id sid tid token lemma pos ht24wh27j2k 1 1 due due ADP ht24wh27j2k 1 2 to to ADP ht24wh27j2k 1 3 their their PRON ht24wh27j2k 1 4 high high ADJ ht24wh27j2k 1 5 catalytic catalytic ADJ ht24wh27j2k 1 6 activity activity NOUN ht24wh27j2k 1 7 and and CCONJ ht24wh27j2k 1 8 low low ADJ ht24wh27j2k 1 9 - - PUNCT ht24wh27j2k 1 10 cost cost NOUN ht24wh27j2k 1 11 ni ni PROPN ht24wh27j2k 1 12 based base VERB ht24wh27j2k 1 13 catalysts catalyst NOUN ht24wh27j2k 1 14 are be AUX ht24wh27j2k 1 15 of of ADP ht24wh27j2k 1 16 special special ADJ ht24wh27j2k 1 17 interest interest NOUN ht24wh27j2k 1 18 for for ADP ht24wh27j2k 1 19 the the DET ht24wh27j2k 1 20 dry dry ADJ ht24wh27j2k 1 21 reforming reforming NOUN ht24wh27j2k 1 22 of of ADP ht24wh27j2k 1 23 methane methane NOUN ht24wh27j2k 1 24 ( ( PUNCT ht24wh27j2k 1 25 drm drm PROPN ht24wh27j2k 1 26 ) ) PUNCT ht24wh27j2k 1 27 , , PUNCT ht24wh27j2k 1 28 however however ADV ht24wh27j2k 1 29 , , PUNCT ht24wh27j2k 1 30 they they PRON ht24wh27j2k 1 31 also also ADV ht24wh27j2k 1 32 suffer suffer VERB ht24wh27j2k 1 33 from from ADP ht24wh27j2k 1 34 heavy heavy ADJ ht24wh27j2k 1 35 carbon carbon NOUN ht24wh27j2k 1 36 deposition deposition NOUN ht24wh27j2k 1 37 , , PUNCT ht24wh27j2k 1 38 which which PRON ht24wh27j2k 1 39 eventually eventually ADV ht24wh27j2k 1 40 results result VERB ht24wh27j2k 1 41 in in ADP ht24wh27j2k 1 42 catalyst catalyst NOUN ht24wh27j2k 1 43 deactivation deactivation NOUN ht24wh27j2k 1 44 . . PUNCT ht24wh27j2k 2 1 in in ADP ht24wh27j2k 2 2 this this DET ht24wh27j2k 2 3 dissertation dissertation NOUN ht24wh27j2k 2 4 , , PUNCT ht24wh27j2k 2 5 the the DET ht24wh27j2k 2 6 deactivation deactivation NOUN ht24wh27j2k 2 7 mechanism mechanism NOUN ht24wh27j2k 2 8 of of ADP ht24wh27j2k 2 9 ni ni PROPN ht24wh27j2k 2 10 supported support VERB ht24wh27j2k 2 11 catalysts catalyst NOUN ht24wh27j2k 2 12 during during ADP ht24wh27j2k 2 13 drm drm PROPN ht24wh27j2k 2 14 has have AUX ht24wh27j2k 2 15 been be AUX ht24wh27j2k 2 16 studied study VERB ht24wh27j2k 2 17 and and CCONJ ht24wh27j2k 2 18 highly highly ADV ht24wh27j2k 2 19 active active ADJ ht24wh27j2k 2 20 and and CCONJ ht24wh27j2k 2 21 stable stable ADJ ht24wh27j2k 2 22 ni ni PROPN ht24wh27j2k 2 23 based base VERB ht24wh27j2k 2 24 catalysts catalyst NOUN ht24wh27j2k 2 25 have have AUX ht24wh27j2k 2 26 been be AUX ht24wh27j2k 2 27 developed.to developed.to NUM ht24wh27j2k 2 28 decouple decouple NOUN ht24wh27j2k 2 29 active active ADJ ht24wh27j2k 2 30 metal metal NOUN ht24wh27j2k 2 31 - - PUNCT ht24wh27j2k 2 32 support support NOUN ht24wh27j2k 2 33 interactions interaction NOUN ht24wh27j2k 2 34 , , PUNCT ht24wh27j2k 2 35 first first ADJ ht24wh27j2k 2 36 ni ni PROPN ht24wh27j2k 2 37 supported support VERB ht24wh27j2k 2 38 on on ADP ht24wh27j2k 2 39 sio2 sio2 NOUN