id	sid	tid	token	lemma	pos
j386057681m	1	1	chlorite	chlorite	PROPN
j386057681m	1	2	dismutase	dismutase	NOUN
j386057681m	1	3	is	be	AUX
j386057681m	1	4	a	a	DET
j386057681m	1	5	heme	heme	NOUN
j386057681m	1	6	dependent	dependent	ADJ
j386057681m	1	7	enzyme	enzyme	NOUN
j386057681m	1	8	that	that	PRON
j386057681m	1	9	catalyses	catalyse	VERB
j386057681m	1	10	the	the	DET
j386057681m	1	11	decomposition	decomposition	NOUN
j386057681m	1	12	of	of	ADP
j386057681m	1	13	the	the	DET
j386057681m	1	14	substrate	substrate	NOUN
j386057681m	1	15	chlorite	chlorite	NOUN
j386057681m	1	16	into	into	ADP
j386057681m	1	17	clì¢åè	clì¢åè	PROPN
j386057681m	1	18	and	and	CCONJ
j386057681m	1	19	oì¢	oì¢	SPACE
j386057681m	1	20	'	'	PUNCT
j386057681m	1	21	_	_	VERB
j386057681m	1	22	'	'	PUNCT
j386057681m	1	23	_	_	X
j386057681m	1	24	.	.	PUNCT
j386057681m	2	1	a	a	DET
j386057681m	2	2	basic	basic	ADJ
j386057681m	2	3	characterization	characterization	NOUN
j386057681m	2	4	of	of	ADP
j386057681m	2	5	the	the	DET
j386057681m	2	6	protein	protein	NOUN
j386057681m	2	7	under	under	ADP
j386057681m	2	8	steady	steady	ADJ
j386057681m	2	9	-	-	PUNCT
j386057681m	2	10	state	state	NOUN
j386057681m	2	11	conditions	condition	NOUN
j386057681m	2	12	shows	show	VERB
j386057681m	2	13	a	a	DET
j386057681m	2	14	robust	robust	ADJ
j386057681m	2	15	enzyme	enzyme	NOUN
j386057681m	2	16	capable	capable	ADJ
j386057681m	2	17	of	of	ADP
j386057681m	2	18	catalyzing	catalyze	VERB
j386057681m	2	19	the	the	DET
j386057681m	2	20	reaction	reaction	NOUN
j386057681m	2	21	at	at	ADP
j386057681m	2	22	rapid	rapid	ADJ
j386057681m	2	23	rates	rate	NOUN
j386057681m	2	24	.	.	PUNCT
j386057681m	3	1	it	it	PRON
j386057681m	3	2	was	be	AUX
j386057681m	3	3	determined	determine	VERB
j386057681m	3	4	using	use	VERB
j386057681m	3	5	epr	epr	NOUN
j386057681m	3	6	and	and	CCONJ
j386057681m	3	7	stopped	stop	VERB
j386057681m	3	8	flow	flow	NOUN
j386057681m	3	9	spectroscopy	spectroscopy	NOUN
j386057681m	3	10	that	that	SCONJ
j386057681m	3	11	the	the	DET
j386057681m	3	12	enzyme	enzyme	NOUN
j386057681m	3	13	forms	form	VERB
j386057681m	3	14	the	the	DET
j386057681m	3	15	highly	highly	ADV
j386057681m	3	16	oxidizing	oxidize	VERB
j386057681m	3	17	ferryl	ferryl	ADJ
j386057681m	3	18	-	-	PUNCT
j386057681m	3	19	oxo	oxo	PROPN
j386057681m	3	20	porphyrin	porphyrin	NOUN
j386057681m	4	1	ì	ì	PROPN
j386057681m	4	2	ââ	ââ	NOUN
j386057681m	4	3	cation	cation	NOUN
j386057681m	4	4	radical	radical	ADJ
j386057681m	4	5	intermediate	intermediate	ADJ
j386057681m	4	6	(	(	PUNCT
j386057681m	4	7	compound	compound	NOUN
j386057681m	4	8	1	1	NUM
j386057681m	4	9	)	)	PUNCT
j386057681m	4	10	upon	upon	SCONJ
