id	sid	tid	token	lemma	pos
hm50tq59w9m	1	1	recent	recent	ADJ
hm50tq59w9m	1	2	studies	study	NOUN
hm50tq59w9m	1	3	showed	show	VERB
hm50tq59w9m	1	4	that	that	SCONJ
hm50tq59w9m	1	5	carbohydrates	carbohydrate	NOUN
hm50tq59w9m	1	6	play	play	VERB
hm50tq59w9m	1	7	critical	critical	ADJ
hm50tq59w9m	1	8	roles	role	NOUN
hm50tq59w9m	1	9	in	in	ADP
hm50tq59w9m	1	10	a	a	DET
hm50tq59w9m	1	11	lot	lot	NOUN
hm50tq59w9m	1	12	of	of	ADP
hm50tq59w9m	1	13	biological	biological	ADJ
hm50tq59w9m	1	14	activities	activity	NOUN
hm50tq59w9m	1	15	,	,	PUNCT
hm50tq59w9m	1	16	and	and	CCONJ
hm50tq59w9m	1	17	conformations	conformation	NOUN
hm50tq59w9m	1	18	of	of	ADP
hm50tq59w9m	1	19	carbohydrates	carbohydrate	NOUN
hm50tq59w9m	1	20	and	and	CCONJ
hm50tq59w9m	1	21	hydrogen	hydrogen	NOUN
hm50tq59w9m	1	22	bonds	bond	NOUN
hm50tq59w9m	1	23	were	be	AUX
hm50tq59w9m	1	24	believed	believe	VERB
hm50tq59w9m	1	25	to	to	PART
hm50tq59w9m	1	26	hold	hold	VERB
hm50tq59w9m	1	27	the	the	DET
hm50tq59w9m	1	28	key	key	NOUN
hm50tq59w9m	1	29	to	to	ADP
hm50tq59w9m	1	30	understanding	understand	VERB
hm50tq59w9m	1	31	these	these	DET
hm50tq59w9m	1	32	biological	biological	ADJ
hm50tq59w9m	1	33	functions	function	NOUN
hm50tq59w9m	1	34	of	of	ADP
hm50tq59w9m	1	35	oligosaccharides	oligosaccharide	NOUN
hm50tq59w9m	1	36	.	.	PUNCT
hm50tq59w9m	2	1	since	since	SCONJ
hm50tq59w9m	2	2	the	the	DET
hm50tq59w9m	2	3	pioneer	pioneer	NOUN
hm50tq59w9m	2	4	work	work	NOUN
hm50tq59w9m	2	5	of	of	ADP
hm50tq59w9m	2	6	karplus	karplus	ADJ
hm50tq59w9m	2	7	,	,	PUNCT
hm50tq59w9m	2	8	spin	spin	NOUN
hm50tq59w9m	2	9	-	-	PUNCT
hm50tq59w9m	2	10	spin	spin	NOUN
hm50tq59w9m	2	11	coupling	coupling	NOUN
hm50tq59w9m	2	12	constants	constant	NOUN
hm50tq59w9m	2	13	(	(	PUNCT
hm50tq59w9m	2	14	j	j	NOUN
hm50tq59w9m	2	15	-	-	PUNCT
hm50tq59w9m	2	16	coupling	coupling	NOUN
hm50tq59w9m	2	17	constants	constant	NOUN
hm50tq59w9m	2	18	)	)	PUNCT
hm50tq59w9m	2	19	had	have	AUX
hm50tq59w9m	2	20	been	be	AUX
hm50tq59w9m	2	21	the	the	DET
hm50tq59w9m	2	22	most	most	ADV
hm50tq59w9m	2	23	important	important	ADJ
hm50tq59w9m	2	24	and	and	CCONJ
hm50tq59w9m	2	25	reliable	reliable	ADJ
hm50tq59w9m	2	26	tool	tool	NOUN
hm50tq59w9m	2	27	in	in	ADP
hm50tq59w9m	2	28	conformational	conformational	NOUN
hm50tq59w9m	2	29	analysis.in	analysis.in	ADV
hm50tq59w9m	2	30	this	this	DET
hm50tq59w9m	2	31	thesis	thesis	NOUN
hm50tq59w9m	2	32	,	,	PUNCT
hm50tq59w9m	2	33	density	density	NOUN
