id sid tid token lemma pos k6439z92h9n 1 1 vibrational vibrational ADJ k6439z92h9n 1 2 spectroscopy spectroscopy NOUN k6439z92h9n 1 3 is be AUX k6439z92h9n 1 4 a a DET k6439z92h9n 1 5 powerful powerful ADJ k6439z92h9n 1 6 technique technique NOUN k6439z92h9n 1 7 for for ADP k6439z92h9n 1 8 interrogating interrogate VERB k6439z92h9n 1 9 the the DET k6439z92h9n 1 10 structure structure NOUN k6439z92h9n 1 11 and and CCONJ k6439z92h9n 1 12 dynamics dynamic NOUN k6439z92h9n 1 13 of of ADP k6439z92h9n 1 14 liquids liquid NOUN k6439z92h9n 1 15 due due ADP k6439z92h9n 1 16 to to ADP k6439z92h9n 1 17 its its PRON k6439z92h9n 1 18 exquisite exquisite ADJ k6439z92h9n 1 19 time time NOUN k6439z92h9n 1 20 and and CCONJ k6439z92h9n 1 21 spatial spatial ADJ k6439z92h9n 1 22 resolution resolution NOUN k6439z92h9n 1 23 . . PUNCT k6439z92h9n 2 1 this this DET k6439z92h9n 2 2 dissertation dissertation NOUN k6439z92h9n 2 3 exploits exploit VERB k6439z92h9n 2 4 the the DET k6439z92h9n 2 5 vibrational vibrational ADJ k6439z92h9n 2 6 technique technique NOUN k6439z92h9n 2 7 to to PART k6439z92h9n 2 8 examine examine VERB k6439z92h9n 2 9 the the DET k6439z92h9n 2 10 structure structure NOUN k6439z92h9n 2 11 and and CCONJ k6439z92h9n 2 12 dynamics dynamic NOUN k6439z92h9n 2 13 of of ADP k6439z92h9n 2 14 various various ADJ k6439z92h9n 2 15 liquids liquid NOUN k6439z92h9n 2 16 : : PUNCT k6439z92h9n 2 17 water water NOUN k6439z92h9n 2 18 , , PUNCT k6439z92h9n 2 19 dilute dilute NOUN k6439z92h9n 2 20 mixtures mixture NOUN k6439z92h9n 2 21 of of ADP k6439z92h9n 2 22 water water NOUN k6439z92h9n 2 23 and and CCONJ k6439z92h9n 2 24 alcohol alcohol NOUN k6439z92h9n 2 25 , , PUNCT k6439z92h9n 2 26 neat neat ADJ k6439z92h9n 2 27 alcohol alcohol PROPN k6439z92h9n 2 28 , , PUNCT k6439z92h9n 2 29 il il PROPN k6439z92h9n 2 30 mixtures mixture NOUN k6439z92h9n 2 31 , , PUNCT k6439z92h9n 2 32 and and CCONJ k6439z92h9n 2 33 water water NOUN k6439z92h9n 2 34 surrounding surround VERB k6439z92h9n 2 35 dna dna PROPN k6439z92h9n 2 36 . . PUNCT k6439z92h9n 3 1 specifically specifically ADV k6439z92h9n 3 2 , , PUNCT k6439z92h9n 3 3 by by ADP k6439z92h9n 3 4 monitoring monitor VERB k6439z92h9n 3 5 the the DET k6439z92h9n 3 6 vibrational vibrational ADJ k6439z92h9n 3 7 frequency frequency NOUN k6439z92h9n 3 8 of of ADP k6439z92h9n 3 9 a a DET k6439z92h9n 3 10 reporter reporter NOUN k6439z92h9n 3 11 group group NOUN k6439z92h9n 3 12 as as ADP k6439z92h9n 3 13 the the DET k6439z92h9n 3 14 surrounding surround VERB k6439z92h9n 3 15 environment environment NOUN k6439z92h9n 3 16 changes change NOUN k6439z92h9n 3 17 , , PUNCT k6439z92h9n 3 18 process process NOUN k6439z92h9n 3 19 called call VERB k6439z92h9n 3 20 spectral spectral ADJ k6439z92h9n 3 21 diffusion diffusion NOUN k6439z92h9n 3 22 , , PUNCT k6439z92h9n 3 23 important important ADJ k6439z92h9n 3 24 dynamical dynamical ADJ k6439z92h9n 3 25 information information NOUN k6439z92h9n 3 26 can can AUX k6439z92h9n 3 27 be be AUX k6439z92h9n 3 28 extracted extract VERB