j386057681m	4	11	reaction	reaction	NOUN
j386057681m	4	12	with	with	ADP
j386057681m	4	13	peracetic	peracetic	ADJ
j386057681m	4	14	acid	acid	NOUN
j386057681m	4	15	.	.	PUNCT
j386057681m	5	1	unlike	unlike	ADP
j386057681m	5	2	other	other	ADJ
j386057681m	5	3	heme	heme	NOUN
j386057681m	5	4	enzymes	enzyme	NOUN
j386057681m	5	5	,	,	PUNCT
j386057681m	5	6	however	however	ADV
j386057681m	5	7	,	,	PUNCT
j386057681m	5	8	when	when	SCONJ
j386057681m	5	9	given	give	VERB
j386057681m	5	10	chlorite	chlorite	NOUN
j386057681m	5	11	as	as	ADP
j386057681m	5	12	an	an	DET
j386057681m	5	13	oxidant	oxidant	NOUN
j386057681m	5	14	,	,	PUNCT
j386057681m	5	15	cld	cld	PROPN
j386057681m	5	16	seems	seem	VERB
j386057681m	5	17	specifically	specifically	ADV
j386057681m	5	18	poised	poise	VERB
j386057681m	5	19	to	to	PART
j386057681m	5	20	carry	carry	VERB
j386057681m	5	21	out	out	ADP
j386057681m	5	22	the	the	DET
j386057681m	5	23	dismutation	dismutation	NOUN
j386057681m	5	24	exclusively	exclusively	ADV
j386057681m	5	25	.	.	PUNCT
j386057681m	6	1	measurement	measurement	NOUN
j386057681m	6	2	of	of	ADP
j386057681m	6	3	the	the	DET
j386057681m	6	4	binding	bind	VERB
j386057681m	6	5	affinity	affinity	NOUN
j386057681m	6	6	for	for	ADP
j386057681m	6	7	neutral	neutral	ADJ
j386057681m	6	8	ligands	ligand	NOUN
j386057681m	6	9	as	as	ADP
j386057681m	6	10	a	a	DET
j386057681m	6	11	function	function	NOUN
j386057681m	6	12	of	of	ADP
j386057681m	6	13	ph	ph	NOUN
j386057681m	6	14	show	show	NOUN
j386057681m	6	15	an	an	DET
j386057681m	6	16	enzyme	enzyme	NOUN
j386057681m	6	17	based	base	VERB
j386057681m	6	18	pka	pka	PROPN
j386057681m	6	19	at	at	ADP
j386057681m	6	20	6.4	6.4	NUM
j386057681m	6	21	.	.	PUNCT
j386057681m	7	1	resonance	resonance	NOUN
j386057681m	7	2	raman	raman	NOUN
j386057681m	7	3	spectroscopy	spectroscopy	NOUN
j386057681m	7	4	at	at	ADP
j386057681m	7	5	alkaline	alkaline	NOUN
j386057681m	7	6	ph	ph	NOUN
j386057681m	7	7	indicates	indicate	VERB
j386057681m	7	8	a	a	DET
j386057681m	7	9	weak	weak	ADJ
j386057681m	7	10	fe	fe	PROPN
j386057681m	7	11	-	-	PUNCT
j386057681m	7	12	oh	oh	NOUN
j386057681m	7	13	bond	bond	NOUN
j386057681m	7	14	suggestive	suggestive	ADJ
j386057681m	7	15	of	of	ADP
j386057681m	7	16	a	a	DET
j386057681m	7	17	strong	strong	ADJ
j386057681m	7	18	h	h	NOUN
j386057681m	7	19	-	-	PUNCT
j386057681m	7	20	bond	bond	NOUN
j386057681m	7	21	donating	donating	NOUN
j386057681m	7	22	residue	residue	NOUN
j386057681m	7	23	in	in	ADP
j386057681m	7	24	the	the	DET
j386057681m	7	25	distal	distal	ADJ
j386057681m	7	26	pocket	pocket	NOUN
j386057681m	7	27	.	.	PUNCT
j386057681m	8	1	with	with	ADP
j386057681m	8	2	uv	uv	NOUN
j386057681m	8	3	/	/	SYM
