id sid tid token lemma pos j3860577g1r 1 1 this this DET j3860577g1r 1 2 dissertation dissertation NOUN j3860577g1r 1 3 describes describe VERB j3860577g1r 1 4 efforts effort NOUN j3860577g1r 1 5 to to PART j3860577g1r 1 6 develop develop VERB j3860577g1r 1 7 spectroscopic spectroscopic ADJ j3860577g1r 1 8 reporters reporter NOUN j3860577g1r 1 9 to to PART j3860577g1r 1 10 understand understand VERB j3860577g1r 1 11 better well ADJ j3860577g1r 1 12 the the DET j3860577g1r 1 13 surface surface NOUN j3860577g1r 1 14 redox redox ADJ j3860577g1r 1 15 chemistry chemistry NOUN j3860577g1r 1 16 of of ADP j3860577g1r 1 17 colloidal colloidal ADJ j3860577g1r 1 18 semiconductor semiconductor NOUN j3860577g1r 1 19 metal metal NOUN j3860577g1r 1 20 chalcogenide chalcogenide NOUN j3860577g1r 1 21 nanocrystals nanocrystal NOUN j3860577g1r 1 22 . . PUNCT j3860577g1r 2 1 through through ADP j3860577g1r 2 2 the the DET j3860577g1r 2 3 use use NOUN j3860577g1r 2 4 of of ADP j3860577g1r 2 5 surface surface NOUN j3860577g1r 2 6 - - PUNCT j3860577g1r 2 7 bound bind VERB j3860577g1r 2 8 metal metal NOUN j3860577g1r 2 9 carbonyl carbonyl NOUN j3860577g1r 2 10 organometallic organometallic ADJ j3860577g1r 2 11 fragments fragment NOUN j3860577g1r 2 12 , , PUNCT j3860577g1r 2 13 changes change NOUN j3860577g1r 2 14 to to ADP j3860577g1r 2 15 the the DET j3860577g1r 2 16 surface surface NOUN j3860577g1r 2 17 electrostatics electrostatic NOUN j3860577g1r 2 18 were be AUX j3860577g1r 2 19 observed observe VERB j3860577g1r 2 20 through through ADP j3860577g1r 2 21 ir ir NOUN j3860577g1r 2 22 spectroscopy spectroscopy NOUN j3860577g1r 2 23 . . PUNCT j3860577g1r 3 1 chemical chemical ADJ j3860577g1r 3 2 reduction reduction NOUN j3860577g1r 3 3 and and CCONJ j3860577g1r 3 4 oxidation oxidation NOUN j3860577g1r 3 5 , , PUNCT j3860577g1r 3 6 photoinduced photoinduce VERB j3860577g1r 3 7 charge charge NOUN j3860577g1r 3 8 trapping trapping NOUN j3860577g1r 3 9 , , PUNCT j3860577g1r 3 10 and and CCONJ j3860577g1r 3 11 modifications modification NOUN j3860577g1r 3 12 to to ADP j3860577g1r 3 13 the the DET j3860577g1r 3 14 metal metal NOUN j3860577g1r 3 15 - - PUNCT j3860577g1r 3 16 to to ADP j3860577g1r 3 17 - - PUNCT j3860577g1r 3 18 chalcogenide chalcogenide NOUN j3860577g1r 3 19 surface surface NOUN j3860577g1r 3 20 stoichiometry stoichiometry NOUN j3860577g1r 3 21 caused cause VERB j3860577g1r 3 22 observable observable ADJ j3860577g1r 3 23 shifts shift NOUN j3860577g1r 3 24 to to ADP j3860577g1r 3 25 the the DET j3860577g1r 3 26 c c NOUN j3860577g1r 3 27 – – PUNCT j3860577g1r 3 28 o o ADP j3860577g1r 3 29 stretching stretch VERB j3860577g1r 3 30 frequencies frequency NOUN j3860577g1r 3 31 of of ADP j3860577g1r 3 32 the