k6439z92h9n 3 29 . . PUNCT k6439z92h9n 4 1 the the DET k6439z92h9n 4 2 vibrational vibrational ADJ k6439z92h9n 4 3 probe probe NOUN k6439z92h9n 4 4 of of ADP k6439z92h9n 4 5 interest interest NOUN k6439z92h9n 4 6 in in ADP k6439z92h9n 4 7 this this DET k6439z92h9n 4 8 research research NOUN k6439z92h9n 4 9 is be AUX k6439z92h9n 4 10 the the DET k6439z92h9n 4 11 od od NOUN k6439z92h9n 4 12 stretch stretch NOUN k6439z92h9n 4 13 , , PUNCT k6439z92h9n 4 14 which which PRON k6439z92h9n 4 15 has have AUX k6439z92h9n 4 16 been be AUX k6439z92h9n 4 17 used use VERB k6439z92h9n 4 18 extensively extensively ADV k6439z92h9n 4 19 in in ADP k6439z92h9n 4 20 experiments experiment NOUN k6439z92h9n 4 21 and and CCONJ k6439z92h9n 4 22 theory theory NOUN k6439z92h9n 4 23 . . PUNCT k6439z92h9n 5 1 experimental experimental ADJ k6439z92h9n 5 2 studies study NOUN k6439z92h9n 5 3 examining examine VERB k6439z92h9n 5 4 the the DET k6439z92h9n 5 5 structure structure NOUN k6439z92h9n 5 6 and and CCONJ k6439z92h9n 5 7 dynamics dynamic NOUN k6439z92h9n 5 8 of of ADP k6439z92h9n 5 9 deuterated deuterated ADJ k6439z92h9n 5 10 alcohols alcohol NOUN k6439z92h9n 5 11 isolated isolate VERB k6439z92h9n 5 12 in in ADP k6439z92h9n 5 13 ionic ionic ADJ k6439z92h9n 5 14 liquids liquid NOUN k6439z92h9n 5 15 ( ( PUNCT k6439z92h9n 5 16 ils il NOUN k6439z92h9n 5 17 ) ) PUNCT k6439z92h9n 5 18 have have AUX k6439z92h9n 5 19 revealed reveal VERB k6439z92h9n 5 20 that that DET k6439z92h9n 5 21 spectral spectral ADJ k6439z92h9n 5 22 diffusion diffusion NOUN k6439z92h9n 5 23 of of ADP k6439z92h9n 5 24 the the DET k6439z92h9n 5 25 od od X k6439z92h9n 5 26 stretch stretch NOUN k6439z92h9n 5 27 of of ADP k6439z92h9n 5 28 the the DET k6439z92h9n 5 29 alcohol alcohol NOUN k6439z92h9n 5 30 slows slow VERB k6439z92h9n 5 31 slightly slightly ADV k6439z92h9n 5 32 as as ADP k6439z92h9n 5 33 the the DET k6439z92h9n 5 34 length length NOUN k6439z92h9n 5 35 of of ADP k6439z92h9n 5 36 the the DET k6439z92h9n 5 37 alkyl alkyl ADJ k6439z92h9n 5 38 chain chain NOUN k6439z92h9n 5 39 increases increase NOUN k6439z92h9n 5 40 . . PUNCT k6439z92h9n 6 1 orientational orientational ADJ k6439z92h9n 6 2 relation relation NOUN k6439z92h9n 6 3 , , PUNCT k6439z92h9n 6 4 however however ADV k6439z92h9n 6 5 , , PUNCT k6439z92h9n 6 6 shows show VERB k6439z92h9n 6 7 a a DET k6439z92h9n 6 8 more more ADV k6439z92h9n 6 9 dramatic dramatic ADJ k6439z92h9n 6 10 effect effect NOUN k6439z92h9n 6 11 as as SCONJ k6439z92h9n 6 12 it it PRON k6439z92h9n 6 13 slows slow VERB k6439z92h9n 6 14 with with ADP k6439z92h9n 6 15 increasing increase VERB k6439z92h9n 6 16 alkyl alkyl NOUN k6439z92h9n 6 17 chain chain NOUN k6439z92h9n 6 18 length length NOUN k6439z92h9n 6 19 . . PUNCT k6439z92h9n 7 1 molecular molecular ADJ k6439z92h9n 7 2 dynamics dynamic NOUN k6439z92h9n 7 3 ( ( PUNCT k6439z92h9n 7 4 md md PROPN k6439z92h9n 7 5 ) ) PUNCT k6439z92h9n 7 6 simulations simulation NOUN k6439z92h9n 7 7 of of ADP k6439z92h9n 7 8 isolated isolated ADJ k6439z92h9n 7 9 water