r	NOUN
ms35t724v5v	6	9	=	=	X
ms35t724v5v	6	10	me	i	PRON
ms35t724v5v	6	11	,	,	PUNCT
ms35t724v5v	6	12	nbu	nbu	PROPN
ms35t724v5v	6	13	and	and	CCONJ
ms35t724v5v	6	14	ph	ph	PROPN
ms35t724v5v	6	15	)	)	PUNCT
ms35t724v5v	6	16	result	result	NOUN
ms35t724v5v	6	17	in	in	ADP
ms35t724v5v	6	18	the	the	DET
ms35t724v5v	6	19	addition	addition	NOUN
ms35t724v5v	6	20	of	of	ADP
ms35t724v5v	6	21	the	the	DET
ms35t724v5v	6	22	–	–	PUNCT
ms35t724v5v	6	23	snr3	snr3	ADJ
ms35t724v5v	6	24	fragment	fragment	NOUN
ms35t724v5v	6	25	to	to	ADP
ms35t724v5v	6	26	the	the	DET
ms35t724v5v	6	27	tri	tri	NOUN
ms35t724v5v	6	28	–	–	PUNCT
ms35t724v5v	6	29	silylated	silylated	ADJ
ms35t724v5v	6	30	ge9	ge9	NOUN
ms35t724v5v	6	31	clusters	cluster	NOUN
ms35t724v5v	6	32	and	and	CCONJ
ms35t724v5v	6	33	the	the	DET
ms35t724v5v	6	34	formation	formation	NOUN
ms35t724v5v	6	35	of	of	ADP
ms35t724v5v	6	36	neutral	neutral	ADJ
ms35t724v5v	6	37	tetra	tetra	NOUN
ms35t724v5v	6	38	–	–	PUNCT
ms35t724v5v	6	39	substituted	substitute	VERB
ms35t724v5v	6	40	species	specie	NOUN
ms35t724v5v	6	41	[	[	PUNCT
ms35t724v5v	6	42	ge9(si(sime3)3)3(snr3)]0	ge9(si(sime3)3)3(snr3)]0	VERB
ms35t724v5v	6	43	.	.	PUNCT
ms35t724v5v	7	1	dynamic	dynamic	ADJ
ms35t724v5v	7	2	behavior	behavior	NOUN
ms35t724v5v	7	3	of	of	ADP
ms35t724v5v	7	4	the	the	DET
ms35t724v5v	7	5	fourth	fourth	ADJ
ms35t724v5v	7	6	substituent	substituent	NOUN
ms35t724v5v	7	7	was	be	AUX
ms35t724v5v	7	8	observed	observe	VERB
ms35t724v5v	7	9	in	in	ADP
ms35t724v5v	7	10	solution	solution	NOUN
ms35t724v5v	7	11	,	,	PUNCT
ms35t724v5v	7	12	and	and	CCONJ
ms35t724v5v	7	13	this	this	PRON
ms35t724v5v	7	14	is	be	AUX
ms35t724v5v	7	15	interpreted	interpret	VERB
ms35t724v5v	7	16	as	as	ADP
ms35t724v5v	7	17	the	the	DET
ms35t724v5v	7	18	–	–	PUNCT
ms35t724v5v	7	19	snr3	snr3	ADJ
ms35t724v5v	7	20	fragment	fragment	NOUN
ms35t724v5v	7	21	migrating	migrate	VERB
ms35t724v5v	7	22	along	along	ADP
ms35t724v5v	7	23	the	the	DET
ms35t724v5v	7	24	three	three	NUM
ms35t724v5v	7	25	germanium	germanium	NOUN
ms35t724v5v	7	26	atoms	atom	NOUN
ms35t724v5v	7	27	within	within	ADP
ms35t724v5v	7	28	the	the	DET
ms35t724v5v	7	29	triangular	triangular	ADJ
ms35t724v5v	7	30	base.studying	base.studye	VERB
ms35t724v5v	7	31	the	the	DET
ms35t724v5v	7	32	similarity	similarity	NOUN
ms35t724v5v	7	33	in	in	ADP
ms35t724v5v	7	34	the	the	DET
ms35t724v5v	7	35	reactivity	reactivity	NOUN
ms35t724v5v	7	36	of	of	ADP
ms35t724v5v	7	37	functionalized	functionalize	VERB
ms35t724v5v	7	38	ge9	ge9	NOUN
ms35t724v5v	7	39	clusters	cluster	NOUN
ms35t724v5v	7	40	and	and	CCONJ
ms35t724v5v	7	41	the	the	DET
ms35t724v5v	7	42	naked	naked	ADJ