the DET j3860577g1r 3 33 functionalized functionalize VERB j3860577g1r 3 34 metal metal NOUN j3860577g1r 3 35 carbonyls.chapter carbonyls.chapter NOUN j3860577g1r 3 36 2 2 NUM j3860577g1r 3 37 describes describe VERB j3860577g1r 3 38 the the DET j3860577g1r 3 39 synthetic synthetic ADJ j3860577g1r 3 40 pathways pathway NOUN j3860577g1r 3 41 for for ADP j3860577g1r 3 42 functionalized functionalize VERB j3860577g1r 3 43 cde cde PROPN j3860577g1r 3 44 - - PUNCT j3860577g1r 3 45 cdm(co)4 cdm(co)4 PROPN j3860577g1r 3 46 ncs ncs NOUN j3860577g1r 3 47 ( ( PUNCT j3860577g1r 3 48 e e X j3860577g1r 3 49 = = X j3860577g1r 3 50 se se PROPN j3860577g1r 3 51 , , PUNCT j3860577g1r 3 52 s s VERB j3860577g1r 3 53 ; ; PUNCT j3860577g1r 3 54 m m PROPN j3860577g1r 3 55 = = PROPN j3860577g1r 3 56 fe fe PROPN j3860577g1r 3 57 , , PUNCT j3860577g1r 3 58 co co PROPN j3860577g1r 3 59 ) ) PUNCT j3860577g1r 3 60 through through ADP j3860577g1r 3 61 x x ADJ j3860577g1r 3 62 - - NOUN j3860577g1r 3 63 type type NOUN j3860577g1r 3 64 ligand ligand NOUN j3860577g1r 3 65 exchange exchange NOUN j3860577g1r 3 66 . . PUNCT j3860577g1r 4 1 through through ADP j3860577g1r 4 2 the the DET j3860577g1r 4 3 addition addition NOUN j3860577g1r 4 4 of of ADP j3860577g1r 4 5 increasing increase VERB j3860577g1r 4 6 equivalents equivalent NOUN j3860577g1r 4 7 per per ADP j3860577g1r 4 8 nanocrystal nanocrystal NOUN j3860577g1r 4 9 of of ADP j3860577g1r 4 10 chemical chemical ADJ j3860577g1r 4 11 reductant reductant NOUN j3860577g1r 4 12 and and CCONJ j3860577g1r 4 13 oxidant oxidant NOUN j3860577g1r 4 14 , , PUNCT j3860577g1r 4 15 the the DET j3860577g1r 4 16 relationship relationship NOUN j3860577g1r 4 17 between between ADP j3860577g1r 4 18 the the DET j3860577g1r 4 19 change change NOUN j3860577g1r 4 20 in in ADP j3860577g1r 4 21 c c PROPN j3860577g1r 4 22 – – PUNCT j3860577g1r 4 23 o o ADP j3860577g1r 4 24 stretching stretch VERB j3860577g1r 4 25 frequencies frequency NOUN j3860577g1r 4 26 was be AUX j3860577g1r 4 27 related relate VERB j3860577g1r 4 28 to to ADP j3860577g1r 4 29 the the DET j3860577g1r 4 30 number number NOUN j3860577g1r 4 31 of of ADP j3860577g1r 4 32 electrons electron NOUN j3860577g1r 4 33 added add VERB j3860577g1r 4 34 or or CCONJ j3860577g1r 4 35 removed remove VERB j3860577g1r 4 36 from from ADP j3860577g1r 4 37 the the DET j3860577g1r 4 38 surface surface NOUN j3860577g1r 4 39 . . PUNCT j3860577g1r 5 1 the the DET j3860577g1r 5 2 differences difference NOUN j3860577g1r 5 3 in in ADP j3860577g1r 5 4 the the DET j3860577g1r 5 5 reducing reduce VERB j3860577g1r 5 6 potential potential NOUN j3860577g1r 5 7 of of ADP j3860577g1r 5 8 the the DET j3860577g1r 5 9 [ [ X j3860577g1r 5 10 fe(co)4]2precursor