water NOUN k6439z92h9n 7 10 , , PUNCT k6439z92h9n 7 11 methanol methanol NOUN k6439z92h9n 7 12 , , PUNCT k6439z92h9n 7 13 and and CCONJ k6439z92h9n 7 14 ethanol ethanol NOUN k6439z92h9n 7 15 in in ADP k6439z92h9n 7 16 the the DET k6439z92h9n 7 17 1 1 NUM k6439z92h9n 7 18 - - PUNCT k6439z92h9n 7 19 ethyl-3 ethyl-3 NUM k6439z92h9n 7 20 - - PUNCT k6439z92h9n 7 21 methylimidazolium methylimidazolium NOUN k6439z92h9n 7 22 bis(trifluoromethylsulfonyl)imide bis(trifluoromethylsulfonyl)imide NOUN k6439z92h9n 7 23 , , PUNCT k6439z92h9n 7 24 [ [ X k6439z92h9n 7 25 emim][ntf2 emim][ntf2 X k6439z92h9n 7 26 ] ] X k6439z92h9n 7 27 , , PUNCT k6439z92h9n 7 28 il il PROPN k6439z92h9n 7 29 were be AUX k6439z92h9n 7 30 performed perform VERB k6439z92h9n 7 31 to to PART k6439z92h9n 7 32 shed shed VERB k6439z92h9n 7 33 insight insight NOUN k6439z92h9n 7 34 into into ADP k6439z92h9n 7 35 the the DET k6439z92h9n 7 36 nature nature NOUN k6439z92h9n 7 37 of of ADP k6439z92h9n 7 38 coupled couple VERB k6439z92h9n 7 39 solute solute ADJ k6439z92h9n 7 40 - - PUNCT k6439z92h9n 7 41 ion ion NOUN k6439z92h9n 7 42 dynamics dynamic NOUN k6439z92h9n 7 43 . . PUNCT k6439z92h9n 8 1 also also ADV k6439z92h9n 8 2 , , PUNCT k6439z92h9n 8 3 md md PROPN k6439z92h9n 8 4 simulations simulation NOUN k6439z92h9n 8 5 of of ADP k6439z92h9n 8 6 the the DET k6439z92h9n 8 7 alcohols alcohol NOUN k6439z92h9n 8 8 at at ADP k6439z92h9n 8 9 dilute dilute NOUN k6439z92h9n 8 10 concentration concentration NOUN k6439z92h9n 8 11 in in ADP k6439z92h9n 8 12 aqueous aqueous ADJ k6439z92h9n 8 13 solution solution NOUN k6439z92h9n 8 14 were be AUX k6439z92h9n 8 15 carried carry VERB k6439z92h9n 8 16 out out ADP k6439z92h9n 8 17 to to PART k6439z92h9n 8 18 provide provide VERB k6439z92h9n 8 19 a a DET k6439z92h9n 8 20 comparison comparison NOUN k6439z92h9n 8 21 . . PUNCT k6439z92h9n 9 1 the the DET k6439z92h9n 9 2 theoretical theoretical ADJ k6439z92h9n 9 3 calculations calculation NOUN k6439z92h9n 9 4 of of ADP k6439z92h9n 9 5 the the DET k6439z92h9n 9 6 spectral spectral ADJ k6439z92h9n 9 7 diffusion diffusion NOUN k6439z92h9n 9 8 dynamics dynamic NOUN k6439z92h9n 9 9 and and CCONJ k6439z92h9n 9 10 orientational orientational ADJ k6439z92h9n 9 11 relaxation relaxation NOUN k6439z92h9n 9 12 of of ADP k6439z92h9n 9 13 the the DET k6439z92h9n 9 14 od od X k6439z92h9n 9 15 stretch stretch NOUN k6439z92h9n 9 16 of of ADP k6439z92h9n 9 17 the the DET k6439z92h9n 9 18 isolated isolated ADJ k6439z92h9n 9 19 vibrational vibrational ADJ k6439z92h9n 9 20 reporters reporter NOUN k6439z92h9n 9 21 in in ADP k6439z92h9n 9 22 [ [ X k6439z92h9n 9 23 emim][ntf2 emim][ntf2 X k6439z92h9n 9 24 ] ] X k6439z92h9n 9 25 agree agree VERB k6439z92h9n 9 26 well well ADV k6439z92h9n 9 27 with with ADP k6439z92h9n 9 28 experiment experiment NOUN k6439z92h9n 9 29 . . PUNCT k6439z92h9n 10 1 the the DET k6439z92h9n 10 2 size size NOUN k6439z92h9n 10 3 of of ADP k6439z92h9n 10 4 the the DET k6439z92h9n 10 5 alcohol alcohol NOUN k6439z92h9n 10 6 does do AUX k6439z92h9n 