ms35t724v5v	7	43	parent	parent	NOUN
ms35t724v5v	7	44	ge94	ge94	PROPN
ms35t724v5v	7	45	–	–	PUNCT
ms35t724v5v	7	46	anions	anion	NOUN
ms35t724v5v	7	47	has	have	VERB
ms35t724v5v	7	48	both	both	CCONJ
ms35t724v5v	7	49	experimental	experimental	ADJ
ms35t724v5v	7	50	and	and	CCONJ
ms35t724v5v	7	51	theoretical	theoretical	ADJ
ms35t724v5v	7	52	implications	implication	NOUN
ms35t724v5v	7	53	.	.	PUNCT
ms35t724v5v	8	1	the	the	DET
ms35t724v5v	8	2	results	result	NOUN
ms35t724v5v	8	3	presented	present	VERB
ms35t724v5v	8	4	in	in	ADP
ms35t724v5v	8	5	chapter	chapter	NOUN
ms35t724v5v	8	6	4	4	NUM
ms35t724v5v	8	7	demonstrate	demonstrate	VERB
ms35t724v5v	8	8	that	that	SCONJ
ms35t724v5v	8	9	like	like	ADP
ms35t724v5v	8	10	the	the	DET
ms35t724v5v	8	11	naked	naked	ADJ
ms35t724v5v	8	12	cluster	cluster	NOUN
ms35t724v5v	8	13	ge94	ge94	PROPN
ms35t724v5v	8	14	–	–	PUNCT
ms35t724v5v	8	15	,	,	PUNCT
ms35t724v5v	8	16	tl	tl	PROPN
ms35t724v5v	8	17	atom	atom	PROPN
ms35t724v5v	8	18	could	could	AUX
ms35t724v5v	8	19	be	be	AUX
ms35t724v5v	8	20	added	add	VERB
ms35t724v5v	8	21	to	to	ADP
ms35t724v5v	8	22	one	one	NUM
ms35t724v5v	8	23	of	of	ADP
ms35t724v5v	8	24	the	the	DET
ms35t724v5v	8	25	square	square	ADJ
ms35t724v5v	8	26	faces	face	NOUN
ms35t724v5v	8	27	of	of	ADP
ms35t724v5v	8	28	[	[	X
ms35t724v5v	8	29	ge9(si(sime3)3)3	ge9(si(sime3)3)3	X
ms35t724v5v	8	30	]	]	X
ms35t724v5v	8	31	–	–	PUNCT
ms35t724v5v	8	32	to	to	PART
ms35t724v5v	8	33	form	form	VERB
ms35t724v5v	8	34	a	a	DET
ms35t724v5v	8	35	tri	tri	NOUN
ms35t724v5v	8	36	–	–	VERB
ms35t724v5v	8	37	substituted	substitute	VERB
ms35t724v5v	8	38	ten	ten	NUM
ms35t724v5v	8	39	–	–	PUNCT
ms35t724v5v	8	40	atom	atom	NOUN
ms35t724v5v	8	41	closo	closo	NOUN
ms35t724v5v	8	42	–	–	PUNCT
ms35t724v5v	8	43	cluster	cluster	NOUN
ms35t724v5v	8	44	[	[	X
ms35t724v5v	8	45	ge9tl(si(sime3)3)3]0	ge9tl(si(sime3)3)3]0	PROPN
ms35t724v5v	8	46	.	.	PUNCT
ms35t724v5v	9	1	intermolecular	intermolecular	ADJ
ms35t724v5v	9	2	dynamic	dynamic	ADJ
ms35t724v5v	9	3	behavior	behavior	NOUN
ms35t724v5v	9	4	was	be	AUX
ms35t724v5v	9	5	observed	observe	VERB
ms35t724v5v	9	6	and	and	CCONJ
ms35t724v5v	9	7	was	be	AUX
ms35t724v5v	9	8	studied	study	VERB
ms35t724v5v	9	9	by	by	ADP
ms35t724v5v	9	10	nmr	nmr	NOUN
ms35t724v5v	9	11	investigations	investigation	NOUN
ms35t724v5v	9	12	.	.	PUNCT
ms35t724v5v	10	1	it	it	PRON
ms35t724v5v	10	2	can	can	AUX
ms35t724v5v	10	3	be	be	AUX
ms35t724v5v	10	4	rationalized	rationalize	VERB
ms35t724v5v	10	5	by	by	ADP
ms35t724v5v	10	6	a	a	DET
ms35t724v5v	10	7	"	"	PUNCT
ms35t724v5v	10	8	tl+	tl+	NOUN
ms35t724v5v	10	9	dissociation	dissociation	NOUN
ms35t724v5v	10	10	–	–	PUNCT