fe(co)4]2precursor NOUN j3860577g1r 5 11 were be AUX j3860577g1r 5 12 explored explore VERB j3860577g1r 5 13 through through ADP j3860577g1r 5 14 the the DET j3860577g1r 5 15 initial initial ADJ j3860577g1r 5 16 energies energy NOUN j3860577g1r 5 17 of of ADP j3860577g1r 5 18 the the DET j3860577g1r 5 19 c c NOUN j3860577g1r 5 20 – – PUNCT j3860577g1r 5 21 o o NOUN j3860577g1r 5 22 stretching stretch VERB j3860577g1r 5 23 band band NOUN j3860577g1r 5 24 and and CCONJ j3860577g1r 5 25 the the DET j3860577g1r 5 26 change change NOUN j3860577g1r 5 27 in in ADP j3860577g1r 5 28 c c PROPN j3860577g1r 5 29 – – PUNCT j3860577g1r 5 30 o o ADP j3860577g1r 5 31 stretching stretch VERB j3860577g1r 5 32 frequencies frequency NOUN j3860577g1r 5 33 from from ADP j3860577g1r 5 34 the the DET j3860577g1r 5 35 addition addition NOUN j3860577g1r 5 36 of of ADP j3860577g1r 5 37 chemical chemical ADJ j3860577g1r 5 38 reductant reductant NOUN j3860577g1r 5 39 and and CCONJ j3860577g1r 5 40 oxidant oxidant NOUN j3860577g1r 5 41 was be AUX j3860577g1r 5 42 compared compare VERB j3860577g1r 5 43 between between ADP j3860577g1r 5 44 the the DET j3860577g1r 5 45 samples sample NOUN j3860577g1r 5 46 . . PUNCT j3860577g1r 6 1 the the DET j3860577g1r 6 2 c c X j3860577g1r 6 3 – – PUNCT j3860577g1r 6 4 o o ADP j3860577g1r 6 5 stretching stretch VERB j3860577g1r 6 6 force force NOUN j3860577g1r 6 7 constants constant NOUN j3860577g1r 6 8 and and CCONJ j3860577g1r 6 9 group group NOUN j3860577g1r 6 10 dipole dipole NOUN j3860577g1r 6 11 moment moment NOUN j3860577g1r 6 12 derivatives derivative NOUN j3860577g1r 6 13 for for ADP j3860577g1r 6 14 each each DET j3860577g1r 6 15 species specie NOUN j3860577g1r 6 16 were be AUX j3860577g1r 6 17 also also ADV j3860577g1r 6 18 calculated calculate VERB j3860577g1r 6 19 and and CCONJ j3860577g1r 6 20 showed show VERB j3860577g1r 6 21 upon upon SCONJ j3860577g1r 6 22 the the DET j3860577g1r 6 23 addition addition NOUN j3860577g1r 6 24 of of ADP j3860577g1r 6 25 reductant reductant NOUN j3860577g1r 6 26 , , PUNCT j3860577g1r 6 27 reduced reduce VERB j3860577g1r 6 28 π π NOUN j3860577g1r 6 29 contribution contribution NOUN j3860577g1r 6 30 from from ADP j3860577g1r 6 31 the the DET j3860577g1r 6 32 surface surface NOUN j3860577g1r 6 33 cd cd PROPN j3860577g1r 6 34 to to ADP j3860577g1r 6 35 the the DET j3860577g1r 6 36 metal metal NOUN j3860577g1r 6 37 carbonyl carbonyl NOUN j3860577g1r 6 38 center center NOUN j3860577g1r 6 39 . . PUNCT j3860577g1r 7 1 altogether altogether ADV j3860577g1r 7 2 , , PUNCT j3860577g1r 7 3 these these DET j3860577g1r 7 4 results result NOUN j3860577g1r 7 5 showed show VERB j3860577g1r 7 6 that that SCONJ j3860577g1r 7 7 cdse cdse NOUN j3860577g1r 7 8 - - PUNCT