ht24wh27j2k 2 40 catalysts catalyst NOUN ht24wh27j2k 2 41 were be AUX ht24wh27j2k 2 42 studied study VERB ht24wh27j2k 2 43 . . PUNCT ht24wh27j2k 3 1 it it PRON ht24wh27j2k 3 2 was be AUX ht24wh27j2k 3 3 shown show VERB ht24wh27j2k 3 4 that that SCONJ ht24wh27j2k 3 5 carbon carbon NOUN ht24wh27j2k 3 6 mostly mostly ADV ht24wh27j2k 3 7 forms form VERB ht24wh27j2k 3 8 on on ADP ht24wh27j2k 3 9 bigger big ADJ ht24wh27j2k 3 10 ni ni PROPN ht24wh27j2k 3 11 crystallites crystallite NOUN ht24wh27j2k 3 12 , , PUNCT ht24wh27j2k 3 13 hence hence ADV ht24wh27j2k 3 14 , , PUNCT ht24wh27j2k 3 15 the the DET ht24wh27j2k 3 16 sintering sintering NOUN ht24wh27j2k 3 17 of of ADP ht24wh27j2k 3 18 ni ni PROPN ht24wh27j2k 3 19 particles particle NOUN ht24wh27j2k 3 20 is be AUX ht24wh27j2k 3 21 one one NUM ht24wh27j2k 3 22 of of ADP ht24wh27j2k 3 23 the the DET ht24wh27j2k 3 24 leading lead VERB ht24wh27j2k 3 25 causes cause NOUN ht24wh27j2k 3 26 for for ADP ht24wh27j2k 3 27 catalyst catalyst NOUN ht24wh27j2k 3 28 deactivation deactivation NOUN ht24wh27j2k 3 29 . . PUNCT ht24wh27j2k 4 1 a a DET ht24wh27j2k 4 2 novel novel ADJ ht24wh27j2k 4 3 synthesis synthesis NOUN ht24wh27j2k 4 4 method method NOUN ht24wh27j2k 4 5 , , PUNCT ht24wh27j2k 4 6 referred refer VERB ht24wh27j2k 4 7 to to ADP ht24wh27j2k 4 8 as as SCONJ ht24wh27j2k 4 9 " " PUNCT ht24wh27j2k 4 10 pressure pressure NOUN ht24wh27j2k 4 11 dilution dilution NOUN ht24wh27j2k 4 12 " " PUNCT ht24wh27j2k 4 13 was be AUX ht24wh27j2k 4 14 developed develop VERB ht24wh27j2k 4 15 , , PUNCT ht24wh27j2k 4 16 which which PRON ht24wh27j2k 4 17 allowed allow VERB ht24wh27j2k 4 18 the the DET ht24wh27j2k 4 19 preparation preparation NOUN ht24wh27j2k 4 20 of of ADP ht24wh27j2k 4 21 highly highly ADV ht24wh27j2k 4 22 dispersed disperse VERB ht24wh27j2k 4 23 ni ni PROPN ht24wh27j2k 4 24 / / SYM ht24wh27j2k 4 25 fumed fume VERB ht24wh27j2k 4 26 sio2 sio2 PROPN ht24wh27j2k 4 27 catalysts catalyst NOUN ht24wh27j2k 4 28 with with ADP ht24wh27j2k 4 29 increased increase VERB ht24wh27j2k 4 30 stability stability NOUN ht24wh27j2k 4 31 . . PUNCT ht24wh27j2k 5 1 in in ADP ht24wh27j2k 5 2 order order NOUN ht24wh27j2k 5 3 , , PUNCT ht24wh27j2k 5 4 to to PART ht24wh27j2k 5 5 prevent prevent VERB ht24wh27j2k 5 6 the the DET ht24wh27j2k 5 7 sintering sintering NOUN ht24wh27j2k 5 8 of of ADP ht24wh27j2k 5 9 ni ni PROPN ht24wh27j2k 5 10 active active ADJ ht24wh27j2k 5 11 sites site NOUN ht24wh27j2k 5 12 , , PUNCT ht24wh27j2k 5 13 nio nio PROPN ht24wh27j2k 5 14 - - PUNCT ht24wh27j2k 5 15 mgo mgo NOUN ht24wh27j2k 5 16 solid solid ADJ ht24wh27j2k 5 17 solution solution NOUN ht24wh27j2k 5 18 - - PUNCT ht24wh27j2k 5 19 based base VERB ht24wh27j2k 5 20 catalysts catalyst NOUN ht24wh27j2k 5 21 with with ADP ht24wh27j2k 5 22 strong strong ADJ ht24wh27j2k 5 23 metal