ms35t724v5v	10	11	association	association	NOUN
ms35t724v5v	10	12	"	"	PUNCT
ms35t724v5v	10	13	mechanism.chapter	mechanism.chapter	NOUN
ms35t724v5v	10	14	5	5	NUM
ms35t724v5v	10	15	describes	describe	VERB
ms35t724v5v	10	16	the	the	DET
ms35t724v5v	10	17	addition	addition	NOUN
ms35t724v5v	10	18	of	of	ADP
ms35t724v5v	10	19	a	a	DET
ms35t724v5v	10	20	variety	variety	NOUN
ms35t724v5v	10	21	of	of	ADP
ms35t724v5v	10	22	alkyl	alkyl	ADJ
ms35t724v5v	10	23	groups	group	NOUN
ms35t724v5v	10	24	to	to	ADP
ms35t724v5v	10	25	the	the	DET
ms35t724v5v	10	26	already	already	ADV
ms35t724v5v	10	27	tri	tri	ADJ
ms35t724v5v	10	28	–	–	VERB
ms35t724v5v	10	29	functionalized	functionalize	VERB
ms35t724v5v	10	30	species	specie	NOUN
ms35t724v5v	10	31	by	by	ADP
ms35t724v5v	10	32	the	the	DET
ms35t724v5v	10	33	reactions	reaction	NOUN
ms35t724v5v	10	34	between	between	ADP
ms35t724v5v	10	35	[	[	X
ms35t724v5v	10	36	ge9(si(sime3)3)3	ge9(si(sime3)3)3	X
ms35t724v5v	10	37	]	]	X
ms35t724v5v	10	38	–	–	PUNCT
ms35t724v5v	10	39	and	and	CCONJ
ms35t724v5v	10	40	r	r	X
ms35t724v5v	10	41	–	–	PUNCT
ms35t724v5v	10	42	x	x	SYM
ms35t724v5v	10	43	undergoing	undergo	VERB
ms35t724v5v	10	44	sn2	sn2	PROPN
ms35t724v5v	10	45	mechanism	mechanism	NOUN
ms35t724v5v	10	46	.	.	PUNCT
ms35t724v5v	11	1	[	[	X
ms35t724v5v	11	2	ge9(si(sime3)3)3et]0	ge9(si(sime3)3)3et]0	NOUN
ms35t724v5v	11	3	was	be	AUX
ms35t724v5v	11	4	crystallized	crystallize	VERB
ms35t724v5v	11	5	and	and	CCONJ
ms35t724v5v	11	6	structurally	structurally	ADV
ms35t724v5v	11	7	characterized	characterize	VERB
ms35t724v5v	11	8	.	.	PUNCT
ms35t724v5v	12	1	an	an	DET
ms35t724v5v	12	2	intramolecular	intramolecular	ADJ
ms35t724v5v	12	3	dynamic	dynamic	ADJ
ms35t724v5v	12	4	behavior	behavior	NOUN
ms35t724v5v	12	5	was	be	AUX
ms35t724v5v	12	6	observed	observe	VERB
ms35t724v5v	12	7	in	in	ADP
ms35t724v5v	12	8	solution	solution	NOUN
ms35t724v5v	12	9	and	and	CCONJ
ms35t724v5v	12	10	theoretical	theoretical	ADJ
ms35t724v5v	12	11	study	study	NOUN
ms35t724v5v	12	12	was	be	AUX
ms35t724v5v	12	13	carried	carry	VERB
ms35t724v5v	12	14	out	out	ADP
ms35t724v5v	12	15	for	for	ADP
ms35t724v5v	12	16	clarifying	clarify	VERB
ms35t724v5v	12	17	its	its	PRON
ms35t724v5v	12	18	pathway.chapter	pathway.chapter	NOUN
ms35t724v5v	12	19	6	6	NUM
ms35t724v5v	12	20	investigates	investigate	VERB
ms35t724v5v	12	21	the	the	DET
ms35t724v5v	12	22	reactivity	reactivity	NOUN
ms35t724v5v	12	23	of	of	ADP
ms35t724v5v	12	24	[	[	X
ms35t724v5v	12	25	ge9(si(sime3)3)3	ge9(si(sime3)3)3	X
ms35t724v5v	12	26	]	]	X
ms35t724v5v	12	27	–	–	PUNCT
ms35t724v5v	12	28	towards	towards	ADP
ms35t724v5v	12	29	transition	transition	NOUN
ms35t724v5v	12	30	metal	metal	NOUN