10 7 not not PART k6439z92h9n 10 8 affect affect VERB k6439z92h9n 10 9 the the DET k6439z92h9n 10 10 spectral spectral ADJ k6439z92h9n 10 11 diffusion diffusion NOUN k6439z92h9n 10 12 timescales timescale NOUN k6439z92h9n 10 13 very very ADV k6439z92h9n 10 14 much much ADV k6439z92h9n 10 15 , , PUNCT k6439z92h9n 10 16 while while SCONJ k6439z92h9n 10 17 there there PRON k6439z92h9n 10 18 are be VERB k6439z92h9n 10 19 distinct distinct ADJ k6439z92h9n 10 20 differences difference NOUN k6439z92h9n 10 21 between between ADP k6439z92h9n 10 22 the the DET k6439z92h9n 10 23 reorientational reorientational ADJ k6439z92h9n 10 24 relaxation relaxation NOUN k6439z92h9n 10 25 timescales.the timescales.the DET k6439z92h9n 10 26 sensitivity sensitivity NOUN k6439z92h9n 10 27 of of ADP k6439z92h9n 10 28 the the DET k6439z92h9n 10 29 phosphate phosphate PROPN k6439z92h9n 10 30 asymmetric asymmetric PROPN k6439z92h9n 10 31 stretch stretch PROPN k6439z92h9n 10 32 vibrational vibrational ADJ k6439z92h9n 10 33 frequency frequency NOUN k6439z92h9n 10 34 to to ADP k6439z92h9n 10 35 dna dna PROPN k6439z92h9n 10 36 hydration hydration NOUN k6439z92h9n 10 37 was be AUX k6439z92h9n 10 38 investigated investigate VERB k6439z92h9n 10 39 with with ADP k6439z92h9n 10 40 md md PROPN k6439z92h9n 10 41 simulations simulation NOUN k6439z92h9n 10 42 and and CCONJ k6439z92h9n 10 43 a a DET k6439z92h9n 10 44 spectroscopic spectroscopic ADJ k6439z92h9n 10 45 map map NOUN k6439z92h9n 10 46 relating relate VERB k6439z92h9n 10 47 the the DET k6439z92h9n 10 48 vibrational vibrational ADJ k6439z92h9n 10 49 frequency frequency NOUN k6439z92h9n 10 50 to to ADP k6439z92h9n 10 51 the the DET k6439z92h9n 10 52 electrostatics electrostatic NOUN k6439z92h9n 10 53 of of ADP k6439z92h9n 10 54 its its PRON k6439z92h9n 10 55 environment environment NOUN k6439z92h9n 10 56 . . PUNCT k6439z92h9n 11 1 95\% 95\% NUM k6439z92h9n 11 2 of of ADP k6439z92h9n 11 3 the the DET k6439z92h9n 11 4 phosphate phosphate NOUN k6439z92h9n 11 5 vibrational vibrational ADJ k6439z92h9n 11 6 frequency frequency NOUN k6439z92h9n 11 7 shift shift NOUN k6439z92h9n 11 8 in in ADP k6439z92h9n 11 9 fully fully ADV k6439z92h9n 11 10 hydrated hydrated ADJ k6439z92h9n 11 11 dna dna NOUN k6439z92h9n 11 12 was be AUX k6439z92h9n 11 13 due due ADJ k6439z92h9n 11 14 to to ADP k6439z92h9n 11 15 water water NOUN k6439z92h9n 11 16 within within ADP k6439z92h9n 11 17 two two NUM k6439z92h9n 11 18 hydration hydration NOUN k6439z92h9n 11 19 layers layer NOUN k6439z92h9n 11 20 . . PUNCT k6439z92h9n 12 1 the the DET k6439z92h9n 12 2 phosphate phosphate NOUN k6439z92h9n 12 3 vibration vibration NOUN k6439z92h9n 12 4 was be AUX k6439z92h9n 12 5 relatively relatively ADV k6439z92h9n 12 6 insensitive insensitive ADJ k6439z92h9n 12 7 to to ADP k6439z92h9n 12 8 water water NOUN k6439z92h9n 12 9 in in ADP k6439z92h9n 12 10 the the DET k6439z92h9n 12 11 major major ADJ k6439z92h9n 12 12 and and CCONJ k6439z92h9n 12 13 minor minor ADJ k6439z92h9n 12 14 grooves groove NOUN