j386057681m	8	4	visible	visible	ADJ
j386057681m	8	5	spectroscopy	spectroscopy	NOUN
j386057681m	8	6	this	this	DET
j386057681m	8	7	holigation	holigation	NOUN
j386057681m	8	8	to	to	ADP
j386057681m	8	9	the	the	DET
j386057681m	8	10	heme	heme	NOUN
j386057681m	8	11	fe	fe	PROPN
j386057681m	8	12	is	be	AUX
j386057681m	8	13	observed	observe	VERB
j386057681m	8	14	with	with	ADP
j386057681m	8	15	a	a	DET
j386057681m	8	16	pka	pka	PROPN
j386057681m	8	17	of	of	ADP
j386057681m	8	18	8.7	8.7	NUM
j386057681m	8	19	.	.	PUNCT
j386057681m	8	20	resonance	resonance	NOUN
j386057681m	8	21	ramen	raman	NOUN
j386057681m	8	22	of	of	ADP
j386057681m	8	23	co	co	ADJ
j386057681m	8	24	bound	bind	VERB
j386057681m	8	25	cld	cld	NOUN
j386057681m	8	26	shows	show	VERB
j386057681m	8	27	both	both	CCONJ
j386057681m	8	28	a	a	DET
j386057681m	8	29	weak	weak	ADJ
j386057681m	8	30	and	and	CCONJ
j386057681m	8	31	a	a	DET
j386057681m	8	32	strong	strong	ADJ
j386057681m	8	33	fe	fe	PROPN
j386057681m	8	34	-	-	PUNCT
j386057681m	8	35	co	co	NOUN
j386057681m	8	36	stretch	stretch	NOUN
j386057681m	8	37	at	at	ADP
j386057681m	8	38	low	low	ADJ
j386057681m	8	39	ph	ph	NOUN
j386057681m	8	40	with	with	ADP
j386057681m	8	41	loss	loss	NOUN
j386057681m	8	42	of	of	ADP
j386057681m	8	43	the	the	DET
j386057681m	8	44	weak	weak	ADJ
j386057681m	8	45	fe	fe	PROPN
j386057681m	8	46	-	-	PUNCT
j386057681m	8	47	co	co	NOUN
j386057681m	8	48	stretch	stretch	NOUN
j386057681m	8	49	at	at	ADP
j386057681m	8	50	high	high	ADJ
j386057681m	8	51	ph	ph	NOUN
j386057681m	8	52	.	.	PUNCT
j386057681m	9	1	a	a	DET
j386057681m	9	2	crystal	crystal	NOUN
j386057681m	9	3	structure	structure	NOUN
j386057681m	9	4	of	of	ADP
j386057681m	9	5	cld	cld	PROPN
j386057681m	9	6	shows	show	VERB
j386057681m	9	7	a	a	DET
j386057681m	9	8	hydrophobic	hydrophobic	ADJ
j386057681m	9	9	distal	distal	ADJ
j386057681m	9	10	pocket	pocket	NOUN
j386057681m	9	11	with	with	ADP
j386057681m	9	12	only	only	ADV
j386057681m	9	13	one	one	NUM
j386057681m	9	14	residue	residue	NOUN
j386057681m	9	15	,	,	PUNCT
j386057681m	9	16	arg-183	arg-183	PROPN
j386057681m	9	17	,	,	PUNCT
j386057681m	9	18	capable	capable	ADJ
j386057681m	9	19	of	of	ADP
j386057681m	9	20	carrying	carry	VERB
j386057681m	9	21	out	out	ADP
j386057681m	9	22	an	an	DET
j386057681m	9	23	h	h	NOUN
j386057681m	9	24	-	-	PUNCT
j386057681m	9	25	bond	bond	NOUN
j386057681m	9	26	donating	donating	NOUN
j386057681m	9	27	role	role	NOUN
j386057681m	9	28	.	.	PUNCT
j386057681m	10	1	together	together	ADV
j386057681m	10	2	these	these	DET
j386057681m	10	3	data	datum	NOUN
j386057681m	10	4	suggest	suggest	VERB
j386057681m	10	5	that	that	SCONJ