hm50tq59w9m	2	34	functional	functional	ADJ
hm50tq59w9m	2	35	theory	theory	NOUN
hm50tq59w9m	2	36	(	(	PUNCT
hm50tq59w9m	2	37	dft	dft	PROPN
hm50tq59w9m	2	38	)	)	PUNCT
hm50tq59w9m	2	39	was	be	AUX
hm50tq59w9m	2	40	used	use	VERB
hm50tq59w9m	2	41	to	to	PART
hm50tq59w9m	2	42	calculate	calculate	VERB
hm50tq59w9m	2	43	j	j	NOUN
hm50tq59w9m	2	44	-	-	PUNCT
hm50tq59w9m	2	45	coupling	coupling	NOUN
hm50tq59w9m	2	46	constants	constant	NOUN
hm50tq59w9m	2	47	involving	involve	VERB
hm50tq59w9m	2	48	hydroxyl	hydroxyl	PROPN
hm50tq59w9m	2	49	protons	proton	NOUN
hm50tq59w9m	2	50	,	,	PUNCT
hm50tq59w9m	2	51	while	while	SCONJ
hm50tq59w9m	2	52	systematically	systematically	ADV
hm50tq59w9m	2	53	changes	change	VERB
hm50tq59w9m	2	54	the	the	DET
hm50tq59w9m	2	55	dihedral	dihedral	ADJ
hm50tq59w9m	2	56	angles	angle	NOUN
hm50tq59w9m	2	57	of	of	ADP
hm50tq59w9m	2	58	interest	interest	NOUN
hm50tq59w9m	2	59	.	.	PUNCT
hm50tq59w9m	3	1	karplus	karplus	PROPN
hm50tq59w9m	3	2	-	-	PUNCT
hm50tq59w9m	3	3	like	like	ADJ
hm50tq59w9m	3	4	equations	equation	NOUN
hm50tq59w9m	3	5	paramerized	paramerize	VERB
hm50tq59w9m	3	6	were	be	AUX
hm50tq59w9m	3	7	in	in	ADP
hm50tq59w9m	3	8	good	good	ADJ
hm50tq59w9m	3	9	agreement	agreement	NOUN
hm50tq59w9m	3	10	with	with	ADP
hm50tq59w9m	3	11	previously	previously	ADV
hm50tq59w9m	3	12	reported	report	VERB
hm50tq59w9m	3	13	equations	equation	NOUN
hm50tq59w9m	3	14	,	,	PUNCT
hm50tq59w9m	3	15	in	in	ADP
hm50tq59w9m	3	16	which	which	PRON
hm50tq59w9m	3	17	small	small	ADJ
hm50tq59w9m	3	18	non	non	ADJ
hm50tq59w9m	3	19	-	-	ADJ
hm50tq59w9m	3	20	carbohydrate	carbohydrate	ADJ
hm50tq59w9m	3	21	molecules	molecule	NOUN
hm50tq59w9m	3	22	were	be	AUX
hm50tq59w9m	3	23	used	use	VERB
hm50tq59w9m	3	24	as	as	ADP
hm50tq59w9m	3	25	model	model	NOUN
hm50tq59w9m	3	26	compounds	compound	NOUN
hm50tq59w9m	3	27	.	.	PUNCT
hm50tq59w9m	4	1	newly	newly	ADV
hm50tq59w9m	4	2	obtained	obtain	VERB
hm50tq59w9m	4	3	karplus	karplus	ADJ
hm50tq59w9m	4	4	equations	equation	NOUN
hm50tq59w9m	4	5	were	be	AUX
hm50tq59w9m	4	6	used	use	VERB
hm50tq59w9m	4	7	to	to	PART
hm50tq59w9m	4	8	interpret	interpret	VERB
hm50tq59w9m	4	9	experimentally	experimentally	ADV
hm50tq59w9m	4	10	collected	collect	VERB
hm50tq59w9m	4	11	3jhcoh	3jhcoh	NUM
hm50tq59w9m	4	12	and	and	CCONJ
hm50tq59w9m	4	13	3jccoh	3jccoh	NUM
hm50tq59w9m	4	14	coupling	coupling	NOUN
hm50tq59w9m	4	15	constants	constant	NOUN