ms35t724v5v	12	31	complexes	complex	NOUN
ms35t724v5v	12	32	.	.	PUNCT
ms35t724v5v	13	1	it	it	PRON
ms35t724v5v	13	2	turns	turn	VERB
ms35t724v5v	13	3	out	out	ADP
ms35t724v5v	13	4	that	that	SCONJ
ms35t724v5v	13	5	naked	naked	ADJ
ms35t724v5v	13	6	transition	transition	NOUN
ms35t724v5v	13	7	metal	metal	NOUN
ms35t724v5v	13	8	atoms	atom	NOUN
ms35t724v5v	13	9	tend	tend	VERB
ms35t724v5v	13	10	to	to	PART
ms35t724v5v	13	11	interact	interact	VERB
ms35t724v5v	13	12	with	with	ADP
ms35t724v5v	13	13	the	the	DET
ms35t724v5v	13	14	triangular	triangular	ADJ
ms35t724v5v	13	15	prismatic	prismatic	ADJ
ms35t724v5v	13	16	bases	basis	NOUN
ms35t724v5v	13	17	of	of	ADP
ms35t724v5v	13	18	the	the	DET
ms35t724v5v	13	19	tri	tri	PROPN
ms35t724v5v	13	20	–	–	PUNCT
ms35t724v5v	13	21	silylated	silylated	ADJ
ms35t724v5v	13	22	monoanion	monoanion	PROPN
ms35t724v5v	13	23	.	.	PUNCT
ms35t724v5v	14	1	[	[	X
ms35t724v5v	14	2	(	(	PUNCT
ms35t724v5v	14	3	ge9r3)cui(ge9r3)(cuipph3)]0	ge9r3)cui(ge9r3)(cuipph3)]0	PROPN
ms35t724v5v	14	4	and	and	CCONJ
ms35t724v5v	14	5	[	[	X
ms35t724v5v	14	6	(	(	PUNCT
ms35t724v5v	14	7	ge9r3)pd0(ge9r3)]2	ge9r3)pd0(ge9r3)]2	SPACE
ms35t724v5v	14	8	–	–	PUNCT
ms35t724v5v	14	9	(	(	PUNCT
ms35t724v5v	14	10	r	r	NOUN
ms35t724v5v	14	11	=	=	PUNCT
ms35t724v5v	14	12	–	–	PUNCT
ms35t724v5v	14	13	si(sime3)3	si(sime3)3	NOUN
ms35t724v5v	14	14	)	)	PUNCT
ms35t724v5v	14	15	were	be	AUX
ms35t724v5v	14	16	synthesized	synthesize	VERB
ms35t724v5v	14	17	and	and	CCONJ
ms35t724v5v	14	18	structurally	structurally	ADV
ms35t724v5v	14	19	characterized	characterize	VERB
ms35t724v5v	14	20	through	through	ADP
ms35t724v5v	14	21	such	such	ADJ
ms35t724v5v	14	22	investigations.chapter	investigations.chapter	NOUN
ms35t724v5v	14	23	7	7	NUM
ms35t724v5v	14	24	presents	present	VERB
ms35t724v5v	14	25	further	further	ADJ
ms35t724v5v	14	26	studies	study	NOUN
ms35t724v5v	14	27	of	of	ADP
ms35t724v5v	14	28	the	the	DET
ms35t724v5v	14	29	nucleophilic	nucleophilic	ADJ
ms35t724v5v	14	30	reactivity	reactivity	NOUN
ms35t724v5v	14	31	of	of	ADP
ms35t724v5v	14	32	organo	organo	NOUN
ms35t724v5v	14	33	–	–	NOUN
ms35t724v5v	14	34	zintl	zintl	PROPN
ms35t724v5v	14	35	clusters	cluster	NOUN
ms35t724v5v	14	36	.	.	PUNCT
ms35t724v5v	15	1	a	a	DET
ms35t724v5v	15	2	variety	variety	NOUN
ms35t724v5v	15	3	of	of	ADP
ms35t724v5v	15	4	main	main	ADJ
ms35t724v5v	15	5	group	group	NOUN
ms35t724v5v	15	6	and	and	CCONJ
ms35t724v5v	15	7	alkyl	alkyl	NOUN
ms35t724v5v	15	8	halides	halide	NOUN
ms35t724v5v	15	9	are	be	AUX
ms35t724v5v	15	10	shown	show	VERB
ms35t724v5v	15	11	to	to	PART
ms35t724v5v	15	12	react	react	VERB
ms35t724v5v	15	13	with	with	ADP