j386057681m	10	6	deprotonation	deprotonation	NOUN
j386057681m	10	7	of	of	ADP
j386057681m	10	8	arg-183	arg-183	NUM
j386057681m	10	9	with	with	ADP
j386057681m	10	10	a	a	DET
j386057681m	10	11	pka	pka	PROPN
j386057681m	10	12	=	=	PROPN
j386057681m	10	13	6.4	6.4	NUM
j386057681m	10	14	is	be	AUX
j386057681m	10	15	followed	follow	VERB
j386057681m	10	16	by	by	ADP
j386057681m	10	17	a	a	DET
j386057681m	10	18	hydrolysis	hydrolysis	NOUN
j386057681m	10	19	reaction	reaction	NOUN
j386057681m	10	20	of	of	ADP
j386057681m	10	21	the	the	DET
j386057681m	10	22	active	active	ADJ
j386057681m	10	23	site	site	NOUN
j386057681m	10	24	at	at	ADP
j386057681m	10	25	ph	ph	NOUN
j386057681m	10	26	8.9	8.9	NUM
j386057681m	10	27	,	,	PUNCT
j386057681m	10	28	yielding	yield	VERB
j386057681m	10	29	hoì¢åè	hoì¢åè	NOUN
j386057681m	10	30	binding	bind	VERB
j386057681m	10	31	to	to	ADP
j386057681m	10	32	the	the	DET
j386057681m	10	33	fe	fe	PROPN
j386057681m	10	34	center	center	NOUN
j386057681m	10	35	and	and	CCONJ
j386057681m	10	36	reprotonation	reprotonation	NOUN
j386057681m	10	37	of	of	ADP
j386057681m	10	38	the	the	DET
j386057681m	10	39	arg-183	arg-183	PROPN
j386057681m	10	40	.	.	PUNCT
j386057681m	11	1	the	the	DET
j386057681m	11	2	catalytic	catalytic	ADJ
j386057681m	11	3	data	datum	NOUN
j386057681m	11	4	as	as	ADP
j386057681m	11	5	a	a	DET
j386057681m	11	6	function	function	NOUN
j386057681m	11	7	of	of	ADP
j386057681m	11	8	ph	ph	NOUN
j386057681m	11	9	show	show	NOUN
j386057681m	11	10	a	a	DET
j386057681m	11	11	pka	pka	PROPN
j386057681m	11	12	at	at	ADP
j386057681m	11	13	ph	ph	NOUN
j386057681m	11	14	6.5	6.5	NUM
j386057681m	11	15	,	,	PUNCT
j386057681m	11	16	likely	likely	ADJ
j386057681m	11	17	from	from	ADP
j386057681m	11	18	the	the	DET
j386057681m	11	19	protonation	protonation	NOUN
j386057681m	11	20	of	of	ADP
j386057681m	11	21	arg-183	arg-183	PROPN
j386057681m	11	22	and	and	CCONJ
j386057681m	11	23	suggest	suggest	VERB
j386057681m	11	24	a	a	DET
j386057681m	11	25	positively	positively	ADV
j386057681m	11	26	charged	charge	VERB
j386057681m	11	27	arg	arg	NOUN
j386057681m	11	28	is	be	AUX
j386057681m	11	29	needed	need	VERB
j386057681m	11	30	for	for	ADP
j386057681m	11	31	properly	properly	ADV
j386057681m	11	32	positioning	position	VERB
j386057681m	11	33	the	the	DET
j386057681m	11	34	anionic	anionic	ADJ
j386057681m	11	35	cloì¢åè	cloì¢åè	PROPN
j386057681m	11	36	within	within	ADP
j386057681m	11	37	the	the	DET
j386057681m	11	38	hydrophobic	hydrophobic	ADJ
j386057681m	11	39	distal	distal	ADJ
j386057681m	11	40	pocket	pocket	NOUN
j386057681m	11	41	for	for	ADP
j386057681m	11	42	reaction	reaction	NOUN
j386057681m	11	43	with	with	ADP