hm50tq59w9m	4	16	in	in	ADP
hm50tq59w9m	4	17	methyl	methyl	NOUN
hm50tq59w9m	4	18	-	-	PUNCT
hm50tq59w9m	4	19	d	d	NOUN
hm50tq59w9m	4	20	-	-	NOUN
hm50tq59w9m	4	21	ìøåáand	ìøåáand	ADJ
hm50tq59w9m	4	22	ìøå¢-lactoside	ìøå¢-lactoside	ADV
hm50tq59w9m	4	23	.	.	PUNCT
hm50tq59w9m	5	1	low	low	ADJ
hm50tq59w9m	5	2	temperature	temperature	NOUN
hm50tq59w9m	5	3	(	(	PUNCT
hm50tq59w9m	5	4	20	20	NUM
hm50tq59w9m	5	5	ìø'_å¡c	ìø'_å¡c	PROPN
hm50tq59w9m	5	6	)	)	PUNCT
hm50tq59w9m	5	7	and	and	CCONJ
hm50tq59w9m	5	8	mixed	mixed	ADJ
hm50tq59w9m	5	9	solvent	solvent	NOUN
hm50tq59w9m	6	1	(	(	PUNCT
hm50tq59w9m	6	2	aceton	aceton	PROPN
hm50tq59w9m	6	3	-	-	PUNCT
hm50tq59w9m	6	4	d6	d6	PROPN
hm50tq59w9m	6	5	and	and	CCONJ
hm50tq59w9m	6	6	water	water	NOUN
hm50tq59w9m	6	7	)	)	PUNCT
hm50tq59w9m	6	8	were	be	AUX
hm50tq59w9m	6	9	applied	apply	VERB
hm50tq59w9m	6	10	to	to	PART
hm50tq59w9m	6	11	reduce	reduce	VERB
hm50tq59w9m	6	12	the	the	DET
hm50tq59w9m	6	13	exchange	exchange	NOUN
hm50tq59w9m	6	14	between	between	ADP
hm50tq59w9m	6	15	hydroxyl	hydroxyl	PROPN
hm50tq59w9m	6	16	protons	proton	NOUN
hm50tq59w9m	6	17	and	and	CCONJ
hm50tq59w9m	6	18	bulk	bulk	ADJ
hm50tq59w9m	6	19	solvent	solvent	NOUN
hm50tq59w9m	6	20	.	.	PUNCT
hm50tq59w9m	7	1	most	most	ADJ
hm50tq59w9m	7	2	h	h	PROPN
hm50tq59w9m	7	3	-	-	PUNCT
hm50tq59w9m	7	4	c	c	NOUN
hm50tq59w9m	7	5	-	-	PUNCT
hm50tq59w9m	7	6	o	o	NOUN
hm50tq59w9m	7	7	-	-	PUNCT
hm50tq59w9m	7	8	h	h	NOUN
hm50tq59w9m	7	9	coupling	coupling	NOUN
hm50tq59w9m	7	10	constants	constant	NOUN
hm50tq59w9m	7	11	measured	measure	VERB
hm50tq59w9m	7	12	were	be	AUX
hm50tq59w9m	7	13	in	in	ADP
hm50tq59w9m	7	14	the	the	DET
hm50tq59w9m	7	15	4	4	NUM
hm50tq59w9m	7	16	-	-	SYM
hm50tq59w9m	7	17	6	6	NUM
hm50tq59w9m	7	18	hz	hz	PROPN
hm50tq59w9m	7	19	range	range	NOUN
hm50tq59w9m	7	20	,	,	PUNCT
hm50tq59w9m	7	21	which	which	PRON
hm50tq59w9m	7	22	should	should	AUX
hm50tq59w9m	7	23	be	be	AUX
hm50tq59w9m	7	24	expected	expect	VERB
hm50tq59w9m	7	25	from	from	ADP
hm50tq59w9m	7	26	a	a	DET
hm50tq59w9m	7	27	free	free	ADJ
hm50tq59w9m	7	28	c	c	NOUN
hm50tq59w9m	7	29	-	-	PUNCT
hm50tq59w9m	7	30	o	o	NOUN
hm50tq59w9m	7	31	rotation	rotation	NOUN
hm50tq59w9m	7	32	.	.	PUNCT
hm50tq59w9m	8	1	however	however	ADV
hm50tq59w9m	8	2	,	,	PUNCT
hm50tq59w9m	8	3	an	an	DET
hm50tq59w9m	8	4	exceptionally	exceptionally	ADV
hm50tq59w9m	8	5	small	small	ADJ
hm50tq59w9m	8	6	coupling	coupling	NOUN
hm50tq59w9m	8	7	(	(	PUNCT