metal NOUN ht24wh27j2k 5 24 - - PUNCT ht24wh27j2k 5 25 support support NOUN ht24wh27j2k 5 26 interactions interaction NOUN ht24wh27j2k 5 27 were be AUX ht24wh27j2k 5 28 developed develop VERB ht24wh27j2k 5 29 . . PUNCT ht24wh27j2k 6 1 cellulose cellulose NOUN ht24wh27j2k 6 2 assisted assist VERB ht24wh27j2k 6 3 solution solution NOUN ht24wh27j2k 6 4 combustion combustion NOUN ht24wh27j2k 6 5 synthesis synthesis NOUN ht24wh27j2k 6 6 ( ( PUNCT ht24wh27j2k 6 7 cacs cacs PROPN ht24wh27j2k 6 8 ) ) PUNCT ht24wh27j2k 6 9 method method NOUN ht24wh27j2k 6 10 was be AUX ht24wh27j2k 6 11 used use VERB ht24wh27j2k 6 12 to to PART ht24wh27j2k 6 13 synthesize synthesize VERB ht24wh27j2k 6 14 ni ni PROPN ht24wh27j2k 6 15 / / SYM ht24wh27j2k 6 16 mgo mgo PROPN ht24wh27j2k 6 17 catalysts catalyst NOUN ht24wh27j2k 6 18 with with ADP ht24wh27j2k 6 19 record record NOUN ht24wh27j2k 6 20 - - PUNCT ht24wh27j2k 6 21 high high ADJ ht24wh27j2k 6 22 surface surface NOUN ht24wh27j2k 6 23 areas area NOUN ht24wh27j2k 6 24 , , PUNCT ht24wh27j2k 6 25 which which PRON ht24wh27j2k 6 26 improved improve VERB ht24wh27j2k 6 27 their their PRON ht24wh27j2k 6 28 catalytic catalytic ADJ ht24wh27j2k 6 29 activity activity NOUN ht24wh27j2k 6 30 and and CCONJ ht24wh27j2k 6 31 stability stability NOUN ht24wh27j2k 6 32 . . PUNCT ht24wh27j2k 7 1 the the DET ht24wh27j2k 7 2 main main ADJ ht24wh27j2k 7 3 criterions criterion NOUN ht24wh27j2k 7 4 for for ADP ht24wh27j2k 7 5 the the DET ht24wh27j2k 7 6 stability stability NOUN ht24wh27j2k 7 7 towards towards ADP ht24wh27j2k 7 8 carbon carbon NOUN ht24wh27j2k 7 9 formation formation NOUN ht24wh27j2k 7 10 were be AUX ht24wh27j2k 7 11 determined determine VERB ht24wh27j2k 7 12 to to PART ht24wh27j2k 7 13 be be AUX ht24wh27j2k 7 14 metal metal NOUN ht24wh27j2k 7 15 dispersion dispersion NOUN ht24wh27j2k 7 16 , , PUNCT ht24wh27j2k 7 17 strong strong ADJ ht24wh27j2k 7 18 metal metal NOUN ht24wh27j2k 7 19 - - PUNCT ht24wh27j2k 7 20 support support NOUN ht24wh27j2k 7 21 interactions interaction NOUN ht24wh27j2k 7 22 , , PUNCT ht24wh27j2k 7 23 and and CCONJ ht24wh27j2k 7 24 an an DET ht24wh27j2k 7 25 increased increase VERB ht24wh27j2k 7 26 amount amount NOUN ht24wh27j2k 7 27 of of ADP ht24wh27j2k 7 28 ni3 ni3 PROPN ht24wh27j2k 7 29 + + NUM ht24wh27j2k 7 30 site site NOUN ht24wh27j2k 7 31 defects.to defects.to PRON ht24wh27j2k 7 32 reveal reveal VERB ht24wh27j2k 7 33 the the DET ht24wh27j2k 7 34 specifics specific NOUN ht24wh27j2k 7 35 of of ADP ht24wh27j2k 7 36 cacs cac NOUN ht24wh27j2k 7 37 method method VERB ht24wh27j2k 7 38 in in ADP ht24wh27j2k 7 39 obtaining obtain VERB ht24wh27j2k 7 40 high high ADJ ht24wh27j2k 7 41 surface surface NOUN ht24wh27j2k 7 42 area area NOUN ht24wh27j2k 7 43 materials material NOUN ht24wh27j2k 7 44 , , PUNCT ht24wh27j2k 7 45 