j386057681m	11	44	compound	compound	NOUN
j386057681m	11	45	i	i	NOUN
j386057681m	11	46	,	,	PUNCT
j386057681m	11	47	generating	generate	VERB
j386057681m	11	48	clì¢åè	clì¢åè	PROPN
j386057681m	11	49	and	and	CCONJ
j386057681m	11	50	oì¢	oì¢	SPACE
j386057681m	11	51	'	'	PUNCT
j386057681m	11	52	_	_	PUNCT
j386057681m	11	53	'	'	PUNCT
j386057681m	11	54	_	_	PRON
j386057681m	11	55	.	.	PUNCT
j386057681m	12	1	the	the	DET
j386057681m	12	2	positively	positively	ADV
j386057681m	12	3	charged	charge	VERB
j386057681m	12	4	arg-183	arg-183	SPACE
j386057681m	12	5	,	,	PUNCT
j386057681m	12	6	along	along	ADP
j386057681m	12	7	with	with	ADP
j386057681m	12	8	a	a	DET
j386057681m	12	9	hydrophobic	hydrophobic	ADJ
j386057681m	12	10	distal	distal	ADJ
j386057681m	12	11	pocket	pocket	NOUN
j386057681m	12	12	are	be	AUX
j386057681m	12	13	likely	likely	ADV
j386057681m	12	14	major	major	ADJ
j386057681m	12	15	determinants	determinant	NOUN
j386057681m	12	16	for	for	ADP
j386057681m	12	17	the	the	DET
j386057681m	12	18	unique	unique	ADJ
j386057681m	12	19	reactivity	reactivity	NOUN
j386057681m	12	20	of	of	ADP
j386057681m	12	21	the	the	DET
j386057681m	12	22	enzyme	enzyme	NOUN
j386057681m	12	23	.	.	PUNCT
j386057681m	13	1	this	this	DET
j386057681m	13	2	research	research	NOUN
j386057681m	13	3	suggests	suggest	VERB
j386057681m	13	4	that	that	SCONJ
j386057681m	13	5	formation	formation	NOUN
j386057681m	13	6	of	of	ADP
j386057681m	13	7	an	an	DET
j386057681m	13	8	electrophilic	electrophilic	ADJ
j386057681m	13	9	high	high	ADJ
j386057681m	13	10	valent	valent	ADJ
j386057681m	13	11	metal	metal	NOUN
j386057681m	13	12	-	-	PUNCT
j386057681m	13	13	oxo	oxo	NOUN
j386057681m	13	14	species	specie	NOUN
j386057681m	13	15	in	in	ADP
j386057681m	13	16	close	close	ADJ
j386057681m	13	17	vicinity	vicinity	NOUN
j386057681m	13	18	to	to	ADP
j386057681m	13	19	a	a	DET
j386057681m	13	20	nucleophilic	nucleophilic	ADJ
j386057681m	13	21	o	o	NOUN
j386057681m	13	22	-	-	NOUN
j386057681m	13	23	atom	atom	NOUN
j386057681m	13	24	containing	contain	VERB
j386057681m	13	25	anion	anion	NOUN
j386057681m	13	26	may	may	AUX
j386057681m	13	27	be	be	AUX
j386057681m	13	28	a	a	DET
j386057681m	13	29	structural	structural	ADJ
j386057681m	13	30	motif	motif	NOUN
j386057681m	13	31	utilized	utilize	VERB
j386057681m	13	32	by	by	ADP
j386057681m	13	33	biology	biology	NOUN
j386057681m	13	34	for	for	ADP
j386057681m	13	35	the	the	DET
j386057681m	13	36	difficult	difficult	ADJ
j386057681m	13	37	reaction	reaction	NOUN
j386057681m	13	38	of	of	ADP
j386057681m	13	39	forming	form	VERB
j386057681m	13	40	an	an	DET
j386057681m	13	41	o	o	NOUN
j386057681m	13	42	-	-	NOUN
j386057681m	13	43	o.	o.	NOUN