hm50tq59w9m	8	8	2.8	2.8	NUM
hm50tq59w9m	8	9	hz	hz	NOUN
hm50tq59w9m	8	10	)	)	PUNCT
hm50tq59w9m	8	11	for	for	ADP
hm50tq59w9m	8	12	h3'-c3'-o3'-h	h3'-c3'-o3'-h	NOUN
hm50tq59w9m	8	13	suggested	suggest	VERB
hm50tq59w9m	8	14	a	a	DET
hm50tq59w9m	8	15	rotational	rotational	ADJ
hm50tq59w9m	8	16	bias	bias	NOUN
hm50tq59w9m	8	17	of	of	ADP
hm50tq59w9m	8	18	c3'-o3	c3'-o3	SPACE
hm50tq59w9m	8	19	'	'	PART
hm50tq59w9m	8	20	bond	bond	NOUN
hm50tq59w9m	8	21	.	.	PUNCT
hm50tq59w9m	9	1	changing	change	VERB
hm50tq59w9m	9	2	solvent	solvent	NOUN
hm50tq59w9m	9	3	to	to	AUX
hm50tq59w9m	9	4	dmso	dmso	ADV
hm50tq59w9m	9	5	reduced	reduce	VERB
hm50tq59w9m	9	6	the	the	DET
hm50tq59w9m	9	7	coupling	coupling	NOUN
hm50tq59w9m	9	8	constants	constant	NOUN
hm50tq59w9m	9	9	further	far	ADV
hm50tq59w9m	9	10	to	to	ADP
hm50tq59w9m	9	11	~	~	PROPN
hm50tq59w9m	9	12	1.3	1.3	NUM
hm50tq59w9m	9	13	hz	hz	NOUN
hm50tq59w9m	9	14	,	,	PUNCT
hm50tq59w9m	9	15	indicating	indicate	VERB
hm50tq59w9m	9	16	stronger	strong	ADJ
hm50tq59w9m	9	17	bias	bias	NOUN
hm50tq59w9m	9	18	in	in	ADP
hm50tq59w9m	9	19	non	non	ADJ
hm50tq59w9m	9	20	-	-	ADJ
hm50tq59w9m	9	21	protic	protic	ADJ
hm50tq59w9m	9	22	solvent	solvent	NOUN
hm50tq59w9m	9	23	.	.	PUNCT
hm50tq59w9m	10	1	this	this	DET
hm50tq59w9m	10	2	bias	bias	NOUN
hm50tq59w9m	10	3	was	be	AUX
hm50tq59w9m	10	4	consistent	consistent	ADJ
hm50tq59w9m	10	5	with	with	ADP
hm50tq59w9m	10	6	the	the	DET
hm50tq59w9m	10	7	gauche	gauche	PROPN
hm50tq59w9m	10	8	conformation	conformation	NOUN
hm50tq59w9m	10	9	of	of	ADP
hm50tq59w9m	10	10	c3'-o3	c3'-o3	SPACE
hm50tq59w9m	10	11	'	'	PUNCT
hm50tq59w9m	10	12	in	in	ADP
hm50tq59w9m	10	13	crystal	crystal	NOUN
hm50tq59w9m	10	14	structure	structure	NOUN
hm50tq59w9m	10	15	and	and	CCONJ
hm50tq59w9m	10	16	was	be	AUX
hm50tq59w9m	10	17	interpreted	interpret	VERB
hm50tq59w9m	10	18	as	as	ADP
hm50tq59w9m	10	19	potential	potential	ADJ
hm50tq59w9m	10	20	hydrogen	hydrogen	NOUN
hm50tq59w9m	10	21	bonding	bonding	NOUN
hm50tq59w9m	10	22	between	between	ADP
hm50tq59w9m	10	23	o3'-h	o3'-h	NUM
hm50tq59w9m	10	24	in	in	ADP
hm50tq59w9m	10	25	the	the	DET
hm50tq59w9m	10	26	glucose	glucose	NOUN
hm50tq59w9m	10	27	ring	ring	NOUN
hm50tq59w9m	10	28	and	and	CCONJ
hm50tq59w9m	10	29	ring	ring	NOUN
hm50tq59w9m	10	30	oxygen	oxygen	NOUN
hm50tq59w9m	10	31	(	(	PUNCT
hm50tq59w9m	10	32	o5	o5	PROPN
hm50tq59w9m	10	33	)	)	PUNCT
hm50tq59w9m	10	34	in	in	ADP