ms35t724v5v	15	14	organo	organo	NOUN
ms35t724v5v	15	15	–	–	NOUN
ms35t724v5v	15	16	zintl	zintl	NOUN
ms35t724v5v	15	17	clusters	cluster	NOUN
ms35t724v5v	15	18	such	such	ADJ
ms35t724v5v	15	19	as	as	ADP
ms35t724v5v	15	20	[	[	X
ms35t724v5v	15	21	ge9(ch	ge9(ch	SPACE
ms35t724v5v	15	22	=	=	NOUN
ms35t724v5v	15	23	ch	ch	PROPN
ms35t724v5v	15	24	–	–	PUNCT
ms35t724v5v	15	25	ph)2]2	ph)2]2	PROPN
ms35t724v5v	15	26	–	–	PUNCT
ms35t724v5v	15	27	,	,	PUNCT
ms35t724v5v	15	28	[	[	X
ms35t724v5v	15	29	ge9(adm)2]2	ge9(adm)2]2	SPACE
ms35t724v5v	15	30	–	–	PUNCT
ms35t724v5v	15	31	,	,	PUNCT
ms35t724v5v	15	32	[	[	X
ms35t724v5v	15	33	ge9(tbu)]3	ge9(tbu)]3	PROPN
ms35t724v5v	15	34	–	–	PUNCT
ms35t724v5v	15	35	,	,	PUNCT
ms35t724v5v	15	36	etc	etc	X
ms35t724v5v	15	37	.	.	X
ms35t724v5v	16	1	we	we	PRON
ms35t724v5v	16	2	believe	believe	VERB
ms35t724v5v	16	3	this	this	PRON
ms35t724v5v	16	4	can	can	AUX
ms35t724v5v	16	5	be	be	AUX
ms35t724v5v	16	6	developed	develop	VERB
ms35t724v5v	16	7	into	into	ADP
ms35t724v5v	16	8	a	a	DET
ms35t724v5v	16	9	general	general	ADJ
ms35t724v5v	16	10	tool	tool	NOUN
ms35t724v5v	16	11	for	for	ADP
ms35t724v5v	16	12	synthesizing	synthesize	VERB
ms35t724v5v	16	13	fully	fully	ADV
ms35t724v5v	16	14	organically	organically	ADV
ms35t724v5v	16	15	functionalized	functionalize	VERB
ms35t724v5v	16	16	zintl	zintl	PROPN
ms35t724v5v	16	17	clusters	cluster	NOUN
ms35t724v5v	16	18	.	.	PUNCT
ms35t724v5v	17	1	the	the	DET
ms35t724v5v	17	2	dissertation	dissertation	NOUN
ms35t724v5v	17	3	ends	end	VERB
ms35t724v5v	17	4	with	with	ADP
ms35t724v5v	17	5	a	a	DET
ms35t724v5v	17	6	summary	summary	NOUN
ms35t724v5v	17	7	and	and	CCONJ
ms35t724v5v	17	8	a	a	DET
ms35t724v5v	17	9	discussion	discussion	NOUN
ms35t724v5v	17	10	of	of	ADP
ms35t724v5v	17	11	future	future	ADJ
ms35t724v5v	17	12	prospects	prospect	NOUN
ms35t724v5v	17	13	,	,	PUNCT
ms35t724v5v	17	14	primarily	primarily	ADV
ms35t724v5v	17	15	focused	focus	VERB
ms35t724v5v	17	16	on	on	ADP
ms35t724v5v	17	17	the	the	DET
ms35t724v5v	17	18	fields	field	NOUN
ms35t724v5v	17	19	of	of	ADP
ms35t724v5v	17	20	embedding	embed	VERB
ms35t724v5v	17	21	clusters	cluster	NOUN
ms35t724v5v	17	22	with	with	ADP
ms35t724v5v	17	23	useful	useful	ADJ
ms35t724v5v	17	24	functionalities	functionality	NOUN
ms35t724v5v	17	25	and	and	CCONJ
ms35t724v5v	17	26	expanding	expand	VERB
ms35t724v5v	17	27	the	the	DET
ms35t724v5v	17	28	synthetic	synthetic	ADJ
ms35t724v5v	17	29	methodology	methodology	NOUN
ms35t724v5v	17	30	into	into	ADP
ms35t724v5v	17	31	other	other	ADJ
ms35t724v5v	17	32	intermetallic	intermetallic	ADJ
ms35t724v5v	17	33	systems	system	NOUN
ms35t724v5v	17	34	.	.	PUNCT