k6439z92h9n 12 15 and and CCONJ k6439z92h9n 12 16 the the DET k6439z92h9n 12 17 sodium sodium NOUN k6439z92h9n 12 18 counterions counterion NOUN k6439z92h9n 12 19 but but CCONJ k6439z92h9n 12 20 was be AUX k6439z92h9n 12 21 enormously enormously ADV k6439z92h9n 12 22 sensitive sensitive ADJ k6439z92h9n 12 23 to to ADP k6439z92h9n 12 24 water water NOUN k6439z92h9n 12 25 interacting interact VERB k6439z92h9n 12 26 with with ADP k6439z92h9n 12 27 the the DET k6439z92h9n 12 28 dna dna PROPN k6439z92h9n 12 29 backbone backbone NOUN k6439z92h9n 12 30 . . PUNCT k6439z92h9n 13 1 comparisons comparison NOUN k6439z92h9n 13 2 to to ADP k6439z92h9n 13 3 experimental experimental ADJ k6439z92h9n 13 4 measurements measurement NOUN k6439z92h9n 13 5 on on ADP k6439z92h9n 13 6 dna dna PROPN k6439z92h9n 13 7 as as ADP k6439z92h9n 13 8 a a DET k6439z92h9n 13 9 function function NOUN k6439z92h9n 13 10 of of ADP k6439z92h9n 13 11 relative relative ADJ k6439z92h9n 13 12 humidity humidity NOUN k6439z92h9n 13 13 suggest suggest VERB k6439z92h9n 13 14 that that SCONJ k6439z92h9n 13 15 one one NUM k6439z92h9n 13 16 water water NOUN k6439z92h9n 13 17 molecule molecule NOUN k6439z92h9n 13 18 per per ADP k6439z92h9n 13 19 phosphate phosphate NOUN k6439z92h9n 13 20 group group NOUN k6439z92h9n 13 21 likely likely ADV k6439z92h9n 13 22 persists persist VERB k6439z92h9n 13 23 at at ADP k6439z92h9n 13 24 the the DET k6439z92h9n 13 25 lowest low ADJ k6439z92h9n 13 26 values value NOUN k6439z92h9n 13 27 of of ADP k6439z92h9n 13 28 the the DET k6439z92h9n 13 29 relative relative ADJ k6439z92h9n 13 30 humidity humidity NOUN k6439z92h9n 13 31 . . PUNCT k6439z92h9n 14 1 finally finally ADV k6439z92h9n 14 2 , , PUNCT k6439z92h9n 14 3 the the DET k6439z92h9n 14 4 calculated calculate VERB k6439z92h9n 14 5 spectral spectral ADJ k6439z92h9n 14 6 diffusion diffusion NOUN k6439z92h9n 14 7 dynamics dynamic NOUN k6439z92h9n 14 8 show show VERB k6439z92h9n 14 9 that that SCONJ k6439z92h9n 14 10 water water NOUN k6439z92h9n 14 11 in in ADP k6439z92h9n 14 12 the the DET k6439z92h9n 14 13 vicinity vicinity NOUN k6439z92h9n 14 14 of of ADP k6439z92h9n 14 15 the the DET k6439z92h9n 14 16 dna dna PROPN k6439z92h9n 14 17 backbone backbone NOUN k6439z92h9n 14 18 is be AUX k6439z92h9n 14 19 slowed slow VERB k6439z92h9n 14 20 by by ADP k6439z92h9n 14 21 a a DET k6439z92h9n 14 22 factor factor NOUN k6439z92h9n 14 23 of of ADP k6439z92h9n 14 24 five five NUM k6439z92h9n 14 25 , , PUNCT k6439z92h9n 14 26 in in ADP k6439z92h9n 14 27 agreement agreement NOUN k6439z92h9n 14 28 with with ADP k6439z92h9n 14 29 nmr nmr PROPN k6439z92h9n 14 30 and and CCONJ k6439z92h9n 14 31 solvation solvation NOUN k6439z92h9n 14 32 dynamics dynamic NOUN k6439z92h9n 14 33 experiments experiment NOUN k6439z92h9n 14 34 , , PUNCT k6439z92h9n 14 35 as as ADV k6439z92h9n 14 36 well well ADV k6439z92h9n 14 37 as as ADP k6439z92h9n 14 38 previous previous ADJ k6439z92h9n 14 39 md md PROPN k6439z92h9n 14 40 simulations simulation NOUN k6439z92h9n 14 41 . . PUNCT