hm50tq59w9m	10	35	the	the	DET
hm50tq59w9m	10	36	galactose	galactose	NOUN
hm50tq59w9m	10	37	ring	ring	NOUN
hm50tq59w9m	10	38	.	.	PUNCT
hm50tq59w9m	11	1	the	the	DET
hm50tq59w9m	11	2	hydrogen	hydrogen	NOUN
hm50tq59w9m	11	3	bond	bond	NOUN
hm50tq59w9m	11	4	was	be	AUX
hm50tq59w9m	11	5	studied	study	VERB
hm50tq59w9m	11	6	theoretically	theoretically	ADV
hm50tq59w9m	11	7	,	,	PUNCT
hm50tq59w9m	11	8	and	and	CCONJ
hm50tq59w9m	11	9	its	its	PRON
hm50tq59w9m	11	10	strength	strength	NOUN
hm50tq59w9m	11	11	(	(	PUNCT
hm50tq59w9m	11	12	~	~	PUNCT
hm50tq59w9m	11	13	4	4	NUM
hm50tq59w9m	11	14	kcal	kcal	PROPN
hm50tq59w9m	11	15	/	/	SYM
hm50tq59w9m	11	16	mol	mol	PROPN
hm50tq59w9m	11	17	)	)	PUNCT
hm50tq59w9m	11	18	was	be	AUX
hm50tq59w9m	11	19	in	in	ADP
hm50tq59w9m	11	20	line	line	NOUN
hm50tq59w9m	11	21	with	with	ADP
hm50tq59w9m	11	22	normal	normal	ADJ
hm50tq59w9m	11	23	hydrogen	hydrogen	NOUN
hm50tq59w9m	11	24	bond	bond	NOUN
hm50tq59w9m	11	25	.	.	PUNCT
hm50tq59w9m	12	1	a	a	DET
hm50tq59w9m	12	2	few	few	ADJ
hm50tq59w9m	12	3	experiments	experiment	NOUN
hm50tq59w9m	12	4	were	be	AUX
hm50tq59w9m	12	5	designed	design	VERB
hm50tq59w9m	12	6	to	to	PART
hm50tq59w9m	12	7	find	find	VERB
hm50tq59w9m	12	8	direct	direct	ADJ
hm50tq59w9m	12	9	evidence	evidence	NOUN
hm50tq59w9m	12	10	of	of	ADP
hm50tq59w9m	12	11	this	this	DET
hm50tq59w9m	12	12	h	h	NOUN
hm50tq59w9m	12	13	-	-	PUNCT
hm50tq59w9m	12	14	bonding	bonding	NOUN
hm50tq59w9m	12	15	.	.	PUNCT
hm50tq59w9m	13	1	some	some	DET
hm50tq59w9m	13	2	interesting	interesting	ADJ
hm50tq59w9m	13	3	observations	observation	NOUN
hm50tq59w9m	13	4	were	be	AUX
hm50tq59w9m	13	5	made	make	VERB
hm50tq59w9m	13	6	,	,	PUNCT
hm50tq59w9m	13	7	however	however	ADV
hm50tq59w9m	13	8	,	,	PUNCT
hm50tq59w9m	13	9	none	none	NOUN
hm50tq59w9m	13	10	of	of	ADP
hm50tq59w9m	13	11	them	they	PRON
hm50tq59w9m	13	12	could	could	AUX
hm50tq59w9m	13	13	firmly	firmly	ADV
hm50tq59w9m	13	14	prove	prove	VERB
hm50tq59w9m	13	15	the	the	DET
hm50tq59w9m	13	16	persistency	persistency	NOUN
hm50tq59w9m	13	17	of	of	ADP
hm50tq59w9m	13	18	this	this	DET
hm50tq59w9m	13	19	h	h	PROPN
hm50tq59w9m	13	20	-	-	PUNCT
hm50tq59w9m	13	21	bond.trans	bond.tran	NOUN
hm50tq59w9m	13	22	-	-	PUNCT
hm50tq59w9m	13	23	glycoside	glycoside	NOUN
hm50tq59w9m	13	24	linkage	linkage	NOUN
hm50tq59w9m	13	25	coupling	coupling	NOUN
hm50tq59w9m	13	26	pathways	pathway	NOUN
hm50tq59w9m	13	27	c	c	X
hm50tq59w9m	13	28	-	-	PUNCT