j3860577g1r 7 9 cdfe(co)4 cdfe(co)4 PROPN j3860577g1r 7 10 ncs nc NOUN j3860577g1r 7 11 were be AUX j3860577g1r 7 12 sensitive sensitive ADJ j3860577g1r 7 13 to to ADP j3860577g1r 7 14 changes change NOUN j3860577g1r 7 15 to to ADP j3860577g1r 7 16 surface surface NOUN j3860577g1r 7 17 reduction reduction NOUN j3860577g1r 7 18 and and CCONJ j3860577g1r 7 19 oxidation oxidation NOUN j3860577g1r 7 20 and and CCONJ j3860577g1r 7 21 that that SCONJ j3860577g1r 7 22 the the DET j3860577g1r 7 23 metal metal NOUN j3860577g1r 7 24 carbonyl carbonyl NOUN j3860577g1r 7 25 bonding bonding NOUN j3860577g1r 7 26 interactions interaction NOUN j3860577g1r 7 27 could could AUX j3860577g1r 7 28 be be AUX j3860577g1r 7 29 tuned tune VERB j3860577g1r 7 30 by by ADP j3860577g1r 7 31 altering alter VERB j3860577g1r 7 32 the the DET j3860577g1r 7 33 nc nc NOUN j3860577g1r 7 34 surface.chapter surface.chapter NOUN j3860577g1r 7 35 3 3 NUM j3860577g1r 7 36 describes describe VERB j3860577g1r 7 37 a a DET j3860577g1r 7 38 new new ADJ j3860577g1r 7 39 synthetic synthetic ADJ j3860577g1r 7 40 pathway pathway NOUN j3860577g1r 7 41 to to ADP j3860577g1r 7 42 metal metal NOUN j3860577g1r 7 43 carbonyl carbonyl NOUN j3860577g1r 7 44 functionalized functionalize VERB j3860577g1r 7 45 metal metal NOUN j3860577g1r 7 46 chalcogenide chalcogenide NOUN j3860577g1r 7 47 nanocrystals nanocrystal NOUN j3860577g1r 7 48 through through ADP j3860577g1r 7 49 z z NOUN j3860577g1r 7 50 - - PUNCT j3860577g1r 7 51 type type NOUN j3860577g1r 7 52 addition addition NOUN j3860577g1r 7 53 of of ADP j3860577g1r 7 54 [ [ X j3860577g1r 7 55 cdfe(co)4 cdfe(co)4 PROPN j3860577g1r 7 56 ] ] PUNCT j3860577g1r 7 57 . . PUNCT j3860577g1r 8 1 the the DET j3860577g1r 8 2 z z PROPN j3860577g1r 8 3 - - PUNCT j3860577g1r 8 4 type type NOUN j3860577g1r 8 5 exchange exchange NOUN j3860577g1r 8 6 mechanism mechanism NOUN j3860577g1r 8 7 for for ADP j3860577g1r 8 8 functionalization functionalization NOUN j3860577g1r 8 9 was be AUX j3860577g1r 8 10 explored explore VERB j3860577g1r 8 11 . . PUNCT j3860577g1r 9 1 the the DET j3860577g1r 9 2 surface surface NOUN j3860577g1r 9 3 metal metal NOUN j3860577g1r 9 4 - - PUNCT j3860577g1r 9 5 to to ADP j3860577g1r 9 6 - - PUNCT j3860577g1r 9 7 chalcogenide chalcogenide NOUN j3860577g1r 9 8 ratio ratio NOUN j3860577g1r 9 9 was be AUX j3860577g1r 9 10 changed change VERB j3860577g1r 9 11 through through ADP j3860577g1r 9 12 l l NOUN j3860577g1r 9 13 - - PUNCT j3860577g1r 9 14 type type NOUN j3860577g1r 9 15 assisted assist VERB j3860577g1r 9 16 z z NOUN j3860577g1r 9 17 - - PUNCT j3860577g1r 9 18 type type NOUN j3860577g1r 9 19 displacement displacement NOUN j3860577g1r 9 20 , , PUNCT j3860577g1r 9 21 and and CCONJ j3860577g1r 9 22 the the DET j3860577g1r 9 23 changes change NOUN j3860577g1r 9 24 to to ADP j3860577g1r 9 25 the the DET j3860577g1r 9 26 surface surface NOUN j3860577g1r 9 27 electrostatics electrostatic NOUN j3860577g1r 9 28 were be AUX j3860577g1r 9 29 observed observe VERB j3860577g1r 9 30 through through ADP j3860577g1r 9 31 ir ir NOUN j3860577g1r 9 32 spectroscopy spectroscopy NOUN j3860577g1r 9 33 . . PUNCT j3860577g1r 10 1 the the DET j3860577g1r 10 2 displacement displacement NOUN j3860577g1r 10 3 isotherms isotherm NOUN j3860577g1r 10 4 of of ADP j3860577g1r 10 5 cdx2 cdx2 NOUN j3860577g1r 10 6 from from ADP j3860577g1r 10 7 the the DET j3860577g1r 10 8 surface surface NOUN j3860577g1r 10 9 were be AUX j3860577g1r 10 10 also also ADV j3860577g1r 10 11 calculated calculate VERB j3860577g1r 10 12 and and CCONJ j3860577g1r 10 13 showed show VERB j3860577g1r 10 14 heterogeneity heterogeneity NOUN j3860577g1r 10 15 in in ADP j3860577g1r 10 16 the the DET j3860577g1r 10 17 effect effect NOUN j3860577g1r 10 18 each each DET j3860577g1r 10 19 binding bind VERB j3860577g1r 10 20 site site NOUN j3860577g1r 10 21 had have VERB j3860577g1r 10 22 on on ADP j3860577g1r 10 23 the the DET j3860577g1r 10 24 surface surface NOUN j3860577g1r 10 25 electrostatics electrostatic NOUN j3860577g1r 10 26 . . PUNCT j3860577g1r 11 1 these these DET j3860577g1r 11 2 results result NOUN j3860577g1r 11 3 were be AUX j3860577g1r 11 4 used use VERB j3860577g1r 11 5 to to PART j3860577g1r 11 6 demonstrate demonstrate VERB j3860577g1r 11 7 the the DET j3860577g1r 11 8 use use NOUN j3860577g1r 11 9 of of ADP j3860577g1r 11 10 cdse cdse NOUN j3860577g1r 11 11 - - PUNCT j3860577g1r 11 12 cdfe(co)4 cdfe(co)4 PROPN j3860577g1r 11 13 ncs ncs NOUN j3860577g1r 11 14 as as ADP j3860577g1r 11 15 a a DET j3860577g1r 11 16 probe probe NOUN j3860577g1r 11 17 sensitive sensitive ADJ j3860577g1r 11 18 to to ADP j3860577g1r 11 19 changes change NOUN j3860577g1r 11 20 to to ADP j3860577g1r 11 21 the the DET j3860577g1r 11 22 surface surface NOUN j3860577g1r 11 23 electrostatics electrostatic NOUN j3860577g1r 11 24 induced induce VERB j3860577g1r 11 25 by by ADP j3860577g1r 11 26 modifying modify VERB j3860577g1r 11 27 the the DET j3860577g1r 11 28 surface surface NOUN j3860577g1r 11 29 metal metal NOUN j3860577g1r 11 30 - - PUNCT j3860577g1r 11 31 to to ADP j3860577g1r 11 32 - - PUNCT j3860577g1r 11 33 chalcogenide chalcogenide NOUN j3860577g1r 11 34 ratio.chapter ratio.chapter NOUN j3860577g1r 11 35 4 4 NUM j3860577g1r 11 36 describes describe VERB j3860577g1r 11 37 the the DET j3860577g1r 11 38 instability instability NOUN j3860577g1r 11 39 of of ADP j3860577g1r 11 40 cobaltocene cobaltocene NOUN j3860577g1r 11 41 under under ADP