mechanistic mechanistic ADJ ht24wh27j2k 7 46 studies study NOUN ht24wh27j2k 7 47 have have AUX ht24wh27j2k 7 48 been be AUX ht24wh27j2k 7 49 performed perform VERB ht24wh27j2k 7 50 ( ( PUNCT ht24wh27j2k 7 51 chapter chapter NOUN ht24wh27j2k 7 52 5 5 NUM ht24wh27j2k 7 53 ) ) PUNCT ht24wh27j2k 7 54 . . PUNCT ht24wh27j2k 8 1 it it PRON ht24wh27j2k 8 2 was be AUX ht24wh27j2k 8 3 found find VERB ht24wh27j2k 8 4 that that SCONJ ht24wh27j2k 8 5 combustion combustion NOUN ht24wh27j2k 8 6 parameters parameter NOUN ht24wh27j2k 8 7 , , PUNCT ht24wh27j2k 8 8 i.e. i.e. X ht24wh27j2k 8 9 , , PUNCT ht24wh27j2k 8 10 time time NOUN ht24wh27j2k 8 11 - - PUNCT ht24wh27j2k 8 12 temperature temperature NOUN ht24wh27j2k 8 13 profile profile NOUN ht24wh27j2k 8 14 , , PUNCT ht24wh27j2k 8 15 combustion combustion NOUN ht24wh27j2k 8 16 front front ADJ ht24wh27j2k 8 17 velocity velocity NOUN ht24wh27j2k 8 18 , , PUNCT ht24wh27j2k 8 19 etc etc X ht24wh27j2k 8 20 . . X ht24wh27j2k 8 21 , , PUNCT ht24wh27j2k 8 22 have have VERB ht24wh27j2k 8 23 a a DET ht24wh27j2k 8 24 direct direct ADJ ht24wh27j2k 8 25 impact impact NOUN ht24wh27j2k 8 26 on on ADP ht24wh27j2k 8 27 the the DET ht24wh27j2k 8 28 microstructure microstructure NOUN ht24wh27j2k 8 29 ( ( PUNCT ht24wh27j2k 8 30 phase phase NOUN ht24wh27j2k 8 31 composition composition NOUN ht24wh27j2k 8 32 , , PUNCT ht24wh27j2k 8 33 crystallinity crystallinity NOUN ht24wh27j2k 8 34 , , PUNCT ht24wh27j2k 8 35 morphology morphology NOUN ht24wh27j2k 8 36 , , PUNCT ht24wh27j2k 8 37 etc etc X ht24wh27j2k 8 38 . . X ht24wh27j2k 8 39 ) ) PUNCT ht24wh27j2k 8 40 of of ADP ht24wh27j2k 8 41 synthesized synthesized ADJ ht24wh27j2k 8 42 materials material NOUN ht24wh27j2k 8 43 . . PUNCT ht24wh27j2k 9 1 it it PRON ht24wh27j2k 9 2 was be AUX ht24wh27j2k 9 3 demonstrated demonstrate VERB ht24wh27j2k 9 4 that that SCONJ ht24wh27j2k 9 5 cellulose cellulose NOUN ht24wh27j2k 9 6 degradation degradation NOUN ht24wh27j2k 9 7 / / SYM ht24wh27j2k 9 8 decomposition decomposition NOUN ht24wh27j2k 9 9 itself itself PRON ht24wh27j2k 9 10 is be AUX ht24wh27j2k 9 11 being be AUX ht24wh27j2k 9 12 catalyzed catalyze VERB ht24wh27j2k 9 13 by by ADP ht24wh27j2k 9 14 metal metal NOUN ht24wh27j2k 9 15 ions ion NOUN ht24wh27j2k 9 16 and and CCONJ ht24wh27j2k 9 17 , , PUNCT ht24wh27j2k 9 18 depending depend VERB ht24wh27j2k 9 19 on on ADP ht24wh27j2k 9 20 metal metal NOUN ht24wh27j2k 9 21 ions ion NOUN ht24wh27j2k 9 22 , , PUNCT ht24wh27j2k 9 23 the the DET ht24wh27j2k 9 24 pyrolytic pyrolytic ADJ ht24wh27j2k 9 25 combustion combustion NOUN ht24wh27j2k 9 26 reaction reaction NOUN ht24wh27j2k 9 27 between between ADP ht24wh27j2k 9 28 metal metal NOUN ht24wh27j2k 9 29 nitrates nitrate NOUN ht24wh27j2k 9 30 and and CCONJ ht24wh27j2k 9 31 cellulose cellulose NOUN ht24wh27j2k 9 32 