hm50tq59w9m	13	29	o	o	NOUN
hm50tq59w9m	13	30	-	-	PUNCT
hm50tq59w9m	13	31	c	c	NOUN
hm50tq59w9m	13	32	-	-	PUNCT
hm50tq59w9m	13	33	h	h	PROPN
hm50tq59w9m	13	34	and	and	CCONJ
hm50tq59w9m	13	35	c	c	X
hm50tq59w9m	13	36	-	-	PUNCT
hm50tq59w9m	13	37	o	o	NOUN
hm50tq59w9m	13	38	-	-	PUNCT
hm50tq59w9m	13	39	c	c	NOUN
hm50tq59w9m	13	40	-	-	PUNCT
hm50tq59w9m	13	41	c	c	NOUN
hm50tq59w9m	13	42	are	be	AUX
hm50tq59w9m	13	43	another	another	DET
hm50tq59w9m	13	44	focus	focus	NOUN
hm50tq59w9m	13	45	of	of	ADP
hm50tq59w9m	13	46	this	this	DET
hm50tq59w9m	13	47	thesis	thesis	NOUN
hm50tq59w9m	13	48	.	.	PUNCT
hm50tq59w9m	14	1	early	early	ADJ
hm50tq59w9m	14	2	parameterizations	parameterization	NOUN
hm50tq59w9m	14	3	of	of	ADP
hm50tq59w9m	14	4	c	c	X
hm50tq59w9m	14	5	-	-	PUNCT
hm50tq59w9m	14	6	o	o	NOUN
hm50tq59w9m	14	7	-	-	PUNCT
hm50tq59w9m	14	8	c	c	NOUN
hm50tq59w9m	14	9	-	-	PUNCT
hm50tq59w9m	14	10	h	h	PROPN
hm50tq59w9m	14	11	and	and	CCONJ
hm50tq59w9m	14	12	c	c	X
hm50tq59w9m	14	13	-	-	PUNCT
hm50tq59w9m	14	14	o	o	NOUN
hm50tq59w9m	14	15	-	-	PUNCT
hm50tq59w9m	14	16	c	c	NOUN
hm50tq59w9m	14	17	-	-	PUNCT
hm50tq59w9m	14	18	c	c	PROPN
hm50tq59w9m	14	19	assumed	assume	VERB
hm50tq59w9m	14	20	similar	similar	ADJ
hm50tq59w9m	14	21	karplus	karplus	ADJ
hm50tq59w9m	14	22	behavior	behavior	NOUN
hm50tq59w9m	14	23	as	as	ADP
hm50tq59w9m	14	24	vicinal	vicinal	ADJ
hm50tq59w9m	14	25	h	h	NOUN
hm50tq59w9m	14	26	-	-	PUNCT
hm50tq59w9m	14	27	h	h	NOUN
hm50tq59w9m	14	28	couplings	coupling	NOUN
hm50tq59w9m	14	29	.	.	PUNCT
hm50tq59w9m	15	1	however	however	ADV
hm50tq59w9m	15	2	,	,	PUNCT
hm50tq59w9m	15	3	there	there	PRON
hm50tq59w9m	15	4	is	be	VERB
hm50tq59w9m	15	5	no	no	DET
hm50tq59w9m	15	6	rigorous	rigorous	ADJ
hm50tq59w9m	15	7	theoretical	theoretical	ADJ
hm50tq59w9m	15	8	support	support	NOUN
hm50tq59w9m	15	9	of	of	ADP
hm50tq59w9m	15	10	this	this	DET
hm50tq59w9m	15	11	assumption	assumption	NOUN
hm50tq59w9m	15	12	.	.	PUNCT
hm50tq59w9m	16	1	in	in	ADP
hm50tq59w9m	16	2	this	this	DET
hm50tq59w9m	16	3	thesis	thesis	NOUN
hm50tq59w9m	16	4	,	,	PUNCT
hm50tq59w9m	16	5	it	it	PRON
hm50tq59w9m	16	6	is	be	AUX
hm50tq59w9m	16	7	clearly	clearly	ADV
hm50tq59w9m	16	8	shown	show	VERB
hm50tq59w9m	16	9	that	that	SCONJ
hm50tq59w9m	16	10	electronegative	electronegative	ADJ
hm50tq59w9m	16	11	substituents	substituent	NOUN
hm50tq59w9m	16	12	can	can	AUX
hm50tq59w9m	16	13	significantly	significantly	ADV