j3860577g1r 11 42 certain certain ADJ j3860577g1r 11 43 photochemical photochemical ADJ j3860577g1r 11 44 conditions condition NOUN j3860577g1r 11 45 . . PUNCT j3860577g1r 12 1 the the DET j3860577g1r 12 2 released release VERB j3860577g1r 12 3 cyclopentadiene cyclopentadiene NOUN j3860577g1r 12 4 radical radical ADJ j3860577g1r 12 5 was be AUX j3860577g1r 12 6 trapped trap VERB j3860577g1r 12 7 and and CCONJ j3860577g1r 12 8 observed observe VERB j3860577g1r 12 9 through through ADP j3860577g1r 12 10 epr epr ADJ j3860577g1r 12 11 spectroscopy spectroscopy NOUN j3860577g1r 12 12 . . PUNCT j3860577g1r 13 1 the the DET j3860577g1r 13 2 wavelength wavelength NOUN j3860577g1r 13 3 dependency dependency NOUN j3860577g1r 13 4 of of ADP j3860577g1r 13 5 the the DET j3860577g1r 13 6 radical radical ADJ j3860577g1r 13 7 release release NOUN j3860577g1r 13 8 was be AUX j3860577g1r 13 9 detailed detail VERB j3860577g1r 13 10 . . PUNCT j3860577g1r 14 1 a a DET j3860577g1r 14 2 reactive reactive ADJ j3860577g1r 14 3 [ [ X j3860577g1r 14 4 cocpi cocpi X j3860577g1r 14 5 ] ] PUNCT j3860577g1r 14 6 species specie NOUN j3860577g1r 14 7 was be AUX j3860577g1r 14 8 proposed propose VERB j3860577g1r 14 9 to to PART j3860577g1r 14 10 be be AUX j3860577g1r 14 11 generated generate VERB j3860577g1r 14 12 and and CCONJ j3860577g1r 14 13 was be AUX j3860577g1r 14 14 shown show VERB j3860577g1r 14 15 to to PART j3860577g1r 14 16 facilitate facilitate VERB j3860577g1r 14 17 the the DET j3860577g1r 14 18 catalytic catalytic ADJ j3860577g1r 14 19 trimerization trimerization NOUN j3860577g1r 14 20 of of ADP j3860577g1r 14 21 alkynes.appendix alkynes.appendix PROPN j3860577g1r 14 22 a a PRON j3860577g1r 14 23 describes describe VERB j3860577g1r 14 24 efforts effort NOUN j3860577g1r 14 25 to to PART j3860577g1r 14 26 probe probe VERB j3860577g1r 14 27 the the DET j3860577g1r 14 28 surface surface NOUN j3860577g1r 14 29 of of ADP j3860577g1r 14 30 metal metal NOUN j3860577g1r 14 31 chalcogenide chalcogenide NOUN j3860577g1r 14 32 nanocrystals nanocrystal NOUN j3860577g1r 14 33 during during ADP j3860577g1r 14 34 photoexcitation photoexcitation NOUN j3860577g1r 14 35 and and CCONJ j3860577g1r 14 36 photocatalytic photocatalytic ADJ j3860577g1r 14 37 conditions condition NOUN j3860577g1r 14 38 . . PUNCT j3860577g1r 15 1 appendix appendix PROPN j3860577g1r 15 2 b b PROPN j3860577g1r 15 3 contains contain VERB j3860577g1r 15 4 additional additional ADJ j3860577g1r 15 5 characterization characterization NOUN j3860577g1r 15 6 of of ADP j3860577g1r 15 7 precursors precursor NOUN j3860577g1r 15 8 and and CCONJ j3860577g1r 15 9 photocatalysis photocatalysis NOUN j3860577g1r 15 10 products product NOUN j3860577g1r 15 11 . . PUNCT