fibers fiber NOUN ht24wh27j2k 9 33 proceeds proceed VERB ht24wh27j2k 9 34 with with ADP ht24wh27j2k 9 35 different different ADJ ht24wh27j2k 9 36 mechanisms.to mechanisms.to NUM ht24wh27j2k 9 37 better well ADV ht24wh27j2k 9 38 understand understand VERB ht24wh27j2k 9 39 the the DET ht24wh27j2k 9 40 reaction reaction NOUN ht24wh27j2k 9 41 pathways pathway NOUN ht24wh27j2k 9 42 of of ADP ht24wh27j2k 9 43 the the DET ht24wh27j2k 9 44 drm drm NOUN ht24wh27j2k 9 45 , , PUNCT ht24wh27j2k 9 46 the the DET ht24wh27j2k 9 47 experimental experimental ADJ ht24wh27j2k 9 48 data datum NOUN ht24wh27j2k 9 49 obtained obtain VERB ht24wh27j2k 9 50 for for ADP ht24wh27j2k 9 51 ni ni PROPN ht24wh27j2k 9 52 / / SYM ht24wh27j2k 9 53 mgo mgo PROPN ht24wh27j2k 9 54 catalyst catalyst NOUN ht24wh27j2k 9 55 was be AUX ht24wh27j2k 9 56 used use VERB ht24wh27j2k 9 57 to to PART ht24wh27j2k 9 58 perform perform VERB ht24wh27j2k 9 59 kinetic kinetic ADJ ht24wh27j2k 9 60 simulations simulation NOUN ht24wh27j2k 9 61 . . PUNCT ht24wh27j2k 10 1 chapter chapter NOUN ht24wh27j2k 10 2 6 6 NUM ht24wh27j2k 10 3 presents present VERB ht24wh27j2k 10 4 drm drm NOUN ht24wh27j2k 10 5 kinetic kinetic PROPN ht24wh27j2k 10 6 simulation simulation NOUN ht24wh27j2k 10 7 results result NOUN ht24wh27j2k 10 8 , , PUNCT ht24wh27j2k 10 9 which which PRON ht24wh27j2k 10 10 were be AUX ht24wh27j2k 10 11 obtained obtain VERB ht24wh27j2k 10 12 by by ADP ht24wh27j2k 10 13 the the DET ht24wh27j2k 10 14 monte monte PROPN ht24wh27j2k 10 15 - - PUNCT ht24wh27j2k 10 16 carlo carlo PROPN ht24wh27j2k 10 17 based base VERB ht24wh27j2k 10 18 " " PUNCT ht24wh27j2k 10 19 kinetiscope kinetiscope PROPN ht24wh27j2k 10 20 " " PUNCT ht24wh27j2k 10 21 stochastic stochastic ADJ ht24wh27j2k 10 22 program program NOUN ht24wh27j2k 10 23 . . PUNCT ht24wh27j2k 11 1 drm drm PROPN ht24wh27j2k 11 2 reaction reaction NOUN ht24wh27j2k 11 3 network network NOUN ht24wh27j2k 11 4 was be AUX ht24wh27j2k 11 5 constructed construct VERB ht24wh27j2k 11 6 and and CCONJ ht24wh27j2k 11 7 simulated simulate VERB ht24wh27j2k 11 8 based base VERB ht24wh27j2k 11 9 on on ADP ht24wh27j2k 11 10 eley eley PROPN ht24wh27j2k 11 11 - - PUNCT ht24wh27j2k 11 12 rideal rideal ADJ ht24wh27j2k 11 13 and and CCONJ ht24wh27j2k 11 14 langmuir langmuir PROPN ht24wh27j2k 11 15 hinshelwood hinshelwood PROPN ht24wh27j2k 11 16 - - PUNCT ht24wh27j2k 11 17 hougen hougen PROPN ht24wh27j2k 11 18 watson watson PROPN ht24wh27j2k 11 19 type type NOUN ht24wh27j2k 11 20 models model NOUN ht24wh27j2k 11 21 , , PUNCT ht24wh27j2k 11 22 using use VERB ht24wh27j2k 11 23 single single ADJ ht24wh27j2k 11 24 and and CCONJ ht24wh27j2k 11 25 dual dual ADJ ht24wh27j2k 11 26 active active ADJ ht24wh27j2k 11 27 site site NOUN ht24wh27j2k 11 28 concepts concept NOUN ht24wh27j2k 11 29 . . PUNCT