hm50tq59w9m	16	14	affect	affect	VERB
hm50tq59w9m	16	15	the	the	DET
hm50tq59w9m	16	16	karplus	karplus	NOUN
hm50tq59w9m	16	17	-	-	PUNCT
hm50tq59w9m	16	18	like	like	ADJ
hm50tq59w9m	16	19	behavior	behavior	NOUN
hm50tq59w9m	16	20	of	of	ADP
hm50tq59w9m	16	21	these	these	DET
hm50tq59w9m	16	22	coupling	coupling	NOUN
hm50tq59w9m	16	23	pathways	pathway	NOUN
hm50tq59w9m	16	24	;	;	PUNCT
hm50tq59w9m	16	25	hence	hence	ADV
hm50tq59w9m	16	26	substituent	substituent	NOUN
hm50tq59w9m	16	27	effects	effect	NOUN
hm50tq59w9m	16	28	should	should	AUX
hm50tq59w9m	16	29	be	be	AUX
hm50tq59w9m	16	30	considered	consider	VERB
hm50tq59w9m	16	31	when	when	SCONJ
hm50tq59w9m	16	32	interpreting	interpret	VERB
hm50tq59w9m	16	33	the	the	DET
hm50tq59w9m	16	34	experimental	experimental	ADJ
hm50tq59w9m	16	35	data	datum	NOUN
hm50tq59w9m	16	36	.	.	PUNCT
hm50tq59w9m	17	1	substituent	substituent	NOUN
hm50tq59w9m	17	2	effects	effect	NOUN
hm50tq59w9m	17	3	are	be	AUX
hm50tq59w9m	17	4	systematically	systematically	ADV
hm50tq59w9m	17	5	studied	study	VERB
hm50tq59w9m	17	6	for	for	ADP
hm50tq59w9m	17	7	c	c	PROPN
hm50tq59w9m	17	8	-	-	PUNCT
hm50tq59w9m	17	9	o	o	NOUN
hm50tq59w9m	17	10	-	-	PUNCT
hm50tq59w9m	17	11	c	c	NOUN
hm50tq59w9m	17	12	-	-	PUNCT
hm50tq59w9m	17	13	c	c	NOUN
hm50tq59w9m	17	14	coupling	coupling	NOUN
hm50tq59w9m	17	15	constants	constant	NOUN
hm50tq59w9m	17	16	.	.	PUNCT
hm50tq59w9m	18	1	the	the	DET
hm50tq59w9m	18	2	results	result	NOUN
hm50tq59w9m	18	3	support	support	VERB
hm50tq59w9m	18	4	the	the	DET
hm50tq59w9m	18	5	usage	usage	NOUN
hm50tq59w9m	18	6	of	of	ADP
hm50tq59w9m	18	7	karplus	karplus	NOUN
hm50tq59w9m	18	8	-	-	PUNCT
hm50tq59w9m	18	9	like	like	ADJ
hm50tq59w9m	18	10	equations	equation	NOUN
hm50tq59w9m	18	11	for	for	ADP
hm50tq59w9m	18	12	c	c	X
hm50tq59w9m	18	13	-	-	PUNCT
hm50tq59w9m	18	14	o	o	NOUN
hm50tq59w9m	18	15	-	-	PUNCT
hm50tq59w9m	18	16	c	c	NOUN
hm50tq59w9m	18	17	-	-	PUNCT
hm50tq59w9m	18	18	c	c	NOUN
hm50tq59w9m	18	19	coupling	coupling	NOUN
hm50tq59w9m	18	20	pathway	pathway	NOUN
hm50tq59w9m	18	21	,	,	PUNCT
hm50tq59w9m	18	22	with	with	ADP
hm50tq59w9m	18	23	some	some	DET
hm50tq59w9m	18	24	necessary	necessary	ADJ
hm50tq59w9m	18	25	modifications	modification	NOUN
hm50tq59w9m	18	26	when	when	SCONJ
hm50tq59w9m	18	27	electronegative	electronegative	ADJ
hm50tq59w9m	18	28	substituents	substituent	NOUN
hm50tq59w9m	18	29	exist	exist	VERB
hm50tq59w9m	18	30	.	.	PUNCT